ML20039D451
| ML20039D451 | |
| Person / Time | |
|---|---|
| Site: | Beaver Valley |
| Issue date: | 12/01/1981 |
| From: | STONE & WEBSTER ENGINEERING CORP. |
| To: | |
| Shared Package | |
| ML20039D444 | List: |
| References | |
| RTR-NUREG-0737, RTR-NUREG-737, TASK-3.D.3.4, TASK-TM NUDOCS 8201040104 | |
| Download: ML20039D451 (111) | |
Text
{{#Wiki_filter:_ _ _ _ - _ _ _ I f L 1 I CONTROL ROOM HABITABILITY STUDY BEAVER VALLEY POWER STATION UNITS NOS. 1 AND 2 Prepared for DUQUESNE LIGHT COMPANY Pittsburgh, Pennsylvania I December 1, 1981 I I I I Stone & Webster Engineering Corporation Boston, Massachusetts B I 8201040104 811228 I PDR ADOCK 05000334 P PDR
{ !I TABLE OF CONTENTS Section Title Page 1 INTRODUCTION . . . . . . . . . . . . . . . . . . . . I 2 POTENTIAL SOURCES OF T0XIC CHEMICALS . . . . . . . . . 2 3 DETERMINATION OF CHEMICAL T0XICITY . . . . . . . . . . 5 4 CONTROL ROOM HABITABILITY DETERMINATION . . . . . . . 4 5 ONSITE CHEMICALS . . . . . . . . . . . . . . . . . . 6 i 6 0FFSITE CHEMICALS . . . . . . . . . . . . . . . . . . 7 7 CONCLUSIONS . . . . . . . . . . . . . . . . . . . 11 REFERENCES . . . . . . . . . . . ... . . . . . . . 12 Appendix Title A CONRAIL HAZARDOUS MATERIALS N0DE REPORT FOR
! MIDLAND, PENNSYLVANIA i
j B DOMESTIC COMMODITY MOVEMENTS AT MILE 35 j (OHIO RIVER) i il I C STONE & WEBSTER " VAPOR" MODEL
! D DEMONSTRATION OF CHEMICAL CONCENTRATION AND 1 PROBABILITY CALCULATION PROCEDURES 'I i,l k
i 'I 1 i j
)
i II
I I. <1S1 er 1AstsS i Table No. Title Onsite Toxic Chemicals I 1 2 Stationary Offsite Toxic Chemicals Within 5-Miles of the BVPS Control Room Intake 3 Predicted Toxic Vapor Concentrations in the Control Room 4 Conrail Track Tengths and Wind Direction rrequencies 5 Aggrega.e Probability of Toxic Chemical Spill Transpr,rted by Conrail 6 Aggrerate Probability of Toxic Chemical Spill I Traastierted by Barge i I I I I I I I l.
E' LIST OF FIGURES Figure No. Title ! D-1 Amw aium Hydroxide: Source - Onsite i 1 ( D-2 Toluene Source - Arco Polymers, Inc. 1 l D-3 Sulfuric Acid: Source - Bruce Mansfield D-4 Chlorine: Source - Conrail : D-5 Naptha: Source - Barge I
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I I lI !I , 11 l lI : 's
I i 1. INTRODUCTION Compliance with Criterion 19 of Appendix A to 10CFR50 requires a control room from which a nuclear power plant can be safely operated or shut down under design basis accident conditions. In this regard, Section III.' .3.4 of NUREG-0737 requires licensees to assure the protection of the cont.ol room operators from the effects of accidental toxic chemical releases (maintain control room habitability). This is accomplished by demonstrating I compliance with the criteria outlined in Nuclear Regulatory Commission (NRC) Regulatory Guides 1.78 (Rev. 0) and 1.95 (Rev. 1) and Standard Review Plan (NUREG-0800) Sections 2.2.1 (Rev. 2), 2.2.2 (Rev. 2), 2.2.3 (Rev. 2), and 6.4 (Rev. 2). Since the Beaver Valley Power Station (BVPS) control room was constructed prior to the issuance of these aforementioned regulatory criteria (1974-1975),.: 1emonstration of compliance with such criteria is necessary. This demonstratian must include the results of an analysis which deternines control room concentrations of toxic vapors following a postulated accidental release occurring either on the site or anywhere I within five miles of the site boundary. This report provides a description and results of such an evaluation performed for the BVPS control rooms for Units 1 and 2. This evaluation involves the calculation of a toxic vapor concentration time history inside the control room for each potential source within five miles of the site. This calculation takes into account the plant layout, control room characteristics, type and location of potential toxic hazards, and design basis meteorology. The resulting toxic vapor concentrations calcu-I lated inside the control room are then compared with the most recent human toxicological data tc assess the potential for operator incapacitation. For those chemicals which could potentially cause a habitability problem, an analysis is performed to determine the aggregate probability of a toxic chemical spill resulting in radiological consequences in excess of 10CFR100 guidelines. The results, discussed in detail later in this report, indicate a probability less than that identified in NUREG-0800 Section 2.2.3 (Rev. 2) for a design basis event. E
- 2. POTENTIAL SOURCES OF T0XIC CHEMICALS
.According to Regulatory Guide 1.78 (Rev. 0), both onsite and offsite potential toxic gas hazards must be considered. Any toxic substance stored onsite in a quantity greater than 100 lb must be evaluated. Offsite sources include stationary facilities as well as transportation sources (truck, rail, and barge) within five miles of the site.
For the BVPS, potential sources of toxic chemical hazards include chemicals .I stored onsite, two stationary sources within five miles of the site, and three transportation sources. The nine toxic chemicals stored onsite, along with stored quantities and distances from the control room intake, are presented in Table 1. The quantities shown in this table are based on the size of the largest single storage container. The two stationary sources include toxic chemicals stored at the nearby Pennsylvania Power Company's Bruce Mansfield Station, located approximately two miles from the BVPS control room intake and Arco Polymers Inc., in Monaca, Pennsylvania, at a I distance of about 4.5 miles from the control room intake. The chemical types and quantities stored at these locations are given in Table 2. The three transportation sources of hazardous materials include the Conrail line which runs along the north shore of the Ohio River, barge traffic on the Ohio River, and truck traffic to and from the two stationary sources. The rail line and barge traffic pass within 650 m and 240 m of the control room air intake, respectively. Appendix A contains the hazardous materials node report for Midland, Pennsylvania, provided by Conrail, which lists the shipment frequency and quantity of all potencially toxic substances shipped by rai during the January 1973 through June 1979 periad. Appendix B E B contains the dome. tic commodity movements at mile 35 of the Ohio River for the calendar years 1977 and 1978, .long with the commodity classification codes. These periods are considered representative of the traffic to be expected in this area. The hazardous chemicals shipped by truck and stationary sources in the vicinity of the Beaver Valley site are determined from a comprehensive survey of industries in the are.. The total response to this survey indicates that only 2 truck routes pass within 5 miles of the site; along I
f Route 18 (2 miles from the control room intake) for shipments to and from Arco Polymers in Monaca and along Route 168 (365 m from the control room intake) for deliveries to the Bruce Mansfield Station. The route for ! shipments to the Bruce Mansfield Station was conservatively assumed to be the closest one to the Beaver Valley site. The chemicals shipped by truck ( are the same as those indicated in Table 2 with the exception of benzene from Arco which is only shipped by barge. l
- 3. DETERMINATION OF CIEMICAL T0XICITY Only those chemicals which have the potential to form a toxic vapor cloud or plume after release to the environment need to be evaluated. This criterion is met by all of the chemicals listed in Tables 1 and 2 with the exception of sodium hydroxide solution which does not form a toxic vapor cloud due to its very low vapor pressure. In addition, not all of the 341 hazardous ma-terials listed in the Conrail node report (Appendix A) fall into this category. Many of these materials are not toxic to humans, many are solids I which cannot emit a vapor, and still others are liquids with very low vapor pressures ahich evaporate at a negligible rate. As a result of these considerations, 119 of the 341 substances listed in Appendix A were evalu-ated for possible toxic effects on the control room operators. Similarly, only five of the commodities shipped by barge were determined to be toxic substances.
The criteria for determining chemical toxicity and setting limits for habitability determinations are derived from regulatory guidance. According to Regulatory Guide 1.78 (Rev. 0), the " toxicity limit" of a chemical is the I maximum concentration that can be tolerated by an average human for two minutes without physical incapacitation (severe coughing, eye burn, severe skin irritation). Standard Review Plan Section 6.4 (Rev. 2), states that acute effects should be reversible within a short period of time (several minutes) without benefit of medication other than the use of a self-contained breathing apparatus. The acute toxicity limits listed in Regulatory Guide 1.78 (Rev. 0), are used in this study wherever possible. Where not defined in Regulatory Guide 1.78, conservative toxicity limits I I
rI l f were set subjectively utilizing more recent available information from authoritative sources.(1-7) I Non guideline toxicity limits are based on the highest concentrations which produce no effects, or minor irritation not affecting mental alertness and physical coordination. In many cases, _ available toxicity information is not based on the 2 minute exposure time specified by Regulatory Guide 1.78, so extrapolation is necessary. Therefore, a fifteen minute exposure time was assumed to add another degree of conservatism to the analysis. This is I also the exposure time used by the American Conference of Governmental Industrial Hygienists (ACGIH) to determine the Short Term Exposure Limit (TLV-STEL). This concentration protects a worker from irritation, chronic or irreversible tissue change, or narcosis of sufficient degree to increase accident proneness, impair self-rescue, or materially reduce work efficiency. The STEL is used in the absence of other information. In cases where appropriate human data are not available, animal toxicological data are used by applying a conservative factor of ten to lower the acute exposure limit. If information is not available for a certain chemical, data for structurally I related chemicals within the same chemical family are used to set lit.cs. In the absence of any specific information, the more conservative workplace limits or Threshold Limit Valve (TLV) suggested by ACGIH are used. Toxicity limits appearing in Table 3 are taken from ACGIH unless noted otherwise. I 4. CONTROL ROOM HABITABILITY DETERMINATION I The effect of an accidental release of each of the chemicals described in the previous section on control room habitability is evaluated by calculat-I ing toxic vapor concentrations inside the control room as a function of time following the accident. This calculation is performed using conservative methodology outlined in NUREG-0570, " Toxic Vapor Concentrations in the Control Room Following a Postulated Accidental Release," and utilizing the assumptions described in Regulatory Guide 1.78 (Rev.0). In a postulated accident, the entire contents of the largest single storage container are released, resulting in a toxic vapor cloud and/or plume which is conservatively assumed to be transported by the wind directly toward the I 4
I I control room intake. In the case of the Conrail chemicals, the amount released is estimated as the quotient of the total tonnage shipped during
.the period and the number of carloads. The larger of the two most popular tank barge sizes (4,500 tons) used on the Ohio River, according to the Arm /
Corps of Engineers in Pittsburgh, was assumed as the amount released in an accident. The probable maximum truck load of 25 tons specified in Regulatory Guide 1.91 was assumed for the released quantity in this case. The forma-tion of the toxic cloud or plume is dependent on the chemical nature and I ambient environmental characteristics. The entire amount of a chemical stored as a gas is treated as a puff or cloud which has a finite volume determined from the quantity and density of the stored chemical. A toxic substance stored as a liquid with a boiling point below the ambient temperature forms an instantaneous puff due to flashing (rapid gas forma-tion) of some fraction of the stored quantity. The remaining liquid forms a puddle which quickly spreads into a thin layer on the ground, subsequently vaporizing and forming a ground-level vapor plume. A high boiling point liquid (above ambient temperature) forms a puddle which evaporates by forced I convection eith no flashing involved. A more detailed description of the methodology used is providet' in Appendix C. The calculations are performed by the Stone & Webster " VAPOR" model (see Appendix C) which requires input information on the chemical's physical properties, control room parameters, meteorology, distance from the spill to control room intake, quantity of chemical released, and toxicity limits. For the BVPS, Unit 2 control room parameters were used as input, including a ventilation rate of 0.094 m 3/sec (200 ft /3min), and a net free volume of 1,671 m3 (59,000 ft 3). This combination of ventilation rate and control I room volume produces the highest air exchange rate (.20 volumes / hour) and thus, the highest predicted control room concentrations in comparison with the Unit I air exchange rate of .16 volumes / hour (300 ft 3/ min + , 114,000 ft3) and the combined control room exchange rate of .17 volumes / hour (500 ft3 / min + 173,000 ft3 ). The most conservative meteoro-logical condition is assumed for the calculation, consisting of Pasquill Class G stability, coupled with a wind speed of 0.5 m/sec, and an ambient It is further assumed that the spill and control room temperature of 40 C. air intake elevations are at ground-level and that the puff or plume center-
.I
l I l l line directly impacts the intake. In all cases, the assumed input parameters result in the most conscrvative approach possible. A demonstra-
. tion of the calculational procedure, with computer program inputs and output for each of the various chemical sources, is provided in Appendix D.
