ML20237K302

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Forwards Results of Nonradiological Chemistry Stds Region I Insp Activities for All Licensees During 1985-1986 Re Nonradiological Water Chemistry Lab Operations
ML20237K302
Person / Time
Site: Shoreham File:Long Island Lighting Company icon.png
Issue date: 08/14/1987
From: Martin T
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I)
To: Leonard J
LONG ISLAND LIGHTING CO.
References
NUDOCS 8708190191
Download: ML20237K302 (4)
v • d • e


Text

_

OG 1 4 1987 j

Docket No.

50-322 i

Long Island Lighting Company ATTN: Mr. John D. Leonard, Jr.

Vice President - Nuclear P. O. Box 618 Shoreham Nuclear Power Station Wading River, New York 11792 Gentlemen:

Subject:

Results of Non-Radiological Chemistry Standards Inspection Activities for All Region I Licensees Routine safety inspections were conducted by this office during the period 1985 to 1986 at USNRC Region I licensees in the area of non-radiological water chemistry laboratory operations.

The purpose of this report is to present results of all licensees inspected, as well as results of measurements made by Brookhaven National Laboratory.

Each licensee is identified by a code.

Your code is 30.

No reply to this letter is required.

Sincerely, Thomas T. Martin, Director Division of Radiation Safety and Safeguards

Enclosure:

Combined Results of Non-radiological Standards Comparison Inspection Activities for Region I Licensees 0FFICIAL RECORD COPY LTR RAD RESULTS - 0011.0.0 06/09/87 2

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l-Long Island Lighting Company 2

cc w/ enc 1:

W. Steiger, Plant Manager B. McCaffrey, Manager, Nuclear Operations Support

'R. Kubinak, Director, QA, Safety and Compliance E Youngling, Manager, Nuclear Engineering Anthony F. Earley, Jr., General Counsel Jeffrey L. Futter, Esquire J. Notaro, Manager, QA Department Director, Power Division Shoreham Hearing Service List Public Document Room (PDR)

Local Public Document Room (LPDR)

Nuclear Safety Information Center (NSIC)

NRC Resident Inspector State of New York bec w/ enc 1:

Region I Docket Room (with concurrences)

Management Assistant, DRMA (w/o encl)

Director, DRSS Director, DRS DRP Section Chief B. Bordenick, ELD R. Goddard, ELD Robert J. Bores, DRSS Y

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87 0FFICIAL RECORD COPY LTR RAD RESULTS - 0012.0.0 06/09/87

1:

E SHOREHAM HEARING SERVICE LIST l'

' Gerald C. Crotty, Esquirej Alan S. Rosenthal, Esquire v Ben Wiles, Esquire Chairman, Atomic Safety and Licensing Counsel to the Governor Appeal Panel Executive Chamber U. S. Nuclear Regulatory Commission l

State Capitol Washington, D. C. 20555 Albany, New York 12224 Mr. Jay Dunkleberger /

Fabian G. Palomino, Esquire y New York State Energy Office Suffolk County Attorney i

Agency Building 2 Executive Chamber Empire State Plaza State Capitol Albany, New York 12223 Albany, NY 12224 Energy Research Group, Inc.j Gary J. Edles, Esquire d 400-1 Totten Pond Road Atomic Safety and Licensing Waltham, Massachusetts 02154 Appeal Panel l

U. S. Nuclear Regulatory Commission Washington, D. C. 20555 W. Taylor Reveley, III, Esquire v-Howard A. Wilbur, Esquire /

Hunton & Williams Atomic Safety and Licensing Post Office Box 1535 Appeal Panel Richmond, Virginia 23212 U. S. Nuclear Regulatory Commission Washington, D. C. 20555

. Honorable Michael Logrande Robert Abrams, Esquire Acting Suffolk County Executive Peter Bienstock, Esquire" l

County Executive / Legislative Bldg.

