ML20237J644

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Forwards Combined Results of Nonradiological Stds Comparison Insp Activities for Region I Licensees for 1985-1986. Facility Identified by Code 1
ML20237J644
Person / Time
Site: Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png
Issue date: 08/12/1987
From: Martin T
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I)
To: Mroczka E
CONNECTICUT YANKEE ATOMIC POWER CO.
References
NUDOCS 8708180269
Download: ML20237J644 (2)
v • d • e


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, 12 AUG 19871 Docket No. 50-213 Connecticut Yankee Atomic Power Company ATTN: Mr. E. J. Mroczka Senior Vice President - Nuclear Engineering and Operations Group P. O. Box 270 Hartford, Connecticut 06141 Gentlemen:

Subject:

Results of Non-Radiological Chemistry Standards Inspection Activities for All Region I Licensees Routine safety inspections were conducted by this office during the period 1985 to 1986 at USNRC Region I licensees in the area of non-radiological water chemistry laboratory operations. The purpose of this report is to present results of all licensees inspected, as well as results of measurements made by Brookhaven National Laboratory. Each licensee is identified by a code. Your code is 1.

No reply to this letter is required.

Sincerely, Ori inal Signed y e

Tho as . Marti , irector Division of Radiation Safety and Safeguards

Enclosure:

Combined Results of Non-radiological Standards Comparison Inspection Activities for Region I Licensees 8708180269 B70812 PDR ADOCK 05000213 G PDR OFFICIAL RECORD COPY LTR RAD RESULTS - 0039.0.0 06/09/87

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T Connecticut Yankee Atomic 2- -1'2 AUG 19874

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. Power Company '

cc w/ encl:-

O. B. Miller, Station Superintendent D. 0. Nordquist, Manager of Quality Assurance

'R. M. Kacich, Manager, Generation Facilities Licensing

.W. D._Romberg, Vice President,. Nuclear'Cperations Gerald Garfield, Esquire Public Document Room (PDR)

Local Public Document Room (LPDR)

Nuclear. Safety .Information Center (NSIC):

NRC Resident InspectorL State of Connecticut-bec w/ encl: ~

Region I Docket Room (with concurrences)

. Management Assistant, DRMA (w/o enc 1)

Section Chief, DRP M. McBride, RI, Pilgrim J. Shedlosky,,. SRI, Millstone 1&2 T.'Rebelowski, SRI, Millstone 3 J. Akstulewicz, LPM, NRR

'R. Bores, DRSS l

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. RI:DRSS h  : SS lL(A1 RI:DRSS RI: RS

-Kottan/geb/mlb. Zibulsky. iak Bellamy Mar n 1/ /87. 6/lI/87 87 B/ $/87 6 /7 0FFICIAL RECORD COPY LTR RAD RESULTS - 0040.0.0 06/09/87

4

) U.S. NUCLEAR REGULATORY COMMISSION REGION I Combined Results of Non-Radiological Standards Comparison Inspection Activities for Region I Licensees Inspectors: hM M Harvey Zibulsky, ahemfM, Effluents l Radiation Protection Section, EP RPB DRSS

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James J! Kottan, Radriatiori Laboratory Specialist, '

Effluents Radiat on Pr te tion Secti n, EP&RPB, DRSS Approved By: ()n a . \ 0~)()

Wa er J. Pascia , Chief,' Ef flueni.s Radiation -

1 Protection Sec lon, EP&RPB, DRSS l l

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1. Introduction.

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[ ~ Region'I has implemented an inspection program in the area of non-radio- l L logical water chemistry. As part of this inspection program, licensees ]

tare required to analyze test standards prepared by Brockhaven National i Laboratory (BNL) for NRC Region I. The data from the first round of this

.part of-the inspection program are now available from all power reactors q

'in Region I and are presented here.

The data a's presented ~ permits each Region I nuclear power plant chemistry laboratory to corpare;its performance with all other Region I nuclear i power plant laboratories. The data for the-BNL known values are also presented so that comparison of the average from all Region I sites.to the known value ray be made. The data'were taken from inspection .-

reports, but are coded here. The letter transmitting this report identified the' individual code (s) for each addressee. Section 3.0 lists the inspection reports data were taken from. The data are presented in Appendix B.

L - 2. Data Analysis-p The. data'were analyzed as follows.

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1. The analytical data from all Region I sites were entered into a q

-data base at BNL. The analytical data consisted of each licensee's result for each analyte at each analyzed concentration. j

)

'2. At each concentration a grand average and standard deviction were

' calculated using the data fram all sites.