I The results of the analysis are summarized in Table 3. This table indicates that 4 chemicals stored onsite, 1 chemical stored at the Bruce Mansfield I station, 6 chemicals located at Arco Polymers, 94 of the 119 toxic chemicals shipped by Conrail, and 5 chemicals shipped by barge have the potential to incapacitate the control room operators. In this context, a potential incapacitation is defined as a predicted toxic vapor concentration in the control room which exceeds the toxicity limit for more than two minutes. All of the Arco chemicals shipped by truck are predicted to have control room concentrations less than toxicity limits and less than those stored at Arco and therefore they are not included in Table 3. In addition, the chemical (ammonium hydroxide) stored at Bruce Mansfield that causes a I habitability problem is a potential problem in regard to truck shipments as well.
- 5. ONSITE CHEMICALS I
The four onsite chemicals determined to cause a potential control room habitability problem include ammonium hydroxide, carbon dioxide, chlorine, and hydrazine. There are several mitigating factors which preclude the liklihood of control room personnel incapacitation following a carbon I dioxide, hydrazine, or ammonium hydroxide release. Although the predicted CO 2 concentration in the control room exceeds the stated toxicity limit (54.8 g/m 3 ), this limit is based on a 10-minute ex-posure for a worker tc function without lapses in judgment. The next highest published limit is 91.3 g/m3 for a 30-minute exposure which causes intoxication. Therefore, the 67.4 g/m 3predicted concentration is not likely to impair operator judgment based on the conservative exposure times which apply to the available toxicity information in comparison with the I Regulatory Guide 1.78 2-minute exposure time. In addition, an Anunciator in the control room for the CO 2 tankpressure[evelswillprovidethe I
I I operators a warning of CO2 system abnormalities. The predicted hydrazine concentration (0.24 g/m 3
) is higher than the stated toxicity limit (0.12 g/m ). However, this limit is conservative for hydrazine because it 3
is based on 10-minute exposure data for methylhydrazine, a more toxic alkay1 derivative. Therefore, it is reasonable to assume that a control room operator can be exposed to a hydrazine concentration in excess of 0.24 g/m 3 for tne 2-minute exposure time specified in Regulatory Guide 1.78 without causing incapacitation. I The maximum ammonia concentration in the control room, predicted by the model, as a result of the evaporation of ammonia from an ammonium hydroxide spill, exceeds the toxic limit used in the analysis, assuming that the ammonia cloud moves directly at the control room air intake. However, it is highly unlikely that the ammonia cloud will reach the control room intake due to its extreme buoyancy (i.e. ammonia is lighter than air). This effect has not been accounted for in the model. Buoyancy evaluations indicate that for every 5 meters of horizontal travel, the ammonia cloud will rise I vertically 100 meters, assuming a horizontal wind speed of 0.5 m/sec. Therefore, since the storage location of the ammonium hydroxide is 61 meters from the control room intake, it is concluded that the ammonia cloud will be well above the level of the intake vent at that horizontal distance and will not affect control room personnel. I 6. OFFSITE CHEMICALS (PROBABILITY ANALYSIS) i The results for the Conrail data, barge data, truck data and offsite station-ary sources are significant only in terms of a probability assessment, since I the model assumes that a series of extremely unlikely events occurs in combination with one another. For example, the predicted control room concentrations presented for the Conrail chemicals assume that the entire contents of a rail car are instantly released at the closest point to the site under design basis meteorological conditions, with the wind blowing directly at the intake. The corresponding impacts for smaller spills, greater distances, or under other less conservative conditions will be significantly less. I E
I According to guidance presented in NUREG-0800, Standard Review Plan Section 2.2.3 (Rev. 2), and in Regulatory Guide 1.78 (Rev. 0), design modifications to warn control room personnel may not be required if all potential toxic chemical accidents and other external man-induced ever.cs do not occur frequently enough to be considered design basis events. This frequency of occurrence of exposures in excess of 10CFR100 guidelines is I identified in NUREG-0800 Section 2.2.3 as approximately 10 when combined with reasonable qualitative arguments. event per year, Therefore, if the aggregate probability of occurrence of all Conrail, barge, truck, and stationary offsite toxic chemical releases which could incapaci-tate control room personnel is less than 106 per year, monitoring equipment for these chemicals is not necessary since the aggregate probability of a toxic chemical release resulting in exposures in excess of 10CFR100 guide-lines is acceptably small. I In order to estimate the aggregate probability of operator incapacitation due to a Conrail or barge toxic chemical release, another computer program is used to sum the product of the various probability factors involved for those chemicals determined to cause a potential habitability problem. These factors include the shipment frequency of each chemical, the frequency of an event causing a spill, the length of track or river length in each 22.5 sector where they pass within five miles of the site, and the frequency of winds blowing into the appropriate sector. Truck shipments are not con-I sidered in the probability analysis since they pose no habitability problem. (The shipment of ammonium hydroxide by truck is not a problem due to its extreme buoyancy, as described in the previous section.) I The shipment frequency of each chemical transported by Conrail is obtained from the node report in Appendix A. These values are linearly normalized to represent an annual frequency, since data are presented for an 18-month per-iod. The frequency of barge shipments is estimated from the average yearly tonnage shipped by the large tank barges (vessel type 5) for the years 1977 I and 1978, assuming the smaller (1450 tons) of the preferred barge sizes on the Ohin River in order to arrive at a conservatively high frequency of shipment. The frequency of an event causing a spill is assumed to be I 8
i 'I 1.5 x 109 and 1.6 x 10~9 event per vehicle mile (frequencies presented in WASH-1238) for railroad and barge shipments, respectively. Track lengths I and river lengths for the appropriate sectors are developed from USGS 7.5 minute topographic maps of the site area and are presented in Table 4 along with the frequency of winds blowing into those sectors based on 1976-1977 onsite meteorological data collected at the 35 ft level. The wind I direction frequencies used in the analysis represent all wind speed and stability conditions which adds another degree of conservatism to the evaluation. A demonstration of this calculational procedure is also .I provided in Appendix D. The results of the probability analysis are given in Tables 5 and 6. The aggregate probability of the 94 potential chemicals shipped by Conrail causing the incapacitation of control room personnel is calculated to be I 4.2 x 10 -6 per year, while the probability for the 5 barge chemicals is 0.8 x 1G
-6 per year. This results in a total probability of 5.0 x 106 per year for all the transportation sources that have the potential to result in a spill causing a control room operator incapacitation.
I For the offsite stationary sources (Arco and Bruce Mansfield), an aggregate probability of operator incapacitation is calculated based on an accident event probability of 10 4 per year and wind direction frequency at the site. The 10~4 per year event probability is that suggested by the NRC for sta-tionary storage facilities. The wind direction frequency is obtained from I three years (1976-1978) of onsite meteorological data and is determined for that wind direction range from each source which causes the toxic vapor plume to impact the control room intake. I This range of wind direction is based on the distance of the source from the intake and an assumed G-stabil-ity plume width of 12 standard deviations which encompasses 95 percent of the plume. These wind direction frequencies are determined to be approxi-mately 0.020 for Arco Polymers and 0.016 for Bruce Mansfield. This results in an incapacitation probability of 2 x 106 per year for each of the Arco Polymers chemicals and 1.6 x 106 per year for the Bruce Mansfield chemicals. I The aggregate probability for these sources is then calculated by multi-plying the individual probabilities by the number of chemicals determined to I I 9
I cause a problem. In the case of Bruce Mansfield, one chemical is shown to exceed toxic limits (ammonium hydroxide). Since this chemical was shown to be of no concern from the onsite source due to buoyancy effects, there is no need to consider it in the offsite probability analysis. Therefore, the Bruce Mansfield chemicals do not contribute to the offsite probability. Table 3 shows that the predicted concentratinns of the six chemicals stored I at Arco Polymers exceed the stated toxicity limits. However, only one chemical, toluene, should be considered a potential problem for control room operators. The toxicity limits for the remaining five chemicals (styrene, etbv1 benzene, benzene, butadiene, and pentane) are overly conservative and can be exceeded by the margins predicted without causing harm or incapacitation to the control room operators. The toxicity limits used in the analysis are based on industrial hygiene and other toxicological data that came closest to meeting the regulatory guidance. The toxicity limits based on a two-minute exposure criterion would be higher than the more conservative limits used in I this analysis, although we do not have the information to set them precisely. In addition, it should be noted that the upper limit of the stored quantity range provided by Arco (Table 2) is used in the analysis which further supports the elimination of these chemicals from the probability determination. I Therefore, the aggregate probability for the Arco chemicals is based on one problem chemical (toluene) resulting in a value of 2 x 10~ per year. I Therefore, the sum of the probabilities calculated for the four offsite sources is then 7.0 x 10 I events per year. Discussions with NRC staff (Mr. Ken Murphy) revealed that a conservative factor of 10 could be applied to this value to identify the number of operator incapacitation events that in itself would result in exposures in excess of 10CFR100 guidelines. Therefore, the probability of a toxic chemical spill resulting in unacceptable , exposures is correspondingly 7.0 x 10~7, which is less than the 10~6 event per year design basis probability objective. I
- I I
a 10 E [
I I 7. CONCLUSIONS Based on the results of the control room habitability evaluation and proba-bility analysis, it is concluded that only 1 chemical stored onsite (chlorine) needs to be monitored for at the control room intake in order to protect the operators from possible incapacitating effects of toxic chemical spills. The aggregate probability of an offsite source of toxic chemicals resulting in exposures in excess of 10CFR100 guidelines in the event of an accidental spill is less than the design basis probability of 10~6 event per year I identified in NUREG-0800, Section 2.2.3. I I I I . I , I I I u 1
l I I REFERENCES
- 1. U.S. Atomic Energy Commission, Regulatory Guide 1.78, " Assumptions for F aluating the Habitability of a Nuclear Power Plant Control Room During a Postulated Hazardous Chemical Release" (1974).
