ML20082M299

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Rev 8 to Operating Procedure 1104-28I, Waste Solidification Process Control Program
ML20082M299
Person / Time
Site: Three Mile Island Constellation icon.png
Issue date: 08/29/1991
From:
GENERAL PUBLIC UTILITIES CORP.
To:
Shared Package
ML20082M290 List:
References
1104-28I, NUDOCS 9109050125
Download: ML20082M299 (31)
v • d • e


Text

- _. - _ _ .-.. _ . .__

k kt Nuclear 1si.i Operatino Procedure 1104 281 Title Revision No.

Waste Solidification Process Control Program 8 ATTACHMENT I Page 1 of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION i DATA SHEET FOR 4 TO 10 Wi% BORIC ACID <

Chemistry Parameters Balance Cal. Info. Liner No.:

Sample Date CMTE No.__ Sample No.:

Boron ppm Serial No. Date: _

Total Solids ppm Cal. Due Date Waste Class pH Total Act. __ mC1/cr I. PRECONDITION!NG:

Weight Percent of Boric Acid (in decimal form):

Boron (ppm) x .01 ( ) x .01 '

1748 - 1748 = _,

(1)

Weight of Untreated Sample: gms (2)

Volume of Untreated Satple- mis (3) I l  !

Weight cf LC1 NaOH Added to Adjust pH ,___ g m s (4)  ;

within range per Section 4.'.4.

pH of treated sample:  !

Weight of Anti-foam Added: .gms (5)

% 011':  % '-

Weight of Emulsifier Added: gms (6)

Volume of treated sampic: mis (7) -

Weight of treated sample:

(2) + (4) + (S) + (6) - ( ) + ( ) +( ) +( ) . ,. (8) t, E1 1 1372c 9109O'3012'] 910::29 PDR ADOcK 050002e9 R PDR

t MUClear THI-1 Operating Procedure 1104-281 Ittle Revision No.

Haste Solidification Process Control Program B ,

i r

ATTACHMENT 1 (Cont'd) Page 2 of 4

!!. DETERMINATION OF PERCENT SOLIDS OF SAMPLE:

Weight of Boric Acid in Untreated Sample: l (2) x (1) -( ) x ( ) . gms (9)

Weight of 50% NaOH:

(4) x 0,5 . ( ) x 0.5 - _ gas (10) l Weight of Solids in Treated Sample: -

(5) + (6) + (9) + (10) .

( ) +( ) + ( )+ ( ) .

gms (11) '

Percent Solids in Treated Sample:

100 x (11) + ((8)) . '

100 x ( ) + (( )) .  % (12) 111. DETERMINATION OF WATER IN SAMPLE FOR SOLIDIFICATION:

Volume of Treated Sample to be Solidified: ml (13)

Weight of Treated Sample to be Solidified: gms (14)

Weight of Water in Sample Contributed oy Waste:

g) x(14f x (1 - (1)] .

,( 8) .

Ox ( ) x (1 - ( )) . gms (15)

() .

Weight of Water in Sample Contributed By 50% NaOH: .

(4) x (14) x 0.5 .

i

~

( ) x ( x 0.5 -

l ( ) , gms (16)

Total Weight of Water . Sample:

(15) + (16) . ()+() . gms (17) ,

i i

E1.: 137:c l

l l

[n ui1 Nuclear w!-,

Operatino Procedure 1104-281  ;

Title Revision No.

Waste Solidif' cation Process Control Program 8 ATTACHMENT 1 (Cont'd) Page 3 of 4 IV. DETERMINATION OF QUANTITY Of PORTLAND TYPE I CEMENT AND METSO BEADS TO USE FOR SAMPLE SOLIDIf! CATION:

Using figure I, find the % solids in sample (12), and DETERMINE the Water / Cement Ratio: (18) l Height of Cement to Use:

(17) . ( ) .

(18) .( ) gms (19)

Weight of Metso Beads to use:

(19) x 0.15 ( ) x 0.15 Sms (20)

Test Solidification Performed By:

Name Date Time V. SAMPLE INSPECTION Sample cured for:

Hours Cured Temp. Cured Verifiea By Date Sample contains "Nn Free Liquid":

Verified By Date Sample " Resists Penetration"-

t Verified By Date  ;

i i l

El-3 1372c

l Ir L)JNuclear TM1-1 1104-28I Drerat1 1 Procedure Title hevia1cn No.

