ML20236W876
| ML20236W876 | |
| Person / Time | |
|---|---|
| Site: | Wolf Creek  |
| Issue date: | 07/30/1998 |
| From: | Warren C WOLF CREEK NUCLEAR OPERATING CORP. |
| To: | NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM) |
| References | |
| WO-98-0076, WO-98-76, NUDOCS 9808060271 | |
| Download: ML20236W876 (180) | |
Text
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W$LF CREEK NUCLEAR OPERATING CORPORATION i
Clay C. Warren
)
Vice PresrJent & Chief Operating Officer JUL 3 01998 WO 98-0076 i
{
U. O. Nuclear Regulatory Commission ATTN: Document Control Desk Mail Station F1-137 j
Washington, D. C.
20555
Subject:
Docket 50-482:
Application for Renewal of the Wolf Creek Generating Station National Pollutant Discharge Elimination System Permit Gentlemen:
This letter transmits a copy of Wolf Creek Generating Station's application for renewal of its National Pollutant Discharge El!.minati on System (NPDES)
Permit.
This submittal is made pursuant to Wolf Creek Generating Station Facility Operating License NPF-42, Appendix B, Section 3.2.
Very truly yours, C y C. Warren CCW/jad Enclosure cc:
W.
D. Johnson (NRC), w/a E. W. Merschoff (NRC), w/a J. F. Ringwald (NRC), w/a K. M. Thomas (NRC), w/a f
}
9808060271 98'd730 PDR ADOOK 05000482 P
PDR i
P.O. Box 411/ Purlington, KS 66839 / Phone: (316) 364-8831 An Equal Opportunity Employer WF/HC/ VET D
o W9LF CREEK NUCLEAR OPERATING CORPORATION Clay C. Warren Vke President and Chief Operating Omcer Ju1y 36, 1998 RP 98-0155 Kansas Department of Health and Environment Technical Services, Bureau of Water Forbes Field, Building 283 Topeka,KS 66620 Attention: Mr. Om Agrawal
Reference:
(1) Letter dated May 11,19s8 from Edward Dillingham (KDHE) to R. Logsdon (WCNOC), NPDES Permit Renewal (2) Letter dated September 22,1995 frorr. W. Woods (WCNOC) to R. Angelo (KDHE), Public Access to Wolf Creek Lal e (3) Letter dated January 21,1998 from D.
illiamson (WCNOC) to M. Massoth (KDHE), Request to increase Copper-Trol Discharge Concentration
Subject:
Renewal of the Wolf Creek Generating Station National Pollutant Discharge Elimination System (NPDES) Permit KS 0079057/I-NE07-P002 DearMr. Agrawal Please find enclosed the completed forms and information necessary to renew NPDES Permit for Wolf Creek Nuclear Operating Corporation (WCNOC). TEble 1.0, Water Treatment Chemicals Used at Wolf Creek, and the Wolf Creek Water Use Flow Diagram are attached for your use in reviewing the concentrations and discharge flowpaths previously approved for water treatment chemicals used at Wolf Creek Generating Station (WCGS). Material safety data sheets and aquatic toxicity data for these water treatment chemicals products are included in accordance with Edward Dillingham's request (Reference 1).
We request that KDHE remove the following Supplemental Conditions fmm our permit as they are no longer valid:
Supplemental Condition No. 9; The Department is to be notified at least 90 days prior to Wolf Creek Cooling Impoundment bemg opened for public assess. Justification -
KDHE was notified at least 90 days prior to opening Wolf Creek Cooling Impoundment for public access (Reference 2).
l Supplemental Condition No.12; Prior to discharge through Outfall 003(b), permittee shall complete the US EPA Form 2c permit application for this outfall and supplement the information previously submitted. This outfall shall be sampled and analyzed for all the required Form 2c parameters when the waste stream is representative of operational 4
mode. Results shall be submitted to KDHE.
j PO. Box 411/ E>urlington KS 66839 / Phone: (316) 364-8831 An Equi I opportumty Employer M F HCVET
[
RP 98-0155 P:ge 2 cf 2 Justification - Wolf Creek submitted EPA Form 2c for Outfall 003(a) to KDHE on July 18,1995.
Supplemental Condition No.15; During the period in which waste streams containing i
monoethanolamine are directed to the settling pond associated with Outfall 005, permittee shall obtain on a monthly basis representative samples from the influent to the 3
pond and the pond and analyze each of the scmples for monoethanolamine, ammonia, l
and nitrate + nitrite. Permittee shall report these results on the monthly DMRs.
Justification - Waste streams contains monoethanolamine are no longer directed to the settling pond associated with Outfall 005 except under Supplemental condition No.16.
l If Supplemental Condition No.15 is removed, Wolf Creek also requests that the I
requirement to monitor for monoethanolamine, ammonia and nitrate + nitrite at Outfall 005 be removed.
This request is justified because Wolf Creek rarely invokes Supplemental Condition 16 and our wastewater discharges into the Lime Sludge Pond i
from the Wastewater Treatment Facility have almost ceased. The only waste streams that currently go into the LSP are blowdown from the precipitator, backwash from the i
sand and carbon filters and occasional flushing out of accumulated sediment from the wastewater treatment basins. None of these three waste streams merit the additional sampling requirements.
We also request the capability as a Supplemental Condition to chlorinate the service water for twenty-four hours a day if it becomes necessary to increase disinfection to protect the plant against macrofouling organisms. This change would cause a modification in Supplemental Condition No. 4(a) to allow simultaneous discharges from one unit.
In addition, we request that KDHE resolve our request of January 21,1998 (Reference 3) by increasing l
the discharge concentration of Beiz Copper-Trol at Outfall 006 to 60 ppm. WCNOC requested the Copper-Trol discharge concentration be increased from 50 to 60 ppm in order to obtain the minimum effective concentration of 50 ppm in the service. and essential service water systems. Increasing the discharge concentration to 60 ppm at Outfall 006 will not exceed our Outfall 003 discharge concentration limit of 6.0 ppm, which is well below the NOEL for Copper-trol. A copy of the January 21,1998 request is attached to this application for your review.
If you have any questions about the above requests, please contact Rdph Logsdon at 316-364-8831, extension 4730.
Sincerely, Clay C. Warren CCW/jaf Enclosures cc: Permit Clerk l
Enclosure I to RP 98 0155 KDHE Water Pollution Control Application i
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k Kansas Permit Application Number STATE OF KANSAS DEPARTMENT OF HEALTH AND ENVIRONMENT / DIVISION OF ENVIRONMENT WATER POLLUTION CONTROL PERMIT APPLICATION FOR INJECTION OR DISCHARGE TO SURFACE WATERS OF THE STATE Pursuant so K.S.A.65-164 and 65-165, the undersigned representing
'YY nb
[e**'4h -
N46e of municipality, institution, complany, corpq% tion or Mrson applying Located at: (Facility Address) billing / Permit Appl'::ation address:
(Leave blank if some as f acility address)
Wnif Crook Genoratinn Atatinn P.O.
Anx 411 Burlinotnn-VR 66A14 hereby makes application for a permit to discharge sewage' into:
Wolf Creek Cooling Impoundment Name of river, stream, lake, etc.
SW.SW NW 8
at.Outfall Location:
S.W_ $]aL_ NF 7
215' 16E Coffey Otr Otr Otr Section Township Range County I certify under penalty of law that this document and all attachments were prepared and/or reviewed under my direction or supervision in accordance with a system designed to assure that qualified, personnel properly gather, evaluate and/or review the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering, evaluating and/or reviewing the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including tne possibility of fine and imprisonment for knowing violations.
l' certify that I am auth'orized to sign this permit application pursuant to 40 CFR 122.22 as noted below.
.0 Signed:
Title:
C h i e f O pe r a t i n o O f f i c e r 7
Clay C. Warren Date:
7bo bB Print or Type Signature l
40 CFR 122.22: This application will be signed by the following: (a) in the case of a corporation, by the principal executive officer of at least the level of Vice President; (b) in the case of a partnership / by a general partner, (c) in the case of a sole proprietorship, by the proprietor, and (d) in the case of publicly-owned treatment works, by the official having responsibility for the overall operations of the treatment works.
'KSA 65164 defines 'sewace" as any substance that contains any of the waste products or excrementitious or other discharges from the bodies of human beings or animals, or chemical or other wastes from domestic, manufacturing or other forms of industry, l
, to RP 98-0155 g
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LOCA IO the instrustiere for seesHed item essenp-NNN tions and for the lepel authortestsons under which mis dem is conected.
- 51. POLLUTANT CHARACTERISTICS INSTRUCT 10848: Compiece A tlwaugh J to detonnine whether you need to submit any permit application forms to the EPA. If you enmeer "ys" to any guascone, you must submit this form and the supplemental tenu lisend in the parenthesis foliossing the quantion. Mort X"in the box in the thirtl column if the supplemental form is attmehed, if Yuu enemer "no" to each quesden, you need not mbmit any of these forms. You may enewer "no"if your activity I
b eEsiuded from permit requirements; see Section C of the instruction. Son else, Section D of the instructions for definitions of bold-fened tenas.
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A. le mis facA66ty e petsissy eened tresemisen warho R. Does or wdl mio fueletty (steer endominy or prepassd>
which remune in a dhessess ao useers of gas U.S.?
X inelude e annemersed enimme feeding aparaden or (FORM 2Al osassie animos prodmotion feelltey vehsen rueutts in e x
EAeshoge to notare of the U.S.? IFORM 28) o
- c. is the a tendsty ashush currentry remuam m eHasherges D. is the a proposed famitty (oper mee poor emocnbed to emeere af gee U.S. other then those elmeer.Jed in X
At A er # stesel suhich will result in a musherge se Y
A or B ehous? (pORM 2C1 of the U17 fFORM 20) m u
E. Does or se666 mis fusility truer.' enere, or dispose of F. Do you or teHi you insect et mis feeitety indusenes or l
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l memordous amen? (FORM 21 X
NA e.iuniolpes e.tnuerst ansioer me essemermost nrotum non-
.,we in one ousner He ofthee,mi no,s.
undaryound saurens of drinkans vuocer? (*ORM el r oo you or enn you enpact et trus vemosty any proouses weier or other fr sids ashish are turought to the surface H. Do you er sont you infest et this facility flukes for one-stel peosome sum a minirg of W by me Frm.h in sonnection swith esmentional oil er natural gas pro-shaction, inject fluists uend for enhanced recovery of X
prooms. soludon mining W minerais, in eNu comhue.
en er natural gas. or iniest fluists for storepp of liquid tier of feeH fuel, or removery of geomennel energy?
(FORM 48 hverocermons? fFORM 4) y 6.
is the fooltry a proposse - -, emesse senach as
.6. se me faciuty a proposed easelonary esewee whsch a one of the 28 industrief essegories listed in the en.
NOT one of the 23 indusertoi omessortse.lioned in the y
structaons and which evill potentietly emit 100 tone instructions and which will potentially emit 200 tons por voor cf any air pollutant reguiseed under the per year of any ser pollutant repuieted under the Cir< ft Clean Air Act and mer effect er te toested in en X
Air Act and rney effect or tie toestedin en etteinnw.et ettninssione eres? (FORM SI eres? (FORM 5) n
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CONTINUE ON REVERSE I
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m XL MAP Attach to this application a topographic map of the eres extending to at least one mile beyond property bounderies. The map must show the outline of the facility, the locwtion of each of its existing and proposed intoke and discharge structures, each of its hazardous weste treatment. storage, or disponel facilities. and each well whers it injects fluids underground indude all springs, rivers and other surface water tiodies in the map ares. See instructions for precise requiremerrts.
xii. NaruRs or sus 4NE55 (prowser a enet anscnpoen Generatica transmission and distribution of electricity
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XIll. CE RTielCATION (see instrucDons/
l l aartW smdse peneity of inw that I how personeHy enembed and am familier with the kliarmetion oubmitted h this application and all l
setschments and that, bened on my houiry of theer persone hunediately ownponalbie for obtaining ttw kformation conteined in the i
opplientlan, I beliew ther the information it true, accurate and complete. I am aners ther there are significant penetties for submitting l
$ alan hforMetion, inCiuding the possibility of fine and imprimorament.
- a. e.au s m ar rician. tita.a (rype or pnns/
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- c. D A rt SIGNED Clay C. Warren Chief Operating Officer 7//kTl i.. i...... e i...
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7A Ferm 36101 (4-e0)
REVERSE 1
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I KS 0079057 l
doarme swu u-se u.u. vNw s-Naa ens a6 P_aTEc Ti N %Nc y FORM gp
- h APPLICATION FOR PEI4MIT TD DISCHA'!!E WASTEVW ATER 4g g EXISTING MANUFACTURING 2, COMMERCIAL,MININ3 AND SILVICULTURAL OPERATIONS NPDES Consolidated Permits Program For each outfall, list the letstude end longitude of its location to tne nearest 15 seconds and the name of the receiving water.
A. Q U F 66
...... i....
I 002 38 14 00 95 l 41 l 15 Wolf Creek Cooling impoundment 1
38 14 00 95 l 41 l 15 Wolf Creek Cooling Impoundment 002a 003 38 l 14 30 l 95 l 41 l 30 Wolf Creek Cooling Impoundment 003a 38 l 14 30 95 l 41 l 30 Wolf Creek Cooling Impoundment 003b' 38 14 30 95 l 41 l 30 Wolf Creek Cooling impoundment i
I I
I lt. ELOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES]
A. Attech a line crewing showing the water flow through the fecihty. Indicate sourcss of sntake water, operptions contributed 0 westeweter to the effluent, f
and treatment units labeled to correspond to the more detasted descriptions in item B. Construct a water balance on the line drawing by showmg everage tiows between entakes, operations, treatment units, and outfalls, if a water botance cannot be determmed (e.g, for certem mmmy echwpes/, provios a pictirri description of the nature and amount of any sources of water and any collection or treatment measures.
l B. For each outtall, provios e description of: (1) All operations contributmg westewater to the effluent. mctuomg process westeweter, sanatary wastewater, coolmg water, and storm water runoff; (2) The average flow contributed by each operation: and (3) The treatment received by the westewater. Contmue on additional sheets if necessary.
- s. OPE R ATION45) CON TRIsWYING FLOW 3 TREATMENT t. CUT.
- L' pag
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- a. OPE R ATlON (lW J i
er es 8,s',s p i
e DESCRIPTION
.g 002 SITE OIL / WATER
- 0. 305 f, 'O GRAVITY OIL SEPARATOR 1-H 4-A 002a DISCHARGt A)
SITE OIL / WATER OIL SEPARATION /DISCHARG& 1-H 4-A SEPARATOR B)
OILY WATER SYSTEM INCLUDES:
l FILTERED WATER OVERFLOW DISCHARGE TO LAKE 4-A STORMWATER RUN-OFF OIL SEPARATION /DISCHARG E 1-H 4-A 003 CIRCULATING WATER 674 MGD CHLORINATION / DISCHARGE 2-F 4-A DJSCHARGE INCLUDES:
CIRC WATER SCREENHOUSE OIL INTERCEPT 0R OIL SEPARATION / DISCHARGE 1-H 4-A SERVICE WATER SYSTEM CHLORINATION / DISCHARGE 2-F 4-A NOTE: Service Water supplies the re quired Essential Service Water Syst 3m Flows 0030 RADIOLOGICAL WASTE 100 GPM FILTER-DEMINERALIZATION 2-A 4-A SYSTEM DISCHARGE 2-J INCLUDES:
WASTE MONITOR TANK A WASfE MONITOR TANK B SECONDARY L100!D WASTE MONITOR TANK A SECONDARY LIQUID
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CON 14NUL ON HEVER5E EPA Ftrm 3510 2C (Rev. 2 85)
PAGE'1OF4
Please ormt e, tvoe in the unshaded erees emtv.
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FORM u x... n v ea* nne. nv A6 v.ur Ec r e& w A.E mw y A
APPLICATION FOR PERMIT T3 DISCHAZE WASTEWATE3 2g g EXISTIN3 MANUFACTURING 2, COMMERCIAL.MININ3 AND SILVICULTURAL OPERATIONS b
NPDES Consolidated Permits Program For each outfall,last the latitude end tongituos of sts locotson to the nearest 15 seconos and the n no of the receiving water.
A.OUTFALL
- 3. k A viv uDE C. LONGITUD E
- ""c""'"**"""'"'**'
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004 38 11 15 95 41 15 Neosho River via Wolf Creek 005 38 14 45 95 41 '
15 Wolf Creek Coolino impoundment i
006 38 l 13 30 95 40 45 Wolf Creek Collino Impoundment l
A. Attacn a line crewing showing the water flow through the f acility, indscoto sources of entake water, costations contrsbutmg wasteweter to the effluent, and trestrnent units labeled to correspond to the more detailed descriptions an item 8. Construct a water balance on the ime drawing by showmg overage f6ows between sntakes, operations, treatment units, and outfalls, if a water batence cannot be determmed (e.g, for certain msnma acDrapes), prowce a pictorial description of the nature end amount of any sourus of water and any collection or treatment mecsures.
B. For each outfall, prowce a description of: (1) All operations contributmg westoweter to the effluent, mcluomg process westewater, sanstary wasteweter, coolang water, and storm water runoff; (2) The everage flow contributed by each operation; and (3) The treatment received by the westeweter. Contmue e n additional sheets if necessary.
I. OPER ATIONf S B CONTRf BUTING FLOW
- s. TREATMENT g, ggy.
e, DESCRIPTION g
g
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- 4. OPER ATION (IMf) n d,.Refe WASTE MONITOR' TANK B STEAM GENERATOR BLOWDOWN 003b WASTEWATER TREATMENT 1150 GPM OIL SEPARATION-SETTLING 1-H 4-A DISCHARGE NEUTRALIZATION AND 2-K DISCHARGE 1-U A;
0!LY WASTE DRAINAGE SYSlEM INCLUDES:
OILY INTERCEPT 0R CONTROL BLDG OILY i
1 WA51E SUMP DIESEL GENERATOR BLDG SUMP CONDENER PIT SUMP 5 l
(E,W.H.S)
LUBE OIL ROOM SUMP TENDON ACCESS GALLARY SUMP
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l TURBINE BLDG SUMPS l
(E,W.N.5)
AUXILARY BOILER REB 0lLER SUMP Ore. cia u ueE O,.6
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CON 16NUE ON REVER5E EPA Form 3510 2C (Rev. 2-05)
PAGE 1 OF 4
kie e onat'or tvoo.a the unshaded.rees iv.
l ~ KS 0079057
~~ l Ge%1Mr,2s FORM u.w. wN ws 3NuRNT Ab PeTECTe = N AGE NC Y
- h APPLICATION FOR PERMIT TO CISCHAME CASTEWATER 2m g EX18 TIN 2 MANUFACTURING 7, COMMERCIAL, MINING AND StLVICULTUR AL OPERATIONS b
peOEs Consolidated Permits Program
- 8. CUTFALL LOCATION
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,e is seconos.nd the,,s.n. of,h.,ec..v.,,e wet.,.
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- e. LAT870DE C. LONGITUDE
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l ti. FLOWS. SOURCES OF POLLUTION. AND TREATMENT TECHNOLOG A. Attach a ime crewmg showsng the water flow through the focalsty, indicate sources of enteke water, operations contributme westowster to the effluent, i
i and trestrnent units labeled tc, correspond to the more detai6ed descriptions in item 8. Construct a water belance on the amo drewmg by showmg average i
flows between entakes, operations, treatment tvuts, and outteils. If a water betence cannot be determmed (e.g, for corsein memnp scorrtres), provios a pictonal description of the nature and emount of any sources of water end any collection or treatment measures.
I
- 8. F:t sech outtall, provios e oescrsorion of: (f) All operations contnbutmg westeweter to the e' ant. mctuomg process westoweter, sanatory wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the westewate, Continue on addstional sheets if necessary
- 2. OPER ATIONfSt CONTRIBUTING FLOW
- 3. TREATMENT
- 1. 6 UT.
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- 4. OPER ATION fli,sfJ
- te d, en ts;
- a. DESCRIPTION g
Afl Y i l A R Y F F F F) 911MP l
B)
CONDENSATE POLISHER NEUTRALIZATION /DISCHARG E 2-K 4-A l
REGENERATION SYSTEM INCLUDES:
HTGH TDS TANK LOW TDS TANKS C)
MAKE-UP WATER NEUTRALIZATION /DISCHARC E 2-K 4-A TREATMtNT SYSTEM l
INCLUDES:
l DEMINERALIZED 1
l REGENERANT SOLUTIONS Di MISCELLANEOUS SOURCES NEUTRALIZATION /DISCHARC E 2-K 4-A INCLUDES:
STEAM GENERATOR DRAINDOWN l
CONDENSATE AND FEEDWATE R l
DRAINDOWN I
PLANT HEATING AND CHILLER SYSTEM DIESEL COOLING WATER SYSTEM 7
BTRS COOLING WATER SYSTEM CLOSED AND COMPONENT 0, c.C. u v e E O ~ u v,,rn.,,,,,,,wm... e...,,,
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CONT 6NUE ON FtEVER5E EPA Form 3610 2C (Rev. 2 85)
PAGE 1 OF 4
E, A s..o. Nuw.w.< con tra n wn i at un a >
6m L;~id5 mas l
Fleese orint er typi en thi unshaded Crys only K5 0079057 em e ><*=~es7 x 88 MM U4. E N V esu M 84.N T A L PWwT E C T 40N im E E N C Y
]
d'h APPLICATION FOR PEhMIT TO DISCH AR2E WASTEWATER I
l g
EXISTING MANUFACTURING, COMMERCIAL, MINING ANLf SILVICULTURAL OPERATIONS l
NPOEs Consolidated Permits Program 1
For each outfall, list the letstude and longitude of its locatiori to tne nearest 15 seconds and the narne of the receiving water.
A.QUT, FALL
- 3. L A TIT U O.E C. LONGITUDE (issfi s.eso.
- s. esim.
- a. esc.
- e. os a.
a. es,=.
s.sec.
l
~
- 11. FLOWS. SOURCES OF POLLUTION. AND TREATMENT TECHNOLO t
A. Attach e ime drawmg showing the water flow through the f acility, Indicate sources of intake water, operatior's contributmg wasteweter to the effluent, and treatment units labeled to correspond to the more detailed descriptions in item B. Construct a water talance on the line drawing by showmg everage flows between mtskes, operations, treatment unsts, and outfalls. If a water balance cannot be determmed (e.g, for certam mmma activities), provide e pictonal description of the nature and amount of any sources of water and any collection or treatment measures.
- 8. For each outfall, provide e description of: H) All operations contributing westewater to the effluent, includmg process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The everage flow contributed by each operation; and (3) The treatment received by the wastewater. Contmue on additional sheets of necessary.
l I. O WT.
- s. ope R ATIONf S) CONTRIBUTING PLOW 3 TRE ATMENT (Nas"
- a. OPE R ATION (la8fl gge gag'gg
- 8. DESCRIPTION gg g
.g n
COOLING WATER SYSTEM FIRE PROTECTION WATER NOTE:
Flows from the A and D system s may be temporarily rerc uted
- o ouu ailuut iat t nrougn toe ol i/ waste separator curing sonormat niant nnoratinnt 004 MAIN DAM DISCHARGE 2.87 MGD 4-A HOTE
- Discharge in compl iance with ap plicable Kansas Water Qu 311ty c ri te9 Ofter -iring 20nc
!" "00 he oiv er 005 LIME SLUDGE POND 1.21 MGD SETTLING / DISCHARGE (1-2 1-U 4-A times / year)
INCLUDES PREMIX TANK PRECIPITOR BLOWDOWN SAND AND CARBON FILTERS BACKWASH 006 ESSENTIAL SERVICE 26.5 MGD CHLORINATION / DISCHARGE 2-F 4-A WATER NOTE:
Receives water from the Servi.:e Water System during rc utine l
operations l
wF F sC6 AL USE ONL Y (gffiastal guedfimf8 8Ub-CGleeDratsj CONiiNUE ON HEVER5E l
EPA Form 3510-2C (Rev. 2 85)
PAGE 1 OF 4 l
u-------------------
CONTINUEO FROM THE FRONT l
C. E.rcept for storm runoff, leeks, ce spells, era cny cf the discherpos dexnbod in 4tems it-A or B Intamtt;nt er sensoren Q TEs frompArts the.*ollowing tables DNO tgo to Sectson 111)
- 3. FREQUENCY
- 4. FLOW l.OUTFALL
- 2. OPER ATION/s) a oavs
- b. MONTNs I
ne tsp cif wr is
(list) ispecify capacity s " w= ""
- . ' * * *. * * =
s.*******
overoses curreses
- '6' fin casas 003a Radwaste System 2
12 0.0002 0.195 0.01MC O.195MG 0.1 003b Wastewater Treatment 4
12 0.0010 0.001 10.098?1G 0.1)MG 0.1 004 Main Dam Discharge 3
5 2.87 23.0 2.87MC 23.0M i 2-3 005 Lime Sludge Pond 37 2
1.21 1.71 1.21MC 1.71M 3 3-7 l
I 181. PR ODUCTIO A. Does an effluent guidehne limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your tacdoty?