- 2. Patty, F. A. (ed.), " Industrial Hygiene and Toxicology," Vol. I and II.
Interscience Publishers, New York, 1958, 1963, and 1978. I 3. Occupational Health Services, Cambridge, Massachusetts - Consultant.
- 4. " Registry of Toxic Effects of Chemical Substances," National Institute for Occupational Safety and Health (NIOSH), 1978.
I 5. Sax, N. E., " Dangerous Properties of Industrial Materials," 3rd Edition, Van Nostrand Reinhold, New York, 1968.
- 6. Criteria Review for Vapor Phase Hydrocarbons. EPA 600/8-80-045.
I
- 7. The International Technical Information Institute, " Toxic and Hazardous Industrial Chemicals Safety Manuai for Handling and Disposal with Toxicity and Hazard Data, 'fekyo, Japan, 1979.
I I I I I 1 e I 12
I TABLE 1 ONSITE T0XIC CHEMICALS Distance from Intake Chemical Name Stored Quantity (m) Ammonium Hydroxide 415 gal 61 (29% Solution)
- Nitrogen 45,000 ft3 30
. Carbon Dioxide 2-10 ton tanks 38 Hydrogen 21,000 ft 3 91 l Chlorine 8-1 ton vessels 152 Hydrazine 10-55 gal drums 61 (35% Solution)
' I Morpholine 10-55 gal drums 130 Sulfuric Acid 325 gal 130 Sodium Hydroxide 10,000 gal 130 (50% Solution)
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TABLE ' ~~ I Sj ATIONARY OFFSITE T0XIC' CHEMICALS WITHIN 5 MILES 0F TIIE BVPS CONTROL ROOM INTAKE i Distance to Chemical Name Stored Quantity Intake (s) lI r Arco Polymers, Inc. f Styrene 50,000-250,000 tons _ 7,320 Ethylbenzene 50,000-250,0U0 tons 7,320 Toluene 500-5,000 teos ' 7,320 Benzene 5,000-25,000 tons ' 7,320 Butadiene 5,000-25,000 tons 7,320 Pentane 25,000 tons 7,320 ; Penn. Power Company (Bruce Mansfield) Sulfuric Acid 20,000 gal - 3,050 Sodium Hydroxide 20,000 gai 3,~ 05 0 I (50% Solution) Ammonium Hydroxide 10,000 gal 3,05/i _
~
(29% Solution) . - Dimethylamine Gas 125 ft3 3,050 , I
~
Hydrazine 1,500 gal 3,050 e (35% Solution) '- Morpholine 175 gal 3,050
~
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~
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+
t j 0 .. _,' 1 - p - / i TABLE 3 i , PREDICTED T0XIC VAPOR CONCENTRATIONS ii Q3 e '- -,.,
"2
,IN THE CONTROL ROOM i~
*,e
~ , -
p - _ Maximum Concentration Toxicity Limit
- 1
/, ,: Chemical (g/m3 )
- (g/m 3)
,i . , i Onsite Stored Chemicals ** } ~ l Ammonium Hydro: ide / 6.61 0.03 ! , p Nitrogen 1.6 274.2 L Carbon Dioxide 67.4 54.82 j - Hydrogen .s 0.09 19.62 , j_ ', ,. Chloririe - 1.5 0.045 ! Hyd razine 0.24 0.122 i
' >Morpholine 0.1 0.1 l.
y 463furic Acid
~
8.3 x 10
-5 0.0012 Arco Stored Chemicals **
l Styrene 9.3 5.62 j2 Ethylbenze'ae 5.6 4.42 l '
~ Toluene ,- 5.2 0.82 l Benzene , 10.3 9.72 I Butadiene 2.9 2.8 Pent'a ne -
28.4 14.92 l l Bruce Mansfield Stored Chemicais** i l Sulfuric Acid -5 2.5 x 10 0.0012 j , Ammonium Hydroxid.e 0.25 0.03 Dimethylamine -4 , 1 9 x 10 0.042 1 ( Hydrazine 7.2 x 10 0.122 l j Morpholine 2.4 x 10 0.1 L Conrail Transported Chemicals 1 [' Chlorine 6.1 0.045 lE !3
^==oata 3o o o3 Hydrogen Chloride 4.9 0.022 l Snifur Dioxide 7.4 0.01
! Carben Dioy.ide 9.5 54.82 i e Dichlorodifluoromethane 10.4 10.52 ) Monochlorodifluoromethane 8.0 10.5' Dimethylamine 4.6 0.042 i - Monomethylamine 3.4 0.022 Trimethplamine l [ 4.1 0.052 1 ) -
@itane 6.9 12.12
- jg
~
^ Butadiene 6.4 2.8
,E i , I '
~
- h. .-
, -- 1 of 4 s-2 3
. . - - - . - . . . . . _ _ _ _ _ _ _ . _ . ~ . _ . . _ . . _ _ . _ _ _ , . . _ _ . - - . . . . - . . - . . - . - - - - . _ , ~ . . - . - _ . - . . --
TABLE 3 (Cont)
- g. Conrai t- Transported Maximum Concentration Toxicity Limit *
-Chemicals (Continued) (g/m 3) (g/m3 ) I i
Butene 6.5 9.32 lI- -Dimethyl Ether Ethylene Inobutylene 3.8 4.4 47.03 271.2 6.3 9.22 Methyl Chloride 5.6 0.3
.I Propane . 2.0 43.12 Vinyl Chloride 7.2 2.61 Methv1 Bsmide 2.6 0.06
'7 Hydrochloric Acid 5.4 0.022 Phosgene 2.7 0.022 Ethylene Oxide 10.4 0.92 Propylene Oxide 11.1 2.42 I ~. Acetaldehyde 10.5 0.31 Monoethylamine 9.5 6 x 10 3 2 Dimethylsulfide I Ethyl Chloride Ethyl Mercaptan 8.9 7.5 6.5 3 x 10 3 3 3.3 4 0.03 Isopentane 14.2 14.92 Pentane 9.3 j I- Diethyl Ether 4.4 14.92 1.52 Hydrocyanic Acid 4.3
,jg . Hydrofluoric Acid. 9.0 0.052 0.032 Acrylonitrile 6.4 0.071 Ethyl Acrylate 3.9 0.1 dcthyl Methacrylate-Monomer 4.0 I Styrene M6numer Vinyl Acetate.
2.6 9.9 0.5 5.62 0.06
~
Acetone ~ 7.3 4.81 Hexane' 9.1 7.22 2-Butanol .. 2.2 0.5 Tert-Butyl Alcohol 3.3 0.5 I Toluene Alcohol Petroleum Naptha 2.2 3.3 5.6 0.82 0.5 2.03
' Hydrogen Peroxide 0.06 3 x 103 1 Carb31ic Acid 0.14 0.041 Cresylic Acid. 0.1 0.02 Phosphorous Ox3 chloride 2.3 3 x 10 3 1
Potassium Hydroxide 0.05 2 x 10 3 2 hromine 4.3 0.032 Allyl Chloride 10.7 0.22 Epichlorohydrin I Benzene Butyl Chloride 3.8 3.4 6.0 0.02 9.72 1.63 Carbon Disulfide 10.2 1.32 y .. { Cyclohexane 3.9 1.3 g (t ..
I TABLE 3 (Cont) l Conrail Transported Maximum Concentration Toxicity Limit
- Chemicals (Continued) (g/m3 ) (g/m3 ) i Naptha 2.1 0.4 Propyl Aldehyde 10.1 0.43 Tetrahydrofuran 7.1 0.7 Butyl Acetate 3.1 1.0 Isobutanol I Butyl Mercaptan Butylamine 1.2 0.09 4.0 0.2 1.5 x 10 3 0.02 Diethyl Ketone 0.9 0.93 I Ethyl Alcohol Ethyl Acetate Ethyl Benzene 1.2 6.8 0.8 2.62 1.4 4.42 I
Ethylene Dichloride 8.4 2.12 Diisobutylamine 1.6 0.023 Heptane 4.4 2.0 Isopropanol 3.7 1.2 I Isobutylacetate Mesityloxide Methanol 2.8 1.3 7.22 0.1 5.6 0.51 I Methyl Ethyl Ketone Octane 1-Propanol 5.8 2.5 1.5 0.92 2.42 0.6 Propyl Acetate 4.3 1.1 Xylene 1.5 0.7 Ethylene Glycol 0.09 0.3 uecyl Alcohol 0.3 I 0 . 2 Furfuryl Alcohol 0.1 0.04 Formaldehyde 5.2 4 x 103 2 Camphor Oil 0.02 0.02 I Ethylenimine Chloroprene Gasoline 5.4 9.2 7.9 4 x 103 0.05 3.0 6 M-Toluidine 0.2 I Nitric Acid Aniline 7.0 0.1 0.04 0.01 0.02 Toluene Diisocyanate 0.2 1.4 x 103 Sulfuric Acid 9.6 x 105 1 x 103 2 ~ Chlorosulfonic Acid 0.1 1 x 10 3 7 Phosphoric Acid 1.9 x 10 3 0.017 I Acetic Acid Acetic Anhydride Acrylic Acid 1.2 1.0 0.3 0.043 0.02 1 x 10~3 Phosphorous Trichloride 3.7 3 x 103 I Sulfur Monochloride Sulfur Dichloride 0.8 6.0 0.02 0.023 Zine Chloride 0.8 4.87 I Dimethyl Sulfate Hexamethylene Diamine 0.01 0.09 5 x 103 7 3 x 10~3 3 I 3 of 4
TABLE 3 (Cont) I Conrail Transported Chemicals (Continued) Maximum Concentration (g/m3 ) Toxicity Limit * (g/m3 ) Bromoacetic Acid 8.7 1 x 10~3 3 I Chloronitrobenzene Monoethanolamine 0.2 0.04 3 x 103 2.42 Methylal 3.3 3.9 Ethyl Crotonate 15.3 0.1 3 Turpentine 0.5 0.8 Cumene Hydroperoxide 2.4 1.33 Ethylene Dibromide 0.5 0.82 Fluorosulfonic Acid 3.9 2.5 x 10_3 3-Monofluorophosphoric Acid 1.4 2.5 x 10_3 3 Fumaryl Chloride 1.9 4 x 10 3 3 Ammonium Hydrogen Fluoride Solution 1.2 ~3 3 Chromic Fluoride Solution 5.0 2 55 xx 10_3 10 Ammonium Hydroxide 3.3 0.03 Barge Transported Chemicals Sulfuric Acid 1.56 x 10 3 1 x 103 2 Alcohols 1.9 0.04 Benzene / Toluene 106.0 0.82 Naptha 133.4 0.4 Gasoline 126.6 3.06 '
- Superscripts for toxicity limits refer to references on page 11. No superscript signifies that the toxicity limit was taken from the Documenta-tion of the Threshold Limit Values, Fourth Edition, 1980 by the American Conference of Governmental Industrial Hygienists Cincinnati, Ohio.
