ML20053D702

Public Version of Revised Lzp Procedures,Including Procedure Lzp 1330-21 Re Determination of Reactor Coolant Chloride Concentration at High Radiation Sampling Sys. Revised Index Encl

ML20053D702
Person / Time
Site:	LaSalle
Issue date:	05/07/1982
From:	COMMONWEALTH EDISON CO.
To:
Shared Package
ML20053D695	List: ML20053D699 ML20053D702
References
PROC-820507-02, NUDOCS 8206070229
Download: ML20053D702 (57)

Text

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PAGE 3 LIP INDEX 8/17/81 REV. REV OATE DISAETT-

) ROC. No. TITLE 01 5/81 01

• IP 1220-1 EMERGENCY TELEPHONE NUMBER 01 T/81 01 1220-4 DELETED LIP 01 l/92 02

' LP 1310-1 NOTIFICATIONS 03 Nf/E- 02 1320-1 AUGMENTATION OF PLANT STAFFING LIP 11/80 02 01

.ZP 13J0-1 POST-ACCIDENT SAMPLING OF REACTOR COOLANT 01 3/81 03

' 49

. 1330-2 POST-ACCIDENT SAMPLING OF THE PRIMARY CONTAINMENT ATMOSPHERE FOR RADIDIDINES DETERMINATION AND PARTICULATES ALTERNATE HEANS 02 3/81 02 1330-3 POST-ACCIDENT SAMPLING OF PRIMARY LIP CONTAINMENT ATMOSPHERE 01 11/80 03 1330-4 POST-ACCIDENT SAMPLING OF THE PLANT LZP VENT FOR RADIGICINES AND PARTICULATES 00 11/80 03 LZP 1330-5 POST-ACCIDENT NOSLE GAS RELEASE RATE OETERMINATION 01 7/81 03 1330-6 DELETED LZP 01 11/80 02 LLP 1330-7 POST-ACCIDENT SAMPLING OF THE STANOBY GAS TREATMENTL (SBGT) SYSTEM EFFLUENT CO 8/81 03 1330-8 SAMPLING LIOUID PROCESS MONITCRS RACIATION LLP OURING LIQUID MONITOR HIGH ALARM CONDITIONS RLINE SAN-2 0t /91 03 L4P 1330-10 11/81 00 DILUTION AND TRANSTER OF GAS 00 3/81 03 t.ZP 1330-11 SARCNSAMPLES 1330-20 POST-ACCIDENT ANALYSIS OF LLP (BACKUP PROCECURE)

I G. 03 LZP 1330-21 DETERMINATION OF REACTOR COOLANT CHI.0 RIDE03CON TRATION AT THE HIGH RADIATION SAMPLING 0aSYSTIM //32 L4P 1330-22 CALIBRATION OF THE MODEL 10 OIONEX ION CHROMATOGRAPH Ci ,700 03 DETERMINATION OF REACTOR COOLANT PH, LZP 133C-23 l CCNOUCTIVITY AND DISSCLVE0 OXYGEN CONCENTRATION AT TnE HIGn RAOIATION SAMPLE SYSTEM 8206070229 820527 i PDR ADOCK 05000373 F PDR

a/17/81 LIP INDEx PAGE 4 PROC. f.0. T!TLE REv. REV OATE CISAETT

/

LLP 133C-24 DETERMINATION OF REACTOR /CCCLANT CO to/8l 03 -

MYOROGEN CONCENTRATION AT THE H1GH RAJIATICN SAMPLING SYSTEM

l. Z P 1330-25 SMIPLING OF REACTOR COOLANT AT THE HIGH 0l 3/O C3 RADIATION SMiPLE SYSTD1 LZP 1330-20 SMIPLING OF CONTAIMIENT AIR AT THE HIGH CQ. 5/f6L C3 RADIATION SMfPLING SYSTEi

.29 133C-27 SAMPLING OF REACTOR C00LAPT OFF-GAS AT Cl 3%p 03 THE HIGH RA01ATION SAPPLE SYSTEM

.LF 1330-26 SM!PLING OF PROCESS t,'ATERS CONTATNTMI'. 'AAnm. 01 3/?S- 03 ACTIVITY AT THE HIGH RADIATION SAMPLING SYSTDi LLP 1330-29 SAMPLING AT THE HIGH RADIATION CO 'f/ f.2 CJ SAMPLING SYSTEM (VALVE OPERATION AT THE VALVE CONTROL PANEL)

' ZP

. 1330-30 TRANSFER OF WASTE FROM inE HRSS 4A3TE CO d /61 03 TANK AND WASTE PUMP uZP 1330-?.1 s 50 See next oace LLP 1390-1 IMPLEMENTING PROCEDURE FOR FIRE: Oi 9/B/ 02 FIRE PARSHALL LLP 1340-2 IPPLEMENTING PRCCEDURE FOR FIRE: Cl 9/6/ C2 FIRE CnIEF (OESIGNATEC SMIFT FOREMAN)

L4P 13*0-3 IMPLEMENTIt4G PROCEDURE FOR FIRE: 0I 9/6/ 02 FIRE OFFICER i:1 (COGNIZANT MAINTENANCE FOREMAN)

.LZP 1340-4 IMPLEMENTING PRCCEDURE FOR FIRE: 01 4/8/ 02 FIRE BRIGADE LLP L340-5 IMPLEMEhrING PRCCEDURE FOR FIRE: C1 8/81 C2 FIRE COMPANY NO. 1 (MAINTENANCE PERSCNNEL)

LLP 13o0-1 PROTECTIVE MEASURES FCR ON-SITE C3 7/81 G2 PERSONNEL LLP 13o0-2 USE OF PCTASSIUM 10 CIDE (KI) AS A CG 7/81 C3 TMYROID 3 LOCKING AGENT LZP 1360-4 SEE NEXT PAGE LIP 137C-1 RESCUE _

CO 10/8C C2 LLP 137C-2 PERSONNEL INJURIES C1 11/30 C2

' LLP 1370-3 FIRST AIO, DECONTAMINATION ANC 00 10/80 02

'VACUATION c CF EXPGSEO AN0/CR

- CONTAMINATEC CASUALTIES  !

L_.;.

Lip 1350-1 CONTROL ~0F CIL SPILLS CO 10/BC C2 M

m. .

_._ e i e

LZP-1330-21 Revisicn 2 April Zo, 19d2 1

DETERMINATICA CF REACTOR CCOLANT CHLCRICE CCNCENTRATICN AT TME HIGH RAJIATICn SAMPLING SYSTEA A. AURDCSE Tne puracse of thi s prececurs is tc celineate a metnce of aetermining :ne reactor cool ant chicr ice concentration at tne High Raciation Sampling System (HRSS) curing normal anc cost-accicent concitions. This prccecure incluces enlar i ca stancarci z ation, samule analysis, system flusning anc column regeneration sections.

o. REFERENCES

1. Sentry Equipment Corporation, Pcst Accicent Samcle System, volume 1.

2. LZP 133C-29. " Sampling at the Hign Raciation Sampling System (valve Cperations at the HRSS Valve Control Panel)."

3. LZP 1330-22, "Calicration of tne Mocel 10 Dionex lon Chromatograpn."

C. PAEREQUIS M

1. Tne operatcr snould ce familiar nitn tne coeration of :ne ion enromatograan.

2. Verify tnat instrument air, approximatel f 100 psig, anc nitrogen, approximately oC asig, are availaale at tne Cnemical Anal fsis Panel (CAP), OPLELJ.

3. Fill a four liter ccilapsaole container witn cemineralizec aater. Remove excess air from tne cottle anc l acel tne cottle. Cennsc: tre cottle to tna waterline :n tne reagent stcrage facility in

ne CAP, CPLE1), open :ne container valve ana tnen vent tne fesc lines.

4 Cnecx that tne containers or eluent, regenerant, ano cnlorice stancarc are approximately nalt tuli,

~

rill it necessary. ,

5. Onecx anc vent pumps ir air oucoles are visiule in

no signt gl ass. Venting is normally requirec anen

ne elvent anc regenerant containers are fillec.

t -

-e s LLP-133C-21 Revisica I .

- April 25, 19d2 1

c. Easure snat tne ion-excnange col uu.ns in usa nave oeon calicratec.

7. Reagents:

3.

C.ClO P Socium tetracorate (Na d 07 10n C)

(E-2).

a.

C.C0c P Socium carconate (Na CC3" 2 I I~

c.

1 A Sulfuric acic (H2SC*I I GENI *

c. I ppe Cnlorice stancarc (CAL-3).

6. Tne sample must nave osen octainec in accercance altn Reference 2 prior to performing this orocecure.

9. Notify Rac/Cnem Supervision if any prcolens are encounterec at tne MRSS panels.

D. PRECAuTICNS

1. A Regulatory Guice 1.3 or 14 release of rission oroducts implies extrenely hign levels pf racioactivity. Jose rates may ce nign encugn to prevent entry into many areas of tne plant enat are normall y naci tacle. Rac/Cnem Supervisicn snoulo ce centactec pricr to entry into any area anen sucn a release of fission proaucts is suspectec.

2. near raciation cosimetry as recc.nmercea oy R ac/Cnem Supervision.

3. dear protective clotning anc respira: cry protectico as reccmmencec cy Rao/Cher Supervision.

4. Aporopriate survey instruments sncula os availaole fcr monitoring caring tnis prececure.

5. Neo calicration curves are recuirec *nen cclaans are crangea, since eacn set of colowns .ill sno.

sligntly.citferent results witn respect tc pean neignt anc cossioly' retention time.

c. Calioration snoulc ce cnecksc after maxing ua ne.

elvent. Results will'Oif*er if :ne ccncentration af tne new eluent ciffer..fron ne cic.

->we 7

LZP-133C-21 Revisicn 2 .

April 2c, 19s2 3

5. W ITATICNS ANC ACTIC15

1. This analysis must ce completed nitnin 24 nours ecllowing an accicent scnciticn.

2. Uncer ccst-accicent ccnciticns. cclumn regeneratica shoulo ce performeo as soon as aracticacle aftur completing tne cn10r ice anal ysi s. Re;eneratica ill significantly recoce or vi rtua11 '/ el i x i rate tne resin columns as a raciation source.

3. The calioration curve snoulo ce chec<ed ever y roar samples oy analyzing a cnlorice standarc.

• . Tne resin columns snoulc ce replacac cuerf year.

anc new calioration curves cevelopec.

5. This prccecure is to na used for measuring cnlorice concentration for tne range of C.1 to 2C pam in primary coolant eater samples. The estimatec crecision is accut 15 sercent rce tne range of C.1 to 1 pga anc 20 percent for the range of 1 to 2C opm. Accuracy of analysis for tne nigner range can os imprcvec to accut : 10 cercent oy calioration in tnat raage. A chicrice cetermination can ce outaineo nitnin 15 minutes after primary cociant is cnargec tc :ne ion enromatograon.

6. Retenticn time for- any ionic species will vary ai tn cump stroke setting. Pump stroxa snoulc remain constant for routine anal ytical use.

7. Regeneration is reauirac accut once ever y f cur nours curing continuous operati on of the system.

8. Juring continuous operation or tne system, tne columns must ce cleanec en a caily casis er every otner regeneration oy ounping C.OCo M scaium carocnate througn the columns rcr 3 15-20 minute perion. inis I is none pricr to regeneration of tne sucarusser j _

col umn.

v. Tnis prccecure. tnougn intencea fcr use uncer ocst-accicent concitions. can os usec f o r -s sa pl i n g at -

~~

cne nRSS canals curing normal operaticns, aurine wnicn tre precautions ma/ nave limitec ap;licatians.

