Text

Informs That NRC Staff Scheduled Meeting with Util on 990218 to Discuss Results of Confirmatory Analysis NRC Performed in Support of Review of Util Request for Exemption & License Amend Re Hydrogen Control Sys at Plant,Units 2 & 3
	ML20203F551
Person / Time
Site:	San Onofre
Issue date:	02/09/1999
From:	Clifford J; NRC (Affiliation Not Assigned)
To:	Ray H; SOUTHERN CALIFORNIA EDISON CO.
References
	NUDOCS 9902180182
	Download: ML20203F551 (2)
	v • d • e

._

O February 9,1999 1

Mr. Harold B. Ray Executive Vice President Southern California Edison Company San Onofre Nuclear Generating Station P. O. Box 128 San Clemente, California 92674-0128 i

SUBJECT:

BACKGROUND MATERIAL FOR FEBRUARY 18,1999 MEETING REGARDING HYDROGEN CONTROL SYSTEMS

Dear Mr. Ray:

The staff has scheduled a meeting for February 18,1999, with you to discuss the results of confirmatory analysis we have performed in support of our review of your request for exemption and license amendment regarding hydrogen control systems at San Onofre Nuclear Generating Station (SONGS) Units 2 and 3. We have enclosed preliminary results of our confirmatory analysis and a occument that explains the analysis methods for your use in preparing for the meeting. While the results are still preliminary, they are being provided now to provide time for your review prior to _the meeting.

j Please contact me at 301-415-1352 if you have any questions.

Sincerely, Original Signed By James W. Clifford, Senior Project Manager Project Directorate IV-2 Division of Reactor Projects lil/IV Office of Nuclear Reactor Regulation Docket Nos. 50-361 DISTRIBUTION:

and 50-362 Docket File PUBLIC

Enclosure:

Preliminary Results PDIV-2 R/F EAdensam cc w/ encl: See next page

_WBateman JClifford EPeyton OGC ACRS KBrockman, Region IV LSmith, Region IV DOCUMENT NAME: SOMTG.LTR OFC PDIV-2 PDIV-2 y

n > tm >

NAME JC afford -

EPeyfc6 DATE 2 / 9 /99 2 / 9 /99 Ok OFFICIAL RECORD COPY 9902180182 990209 PDR ADOCK 05000361 P

PM pq imoiL((:n:ES.FTPD C * *'jH

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Mr. Harold B. Ray 2-February 9, 1999 cc w/ encl:

Mr. R. W. Krieger, Vice President Resident inspector / San Onofre NPS Southem Califomia Edison Company clo U.S. Nuclear Regulatory Commission San Onofre Nuclear Generating Station Post Office Box 4329 P. O. Box 128 San Clemente, Califomia 92674 San Clemente, Califomia 92674-0128 Mayor Chairman, Board of Supervisors City of San Clemente County of San Diego 100 Avenida Presidio 1600 Pacific Highway, Room 335 San Clemente, Califomia 92672 San Diego, Califomia 92101, Mr. Dwight E. Nunn, Vice President Alan R. Watts, Esq.

Southem Califomia Edison Company Woodruff, Spradlin & Smart San Onofre Nuclear Generating Station 701 S. Parker St. No. 7000 P.O. Box 128 Orange, Califomia 92668-4702 San Clemente, Califomia 92674-0128 Mr. Sherwin Harris Resource Project Manager Public Utilities Department City of Riverside 3900 Main Street Riverside, Califomia 92522 j

Regional Administrator, Region IV U.S. Nuclear Regulatory Commission Harris Tower & Pavilion 611 Ryan Plaza Drive, Suite 400 Arlir.gton, Texas 76011-8064 Mr. Michael Olson San Onofre Liaison San Diego Gas & Electic Company P.O. Box 1831 San Diego, Califomia 92112-4150 1

1 Mr. Steve Hsu Radiologic Health Branch 7

State Department of Health Services Post Office Box 942732 Sacramento, Califomia 94234 I

e

-g m--

NUREG/CR-2847 LA-9459-MS R4 COGAP: A Nuclear Power Plant Containment Hydrogen Control

~

System Evaluation Code f

Manuscript Completed tune 1982 Date Published: January 1983 Prepared by R. G. Gido Alamos National Laboratory Alamos, NM 87545 Prepared for Division of Systems integration Office of Nuclear Reactor Regulation U.S. Nuclear Regulatory Commission Washington, D.C. 20Eili5 NRC FIN A7105 i

(

i

'5302iq)ps% 3 Int

wm 7

)

i I

l COGAP: A Nuclear Power Plant i

l Containment Hydrogen Control i

System Evaluation Code l

f l

t i

l

,d j

j Prepad by R. G. Gido l

Los Alamos National Laboratory l

Prepared for i

U.S. Nuclear Regulatory l

Commission l

i I

1

~.

I COGAP: A NUCLEAR POWER PLANT CONTAINMENT HYDROGEN CONTROL SYSTEM EVALUATION CODE by R. G. Gido ABSTRACT l

t The accounting of containment gas concentration l

following a loss-of-coolant accident is important in the safety evaluation of hydrogen combustible-gas control systems for nuclear power plants.

The COGAP code provides such accounting including the effects of (1) the l

l reaction of sitconium and water; (2) radiolysis of core l

and sump water; (3) corrosion of sinc, aluminum and copper; (4) recirculation between compartments; l

(5) hydrogen recombiners; (6) purging; (7) nitrogen addition; and (8) atmospheric steam.

Controls are available to determine when options are initiated; for example, the hydrogen recombiner can be started when the hydrogen concentration reaches a user-specified value.

I.

INTRODUCTION Following a loss-of-coolant accident (LOCA), hydrogen gas any accumulate within the containment of a nuclear power plant. The hydrogen could result l

from (1) metal-water reaction involving the zirconium fuel cladding and the reactor. coolant; (2) radiolytic decomposition of water, which will produce oxygen also; and (3) corrosion of construction materials.

A potentially hazardous situation could result if there is sufficient oxygen to promote hydrogen burning or detonation. herefore, calculations met be performed to determine the gas concentrations in the containment and the effect of combustible-gas control systans, that might be used to keep the gas recombiners..,2 The COGAP concer.trations at acceptable leve'.s, such as l

i 1

~..

l

~

Gas Analysis Program) code was written to perform such

(_ Combustible csiculations.

by D. Shum of the Nuclear Reguistory Commission (NRC)

COGAP was written 3).

COGAP-II was written as a where it was referred to as COGAP-II (Ref.

replacement for the orginal COGAP (Ref. 4) used by the NRC for many years to plants.

ovaluate containment combustible-gas control systems for nuclear power to Los Alamos for review, modification, and public release COGAP-II was sent through the National Energy Software Center in Argonne, Illinois.

For convenience, the original name COGAP was retained.

I l

II. DISCUSSION Additional section the various f eatures of COGAP ere discussed.

In this insight into the code asy be obtained from the Description of Input in Appendix Sample Problems in Appendix B. The discussion that follows will be A and the means of presented in terms of sources of hydrogen (and sometimes oxygen) and controlling the gas concentrations.

i A.

Hydromen Sources 1.

Oxidation of Core Zirconium... Hydrogen can be generated during a LOCA the surrounding steam.

The by the reaction of hot zirconium cladding 'with equation used for this reaction in COGAP is Zr + 2H O = Zr02 + 2H2 + Energy 2

i generated is controlled by user specification of the The amount of hydrogen the total that is oxidised.

The total core zirconium and the per cent of hydrogen generated is added to compartment number one only as a linear of time over a user-specified interval after the end of blowdown.

Following a LOCA, hydrogen and Radiolysis of Core and Susp Water.

2.

4o oxygen can be' produced in the core and sump by radiolysis of water accordi*

the equation (2)

R 0 + energy = B2 + 0.5 x 02 2

2 i

m,

The core cooling water radiolysis primarily results from gamma radiation energy produced by the decay of fission " fragments in the fuel. H e sump water radiolysis results from the energy produced by the decay of fission fragments and heavy elements dissolved in the sump water. The rate of hydrogen and oxygen production due to radiolysis therefore is dependent on the (1) energy production rate as a function of time, (2) f raction of the energy that is absorbed by the water, and (3) the hydrogen yield per unit of energy absorbed (the oxygen yield will be 0.5.of the hydrogen yield). The general format for the calculation of hydroken production due to radiolysis is described below.

The energy production rates, which are based primarily on Ref.

5, are described in greater detail in Appendix C.

Reference 6 provides guidaace regard'ing the values of the user-specified. parameters that affect the radiolyti-hydrogen production. Note that cne hydrogen and oxygen due to radiolysis of the core water are deposited initially into compartment one. The hydrogen and oxygen due to radiolysis of the sump water are distributed according to the user-input compartment FRC parameter.

In equation form, the total hydrogen production can be expressed by (see Ref.

2, Sect.