**Please refer to the text (pages 6-10) for an explanation of how those chemicals which appear to exceed toxicity limits were eliminated from consideration.
I I I I If Of k
! l 1 1 I TABLE 4 l l CONRAIL TRACK LENGTHS AND j E WIND DIRECTION FREQUENCIES i I Upwind Sector Track / River Length ** Wind Direction Frequency (miles) (Percent of total time)
- NE 3.25 4.1 i
f NNE 1.41 3.3 N 0.32 5.2 NNW 0.18 3.5 , NW 0.19 4.4 j WNW 0.34 4.1 l W 0.75 7.7 WNW* 4.24 4.1 e
- Track passes through WNW sector twice
**The track and river lengths are assumed equal since the track runs along the north shore of the Ohio River l
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W m M M M M W. m W M M M' W M M W W TABLE 5 - Continued SULFUR DICHLORIDE 84 0.133E-09 0.4660-10 0.166E-10 0.630E-11 0.036E-11 0.139E-10 0.570E-10 0.174E-J7 0.457E-09 CHLOROt4I T ROE ttlZEllE 85 0.133E-09 0.466E-10 0.166E-10 0.630E-11 0.036E-11 0.139E-10 0.570E-10 0.174E-09 0.457E-09 ItETHYL ER0ft10E 06 0.133E-09 0.466E-10 0.166E-10 0.630E 11 0.036E-11 0.139E-10 0.570E-10 0.174E-09 0.457E-09 DIISO9UTYLAttitlE 87 0.133E-09 0.466E-10 0.166E-10 0.630E-11 0.036E-11 0.139E-10 0.578E-10 0.174E-$9 0.457E-09 DECYL ALCOHOL 88 0.133E-09 0.466E-10 0.166E-10 0.630E-11 0.836[-11 0.139E-10 0.570E-10 0.174E-09 0.457E-09 IlotiOFLOOROPitOSPHORIC 89 0.133E-09 0.466E-10 0.164E-10 0.630E-11 0.836q-11 0.1390-10 0.578E-10 0.174E-09 0.457E-09 FullARYL CHLORIDE 90 0.133E-09 0.466E-10 0.166E-10 0.630E-11 0.836E-11 0.139E-10 0.570E-10 0.174E-09 0.457E-09 AICIONIUll H FLUORIDE 91 0.133E-09 0.466E-10 0.166E-10 0.630E-11 0.036E-11 0.139E-10 0.578E-10 0.174E-09 0.457E-09 01HETHYLSULFIDE 92 0.133E-09 0.466E-10 0.166E-10 0.630E-11 0.836E-11 0.139E-10 0.570E-10 0.174E-09 0.457E-09 BUTYLAllENE 93 0.133E-09 0.466E-10 0.164E-10 0.430E-11 0.836E-11 0.139E-10 0.578E-10 0.174E-09 0.4hlE-09 DIETHYL HETONE 94 0.133E-09 0.466E-10 0.164E-10 0.630E-11 0.836E-11 0.139E-10 0.578E-10 0.174E-09 0.457E-09 TOTAL PROBASILITYs 0.420E-05 k of k
g g g g a g a m m p M M W M M M M W W DUQUESNE LIGHT CO. BEAVER VALLEY P0HER STATION ALL 5 T0XIC CHEHICALS EVALUATED, 1977- 1978 BEAVER VALLEY HETEOROLOGICAL DATA AGGREGATE PROBABILITY OF T0XIC CHEHICAL SPILL TRANSPORTED BY BARGE 00HMHIND SECTOR CONTRIBUTORS (00HtG4IND DISTANCEtHILESil HE HNE N NHH NH HtM H HtM T0XIC CHEHICAL RA!M 3.25 1.41 0.32 0.18 0.19 0.34 0.75 4.24 SECTOR TOTAL GASOLINE 1 0.148E-06 0.517E-07 0.185E-07 0.701E-08 0.930E-08 0.155E-07 0.642E-07 0.193E-04 0.508E-06 BENZENE / TOLUENE 2 0.341E-07 0.119E-07 0.426E-08 0.161E-08 0.214E-08 0.357E-08 0.148E-07 0.445E-07 0.117E-06 ALCOHOLS 3 0.196E-07 0.685E-08 0.245E-08 0.927E-09 0.123E-08 0.20SE-08 0.850E-08 0.256E-07 0.672E-07 SULFURIC ACID 4 0.166E-07 0.581E-08 0.208E-08 0.784E-09 0.104E-08 0.174E-08 0.721E-08 0.217E-07 0.570E-07 NAPTHA 5 0.128E-07 0.447E-08 0.160E-08 0.605E-09 0.803E-09 0.134E-08 0.554E-08 0.167E-07 0.438E-07 TOTAL PROBABILITY: 0.793E-06
i t !I
- l i
I il i+ 'I !I i I t APPENDII A i CONRAIL HAZARDOUS MATERIAIS NCDE REPORT FOR MIDLAND, PENNSYLVANIA lI s iI i 4 i I I iI I A-1 I
e e m e M eM M M W W m M 'M M M m m M APPENDIX A 5/ue/ou ====== ConqAlt - MA,tnfilHG AND $4LLS - PL A *V I N G * * * * *
- PAbd 1 HAZ AR00US NA TERI ALS NUDE HEPQHT FAODuCfD FOR STONE AND WEOSTER NOOL ACilvity BY TYPE F6cM sANuany 1970 TbHU JurdE 1979 L = LUCALe U = OHlb!NAlthbe T = lt WMINAllNG, AND A = IMHU NAl MATL. TYPL OF STCC NU"MEH DESCHIPilON OF CUMMoul1Y CuOL Nubt hdet NAME TH AF F IC CARLOADS TONG 4901105 AMMUNITION FUH CANNad wi1M EAPLUSIVL AA 229 MlULAND A 1 34
*90113u AMbuNilluN FOH SMALL-AHMS wl1H EAPLUSIVL AA 229 MlVLAND A 1 - - b3 - -
690143u EXPLUSIVL BOMH AA 229 M10LANU A 2 66 69ultJ5 EAPLUh!VE MINE AA 229 FlOLAND A 1 +3 490le60 EAPLOSIVE PROVECilLE - AA 229 MIDLAND -A 1 57 N. M. Cbut sum 6 258 690lu6e 229 MlULAND A 1 - H. M. CLDL SUM 1 4902110 AMMUNITION FOR CANNON HITM EMP1Y - AH dt9 M 10 L A N D - --- - A------- 1 32 49021*0 AMMUNIllOre Fok CANNUN H11NOUT PH0JLCTILL AH 229 MIDLAND A 9 427 4902150 HOCati AMMUNITION hiin thPTY PH0JECTILL Au 229 MIDLANU A 1 75
*9pt*1u PwUetLLAni LAPLU51VEeSOLlu IbVN PUwoEkl Au 249 MlbtAND A 2 - - - -- --
490/53u HOCati Mul0R (CLASS 6 EAPLOSIVEl ab 229 M!ULAND A 4 107 490<e20 SPECIAL FIREwCHKS Au 229 M10 LAND A I 09 M. M. COut SUN - - - - - - - - - - - -- ---- - - - - - - - - - 18 767
> 4903170 SMALL-ARMS AMMUNil10N AC 229 MIDLAND A 8 177 b 49uJdlu CUMe!NAlluN PHIMEH AC 249 M!UL Af40 A 1- --- 13 --
4903500 TUY CAPS AC 249 MIULAND A 1 40 M. M. CUOL SUM 10 210 690412u CHLualNL Nb 229 MlULAND A 25 1,496 4906210 ANHYDHOUS AMMor41 A Nb 229 MIOLAND A 91 5,224 4406c/h N V DaVbt f4 LHLONIOt. Nb 229 MIOLAND A 18 - - - - 1, 2 0 7 --- - - 4906c9u SULFUM UlOX1DE NG 229 MIOLAND A 2 les
*906350 OAYutN Nb 229 MIDLAND A 2 26
*90*50s C AHn0N 010 A IDE G Ab e L 10VEF IED- (HMINING---- -
Nb - 2d9 M10LAlwQ -A 9 660 49065u9 CAwuuN OlUAIDE*LluuttlLD NG 229 M10 LAND A 9 605
*40=$15 COMPhESStD GA5 uONFLAMMAHLEeN.C.S. NG 229 MIOLAND A 1 66 49b6Slb OILeLUMuoIFLUCHUMLlHAf4L Nu 2t9 M10 LAND A 39 -- - 3 , o 4 5 --- --
4904552 MONUCHLUH001F LUJnuMF TH ANE Nb 229 MIOLAND A 7 604 4906370 COMPHESSLU GAbeNONFLAMMAuLE N.O.S. NG 229 MIOLAND A 51 4,393 490*Seu COMP *ESSt o-G AS eN0NFL AMM AbLE N.O.S. IG AS - NG - 229 M10 LAND ---A -- 1 13-M. M. tuot SUM 255 18,124
.90531u OIMtTNTLAMINLeANnYUHOuS Fb 229 MIDLAND A 19 -- - 979 ..-. - - . . - - - - .
