ML20132B104

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Effluent & Waste Disposal Semiannual Rept,Jan-June 1985
ML20132B104
Person / Time
Site: Crane Constellation icon.png
Issue date: 06/30/1985
From:
GENERAL PUBLIC UTILITIES CORP.
To:
Shared Package
ML20132B073 List:
References
NUDOCS 8509260105
Download: ML20132B104 (16)
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ATTACHMENT 5 (4410.85-L-0175) 12 Pages EFFLUENT AND WASTE DISPOSAL SEMI ANNUAL REPORT January 1, 1985 - June 30, 1985

. SUPPLEMENTAL INFORMATION FACILITY TMI-Unit 2 (including EPICOR-II } ICENSEE DPR-73-320 1.

Regulatory L1=its a.

Fission and activation gases:

^

ech Specs, c.

Pa t c ates, half-lives) 8 days:

[

3 d.

Liquid effluents:

2.

Maximum Permissible Concentrations Provide the MPCs used in determining allowable release rates or cencentrations, a,

Fission and activation gases:

cu ates, half-lives > 8 days:

, art 0, Appen m B ar d.

Liquid effluents:

3.

Average Energy Provide the average energy (E) of the radionuclide mixture in releases of fission and activation gases, if applicable 0.253 MeV (Kr-85) 4.

Measurements and Approximations of Total Radioactivity Provide the methods used to measure or approximate the total radioactivity in effluents and the methods used to determine radionuclide composition.

Fission and activation gases:

Ge(Li) Spectrometry,LiquidScintillation a.

b.

Iodines:

Ge(Li) Spectrometry c.

Particulates:

Ge(Li) Spectrometry, Gas Flow Proportional Countir d.

Liquid effluents:

Ge(Li) Spectrometry, Liquid Scintillation 5.

Batch Releases Provide the following information relatir.g to batch releases of radioactive materials in liquid and gaseous effluents.

1985 1985 A.

Liquid 1st Quarter 2nd Quarter l '. Number of batch releases:

51 39 2.

Total time period for batch release:

f4/A ft/A 3.

Maximum time period for a batch release:fi/A fi/A 4.

Average time period for batch releases: ft/A ft/A 5.

Minimum time period for a batch release:fi/A fl/A 6.

Average stream flow during periods of release of effluent into flowing stream:fi/A ft/A See flote (1) and

  • on Page 6 of this report fl/A= flot Applicable 85092601058 GOO 2 PDR ADOCK O OO O PDR R

5.

Batch Releases (cont.)

1985 1985 B.

Caseous 1st Quarter 2nd Quarter 1.

Nu=ber of batch releases:

None None 2.

Total time period for batch releases:

N/A N/A 3.

FLivimum time period for a batch release:

N/A N/A 4.

Average time period for batch release:

N/A N/A 5.

Funimum time period for a batch release:

N/A N/A 6.

Abnor=al Releases s

A.

Liquid 1.

Number of releases:

None None 2.

Total activity released:

N/A N/A B.

Gaseous 1.

Nu=ber of releases:

None None 2.

Total activity released:

N/A N/A J

e i.

.e.

a-e' s e st..

r

.--r

[

TABLE IA EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT GASEOUS FFFLUENTS-SUMMATION OF ALL RELEASES UNIT lst 2nd EST. TOTAL gI QUg Qg R

ERROR, %

A.

Fission & activation gases 7

_l. Total release Ci

<LLD

<LLD

607,
2. Averace release rate for period UCi/sec.

N/A fl/A h0E3g p

t=

3. Percent of Tech Spec li:: tit N/A N/A B.

Iodines

.1 i

1. Total Iodine-131 Ci N/A fi/A N/A
2. Average release rate for period UCi/sec.

N/A N/A

3. Percent of Tech Spec li::lic -

N/A N/A C.

Particulates

~

Particulates with half-lives 3 q n,..,

Ci 6.80E-6 6.48E-6 60%

2. Averas;e release rate for period uCi/sec.

8.74E-7 8.74E-7 E-C

3. Percent of Tech Spec limit 3.64E-3 3.43E-3
4. Cross alpha radioactivity Ci 7.84E-8 2.43E-7 1

D.