-caever, normal routine sangling precaaticns snealc ne coservec.

.m.

LZP-1330-21 devision 2 _

Aaril Zo, 1982 4

F. PcCCEDUR6 U2Li Scr noun naves associats; itt tne valves operat6c in tnis procecura, refer to Attacnment d.

1. Verify tne folicainc val es lineup at tne L5P. OriloJ:

a. RC-V-1.1 (closec).

a. RC-V-1.2 (cicsec).

c. RC-V-1.3 (cicsec).

c. RC-V-l.4 (closed).

e. RC-v-1.5 (closec).

f. Verify RC-V-4 is closeo. Connect the flush water hose to RC-0-1 and open tne flush .ater line valve.

i g. RC-V-5.1 (closec). .

n. AC-/-5.2 (closec).

'i. RC-V-2 (closes).

J. RC-v-9 (cicsec). l

k. RC-V-11 (closec).

1. RC-V-2C (closec).

t

m. RC-V-21 (closac).

a. RC-V-1c (closec).

~

o. dC-V-3.1 (clasec).

c. RC-V-3.2 (closec).

4.- RC-Ov-1 (oYDASS).

r. RC-V-13 (o O'cicc<).

4,,

l

• A,,..~

'e .

e LZP-1330-21 Aevision 2 -

April io, 1962 5

s. RC-V-lo (3YPASS).

t. RC-V-22 (TC C. HEM PANEL).

u. RC-V-17 (classd).

v. RC-V-7 (csen).

... RC-9-3 (coen).

2. Verity tne folicwing valve lineup at tne C.P. OPLElJ:

a. Connect enc flusn ater nose tc C-3 anc caen tne flusn water line valva.

c. V-10 (open).

c. v-11 (cpen).

c. V-12 (open).

a. V-2 (open).

f. V-8 (open).

g. v-15 (cicsec).

n. v-9 (closec).

i. V-29 (TO NITROGdt. 3dPPLY).

J. V-S (CLOSEC).

<. V-6 (CXYGEN C ALId 50LUTIC:J) .

1. V-7 (YSI OXYGEr. ANALYIER).

3. Startup tha Icn Cnromste ,:racn at tne CMF. CPLE-J.

in accorcanca itn tne falle.ing:

3. olace'tne P0aER and uIn s itenes tc C3 position.

D. Place LCAC/IP, JECT suitch in LCAO ccsition.

I

~"

c. Place tne E-2 switen in tna 09 pcsition. l M ^

_ . , _ _ , .._..s .-- . . . . .-- . .-

w -

C -p t m-- - ---

LLP-1330-21 Revision 2 _

April 2e, 1982 b

c. Place tne SEPtPATJR switen in tne SEP-1 positicn.

e. Place tne SuPPRESSCR s.iten in the SLP-1/RG..-

2 positicn.

4 Startuo the cenouctivity mater at tre CAP OPLEla.

in accorcance with cne rollcwing:

s. Set MCCE s. itch to LERC anc adjust tre meter to zero with tne scren oel o. the me ter race.

c. Set MOCE saitch to CAL tc set tne reter at rull scale. CAL is sajustac .itn the scre, at cne top of the meter circuit ocarc. The aaj us t.ne nt screw is lacelec METER.

c. Set tne FJC2 switen to LIN.

c. Set the umho full scale saiten tc 3C. After coeration cr the system for approximately 30 n.i n u t e s , set the switen to 1.

e. Set tne CFFSET range switch to x 1C.

5. Perform the system baselire st3Dilizaticn in accoracace witn the folic.ing:

a. At tne CAP. 0?LdlJ, cneck tnat One eluent pump switen is CN.

l

?.CT:

---a setentien time for any ionic species .ill vary ainn cuma stro<e setting. Jumo stroke snoulc remair.

cons ant for routine analytical use.

c. Turn the puma saiten en tne c'4P. CPLE4J. to the C4 position.

c. Turn tre gauce switen en the CPP, CDLi*J. to tne CN cosition. ' ar ndl aper-ating pressure is 20C ps ig, hc vver . prassure .ill fi ctuat= Jue tc the punc reciprocating,

c. Operate tne system rcr aparoxiaately 3C winutes or until tre aaseline stacilizes witr tne umno setting in tre i Josition.

uM O

w

/

/

L4P-1330-21 Revisicn e

/ Aaril 2c, i412 7

C. Perform the Chloride CalicratiJn CneCK in UCCcrGaHCe witn tne folicwins at ne CAP. OPLElJ, cr as c:norniS6 cirectac:

3 Al i gn val vo v-5 to CrLLd1JE CALIS SOL'JTICA.

c. a uj o s: valvt v-15 until sufficien ria. is incicatec cy the re2 flo. incic ator li;nt.

Allo. tne line to flusn ror a mininun of :.o (2) minutes.

c. At the CMP, OPLE4J. alace tne LOA 0/IAJECT s.i ch in tne IAJECT position. Turn en tre cnart recorcer (tne switen is locatec insica an ne ic er rignt as tna recorcer is pullec out).

c. Press tne PIP event recorcer,ouston en :ne CAP.

CPLElJ. Concuctivity .ne te r o r m a r K tre injnct positicn on tne cnart paper of tre reccrcer.

Recora the standarc icentificati'cn anc ca;=

anc time ci analysi s on tne enart p3pur.

e. Turn valve V-5 to ne CLCSED acsition.

f. After approximately one nicute, place tne LCAD/IP. JECT swi ten at tne CAP, OPLE4ae in tne LGAD sositi:n. Tna cnloride asak .ill occur at approximatcly six ninutes af ter i njecti on.

Tnis cean neign mcv se usec as tne rerer:nce point to cetermine the enl arice concentrat ion in su9 sequent unknc n samoles. Turn orf tne chart recorcer en tne CMF, OPLE4J.

g. Tne cniorice stan; arc .ill ne automatic 311y flusrec fro.n na analyzer. Allow ascrcximately tan (LC) minutes to coirolete tris coeratian.

n. Alijn valve V-5 to LIaLIC SAPPLE.

i. Align valve V-29 to tne vent acsi ti cn.

7. o urge :ns system for One reac:cr ccclent ser.a l s in accorcance itn_ :ne fellowinj at tne LSP, GPLJ-a.

a. At ne CAD, OPLE1J, VGrify '/ ~ 5 is alijnec :s LICUID 3A?'PLE.

_p 3. O p e n c'.C-V-1.1 (-1.2, -1.3. -1 4. or -1.5),

cepending cn sample source.

L2P-L330-21 savision 2 Aaril 26, lic2 e

c. Coon RC-VREL-L until RC-FI-l incicatas 35-*0 incnes of water. Parge for a girinun cr five (5) minutes. Slowly close RC-vaEL-1 antil MC-FI-L inoicatas 12-15 incnes cf natsr. Cc.9tinue tne purgo ror a enini ese cf anc (L) minuta.

a. C1cse FC-V-3.

e. Coen RC-V-2.

f. Acjust RC-VREL-2 until RC-F1-2 incicates 1d-22 ircnas of watcr..

g. verity snat tne rion rate at tre CAP Icn Cnroratograpn lina is 13 ml/rin cy ocserving tne roc incicator on the CAP, CPLElJ, i s l i t.

F l u sn f o r a m i n i r..um o f rive (5) mirutes.

1

3. Analyze tha sample in accordance nitn tro rollo.ing at the CAP, OPLE1J. or as otneraise cirectec:

a. At the CFP. CPLE*J, placs tne LCAD/IAJECT soiten in tne IAJECT position anc turn en tre cnart recorcer.

o. Press tne FIP event recoroGr outton cn the CAA i concoctivity meter or mar 4 :ne inject aasiticn on the chart paper at tne Cs1P CPLE4J. Aacora tne sarple source, cace anc tire or analysis, on LRC Ferm IC97C. A t t a chne nt A.

c. After aaproxi.mately one minute, place LCAU/ INJECT switen on tne CMP, CPLE4J, in tne LJAd pos i ti on.

Tne cnlorice osax will occur at aspecximately six minutes after injection. Tarn arr tne cnart recorcer.

3 J. Turn valve V-5 to t,e CEFIN 'aATER positicn.

Flusn witn ceT,ineralizec water f c r s :r. i n i .:.um of t'a o (2) minutes.

e. If the cniorice p034 Jces oft-scais. a reanal ysi s must ce compl etec u s i ng a l ar ge r mi c rc.T.nc sitting (3-uenc). Align v-5 tc LICul0 SA.irLE, riusn for a minicum er ore (1) ainute, and repeat Steps F.d.a. tnrougn F.8.c.

-9 Fluth tne syster in accorcance aitn'tre iclicaing

.at the L3P. CPLCed. or as ot7erwise airect=c:

h-g .-

LZP-l>30-21 Revision 2 Aars1 2d, 1462 9

3. At the CAP. CPLElJ, ali gn V-S to LIOUIC $=MPLE.

c. At the valve Control Panel. CPLC9J. secure Ona saroling lineup in accercance aitn hoference

2. Steps F.1.c.6) tnr:ugn F.1.c.7).

c. At tne LSP. 00LJ8J. Clcsa RC-v-1 1 (-l.2 -1 3

-L.-. cr -1.5).

c. Coen RC-V *.

e. Acjust RC-vR EL-2 unt i l RC-FI-2 incicates id-22 incnes of .ater. Flusn aitn Gemineralizea

-atar for a minimum cf trree (3; .n i nu t e s .

r. Close RC-V-7.

g. Cpen RC-v-3.

n. Adjust RC-VREL-1 until RC-FI-l inoicates 35-40 incnes of .ater. Flush wi tn cemi neral izac nacer for a minimum of one (t) minute.

i. Cicse RC-V-3.

j. Coen RC-V-1.1 (-1.2, -1 3, -1 4, or -1.5) a n'a riusn aitn cemineralized nater fcr a miniaum a or five (5) minutes.

4. Close RC-V-1.1 ( - 1. 2, - 1 3, -1.4, cr -1.5).

1. Coen RC-V-S.1 anc RC-V-d.2.

n. Acjust RC-VREL-2 unti' RC-FI-2 incicates 10-22 inches of aater. Fla;r witn deaineralize; water for a minimum cf trree (3) minutes.

n. At One CMP, COLE 4Je cyc l e tne LO AD/ IP.J EC T s.itcn at least three times. Return it tc tne LJAJ position.

c. At tne CAP. CPLElJ. align V-5 to LLUSEO.

c. Turn V-o on tne CAP, CPLELJ, tc LICUIJ 5AaPLE ano fluso ni tn ce.ni neral i zea as ter for 3 ainimua cr tao (2) minutes.

a e *

+.

____m.____ m_ _ _ - . _ _ . _

LZP-1330-21 Aevisicn 2 April Zo, 1o62 1C

q. Turn V-5 cc CxYGEq CALtd S C L U T I C.N .

r. At tre CAP, OPLEl), cicse tne flust water valve and oisccnnect tre f l usn . ate r ne se f r om 0-3.

s. Secure flusning of closing tre fciloning valves on the LSP, CPL]eJ:

1) RC-V-d.2.

2) RC-V-8.1.

3) RC-V-2.

4) RC-V-3.

5) RC-V-4

t. At the LSP, CPLD6J, close One flust water valve anc cisconnect the fl usn water nc se f rc.n RC-C-1.

u. At tne Valve Ccntrol Panel, CPLC9J. Secure tne system lineup in accorcance witn Reference 2.

Steos F.'l.a.d) thrcagn F.1.f.

10. Regenerate tne columns in accercance itn the following:

a. Uncer post-accident concitions, column regeneration i s per formec as scon as practiccole after completing One chicrice analyses.