[ v Es fromplete Item til BI C NO tte to Section IV1
- 8. Are the limitations in the applicable effluent guidehne expressed in terms of productiort (or other measure of operation)?
Q v ts fromplete item !!! CI
- D No too to Sectson IVI C. If you answered "yes" to item ill B. list the Quantity which represents an actual measurement of your level of production. expressed m the terms and units used m the applicable effluent guidehne and mdicate the affected outfalls.
l l
_1,. AVERAGE PAILY PRODUCTIOfd g,,,,gergo
(
==> 'a,,,,
a.............
o.............
c..........-.~...........
,,,s,
IEPeClfyl l
l 4
I l
IV. IMPROVEMENTS -,
~
g l
A. Are you now requirett tav any Federal. State or local authority to meet any implementation schedult for the Construction. upgrading or operation of waste-water treatment equipment or practices or any other environmental programs which may affect the descharges described m this appiscation? This metudes, t
but is not hmeted to. permit conditions, administrative or enforcement orders, enforcement compiiance scheduie letters, stipulations, court orders, and grant or toen conditions.
Q vts fromplete the following tablel NO (go to item IV Bb
- i. sorNTarscavsON Or CONDITION,
- 2. AFFECTED OUTF ALLS p,,FM h M Yg 8
l AsREsMENT. ETc.
8 *RIEF DESCRIPTION OF PROJECT a..
I n..
...e....
,ogg,
p,gy;;
l 1
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B. OPTION AL: You may attach additional sheets oescribmg any additional water pollution controt programs (or other ennronmenrat projects which may affect your efischeroes/ you now nave unoerway or which you plan. Indicate whether eacn program is now underway or pianned, and indCate your actual or pianned seneouses for coristruction. ]uang..x., er DESCRIPTION OF ADDITION AL CONTROL PROGR AMs is ATT ACNED EPA Form 3510 2C (Rev. 2-85)
PAGE 2 OF 4 CONTINUE ON PAGE 3 l
l
kPA1D.
uen t a y from igjm j af form jp CONTtNUED FROM FA*E 2 Aporovstsnoores ? 3188 A. B,86 C: See instructions before proceedsng - Complete one set of tables for each outfall-Annotets the outfelt number m the spoor provided.
NOTE: Tables V A. V-8, and V C are included on separete sheets numbered V-1 through V 9.
D. Use the space below to list any of the pollutants listed in Table 2c 3 of the instructions, which you know or have rosson to beheve is descharged or may be :
dlScharged from any outfall. For every postutant you list, briefly describe the reasons you believe it to be present and report any onelytical data m your ;
possession.
1
- 1. POLLUTANT 2.eOtJRCE
- 1. POLLUTANT
- 3. SOURCE l
1 1
not applicable l
l J
l i
l VI. POTENTI AL OtSCHARGES NOT COVERED BY ANALYSISM u any pollutant 6ssted an item V-C a substance or a component of a substance whech you currently use or manutecture as an intermediate or imal product or hyproduct?
5 O v Es flict all such notiusents below) 11NO tIo to item VIB) l I
i l
l l
EPA Form 3510 2C (Rev. 2 85)
PAGE 3 OF A CONTINUL ON REVERS 3
s e COtiTINUED FOOM THE F"ONT
'D3 you have any knowledge or toeson 13 believe that any biologicet test for acute or chron6e toxic!ty has been snede on any of your cischarges or on a receiving water in relation to your discharge within the last 3 years?
D YEs fidentify the teettsb and devernbe their purposes belows h No tso to sect.on VI!!)
VillCONTRACT ANALYSIS INFORMATION Wire any of the snelyses reported in item V performed by a contract laboratory or consulting firm?
W Nldle'd"C'i.*A'e73 T."L* llr"*o"lf"M"s'lllli *" ""'*""
0""****"*
N f,,,T[,'ff H 6
A. N AM E
- m. AconEss N
en,
Southwest Research 6220 Culebra Road
- 210-522-2169 VOCs by GC/MS; BC D ;.
Institute P.O. Drawer 28510 i
COD; TOC;Ammoni a; :N; San Antonio, TX 78228 Toxic metals; Phenols:Djoxin; oil / grease; Nitrate / Nitrite l
Continental Analytical S vcs.
1804 Gl endal e Road -785-827-1273 VOCs by 'GC/MS; B0';'
)
Salina, Kansas COD; TOC;Ammoni a; :N 67401 Toxic metals; i
Phenols; Dioxin ;
oil / grease; Nitrate / Nitrite Ic:rtify underpenetty ofla w that this document andellettechments were prepared under my direction or supervision in accordance with a system designe dto Essute that qualifoedpersormelproperlygather andevoluete the information submitted. Besedon my onquiry of the person orpetsons who manage the system or thosepersons directlyresponshk forgathering the information, the informstron subtruttedos, to thebest of my knowledge andbehef. true. accurate, andcomple te.
I cm ewere that there are significant penettoes for submrtting false informattorL meludong the possobihry of fine and imprisonment for knowing violations.
l l
A. N AME er OFP4Ca AL 1rtTLE (type or prant; s. PHON E N O. f erra Code & no.)
Clay C. Warren, Chief Operating Officer 316-364-8831 I
C. SIGN URE D. D ATE $6GNED
,,A,op.c,.e......,
4
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Enclosure to RP 98-0155: Form 2C parts V-A, V-B and V-C for outfall 002 and 002(a)
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TY eMeadom H Betz 88P EFFECTIVE DATE: 03-OCT-1997 PRINTED DATE: 02-DEC-1997
- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : SPECTRUS OX1200 PRODUCT APPLICATION AREA: SOLID MICROBIAL CONTROL AGENT.
COMPANY ADDRESS: BetzDearbom inc. 4636 Somerton Road, Trevose Pa.19053 l Information phone number- (215) - 355-3300 EMERGENCY TELEPHONE (HEALTH / ACCIDENT): (800)-877-1940 (USA)
- 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the tJ.S. OSHA HAZARD COMMUN. CATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
i l HAZARDOUS INGREDIENTS: ) CAS# CHEMICAL NAME l 16079-88-2 1-BROMO-3-CHLORO-5,5-DIMETHYLHYDANTOIN l Oxidizer; irritant (eyes and skin) No component is considered to be a carcinogen by the National Toxicology Program., the intemational Agency for Research on Cancer or the i Occupational Safety and Health Administration at OSHA th,resholds for i carcinogens. l l PAGE 1 CONBNUED
' PRODUCT NAME : SPECTRUS OX1200 EFFECTIVE DATE: 03-OCT-1997 I
- 3) HAZARDS IDENTIFICATION l
=_=__-_-_::_.
= =
EMERGENCY OVERVIEW l 1 DANGER Moderately irritating. May be corrosive in contact with moist skin. Severe irntant to the eyes. Dusts cause irritation to the upper respiratory tract. DOT hazard: Oxidizer Emergency Response Guide #35 1 Odor: Slight; Appearance: White, Granules l Fire fighters should wear positive pressure self-contained breathing I apparatus (full face-piece type). Proper fire-extinguishing media: I Flood with water. Use of CO2 or foam may not be effective. 1 -. ____:==_--__-____:_==-__-:===.==:== l POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: l l Primary route of exposure; Moderately irritating. May be corrosive i in contact with moist skin. ACUTE EYE EFFECTS: Severe irritant to the eyes. ACUTE RESPIRATORY EFFECTS: i Dusts cause irritation to the upper respiratory tract. INGESTION EFFECTS: f May cause severe irritation or burning of the gastrointestinal tract. TARGET ORGANS: No evidence of potential chronic effects. l MEDICAL CONDITIONS AGGRAVATED: l Not known. SYMPTOMS OF EXPOSURE: May cause redness or itching of skin. PAGE 2 CONTINUED
PRODUCT NAME : SPECTRUS OX1200 EFFECTNE DATE: 03-OCT-1997
- 4) FIRST AID MEASURES SKIN CONTACT:
Remove clothing. Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment. INHALATION: Remove victim from contaminated area. Appl treatment. Immediately contact a physician. y necessary first aid l INGESTION: Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician. Dilute.,ontents of stomach using 3-4 glasses milk or water.
- 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire figh!ers should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: Flood with water. Use of CO2 or foam may not be effective. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F > 93C P-M(CC) MISCELLANEOUS: Oxidizer UN1479; Emergency Response Guide #35
- 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
VIntilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container. Product releases chlorine when wet. Spill residue may be neutralized with 3% hydrogen peroxide. solution. DISPOSAL INSTRUCTIONS: Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted weste treatment facility or discharged under a permit. Product cs is - Dispose of in approved pesticide facility or according to labelinstructions. PAGE 3 CONTINUED
PRODUCT NAME : SPECTRUS OX1200 EFFECTNE DATE: 03 OCT-1997 l l
- 7) HANDLING AND STORAGE l
l HANDLING: Oxidizer. Avoid all contact with reducing agents, oils, greases, ) organics and acids. l STORAGE: i Keep containers closed when not in use. Keep dry. Do not store at l high temperature or near oxidizables or combustibles.
- 8) EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS l
CHEMICAL NAME 1 -BROMO-3-C HLORO-5.5-DIMETHYLHYDANTOI N PEL (OSHA): NOT DETERMINED TLV (ACGlH): NOT DETERMINED MISC: Note-manufacturer's recommended exposure limit: 0.2 mg/m3. l ENGINEERING CONTROLS: i Adequate ventilation to maintain air contaminants below exposure l limits. l PERSONAL PROTECTNE EQUIPMENT: l Use protective equipment in accordance with 29CFR 1910 Subpart i RESPIRATORY PROTECTION: i A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR l 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER l l WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. l USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED j WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS. If air-purifying respirator use is appropriate, use a respirator with acid gas cartridges and dust / mist profilters. SKIN PROTECTION: gauntlet-type neoprene gloves, chemical resistant apron-Wash off after each use. Replace as necessary. EYE PROTECTION: airtight chemical goggles ~ PAGE 4 CONTINUED
l PRODUCT NAME : SPECTRUS OX1200 l EFFECTNE DATE: 03 OCT-1997 i
- 9) PHYSICAL AND CHEMICAL PROPERTIES D:nsity NO DATA Vapor Pressure (mmHG)
< 1.0 1 Freeze Point (F) NA Vapor Density (air =1) < 1.00 Freeze Point (C) NA Viscosity (cps 70F,21C) NA % Solubility (water) 0.2 Odor i Slight l Appearance White l Physical State Granules Flash Point P-M (CC) > 200F > 93C pH 5% Disp. (approx.) 4.7 Evaporation Rate (Ether-1) < 1.00 i NA = not applicable ND = not determined
- 10) STABILITY AND REACTIVITY STABluTY:
Stable under normal storage conditions. HAZARDOUS POLYMERIZATION: l Will not occur. INCOMPATIBluTIES: Slowly releases halogen gases when contaminated with moisture. May react with alkalies, acids, organics or reducing agents. l DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. CETZ INTERNAL PUMPOUT/ CLEANOUT CATEGORIES: "B" PAGE 5 CONTINUED
PRODUCT NAME : SPECTRUS OX1200 EFFECTIVE DATE: 03 OCT-1997
- 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT:
578 mg/kg NOTE - 600 mg/kg per alt. source; dehalogenated byproduct rat oral LD50: >4,000 mg/kg Teratology RAT: NOTE - Dehalogenated byproduct study had terata (secondary) at maternal toxic doses R: productive Toxicity RAT: 4,500 mg/kg/ day NOTE - Dehalogenated byproduct study had no adverse reproductive toxicity Darmal LD50 RABBIT: >2,000 mg/kg NOTE - Alternate source concurs Inhalation LC50 RAT: 1.88 mg/L/4hr NOTE - >3.2 mg/L/4hr at 100 ppm (no deaths) per alternate source Skin Irritation Score RABBIT: 6.1 NOTE - 6.98 per alternate source; reversible; dehalogenated byproduct score: 0.8 Eye Irritation Score RABBIT: 103 NOTE - 14 day-irreversible-max.at day 3; dehalogenated byproduct score: 12.8-reversible 90 Day Feed Study RAT: NOTE - Dehalogenated byproduct 90-day oral LD50: >2,000 mg/kg/ day Skin Sensitization G. PIG: POSITIVE NOTE - Buehler Test; Dehalogenated byproduct was negative in Buehler Test Amas Assay BACTERIA: NEGATIVE NOTE - +/- me'.aolic activation; Dehalogenated byproduct: negative Non-Ames Mutagenicity YEAST: NEGATIVE NOTE - Dehalogenated byproduct negative for: Mouse Lymphoma, SCE, Cell Transformation l PAGE 6 CONTINUED --___.--_-------_____--------_--_----_J
l PRODUCT NAME : SPECTRUS OX1200 l EFFECTIVE DATE: 03ET-1997 l
- 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50:.9 mg/L No E#ect Level:.52 mg/L Fathead Minnow 96 Hour Static Acute Bioassay LC50: 2.34 mg/L No E#ect Level: 1.8 nWL Daphnia magna.48 Hour Static Acute Bioassay l
L LC50:.47 mg/L No Effect Level:.31 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay LC50: 20.8 mg/L No Effect Level: 11.6 mg/L BIODEGRADATION COD (mg/gm): 938 TOC (mg/gm): 255 BOD-5 (mg/gm): 6 BOD-28 (mg/gm): 11
- 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is :
D001=lgnitable. Please be advised; however, that state and local requirements for wests disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. -14) TRANSPORT INFORMATION DOT HAZARD: Oxidizer UN / NA NUMBER: UN1479 DOT EMERGENCY RESPONSE GUIDE #: 35 PAGE 7 CONTINUED
PRODUCT NAME : SPECTRUS OX1200 EFFECTIVE DATE: 03&T-1997
- 15) REGULATORY INFORMATION TSCA:
This is an EPA registered biocide and is exempt from TSCA inventory requirements. CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated constituent preeent at OSHA thresholds FIFRA REGISTRATION NUMBER: 3876-150 FOOD AND DRUG ADMINISTRATION: 21 CFR 176.300 (slimicides for wet end use) When used in this specified application, all ingredients comprising this product are authorized by FDA for the manufacture of paper and paperboard that may contact aqueous and fatty foods as per 21 CFR 176.170(a)(4). SARA SECTION 312 HAZARD CLASS: Immediate(acute); Fire SARA SECTION 302 CHEMICALS: No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds I ( I PAGE 8 CONTINUED
l PRODUCT NAME : SPECTRUS OX1200 l EFFECTNE DATE: 03-OCT-1997 i
- 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 2
Moderate Hazard Fire 1 Slight Hazard Reactivity 1 Slight Hazard Special OXY DOT or NFPA Oxidizer (1) Protective Equipment C Goggles, Gloves, Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations. CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 24-SEP-1997
- NEW **
03-OCT-1997 8 24-SEP-1997 PAGE 9
MATERIAL Sef2Deerbom lA E EFFECTIVE DATE: 18-NOV-1997 Betz CT-2 PRINTED DATE: 02-DEC-1997
- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : SPECTRUS CT1300 PRODUCT APPLICATION AREA: WATER-BASED MICROBIAL CONTROL AGENT.
COMPANY ADDRESS: BetzDearbom inc. 4636 Somerton Road, Trevose Pa.19053 Information phone number: (215) - 355-3300 EMERGENCY TELEPHONE (HEALTH / ACCIDENT): (800)-877-1940 (USA)
- 2) COMPOSITION I INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the (J.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS: CAS# CHEMICAL NAME 68424-85-1 (C12-16) ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE Corrosive (eyes and skin) 64-17-5 ETHYL ALCOHOL (ETHANOL) Flammable liquid; irritant (eyes); potential liver and kidney toxin; may cause CNS depression No component is considered to be a carcinogen by the National Toxicology l Program., the Intemational Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens. PAGE 1 CONDNUED
PRODUCT NAME : SPECTRUS CT1300 EFFECTIVE DATE: 16-NOV-199Y
- 3) HAZARDS IDENTIFICATION
. u EMERGENCY OVERVIEW DANGER Severe irritant to the skin. Potential skin sensitizer. Corrosive to the eyes. Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract. DOT hazard: Combustible liquid j Emergency Response Guide #27 Odor: Mild; Appearance: Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). Proper fire extinguishing media: ~.hemical, carbon dioxid.e, foam o..r water ~... dry c
_
...w POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; Severe irritant to the skin. Potential skin sensitizer. I ACUTE EYE EFFECTS: Corrosive to the eyes. ACUTE RESPIRATORY EFFECTS: Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract. INGESTION EFFECTS: Toxic; May cause severe irritation or burning of mouth, throat,.and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses. TARGET ORGANS: Prolonged or repeated exposures may cause CNS depression, skin sensitization, and/or toxicity to the liver and kidney. MEDICAL CONDITIONS AGGRAVATED: Not known. SYMPTOMS OF EXPOSURE: Inhalation of vapors / mists / aerosols may cause eye, nose, throat and lung irritation. Skin contact may cause severe irntation or burns. l l PAGE 2 CONTINUED l l
PRODUCT NAME : SPECTRUS CT1300 EFFECTNE DATE: 18-NOV-1997 l
- 4) FIRST AlD MEASURES SKIN CONTACT:
Remove clothing. Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment. INHALATION: Remove victim from contaminated area. Ap treatment. Immediately contact a physician. ply necessary first aid INGESTION: Do not feed anything by mouth to an unconscious or convulsiva victim. Dilute contents of stomach. Induce vomiting by one of the standard methods. Immediately contact a physician.
- 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
l Fire fighters should wear positive pressure self-contained breathing i apparatus (full face-piece type). EXTINGUISHING MEDIA: Gy chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. FL. ASH POINT: l 130F 54C P M(CC) i l. MISCELLANEOUS: ) Combustible liquid . NA1993; Emergency Response Guide #27
- 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container. Remove ignition sources. Flush area with water. Spread sand / grit. DISPOSAL INSTRUCTIONS: Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted weste treatment facility or discharged under a permit. Product cs is - Dispose of in approved pesticide facility or according to labelinstructions. PAGE 3 CONTINUED
f PRODUCT NAME : SPECTRUS CT1300 EFFECTIVE DATE: 18-NOV-1997
- 7) HANDLING AND STORAGE HANDLING:
Combustible. Do not use around sparks or flames. Bond containers during filling or discharge when performed at temperatures at or t above the product flash point. STORAGE: Keep containers closed when not in use. Reasonable and safe chemical storage. Protect from freezing.
- 8) EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME l
l (C12-16) ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE i PEL OSHA): NOT DETERMINED l TLV ACGlH): NOT DETERMINED ETHYL ALCOHOL (ETHANOL) PEL (OSHA): 1,000 PPM TLV (ACGlH): 1,000 PPM ENGINEERING CONTROLS: Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT: Use protective equipment in accordance with 29CFR 1910 Subpart I i RESPIRATORY PROTECTION: A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI ZB8.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. i USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED - WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS. l if airgurifyi respirator use is appropriate, use a respirator organic vapor cartridges and dust / mist profilters. SKIN PROTECTION: neoprene gloves-Wash off after each use. Replace as necessary. EYE PROTECTION: splash proof chemical goggles l l l PAGE 4 CONTINUED
l PRODUCT NAME : SPECTRUS CT1300 EFFECTIVE DATE: 18NOV-1997
- 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav.(70F,21C) 0.965 Vapor Pressure (mmHG) 44.0 Freeze Point (F)
-7 Vapor Density (air =1) < 1.00 Freeze Point (C) -22 Viscosity (cps 70F,21C) 73 % Solubility (water) 100.0 Odor Mild Appearance Colorless To Yellow Physical State Liquid Flash Point P-M (CC) 130F 54C pH As Is (approx.) 8.9 l Eve.poration Rate (Ether =1) > 1.00 l NA = not applicable ND = not determined
- 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditiens. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITIES: May react with strong oxidizers. DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. TZ INTERNAL PUMPOUT/ CLEANOUT CATEGORIES: BE..B"
- 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT:
445 mg/kg Dermal LD50 RABBIT: >1,800 mg/kg PAGE 5 CONENUED
PRODUCT NAME : SPECTRUS CT1300 EFFECTIVE DATE: 18 NOV-1997 l l 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified. LC50:.72 mg/L i No Effect Level:.41 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay Test concentrations were analytically verified. LC50:.04 mg/L No Effect Level:.026 mg/L R inbow Trout 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified. LC50: 2 mg/L No Effect Level: 1.2 mg/L Mysid Shrimp 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified. LC50:.16 mg/L No Effect Level:.03 mg/L Sheepshead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified. i LC50: 1.76 mg/L No Effect Level: 1 mg/L Monidia beryllina (Silversides) 90 Hour Flow-Thru Bioassay Test concentrations were ana ytically verified. LC50:.62 mg/L No Effect Level:.35 mg/L BIODEGRADATION COD (mg/gm): 1470 TOC (mg/gm): 380 BOD-5 (mg/gm): 43 BOD-28 (mg/gm): 156 i I PAGE 6 CONTINUED
I l l EFFECTWE DATE: 18-NOV-1997 PRODUCT"NAME : SPECTRUS CT1300 j
- 13) DISPOSAL CONS!DERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is :
D001=lgnitable. l Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. 3 l
- 14) TRANSPORTINFORMATION DOT HAZARD:
Combustible liquid UN / NA NUMBER: NA1993 DOT EMERGENCY RESPONSE GUIDE #: 27 i
- 15) REGULATORYINFORMATION l
l TSCA: This is an EPA registered biocide and is exempt from TSCA inventory requirements. CERCLA ANDtOR SARA REPORTABLE QUANTITY (ds ): RQ No regulated constituent present at OSHA threshol l FIFRA REGISTRATION NUMBER: 3876-149 POTABLE WATER APPROVAL: NSF certified. Maximum use for reverse osmosis 10 mg/L. FOOD AND DRUG ADMINISTRATION: 21 CFR 176.300,(slimicides for wet end use) When used in this specified ap)lication, all ingredients comprising this prod uct are aut1orized by FDA for the l manufacture of paper and paperboard that may contact aqueous and fatty foods as per 21 CFR 176.170(a)(4). SARA SECTION 312 HAZARD CLASS: Immediate(acute);D Chronic); Fire SARA SECTION 302 CH DCAL3: No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: No regulated constituent present at OSHA thresholds i i CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT(PROPOSITION 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds PAGE 7 CONTINUED l i
PRODUCTNAME : SPECTRUS CT1300 EFFECTNE DATE: 18-NOV-1997 MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds
- 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 3
Serious Hazard Fire 2 Moderate Hazard Reactivity 0 Minimal Hazard Special NONE No special Hazard (1) Protective Equipment B Goggles, Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations. l CHANGE LOG EFFECTIVE l DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 18-NOV-1997
- NEW **
l i l l PAGE B
eadom DT EET EFFECTIVE DATE: 29-JAN-1997 Betz WCNOS PRINTED DATE: 02-DEC-1997
- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I
PRODUCT NAME : DEPOSITROL BL5303 . PRODUCT APPLICATION AREA: WATER-BASED DEPOSIT CONTROL AGENT. l COMPANY ADDRESS: 36 koad Information phone num, Trevose Pa.19053ber- (215)- 355-3300 EMERGENCY TELEPHONE (HEALTH / ACCIDENT): (800)-877-1940 (USA) 1
- 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
I HAZARDOUS INGREDIENTS: CAS# CHEMICAL NAME 2809-21-4 PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE) BIS- (HEDP) Corrosive (eyes) No component is considered to be a carcinogen by the National Toxicology Program the intemational Agency for Research on Cancer or the Occhpati'onal Safety and Health Administration at OSHA th,esholds for r carcinogens. l l I l l PAGE 1 CONTINUED
PRODUCT NAME : DEPOSITROL CL5303 EFFECTIVE DATE: 29 JAN-1997
- 3) HAZARDS IDENTIFICATION z _.
