ML20095G784

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Change 95-086 to Rev 4 to Technical Procedure CP-217, Specs & Surveillance:Secondary Chemistry
ML20095G784
Person / Time
Site: Calvert Cliffs  Constellation icon.png
Issue date: 10/12/1995
From: Eshelman E
BALTIMORE GAS & ELECTRIC CO.
To:
Shared Package
ML20095G750 List:
References
CP-217, NUDOCS 9512210287
Download: ML20095G784 (26)
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Text

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1 12/4/1995 11:01:07 USER CONTROLLED CALVERT CLIFFS NUCLEAR POWER PLANT O TECHNICAL PROCEDURE CP-217 SPECIFICATIONS AND SURVEILLANCE :

SECONDARY CHEMISTRY l

REV.4 PCR 94-049 l

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12/4/1995 11:01:07 USER CONTROLLED Page 2 of 25 RECORD OF REVISIONS AND CHANGES EVISION CHANGE NUMBER NUMBER

SUMMARY

OF REVISION OR CHANGE 4 94-089 ATTACHMENT #2, SULFATE - VALUE BEFORE 5% POWER COLUMN, ADDED 'BEFORE 350F" 4 94-109 ADDED CONTROL ROOM HABITABILITY PRECAUTION TO SECTION 5.0 ADD ETA SPECIFICATIONS AND SURVEILLANCES TO ATTACHMENTS #1,3,4 AND 10 1

4 95-044 ATTACHMENT #1, CHANGE CHLORIDE ACTION LEVEL 1 VALUE l TO >20 PPB l ATTACHMENT #4, IRON & COPPER ANALYSIS FREQUENCY CHANGED TO >80% POWER FOR >5 DAYS AS DESCRIBED IN ,

FOOTNOTE 1, ADDED SPECIFIC CONDUCTMTY PARAMETER l WITH FOOTNOTE 3 BASED ON MCR COMPLETION ATTACHMENT #8, DELETED COLUMN FOR "VALUE BEFORE PUMPING FORWARD", ADDED FOOTNOTE 1 ON SUSPENDED SOLIDS SAMPLING FREQUENCY, ADDED IRON PARAMETER AND FOOTNOTE 2 STATING FREQUENCY IS "AS DIRECTED BY SPC."

ATTACHMENT #10 REMOVED CATION CONDUCTIVITY SAMPLE FREQUENCY COIJDiTION FOR AMMONIA, HYDRAZINE, ETA AND MORPHOLINE, REMOVED SPECIFIC CONDUCTIVITY SAMPLE FREQUENCY CONDITION FOR CHLORIDE AND SULFATE, ADDED FOOTNOTE 3 4 95-080 PAGES 10 AND 11, ADDS REQUIREMENT TO NOTIFY SPC & RECORD TIME OF OCCURANCE FOR COMING OUT OF AN ACTION LEVEL 1 &

2.

PAGE 114 D (2) (B) THRESHOLD WAS ADDED TO ACTION LEVEL 1.

PAGE 14 ATTACHMENT #1, CHEMISTRY HOLD FOR START UP IS CHANGED FROM 5% REACTOR POWER TO 10%.

PAGE 15 ATTACHMENT #2, ELIMINATES 5% START UP HOLD.

PAGE 18 ATTACHMENT #5, ADDED COLUMN VALUE BEFORE >30%

AND INCLUDED DISSOLVED OXYGEN VALUE OF <10.

PAGE 19 ATTACHMENT #6, REASSIGNS 5% CHEMISTRY HOLDS TO 10% POWER HOLDS.

PAGE 21 ATTACHMENTS #8, FREQUENCY WAS CHANGED, FOOT NOTE 2 WAS MODIFIED TO CLARIFY SAMPLING CONDITIONS.

4 95-086 PAGE 18 ATTACHMENT #5, REMOVED COLUMN "VALUE BEFORE

>30%" AND REPLACED WITH FOOTNOTE (2).