Regeneration alli significantly recuce or vi rtuall y el imi nate tne resin colonns as a raciation source.

c. Colunn regeneration is performec ever/ 4 nours if tne icn enromatcgrapn is in centinucus usu.

Tne neec for coluen regeneraticn uncer otner cor.citions is incicatec c/ a nign caseline conductivity. or a significant crange in One tine for the cnloride Dead OC ccCur,or Cnange in osax neignt onen ranning tos cnlorias i stancara. A socium carocnate flust is perforr.ec prior to every otner regeneration. Go tc steo F.10.e. it_on1y regeneraticn is recuirse.

c. Psrfern tne f ol ic.ing lin.ua fer flusniny ct

"~ '

tne resin colunns:  !

l I

• l 4

L2P-1330-21

<evision 2 _

april Zs. 19b2 11

1) Pl ace tne *CGE saiten on :ne CAP, CPLcla, ccncuctivity meter at ZERC.

2) Placa :na El saitch on tne CMP. rtiva.

in tne CN (ug) position.

3) Place ne E2 saiten on :ne CMP. CPLE6J.

in tne CFC (ao.n) pcsition.

4) Pl ace tne SEPARATCR switch cn tre CPP.

CPLC4J. in tne SEP-1 (Jp) pCsiticn.

5) Place the SU3 PRESSOR switen or une C9P.

OPLE4J. in tne S U P - 1/ R Gt.-2 (uc) position.

6) Place tne PLMP saiten on tne CMP, CPLE4J.

in tne CN (up) pos i ti on.

d. The valve lineup in Step F.lC.c aill provide for socium cartonate flusning cf oc:n columns.

Caerate for 15-2C minutes, then turn tne di saiten on tne CMP, OPLE4J, to tne CFF pusstion (ao.n) anc riusn for LC minutes.

e. Place tne PUFP saiten en the CFP. CPLE4Je in tne off (ccon) pos i ti on.

f. Cn the CF?, CPLE4J. ;rn the SLPPRESSjR switcn to tne SUP-2/4GN-1 (co n) positicn.

g. Cepress the REGENERATICN START ouston en :ne CMP, CPLE4J. Tne syst3m timer is set to provice for a 15 minute acid regeneration tolicoso of a 45 minute water rinse, cc not cnange One setting. After one nour :ne system will snut oft automatically anc tne rec reacy lign: .ill ce activatec.

11. Secure the system arter completion cf cclumn regeneration in accorcance oitn tra felicain,:

a. Turn :ne icn enromatcgrapn PCAER sw i tct; cn :ne CMP. CFLE4J. c CFF.

c. Turn :ne AIa saiten to CFF on tne C:4P. CPLE*J.

c. Turn tr.e GAUGE seiten to CFF, en tne CFP, CPLE4J.

i I

L 4P- L.3 3 0-21 Revision 2 April Zo, 1982 L2

10. Calculate the cnlorice concentration in accorc6nce witn the folicning:

+- a. Measurs tne neignt of tne cnlorica s t an.;a r c

p- pea < (PH e units. anc recorc cn LRC 3CRM lO97C (A tachm!n)tA).

c. Measure tne neigre of tne sa.T.ple peae ( 4. ) .

' i- , units, anc recora on LRC Fcr.T 1097C (Attadnment A).

4 c. Calculate anc recora tne chlorice concentration I

in accercance oitn LRC FCAP 1097C ( Attaen.nent

A).

13. Attach the strip cnart from tr.e ion cerc.natograan to LRC FORM 1C97C (Attacnn.ent A) anc foraarc to Rac/ Chem' Supervision.

]

G. LdQMES, 1

, , 1.- *:o n e .

+

H. TjfGsN IC AL SPECIS Q TION REFER QCJS

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. LZP-1330-21

• Revision 2 AorII 26, 1932

. . It

- AT"'ACEiEiT A IA SALI.I CCU: TIT ST. CON Post-Acciden: Analysis cf Chloride Workshee:

SAMPLE SOURCE:

Date Tire C

s Chloride Standard Concen::acien, ppm 1.00 ppm Step F.12.a.

PH Chloride SIandard Peak Height, units Step F.12.b.

PH Sample PeaE Height, neits Step F.12.c.

C

" c.

. Sample Chloride Conden::atien, ppu

(

C, = (C,) x (PHu)

(PH,) ,

l LRC ?CRM 1097C i

md

J l i

, , . ,1 f )

l lip-1330-21 Revision 2 April 26, '9c2 14; 2

ATTaCeME7T d VALVE LISTI7G -

AC-y-l.1 Reactor Recir Loop 3 Sample Catcut Valve 2C-v-1.2 kT De nin inle: Sa.nple Cutout Valve RC-y-l.3 Pre Loop A Samole Cutout Valve RC-v-1.* RHR Locp 3 Sample Cutout valve KC-V-1.5 RT Demin Outlet Sample Cutcut valve RC-V-2 Sample Scurce Isolation Valve RC-V-3 Sample Purge Cutout valve RC-y-* Flusning . vater Isolation valve RC-V-5.1 Pressurizac Sample Inle Isolaticn valse RC-V-5 2 Pressurizac Sample Outlet Isclation valve RC-V-7 Dil utea Saccl e byoass val ve RC-V-8.1 RC-SF-1.2 Inlet Isolation Valve RC-V-d.2 RC-SF-1.2 Outle: Isolatica Valve-RC-V-9 RC-EV-1 Isolation va,1ve ,

RC-V-10 RC-EV-1 Evacuation Cutout valve' RC-V-11 Cff gas 4 aay valve d' AC-v-12 Argon to Air Ejec cr Cutcut valva <

RC-V-13 Off gas vial Evacuation Cutout V.il ve

• RC-V-14 Argon Supply tc C f f- sj a s V i a l Cutcut Valve RC-V-15 Off-cas Sample , u Cnec.tatograpr !sciation valve , , f

/-

3C-V-It RC-SF-1.2 's . e. ga Cutout valve /

HC-V-17 Reactor C o ) . m.

,c'Samcle Cutout valwe RC-V-Ld. Reactor Coc - ant u.icilutec Saxple Sackflusn Cutout valve RC-V-19 Reactor Coolant Uncilutec'Saaple Injection-3C-y-2C Valve l RC-C-1 Fill val ve 9C-V-21. RC-C-l Isolation valve RC-V-22 Licuia Sample to CAP-Isolaticn JJ1ve RC-CV-l Reactor Coolant Dilatec Sample Injecticn valve RC-CV-2 Crf gas Samole Injection valve -

RC-vREL-l Reactor Coolant-Purge Torottleivalve RC-VREL-1 Reactor Coolant Samole'Teret'tle valve v-l Cfr gas Sample to Gas Cnromatocrapr V-2 Ion Cnromatograpn :0 aaste V-5 Ion Cnromatograan Saxole Scurce Selection v-o C Analyzer Sample Scurce Selectior V-7 C An lyzer Selection 2

v-8 C y Analyzar Ciscrar,e Valve V-9 C Calioration Sclution Catou: l-2 T.

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t LZF-1330-21 Acvision 2 -

april 2c. Lic2 15 (finaf ,

(; ;V-l Na Instruxent Air Cutout V-ll ,

Cemineralizec aatar Catout . valve V-12' .: s . Nitrogen Supply Catout talve

- v Ar,gon Supply Cutcut valse V- 15 : Cal-3 Isclation valve p~ j , v-16 Cal-2 Isclation valve

/- v-17 0, Calicraticn Solution Tan < Aecirc valva V-18 0; Calioration Sclution Tanx Jrain Valve

,. 4- V.- 19 C31-3 Crain talve j"

_ V-2C V-24 Cal-2 Cra in val ve Cemin water Fill to J 2 Cal. Soln. T4.

~.

'V-25 Cal-1 Crain val ve

. 1-20 Cal-1 Isolation val se

1. == V-27 Nitrogen Suppl y to Cal-1 N V-28 - Nitrogen Supply to Cal-2 v-29, Nitrogen Supply to Cal-3 J

V-3C Cal-1 Cal-2 Selection valve e

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L4P-1330-22 Ravision 2 -

Asril 2=. 1932 i

CALIdAATIGN OF THE FOCEL 10 DIONEA 10N CnROPATOGRAPM A. PuRotSE Tne purpose of this procecure is te celineate a metnca ter calicration cf -re vocel IC Cicnex Icn Crrena-cgrapn at tre Hi gn Reciation Samplin g system (NRSS).

d. 315EEENCES

1. Sentry Equipment Corporation. Post Accicent s a:na l e System. Voluma 1.

2. LZP 133C-21. "Jeterminati.cn of xeactor Coclent Cnicrice Concentration at tne migh Raciation Sampling System."

C. P R ER e'.U I S I T E S

1. The operator snould ce familiar with tne coeration of tne ion enroratograan.

, 2. Verify snat instrument air, approximately ICC psig, and nitrogen, approximately oC psig, are availacle at the Chemical Anal fsis Panel (CAP), OPLElJ.

3. The icn.excrange colunns nave oeen recently regeneratec or replacec.

4 . Reagents:

a. C .C 10 M. Socium tetraoorata (Na.S 0 *1Cn_0) c *7 4 (E-2).

D. C.C06 F Socium carbonate (Na 4 CC 3

• 1CH.0) c ti-l).

c. 1 N Sul f uric aci c ("2 C,) (4EGEN).

c. Chlorice stancarc; 1 opm, 0.5 poa. C.2 ppm.

and C.1 ppm cnicrice.

5. Fill a four liter collapsaole centsiner witn cenineralizec water. Asacve excess air from tne

-Octtle. ana laost. Connect it to tre waterline in t r. d reagent storage f ac il i ty . Coen tre ccntainer

-valve anc vent feec 1ines.

x- -

LZP-1330-22 Revision 2 -

Aaril 2o, 19c2 2

6. Cnec< that tne elaent anc regenerant containers are aporoximatelp nalf full.

7. Ensure tnat tre cnicrias calicration solution tanx, CAL-3, i s over nal f full cf 1 ppm cnicrice stancard.

C. PR EC AUT I 2r,5

1. Curing normal oceration. :nere are expected tc os no raaiation hazarcs associatec with tne cerfccmarce of tnis procecure, nowever, tne fcilowing precautions shoulc ce ocservac:

a. A Regulatory Guice 1.3 or 1.4 release or rissicn prcoucts i mplies extremely ni 9n lawels or racicactivity. Cose rates aay oe righ enougn to orevent entry inte mary areas of tne plant that are normally hacitable. Rac/Cnem Supervision snculd os contacted prior to entry into any area when sucn a release of tissior prccucts is suspected.

o. Wear radiation oosimetry as reconmenced of Rac/ Chem Supervisicn.

c. wear orotective clotning anc respiratory prctectico as recommencea cf Rad / Cree Supervision.

c. Acprcoriate survey instruments shoulc ce availacle for monitoring curing tni s procecare if it is performec uncer ocst-accicent conoiticns.

E. L T M I T 2 T I Gt15 AND ACTIONS

1.  ?.ctity R ac/ Chem Supervi s i cn if any prcolens are encountered at tne'HRSS panels.

2. This procecure is intencea ror use in caliarating tre ion cnrenatcgrapn in :ne C.1 to 1 ppm cnicrice range. Ho,ever, calicration can ce performec i r.

One 1 tc 20 ppm range ni:n tne use cf tre ap;ropriate calicratiion solutions eric tni s procecure.

