ML20117M546
| ML20117M546 | |
| Person / Time | |
|---|---|
| Site: | San Onofre  |
| Issue date: | 08/27/1996 |
| From: | Kay D SOUTHERN CALIFORNIA EDISON CO. |
| To: | Robertus J CALIFORNIA, STATE OF |
| References | |
| NUDOCS 9609170505 | |
| Download: ML20117M546 (32) | |
Text
{{#Wiki_filter:- . . _ - - . -- - . - . - -. --. . .. l- L . 4 ,
/
Southem Califomia Edison Company SAN ONOFRE NUCLEAR GENERATING STATION j P. O. 80X 128 I SAN CLEMENTE. CALIFORNIA 92674 4128 August 27,1996 l Mr. John Robertus, Executive Omcer l California Regional Water Quality Control Board l San Diego Region ; 9771 Clairemont Mesa Boulevard, Suite B
- San Diego, CA 92124-1331
SUBJECT:
REQUEST FOR NPDES PERMIT AMENDMENT OR OTHER GRANT OF AUTHORIZATION FOR DISCHARGE OF METAL CLEANING WASTEWATER - SAN ONOFRE NUCLEAR GENERATING STATION UNITS 2 & 3 l i
Dear Mr. Robertus:
Southern California Edison (SCE) requests your authorization for a material change in the discharge of San l Onofre Nuclear Generating Station (SONGS) Units 2 & 3 (Board Order Nos. 94-49,94-50). SCE intends to discharge low-volume treated wastewater emuent from a steam generator cleaning process at SONGS. l This process and the wastewater discharge were not included in the application packages previously submitted for the most recent NPDES permit renewals. Consequently, the Regional Board did not adopt chemical metal cleaning waste emuent limits or monitoring requirements in the permits. We believe this discharge may be subject to federal emuent guidelines found at 40 CFR 423.12(b)(5). Unit 2 Maintenance Outage is scheduled to begin in December 1996. Unit 3 Maintenance Outage is scheduled to begin in April 1997. Each outage will generate roughly 750,000 gallons of waste water, consisting of 250,000 gallons of treated steam generator cleaning solution and roughly 500,000 gallons of post-cleaning rinsate. The majority of the discharges will occur intermittently over a 2 week period. The remaining discharges will occur infrequently over a several month period as treatment allows. Both the solution and rinsate will be treated to meet the above emuent guidelines before being commingled into the combined cooling water discharge of the station. The steam generator cleaning discharges will consists mainly of water and the following chemicals will be present: Diammonium EDTA Ammonium Hydroxide Hydrogen peroxide Hydrazine I [b,),-aJ i l Ethylenediamine / l Alkylthol based corrosion inhibitor 9609170505 960827 ' PDR ADOCK 05000361 P pon
~
Mr. John Robertus August 27,1996 Page 2 The following commonly used chemicals will be used during the treatment of the water and wi!! be present in the discharges: Sulfuric Acid Soda Ash Lime Carbamates Floceulat polymers Sodium Hydroxide The used cleaning solution as well as the post-cleaning rinsate will be neutralized and filtered to remove solids prior to discharge as a low-volume wastewater. The treated wastewater may contain EDTA, iron, copper, and TSS. For your information, I have attached a copy of the effluent limits and monitoring requirements for chemical metal cleaning wastewater at Edison's Redondo Generating Station. SCE has not included NPDES application Forms 1 and 2C with this request. Regional Board staff may rely on the most recent NPDES permit renewal applications (1989-1994) for information on all other plant processes and discharges. If you have any questions, please call me at (818) 302-2149 or MaryJane Johnson at (714) 368-6651. Sincerely,
$ et%
DYD . KAY, D. Env. St. Environmental Specialist Attachment
\,
cc: U.S. Environmental Protection Agency, Region IX, Water Permits Branch bec: R.V.D. Reid (w/o att.) H. W. Newton W. C. Marsh M. J. Johnson N. J. Mascolo K. C. Yhip R. K. Heckler
l
~
SCE, Mandalay G:n";rsting Station CA0001180 order No. 94-131 l 0 '
- 6. If the USEPA Administrator does not approve the Section !
301(g) variance as discussed in Findings 20, the effluent 1 limitations ~in A-5 are not applicable, and the following effluent limitation is applicable. , l Discharce LimitationD1 Constituent M Daily Maximum Total residual mg/l 0.2 chlorineP2 (1) The daily mass emission limits (in Ibs/ day) shall be determined using the tabulated concentratien limits and actual flow rate. [2] Based on the State Board approved Ocean Plan Exception using a l minimum initial dilution of 5.2. Total residual chlorine may ' not be discharged from any single generating unit for more than 10 minutes per condenser half per shift. For chlorine discharges of up to 10 minutes, the daily maximum
. limit is 0.365 mg/1. For chlorine dischargec exceeding 10 minutes, the applicable total residual chlorine limitations shall be that calculated using procedures outlined in Table B
" Toxic Material Limitations" of the Ocean Plan.
- 7. Effluent Limitations for Inplant Waste Streams:
- u. The discharge of metal cleaning wastes"3 with constituents in excess of the following limits is prohibited:
DISCHARGE LIMITATIONSDI 30-day Daily Constituents Units Averace Maximum Suspended solids mg/l 30 100 Oil and grease mg/l 15 20 Copper, total mg/l 1.0 1.0 l Iron, total mg/l 1.0 1.0 [1] For the purpose of these limitations, metal cleaning wastes shall mean any wastewater resulting from chemical cleaning of any metal process equipment including, but not limited. to, boiler tube, boiler fireside, and air preheaters. (2) The daily mass emission limits (in lbs/ day) shall be determined using the tabulated concentration limits and actual flow rate. 9
l Monitoring and Reporting Program No. 2093 CA0001180 Southern California Edison Mandalay Generating Station 6
- 2. Metals Minimum
, Type of Frequency constituents Units Sample of Analysis 4
Antimony pg/l grab semi-annually Arsenic pg/l grab semi' annually ! Beryllium pg/l grab semi-annually Chromium (III) pg/l grab semi-annually Hexavalent chromium pg/l grab semi-annually Cadmium pg/l grab semi-annually Copper pg/l grab semi-annually l Lead pg/l grab semi-annually Mercury pg/l grab semi-annually Nickel pg/l grab semi-annually 4 Selenium pg/l grab semi-annually Silver pg/l grab semi-annually Thallium pg/l grab semi-annually Zinc pg/l grab semi-annually B. The effluent monitoring program for Inplant Waste Streams is as follows:
- 1. chemical Metal cleanine Wastest ,
4 Minimum ! Type of Frequency ) Sample Constituents Units of Analysis Flown mgd --- monthly i pH pH unit grab monthly i Suspended Solids mg/l grab monthly oil and grease mg/l grab monthly . Copper, total mg/l grab monthly Iron, total mg/l grab monthly l 4 [1] If no discharge occurred during the month, the report shall so state. 1 1 T-5 i
A T*E R I A L SAFETY DATA S H' E E T a.___ ____________-__________________________________-______________
'sw Chemical U.S.A.* Midland, MI 48674 Emergency Phone:517-636-4400 l '.RODUCT NAME: ' Product Code: 30421 Page: 1 ENEDIAMINE Iffective Date: 08/18/08 Date Printed: 02/24/89 MSDS: 000161 1
l
- s. INGREDIENTS: (3 w/w, unless otherwise noted)
Ethylenediamine CAS# 000107-15-3 99% This. document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.12001. In addition, other l substances not ' Hazardous' per this OSHA Standard may be listed. l Where proprietary ingredient shows, the identity may be made available as provided in this standard. i
- 1. PHYSICAL DATA:
BOILING POINT: 239F. 115C VAP. PRESS: 10 mmHg G 20C ! l VAP. DENSITY: 2.07 " SOL. IN WATER: Mixes completely. SP. GRAVITY: 0.893-0.906 25/25C { l FREEZING POINT: 51F, 11C APPE W.NCE: Colorless liquid.
' DOR: Ammoniacal odor.
- 3. FIRE AND EXPLOSION HAZARD DATA: !
FLASH POINT: 101F. 28C
.ul.Tr!OD USr'- DMCC FLAMMABLE LIMITS LFL: 2.6% G 100C UTL: 14.2% G 100C DCINGUISHING MEDIA: ' dater fog, ale:hol foam, CO2, dry chemical. l 1
FIRE & EXPLOSION HAZARDS: Not available. ' pip,E_FIOhTTHQ JniiTI W'uT2 I?H f t.ill vyotective clothing (see section 8) anc a positive pressurb, self-contained breathing apparatus. b (Continued on Page 2) (R) Indicates a Trademark of The Dow Chemical Company !~ M . Operating Unit Of The Dow Chemical Company G S g
I
* ~
T ,E R *I A L - SAFETY DATA SHEET Midland, MI 48674 Emergency Phone:517-636-4400 [ Chemical U.S. A.
- 36CT NAF.E: Product Code: 30421 Page: 2
- LENEDIAMINE ective Date: 08/18/08 Date printed: 02/24/89- MSDS:'000161 F.F_1.C ;VITY . DATA : 3 STABIL;TY: ICONDITIONS TO AVOID) Autoignition temperature in air is approximately 763F, 406C.
l INCOMPAT!SILITY: (SPECIFIC MATERIALS TO AVOID) Acid, oxiditing material, halogenated organic compounds , aldehydes , ketones , and acrylates. Mixture .with these materials will result in a : temperature.and/or pressure' increase. - MAZAliDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides when burned. 1 , F_1.ZAF.DOUS POLYM_ 9 IZATION: Will not occur. ENVIRONMENTAL AND DISPOSAL INFORMATION: l ACTION- TO TAKE FOR SPILLS / LEAKS : Large spill - dike up and i dilute with water. Pump into appropriate containers. Small spill - dilute with water and recover or use noncombustible absorbent material /cr.nd and shovel into suitable containers. Otherwise,
- SPOSAL M5.'I":iOD: Large quantities could be recovered.
incinerate in accordance with local regulations. Keep out of public water suppJ.ies. The Dow Chemical Company may be contacted f cr advice. MEAL 2 MAZARD DATA: EYE: May cause severe irritation with cornsal injurv which may
- recult in permanent- impairment of vision, even blindness.