Department of Law Veteran's Memorial Highway State of New York Hauppauge, New York 11788 Room 46-14 Two World Trade Center New York, New York 10047 Martin Bradley Ashare, Esquire V Richard M. Kessel

]

Suffolk County Attorney Chairman and Executive Director 1

H. Lee Dennison Building New York State Consumer Protection Board j

Veteran's Memorial Highway Room 1725 J

Hauppauge, New York 11788 250 Broadway New York, New York 10007 James B. Dougherty, Esquire d 3045 Porter Street, N.W.

Washington, D.C.

20008 I

l l

2 4

MHB Technical Associates Francis J. Gluchowski t/

l

' 1723 Hamilton Avenue, Suite K Assistant Town Attorney San Jose, California 95125 Town of Brookhaven Department of Law Stephen Latham, Esquire )

3233 Route 112 John F. Shea, Esquire Medford, New York 11763

. Twomey, Latham & Shea Post Office Box 398-Paul Sabatino, II, Attorney at Law y 33 West Second Street Counsel to Legislature Riverhead, New York 11901 Legislative Building Veteran's Memorial Highway Jonathan D. Feinberg, Esquire /

Joseph I. Lieberman, Attorney General /

New York State State of Connecticut Department of Public Service 30 Trinity Street Three Empire State Plaza Hartford, Connecticut 06106 Albany, New York 12223 Ezra I. Bialik, Esquire j

Brookhaven Town Attorney

/

~ Assistant Attorney General 3233 Route 112 Environmental Protection Bureau Medford, New York 11763 New York State' Department of Law 2 World Trade Center Department of Public Service New York, New York 10047 Director, Power Division Three Empire State Plaza Herbert H. Brown, Esquire j Albany, New York 12223 j

Lawrence Coe Lamnpher, Esquire Kirkpatrick, Lockhart, Hill, Christopher & Phillips 1900 M Street, N.W.

Washington, D.C.

20036 Karla J. Letsche, Esquire v Kirkpatrick, Lockhart, Hill, Christopher & Phillips 1900 M Street, N.W.

l Washington, D.C.

20036

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I 1

l U.S. NUCLEAR REGULATORY COMMISSION REGION I i

Combined Results of Non-Radiological Standards Comparison Ir.spection Activities for Region I Licensees Inspectors:

M Harvey Zibulsky, ChemtM, Effluents Radiation Protection Section, EP R

, DRSS

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James I Kottan, Rad'iation Laboratory Specialist,

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Effluents Radiation Protection Section, EP&RPB, DRSS

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R, Approved By:

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&u Walter J. Pasciak, Chie,

ffluents Radiation Protection Sec n, EP&RPB, DRSS nown-se

Details 1

1.

Introduction Region I has implemented an inspection program in the area of non-radio-j logical water chemistry.

As part of this inspection program, licensees are required to analyze test standards prepared by Brookhaven National Laboratory (BNL) for NRC Region 1.

The data from the first round of this l

part of the inspection program are now available from all power reactors in Region I and are presented here.

The data as presented permits each Region I nuclear power plant chemistry laboratory to compare its performance with all other Region I nuclear power plant laboratories. The data for the BNL known values are also presented so that comparison of.the average from all Region I sites to l

the known value may be made.

The data were taken from inspection 1

reports, but are coded here.

The letter transmitting this report identified the individual code (s) for each addressee.

Section 3.0 lists the inspection reports data were taken from.

The data are presented in Appendix B.

2.

Data Analysis The data were analyzed as follows.

1.

The analytical data from all Region I sites were entered into a data base at BNL.

The analytical data consisted of each licensee's result for each analyte at each analyzed concentration.

2.

At each concentration a grand average and standard deviation were calculated using the data from all sites.

3.

A range consisting of the grand average plus or minus two standard deviations was established. Any values outside of this range were considered outliers.

4.

A new grand average and standard deviation were calculated excluding the outliers determined in step 3.

5.

A range consisting of the grand average plus or minus two standard

)

deviations was again established.

Any values outside this range were considered outliers.