Waste Solidification Process control Program 12 i

ATTACHMINT 1 (Cont'd) Page 4 of 4 Additional batches solidified based on this sample solidification Liner Waste Liner Waste Liner Waste No. Vol. Date No. Vol Date No. Vol. Date

2. 5. 8.
3. 6. 9.
4. 7. 10.

FOOTNOTES

1. Mr.ximum allowable oil content for etable waste is 14 by volume.

VI. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT Test Sample Meets Acceptance criteria (Section 12) Name / Date / Time .,

! i Test Solidification Data Sheets (Calculations) Reviewed N arne / Date / Time e

i l

L l

l El-4 1372C s

Nuclear Ts! i Operating Procedure 1104-281 litie Revision No.

Waste Solidification Process Control Program 8 ATTACHMENT 2 Page 1 of 3 SOLIDIFICATION CALCULATION SHECT FOR 4 TO 10 HT% BORIC ACID Liner Type to be used I. Volume of Untreated Haste to Add to Linerl .3:

(3) Max. Treated Haste Vol.

I77 x from Solidification Data Tables -

( ) ,

( ) x -

___ft3 (21)

II. Volume of Additives to Add to Liner:

NaOH: (4) x 4.86 x (21) - ( ) x 4.86 x( ) - gals (22)

(3) ()

Anti-foam: (5) x 7.48 x (21) - ( ) x 7.48 x ( ) - gals (23)

(3) ()

Emulsifier: (6) x 7.48 x (21) - ( ) x 7.48 x( ) - gals (24)

(3) ()

III. Volume of Treated Haste to be SolidifiedI :

(22) + (23) + (24) ( ) +( ) + ( )

(21) + 7.48 - ( )+ 7.48 = ft3 (25)

IV. Cement Quantity for Full Scale Solidification:

(19) x 62.4 x (25) =( ) x 62.4 x ( ) - Ibs (26)

(13) ( )

(26) + 94 - ( ) + 94 - bags 2 5 V. ASMS Quantity for Full Scale Solidification: i (26) x .15 - ( ) x .15 - Ibs (27)

(27) + 100 - ( ) + 100 - bags 2 E2-1 1372c

(UClear ""

Tsi.i Operating Procedure 1104-?8!

Title Revision No.

Waste Solidification Process _ Control Drogram 9 ATTACHMENT 2 Page 2 of 3 VI. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIDIFICAT101 CALCULATION SHEETS REVIEWED Name / Date / Time FOOTNOTES I

The volume of treated waste to be solidified in a single liner cannot exceed the maximum treated waste volume listed on the attached Solidification Data Tables.  !

2 Round off up to the nearest whole bag.

3 Use the actual waste volume added to the liner in Steps / Equations 22, 23 and 24 if the waste volume added to the liner is less than the value obtained in Step / Equation 21.  ;

VII. DCTERMINATION OF THE QUANTITY OF CEMENT ADDED TO WASTE:

Quantity of Cement Added to Hopper: lbs (28)

Quantity of Cement Left in Hopper: lbs (29)

Quantity of Cement Added per ft.3 Waste:

(28) . (29) - ( ).( ) -

lb} cement /

(25) ( ) ft3 waste NOTE: Minimum Quantity of Cement Allowable for 4 to 10 Ht. %

Boric Acid Class A Unstable Waste is 62 lbs./ft.3, For Stable waste solidifications all the cement must be  ;

added to the liner.

Quantity of Cement Added Meets Minimum Requirements for unstable waste forms:

Vert' Tied By Date The recommended minimum treated waste volume and minimum solidified waste volume meet the requirements of the Solidification Data Tables for STABLE waste forms.

Verifled By Date E2-2 1372c i

MUClear ""*'"

1sl i Operating Procedure 1_104-281 litle Revision No.

Waste Solidification Process Control Program 7 A T' h4ENT 2 (Cont'd) Page 3 of 3 SCL:: ATION DATA TABLES FOR 4 WT7. BORIC ACID HN-100 HN-100 LVM Series 3 Series 31 Usable Liner Vol. (cu. ft.) 141.1 157.5 Max. Treated Haste Vol. (cu. ft.) 104.4 116.6 Hax. *olldtfied Haste 141.1 157.5 Vol. (cu. ft.)

Recommended Min.

Treated Waste Vol. 98.1 103.8 (cu. ft)2 Hin. Solidified Waste Vol. (cu. ft)2 132.6 140.2 Max. Rad. Level 12 12 R/hr Contact

1. For less than A2 quantities of LSA waste. For greater than A2 quantitles of LSA waste, the naximum treated waste volume is 112.4 cu. ft due to weight limitations.
2. These minimums are required when shipping to Barnwell, to comply with the 15%

maximum vold space criteria for liners containing solidified stable waste forms.