*?apors'may irritate eyes.
5y.!% CONTACT: Short sinele exposure may cause severe skin burns. Has_ caused allergic skin reactions in humans. ! DOT Classification: Corrosive. SKIN ABSORPTION: A single prolonged exposure may resuit in the material being absorbed in harmful amounts. The LD50 for skin absorption in ra.bbits ' is 657 mg/kg. b
- ntinued on Pace 3)
.) ' Indicates a Trademark of The Dow Chemical Company An Operating Unit Of The Dow Chemical Company e
B n -- - n n - -w-- -- - .,,
f .. 4 ATERIAL S A.T E T Y DATA 0HEET l , v now Chemical U.S.A.^ Midland, MI 43674 E=creency Phone:517-636-4400
-~' JCT NAME: Product Code: 30421 Page: 3
.. INEDIl>MINE .
- ffective Date: 08/18/88 Date Printed: 02/24/89 MSDS: 000161 i
1
.. HE;d.TH HAZARD DATA: (CONTINUED) i INGESTION: Single dose oral toxicity is low to moderate.
Ingestion may cause gastrointestinal irritation or ulceration. , May cause evere burns _of the mouth and throat. The LD50 is 1460 mg/kg for rats and 470 mg/kg for guinea pigs. INHALATION: Excessive vapor concentrations are attainable and , could be hatardous on single exposure. Excessive exposure may [ cause severe irritation to the upper respiratory tract. May cause respiratory sensititation in susceptible-individuals. . SYSTEMIC & OTHER EFFECTS: Repeated excessive exposures may cause : liver and kicney injury. Did not cause cancer in long-term l animal studies. Birth defects are unlikely. Exposures having no effect-on the mother should have no effect on the fetus. Did not cause. birth defects in animals; other effects were seen in the fetus only at doses which caused toxic effects to the mother. In animal utudies, has shown not to interfere with reproduction. Preponderance of negative data indicates minimal or no mutagenic potential. 7 FIRST AID: EYES: Immediate anc continuous irrigation with flowing water for at least 30 .inutes is imperative. Prompt medical consultation is essential. 1 SEIN: In case of contact. immediately flush skin with plenty cf water for at least 15 minutes while removing centaminated - clothing and shoes. Call a physician if irritation persists.
- dash clothine before reuse. Destroy centaminated shoes and other leather items or articles which cannot be decontaminated. I 1
INGESTION: Do not induce upmitine. Give large amounts of water i or milk if available and transport to medical facility. NHALATION: Remove to fresh air if effects occur. Consult a physician, c
! Continued on Page 4)
;R) Indicates a Trademark of The Dow Chemical Company f 1.n Operating Unit Of The Dow Chemical Company 9
9
.,. - .~-- y ,,-- . . _ - ,
l SAFETY DATA GHEET
. i'_E R I A L .12 _________________._____.._________ ___________________________.
i Chemical U.S.A.* Midlanc, MI 48674 Emergency phone:517-636-4400
) UC'" NAME : product Code: 30421 Page: 4 WLENEDIAMINE -
i factive Date: O_8/18/88. Date printed: 02/24/89 MSDS: 000161 F'IRST AID;-(CON"'!NUED) NOTE TO PHYSICIAN: Corrosive. May cause stricture. If lavage is performed, .succest endotracheal and/or esophagoscopic control. ; If burn.is present, treat as any thermal burn, after , decontamination. No-specific antidote. Supportive care. l
- Treatment based on judgment of the physician in response to
-reactions of the patient. Excessive exposure may aggravate .
preexisting asthma, liver and kidney disease. HANDLING PRECAUTIONS: t EXPOSURE GUIDELINE (S): ACGIH TLV and OSHA- PEL are 10 ppm. I VENTILATION: Control airborne concentrations below the exposure guideline. Use only with adequate ventilation. Local exhaust ; ventilation may be necessary for some operations. RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline. Rnen respiratory protection is recuired for certain operations, use an approved air-purifying respirator. SKIN PROTECTION: Use protective clothing impervious to this material. Selection of specific items such~as gloves, boots, apron, or full-body suit will cepend on operation. Wear a f ace-shield which allows use of chemical goggles, or wear a , full-f ace respirator to protect f ace and eyes when there is any i likelihood cf splashes. Safety shower should be located in ! immediate work area. Remove contaminated clothing immediately, wash skin area with soap and water, and launder clothing before reuse. Contaminated leather items, such as shoes, belts and ; watchbands, should be removed and destroyed. ETE PROTECTION: Use chemicals. goggles. Wear a face-shield which allows use of chemical gocqles, or wear a full-f ace respirator - I to protect face and eyes when there is any likelihood of splashes. If vapor = exposure causes eye discomfort, use a full-i face respirator. Eye wash fcuntain should be located in. l immediate work area.
- ontinued on page 5)
R) Indicates a Tracemark of The Dow Chemical Company An Operating Unit Of The Dow Chemical Comeany 9
.e
'rs-- c w w- -te- v # m "
[A T'E R I A L
. SAFETY DATA 5HEET
_____L._____________________________________________________________ ic'w Chcmical U.S.A.* Midland. MI 48674 Emeraency Phone:517-636-4400 '90 DUCT NAME: Product C'de: o 30421 Pace: 5 . LENEDIAMINE Offective Date: 08/18/08 Date Printed: 02/24/89 MSDS: 000161
. ADDITIONAL II:70RMATION:
REGULA'fCRY REQUIREMENTS: SARA HAZARD CATEGORY: This product has been reviewed according to the EPA ' Hazard Categories' promulgated under Sections 311 and 312 of the Superfund. Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: An immediate health hazard A delayed health hazard
- A fire hazard SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Ground all transfer ecuipment. Store below 120F, 49C and above 51F, llc. Hold bulk storage under nitrogen blanket.
Ethylenediamine should not come in contact with c.opper or coppor bearing alloys.
'SDS
. STATUS: Revised .Nection 4.
4
\
Th2 ' Inf or ation Herein Is Given In Good Faith, 2ut No Warr.;nty, i Express Or-Implied, I.< Mace. Consult The Dow Chemical Comeanf 7cr Further Informacien.
- An Operating Unit Of The Dow Chemical _ Company e .
e
g . 202-433.TJ16 O U T SID E T.-t E C O NT;NEN T/.L U.S. A N O IN WAS htN u i v A. U.C.)
. EMERGENCY RESPONSE INFORMATION SHEET CORROSIVE MATERIAL UN1604, RQ+
P.C. 30421 ETHYLENEDIAMINE
, }' ( l ,2-DI AMINOETH AN E)
~
COMPOSITION: ETHYLENEDIAMINE, MIN. 991 _- FORM: LIQUID, COLORLESS, AMMONIA ODOR FLASH POINT: 10l* F ( TCC) SPEC GRAVITY: 0.893 - 0.906 0 25'C FLAM LIMITS: 2.5% .12.0% ! 100*I SOL IN WATER: MIXES COMPLETELY VAPOR HA2: CORROSIVE, COMBUSTISLI TREE 2E POINT: 51*F REACTS WITH: ACIDS, OXIDIZING SOILING PT: 239'F - 246*F MATERIALS AND HALOGENATED ORGANIC COMPOUNDS . _ _ _ _ _ _ _ _ _ _ _ _ _H_ _E_ _A_ _L_T_ _H_ _ _H_ _A_ _ Z_A_ _ _ _ _
,i _ _CYE _ _S : S EV E RE BU RN . POSSIBLE BLINDNESS.
i i SKIN: SEVERE BURN. ALLERGIC SKIN REACTION (RASH, ITCHING). TOXIC BY I I I I ABSORPTION. i i INHALATION: SEVERELY IRRITATING. ALLERGIC RESPIRATORY RE' ACTION. HAS i I OFFENSIVE ODOR. 1 LOW TOXICITY, BUT CORROSIVE--CAUSES BURNS . l INGESTION: l l 1 l
- I ANIMAL
- CORROSIVE. KEEP ANIMALS AWAY.
. I e-cu. AvnIn ry, ov INTn n.Trin ar usTc M . . MAy cAUSE toCAtiziD eIcu t"r_.!
.~$ i. * , ..
UV tivi u c4' LOM b u s A l e Lt. . rs t.F P V P n i N i> . i m u t.A l t. AntA nhu u t.N I c.tv i n I . IN EYES, ON SKIN, ON CLOTHINC. DO NOT BREATHE VAPORS. USE WATER S SPRAY TO REDUCE VAPOR. NO SMOKING, FLARES, OR OPEN FLAMES. SHUT C EF IGNITION AND LEAK IF WITHOUT RISK. USE NONCOMBUSTIBLE AnscnncHT P MATERIAL / SAND AND SHOVEL INTO SUITABLE CONTAINERS. DIKE LARGER E SPILLS AND RECOVER. PREVENT ENTRY INTO SEWERS AND/OR NATURAL WATEFS. L lA CtorHING: APPARATUS. WEAR FUu. PROrECTIvE Ct.OTHING AND SEI.r-CONTAINED sREATHI m [K DISPOSAL: CONTACT MANUFACTUPER AND AUTHORITIES.
"RO: SPILL OF REPORTABLE OUANTITY MUST BE REPORTED.