Tritium

1. Total release c1 1.79E0 2.81E0
607,
2. Averace release rate for period 11Ci/sec.

2.30E-1

?.58E-1 (8$E b

3. Percent of Tech Snec limit 4.79E-3 7.46E-3 for H-3

.,_--y

4 m

m m.

TABLE IB EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT GASEQUS EFFLUENTS-GROUND LEVEL RELEASE Continuous Mode.

Batch Mode Nuclides 1935 198b 19c3 19db UNIT l

Released 11 QhARTER QU TER Q

TER QUE ER 1.

Fission gases l

krveton-85 Ci

< LLD

< LLD N/A N/A krypton-853 Ci

< LLD

< LLD N/A N/A krypton-87 Ci

< LLD

< LLD N/A N/A krypton-88 C1

< LLD

< LLD N/A N/A xenon-133 Ci

< LLD

< LLD N/A N/A xenon-135 Ci

< tin

-tt0 N/A N/A xenon-135m Ci

< LLD

< LLD N/A N/A xenon-138 Ci LLD

< LLD N/A N/A Others (specify)

Ci Ci C1 C1 Ci Unidentified Ci ~

< LLD

< LLD N/A N/A Total for period Ci

< LLD

< LLD N/A N/A 2.

Iodines iodine-131 C1

-tin e it n n/A n/A

)

iodine-133 Ci

< LLD

< LLD N/A N/A iodine-135 Ci

< LLD

< LLD N/A N/A Total for perind Ci

< LLD

< LLD N/A N/A !

i

-,. -., - _ _ ~

g,

.-w r

e g~

-,--,,w--

--~

4 I

TABLE IB (cont.)

EFFLUENT AND L'ASTE DISPOSAL SEMIANNUAL REPORT GASEOUS E"JLUENTS-GROUND LEVEL RELEASES t

1 j

1 Continuous Mode Batch Mode Nuclides UNIT

}$

N[

kkh Nh Released gg QUARTER QUARTER QUARTER QUARTER I

3.

Particulates s trontiu:n-89 ci

< LLD

< LLD N/A N/A strontiuo-90 ci

< LLD

< LLD N/A N/A cesium-134 ci

< LLD

< LLD N/A N/A cesium-137 c1 7.67E-8

< LLD N/A N/A barium-lanthanum-140 Ci

< LLD

< LLD N/A N/A

)

Others (specify) 4 4

l 1

i t'n idan tified 6.73E-6 6.48E-6 N/A N/A f

I 1

1 i

I I

i 1

e i

,m7____._,

...-,_____,__,..___...c.,

,..---y

,,,___.--,,,y

TABLE 2A EFFLUD;T AND WASTE DISPOSAL SEMIA!i'iUAL REPORT LIQUID EFTLUDITS-SLT!ATION OF ALL RELEASES Tech. Spec. Limit = 10CFR20, Appendix B. Table II, Column 2 1231T Ih Ih EST. TOTAL QUARTER QUARTER ERROR % A. Fission and activation products

1. Total releases (not inciuaing tritiu=, eases, aloha)

Ci 3.99E-5 4.96E-5 160.5

4. Average ollutec concentration d" rim ~riod uCi/ml 5.36E-12 Based on 2E-5 a ne,p
3. Percent of applicable limit 2.68E-5 2.08E-5
.Ci /m1 (Cs-137)

B. Tritium

1. Total release Ci 3.56E-5 7.25E-5 260%
2. Average ciiutec concentration durinc period UCi/ml 4.78E-12 7.69E-12 Based on 3E-3
3. Percent of applicable li=it 1.59E-7 2.56E-7 pCi/ml (H-3)

C. Dissolved and entrained gases

1. Total release Ci

< LLD < LLD i60;

i. average ollutec concentration durin ratind uct/mi fi/A fi/A
3. Percent of applicable limit ft/A ft/A D.