. #* 33.TsM15

$I.fi for no n names associated with tne v3lves acerat3G in tnis procacure. refer to attacnment =.

m m

LLP-1330-22 -

Revision 2 Asril 2d, 19c2 3

1. Verity the f olicwing valve l ineup at tne Licuia Sampling.Pacel (LSP). OPLCoJ.

a. RC-V-1.1 (cicssa).

o. AC-/-l.2 (closec).

c. AC-/-l.3 (clossa).

c. AC-V-1.* (closed).

a. RC-V-1.5 (clcssc).

t. RC-V-22 (TC WASTE).

2. verity tne folicaing valve linaup at tne CAP, ;PLElJ:

a. V-10-(open).

o. V-ll (caen).

c. V-12 (cpen).

c. V-2 (cpen).

3. V-d (open).

f. V-29 (to vent).

g. V-3 (CLOSED).

n. V-e (OXYGEN CALIB. SCLuTICN).

i. V-7 (YSI OxvGEN A..iLYZER).

J. V-15 (cicse2).

<. V-9 (closec).

1

1. Connect tne flush water rose tc C-3 anc caen I tne flush water.line valve. I 1

4

3. Start ~ up tne' Ion Chromatograpn at tna Creaical I

. tonitering Panel (CFD).~GPLE6J' in accorcance si n

na'rcllowing:

9 me b w

LZP-1330-22 '

Revssien 4 April 23. 1462

~

a. PlOCe the POW 68 and AIR saitenes tc CN Jcsition.

a. Place LUA0/ INJECT saiten in LOA 0 ocsition.

c. Place tne 6-2 soitcn in :ne UP position.

u. Clace :ne SdPARAT3A switen in tne SEP-i position.

4. Place tne SUPPR$5SC4 switcn in ene SLP-1/AGs-Z acsiticn.

4. Start up tne Conouctivitf lie er at the CAP. CPLdiJ.

in acccraance ai:n ne folicning:

a. Set MOCE switen to 254C anc aujos; tre ne:er to zerc aith the screw celca the meter face.

a. Set the MODE switen to CAL tc set tne meter at full scale. CAL is aajustec with tne screw at the top cf the meter circuit ocard. Tne adjustment screw i s l acelec .uET64

c. Set tne "0CE switen to LI,v.

d. Set tne umno full scale seiten c 30. After-operation ct the system tar apprcximately 30 minutes, set tne switcn to L.

e. Set ne CF5 SET range s itch to x 1C.

S. Perform the system caselire stacilizaticn in accarcance wi:n tne folic,ing:

a. At tne CAP, CPLdlJ. cneck t1e e f fl uent u u.iS saiten in Gr..

3. Turn the puac saiten on tne CAP, OPLE*J. to tne CN ocsition.

c. Turn the gauge switch cn :ne C.vP, CPLd4J.'tc tne CN pcsition. Normal'aperdting OressLre is 200 psig, naaever, oressure will fluctuote due

to the cuac reciprocating.

c. Cuerate tne systen ice approximately 3G Tinutes or until.tre 063eline s:63IliZes witn tne uuho setting in :ne i susition.

i.

l - ee f 'V-

LZP-1430-22 Revision 2 april io, 1962 5

c. Analyze tha chlcrice stancora in accorcance oitn tha following:

3. At tre CAP. OdLilj. align v-5 to CLUSdC anc V-29 to tne vent position.

c '. Cpen V-13 in the rear of tne Cad. CPLElJ.

c. Inject 15 11 of sne 0 1 com cnlorice stanjaru tnrough tne seutun, in tne rear of tre cad.

OdLElJe using Caution not to inject any air cuboles aitn the solution.

w. Cl a ss V-13.

c. At ene CFP. CDLE4J, place tne LOA 0/IAJECT s.iten in tra IAJECT position. Turn cn tre cnart recoraer.

f. Press tre PIP event recorder on the CAP, CDLdlJ.

cuncuctivity T. ster. Reccro the stancarc concentration, cate ano time or analysis on the chart paper.

1

-g. After approximately one minuts, place the l LUA0/I.\ JECT s iten at tne C:4P , OPLE4J. in tne LOAO position. Tas cnlorice peak .ill occur at aporoximately six minutes arter injection.

Tnen turn off tne cnart recoraer on tne C4P.

CPLE4J.

MI_5 It tne cnloride peak is Orf scale. repeat steos F.o.O througn F.3 9 using a larger umro setting.

-n. The cnlorice stancarc will os automatically flushec frc.n the anal /zer. Allo acpecxi na el y ten (IC) minutes to complate this cueracian.

i. Receat Stecs F.6.c througn F.o.h fer e6cn cnlorice stancarc. J . 2 p p.n anc C.5 aam cr.!: rice.

^7 . 2nalyze tre 1 ppn cnicrice stancarc in accarcanc2 with :ne f ol i c. i ng:

c. A l i an v al ve v-2 7 ar. One CAP, GPLElJ. ta AIT4CGEh SuPVLY.

"o '

o l LZP-1330-22 Revision 2 Aaril Zo. 19e2 6

c. At the CA), CPLE1J. align salve V-5 to ChtCRIJE CALIS SCLUTICN.

c. At une CAP. CPLElJ. adjust valve /-15 until sufficient flow is inaicatad ay tne rec tica incicator lignt. Flusn for a .T.ini. Tun cf taa (2) m i r,u t a s .

c. At tne Cre o . CPLE4J. place tne LCA3/ INJECT s,itcn in :ne ItsJECT pos i ti on. Turn en tre cnart recorcer.

e. Press taa PCP event recorcer on uns con uctivity meter en tna CAP. CPLila. Tucccc tne stan; 3ru concentrat.cn. caco and tic.e or analysis on the cnart pasar.

f. On the CAP. CPLE1J. turn valve V-5 tc tne CLCSEv position.

g. After approximstely cne ainate. place tas LOAC/ INJECT switen at tne CMP. CFLE*J. in tne LOAD pcsition. Tns chlorica asan .i11 occur at approximately six ,inutes arter injsction.

Tnen turn crr tne cnart recorder on tne Cid.

OPLE4J.

Mll If tne cnlorice ceak is orf scala, repeat St=cs F.7.o thrcugn F.7.g - asi ng a l arger umho setti n 3

n. The cnlorice stancarc will se autonatically flusnso fre.n ene analyzer. Allow aaprox i natel y tan (IC) ninctes to campleta this cuerati n.

6. Regenerate anc flusn tne coluans in acccrcance aitn t.ne follo ing at tre L:19. .0PLE*J:

a. -Perfcre tne tclicaing linaua for flusning of tne resin colunns:

1) Jlace thJ SCJE switen or tnE LAP. 2PLilJ.

ccncuctisity x.eter to ZERC.

2) Place tne E-i saitcr an t r a C t' 3 CPLi-J.

in tne C?! (a;; ucsiticn.

N ._ M --awa- O 4 - --

/

LZP ,1330-!2 .

Revision :

Asril 2s, 19d2 7

3) Place One d-2 saitcr cn :na C.vP, CPLE4J, in the GFF (acan) ocsitian.

4) Pl ace na SEPA1ATCR switcr cn :n- Crv.

OPLE4J, in tre SED-i luc) pcsition.

5) sl ac e tr.e auPotESS0R 5 4 i ten on tn C:'c ,

CPLE*J, in tn SUP-1/<'J.%-2 (ac) pcsition.

t) Place the PunP swL ten on tne CMP, CPLE*J, in inc GN (ua) positicn.

c. Tnis lineup will provice fer scaiun carocaate flushing of ne separator colaan. Jperate for 15-20 cirutas. .tnen turn :ne d-1 switen to the water position (coan) anc flust for 10 minutes.

c. Place tne cu.T.o smiter, on tne CMP, CPLd4J in the CFF (ccon) pos i ti on.

c. Place ins SUPDRESSC4 switen in :na SLP-2/AGS-1 position. ,

e. Cepress the regeneraticn star outton. Tne s y s te.n t i me r mu s t os set to previce for a 15

.ninute sci c regeneraticn f oll owec O y 3 45 ninuta

.ater rinse. After cne hour tha system .ill snut off autcmatically ano :ne rea reacy lignt will os activatec.

9. Secure the system atter ccmpletion cf cclumn receneration in accorcance aitn tre fcilo.ing:

i

a. Turn the icn cnrcuatograpn PCaER switen cn_cne CMP, CPLE*J, Oc CFF.

n. Turn the AIR saiten an t r e - C .6 P . CPLE4J. t c u F .C .

c. Turn tre GUAGE switen en :n. cyp,-CPLE*J, to CFF.

10. Plot tne cnicrice coliuracicn curve in acccroanci airn tne f ol l c a ing:

3. Feasure tne neign; at eacn osan for its resa.ctivv stancarJi C.1 cba, J.2 p p:n , 0.5 por anc 1.G por cnicrice.

s-_

1 T

• L 2 P- l'3 3 C-2 2 '

Revisicn::

aaril 2t, 19d2

?,

c. Cn a sheet of linaar graph oaper, plct-tna pe6x neignt, in units, cn the vertical axis and tn=

chlorice concentrations, i n paa,.or. tne norizontal axis. Re for *o Attacanert A.

1-

c. Craw tne oest fit straigne line tnrco.jn One data acints.

11 Attach tne strip cnart from the ica cnrcnaccgrapn tc One cnicrice calicration curve ano fer.ard tc Rad / Chem Supervision far rasien.

G. _C~6.CKLISTS a

1. Ncne.

} H. TECeNIC S SPEgFird TIOb. R E ERENCES 4

$ 1. None.

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. . LIP-1330-22

-* Revision 2

• - April 26, 1982 10 (Final) d ATTACHMEllT 3 VALVE LISTING RC-V-1.1 Reactor Recirc Loop B Cutout Valve RC-V-1.2 RT Demin inlet Cutout Valve RQ-V-1 3 RHR Heat Exchanger A Cutout Valve RC-V-1.4 RHR Heat Exchanger B Cutout Valve RC-V-1.5 RT Demin Outlet Cutout Valve V-2 lon Chromatograph to Waste V-5 lon Chromatograph Sample Source Selection Valve V-6 02Analyzer Sample Source Selection Valve V-7 02Analyzer Selection Valve V-8 0 Analyzer Discharge Valve 2

V-9 02 Calibration Solution Cutout Valve V-10 Instrument Air Cutout Valve V-Il Demineralized Vater Cutout Valve V-12 Nitrogen Supply Cutout Valve V-13 lon Chromatograph Manual injection Valve V-15 Cal-3 Isolation valve V-19 Cal-3 Drain Valve V-29 Nitrogen Supply to Cal-3 i

l 1

r

< , , - - - - ,,- w y w q-m --

-O e, LZP-1330-23 Revision 1 -

Acril Zo, 1962 1

CETtRMINATICh C5 REACTCR CCJLA.NT or, C Cf.C UC T I V I T Y ANC DISSCLVEC CXYGEN CCNCENTRATICN AT THE PIGH RAJIATION SAGLING Sr$ TEA f

A. Pua0CSE ine purpose cf this procecure is tc celineate tne steos recuirea to cetermine reactor cociant pm, concuctivit/,

ano cissolvec oxygen concentration at une eign Raciation Samtling Systen (MRSS) curing normal anc pcst-acticent coerating ccncicions.

d. PECEDENCES

1. Sentry Ecuipment Corporation, Post-Accicent Sample System, volume 1.

2. Stancarc Metnces fer tne Examination cf water and aaste-ater, 1*tn Ecition, 1975, pp. 446-*47.

3. LZ3 133C-29, " Sampling at the High Raciation Sa.noling Syster (Valve Operation at tne HRSS Valve Centrol Panel)."

C. Pljo E ;t> I S I T E S ,

1. verify tnat ni trogen, acaroximatel y 6C psig. is availaole at tne Cne:ai ca l Anal y s i s Panel (CAP),

-)P L E 1J .