J CM BUSTTBLE. MAY DECOMPOSE IN HEAT / FIRE RELEASING PRODUCTS OF
.gn GREATER HAZARD. DO NOT PUT OU r ANY FIRES AT VENTS UNTI' LEAK ~ S E-!C T M- OFF. ,
3 SMALL FIRES: USE DRY CHEMICAL OR CO2* I
.: .6 R LARGE ?!RES: USE WATER SPRAY, FOG, OR FOAM. IT iO I F '.' A5 5 IV E FIRE: USE UNMANNEO HOSE HOLDER OR l'.ON!!OR N0!!".EE.
*Y. THIS IS IMPOSSIBLE, WITHDRAW FROM AREA AND LET FIRE SURN. DIKE
.I-.l. : LIOUID RUN-OFF . PREVENT ENTRY INTO SEWERS AND/OR NATURAL iATERS.
3L
- CLOTHING: WEAR FULL PROTECTIVE CLOTHING & POSITIVE-PRESSURE,
~D SELF-CONTAINED BREATHING APPARATUS.
?.m -d.
vn n -
- :: Annt.v A n t r nnu sv.siinuvus inniuni.vh niin c a.un i nu a n i :. n LEAST 30 MINUTES IS IMPERATIVE. PROMPT MEDICAL CONSULTATION IS F ESSENTIAL. .
IA SxI": Ix"EDI ATEtY rtuSH WITH PtENTY Or WATER FOa Ai tEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING. CONSULT MEDIC AL P ERSONNEL. RI CtOrHING: REMOVE CONrAMIN ATED CtOTHING IMMEDIATELY AND WASH BEFORE DESTaOY CONTAMINATED SHOES AND LEATHER ITEMS. SD REUSE. INHALATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. CONSU LT MEDICA'- TT PERSONNEL.
._1 iCom .nyn.new
*he we,%. .. a ni. nec n...sn s ,i....y pre s.nu e .: . c om.hme nt.ry . ... in c..c i.dn. .nc ,s. to in. t>e st of The 0.w Che rn.c.
- w. .. .....nai..n. ou ., . ni.. ,, . ., .nu .. ... .. ie ,u
. e c . . n. . . ...r. . ce ,.a . no .iu i. 4. .e in. e u. enni.e. own m. y ..n e. .ne ...i.u. m . , e n. n . . . o , in . ,,,, . . , . . ..n . .. o.,, i. .. . , n. ~
, e .m .. . . . . . . . . c .., n na i . v u t. .n . . n. . . . c on..i. .n
. c e .m cu,, ni...,..
c r...., .. n.u u . .. nn ,y e . ..u ..u y i ., , ,. cine . n . . . o n , i . . . . DOW CHEM! CAL U.S.4. APP. 0 4 GES
__ _ . _ ~. . --. - , . *:. l , ,,. MATERIAL 5.A F E T Y . D A T.A 5HEET Dcm Chemical U.S.A. Midland, MI 48574 Emergency Phone: 517-635-4400 Product Code: 90602 Page: 1 ! yy PRODUCT NAME: YERSENE (R) DIAMMONIUM EDTA CHELATING AEENT ) E f f ective Date: 06/19/85 Date Printed: 03/04/87 MSDS:000563 i.
~
INGREDIENTS: . l l Olammonium salt of ' ethylenediaminetetraacetic acid CAS/ 020824-56-0 L5: Water CAS# 007732-18-5 55: (Active ingredients as edta acid - LO ) 1 This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition. other substances not ' Hazardous
- per this OSHA Standard may be listed.
- Where proprietary ingredient shows, the identi ty may be made l available as provided in this standard. I t'
- 2. PHYSICAL DATA:
BOILING P0lWT: 219F, 10LC VAP PRESS: Same as water VAP DENSITY: Same water ; SOL. IN WATER: Completely mis-ible l SP. GR AVITY: 1.21 25/25C APPEARANCE: Light straw colored liquid. 000R: Ammonia odor. FREEZE POINT: 7F, -14C m -. . 37 FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: None METHOD USED: PMCC FLAMMABLE LIMITS LFL: Not applic. - --- -- UFL: Not applic. (Continued on Page 2) (R) Indicates a trademark of The Dow Chemical Company . i [ I
- MAIEEIAL SAFEit -
AiA $ ,- i . ;
~
Dow Chemical U.S.A. Midicnd. MI 48574 Emergency Phone: 517-635-4400
- Product Code: 90602 Page: 2
- PRODUCT NME: YERSENE (R) DIAWM3NIlN EDTA CHELATING AGENT Effective Date: 06/19/85 Date Printed: 03/04/87 KSDS:000563 i
f,
- 3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED)
EXTlHGUISHING ME0l A: Water fog alcohol foam. CO2. dry chemical . FIRE & EXPLOSION HAZARDS: Not availabic. FIRE-FIGHTING EQUIPMENT: Vear positive pressure self-contained breathing apparatus.
- 4. REACTIVITY DATA:
STABILITY: (CONDITIONS TO AVOID) Stable under normal storage and use conditions. Oxidi-ing INCOMP ATI B I LITY: (SPECI F I C MATERI ALS TO AVOID) materials. Contact with steel produces hydrogen. HAZARDOUS DECOMPOSITION PRODUCTS: Ammonia, nitrogen oxides f unoer fire condi tions. HAIARODUS PO'.YMERII ATION: Vill not occur.
- 5. ENVIRONMENTAL AND DISPOSAL INFORMATION:
ACTION TO TAKE FOR S?!LLS/ LEAKS: Soak up with absorbent material anc scoop into crums. Flush residue wi th plenty of water. Wash area with soa: and water. Avoid wash water enter ing
-- na tur a l wa t e rwa y s or aD'obiJ e wa t er supplies.
OlSPOSAL METHOD: Incinerate according to local, state and f ederal regulations.
- 6. HEALTH KAZARD DATA: -
[YE: May cause pain. May cause slight transient (t empor a r y) eye irritation.
. SKIN CONTACT: Prolonged or repeated exposure may cause skin irritation.
(Continued on Page 3)
/
(R) Indicates a trademark of The Dow Chemical Company
,,w,3 ;-.. .
l . l ... . Dow Chemical U.S. A. Widland, WI 48574 'Emen;pncy Phine: 517-53o-4400 Product Cods: '90602 Pcgs: 3
PRODUCT NAME: YERSENE (R) DIAMONIIN EDTA CHELATING AGENT 03/04/87 MSDS:000363 Effective Date: 06/19/85 Date Printed: .
! 6. HEALTH HAZARD DATA: (CONTINUED)
- , i SKIN ABSORPTION
- A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. The dermal LD50 has not been determined.
INCESTION: Single dose oral toxicity is low. The oral LD50 for rats was >2000 mg/kg. INHALATION: Single exposure to vapors is not likely to be hazardous. SYSTEMIC L OTHER EFFECTS: Repeated exposures are not anticipated to cause any significant adverse ef f ects. The trisodium salt of edta did not cause cancer in laboratory an aals. Sirth defects are unlikely. Edta and its sodium salts have been reported to cause birth defects in laooratory animals only at e exaggerated doses that were toxic to the mother. These effects are likely associated with zine deficiency due to chelation.
- Exposures having no effect on the mother should have no effect on the fetus. In animal studies. has been shown not to interfere with reproduction. Most data indicate that edta and its salts are not mutagenic. Minimal effects reported are likely oue to trace metal deficiencies resulting f rom enelation by ecta.
- 7. FIRST AID:
-. n --
.. EYES: Irrigate immediately with water for at least 5 minutes.
SKIN: Wash off in flowing water or shower. INCESTION: Inouce vomiting if large amounts are ingestec. Censult medical personnel. - INHALATION: Remove to fresn'ai'r-if effects occur. Consult a physician. No specific antidote. Supportive care. NOTE TO PHYSICI AN: Treatment based on judgment of the physician in response to i (Continued on Page L) ( (R) Indicates a trademark of The Dow Chemical Company l 9
- ~ - - - . . - . . _ . _ _ _ . . _ _ ,- _ _ __ _
4 . M A I i K 1 A '. 3Ar 1 ,A,A 3n: g . .
~ '
- D:w Chemical U.S.A. Widland, WI 48574 Emergsney Phono: 517-E36-4400 Product Code: 90602 Page: 4
[.. PRODUCT MAME: VERSENE (R) DIAM CHIUW EDTA CHELATING AGENT Effective Date: 06/19/85 Date Printed: 03/04/87 M505:000563 i l
- 7. FIR $TAID: (CONTINUED) reactions of the patient.
- 8. HANDLING PRECAUTIONS:
! EXPOSURE CUIDELINE (5): None established. l
~
VENTILATION: Good general ventilation should be sufficient for most conditions. RESPIRATORY PROTECTION: No respiratory protection should be needed. f n misty atmospheres, use an approved mist respirator. SKIN PROTECTION: For brief contact. no precautions other than clean body-covering clothing should be needed. Use impervious gloves when prolonged or frequently repeated contact could f occur.
- EYE PROTECTION: Use chemical goggles.
- c. ADDITIONAL INF004ATION:
SPECI AL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORACE: Avoic breathing mists if generated. Practice reasonable care an: caution. Storage i n steel generates flammacle hyorogen gas.
~~
P.505 STATUS: Revised wa 1-c. - -
\
6 (R) Indicates a trademark of The Dow Chemical Company The information Herein is Given in Good Faith, But No Warranty, Express Or implied, is Made. Consult The Dow Chemical Company
/ For Further information.
.e n
~~ ' ' "
]""p' OCEAN
- Nctwerk iMERGENCY PHONE 1800 OLIN 911
~.
SECTION I - IDENTIFICATION
~
CHEMICAL NAME & SYNONYMS Myrrczine Solution. 357.
- FORMULA TRADE NAME CHEMICAL FAMILY SCAV-QX' Hygeez1ne N;H,.H,0 CAS NO.