6.2.5, Appendix A)

CEgc+UI P

ss W

S H " T"N 100 where SH = hydrogen production rate H2 lb,-sole /s; l

P = reactor operating thermal power level, MW, a user-specified g

value; R,= conversion factor, 454 g-sole /lb, mole; I

N = Avagadro's number, 6.023 x 1023 g2 molecules /g-mole; C = radiolytic hydrogen yield [G(H)cl in the core water relative to c

the energy absorbed, H2 molecules /100eV a user-specified value; Ee = fission product gamma decay energy absorbed. by the core water,

)

eV/(s-MW ), see Eq.

(4) below; g

3

4 i

=

G, = radiolytic hydrogen yield

[C(H),] in the sump water solution relative to the energy absorbed, H2 molecules /100eV, a user input value; and E, = dissolved radioisotope decay energy absorbed by the sump water, f

eV/(s-MW ), see Eq.

(5) below.

g l

The expression G(H) is introduced because of its use in Ref. 6 and Appendix A, COGAP Input Description. The E term in Eq.

(3) is defined by c

(4)

E, = (f ), Ry a

i I

where (f )e = fraction of total gamma decay energy absorbed by the core water, a 7

user input value, and E = total fission product gamma decay energy production

rate, 7

eV/(s-MW ), see Appendix C.

g The E, term in Eq.

(3) above is defined by (5)

E, = (fg), Egg + (f ), H y

y where (f +g), = fraction of total dissolved-solid decay energy absorbed in the 7

sump water outside the core; E +g = total dissolved-solid decay energy production rate, eV/(s-MW ),

e y

see Appendix C; fy = fraction of radiciodine decay energy absorbed in the sump water outside the core; and By = radiciodine decay energy production rate, eV/(s-MW ), see Appendix g

C.

3.

Reaction of Containment Surfaces. Another possible source of hydrogen could be from metal surfaces exposed to environments containing steam, corrosive sprays, fission products, and radioactivity.

high-temperature Such expo ~ re ht reer' t in surface corrosion reactions that prodr --

hydrogen.

Surfaces composed of aluminua, zine (including galvanized and 4

zine-base painted surfaces), and copper are candidates. Corrosion tests have been performed to determine the behavior of the various metals used in the containment when exposed to emergency core cooling solutions at reference design-base-accident conditions.

The chemical equations used in COGAP to determine the hydrogen generated due to corrosion are 2A1 + 3E 0 = 3H2 + A1 023,

2 En + HO= B2 + Zno

, and (6) 2 Cu + HO= B2 + Cu0 2

Thus, 1.5, 1.0, and 1.0 soles of hydrogen are generated for each mole reacted of aluminum, sinc, and copper, respectively. The hydrogen production rates are completely controlled by user input of corrosion surface area, surface thickness, and rate of corrosion.

4.

Hydromen (and Oxyaen) Dissolved in Primary Coolant. The moles of hydrogen and oxygen dissolved in the primary coolant during normal operation can be specified by input. These are released in the first time step of the COGAP calculation.

Distribution of these gases is controlled by the compartment FRC parameter, which is specified for each compartment by the user.

Each compartment's fractional distribution is based on the compartment FRC i

fraction of the se of the FRC for all compartmente, which is described in the Appendix A input description.

B.

Gas Concentration Control options f

Gas concentrations and their control are based on the ideal gas equation f

NRT (7)

PV

=

where P is the absolute pressure, V is the volume, N is the total number of gas i

soles, R is the unive-sal gas constant, and T is the abso):te tempersture.

g i

5

constant volume flow rate fans (that is, constant rotations per As a result, unit time) transfer gas soles according to dN dV P

(8) g=g=g, where t is time and P and T are the pressure and temperature for the flow source.

These equations are used to exercise the control options that are described in the following.'

Note that all flow devices in COGAP are assumed to have a constant volumetric flow rate specified by the user in cubic feet per minate (cfe).

The j

resulting solar flow rate is that based on Eq.

(8) with the pressure and temperature being those for the flow source.

If the flow source is a compartment, its pressure and temperature are used with (a) temperature specified by the initial-temperature and the temperature-variation-vith-time he nitrogen addition and inputs and (b) pressure calculated from Eqa (7).

sources are assumed to be at standard ambient' conditions of 14.7 purging flow psia and 70 F.

Ambient flow sources at different conditions can be specified 8

by modification of the efs on the basis of Eq.

(8). For example, an ambient a efs specification flow source at a pressure of 2 x 14.7 psia would require is twice that for the same volumetric flow rate of an ambient flow source that i

at 14.7 psia.

1.

Steam Accounting. To include the presence of steam and its effect on concentrations, an input flag mast be set. his allows use of the initial gas steam in each compartment relative humidity to specify the initial amount of is based on relative humidity as the ratio of the compartment; this in turn steam partial pressure to the steam saturation pressure at the compartment initial temperature.

he steam partial pressure then is used in Eq.

(7) to determine the compartment steam moles. For each time thereaf ter,-the number of steam moles in each compartment is determined from an input table of saturation temperatures vs time.. R ese temperatures are taken to be the steam temperatures in the compartments from which corresponding steam partial pressures are obtained. The compartment steam moles then are determined from Eq.

(7).

Note that this procedure results in compartment steam mole content 6

that is independent of mole transfer functions such as recirculation and purging.

However, the presence of stena.on the concentrations of other gases is accounted for in the transfer calculations. The steam option is not part of the accepted method of licensing analysis and is provided only for the -

convenience of the user.

2.

Purging. A purge for each compartment can be specified.

The purge causes the addition of air at standard ambient conditions to the compartment and the removal of compartment contents at the compartment conditions that existed at the beginning of the time step. The addition and removal are calculated by Eq.

(8) for the user-specified volumetric flow rate. The purge could cause the compartment gas concentrations to change because the mixtu es being exchanged could have different concentrations. In addition, the total gas moles in the compartment could change because the mixtures being exchanged could have different densities.

3.

Nitrogen Addition. Nitrogen addition is specified by giving a

nonzero value for the volumetric flow rate of the addition. The nitrogen is assumed to be at standard ambient conditions with the moles added determined by Eq.

(8).

The addition is made fpr all times. Note that the addition of nitrogen from a source with values of pressure and temperature different from standard conditions could be' accomplished by modification of the volumetric flow rate rate based on Eq. (8).

4.

Racirculation. The exchange of compartment contents can be specified by identification of the (1) number of recirculation connections, j

(2) compartments involved in each connections, and (3) volumetric flow rates for each connection.

5.

Hydrogen Recombiners. Several recombiner connections can be j

specified to modify the hydrogen and oxygen concentrations of the compartments at specified volumetric flow rates. The recombined flow can be designated to (1) return to the source compartment, (2) be returned to any other compartment, or (3) not be returned to any compartment. Recombiners can be specified to i

begin on the basis of (1) an initiation time, (2) the hydrogen concentration in a particular compartment, or (3) the average hydrogen concentration for all j

compartments.

i 7

REFERENCES

" Control of Combustible Gas Concentrati*ons in Containment Following a 1.

Nuclear Loss-of-Coolant Accident," Regulatory Guide 1,7, Revision 2. U. S.

Regulatory Commission (November 1978).

" Standard Review Plan for the Review of Safety Analysis Reports for Nuclear 2.

Power Plants," Office of Nuclear Reactor Regulation,.

U. S.

Nuclear Regulatory Commission report NUREG-75/087, LWR Edition (May 1980).

3.

D. H.

Shum, " Development of a Code (COGAP-II) for Evaluation of Combustible Gas Concentrations and Mixing in Various Compartments of a i

Containment," Memo to Z. R.

Rosstoczy, Chief, Analysis Branch, Division of 16, 1976).

Systems Safety, U. S. Nuclear Regulatory Commission (September 4.

J. A.

Kudrick, " Computer Program (COGAP) for Predicting Containment Following Loss-of-Coolant Accidents,"

Bydrogen and Oxygen Concentrations Tedesco, Assistant Director for Containment Safety, Atomic Memo to R. L.

Energy ':ommission, Directorate of Licensing (December 2,1972).

" Residual Decay Energy for Light Water Reactors for Long-Term Cooling,"

5.

Branch Technical Position APCSB 9-2, attached to Section 9.2.5 of Ref 2.

" Control of Combustible Gas Concentrations Following a Loss-of-Coolant 6.

of Accident," Branch

Technical Position CSB 6-2, attached to section 6.2.5 Ref.

2.

W_

M_

1 1

8

/

n-

+,,

O APPENDIX A COGAP INPUT DS CRIPTION This appendix presents the COGAP input format, variable names, dimensional units, and variabit. descriptions. Note that necessary cards are identified by use of the word REQUIRED in upper case letters. Reference to a card is made by using the referenced card name with the first letter of each card description word in upper case,'for example, the note for the Integer control parsaeters card refers to the Temperature vs Time Sets card. Volumetric flow rates are specified in efa with the solar flow rates based on the flow source pressure and temperature by Eq.

(8). The purge and nitrogen addition flow sources are 0

assumed to be at the standard conditions of 14.7 psis and 70 F.

The expression N1. eans not equal.

