ML20199G714

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Rev 20 to Surveillance Procedure SP-730, Explosive Gas & Storage Tank Monitoring Chemistry Surveillance Program
ML20199G714
Person / Time
Site: Crystal River Duke Energy icon.png
Issue date: 01/01/1998
From:
FLORIDA POWER CORP.
To:
Shared Package
ML20199G701 List:
References
SP-730, NUDOCS 9802040329
Download: ML20199G714 (14)


Text

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Rev. 20 Effective Date /-/- 9[

SURVEILLANCE PROCEDURE '

SP 730 FLORIDA POWER CORPORATION CRYSTAL RIVER UNIT 3 EXPLOSIVE GAS AND STORAGE TANK MONITORING CHEMISTRY SURVEILLANCE PROGRAM I

APPROVED BY:

Interpret tio { tact

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(SIGNAT)tREONFILE)

DATE: ////9f' l_

lNTERPRETATION CONTACT: Manager Nuclear Chemistry

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- JABLE OF CONTENTS SECT 10N 1.0 E831 2.0 PURPOSE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 REFERENCES 2.1 ................ . . . . . . . . . 1 2.2 JMPLEMENTING REFERENCES . . ......... ... 1 REVELOPMENTAL REFERENCES 2.2.1 Off. Site Dose Calculatio.............. 1 2.3 100CM) References ...........

CNIS EQUIPMENT

. . n NanuAl 1 10

................... 2 PER$QHMEL_JN00CTR] NATION 3.1 3.2 lETP0lNTS . .

. .... .............. 2

3.3 DESCRIPTION

. . . . . .. .. ... .. .. .. ... .. .. .. .. ... .. 2 DEFINITIONS . . . . . . 3 3.4 RESPON5fBILITIES ............. 3 3.5 3.6 LIMITS AND PRECAUTIONS..................

3 -

3 3.7 ACCEPTANCE CRITERIA . . . . . . . . . . . . . . . 4 PREREQUISITES . . .~ . . . . . . . ......... 5 4.0 INSTRUCTIOH1 ......

4.1 4.2 MUT-1 . . . . . .................. 5 4.3 WDT-1A ..................

................. 5 WDT-1B 4.4 WDT-lC ................. ..... . . ,

6 7

................... ... 8 110 FOLLOW-UP ACTIONS 5.1 . . . . ,_. . . . . . . . . . . ... . . . .

Bil19 RATION INSTRUCTIONS .

9 5.2 CONTINGENCIES . . . . . . . . . . . . . 9

........ 9

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t SP-730 Rev. 20 Page i j

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,,s 1.0 PURP_Qi[

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l This procedure directs the sampling and analysis requirements for the explosive gas and storage tank systems defined by'its associated programs.

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2.0 REFERENCES

2.1 IMPLEMENTING REFERENCES l 2.1.1 AI-1500, Conduct of Chemistry and Radiation Protection Department l 2.1.2 CHA 115A, Gas Chromatography Varian 3400CX 2.1.3 CH 230, Gamma Spectroscopy and Operating Instructions for the Chemistry Computer System 2.1.4 CP-lll, Initiating and Processing of Precursor Cards and Problem Reports 2.1.5 CH 518A, Waste Gas Decay Tank 1A Sampling 2.1.6 CH-518B, Waste Gas Decay Tank 1B Sampling 2.1.7 CH-518C, Waste Gas Decay TanLIC Sampling .

2.1.8 CH 5180, Automatic Sampling of the In-Service Waste Gas Decay Tank 2.1.9 CH 611B, Makeup Tank Gas Space Sampling 2.1.10 SP 442, Speciti Conditions Surveillance Plan-2.2 QIVELOPMENTAL REFEREMQIl l 2.2.1- Off-Site Dose Calculation Manual (0DCM1 References Applicable Sury. Perf. Requirements Sury.

References Freq.

Durina Modes Durino Modes Frea. Notes ODCH 2.16.a.1 All modes All modes ODCM 2.16.a.2 lx/4hr. (1)

All modes All modes D ODCM 2.17.1 All modes (2)

All modes W ODCM 2.17 All modes All modes D ODCM 2.18.1 All modes All modes Continuously ODCM 2.18,a All modes All modes H >4% (6)

ODCM 2.lB.b All modes All modes H,2>4% (7)

SP-730 Rev. 20 Page 1

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. . , Frequency Notes l

,1) When Hydrogen /0xygen monitors are inoperable during DEGASSING operations.

(2) When Hydrogen /0xygen monitors are inoperable during other operations.