.90553u FouumtInVLAMINL.ANHYDHOUS tb d29 MIOLAND A 13 523 44055*U THl*LINYLAMINEeANMYDHOUS FG 229 MIDLAWO A 6 209 4905702 HUTAN4 (uuTANEelMPURE.FUH FUHTHER tb 229 MIOLAhd - - - - .A---- --- 3 257 49057u3 HUIAUlthletNM:HITED (601A01EntelMPUHE, tb 229 MIDLAND A 2 158
*90510 du!AplENLethM1011E0 (6UTADIENL FDOM FG 229 M10 LAND A 72 5:744
=9J57ub eUlaht tb 229 MlutAND A 1 -- 16 - . . . - . _ _ -
*9951u7 LluutfIto PETHuttL% nas (Huitht GASe PG 2 2 '. M10LAr.0 A 1 72
*99511u COPHHtS5LD GA5eFLAMMAuLEeN.O.S. tG 2d9 MIDLAND A 2 33
*905711 LluutF ito HETROLEUM GAS -tout YLENE.- . -- tb 220 M10 LAND - A -. -- - 1 50
*9nd725 Olmt1MYL ETHEM FG 229 M10 LAND A 234 7,656 49057J. ETHYLLNE FG 229 MlutAND A 62 4,059
5/06/ou '" * *
- CONd A I L - M Ak n t i :1.t. Ar.J S AL LS - FL A reN ING *""" PALE 2 HA/AHDOV5 M Al[HI ALS r QDi HtPuHI FHUOUCLU f0H S IUr.E Ar.D ht H5IEN rdOUL ACIIVIIY HY IYPt S Ht/M J Alst/ A N Y 197o l *- H O JUNt 1979 La LOCAL, 0 = OHIb!NAllah. I = ItHb!Nal!NG. AND A = TMHu nAl. MATL. TYet UF STCC NU%f H UESCHIPil0N OF COMFJuliY Cout hubE hoof NAME THAFFIC C AHL O ADS-- - TONS 4905167 150Hu1 ant to 229 MjutAND A 17 5*S 4905 fen 15vnu1YLtNE Fu /t9 Mlot ANu A 109 753 - - - -
690575/ L!butflEU PLTHOLLUM GA5 t6 229 M10 LAND A 41$ 29,917
.905101 MiinVL CnLORIDE FG 249 MIOLAND A 89 5,290 4 9 (,5 7 H 1 FwOMANE -
F6 229 F*]OLAND - A - 1-- 13 490579c v i re Y L CHLONIDE tb 229 MIDLAND A 4e553 420,831 4905eJu COMewE55t0 G AS F L AMMAblE eN.O.S. t E IHYLENt Fu 229 M10 LAND A 1 77 H. m. CUut SUM be601- 4 8 4 , 0 3 5 --- -- 490etc0 ETHYLLNE IMINtelNHIBITEU FL 229 MIDLAND A 1 73 4906610 ETHYLLNE 0x!DE -- - - - - - - - t' L - 229 H l ut AND ----- A - -381 29 700 496eetu PHvPYLEht Ox!UL FL 2/9 MIULANU A 157 11 331 4t 49 0 e as t u A C H Y LUr. l i d iL E et 2/9 MIuLAND A 21 1 275 490/960 NilWOCtLLULUSE.wtl wiiH Nul Lt55 IHAN FL 2t9 M10 LAND A 5 294 - . - - - 490721u ACEiALUENYDE FL 229 MIOLAND A 33 2e140 4907215 EINYL ALHYLAft INHlu!IED FL 229 M10 LAND A 186 14 386 4907223 - FL AMM AULE L IQUIDeN.0.5. t CHLOHOPHE NEl- - P L -- -- 2 29 M I DL AND - --- A - 1 -78 4907450 MEInVL MtIHACHYLAIE MONUMEH INNIBITED FL 2t9 M l eL Ar.D A 57 4ebt9
- e. 4907t51 MEleVL MtlHACHYLAIE MONOMEHelNHIHlitO FL 2/9 M!OLAND A 1 bl I 49 ult 55 Mt i nY L Mt IM A(,H Y L AI[ MUNuMLHeUNjhHlblitO FL /g4 MIULauO A 7 -- - -- 5 9 4 4907250 MEinYL MtlHACHYLAIL MONUMER UNINHIBITED FL 229 M ! ut Ar.D A 12 9ol 4907263 F L AM M AttL t LIGul0eN.O.S.(150 BUTYL FL 229 M10 LAND A 1 74 4907265 - 5TYwtNE MONOMEH e lNn!BITEU -- - '
FL - 229 MIDLAND. -- - A 01 850
*907270 VINYL ACLIATE FL 2t9 MIutAND A 78 6,556 4907612 ALLYL CMLONIDE FL 229 MlulANJ A !9 608
*907 2u FlamuAbLt t. luulo r o d.0,5. (LPICHLOH0 HYDRIN) PL 229 M10 LAND A . - -- ---- - 2 9 0 4907e35 MONotINYLAMINE FL 249 MIOLAr.D A 2 113 490e105 ACtTUNE PL 229 M10 LAND A 292 16e679 490H106 ACETONE ulL. - - - - - - - - - - - - - - - ---
FL 229 M I OL A ND ---- A 1 35 490811u HENZENL teen 20LI FL 229 MIDLAND A 1 36 490elle tiLNilNL PL 229 MlulAND A 3 111 ovon!!5 HulvL CnLOHIOE FL f* 249 M I uL Ar.D A -..- - - 13 - _.. . - _ e d 5 _-.
*90o125 CAwvuN HISULFIDE,(OR) CAHbON DISULFIDE FL 249 M10 LAND A 5 305 6906132 CYCLONEAANE FL 229 PIOLAND A 13 510 490ol51 -pl> ETHYL SULF IDE - - - - - --- - - - - - - --
t L - --- /d9 M I UL A r4D ------ - A 1 44
*9uh156 EletH (DIETHYL ETHEH 0THER TNAN ANESTHE- FL 229 M10 LAND A 1 17 490ol57 lc T ME R (UIETHYL ETHLH.ANL51HE51A GHADEI iL 229 MIOLAND A 2 42 69pnibe tTNYL CHLORIOL PL 229 M!ULAr.D A - 349 - - 13 e 0 9 4 -- - -
*908169 EINYL MtHCAPTAN FL 229 M]ULAND A 1 36 490Mlle 6450LINL FL 229 M10 LAND A 8 265
*90H1H3 HE A ANE - - > - - - - - - - - - - - -
F L . -- - 2/9 MIOLAND - - . K .-70 6 117 490e19d IS0PENTAht FL 229 MIOLAND A 2 172
*90nt/2 MEinYLAL FL 229 MIOLAND A 1 18 49pn235 vtNIANL PL 249 MIDLAND A la 927- . - - . - .
H. h. Cout SUM le831 120:516 4906257 -- - - -- - - .- - 229 MIDLAND A. . 8_ 627 H. M. Cu0t SUM '8 627
g g g @ M E 5/06/60 ****** CONHall - AAHMt Ilhu ANO Salt 5 - PLANNINb ****** 9 AGE 3 MA2AMD005 NA EHIALS tsuvE ktPoHT PHbPUCLC FUN SIUr.E AND WL6b1ER LNOUL
= LOCALE ALIIVIIYU = HY 1YPt FHUM sAhuawY 1976 TbHU JUNL 1979 OR ! b l N A l l f.b . I
- IE4MlWAIINUs AND A a TMHU
. ~~~
STCC NUMetH mal. MAIL. TYPL OF OESC41PTION OF "UMMUO!TY - -- CODE Nuut NUDF NAME- TR AFFIC - - CARLOA05 TONS
*900405 PtinuLtud LINEW FL 490Httu d29 MlOLANu A 1 15 PwuP ] Ue= AL ut H Y DL (PH0YPL ALULHVUE) tL d29 MIULAND 49D5490 TE TH AMVLHUFUR AN A 21 -
1,409 - - - - FL 229 M10 LAND 4909105 ALCUHutsu.U.S.(FLAMMAULE LIOUID) A 36 3e432 490912e tl //9 MIOLAND A MUIYL ACtfATE --- 1 13 4909129 HUITL ALLUMUL (2-HUTANUL) tL 2/9 MIOLAND -- - x 18 l e 7o3-49091JO tL 2/9 M10L Ar.O x 39 2,918 NUlYL ALCOMOL (it WI-HUT YL ALCUHOL) FL 229 MIOLANO 0 69091Ju HulVL ALLUMOL (ILHI-dulVL ALCUHOL) 16 700 4909131 FL 229 M10 LAND hu1YL ALCOMUL (IbObuiVL ALCon0L) A 35 -- 2,179 - - - - - - - - 49u9133 HUIYL MLHCAPTAN tL 229 M10 LAND A 10 6o5 4909134 FL 2/9 MlULAND A 4 146 HUTYLAMinE (TERT-8UTYLAMINEt- - - - - - - - fL -- 229 M10 LAND x 4909141 DENATOWEu ALCOHOL ! '* 3 4909142 tL 229 MIOLAND A 30 le912 ALCUMULe4 0.5.(DENATURED ALCOHOL tL 249 M10 LAND 1 490vl50 OltInvL AETUNL 3 201 4909157 FL 2/9 M10 LAND 0 FLANSAuLL Ll4UIDeN.0.5. FL 1-------- 2 8 --- - 4909159 249 M10 LAND A 13 COLuuht bPIHlIS IETHYL ALCOHOL) >L 229 M10 LAND 1 4909160 FTHYL ACETATE - - - - - - - - - - - - -- --- - A 6 94
*909162 - F L -- 2 / 9 MlOLAND- --A-EinVL CHuiONAIE FL 17 1+313 4909]bJ ETMYL NtralENE 229 MI DL Ar.D A 2 233 FL 2t9 MlatsNO p 4909166 FTHyltNt DICMLONIDE FL A 7 213 I 4909177 229 MIGLAt.U A -
9-FLAMMAbLL Lluu! den.O.S.(UllS0dVLYLAMINE) 7 2 8 ---- -- 490'.190 FL 229 M!aLAND x MEPTANE FL 1 68 4909190 - N E P T A N L ------ - - - - - --- - - - - - - - 229 MlOLAND T 7 567 4909 dub F L--- 2 29 MIOLAND- -X-ISUFHuvANOL FL 7 563 4909 tub ISOPHOPANUL 249 MlOLAND 0 4 116 FL 249 MIOLAND A 4909 dub AL(UnULeN.O.S.(ISUPHOPANUL AND METHANOL FL 229 M10 LAND 31 2 032 490940/ A 5 ISUnUIYL ACETATE FL e5 --- 490942u 2t9 M10 LAND A 7 Sb3 MEHCAPTAN MIAIUHE ALIPHATIC FL 2t9 MlutAND A 490942J ME511YLUAIDE- - 17 621 490943u ntiMANUL (METNYL ALCONULewuUD ALCOMUL,
- - ----- -- -- - F L - --- 2 2 9 MIULAND- A- 1 72 49092Ju FL 229 MICLANO O ME1HANUL (MEINYL mLCOHOL.*U00 ALCOHOLe FL 1 70 49094J/ ALCuH0LeH.U.S.(MLIMANUL.CUNTAMINATEU, 229 MIULAND X 3 218 490ve*3 tL 229 MIDLAND A.