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I CP-217 12/4/1995 11:01:o7 USER CONTROLLED l Rsv. 4 i Pags 3 of 25 l TABLE OF CONTENTS l

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ECTION TITLE PAGE I 1

! 1.0 P U R P O S E ............ ... .... ... .......................................6 2.0 APPLICABILITY / SCOPE .. . . .. ...... .. .. . .. . .. .. .. . ...... .. .. ... . . . 6 l 1

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3.0 REFERENCES

AND DEFINITIONS . . . ...7 I

A. Procedure Development ........ ............... . . . . . . .... .7 B. Procedure Performance .......... ..... .......... ..... ........... ...... . . 7 C. Defi n itions . . . . . . . . . . . . . . . ... .. . . .. . . .. . .. . . . . . . . . . .. . . .. . . . . . . . . . . . . . . . . . . . . . . 7 4.0 PREM EQUISITES ... . . . . . . . . . .. .. .... . .. .. . . .. . . ... . .... ... . .. . . .... . . . . . . ... . .. . . .. 8 A. R espo nsibilities . . . . .. . . . .. . .. . . .. . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . .. . .. 8 B. Specifications and Surveillance . ..... . . . . ....... ... . . . . .. . . 9 5.0 PRECAUTIONS . .. . . .. . . . . . . . . . .9 1

6.0 PERF ORMA NC E . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . .. . . . . . . . . . . . . . .. . . . . . . . 10 A. Su rveilla nce .. . . . . ... . . . . . . . . .. . . . . . . . . . . . . . .. . . . . . . .. . . .. . . . . . .. . .. . .. . . . . . . . . . . 10 B. Speedications and Special Corrective Actions. .. . . 10 C. Genenc Cormction Actions .............. .. ....... .. . ..... ... .... . 10 D. Out of Service Monitor .. .. . . .. ...... .. .. . .... .. .... . ...... ... . .12

.0 POST PERFORMANCE ACTIVITIES ... ........... ... ... ... , .12 8.0 BASIS . . . .....................12 9.0 RECORDS .. . .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................13 ATTACHAMENTS Altschment 1, Steam Generator Cher 'stry - Power Operation (Mode 1)... .14 Attachment 2, Steam Generator Chemistry - Hot Standby (Modes 2,3 & 4).15 Attachment 3, Steam Generator Chemistry - Wet Layup (Modes 5 & 6) ... . 16 Attachment 4, Feedwater Chemistry - Power Operation (Mode 1) .... . . ...17 Attachment 5, Condensate Chemistry - Power Operaton (Mode 1).. ... .. ..18 Attachment 6, Steam Generator Feed Source - Hot Standby (Modes 2, 3 & 4) . . . . .. . .. .. .. . ... . ... . ... . . . . . . . . . .. . . . .. . . . . . .. . . . . . . . . . . . . . . . 18 Attachment 7, Main Steam - Power Operation (Modes 1 & 2). ... ...... ..... .. 20 Attachment 8, Hester Dram Tank Chemistry - Power Operation (Mode 1) ... 21

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i 12/4/1995 11:01:07 USER CONTROLLED Rev.4 Page 4 of 25 TABLE OF CONTENTS (continued) nt 9, Condensate Storage Tank Chemistry - All Modes.... ............ 22 Attachment 10, Individual Condensate Demineralizer Effluent -

Power Operation (Modes 1 & 2) ............. ........ .... ................ 23 Attachment 11, Condensate Domineralizer Regeneration Specifications....... 24 Attachment 12, Steam Generator Blowdown lon Exchanger Effluent -

Power Operation (Mode 1) ... ... .... ............ ... . ................ .. . ..... 2 5 i

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i 12/4/1995 11:01:o7 USER CONTROLLED CP-217 Rsv.4 Page 6 of 25 1.0 PURPOSE This procedure provides the Chemistry Specification and Surveillance Program for the  !

steam generators and associated secondary systems.

2.0 APPLICABILITY / SCOPE i l

A. This procedure is applicable to the Plant Chemistry Unit.

B. This procedure is applicable to the Chemistry Programs Unit.

C. This Chemistry Specification and Surveillance Program is applicable to the following systerns:

1. Steam Generators (All Modes)
2. Condensate Storage Tanks (All Modes)
3. Feedwater (Mode 1)
4. Condensate (Mode 1)
5. Main Steam System (Modes 1 and 2)
6. Heater Drain Tanks (Mode 1)
7. Steam Generator Feed Source (Modes 2,3, and 4)
8. Condensate Demineralizer Emuent (Modes 1 and 2)
9. Steam Generator Blowdown lon Exchanger Effluent (Mode 1) .