EMERGENCY OVERVEW CAUTION May cause moderate irritation to the skin. May cause moderate irritation to the eyes. Mists / aerosols may cause irntation to upper respiratory tract. I i DOT hazard: Corrosive to steel l Emergency Response Guide #153 i Odor: Sh'ght; A--;rance: Yellow, Liquid i l Fire fighters shou:d wear positive pressure self-contained breathing i apparatus (full face piece type). Proper fire extinguishing media: l c _ - - y- -dr chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS l ACUTE SIGN EFFECTS: Primar skin. y route of exposure; May cause moderate irritation to the ACUTE EYE EFFECTS: May cause moderate irritation to the eyes. ~ AOUTE RESPIRATORY EFFECTS: 1 Mists / aerosols may cause irritation to upper respiratory tract. l INGEST;ON EFFECTS' i May cause gastrointestinal irritation with possible nausea, i vomiting, abdominal discomfort and dian11ea. l TARGET ORGANS: 1 No evidenco of potential chronic effects. MEDICAL CONDITIONS AGGRAVATED: Not known. i SYMPTOMS OF EXPOSURE: May cause redness or itching of skin. 1 PAGE 2 CONTINUED
PRODUCT NAME : DEPOSITROL CL5303 EFFECTNE DATE: 29 JAN-1997 l.4) FIRST AlD MEASURES SKIN CONTACT: Remove contaminated clothing. Wash exposed area with a large quant;ety of soap solution or water for 15 minutes. EYE CONTACT: l Immediately flush eyes with water for 15 minutes. Immediately contact a physictsn for additional treatment. INHALATION: l Remove victim from contaminated area to fresh air. Apply gg first aid treatmerit as necessary. j Do not feed anything by mouth to an unconscious or convulsive l victim. Do not irxluce vomiting. Immediately contact physician. Dilute contents cI stomach using 3 4 glasses milk or water. l l.5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS: ' Fire fighters should wear positive pressure self-contained breathing i apparatus (fullf 'ece type). EXTINGUISHING ME chemical, carbon dioxido, foam or water DOUS DECOMPOSITION PRODUCTS: i Thermal hi.i.,ci.ition (destructive fires) yields elemental oxides. FLASH POINT: > 200F P-M(CC) E'lSCELLANEOUS: Corrosive to stesi UN3265; Emergency Response Guide #153
- 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and i absorb on absorbent material. Place in waste disposal container. Flush area with water. Wet area may be slippery. Spread sand / grit. DISPOSALINSTRUCTIONS: Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted weste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
- 7) flANDLING AND STORAGE HANDUNG:
Acidic. Do not mix with alkaline material. STORAGE: Keep containers closed when not in use. Use approved containers only. Avoid high temperature storage. Store away from combustibles. Contact with metals may release flammable hydrogen gas. PAGE 3 CONTINUED
PRODUCT NAME : DEPOSITROL BL5303 EFFECTIVE DATE: 29-JAN-1997 i
- 8) EXPOSURE CONTROLS / PERSONAL PROTECTION f
EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE) BIS-(HEDP) PEL (OSHA): NOT DUERMINED TLV (ACGlH): NOT DETERMlHED ENGINEERING CONTROLS: adequate ventilation i PERSONAL PROTECTIVE EQUIPMENT: l Use orotective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION: l A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORY WITHIN USE LIMITATIONS ASSOCIATED i WnTH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS. l If air-purifying rospirator use is appropriate, use a l respirator with dust / mist filters. l SKIN PROTECTION: rubber gloves-Wash off after each use. Replace as necessary. EYE PROTECTION: splash proof chemical goggles
- 9) PHYSICAL AND CHEMICAL PROPERTIES 18.0 Spaciffc Grav. (70F) 1.184 Vapor Pressure (mmHG)
Freeze Point (F) 25.00 Vapor Density (air =1) < l.00 Viscosity (cps 70F) 23 % Solubility (water) 100.0 Odor Slight Appsarance Yellow j Physical State Liquid Flash Point (F) > 200 P-M(CC) pH As Is (approx.) 2.7 Evaporation Rate (Ether-1) < 1.00 NA = not applicable ND = not determined l + i PAGE 4 CONTINUED
PRODUCT NAME : DEPOSITROL BL5303 EFFECTIVE DATE: 29 JAN-1997 f
- 10) STABILITY AND REACTIVITY STABluTY:
Stable under nonnat storage condit'ons. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBluTIES: I react with strong oxidizers. I DE MPOSITION PF;ODUCTS: Thermal decuiTposition (destructive fires) yields elemental oxides. 1 TZ INTERNAL PUMPOUT/ CLEANOUT CATEGORIES: l BEB"
- 11) TOXICOLOGICAL INFORMATION l
Oral LD50 PAT: >2,000 mg/kg I NOTE - Estimated value Darmal LD50 RABBIT: >2,000 mg/kg NOTE - Estimated value Skin Irritation Score RABBIT: 0.0 Eye Irritation Score RABBIT: MODERATE NOTE - Completely reversible; estimated based on testing of similar l material l l i l 12) ECOLOGICAL INFORMATION i AQUATIC TOXICOLOGY l No Data Available. BIODEGRADATION i l COD (mg/gm): 233 Calculated TOC (mg/gm): 81 Calculated BOD-5 (mg/gm): 5 Calculated BOD-28 (mg/gm): 15 Calculated
- 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a weste, the US RCRA hazardous weste identification number is :
i D002= Corrosive (steel). i Please be advised; however, that state and local requirements for weste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding i the proper disposal of this material. PAGE 5 CONTINUED l E____________________________._.__.__._.._.__
I PRODUCT NAME : DEPOSITROL EL5303 EFFECTWE DATE: 29-JAN-1997
- 14) TRANSPORT INFORMATION DOT HAZARD:
Corrosive to steel UN / NA NUMBER: UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153 l' l.15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory. CERCLA ANDIOR SARA REPORTABLE QUANTITY (dsRQ): No regulated constituent present at OSHA threshol l SARA SECTION 312 HAZARD CLASS: Immediate(acute) SARA SECTION 302 CHEMICALS: No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION l CALIFORNIA SAFE DRINKING WATER AND TOXIC l ENFORCEMENT ACT (PROPOSITION 85) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds i i PAGE 6 CONTINUED l
PRODUCT NAME : DEPOSITROL BL5303 EFFECTNE DATE: 29 JAN-1997
- 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 2
Moderate Hazard l Fire 1 Slight Hazard Reactivity 0 Minimal Hazard l Special NONE No special Hazard (1) Protective Equipment B Goggles, Gloves (1) refer to section 8 of MSDS for additional protective equipment l recommendations. CHANGE LOG EFFECTIVE I DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 29-JAN-1997
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I PAGE 7
i i i BETZ LABORATORIES, INC. 4636 SOMERTON ROAD, TREVOSE,.PA 19053 t PRODUCT: POWERLINE-WCN05 May 18, 1995 l AQUATIC TOXICOLOGY Fathead minnow 96 Hour Calculated Acute Toxicity l LC50: 1597 MG/L NOEL: 608 MG/L l Daphnia magna 48 Hour Calculated Acute. Toxicity LC50: 1171 MG/L 1 NOEL: 1078 MG/L l BIODEGRADATION i COD (mg/gm) : 253 Calculated TOC (mg/gm) : 85 Calculated BOD-5 (mg/gm): 5 Calculated BOD-28 (mg/gm) : 15 Calculated Closed Bottle Test t Degradation in 28 days: O Calculated Zahn-Wellens Test % Degradation in 28 days: 5 Calculated MAMMALIAN TOXICOLOGY Oral LD50 RAT: >2,000 MG/KG Note - ESTIMATED VALUE Dermal LD50 RABBIT: >2,000 MG/KG Note - ESTIMATED VALUE 1 Eye Irritation Score RABBIT: MODERATE Note - COMPLETELY REVERSIBLE; ESTIMATED BASED ON TESTING OF SIMILAR MATERIAL r
BETZD 'gggTERIAL Set 2Dearbom EFFECTIVE DATE: 28-JAN-1997 Betz Copper-Trol y PRINTED DATE: 02-DEC-1997
- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : INHIBITOR AZ8103 PRODUCT APPLICATION AREA: WATER-BASED CORROSION INHIBITOR.
COMPANY ADDRESS: BetzDearbom inc. 4636 Somerton Road, Trevose Pa.19053 Information phone number: (215) - 355-3300 EMERGENCY TELEPHONE (HEALTHIACCIDEf JT): (800)477-1940 (USA)
- 2) COMPOSITION I INFORMATION ON INGREDIENTS Information for specific pro 6xt ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS: CAS# CHEMICAL NAME 1310-73-2 SODIUM HYDROXIDE (CAUSTIC SODA) Corrosive; toxic (by ingestion) 118685-34-0 BUTYL BENZOTRIAZOLE, SODIUM SALT Corrosive (eyes and skin); sensitizer (skin) l l No component is considered to be a carcinogen by the National Toxicology l Program the Intemational Agency for Research on Cancer or the l Occupati,onal Safety and Health Administration at OSHA th,resholds for carcinogens. l PAGE 1 CONTINUED
1 PRODUCT NAME : INHIBITOR AZ8103 i EFFECTIVE DATE: 28 JAN-1997 j l
- 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW i
DANGER Corrosive to skin. Skin sensitizer. Corrosive to the eyes. Mists / aerosols cause irritation to the upper respiratory tract. DOT hazard: Corrosive to skin Emergency Response Guide #60 Odor: Mild; Appearance: Dark Brown, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus (full face pioos type). Proper fire-extinguishing media: . y chemical, carbon dioxide, foam or water dr POTENTIAL HEALTH EFFECTS I ACUTE SKIN EFFECTS: Primary route of exposure; Conosive to skin. Skin sensitizer. ACUTE EYE EFFECTS: Corrosive to the eyes. ACUTE RESPIRATORY EFFECTS: Mists / aerosols cause irntation to the upper respiratory tract. INGESTION EFFECTS: May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, dienhea, lethargy and collapse. Possible death when ingested in very large doses. TARGET ORGANS: Prolonged or repeated exposures may cause tissue necrosis, primary l irritant dermatitis, and/or skin sensitization. l MEDICALCONDITIONS AGGRAVATED: Not known. SYMPTOMS OF EXPOSURE: Causes severe irntation, burns or tissue ulceration with subsequent scarring, r PAGE 2 CONTINUED
1 PRODUCT NAME : INHIBITOR AZ8103 ' EFFECTIVE DATE: 28 JAN 1997 l i
- 4) FIRST AlD MEASURES SKIN CONTACT:
Remove clothing. Wash area with large amounts of soap a slution or water for 15 min. Immediately contact physician. EYE CONTACT: Immedsetely flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment. INHALATION: Remove victim from contaminated area. Apply necessary first aid i treatment. Immediately contact a physician. INGESTION: Do not food anything by mouth to en unconscious or convulsive victira. Do not induce vomiting. Immediately contact physician. l Dilute contents of stomach using 34 glasses milk or water. l l
- 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (fullface-piece type). EXTINGUISHING MEDIA: chemical, carbon dioxide, foam or water US DECOMPOSITION PRODUCTS: Thermal decutivcsition (destructive fires) yields elemental oxides. PLASH POINT: > 200F P-M(CC) MISCELLANEOUS: Ccrrosive to skin UN1824; Emergency Response Guide #60 l
- 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in weste disposal container. Flush area with water. Wet area may be slippery. Spread sand / grit. DISPOSAL INSTRUCTIONS: Water contaminated with this product may be sent to a sanitary sever treatment facility,in accordance with any local agreement,a permitted weste treatment facility or discharged under a permit. Product i l as is - incinerate or land dispose in an approved landfill. l
- 7) HANDLING AND STORAGE HANDLING:
Alkaline. Corrosive (Skinleyes). Do not mix with acidic material. STORAGE: Keep containers closed when not in use. Do not freeze. If frozen, thew and mix completely pnor to use. PAGE 3 CONTINUED l
PRODUCT NAME : INHIBITOR AZ4103 EFFECTWE DATE: 28-JAN-1997
- 8) EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS SODIUM HYDROX1DE (CAUSTIC SODA)
PEL OSHA : 2 MG/M3 TLV ACGI ): 2 MG/M3(CEILING) BUTYL BENZOTRIAZOLE, SODIUM SALT I PEL (OSHA): NOT DETERMINED TLV (ACGlH): NOT DETERMINED l ENGINEERING CONTROLS: Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTNE EQUIPMENT: Use protective equipment in accordancx, with 29CFR 1910 Subpart I t RESPIRATORY PROTECTION: l A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR l '1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS. ) l If air respirator use is appropriate, use a I l resperator dust / mist filters. l SKIN PROTECTION: gauntlet-type rubber gloves, chemical resistant apron-Wash l off after each use. Replace as necessary. EYE PROTECTION: splash proof chemical goggles, face shield l
- 9) PHYSICAL AND CHEMICAL PROPERTIES l
Spscific Grav. (70F) 1.184 Vapor Pressure (mmHG) ~ 22.0 l Freeze Point (F) -4.00 Vapor Density (air =1) < 1.00 i Viscosity (cps 70F) 37 % Solubility (water) 100.0 l Odor Mild j l -Appearance Dark Brown j Physical State Liquid l Flash Point (F) > 200 P-M (CC) pH As Is (approx.) 13.5 . Evaporation Rate (Ether =1) < 1.00 NA = not applicable ND = not determined l i l f PAGE 4 CONBNUED I
PRODUCT NAME : INHIBITOR AZ8103 EFFECTNE DATE: 28 JAN-1997
- 10) STABILITY AND REACTIVITY STABluTY:
Stable under normal at conditions. HAZARDOUS POLYME TION: Will not occur. INCOMPATIBluTIES: May react with acids. DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/ CLEANOUT CATEGORIES: "C"
- 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT:
945 mg/kg NOTE - Estimated value l Darmal LD50 RABBIT: >S,000 mg/kg NOTE - Estimated value l l l l I l l l PAGE 5 CONTINUED l l f
PRODUCT NAME :INHl88 TOR AZ8103 EFFECTIVE DATE: 28 JAN-1997
- 12) ECOLOGICAL INFORMATION 1
AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50: 28.1 mg/L-No Effect Love : 21 mg/L Fathead Minnow 96 Hour Static Acute Bioassay i pH of test solutions was adjusted to a level of 6-9. l LC50: 39.4 mg/L l L No Effect Level: 28 mg/L Daphnia magna 48 Hour Static Acute Bioassay pH of test solutions was adjusted to a level of 6-9. LC?O: 66 mg/L No EN Level: 28 mg/L l l Mysid Shrimp 96 Hour Static Acute Bioassay LC50: 17.2 mg/L No Effect Level: 6.25 mg/L Menidia beryliina (Silversides) 96 Hour Static Acute Bioassay l Mortality was observed in lowest concentration tested. LC50: 20.5 mg/L 5% Mortality: 6.25 mg/L BIODEGRADATION COD (mg/gm): 271 Calculated TOC (mg/gm): 67 Calculated BOD-5 (mg/gm): 7 Calculated 80D-28 (mg/gm): 7 Calculated l
- 13) DISPOSAL CONSIDERATIONS I
ff this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : D002= Corrosive (pH). Please be advised; however, that state and local requirements for l waste disposal may be more restrictive or otherwise different from i federal regulations. Consult state and local regulations regarding the proper disposal of this material. l PAGE 6 CONDNUED
' PRODUCT MAME : INHIBITOR AZ8103 EFFECTIVE DATE: 284AN4997
- 14) TRANSPORT INFORMATION 1
DOT HAZARD: Corrosive to skin UN / NA NUMBER: UN1824 DOT EMERGENCY RESPONSE GUIDE #: 60
- 15) REGULATORYINFORMATION TSCA:
All components of this product are listed in the TSCA inventory. CERCLA ANDIOR SARA REPORTABLE QUANTITY (RQ)ODA); 741 gallons due to SODIUM HYDROXIDE (CAUSTIC S SARA SECTION 312 HAZARD CLASS: immediate(acute); Delayed (Chronic) SARA SECTION 302 CHEMICALS: No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 66) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION I No regulated constituent present at OSHA thresholds j i-l l PAGE 7 CONTINUED
PRODUCT NAME :INHlBITOR AZ8103 EFFECTWE DATE: 284AN 1997
- 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 3
Serious Hazard l Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special CORR DOT corrosive (1) Protective Equipment D Goggles, Face Shield, Gloves, Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations. l CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 28-JAN-1997
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l l PAGE 8
e i i P BETZ LABORATORIES,INC. '4636 SOMERTON ROAD,TREVOSE,PA.19047 PRODUCT: COPPER-TROL CU-1 1/22/91 AQUATIC TOXICOLOGY l DAPHNIA MAGNA ) 0% MORTALITY: 65 MG/L 48 HR. LC50: 112.5 MG/L RAINBOW TROUT 0% MORTALITY: 21 MG/L 96 HR. LC50: 28.1 MG/L l FATHEAD MINNOW 0% MORTALITY: 49 MG/L 96 HR. LC50: 60.6 MG/L l 1/22/91 MAMMALIAN TOXICOLOGY ORAL LD50 -NO DATA l DERMAL LD50 -NO DATA SKIN IRRITATION SCORE-NO DATA EYE IRRITATION SCORE-NO DATA INHALATION-NO DATA l l
MATERIAL SAFETY DATA SHEET i As% $ $ hjk g P.O. Box 1346 =hw Pittsburgh, PA 15230-1346 e a, a n a r i ou l 24 Hour Emergency Telephone--(412)777-8000 Soction 1. PRODUCT IDENTIFICATION PRODUCT NAME: Pre-Tect 7080 HP CHEMICAL DESCRIFFION: Monoethanolamine in water PRODUCT CLASS: Water treatment MSDS CODE: OF71 Section 2. HAZARDOUS INGREDIENTS AND EXPOSURE LIMITS CAS % by Chemical Name Number W&t. OSHA PEL ACGIH TLV Monoethanolamine (MEA) 141-43-5 80 TWA 3 ppm,8 TWA 3 ppm, 7.5 3 mg/m ; $rEL 6 mg/m3; STEL 6 3 ppm,15 mg/m3 ppm,15 mgtm (Synonyms: Ethanolamines and 2-Ammoethanol.) i Section 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER! May cause severe eye and skin damage. May be harmful it absorbed throu6h skin or if swallowed. Aspiration may cause lung damage. May cause respiratory tract irritation. Repeated exposure may cause kidney and liver damage. PRIMARY ROITIES OF ENTRY: Eye and skin contact, skin absorption, mhalation, ingestion TARGET ORGANS: Eye, skin, lung, liver, kidney, central nervous system MEDICAL CONDTITONS AGGRAVATED BY EXPOSURE: Inhalation may aggravate asthma and inflammatory or fibrotic pulmonary disease. Because of its irritating r@es, this material may aggravate an existin6 ermatitis. d l t PaSe 1 MSDS Coce: 0F71 Conunued on Page 2 issue Date: 11/17f)4
1 MATERIAL SAFETY DATA SHEET ) POTENTIAL HEALTH EFFECIS: EYE CONTACT: This product may cause severe irritation and damage upon contact with the eye. SKIN CONTACT: This product may cause irntanon upon contact with the skin. If not removed promptly, burns may result. By OSHA definition, pure monoethanolamme is tox2c by skin absorption. Prolonged or widespread skin contact may result in the abscrption of harmful I amounts of material. There is no evidence that the ethanolammes can cause allergic contact dennatitis. l l INGESTION: Swallowmg monoethanolamine may cause chemacal burns of the mouth, throat, esophagus, and stomach. Signs and symptoms will include pain or discomfort in the mouth, i chest, and abdomen, nausea, vomiting, diarrhea, dizzmess, drowsmess, faintness, weakness, collapse, and coma. Aspiration may occur durmg swauowmg or vomiting, resulting in lung ) mpury. INHALATION: Breathing psoduct mist or vapor may cause irritation with coughing and <h==nfort in the nose, throat and chest. Prolonged exposure to moderately high vapor concentrations may l l cause local injury to the respiratory tract. However, the sensory irritant propernes of. monoethanolamme vapors should pve adequate wammg of a potential acute inhalation j overexposure situation. In ammal P , subacute high level exposures to monoethanolasune vapor and mist produced pulmonary damage, lethargy, and some j non-specific degenerative changes in the liver and kidneys. Lab tests have found ~ moncethanalamme to be a central nervous system (CNS) stimulant at low doses, and a CNS depressant at lethal doses. SUBCHRONIC, CHRONIC: Prolonged or repeated exposure to monoethedm%e may cause liver and kidney damage. Ia.;; ' i inhalation of moncethanolamme vapors has caused nerve damage in laboratory animals. Oral intake of monoethanolamine during pregnancy has caused embryotoodcity and maternal toxicity in rats. In spite of i the widespread use of monceth d=Me in industry, no reports of injury to workers have been found. 1 CARCINOGENICITY: N!P: 'No mgredients listed in this section* IARC: 'No ingredient: listed in this section* OSHA: l
- No ingredients listed in this section*
l Section 4. FIRST AID MEASURES l EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid immediately. r SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes whale removmg contanunsted clothing and shoes. Seek medial aid immediately. Wash clothing before reuse. I INGESTION: If swallowed, do NOT induce vomiting. Give large quantities of water. Seek snedical aid immediately. Never give anything by mouth to an unconscious person. i MSDS Cooe: 0F71 Pa6e 2 issue Date: 11/17/94 Conunued on Page 3 l
MATERIAL SAFETY DATA SHEET INHALATION: If inhaled, remove to tresh atr. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical aid. Stetion 5. HRE-HGHTING MEASURES FLASH POINT: > 200*F (TCC) This product is not by definition a " flammable liquid" or a " combustible liquid". LOWER FLAMMABLE LIMm Not available UPPER FLAhOdABLE LIMrr: Not available AUTO-IGNmON EMPERA'IURE: Not available EXTINGUISHING MEDIA: Apply alcohol-type or all-purpose-type foams by manufacturer's recommended techniques for large fires. Use CO or day chemical media for small fixes. 2 FIRE-FIGIENG INSTRUCITONS: Exercise caution when fighting any chemical fire. A self-contained breathing apparatus and protective dothin6 are essential. Do not direct a solid stream of water or foam into hot, burnmg pools; this may cause spiattenng and increase fire intensity. FIRE de EXPLOSION HAZARDS: Product emits tosde gases under fire conditions. For any liquid organic product that has a flash point, it should be noted that ignition may occur at temperatures below those published in the literature as autoignition or ignition tesaperatures. Ignition temperatures deczense with inczensing vapor vehene and vaportair contact time and are influenced by pressure dianges. Any proposed use of this y. h in elevated-temperature prar===== should be thoroughly evaluated to assure that safe operating conditions are established and maintained. l DECOMPOSmON PRODUCIS: 1hermal decomposition or cosabustion may produce carbon monoxide, carbon dioxide, and nitrogen cuides. NFPA RATINGS: Health - 3 P' = " "My - 1 Reacsivity = 0 Special Hazard = None l Hazard raung scale: o-p====i 1-slight 2-Mad -as s-senaus 4-severe Section 6. ACCIDENTAL RELEASE MEASURES SIEPS TO BE TAKEN IF MATERIAL IS RE!JiASED OR SPElJID: Remove au sources of ignition. Wearing appropnate personal protective -, ', ~. contain spin, causet onto inent absorbent and place into suitable container. l Section 7. HANDLING AND STORAGE l HANDIJNG: Do not get in eyes, on skin or clothing. Avoid breathing vapor or mist. } Use with adequate ventilation. Wash thoroughly after handlin6-Keep contamer closed when not in use. MSDS Code: OF71 Page 3 !ssue Date: 11/17/94 Conunued on Page 4 ~ l
MATERIAL SAFETY DATA SHEET l STORAGE: Store in well-ventilated area free of sources of ignition. Separate from oxidizing materials. Szction 8. EXPOSURE CONTROLS / PERSONAL PROTECTION l PERSONAL PRO 1ECTTVE EQUIPMENT: EYE / FACE PROTECTION: Chemical splash goggles and face shield SKIN PROTECHON: Chenucal resistant gloves and protective clodung l RESPIRATORY PROTECHON: If auborne concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134). ENGINEERING CONTROLS: Use local and/or general exhaust ventilation to maintain airborne concentrations below exposure limits. WORK PRACTICES: Eye wash station and safety shower should be accessible in the immediate area of use. Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: 338'P for MEA SOLUBILITY IN WATER: Complete VAPOR PRESSURE: 0.28 - 0.35 mmHg 8 20*C SPECIPIC GRAVITY: 1.00 - 1.04 e 25'C for MEA VAPOR DENSIIY (air = 1): 2.1 for MEA pH: 13.7 8 25'C % VOLA 1TLE BY WEIGHT: 20 (water) FREEZING POINT: < -40 *F APPEARANCE AND ODOR: Qear, colorless, low viscosity liquid with mild ammoniacal odor. Section 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Keep away from heat and flame. This y.u.may undergo a self-sustaming themial decomposition when heated to temperatures above 250*C (482*P). INCOMPATIBIIlTY: Strong oxidizers and acids, alununum, copper, aldehydes, ketones, aczylates, organic anhydrides, and organic halides. DECOMPOSITION PRODUCIS: Thermal decomposition or combustion may produce carbon monoxide, l carbon dioxide, and nitrogen oxides. S:ction n. TOXICOLOGICAL INFORMATION ON PRODUCT: See the followmg information on ingredients. MSDS Cone: OF71 Page 4 Issue Date: 11/17/94 Continued on Page 5 ~ )
MATERIAL SAFETY DATA SHEET ON INGREDIENTS: Oral LD o Dermal LDr,o Inhalation LC o 5 5 Qemical Name (rat) _ (rabbit) (rati Monoethanolamine (MEA) 1720 ang/kg 1000 mg/kg Not available l Szction 12. ECOLOGICAL INFORMATION ON PRODUCT: l See the following information on ingredients. i i l ON INGRED3ENIS: Chemical Name Aountic TOMk2tY Data Monoethanolamme 96 hr LCso (fathead manow): 125 ppm 24 hr LC o (Daphnia magna): 140 ppm 5 l- % hr LC (bluegill sanash): 75 ppm ~ 5 l Section 13. DISPOSAL CONSIDERATIONS RCRA STNIUS: Discarded pmduct, as sold, would be considered a RCRA Hazardous Waste based on the charactenstic of corrosivity. De EPA Hazardous Waste Number is D002. DISPOSAL: Dispose of in accordance with local, state and federal regulations. l l Section 14. TRANSPORT INFORMATION l DOT CLASSIFICATION: Cass/ Division: 8 Proper Shipping Name: Ethanolamme solution label: Corrosive Packm8 Group: III l ID Number: UN 2491 Section 15. REGULATORY INFORMATION l l OSHA Hazard Communication Status: Hazardous 15CA: De mgr=rH==*= of this product are listed on the Taxic Substances Control Act (ISCA) Cheaumi l Substances Inven Jay. CERCLA reportable quantity of EPA hazardous substances in product: Osenucal Name EQ_
- No mgredaents listed in this seenon*
l i. Product RQ: Not applicable (Noufy EPA of product spills exceedmg this amount.) j MSDS Code: OF71 Page 5 ~ Issue Date: 11/17/94 Conunued on Page 6 1 I u_ j
i MATERIAL SAFETY DATA SHEET i SARA TTII.E III: i Section 302 Extremely Hazardous Substances: l Chemical Name CAS
- BD_
TPO 'No in6redients listed in this section* Section 311 and 312 Health and Physical Hazards: Immediate Delayed Fire Pressure Reactivity l [yesi [yes] [no] [nol [no] l Section 313 Toxic Ch-Ir=l=: l Otemical Name CAS* % by Weieht l
- No mgredients listed in this section'
{ l Section 16. OTHER INFORMATION 1 HMIS RATINGS: Health = 3* Flammability - 1 Reactivity - 0 Personal Protectne Equipment = X (to be spa =d by user depending on use conditions) "There are W-1 chronic health effects to consider. l l Hazard radng smie: 0-Minknal 1-Slight 2-Moderate 3-Serious 4-Severe l MSDS REVISION
SUMMARY
- Not applicable White this information and recommandottom set forth herein are bettewed to be accurate as of the date hereof, CALMN CORPORATION MAKES No WARRANTY WITN RESPECT HERETO AND DISCLAIMS ALL LIAs!LITY FROI RELIANCE THEREON.