TITLE CARD (18A4) - one card REQUIRED INTEGER CONTROL PARAMETERS (715) - one card REQUIRED Word /Last VARIABLE Column Units Description 1/5 ICON (1)

Specifies use of purge and recombiner where none 1 = No purge and no recombiner; 2 = With purge only; 3 = Uith recombiner only.

2/10 ICON (2)

Specifies whether there are more cases where none 0 = last or only case; NE O = Another set of input follows.

3/15 ICON (3)

Plot control, which currently is unavailable, where none 0 = No plots; NE O = With picts.

4/20 ICON (4)

Number,of compartments (1 min, 5 max).

none Number of connections between compartments for 5/25 ICON (5) none recirculation (20 max).

9

Specifies H2 concentration for comparison with CON (3) 6/30 ICON (6)

(Floating Point, Control Parameters card) to decide none when purging or recombination should be initiated.

0 = Average of all compartments used; X = Concentration of compartment X used.

7/35 ICON (7)

Specifies accounting of steam where 0 = No steam accounting; none NE O = With steam.

Note - Initial steam content for individual compartments is based on the Specifications card variable RELHUM(i).

At later times, Compartment being saturated at the compartment steam content is based on its atmospherevs Time Sets card below, see Sec.

temperature specified in the Temperature 11.B.1.

FLOATING POINT CONTROL PARAMETERS (5F10.0) - one card REQUIRED Word /Last VARIABLE Column Units Description 1/10 CON (1)

Problem end time.

days 2/20 CON (2)

Purge or recombiner initiation time.

days 2 concentration at which purging or recombination 3/30 CON (3)

H begins. CON (2) must be ero to use this option.

4/40 CON (4)

Racirculation fan (s) start time.

days Interval after and of blowdown over which H2 5/50 CON (5) fros the Ir-H O reaction is linearly released 2

s into compartment one.

COMPARTMENT SPECIFICATION (8F9.0) - ICON (4) cards expected The i Compartments will be numbered in the order of entering these cards.

index is the compartment numbs.. Note that the first compartment is special and the H2 and 02 because of the hydrogen release has to the Er-E 0 reactice, 2

due to radiolysis of the core water enter only compartment one.

Word /Last VARIABLE Column Units Description 1/9 V(i)

Compartment volume.

ft3 Total pressure.

2/18 PA(i) 2 lb /in f

10

3/27 PN(1) 2 Ritrogen pertial pressure.

If the total pre:sure is' lb /in equal ro PN(i) and there is steam, the nitrogen f

f partial pressure is reduced to accommodate the steam.

A PN(i) of zero results in the nitrogen and oxygen mole fractions of air.

4/36 T(i)

Initial temperature.

If there is steam indicated, OF this temperature will be the initial saturation temperature, see RELHUM(i) that fellows.

5/45 RELHUM(i)

Initial relative humidity, which is PV(1)/PSAT, none where PV(i) is the steam partial pressure and PSAT is the steam saturation pressure at T(i).

6/54 RP(i)

Purge volumetric flow rate of ambient air added to cfm this compartment with an equal volumetric flow rate removed from this compartment.

7/63 FRC(i)

Factor used to determine the distribution of the 1

hydrogen and oxygan (a) dissolved in the reactor coolant water and (b) genees..d ".; radiolysis of sump water. The moles added to each compartment are the product of the total moles available and the FRC(i) divided by 100. Thus, the FRC(i) can be interpreted as a percentage if they sum to 100.

8/72 ADN(i)

Nitrogen addition rate.

cfm CONNECTION SPECIFICATION (215, F10.0) - ICON (5) cards expected j is a connection index based on the order of inputting these cards Word /Last VARIABLE Column Units Description 1/5 NJ1(j)

Compartment at connection inlet. A sero value will result in nothing happening to compartment NJ2(j).

none 2/10 NJ2(j)

Compartment at connection outlet. A sero value will none result only in removal from the UJ1(j) compartment.

3/20 VR(j)

Volumetric flow rate between compartments.

cfm 1

11

FIRST REACTOR COOLANT PARAMETEli CARD (6F10.0) - one card REQUIRED Word /last VARIABLE Column Units Descripti6n 1/10 RC(1)

Aeactor thermal power.

t 2/20 RC(2)

Reactor operating time.

h 2/30 RC(3)

Zirconium mass.

Ib, 4/40 RC(4)

Pe'r cent zirconium reacted with water. The resulting hydrogen is added to compartment one only.

5/50 RC(5)

Oxygen dissolved in reactor coolant water.

Ib,-wole 6/60 h.,(6)

Hydrogen dissolved in reactor coolac.t. rat r.

Ib -sole Note - The dis, solved oxygen and hydrogen are added to each compartment over the x RC(6)

/ 100, first time step according to FRC(i) x RC(5) / 100 and FRC(i) respectively, with FRC(i) f rom the Compartment Specification card.

SECOND REACTOR COOLANT PARAMETER CARD (6F10.0) - one card REQUIRED Word /Last VARIABLE Column Unitr.

Description 1/10 RC(7)

Radiolytic hydrogen yield G(H)e in core water

)

molecules used in Eq. (3). This hydrogen and the associated

/100 eV-oxygen go to compartment one only.

2/20 RC(8)

Radiolytic hydrogen yield G(H),in sump water molecules solution used in Eq. (3)

/100 eV Per cent fission-product decay energy absorbed by the 3/30 RC(9) core water, resulting in radiolysis and the generation of per cent hydrogen and oxygen, which are added to compartment one.

4/40 RC(10)

Per cent of total solid fission-product decay energy absorbed by the sump water solution.

per cent 12

- _, _. ~. - - - - - --. - -

l l

l I

5/50 RC(11)

' Per cent of total iodine isotope decay energy per cent absorbed by the sump water solution.

6/60 RC(12)

Reactor coolan't blowdown time used to determine s

the time after which the Zr-R 0 reaction hydrogen 2

is introduced into compartment one.

l Note - RC(8), RC(10) and RC(11) affect the hydrogen and oxygen generation due to sump water radiolysis.

NUMBER OF CORROSION SURFACES (15) - one card REQUIRED Word /Last ' VARIABLE,

Column Units Description 1/5 NC Number of aluminum, sinc, or copper corrosion surfaces none (10 max).

CORROSION SURFACE DESCRIPTION (215, 2F10.0) - NC caads expected 1 is surface number index tased on the order of entering these cards Word /Last VARIABLE Column Units Description l

1/5 Iv0(i)

Number of compartment in which surface is located.

none 2/10 MAT (i)

Identification of surface material where none 1 = aluminum, 2 = sine, 3 = copper.

3/20 SURF (i)

Surface area.

1 ft2 4/30 THK(i)

Surface thickness.

in.

NUMBER OF TIMES FOR CORROSION RATE SPECIFICATION (4F10.0) - one card expected if NC.(Number of Corrosion Surfaces card) is not sero Word /Last VARIABLE Column Units Description 1/5 NFT Number of cards that follow for specification of corrosion rate vs time (2 min, 10 max).

none 13

j CORROSION RATES VS TIE (4F10.0) - NPT cards expected (only if NC s 0) 1 is the order of reading the The values of time must be increasing.

cards.

Word /Lest VARIABLE

-Description Coluan Units k/10 TIEV(i)

Time.

days Aluminum corrosion rate at time TIEV(1).

2/20 ACOR(i) mil /yr Zinc corrosion rate at time TIEV(i).

3/30 ZCOR(1) mil /yr Copper corrosion rate at time TIEV(i).

4/40 CCOR(1) mil /yr Note - More sets can ba provided in a similar manner on additional cards.

NUMBER OF TIME INTERVALS AND DIAGNOSTIC CONTROL (IS, 2F10.0) - one card REQUIRED Word /Last VARIABLE Description Column Units Number of intervals that can have different time steps and print intervals (1 min, 20 max).

1/5 KTIME none Time at wMeh diagnostic printing begins.

2/15 TIDIINI days Time at which diagnostic printing ends.

3/25 TIDIFIN days TIE STEP AND PRINT CONTROL (2F10.0, 2Il0) - KTIE cards expected J

i is the order of reading the cards.

Word /Last VARIABLE j

Description Column Units f

Time at begining of interval.

1/10 TIMEX(i) days Time increment used for performing calculations 2/20 TIEY(1) within interval.

days 14

3/30 NPRINT(i)

' Number of time steps between prints.

~

none 4/40 NFLOTF(i)

Number of time' steps between points plotted; however, plotting is currently unavailable.

none Notes - To get printed output at TIEX(i+1), the NPRINT(i) and TIEY(i) should be specified to produce output at TIEX(i+1).

Also, the time increments [TIEY(i)] (1) must be sufficiently small to preclude the removal of more moles from a volume than are available, (2) should be varied to establish that the results of interest are not affected by the time increment size, and (3) are required to satisfy (1) when the steam option is used has been found to be smaller than when this option is not used; e. g., the sample problem time increments had to be reduced by a factor of 10 Appendix B when the steam option'was included.

NUMBER OF TEMPERATURE VS TIE SETS (IS) - one card REQUIRED Word /Last VARIABLE Column Units Descaption 1/5 NT1 Number of time-temperature sets (2 min, 20 max).

none Note - The temperatures that follow will be the those for all compartments after zero time.