1 This ram is based on Technical Speedications, BGE's interpretation of industry l stan a and recomrnendations made by Combustion Engineering. It ensures a timely I response to chemical and radiochemical excursions with appropriate corrective actions.

Remedial actions are specified to minimize corrosion degradation of components and to ensure that secondary system integrity is maintained.

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3.0 REFERENCES

AND DEFINITIONS A. Procedure Development i

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1. Technical Specification: 3/4.7.1.4 4 2. PWR SECONDARY WATER CHEMISTRY GUIDELINES: REVISION 3, Electric l Power Research Institute, EPRI TR-102134, May 1993.
3. COMBUSTION ENGINEERING CHEMISTRY MANUAL, CENPD-28, Revision 3,

, September 1982.

4. GUIDELINES FOR CHEMISTRY AT NUCLEAR POWER STATIONS, institute of Nuclear Power Operations, INPO 88-021, Rev. 01, September 1991.

B. Procedure Performance

1. CP-102, General Information Records
2. CP-108, Chemistry Technical Evaluations
3. CP-224, Specifications and Surveillance - Unmonitored Radiooctrve Effluent Pathways and Primary to Secondary Leak.

C. Definitions l

1. ACTION LEVEL 1: A value or range of values for a chemical or radiochemical parameter which:

(1) is inconsistent with Chemistry Section goals, (2) indicates an adverse trend has developed, or 1

(3) indicates long-term impacts simuld be anticipated or expected

2. ACTION LEVEL 2: A value or range of values for a chemical or radiochemical parameter which:

(1) exceeds a Technical Speaficahon or other govemment reguisbon, (2) indicates an adverse trend has 65, or (3) indicates short-term, adverse impacts should be anticipated or expec6ed

3. ACTION LEVEL 3: A value or ra of values for a chemical or radiochemical parameter at which it is not advisa to contmus unit operation due to the potential immediate impact on system integrity.
4. C/DR-W. measured, daily recording of reading, instrument response venfied wee
5. ETA Ethanolamine or monoethanolamine (MEA),A morpholine analog. Pcn n-m O

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6. FULL-FLOW CONDENSATE POLISHING: The state where most l (e g. >90%) of the condensate flow is routed through the condensate polishers.  !
7. PARTIAL-FLOW CONDENSATE POLISHING: The state where condensate polishers are not full-flow.
8. PUMPING FORWARD: When the discharge of the heater drain tank is routed to the i condensate system downstream (forward) of the condensate polishers.

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9. TARGET: The value or range of values for a chemistry or radiochemistry parameter which represents a goal or a predetermined warning Emit. A TARGET is not a specification.
10. TECHNICAL EVALUATION: A formalized, documented assessment of a chemical or radiochemical excursion.

4.0 PREREQUIS7S A. Responsibilities

1. Technicians are responsible for sampling, analysis, documentation and initial notification of the SPC as indicated in this procedure and on the attachments.
2. The SPC is responsible for:
a. Ensuring all surveillance frequencies prescribed by this procedure are met.
b. Ensuring that the GSC and the Shift Supervisor are notified of Action Level conditions.
c. Ensuring all Technical Evaluations required by this procedure are initiated per CP-108.
3. The GSC is responsible for ensuring Technical Evaluations required by this procedure are performed in accordance with CP-108.

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12/4/1995 11:01:07 USER CONTROLLED Page 9 of 25 B. Specifications and Surveillance Specifications and surveillance shall be performed per the following Attachments:

ATTACHMENT No.