l PREPARED BY: P.J. Maloney l 1 I MSDS Code: OF71 Page 6 Issue Date: 11/17/94 Last Page
MATERIAL SAFETY DATA SHEET P.O. Box 1346 Pittsburgh, PA 15230 1346 e o a e o a a r i o u 24 Hour Emergency Telephone--(412)777-8000 Section 1. PRODUCT IDENTIFICATION l PRODUCT NAME: Pre-Tect 9002HP CHEMICAL DESCRIPTION: Aqueous amine solution PRODUCT CLASS: Boiler water treatment MSDS CODE: OF64 Section 2. INFORMATION ON INGREDIENTS CAS % by Chemical Name Number Weicht. OSHA PEL ACGTH TLV Dimethylamine (DMA) 124-40-3 2 1WA 10 ppm,18 TWA 5 ppm, 9.2 mg/m3 3 mg/m ; STEL 15 l ppe, 27.6 mg/m3 Section 3. HAZARDS IDENTIFICATION I EMERGENCY OVERVIEW DANGERI May cause severe eye and skin damage. May be harmful if swallowed. i May cause allergic skin reaction. May cause respiratory tract irntation. Combustible liquid and vapor. May form suspected cancer-causing nitrosamines if mixed with nitrites. l PRIMARY ROUTES OF ENTRY: Eye and skin contact, inhalation, skin absorption, ingestion TARGET ORGANS: Eye, skin, lung, mucous membranes, liver MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Asthma Skin disorders and allergies Chronic respiratory disease. e.g., bronchitis, emphysema Eye disease MSDS Code: OF64 Page ! Issue Date: 05-16-95 Connnued on Page 2 L_-__---------_--
MATERIAL SAFETY DATA SHEET POTENTIAL HEALTH EFFECIS: EYE CONTACT: This product may cause irreversible eye damage upon contact depending on the length of exposure, solution concentration and first aid measures. Product vapor in low concentrations l can cause tearing, conjunctivitis and corneal edema when absorbed into the tissue of the eye from the atmosphere. Comeal edema may give rise to a perception of " blue haze" or " fog" around lights. The condition is transient and has no known residual effect. SKIN CONTACT: This product may produce burns upon contact with the skin. The severity of the bum is generally deterinined by the concentration of the solution and the duration of the exposure. The vapors may also be irritating to the skin. DMA may cause an al!argic skin reaction and may be absorbed through the skin causing nausea, headache, an.1 general discomfort. l i INGES110N: Ingestion of this y.mi.act may cause severe irritation or burns of the mucous membranes of the mouth, thmet, esophagus and stomach. f INHALATION: DMA vapors are irritating to the respiratory tract. Inhalation of vapors may produce cheaucal pneumonitis, pulmonary edema, and delayed scarnng of the airway and other affected i organs. Repeated and/or prolonged exposure to vapors may cause ciuenic irritation of the respiratory tract, bronchopneumonia, and other adverse respiratory effects sud as cough, tightness of chest, or shortness of breath. SUBCHRONIC, CHRONIC: DMA added to the diet of rats at 150 mg/kg for 3.5 months increased liver demethylase activity even in the presence of the enzyme inducer casein. In a subchronic study,15 rats,15 gs.inea pigs,3 rabbits,2 dogs, and 3 monkeys were exposed continuously by inhalation at apprommately 5 ppm of DMA for 90 days. There were no deaths or signs of toxicity and all hematologic values were normal. On hise yd.ck ic examination, interstitial inflammatory changes were noted in the lungs of each speces. ii Further, the 3 rabbits and 2 monkeys showed c!lilatation of the bronchi. In a 2-year inhalation study, groups of 95 male and 95 female rats and mice were exposed 6 hours / day, 5 days / week at 10, 50, or 175 ppm of DMA. Concentration-dependent toxicity was charactenzed by deceased body weight (175 ppm only) and progressive inflammatory, degenerative, and hyperplastic lesions of the nasal passages. Nasal toxicity was similar in both rats and mice (no sex differences) affecting respiratory and olfactory epithelia. Lesions were severe at 175 ppm, moderate at 50 ppm, and i focal and mdd at 10 ppm. CARONOGENICITY: NTP: l
- No ingredients listed in this section*
IARC:
- No ingredients listed in this section*
OSHA: 'No ingredients listed in this section* Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid immediately. MSDS Code: OF64 Page 2 Issue Date: 05-16-95 Connnued on Page 3
1 MATERIAL SAFETY DATA SHEET l SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Seek medical aid immediately. Wash clothing before reuse. Destroy contaminated leather apparel. Vicums with major skin contact should be maintained under medical observation for at least 24 hours due to the possibility of delayed reaction. INGEETION: If swallowed, do NOT induce vomiting. Give large quantities of water. Seek medical aid immediately. Never give anything by mouth to an unconscious persor Note to Physicians: This y.=dect is highly injurious to all tissues, similar to that of ammonia or ammonia gas. Chemical pneumonitis, pulmonary edema, laryngeal edema and delayed scarnns of the airway or other affected tissues may occur following exposure. There is no spenfic treatment. Clinical mar.4gement is based on supportive treatment, whids is simdar to that for thermal burns. INHALATION: If inhaled, remove to fresh air. If not breathing, give artifical respiration. If breathing is difficult, give oxygen. Seek medical aid. Prevent aspiration of vomit. Tum victim's head to the side. Assure mucous does not obstruct airway. Section 5. FIRE-FIGHTING MEASURES FLASH POINT: 127'F (COC) This product is a combustible liquid. LOWER FLAMMABLE LIMIT: Not available UPPER FLAMMABLE LIMIT: Not available AUTO-IGNmON TEMPERATURE: Not available EXTINGUISIGNG MEDIA: Use cog, dry chemical, alcohot foam. FIRE-FIGHTING INSTRUCI1ONS: Exerose caution when fighting any chemical fire. A self-contained l breathing apparatus and protective clothing are essential. Use water to }:eep fire-exposed containers cool. FIRE & EXPLOSION HAZARDS: Product emits toxic gases under fire conditions. Product vapors are l heavier than air and may travel a considerable distance to a source of ignition and flash back. Vapors may collect in closed spaces such as sewers, caves or closed structures. l DECOMPOSmON PRODUCTS: Upon decomposition, ammonia vapors are liberated. Upon combustion in the presence of sufficient oxy 5en, product generates harmful carbon monoxide, carbon dioxide, and nitrogen oxuie gases. Nitrogen oxide can react with water vapor to yield nitric acid. Combustion of product under oxygen-starved conditions can be expected to picduce numerous toxic products induding: nitriles, cyanic acid, isocyanates, cyanogens, nitrosamines, amides, carhamates. NFPA RATINGS: Health = 3 Flamn ability = 2 Reactivi:y = 0 Special Hazard - None Hazard ratmg scale: 0-Mmunal ! = Slight 2-Moderate 3-Senous 4-Severe MSDS Code: 0F64 Pas;e 3 !ssue Date: 05-16 95 Connnued on Page 4
MATERIAL SAFETY DATA SHEET l S:ction 6. ACCIDENTAL RELEASE MEASURES SEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Ventilate area of spill. Eliminate all ignition sources. Approach release from upwind. Use water spray to cool and disperse vapors, protect personnel, and dilute spills to form nonflammable mixtures. Five percent sulfuric acid may be used to neutralize diluted pools. Wearing appropriate personal protective equipment, contain spill, collect onto noncombustible absorbent like sand or earth and place into suitable container. Vapors tend to remain dose to the ground and collect in out-of-the-way places. Use non-sparking blowers or ventilation j facilities to remove potential explosive or toxic accumulations. Section 7. HANDLING AND STORAGE HANDLING: Do not get in eyes, on skin or dothing. Avoid breathing vapor or mist. Keep away from heat and flame. 1 Use with adequate ventilation. Wash thoroughly after handling. Keep container dosed when not in use. l Remove all equipment which may be a source of ignition from vidnity while handling. Empty containers may contain explosive vapors. Plush empty containers with water to remove residual flammable liquid and vapors. STORAGE: Keep away from oxidizers, heat or flames. Store away from ignition sources. Ground all containers during transfer. Store in steel containers preferably located outdoors, above ground, and surrounded by rhka to contain spills or leaks. Sectrical installations should be in accordance with Artide 501 of the National Electrical Code for Class ! Division 2 locations. Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECFiE EQUIPMENT: EYE / FACE PROTEGON: Chemical splash goggles and face shield SKIN PROTEGON: Chemical resistant gloves and protective dothing l RESPIRATORY PROTEGON: If airborne concentrations exceed published exposure limits, use a NIOSH ayy.sced respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134). t ENGINEERING CONTROLS: local exhaust ventilation may be required in addition to general room ventilation to maintain airborne concentrations below exposure limits. WORK PRAGCES: Eye wash station and safety shower should be accessible in the immediate area of use. UNSA11SFACTORY MATERIALS OF CONSTRUGON: DMA corrodes copper, aluminum, zinc, and galvanized surfaces. Page 4 MSDS Code: OF64 Connnued on Page 5 Issue Date: 05-16-95
MATERIAL SAFETY DATA SHEET Section 9. PHYSICAL AND CHEMICAL PROPERTIES l BOILING POINT: Not available SOLUBILITY IN WAN Complete i VAPOR PRESSURE: 2 torr 910*C (for DMA) SPECIFIC GRAVITY: Not vailable VAPOR DENSITY (air = 1): 1.55 (for DMA) pH: Basic % VOLATILE BY WEIGHT: 100 FREEZING POINT: Not available APPEARANCE AND ODOR: Clear, colorless liquid with ammoniacal / fishy odor. l Section 10. STABILITY AND REACTIVITY j CHEMICAL STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur l l CONDmONS TO AVOID: Keep away from heat and flame. INCOMPATIBILITY: Strong oxidizers, acids, copper, aluminum, zinc and galvanized surfaces. DECOMPOSmON PRODUCIS: Upon decomposition, ammonia vapors are liberated. Upon combustion in the presence of sufficient oxygen, product generates harmful carbon monoxide, carbon dioxide, and nitrogen oxide gases. Nitrogen oxide can react with water vapor to yield nitric acid. Combustion of product under oxygen. starved conditions can be expected to produce numerous toxic products including: nitriles, cyanic acid, isocyanates, cyanogens, nitrosamines, amides, carbamates. Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT: l See the following information on active ingredient. ON INGREDIEN'IS: Oral LDg Dennal LD a Inhalation LC 5 50 Chemical Name (rat) (rabbit) (rat) Dimethylamine (DMA) 698 mg/kg Not available 4540 ppm /6H l Section 12. ECOLOGICAL INFORMATION i ON PRODUCT: Aquatic toxicity data on a 10% solution of DMA: 48 hr LC a (Daphnia magna): 675 ppm % hr LCso (fathead minnow): > 1000 ppm % hr LCg (bluegill sunfish): > 1000 ppm Aquatic toxicity data on a 2% solution of DMA: 7-day NOEC (Ceriodaphnia dubia): 1000 ppm (for-survival and reproduction) MSDS Code: OF64 Page 5 issue Date: 05-16-95 Connnued on Page 6
MATERIAL SAFETY DATA SHEET Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: The EPA Hazardous Waste Number is UO92. DISPOSAL: Dispose of in accordance with local, state and federal regulations. Incineration is acceptable and the preferred method of disposal. However, nitrogen oxide emission controls may be required to meet l specifications. Chemical and/or biologu:al degradation is feasible. A suitable industrial or municipal i waste treatment system can be used depending on the quality and quantity of waste to be treated, the I treatment plant capability, and discharge water quality standards. Incinerate in an open container. Do not dump into municipal sewers or enclosed drains that present a fire or explosion hazard. Section 14. TRANSPORT INFORMATION l DOT CLASSIFICATION: i Cass/ Division: 3 Proper Shipping Name: Flammable liquid, corrosive, n.o.s. (Dimethylamine) Label: Rammable liquid, Corrosive Packing Group: m i ID Number: UN 2924 Section 15. REGULATORY INFORMATION l OSHA Hazard Communication Status: Hazardous 'ISCA: The ingredients of this product are listed on the Toxic Substances Control Act (TSCA) Chemical j Substances Inventory. CERCLA reportable quantity of EPA hazardous substances in product: l i Chemical Name EQ. Dimethylamine (DMA) 1000 lb Product RQ: 50,000 lb (Notify EPA of product spills exceeding this amount.) SARA TITLE m: Section 302 Extremely Hazardous Substances: Gemical Name CAS* RQ HQ_ l 'No ingredients listed in this section* l Section 311 and 312 Health and Physical Hazards: Immediate Delayed Fire Pressure Reactivity l [yes] [yes! [yesj [no) (no] l Section 313 Toxic Chemicals: Chemical Name CAS* % by Weicht Dimethylamine (DMA) 124-40 3 2 l MSDS Code: OF64 Pa5e 6 Issur Date: 05 16-95 Conunued on Page 7 l l
MATERIAL SAFETY DATA SHEET Section 16. OTHER INFORMATION HMIS RATINGS: Health = 3' Flammability = 2 Reactivity = 0 Personal Protective Equipment = X (to be specified by user depending on use conditions)
- There are potential chronic health effects to consider.
Hazard rating scale: 0- Minimal ! = SLght 2 = Moderate 3= Serious 4 - Severe MSDS REVISION
SUMMARY
- Supersedes MSDS issued on 9-21-94. The MSDS has been changed in Section.
12. I Wile tHe information and recommendations set forth herein are believed to be accurate as of the date hereof, CALGON CCltPORAfl0N MAKES NO WARRANTY WITN RESPEcf HERETO AND DISCLAIMS ALL LI ASILITY FROM RELI ANCE THEREO PREPARED BY: P.J. Maloney MSDS Code: 0F64 Page 7 l Issue Date: 05-16-95 Last Page t ~
7 MATERIAL SAFETY DATA SHEET Ad PRODUCT CARBOHYDRAZIDE NALCO 1250 PLUS N ALC O Emergency Telephone Number Medical (800) 46'2 5378(24 hours) (800)1 M ALERT SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 1250 PLUS DESCRIPTION: An aquecus solution of a modified amino compound NFPA 704M/HMIS RATING: 1/1 HEALTH 1/1 FLAMMABILITY 0/0 REACTIVITY 0 OTHER 0= Insignificant l= Slight 2= Moderate 3=High 4= Extreme SECTION 2 COMPOSITION / INGREDIENT INFORMATION i Our hazard evaluation of the ingredient (s) under OSHA's Hazard Communication Rule, 29 CFR 1910.1200 has found none of the ingredient (s) hazardous. SECTION 3 HAZARD IDENTIFICATION EMERGENCY OVERVIEN: CAUTION! May cause irritation to skin and eyes. Avoid contact with skin, l eyes and clothing. Do not take internally. l Empty containers may contain residual product. Do not reuse container unless l properly reconditioned. PRIMARY ROUTE (S) OF EXPOSURE: Eye, Skin l l LTE CONTACT: May cause irritation with prolonged contact. I SKIN CONTACT: May cause irritation with prolonged contact. INGESTION: Can be harmful. SYMPTOMS OF EXPOSURE: A review of available data does not identify any ( symptoms from exposure not previously mentioned. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 4 FIRST AID INFORMATION l ETES: Flush with water for 15 minutes. Call a physician. SKIN: Flush with water for 15 minutes. INGESTION: Induce vomiting. Give water. Call a physician. INHALATION: Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble. breathing or in convulsions, do not induce vomiting or give water. 9?.c:: : OF 9 NALCO CHEM 8 CAL COMPANY ONE NALCO CENTER
- NAPERVILLE. ILLINOIS S0563-1198 AMEA S30-3051000 L_____--_____----_-
MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS N ALC D Emergency Telephone Number Medical (800) 482 5378 (24 hours) (800)1 M ALERT MM SECTION 5 FIRE FIGHTING FLASH POINT: None EXTINGUISHING MEDIA: This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use water to cool containers exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. SECTION 6 ACCIDENTAL RELEASE MEASURES IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (800) I-M-ALERT or (800) 462-5378. SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 15. Large liquid spills: Dike to prevent further movement asad reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 15. SECTION 7 HANDLING y STORAGE Handling: Avoid contr.ct with skin, eyes, and clothing. Storage : Keep cont.ainer closed when not in use. SECTION 8 EXPOSUPE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOLH approved or equiva3ent respirator. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a positive pressure, stif-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding squipaent, doing maintenance or handling product. Examples of niirile, PVC, natural impermeable gloves available on the market are neoprent, PAGE 2 OF 8 6 0 563-11 98 NALCO CHEMICAL COMPANY ONE NALCO CENTER
- NAPERVILLE. ILI INCIS
[ - wmancsw
MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS N ALC O Emergency Telephone Number Medical (800) 482 5378 (24 hours) (800)I M ALERT SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION ( CONTINUED ) rubber, viton and butyl (compatibility studies have not been performed). The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the effected area. Launder contaminate.1 clothing before reuse. HUMAN EXPOSURE CHARACTERIZATION: Based on Nalco's recommended product application and our rceoemended personal protective equipment, the potential human exposure is HIGH. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear, colorless FORH Liquid DENSITY: 8.7-lbs/ gal. SOLUBILITY IN WATER: Completely SPECIFIC GRAVITY: 1.04-1.05 0 77 Degrees F ASTM D-1298 8.4 ASTM E-70 pH (NEAT) = VISCOSITY: 3 eps e 75 Degrees F ASTM D-2983 1 FREEZE POINT: 28 Degrees F ASTM D-1177 211 Degrees F @ 760 nun Hg ASTM D-86 BOILING POINT: s FLASH POIFT: None l NOTE: These physical properties are typict i values for this product. SECTION 10 STABILITY AND RIACTIVITY INCOMPATIBILITY: Mineral acids, nitrites. Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganates) which can generate heat,, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, CO2, NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. I SECTION 11 TOXICOLOGICAL INFORMATION TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but studies have been conducted on a similar product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LD50 = Greater than 5,000 mg/kg PAGE 3 OF 8 NALCD CHEMICAL COMPANY ONE NALCO CENTEFI
- NAPERVILLE. ILLINOIS SCES3-1198 AAEA 830GO510CX3
MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS N ALC O Emergency Telephone Number Medical (800) 482 5378 (24 hours) (800)1 M ALERT SECTION 11 TOX1COLOGICAL INFORMATION ( CC..INUED ) ACUTE DERMAL TOXICITY (ALBINO RABBITS): LD50 = Greater than 2,000 mg/kg PRIMARY SKIN IRRITATIO,1 TEST (AL3INO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 0.33/8.0 Minimal irritation PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRLIZE RATING: 0.33 /110.0 Practically non-irritating OTHER TOXICITY RESULTS: Ames test was weakly positive. i HUMAN HAZARD CHARACTERIZATION: Based on our hazard characterization, the potential human hazard is: LOW SECTION 12 ECOLOGICAL INFORMATION AQUATIC DATA: Results below are based on a similar product. 96 hour static acute LC50 to Bluegill Sunfish = 190 ppm l 96hourstaticacute$C50toRainbowTrout=360 ppm Results below are based on the product. 7-day chronic static renewal IC25 for Cariodaphnia Dubia reproduction = 17.3 mg/L 7-day no obsarved effect concentration is 8.1 mg/L based on no effect on reproduction. 48 hour static acute LC50 to Cariodaphnia Dubia = 85 mg/L 48 hour no observed effect concentration is 31 mg/L based on no mortality. TOXICITY RATING: If released into the environment, see CERCLA in Section 15. ENVIRONMENTAL HAZARD CHARACTERIZATION: Bassed on our Hazard Characterization, the potential environmental hazard ist MODERATE. Based on Nalco's roccanended product application and the product's PAGE 4 OF 8 NALCD CHEMICAL COMPANY ONE NALCO CENTER
- NAPERVILLE. ILLINOIS 6 0 5 6 3-1 1 9 8 AAEA B3C}3C25-1000
MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS NALCO Emergency Telephone Number Medical (800) 462 5378 (24 hours) (800)1 M-ALERT SECTION 12 ECOLOGICAL INFORMATION ( CONTINUED ) characteristics, the potential environmental exposure is: MODERATE. SECTION 13 DISPOSAL CONSIDERATIONS DISPOSAL: If this product becomes a waste, it does not meet the criteria of I a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it du.es not have the characteristics of Subpart C, nor is it listed under Subpart D. As a non-hazardous liquid waste, it should be solidified with stabilizing cgents (such as sand', fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be deep-well injected in accordance with local, state, and federal regulations. SECTION 14 TRANSPORTATION INFORMATION PROPEk SHIPPING NAME/ HAZARD CLASS MAY VARY EY PACKAGING, PROPERTIES, AND MODE OF TRANSPORTATION. TYPICAL PROPER SHIPPING NAMES FOR THIS PRODUCT ARE: ALL TRANSPORTATION HODES : PRODUCT IS NOT REGULATED DURING TRANSPORTATION SECTION 15 REGULATORY INFORMATION l The following regulations apply to this product. FEDERAL REGULATIONS: OSHA'S HAEARD COMMUNICATION RULE, 29 CFR 1910.1200: l Based on our hazard evaluation, none of the ingredients in this product cre hazardous. I CERCLA /SUPERFUND, 40 CFR 117, 302: l Notification of spills of this product is not required. SARA /SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION SO2 - EETREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an PAGE 5 OF 8 NALCD CHEMICAL COMPANY CNE NALCO CENTER
- NAPERVILLE. ILUNCIS 605S3-1198 AAEA G30 305-1000 l
l MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS N ALC O Emergency Telephone Number i Medical (800) 462 537C (24 hours) (800) 1 M-ALERT SECTION 15 REGULATORY INFORMATION ( CONTINUED ) Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200. Under SARA 311 and 312, the EPA has established threshold quantities for the ecporting of hazardous chemicals. The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients on the List of Toxic Chemicals. TOKIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & Da Consult section 13 for RCRA classification. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, Sec. 111 (40 CFR 60), Sec. 112 (40 CFR 61, 1990 Amendments), Sec. 611 (40 CFR 82, CLASS I and II Ozone depleting substances): This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS: CALIFORNIA PROPOSITION 65: Hydrazine is known to the State et California to cause cancer. This product l contains levels of hydrazine at less than 0.1%. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS This product does not contain ingredients listed by State Right To Know Laws. PAGE 6 OF 8 NALCD CHEMICAL COMPANY ONE NALCO CENTER
- NAPERVILLE. ILt.JNCIS SQ563-1198 AREA B3CF305-1000
MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS NALCD Emergency Telephone Number Medical (800) 462 5378 (24 hours) (800)1 M ALERT a i SECTION 16 OTHER INFORMATION I N21co internal number FlO2948 j SECTION 17 RISK CHARACTERIZATION Due to our conunitment to Product Stewardship, we have evaluated the human end environmental hazards e,d exposures of this product. Based on our r:conunended use of this pscoduct, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:
- The human zisk is LOW.