The sero time temperature is specified on the Compartment Specification card. If ICON (7) of the Intes.r Control Parameter is sero, these temperatures only result in a change in the compartment pressures by Eq.

(7).

The accounting of steam may be called"for by ICON (7) of the Integer Control Parameter card as nonzero.

In this case, these temperatures are the compartment steam saturation temperatures for the determination of compartment steam moles.

TIE VS TEMPERATURE SETS (6F10.0) - cards expected based on NTI and the f act that three sets can bit specified per card Word /Last VARIABLE Column Units Description 1/10 THE(1)

First set time.

days 2/20 TEMP (1)

First set temperature.

oF i

15

/

l 3/30 THE(2)

Second set time.

days I

- 4/40 TEMP (2)

Second set temperature.

OF l

l 5/50 TME(3)

Third set time.

days i

6/60 TEMP (3)

Third set temperature.

F Note - More sets can be provided in a similar manner on additional cards.

l NUKBER OF HYDROGEN RECOMBkNER CONNECTIONS (15) - one card expected only j

if ICON (1) on the Integer Control Parameter card is three Word /Iast VARIABLE Column Units Description 1/5 NT3 Number of hydrogen recombiner connections (20 max).

none ETDROGEN RECOMBINER CONNECTIONS (215, F10.0) - NT3 cards expected j is the order of reading these cards.

Word /Iast VARIABLE

. Column Units Description 1/5 NR1(j)

Compartment that provides flow to a recombiner.

NR1(j) = 0 results in no flow into compartment none NR2(j) due to this connection.

2/30 NR2(j)

Compartment that receives flow from NR1(j) after recombination. NR2(j) = 0 results in flow removal none from NR1(j) only; and NR2(j) = NR1(j) results in the recombined flow being returned to NR1(j).

3/20 BR(j)

Recombiner volumetric flow rate.

cfm Note - More connections can be specified in a similar manner on additional cards.

l l

16

i I

I APPENDIX B SAMPLE PROB { EMS j

Figure B-1 presents the output for two sample problems, which were constructed to demonstrate the various code options and therefore asy not be f

representative of "real" problems. Note th:e the output includes a listing of the input cards, interpretive descriptions of the input, and the calculated results. D e sample problems are described briefly below even though they could be constructed from the input.

Sample Probles 1 The integer-control parameters specify that there will be purging, an I

additi na case (Sample Problem 2), no plotting, one compartment, no recirculation connections, purge initiated when the compartment one hydrogen concentration exceeds a specified value, and there is steam.

He real-number control parameters specify a total probles time of 20 days, purse-initiation j

hydrogen concentration of 3.5%, and an interval of 120 s after the and of j

blowdown for the release of the Zr-H O reaction hydrogen. The comp'artment has 2

2 x 10 gg ; is initially composed of air and steam at 14.7 psia, 120 0F, and a 6

3 relative humidity of 0.5; has a purge capacity of 150 cfa; and will receive 100% of the (1) the H2 due to sump-water radiolysis and (2) the 02 and H2 dissolved in the primary coolant, which depend on subsequent specifications.

The reactor (which is always in compartment one) parameters are self explanatory.

h e corrosion parameters specify that the compartment has (1) an 2

aluminum component with an area of 25 000 ft and thickness of 0.2 in.

and 2 and a thickness of 0.003 in.

(2) a zine component with an area of 75 000 ft The corrosion rates are specified to vary with time based on four time entries with aluminua rates that vary from 20 000 to 500 mil /yr and zine corrosion rates from 300 to 10 mil /yr. Small time steps are specified as suggested in Appendix A.

Note that after zero time, the compartment temperatures specified will be the staae-saturation temperatures.

'The Sample Probles 1 calculated results show that (1) at time sero, the I

compartment h,

str Ward-air nit-ogen and oxygen concen* rations with the initial humidity, (2) the temperature and steam content increase sharply over 17

the first time step printed because of the specified steam-saturation, temperature, (3) the hydrogen increases sharply over the first time step printed because of the Zr-H O reaction, (4) 'the hydrogen due to metal corrosion 2

rates decrease with time, (5) the nitrogen and oxygen moles increase at 6 days be cause the hydrogen concentration reaches 3.5% causing the purse to be initiated, and (6) a maximum hydrogen concentration of ~3.8% is reached at

~12.5 days.

Sample Problem 2 he integer-control parameters specify that there will be a recombiner, no additional case, no plotting, two compartments, two recirculation connections, recombiner operation initiated when the compartment one hydrogen concentration exceeds a specified value (which has no significance for this problem because an initiation time is specified), and so steam. he real-number control 8

parameters specify a total problem time of 20 days, recombiner initiation at days, recirculation fan initiation at 0.75 days, and an interval of 120 s after the end of blowdown for the release of the Ir-B 0 reaction hydrogen.

he 2

6 6

3 compartment volumes are 0.3 x 10 and 1.2 x 10 ft, initially composed of air 2 will only at 14.7 ps;.ia; the temperatures are 135 and 90 'F; and compartment due to sump-water radiolysis and (2) the 02 and H2 receive 100% of (1) the B2 subsequent. specifications.

dissolved in the primary coolant, which depend on One recirculation fan will transfer 100 cfm from compartment one to compartment two and the second fan will transfer 100 cfm from compartment two to h e reactor (which is always in compartment one) parameters compartment one.

are self explanatory. he corrosion parameters specify that, compartments one and two both have an aluminum and a sinc component. he corrosion rates are specified to vary with time based on 10 time entries with a complicated variation of corrosion rates. A recombiner to reenve 100 cfm from compartment one and return the recombined flow to compartment two is specified.

For Sample Problem 2, (1) the compartment one and two concentrations start j

i 1

toward common value after the recirculation starts at 0.75 days, which is its anxious of about when the compartment one hydrogen concentratf n reaches

~3.8% and (2) the number of hydrogen and oxygen t<1es begins to decrease after the recombiner is initiated at 8 days.

l 18 w

n

v

~ - ' '

p-I l

l 1

LISTING OF IedPWT CeROS I

l tm.S to et 30 SS 30 SS

.0

.S

.0 SS

.0

.S

,0

,8

.0 l

coser SampLt pa0 stem t l

3 8

0 t

t 30.

O.

3.5 O.

430.

l 3.85 44.1 0.

930.

.5 190.

100.

C.

30St.

48000.

9000, t.S 0.

C.

.9

.S 10.

9.

So, 30.

l 3

i 1

6 3S000..3 9

3 79000. 003 a

0 30000.

300.

O.

.03 1000.

100.

O.

.09 1000.

D0.

Os 30.

800.

10.

O.

4 C.

.0003 900 9.

.001 9000 to.

.00 000 30.

.08 to 3

0.

340.

40.

340.

Cesar SampLs paceLam 3 3

0 0

3 3

0 0

30.

8.

O.

.79 130.

. 388 te.?

0.

835.

O.

1.388 64.7 C.

90.

O.

C.

100.

O.

t 3 900.

3 6 900.

4000.

66000.

00000, t.

O.

.5

.S to, t.

90.

30.

e i

t 900.

.03 4

3 90000.

.001 3

4 900.

.03 3

3 70000.

.001 to 0.

378.

3.0 C.

.03003 1380.

13.ip 0.

.0stae 3083.

33.9 0.

.19974

3344, 27.9 c.

. t?M t 3He.

St.S 0.

.94733

4479, 19.e D.

.97070 9360.

44.4 0,

t.9914

000, 8.0 C.

3.3148 S 3O.

e.S 0.

30.

375.

3.8 c.

e 0,

.001 100 0

9.

.01 SJO G

-90.

.01 000 0

&4.L S to 19 30 SS 30 SS 40 AS 90 SS 00 SS TO TS 90 1

i LISTING OF !self CaaOS COL *S 90 19 30 SS 30 SS 40 45 to 94 to OS 70 TS 00 30.

.01 90 0

340'.

'i 9.

340.

40.

t 000.

t 3

00L-S to 19 30 SS 30 SS 40 45 to SS 30 OS 70 75 to i

I l

l Fig. B-1 Listing of input cards for Sample Problems 1 and 2.

19 1

. - ~ ~ ~.. ~..- -..

... ~ -~. - -.

. -... - - -. ~.

=..

53/01/06 Cosso Sassett penetta t I C454 el

.... lesPut Dat e * ***

I Ca$t ti' Cente0L pasamittel ICWWIei SC9ul31 59BNI3)

ICOsse a i BCSust S S SCONtti SCONIti 3

1 9

4 0

t t

sem I tI C9m (3 9 Cens E S t CD tal CSN I$5 satt SatS Plettest Da'5 StC 30 00 S.80 9.90 0.00 130.00 Poeamttt#$ 9De 8 aces WD4uut vetunt WDLuut 1914L Det$

p.ess pets tiesptestuet ett, eeJM.

pus Satt teC est 60 satt em.

