ML20083N882

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Forwards Responses for Remaining Criteria for NUREG-0737, Item II.B.3 Re post-accident Sampling Sys,Including Revised Table of Integrated Dose Rates
ML20083N882
Person / Time
Site: FitzPatrick Constellation icon.png
Issue date: 04/16/1984
From: Bayne J
POWER AUTHORITY OF THE STATE OF NEW YORK (NEW YORK
To: Vassallo D
Office of Nuclear Reactor Regulation
Shared Package
ML20083N885 List:
References
RTR-NUREG-0737, RTR-NUREG-737, TASK-2.B.3, TASK-TM JPN-84-23, NUDOCS 8404190317
Download: ML20083N882 (9)


Text

123 Ma.n Street h

Vvhte Plains. New York 10601 j

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& Authority April 16, 1984 JPN-84-23 s

Director of Nuclear Reactor Regulation U.S. Nuclear Regulatory Commission Washington, D.C.

20555 Attention:

Mr. Domenic B. Vassallo, Chief Operating Reactors Branch No. 2 4

Division of Licensing

Subject:

James A. FitzPatrick Nuclear Power Plant Docket No. 50-333 NUREG-0737 Item II.B.3 Post-Accident Sampling System (PASS)

References:

1.

NRC letter, D. B. Vassallo to L. W. Sinclair, dated July 27, 1982.

,o 2.

NYPA letter, J. P. Bayne to D.

B. Vassallo, dated October 5, 1983 (JPN-83-8 5) 3.

NEDC-30088 " Response to NRC Post

-r-Implementation Review Criteria for Post-Accident Sampling Systems," dated April, 1983.

Dear Sir:

~

Reference 1 transmitted the criteria and guidelines for NUREG-0737 Item II.B.3.

Reference 2 provided responses for criteria 1, 2d, 3, 6, lla'and llb and committed to provide the remaining responses within six months.

This letter provides responses for the remaining criteria and includes a revised Table of Integrated Dose Rates.

The following attachments are included:

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B404190317 840416' 4-PDR ADOCK 05000333

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1.

Attachment A lists NRC criteria 2a, 2b, 2c, 4, 5, 7, 8,

9, and 10, and provides the Authority's responses.

2.

Attachment B is the " Core Damage Estimation Procedure" for the FitzPatrick Plant.

3.

Attachment C is the " PASS Containment Radiation Monitoring Procedure" for the FitzPatrick Plant.

4.

Attachment D is a letter from General Electric (GE) to the NRC on the " Accuracy of Dissolved Gas Measurement for GE Post-Accident Sampling Systems."

5.

Attachment E provides a revised Table of Integrated Dose Rates to replace Table 2 of Reference 2.

If you have any questions, please contact Mr.

J. A. Gray, Jr. of my staff.

Very truly yours, s!

-! j' -

c J./P'.Bhyne xecutive Vice President Nuclear' Generation cc:

Office of the Resident Inspector U. S. Nuclear Regulatory Commission P. O. Box 136.

Lycoming,>N.Y.

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t' JAMES A~. FITZPATRICK NUCLEAR POWER PLANT I

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>il Criterion:

(2) The licensee shall establish an on-site

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radiological and chemical analysis capability to f

j provide, within a three-hour time frame

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established above, quantification of the j

following:

3 J

al certain radionuclides in the reactor coolant

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and containment atmosphere that may be 4

indicators of the degree of core damage i

(e.g.,

noble gases, iodines and cesiums, and j

non-volatile isotopes) ;

h b hydrogen levels in the containment atmosphere; k

c) dissolved gases (e.g., H ), chloride (time 2

allotted for analysis subject to discussion below), and boron concentration of liquids.

Response

(2a) The FitzPatrick Plant on-site radiological analysis of post accident samples is performed using a Ge(Li) detector / multi-channel analyzer (MCA) spectrophotometer system with a counting h

cave of sufficient shielding to remain operable

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in the worst case background radiation levels

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within 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> after an accident-(based on g

projected Reg. Guide 1.3 and 1.4 source' terms).

. Provisions have been made to handle samples in f.

such a manner as to minimize personnel exposure through the use of transport casks and sample i

dilution caves.

In addition. remote handling

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tools will be available for hendling highly

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radioactive samples.

Reduction in exposure levels is also attained with an approximate 100:1 dilution (internal to the PASS sink) of-i reactor coolant.