Cross alpha radioactivity

1. Total release Ci flote 3 flote 3 60; L. Volu e of WdSCO reludsco (orior to dilution) liters 5.67E4 1.44E5 25%

[* DYS forN1 " d Y "8 liters 7.45E9 9.43E9 10;

  • Includes only those releases mentioned in flote (1) which were found to contain radio-isotope concentrations >LLD.

flote:(1):There were no liquid releases from the radwaste system during the first half of 1985 since this system is flanged off from the discharge lines. However, low concentrations of radionuclides have been occasionally found in the industrial waste stream and sanitary waste and are appropriately included in item A2. flote:(2): Refer to Table 5 for typical LLD values. flote:(3):The alpha values will be determined by offsite vendor analysis of a. composite sample..-

__ - = - - -- _. - --_ _ TABLE 2B EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT LIQUID EFFLUENTS (Note 1) Continuous Mode Batch Mode h Ih l Nuclides UNIT i Released (( QUARTER QUARTER QUARTER QUARTER i 5tE 5 l strontium-89 Ci NOTF 2 NOT :;E? < tt0 <tiO strontiun-90 Ci !iote 3 1 ate 3 cesium-134 Ci " llD < llD cenium-137 Ci 3.76E-6 1.43E-5 indina-111 ce < LLD < LLD cobalt-58 Ci < LLD < LLD cobalt-60 Ci < LLD < LLD 1 iron-59 Ci < LLD < LLD rine-65 Ci < LLD < LLD caracanese-54 Ci < LLD < LLD chromium-51 Ci < LLD <tLD zirconium-niobium-95 Ci < t. L D < t LD colybdenum-99 Ci < l.L D < LLD technettua-99m Ci < LLD < LLD barium-lanthanum-140 Ci < LLD < Lt.D cerfun-141 Ci < LLD < LLD Other (v ocifv) Ci < LLD < LLD Ci .l C1 Ci C1 Ci r* Unidentified C1 3.61E-5 3.52E-5 Total for period Ci 3.99E-5 4.96E-5 I xenon-133 - Ci < 110 < I LD xennn-115 Ci < LLD < LLD ) ' lote (1) includes only those releases mentioned in hote ll) page 6. iote (2) There was no continuous release of effluent from Unit II during the second half of 1 i Note (3) The Sr-90 values will be determined by Nfsite vendor analysis of a composite s

Unit 2 January to June 1985 - SDS & LSA TA3LE 3A EFFLUENT AND WASTE DISPOSAL SEMIM;';UAL REPORT SOLID WASTE AND IRRADIATED FUEL SHIP.Tl;TS A. Solid waste shipped off-site for burial or disposal (not irradiated fuel)

1. Type of waste egit f,pyyjf

((g6p gL\\L T 5 pent resins, filter sludges 4. 3 e m 793 md avarorator bottees. etc. Ci 6944.0lPCi 5.

b. Dry ce=pressible waste, contaminated m 3 g0g)}f9 5%

m" equipment, etc. c,

c. Irraatates co=ponents, control 3

m rod s. e t c. C1 67

d. Other (describe)

Ci ~~ ~~

2. Estimate of major nuclide co 00mition (bv type of wagte)
2. Cs 13/

77.73% Sr 90 17.5, Cs 137 3.13, Ru 106 .69 :

b. Cs-137 91.23 7 Tc 99 5. 4 E Cs-134 4.118:

Sr-90 4.314 - Sb 125 5.bt-2g

e. h/A

= ~ '4

d. M/A 1

I

3. Solid Waste Disposition
unber of Shipments Mode of Transportation Destinatien

\\A) 2 shipments Tractor-Ca s k-(14/ I POM) Richland, Washington (B) 6 shipments Tractor. Flatbed Hanford, Washington

  • (B) 4 shipments Iractor Closed van Han tora, wasriirigton i

3. Irradiated Fuel Shipments (Disposition) Number of Shipments Mode of Transportation Destination N/A N/A

  • (B) LSA shipped in f 396 steel drums at 7.5 fgJ each )

L 45 steel boxes at 98 ft each,f .a.