Cutt P$la P$$a t

P$te/ Plat Ces 99 ACTION Cf W t

9000000.00 to 100 9.0000 490.0

.90 900.50 000.00 0.00

9. Casteert paesagttes o

et000.00 884Cf98 988eatless flat feell o

9000 90 Ile.patte stattION. Pfe. CENT t.90 e

Salt 90 StaC19e P0wle FMI 80 Dil60Lvt0 tes PeI COOL 4te actt le D 00 339Cminas wtledt (L951 p.30

.90 Ise tuner SOLUT80NtE0kt/s00 tel*

93 93SSOLwt0 les pe3 COOL.tts.aptile

.90 Sint 90.00 S/0 SOtt0 east sel St Suur sette

5.00 Steel in CDet 50LUTISutu0Lt/e00 trie 30.00 9/0 assG 685 Of Cost vatte SLOW 0eues Ducettow (SICS S/S B000est sea agl. St Suur waite

90.00 44StW tSe teenW1 was3acLt3 (Lasetesus. 71ssC see Compte Egee0 stems passertres 3

es. 38 aLU.. Itast ese Co* Pts Compensteftl

SCONf O.st te Puntt ase te og etteugleste spL. 42, mattel&L Diet.aeta testenestl$

e3 ggtee pgegg 993 gegeg g e3 ggfee ett etC9selsste Seemtsk e Last test es emett gast Cast e e muttsett Cast t

t 3.tegot*ee 3 Seoot*0f

- - - t9ttless set ava Lastit9/09/***

t 3

1.0000tesa 8.0000E 88 Imut3 p* O se PLet a t Pt97188st eG Slettattens WWE 99 magggggggg ptptisess ett etestaatsens gut to attat Egesestsee Costt, m ittlek EgeeOS19u Dettl attle LOC 4 9491138s eG etestattges agt tg pe.este stattl9ms o

et. Of P15. Ses teett e

69ttgest 90 tat set etestaatsens dCletteattste les ta, m.

PEDttless eG Ce'ssCterteat3gu gas te. WDL.

t gest AL CDs esit ! E9e satt C 598.8478 e3 PLOtfledC est C9 Sat $

1L/'s SIL/'s 83L/'8

3

e

L9113ess S3 39WClestes18sas les 16 geg.

10 ALL test 850VE Cantt WILL St PLettgg g.g0 90000,90 SM.90 9 90

.33 0000.90 000 00 9.00

- - pt9ttless set eve t t aglit 9 /eC l* * *

.95 9900.80 to.90 e.00 3Csest alo edusete De stLWut&

30.80 900.90 to.90 9.90 f tShit h enaste se,suwCiteut Stenst e k 9 test ayteest watut 97 aLL temuksetatert est CONCterteattp v3LL st y5to ea test est genst les a tempt. ggg gt Ult 0 test $188 517t fasLt teenHt h e se $ttaa et estes gitam Salte Obs &&tgestigas tger p15. Ses teette a 80ert#P

PostLes see 1But.Dett Stast S W e tiet at unstes puestes se og eggesagaste tgat 13st test. petett PL91 Darl 967

'Ste.

Fete.

Sta#15. Sats muf 3) e se Cemetterteattens at gnegene ginggang se og

't.900

.00090 000 9

ettesesente staats 5588149

tiet at uttlCes tag og agCleCULat194 taas e.gg0

.g0e00 egge 9

90 000

.es000 e00 9

Stat 15. DaTS Coset 3 D e guest 3ans tes eqs ettleggg poen ps. egg 30 300

.99000 90 9

mate 3 9 e so etsstaatsen mattegaLg

1 4Leestenen CWart aleest ert fleu'. attle L9Cs

I Ilest II TeGeI Sk $IIDO sett.tetSt ttgPS ejtt $4 $aT TteED

9 88'Pte es0 38 P15. See taakt

3 t$st Stamp.

esotit - tes35 L90 tem WILL St Desertre tee test ygest gett 34Lv.

UDL em. e eeugsg stattge 880t. STS.

Davt 98g.9 Desput 0.0 att Pastl&L es3 petggust. ResLttl tog Cawtelsestert g.000 940 90 Il DetSSWelfte arties set tettt8aLLv.

e0 cop 980.90 Fig. B-2 Description of input f or Sample Probles 1.

20

m._~

___.__._____.____.___.________-______m, i

i I

Seeep tempts eggstle t 93/01/06 t Cent tt

..,-. gu?put gate....

t tatt il 996 t3et

................. Lg.agngt.................

....... 9ge.ggert........

9ett. Temp.

88.

DevS ter est e3 Site.

Totat est est 33 sites thia t

t 9.eep 9.90 9531.95 933.39 393.99 efft.33 0.00 94.00 19.9d 9.98 94.90 130.0 t

400 34.et 303t.99 9M. ?S 9093. M 98436 90

.33 31.83 3.et 99.14 49.99 380.0 t

.300 Se.34 9531.93 930.00 Sett SS etlet.93

.3t 3t.99 8.e3 99.Se d4.44 380.0 t

.MO 83.e3 3834.95 980 et 6663.96 title.te

.39 39.96 9.e3 99.63 89.04 340 0 t

.800 St.9s Stat.99 De t. M 9063.96 19966.90

.et 34.93 a.43 39.07 89.9s Dec.0 t

.500 -

90.33 stat.95 943.t3 estr.se tttte.pt

.58 St.se S.e4 99.33 49.00 340.0 t

.900 88.30 3539.95 944.37 9453.99 tit 91.e4

.St St.de S.de St.d? dt.98 380 0 9

.900 96.39 3%39.99 946.33 Sett SS t o tM.38

.se St.e6 9 ed St.af 48.03 380 0 t

.000 93.97 3539.99 986.39 0083.09 19305.O?

99 St.e3 S.49 39.31 et.96 340 0 t

.900 99.31 3930.9s 947.M tet2.99 t es ta.S t

.53 31.et 0.89 99.33 82.88 340.0 t

9.000 99.08 Stat.95 948. 4e 4e33 g3 st334.90

.33 38.30 0.et 99.38 83.99 380 0 t

3.000 110 47 3629.95 994.93 sett.99 99300.?9 8.99 39.41 8,48 98.07 et.d4 3e0.0 e

3 WO 33?.13 393 6.M 968.38 0893.06 99313.90 9.98 30.91 S 89 98.89 83.00 380.0 9

8.000 303.99 3t29.99 tot 30 ettt 96 194e3.39 3 64 30.98 8.e4 to te et 94 340 9 8

5 000 ste 41 9635.96 9?O ST 9683.09 99999.93 3.97 30.00 e.as 97.30 83.t9 340.C t

e 300 eOS.St Maf,tt 9?0.43 0893.43 91983.99 3.64 30.90 0.e9 St.43 83.81 340 0 t

T.WO 893.99 Sett 90 993.94 4093.43 19001.tt 3.03 30.Se 0.96 97.03 es.te 380 0 9

S,900 838.53 Stat.88 1905.43 9893.13 t tfee.M 3.90 39.08 8.98 94.04 e4.05 340.0 t

9.000 443.03 3898.04 9096.83 9853.13 19005 99 3.?g 39.39 S.09 96.35 ed.30 340.0 9

40 000 est a0 site.St tops.se sett.t3 stess.se 3.99 St.se e.st es.ge 44.S3 Sep c t

98.000 493.94 St?O.99 9036.03 ' elet.81 99906.e7 3.89 it.S?

9.99 St.03 44.08 M0.0 t

t 13 000 ett 19 3003.64 tees.?3 4649.01 90see.64 3.83 31.83 8.13 96.83 ed ed 340 0 0

13.300 e98.00 3033.09 test SS Goet.61 19994.13 3.83 St.98 S.98 SS ed 44.98 340 0 t

te 3c0 ese to Sete to sett 99 9848.81 93090 SS 3.01 33.99 e 93 96.30 49.10 380.0 t

15.000 801.99 3083.??

9063.01 0689.S? 19084 e t 3.99 33.33 S St St.st es.St 380.0 9

96 000 899 OS 3903.49' test.90 GMt.St 130?O.39 9 TT 33.3e 5.83 96.98 48.30 Sec.0 9

91.900

93.03 3933 95 tett te Stet.S? 19990.83 3.Te 33.et S.99 54.97 49.31 380.0 0

90 000 440.38 3980.96 1913.40 4489.61 19901.30 9.90 33.64 0.07 M. 09 89 48 Dec 0 1

l 9

99 900 es3.??

3994.30 tete SS eset.e? tetet et 3 es 33 63 8 es 94.83 et.e9 340.0 9

30 000 eN St 3909.44 tett 48 Stel S? 19t31 94 3 at 33.14 0.90 ed.?? #8.93 380.0 t

30 Die 438.00 9999.37 tett.90 Stat.81 13:33.04 3 80 33.19 8.90 94.?? et.93 340.0 e

og ettsteettges put 19 939ttetert SEWCts 19 Cal 99ttseit 13et Me.ees eeD.