The environmental risk is: HODERATE. Any use inconsistent with Nalco's recommendations may affect our risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process. This product material. safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literatursi. Individuals handling this product should be informed of the reconsnended safety precautions and should have access to this information. For any other uses, exposures should be evaluated co that appropriate handling practices and training programs can be j catablished to insure safe workplace operations. Please consult your i local sales representative for any further information. SECTION 18 REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH. Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (CD-ROM version), Micromedex, Inc., Englewood, CO. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Han, Geneva World Health Organization, International Agency for Research on Cancer. Integrated Risk Information System, U.S. Environmental Protection Agency, l Washington, D.C. (CD-ROM version), Micromedex, Inc., Englewood, CO. PAGE 7 OF 8 NALCD CHEMICAL COMPANY ONE TNQ CENTER
- NAPERVILLE. ILUNOIS 605S3-1198 l
MEA B3XKE.1CCC )
MATERIAL SAFETY DATA SHEET PRODUCT NALCO 1250 PLUS N ALC D Emergency Telephone Number Medical (800) 482 5378 (24 hours) (800)1 M ALERT SECTION 1B REFERENCES ( CONTINUED ) Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service. Title 29 Code of Federal Regulations, Part 1910, Subpart z, Toxic and Hazardous substances, occupational Safety and Health Administration (OSHA). Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, Ohio (CD-ROM version), Micromodex, Inc., Engelwood, CO. Shepard's Catalog of Teratogenic Agents (CD-ROM version), Micromedex, Inc., Engelwood, CO. Suspect chemicals Sourcebook (a guide to industrial chemicals covered under major regulatory and advisory programs), Roytech Publications (a Division of Ariel Corporation), Bethesda, MD. The Taratogen Information System, University of Washington, Seattle, Washington (CD-ROM version), Micromedex, Inc., Englewood, CO. ? PREPARED BY: William S. Utley, PhD., DABT, Manager, Product Safety DATE CHANGED: 12/19/94 DATE PRINTED: 04/09/97 i l PAGE 8 OF 8 NALCO CHEMICAL. COMPANY ONE NALCO CENit:M
- NAPERVILLE, ILLINOIS 6 0 553-11 98 AREA S30-3o51000
l l PAGE 1 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00212 l CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET MATERIAL CODES i MATCODE PRIME LOC 60010011 A3010303A VENDOR INFORMATION VENDOR: CLIMAX MOLYBDENUM COMPANY STREET ADDRESS: 1626 COLE BLVD. CITY: GOLDEN, COLORADO STATE: CL ZIP CODE: 80401-3292 BUSINESS PHONE NUMBER: 303-231-0320 EMERGENCY PHONE NUMBER: 800-424-9300 SAFETY DATA SHEET REVIEW: 910612 SUBSTANCE IDENTIFICATION SUBSTANCE: SODIUM MOLYBDATE TRADE NAMES / SYNONYMS: MOLYDBATE, SODIUM,CRYSTALINE; DEHYDRATE FORM CHEMICAL FAMILY: N/A MOLECULAR FORMULA: NA2M004.2H2O RESPONSE NUMBER: NFPA RATINGS (0-MINIMAL, 1-SLIGHT, 2-MODERATE, 3-SERIOUS, 4-SEVERE) HEALTH: 1 FLAMMABILITY: 0 CHEMICAL REACTIVITY: 1 SPECIAL HAZARD: alk WCGS CHEMICAL CATAGORY (I THRU VI PER ADM 01-118): III NON-HAZARDOUS WASTE COMPONENTS AND CONTAMINANTS i PERMISSABLE COMPONENT NAME PERCENT CAS NUMBER EXPOSURE Sodium Molybdate 100 010102-40-6 5 mg/m3 PFYSICAL DATA DESCRIPTION: White odorless powder BOILING PNT: 687 C MELTING PNT: N/A SP. GRAVITY: 2.56 VAPOR PRESSURE: N/A PH: N/A SOL. IN WATER: 56 GRAMS cc j ODOR THRHD: N/A VAPOR DENSITY: N/A l
PAGE 2 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00212 ) CHEMICAL CONTROL SYSTEM ] MATERIAL SAFETY DATA SHEET j i k HEALTH EFFECTS AND FIRST AID REPORTS OF MOLYBDENUM TOXIC EFFECTS IN THE INDUSTRIAL STTING IS RARE. HAS A RELATIVE LOW ORDER OF TOXICITY. INHAIATION OF DUST / FUMES (MOO 3) IS IRRITATING TO EYES, NOSE AND MUCOUS MEMBRANES. RUSSIAN LITERATURE INDICATES POSSIBLE PULMONARY DISORDER RESEMBLING PNEUMOCONIOSIS. ALSO ) i JOINT DISORDERS (GOUT-LIKE) WITH INCREASED URIC ACID LEVELS NOTED. AN ESSENTIAL METABOLIC FACTOR.IN MAN. A CONSTITUENT ENZYME IN XANTHINE OXIDASE WHICH OXIDIZES XANTHINE OR HYPOXANTHINE TO URIC ACID. METABOLISM OF MO IS CLOSELY ASSOCIATED WITH COPPER IN THE BODY. EXCESSIVE INTAKE OF MOLYBDENUM MAY PRODUCE COPPER DEFICIENCY SYMPTOMS. HAS A HIGH RATE OF EXCRETION FROM THE BODY, ONE-THIRD WITHIN A 24-HR PERIOD. FIRST AID: l EYE CONTACT - FLUSH IMMEDIATELY WITH RUNNING WATER FOR 15 MINUTES, t INCLUDING UNDER EYELIDS. I SKIN CONTACT - FLUSH CONTACT AREA WITH WATER, WASH WITH SOAP & WATER. INHALATION - REMOVE TO FRESH AIR. RESTORE AND/OR SUPPORT BREATHING, AS REQUIRED. l INGESTION - INDUCE VOMITING, CONTACT SITE MEDICAL DEPARTMENT I FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: WEAK FIRE & EXPLOSION HAZARD WHEN POWDER IS EXPOSED TO HEAT / IGNITION FLASH POINT: N/A FIREFIGHTING MEDIA: N/A FIREFIGHTING INSTRUCTIONS: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APAPRATUS. L-l ]
PAGE 3 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00212 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET TOXICITY THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. ACUTE TOXICITY OF SODIUM MOLYBDATE ANIMAL TL50 MG/L NO EFFECT MG/L BLUEGILL 10,000-24H; 6790-96H 2400 RAINBOW TROUT 10,000-24H; 7340-96H 3200 CHANNEL CATFISH 10,000-24H; 10,000-96H 7500 FATHEAD MINNOW 10,000-24H; 7630-96H 5600 WATER FLEA 3370-24H
- 3220-48H 1800 SCUD 4800-24H
- 3940-48H COMPARATIVE ACUTE TOXICITY CHEMICAL SPECIES TESH H TOXICITY,TL50 MG/L MOLYBDATE RAINBOW TROUT 96 7340 CHROMATE RAINBOW TROUT 96 285 MOLYBDATE DAPHNIA 48 3220 CHROMATE DAPHNIA 48 3
ORL - RAT TDLO: 2810MG/KG (35W PRE) ORL - MUS TDLO: 448MG/KG (MGN) 1PR - RAT LDLO: 114MG/KG 1TR - RBT LDLO: 70MG/KG USSR studies in 1961 and 1966 found signs of gout in factory workers and among inhabitants of molybdeum rich areas of Armenia.
- However, a 1979 U.S.
study found no evidence of gout in factory induced workers. REACTIVITY REACTIVITY: FAIRLY STABLE AT ORDINARY TEMPERATURES. INCOMPATIBILITIES: COMBUSTIBLE IN POWDERY OR PARTICULATE STATE. OXIDIZED TO TRIOXIDE ABOVE 400C, SLOWLY OXIDIZED BY STEAM. REACTS WITH HALOGENS TO YIELD INCANDESCENCE. INSOLUBLE IN HC1, HF, NAOH, DILUTE H2SO4, AND AQUA AMMONIA. WHEN HEATED, MAY FORM A HYXACARBONYL HYDROXIDE, OR TRIOXIDE WHICH ARE HAZARDOUS. TRIOXIDE IS IRRITATING TO EYES, NOSE & THROAT. SEE COMMENTS: DECOMPOSITION: N/A l POLYMERIZATION: N/A CONDITIONS TO AVOID: I N/A l l l L___________________ j
l PAGE 4 OF 5 [ CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00212 ( CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET SPILL AND LEAK PROCEDURES l FOR SIGNIFICANT CHEMICAL SPILLS, REFER TO ADM 01-230 " CHEMICAL RELEASE AND RESPONSE". FOR ADDITIONAL RESPONSE INFORMATl3N REFER TO THE MSDS OVERVIEW. NOTIFY SAFETY PERSONNEL OF POWDER SPILLS. REMOVE SOURCES OF HEAT OR IGNITION. SMALL SPILLS CAN BE REMOVED BY VACUUMING OR WET SWEEPING IN ORDER TO KEEP AIRBORNE DUST AT A MINIMUM. CLEAN UP PERSONNEL SHOULD WEAR l RESPIRATORS AND PROTECTIVE CLOTHING. DISPOSAL - RECLAIM SCRAP METAL FOR SALVAGE OR REUSE. FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS. CONTACT ENVIRONMENTAL GROUP TO ARRANGE FOR DISPOSAL. PROTECTIVE EQUIPMENT USE GENERAL AND LOCAL EXHAUST VENTILATION TO KEEP DUST / FUME CONCENTRATIONS BELOW THE TLV. SUITABLE PRECAUTIONS IN THE FORM OF A RESPIRATOR TO BE TAKEN AGAINST INHALATION OF SOLUBLE MO COMPOUNDS OR THE OXIDE. WORKERS SHOULD BE PROVIDED WITH CHEMICAL SAFETY GOGGLES, THICK GLOVES, AND COVERALLS WHEN WORKING WITH TIIIS MATERIAL. SAFETY EYEWASH STATIONS SHOULD BE PROVIDED IN AREAS OF USE & HANDLING. DAILY CHANGE OF CLOTHES ADVISABLE WITH SHOWERING BEFORE CHANGING TO STREET CLOTHES. REEMPLOYMENT AND PERIODIC PHYSICAL EXAMINATIONS TO INCLUDE IRRITANT EFFECTS TO EYES OR RESPIRATORY TRACT AND THE GENERAL HEALTH OF THE WORKER. HANDLING STORAGE AND TRANSPORTATION INFORMATION DEPARTMENT STORED IN: WAREHOUSE RECEIVING, WAREHOUSE, WATER TREATMENT P: ANT. TYPE OF CONTAINERS: Not Determined QUANTlTIES: Not Determined STORAGE PRECAUTIONS: STORE IN COOL, DRY, WELL-VENTILATED AREA, AWAY FROM SOURCES OF HEAT AND IGNITION AND AWAY FROM INCOMPATIBLE MATERIALS. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. USE GOOD HOUSEKEEPING PRACTICES TO KEEP AIRBORNEPARTICULATE AT A MINIMUM. ENVIRONMENTAL CONCERNS CONTACT ENVIRONMENTAL GROUP TO ARRANGE FOR DISPOSAL. l f l
PAGE 5 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00212 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET COMMENTS USE GOOD HOUSEKEEPING PRACTICES TO KEEP AIRBORNE PARTICULATE AT A MINIMUM. ALTHOUGH MOLYBDENUM COMPOUNDS.ARE OF.A LOW ORDER OF TOXICITY, ANIMAL STUDIES INDICATF TAKING PROTECTIVE MEASURES AGAINST THE MORE SOLUBLE COMPOUNDS AND MAYBDENUM TRIOXIDE DUST AND FUME. MINIMIZE SKIN CONTACT BY WEARING APPROPRIATE PROTECTIVE CLOTHING AND PRACTICE GOOD PERSONAL HYGIENE. AVOID BREATHING DUST OR FUME. INCOMPATIBILITIES: SOLUBLE COMPOUNDS-ALKALI METALS, SODIUM, POTASSIUM, MOLTON MAGNESIUM. INSOLUBLE COMPOUNDS - STRONG OXIDIZERS. l i j I l L_________________________--_-____
I l l i PAGE 1 OF 3 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00540 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET MATERIAL CODES NO MATCODE ATTACHED TO THIS PRODUCT VENDOR INFORMATION VENDOR: SHERWIN WILLIAMS CHEMICALS STREET ADDRESS: 501 MURRAY ROAD CITY: CINCINNATI STATE: OH ZIP CODE: 45217 BUSINESS PHONE NUMBER: SHERWIN WILLIAMS CHEMICALS EMERGENCY PHONE NUMBER: 800-424-9300 SAFETY DATA SHEET REVIEW: 910225 SUBSTANCE IDENTIFICA7 ION SUBSTANCE: SODIUM TOLYTRIAZOLE TRADE NAMES / SYNONYMS: Granular form I COBRATEC,TT-50S CHEMICAL FAMILY: TRIAZOLE MOLECULAR FORMULA: C7H6N3NA RESPONSE NUMBER: NFPA RATINGS (0-MINIMAL, 1-SLIGHT, 2-MODERATE, 3-SERIOUS, 4-SEVERE) 1 HEALTH: 1 FLAMMABILITY: O CHEMICAL REACTIVITY: 1 SPECIAL HAZARD: OXY WCGS CHEMICAL CATAGORY (I THRU VI PER ADM 01-118): III HAZARDOUS WASTE COMPONENTS AND CONTAMINANTS PERMISSABLE COMPONENT NAME PERCENT CAS NUMBER EXPOSURE Sodium Hydroxide 001310-73-2 C2mg/m3 TOLYLTRIAZOLE 00000000000 PHYSICAL DATA DESCRIPTION: CLEAR, RED-BROWN, ESSENTIALLY ODORLESS SOLUTION BOILING PNT: ~212 F MELTING PNT: N/A SP. GRAVITY: 1.19 @ 25 C VAT 3R PRESSURE: N/A PH: 13.5 SQL. IN WATER: 100% ODOR THRHD: N/A VAPOR DENSITY: N/A HEALTH EFFECTS AND FIRST AID CAUSTIC - MAY CAUSE BURNS TO SKIN AND EYES EMERGENCY PROCEDURE - FLUSH THOROUGHLY WITH WATER IN CASE OF ACCIDENTAL EXCESSIVE EXPOSURE. CONTACT SITE MEDICAL DEPARTMENT IF EYES ARE INVOLVED. FLUSH EYES WITH RUNNING WATER FOR 10 MINUTES. FIRE AND EXPLOSION DATA ) FIRE AND EXPLOSION HAZARD: NONE
PAGE 2 OF 3 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00540 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET FLASH POINT: NONE FIREFIGHTING MEDIA: N/A .FIREFIGHTING INSTRUCTIONS: N/A-TOXICITY I THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON l CERTAIN PEOPLE. ORAL LD50 (RATS): 675 MG/KG PRIMARY SKIN IRRITATION (RABBITS) : NOT A PRIMARY SKIN IRRITANT DERMAL LD50 (RABBITS): 2 GRAMS / KILOGRAM EYE IRRITATION (RABBITS): CAUSED EYE IRRITATION INHALATION 1 HOUR LC50: 1.73 MG/L.
- ACTUAL CONCENTRATION MEASURED IN BREATHING ZONE.
REACTIVITY l . REACTIVITY: { STABLE INCOMPATIBILITIES: MIXTURE WITH ACIDS WILL PRODUCE HIGH HEATS OF REACTION l DECOMPOSITION: I MAY INCLUDE CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES AND -HYDROGEN CYANIDE POLYMERIZATION: i WILL NOT OCCUR CONDITIONS TO AVOID: N/A SPILL AND LEAK PROCEDURES FOR SIGNIFICANT CHEMICAL SPILLS, REFER TO ADM 01-230 " CHEMICAL RELEASE AND RESPONSE". FOR ADDITIONAL RESPONSE INFORMATION REFER TO THE MSDS OVERVIEW. IN CASE OF SPILL: USE SUITABLE ABSORBENT MATERIAL AND FLUSH SPILL OR LEAK WITH. WATER. WASTE DISPOSAL METHOD: SANITARY LANDFILL OR INCINERATION IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. l CONTACT ENVIRONMENTAL GROUP TO ARRANGE FOR DISPOSAL. l I
PAGE 3 OF 3 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00540 l CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION: ADEQUATE VENTILATION OR OTHER ENGINEERING CONTROLS SHOULD BE USED TO REDUCE EMPLOYEE EXPOSURE BELOW OSHA PERMISSIBLE LIMITS. IF CONTROLS ARE NOT ADEQUATE OR AVAILABLE, USE A RESPIRATOR APPROVED BY NIOSH/ MESA UNDER SCHEDULE TC-23C FOR PROTECTION AGAINST NOT MORE THAN 1000 PPM ORGANIC VAPORS, DUSTS, FUMES AND MISTS WITH A PERMISSIBLE EXPOSURE LIMIT OF NOT LESS THAN 0.05 MG/M3 OR 2 MMPCF BASED ON AN EIGHT HOUR TIME-WEIGHTED AVERAGE. PROTECTIVE GLOVES: USE APPROVED HAND PROTECTION. EYE PROTECITON: USE APPROVED EYE PROTECTION. OTHER PROTECTIVE EQUIPMENT: NORMAL WORK CLOTHES SHOULD BE CHANGED IMMEDIATELY AFTER SPILL., LOCAL EXHAUST IS RECOMMENDED. HANDLING STORAGE AND TRANSPORTATION INFORMATION DEPARTMENT STORED IN: WAREHOUSE RECEIVING, WAREHOUSE, WATER TREATMENT PLANT. TYPE OF CONTAINERS: Not Determined QUANTITIES: Not Determined STORAGE PRECAUTIONS: CORROSIVE SOLUTION. STORE ONLY IN CONTAINERS. RESISTANT TO CAUSTIC SOLUTIONS. AVOID CONTACT WITH SKIN AND-EYES. i ENVIRONMENTAL CONCERNS l CONTACT ENVIRONMENTAL GROUP TO ARRANGE FOR DISPOSAL. l COMMENTS I N/A 1 t I C_______.__._______
PAGE 1 OF 6 OCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00672 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET MATERIAL CODES MATCODE PRIME LOC 10010071 B6060701A l VENDOR INFORMATION VENDOR: NALCO CHEMICAL COMPANY STREET ADDRESS: ONE NALCO CENTER CITY: NAPERVILLE STATE: IL ZIP CODE: 60563-1198 BUSINESS PHONE NUMBER: 708-305-1000 800-462-5378 EMERGENCY PHONE NUMBER: 800-424-9300 SAFETY DATA SHEET REVIEW: 960425 SUBSTANCE IDENTIFICATION SUBSTANCE: NALCO 1355 SURE-COOL TRADE NAMES / SYNONYMS: MERCAPTOBENZOTHIAZOLE 10010071 10010014 [ AN AQUEOUS SOLUTION OF BORATES, SILICATES, NITRATES, NITRITES AND. Sure-Cool.1355 CLOSED SYSTEM Inhibitor NALCO 39-L CLOSED SYSTEM TREATMENT CHEMICAL FAMILY: N/A MOLECULAR FORMULA: N/A RESPONSE NUMBER: NFPA RATINGS (0-MINIMAL, 1-SJ 'iHT, 2-MODERATE, 3-SERIOUS, 4-SEVERE) HEALTH: 2 FLAMMABILITY: O CHEMICAL REACTIVITY: 0
- SPECIAL HAZARD: ALK WCGS CHEMICAL CATAGORY (I THRU VI PER ADM 01-118): IV NON-HAZARDOUS WASTE COMPONENTS AND CONTAMINANTS PERMISSABLE COMPONENT NAME PERCENT CAS NUMBER EXPOSURE Sodium Metasilicate 5
006834-92-0 5 mg/m3 Sodium Hydroxide 5 001310-73-2 C2mg/m3 Sodium Nitrite 1-5 007632-00-0 1 mg/m3 Sodium tetraborate 1-5 001330-43-4 1 mg/m3 l Sodium Nitrate 00000000000 l Water 007732-18-5 I . PHYSICAL DATA DESCRIPTION: I CLEAR TO HAZY DEEP RED LIQUID; NO ODOR l BOILING PNT: 212 DEG F @760 MM/HG MELTING PNT: -20 F SP. GRAVITY: 1.12-1.16 @ 77 F VAPOR PRESSURE: N/A PH: 11.1-11.8 SOL. IN WATER: COMPLETELY ODOR THRHD: N/A VAPOR DENSITY: N/A
PAGE 2 OF G 1 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00672 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA. SHEET HEALTH EFFECTS AND FIRST AID WARNING: Harmful or fatal if swallowed in large doses. Contains Sodium Nitrite, causes blood system disorders when swallowed. Do not take internally. May cause irritation to skin and eyes. Avoid contact with eyes, and prolonged or repeated contact with skin. Empty containers may contain residual product. DO NOT reuse container unless properly reconditioned.. _______________--------First Aid-*------------------------------------ EYES: Immediately flush with water for 15 minutes while holding eye-lids open. Call Health Services At Once SKIN: Flush with water for 15 minutes. INGESTION: Induce vomiting. Give water. Call Health Services INHILATION: Remove to fresh air. Treat symptoms. Call Health Sys. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. EYE: Moderate irritation SKIN: Mild short lasting irritation INGESTION: Can cause kidney damage. Can be harmful or fatal. FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: MAY EVOLVE NOX UNDER FIRE CONDITIONS. FLASH POINT: NONE FIREFIGHTING MEDIA: N/A FIREFIGHTING INSTRUCTIONS: N/A I TOXICITY THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. Sodium nitrite causes formation of methaemoglobinaemia leading to cyanosis and possible death if ingested. Repeated ingestion of small amounts causes blood pressure to drop, rapid pulse, headaches and visual disturbances. Causes CNS effects. Sodium nitrite. Pregnant women are particularly sensitive to methaemoglobinaemia. LD50=3,362 mg/kg Skin irritation index 0.5/8.0 Minimal irritation EYE irritation 16.7/110.0 Experimental animal studies have shown reproductive effects related to Sodium nitrite affecting offspring of treated parents. These effects are not transmissible. Bacterial assay mutation studies have been positive. Tumorigenic data is suspect. {