Mt1HYL tfHYL METUNL (L1MYL MEIMYL FL - . -- 45 49094.J 229 M10 LAND 0 9 274 ME1HYL EIHYL METordt (ETHYL ML1HYL FL 249 M!OLAND 6909443 MElmTL LTHYL nETONE (E T N VL ME THYL. ---- 1 2 155
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& L - --. 2 2 9 MILLAND- --- A ly FLAMMA0LE LIQUlueN.O.S.(MLTHYL ISOBUTYL FL 734 490925u OCIANE 2/9 MIULAND A 9 594
*9094b7 FL 229 M!ULAND X ALCUnuLem.0.S.(1.PHOPANULI 2 190 49094eo FL 249 MIDLAND A PHOPvL ALETATE FL 19 .--- . -le273----.--
4909J05 TOLutNE 229 MIDLAND A 3 309 FL 229 M l UL Ar.D avuvJAO ANVL FUMM ATE - - X 47 2:018
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- _ _1 13 999350 AYLtNE 229 MlULAND 0 1 36
.vlulut ALuMlHUM LIQUID (UH P A lle l l tL 249 MIDLAND A 16 538
*41ulut FL 229 M10 LAND A ALCOMULen.0.5.(FLAMMAdLtl (ALCOHOLelN FL 229 M10 LAND X 1 -
16 --- - - -- 4919106 ALCOnuteN.O.S.(FLAMMAHLtl (ALCUMOL OR 21 1,390 491v1u1 PL 249 M10 LAND X ALCUMUL e h.0.S. (FL AMM ABL E ) ( BH ANDY e --- - FL 1 38
*slull* CENtHiellWUI0eN.U.b.(FLAMMABLE) 229 M10 LAND-- - A----- -8 -638 491ollo FL 229 MIOLAND A CtMENieHUUFINGeLluulo 6 107 el 229 MIULAND A 2 ,35
M Stue/ou ****** CONNAll - NAHntIlbb And SALLS - PLAhNING ****** PAGE 4 NA/ANDUUS MAltHIALS NUDt MteoHI Ph000CtD tOH SIUNL AND WLb5ILH N00E Acilvily Hr ITPt FHuM sANUANY 1916 ihWU JdNL 1979 L = LulAL, O s OHlulNAllNbe I s ItHMihallNG. AND A a ThWU e NAl. MATL. TYet OF STCC NUMEEH UtSCRIPfluN OF COMM00!TY LuDt NUut NUDE NAME THAFFIC CARLOA05 -- TONS 491oltu CLFENieHudHLH tL 2/9 MIOLAND A 3 60 49]uteb COMPOUNueLLEA4lnbel14Ulu (fLAMMAHLL) FL 2cv MlOLANO A 2 *1 - 491bl*7 COMPuUnveCLEANINusL]OUlu (FLAMMAhltl FL 2/9 M10 LAND A 16 270 49101S2 FLAMMAbLt LIQUIUe4.U.S.tPAINI UILSeNEC) FL 249 MIOLAND A 25 3b3 4910153 COMPUONDeLACQUiMePA!NI,(OH) VANNISMeHE- FL 229 M!OLAND -- A 35 leS94 4910151 ComPOUhueINEE lOkt wELO 61LLIN6.Lluu!D FL 229 M10 LAND A 12 610 4910165 CHUUE OILePLTHottOM (FLAMMABLL) PL 229 MIGLAND A 3:206 281,254 491olle EMAUICAIUHePAINI (UNI GHtAblellGUlO tL 2t9 MlVLANU A S - -
' 15 4 - --- ---
49101d1 EATHACIeLIQUlu FLAV 0HING fL 229 MlVLAND A 9 145 4910195 FLAMMAeLE Lluu!Deu.0.S. tL 229 MlutAND T 2 103 4910185 ' FLAMMAHLL LIQUIDeN.O.S. - - - FL- - 229 M10 LAND -' A 101 0,339 491ul91 UHUG5 Ok MFDICINESeN.O.S.(FLAMMARLE FL 2t9 MIOLAND A 1 34 4919205 thn IFLAMMAULEl llhn PHINIIN6eNEC) e FL 229 MlutAnd A 8 125 491uelu INbtLIIC10EeLluulDeN.O.S.(FLAMMAHLE FL 229 M!ULAND A 4 - - - - - - - - 7 6 --- 491ut25 ALCunULen.0.5.(FLAMMAbLL) [Lluu0R5e tL 229 MIOLAND A 83 4,899 491u239 NAPHTMA (FLAMMAHLLI FL 29 MIULAND A 34 2,099 4910t*J PtTHOLEUM OIL N.O.S.tPEIHULEUMePARTIALLY- FL--- 229 MlUL AND - A- --- - - I 66 491u2*S O!LeN.O.S.ePEIRULEUM Olle(UHI PETHOLEUM FL 229 MluLAND A 95 5,682 4910452 PAlnI (FLAMMAHLL) (ASPHALIUM UN COAL TAH FL 229 MinLANO A 7 143
> 491u253 VANSISH IFLAMMAHLt) (ASPNALTUM UR CUAL FL 2/9 MlULAND jr 691u45% pal %IeLACUUER OH SHFLLAC (HU6HtH TINE PL 229 M10 LAND A
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-- 13 13 4910255 FLAMMAULL LlOulDeN.0,S.(PAINT OIL FL 229 MIULAND A 2 26 4910257 PEIHOLEUM DIST ILL AIE lFL AMMAHLE I -(PETRO ~ FL 249 M10 LAND --A- 86 5,799 691u256 PLlHOLtuM OIS11LLAIE (FLAMMAbLLI FL 229 M!ULAm0 A 10 bu3 4910459 PETHOLEUM NAPHIMA (F L AMM AULL) FL 229 M10 LAND 0 22 742
*91uc59 PLINULtuM NAPNIMA (F L AMM AHLE ) FL 229 MIOLAND A 66 - 4eb78 4910240 NEblN SOLUTION (HESIN ruMPOUN0eLIQUIDI FL 229 MIDLAND A 67 3slJS 4910491 SOLVtNieN.O.S.(FLAMMAHLtl (50LvtNISe FL 229 M!ULAN0 A 13 409
$91030H ALCOHOLeN.0.5.tFLAMMAblE) ISPlHliSo -- - -- - F L ---- 2 2 9 MIOLAND- A 2 40 491oJu9 ALC0HOLeN.O.S.EFLAMMAbLL) (SP!HiiSe FL 249 MIOLAND A 22 2e068 441031J TUNPtNTINE (FLAMMAHLE) FL 229 MIDLAND A 1 29 691u*uJ ALCOMULeN.O.S.4FLAhMAHLtl (Ut N ATUNEU PL r ' 229 MlULAND A -
2 - --- --- - 4 0 --- -- -- 491u*lo FLAMhabLt L10VlueN.O.S.tPLASTICIZLHS. FL 229 MlULAND X 9 541 4910436 FLAMMAULE LIQUlueN.O.S.lbaMMitH FL 229 MIuLANU A 1 13 491u=42 -FLAMMABLE-L10ulDeN.O.S.twuSIN L I Q U OH I - - ------ -FL 2d9 M10 LAND -A 6 23+ 4910444 FLAMMAHLt LIQUIDeN.O.S.(HUSIN FL 229 MIOLAND A 2 61 491D**b FLAMMAbLL Lluu! den.O.S.(HUSIN GLOSS OH FL 229 MIOLAND A 11 425 491050c ADatdivteN.O.S.tFLAMMAHLL) (INSLCTICIDE FL 229 MlOLAND A 7 .- - - 1 6 3 --- --- . --- - - 4910500 ADNt 51 vt eN.O.S. t F L AMM AbLt ) FL 249 MIOLAND A 6 87 491u51= FL AMM AhLE L IQUID.N.O.S. lHEF INtHY IL 229 M10 LAND A 3 248 4910$60 FLAMMAsLE LIQUID N.O.S. (CHEMICAL PLANT- FL- 229 M10 LAND _A -- -- -- 1 1 868
*91056$ HEFHibtHAIING MACMINEeFLAMMAHLE LIQUID FL 229 MID%AND A 1 63 H. M. Luut SOM 4 523 354,174
~~~ ~~
491223u COMbuSTieLE Lluulo N.O.S.(MYONUAYPROPYL LL 229 MIOLAND A 1 T9
*v1310J ALCOMOL eh.0.S. t cuMHuSi lHLE L luu!DI CL 229 MIOLAND A 26 1 702 4913116 ETMYLENE GLYCOL MONUEIMYL ETMLH CL 229 MILLAND A .-
-8 - 647 4913117 EINvLENE 6LYCUL MUNDE1MYL LTMLH ACEIATE LL 229 MIDLAND A 2 156 4913121 ALC0HOL e N.O.S. t COMuuST IuLE I (UtCYL LL 249 MIOLAND A 1 80
O E M S/ub/uu ****** CUNHA!L - MAHM IING AND SALLS - FLANNING ***e** PAGE $ MA/AWDUUS MAIEHIALS NUME htPUNI PHUDUCLD FUk b l Of.L AND htHSIER HOOL ACIIVIIY HY lYPt .kUM JANUANY 1976 IMHU JUNL 1979 L z LOCAL. O a OH!b!NAllbbe I z TLRNINAllNbe AND A a THku NA/. MATL. TYPL OF biCC r.UMeF H UESCRIPTION OF COMMUD11Y CUUE NUDE NUDE NAME TRAFFIC CARLOADS TONS 491Jite ALCUHULeH.O.S.tCUMHUSilnLL) (FUHFUNYL LL 229 MIUL,hND A 8 463 491Ji+J AL(UMUL N.O.S.tCUMuuSI!nLtl (MtlHYL' LL 229 MlOLANU i 1 07 - - - - - - - - 49 t J 16'J ALCOMULeN.0.5.(COMHUS11HLL) (MtIHYL CL 229 MlOLAND A 1 67 691J1*4 FOwMALUEHYDE (OH) F0HMALIN SULuilDN (IN CL 2/9 MluLAND A 21 1,6*9 691JIS3 CAMPHUR O!L - CL 229 M10LANO -- A 1 29 491Ji$n ALCOMULsN.O.S.tCOMnuSildLE) (ULIYL CL 2/9 NIULAND X 16 le048 6913162 fiHTLLNE blYCUL MUNOMLIHYL F IMt H CL 2/9 MIULAND A 4 339 4913175 COMHublinLE LIUulueN.O.S.IIOLulutNtl LL Pd9 M10 LAND A 3 - 244 --- -- 491510c ALCUHOLeN.O.S.4LUMnUSIluLE) (ALCOHOL.IN CL tt9 MluL Af.0 A 2 l*7 4915113 FUtL OIL (COMbuS11HLE) CL 249 MIOLANU X 2 150 4915116 CEMENiettuu! den.O.SetCOMcVST!HLEI CL 229 M10 LAND -- X 1 20 4915115 DISIbfECIANIeLIQUIDeN.O.S.tCOMuuSilbtEl CL 229 M10 LAND A 2 94 49151JS CUnL IAH LIGHT Olt (COMduSiinLLI ICHUDE CL 2J9 MIOLANU i 1 96 4915135 (UAL 14H LIGHI Olt (COMHU$linLLI (CHUDL CL 229 MIOLAND X 1. - -- - - - - 9 6 - 4915141 COMv0VNU.CLEANINbellOU10 (COMHUST!bLE) CL 229 M10LANO X 3 66 491515d CCMHUSTiblE LIQUIDeN.O.S.tPAINT OILS, CL 229 M!ULAND X 1 13 4915157 COMeuuND*THEE tud) WEED k!LLIN6eL10UID CL-~ 229 M10 LAND -X 10 853 4915171 NEHUSLNL (COMdubilutEl CL 2/9 MIOLAND A 1 33 4915165 (UMHUS11dLE L100lo.N.O.S. CL 229 MlOLAND 0 1 30