W1&L 1994L l

6 9 500 9.90 9.90 9.90 9.00 9

.900 931.98 3594.94 9399.98 9e90.48 9

. 3W SST.M ette 93 Sete.90 19973.37 4

.300 991.04 telt 93 98991.99 98?St.99 9

.e00 SST M 9689.93 19933.93 potte.te t

,900 S3? M Tott 90 99944.08 33733 90 t

.000 tai te H et 93 17398.99 36834.e9 9

.990 911.06 9333 98 99884.33 Stett.se d

9

.000 939 94 9000.31 36833.35 33ett se 9

.900 SST.S8 90194.31 380st.99 95397.73 9

9.000 83?.94 teste St 36399.31 geget.e3 9

3.000 431.05 17t13.00 metet.t? 99998.14 t

3 900 831.M 39430.94 99643.39 90004.99 9

d.000 931 SS Steet 40 90180.98 999494.53 9

6. MO 639.SS Steet to ttteet.90 teGDee.99 9

6.800 431 Os 31014.33 13ttet.99 toasts.30 9

9.300 931.98 34903.90 199489 90 000981.38 t

S.800 431.84 37333.83 t?ttet.30 gottes.1e t

9 900 SST SS 3999? et 990300.91 830996.30 e

te 500 SS1 et 48343.88 3M970.03 399999.te 9

ft 900 931.95 estM.e3 337301.99 313est.93 e

of 800 939 M 88?30 et settee.81 393M s.34 9

13 000 431. H ett M.De M f?09.99 398083.09 9

64.000 SST to 90099 ft Stes31.63 settet.te t

SS 000 SS1 96 59998.3e 39 stat.pt 350083.34 t

to 800 831 SS M T?S to 343069 11 388983.43 3.30 398090.93 944.M. BT 33079.9.e3 eeMes.M t

41.900 431. H M8 es $483 9

M see 31 es,.s eMSc Si astees. co d30eM.33 es?. e. et9 M.98 S u tte.M e M u f.M t

99 9o0 9

30 soO 9

30 090 S3t.M StMs.e3 avd3M.M e3M M.es 4

Fig. B-3 Calculated res.ults for Sample Probles 1.

21

_ _ _ -. - _. _ ~ _.. ~

+

33/07/Os CD&at les*Lt peOsttu 3 s Cast pl l

.... tesp:/t gat e....

I Call Ji

i teWte0L #eeestitel ICSNtil 3CONlt) ICowtal 3Cenf al atWNill ICDetti Scoutti 3

0 9

3 3

4 9

CON Itl CON 031 CON (31 COW (el COM ($1 l

94v5 Davl Pt9Clart DetS SEC 90.00 0.00 9.00

.TS 430.00 poetettIel ese ea0M vg4Uut WDLust USLWat T9tal 8865 P.ee sett vturtsatUnt ett. esp. ens.eavt Fec est 40 satt em.

Curt PSIA ella f

- lte/ Plat Ste feeCTitu Cte I

t 90C900.00 te.900

9.9000 195.0 9.90 9.90 9.00 9 90 3

4800000.00 98.700 9.8000 90.0 0.00 0.80 900 00 0.00 l

diasctlaw *ateattfel WOLfl*

WOLlell FL9V Sett

)

1 9

3 900.00 3

9 900.90 6 t..e.=tte.

DieCTSD #DWte teut) e e000 00 SteCTE,e SPfeetlest Tlet teell o

90000.00 33*C0mlWe et teest (L959 e

80000 00 Tie.sette election. Pte.Clut e

0.90 93 Ol550Lvt0 tes pel COOL.tLO-eIOttle 0.00 ess OlllOLwtc les pel.3OOL.tL5=W Ltle 9.00 8t00 la cool SOLU 130Hiu0Lt#990 tvle

.90 Stul See Sump SOLUTI mtuGLt/e90 tulo

.90 D/0 essG act. av test satte e

60 90 S/S 9DLIO esDS eBS Be Same* Wette e 4.00 9/8 8903est esos agg, av guer satte e 30 30 staggewu gunatggw (SICI e

90.00 4e ALungsman, gjest ase CSP'f8 C9ee953sN paeautiges es. 98 ALU.. Elast ese C98988 C0 mpg l Sert $ e e

UDL. 083.

matt #let tafet.8964 tesite4fl$

Ft3 gestest 5 9

4 5 f N ?*03 9.00008 03 9

3 9.Oppet*De t.00008+03 y

e e.ese0teet 3.80006-03 3

3 9.en006*ee t.90006*D3 Esart. mattegat 20ee95 ten tatt$ ettte LOCA es. Of Pit SW teSLt e 90 ggutagnestert vger. ettle 19CS esatt mttt tiert wist 91 Sat Star to testet Il Sites 13eit 44.333 Sett 3.80s.94tt C. COW.Sett ag, ge pig. go tegLt e 3

Darn SIL/tt elk /9e SIL/te 1955 vleD.

9.90 Sgt.90 9.00 9 00 pe95 946 9 1

.83 4390 90 93.90 9 80

.01 9063.00 93.00 9.90 9.800 See 30

.t3 3948 80 31.90 9.90 et.900 980.80 99 9384.00 31.90 9.00

.96 sett to 99 ao 9 90

.98 9780 00 te.c0 9.30 t.94 000 00 9.90 0 00 3 Se 600 00 e.90 9.00 30.00 315.00 3 00 9.00 ptgom paeastitag toe ett estes98His Stat life.5trt taSLt egl. et duasCtleNS tes ettee, e e Ptl. pas teette e

*;,r"

=m

=taf

..I

,,. test.

.e e.t

.L.t Dawg Das F980.

9980 9

8 9 see

.opeep 900 9

9.900

.91900 000 9

to 900

.94000 900 0

30.o00

.Seo00 30 o

Fig. 3-4 Description of input for Sample Problem 2.

22 u

.m

. _ _, > _ ~ _

+

4 e

i t98ee Seas %t pesette,3 e3/01/0e t telt at

.... w ippt gets....

t cast 31 l

99(

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.................LB-Mtl******-*******

- - - ==++ 9te Clert --+-..

9 eft. woe.

3 em.

Det$

ett est 93 t? tem 191eL tot e9 83 Sites Pale t

9 9.o00 9.oD DM se us. e3 e so at t.M 0 oc

?9.e6 30 99 o e0 te.to tot.0 t

.900 96.40 tot de let 30 0.00 TOS 93 3.33

??.06 30 83 9 00 11.14 980 0 t

.900 tt 04 See de 487.37 0.00 183.69 3 el 96.Se 90.07 9.00 91.93 3e0.0 t

.300 90 99 646 es let 13 0.00 999.9%

3.93 98.31 30.?O O 90 11.90 980.0 t

.eOO 33.g1 tes de see et 0 00 190.99 9 Se 90.00 90.99 9.30 17.91 Sec.0 t

.500 94.98 644.84 689.99 0.89 0 790.00 3 et TS.83 30.?S 0.00 94.03 340.0 0

.000 98.88 See.de 900.99 9.00

?33.06 3 43 Tt.99 90.?9 9.00 te.ge 9e0.0 t

.100 31.9%

See de 990.00 9 80 134.91 3.86 99.31 90 89 0 00 GS to 360 0 t

.900 94 99 999.93 193.30 9 90 T30.50 3 00 TS.Se 30.94 0.00 98.31 380.0 t

.900 33.90 999 88 9H.00 0 80 130.04 3.54 99.9%

30.93 0.90 48.83 340.0 9

.999 90.04 909.33 9M 83 0.90 189.00 3.8%

96.33 90.98 9.00 #8 99 980.0 t

9.999 SS.TT tet.e0 960.9%

0.00 998.98 3.36 94.81 31.13 0.00 18.91 340.0 t

3.999 13.91 943.te Set.at 0.00 943.98 3.e9 96. H 30.97 9 30 99.80 940.0 9

3.999 31.33 983.30 968.99 0.00 999.99 3.??

90.03 St.39 9.00

99. 94 980.0 t

4 999 93 90 983.30 963.95 0.00 968.75 3.03 99.?3 39.98 0.00 99.33 980.0 t

9.999 M. 90 983.

944.01 0.00

??t e?

3.97 99.87 St.37 9.00 99.30 980.0 t

6 999 31.01 983.

944.03 0 00 1,14.03 3 89 99.33 St.99 0.06 99.37 380 C

(

t T. 9n M.u m.M SM.n

.. 0 w ?

3 90 u.M 89.33 9..O w.43 H0. 0 4

9 em 98.st SH. 33 u3.o e.eO evt.33 3.M TS.oi 39.30 e e0 w.83 940 0 1

9 9 999 94.05 901.97 643.00 0 00 988 et 3.00 79.43 St.8?

9 90 46.13 980 0 1

9 48.999 900.90 0.00 843

?S.?S 94.91 340.0 90.e.s 199 99, 93,.30 3.90 St.t3, e.00 9

om 89 e tot to m1 e0

.M 9..

,. 93 St.0 e 0

9. 86 980 0 8

30 000 17.48 901.90 138.11 0 00 SST.54 3.98 94.33 St.00 0.00 96.4% 340.0 3

.. 0

.0 33 9,

.M.6

...O m t.34 90

,8 9.