2. verify tnat nitrogen, aaproximately ICC asig. is availaole at tne Liquid S a.ap l i ng P anel (L5P), uPLCou.

3. Tre operator sncula ce familiar .itn tne caeration of tne HRSS panels.

4 Estaolisn ccmmunications .itn ne Unit Nuclear 5tation Operator (NSO).

5. The sample iTust nave C&en octainec in aCCCrdancL witn Reference 3 cricr.to scrforming tnis pracecare.

i

e. Ensure tne curfer sol uti on tanks are apprca i.natel y +

Ir-fall af tne recuirec oufrers.

! 7. Verify the oxygen calioration tann is fillac .itn j aemineraliLec a3ter.

i w,

LZP-1333-23 Revision 1 .

April 26, 19e2 2

3. Buffer. pm *, (CAL-1).

o. Buffer, pH 7 (CAL-2).

D. P32CAUTIO?,5

1. A 3egulatory Guice 1.3 cr 14 release of fissicn

rocucts i rag l i e s e x t r e.ae l y rign levels cr racicactivity. 2cse rates Jay ou nign encugn to orevent-entry into many areas of the plant tnat are normally hacitable. Rac/Cnem Supervisicn sncula De ccr.tactec pricr to entry into any area wnen sucn a release of rission creducts is suspectec.

2. asar raciation cosimstry as reccamarcec of Mac/Cne.a Supervision.

3. wear protective clotning onc respiratcry protection as recommencec by Gac/Cnam Supervision.

4.- Accropriate survay instruments snculo os availacle for monitoring curing this precedure.

E. LIMITATICNS ANC ACTirms

1. Notify Rac/Cnea Suoervision if any prcolens are anccunterec at the HRSS sanels.

2. Tnis procedure. tncugn intenced fcr use under ost-accicent conditions. can ce usac for sar;1ing at ene HRSS panel s curing normal operations. curing which the precautions ma/ nave linitec applications.

Honever. normal roatins samoling precauticas snualJ ce oos6rved.

3.- Calioration operations must ce perfertec arier to ficwing reacter coolant to ene CAD. 07LElJ.

4 when cperating at a ni;n oxygen les l. the 4eancro analyzer aill acnieve an equilitrium value in apcroximately fiftsen (15) ainutes. Arter caliuration of tne prcoe in a Jissolvac oxygan concentr3 tion cf

~

souroximataly.s ocm. tne orcoe .ill ca<e aoprcxitately two nours tc rocaver to oxygen levels ir tne Ivo

po ranga. Mcweser ne Rexacro is nct cesignsc fcr use in a post-as.iseat concition.

5. anen tilling tna cissolvec oxy,en racirculaticq nans. .rair.tain a aiscanca of enres incnes autawun

e .

+ .

LZP-1330-23 Ravision l -

l -pre 1 23, 19c2 3

the final .ater l esel anc the rec i rcul .iti ca spro f nozzle.

c. A reci rcul aticn time cf ona ncur is ce:uirac tc schieve ccmplete air s3:uration or the racirculation tar < water.

7 ab reacings are to De ta<an 001y after t3rminatiLn af f l o . a n.1 stacilizatic, or tot meter ras;out.

c. Tna ox fgen anal yzers sncal a os cal icratec aesal /

.ren in use anc wnen ene analyzer is suspectse ta ce out or caliaraticn.

9. Tne um instrunent snaule ca st ancarcizac at lasst j cnce par cay wnen in use. anc ansn tne i n s t r u.r a n t I is suspectec to os out of calioracicn. I i

10. Tna cocauctivity instrument shoulc ce calioratec at least once par quarter and when the i r. s t r u.ne nt is suspectea c ce cut of cal i b rat i on. .

11. If the Rexncrc analyzer nas cesn in a stutdcan condition for a perioc longer tnan tuc (2) .eens, in9 prote snoul o ce corici tioned av fic4ing csmi nerali zec water tnrcusa the flo. esseaal v for a minimuir. of tnirty (30) minutes prior to caliaraticn.

12. Tre pH anc conductivity .nonitcrs anc cisscivsc oxfgen ansiyzer rust ce energizec for a ;crica of 3^ minutes prior to calicration cr anal fses caing performes.

F. PRCCEOLPE 3EI5 cr ncun naT.es associates i ce - ne val ves aperatec in tnis procecure, refer to Attachment C.

1. At ene Cnemical >onitoring Panel (c.vP). : Pus-a.

verify tne INJECT /LCAC s.iten for uns Icn Cnreaatograyn is in the LCAC position to permit f i nal 's y s te.T flusning.

..- 2. At tnc Licuic Sampling Pansi (LSP). OPLCdJ. verify in 3 fcilowing valve lineas:

e mm -

l E

/

LZP-1330-23

, kevision 1 4aril 2s, 1952 -

a. PC-V-1 1 (closec).

D. PC-V-l.2 (closec).

c. 2. C - V - 1. 3 (closec).

c. FC-V-1.4 (cl o ssc ) .

e. )C-V-l.3 (closec).

f. Verify RC-V-6 is closca. Connect cne fluan

~'

-water hose to RC-D-1 ano ocen tne rluse noter line valve.

t

-[ g. RC-V-5.1 (closec).

n. RC-V-5.2 (closec).

8 RC-v-2 (clossa).

j. RC-V-16 (closec).

< . c.C -V - d .1 (cl osec) .-

1. RC-v-3.2 (closecf.

m. RC-CV-1 -(SYPASS).

n. . AC-V-9 ( C L";S EC ) .

o. RC-V-2C-(closec).

o. RC-V-21 (cicsec).

4 RC-V-ll (CLCSEd).

r. G. C -V- i d -(6 o'ciccx).

s .1 PC-V-lo (5YPsS3).

t. RC-V-22. (Tl CHEM PANEL).

u. RC-V-17. ~ (closea). --

v. RC-V (caen). l

, l-

' ~

r' emum

,, - ,- +-,-r- . , , -c,_

+.

d LZP-1330-23 kevisicn 1 April Zo. 1982 5

. RC-v-3 (open).

3. A: ne CAF. JPLEld. Verify Ene follC'.ing v31ve lineup:

s. V-10 (opon).

3. V-11 (cpen).

c. v-12 (ocen).

c. V-e (coen).

c. V-2 (coen).

t. V-27 (vent).

g. V-23 (vent).

n. v-29 (vent).

i. v-lo (closecs.

j. V-Zo ( cl osec ) .

k. V-5 (CLCSED).

1. v-9 (cicsec).

c. V-17 (closec).

n. V-24 (closec).

a.- V-e ( C X YG El4 CALI3 SCLUTION).

p. v-33 (TC CAL-1, (pw-* ouffer tank)).

a. Connect :ne flasn osser nose tc J-3 anc cgen tne flusr ater lino salve.

-.cr post-accicen; sampling, align valve V-7 on ne Cao. CaLE1J. to :ne fSI 0xyGEN ANALY2ER pcsitiqr.

Fcr normal saxol iny, al i jn valve V-7 to tra 4EANdRS JxYGEr. AN ALYZER scs i tior..

5. Start-uc tne pm aster at ne. Cnomical iacni:crint, Parel ( C.d P ) . CPL 24J. . in acccrcance witn -r4 f o l l o . i n c,. :

$ m:

LZP-133C-23 Revision 1 ,

April 26, 1932 e

o. Placc tne internal S-1 toggle sai cn tc the CN position.

6. Start-up tne conductivite monitor at t n e C '10 , OPL5*a, in accorcance witn ene rollo ing:

3. Ocserve tnat ne .nster reading is cn znrc nen tne sel ec tor switcn is on Zdad. It so, vroce=c to stcp F.o.c. If tnis is not tre case, aisconnect tne oco er caule ano recracx tne necnanical zero .ith acwer off. If necessary, use a small scrcadriver to acjust tne meter's necnanical zero tnraugn tne center nele in tront of'tha panel.

c. Reconnect tne po.er cacle anc caserve tn=

mecnanical z=ro. The meter sncula gcint to zero. If tne point r is not on zero, cararully acjust internal triamer P3e to orir.g cne pointer to zero.

c. Tarn tre selector saiten.to CHECK. Tne weter incicator scould 7.ove to CHECA on tne n.ete r scale. If the meter does not CHECK properly, it is cut of calioraticn. inrorm Rad /Cnem Supervision.

c. Swi ten the sel ector sn i ten to PE ASLRE. T.ie n.on i t o r is nc. resay fcr operaticn.

7. For post-accicent sampling, start-up tne YSI dissclvec oxygen analyzer in accorcance nitn Step F.d. For sanipl ing curi ng normal ocerations, start up tra Rexnoro dissolvec oxygen analyzer at tne CMP. Opus-a.

in accordance .ith tne (cllowing:

a. Cneck that the sc er soitch is in :ne CFF pcsition.

c. Use a s.nal l scra driv $r to adjust tne .recnon i c al zaro through r.ne plac< screa on tne weter race.

c. Place the po.er sai cn in tna CN pcsition.

^

c. Turn ene function salact saiten to tne Z ER G cositico.

J-s

w g -

r s

u4P-i330-23 Rsvision 1 A)rtl 209 190d 7

e. Use a small screacriver ta turn :ne ZE;5 ACJ f or a zero reacin; on the instrunent.

f. Turn :ne .:L?!C T I ON saiten tc ne "dC Tg/l" positicn.

3. For post-acciccnt sanpling, start-up tne YSI ciisclvec oxygen analyzer st Sne CMP. OPLE-Je in accurconch 4i n tre fcilesing:

a. Turn tre PCiER saitcn to JN.

3 Turn the 0, F I L T E S. 3 itch to JF;.

c. Turn ene 0 2 U;G suitcn to ;-20 ppm.

c. Turn the PEN Ib,PUT tc ZERO.

e. Turn the CHART SPEEO to RAPIC.

f. Acjust the PEh ZERO control until tne pen trac =s a l ine on ene 0-20 cnart scale at C.

g. Turn the CHAFT SPEED to 10.

n. Turn the 36N INPUT to C .

9. If the calicration of tne 0 analyzer tc ce usea has osen perform.ea for tne 2weex, prccesc to Stap F.lC. If the calioration has not osen perfer.Tec, recirculate tre cissol<ec O, calicration tank in acccroance witn tne follo ihg at the CAP, GPLEid:

a. Coserve tne level in the oxygen calibratior, tar. < C A L-4 It water must oe accec to tre tans, open V-24 ano fill ne tank enen close V-24

o. Caen rully 1-17.

c. Turn :ne recirculation pump CN. Incicatcr lignts for n e p u.r.a sncule l i .;n t en corn ra CAF. OPLElJ. Snd CMP, CPLE4J.

c. Recirculate c water for a cerica of cne (;)

nour. l 1

I

3. Cortinue to recirculata until toe' actual calicration is perfarc.ec. anen tne actual

\

ee l

l

-. . i

. I LZP-1330-23 Revision 1 April 20, 1962 d

calioration is performec, reac and recccc nne temperature of the water in CAL-4 cn LRC Form 1097A (Attacnment A).

f. Cetermine One dissolvec cxygen ccacentratica f rc:n Attachment 6 ana recora it cn LRC Fctm 1097A (Attacnnent ).