E2-3 1372c

Ie d lNuclear 1Hi.i Operatino Procedure 1104-281 Title Revision No.

Waste Solidification Process Control Program 8 i

i ATTACHMENT 3 Page 1 of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C "EST SOLIDIFICATION DATA SHEET > 10 TO 20 WT% BORIC ACID Chemistry Parameters Balance Cal. Info. Liner No.: l r

Sample Date CMTE No. Sample No.: .

Boron ppm Serial No. Date:

iotal Solids ppm Cal. Due Date Waste Class pH Total Act, pCl/cc

!. PRECONDITIONING Weight Percent of Boric Acid (in decimal form):

Boron (ppm) x .01 ( ) x .01 - (1) 1748 - 1748 Weight of Untreated Sample: _

gms (2)

Volume of Untreated Sample: mis (3)

Weight of 50% NaOH Added to Adjust pH per Section 5.2.4: gms (4) pH of treated sample:

Weight of Anti-foam Added: gms (5)

% 0111 :  %

Wetght of Emulsifler Added: gms (6)

Volume of treated sample: mis (7)

Weight of treated sample:

(2) + (4) + (5) + (6) - ( )+( ) + ( )+( ) - gms (8) l E3 1 1372c

Number Ir U lNuclear Tsi-i Operating Procedure 1104-281 Title Revision No.

Waste Solidification Process Control Program 8 i

AT'aCHMENT 3 (Cont'd) Page 2 of 4 II. DETERM1 ATION OF PERCENT SOLIDS OF SAMPLE Weight of Boric Acid in Untreated Sample ,

(2) x (1) -( ) x ( ) - gms (9) >

Height of 50% Na0H:

(4) x 0.5 - ( ) x 0.5 - gms (IC )

Height of Solids in Treated Sample:

(5) + (6) + (9) + (10) -

( )+( )+( )+( )- gms (11)

Percent Solids in Treated Sample:

100 x (11) + ((8)) -

100 x ( ) " (( )) -  % (12)

!!!. DETERMINATION OF WATER IN SAMPLE FOR SOLIDIFICATION:

Volume of Treated Sample to be Solidified: ml (13)

Height of Treated Sample to be Solidified: gms (14)

Height of Hater in Sample Contributed by Haste:

'12] x (14)' x (1 - (1)) -

,( 8) ,

b( ) x( ) x (1 - ( )) . gms (15)

Height of Water in Sample Contributed by 507. NaOH:

~

'L41 x (14)~ x 0.5 - '( ) x ( ) x 0.5 - gms (16)

,( 8) , ,

( )

Total Weight of Water in Sample:

(15) + (16) - ( )+( ) . gms (17)

E3-2 1372c

c L)] Nuclear THI-i Operating Procedure 1104 281 Title Revision No.

Haste Solidification Process Control Program 8 ATTACHMENT 3 (Cont'd) Page 3 of 4 1

IV. DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENT AND HETSO BEADS TO USE FOR SAMPLE SOLIDIFICATION:

sting Figure I, find the 7. solids in sample (12), and DETERMINE I U.e Water / Cement Ratio: (18)

Weight of Cement to Use:

(17) ( )

(18) = ( ) = gms (19)

Weight of Metso Bedds to v e.

(19) x 0.15 - ( )x 0.' _gms (20)

Test Selldification Perfo't By:

Name Date Time V. SAh?LE INSPECTION Sample cured for:

Hours Curea _ __,__,

Temp. Cured ,

Verified By Dati Sample contains "No Free Liquid"-

~~ ~

Verified By Date Sample "Retists Penetration"-

~~

Verified dy Date E3-3 1372:

te U1 Nuclear TM1 1

"" " r Operating Procedure 1104-287 Title T.evision No.

Waste Solidif Qation Process Control Program 12 ATTACHMEN'1 3 (Cont'd) Page 4 of 4 Additional batches solidified based on this sample solidification:

Liner Waste Liner Waste Liner Waste No. Vol. Date No. Vol. Date No. Vol. Date

2. 5. 8.
3. 6. 9.
4. 7. 10.

FOOTNOTES:

1. Maximum allowable oil con *ent for Stable Waste is 1% by volume.

IV. INDEPENDENT VERITICATION BY GPUN MANAGEMENT Tert Sample Meets Acceptance Cr. eria (Section 12) Name / Date / Time Test Solidification Data Sheets (Calculations) Reviewed Name / Date / TLme r

l l

i 1

l l

E3-4 1372c

,c

ENuclear 13,_,

Operating Procedure uumeer 1104-28I Title Revision No.