PAGE 3 OF 6 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00672 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET REACTIVITY REACTIVITY: N/A INCOMPATIBILITIES: N-NITROSAMINES, MANY ARE CANCER CAUSING AGENTS CAUSING AGENTS TO LABORATORY ANIMALS, MAY BE FORMED THEN CERTAIN AMINES ARE MIXED WITH i NITROUS ACID, ORGANIC OR INORGANIC NITRITES OR ATMOSPHERES WITH HIGH NITROUS OXIDE CONCENTRATIONS. AVOID CONTACT WITH STRONG ACIDS (EG.SUL-FURIC, PHOSPHORIC, NITRIC, HYDROCHLORIC, CHROMIC, SULFONIC) WHICH, GEN = ERATES HEAT, SPLATTERING OR BOILING & RELEASES TOXIC FUMES. DECOMPOSITION: f IN THE EVENT OF COMBUSTION CO,CO2,NOX MAY BE FORMED. DO NOT BREATHE SMOKE OR FUMES. WEAR SUITABLE PROTECTIVE EQUIPMENT. POLYMERIZATION: N/A CONDITIONS TO AVOID: N/A SPILL AND LEAK PROCEDURES FOR SIGNIFICANT CHEMICAL SPILLS, REFER TO ADM 01-230 " CHEMICAL RELEASE AND RESPONSE". FOR ADDITIONAL RESPONSE INFORMATION REFER TO THE MSDS OVERVIEW. IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (312-920-1510) SMALL LIQUID SPILLS: CONTAIN WITH ABSORBENT MATERIAL, SUCH AS SAW DUST, CLAY, SOIL OR ANY COMMERCIALLY AVAILABLE ABSORBENT. SHOVEL j RECLAIMED LIQUID AND ABSORBENT INTO RECOVERY OR SALVAGE DRUMS FOR DISPOSAL. REFER TO CERCLA INFO IN ENV. SECTION LARGE LIQUID SPILLS: DIKE TO PREVENT FURTHER MOVEMENT AND RECLAIM INTO RECOVERY OR SALVAGE DRUMS OR TANK TRUCK FOR DISPOSAL. REFER TO CERCLA. LARGE LIQUID SPILLS: DIKE TO PREVENT FURTHER MOVEMENT AND RECLAIM INTO RECOVERY OR SALVAGE DRUMS OR TANK TRUCK FOR DISPOSAL. REFER TO CERCLA. DISPOSAL: IF THIS PRODUCT BECOMES WASTE, IT DOES NOT MEET THE CRI-TERIA Ct A HAZARDOUS WASTE AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261, SINCE IT DOES NOT HAVE THE CHARACTERISTICS OF SUBPART C, (I.E. D0001 THROUGH D017) NOR IS IT LISTED UNDER SUBPART D. AS A NON-HAZARDOUS LIQUID WASTE, IT SHOULD BE SOLIDIFIED BEFORE DISPOSAL TO A SANITARY LANDFILL. CAN BE DEEP-WELL INJECTED IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. ,__________._____..m_
l PAGE 4 OF G CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00672 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION: RESPIRATORY PROTECTION IS NOT NORMALLY NEEDED SINCE THE' VOLATILITY AND TOXICITY ARE LOW. FOR LARGE SPILLS, ENTRY INTO LARGE TANKS, VESSELS OR ENCLOSED SMALL SPACES WITH INADEQUATE VENTILATION, A PRESSURE-DEMAND, SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED. VENTILATION: GENERAL VENTILATION IS RECOMMENDED. PROTECTIVE EQUIPMENT: USE IMPERMEABLE GLOVES AND CHEMICAL SPLASH GOGGLES (ANSI Z 87.1 REQUIREMENTS AND SELECTION OF GLOVES, GOGGLES, SHOES, ETC ) WHEN ATTACHING FEEDING EQUIPMENT OR DOING MAINTENANCE. IF CLOTHING IS CONTAMINATED, REMOVE CLOTHING AND THOROUGHLY WASH THE AFFECTED AREA. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES AND LEATHER ITEMS. HAVE EYEWASWH AND SAFETY SHOWER AVAILABLE HANDLING STORAGE AND TRANSPORTATION INFORMATION DEPARTMENT STORED D : N/A TYPE OF CONTAINERS: Not Determined QUANTITIES: N/A STORAGE PRECAUTIONS: DOT PROPER SHIPPING NAME/ HAZARD CODE HAZARDOUS SUSTANCE, LIQUID N.O.S. ORM-E NA 9188 CONTAIN: SODIUM NITRITE 2 i l l
PAGE 5 OF 6 CCS' WOLF CREEK NUCLEAR OPERATING CORPORATION 00672 CHEMICAL CONTROL SYSTEM l MATERIAL SAFETY DATA SHEET I i ENVIRONMENTAL CONCERNS THE FOLLOWING REGULATIONS APPLY TO THIS PRODUCT. l . FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: BASED ON OUR HAZARD EVALUATION, THE FOLLOWING INGREDIENTS IN THIS PRODUCT ARE HAZARDOUS AND THE REASONS ARE SHOWN BELOW. SODIUM NITRITE - CHRONIC HUMAM EFFECTS' SODIUM MERCAPTOBENZOTHIAZOLE - SENSITIZER l SODIUM TETRABORATE = TWA 1 MG/M3 ACGIH TLV -CERECLA, 40 CFR 117, 302: THIS PRODUCT CONTAINS SODIUM NITRITE, A REPORTABLE QUANTITY (RQ) SUBSTANCE AND IF 2,000 POUNDS OF PRODUCT ARE RELEASED, IT REQUIRES NOTIFICATION TO THE NATIONAL RESPONSE CENTER, WASHINGTON, C.C. (1-800-424-8002). TOXIC SUBSTANCES CONTROL ACT (TSCA): THE CHEMICAL INGREDIENTS IN THIS PRODUCT ARE ON THE TSCA 8 (b) INVENTORY LIST (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: IF THIS PRODUCT BECOMES A WASTE, IT DOES NOT MEET THE CRITERIA of a hazardous waste. Federal water Pollution Control'Act, Clean Water Act, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): this product contains the following ingredient (s) covered by the clean water act: Sodium Nitrite: -clean air act, 40 CFR 60, Section 111, 40 CFR 61, Section 112: This product does not contain ingredients covered by the clean air act. Regulated in those states using the TLV for Sodium Tetraborate as a criteria for listing, user's responsibility: i This product material safety data sheet provides Health and Safety i. information. The product is to be used in applications consistent with our product literature. Individuals handling this product shoud be informed of the recommended safety precautions and should have access to this information. For any other uses,. exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. 96 HOUR STATIC ACUTE LC50 TO BLUEGILL SUNFISH = GREATER TNAN 1000 MG/L j 96 hour no observed effect concentration is 100 mg/l based on no ) mortality or abnormal effects, t 96 hour static acute LC50 to Rainbow Trout =200 mg/l l . Toxicity Ratiang: Slightly toxic. This product contains sodium nitrite, Reportable quantity if 2000 lbs. of product is released, requires National Response Center Notification 800-424-8802 SARA secations 302, 311, 312,'and 313 l This. product does not contain ingredients listed in Appendix A and B l as an EHS. Immediate and Delayed' health hazards. l-i
PAGE 6 OF 6 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00672 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET Immediate and Delayed health hazards. COMMENTS N/A i I i i l l
l PAGE 1 OF 5 .CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00138 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET MATERIAL CODES MATCODE PRIME LOC 60010001 P100BK VENDOR INFORMATION l VENDOR: Harcros ChemicalsInc. STREET ADDRESS:.5200 Speaker Rd. CITY: Kansas City STATE: KS ZIP CODE: 66106 BUSINESS PHONE NUMBER: 913-321-3131 EMERGENCY PHONE NUMBER: 800-424-9300 SAFETY DATA SHEET REVIEW: 920619 SUBSTANCE IDENTIFICATION SUBSTANCE: AMMONIUM HYDROXIDE (28-30%) TRADE NAMES / SYNONYMS: HARTSHORN", NH40H, GE MATERIAL D4B2 AQUA AMMONIA, AMMONIUM HYDRATE, AMMONIA WATER (STRONG), " SPIRIT OF CHEMICAL FAMILY: Nitrogen Hydroxide MOLECULAR FORMULA: NH (4) OH/H (2) O RESPONSE NUMBER: NFPA RATINGS (0-MINIMAL, 1-SLIGHT, 2-MODERATE, 3-SERIOUS, 4-SEVERE) HEALTH: 2 FLAMMABILITY: O CHEMICAL REACTIVITY: 2 SPECIAL HAZARD: OXY WCGS CHEMICAL CATAGORY (I THRU VI PER ADM 01-118): IV i NON-HAZARDOUS WASTE l COMPONENTS AND CONTAMINANTS f-PERMISSABLE COMPONENT NAME PERCENT CAS NUMBER EXPOSURE AMMONIA 007664-41-7 25 ppm Water 007732-18-5 PHYSICAL DATA-i i L'ESCRIPTION: CLEAR, COLORLESS LIQUID WITH STRONG PUNGENT ODOR OF AMMONIA. I I ( BOILING PNT: 80F MELTING PNT: N/A l SP, GRAVITY: 0.397@60F VAPOR PRESSURE: 546@20C PH: 11.6 SOL. IN WATER: COMPLETE ODOR THRHD: N/A VAPOR DENSITY: <1
PAGE 2 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00138 CHEMICAL CONTROL SYSTEM j MATERIAL SAFETY DATA SHEET HEALTH EFFECTE AND FIRST AID l AMMONIUM HYDROXIDE IS IRRITATING AND CORROSIVE TO BODY TISSUES. EXCESSIVE INHALATION OF VAPORS IS IRRITATING TO THE MUCOUS MEMBRANES OF THE RESPIRATORY TRACT AND CAN RESULT IN HEADACHE, COUGHING, SEVERE I LUNG CONGESTION (EDEMA AND DIFFICULTY IN BREATHING). SKIN CONTACT WITH LIQUID CAN IRRITATE, REDDEN AND CAUSE BURNS. LIQUID CONTACT WITH j THE EYE CAN BE SEVERELY DAMAGING AND CAN RESULT IN LOSS OF VISION. INGESTION IS CORROSIVE TO THE DIGESTIVE TRACT, FIRST AID: EYE CONTACT - IMMEDIATELY FLUSH WITH LOTS OF RUNNING WATER FOR AT LEAST 15 MIN., INCLUDING UNDER THE EYELIDS; THEN CONTACT PHYSICIAN IMMEDIATELY, PREFERABLY AN OPHTHALMOLOGIST. SPEED AND THOROUGHNESS l IN RINSING EYES IS IMPORTANT TO AVOID PERMANENT INJURY. SKIN CONTACT - IMMEDIATELY FLUSH WITH LOTS OF WATER WHILE REMOVING j CONTAMINATED CLOTHING AND SHOES. GET SITE MEDICAL HELP PROMPTLY IF LARGE AREAS ARE AFFECTED OR IRRITATION PERSISTS. INHALATION - REMOVE TO FRESH AIR. RESTORE BREATHING IF REQUIRED AND/ OR HAVE TRAINED PERSON ADMINSTER OXYGEN IF BREATHING IS DIFFICULT. I KEEP WARM AND AT REST. CONTACT SITE MEDICAL DEPT. IMMEDIATELY. FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: UEL 25% LEL 16% (evolved ammonia) i FLASH POINT: N/A l FIREFIGHTING MEDIA: l l USE MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. USE COLD l WATER SPRAY TO CONTROL VAPORS AND COOL FIRE-EXPOSED CONTAINERS. t FIREFIGHTING INSTRUCTIONS: WHEN HEATED, MATERIAL WILL EMIT NH3 VAPORS WHICH NECESSITATES RESPIRATORY AND EYE PROTECTION FOR FIREFIGHTERS. USE PROTECTIVE l CLOTHING. a spray or fog of water is effective in removing the generated ammonia gas from the atmosphere. Keep containers cool with water stream and spray. i SEE COMMENT SECTION FOR UNUSUAL FIRE AND EXPLOSION HAZARDS: l 1 ( Y I l
PAGE 3 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00138 CHEMICAL CONTROL C'lSTEM MATERIAL SAFETY DATA SHEET i TOXICITY THIS PRODUCT, AS WITH ANY CHEMICAL, MM ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. PROVIDE GENERAL AND LOCAL EXHAUST
- VENTILATION AS REQUIRED TO MEET TLV.
FOR EMERGENCY AND NONROUTINE CONDITIONS ABOVE THE TLV A CHEMICAL CARTRIDGE RESPIRATOR WITH A FULL-FACEPIECE RESPIRATOR IS SUITABLE FOR EXPOSURES BELOW 300 PPM; ABOVE 300 PPM OR IF CONCENTRATION UNKNOWN USE APPROVED SELF-CONTAINED RESPIRATOR WITH FULL FACEPIECE. USE SPLASH-PROOF, CHEMICAL SAFETY GOGGLES, AND WHERE NEEDED, A FACESHIELD OR MASK TO PROTECT AGAINST SPLASHES AND FROM MISTS AND NH3. USE A RUBBER SUIT, BOOTS, GLOVES, APRON, OR OTHER PROTECTIVE CLOTHING AS l REQUIRED FOR WORKPLACE CONDITIONS TO PREVENT CONTACT WITH AMMONIUM HYDROXIDE SOLUTIONS. AN EYEWASH STATION AND A SAFETY EHOWER MUST BE IMMEDIATELY ACCESSIBLE TO WORKERS WHERE THIS MATERIAL IS USED OR HANDLED. WASHING FACILITIES AND LARGE AMOUNTS OF CLEAN WATER MUST BE AVAILABLE FOR EMERGENCY USE WHERE SPILLS MAY OCCUR. i REACTIVITY 1 REACTIVITY: MATERIAL IS STABLE IN COOL STORAGE IN CLOSED CONTAINERS. t INCOMPATIBILITIES: AMMONIUM HYDROXIDE IS STRONGLY ALKALINE AND IS INCOMPATIBLE WITH ACID MATERIALS AND WITH COPPER, TIN, ZINC, ALUMINUM AND THEIR ALLOYS AND l WITH GALVANIZED SURFACES. VIOLENT REACTIONS CAN OCCUR, FOR EXAMPLE, WITH DIMETHYL SULFATE, OR FLUORINE. EXPLOSIVE MATERIALS CAN RESULT FROM REACTION WITH IODINE OR WITH SEVERAL SILVER COMPOUNDS. ADDING NAOH TO THIS MATERIAL AND/OR HEATING WILL VIOLATIZE NH3. DECOMPOSITION: N/A POLYMER *'ATION: WILL OT OCCUR. CONDITIONS TO AVOID: SEE INCOMPATIBILITIES SECTION I' i
l l l l l PAGE 4 OF 5 i CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00138 CHEMICAL CONTROL SYSTEM l MATERIAL SAFETY DATA SHEET SPILL AND LEAK PROCEDURES l FOR SIGNIFICANT CHEMICAL SPILLS, REFER TO ADM 01-230 " CHEMICAL i RELEASE AND RESPONSE". FOR ADDITIONAL RESPONSE INFORMATION REFER TO THE MSDS OVERVIEW. PREPARE WRITTEN PLANS FOR EMERGENCY. INFORM SAFETY PERSONNEL OF LARGE SPILLS AND EVACUATE AREA. PROVIDE VENTILATION. THOSE INVOLVED IN l CLEAN UP NEED PROTECTION AGAINST CONTACT WITH LIQUID AND INHALATION OF MIST OR VAPORS. CONTAIN SPILL FOR RECOVERY WHEN FEASIBLE OR FLUSH WITH WATER TO HOLDING AREA FOR NEUTRALIZATION (DO NOT FLUSH DIRECTLY TO SEWER OR SURFACE WATER). DISPOSAL: FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS FOR PH, NH3 CONTENT, AND SALTS CONTENT FOR EFFLUENTS. AMMONIUM HYDROXIDE CAN BE DILUTED WITH WATER, NEUTRALIZED AS REQURED WITH DILUTE hcl OR DILUTE ) H2SO4, AND THEN HIGHTLY DILUTED WITH WATER FOR DISCHARGE. SUITABLE SCRAP AMMONIUM HYDROXIDE MIGHT BE CONSIDERED FOR USE IN NEUTRALIZING ACIDIC WASTES. IF DESIRED, AQUEOUS NH3 CAN BE RECOVERED FROM SCRAP FOR USE OR SALE. CONTACT ENVIRONMENTAL GROUP TO ARRANGE FOR DISPOSAL. 1 CONTACT CHEMISTRY DEPARTMENT FOR NEUTRALIZER This material la a RCAA corrosive waste having a hazardous waste ID no DOO2 PROTECTIVE EQUIPMENT PROVIDE GENERAL AND LOCAL EXHAUST VENTILATION AS REQUIRED TO MEET TLV. FOR EMERGENCY AND NONROUTINE CONDITIONS ABOVE THE TLV A CHEMICAL CARTRIDGE RESPIRATOR WITH A FULL FACEPIECE RESPIRATOR IS SUITABLE FOR EXPOSURES BELOW 300 PPM; ABOVE 300 PPM OR IF CONCENTRATION UNKNOWN USE APPROVED SELF-CONTAINED RESPIRATOR WITH FULL FACEPIECE. USE SPLASH-PROOF, CHEMICAL SAFETY GOGGLES, AND WHERE NEEDED, A FACESHIELD OR MASK TO PROTECT AGAINST SPLASHES AND FROM MISTS AND NH3. USE A RUBBER SUIT, BOOTS, GLOVES, APRON AND OTHER PROTECTIVE CLOTHING AS REQURIED FOR WORKPLACE CONDITIONS TO PREVENT CONTACT WITH AMMONIUM 1 HYDROXIDE SOLUTIONS. AN EYEWASH STATION AND A SAFETY SHOWER MUST BE IMMEDIATELY ACCESSIBLE TO WORKERS WHERE THIS MATERIAL IS USED OR HANDLED. WASHING FACILITIES AND LARGE AMOUNTS OF CLEAN WATER MUST BE AVAILABLE FOR EMERGENCY USE UHERE SPILLS MAY OCCUR. HANDLING STORAGE AND TRANSPORTATION INFORMATION DEPARTMENT STORED IN: WAREHOUSE RECEIVING, WAREHOUSE, AND 2000 ELEVATION OF THE TURBINE BUILDING. SEE COMMENTS. TYPE OF CONTAINERS: Not Determined QUANTITIES: Not Determined t
PAGE 5 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00138 CHEMICAL CONTROL SYSTEM l MATERIAL SAFETY DATA SHEET STORAGE PRECAUTIONS: STORE IN COOL (BELOW 80.F TO AVOID PRESSURIZATION ABOVE 1 ATM) AREA IN CLOSED CONTAINERS, AWAY FROM SOURCES OF HEAT, DIRECT SUNLIGHT AND INCOMPATIBLE MATERIALS. HANDLE AS A CORROSIVE LIQUID. PREVENT DAMAGE TO CONTAINERS. ABOVE 50 F, THE AMMONIA' VAPOR FROM THIS MATERIAL CAN BE A SERIOUS HAZARD IN A SPILL SITUATION. USE CAUTION IN OPENING SEALED CONTAINERS FOR PROPER PRESSURE RELIEF. DRAIN EMPTIED CONTAINERS ENVIRONMENTAL CONCERNS DISPOSAL: FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS FOR PH, NH3 CONTENT, AND SALTS CONTENT FOR EFFLUENTS. AMMONIUM HYDROXIDE CAN BE DILUTED WITH WATER, NEUTRALIZED AS REQUIRED WITH DILUTE hcl OR DILUTE H2SO4, AND THEN HIGHLY DILUTED WITH WATER FOR DISCHARGE. SUITABLE SCRAP AMMONIUM HYDROXIDE MIGHT BE CONSIDERED FOR USE IN [ NEUTRALIZING ACIDIC WASTES. IF DESIRED, AQUEOUS NH3 CAN BE RECOVERED f FROM SCRAP-FOR USE OR SALE. REFER TO LEAK AND SPILL SECTION CONTACT ENVIRONMENTAL GROUP TO ARRANGE FOR DISPOSAL l COMMENTS WORK PRACTIC6J AND EQUIPMENT MUST BE ARRANGED TO PREVENT CONTACT OF AMMONIUM HYDROXIDE WITH THE PORKER'S BODY AND TO AVOID INHALATION OF VAPORS. TRAIN WORKERS IN PROPER HANDLING OF AMMONIUM HYDROXIDE. REPLACEMENT AND PERIODIC MEDICAL EXAM IS RECOMMENDED FOR AMMONIA WORKERS AND ADDITIONAL EXAMS SHOULD BE PROVIDED IF EXCESSIVE EXPOSURE OCCUR. KEEP RECORDS. PRECLUDE FROM EXPOSURE WORKERS WITH EYE OR 1 PULMONARY DISEASES. l UNUSUAL: Rapid addition to concentrated universal acids could create explosive l conditions of 16-25% ammonia by volume. Such concentrations could occur if aqua ammonia is heated in a confined area which is not adequately ventilated. ' NH(3) increases the fire hazard from other combustible materials. including oil. Flammable limits are broadened by increasing temperature. I I ~_ ___.-________m___._-s__-.___ _ _ _ - _ = _. _ _... _ ____.=-.______.______.__._.__m__
PAGE 1 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00085 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET MATERIAL CODES MATCODE PRIME LOC 10010007 P200BK VENDOR INFORMATION VENDOn: Fairmount Chemical Company, Inc. STREET ADDRESS: 117 Blanchard Street CITY: Newark STATE: NJ ZIP CODE: 07105 BUSINESS PHONE NUMBER: 201-344-5790 EMERGENCY PHONE NUMBER: 800-424-9300 SAFETY DATA SHEET REVIEW: 971103 SUBSTANCE IDENTIFICATION SUBSTANCE: DEOXY-SOL TRADE NAMES / SYNONYMS: HYDRAZINE HYDRAZINE AQUEOUS SOLUTION 55% HYDRAZINE HYDRATE 55% CHEMICAL FAMILY: AMINES MOLECULAR FORMULA: N2H4.H2O RESPONSE NUMBER: 59 NFPA RATINGS (0-MINIMAL, 1-SLIGHT, 2-MODERATE, 3-SERIOUS, 4-SEVERE) HEALTH: 3 FLAMMABILITY: 1 CHEMICAL REACTIVITY: 2 SPECIAL HAZARD: COR WCGS CHEMICAL CATAGORY (I THRU VI PER ADM 01-118): I HASARDOUS WASTE COMPONENTS AND CONTAMINANTS l PERMISSABLE COMPONENT NAME PERCENT CAS NUMBER EXPOSURE HYDRAZINE 30-40 000302-01-2 0.03 ppm NIOS9 WATER 60-70 007732-18-5 l PHYSICAL DATA l DESCRIPTION: CLEAR, COLORLESS LIQUID WITH AN AMMONIA-LIKE ODOR. BOILING PNT: 230 DEG. F. MELTING PNT: NOT APPLICABLE SP. GRAVITY: 1.043 @ 15 DEG. C. VAPOR PRESSURE: NOT DETERMINED PH: 9.3 - 10.3 SOL. IN WATER: COMPLETE ODOR THRHD: 3.0 ppm VAPOR DENSITY: NOT DETERMINED
i l PAGE 2 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00085 j CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET HEALTH EFFECTS AND FIRST AID First Aid:
- EYE FLUSH FOR AT LEAST 30 MIN., INCLUDING UNDER EYELIDS.
REMOVE CONTAMINATED CLOTHING UNDER SAFETY SHOWER. CONTACT PHYSICIAN! CONTINUE FLUSHING WITH WATER. SKIN BURNS TO BE l TREATED LIKE ALKALI OR THERMAL BURNS. INHALATION: REMOVE TO. FRESH AIR. RESTORE AND/OR SUPPORT BREATHING. CONTACT PHYSICIAN! KEEP WARM AND AT REST. PULMONARY EDEMA MAY OCCUR If a person experiences nausea, headache or dizziness, person should stop work 1 immediately and move to fresh air until these symptoms stop. l Contact Health Services. INGESTION: Immediately drink large quantities of water. Induce vomiting. DO NOT give anything by mouth if the person is unconscious or having convulsions. SKIN: Immediately flush with water for at least 30 minutes. Call Health Services. If clothing comes in contact with the product, it should be removed immediately and should be laundered before re-use ****** SIGNS, SYMPTOMS, AND EFFECTS ******** ACUTE: (INHALATION) Hydrazine is highly irritating to the nose, throat, upper respiratory tract and lungs. Inflammation of the respiratory tract may lead to bronchitis. Vapor can also cause eye irritation. Pulmonary edema and lung damage may occur. Damage may also result l to liver, kidneys and blood. High exposure may give rise to hemolysis of the blood cells. Vomiting, diarrhea, nausea, dizziness, cyanosis and convulsions may also occur. A single exposure would not likely produce fetal toxicity and malformations, but several exposures may6 cause these effects to the fetus.
- CHRONIC: The repeated inhalation of hydrazine may produce inflammation of the nasal, tracheal and bronchial tissur.