(3) The Quantity of radioactive material in each Waste Gas Decay Tank shall be determined to be <39000 Curies (censidered as XE 133) whenever radioactive material is added to the tank.

(4) The Quantity of radioactive material in each Waste Gas Decay

' Tank shall be determined to be <39000 Curies (considered as XE 133) during primary coolant system DEGASSING operations, s

(5) The concentrations of hydrogen and oxygen in the in service Waste Gas Decay Tank shall be continuously monitored with the '

hydrogen and oxygen monitors required OPERABLE by Specification 2.16 or by sampling in accordance with Specification 2.16.a.

(6) Whenever the concentration of hydrogen in t / Waste Gas Decay Tank is greater than or equal to 4% by volue and the -

i concentration of oxygen in that Waste Gas Decay Tank is greater than 2% by volume, but lest than 4% by volume, without delay begin to reduce the oxygen concentration to within its limit.

(7) Whenever the concentration of hydrogen in any Waste Gas Decay Tank is greater than or equal to 4% by volume and.the concentration of oxygen in that Waste Gas Decay Tank is greatet '

than or equal to 4% by volume, immediately sus)end additions of waste gas to that Waste Gas Decay Tank and wit 1out delay begin to reduce the oxygen concentration to within its limit.

2.3 CMIS E001PMENT WDT-1A, WDT 18, WDT-lC, WDGA-1, MUT 1 3.0 PERSONNEL INDOCTRINATION 3.1 ETPOINTS None f

SP-730 Rev. 20 Page 2

- 3.2 M5CRIPTION 3.2.1 The Waste Gas Decay Tanks (WGDTs) provide a location for the safe collection and storage of gases evolved from the Reactor Coolant.

3.2.2 Volumetrically, the principal gases are hydrogen and nitrogen.

Radioactive fission products and activated dissolved gases contribute a very small fraction of the total volume.

-3.2.3 The WGDT's may be sequentially monitored for hydrogen and oxygen l mixtures automatically by the Waste Gas Analyzer (WDGA 1). The in service WGDT will normally be sampled continuously.

l 3.2.4 TheMakeupTank(MUT-1)actsasareceiverforreactorcoolant(RC) letdown, seal return system, makeup and chemical additions.

3.3 DEFINITIONS None 3.4 RESPONSIBILITIES

! 3.4.1 The Manager Nuclear Chemistry is responsible for the content of this procedure, shall act as Interpretation Contact for any. questions regarding intent, and has final authority regarding the procedure.

3.5 LINITS AND PRECAUTIONS l' 3.5.1 The maximum extension time to perform this surveillance should not exceed 125Y. of the time interval.

l 3.5.2 For work located in Radiation Control Areas, due consideration must be given to the ALARA Program. This may result in a determination l that special preparations or precautions are necessary, 3.5.3 This procedure may result in the generation c F rad 9tt *e waste.

Plan and perform this procedure such that rajioactw v.. ,te generation is reduced to a minimum.

SP.730 Rev. 20 Page 3

3.6 ACCEPTANCE CRITERIA 3.6.1 The HUT 1 Upper Limit (UL) for Principal Gamma Emitters (Considered asXe133)is122uti/cc.

3.6.2 1E UL for MUT 1 is exceeded, QB MUT 1 is unavailable for sampling, E the in service WGDT and any WGDT which has been added to since last performing SP 730 shall be sampled and total curie content determined.

3.6.3

. (3.QE40(imMperWGDT)f1 E6 VN 122 80 = 0 00 M 11294 2.83E4 @

WGOT, FT',

Since the MUT is the principal and most concentrated radioactive '

material addition to the WGDTs, it can be determined that the WGDT-inventory will remain below 39,000 Ci if MUT-1 concentration remains below122pCi/cc.

3.6.4 IE Ut for MUT is exceeded, 0.8 MUT 1 is unavailable for. sampling, '

IllEli the in service WGDT and any WGDT which has been added to since last performing SP 730 shall be sampled and total curie content determined.

3.6.5 The Waste Gas Decay Tank upper limit for radioactivity (Considered asXe133)is39000 Curies.

3.6.6 The Waste Gas Decay Tank u)per limit for Hydrogen concentration upper limit 4% by volume wienever the Oxygen concentration 22% by volume.

3.6.7~ The Waste Gas Decay Tank upper limit for Oxygen concentration upper limit 2% by volume whenever the Hydrogen concentration 24% by volume.

3.6.8 IE the hydrogen concentration is greater than or equal to 4%,

A!!D the oxygen concentration is greater than 2% but less than 4% by volume.