STEAM GENERATOR CHEMISTRY - POWER OPERATION (MODE 1) 1 STEAM GENERATOR CHEMISTRY - HOT STANDBY (MODES 2,3 & 4) 2 STEAM GEERATOH CHEMISTRY-WET LAYUP (MODES 5 AND 6) 3 FEEDWATER CHEMISTRY - POWER OPERATION (MODE 1) 4 CONDENSATE CHEMISTRY - POWER OPERATION (MODE 1) 5 STEAM GEPERATOR FEED SOURCE- HOT STANDBY 6 (MODES 2,3 AND 4)

MAIN STEAM - POWER OPERATION (MODES 1 AND 2) 7 HEATER DRAIN TANK CHEMSTRY - POWER OPERATION (MODE 1) 8 CONDENSATE STORAGE TANK CHEMISTRY - ALL MODES 9 l l

lNOMDUAL CONDENSATE DEMINERALIZER EFFLUENT - POWER 10 1 OPERATION (MODES 1 AND 2)

CONDENSATE DEMINERALIZER REGENERATION SPECIFICATIONS 11 STEAM GENERATOR BLOWDOWN AON EXCHANGER EFFLUENT - POWER 12 OPERATION (MODE 1) 5.0 PRECAUTIONS 5.1 Achon Levels rney be waived only after QR or PRC or PORSC review & royal Authority signature 5.2 New bulk pH additrves must be evaluated for Control Room Habitability prior to rca use. w. sos O

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12/4/1995 11:01:07 USER CONTROLLED Page 10 of 25 6.0 PERFORMANCE A. Surveillance

1. VERIFY surveillances in Attachments 1 - 12 are performed.

B. Specifications and Special Corrective Actions  ;

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1. COMPARE surveil?ance resun to the Target, Action Level 1, Action Level 2, and Action Level 3 values listed on the respective attachments, AND PERFORM any special corrective actions required by the attachment.

C. Generic Corrective Actions

1. VERIFY that all information is docurnented per applicable Chemistry Procedures.
2. IF Target is exceeded, THEN
a. NOTIFY the SPC.
b. DOCUMENT notification in appropriate record.
c. IMPLEMENT correchve actions as directed by the SPC.
3. IF Action Levellis exceeded THEN:
a. RECORD the sample time as Action Level 1 time of initiation in appropriate record.
b. NOTIFY the SPC AND RECORD notification in appropriate record.
c. NOTIFY the Shift Supervisor, as directed by the SPC - EXCEPT as noted in applicable ettacts,ent footnote - AND RECORD notification in appmpriate record.
d. RESAMPLE AND ANALYZE the aflected parameter as soon as prachcal, or as directed by SPC, to venfy entry into the Acbon Level 1 conde'b'on.
e. INCREASE surveillance frequency as directed by the SPC.
f. RECORD the time when out of Action Level 1 AMD NOTIFY pen SPC and SS, as d by SPC. se.

oso

g. IF a parameter has not cleared Action Level 1 for at least 24 consecutive

. _ . hours during a seven period following the Acbon Level 1 time of initiation, THEN PE AM Action Level 2 responses for those parameters with Action Leve! 2 values.

h. IF the parameter has not cleared Action Level 1 within seven days following the Acoon Level 1 time of initiation, THEN INITIATE a Technical Evaluation per CP-108.

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4. IF an Acton Level 2 value is exceeded, THEN:
a. RECORD the sample time as Action Level 2 time of initiation in appropriate record.
b. NOTIFY the SPC, and the GSC as directed by the SPC, AND RECORD notification in appropriate record
c. NOTIFY the Shift Supervisor, as directed by the SPC AND RECORD notification in appropriate record.
d. AS necessary, ADVISE the Shift Supervisor of plant corrective actions applying to Action Level 2 for secondary systems.

(1). IF a Technical Specification is exceeded, THEN corrective actions SHALL BE performed per the applicable Technical Specification.

(2). IF a secondary system Achon Level 2 condition is caused by other than a Technical Specification parameter THEN:

(a) REDUCE power to s 30% within eight hours of the Action Level 2 time of initiation, (b) Power reduction MAY BE terminated WlEN the parameter pca has cleared Action Level 1 threshold AND the source of soeo the impurity ingress is controlled.

(c) Retum to full-power MAY BE cornmenced WHEN parameters clear Action Level 1.

e. RESAMPLE AND ANALYZE for the affected parameter as soon as practical to verify entry into the Action Level 2 condition.
f. INCREASE surveillance frequency as directed by the SPC.
g. RECORD sample time when out cf Achon Level 2 Am NOTIFY SPC PCR and the SS, as directed by SPC. m.