> 49151nd CumnubilnLE LIOUIUeN.O.S. CL 249 MIDLANO i 15 -- 842 8
49151a5 COMeubilHLE LluulueN.O.S. CL 229 MlulAND x 158 10,312
+915187 SOLvtNieN.O.5.tCOMPUSilbLt) CL 229 MIULAND A 19 1 530 4915239 NAPHINA (COMHUSildLE) - - --
CL -- 229 MIULAND 0 1 34 4915c39 NAPHINA LCOMbOSTIHLE) CL 2/9 MIOLAND A 9 616 49352*J COMnU5TlHLE LIOulU.N.O.S tPLIHUlfUM, CL 229 MlVLAND A 11 609 49154*5 OlteN.O.S.ePLlHULtuM VILE (OH) PLTHOLEUM CL 2d9 MlOLAND A 31 - ---- --2 0 0 5 - 4915251 PAINieLALOULHeSTAIN,(OR) VAHNISHeUHUNZE CL 229 M!ULAND A 4 138 4915252 PAINI (COMBUSiluLE) (ASPHALTUM OR CCAL CL 229 MIDLAND A 1 20 4915455- COMHUSilblE LIOU10eN.O.S.tPAINT O I L --- - -- - CL - 229 MIOLAND- A 1 60 4915451 PElHULEUM OISilLLATE (CUMdVST!uLE) LL 229 MIDLAND A 7 548 4915259 PLINULEUM NAPHTHA ICOMHUSTIRLE) CL 229 M!ULAND A 7 295 4915tnd TAMeLIOUID (CUNHUSIIHLL) (PINL TAH) CL , 249 M!ULAN0 X.- --
- 1. . . . - - -
6915265 PLASTIC SULVENieb.U.S. ICOM60STlhtt) CL 229 M!OLANO x 1 25 49152nu HL51N SULUTION thtSIN COMPUUN0eLIQUIDI CL 249 MIDLAND A 2 75
+915d97 SULvthleh.O.S.tCOMHUSTleLEl-(SOLVENIS, - C L--- 249 MlOLAND -- X 5 360 691536J CHtOSOIL. COAL TAN CL 229 MIOLAND x 96 7 329 491S*1u COMHU$iluLE LluulDeN.O.S.tPLASIlCl2LRS, CL 229 MIOLAND X 5 174 M. M. LOOL SUM 492 - - 33,402 ----
491e!*1 PHUdkMUh. iewHITE tuR) VLLLowelN WATLH FS 229 MIDLAND A 217 20,744 491632u PHUSPHUMus PLNTASULFIDE - FS -- 229 MlutAND ----x -- - 9 563-4910401 CALCIUMeNLTAL FS 229 MIDLANJ A 2 39
*91bou5 CLSIUM MLIAL FS 229 M10 LAND A 1 11 491e*00 CALCIUM CANBIOL FS 249 MlOLAND A 9 795._ - - . - - - -
49167*u SODIUM SULFIDEeANHYOHUU5 PS 229 MluLAND A 6 311
*9111e5 NiiHUCLLLULOSEowLl WIin NOT LLSS THAN F5 229 MIULAND A 3 41 4917311 CHAh00AL edluuETith (OH) 6HIUUETS ICHAR= FS - 229 MIULAND - A------- 27-. 540
*917J12 CHANC0AL dRIQUETTES 109) 3HluuETS (CHAH- FS 229 MIOLAND A 42 1,814 6917332 FLAMMAdLL SOLIDeN.O.S. FS 229 M10 LAND A 1 13
O E O O M S/we/ou ****** CUNH A ll - H AWMt l lw', Al.O Salt $ = VLAhh!Nb ****** PAfsE 6 NA2AWOOO5 MAILHIALS NuDt HtPUNI Pw WuCLb t UN b l ON+ AND =Lb5!LR NOUt aCliVilY HY I Y Pt FHuM JANUAdY 1975 IPHU vVNL 1919 L = LUCAL. U = UNiblNAllhus I = itHM[NAl1NGe AND A
- INHU nAl. MATL. TYPL OF STCC NumeF H UtSCRIPTION OF COMM00!iY Cout AOUE NOUE NAME TRAff!C C A R LO A DS -- -----T O NS 6917Jon HvHkt H 5 CHAP OH wunHtw our'tINb5 PS 229 MIOLAND A 2 64
*917J7% ndou5 UN MtOIClut5e4.0.5.ttLAMMAhll t5 229 MIOLAND A 1 14 - -
- e. a. Lust bum 320 24,949
=vio310 AM*0N!UM N]fwATE FtHT!L12ER (CONTAINING UM 229 M10 LAND A - -- -- -- 2 0 3 -- 16,131
*ste311 AMauhluM taliHATL INO OHb NIC CUATINul uM 229 MlutAND A 250 23,751
=91M335 H Y us u6t t. PEHOAIDE 50LU11UN t oVt d 526 uM 229 MlVLAND A 75 3 ebb 5 691o*ue MLt atn!Nu POnot H. (Ovtk J96 AVAILA6Lt uM 249 MIDLAND A 2 e6 -- - - -
691e==5 THicnLusO-5-inI Allht IHlOHL (OHYeCONIAIN- UM 229 MIDLAND A 2* 371
=vic5t5 hilaAllNG (MIALU) Aclu us 2t9 MIOLANO A 16 e30 691o548 NIIwlC ACin (OVEN 40$1 -
um 2t9 MIOLAND T ---- - -- - - 5 192 691e52m N!!w!C AL!O (OVtH 406) OM 2/9 MlulAND A 12 *e6 491e549 nil =lC AC10eFUMING OM 229 M10LANu A 1 12 491e104 AMat,NIum n!IkAIL-FMO5PMalt UM 2/9 MIDLAND A 4 - -- 395 - - - - --
*9137o3 A*MuhlVM NilHATE MIALD FEHilLilER UM 2/9 MlULAND A 10 Bs7 6910109 HAHluM f*IIWATE UM 2t9 MIOLAND. A 1 51
=91e715 CALCluM NYPOCMLURITE MIATUNE.(OHYletCON-- OM 2d9 HIOLANO ---
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---- 1 1 215 6914723 50uluM CMLOHATE (CMLONATE OF 500Al VM 229 MIOLAND A 8 600 691n?31 N11wATEen.0.5.tNIINATE OF 500A-POTASMI OM 229 MIOLAND A 3 101 7 *wle#J2 niinalteh.D.S. Um 229 M10 LAND A 2 -
-- 5 0 ---- -
os 691e/J7 PCIA5SIUM N!lHATE UM 229 M!utAND A 47 2 365 49167,0 POTAadluM PENMANGANait (PLHMANGANATE OF OM 229 M10 LAND A 1 70 491Mf66 SODIUM NIINATE -- -- - - - - - - - - - OM - 229 H I OL AN J ----- -- A -- 81 :*892 691o747 Suu!UM HliHITE OM 229 M!ULAND A 5 200 691el5 STMONTIUM NITHATE OM 2t9 MIOLAND A 16 795 4916750 21NC AMMUNIUM NiidlTE OM 229 MIutAND A 1 - --- -- 9 0 --- 09167o5 UAfbillNb HATLHIAleN.0.5 ISODIUM OM 229 MIOLAND A 21 415 491e910 OAiolZlhu MAlENIAL,N.U.S. (FLOUR OM 229 M10 LAND A 1 22
- n. M. LuoE SUa4 - - - - - - - - - - - - - - - - - - - - - - - -
- --8 0 0 57,262
=vl9525 CUMENE MYUROPCHOAIOE UP 249 MIOLAND A 3 51 M. M. Luot sum .c 3 -
6920125 HvowuCYANIC ACIDeLIQUEFIED PA 249 MIULAND A 12 345
=9205 0 PMu5 GENE - - - - - -- -- -- WA- 229 M I D L A N D - ---- - - A 16 240 M. M. (Uut SUM 28 565 ,
*92121u canretil ACIDeltuul0 (UN) PHLNUL.LluulD Pd 229 H!ULAND A 28 .. 2,435 . . . - - - -
*421220 CAwnutIC ACID (OH) PHENOL Pa 2d9 HIULAND A 305 26,808
=921*1u ANILINL ulteLluulo PH 229 MIULAND A 25 2,061
*421*25 olhilHOPMENOL SULul104 --
ke 229 MIDLAND -- - A---------- 1 -84
=921*di DHUGS UM MLOICINt5.N.O.5.tlluul01 Pn 229 MluLAND A 2 99
=921429 POISuNUU5 50 LID.N.O.S. tMtPT ACMLORI PM 2d9 MIOLAND A 1 50
=921=J. IN5t CilClut ONY IINStCilC10t5elNSEC1 04 VM 229 MIULAND A 1 27 - - -
69/1436 MEINTL HHOMIDE AND LTHYLLNE DIHHOMIOL PH 229 M10 LAND A 1 13