DESCRIPTION 302-01-2 01ccr colorless 1toutB witn ocor of ammonia SECTION II - NORMAL HANDLING PROCEDURES PRE;;.UTION5 TO BE TAAEh IN MANOLING AND STORAGE Do nut get in eyes, on skin Avote or on creatning clothing. mtst Do not take internally. or vapor. Discarc any Upon contact witn contaminated skin or teatner oyos, wasn off witn water. cetteles. Store in a cool. Cry. well-ventilatec area away f rom om tatz tng materials ano actos. I avolo exoosure to ctract sunlignt or nign temperatures. l l l VENTILATION REOUIREMENTS CICTECTIVE EQUIPMENT As reautree to keep atraorne concentrations of ! EYES Coggles f nyorar.tne colow TLV l CLOVES Buty) ruceer OTHER Covera 11s. ooots anc outyi ruocer apron SECTION III - HAZARDOUS INGREDIENTS LD50 LC50 $1CN!FICANT EFFEC'S BASIC MATERIAL 0SHA PEL l Carctnogenic in i com 95 mg/kg 570 com/ My=razine laporatory animals. (suin) cereal 4 nes Damage to major organs. (racott) Irritant to snin, (rat) eyes anc muccus memoranes. SEC-' ION IV - FIRE AND EXPLOSION HA ARD DATA FL w aBLf. Lovgg j yppgg g QSHA CLAS$ITICATION Not regulatto EXPLOSIYi,s, , FLASH POINT Not flammaele , , , , MET)cD (Non-ignttaole) LIMIT I l J lEXTINOUISHING MEDIA Mycra:ine solut ton concentratec ey f iree exposure
,e 4 n.w 4...
can 1 toerate nyc a:ine veoor l tt...ta..v. t..... ave .-.a. 4 * . o rvw t rince w,., op.,. [
. SPE.*AL FIRE HAZARD & FIRE FIGHTING PROCEDURES use ts N;05h/M5Ha involved coorovec in a fire.pos s t sve Wear press erucoer a outy) sol l enc a* sulatec o=containec creatning suit wnen apoaratus fignting wnen any tnis a fire involving material mateetal. _
SECTION V - HEALTH HAZARD DATA _ g [ TetAE5MOLO L.1MIT VALUE com Tva faccfM 1985-861 _I I wvo-a:sne (skin) 0.- g SYm8 TOMS OF OVER EXPOSUAL Ot ;1 ness, nausea, sntn. eye. mucous memorane trettation. CNS J oseression. Mav cause tem =. ettneness. Damace to tiver. 1unos. ktonevs anc elecc-EMERGENCY f lRST. AID PROCEDURES Aemove all contaminatec clotning. Flush thorougnty witn water for 15 msnutes. call a _ l IXIN envstetan. IEYES F lusn tnoacuen t v wi th wate- for 15 re.tnotes, casi a onysician.
- novce vomi t ing my s t ick ing fin 9er oown inrest. Call Drink large cuantities of water. _-
.In ts?;cy a onysician.
l . . .. ... .... . ..........
l .. . CMEMICAL MAnt 5:Av-exo PROCLA~T CODE m 000 -- SECTION VI - TOZICOLOGY (PRODUCT) 1
. l stuales 'wTP CARCINDGENICITT Carcinogente - animal ACUTE ORAL LD 50 estTAGENICITY Posi t ive a40 sug/kg Irat) .
ACUTE DERMAL LD 50 ETE IRRITATION Irritant Amorom 400 mg/kg (racot t) PRIMARY SKIN 2RRITATION I 2erttant ACUTE Ile4ALATION LC 50 aoorom .1500 com (4 mesi PRIPICIP AL RDUTES OF AESDRPTION Der-ma l , inna letion CNS oeoression. Damage to i tver. EF F ECTS DF ACUTE EXPDSURE T emo , o l i none s s . o t:: t ne s s , naus ea . l tungs, k teneys ano olooc. Irritant to suin. eyes anc mucous memoranes. l tungs. k toneys. D1000 ano Bloco f orming organs. l EFFECTS DF CHRDNIC EXPOSURE Damage to i tver. May cause fetal malforenations. allergte sonstti:stion to su tn. cermat tt'.s. l SECTION VII - SPILL AND LEAKAGE PROCEDURES (CONTROL PROCE ACTIDN FDR MATERI AL RELEASE OR SPILL Remove all sources of ignstion. trear goggles. Dutyl ruocer gloves. Docts ano sitcker sutt. For l spills inocers or involving not Ins t er t a l wear a positive pressure sucoltes air resotrst9r (see 2$ CFR or < J self-containec creatning accaratus. Follow C5HA regulations for resstrator usecontents to non-leamim;l 1910.134). Isolate area of soti) by otktng. Stop source celuting of team. nyortrine Transfer to a 17. or less container or storage vessel. Neutralize sotti oy f testless concentratton of a nyoocntortte solution ; to tota lly neutral t:e the nyora:1ne. Test for neutralization. Aftercontaminatec neutralt:stion transfer ints concentrat ton. Tnen son an eoval amount of a 5% or clotning pedo *e matertal te an accroortate container for proper otsposal, wasn all snown on tne front of reuse. In tne event of a large spill. call tne emergency teleonone numoer snis sneet. TRANSPORTATION EMERGENCY , CONTACT CHEMTREC 800-424-9300 , WASTE DISPOSAL METHOD l emoty cor: tainers anc materials useo in cleaning us sot 11s or Discoseinof a centaminates manner approvec o couct.f or tni s ma t e a t a l . Consult approortate Feceral. 5 tate ano local leaus regulatory agencies to ascertain procer otsposal proceoures. 4 l
. \
l
)
SECTION VIII - SHIPPING DATA D.D.T. Not regulatec SECTION II - REACTIVITY DATA t* O OOM C NAIMOOd5
- ST A51,.E x uNSTASLL AT F POLYMERIZATION lw1LL NOT OCCUA CCNDITIDNS TO AVD!D Cemcentration of mateetal ev evaooratton IN'DMP ATIEILITYlMATERI AL TD 'AVDID) wtit react witn oxygen.
oxicants, eeny metal extees anc ce-tain metal salts in tnet r noueous so)ut tons HAIARCDUS DEODMPDS* TION PRCDUCTS -- l 1mee*? ava-? af e s. SECTION % - PHYSICAL DATA 5 ev0Laf;LES Ne eats ; NEL TINO 231Ni .t**8 t vtPOR PRESSURE Ne cete iEvapORaTION Ad.T E ne os? _
~ e 0! L *. NG 901 TWT :;5 :
, solus 1L Tt th waT E A comos e-e C8*8-j iVAPOR OENSI T Y t t.1 R 81 i NO i PH
~E GECI F IC GRt- M?tM23*1i
- C 1 fr 6
e " '# DATE SN
.p s' see io t-to 7
' **'*" FURNISHED BY INFORMA~:ON : FURNISHED TO l ATTN: DEPT MsNDLING MATL SAFETY DATA SHEETS o,pertment of Ermtonmental Hygiene end Tontccl89F ;
P&C:F1 NJaLEAR SEkVI E g2031789 5436 2222 carg OR2VE ap R I CktL AND WA IS232 7 Vil.O CORPORATION 12D Long Ridge Road. Stamtore. Connecticut CE ne-c AN* N etwork
g MATERIAL SAFETY DATA SHEET . PACE 1 l f /r -;X/ /./ 70 l j PETRO!.ITE CORPORATION REVIS10W DATE: 02/14/89 l 369 MARSHALL AVE. F.MERGENCY PHONE: 1-314-961-J500 ST. LOUIS MO 63119 U.S.A CHMMTREC r.MER NO: 1 800 t
................................'.........................................-424-9300 SECTION 1 PitODUCT IDENTIr! CATION l
l l PRODUCT: CCIO801 TRADE NAME: N/A LABEL: 012 l Sil!PPING NAME: NOT HAZARDOUS PER D.O.T. CFR TITLE 49 CllEMICAL DESCRIPTION ACYLATED POLYAMINES AND A SULFUR-CONTAINING POLYAMIDE IN METHANOL AND WATER. SECTION 2 IIAZAltDOUS INGREDIENTS . CAS NUMBER MATERIAL 1 EXPOSURE LIMITS
** Sulfur-containing polyamide 10-30 Not Established f 1
000G7-5G-1 Methanol 1-5 ACGIll TLV: 200 ppm TWA OSilA PEL: 200 ppm TWA ACCIll STEL: 250 ppm
** Specific chemical identity is being withheld for confidential business purposes.
"~'
SCCTION 3 PilYSICAL DATA SPECIFIC GRAVITYllI20 e 1.06G0 r)i 1.030 VOLATTLITY: N/A VAPOR PRESSURE: Not Established SOL. IN WATER: Soluble APPEARANCE AllD ODOR: Amber liquid. Amine odor. *
.................................................................................... l SECTION 4 r!RE AND EXPLOSION llA7.AHO DATA FLASH POINT: >200 F FLAMMADt.E LIMITS: Not Establishe FLASH METHOD:
STCC ASTM D-3828 , EXTINGUISilING MEDIA: Use water spray or tog, alcohol-type foam, dry chemical or CO2. r!RE F1CHTING PROCEDURES: Use a self-contained breathing apparatus with full facepiece operated in pressure-camancl or other positive pressure mode .
*** CONTINUED ON PAGE: 2***
4 9
MATERIAL SAFETY DATA SHEET PACE 2
*** CONT 1HUATION OF'CC 0801 .
Non-flammahle. Keep fire-exposed containers enol using water spray. . 1
. 1 UNUSUAL TIRE AND EXPLOSION llAZARDS:
None known.
