ML20237K653
| ML20237K653 | |
| Person / Time | |
|---|---|
| Site: | Vermont Yankee  |
| Issue date: | 08/17/1987 |
| From: | Martin T NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I) |
| To: | Murphy W VERMONT YANKEE NUCLEAR POWER CORP. |
| References | |
| NUDOCS 8708190353 | |
| Download: ML20237K653 (2) | |
Text
__ __.
i AUG 171987 Docket No. 50-271 Vermont Yankee Nuclear Power Corporation ATTN: Mr. Warren P. Murphy Vice President and Manager of Operations RD 5, Box 169 Ferry Road Brattleboro, Vermont 05301 Gentlemen:
Subject:
Results of Non-Radiological Chemistry Standards Inspection Activities for All Region I Licensees Routine safety inspections were conducted by this office during the period 1985 to 1986 at USNRC Region I licensees in the area of non-radiological water chemistry laboratory operations. The purpose of this report is to present results of all licensees inspected, as well as results of measurements made by Brookhaven National Laboratory. Each licensee is identified by a code. Your codes are 21, 22.
No reply to this letter is required.
Sincerely, Thomas T. Martin, Director Division of Radiation Safety and Safeguards
Enclosure:
Combined Results of Non-radiological Standards Comparison Inspection Activities for Region I Licensees j i
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OFFICIAL RECORD COPY LTR RAD RESULTS - 0035.0.0 06/17/87 -0y 8708190353 B70817 PDR ADOCK 05000271 G PDR 1 ,
l Vermont Yankee Nuclear Power 2 cc w/ encl:
R. W. Capstick, Licensing Engineer J. Gary Weigand, President and Chief Executive Officer J. P. Pelletier, Plant Manager
! Donald Hunter, Vice President l Cort Richardson, Vermont Public Interest Research Group, Inc.
Gerald Tarrant, Commissioner, Department of Public Service Public Document Room (PDR)
( Local Public Document Room -(LPDR)
Nuclear Safety Information Center (NSIC)
NRC Resident Inspector State of New Hampshire State of Vermont bec w/ encl:
i Region I Docket Room (with concurrences)
Management Assistant, DRMA (w/o enc 1)
! Section Chief, DRP l M. McBride, RI, Pilgrim l H. Eichenholz, SRI, Yankee l V. Rooney, LPM, NRR l Robert J. Bores, DRSS 4
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,i Combined Results of Non-Radiological Standards
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! Inspectors: Y l t Harvey Zibulsky,( Chesitst, Effluents. Radiation Protection Section, P&RPB, DRSS
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- 1. Introduction l
Region I has implemented an inspection program in the area of non-radio-logical water chemistry. As part of this inspection program, licensees are required to analyze test standards prepared by Brock"aven National Laboratory (BNL) for NRC Region I. The data from the first round of this part of the inspection program are now available from all power reactors in Region I and are presented here.
l The data as presented permits each Region I nuclear power plant chemistry laboratory to compare its performance with all other Region ' nuclear l
power plant laboratories. The data for the BNL known values are also l presented so that comparison of the average from all Region I sites to y the known value may be made. The data were taken from irspection ;
reports, but are ceded here. The letter transmitting this report ;
l identified the individual code (s) for each addressee. Section 3.0 lists ;
the inspection repcrts data were taken from. The data are presented in Appendix B.
- 2. Data Analysis i j The data were analy ed as follows. i l
l 1. The analytical data from all Region I sites were entered into a data base at ENL. The analytical data consisted of each licensee's result for each analyte at each analyzed concentration.
- 2. At each concentration a grand average and standard deviation were calculated using the data from all sites.
l 3. A range consisting of the grand average plus or mir.;s two standard deviations was established. Any values outside of this range were considered outliers.
- 4. A new grand average and standard deviation were calculated excluding the outliers determined in step 3.
- 5. A range consisting of the grand average plus or minus two standard' deviations was again established. Any values outs 4ce this range were considered outliers.
