ML20045G213

Requests Approval to Use Calgon CL-4000 in Raw Water Sys on Temporary Basis Under Permit Application Outfall 001

ML20045G213
Person / Time
Site:	Mcguire, McGuire
Issue date:	07/01/1993
From:	Atherton N DUKE POWER CO.
To:	Sullins C NORTH CAROLINA, STATE OF
References
NUDOCS 9307130053
Download: ML20045G213 (8)

Text

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ll l Duke h>wer Company Generation Services Department 13.09 llagers ibrry 1&>ad fluntersvdle, NC28078 7929 i DUKEPOWER 5 v July 1,1993 l

Ms. Coleen Sullins Pr mats and Engineering Unit fi;rth Carolina Department of Environment, Ilealth and Natural Resources Division of Environmental Management P.O. Box 27687 Raleigh , North Carolina 27611-7687 -

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Subject:

McGuire Nuclear Station NPDES Permit No. NC0024392 Request for Approval to Use Dispersant File: MC-702.13

Certified : P 384 361034

Dear Ms. Sullins:

McGuire Nuclear Station would like to request approval to use a dispersant called Calgon CL-4000. This chemical product will be used in one of our raw water systems on a temporary basis as a part of a study. The use of dispersant in our systems has already been addressed in our permit application under Outfall 001. Also, in a letter to you dated July 9,1992, McGuire was allowed the use of this dispersant in a similar request .

Approximately 312 pounds of this dispersant will be injected daily down stream of a nuclear service water pump in order to inhibit silt deposition in one train of the RN system. Effluent from the system will be diluted by approximately 2,500 MGD of once *

• through cooling water prior to discharge at the permitted outfall.

We roquest approval to begin using this dispersant on or near September 20, 1993, ar- . ;i'l October 31, 1993. Please find enclosed an MSLS sheet for this product.

We e.c neciate your consideration of this request. Should you have questiens or need uiditional information, please contact Norma Atherton at (704) 875-5963.

Sincerely,

~/ht)wt.. >'Y h &

Norma G. Atherton, Scientist Environmental Division Water Protection l

88 9307130053 93070t -

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Mr. Randy Kepler, NCDEliNR,' Raleigh, NC Mr. Mike Parker, NCDEIINR, Mooresville, NC I

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cc: UlS. NUCLEAR REGULATORY COMMISSION DOCUMENT CONTROL DESK WASIIINGTON, D.C. 20555 U.S. NUCLEAR REGULATORY COMMISSION  !

101 MARIETTA STREET, NW, SUITE 2900 ATLANTA, GEORGIA 30329 U.S. NUCLEAR REGULATORY COMMISSION 0FFICE OF NUCLEAR REACTOR REGULATION WASIIINGTON, D.C. 20555 MR. Kim Van Doorn NRC Resident Inspector McGuire Nuclear Station 12700 llagers Ferry Road 11untersville, N.C. 28078 O

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SENT DYi 07-01-93 03:24PM 4127778643a 704 875 5038 M2 MATERIAL SAFETY DATA SHEET ,,,, y,,,,,,,,,,,,,

653401 12 87 340 PnoouCT N AME CL4000 C.A. .L. .G. . .O. . .N SUB510lART OF WiGCE & Co..thC.

1 SECTION 1 .

MANUFACTURE A'S N AMC EMfRGENCY Calgon Corporation TELEPHONE NO. (412) 7,7,8000 AconEss P.O. Box 1346, Pittsburgh, PA 16230 C "^

A YN NY Partial (v Neutralized PolvacrYlle Acid Rnintinn IURMU'^

gg we SECTION H HAZARDOUS INGREDIENTS, '

PRINCIPAL HAZARDOUS COMPONENT (S) CAS # TLV lunits)

' BY WElGHT ORAL. LDs e DEFtMAL Loi.

Cnemical ACGlH OSHA OTHER Name This product would not be regarded ..

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common y.m. to contain any husrdous ingrediert i Ia*m7"' accordh>g to OSHA Huerd Communication

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ti m. Standard (29 CFR 1910.1200).

[ hem v.m.ical Comenon Nome ChemlC 41 Name GWn N.m.

chemic.i y em. ,

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SECTION IH PHYSICAL DATA l

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DOILING PolN T (' FI

> 212 SPECIFIC GR AVITY tMs O*1) i , .,, j 7 . $ ,3 9 t

VAPOR PHF$5URF (mmHg i PE ACCNT VOLATILE

.___ - Similar to Water BY VOLUME (M 70 EW--

v APon otN3:TY ( AIR-il Similar to Water oH 2.8 3.2 SOLUBILITY IN WATtit Complete l OTHER APPE An ANct AND OnOn Clest pale yellow liquid N/A = Not appGc.sbie ~ ~ ~ ~ ~~-~ ~

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Mile this enform.s tion anct rwmenw,*.'.,~ ~* rw s.  :. --- u.. .

m y gyt 07-01-93 03:24PM 4127778643-t 704 875 5038 H3 SECTION IV FtRE AND EXPLOSION HAZARD DATA .