Further sample dilutions will be performed in the radiochemistry lab under a fume. hood.

A Plant specific core damage estimate procedure (AttachmentlM has been prepared based on the generic procedure submitted by the BWROG.

The procedure estimates the core damage: based on

. fission product concentrations and integrates other physical parameters for confirmation of-these estimates.

Attachment C,;provides'a Plant'-

unique procedure for estimating the core damage based on the' containment radiation monitors.

4 i

Responset (2bi A gas chromatograph located in a fume hood will 1

3' be used for analysis of hydrogen gas from the y

. *s' primary coolant gas sample.

In addition, the j.

containment atmospheric monitoring system s

f hydrogen analyzer provides in-line monitoring of hydrogen.

Atmospheric samples are available f

from the torus, drywell and secondary x

s containment.

The gas sample is withdrawn from

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the sample vial through a small access port from i

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the gas vial cask in the PASS sink.

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' Response.:

(2c) Chloride concentrations will be analyzed of f-site by Babcock and Wilcox as mentioned in

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Response 5.

An initial scoping for chlorides j

will be conducted on-site by the turbidimetric i

or spectrophotometric method.

Boron will be g

3 analyzed tur the carminic acid method.

Liquid 1

sample pH will be measured with a flat surface h

combination electrode.

3 ii

, Criterion:

(4) Pressurized reactor coolant samples are not required if the licensee can quantify the amount 1

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of dissolved gases with unpressurized-reactor coolant samples.

The measurement of either total dissolved gases or H2 gas in reactor coolant samples-is' considered adequate.

Measuring the 02 concentration is recommended, but is not' mandatory.

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Response

(4)

As described in Attachment D, the plants with the GE PASS system are changing'_the method of measuring dissolved gas.

The method, including L

range and accuracy, is all described in 1

Attachment D.

At the time of this: letter, no J

written confirmation of approval from the NRC

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for this dissolved gas modification has been h

received tar the Authority.

Therefore the L

FitzPatrick Plant can not confirm the ranges and accuracies'at this time.

The Authority will i.

confirm the entire dissolved gas portion of~the PASS after resolution of this issue and receipt of an approved. Technical, Specification Amendment:

to allow sampling!during power operation with a containment atmosphere' monitor temporarily:

a isolated.

I Criterion:'

(5)l The time for a chloride: analysis to be' performed is dependent upon two factors:

(a) if the

-plant's coolant water-is seawater or brackish-water ~and-(4 if there is only a single barrier

,between primary containment systems and the.

cooling water.

Under both of the-above

1 conditions the licensee shall provide for a yi chloride analysis within 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of the sample i

being taken.

For all other cases, the licensee

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shall provide for the analysis to be completed

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within 4 days.

The chloride analysis does not g

have to be done on-site.

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Response

( 5)

Since the FitzPatrick Plant does not use seawater or brackish water for plant cooling, a

T the chloride analysis is required to be I

completed within four (4) days.

An on-site f

scoping analysis using the turbidimetric method J

is available for an initial approximation.

Arrangements have been made with Babcock and Wilcox for accurate chloride measurements within 4 days, using an ion specific electrode with a liquid ion chromatograph as an alternate technique.

4 d

In addition, the FitzPatrick chemistry 1aboratory has purchased a liquid ion

a chromatograph and will investigate the use of 1

this equipment to more accurately analyze for f

chlorides and to further reduce personnel y

exposure.

3 Criterion:

(7) The analysis of primary coolant samples for i

boron is required for_PWRs.

(Note that Rev. 2 7

of Regulatory Guide 1.97 specifies the need for primary coolant boron analysis' capability at BWR f

plants).

i nesponse:

(7)

Boron analysis capability for' liquid coolant samples will be performed by the carminic acid-method in the on-site laboratory.

Criterion:- (8)

If in-line monitoring'is used for any sampling y

land analytical capability specified herein,-the-E licensee shall provide backup sampling through~-

-grab samples,'and shall demonstrate the capability of analyzing thel samples.

Establishedfplanning for' analysis at off-site a

facilities is: acceptable.

Equipment provided

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for backup sampling shall be capable of-

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.providing at-least one sample per day for 7. days

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following. onset of the accident, and:at least one : sample per. week until' the accident _ condition-no longer exists..

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Response

( 8)

The FitzPatrick Plant will not utilize in-line

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monitoring for PASS sampling.