Waste Solidification Process Control Program 8 ATTACHMENT 4 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR > 10 TO 20 WT7. BORIC ACID Liner type to be used I. Volume of Untreated Waste to Add to l.inerl ,3:

(3) Max. Treated Haste Vol.

Tii x from Solidification Data Tables -

l ( )

( ) x - ft3 (21)

II. Volume of Ad61tives to Add to Liner:

NaOH: (4) x 4.86 x (21) - ( ) x 4.86 x( ) - gals (22)

(3) ( )

Anti-foam: (5) x 7.48 x (21) - ( ) x 7.48 L ( ) = gals (23)

(3) ( )

Emulsifier: (6) x 7.48 x (21) - ( ) x 7.48 x( ) - gals (24)

(3) ( )

III. Volume of Treated Waste to be Solidifiedl :

[ (22) + (23) + (24) ( ) +( )+( )

l (21) + 7.48 - ( )+ 7.48 - ft3 (25)

IV. Cement Quantity for Full . .le Solidification:

(19' x-52.4 x (25) -( ) x 62.4 x ( ) - lbs (26)

R) ( ) l (26) + 94 - ( ) 94 - bags 2 V. ASMS Quantity for Full Scale Solidification:

i (25) x .15 - ( ) x .15 - lbs (27)

(27) + 100 - ( ) 100 - bags 2 Ea-1 !372c

ENuclear ,,1_,

sumter Operuting Procedure 1104-281 I

Title Revision No.

Haste Solidification Process Control Program _

9 .

ATTACHMENT 4 Page 2 of 3 SOLIDIFICATION CALCULATION SHEET FOR > 10 TO 20 WT% BORIC ACID VI. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIDIFICATION CALCULATION SHEETS REVIEWED Name / Date / Time .

FOOTNOTES 1

l 1 The volume of treated waste to be solidified in single liner cannot exceed the maximum treated waste volume listed on the attached Solidification Data Tables. .

2 Round off up to the nearest whole bag.

3 Use the actual waste volume added to the liner in steps /eouations 22, 23 and 24 if the waste volume added to the liner is less than the value obtained in Step / Equation 21. ,

VII. DETERMINATION OF TH! QUANTITY OF CEMENT ADDED TO WASTE:

Quantity of Cement Added to Hopper: lbs (28) l Quantity of Cement left in Hopper: lbs (29)

Quantity of Cement Added per ft.3 Waste:

(28) - (29) - ( ) - i ) -

lbs cement /

t (25) ( ) ftb waste NOTE: Minimum Quantity of Cement Allowable for >10 to 20 Wt.

1 Boric Acid Class A Unstable Waste is 60 lbs./ft.3, for STABLE waste solidifications all the cement must be added to the liner Quantity of Cement Added Meets the Minimum Requirements for unstable waste forms:

Verified By Date it recommended minimum treated waste volume and minimum solidified waste volume meet the requirements of the Solidification Data Tobles for STABLE waste forms.  :

~~~ ~ ~ ~

i Vuified By Daie E4 2 1372c

[r r >lNuclear 7Ht-i Operating Procedure Number 1104-281

~ Title Revision No.

Haste Solidifice, Process Control Program 7 ATTACHMENT 4 (Cont'd) Page 3 o' 3 SOLIDIFICATION DATA TABLES FOR > 10 TO 20 WT1 BORIC ACID HN-100 HN-100 LVM Series 3 Series 31 Usable Liner Vol. (cu. ft.) 141.1 157.5 Max. Treated Waste Vol. (cu. ft.) 101.3 113.1 Hax. Solidified Waste 141.1 157.5 Vol. (cu. ft.)

Recommended Min.

Treated Waste Vol. 95.2 100.7 (cu. ft)2 Min. Solidified Waste Vol. (cu. ft)2 132.6 140.2 Max. Rad. Level 12 12 R/hr Contact -

1. For less than A2 quantitles of LSA waste. For greater thi.n 8.j quan*_ 'in. of LSA waste, the maximum treated waste volume is 106 cu. ft. due t- seigh.

limitations.

2- These minimums are required when shipping to Garnwell, to comply with the 15%

maximum vold space criteria f,, liners containing solidified stable waste forms, l

i l

E4-3 1372c l

[c UINuclear THI-l Number Operating ProcM ure 1104-281 Title Revision No.

Haste Solidification Procer.s Control Program 11 ATTACHMENT S page 1 of 2 CLASS A UNSTABLE AND r. TABLE, CLASS B AND C TEST SOLIDIFICATION DAT,*. SHEET FOR WASTE Olt Chem. Parameters (Conc. Waste) Balance Cal. Info Liner No, Sample Date CMTE No. Sample No.

Boron ppm Serial No. Date:

Total Solids opm Cal. Due Date: Waste Class-pH l

Total Act, pC1/cc

1. SAMPLE PREPARATION Volume of Oli to be Solidified: _

mis (1)

Volume of Concentrated Waste added to the oil: mis (2)

Total Volume of Sample: mis

% Oil by Volume:

(1) x 100 - ( )_x 100 - 1 (3)

(1) + (2) ( )+( )

Height of 50 wt% NaOH added to sample to raise pH > 5 gms (4)

Quantity of Emulsifier to Add to Sample: mis (S)

Quantity of Anti Foam Added to Sample: mls (6)

Quantity of Portland Type : Cement Added to Sample: gms (7)

Quantity of Anhydrous Sodium Metasilicate Added

' . Sample: gms (8)

Test Soliditication Performed By:

Name Date ilme ~

E5 1 1372c

?

U N 7gy_3 Operating Procedure 1104-28I Title Revision No.

Waste solidification Process control Program 12 ATTACHMENT 5 (Cont'd) Page 2 of 2 i

II. SAMPLE INSPECTION ,

Sample cured for:

Hours Cured Temp Cured ,

5 Verified By Date Sample contains "No Free Liquid":

Verified By Date Sample "Resiuts Penetration":

Verified By Date Additional batches solidiflod based on this cample solidification Liner Waste Liner Waste Liner Paate No. Vol. Date No. Vol. Date No. Vol. Date

2. 5. 8.
3. 6. 9.
4. 7. 10.

III. INDEPENDENT VF"IFICATION BY GPUN KANAGEMENT Test Sample Meets Acceptance Criteria (Section 12) Name / Date / Time l Test solidification Data Sheets (Calculations) Reviewed Name / Date / Time 1

l ES-2 1372c

[W INuclear Tsi-i Operating Procedure 1104-281 Title Revision No.

Waste Solidification Process Control Program 8 ATTACHMENT 6 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR HASTE OIL Liner type to be used I. PARAMETERS FOR FULL SCALE SOLIDIFICATION Emulsifier:

(5) x 7.48 + (1) - ( ) x 7.48 + ( ) - gal / .(9) l ft3 Anti-foam 1 1 (6) x 7.48 x (1) + (2) -( ) x 7.48 x ( )+( ) gal / (10) ft3 Cement:

1 1 (7) x 62.43 x (1) + (2) - ( ) x 62.43 x ( )+( ) lbs/ (11) ft3 ASMS:

1 1 (8) x 62.43 x (1) + (2) - ( ) x 62.43 x ( ) +( ) lbs/ (12) ft3 II. QUANTITIES TO BE ADDED FOR FULL SCALE SOLIDIFICATION Volume of untreated waste to add to liner (Max Treated Haste Vol from Solidification Data TaF'" ): 3 (13)

Concentrated Haste to be added:

60% x (13) x 7.48 0.60 x ( ) x 7.48 - gals (14)

Haste Oil to be added:

407. x (13) - 0.40 x ( ) - ft3 (15) 40% x (13) x 7.48 - 0.40 x ( ) x 7.48 - gals E6-1 1372c