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h. INITIATE a Temnical Evaluation per CP-108 within seven days after Action Level 2 time ofinillation.
i. IF the parameter has not cieered Action Level 1 within 100 hours0.00116 days <br />0.0278 hours <br />1.653439e-4 weeks <br />3.805e-5 months <br /> followmg the Achon Level 2 time of inibation, THEN PERFORM Achon Level 3 responses for those parameters with an Action Level 3 value.
5. IF an Achon Level 3 value is exceeded. THEN:
a. RECORD the sample time as Adon Level 3 time of inibation in appropriate record.
b. NOTIFY the SPC, and the GSC as directed by the SPC AND RECORD notecation in appropriate record
c. NOTIFY the Shift Supervisor, as drected by the SPC AND RECORD notmoeuon in appropriate record. i O l

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12/4/1995 11:01:07 USER CONTROLLED CP-217 Rev. 4 Page 12 of 25

d. AS necessary, ADVISE the Shift Supervisor of plant corrective actions required by Action Level 3:

(1). INITIATE an orderly shut down within four hours of the initiation of the Action Level 3 condition, AND (2). Restart MAY proceed when chemistry parameters are within startup specifications,

e. RESAMPLE AND ANALYZE for the affected parameter as soon as

! practical to verify entry into the Action Level 3 condition.

f. INCREASE surveillance frequency as directed by the SPC.
g. INITIATE a Technical Evaluation per CP-108.

D. Out-of-Service Monitor.

IF a continuous monitor with a C/DR-W Frequency is out-of service. THEN PERFORM grab sample surveillance at least once per four hours in Modes 1,2,3, or 4. [B133]

7.0 POST-PERFORMANCE ACTIVITIES None.

8.0 BASIS PROCEDURE COMMITMENT R E tt:MENCE

, SECTION 5.1 B345 NRC 89-04 8.0.D B133 INPO CY.3-3 (1984)

Attachments 1. 2, & 3 B014 Tech. Spec. 3/4.7.1.4 Attachments 1 & 3 B492 SOER 82-13-R04 Attachment 4 B507 INPO CY.4-2 (1987)

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9.0 RECORDS None 10.0 ATTACHMENTS l

Refer to Table of Contents s

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Rev.4 e l O Page 14 of 25 ATTACHMENT 1. STEAM GENERATOR CHEMISTRY - POWER OPERATION (MODE 1)

PARAMETER UNITS FREQUENCY TARGET ACTION ACTION ACTIoM VALUE BEFoRE VALUE eEFoRE BASIS PCR LEVEL 1 LEVEL 2 12 VEL 3 10% power 30% power 95-000 pH (IF ful-tow cond. potshing) C/DR-W 2 8.7 <8.7 pH (IF partioMiow cond. poMshing) C/DR-W 29.0.510.0 <9.0 Cabon ConductMty S/cm C/DR-W 5 0.3 >0.8 (1) >2.0 (1) >7.0 (1) 52.0(1) s 0.8 (1) i Conducevity (specec) nS/cm C/DR-W g Chionde ppb D s1.35 >20 >100 >500 <100 520 PCR ) )

Fluoride ppb W 954 4 h Morphotne(IMEN used) ppm W <6 8 ETA (WHEN used) ppm W <12 PCR h

Sodium ppb D 50.8 >20 >100 >500 5100 520 94-109 Suffets ppb D 11.35 >20 >100 >500 s20 [8492] S Gamma Activity pC% 1/72 hr (2) [5014] 5 l-131. D. E. pC% 1/72 hr (2) >o.1(3) 20.19) s 0.1(3) [B014] E Calion ConductMty Balance pS/cm W i 30 % 8 Conductivity (specdc) Belence pS/cm W i 30 % y Acadets (IF morphonne or ETA used) ppb W PCR p Formate (F morpholine or ETA used) ppb W 94-i0g O Ammonia ppb W Suos ( Achon Loved 1 epptes At > B0% Power) ppb W s10 >100 Tribum pCilg see CP-224 (2) pH Bolence W t 0.2 Nec Rallo (rnoier) W Avg. 0 5-0.7 No:(Cl + SO4 )(rnoler) W Avg. 0.3 - 0.5 Hydrazine ppb W NOTES:

1. Cation conductivity limit and Achon Levels may be based on the cation conductivity calculated from Cl & SO4 concentrations
2. IF steam generators are contammated. TNEN refer to CP-224
3. PERFORM corrective action por Technical specification 3/4.7.1.4

O O E'. O Page 15 of 25 ATTACHMENT 2. STEAM GENERATOR CHEMISTRY - HOT STANDBY (MODES 2,3, & 4) i PARAISETER UDETS FREQUENCY TARGET VALUE BASIS BEFORE i CRITICAL pH C/DR-W 2 8.7 Canon Conductrylty pS/cm C/DR-W s 2.0 -

ConductMay (specMc) pS/cm C/DR-W 2 s

i D C 50 e i Chloride ppb e Sodlum ppb u 5 50 [

SuNate ppb O s 50 s 100 before [EM92) PCR 350*F s44se M S Gemme ActMty pC#gm 1/72tu W W je014] Pen Si NI s 0.193 ss-oso S 1-131. D. E. pCWDm 1/72 hr lB014] n .

I Fluoride ppb D s50 g ,

sliica ppb W 8 NOTES:

1. The Steam Generators SHOULD BE sampled as soon as pradical BUT no later than 4 hours4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br /> after a reador trip. pca esoso  ;
2. IF steem generators are contaminated, THEN refer to CP-224
3. PERFORM corrective acelen per Technical specificatloa 3/4.7.1.4 t

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ATTACFRIENT 3. STEAM GENERATOR CHERRISTRY -WET LAYUP (RSODES 5 & 6)(1)

$ Of CP Page 16 of 25 l;

UDES FREQUENCY TARGET ACTION VALUE BEFORE BASIS PARA M LEVEL 1 200F ppb before feeding steam s100 >100 D6esolved O2 (fW source) generators oH (2) 2 9.8 <9.8 2 8.5

-Ch Wide ppo (2) 5100 >1,000 5100 R Sodk im ppb (2) 5100 >1,000 5100 Suteks ppb (2) 1100 >1.000 5100 before 350*F [B492) $

Hyd e w ppm (2) 75- 300 <75 h Morphoh' ( when used ) ppm (2) $

o PCR N ETA (when used) ppm (2) 04-ios Si m

Fluoride ppb W 5100 n TIC / TOC ppb W IF pH <9.8 E s

ppm As determined by o sace SPC  ;

O Trttlum pCVg see CP-224 Gemrie ActMiy pGg M [B014]

t-131, D. E. pW9 4I M moTas:

1. IF th.C's is expected within 7 days, THEN these v*=hnQs arB not applicable, AND UNLESMhe steem generators wRI be drained for maintenance, the steam generators SHOULD BE fHied AND hydrazine added to 2 5.0 ppm.
2. The Steen,a nerators e SMALL BE sampled 1tW. WHEN Steam Generators recirculation is established, they SHOULD BE sampled 3,W until the SPC determenes that chemistry is stable. THEN 1/W.

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CP-217 Rev. 4 Page 17 o 5 [

ATTACHRAENT 4. FEEDWATER CHEtBIRTRY - POWEF< OPERATION (RAODE 1)

PARAREETER UNITS FREQUENCY TARGET ACTION BASIS t LEVEL 1  !

pH (F fuB-Row cond. poHeMog) C/DR-W 29.0 <8.8  ;

pH (F perbel-Gow cond. pakshing) C/DR-W 29.3 <9.3  !

pS/cm C/DR-W PCR ,

SpecfAc ConductMty (3) i P

s f

Cation ConductMty pS/cm C/DR-W g  !