10. If the ps instrument has oenn standarcizec for tae cay, crcceec to Step F.li.. it tne pn instrument nas not ceen stancarcized for the caf. crccesc in acccrcance with sne fciloaing at tne CAF, GPLElu, or as otneraise directec:

a. Align V-30 to pr calioraticn tanx CAL-1, an -

ouffer tank.

o. Align V-o to ph CALId SCLJTICN.

c. Align V-27 to tne nitrogen supply line.

d. Adjust V-23 until sufficient flow is inaicatea of the red floa incicator lignt. Alloa to flush for a minimum of two (2) minutes.

e. Turn V-e ccur.tercicc<.i ig to UXYGEN CALIS SOLUTICN to terminate fica and align V-27 to i

the vent Josition.

f. Acjust the ob meter reading to indicate a pn cufter value of 4.0 cy turning standarcize cortrol R-3, on tne pH meter at tne C'iP, CPLE*J.

g. Caserve the pn monitor reacing fcr too (2) minutes anc acjust if crift exceeds : C.1 an units.

. n. Align v-e ts OcMIN a ATER and flusn fcr a ra i n i mu.a of too (2) ainutes.

i. Cicss v-25.

j. Align V-3C to pH catioration tann CAL-2, n 7 Dufter tanx.

k. Align V-2d tc the nitrCgen supply line.

r,+,-

LZP-1330-23 Aavision 1 -

April Zo. 1982 9

1. Align V-6 to pH CALI3 SOLUTICN anc acjust v-le until tne red fics indicatcr i s li t. All w to flusn ror a minimum of t.0 (2) n i n'u te s .

m. Turn V-o econ-ercicck ise to tre UAYG5.1 C-Lfc l

> SOLUTIC1 to terminate rica anc align v ce to vent ocsition.

n. Coserve tne pH reacing anc recccc cn L40 Fcrm IC97A (Attacnment A). Tre pr raacing sncula ce within 0.5 pH onics of ne currer salua of 7.0. If tne value is nct 0.5 ce units, repeat Stecs F.lc.a enrougn F.10.m.

o. Align V-6 to OEMI4 aATER and f l u sn f cr a mi n i mu.n of two (2) minutes.

p. Close 9-lo.

11. If the oxygen anal yzer to ce usec nas oeen calioratec for tne week, proceec to step F.12. If it nas not seen calibratec, prccess in acccrcance .ith eno following at tne CAP, JPLElJ, or as otnermise cirectec:

a. Coen V-9.

3. Align V-c to OXYGEN CALIB SCLOTICc4.

c. Coserve tnat recirculation pump is ON.

c. Cicse V-17 urtil-200 ml/nin fica rate is incicatec by tne rad fl o. incicator. Allow to flust for a minir.um et five (5) mirutss.

c. while flusning, acjust the O cal icrati on <nco en tne YSI monitor or tne cab 20J cn :na <e4nor moni Or, at tns CSP, CPLE=J. Oc incicate tne dissolvec cxygen concentraticn in ppm previousiy determinec in Step F.9.f.

f. Turn tre recirculati on puma CFF.

g. Cicse V-9.

n. Align v-e to LIguIO SAMPLE.

12. o urge One LSP. CPLJ8J. anc CAP. JPLE1Je in accorcance oitn tne folic.ing:

~=

1 1

o . 1 LZP-1330-23 Revisicn 1 Acril 2o, 19c2 10

a. At tne CAP. GPLElJ. verif f V-6 is alignec to LILU10 SAMPLE.

o. At the LSP, GPLD8J, open RC-V-l.1 (-1.2, -1.3,

- 1 4, or -1.5) ceaencing on :nu sanale scarce.

c. At the LSP, CPL 0es, caen PC-VREL-1 until .4 C -

FI-l incicates 35-42 incnes of nacer. Jurge for a minimum of rive (5) minutes. Sicaly cicse RC-1REL-1 until RC-FI-l incicates 12-15 incnes of ater. Continue tne ourge for a minimur of one (1) ainute.

3 Clcse RC-V-3 on tne LSP, CPLC3J.

e. Goen RC-V-2 on :ne u5Pe CPL 0dJ.

f. At the LSP, OPL0dJ. acjust RC-VREL-2 until RC-FI-2 incicates 18-22 inches of water.

g. Varify trat tne flon rate at the CAP, CPLElJ, is 200 ml/ win cy ooserving :ne rea flow inoicatcr is lit. Acjust RC-VAEL-2 on the LSP, CPL 08Je if necessary to cotain proper fica rate.

n. At CFP. CPLE4J, turn YSI CHART SPEED tc RAPIC anc verify PEN INPUT is set to 0 if the YSI monitor is to De usec for the anblysis.

13. To perferr tne samole anal fses, proceed in accoraance wi:n tne folic ing:

, a. Purge tne CAPE GPLElJe fCr a minimum of ritteen (15) minutes. During purging. procesc tc Stes F.l3.n.

o. Cetermine tne cisscIvec cxygen ccncentration at the CMPe CPLE*J. in~accorcance witn the tollowing as appropriate:

1) If tne Aexnorc cissc1vec cxygen .neter is ceing usac, caserve the meter reacing anc turn tc a loner scal 3 ocsi tion as :ne meter reacing cecreases. Alle to purge fcr fifteen (15) mirutes. :nen recorc the aissolvec oxygen reading cn LRC Fcrr 1097A (Attacnment A).

Nhd

t

/

/

L2P-1330-23 Revision 1 April 2o, 1982 il

2) If tne YS1 CissclVec oxygen meter is ceing usec, flusn for five (5) *inutes or until the YSI trace is linear.

c. Coserve anc recorJ :ne ccncoctisitf mater reading anc tno temperature of tne sample stream trcm tre CPP, CDLi-J. Recorc c0 LRC Form IC97A

'(Attachment A).

c. At the CAP, CPL 51), turn /-d ccuntercloc<~ise to OXYG2h Call 3 SOLJIICN OC terminate fic..

e. After terminating floa, cermi the cF reaaing to stacilize for a mini num of tac (2) minutss.

Recorc tne on reading en LRC Fcra 1097A (Attachment A).

14 Flusn the CAP, CPLElJ. anc LSP, OPLC8J. in accorcance

! with the folic.ing:

a. At tne CAP, CPLE1J, align V o to LIJu1C SAMPLE.

o. At the Valve Control Panel, CPLC9J. secure the saxpling lineup in acccrcance witn Reference ,

3 Step F.1.0.c) tnrougn ~.1 0.7). I

c. At the.LSP, CPLO8J. Cicss RC-V-1 1 (-l.2, '.3,

-1,4, -1.5).

c. At ene LSP. OPLDEJ, caen 4C-v-6

e. Ac ne LSP. CPLO6J. adjust RC-VREL-2 until kt-FI-2 incicates 18-22 inches of nacer. Flusn itn cemineralizec water for a minimum of tnroe (3) minutes.

r. .At tne LSP, CPLD8J. cicse.RC-V-7.

g. At tne LSP, CPLUSJ, osen RC-V-3.

n. At the LSD, CPLC8), acjust RC-V4 E L- 1 ur,t i l RC-FI-l incicates 35-43 inches of .ater. Clasn aita cemineralizec water for a .ni n i mu.a o r one (1) minute.

i. At the LSP, CPL 3eJ. cicss RC-V-3.

J. At the LSP, CPLO6Je caen RC-V-l.1 (-1.2, -1 3,

-1.4, -1.5) aepencing On ne sample scurce

~-. .

L2P-1330-23 Revisicn 1 ~

April 2o, 19c2 12 sanulec, anc flusn with camineralizac .ater for a mininum of fise (5) minates.

k. At the LSP, OPLOeJ, close AC-1-l.1 (-l.2, -1.J.

- 1 4, -1.5).

1. At .e LSP, CPLC8J, open AC-V-8.1 anc RC-V-d.2.

m. At tne LSD, CPLD8J, adjust RC-V REL-2 unt i l 4C-FI-2 indicates 18-22 inches of nater. Flusa

-itn cemineralizec water fer a minimum of enree (3) minutes.

n. At the CAJ, CPLElJe tarn V-b CC CAYdEN CAbid SCLUTICa.

o. At the CAP, CPLE1J, turn V-5 tc LICJI] SAMPLE anc flusn itn cemi neral izac water ter a minimum of tnree (3) minutes.

p. At the CAA, CPLElJ, turn V-5 to CLGSE).

Q. At the CAP, CPLdlJ. clcse tne flush water valve anc disconnect the flusn ater nose tram 0-3.

r. Secure flusning cy closing the fcilo ing at the LSP, OPLC8J:

1) RC-v-8.2.

2) xC-v-8.1.

3) RC-V-2.

• ) RC-V-4

s. At the LSD, CPLD6J, clcSe tne fl usr water valve ana cisccnnect the flasn aater ncss tron RC-CV-1.

15. Secure the sarole system in accercance witn the following at tne C:4P, CPLd,J cr as etneraise cirectec:

i a. Cn tne or monitor, turn s.itta 5-1 tc :ne LFF position.

c. Cn tne concuctivity moritor, turn ene function select s iten ta -ne ZERC positicn.

% des =5

L Z P- l '. 3 0-2 3 -

Revision 1 Aprii Zo. 19d4 13

c. If tne Rexnora a.cnitor aas usec, turn tne f uncticn select s.v i ten tc tne 26R0 pcsition.

c. If :ne (SI conitcr was usec, ccecx tra :no YSI po er switen is in the OFF ocsition anc remove One chart ascer, mar < :ne crart pager aith cate. cias, enart speec, C rang , anc samale ocin:.

e. Secure tre system lineup in accorcance ni:n Reference 3. Steps F.1.c.8 :nrcugn F.L.r.

O lo. Ifg tne sample or temperature exceecs 20-3C C. as to 25 C in accercance oitn the fcilo ing:

pF = aH +

0 03 (T - 25) f where: pF = OH correcrec to 25 C.

7 ab t = pr frca Step F.13.e.

. T g

= temperature ( C) from Step F.13.c.

Recorc the results en LRC Fcre 1097A (Attacnment A).

c

17. Correct tne measurec concuctivity tc 25 c in accordance oitn tne f olicwing f ormul a:

Cg = Cy - 0.013+(5.8E-5 x T 2)

-1 + C.013 ( T 1 - 25E ) ~

.nere: Cg = Concuctisit/ correctec tc 25 C.

rrom steg F.'3.c.

C2 = Concuctivit/

T = Te.rperature C rrom Stes F.i3.c.

Decora tne results on CRC Fcre 1097A (Attachment A).

13. Recorc tne ci sscl vsc ox ygen ~ cencentr atica orr t r.e YSI chart aaoer on LAC Forn LC97A (Attacnment a; os appropriate. t 10 Foraarc all paper ork 3nc cnart recorcings to iaJ/ Cram suaervision for resien.

6

.m

8 LLP-133C-23 Revision 1 April Zo, 1982 1-G. CHECALISTS

1. Ncne.

M. T se,4N I t a t SPECIFICATION R E C E 4 :',C E S

1. 3/4.4.4 i

t

LZP 1330-23

• Re@sion I (i Q'- Apfli 26, 1982 ATTACllMENT A 15 1.aSalle County Station

.i

• IIRSS Analyses Date:

l I

pli, LZp 1310-23 Conductivity.LZP 1330-23 n_insolved oxvnen.tZp 1310-23 Standardization Init/ Time: Sample Init/ Time: Calibration Init/ Time:

Calibration Check Init/ Time: Recirc. Water Teinperature, C:

Satiiple Temperature, C:

Measu red Conduc t ivit y..umlio/cm: Recirc. Water 0 Conc.,mg/1:

I Hensured pII: (pil-7) 2 7.0 Correct the measured conductivity to 8"*I' I " I"IENI""

Buf fer pli Value:

Check SAT /UtiSAT,I O .I pil units: 25 C using the following formula: Sampic D.o., mg/l:  ;

Sample Inft/ Time:

Sample Temperature, o:C C =C2-{0.018t(5.8E-5xTgh 3

Heasured pil: 1 + 0.018 (Tg - 25 C) Off-Gas LZP 1330 27 Vacuum, RC-C-2.1., Step F.1.d.fs.