_ - _ _ _ - _ _ _ _ - _ _ _ _ _ __ .- . _ _ . _ _ __ _ _ _ _ _ _ __ .__ ._D

U1 dlNuclear THI-1 Nueer Operating Procedure 1104-281

~ Title Revision No.

Waste Solidification Process Control Program 9 ATTACHMENT 6 (Cont'd) Page 2 of 3 Emulsifier to be added:

(15) x (9) -( )x( ) -

gals Anti-foam to be Added:

(13) x (10) - ( )x( ) -

gals ASMS to be added:

(13) x (12) - ( ) x( ) -

_lbs (16)

(16) + 100 - ( ) + 100 - bags l Volume of cement to add to liner:

(13) x (11) - ( ) x( ) -

Ibs (17)

(17) + 94 - ( ) + 94 - bags I FOOTNOTES:

1 Round off up to the nearest whole bag.

2 Redure the quantity of total waste in the liner by 1 ft3 for every 10 gallors of anti-foam added to the liner No acjustment is necessary for the first 10 gallons, 3

Use actual waste volume added to the liner in step /eaudtions used in Sect'.on II if waste volume added to the liner is less than the value obtained in Step / Equation 13.

III. INDEPENDENT VERIFICATION BY GPUN MANAGEMfNT SOLIDIFICATION I CALCULATION SHEETS REVIEHED_

Namo / Date / Time l

{

E6-2 1372c

Ic udlNuclear 781-1 Number Operating Procedure 1104-281 Title Revision No.

Haste Solidification Process Coatrol Program 7 ATTACHMENT 6 (Cont'd) Page 3 of 3 i SOLIDIFICATION DATA TABLES FOR HASTE OIL HN-100 HN-100 Series 3 LVH Usable Liner Volume, (ft 3) 141.1 157.5 Max. Haste Volume (oil and conc. waste), ft3 93.7 104.6 Max. Solidified Volume, ft3 141.1 157.5 Maximum Rad Level R/hr Contact 12 12 i

l l

l l

i l

l E6-3 1372c

Ir kllNuclear Tsr-i Opcracing Procedure 1104-281 Title Revision No.

Haste Solidification Process Control Prograin 8 ATTACHMENT 7 Page 1 of 2 CLASS A STABLE, CLASS B AND C TEST SOLIDIflCATION DATA SHEET FOR USED PREC0AT Balance Cal. Info. Chemistry Parameters Liner No.:

CMTE No, pH Sample No.:

Serial No. Gamma Scan mC1/ml Date:

Cal. Due Date  % 011  % Waste Class I. SAMPLE PREPARATION Height of Dewatered Powered Resin gms (1)

Volume of Dewatered Powered Resin ml (2)

Weight of Hater Added to Powdered Resin: gms (3)

Total of Volume of Powered Resin Slurry; ml (4)

Quantity of Anti-foam Agent Added to Sample: gms (5)

Quantity of oil in Sample _ ,_ 1 (6)

Quantity of Emulsifying Agent Added to Sample: gms (7)

Inttlal pH of Sample: (8)

II. SOLIDIFICATION Quantity of Ca(OH)2 necessary to raise pH > 11.5: gms (9)

Final pH of Sample: (10)

! Quantity of Portland Ceinent AdJed to Sample gms (11)

Final Sample Volume: mis (12)

Test Solidification Performed By:

Name Date time E7-1 1372c

[e q)1 Nuclear Ts -

Operating Procedure 1104-28I Title Revision No.

Waste Solidification Process Control Program 12 ATTACHMENT 7 (Cont'd) Page 2 of'2 CLASS A STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR USED PRECOAT III. SAMPLE INSPECTION Sample cured for Hours Cured Temp. Cured Verified By Date Sample contains "No Free Liquid":

Verified By Date Sample " Resists Fenetration":

Verified By Date Additional batches solidified based on this sample solidification:

Liner Waste Liner Waste Liner Waste No. Vol. Date No. Vol. Date No. Vol. Date

2. S. B.
3. 6. 9.

4, 7. 10.

IV. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT Teen Sample Meets Acceptance Criteria (Section 12) Name / Date / Time Test Solidification Data Sheets (Calculations) Reviewed- '

N ame / Date / Time E7-2 1372c

P UINuclear m -1 Operating Procedure Number

_ 1104-281 Title ,

P Waste Solidification Process Control Program 8 ATTACHMENT 8 Page 1 of 3 SOLID!flCATION CALCULATION SHEET FOR USED PREC0AT Liner Type to be used I. PARAMETERS FOR FULL SCALE SOLIDIFICATION:

Quantity of Water:

(3) x 7.48 - ( ) x 7.48 , gal / (13)

(2) ( ) ft3 of waste Quantity of Anti-Foam Agent:

(5) x 7.48 - L ) x 7.48 gall (14) 1 (2) ( ) ft3 of waste Quantity of Emulsifier:

(7) x 7.48 - ( ) x 7.48 , gal / (15)

(2) ( ) ft3 of waste Quantity of Ca(OH)p:

(9) x 62.43 - ( ) x 62.43 , _ ___ lbs/ (16)

(2) ( ) ft3 of waste Quantity of Portland Type 1 Cement:

(11) x 62.43 - ( ) x 62.43 , ibl/ (17) l (2) ( ) ftJ of waste II. QUANTITIES TO BE ADDED FOR FULL SCALE SOLIDIFICATION Volume of Dewatered Powdered Resin to be Solidified
ft3 (18)

Quantity of Water:

(18) x (13) - ( ) x( ) - gal (19)

Quantity of Anti-Foam Agent:

(18) x (14) - ( ) x( ) - gal (20)

, Quantity of Emulsifier:

1 (18) x (15) - ( )x( ) - gal (21)

[8-1 1372c l

l

Nuclear Number IMI 1 Operating Procedure 1103-281 Title Revision No.

Waste Solidification Process Control Program 9 ATTACHMENT 8 (Cont'd) Page 2 of 3 SOLIDIFICATION CALCULATION SHEET FOR USED PREC0AT Quantity of Ca(OH)2 (18) x (16) - ( ) x ( ) -

lbs (22)

(22) + (100) - ( ) +( ) -

bags 2 Quantity of Portland Type Cement:

(18) x (17) - ( ) x( )a lbs (23)

(23) + (94) - ( ) +( ) - bags 2 I

The volume of waste, to be solidified in a liner cannot exceed the maximum settled and treated waste volume listed on the Class B Haste Solidification Data Table for used precoat.

2 Round up to the nearest whole bag.

d III, INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIDIFICATION CALCULAi!ON SHEETS REVIEWE0 Name / Date / Time l

l r

E6-2 1372c

1 '

Number Ic d)] Nuclear mi-i Operating Procedure 1104-281 Title Revision No.

Haste Solidification Process Control Program 8 ,_

ATTACHMENT 8 (Cont'd) Page 3 of 3 50LIDiflCATION DATA TABLE FOR USED DREC0A1 .

HN-600 MUS HN-200 MU l

Usable Liner Volune, f t3 59.3 59.4 '

l Max. Solidified Haste Vol. ft3 59.3 59.4 l

Max. Dewatered Haste Vol., ft3 33.3 33.3 i

Min. Haste Vol. ft3 32.9 32.0 ,

Min. Solidified Haste Vol, ft3 58.6 57.0 Max. Radiation Level R/hr Contact of Liner 100 800 ,

EB-3 1372t

Nut ' *

[r gj lNuclear m -1 Operating Procedure 1104-28I Title Revision No.

Haste Solidification Process Control Program 8  ;

s ATTACHMENT 9 Page 1 of 2 CLASS A STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET ,

FOR BEAD RESIN Balance Cal. Info. Chemistry Parameters Liner No..

CMTE No. p H. Sample No.:

Serial No. Gamma Scan mci /mi Date:  !

Ca'l. Due Date 1 011  % Haste Class:

1. SAMPLE PREPARATION Sample Height: gms (1)

Sample Volume: ml (2)

Weight of EC-3: gms (3)

Height of water: gms (4)

Height of Anti-foaming agent added to sample: gms (5)

Quantity of oil in sample:  % (6)

Height of Emulsifier added to sample: gms (7)

Initial pH of sample: (R)

II. SAMPLE SOLIDIFICATION l Height of Ca(OH)2 added to sample to raise

  • the pH > 11.5: ams (9) i Final pH of sample: .

(10)

Height of Portland Type 1 cement added to sample
gms (11) l Final Sample Volume: ml (12)

Test Solidification Performed By:

Name Date Time E9 1 1?72c

U"iFiNuclear TM1 1

"" - r operating Procedure 1104-281 Title Hevision No.

Waste Eolidi,fication Process Control Program 12 _

ATTACitMENT 9 (Cent'd) Page 2 of 2 CLASS A STABLE,' CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR BEAD RESIN 1

III. SAMPLE INSPECTION Sample cured fort Hours Cured Temp. Cured Verified By Date 1

l Sample contains "No Free Liquid":

l Verified By Date  !

Sample "Resiste Penetration":

Verified By Date Additional batches solidifled based on this sample solidification:

Liner Waste Liner Want<

  • Liner Waste No. Vol. Date No. Vol. Date No. Vol. Date
2. 5. 8.
3. 6. 9
4. 7. 10.

l IV. INDEPENDENT VERIFICATION BY c"UN MANAGEMENT 1

Test Sample Meets Acceptance

  • Criteria (Section 12) Name / Date / Time
Test solidification Data l Sheets (Calculations) Reviewed l

Name / Date / Eme I

l l

, E9-2 1372c l