IllEE NOTIFY Operations to reduce oxygen concentration immediately.

SP-730 Rev. 20 Page 4 i l

.. 3.6.9 If the hydrogen concentration is greater than 4%,

680 the oxygen concentration is greater than or equal to 4% by .

volume.

181H NOTIFY Operations to suspend waste gas additions to the affected tank and have Operations reduce oxygen concentration immediately.

3.7 PREREQUISITES l None 4.0 INSTRQG119t[1 4.1 MMI:1 '

4.1.1 If scheduled, IHIH OBTAIN a sample of MUT 1 gas space in accordance with Cll-611B, Makeup Tank Gas Space Sampling. -

/ /

Initial / Date / Time NOTE: The gas gamma sample must start counting within.'30 minutes of sample tLme.

4.1.2 PERFORM a gas gamma analysis to determine Xe 133 equivalence:

1. RECORD the highest WGDT pressure: psig
2. LOG ON the chemistry computer system node CRGAMA, CRCHEM, or CHIP.
3. SELECT PRIMARY COUNTING MENU.
4. SELECT SP-730 COUNT MENU.
5. SELECT MV CE-118 MUT 34GS SP-730,
6. ENTER required sample data and start the count.
7. LOG OFF the system.

The acceptable range for MUT-1 Xe-133 equivalence is s 122 pCi/cc.

MUT-1 Xe-133 equivalence = pCi/cc

/

Initial /Date SP-730 Rev. 20 Page 5

9 m, 4.2 WDT-1A i'! .

4.2.1 Jf scheduled,

. M OBTAIN a sample of WDT 1A in accordance with CH 518A, Waste Gas Decay Tank 3A Sampling, Section 4.2, WDT 1A Grab Sample.

/ /

Gas Gamma Initial / Date / Time

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Gas Chramatography Initial / Date / Time NOTE: The gas gamma sample must start counting within 30 minutes of sample t' me.

4.2.2 If scheduled, It[ffi PERFORM a gas gamma analysis to determine Xe 133 equivalence:

1. RECORD WDT 1A pressure: psig
2. LOG ON the chemistry computer system node CRGAMA, CRCHEM, or '

CHIP.

3. SELECT PRIF.r.; COUNTING MENU.
4. SELECT SP-7.'.l, COUNT MENU.
5. SELECT WD CE-Il2 A WGDT 34GS SP-730.
6. ENTER required sample data and start the count.
7. LOG OFF the system. _ .

The acceptable range for WDT-1A Xe 133 equivalence is s 39,000 Ci.

WDT-1A Xe-133 equivalence = Ci f

/

Initial /Date 4.2.3 If scheduled, IllEli PERFORM a gas chromatography analysis in accordance with CHA-IISA, Gas Chromatography - Varian 3400CX, to determine hydrogen and oxygen concentrations.

The acceptable range for oxygen concentration is s 2.0 % whenever hydrogen concentration is ;t 4.0 %.

WDT-1A hydrogen concentration -  %

WDT-1A oxygen concentration -  %

/

Initial /Date 8

SP-730 Rev. 20 Page 6

4.3 WDT-18 4.3.1 If scheduled, IH G OBTAIN a sample of WDT-1B in accordance with CH-51BB, Waste Gas Decay Tank 3B Sampling, Section 4.2, WDT-1B Grab Sample.

/ /

Gas Gama In'itial/ Date / Time

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Gas Chromatography Initial / Date' / Time-NOTE The gas gama sample must start counting within 33 minutes of sample t' me.

4.3.2 IE scheduled, Id@ PERFORM a gas gamma analysis to determine Xe-133 equivelence:

, 1. RECORD WDT-10 pressure: psig

2. LOG ON the chemistry computer system node CRGAMA, CRCHEM, or '

CHIP.

3. SELECT PRIMARY COUNTING MENU.
4. _ SELECT SP-730 COUNT MENU.
5. ,_ SELECT WD CE-Il3 B-WGDT 34GS SP-730, 6.

7._ ,_ LOG OFF the system. ENTER required sample data and start the count.

The acceptable range for WDT-1B Xe 133 equivalence is s 39,000 Ci.

WDT-1B Xe-133 equivalence - Ci

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Initial /Date 4.3.3 If scheduled, iller PERFORM a gas chromatography analysis in accordance with CHA IISA, Gas Chromatography - Varian 3400CX, to determine hydrogen and oxygen concentrations.