If the sample pit temperature exceeds Where: Cg = Cogductivity corrected to pressure, RC-G-2.1. . Step F.2. 0 20-30 C, correct the pit to 25 C in 25 C .

pressure, RC-C-2.1., Step F.2.y.

accordance with the following:

C2 = Hensured Conductivity pur = plii 4 0.03 (Ti - 25) Sample init/ Time:

Tg = Sample Temperature, C Where: plira pII corrected to 25"C Comments:

plig = measured pli Tg : Saeple Temperature, "C

. l Reviewed:

ph at 25"C: Conductivity at 25"C, umho/cm:

1,RC FORM 1097A

W LZP-1330-23 Revision 1 Acr!! 26, 1982

r. - c. 3g ATTACHMENT B SOLUBILITY OF OXYGEN IN WATER EXPOSED TO WATER-SATURATED AIR DISSOLVED OXYGEN TEMPgRATURE DISSOLVED OXYGEN TEMPjRATURE C mg/l C mg/l 0 14.6 1 14.2 26 8.2 2 13.8 27 8.1 7.9 3 13.5 28 4 13.1 29 7.8 5 12.8 30 7.6 6 12.5 31 75 7 12.2 32 7.4 8 11.9 33 7.3 9 11.6 34 7.2 10 11 3 35 7.1 11 11.1 36 70 12 10.8 37 6.9 13 10.6 38 6.8 14 10.4 39 6.7 15 10.2 40 6.6 16 10.0 41 6.5 17 9.7 42 6.4 18 9.5 43 63 19 9.4 44 6.2 20 92 45 6.1 21 9.0 46 6.0 22 8.8 47 5.9 23 8.7 48 5.8 24 8.5 49 5.7 25 8.4 50 5.6 7

i un s 4 -

-e

, LZP 1330-23

,.., Rsvi si on ;

,, ,. Aoril ?A, 1982 ATTACHMENT C 17 (FinaO VALVE LISTING RC-V-1.1 Reactor Rectre Loop B Sample Cutout Valve RC-V-1.2 RT Demin inlet Sample Cutout Valve RC-V-1.3 RHR Loop A Sample Cutout Valve RC-V-1.4 RHR Loop B Sample Cutout Valve RC-V-1.5 RT Domin Outlet sample Cutout Valve RC-V-2 Sample Source isolation Valve RC-V-3 Sample Purge Cutout Valve RC-V-4 Flushing Water Isolation Valve RC-V-5.1 Pressurized Sample inlet isolati on Valve RC-V-5.2 Pressurized Sample Outlet isolation valve RC-V-7 Diluted Sample Bypass Valve RC-V-8.1 RC-$F-1.2 Inlet isolation valve RC-V-8.2 RCSF-1.2 Outlet isolation Valve RC-V-9 RC-EV-1 Isolation Valve RC-V-10 RC-EV-1 Evacuation Cutout Valve RC-V-11 Cf f-Gas 4-way Valve RC-V-12 Argon to Air Ejector Cutout Valve RC-V-13 Off gas Vial Evacuation Cutout Valve RC-V-14 Argon Supply to Off gas Vial Cutcut Valve RC-V-15 Off gas Sample to Gas Chromatograph Isolation Valve RC-V-16 RC-SF-l.2 Argon Purge Cutout Valve RC-V 17 Reactor Coolant Grab Sample Cutout Valve RC-V-18 Reactor Coolant Undiluted Sanple Backflush Cutcut Valve RC-V-19 Reactor Coolant Undiluted Sample injection Valve RC-V-20 RC-C-1 Fill Valve RC-V-21 RC-C-1 Isolation Valve RC-V-22 Liquid Sample to CAP isolation Valve RC-DV-1 Reactor Coolant Diluted Sample injection Valve RC-DV-2 Off gas Sample injection Valve RC-VREL-1 Reactor Coolant Purge Throttle Valve RC-VREL-1 Reactor Ccolant Sample Throttle Valve.

V-1 Off gas Sample to Gas Chromatograph ,

V-2 ton Chromatograph to Vatte.

V-5 lon Chromatograph Sample Source Selection i V-6 0, Analyzer Sample Source Selection V-7 0~ Analyzer Selection.

V-8 0 Analyzer Discharge Valve V-9 0 Calibration Solution Cutout V-10 I strument Air Cutout V-11 Domineralized Vater Cutout Valve V-12 Nitrogen Supply Cutout Valve V-14 Argon Supply Cutout Valve V-15 Cal-3 Isolation valve V-16 Cal-2 Isolatico Valve

- V-17 0 Calibration Solution Tank Recirc Valve V-18 0 Calibration Solution Tank Drain Valve V-19 C 1-3 Drain Valve V-20 Cal-2 Drain Valve V-24 Demin Water Fill to 02 Cal. Soln. Tk. ,

V-25 Cal-1 Drain valve V-26 Cal-1 Isolation Valve V-27 . Ni trogen Supply to Cal-1 V-28 Nitrogen Supply to Cal-2 ,

- V-29 Nitrogen Supply to Cal-3

- V-30 Cal-1 Cal-2 Selection Valve

, s e me , l,)

4-- [ ,.

j

/

l

- LZP-1330-26 Revision 2 May 7, 1982 1

i SAMPLING OF CCNTAINMEAT AIR AT THE HIGH RADIATION SAMPLING SfSTEM A. PilR PO S E The purpose of this orocedure is to celineate a metnod of oo*.aining a containment air sample at the Hign naciation Samoling System (dRSS) suppi oinent i ng ne conta inme nt monitors curing normal ano Jost-accident conoitions.

C. REFERENCES

1. Sentry Equipment Corporation, Post-Accicent Sample Systen. Volume L.

2. LZP 1330-29, " Sampling at tne Hign Raciation Sen.oling System (Valve Operation at tne HASS Valve Control Panel)." -

3. LLP 1330-31. "HRSS Samole Movement."

4 AAIS-CCP-0002,," General Radionuclice Analysis of a Gas Sample."

5. AAIS-CCP-00C3, " Particulate Radionuclide Analysis."

o. AAIS-CCP-C004, "Iooine Radionucliae Analysis."

/

7. Action Iten Recora (AIR), L-81-494 e ,8. Hewlett Packard Program Instructions, "I-131 Equivalent Concentration."

9. GSEP Environmental Osrector Emergency Plan Impl eme nti n g Precedure EO-16. " Quick Estimate or Of f si te Dose l* From Unplanned Release: Liquia and Gaseous."

10. Calcul ations of Distance Fag;grs for Power and T+st Reac121 lil2s, Cnemical Information uocument, Oisision

~~

of Licensing ano Regulations, wasnington. 0.C.. 23

• arch 62. TIO 14a*4, Taole III.

'C. PR34E0utSITE1

1. Verify tnac nitrogen pressure, approxi.nately LCC psig, is availaole at tne Containment Air Centrol w  ; Panel (CCP), CPLE2J.. Verify snat argon pressure.-

.y f

5

a .

LZP-1330-2e Revision 2

.ay 7, 1982 2

approximately 90 psig, is availaole tc tne sample partitioner panel.

2. Verify tnat tne CCP printer po er is C4 anc tne arinter is set to the proper date and time.

3. Set the CCP FUNCTION SELECT to tne SF1-SF3/GGO position and ooserve ene follosing at the CCd,

PLE2J

a. The POWER UN light turns on.

o. Annunciator winccas glow steady in:

R04 COL 1 1 1 2 1 3 2 2

c. Tne flow monitor 204 and 10C% flow lignes turn en for approximately 25 seconos after power is first applied.

E9If There is no flow Ot this time.

d. The 20 minute Grass Gamma Detector (GGO) timer is energized.

!!915 There is no GGD inclucea in this system, however, the steps were incluced to clarify tne timer sequencing.

6 Press tne annunciator RESET pusnoutton to turn cr f all lighted annunciator wincows.

~

5. ' press the system RESET outton.

6. press ene exercise RE5ET outten.

A^:9

7. press tne exercise START outton.

1,*g

= --

• 7

LZP-1330-26 Revision 2 May 7, 19d2 3

8. Depress tne exercise STOP outton.

1911 The exercise STOP outton snould remain in, anc gica reo.

9. Verity all air ano solencia valve selector saitenes on One CCP, OPLE2Je are positionec to CLOSE.

10. Press the PILCT LIGHT TEST pusnoutton on tne CCP, CPLE2J. anc ouserve all pilot lignts are functional.

11. Press the annunc'iator TEST outton on tne CCP, CPLE2J,  !

anc verify tne following:

a. Horn sounds.

D. Annunciator winaces flasn on and off in:

ROW COL 1 1 1 2 .

1 3 2 2

c. Annunciator winocw in Rod 2. CCL 1 lignes up and remains l ightea.

d. Annunciator winacw in ROW 2, COL 3 is off.

This position has no operator function.

12. Melease the annunciator TEST pusnbutton. Verity l tnat tne annunciator win'acw in row 2 CGL'1 turns off anc remains ofr.

13. . Press the annunciator ACAN0aLEDGE pusnoutton en ne l CCP, OPLE2J. Verify tne following:

a. Horn turns off.

c. All flasning winacws enange to a steady glow.

29If If cesirac, ausn :ne T5ST pusnoutton to retest RO.

2. CCL 1 lanps. mCa 2, CCL 1 lamos remain ligntac

~. .

LZP-1330-26 Revision 2 May 7. 19o2 4

as long as the TEST pusnoutton is pressed. The otner wincows will raintain a steacy gicw.

14. Press the annunciator kESET pusnoutton en the LCP. I OPLE2J. Verify tnat all annunciator .inacas return

• o tne normal (off) concition.

15. At the Containment Air $dmaling Ponel (CASP). CPLC9Je l verify tne following:

a. The green INACTIVE pilot lignt is on.

o. All four green SAMPLE FLASA IfdACT IVE pilot lignts are on.

16. Octain tne sample in accorcanca witn Reference 2 I prior to performing tnis procedure.

17. Equipment: I

a. Partioner sampling assemoly.

D. PRECAUTIONS L. A Regulatory Guice 1.3 or 1.4 release of fission procucts implies extremely nign levels of racioactivity. Oose rates may ce nign encugn to prevent entry into many areas of tne plant tnat are normally nanitaole. Rac/Cnem Supervision snoulo oe contactec prior to entry into any area anen sucn a release of fission products is suspectec.

2. dear radiation cosimetry as reccomenced oy Rac/Cnem Supervision.

I

3. aear protective clotning and respiratcry protection as recommenced oy Rac/Cnem Supervision.

• . Appropriate survey instruments snould oe availaule fcr monitoring auring tnis procedure.

5. A lod NEGATIVE CAeINET P4 ESSURE ALARM. at tne l Containment Air Con *rol Panel OPLE2J. implies a antantial for airborne activity leaking into tne "RSS roon. Investigate anc correct une proolem imieciately to precluce contamination of tne area.

4

%6-W e

4 LZP-A33C-2e Revision 2 May 7, 1982 5

E. [fMITATIONS AND ACTIONS

1. The exercise stoo pusnoutton, when pusned, will stoc  !

outomatic sequencing and cisable tne start pusnoutton.

2. If any proolems are encounterea at tne FRSS panels, l contact Rad /Cnem Supervision.

3. Inis procedure, enough intencea for use uncer oost- l accident conditions, can be used for saa.pling at tne HRSS panel s during normal operations, during which the precautions listea may have limited acplications. However, normal routine samaling precautions snoulo ce ooservec.