- 6. The above precess was repeated until a range was cbtained with no outliers. This range was used for the data comparison.
A sample calculation is presented in Appendix A.
.~
l It must be recognized that the data used to generate the averages are not of equal weight. For example, some laboratories were permitted to reanalyze the standards if problems could be identified and corrected during the inspection. Also some of the BNL standards were diluted to different final concentrations by the licensees prior to analysis to allow them to analyze within their calibration range. The results were then normalized back to the original dilution in order to enable compa-ison.
In addition, all methods of analysis for a particular analyte were grouped together.
- 3.
References:
j Site Docket No. Inspection No.
Beaver Valley #1 50-334 85-07 Beaver Valley #2 50-412 86-14 l, Calvert Cliffs #1 50-317 86-08 ,
l Calvert Cliffs #2 50-318 86-08 l FitzPatrick 50-333' 85-23 Ginna 50-244 85-14 Ct. Yankee 50-213 85-24 Hope Creek 50-354 85-59 Indian Pt. #2 50-247 86-07 l Indian Pt. #3 50-286 86-04 Limerick 50-352 86-10 Maine Yankee 50-309 85-33 !
Millstone #1 50-245 86-04 l Millstone #2 50-336 86-04 Millstone #3 50-423 86-13 Nine Mile Pt. #1 50-220 85-30 Oyster Creek 50-219 86-16 l Peach Bottom #2 50-277 85-28 Peach Bottom #3 50-278 85-26 Pilgrim 50-293 85-23 i Salem #1 50-272 86-03 Salem #2 50-311 86-03 Seabrook 50-443 86-22 Shoreham 50-322 86-11 Susquehanna #1 50-387 85-27 Susquehanna #2 50-388 85-22 Three Mile Island #1 50-289 85-17 Vermont Yankee 50-271 85-38 Yankee Atomic 50-29 85-21'
l Appendix A Sample Calculation The chloride measurements at approximately 30 ppb were chosen for this example.
Step 1 1 The following data were in the BNL data base for chloride at approximately 30 ppb. i l
Site No. Value (ppb) Site No. Value (ppb) Site No. Value (ppb) 1 30.7 16 27.1 31* 26.7 2 30 17 39.3 32* 71 3 30.2 18 28.8 33 not analyzed 4 24.3 19 28 5 30.9 20 29.3 l 6 30.9 21 23.3 '
7 32.7 22 28.9 8 38.3 23 not analyzed 9 32 24 30.7 10 34.2 25 not analyzed 11 37 26* 41.3 12 28.7 27 33 13 not analyzed 28 -
14 30.7 29 52
- normalized data 15* 43.35 30 29.7 Step 2 i
A grand average and standard deviation were calculated for all 28 values:
Grand average = 33.6804 = I xi n
Standard deviation = 9.5116 _ yg n-1 Step 3 From step two above, a range of 52.7036 - 14.6572 was established. The value from site 32 was determined to be an outlier.
Step 4 A new grand average and standard deviation were calculated excluding the outlier determined in Step 3.
grand average = 32.2981 (n=27) standard deviation - 6.1966
Appendix A Sample Calculation (continued) l Step 5 From step 4 above a range of 44.6914 - 19.9048 was established. The value ;
from site 29 was determined to be an outlier. l Step 6 The above process was completed through seven more iterations as follows: l n x s range outlier sites 26 31.5404 4.8796 41.2996 - 21.7812 26, 15 24 30.6417 3.8514 38.3444 - 22.9390 17 23 30.2652 3.4571 37.1794 - 23.3510 8, 21 21 30.2143 2.7368 35.6880 - 24.7406 4, 11 19 30.1684 1.9542 34.0768 - 26.2600 10 18 29.9444 1.7419 33.4283 - 26.4605 None j j
Thus out of a total of 28 values 10 were outliers. The range of 33.4283 -
26.4605, which contained no outliers, was used for final comparison.
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