Chronic l bronchitis can result. Damage to the liver, kidneys, and blood may i also occur. Damage to blood may be characterized by hemolysis and reduction of packed cell volume. Fetal toxicity and malformations can also result. l FIRE #;- EXPLOSION DATA FIRE AND EXPLOSION HAZARD: AQUEOUS HYDRAZINE SOLUTIONS WILL NOT IGNITE READILY. FLASH POINT: MORE THAN 212 DEG. F FIREFIGHTING MEDIA: WATER, CARBON DIOXIDE AND DRY CHEMICAL. FIREFIGHTING INSTRUCTIONS: USE WATER SPRAY TO PUT OUT FIRE AND DILUTE SPILLS TO NONFLAMMABLE MIXTURES, TO DISPERSE VAPORS, AND TO COOL FIRE-EXPOSED CONTAINERS. FIGHT FIRES FROM SAFE DISTANCE AND PROTECTED LOCATION. HYDRAZINE VAPOR IS FLAMMABLE AND CAN BE AN EXPLOSION HAZARD WITH OXIDIZERS OR HEATING. POISONOUS GASES WILL BE PRODUCED IN A FIRE. FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE GEAR AND SCBAs.
l PAGE 3 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00085 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET TOXICITY THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. IARC-ANIMAL POSITIVE CARCINOGEN. It has been shewn to cause lung cancers, liver cancers and leukemia in i laboratory animals. Positive mutagenicity eye irritant; Skin l irritant - Damage to lungs, liver, kidneys, blood and CNS. l Hydrazine has been shown to produce embryolethanlity and fetal l malformations in lab animals. - Hydrazine contact with the skin, eyes, and respiratory tract can cause irritation and/or burns. Exposure to large single doses, or smaller repeated doses of Hydrazine may cause death, temporary blindness, dizziness, nausea, and damage to internal organs. Repeated exposure may cause bronchitis to develop with a cough, phlegm and/or shortness of breath. Exposure can damage the nervous system and cause problems with balance, strength and coordination. Hydrazine exposure may also cause low blood counts. REACTIVITY REACTIVITY: Stable but will react with oxygen in air. Do not store in sunlight or near heat source. INCOMPATIBILITIES: Avoid contact with strong oxidizers such as hydrogen peroxide, fluorides, fuming nitric acid and chlcrine. Avoid metals such as iron I copper, lead, manganese, molybdeum. Avoid contact with organic materials Absorption of hydrazine solution by rags, cotton waste, sawdust, or similar organic materials will result in spontaneous combustion. DECOMPOSITION: Ammonia, hydrogen, nitrogen and water; nitrous oxides are released in a fire; Decomposition temperature: -482 degrees F. POLYMERIZATION: WILL NOT OCCUR. CONDITIONS TO AVOID: KEEP OUT OF DIRECT SUNLIGHT. STORE AWAY FROM STRONG OXIDIZERS IN TIGHTLY CLOSED CONTAINERS IN A COOL, WELL-VENTILATED AREA.
l l PAGE 4 OF 5 l CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00085 CHEMICAL CONTROL SYSTEM MATERIAL SAFETT DATA SHEET i l SPILL AND LEAK PROCEDURES FOR SIGNIFICANT CHEMICAL SPILLS, REFER TO AP 31B-002 " CHEMICAL RELEASE AND RESPONSE". FOR ADDITIONAL RESPONSE INFORMATION REFER TO THE MSDS OVERVIEW. INSTITUTE PLAN PREPARED WITH SUPPLIER'S fu GUIDANCE. NOTIFY SAFETY PERSONNEL OF SPILLS. EVACUATE ALL EXCEPT TRAINED CLEAN-UP PERSONNEL WHO ARE PROTECTED AGAINST INHALATION & CONTACT. USE OPTIMUM EXPLOSION-PROOF VENTILATION. REMOVE SOURCES OF HEAT OR IGNITION. Wear goggles, butyl rubber gloves, boots and slicker suit. For spills indoors or involving hot material wear positive pressure supplied air respirator or SCBA. Follow OSHA regulations for respirator use. Isolat e area of spill by diking. Stop source of leak. Neutralize spill by fi rst dilutirg hydrazine to a 5% or less concentration. Then add an equa 1 amour *, of a 5% or l less concentration of a hyporchlorite solution to totally l neutralize the hydrazine. Test for neutralization. After neutr l alization transfer this material to an appropriate container for prope r disposal. Wash all contaminated clothing before reuse. In the event of a large spill, call the emergency telephone number shown on the front of this sheet. PROTECTIVE EQUIPMENT Respiratory protection necessary if there is potential for exposure. Use local exhaust ventilation to maintain levels below the TLV Wear butyl gloves and boots, face shield with safety glasses A full impermeable suit is recommended if exposure is possible to large portion of body. Eye wash and safety shower must be available at or near work area. (Butyl Rubber) HANDLING STORAGE AND TRANSPORTATION INFORMATION DEPARTMENT STORED IN: WAREHOUSE, AND RECEIVING AREA, TURBINE BLDG. 2000 LEVEL, NE AREA, AQ SYSTEMS, FE SYSTEM, CHEMICAL WATER MAKEUP FOR PLANT SYSTEMS. TYPE OF CONTAINERS: Not Determined j QUANTITIES: Not Determined l STORAGE PRECAUTIONS: Store away from heat, sparks, open flame, and oxidants. Store only in well-ventilated areas. Do not contaminate. Transfer lines and l piping should be electrically grounded. DO NOT STORE IN TEMPERATURES OVER 80F. ] Do not expose to direct light. i
1 i l l PAGE 5 OF 5 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 00085 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET ENVIRONMENTAL CONCERNS If this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: U133. ? If this nroduct becomes a waste, it will be a hazardous waste I which is subject to the Land Disposal Restrictions under 40 CFR 268 [ and must be managed accordingly. Spills in excess of 3 pounds, 1 /2 gallon, requires EPA notification if product goes down drains or exposes the l environment. COMMENTS STORE IN TIGHTLY CLOSED CONTAINERS IN A CLEAN, COOL, WELL-VENTILATED l I AREA WITH CONTROLLED DRAINAGE, AWAY FROM OXIDIZING AGENTS. ACIDS, DIRECT SUNLIGHT & SOURCES OF HEAT OR IGNITION. WATER SPRINKLER-PROTECTED, SHLETERED, OUTSIDE OR DETACHED STORAGE PREFERRED. PROTECT CONTAINERS FROM PHYSICAL DAMAGE; GROUND & BOND FOR TRANSFERS TO PREVENT STATIC SPARKS; INERT WITH NITROGEN ATMOSPHERE. PREVENT CONTAMINATION OF HYDRAZINE. CONCRETE PADS, DIKES, DRAINS AND CONTAINMENT HAVE BEEN RECOMMENDED FOR LARGE TANKS AND DRUMS. AVOID BREATHING & CONTACT WITH VAPORS! PREVENT LIQUID CONTACT WITH EYES, SKIN, AND CLOTHING! DO NOT INGEST! PRACTICE GOOD PERSONdEL HYGIENE. WASH WELL AFTER HANDLING. OBSERVE LABEL PRECAUTIONS. RIGIDLY FOLLOW PROPER HANDLING REQUIREMENTS. OBTAIN GUIDANCE FROM SUPPLIER. USE PROPER VENTILATION. FOLLOW CODE FOR ELECTRICAL i SERVICES. DEPARTMENTS USING: FE SYSTEM, AQ SYSTEMS 2000 LEVEL TURBINE-NORTH AND i SOUTH END, AND FE SYSTEM 2015 LEVEL TURBINE BLD., USED TO CONTROL AUX, BOILER WATER AND PLANT SYSTEMS. DO NOT STORE IN TEMPERATURES OVER 80 F. i i i
PAGE 1 OF 3 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 01757 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET MATERIAL CODES NO MATCODE ATTACHED TO THIS PRODUCT VENDOR INFORMATION VENDOR: Betz Dearborn STREET ADDRESS: 1 Quality Way CITY: Trevose STATE: Pa ZIP CODE: 19053 BUSINESS PHONE NUMBER: 800-877-1940 EMERGENCY PHONE NUMBER: 800-424-9300 SAFETY DATA SHEET REVIEW: 980617 SUBSTANCE IDENTIFICATION SUBSTANCE: Spectrus OX1201 TRADE NAMES / SYNONYMS: LiquiBrom 4000 Sodium Bromide solution Slimicide C-94 CHEMICAL FAMILY: N/A MOLECULAR FORMULA: N/A RESPONSE NUMBER: NFPA RATINGS 0-MINIMAL, 1-SLIGHT, 2-MODERATE, 3-SERIOUS, 4-SEVERE) HEALTH: 1 FLAMMABILITY: O CHEMICAL REACTIVITY: O SPECIAL HAZARD: N/A WCGS CHEMICAL CATAGORY (I THRU VI PER ADM 01-118): IV NON-HAZARDOUS WASTE COMPONENTS AND CONTAMINANTS j PERMISSABLE COMPONENT NAME PERCENT CAS NUMBER EXPOSURE Sodium Bromide 40 007647-15-6 PHYSICAI.: DATA DESCRIPTION: Colorless Liquid BOILING PNT: N/A MELTING PNT: -30 SP. GRAVITY: 1.403 VAPOR PRESSURE: 18 PH: 7.5 SOL. IN WATER: 100% ODOR THRHD: N/A VAPOR DENSITY: <1 i L_____.____.
I l PAGE 2 OF 3 ) CCS WOLF CREEK NUCLEAR OFERATING CORPORATION 01757 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET i l HEALTH EFFECTS AND FIRST AID Moderately irritating to the eyes Mists / aerosols may cause irritation to upper respiratory tract. i
First Aid------------------------------------
l Skin-Remove contaminated clothing. Wash exposed area with a large I quantity of soap solution or water for 15 min. I Eye-Immediately flush eyes with water for 15 min. Immediately contact Health Services for additional treatment. j Inhilation-Remove victim from contaminated area to fresh air. Apply appropriate first aid. Ingestion-Induce vomiting. Contact Health Services. FIRE AND EXPLOSION DATA FIRE AND EXPLOSION RAZARD: N/A FLASH POINT: >20G F FIREFIGHTING MEDIA: Dry chemical, carbon dioxide, foam or water l FIREFIGHTING INSTRUCTIONS Firefighters should wear positive pressure SCBA TOXICITY THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. REACTIVITY REACTIVITY: Stable INCOMPATIBILITIES: N/A DECOMPOSITION: Thermal decomposition yielda elements: oxides POLYMERIZATION: N/A CONDITIONS TO AVOID: N/A l C__ _ _ _ _ _ _. _ _ _ _ _ _ _ _ _. _ _
PAGE 3 OF 3 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 01757 CHEMICAL CONTROL SYSTEM ERIAL SAFETY DATA SHEET SPILL AND LEAK PROCEDURES FOR SIGNIFICANT CHEMICAL SPILLS, REFER TO ADM 01-230 " CHEMICAL RELEASE AND RESPONSE". FOR ADDITIONAL RESPONSE INFORMATION REFER TO THE MSDS OVERVIEW. Ventilate area, use specified protective equipment. Contain and absorb on absorbent material. D! ace in waste disposal container. The contaminated absorbent should be considered a pesticide and disposed of in an approved pem 1 cide landfill. Plush area with water. Wet area may be slippery. If so, spread sand / grit. Disposal: Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement, a permin-ant waste treatment facility or discharged under a NPDES permit. PROTECTIVE EQUIPMENT If exposure is above 5mg/m3, supplied air is recommended Use adequate ventilation i Dust and mist respirator suggested f Chemical goggles required l HANDLING STORAGE AND TRANSPORTATION INFORMATION DEPARTMENT STORED IN: N/A l TYPE OF CONTAINERS: N/A l QUANTITIES: N/A STORAGE PRECAUTIONS: Keep drums and pails closed when not in use. Immediately remove contaminated clothing, wash before reuse. ENVIRONMENTAL CONCERNS t j N/A i I COMMENTS N/A
PAGE 1 OF 4 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 02654 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET MATERIAL CODES NO MATCODE ATTACHED TO THIS PRODUCT VENDOR INFORMATION VENDOR: Van Waters & Rogers Inc. STREET ADDRESS: 6100 Carillon Point CITY: Kirkland STATE: WA ZIP CODE: 98033 BUSINESS PHONE NUMBER: 206-889-3400 EMERGENCY PHONE NUMBER: 800-424-9300 SAFETY DATA SHEET REVIEW: 970417 SUBSTANCE IDENTIFICATION SUBSTANCE: Sodium Hypochlorite TRADE NAMES / SYNONYMS: Sodium Hypochlorite 7-15%, liquid chlorine, liquid bleach, Pure Chlor, Sunn Sol 150, Liquichlor CHEMICAL FAMILY: Hypochlorite MOLECULAR FORMULA: N/A RESPONSE NUMBER: i NFPA RATINGS (0-MINIMAL, 1-SLIGHT, 2-MODERATE, 3-SERIOUS, 4-SEVERE) HEALTH: 3 FLAMMABILITY: O CHEMICAL REACTIVITY: 2 SPECIAL HAZARD: Oxy WCGS CHEMICAL CATAGORY (I THRU VI PER ADM 01-118): V NON-HAZARDOUS WASTE COMPONENTS AND CONTAMINANTS PERMISSABLE COMPONENT NAME PERCENT CAS NUMBER EXPOSURE l Sodium hypochlorite 7-15% 007681-52-9 Water 007732-18-5 Sodium hydroxide 0.5-2.5 001310-73-2 Sodium chloride 5.0-11. 007647-14-5 PHYSICAL DATA DESCRIPTION: i Greenish-yellow liquid BOILING PNT: Decomposes on htg. MELTING PNT: N/A SP. GRAVITY: 1.08-1.26 VAPOR PRES 3URE: @25 Deg. C:no data PH: @ 25 Deg. C:>11 SOL. IN WATER: Miscible ODOR THRHD: N/A VAPOR DENSITY: No data l 1
PAGE 2 OF 4 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 02654 CHEMICAL CONTROL SYSTEM I MATERIAL SAFETY DATA SHEET HEALTH EFFECTS AND FIRST AID Harmful if inhaled and ingested. Harmful if exposed to skin or eyes. Sodium hypochlorite has the potential to be immediately dangerous to life or health. Inhalation of this material is irritating to the nose, mouth, throat and lungs. It may also cause j burns to the respiratory tract with the production of lung edema I which can result in shortness of breath, wheezing, choking, chest pain, and impairment of lung function and permanent lung damage. Chronic: repeated inhalation exposure may cause impairment of lung ) function and permanent lung damage. Eye: severe irritation and/or j burns can occur following eye exposure. Contact may cause impairment of vision and corneal damage. Skin: dermal exposure can cause severe irritation and/or burns characterized by redness, swelling and scab formation. Prolonged skin exposure may cause destruction of the dermis with impairment of the skin at site of contact to regenerate. Chronic: effects from chronic skin exposure would be similar to those from single exposure except for effects secondary to tissue destruction. Ingestion: irritation and/or burns can occur to entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding, and/or tissue ulceration. First Aid: Eyes: immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Call a physician at once. Skin: immediately flush with water for at least 15 minutes. Call a physician. If clothing comes in contact with the product, the clothing should be removed immediately and l should be laundered before re-use. Ingestion: immediately drink i large quantities of water. Do not induce vomiting, call a physician at once. DO NOT give anything by mouth if the person is I unconscious or if having covulsions. Inhalation: if person experiences nausea, headache or dizziness, person should stop work i immediately and move to fresh air until these symptoms disappear. If breathing is difficult, administer oxygen, keep the person warm and at rest. Call a physician. In the event that an individual inhales enough vapor to lose consciousness, person should be moved to fresh air at once and a physician should be called immediately. If breathing has stopped, artificial respiration should be given immediately. In all cases, ensure adequate ventilation and provide respiratory protection before the person returns to work. FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: No FLASH POINT: Not applicable FIREFIGHTING MEDIA: Not applicable I i
PAGE 3 OF 4 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 02654 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET FIREFIGHTING INSTRUCTIONS: Use water to cool containers exposed to fire. On small fire, use dry chemical, Carbon Dioxide or water spray. On large fires, use water in flooding quantities as fog. In case of fire, hazardous concentrations of chlorine may be formed. TOXICITY THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. 1 REACTIVITY REACTIVITY: Oxidizer l INCOMPATIBILITIES: Iron, copper, acids, ammonium compounds, organics, or other oxidizers. l l DECOMPOSITION: 1 Chlorine gas POLYMERIZATION: Will not occur CONDITIONS TO AVOID: High heat, sunlight and ultra-violet light SPILL AND LEAK PROCEDURES FOR SIGNIFICANT CHEMICAL SPILLS, REFER TO ADM 01-230 " CHEMICAL RELEASE AND RESPONSE". FOR ADDITIONAL RESPONSE INFORMATION REFER TO THE MSDS OVERVIEW. I For all transportation accidents, call Chemtrec at 800-424-9300. Reportable quantity (pounds): 100 lbs. (Per CFR 302.4) Hazardous concentrations in air may be found in local spill area and immediately downwind. Air release: Vapors may be suppressed by the use of a water fog. Capture all run off water for treatment and disposal. Water release: This material is soluble in water. Dike or cont.ain material via use of compatible absorbents. Remove material with use of vacuum or pump operation and treat before disposition. This material is harmful to aquatic life. Land spill: compatible absorbents; sand, clay soil, commercial absorbents. Spill residues: dispose of per guidelines under Section XII, waste disposal.
PAGE 4 OF 4 CCS WOLF CREEK NUCLEAR OPERATING CORPORATION 02654 CHEMICAL CONTROL SYSTEM MATERIAL SAFETY DATA SHEET PROTECTIVE EQUIPMENT Response to this material requires the use of self-contained breathing apparatus (SCBA). Additional protective clothing must be worn to prevent personal contact with this material. These items include but are not limited to boots, gloves, hard hat, impervious
- clothing, i.e. chemically impermeable suit.
Compatible materials for response to this material are neoprene, butyl rubber, viton and saranex. HANDLING STORAGE AND TRANSPORTATION INFORMATION DEPARTMENT STORED IN: N/A TYPE OF CONTAINERS: N/A QUANTITIES: N/A STORAGE PRECAUTIONS: This material is regulated as a DOT hazardous material. Hazard / label placard: corrosive. Store in a cool, dry, well-ventilated area. Avoid high temperatures and exposure to direct sunlight. Do not store at temperatures above 15-21 Deg. C(60-70 Deg. F). Store in the dark at the lowest possible temperature, but keep from freezing. ENVIRONMENTAL CONCERNS If this product becomes a waste, it DOES NOT meet the criteria of a hazardous waste as defined uner 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D. As non-hazardous liquid waste, it should not be disposed of in accordance with local, state and federal regulations by treatment in a wastewater treatment system. Care must be taken to prevent environmental contamination from the use of this material. COMMENTS N/A l l l L l
l o to RP 98-0155 Letter RP 98-0016 to KDHE dated January 21,1998 RE: Request to increase the Discharge Concentration of Betz Copper-Trol at Outfal1006 and Permission for a One a Time Use of Triton X-100 -i I l 4 1 I l ) I i l l i I ( l. l ) C-_______._.s
W$LF CREEK NUCLEAR OPERATING CORPORATION January 21, 1998 RP 98-0016 Kansas Department of Health and Environment Industrial Programs Section Forbes Field Topeka KS 66620 Attention: Ms. Marian Massoth
Subject:
Request to Increase the Discharge Concentration of Betz Copper-Trol at Outfall 006 and Permission for a One Time Use of Triton X-100.
Dear Ms. Massoth:
The purpose of this letter is to request your review and approval to increase the discharge concentration of Betz Copper-Trol at outfall 006. Additionally, we are requesting permission to use on a one time only basis Triton X-100 at Wolf Creek Generating Station. In the following paragraphs, we will highlight our reasons for these requests. A Material Safety Data Sheet and aquatic toxicity data for these two chemicals are attached to this letter. Increased Discharge Concentration for Betz Copper-Trol WCNOC is requesting KDHE approval to increase both the use and discharge concentration of this chemical. This request is based on a letter we received from BetzDearbom Company. In the letter. Betz characterizes our service water heat exchangers corrosion rate as increaring during i the summer months. This letter is attached for your review. We are currently making a copper-trol addition once a month. We would like to increase the frequency of copper-trol addition based upon corrosion rate monitoring in the service water system. The addition of copper-trol to the service water would not exceed once per day treatment for a duration of 15 to 30 minutes. Also, our discharge concentration for the copper-trol is limited to 50 ppm at outfall 006 which is at the minimum recommended treatment range for this chemical treatment. To keep from exceeding this discharge limit, we keep the chemical feed rate down such that we only obtain a residual in the range of 40 to 45 ppm in the service and essential service water discharge at outfall 006. l P O. Box 411/ Burhn; ton. KS 66839 / Phone. (316) 364-8831 ( . som. o,,,,,,,, emo,o,,, we, cmer L --
I l We are requesting your approval to increase the discharge concentration of copper-trol from 50 l ppm to 60 ppm so we can reach the target residual range of 50 ppm in the service and essential service water systems without exceeding any discharge limits. The discharge concentration for copper-trol at outfall 003 would be maintained at 6.0 ppm. The goal for the above request is to reduce the corrosion rates we are detecting in the service and essential service water systems. One Time Use of Triton X-100 l WCNOC is requesting KDHE approval for a one time use of Triton X-100. This chemical will l be used to clean our condensate polisher resins that became fouled during our last refueling outage. This fouling is causing the resin to have poor rinse characteristics. As a result of this we do not get good resin separation during the regeneration process. The poor resin separation is causing increased levels of sulfates in our steam generators. Triton X-100, a detergent, will remove the contamination from the resin. The contamination removal by Triton X-100 has been demonstrated by a test lab to increase the rinse characteristics ten-fold. The calculated concentration of Triton X-100 at outfall 003 will be approximately 0.25 ppm. well below the aquatic toxicity no-effect level of 18 ppm for Daphnia magna. This calculation is based on the amount of Triton X-100 that will be used on the six individual resin beds, the waste product dilution in the wastewater treatment basin and the discharge rate from outfall 003b to outfall 003. If you have any questions about the above requests, please contact Ralph Logsdon at (316)-364-f 8831. extension 4730. Sincerely, Daniel Williamson DW/jaf Attachments 6 i l 9 i j
i 1 l I \\ BetzDearborn water uanagement ame January 13.1998 l Mr. Russ Parker Wolf Creek Nuclear Operating Corporation i P.O. Box 411 Burlington, KS 66839 l
Subject:
Service Water Cooling BetzDearborn Copper-Trol CU1 Application Mr. Russ Parker We are currently applying BetzDearborn Copper-Trol CU1 to the plant service water cooling once per month. The purpose of this application is to provide corrosion protection for the service water system heat exchangers. Copper-Trol
- CU1 is a unique copper corrosion treatment program exclusive to BetzDearborn.
I The Copper-Trol
- CU1 corrosion inhibition program was developed in 1984 at BetzDearborn (formerly Betz Laboratories). It grew out of a research effort started in l
1982 to investigate the behavior of tolytriazole and it's parent compound, benzotriazole 1 l i (BZT or BT). Our work showed that the TTA molecule acted to stabilize the copper (1) oxidation state. This finding prompted a new look at the bonding mode of TTA to the copper ions. A "new and improved" molecule was ultimately designed. 1 This unique molecule, the use of which is patented, is a modified BZT altered to bond more strongly to the copper substrate. This stronger bonding means that the film adheres to the surface better than TTA and is therefore more persistent. Typically Copper-Trol
- CU1 film lasts many times longer than that of TTA. A single dose of 1TA fed to a cooling system will provide protection for only 24 to 36 hours. By contrast, the same dose of Copper-Trol CU1 can last for several weeks. The film is far more stable to pH upsets and chlorination than TTA.
The Wolf Creek service water system has numerous copper / copper alloy exchangers with large combined surface area and water usage. For this reason Copper-Trol CU1 provides a significant cost and operating savings as compared to continuous TTA applications. i The minimum recommended treatment rate is 50 ppm as product. The minimum contact time is 15 minutes. The concentration of 50 ppm is critical to ensure effective film development. Shaping the Future of Water & Prxess Treatment
The current Wolf Creek service water feed rate is 1.4 to 1.5 gallons per minute for 15 minutes. This produces a maximum residual in the range of 40 to 45 ppm in the service water discharge. This is below the target residual minimum of 50 ppm. The target corrosion rate for copper and copper alloys is < 0.2 mpy. Corrosion test . specimen and corr-rate meter data indicate the service water corrosion rates are well above the 0.2 mpy target. The corrosion rates for copper / nickel (90/10) have been > 1.1 mpy during the summer when the lake water temperature elevates. Although these average corrosion results are high, they are considerably less compared to the circulating water measurements. This is due to the protection by the BetzDearborn Copper-Trol
- CU1. Increasing the treatment frequency and concentration will help reduce the excessive corrosion in the service water systems.
- This will be especially critical if the plant converts to continuous low level sodium hypochlorite feed for macro / micro fouling control,. Copper and copper alloy corrosion rates accelerate in the presence of strong oxidizers such as sodium hypochlorite. In an effort to improve the corrosion rates I recommend the following program changes: increase the volume of Copper-Trol CU1 feed to the service water system to e achieve the minimum 50 ppm target residual. increase the frequency of Copper-Trol
- CU1 addition based upon system e
monitoring not to exceed once/ day treatment addition. Regards. BetzDearborn Water Management Group 7% 4 D v Thomas H. James Account Manager l D
1 l 4 BETZ LABORATORIES,INC. 4636 SOMERTON ROAD, TREVOSE, PA. 19047 BETZ MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 (PAGE 1 OF 3) PRODUCT : COPPER-TROL CU-1 EFFECTIVE DATE 05-18-89 PRINTED: 3-Sep-1989 REV:SEC.3 PRODUCT APPLICATION : WATER-BASED CORROSION INHIBITOR.
SECTION 1-----------HAZARDOUS INGREDIENTS---------------
INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE l AND CHRONIC HAZARDS OF THIS FORMULATION. SODIUM HYDROXIDE *** (CAUSTIC SODA) ;CAS#1310-73-2 ; CORROSIVE; TOXIC IF ORALLY INGESTED:PEL:2.OMG/M3;TLV:2.OMG/M3(CEILING). TRADE SECRET INGREDIENT; POTENTIAL SKIN SENSITIZER; CORROSIVE TO SKIN AND l EYES;PEL:NONE;TLV:NONE.THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. l i i
SECTION 2-----------TYPICAL PHYSICAL DATA-------------------------
PH AS IS (APPROX.) 13.5 ODOR: MILD FL.PT.(DEG.F): >200 P-M(CC) SP.GR.(70F)OR DENSITY: 1.184 VAPOR PRESSURE (mmHG): 18 VAPOR DENSITY (AIR =1): <1 VISC cps 70F: 37 % SOLUBILITY (WATER): 100 EVAP. RATE: <1 ETHER =1 APPEARANCE: BROWN-BLACK PHYSICAL STATE: LIQUID FREEZE POINT (DEG.F): -4
SECTION 3-----------REACTIVITY DATA------------------------------
STABLE.MAY REACT WITH ACIDS.DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT CATEGORY 'C' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES.
( __ - BETZ MATEL_aL SAFETY DATA SHEET (PAGE,, OF 3) PRODUCT: COPPER-TROL CU-1 EFFECTIVE DATE 05-18-89
SECTION 4-----------HEALTH HAZARD EFFECTS------------------------
ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE CORROSIVE TO SKIN. POTENTIAL SKIN SENSITIZER ACUTE EYE EFFECTS *** CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** i MISTS / AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT ) CHRONIC EFFECTS OF OVEREXPOSURE *** PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS AND/OR DERMATITIS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** CAUSES SEVERE IRRITATION, BURNS OR TISSUE ULCERATION WITH SUBSEQUENT l 1lCARRING. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF ORALLY INGESTED.