Dissofwed Oxygen pp0 C/DR-W 51.0 >5.0  :

[

Sodium ppb C/DR-W 50.2 {

Hydrazine ppb D 2100 <100 [B607] {

Morpholine (VREN used) ppm D <6.0 [B507]

ETA (WHEN used) ppm D <5.0 [B507] p j W'O l O

Iron ppb W (k11egrated)D) <3.5 >5.0(Z) pm r-i Copper ppb W (Integrated)D) <0.2 >1.0(Z) 9 Ammonie ppb D 2250 [B507]

pH belence W i 0.2 i NOTES:

1. Sergio SHOULD be integrated over entre week and is requked mRer unit is at > 80% power for greater than 5 days. PCR 96-044
2. Shift Swervisor notificebon 15 NOT required fbr Achon Level 1 Fe or Cu.

3 When instrument is available. PCR 95444 i

O  % = #

O Page 18 of 25 ATTACH 00ENT 5. CONDENSATE CHERSISTRY - POWER OPERATION (MODE 1)

UNITS FREQUENCYtU TARGET ACTION ACTION basis PCR S PARARSETER LEVEL 1 LEVEL 2 95-080 Caton Conductmty (cond. pumps at TPSS) pS/cm C/DR-W 5025 I

Catson Conductivity (indMdual HW at TPSS) pS/cm C/DR-W 50.25 ppb C/DR-W 52.5 >10 >30(2) PCR Dissolved Oxygen (at TPSS) .95-08R

=

g>b C/DR-W 50.2 D e

pH (at TPSS) C/DR-W $

ppb C/DR-W 50.2 Sodium (st CDSS)

Conductivty(specWic) (61CDSS) S/cm C/DR-W r O

Cation Conductivity (at CDSS) pS/ctn C/DR-W 5025 Si E

NOTES:

8

1. IF there are redundant TPSS & CDSS monitors. AND one is outof-service. THEN the others analyzer readings may be used. 5 AND the 1/4 hr samphng and analysis IS NOT required. 8  !

P

2. During power ascension,IF in Action Level 2. THEN a 30% power hold is estat*shed unni DO is sto ppb. 8 ,

l

i O  % S' O Page 19 of 5 ATTACHMENT 6. STEAM GENEMATOR FEED SOURCE (1) - HOT STANDBY (MODES 2,3, & 4) j PARARETER UNITS FREQUENCY TARGET ACTION VALUE BASIB LEVEL 1 BEFORE 10% POWER PCR 96-000 pH C/DR-W 28.8 <8.5 Cadon Conductwity pSicm C/DR-W 5025 C Dissolved Oxygen ppb C/DR-W s100 >100 <100 k-Sodium ppb CIDR-W 51 8 w

Chloride ppb D s1 -

Sulfste ppb D s1 y Hydrarine ppb D 2100 <100 >100 k AND AND 23 X DO <3 X DO k" Suspended Souds ppb Before initial SG feed s100 4

NOTES: E l-

1. Attachment 6 RAAY apply to Ef1NER foedwater or condensate WHEN used as a steam generator feed in Modes 2, 3, & 4. Table only applies when 8 food!ng steem generakn

O 9  % g,7qf5 Page 20 o  ;

ATTACHMENT 7. MAIN STEAM - POWER OPERATION (MODES 1 & 2)

PARAGE!TER UNffs F9tEQUENCY TARGET BASIS Cetion ConductMty pS/cm  ?'DR-W 50.2 ConductMty (specac) pS/cm C/DR-W U

2 2

3 w

O t u

t O

5 8

P G ,

(

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Page 21 of 25 i l

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\

ATTACHMENT 8. HEATER DRAIN TANK CHEMISTRY - POWER OPERATION (MODE 1) t t

i '

PARAllAETER UNITS FREQUENCY TARGET BASIS PCR 95444

[ Suspended Sohds ppb es required (1) 5100 -

~

Iron ppb (neograted)(2) sto 2 D l w

U.. ,

o

~ i 1

8 I

1. During start up, where HDT pump discharge semple po'nts are installed, sample concurren9y with j Heater Drain Tank (HDT) pump being placed in service m  !

=

2. As directed by SPC. PCR Q 8" 'i 8

F m

i CP-217 Rev. 4 Page 22 25 i

ATTACHRAENT 9. CONDENSATE STORAGE TANKS - ALL MODES (1) ,

PARAMETER UNITS FREQUENCY TARGET ACTION BASIS LEVEL 1 ,

CNortde ppb W sMQC >1.0

~

Dissolved Oxygen ppb W s100 >100 Suica ppb W <10 t

- li Sodium ppb W sMQC >1.0 $  !

y un  !

