ML25106A052

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Pre-Submittal Meeting for 10 CFR Part 20, 10 CFR Part 50 Appendix I, and 40 CFR Part 190 Exemption Request Regarding Application of Potassium Hydroxide
ML25106A052
Person / Time
Site: Sequoyah  Tennessee Valley Authority icon.png
Issue date: 04/07/2025
From:
Tennessee Valley Authority
To: Kimberly Green
NRC/NRR/DORL/LPL2-2
Buckberg, P
References
Download: ML25106A052 (1)


Text

Sequoyah Nuclear Plant April 7, 2025 Pre-submittal Meeting for 10 CFR Part 20, 10 CFR Part 50 Appendix I, and 40 CFR Part 190 Exemption Request Regarding application of Potassium Hydroxide (KOH) to control Reactor Coolant System pH

Agenda

  • Introduction
  • Purpose
  • Regulations Applicable to Sequoyah ODCM
  • Sequoyah Technical Specification
  • History of Rulemaking
  • Proposed Exemption
  • Basis for Proposed Exemption
  • Precedents
  • Summary
  • Schedule for Submittal 2

Introduction

  • U.S. Government Accountability Office raised questions in 2013 regarding supply of Enriched LiOH for nuclear power reactors; supply chain concern exists to this day.

Enriched LiOH is currently sourced only from Russia and China Enriched LiOH is normally used in PWRs to control pH in RCS

  • Utilities reached out to Electric Power Research Institute (EPRI) to identify other chemicals suitable for this application.
  • EPRI reported that KOH has been used for decades in Eastern European Russian style reactors, VVERs, similar to PWRs in design.
  • EPRI created a KOH Advisory group and identified the plants that would meet target criteria for KOH application.

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Introduction

  • Sequoyah (SQN) best met the target criteria for KOH application.
  • SQN is planning addition of KOH to control the pH of the primary side reactor coolant, a first of a kind application for a North American PWR.

Identified the need to revise the SQN offsite dose calculation manual (ODCM) to account for radionuclides associated with KOH.

Regulatory guidance including Regulatory Guide 1.109 and NUREG-0172 are based on standards for dose calculations developed before application of KOH was a consideration for pH control.

As a result, the method for determining dose conversion factors associated with KOH radionuclides of Chlorine, Potassium, and Argon are not part of the current license basis for SQN.

Methods for determining needed dose conversion factors are available in International Commission on Radiological Protection (ICRP) and Federal Guidance Report (FGR) standards l 4

Purpose

  • The purpose of this meeting is to discuss the need for a permanent exemption to the operating licenses for SQN Units 1 and 2 from the following regulations, as they relate to the application of KOH.

10 CFR Part 20 10 CFR Part 50 Appendix I 40 CFR 190

  • Exemption needed to support a revision of the SQN ODCM that accounts for the additional radionuclides generated when using KOH.

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Regulations Applicable to SQN ODCM 10 CFR Part 20 Standards for Protection Against Radiation 10 CFR Part 20.1302, Compliance with dose limits for individual members of the public.

10 CFR Part 20 Appendix B, Annual Limits on Intake (ALIs) and Derived Air Concentrations (DACs) of Radionuclides for Occupational Exposure; Effluent Concentrations; Concentrations for Release to Sewerage.

10 CFR Part 20.2301 Applications for exemptions - Exemptions may be granted if the Commission determines the exemption is authorized by law and would not result in undue hazard to life or property.

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Regulations Applicable to SQN ODCM 10 CFR Part 50 Domestic Licensing of Production and Utilization Facilities 10 CFR Part 50.36a, Technical specifications on effluents from nuclear power reactors 10 CFR Part 50 Appendix I, Numerical Guides for Design Objectives and Limiting Conditions for Operation to Meet the Criterion "As Low as is Reasonably Achievable" for Radioactive Material in Light-Water-Cooled Nuclear Power Reactor Effluents 10 CFR Part 50.12 Specific exemptions 50.12(a)(1) Exemptions may be granted if the Commission determines the exemption is authorized by law and would not result in undue hazard to life or property 50.12(a)(2)(vi) Special circumstances present not considered when the regulation was adopted for which it would be in public interest to grant an exemption l 7

Regulations Applicable to SQN ODCM 40 CFR Part 190 Environmental Radiation Protection Standards for Nuclear Power Operations 40 CFR 190.10 Standards for Normal Operations Annual dose equivalent limits to any member of the public Limits on radioactive materials entering the general environment from the entire uranium fuel cycle l 8

SQN Technical Specification l 9 Proposed exemption would not change any of the existing SQN TS requirements.

Proposed exemption would allow SQN to evaluate continued compliance with TS 5.5.1 and TS 5.5.3 with the implementation of KOH for pH control.

SQN Technical Specification l 10

History of Rulemaking l 11 SECY-01-0148 Process for revision of 10 CFR Part 20 regarding adoption of ICRP recommendations on occupational dose limits and dosimetric models and parameters.

Some licensees have requested exemption from sections of 10 CFR Part 20 that allows them to use updated ICRP internal dosimetry models.

Exemption requests have been granted on case-by-case basis.

SECY-12-0064 Recommended Staff development of draft 10 CFR Part 20 regulatory basis to align with ICRP 103.

Significant NRC effort put forth including Advance Notice of Public Rulemaking (ANPR) and solicitation of public and stakeholder input.

SECY-16-0009 Enclosure 1 subsequently concluded that current regulatory framework provided adequate protection and recommended rulemaking be discontinued.

Proposed Exemption Proposed exemption would be an allowance to use the following ICRP and FGR methodologies to calculate dose coefficients associated with identified KOH radionuclides for the purpose of evaluating compliance with the requirements of 10 CFR Part 20, 10 CFR 50 Appendix I and 40 CFR 190.

ICRPs 72, 119, 144 and 151 along with FGR-12 and FGR-15 to determine dose coefficients for radionuclides of Chlorine, Potassium and Argon only.

Proposed exemption would not apply to the determination of dose coefficients for any other radionuclides.

This would be a permanent exemption for SQN Units 1 and 2.

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Basis for Proposed Exemption 10 CFR Part 50 Appendix I, 40 CFR 190 and 10 CFR Part 20 are based on ICRP 2 and ICRP 30 which do not account for KOH as an RCS pH control agent.

NRC has recognized that current regulations and guidance documents are static in relation to developments in standards such as ICRPs and others.

ICRPs 72, 119, 144, and 151 are industry standards.

FGR-12 and FGR-15 were developed jointly by the Environmental Protection Agency (EPA) and Oak Ridge National Laboratory (ORNL) for use in implementing radiation protection programs.

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Precedents

Approved exemption from all sections of 10 CFR Part 20 that referred to quantities in Appendix B and instead use quantities calculated using ICRP 68.

Commission approval of the Staff granting of exemptions on a case-by-case basis.

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Summary l 15 Recognized supply chain concerns for continued availability of Enriched LiOH.

SQN is working with EPRI to evaluate the use of KOH as an alternative to Enriched LiOH for reactor coolant pH control.

Use of KOH would introduce radionuclides not considered in the current licensing basis for SQN.

Existing regulations do not support use of newer ICRP methodologies needed for calculation of KOH radionuclide dose coefficients for inclusion in the ODCM for SQN.

Proposed exemption would be an allowance to use the identified FGR and ICRP methodologies to calculate KOH radionuclide dose coefficients.

Schedule for Submittal l 16

  • TVA requests NRC approval by August 31, 2025 Allows for timely revision and approvals of the SQN ODCM Supports fall 2025 refueling outage for SQN Unit 1