W 96

.. 0

.,0 W.0 a

3 000 8.t?

2388 59 439.83 0 90 9997 98 95 90.07 90.90 9.90 90.?S 980.0 l

.M0 v.M m e 97 m to e oO 9003 u

.M nn MM e.e0 u.n ve0 0 3

900 9.01 338e.91 839.98 0.00 3006.30

.33 98 Se 39.00 0.00 #8.00 U40.0 3

.e00 11.90 BM4 91 639.94 9 90 3001.93

.38 10.4*

St **

9.e0 93 08 180.0 3

.000 93.D?

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3 9.m e.e0 tom. S t 9

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t um s?307.3 e

am

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S tM.

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Fig. B-5 Calculated results for Sample Problem 2.

23

\\

APPENDIX C DECAY ENERGY PRODUCTION 'FOR RADIOLYSIS l

i that This appendix describes the decay energy production source equations are the bases for the B, R +6, and HI expressions in Eqs. (4) and (5) used for y

7 l

The decay energy production source the determination of water radiolysis.

equations used are-5, the fission product decay energy production given by Eq. (2) of Ref.

1.

239 given by Eq. (3) of heavy element decay energy production due to U 2.

the Ref.

5, 239 given by Eq. (4) of the heavy element decay energy production due to Np 3.

Re'.

~, and I31 through 1135, which provides the 4.

the decay energy production due to I HI expression.

to be the First, the total decay energy production (E,g) is calculated g

The sump water decay energy production of the first three items above.

sum tern E +g then is determined by subtracting the energy production due to iodin is simply y

The core water decay energy production tern By (H ) f rom the total.

I The above operations can be expressed in equation form by one-half of E +g.

y R +g = Egog - HI y

y = 0.5 x B g = 0.5 x Egog - 0.5 x HI.

R y

hydrogen production is The combined energy available (H,,ti) for radiolytic then H,,11 = E +g + By + HI y

"Itot - RI + 0.5 x Hgot - 0.5 x HI + HI

.x H,g - *5xHI.

=.

g 24

i This shows that the COGAP decay energy production available for radiolytic hydrogen generation is about 50% greater than the actual generation presented I is 1 to 10% of Ecot). However, the energy used for in Raf.

5 (the H radiolysis is modified by the user supplied fractions that determine the energy 1

absorbed, as shown in the input description in Appendix A.

0 25

e t

~

DISTRIBUTION l

Copies 333 Nuclear Regulatory Commission, R4, Bethesda, Maryland 2

Technical Information Center, Oak Ridge, Tennessee i

48 Los Alamos National Laboratory, los Alamos, New Mexico 383 1

t a

f 6

9'

?

I 6

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,Q

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e UREGCR5847 U.S. NUCLEAR REGULATORY COMMIS$10N BIBLIOGRAPHIC DATA SHEET LA-9459-MS

.E AND SUBTITLE (Asa Veeme 40., sf ap,rapreew/

2. t&eare staitJ COGAP: A NUCLEAR POWER PLANT CONTAINMENT HYDROGEN CONTROL SYSTEM EVALUATION CODE 3 REciP ENT S AccES$ ion NO.

7. AUTHORISI

6. DATE REPORT COMPLETED R.G. Gido

"$n'e" I'52 9 PERFORMING ORGANIZATION NAME AND MAILING ADORESS isaciver le Coer)

DATE REPORT ISSUED woNTH lVEAM Los Alamos National Laboratory January 1983 P. D. Box 1663

$ a,. a,4, Los Alamos NM 87545 e a mes:

12. SPONSORING ORGANIZ ATION NAME AND MAILING ADDRESS Isacher le coarJ p

Division of Systems Integration Office of Nuclear Reactor Regulation

" ' " " " ~

U. S. Nuclear Regulatory Commission Washington, DC 20555 FIN A7105 13 TYPE OF REPORT Pt A.DD Cove mE D flec4se,, sees)

Technical

15. SUPPLEMENTARY NOTES 14 fles,e avets

16. ABSTRACT 200 scores or sauf The accounting of containment gas concentration following a loss-of-coolant accident is important in the safety evaluation of hydrogen combustible-gas 1

control systems for nuclear power plants. The COGAP code provides such accounting including the effects of (1) the reaction of zirconium and water; (2) radiolysis of core and sump water; (3) corrosion of zinc, aluminum and copper; (4) recirculation.between compartments; (5) hydrogen recombiners; (6) purging; (7) nitrogen addition; and (8) atmospheric steam. Controls are available to detemine when option, are initiated; for example. the hydrogen recombiner can be started when the hydrogen concentration reaches a user-specified value.

17. KEY WORDS AND COCUMENT ANALYSIS 17e DESCRIPTORS

DENTIFIERS OPEN.ENDE D TERMS ri NO Or PAcc5 is gegt;v,ggrass,,,.,v/

is AvAiLAs LiTY STATEMENT Unlimited 2o gy3ggru,,,ri 22 price

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.041 1000 10.

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SA, EITH PEC(MBINERS, 2510F TOTAL DECAT'ENERGT FROM SOLIDS TO THE StMP i

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COL-S 10 15 20 25 30 35 40 45 50 53 60 65 70 75 90 1

01/29/19 99:07:59 SUN SAN ONOFPE DBE, MO RECOMBINERS

( CASE 1) 0

- - INPUT DATA ----

( CASE 1)

O CONTROL PAPANETERS ICON (1)

ICON (2)

ICON (3)

ICON (4)

ICON (5)

ICON (6)

ICON (7) 1 4

0 1

1 CON (1)

COM (2)

CON (3)

COM (4)

COM (5)

DAYS DAYS PEPCENT DAYS SEC 10.00 0.00 2.00 0.00 120.00 0

PARAMETERS FOR EACH VOLONE VOLUME YOLUME TtyfAL PRES P.N2 PPES TEMPERATURE REL NUM.

PUR. RATE FRC N2 AD. RATE NO.

CUFT PSIA PSIA F

PS174/PSAT CFM FRACTION M

1 2305000.00 14.700 0.0000 120.0 0.50 0.00 100.00 0.00 r

0, R. C001 ANT PARAMETERS

'. 40.00 3560.00 PIACTOR OPEPATING TIME (RRS)

REACTom PONER (MNT)

=

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=

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0.00 H2 DISSOLVED IN PRI. COOL.(LB-MDLE)= nan C(H) IN COPE SOLUT10N(M012/100 EV)*

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=

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Jan 29199916:08 MS.gg Page 5 '

ICON (1)= 1 NO PDPJ.*. AND NO R2 RECOMBINER

=2 NITR PURCE

=3 NITN H2 RECCMBINER

=4 NITH PASSIVE AUTOCATALTTIC RECOMBINER (PAR)

ICON (2)= 0 1AST CASE OR ONLT ONE CASE

1 MULTIPLE CASE

- - P1DTTING NOT AVAIIABLE(9/80/***

ICON (3)= 0 NO PIJDT

1 PLOTTIIeG M2 GENERATION DOE TO RADIOLTSIS PLOTTIleG N2 CENERATION DOE TO METAL CORROSION PLOTTING M2 CENERATION DOE TO EM-M20 REACTION PLOTTING TOTAL R2 GENERAtl0N

=2 PLOTTING R2 mr.w a nTION III EA. VOL. *

=3 PLOTTING N2 CONCENTRATION IN EA. VOL.

=4 PLOTTING 02 CONCENTRATION IN EA. VOL.

= 10 ALL THE AROVE CASES NILL BE PIDTTED

- - PIDTTIteG MOT AVA!!ABLE(9/80)***

ICON (4 ) =

NUMBER OF VotDMES 1 CON (5) =

NUMBER OF JUNCTIONS ICOM(6)= 0 THE AVERAGE VAIDE OF ALL C019AR7ENT R2 CONCENTRATION NILL BE USED

K Tile It2 CONC. IN X CCMPT. NILL BE USED ICON (7)= 0 WO STEAM

=1 NITH STEAM BASED ON SATURATICIt TEMP CON (1)

PROBLEM END TITE. DAYS

=

TIME AT NMICH PURGING OR R2 RECCISINER CON (2)

=

STARTS, DATS H2 CONCENTRATION AT NRICH PORGING OR R2 CON (3)

=

RECOMBINER STARTS TIME AT NNICH THE R2 KCIRCOIATION FAN CON (4)

=

STARTS, DATS DURATION FOR M2 RE11ASED FROM ER-H2O CON (5)

=

MAT (1) 182 CENERATION MATERIALS

=

=1 ALUMINUM

=2 EINC

=3 COPPER 0

NOTES - THIS LEGEND NILL BE PRINTED FOR TNE FIRST CASE ONLT.

VOL.NO. 1 MOUSES REACTOR COOL. STS.

INPUT 0.0 FOR PARTI AL N2 PRESSURE, ONIESS THE CONTAINMENT IS PRESSURIZED NITH N2 INITIALLT.