6.

The above process was repeated until a range was obtained with no outliers. This range was used for the data comparison.

A sample calculation is presented in Appendix A.

a It must be recognized that the data used to generate the-averages are not-of equal weight.

For example, some laboratories were permitted to reanalyze the standards.if problems could be identified and corrected during the inspection. Also'some of the BNL standards were diluted to different final. concentrations by the licensees prior.to analysis to allow

~

them to analyze within their calibration range.

The results were then normalized back-to the original dilution in. order to enable comparison.

H In addition, all methods of analysis for a particular analyte were grouped-together.

3,

References:

Site Occket No.

Inspection No.

Beaver Valley #1 50-334 85-07 Beaver Valley #2 50-412 14 Calvert Cliffs #1 50-317 86-08

'Calvert Cliffs #2 50-318 86-08 FitzPatrick 50-333 85-23 l

Ginna 50-244 85-14 Ct. Yankee-50-213 85-24 Hope Creek 50-354 85-59 Indian Pt #2 50-247-86-07 Indian Pt. #3 50-286 86-04 Limerick 50-352 86 !

Maine Yankee 50-309 85 Millstone #1 50-245 86-04 Millstone #2 50-336 86-04 Millstone #3 50-423 86-13 Nine Mile Pt. #1 50-220 85-10 Oyster Creek 50-219 86-16 Peach Bottom #2 50-277 85-28 Peach Bottom #3 50-278 85-26 Pilgrim 50-293 85-23 Salem #1 50-272 86-03 Salem #2 50-311 86-03 J

Seabrook 50-443 86-22 Shoreham 50-322 86-11 q

Susquehanna #1 50-387 85-27 j

Susquehanna #2 50-388 85-22 Three Mile Island #1 50-289 85-17 Vermont Yankee 50-271 85-38 Yankee Atomic 50-29 85-21 4

1

Appendix A Sample Calculation

'The chloride measurements at approximately 30 ppb were chosen for this example.

Step 1

.The following data were in the BNL data base for chloride at approximately 30 ppb.

Site No.

Value (ppb) Site No.

Value (ppb)

Site No.

Value (ppb) 1 30.7 16 27.1 31*

'26.7 2

30 17 39.3 32*

71 3

30.'2 18 28.8 33 not analyzed 4

24.3 19 28 5

30.9

'20 29.3 6

30.9 21 23.3 7

32.7 22 28.9 8'

38.3 23 not analyzed 9

32 24 30.7 10 34.2 25 not analyzed 11 37 26*

41.3 12 28.7-27 33 13 not analyzed 28 14 30.7 29 52

  • n:rmalized data 15*

43.35 30 29.7 Step 2 A grand average and standard deviation were calculated for all 28 values:

Grand average = 33.6804 I xi n

Standard deviation = 9.5116 I (xi-x)2 _y2

=

n-1 Step 3 From step two above, a range of 52.7036 - 14.6572 was esta:lished.

The value from site 32 was determined to be an outlier.

Step 4.

A new grand average and standard deviation were calculate: excluding the outlier determined in Step 3.

grand average = 32.2981 (n=27) standard deviation - 6.1966

Appendix A Sample Calculation (continued)

Step 5 From step 4 above a range of 44.6914 - 19.9048 was established.

The value from site 29 was determined to be an outlier.

Step 6 j

The above process was completed through seven more iterations as follows:

.n x

s range outlier sites 26 31.5404 4.8796 41.2996 - 21.7812 26, 15 24 30.6417 3.8514 38.3444 - 22.9390 17 23 30.2652 3.4571 37.1794 - 23.3510 8, 21 21 30.2143 2.7368 35.6880 - 24.7406 4, 11 19 30.1684 1.9542 34.0768 - 26.2600 10 18 29.9444 1.7419 33.4283 - 26.4605 None Thus out of a total of 28 values 10 were outliers. The range of 33.4283 -

26.4605, which contained no outliers, was used for final comparison.

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