"s SECTION 5 IIEALTil HAZARD DATA I
EFFECTS OF OVr.REXPOSURE: ; INHALATION: l Prolonged or excessive exposures may result in respiratory 1rritation, headache and nausea. In extreme cases may cause CNS depression leading to dizziness, drowsiness and narcosis. l SKIH AND EYE CONTACT: Intermittant, brief skin contact may result in mild ; irritation. Proinnged contact with skin may cause moderate to severe irritation resulting in rashes and dermatitis.
~
I contact with eyes will cause moderate to severe irritation, and may produce moderate but reversible eye injury. l INCESTION: May be harmful if swallowed. Hay cause gastrointestinal distress with nausea, vomiting and diarrhea. - j EMERGENCY AND TTRST ATD PROCEDURES: i wash skin thoroughly with soap and water. If rash or irritation develops, consult a physician. I.aunder clothing l before reuse. If in eyes, irrigate with flowing water immediately and continuously for fifteen minutes". Consult a physician promptly. If inhsled, remove to fresh air. Administer oxygen if
.ecassary. Consult a physician if symptoms persist or exposure was severe.
Due to po:nibJa aspiratinn into the lungs. DO NOT induce vomiting if ingested. Consult a physician immediately. NOTE TO PHYSICIAN: Administer activated carbon if indicated. SECTION G REACTIVITY DATA 6 STABILITY: Stable under normal ennditions of storag- and use. l
. 1 INCOMPATIBILITY:
Keep away from strong oxidizing agents.
***CONTTHLIED OH PAGE: 3***
m e
.a 4
. Ea&AaaM
.ggggggg MATERIAL SAFETY DATA SHEET , s c ,.
3
*** CONTINUATION Or CCIOB01 *** .
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of sulfu*r'and nitrogen. J HAZARDOUS POLYMERIZATION: Will not occur. SECTION 7 SPILL AND LEAK PROCEDURES 2 ! IT MATERIAL IS SPILLED OR RELEASED: Small spill - Absorb on parer, cloth or other material. Large spill - Dike to prevent entering any sewer or water-way. Transfer liquid to a holding container. Cover residue with dirt, or suitable chemical adsorbent. Use personal protective equipment as necessary. 1 DISPOSAL METHOD: Place chemical residues and contaminated adsorbent materials l into a suitable waste container and take to an approved hazardous waste disposal site. Dispose of all residues in ' accordance with applicable waste management regulations. DECONTAMINATION PROCEDURES: , Not appropriate.
..................................................................................... l
- SECTION O SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION:
When concentrations exceed the exposure limits specified, use of a HIOSH-approved organic vapor cartridge respirator is recommended. Where the protection factor of, the i respirator may be exceeded, use of a self-contained i breathing unit may be necessary. VENTILATION: General ventilation should be provided to maintain ambient concentrations below nuisance Jcvels. Local ventilation of ' emission. sources may be necessary to maintain ambient concentrations below recommended exposure 11mits. 1 PROTECTIVE CLOTHING: Chemical-resistant gloves and chemical goggles should be used to prevent skin and eye contact. SECT 10N 9 SPECIAL PRECAUTIONS Avoid breathing of _vapnrs and contact with eyes, skin or clothing. Hazardous product residue may remain in emptied container. Do not reuse container without commercial cleaning or reconditioning.
*** CONT 1 HUED ON PAGE: 4***
- e a
W ' h$ * *,: #--Nis**
- h*L -]
&movAL 'f if <d o f
k p_ g N [ S @ . ' ,5 -{. ([ h 3 [ 5} h k h $ j h h $ c hM.!M[ hN . 6 M 10ENTir1CATroN MATERIAL SAFETY DATA SHEET i NAME Hydrogen' Peroxide (30 to 52%) GRADE Albone* 35, 50, 35 CG, CHEMICAL FAMILY 50 CG, 50 M: Kastone* Kastone* B; inorganic Peroxide Perone
- 30 EG, 35, 50; Tysu1*
505, WW35, W50 FORMULA SYNONYMS Peroxide . CAS REGISTRY NO. s flS NAME Hydrogen Peroxide 7722-84-1 l 10. NOS./ CODES PRODUCT INFORMATION PHONE NIOSH Registry No: MX 0900000 (800) 441-9442 MANUFACTURER / DISTRIBUTOR MEDICAL EMERGENCY PHONE E. 1. du Pont de' Nemours & Co. (Inc.) (800) 441-3637 ADDRESS TRANSPORTATION EMERGENCY PHONE
- Wilmington, OE 19898 CHEMTREC (800) 424 9300 PHYS 1 cat. DATA BOILING POINT, 760 m Hg MELTING POINT 0
106 to 114 C (222 to 2370F) -26 to -520C (-15 to -62 0F) (See page 2 for specific grades) VAPOR PRESSURE SPECIFIC GRAiITY 18 to 25 m Hg at 300C (860 f) l 1.1 to 1.2 (See page 2) (See page 2) l VAPOR DENSITY SOLUBILITY IN WATER l 0.8 to 1.0 (calculated) 100% pH INFORMATION , EVAPORATION RATE (BUTYL ACETATE =1) Apparent pH = 3.3 at s >1 30% to 1.8 at 50% APPEARANCE FORM Clear Liquid 000R COLOR Slightly pungent, irritating Colorless
- Reg. U.S. Pat. & Tm. Of f. , Du Pont Company. Albones , Kastone*, Peronee , and Tysul8 Hydrogen Peroxide are made only by Du Pont.
E-79896 Date: 10/85 l c - . ;-*.**~~.'. ':':.:':.':*.: :":~:::..".::.. .::*.- .::.: \
_..__ _ m , r < . F' IRE AND EXPLOSION DATA. , FLASH POINT Will not burn. AUT0!GNITION TEMPERATURE Not appitcable. t AUT00ECOMPOSITION TEMPERATURE Not applicable. EXTINGUISHING MEDIA
- II - Flush away with water. .
FLAMMABLE LIMIIS IN AIR, % BY VOL.- Will not burn, but decomposition will release oxygen which will increase the explosive limits'and burning rate of flanrnable vapors. FIRE AND EXPLOSIDH HAIARDS Strong oxidizer. Contact with clothing or combustibles may cause fire. l Contact with organic liquids or vapors may cause ininedtate fire or - explosion, especially if heated, or may result in a delayed detonation. Cool tanks or containers. Wear full protective clothing l SPECIAL FIRE FIGHTING INSTRUCTIONS T1ood with water. i (rubber suit and boots) including chemical splash goggles or hood and self-contained breathing apparatus. HEAT.TH HAIARD INFORMATION l PRINCIPAL HEALTH HAZARDS (Including Significant Routes, Ef fects, Symptoms S of Over-Exposure, and Medical Conditions Aggravated by Exposure) s .' May cause eye burni; effects may be delayed. 'Causes skin irritation or burns. Causes lung irritation. Harmful ^if swallowed. l Inhalation 8-hour LC50: >2000 ppm in rats (g0% H22 0) Skin absorption LD50: 700 mg/kg (90% H22 0 ); g200 mg/kg (70% H 022
. in rabbits Oral LD50: 75 mg/kg in rats (75% H22 0)
Toxic ef f ects described in animals f rom short exposures include irritation and corrosion of mucosalTests surfaces. Tests in animals for mutagenic activitydemonstrate in bacterial no or carcinogenic activity. manrnalian cell cultures have been inconclusive, with positive results in some studies, and negative (esults in others. Tests for developmental l l f activity (effects to the fetus) in animal species have been inconclusive, with positive results in some studies, and negative results in others. l 7ests in animals demonstrate no reproductive toxicity. s' kin Human health effects of overexposure may initially include: irritation with discomfort or rash, eye irritation with discomfort, . tearing, or blurring of vision, or irritation of the upper respiratory' eye corrosion with l ! passages. Higher exposures may lead to these effects: corneal or conjunctiva 1 ulceration, skin burns or ulceration, or temporary lung irritation effects with cough, discomfort, difficulty breathing, or [ There are inconclusive or unverified reports of human [g shortness of breath. s ens iti r.c M on. , l 4.r E-19E9s Date: 10/85 3 ,
~ - -
l l l . . i - more resistant to fire than natural fibers. Clothing fires and skin damage
< occur less quickly with 50% or less peroxide than with 70%-material, but
- i. adequate personal protecti'on is essential for all industrial concentrations.
Protective skin creams offer no protection from hydrogen peroxide and should not be worn. .
- I DISPOSAL INFORMATION
- t AQUATIC T0XICITY The 96-hour LC50 in catfish is 37.4 mg/L.
SPILL, LEAK OR RELEASE Comply with Federal State, and local regulations on reporting releases of water. Flood area with water and drain to an approved chemical sewer or wastewater treatment system, including municipal sewers if approved. May - be destroyed with sodium metabisulfite or sodium sulfite (1.9 lbs. 502 equivalent per Ib. of peroxide) after diluting to 5-10% peroxide. WASTE DISPOSAL Comply with Federal, State, and local regulations. If approved, may be diluted and drained to a municipal sewer or waste treatment plant. May be drained through a scrap metal pit (iron, copper, etc.) to reduce peroxide concentration. SHIPPING INFORMATION o 00T (172.1011 00T/IMO (172.102) PROPER SHIPPING NAME PROPER SHIPPING NAME Hydrogen Peroxide Solution' Hydrogen Peroxide, (8% to 52%) Aqueous Solution (20 to 60%) HAZARD CLASS HAZARD CLASS 0xidizer Oxidizer, 5.1 l UN NO. 2014 UN NO. 2014 00T LABEL (S) Oxidizer SUBSIDIARY RISK Corrosive
'Not regulated by 00T as a hazardous material, in tank cars and tank trucks.
l E-79896 Date: 10/85 5 O y
- y. g .
l ,
'. J.T.BAu . ,
- c. .o i
- C p ICALS J. T. Baker Chemical Co., 222 Red School Lane. Phi!!ipsburg, N.J. 0(865 WS.w -n -
- :: a. H.s~ ;.u. 3 5r m:. w .z. . > -tW::.sr ;n.. ._w.-'. 2. ...~~w-t.::,me.