Unit 2 January - June 1985 - Epicor TABLE 3A EFFLUENT AND WASTE DISPOSAL SEMIM;NUAL REPORT SOLID WASTE AND IRRADIATED FUEL SHIPMENTS A. Solid waste shipped off-site for burial or disposal (not irradiated fuel) f

1. Type of vaste UNIT 3cy

{gjgRy.R 6

a. 5 pent resins, filter sludges, m'

gh 5% avarnrator bottnes. etc. Ci

b. Dry cc pressible waste, contaminated m 3 equir ent, etc.

m

c. Irraatatec cc:ponents, control 3

m rod s. e t c. C1 D

d. Other (describe) l Ci
2. Estimate of =ajor nuclide t

ec-onsition (bv type of was te) n. Eb 125 72.2 % i Te 125m 16.54 Cs 137 6.62 7 Sr 90 1.75 : b. (.s - l J / Ba-137m Cs-134 Sr-90 ?. Y-90 t c. h/A d. N/A

3. Solid Wasto Disposition Nu-ber of Shir.ents Mode of Transportation Destination
  • (a) 2 shipments Tractor-flatbed Hanford, Washington (a) 2 shipments Tractor - Cask (14/190m)

Hanford, Washington B. Irradiated Fuel Shipments (Disposition) Number of Ship =ents Mode of Transoortation Destination

  • Shipped in 3-170fg3 steel liners 1-50ft steel liners l

. a. u---.

Unit 2 January - June 1985 - Miscellaneous Liners TABLE 3A EFFLLINT AND WASTE DISPOSAL SEMIAN';t'AL REPORT SOLID WASTE AND IRRADIATED FUEL SilIPMENTS A. Solid waste shipped off-site for burial or disposal (not irradiated fuel)

1. Type of waste UNIT jh ggggTAL T
a. spent resins, filter sludges.

m' g8 gaf g .I avarorator bottor.g. etc. Ci 8

b. Dry compressible waste, contaminated a

3 equirmont. etc. c4 ~~

c. Irra41stec cc:ponents, control 3

m red s a t e. C1 m7

d. Other (describe) l Ci

~~

2. Esti= ate of major nuclide ecanegition (bv type of wagte)

Cs 13i 44.2V4 i Co 60 P2.28 Ni 63 /1.61 H3 5.13: b. Cs-137 n3 137m Cs-134 Sr-90 Y-90 g e. h/A l d. N/A t J. Solid Waste Disposition Nu-ber of Shin ents Mode of Transportatian Destination (a) 2 shipment; Trac tor-t la tbed Hanford, Washington B. Irradiated Fuel Shipments (Disposition) Number of Shipments Mode of Transoortation Destination d Shipped in 6 - 170 ft steel liners .g.

h TABLE TV TYPICAL GASEOUS EFFLUENT LLD (Lower Limit of Doctection) VALUES ASSUMPTIONS : Sample Volume (ftarinelli) 1640 cc I Sample Volume (Particulate Filters) 5.0E8 cc Sample Volume (Gas bubbled through water) 1.0E6 cc Sample Volume 100 ml l Sampie Aliquot 3 ml i j Sample Counting Time: a=20 min; 3H=10 min; 8=10 min; y=1000 soc Sample Founters: y emitters 25?.Ge(li) l a or 8 Proportional Counter 3H Liquid Scintillation Counter IS0TODE pCl/ccLLD, TYPE SAMPLE i Gross Alpha a 7E-16 Particulate Filter Paper \\ j Gross Seta 8 2E-14 Particulate Filter Paper Tritium 3H 4E-10 Air bubbled thru water by i Fisher Milligan gas washer Krypton-85 85 SE-6 Marinellf t 9 Krypton-85m 85m 2E-8 Marinelli 4 gp Krypton-87 97 4E-8 Marinelli Kr i Krypton-88 38 4E-8 Itarinelli g# Xenon-133 133 3E-8 Marinelli 13 3m*** I Xenon-133m IE-7 tia rinelli i Xenon-135 135*' 2E-8 Marinelli i 4 Xenon-135m 135m$ 2E-7 Marinelli Xenon-133 138 2E-7 Marinellt lodine-131 1 31 2E 8 Marinelli -[ g j lodine-133 133 2E-8 Marinelli g i lodine-135 135 2E-7 Marinelli g I 54,n SE-14 Particulate Filter Paper { ttanganese-54 59,7 l Iron-59 IE-13 Particulate Filter Paper I Cobalt-58 SS " SE-14 Particulate Filter Paper C l Cobalt-60 60 8E-14 Particulate Filter Paper l 1 C Zine-65 65 "o IE-13 Particulate Filter Paper i 90f 6E-14 Particulate Filter Paper