The acceptable range for oxygen concentration is s 2.0 % whenever hydrogen concentration is ;t 4.0 %.

WDT-1B hydrogen concentration -  %

WDT-1B oxygen concentration -  %

/

Initial /Date SP-730 Rev. 20 Page 7

l 4.4 WDT-1C 4.4.1 E scheduled, M E OBTAIN a sample of WDT-1C in accordance with CH 518C, Waste Gas Decay Tank 3C Sampling, Section 4.2, WDT-1C Grab Sample.

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Gas Gamma Initial / Date / Time

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Gas Chromatography Initial / Date / Time NOTE: The gas nanna sample must start counting within 30 minutes of samp'e t'me. '

4.4.2 E scheduled, JEfB PERFORM a gas gamma analysis to determine Xe-133 equivalence:

1. RECORD WDT-1C prescure: psig
1. LOG ON the chemistry computer system node CRGAMA, CRCHEM, or
  • CHIP.
3. SELECT PRIMARY COUNTING HENU.
4. SELECT SP-730 COUNT MENU.
5. SELECT WD CE-114 C-WGDT 34CE $P-730.
6. ENTER required sample data and start the count.
7. . LOG OFF the system. . _ _ .

The acceptable range for WDT-10 Xe 133 equivalence is s 39,000 C1.

WDT-1C Xe-133 aquivalence - Ci

/

Initial /Date 4.4.3 E scheduled, M S PERFORM a gas chromatography analysis in accordance with CHA-115A, Gas Chromatography - Varian 3400CX, to determine hydrogen and oxygen concentrations.

The acceptable range for oxygen concentration is s 2.0 % whenever hydrogen concentration is it 4.0 %,

WDT-1C hydrogen concentration =  %

WDT-1C oxygen concentration -  %

/

Initial /Date SP-730 Rev. 20 Page 8

5.0 F0LLOW-UP ACTiggi l 5.1 RESTORATION INSTRUCTIONS 5.1.1- System restoration instructions are provided in the applicable sampling procedures.

5.1 CONTINGENCIE5 5.2.1 NOTIFY the following personnel of any results outside the limits specified in Section 3.6 and generate a FUR in accordance with Al-1500.

Chemistry Supervision

  • SS00 5.2.2 Record on the FVR any action taken to correct and monitor the out-ofspecificationcondition(i.e.,increasenitrogenconcentration.
  • transfer portion to another WGDT or increased sample frequency per the requirements of SP-442).

5.2.3 E the Surveillance Procedure cannot be completed in the required l time interval outlined in Section 3.5, E inform Chemistry Supervision, AND generate a FUR and PC in accordance with Al-1500 End CP-111.

5.2.4 E a limit is exceeded in Step 3.6.5, M DOCUMENT per the requirements of CP 111.

5.2.5 E a limit is exceeded in Step 3.6.8, M GENERATE a FUR in accordance with AI 1500 5.2.6 E a limit is eneeded in Step 3.6.9, M DOCUMENT per the requirements of CP-111.

SP 730 Rev. 20 Page9(LASTPAGE)

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4 ATTACHMENT B EXCERPTS FROM CRYSTAL RIVER UNIT #3 OFFSITE DOSE CALCULATION MANUAL e

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, CONTROLLED COP (

CRYSTAL RIVER - UNIT #3 0FF-SITE DOSE cat.CULATION MANUAL 1 <

e APPROVED BY: A Manager /suclear chemistry CATE: ldl2 2/90

/ 'I

\ REVI5!ON: 23 APPROVED BY: Interpretation Contact

.L.E b d ChemRad Specialist II

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  • d WASTE GAS DECAY TANKS 2.17 The quantity of radioactivity contained in each Waste Gas Decay Tank shall be limited to less than or equal to 39000 curies (considered as Xe 133).

APPLICABILITY: At all times.

ACTION:

a. With the quantity of radioactivity in any Waste Gas Decay Tank exceeding the above limit, immediately suspend all additions of radioactive material to that tank, and w' thin 48 hours5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> reduce the tank contents to within its limit.

SURVETilANCE REQUIREMENTS 2.17.1 The quantity of radioactive material contained in each Waste Gas l Decay Tank shall be determined

  • to be within the limit at least once-per 7 days whenever radioactiva materials are being added to the tank, and at least once per 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> during primary coolant system DECASSING operations.

Determining that each waste gas decay tank is in compliance with the limit may be done by a method other than direct sampling of the tank provided it is in accordance with an approved procedure.

OFF-SITE DOSE CALCULATION MANUAL Page 46

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