. z.. .
J m .m t.g.<x.=m.<n.;.h.
- w. ;: . . m ,. g .,.c .y.w h=.v ema.w:o.w.,e,r:e.o=.=+-1,
, . .w .e . >. = .
c.:. n,J.t. e.,t.-6.:.a z;4 g;9 .s.,;P
- CHEMICAL NAME FORMULA i
3 Ammonium Hydroxide NH.CH l . 4 J SYNONYM OR CROSS REFERENCE CAS NO: 133 62 16 l . EPA NO: A106-1429
.. " "" \
. Ammonium Hydrate; Aqua ammonia - l i I l yI 0. -~Get.M:h> w a sea =>n=. l
=c. e . 7.:
3 4 Woaim.Ti'.. e.1.%c;.: p.,e
- .C&v.Z"-C
- r. .:-#.t'::c-i
- s. --- .
2.h$.
-u m- :+.. . e w.ar.,.E:3.h.a. x.,ge...
i: te . r.:, .'L. 4pr.mk : tW,?.
-m4 se.a... .... s:m<e.v :.,.m-..mm8s .+v_<. r:2 C.9..91.; cf.i.g=p%....W 1
I r MATERIAL NATURE OF HA2.ARD l } . i A:.t.d 1.-.. v.
.'*y .L T rh b c.-:.. er. -t.t s.7.- . 2;*[.?, ;H ! . .-... . .N . .,n.:v.% 7 .,-.T. . . c.'t ;.0 f.r.T. W --- .i : . . '.--W.h a -- c.1 J.
( BOILING POINT .MELTING POINT t .. . . . 2 i
-77.C. . i VAPOR PRESSURE SPECIFIC GRAVITY 0.9 .
i i VAPOR DENSITY (AIR *1) , PERCENT VOLATILE BY VOLU!.:E (%) WATER SOLUBILITY EVAPORATION RATE Complete ( =1) l APPEARANCE
- Colorless liquid with pungent odor.
P ',-;-:y9:.:f.id. e_
-G
'C '*** M..i.d
-dQ.rar D. . =2,8. , < #b' "M*'9 -
eJ N ',G.-T.'.W1:c::#;
=
3.A.w. p ;d T -h.:.'C: v. ?1?mers'rt
*s.,'-G,aN.=:i7:(-i.gPr st.
.H. Laa. "c#- i n; t i/2.9.T*:.W(.M.UEl-~O f...$ :::>. e:.
.T e :m. t ..
1
%W' '.esi"1.i,jE e:= ./t i FLASH POINT (metnod used) : FLAMMABLE LIMITS Lower l Uccer I
. FIRE EXTINGUISHING .
I M EDl A ' 1
- SPECIAL FIRE FIGHTING PROCEDURES i
UNUSUAL FIRE AND EXPLOSION HAZARD f t y ,i "r. . ",,.-4." Jh.,.,p..* 's..
- y-. L N.g ~-toNsc* .
- -<, .:,20~
.a .. ...--:
. .. 4** :s */.:% G9.
- -s ss .~'"^~~~;'-
^
. ,J.*T
-e a....., ~ ^uW J;~ *P
Y
~@'
' ~;* *'5 ".'".W.9.
X** L' '. "E.
- - . . .s . ?
- r . .: idj'.E.
l l ..;.'s.
, ,.., bis ".'.Q *h?.**e. *f~sa~.n
. d' .' i.* ** *' s'.t :~~~-''-*-~~?*-- -
j THRESHOLD Lluli VAL.UE
- /~ 50 ppm 4
- .
j HEALTH HAZ.ARDS
; Vapor causes severe burr.s. Vapor extremely irritating. _
FIRST AID PROCEDURES in case of contact,immediately flush eyes or skin with plenty of water f or . teast 15 minutes while removing contaminated clothing and shoes. If inhaled. remove to fresh air. If not breathing, give artificial respiration.lf breathing is diMicult.give oxygen. If swallowed,if coracious,give large amounts of dilute vinegar l lemon juice or orange juice and f ollow ,,im rnilk, or egg ,.hites beaten with . vater, C.a!! 15aa physician. Page J A
_ . _ __ ~m - - ._ ___m _ _ _ - _ - - _ - _ - - . _ _ _ _ _ _ . _
.- *.O *.
g' ..., . . r.. .=rn, r. . t., W.,.*p.s. .t:. C. .:= . u. .*..v. tv.:. .. :v., . . <::.. .. . ... i. ...:'.. . .. '. . )
. W,
, . r.).:::
. ..;. ~.. ... :h: '.-i,..
'. : .r..
1 ST A BILITY UNSTABLE I CONQlTIONS TO Avoto i . STABLE x Ao'Y6sc Acio; Chiososultonic Acid
- O.mennyt Sulf ate: Fluorme: Gold
- INCOMPAT and Asqua ABILITY Regia;(fr
- aterials Myotocn.oric to avoic)Acia: Hydrofluoric Acid;lodins; Nitric Acid;Oleum; Prop'electone (betal:
- Silver Nitrate: Silver Omide an Ethyl Alcohol:Silvee Omide;5ilver Permanganate: Sulfuric Acid
_ HAT /.ROOUS DECOMPOSITION PRODUCTS MAY OCCum CONOlTIONS TO,AVOIO j HAZARDOUS ! POf.YMERI'.ATION wtLL NOT OCCUR X e - e
~ .- m- --- .-6h6. - w h -e. , . s. -y-c q.vpn.se.
m.s=-if.-drTr.wAa,c--. dRG:-s.*W. n? -ad =~- T=.2.q r-#.Pf p.v. . e n b:~.%M. . p . u.u
.ng;1g::7.L..sm%;,.2?
2.~p-e --s.g r.: ..
- ~= -q:.%.::.a.;;
A: u Wk:. .s;m.:
\q..n.%;::p.- t.m. ..
I SPILLS . 5 Neutralize with HCt. Soak up with sand, earth or ver'miculite. Carefully rweep up and remove. -I ! i ] i O!SPOSAL 4
- Oispose through a waste treatment plant if local environmental regulations permit.
T (
- 1
- < ~x-*
i l.u.: q:e..p.%A.:p O.& wc,;.Y,.a,. : :: :z:: .:w.".v: o.. ~,.:\..t.n.,
- 1 s .a. oa: r. xM. q e;.r *7.a.c. .. . - - . q.:..w:+~.2i.:.s, .v. m, .n .;
rF-;. d.c..se-.. i
. .,. : :e. a:_.., - nm
.m ,: eg.s:t.re wbIsr :v >. ...r: i's.g
; o.i . : . .:j,.
.':< - ..-a. :. . . .-0 s1 - . . .:'w:- -.**' P. .9. .:a .-;;-
a:-
. .r:.u. ..r . m. .. .
. a, . . . ?s- .. .r. .
1 RESPIRATORY PROTECTION (specify type) i yENTILATION LOCAL SPECIAL 1 ' X n MECMANICAL (general) OTHER ! X ! EYE PROTECTION i ! PROTECTIVE GLOVES Neoprene gloves large f ace sh* eld i - a j OTHER PROTECTIVE EQUIPMENT Approved work.ms clothes
. . /.v: -n...,'. . . . . . - - . - . .
.. ,;, I.,.;. a,:.es - -s ., ;. 4T. +
e . se -- :- g*:
- y. ::..-s.y
. . .v..:,,
- .... . . . g". )
i!. ; . .
)
%..::ps .r,4 - w s i L. . - 4,- 3.ut.-pT* i .m y- .Q.- g , . i p t e- ::, ;.l . es.s e,..o .,=..
- l. ~6.
,t... .;p ,'ww .: s ~ ~.-3D. .,7---- " '.u.,';4 u%....f.;
- 8. g . . ,
g.. . . m. m. . . . .. .::. ,;t,y. t 'h y. .s.. -2.. - .*.. '[ p.. s'2.',*,*. . . :. , a,w&:--f. o . <. .5. - , . . .;- g'-:u :. w
. .. .. w
- t. .s . .
. . t..
} STORAGE & HANDLING ! Loosen closure cautiously before ogwening. Keep in tightly closed container. Store at room temperature not above :'E*C. (77'F.) Do not get in eyes, on skin, on clothing. A,oid breathing vapor. Wash thoroughly after j handling. .
..x.,,,... . 4
? ::,,. ... L : r.. ..:. .. ,r ::we :., n s : :: >.a ,... w . ;;.-.~. \ ....: . :.. n 1
.; ;:.i
- - . q N: . ; ,r ~ .y.
e* y:. -.~. {n@.w. u
../;.... -r . a . p n .p, .w.
-,,.M:
3 .. .r r- - -- -- - .'_.m
=. ;
~.. .: :r
-e. .:::. .wi.. . . +. . .. >w:.*i..s .. m: :. e. .-...;.:-:.
- . ...g. :.. .. .o. a. .y.'e.-
p ...... . . . . . . .
. .. . r. ! /
1
/ , -
1 4 I Ace . or I, fij
- o. i. .. ... m ._-[h*f- ume. : s.t. Mas-mT/e
- n. . a u. t cu. in :
io.. u .i.,.o su. ., on snm, no e c.,-..i.e s... . . ,,,,,,,, . e e.a e.. . .a. .. . . .. ,. i.o-.c .,
- n. .es.,-.i . .e a u . . . :. n . . . .- . . -, ,
...c . ... . . n . . m. . . . . . . . a . ..~ , i . c . ..-. . , . ,,a . ..u. . .. i n. . .a i . . .. . . ., . .. . . .
. e,ce.u.y........,,..........nu......,so,,,e,.,so,,,....,..-,...,,,.,.,...,,..o.,,..,u..a<.,.....:. rn.