Sulfate ' ppb W sMOC >1.0 -

Gamma A::svtty pCitgm see CP-224 h Tritium pCVgm see CP-224 k Si  !

NOTES: g l l

1. WHEN transferring to the CST by other than normal pathway, (DIST or COND. or Vendor DI Water System), h i THEN analyse for Ns, Cl, SO4, & SiO2 is required. g F paramotors exceed Action Level 1 vs,;.es, THEN SPC approval for transfer is requred S i r- I l

i i

l l

i l

l l

l l

[

f I

__.m.m.._ . . . . . . . . _ _ _ . . . _ _

CP-217 Rev. 4 Page 23 of j ATTACHMENT 10. INDIVIDUAL CONDENSATE DEMINERALIZER EFFLUENT--POVWER OPERATION (MODES 1 & 2) i PARABAETER LNETS FREQUENCY TARGET ACTION BASIS LEVEL 1 i

4 Conducthaty (spoolRc) pS,tm C/DR-W 50.1 >0.1 Ceten ConductMty pS/cm C/DR-W 50.1 >0.1 Ammonia ppb D. F conductMty suQC >MoC t 2 0.1 pS/cm 3 o

U' Hydradne ppb D, F conductnnty sMQC >MQC 2 0.1 pS/cm C Morphonne ppm D,IF conductvity SMOC >MOC PCRB d l 2'O.1 pS/cm 5 AND WHEN used Si ETA ppm D. IF conductMty SMQC >MCC PCR m 2 0.1 pS/cm 94-100 " i AND WHEN used {a i Sodom ppb C/DR-W U) F3 (3) 502 >0.2 g r-Chloride ,

pob D, IF cation cond. sMQC >MQC  ;

2 0.1 pS/cm o Sulfate ppb D. IF caton cond. sMQC >MOC 2 0.1 pS/cm i

NOTES:

1. Analyzer SHOULD be augned to common oftaent, EXCEPT for the first 30 minutes of service for a new bed OR per SPC instruction.
2. F analyzer is out-of-service TlWN SAW atoom generators for sodium within one hour of placing new dommeralizer bed in service.
3. If analyzer is outer-service. THEN the Feedweter or the Condensate Na analyzer reading may be used, as directed by the SPC, and PCR 9>044 once per 4 hour4.62963e-5 days <br />0.00111 hours <br />6.613757e-6 weeks <br />1.522e-6 months <br /> sampling is not required.

l

. . . . - . ~ . . . . - . . .

CP-217 Rev. 4 Page 24 of 25

! I i

ATTACHMENT 11. CONDENSATE DEMINERALIZER REGENERATION SPECIFICATIONS I

r i

PARAMETER UNITS FREQUENCY YALUE PRIOR BAS 86 l  !

TO TRANSFER Conductivity (specific) pS/cm Continuously, while rmsing after 56 04U _

in Cation / Anion Tonk Rinse regeneration R  !

l ConductMty (specde) pS/cm Continuously, while rinsing 50.10W) b  :

i in Holding Tank Emuent $  !

l

~ t NOTES: 7 l 8 i

1. Value before transfer to Holdmg Tank for contmustion of rwrnal regeneration g 2
2. Value before transfer to S3rvice Vessel. 8 E
3. IF rince takes 2 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />, THEN REPEAT regeneration as directed by SPC. g i

8  ;

F m

o  :

i i

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i

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O -

CP-217 Rev.4 j

Page 25 of 25 ATTACHWNT 12. STEAM GENERATOR BLOWDOWN ION EXCHANGER EFFLUENT- POWER OPERATION (MODE 1)

PARAMiTER UNITS FREQUENCY TARGt!T BASIS Sodium ppb as directed by SPC sMQC R

Chloride ppb as dwected by SPC s MOC R G

8 SUNate ppb as dWected by SPC s MOC -

2 o

Fluoride $ as directed by SPC sMQC 5u 5

. =

8 4

s= ,

o  !

f, I

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