The GE system employed at the FitzPatrick Plant utilizes a grab sample system which is transferred into a cask and analyzed in the chemistry lab on-site.

For backup capability and primary chloride measurements, the undiluted sample will be inserted in a Post Accident Shipping C a k.

Two casks have been purchased by the Pooled Inventory Management spare parts program (PIMS),

of which the Authority is a member.

These casks, being manufactured by Nuclear Packaging, Inc.

are awaiting final NRC licensing approval and subsequent delivery to the Memphis, Tennessee warehouse.

Emergency withdrawal procedures have been-developed.

i Additional arrangements have been made with Babcock and Wilcox for receipt of the cask for backup sampling capability which meet all of the Reg. Guide 1.97 ranges and accuracies.

l-Criterion: (9)

.The licensee's radiological and chemical sample analysis capability shall include provisions to:

W Identify and quantify the isotopes of the nuclide categories discussed above to levels corresponding to the source-

-terms given in Regulatory Guide 1.3 or 1.4 and 1.7.

Where necessary and practicable,.the ability to dilute

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samples to provide capability for measurement and reduction of personnel exposure should be provided.

Sensitivity of on-site liquid sample analysis capability should be such as to permit measurement of nuclide concentration'in the range from approximately hgCi/g to 10 Ci/g.

-h Restrict b'ackground levels of radiation inLthe radiological and chemical analysis facility from.

sources such that the. sample analysis will provide results with an acceptably.small error.(approximately.

a factor 2).

This can be accomplished through the use of sufficient sh,ielding around samples and outside-sources, and~by the use'of a ventilation: system design which-will control the presence of airborno-radioactivity.

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Response

(9ai As discussed in Attachment B, the source terms g

for FitzPatrick Plant are based on Reg. Guide 1.3 and 1.4.

The predicted activities from the e

4 various samples drawn were based on a reference f

BWR-6/238 Mark III containment (Reference 3).

1 Correction factors were applied (coolant mass, j

containment and drywell volumes, thermal rating) to develop plant unique activities for the j

FitzPatrick Plant.

These activities were j

incorporated into integrated whole body and k

extremity doses (Attachment E), for samples taken 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br /> after the accident.

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As discussed in response 2A, internal dilution 1j of approximately 100:1 is conducted for highly radioactive coolant samples to minimize 1

personnel exposures.

Also, transport casks are j

used for the same purpose.

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Although the maximum expected primary coolant activity for the FitzPatrick Plant is estimated at 2.63 Ci/g, capability for measuring up'to 10 1

Ci/g is available with a dilution of 1X10,

7 l-(9b) The GeLi detector in the FitzPatrick chemistry laboratory is adequately shielded to insure that l

background radiation levels 2 hrs. after an

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accident (allowing 1 hr. for obtaining, transporting and preparing the sample) do not radically affect the sensi,tivity (f actor of 2).

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Criterion: (10) Accuracy, range, and sensitivity shall be adequate to provide pertinent data to the-

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operator in order to describe radiological and'

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chemical status of the reactor coolant systems.

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Response

. (10) The accuracy, range and sensitivity for post accident sampling and~ analysis at FitzPatrick

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are adequate to provide pertinent data to the i

operator for'the radiological and chemical j

status of the reactor coolant systems, as shown t.

below.

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Analysis Range Accuracy j;

Gross Activity AgCi/g-10 Ci/g i 100%

i (Radionuclide)

Boron 100 - 1,000 ppm 1 50 ppm

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. Chloride (Of f-s ite)

<0.5 ppm i 50 ppb

(

0.5 ppm - 20 ppm

+ 10%

e Total dissolved gas To be addressed following resolution of the j;

dissolved gas issue.

l pH*

1 - 13

-+.03 i

  1. Assuming conductivity

>l Mpho/cm j

The procedures for the above, have been tested by GE with the effects of radiation and interference from other a

i constituents being negligible.

See Reference 3 for a-1 explanation of these results.

j Training for applicable personnel in the collection,

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-transport, and on-site analysis of samples for the PASS will

'be_ conducted annually and documented in'the Indoctrination

-Training Procedure ITP-7 for Radiological and Environmental m.

Li Technicians (chemistry).

Functional testing and calibration frequency will be addressed in the Authority's Technical ~

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. Specification Amendments related to NUREG 0737.

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