- - . - . . , . . , . . . . . . . . . . . . . ...,-,,,.,.-.....,.....,,,,,,,,,, t.q ,,. . c. .,,
222 Acv SchuvL LAnc, gn g tL I Ps duxG o HJ G6ded J. T. a A A st CncFaCow C. u a T A a M dc I M A I L A 1 A L $A F i i r 24-MSun -MinwdNLY fcLePhdNc -- 1201) 939-4101 i l
'nEMTREC (Judi si 4-y 3s0 -- N A110t..L R c S vLt.s h Le n T E x & todol 429-ddO2 j PAGc: 1 AMMuniUM hYbd0X10c !*$$UED: 01/24/66 910 -U1 FCCTIVh: 1U/04/05 !
a a n n o s s u z z ScCTICA saas= s s a s = = =.= = a m a z z a s a s s a = = = 1 - P400LCT isciiTielC=T10tv s o mo s s s s a s = = = = = = = s 8:= = = s: s a s s = = = s s s s a cs s s s maz zz s = = == = = s COUCT NAMc: AMMONIbM MY ORU A I D-c 74H40H
.RMULA: 'RMULA nf: 36 05 .S NO.: 01336-21-3
- 309o2scuc l ,
I:C3n/R T dC3 N0.: AMPUNIA SOLUTION; AGUA AMMONIA ';rMCN SYNONYMS: 4 6 0 7,9 7 30,97 3 3,5 3 50,9 719,9 7 29,5 3 5 d ,9 7 21,9 731, 5019,9 7 20,313 e l 4CDULT ;00ES: maanaa =================susassss============================= PRECAUTIONAkY LAchlLINb z=ss=====szaa======= 33 ass =.3===============ss==zs========ss========3ms======== axhk S.F-T-DATA (TM) SYSTcM HEALTH - 3 (e01 SON) FLAMMao[L11Y - 1 REACTIVITY - 2
- CONTACT - 3 (CGRdOS1VE)
A S CR A T C.tY PdGTECTIVE hwu1PHENT L E5 L 5HIELJi La5 CUAT C a P AL.14 VeAT HCOUi PdLPck JLOVe$
~ KEC AU T I ON AA Y LA6dL STArenEhis F0I50N A A G L-M CAUSES sUnh5 VAFUR EATRcMhLY 1RRITATING MAY BE FATAL IF SWALL0ndQ .3 NOT GET IN EYES. Ca SAIN, *N CLOThinw. USd 41TH AJE'auATE 30 NOT 5AEATHE VAPCR. Ahc7 la TIGnTLY CLOSED CONTAlacA. .ENTILATION. WA3H TNGROUuMLY Afick HAfiDLlHG.= = = = = = = = = = = = = = = = = = = = = = = = = = = =
- ssos=======================================05 ScCT1Jn 11 - haLAk00 CCMPONcNTS ====
=======s======================================== 2 CA
- su========================GdPuhthT C 20-30 1336-21-6 A.".MC N I UM H YU F.C X I O 2 ====================================
====s==================================== SdCTICh III - PHYSICAL OATA
- ssus:======================a====================== Y APUA P RCS3uKd(MM ngl: N/A 3DILING PCINT: h/A n/A VAPCA QENSITY(AIR =L):
MELTING PGINT: N/A kV APORA TION AATC: N/A
""ECIFIC uRaviTY: L.iO l t ouT YL ACcI AT c811 l (niC=tl LudPLETe (IN ALL PnuPukTAUNSI '4 VdLATILc5 BY VOLUMc- 100 iCLUJILITYinibl*
CUhTI.svug Un PAue: 4 Pace 15 c
224 Acu s o n g y L L ,.:, c , p h l t L I P h w u h *w e NJ doe 6s
\rAncn c., E t' l C A L CG.
.; A TA a n a h T
. M A I t. x 1 i. :. A > i T Y s.i-rCus 2!' = no t..L Y Tr.LLPnu..J -- (40L1 e24-2131
.HhmTAcc 4 f Cut 4,4,-9Ju0 -- ri A T uNAL ac3rCruk LE.NT-n - (o001 444-ooc 4 PAGE: 2 AMM3NI UM r1Ycauxlue lo -ut IS3utO: 01/ 24/ so EcrivE: IC/04/05 SSS2 3 ss ssass 3 = s ssssss ss s sss ss aa rza s s3J a zz saggass a ss atz z z z ats s sss ss=&s zz asssa
,SVLIION III - PHYsILAL UATA (CLNTINuiD1 5 38 S S a s a z z s 3s E E E ass a z z E a z3 3 E s s E s3 s a s 2 3 3 Ss 3ss3 35 s E=2 E233 33:3s S sEs S E =3 hAAANCE 4 000R: LLcAk CULUALC*3 a $0Luf!ct. niTM A sTRChu OCOR.
s as s m a s s s s a z z a z z a s s a s sa r za s s s s = = s s s ss a zz zsz u s s s a n s as as s,2:s e sz= ==== s e ssa ns 3ECTION I V r: 1Rt AreC dxPLOS ALA MALARO DATA s a ss a ss e s s ss s s z a s s s s s NFPA s = =704M s sDATING:= = s s 3-1-0 s sa s s s s a s u
.SH FulnT: iJ/ A .E kATIhGutSHING nEU1A USE EATIhGU13H1HG MEDIA APPROPRI ATE FCK SuARouacinG F IR=. .C1AL F I k E-F 10 ri T I t:b Pd*LcDuds3 FIAEF13nTE45 anGLLJ aEAR PKGPed P AGTELT!vi c401eME.NT At<0 icLF-CONT AIN ERh Airif t:G APPAXATus n!Tn FULL i aC EF IEtc OPERATCC in POSIT!ve PRE!SURE
-4fC GASES PRODUCc0 AMMuisIA s a ss a z zz ss s ssss sSLCTIuN.y ss s== = =sa zza zz=a z zzz s =ss z z asazzz= ssz uz as s nc ALTH nAIARO CATA
- s:s===ss====== sse i s s,s = = = = = = s s = = = = = = = = = s s : s = m s s = = = = = = = = = = = a 3 : : : : : : t : : : :
LUSD (OnAL nAT)(du/nG)
- 330 t! CITY:
=i:C T S uF CV C hk APD:.o u.sc CG! T ACT niin Jrs !N CR tYds MAY ' AL St SEV6ns lxRITATION Od sURNS.
!AnALATidh GF v FOP.S nxY L AUS E C0bGNINJ, CniST P A l t, S , v1FFICULTY d R d A TH 1 *io Cd UNCONSCIDUShcS3.
II.G E S T I Ot. r1 A Y CAu3e SEVERE Suxn1hd TD ricuTH ANu $TunALn. ERGENCY ANO FIRST AID Fx0CIUs/dE3 CALL A PnYSICIAJ. IF 5'a AL LC'4& C . v0 NUT 1hJVCE vualTihb; IF CUNSCluub, olVE LAAGE AMCulviS UF WALER. IF lt. HALE 0. 3'iMCvi TO FedSn 'Ald. IF Nur ORE A THIi4G. dive AdTIFICIAL R c S F I d A T l uN ,, IF 5A4AThlNG is 01FFILull. GIVE CAYGc.i. IN CAS'c UF LChTACT* IMMC01ATcLY FLUSH EY:S un sAlh niin PLENTY UF wxTE. AT LEAST 15 d!NuTd; aHILs den 0Vit 6 CONT Adit;A T Eu LLO!n !NG ANO SnGES. ASM C L GT H I t. *, cierGn2 RE-uih. is========s========22:=me===========,,=,,=====.============:='================ acCTIGN VI - HEACTIv1TY CATA
=================================
-:s===========================================dLYMEnlAATION: MAlekLdu3 P aiLL uCT ULwUd "AdILITY: iTAJLc INDITIGNS TO AVOIO: NEx1
.CCMP A T I cL*d5 : lifRGN) AC1v3+ F L O O R i f.{.
I C C.".P O 31 T I L A pkC;ULTd: Artab it A
- C.:hiistuce Gin eAal: 3 Pace 15d
. - - . . - . - ~ . - - _ - . . -._- _
. ~,
ice A4v sensvt L . .q , entLLivausnw. 4s casos s n c .* ! L .. L cv. 7
* */ (.cAA:n 4 A T c A1 A L 5 a ec I y s. I a Jn c 6 T J4 nwen desdddNLY T c L iP h6..c . -- 1J01) siv-4151 j
h cme.-TRei u (JJJi ves-v300 nAI!ChAL'd6SruhS= tchIcd 4 IdOUI %J4-ddC2 1 PAGE: 3
-MMuslun NYOACx10e I5910 -el 10/u,/ D ISSUhu: 01/24/$6 FFLCTivc: 32s3333333333333 4 33 3 33 3 3 33 3 3 3 3 A s = = 3 3 3 3 33 3 3 3 3 3 3 3 2 3 3 24 3s 3 3 3 3 3 3 S:23 33 3 3 3 3 3 3 3 = 3 .