F. D40C90VRE U.915 For noun names associated with tne valves operateo in tnis procecure, refer to Attachment A.

1. Install the sample stack on the partitioner in accoraance witn the following:

a. Install tne neecie on a sample cartriage.

o. Install tne cartridge on top of tne carcitioner.

A slight taisting force is required to seat tne cartridge.

c. Install ine plexiglass cover over tne cartriage assemoly so tnat the neeole orotruces tnrougn tne small hole in top.

d. Install vial ano seotum in vial nolaer, tnen place tne vial assemoly on top of tne cartriage stacn.

2. At tne CCP. OPLE2J, adjust tne nitrogen oressure regulator PC-1 until tne pressure gauge reaas 100 psig.

3. Adjust tne operator pressure regulator en :ne samole partitioner to S0 psig.

• . At tne CCP, OPLE2J, to sackflusn tne samole lines.

OPEil SV-5 enen OPEN Sv-1:. Allow to flusn for 2 minutes.

u.-

L4P-1330-26 Revision 2 May 7. 1982 o

5. After completion of the sample line oackflusn, to purge the sample OPEN AV-2, AV-1, and SV-1.2.

6. At the partitioner controller, place tne toggle switch on the back of tne controller in the UP pos i ti on.

7. Set the rotary switen on tne front cf sne partitioner controller to INITIATE SAMPLE CYCLE.

8. Prass tne POWER Oh switen on ene partitionar controller. The switen snoulo glo. red.

9. Verify tne HEATER ON switen on :ne partitioner controller is in tne O's oosition, glows rec.

10. Select the cesirec numoer of sample injections on the partitioner controller thumowheel. In a post accident concition, it will normally ce sel ectea to "1". This may De changea as directed oy Rac/Cnem Supervision.

11. Press tne INITIATE SAMPLE CYCLE pushoutton to start sampling. The following actions snoula new occur automatically:

a. Rotary smi ten moves to EVAC.

b. After 15-2C seconas, tne rotary switcn nill advance to VAC CK.

c. If the system'is leak-tight, the pressure will not increase more tnan 0 3 psi. If tne pressure rises aoove the lower level setpoint (approximately 1.2 osi), the sampler nill not advance oeynno tne VAC CK position. To clear  !

tne macnine, cer form tne following secuence: i i

1) Turn main pc er off; j i

2) Manually resat the front panel rotary I I

switcn to S A.'iP L E INITIATE CYCLE oy rotating J pr, doc y g . The saiten the swi'.cn cojn shoulo rotate easil y. '

i-

3) Disassemole the stac< ano replace the {

cartridae, needl e, and sectum on gas vial.

~

Ine neecle snould not oe damagea or it may tear the sectum,' caus ing a l aan.

+ + - ,

3

~. , ,

LZP-133C-2o Revision 2 May 7, 1962 ,

7

12. The rotary switen will tnen cycle tnrougn 3 more EVAC and AR FILL cycles to properl y flusn tne saaple assembly.

2Gli The following, Steo F.13., must ce accomplisnec immeciatelv . hen tne rotary switen has aovancea to 5x LUAD. .

I

13. anen the rotary switch advances to tne SX LOAD I l

position, i mmec i atel y CL0SE SV-5. Tne samale time  !

is to ce ceterminea wnen tne sample stacx on tne cartitioner pops uo. i

14. when tne sampling sequence has been completec, tne rotary switch will advance to tne INITIATE SAMPLE CYCLE position. Flush tne samole lines in accordance with tne f ollowing at tne CCP, GPLE2J:

f

a. CLOSE AV-2, and eacxflusn tne sample lines ror 3 minutes.

l

o. CLCSE SV-1.2 anc AV-1, tnen CPEN SV-5, ano l flush tne samole lines for 3 minutes. l

c. CLOSE SV-5, tnen OPEN AV-2, anc flush tne sample line for 3 minutes.

c. CLCSE SV-LO anc As-2.

15. Set the CCP FUNCTION SELECT switen to GFF.

lo. Depress tne POWER ON pusnoutton on the partitioner controller and verity tne light goes out. i

17. Upon completion of tne sacoling operations, secure tne sampling li,neup in accorcance witn deference 2.

Steps F.4.o.6) tnrougn F.*.c.

15. To remove the partionea sample, proceed in accorcanca 4itn tne follo.ing:

a. Remove the vial ano nousing from tre partitioner.

Log tne following information (as aopropriate) for entry into tne A.A.I.S.:

%+-

m._____ . _ - _ _ - _ . _ _ _ . _ _

o - ..

r

/

/

L4P-1330-2e Revision 2

.May 7, 1982 e

1) System samplea and unit.

2) Sample locetion.

3) Sample time on.

4) Samole time off (tnis time aill oe tne same as time on).

5) Sample cate on.

6) Sample cata of f (tnis case will te tne same as cate on),

7) Reactor po er, .reganatts tneraal.

8) Reactor power, megawatts electric.

4) Initials.

o. Remove the protective hous'ing trom the noole gas vial and cetermine tne raci ation level or tne sample. If raciation levels warrant, pl ace tne vial in a leac snielc for transporting to the analytical area.

c. Demove the protective housing from tne particulate anc iodine cartriages.

d. Remove neecl e .f ro.n the sampler unit. ~

e. Remove the particulate and iocine cartricges.

f. Transport tne samples to tne sample preparation area in accorcance witn Reference 3.

g. Separate the particulate filter anc iocine cartricge utilizing a knife to cut tne connectors.

Cut rel ati vel y closa to One top anc nottom of tne samples in order to set tn ein riat in seconcary containers.

n. Place tne silver zeolite iocine cartriace inlet sida cown into its pl astic sample hoicer.

i. Place tne particulate filter inlet sice ua in a plastic petri cisn.

l iL

l

~. , . ,

LZP-133C-2o Revision 2 May 7. 1962 9

J. Wrap tne sample containers in plastic wrao or seal in plastic bag.

k. Label the samples in accordance witn :ne following:

1) System samplea anc unit.

2) Sample location.

3) Sample time.

4) Sample cate.

5) Sample voluxa.

6) Survey results.

7) Initials.

1. Preoare tne post-accident sample partitionar for further samoling in accoraance witn Stsos F.1.a. througn F.1.e.

19. Perform tne radioactive analysis ror eacn sample in- l accordance with Referenca *. 5,oor o. as appropriate.

20. Determine tne I-131 equivalent concentration using l th Hewlett Packarc Calculator program in accorcance with Reference 8.

21. If the hewlett Packarc calculator or calculator l program "I-131 Equivalent Concentration" is not availaola, calculate tne I-131 equivalent concentration of tne containment air samole in accorcance witn Attacnment a.

22. Calcul ate -the iocine, particulate, and noble gases l curie content in-the primary containment in accorcance witn-the follo-ing:

B911 Calculations snoulu os performeo on sne isotopic analysis naro copy printar output.

a. Calculate tne total I-L31 equivalent curie content of - tne pr i mar y containment in accorcance

- with ena following:

> _ %d

- s e. e LZP-1330-2o Revision 2 May 7. 19d2 10 C = G G d H Ssci (IE06 uCi/Ci) hhere: C = Total I-131 equivalent curie content in ene primary containmer.t.

S= I-131 equivalent concentration -

uCi/cc. in ene sample from 5teo F.7. or F.8.

1.1E10 cc = Primary containment free air volume.

c. Sum ne particulate racicnuclice concentrations, uCi/cc, from tne isotopic analysis in Step F.7.

c. Calculata tne :otal particulate curie content of the primary containment in accoraance with the following:

C = m i,1 d g ogcl (1E0o uCi/Ci) wnere C = Total particulate curie content of tne primary containment.

S = Particulate racionuclice concentration, uCi/cc, in tne samole from Step F.10.o.

1.1E10 cc = Primary containment free air volume,

d. Sum the noole gas radionuclioe concentrations, uti/cc. from tne i sotopic anal ysi s in Step F.7.

a._ Calculate tne total noole gas curie content of tne primary containment ;n accorcance oit, ne following:

C M u r. M S S G.1 (lE06 uCi/Ci)

_anere: C = Total _noole gas carie content of the primary containment.

}-

i

LZP-1330-2e Revision 2 May 7, 1982

• 11 5 = Noole gases racionucliae concentration, uCi/cc, in tr.e sanole from Step F.10.o.

L.lE10 cc = Primary containment free air volume.

23.' Report tne sample results to the Rac/Cnem Director l

'for evaluation in accorcance witn Reference 9.

24 Route all output cata and calculations to 4aa/ Chem ,

I

'Suoervision for review.

G. (HJ Q,g STS

1. None.

H. TECHNICAL S P EC ISCJ_T IONJgggg,5

1. Ncne.

- CL. -

L '.

4, .. ,. .

' - ', LZP 1330-26

- Revi ',,. 4

. - May 7, 1082 17 ATTACHMENT A VALVE LISilNG AV-1 Sample Flask #1 Inlar' SV-1.2 Sample Flask #1 Outlet SV 2.1

• Sample Flask #2 Inlet SV-2.2

• Sample Flask #2 Outlet SV-3.1* Sample Flask /3 Inlet SV-3.2

• Sample Flask /3 Outlet SV-4.1* Sample Flask /4 Inlet 1

SV-4.24 Sareple Flask 14 Outlet SV-5 Sample Purge

. AV-2 CASP Outlet SV-10 Nitrogen inlet

• NOTE: SV 2.1 through 4.2 are no longer used in this procedure. ,

t i

I i

i r

I

k. _ _ _ . ._. _

.eev

~ = - - - - - - ----

LZP 1-330-26

't . - ' * . Revision 2 May 7, 1082 t3 a

M

• ~"~"

Decernisati:n of I-131 equivalent concentra:1cn of the centainmen:

at: grab san:ple in the event that cenpute: 4:alysis is soc available. .

Datermina the I-135 concentration in the cen9 d--en:

1.

air grab sampla f cs Step ?.7c air

2. Decernise the I-135 cencentracies in the ces:ain=en:

at T , che c1== ac which the release was =ade to ha ecucid-="t, using the folleving equation:

A I-135 concentra:1ca (uC1/cc) sc I, = ,.g

• ihere:

. A - I-135 ccacentracies (uci/ce) f:c=

p:ccedure Scap ?.7 .

e = 2.713 "I

A= 1.724 I-03 d decay cc=::.

t = Sa=pla decay c1=e (sin.) -

reacco shu:dewn to sample time ( A T)

3. ceterni=e the concancratics of I-131, I-132, I-133 a=d I-13f. usi:g che follevi=g rela:1:sships: . - - .

I-131 Cencentra=1cn (uci/ce) - I-135 c=ncentracion x 1.cI-01 I-132 Concentracien (uci/ce) = I-135 Ccucentratice x 9.232-01 I-133 Concentracten (uci/ce) = I-135 c==centrati:n x 6.352-01 f

I-134 Ccucancratien (uC1/ce) = I-135 c:ncent:s:1cn x 1.346 i

4. Determine :he I-13I equivalene ecu' cent: 2:1:n of all icdi=a c==cen::::1:=s in the containment al us1=g :he fo11cv1=g equation:

.ccal I-131 Iquivales: - I-131 cencen::a:1:n + (1-132 Concentration)(0.036) l Ceccentratien (uci/cc)

+ (1-133 Concentratten)(0.027) + (1-134 Concen tra t t en) (0.017) l 1 I _

+ (1-135 Concentration)(0.084)

}'

-.sy'd by%