  • Strontium 90 1

!!alybdenum-99 99j',# 2E 14 Particulate Filter Paper Ruthenium 103 103, 3E-14 Particulate Filter Paper g i Silver-110. Il0m., 7E-14 Particulate Filter Paper l Cesium-134 13402 6E 14 Particulate Filter Paper i Cesium-137 137 {,' SE-14 Particulate Filter Pap 3r 4 i Cerium-141 141 3E-14 Particulate Filter Paper C l Corium-144 144 2E-13 Particulate Filter Paper Ce i

j 1
  • Determined 'sy beta spectrometer

{ p i i I

I i i. i 4 TABLE V 1 l I + TYPICAL LIQUID EFFLUEili LLD (Lower Limit of Octection) VALUES I L ( ASSUMPTIONS : Sample volume = 1 11ter = 1000 cc Sampic counting time - 1000 sec i Sample counted with a 251 Ge(Li) l for Gamma Emitters y { IS3 TOPE Cf/cc LLD NOTES i I l Gross Alpha a 4E-9 Counted with proportional counter l Gross Beta 8 7E-8 Counted with proportional counter { Tritium 3 4E-6 Counted with Liquid Scintillation .{ g counter Krypten-85 85 IE-4 i Xenon-131m 131n*" 2E-5 I Xenon-133 133 ' IE-6 X Xenon 135 135 3E-7 j Chromium 51 51 3E-6 Cr i Manganese-54 54 4E-7 1 Cobalt-58 58"" 4E-7 I i Iron-53 59 9E-7 C I Cobalt-60 60 ' 6E-7 Zinc-65 65 o 1E-6 C i Zirconium-95 95 " 7E-7 I i fliebium-95 95 " 4E-7 2 D i Molybdenum-99 99"0 3C-7 ) Tect.netium-93m 99m"ic 3E-7 511ver-11Cn 110m 6E-7 j Antimony-125 125' 9E-7 3 Cesium-134 134 SE-7 Cs 1 Cesium 136 136 4E-7 3 C5 Cesium-137 137 SE-7 l Barium 140 140 IE-6 Cs i Lanthanum 140 140 7E-7 i 08 i Cerium-141 141 a GE-7 L i j Cerium-144 144 3E-6 i todine-131 131 3E-7 lodine 133 133f t 4E-7 Phosphorus-32 32 1E-6 These LLO values for itquid sampic I p fron-55 55 St-a I Strontium 39 89, SE-3 analyses of gross alpha, 32p. 55 7 Fe ' } Strontium 90 90 SE-3 5r 895r e and 90 r are the same as Unit 1 5 5r Gross Alpha a IE-7 which are of fsite vendor LLO values } i l I I 1 I i

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l' .t 2nd Quarter ATTACHMENT 6 J. Frequency Tables (4410-85.L-0175) SITE,..e[E p.LE 3563. spe g t. ee/se/so es.?4 Sitt tuott 1 L E 8 5L s. 13:11 ee/ m m,84 enouns A? Entee wspee sME3 Aces 3:nECTich eeDWD5 at E ACM Wlass SMES Aset SIIECTIObs PEploe OF #EC3Re = steestet.eSeele24 M 880f 0F nECope. sos *Stel.seestete Stach !v v CL ASS 4 31/32 51 ass;lt? C.A56 e 81/92 EL E w A110se...........--......E s. 5P s eem ............ M CTION 88883A L A8*5E 318 Sea 1 SM pl EL E w A'.10pe. SPE ...........E.S.5Pi m ...............80h.Si.tesA SIMC1 ...........eftSea LAP 5E. i wisee SPEEB8fWet blece SPEEartypes i w:m3 wl>8 1 Si p[Ci t ose s.1 4-7 e.t2 15-se es-24

  • 24 TOTAL ti eE E'i0se e.5 4-7 a.82 15-!S 1e-24
  • 24 TOTAL se e

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