SeLT!un vil - 3 FILL Anu c1hvaS=L PA0CdCUAcs l l = S W = = E E 2 2 2 3 5 8 8 8 = 3 = = 8 3 8 = = 2 3 = E = =33 3 3 333 33 3 3 3 3 54 3 . TEPS TO Li TAAEN th in0 cVc.11 CF A SPILu CR OIatnAKG6 STC l I We=R ScLe-CusTA1AED sREATHIN. APP AAATuSAndA. VENTILATE A.ed FULL PdLT6LTIV6 LAAEFULLY CLOT nduTAAL126 , LEAA 17 YCU CAN CO 30 alinuuT KISA. SPILL hlTH UILUTC HCL. FLUSM AKdA WITn FLOGOINu A.4UUN T 3 OF WATcR. (USE C 4uTI Oh. ) I J. 1 uAKER NduTAdLII-2(R) CAUSTIL NhdTkALIZIR IS AECbaMENDEC FOR SPILLS CF THIS PA000CT. < ISFUSAL PACCs0U4c 013FOSc IN ALCORUAhCc *1Tn ALL ArPLILAdLk FcCh4AL, STAThe AND LOCAL 1 eNVIRONMcNial REsVLATIO.sS. 0002, J003 (CCEROSIV6, A6 ALT 1vE 'aASTC) **zzs=
.PA HAZAACOu3 dASid NUMmeA: ,
assz:=================8=8:=*==s==========sas==msasazzz=ssss=*==s***==**** a:CTIC, VIII - FAOTELT1vE iwu1PMENT l s=====================s=====s::=======23:=s========================= l v$E ADEQUAT'c u2HERAL Oh LCCmL ExnAUST VdNTILATION
.' E N T I L A T I C:4: Tu Khk/ VArv4 And MfJT LEvits A4 Lc, AS POSSI6Lt.
J EsFIRATUxy FACT:CTICN: huhi R aufn2O ancKc AOcwUATE VdNTILAT10N l LUdu!TIONS hAIST. IF AidBvKnt LONCdhTRATICh IS I olun, A LnEHILAL CAxid!L E u AESPIRATOA n!TH MM041A/ AMINE LAATAluut 15 neCOMadNUs0. IF LARTAIDJi LChLcNTRAT10h dALeewa .APALITY se dESP1K. TOR, A 5 ELF-CsaTAINE0 oneATn1Nu APPARATUS IS AGVIStD.
;AFcTY uds,Les AND FACL ShlELD, UNIFUMM, h/ SKIN PROTiCTICf. FRCTcLTIVe $UIT, xvcac< uLUVES ,,__,_=,=____==,,_,,,
Adi AcCOMMENDED. =,_
-===================:=======,,=,,=,,_,,==_,,,==,,_,_,,CAVTIONS 56LTICA IA - STCRAuf a40 nAieOLlHG PRh
====,,==============================
==s====a:===================,============,=ic s ant ain1Fs SAF-T-SATA (Tdi 510AAod LLL0k LO'E:
SPECIAL PKcCAUTION3 KecP CJhTAINck TIGnftY LLCSED. STUki in LORKOSIGN-PROOF AREA.
=====================================::
========================================TA (Aah590*TATIJN n UA Aa0 A*dlTICNAL 1hF0AMATICN SECTION K -
========ss=========s:==============s================
CCMfSTIC (U.u.T.) PRCPdR >H1991NG hams .MMUh!UM HYUXLAIC5 (14-**4 AnMONIA1
*
- Z ARU CLASS c u AR US I'v t matin 14L (ca.ulG)
;' Adol 2
/NA cOAAU31Ve
.LELC !
R=FORTAcLe LUANTITr 100s Lei. CUNTi.%uca CN / *< .> d ; n Page 15e
. e . .
,,h 1 L L ! r a u sK d e NJ Uo=c3
. e. .
a. a A c t. .* d .' a t g so. s,,,4 Ac. ggnygt t, . .. g , 3 a i" c ! y V a T ,. :, n c a T
/* '4 A I C 4 1 A L J - n .e'J e. c !' c n o hi4L y T c L c.r'nu'4d -- tic!) osv-elsi
(:UUl n c ., :t 2 0., -- a i I LW A L n c A P Oi.a c C t.4 T ' x ., f00V) ae d de-coV4 nc.*TkcC a i t' A G E : 4 AMMCid108 etVOXwAICd c, -01 Is5udD: Ul/2t/dor j LTIVd: Iv/04/36 ========u========================== 1 s
' de. T s 1e".;i; s =a = -= =I b= is7..niaTIC.i
= = = = = = = JATA = = = = A.,
= =u a= JiL
= = = = = = = = = = = = = = = =I T I U ts e. L i ..N AM
- ss=s===========================================================
19 ,
- I
- xN A T I Ct. A L II.".C.) 3hd S:11 P 71: 6 .d AP.c Ae4ndislA J3Lu f luei$ (lu-25A AMM0nlAl J aKO CLA33
.A UNdoT4 iLS CundOSIVE
as======================================================
1 A.dD (a) C'cSIGNATE Ixabchanns. a .% T APP L IC Arild Ca .svi AVAILAuLs I N r C F..M A T 10t. PocilanEO lh Tnli H TcRIAL SArcly LATA sne:i das bisN COMPILE 0 vux c AP D'. l b.v C d
;= 0 gat A PhGsE.vTeu lis vA410Ud TCCnNICAL PU:s L I C A T I ONS . IT 15 vild ' $ ac SPOddl: ! LIT Y Tu DETedHine Tne 30tTAclLITY uf Tnl6 li. F O Rt4 A T I C H AOCP T !Ori Lf- NECESSAdy S AFiiTY PREC AvilGr.s. aE nE5 cave Ine AlunT TO Xhv156 iAIAL SAFdTY 0ATx Shc=73 PtAldu!LALLY Aj N2a thFGnMailwh ocCCMtS AVAllmcL6.
-- LAST sAbE e -- l l
I L
. Fa;e 15f
- _ . _ . _ _ _ _ _ _ . . . _ _ _; .7 3 . a.,)aiert;: batety v.ata sheet w r id
. U.S. Departmerd of Labor .'
a as % = -
%- - _; % ,,,, ,s , %
OSMCs Mazars Comrwecanon 6--_ ; m 1 _ . .
- a ss CFR teso.utn. maammes mum he '- -*M
! .,eormass kr speedic - -6 .
Bulletin 134 ) , lacxTTTT (Aa &ases,an Lammt W Lee . - . i aanna an== ammen me amt s==med amar he a amr ====== e an _ wttvnf Tve A-600 OM Tea M ..c. v. 4. 88=====ma a amma, me amass sww me ===ms e amame am, j >ecSon !
} a n., <
. . . . . _ _ . . ., T r minaar - - - - - -
Parolite. Company 215-668-9090 ! p'er==s r?. 7s ,f==. Car. h **8 & Cans / ." fj .jpJe.,aner er summmma , ,,,,. ] 150' Monument Road 215 #68 0090 j Eala Cynvyd. iA 19004 . . . o p, ,.m . - i j December 23, 1985 . e . i / 59=nes
- Pas == m==r=t -
j Sec_:,m N - Ha.=ardous ingredientAMentfty information i On=r t. mum j m caneuwus tso=cr6e chament knarer Cm Nuns (sn C6HA PC. AC004 TLY
- -... 6 mm
%ne
) i 1 1 / . ( t .i . l ._. .. . . ~ . . . . . ! See:-m Lu - PhyskauchemLaj C:.ars.:.ertrecs - t W Psms
- spease camer tinog -
l N/A 1.1 i ~n . p== nc,a a i m ras - ' l w/A ' e - sn o. . ,- ivnourI.-_y Wa 4 . . % n-e e -a . . " 3 N/A .
&W h=== .11
] a- = n waar Negligible 4
- A r - - w are o mar j
t Vnite spherical beads - amine odor - 1 i Wa N - N su! E::plosion Rs:zrd oat ' P="n Ptus Ww u==q rw miga,sm,. g,g,, g . No flash co4nt . E-- v- - v h . j . CO.,, dry chemical ~. vater f og - J Eo=== Fw F 9 vg Pnua=was j Wear OSKA/NIOSH aceroved. cressure demand, celf contained bre.tM ar apparatus j h Fra arw f.gmanian renamros " l None. .
. P*9' 1 6 w e ^"**= W
=ac= 160a -
J
- , e '
o, ,- WiW" i - Dulletin 134 l'* 4 i 5.ecthan V - Nacuvtry Data-i ' ! > 6m===== l c ===== m a=== - i I smes= t I Avoid temocratures over 60*C (140*T) W M W " * . 4.a 4 ,s ......_.45.
,. . . . . e , et afrrfe aeid. e .ar-eae en444 '- ree-:2 euwama %~ er hypensaNH, . CH,NH, and relat ed a=ine s . CO . CO. , styrene. divinyl benze:.e eu.s.a.com.m w.sy Cms ]
m__ r_,-_
.. 'l Camasrm a A.es s
W *** CN l1l . . f S ce,on VI - Health M*-ud Data _ ., c,.r. -r w . .. - I . None Hone
* * * * #""
- Resin is a strongly alkaline material - -
i . W C aa m ogramasr CW 6; - M cm y g . MTrr . N/A - i j s.gra ama r, . aOrn , 4 Ey(contact. May cause =mchanical irritation like other forci;: i
' " W ^~"
- w wr s tv E-n ,.
bodies. ! EN ** *
- Eye contact. Flush thoroughly, call physi: iso if irri ati n _,
l - nerstses. t - i secm vil - Prec.2ue:cu tar Safs Hand!!ng a.nc Usa ' - -
"wE" .s..e n. .-.. .
r o.no6.T.snaC - m asT oechanic:2.3v cause ' 3 Resin beads on floor vill E -
<- to be slippery.
Sweep uo thoroughly and set aside for recovery or dir:osal. t . i i
- P E .'.ccpt unere odor is *Ijec?[bst.17this =.2tcri.r.1 cs: be disposed of &&
j erdinarv frash. d;. :e
--m e 6. Tu.arvn nerounc ars % Keep dru=s and plastic bag liners sealed to prevent l &
J and to contain odor. can- e ~-w _ S: ore belov 4C*C (120*T) and above.0*C (32*T) 3 _ j i i i Se. ion Vu!' Cc.ntrol We=" us
! ." ; -y rum.czan. M T fpv Hone i -
j % L~ - W ;omi roc = venti..a:1on l 3a=== _ 1 { w. m wwas f=r==r l O'= Safety classa.s (A."ET ~87.1)
.}}