3. A range consisting of the grand average plus or minus two standard

~ deviations was established. Any values outside of this range were j considered outliers.

4. A new grand average and standard deviation were calculated excluding the outliers determined in step 3.
5. A range consisting of the grand average plus or minus two standard deviations was again. established. Any values outside this range were considered outliers.
6. The above process was repeated until a range was cbtained with no

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outliers. This range was used for the data comparison.

A sample calculation is presented in Appendix A.

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.O 4

It must be recognized that the data used to generate.the averages are not of equal weight. For. example, some laboratories were permitted to j reanalyze the standards if problems could be identified and corrected during the inspection. Also some of the BNL standards were diluted to different final concentrations by the licensees prior to analysis to allow them to analyze within their calibration range. The results.were then.

normalized back- to' the original dilution in order to enable ccmparison.

In addition, all methods of analysis for a particular analyte were grouped together.

3.

References:

Site Docket No. Inspection No.

Beaver Valley #1 50-334 85-07

. Beaver Valley.#2 50-412 86-14 Calvert Cliffs'#1' 50-317 86-08 Calvert-Cliffs #2 50-318 86-08 FitzPatrick 50-333 85-23 Ginna 50-244 85-14 Ct. Yankee- 50-213 85-24 Hope Creek 50-354 85-59' Indian Pt. #2 50-247 86-07 Indian Pt. #3 50-286 86-04 Limerick 50-352 86-10 Maine Yankee 50-309 85-33 Millstone #1 50-245 86-04 Millstone #2 50-336 86-04 Millstone #3 50-423 86-13 Nine Mile Pt. #1 50-220 85-10 Oyster Creek 50-219 86-16 Peach Bottom #2 50-277 85-28 Peach Bottom #3 50-278 85-26 Pilgrim 50-293 85-23 Salem #1 50-272 86-03

~ Salem #2 50-311 86-03 Seabrook 50-443 86-22 Shoreham 50-322 86-11 Susquehanna #1 50-387 85-27 Susquehanna #2 50-388 85-22 Three Mile Island #1 50-289 85-17 Vermont Yankee 50-271 85-38 Yankee Atomic 50-29 85-21 ,

1 1

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l L______________

Appendix A Sample Calculation The chloride measurements at approximately 30 ppb were chosen for this example.

Step 1 The following data were in the BNL data base for chloride at approximately 30 ppb.

l Site No. Value (ppb) Site No. Value (ppb) Site No. Value (ppb) 1 30.7 16 27.1 31* 26.7 2 30 17 39.3 32* 71 3 30.2 18 28.8 33 not analyzed 4 24.3 19 28 5 30.9 20 29.3 6 30.9 21 23.3 7 32.7 22 28.9 8 38.3 23 not analyzed 9 32 24 30.7 10 34.2 25 not analyzed 11 37 26* 41.3 l 12 28.7 27 33 13 not analyzed 28 -

l 14 30.7 29 52

  • normalized data l 15* 43.35 30 29.7 Step 2 l

A grand average and standard deviation were calculated for all 28 values:

Grand average = 33.6804 , I xi j n

Standard deviation = 9.5116 _ _ e/

= I (xi-x)2 _l2 j n-1 i

_l j Step 3 '

From step two above, a range of 52.7036 - 14.6572 was established. The value from site 32 was determined to be an outlier.

Step 4 A new grand average and standard deviation were calculated excluding the outlier determined in Step 3.

grand average = 32.2981 (nr27)  !

standard deviation - 6.1966 l l

l I

i

Appendix A Sample Calculation (continued)

Step 5 From step 4 above a range of 44.6914 - 19.9048 was established. The value from site 29 was determined to be an outlier.

Step 6 The above process was completed through seven more iterations as follows:

n x s range outlier sites 26 31.5404 4.8796 41.2996 - 21.7812 26, 15 24 30.6417 3.8514 38.3444 - 22.9390 17 23 30.2652 3.4571 37.1794 - 23.3510 8, 21 21 30.2143 2.7368 35.6880 - 24.7406 4, 11 19 30.1684 1.9542 34.0768 - 26.2600 10  ;

18 29.9444 1.7419 33.4283 - 26.4605 None Thus out of a total of 28 values 10 were outliers. The range of 33.4283 -

26.4605, which contained no outliers, was used for final comparison.

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