i Ir LUNuclear 1Hi-i Operating Procedure 1104-281 Title Revision No.

Waste Solidification Process Control Program 8 ATTACHMENT 10 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR BEAD RESIN Liner Type to be used:

11. PARAMETERS FOR FULL SCALE SOLIDiflCATION Quantity of EC-3:

(3) x 6. 3 . ( ) x 6.3 gall (13)

(2) ( ft3 of waste Quantity of Hater:

(4) x 7.48 . ( ) x 7.48 gal / (14)

(2) ( ) ft3 of waste Quantity of Anti-Foam Agent:

(5) x 7.48 . ( ) x 7.48 gall (15)

(2) ( ) ft3 of waste Quantity of Emulsifier:

(7) x 7.48 . ( ) x 7.48 gal / (16)

(2) ( ) ft3 of waste Quantity of Calcium Hydroxide Ca(OH)2:

(9) x 62.43 . ( ) x 62.43 Ib (17)

(2) ( )

ftg/ of waste .

Quantity of Portland Type 1 Cement:

(11) x 62.43 . ( ) x 62.43 Ibs/ :18)

(2) ( ) ft3 of waste

11. QUANTITIES TO BE ADDEO FOR FULL SCALE SQLIDIFICAf10N Haste Volume of to be Solidified1 ,3: ft3 (19)

Quantity of EC-3:

(19) x (13) . ( )x( ) a gal (20)

EIO 1 1372c I

P a>] Nuclear Number THI-l Operating Procedure 1104-2PI litle Revision No.

Waste Solidification Process Control Program 9 ATTACHMENT 10 (Cont'd) Page 2 of 3 SOLID!f! CATION CALCULATION SHEET FOR BEAD RESIN Quantity of Water:

(19) x (14) - ( ) x( ) -

gal (21)

Quantity of Anti-foam Agent:

(19) x (15) - ( )x( ) -

gal (22)

Quantity 5f Emulsifier:

(19) x (16) = ( ) x( )- gal (23)

Quantity of Calcium Hydroxide Ca(OH)p:

(19) x (17) - ( ) x( ) -

Ibs (24)

(24) + (100) - ( ) + 100 - bags 2 OJantity of Portland Type Cement:

(19) x (18)

+

- ( ) x( ) - Ibs (25)

(25) (94) = ( ) + 94 - bags 2 I

The volume of dowatered bead resin to be solidified cannot exceed the mawimum treated . .'e volume listed on the Class A Stable, Class B and C Test Solidification Data Sheet for Bead Resin.

2 Round up to the nearest whole bag.

3 Reduce the quantity of waste in liner by 1 ft3 for every 10 gallons of anti-foam agent plus emulsifier added to liner.

t l

III. INDEPENDENT VERIFICATION Bf GPUN MANAGEMENT SOLID!flCATION CALCULATION SHEETS REVIEWED ~

Name / Date / Time l

E10-2 1372c I

MUClear THI-i Operating Procedure 1104-28I Title Revision No.

Waste Solidification Process Control Program 8 ,

ATTACHMENT 10 (Cont'd) Page 3 of 3 SOLIDIFICATION DATA TABLES FOR BEAD RESIN HN-100 HN-600 HN-600 LVMU HN-200 MU LVMVGS Usable Liner 148.8 59.4 64.0 61.7 i Volume (cu. ft.)

Max. Dewatered 120.0 47.9 51.6 49.8 Haste Volume (ce, ft.)

Mix. Solidified 148.8 59.4 64.1 61.7 Waste Volume (cu. ft.)

Max. Rad. Level 12 800 100 100 ,

R/hr Contact Hin. Recommended (l)

Haste Vol (ft 3' 106.9 46.0 -

47.3 Min Solidif..JII) 132.6 57.0 -

58.6 (1) Crout will have to be added to the HN600 MU to increase the solidified waste volume to meet the 15% maximum void space criteria for shipment to '

Barnwell.

l I

l l

F E10-3 1372c

Ir MjNuclear' m, _1

"- r Operating Procedure 1104-:BI Title Pevision No.

Waste Solidification Process Control Program 13 ATTACHMENT 11 Pago 1 of 1 TEST SOLIDIFZCATION USING WESTINGHOUSE - HITTMAN PROCEDURE Waste to be Processed _

Westinghouse ..ittman Procedure No.

Procedure - Title Current Revision Justification to use this alternate test procedures Eng. Review By Liner Not Alternate Test Procedure Approved for Uso i

Sample Not Name /Date l

Liner Type Waste Class Balance Cal Info. Chemistry Tarameters CMTE No. Sample Date __

l .

Serial No. _

Boron ppm Cal. Due Date Total Solida ppm pH Total Activity mci /cc Independent Verification by GPUN Management Test Samplo Meets Acceptance Criteria (SectLon 12)

Name /Date / Time Tset Solidification Data Sheets (Calculations) Reviewed Name / Date / Time E11-1 1372c h

STD-P-05-003 1104-281

- Pcgo 32 of 35 Revision 9 0.94 '

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