SECTION 5------------FIRST AID INSTRUCTIONS----------------------
SKIN CONTACT *** REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS OF SOAP SOLUTION OR WATER l'.EYEUONTACT*** FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A ] PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE *** REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID j TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION *** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM l DO NOT INDUCE VOMITING.IMMED. CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GIASSES MILK OR WATER
SECTION 6-----------SPILL, DISPOSAL'AND FIRE INSTRUCTIONS---------
SPILL INSTRUCTIONS *** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL. PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND / GRIT. l. DISPOSAL INSTRUCTIONS *** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY IDCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT ' PRODUCT (AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS *** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE). DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER
BETZ MATER M SAFETY DATA SHEET (PAGE .2 OF 3) PRODUCT: COPPER-TROL CU-1 EFFECTIVE DATE 05-18-89
SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-----------------
USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION *** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BEIDW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION *** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH DUST / MIST FILTERS. RECOMMENDED SKIN PROTECTION *** GAUNTLET-TYPE RUBBER GIDVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE. REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION *** SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD
SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-------------
STORAGE INSTRUCTIONS *** KEEP DRUMS & PAILS CIASED WHEN NOT IN USE. DO NOT FREEZE.IF FROZEN, THAW AND MIX COMPLETELY PRIOR TO UST HANDLING INSTRUCTIONS *** GENERAL-IMMEDIATELY REMOVE CONTAMINATED CLOTHING, WASH BEFORE REUSE SPECIFIC-ALKALINE. CORROSIVE (SKIN / EYES).DO NOT MIX WITH ACIDIC MATERIAL. ococco******************************************************************** THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) ococo********************************************************************* APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ... REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT: l 740 GALS. (SODIUM HYDROXIDE) l ... RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE l IDENTIFICATION NUMBER IS: D002= CORROSIVE ... DOT HAZARD CLASSIFICATION: CORROSIVE TO SKIN ... DOT SHIPPING DESIGNATION IS: UN1824 SODIUM HYDROXIDE SOLUTION l l ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO l CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 302 CHEMICALS: NONE PRESENT IN SIGNIFICANT AMOUNTS .... SARA SECTION 313 CHEMICALS: SODIUM HYDROXIDE (1310-73-2) 11.0-15.0% ; ... SARA SECTION 312 HAZARD CLASS: IMMEDIATE(ACUTE) AND DELAYED (CHRONIC) ... MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 3 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - CORR ; PE - D
i i BETZ LABORATORIES,INC. I 4636 SOMERTON ROAD,TREVOSE,PA.19047 PRODUCT: COPPER-TROL CU-1 10/12/89 AQUATIC TOXICOIDGY I DAPHNIA MAGNA 0% MORTALITY: 65 NG/L 48 HR. LC50: 112.5 MG/L RAINBOW TROUT 0% MORTALITY: 21 MG/L 96 HR. LC50: 28.1 MG/L FATHEAD MINNOW 0% MORTALITY: 49 MG/L 96 HR. LC50: 60.6 MG/L 10/12/89 MAMMALIAN TOXICOLOGY ORAL LD50 -No DATA DERMAL LD50 -No DATA SKIN IRRITATION SCORE-NO DATA EYE IRRITATION SCCRE-NO DATA INHALATION-NO C.5TA 9
1 [EcE!?!Eo1 12 23 97; etS0aui 45 ** ADil!L ; et SENT EY:C.S.S. NETWORK
- 2-23-97 8 9:56 i P 316 364 4130 0 1 WFAX0006 VCA0033 9088 23DEC97 0910/0911 T0: CURTIS PALUER WOLF CREEK NUCLEAR 1550 OXEN L N.
BURLINGTON 4A 56839 PAGE 1 l UNION CARSIDE CORPORATION
- aentaL =arcir unia aneci l
EFFECTIVE DATE 12/15/95 Union Carbios urges each customer or recipient of this MSDS to study it carefully to become aware of and understanc the iszards associated with-the product. The reader should consider consulting reference works or individuals who are experts in ventilation. toxicology. l and fire prevention. es necessary or appropriate to use and understand th: :::: :: r. :i r.: 0 ir. :hi: M*05. To promote safe handling. each customer or recipient should (1) notify its employees. egents. contractors and others wnom it knows or believes will use t n i-s meterial er the information in Luis MSDS and any other information regarding nazards er safetyi (2) furnish this same information to each of its l Oustomers for the producti and (3) request its :ustomers to rotify their employees. customers, and other users of the product of this information 1: 19ENTIF] CAT]gN EE000CI NAUe* TRIIGI4 X-IGG SUFfsitini CHEMICAL NAME: Octylphenoxypotyethoxyethanoi Nonionic Surfactant I CHEMICAL FAMILY: Nonionic Surfactant FORMULA: C33H60010,5 i "0LE C'JL A*. WE I 2"T ! $2d i Av:r:::: SYNONYMS: An alkyacnenol-hyoroxypolyoxyethylene CAS a AND NAME: See Section III. " Ingredients" II. PHYSICAL DATA (Determined on typical material) l BOILING POINT. 760 mm Hg: >200 C (>392 F) = 11 1.067 at 20/20 C l SPECIFIC QRAVITY(H2O t Copyright 1995. Union Caroide TRITON is a registered tracemark of Union Carbide. EMERGENCY PHONE NUMBERS: 1-800-UCC-HELP (Numoer availaole at all times) OR (3D4) 744-3487 j i
- n..u. t n w c a.m..m e n.c e n.o. o n n..a t. t. n. w.
39 Old Ridgebury Road. Danbury. CT 06817-0001 i PAGE 2 EA0000I N4 net IAITON X-iOO surfactant 1 I l l
AfctivfDs '2 23.eF; 91soAH; 46 ** s.Du1N.; K2 SENT BY:C. S. S. NETWORK
- 12-23-97 : 9:57 :
P 316 364 413038 2 FREEZING POINT! 6 C (43 F) VAPOR PRESSURE AT 20'C: <0.01 mmHg VAPOP. DENSITY teir - 1** >1 EVAPORATION RATE: inuiyi '6issii = li* CC. 01 SOLUBILITY IN WATER Dy wt: 100% at 20 C APPEARANCE: Transparent pale yellow ODOR: Mild P.uYSICAL
- TATE:
Liaaid PERCENT VOLATILES (by weight) : 0.0065 III. INGREDIENTS 4 MATERIAL CAS# EXPOSURE LIMIT >97 Octytphenoxypoiyethoxy 9036-19-5 None established -itii66i < 3 Polyethylene Olycol 25322-68-3 None established I V. FIRE AND EXPLOSION HAZARD DATA --- --------- ------------------~~---- .a.t..i c i n
- w. o n e u. r.
aw ,+.. 485 F (251 0) Eensky-Martens closed dup ASIN O 93 555 F (290 C) Clevoland 00sn Cup ASTp D 92 F L A M M A B. L. E. L. I. M I. T S I. N. A I. R. ov v o l u. m e. : LOWER: Not Determined l urren. nv6 ww6ermanwu 1 i EXTINGUISHING MEDIA: ADply alcohol-type or all-purpose-type foam Dy manufacturers' recommended techniques for large fires. Use water spray. carbon dioxide. or dry chemical media for small fires. SPECIAL FIRE FIGHTING PROCEDURES: onna
- a,
.n PRODUCT NAME: TRITON X-100 Surfactant i Uo not airect a soiin stream of water or foam into hot, curning pooisi this
REcEIVEo: 12 23 eft 9:51Aug 46 em Lou 1N.3 s3 SENT BY:1 S.S. NETWORK
- 12-23-07 : 9:58 P 316 364 413030 3 ony cause frothing and increcsc fire intensity.
Use self-contained breathing apparatus and protective ciotning. UNUSUAL FIRE AND EXPLOSION HAZARDS: This material may produce a floating fire hazarc. See "Other Precautions
- in Section I X.
s V.
HEALTH HAZARD DATA TLV AND SOURCE: None established by OSHA or ACGIH, EFFECTS OF SINGLE OVEREXPOSURE: SWALLOWING: Gederately toxic. May cause abdominal discomfort. naussa. vomiting. and di:rth::. Aspiration into the lungs may occur during ingestion or vomiting. resulting in lung injury. SKIN ABSORPTION: f No evidence of harmful effects from avalfable information, INHALATION: U!gg may gagge }rritagign gf thg eggefraggry tragg. ggogrigqqqq na nage! discomfort and discharge. with chest pain and coughing. I EKIN CONIACI* Brief contact is not irritating. Prolonged or repeated contact may cause discomfort and local redness. EYE CONTACT: Causes severe irritation. experienced as discomfort or pain, excess blinking and tear production. marked excess redness and swelling of the conjunctive, and chemical burns of the cornes. Iri:!: ::y :::gr EFFECTS OF REPEATED OVEREXPOSURE: No acverse effects anticipated from availaDie information. MEDICAL 00NDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicology information and of the physical and chemical properties of the material suggests that overexposure is unlikely to sacravate ex{stino medical conditions. f SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN NEALIE MAIAEC E'v'ALUAIION: Contains surfactant which. based on studies with rabbits involving the -sustained occluded contact of the undiluted surfactant with skin. indicate that such conditions may result in the development of inflammatory changes in f I the lung. Developmental effects including extra ribs and other skeletal variations were observed in the fotyses of rats treated with maternally toxic levelsPAGE 4 PM00"CT NAMEi TRITON X-100 Surf:::::: of a g-mole ethoxylate of octylphenol or nonylphenol. The significance of these findings to humans is unclear as seversi human studies aid not show
cscsivro: 12 23.s7; 9:s Ami as => AoMIN.4
- 4 SENT BY:2.S.S. NETWORK 112-23-97 I 9:58 :
P-4:~ 316 364 413010 4 any association of congen;tal effects in children anc meternal exposure to spermicides containing octyi or nonylphenol ethoxylates. OTHER EFFECTS OF OVEREXPOSURE: 'None' currently known. F. M.. F. R.. O. F. N.. C. Y. A N.. D. F. T. R.. A. T.A..f D. P. R.. O. C. F. n. l.l R.. F. R. i SWALLOWINO: i If hiEishi is fuiiy 66hi6ioui. iive two dissiii sf w i t i f. DO NOI INDUCE VOMITINO. Obtain medical attention. SKIN: Remove contaminated clothing. Wasn skin with soap and water. Obtain medical attention if irritation persists. Wash clothing before reuse. INHALATION: If :07 :y:pt :: d:::!:p.
- :: f r :n :ir.
EYES: immediately flush eyse with water and conalaue washing for at least 15 minutes. 30 NOT remove contact lenses. if worn. Obtain medical attention without delay. preferably from an ophthalmologist. NOTES TO PHYSICIAN: 'There {s ng sneg!f!g antidgte. Treatment gf nyerexognure shguid be diregted et the control af symptoms and the clinical condition of the patient. Any material aspirated during vomiting may cause lung injury. Therefore. 6Eisis in6UIo 66% oi 16dO6sd Eiinshi6sily' 6/ pni/Ei66i6616siip. If it is considered necessary to evne. ate the stomach contents. this should be done by Gesne least likely to cause aspiration t e
- g.. gastric lavage after endotracheal intubation).
VI. REACTIVITY DATA STA"!LITYi S:: !: CONDITIONS TO AVOID: Erolonged excessive nest may cause proouct decomposition. INCOMPATIBILITY (materials to a v o l d) Normally unreactivat however. avoid strong bases at high temperatures. strong acids. strong oxidizing agents anc materials reactive with hyoroxyl compounds. HAZARDOUS COMSUSTION OR DECOMPOSITION PRODUCTS: Burning can produce the following products: CeIDOL E050XIUG s00/OI 06T000 diOXids. Carbon monoxide is highly toxic if inhaledi carbon dioxide in sufficient concentrations can act'as an asphyxiant. HAZARDOUS POLYMERIZATION: Will Not Occur PAGE 5 PRODUCT NAME: TRITON X-100 Surfactant CONDITIONS TO AVOID: None known.
"EcEIVEot '2 23 e78 sis 2AN: 45 s* AoW:N.8 (6 SENT CY:n.S.S. NETWORK
- 12-23-97 8 9:59 :
P-45~ 316 384 413080 5 VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wear eye and skin protection. Floor may be slipperyi use care to svold falling. Contain spills immediately with inert materials (eg. s an o, earth). .A,y g i j d{gghgrog gg ngggggl gggggg; Trgggfgr I{gg{dg ggd gglig d{g,{go material to suitable containers for recovery or disposal. To avold gelling and foaming problems. do not use water to flush away spills. AQUATIC EFFECTS: 98 h r. Fathead Minnow LC50
- 8. g mg/L WASTE DISPOSAL' METHOD:
Incinerate in a furnace where permitted under Federal. State, and local regulations. W i..t ?. C.D C P. T..A I .O p n T. C P. T. T. n..M. k5ShiRAYOkY hkOTECiiON (specify typel :
=
None expected to be needed. However, wnere misting may occur, wear a MSHA/NIOSH approved (or equivalent) half-mask air purifying respirator. V. F. N., T T. L. A T. T. O. N.. : General (mechanical) room ventilation is expectea to be satisfactory. rnvieviave u6vves. PVC-coated EYE PROTECTION: Conogoggles OTHER PROTECTIVE EQUIPMENT: l Eye Bath. Safety Shower 00:*.10*! A O." C ".
.-------------------------------~~
I X. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: DANGER! CAUSES EYE BURNS. HARMFUL IF SWALLOWED. CAUSES SKIN IRRITATION. PLASTIC CONTAINER. IF PRESENT. MAY CAUSE STATIC IGNITION HAZARD. ASPIRATION MAY CAUSE LUNG DAMAGE. I l Do not get in eyes. Do not swallow. PAGE 6 PRODUCT NAME: TRITON X-100 Surfactant AIOld 000t*0! "100 *%10 00d O ! O!U10". Do not handle or empty in presence of flammable vapor. Neop container c i o s s o.
'necstvso: 12 as e78- ~ 4s== tom N.I se e: sana: ' SENT BY 11 S. S. NETWO'.N
- 12-23-97 : 10:00 i P 316 384 413083 6
-Use with adequate ventilation. Wash thoroughly after-handling. FOR INDUSTRY USE ONLY OTHER PRECAUTIONS: NOTICEL NOT.TO BE USED AS A BICCIDE IN INTRAVAGINAL END-USE APPLICATIONS <!NCLUDING SPERMICIDES). FOR INDUSTRY USE ONLY.
- - S u r f a c t a n t s can cause' foaming problems in tiological wastewater treatment plants-and.sther high shear operations, r
This. product may contain trace amounts of Ethylene oxide (CAS N o. 75-21-83. a condition which creates the potential for accumulation of ethylene oxide in the head space of shipping and storage containers and in enclosed areas where the product is being handled or used. Ethylene Oxide is listed by OSHA
- ;r:0:0 !'/ ::r:ine;:.11: :: h ::.1:. IARC :: ::rcia:;::i: t: nu::::. :r.d NTP es reasonably anticipated to be carcinogenic.
OSHA considers that. at excessive levels. ethylene oxide may present reproductive. mutagenic. genotoxic. 9eurologic and sensititution hg&&rds, f this orcouct is handled with adeauste ventilation.- the presence of these trace amounts '. s est. expected to. result -in any short or long term hazard. ,This product may not be exempt from OSHA's ethylene oxide standard. 29CFR191Q 1QA7: ysgra shguly cgme!y with all acolfgable orgvjejnns. Personnet should.be monitoreo to ostermine levois of exposure to etnyiene oxide. If necessary. protective measures should be taken. The OSHA OiFEliilbli iM66iufi Iisit fiF iinyishi 6 Midi li I ppE TS A. Ini i&Ei66 i s 'v i l is
- 0. 5 ppm TWA.
the ACGIH TLV is 1 ppm TWA and OSHA has established an excursion limit of 5 ppm :15 minute average). ADDITIONAL INFORMATION: Additional product safety information on this product may be obtained by calling ~your Union Carbide Corporation Sales or Customer Service' contact. PROCESS 9AIARD: 5:00: r:!:::: Of h:t Or;:ni: ::::10:t ':::r: Or mi::: frc: i-process equipment operating at elewateo temperature and pressure, er sudden ingress of air into hot eauipment under a vacuum, may result in ignitions ) witnout.tne presence of oovious ignition sources, kuolisned 'autoignition-or " ignition
- temperature values cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions.
1 Any use of this product in elevated-temperature processes should be thoroughly avaluated to establish and maintain safe coerstina cond(tions. Surther information is.svailable in a technical bulletin entitloo " Ignition Hazards of-Organic Chemical Vapors.*
...------......-----...--------..-n-......-----------..--...-------
I X. REGULATORY INFORMATION j. PAGE 7 PRODUCT NAME: TRITON X-100 Surfactant STATUS ON SUBSTANCE LISTS: The ::::::tt:ti:r.: :h::
- r: :::i::: Or :: 1!!:; !:::!: (tel;nt U :: b:
u se d..f or calculations for regulations. Trade Secrets are indicated by "TS". FEDERAL EPA i __m-m-m.--__
RECEIVEDs
- 2 23 97;.
9:54&Mi 46 ** Aou:N.; 87 SENT BY:*A S. S. NETWOIK
- 12-23-97 ; 10:00 :
P 316 364 4130:D 7 Comprehensive Envircnnontal Response Compensation. and LiaDility Act of 1950 (CERCLA) requires notification of the National Response Center of release of cuantitles of Hazarcous Substances equal to or greater than the reportaole cuantitles (Res) in 40 CFR 302,4 Components present in this product at a level whicn could require r a. n. n. r t..i n e,
- u. n.. d. a. r. t. h.. a.
S. t. a. t. u. t. a. ". P. a. : UPPER BOUND CAS NUMBER CONCENTRATION % CHEMICAL " o' n* e* m 4 usycoi c6ner 123-91-1 0055 i Dioxane 75-21-8 0010 Ethylene oxide 1 1 Superfund Amendments and Reauthorization Act of *986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQs) and rolesse I i r:::rtin; 0:::: :: *:;:rt:0!: 0":r.:!:1:: !*Q:) in 10 CF* 355 tussd for SARA 302. 311 and 312). Components present in this product at a level whicn could require reporting under One statute are:
- NONE *as t
j $uperfund Amendments and Reauthgritatign Act gf '986 (SARA) Title III recuires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSDSs that sFi 665Iid ind diiiFludiid f67 Inli EiisFisI. Components present in this product at a level which could require reporting under the statute are: 1 UPPER BOUND CAS NUMBER CONCENTRATION % CHEMICAL None 2 Glycol Ether i 1 TSCA INVENTORY STATUS: Ihe ingredients of this product are on tne ISCA inventory. STATE RIGHT-TO-KNOW l CALIFORNIA Proposition 65 l This' product contains trace levols of 1.4-D10XANE known to the State of ..a en..u. e.. e --,me .s. e.... .a ..>a...s. weiaturnas 6u unuse ennuwe snu cinatenc waauc anuwn 69 wnw s.rww vi vasasurnam ...re.--a. to cause cancer. birth defects or other reproductive n o r m. PAGE B PRODUCT NAME: TRITON X-100 Surfactant NASSACMUSETTS 105 O!*, 570.000 *1;tt-TO-F. :t S e c r. ;.C : L!:: !!SL) Hazardous Substances and Extraordinarily Hazardous Substances o the MSL must be identified when present in products. 60mponents present in snis proouct at a invoi wnicn couic require fL_____________-______
45 so Aou1N.; se f.EcElbEot '2 23 97; 9:54Aug SE*lT BY:M.S.S. NETWORK 112-23-97 3 10'01 i P 316 364 4130:0 8 reporting under the statute are: EXTRAORDINARILY WAZARDOUS SUBSTANCES 8 => 0.0001%) JPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % l l Dioxane 123-91-1 0055 l Ethylene oxide 15-21-6 0010 l - -............... ~.... rcnnov6vansa magns-io-nnow. nasarouus suos6ancu Lau6 Hazarcous Substances and Special Hazarcous Sunstances on tne List 6vst be identified when present in products. "omoonents present in this procuct at a lewel whicn could reqJire reporting under the statute are: HAZARDOUS SUBSTANCES 1 => 1%: UPPER BOUND CHEMICAL CAS NUMBER CONCENTRATION % i S!y:0! "th:r N::: 2 l l r CALIFORNIA SCAQMD RULE 443.'1 v0C*S: Vapor Pressure at <0.01 mmHJ at 20'C. VOC 0 g/L l l VOC 0 g/L less water and less exempted solvents ...-am......... uenen nuov6Msunt Anrunentawn. EPA Hazard Categories: Immeciate Health. Delayed Health NOTE The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as cf the date of this Material Safety Data Sheet. Since the use of tSis infor-
- i:r. :".0 Of tt::: 0 ;i r. i : r. : : r.
t r. : :: r.01 t i : r. : Of t r. : ::: :? : P. : ;r:0;;; tr: rot within the control of Union Carbide. it is tne user s obligation to deter-mine tne conditions of safe use of the product. Date: 12/10/90 REVISION DATE: 12/15/95 Printed in USA REVISED SECTIONS Revisions in this MSDS occurred in the folitwing section: Section V: HEALTH HAZARD DATA Significant Lab Data ESection IX SPECIAL PRECAUTIONS O t 7e s i T G U L U t i OIi s PRODUCT: 89521 PAGE 9 PRODUCT NAME: TRITON X-100 Surfactant F NUMBER: NO381H FROM SCVM370 ALLWCS1 w e. t - n. n. s n. o
fiECEfviD: 12 23.s7; '0:42Ami 713 ste 7021 mm ADMIN.;
- 3 DEC 23 '97 l 0 :,56 FROM UNION CARBIDE TO 910163E44130 PAGE.003 1
4 l EC9.8.OG!CAI fag ANDEFFECTSDATA FORTRITOlee X.100 SURFACTANT 1 " N X:!0C nuusmerader'um DoorencelOxyges Demand ObOD)' 2.18 l Measmen.mg 02/mg compend(COD) ~.19 Calculated, mg 02/mg compound Faa^hamaa.1 Oxysea Demand (BODY (BOD / COD x 100) 30 Dey 5.% bioensbion 40 Day 10.% biooxideuon 49 D::= !$, M===larir=. $1 Day 20.% bioomwimm= rA.U
- JVip. @uanau as 3
...c_,.. t 70 Day 28. % of theoisucalCO2 prodecnon -. 4 OECD. 301E. Screemas Test
- 58 Day 7, % DOC redecdon 62 Day 14, % DOC redmetion aG Day 21 % DOC sdocoon 80 Day 28.9 DOC redocuos r ~aa +.i ra w 3
-5000 Bactanalinhabition.1C50.mg/l Toxicity to fathead minnows' 8.9 96 hour 1.cso.ms/L Naes&r442 :w 0f050. M Toxxaty to Daphmamagna' tu 48 hour icu. ms/1. I8 No observed effect ccac. (NOEC). mg/L OECD. C.; ':=-:-s for Ecomoanne Cooperanon and Development lu a w,,m, ,..i. mv, A .=t I.m. _m, ri.ra.c.e.c.u_.re.,nu.b.h.s.he.d..is standsed Manhads isteg Enaminanen of Wasar and Wassewasar.17th ed Public Hemish Assoc. (1989). Calcuissed valus bas oxygen segesed to oxidtsa abe inesenal to carbon dioxide and waser. mv d Meshods. a a.,d s. eat.e,nablished a. Stande a a.u. 6 4.a. : wo,,i., .. -. ~ Bi===d=*=a= calculased a.weensage remo of BOD and DOD (BODrTbOD x 100). ;' domssac aewage asceoorganisses used as seed. m ouw - se,4 u
- 4...w. _ or.,
A;,st.,.,.v.n.s.w. d ohn inserial is. h.a.. .y.. De anst soleman comssses becssnali -: 'n liftessencal numeral sales and the east .h.J=ae Testase le see el====Aad as readdy t : *. ' "- if the ' ' ~ '; '" = ras is >606. 4~. -... ~- en.a,.... ven u avan..uun en w.u - ...i. i. 4 ; w u2_ aim s, --m u y -.n~ - - Sysessa needed with anczoorgamimms tasa rich soil and dissolved organne carbon (DOC) r-Aweir= desassac sewage effluesas. Test maanrials classided as runddy t-: rg ' "- if DOC rasmonom is >705 I. 'Desssummed by narbedity/ growth proosemos where the==ad>== inhibition conceseseen GC50)is measuedl suring tee sees. ) atar 16 hours of incubeman wish sewage _ +-; Y.esamed asianows ano Depinna magna *encessays wiis sGidEElad Id fui $0Gfa02'~~~~ I=.a==.2 CD:llIl Agnene 1 abs==*wy by procedens pohbahed by EPA and OSCD. 'Puhead smanows and Daphuma unagma beoess.ays wass caduceed at the Sousk Charlessee Techas l Aquenc tamorasary ey procnemos poeuanos ey r.rA man ums.u.}}