I:2 LESS THAN 0. AT TIME =

0.0002 IN Y = 1 1

01/29/19 99:08:02 SUte SAN ONOFRE DBE,100 RECCDtBINERS

( CASE 1) 0

OUTPUT DATA ----

( CASE 1)

VOL TIME

----- --- LB -MOLE S

--- PER-CENT --

PRES. TEMP.

Eo.

DATS H2 N2 O2 STEAM TOTAL M2 N2 02 STFRt PSIA F

1 0.000 0.00 4059.04 1075.74 313.70 5448.48 0.00 74.50 19.74 5.76 14.70 120.0 1

0.100 5.83 4059.04 1078.25 4277.23 9420.35 0.06 43.09 11.45 45.40 29.22 206.9 1

0.200 9.58 4059.04 1079.80 3313.80 8462.22 0.11 47.97 12.76 39.16 25.73 193.6 1

0.300 12.71 4059.04 1081.06 2845.39 7999.21 0.16 50.75 13.52 35.58 24.03 185.9 1

0.400 15.45 4059.04 1082.16 2432.50 7509.15 0.20 53.48 14.26 32.05 22.33 178.2 1

0.500 17.89 4059.04 1083.14 2010.05 7230.13 0.25 56.14 14.98 28.63 21.21 170.6 1

0.600 20.11 4059.04 1084.04 1753.26 6916.46 0.29 58.69 15.67 25.35 20.04 162.9 1

0.700 22.15 4059.04 1084.88 1477.62 6643.69 0.33 61.10 16.33 22.24 19.01 155.2 1

0.800 24.03 4059.04 1085.67 1238.92 6407.65 0.37 63.35 16.94 19.33 18.11 147.6 1

0. 900 25.77 4059.04 1086.41 103'.21 6204.43 0.42 65.42 17.51 16.65 17.31 139.9 1

1.000 27.38 4039.04 1087.13 85%.85 6030.40 0.45 67.31 18.03 14.21 16.61 132.3 1

2.000 40.17 4059.04 1093.17 614.34 5806.72 0.69 69.90 18.83 10.58 15.64 119.2 songs.ou4

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16.0000 0.00 45503.84 4577.80 50081.65 1

17.0000 0.00 47112.71 4726.58 51839.28 1

18.0000 0.00 48678.71 4875.35 53554.06 1

19.0000 0.00 50204.47 5024.12 55228.59 1

20.0000 0.00 51692.27 5172.89 56865.16 1

21.0000 0.00 53144.18 5321.67 58465.85 1

22.0000 0.00 54562.08 5470.44 60032.52 1

23.0000 0.00 55947.68 5619.21 61566.89 1

24.0000 0.00 57302.55 5767.*8 63070.53 1

25.0000 0.00 5e628.15 5916.75 64544.91 1

26.0000 0.00 59925.85 6065,53 65991.38 1

27.0000 0.00 61196.92 6214.30 67411.22 1

28.0000 0.00 62442.54 6363.07 68805.61 1

29.0000 0.00 63663.82 6511.84 70175.67 1

30.0000 0.00 64861.83 6660.62 71522.45 3

01/29/19 99:08:02 SUN SAN ONOFRE DRE WITR REC 0191NERS

( CASE 2) 0

--- INPUT DATA ---

( CASE 2)

O CONTROL PAPAMETERS ICON (1)

ICON (2)

ICON (3)

ICON (4)

ICON (5)

ICON (6)

ICON (7) 3 4

0 1

1 COM (1)

COM (2)

CON (3)

COM (4)

CON (5)

DAYS DAYS PERCENT DAYS SEC 30.00 0.00 2.00 0.00 120.00 0

PARAp8tTERS FOR EACH VOLUME VOLUME VOLUME TOTAL PRES P.N2 PRES TEMPERATURE REL.

HUM.

POR. RATE FRC N2 AD. RATE No.

CUFT PSIA PSIA F

=PSTM/PSAT CF7(

FRACTION CFM I

270 % 00.00 14.700 0.0000 120.0 0.50 0.00 100.00 0.00 9

R. COOLANT PARAMETERS REACTOR POWER iMerr) 3560.00 REACTOR OPERATING TIME (HRS) 17500.00

=

ZjRCONIUM WFIGHT (LBS)

=

0.00 ZIR-WATER REACTION. PER-CENT 0.00

=

02 DISSOLVEt> IN PHl. COOL.(LB-MOLE)=

0.00 R2 DI$ SOLVED IN PRt. COOL.(LB-MOLE)= nan CtN) IN CORE SOLUTIONtit)LE/100 EV)*

O.40 CtH) IN SUMP SOLUTIONtMOLE/100 EV)=

-0.40 1.75 0/0 MPG ABS. BY COPE WATER

=

10.00 0/0 SOLID NRC ABS. BY SUMP WATER

=

O/0 10 DINE NRG ABS. BY SUMP WATER =

40.00 BLOWDOWN DURATION (SEC) 20.00

=

1 01/29/19 99:08:02 SUN SAN ONOFRE DBE WITN RECOMBINERS

( CASE 29 0

INPUT DATA ----

( CASE 2)

[

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1 9.0000 0.00 32698.15 3504.78 36202.93 1

10.0000 0.00 34736.41 3673.24 38409.65 1

11.0000 0.00 36690.46 3832.28 40522.74 I

12.0000 0.00 38571.46 3982.71 42354.18 1

13.0000 0.00 40387.56 4131.49 44519.05 1

14.0J00 0.00 42145.09 4280.26 46425.35 1

15.0000 0.00 43849.13 4429.03 48278.16 1

16.0000 0.00 45503.84 4577.80 50081.65 1

17.0000 0.00 47112.71 4726.58 51839.28 1

18.0000 0.00 48678.71 4875.35 53554.06 1

19.0000 0.00 50204.47 5024.12 55228.59 1

20.0000 0.00 51692.27 5172.89 56865.16 1

21.0000 0.00 53144.18 5321.67 58465.85 1

22.0000 0.00 54562.08 5470.44 60032.52 1

23.0000 0.00 53947.68 5619.21 61566.89 1

24.0000 0.00 57302.55 5767.98 63070.53 1

25.0000 0.00 58628.15 5916.75 64544.91 1

26.0000 0.00 59925.85 6065.53 65991.38 1

27.0000 0.00 61196.92 6214.30 67411.22 1

28.0000 0.00 62442.54 6363.07 68805.61 1

29.0000 0.00 63663.82 6511.84 70175.67 1

30.0000 0.00 64861.83 6660.62 11522.45 1

01/29/19 99:08:06

$UN SA, MO RECOMBINERS, SOLIDS GIVE 10% OF TOTAL DECAT ENERGY TO SUMP

( CASE 3) 0

INPUT DATA ----

( CASE 3)

O CONTROL PARAMETERS ICUN(1)

ICON (2)

ICC4t (3)

ICON (4)

ICON (5)

ICON (6)

ICON (7) 1 1

0 1

1 CON (1)

CON (2)

COM (3)

CON (4)

COM (58 DAYS DAYS PERCENT DAYS SEC 30.00 0.00 2.00 0.00 120.00 0

PARAMETERS FOR EACH VOLUME VOLUME VOLUME TOTAL PRES P.N2 PRES TEMPERATURE PEL.

PJM.

PUR. RATE FRC N2 AD.PATE NO.

CUFT PSIA PSIA F

PS?M/PSAT CF74 FRACTION Cfl9 1

2305000.00 14.700 0.0000 120.0 0.50 0.00 100.00 0.00 0,

R. COOLANT PARAMETERS 17500.00 PEACTOR PONER 08WT) 3560.00 REACTOR OPERATING TIME (HRS)

=

0.00 EtR-NRTER REACTION, PER-CENT 0.00 ZIPC041UN NEtGHT (LBS)

=

02 DISSOLVED IN PRI.C001..(LB-MOLE)=

0.00 R2 DISSOLVED IN PRI.C00L.(LD-M012)= nan C(R) IN CORE SOLUT10N(MOIX/100 EV)=

0.40 C(F) IN SUMP SOLUTION (MOLE /100 EV)=

0.40

=

18.10 O/0 NRG ABS. BY CORE NATER 0.00 0/0 SOLID NRC ABS. BY SUMP WATER

=

20.00 O/0100!NE MRG ABS. BY SUMP WATER =

75.00 BLONDONN IRPATION (SEC)

=

1 01/29/19 99:08:06 SUN SA, NO RECOMBINERS, SCLIDS CIVE 10% OF TOTAL DECAY ENERGT To SUMP r

( CASE 3) l 0

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( CASE 3)

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01/29/19 99:08:10 SUN SA, NITR RECUMBIN., SOLIDS GIVE 10% OF TOTAL DECAY ENERGY TO SUMP

( CASE 4) 0

INPUT DATA ----

( CASE 4) 0 (XNf?ROL PARAMETERS TCON (1 )

ICON (2)

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=

1 01/29/19 99:08:10 SUN SA, NITH RECOMBIN., SOLIDS GIVE 10% or TOTAL DECAY ENERGY TO SUMP

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ML20203F551

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ML20203F551

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