FLASH PolNT IMethod used'.

Not Flammable: Aqueous Solution i EXTINGUISHING MEOt A

.. s Product h not flammable or combustible.

5 SPECI AL FIRE FIGHTING

' PQOCEDURES Exercise caution when fightin2 any chemical fire. A self-contained breathing appatetus and protective clothing are essential.

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, UNUSUAL FiftE AND

EMPLOSLON H AZARD$ \

, None i

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1@s d f*hWE: AtTH HAZARD DATA . . . . . . - . . .

EFFECT OF OVEREXPOSURE A. OCUTE .

t. INGESTION The product is expected to be proctically non-toxic through Ingestion.

The oral LD60 is > 5.0 g/kg (ret).

2. INHALATION No appilcable information was found concerning inhalation hatards due to polyscrylic acid.

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3. OCnMAL EXPOSURE  !

e Toxic

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The product la expected to be practically non toxic through dermal absorption. The dermal LOGO valus la > 20 g/kg (rabbit).

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n. ia mit ATion The product, when tested on rabbits. showed no signs of skin irritation.

It is not expected that contset with this product would cause skin l<ritation.

• *S' ^*N No doeurnented cases of skin sensititetion have been reported  !

as a result of using the product. I I

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SENT~BY1- 07-01-93 03:25Pi1 41277786434 704 875 5038 N4 e, EYE 1RRITATION lDstillatIon of the Product in rebbit eyes produced Irltle end es njunctival irritation which cleared by Day 3. The eye scores on Day 1 ranged from 6-17/110 (unwadied) and from 2 8/110 (weshed), No corneal effects were observed in either the washed or unwashed eyes, However, on the basis of thue date, this product would not be considered a primary eye irritant according to the 05HA Standard,

6. $UDCH M ONIC, CH R ONIC, O TH E R No applicable infurmation was found concerning adverse potential heatth effects result!nD from subchronic and chronic exposure to the product.

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FIRST AfD A, EYE in case of contact,immedletely flush eyes with plenty of water for et least 16 minutes. If irritation develops, seek medical aid,

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R SKIN Not Applicable C. INGESTION Not Applicable l

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I D. INH AL A TION Not Applicable IMP 4340 11/17/87 l

5t.tu EtYt 07-01-93 03:2SPM 41277786434 704 875 5038 tl 5 i

SECTION VI REAb'lVITY DATA STABLE X iT Attt LIT V CONDITIONS MThag -

TO Avolo Unknown

NCOMPATAOILITY .

{Mateneh to A.64) Strong beleg and OAidllers i

i ll2AHOOU3 UECOMPOSITION _

nooucis -

Ostdes of nitrogen and carbon

SECTION V E 'aa 'saa aaaceaba=$ '~

'EPORT ABLE QU ANTITIE L IHQ)

N Los OF EPA H A/AHOOUS UBST ANCES IN FHOOUCT t- NOTIF Y EPA OF PRODUCT SPILLS EQUAL TO On EXCEEDING 7 _ _ _ . .

N/A

_ L B S.

i 3 (nes To BC' 7AmLN IN C ASE

,," ' Di4 pole 01 in ACCQrdenCe With loCaI, Itat8 and f 6 der $l f eQulallons. Oike areE to Cont 8ln os rnuch spilled material es possible. Remove any remaining material by absorbing on vermiculite or other suitable absorbing meterial and place in a sealed container for dispoial, Hosa spill area well unce product can make floors slippery,

, AstE Di$POSAL METHOD Dispose of in e landfill or Incinarete in accordance with local, stete end federal regulations.

SECTION Vill HANDLING / STORAGE '

10TECTivt CL ovts EYC PAOTECTION As a good Iridustrial hygiene practice.

Not Required chemical splash goggles should be used.

IHCH PHOTECTiV'E pOTHING Not Required ESPIA ATOHY PnOTECTION Not Required

'N TIL ATION LOC A L F X H AUST OTHEA **

Not Re3uired ___

M t' C H AN R A L Normel *~'"

Not Required QR AGE t. H ANOl.lNC Nome quked__ '

Keep container closed when not in use,

%sh thoroughly of ter handling 4

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Nons JJ/A = Not Annhe.M.

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