=921=45 MulOH tutL ANiinNOCK COMPOUND (URI PH 229 M10LANU A 311 28e2d6
=921457 NIThuCHLUMMENZthtORTM0elluulu PH 229 HIOLAND A 1- -96 4921,5o N11HUCMLuHHEhltNtoMETA UH PAHAe50LIO PH 249 MIULAND A 1 64 6921401 OHGANIC PM05PNAIL,OH4ANIC PMuSPMATE COM- Pb 229 M10 LAND A 5 298
E E E E O S/u0/ou ****** (UNHAll - MARRtliab Aun S Alt S = PLAmNING ****** PAug T MA/AhDOUS MAltHIALS Nuot $4PbHI > HODuCtU r OM SlONt AND M HSILH N00t ALitvily HY lyPt FHUM UANuawY 19fn 1*MU JUNE 1979 L = LOCALE O a OHIGINAllNbe I a TLHMINAi!NG. ANJ A a THHu Mil. M4TL. TYPt CF STCC NUMhtk blSCRIPfl0N OF COMM00!TY Cout huuE NOUE NAME THAFFIC CAHLOA05 TONS 69/1463 OwNANIC PnOSPMATL HIAIUHLoUHGANIC PMOS- en 229 MIutAND A 12 107 Sv/16%/ vawANilwuANILINteSullu Pn 249 MIULAND A 1 19 -- -- 6921*iS PU150NovS Lluulu.N.O.S.teu150NuuS Pu 249 MIOLAND A 95 Se709 4921 76 POISuNuud 50LIU N.U.S.tPolSONOUS SOLIDe >d 229 MIOLAND A 13 675 6921*FU SikvCNNINE SALToSOLID -- Po 229 M!OLAND A - - - - - 1 95 6921575 IULutNL pliSOCYANAIE PM 229 M!vtAND A 24 2,031 692J2t7 SoutOM CYANIOt SuLUTION Pb 2t9 MIULAND A 14 537 69tJttn SDuivM LYANIUteSULIO Fu 249 MlOLAND A 9 - 315 -- - -- 6923293 Pu]SUNuuS SOLIDeN.O.S.(SVLPNUHellNC en 229 M10 LAND A 1 6S H. N. CLUL SUM 852 72 976 6930010 FLOOSulF ONIC ACID CM 229 M10 LAND A 7 341 6930022 NYowuFLuukIC Aclu SOLUTION CM 229 MlULAND i 1 48
*930022 MYunUF LuvHIC Aclu SOLUlluN LM 229 M10 LAND A 23 -
-- - l e C 16 ---
6930u24 MYoruFLuuMIC AClo.ANHYDHOUS LM 229 MIOLANu A 145 9 412 6930u26 NYDnuFLuuSILICIC ACIO LM 229 MIOLAND A 3 173 6930040 'SULFUNIC ACID- ~- - - - - - - - CM - - 2t9 M 10 L A N D - ~~- - - T ----- -13 9,2 493u0*O SULFuk!C ACID CM 2?9 M]ulAND A 11 S23 6930to! ACluellOUIDeN.U.SetACIDSelN0HGANICeNEC. CM 229 MIDLAND A 11 414
> +93uto* CHLunOSutFONIC ACID LM 2/9 MIULAND A 4 --
266 I *93ut2M HYDwuCHLUHIC (MUNIATICI ACID 229 MIOLAND
'4 LM A 4 341 4930440 MONUFLUUMUPMOSPMOHlc AC10eANNYDHOUS CM 229 MIOLAND A 1 IS 493u467 - CodHUSIVt -L 10VID e N.0 e S. t PMOSPH AT IC -FER -- CM -- 229 HlULAND -- A - 3 302 693o248 PnoSPMuklC ACID CM 229 MIutAND A 1 43 693u45J Stunut ACID CM 229 MlULAND A 1 39 4931Ju3 Attill AllDeGLACIAL CM 249 M!OLANO A 72 ---- 5,4e 5 --
49313ue ACtllC ANhyDnIDE (M 229 MIDLAND A 4 228 4931*ul ACEllC ACID (AuUt005 SOLuTIONI LM 249 HIOLAND A 5 176 4931403 COHHOSivE SOLID N.O.S.(ACIDeNEC.DHfe-- CM - -- 2 29 M10 LAND A- 1 13 6931*ue Actuettuu! den.U.S.EACIDehtCelluulDe CM 229 M!OLAND A 12 629 693140$ ACHYLIC ACIO CM 229 MlULAND A 8 709 4v31411 nHurOALLilC ACIO SULulluN CM ,/ 249 MlOLAhD A -- - 1 ----------64 4931487 Cownublvt LluulD N.O.S.tCHESYLIC ACID) CM 229 MIDLAND A 39 2.2*S
*931**u ISUPENIANulC Aclu CM 249 MlulAND A 1 37 4931**t *lNING Ht A0tNi eL10010 (CONI AINING 20%- OH- ( M -- - 229 MIOL AND - -- A IS 724 493!740 FUMANYL CHLOHIDE LM 249 MIULAND A 1 IS 693tJ01 AMMUN!uN MYDHOGFN FLUOHIDE SOLUTION CM 229 MIOLAND A 1 15
*4JcJJ9 CHNUNIC FLUOHIDE.50Llu LM 249 M!uLAND A 6 --
--591
*9Jt3*U CHHUMit tLUOHIDE SULullON CM 249 MIDLAND A 25 2 397 493cJet FfhwlC CHLOHlut SULUll0N (IHON CHLUNIDE,
- CM 229 MlulAND A 148 14 211
*93tJ6J FtHdic CnLOHIDE SOLUTION-IIRON CHLOHIDE CH - --249 MIOLAND - - - - -A. .-----1 95 493tJ52 FnuSFMuhuh UAYCHLOwl0L LM 229 MIOLAND A 62 2,0u0
*u3tJ59 enOSPMuhuS 1HICMLuMIDL CM 2t9 M!OLAND A 3 lub
*93tJau SuL>uN CmLOHIDt IMON0 AND DI) LM 229 MI9 LAND A 1 - -- 41 .- - - - - - - -
493cJvJ ZINC CnLowl0E SOLull0N CM 229 MllLAND A le 947 49333tt Olat THYL SULF Alt CM 229 MIVLAND A 4 190
*933332 FIMYL PNOSpHohouS DICHLONIDEeANHYORuuS CM - 229 M]uLAND A --- - 7 --- 275
*9352U0 SuplDM MTOHOAIDE SuLUI1UN (CAubilC S004 CN 229 M10LANu A 2 123 4935210 ALMALINt CORROSIVE HAT 1 THY FLUID CM 229 M10 LAND A 2 24
S E E E $/Ub/bu ****** CutJN A ll - M A H e.t I l r.ii Anis Salt $ - 6% ANNINu ****** +' A b E 8 M A/ AH(Ji)US M A ll H I ALS P.Uld Ht t'teH I PHLIDUCtu FUN S I ON t. ANU ktOSILH NO )t ACllVIIY HY l Y r*t FNLM w t.W U A p* f 1970 IP HU JUNL 1979 L = LOLAle U = OHIblNAllht.e I
- ItWMinA11NU. AND A a 1Mnu HA/. M ".1 L . TYPL OF STCC Numst H btSCRIMil0N UF COMMoo!TY Cout Nuut NUDE NAME THAFFIC CARLOA05 - TONS 6935(20 AL*ALINL LOHkUS!vt LIUUlUom.u.S. (M P/s Mla)L AND A 45 le898 69J5ctj ALnALINL LOHHUS!vt Ll4Ulueh.U.S.t>AlIY LM (/9 M!tiLANU A 1 JO - - - -
4935t(5 PUIASSluM NYCHOAIUt eUHY eSULIbet L AM e LM t/9 M!bLANU A 57 le269
*435cJu VOTA5 SLUM MY UH UJL l ut e L l QU I D (OH) SULUTION (M 249 MIOLANU A 38 2 de3 493St35 500 lum MYDH0XIDLeuwY SOLIUeFLAMEehfADe CM 249 M10 LAND A - --- 14 0 - - 4,355 69J5c60 SUuluM HYOHUAIDL,LIQOlu (UHISULUTION LN 2/9 MlULAND T 1 b*
693Sdeu SOo!UM MYUHU A lut el!401() (UNISULui!ON LM 249 M ! UL A.'.D A 102 8e932 4935t*5 CON"USIVL L!bu!'seN.O.S.tCAUSill SUDA AND (M 2r4 MlOLANU A 1 o 3 - --- - -- 69he% COhMOh!VL SULIDeN.U.S.(LIMC SALTS.NLC) LM 2/9 MIULANU A 1 50 49352$4 SUDIUM MYOHUAIDLouHYeSULlueFLAnleblAueUH LM 229 MlOLAND A 10 852
*93StMU AMMUN!UM MYDH0X1DE (CUNTAINING NOT MORE CM - - - 229 MIULANU -
A- ---- -- 1 1 1o6 6935610 N aMINUllMYLPIPLHAt!NE LM 249 M10 LAND A 2 e2 6915b45 MLAAMLIMYLENE DIAMINE SULUTION CM 2/9 MiULAND A 1.279 116 572 9935665 M D'eu t I M A NUL A M I NL LM c29 M!ULAND A 10 - - -770 ---- --
#93568u ILIwAMLTHYLAHMONIUM MYDHUAIDL, LIQUID LM 229 MIOLAND A 1 96 6936110 bHuma l NE CM 229 MIOLAND A 46 1:391 493b504 Ft AllEHY etLECTHIC S10H AGE ewtTowlTM -
LM - 249 MlOL AND - ---A - - - 37
*93e50* CO*HOS!Vt SULIDeN.O.S.ibAliEHY SETS IN CM 249 MlULAND A 1 20 6 9 3 t>5 )
- COMHOUNboCitANINbellOUID (SMUAE FLUL LM 229 MIDLAND A 2 41 49Jedl5 COMMUUHueCt r Aw!N6ellDulu (LUHHUS! vel LM 229 M!utANU A 27 - - -- 7 0 6 --- -
> 49Jeblb COMPOUNueCLt.ANINbelluulu (CONHOSIVE) LM 229 MlOLANU A 47 b *93b5Je C0p+UUNU,L ACOULH e F AIN I e (UH) VANNiiH CH 2/9 MlULANU A 3 1
53 493b5J9 CUHMUSIVE LIQUIDeN.G.5.(PLTROLtUM - C M -- 229 MlWLANO- - - A - --- 5 430 49305*U CCMHUSIVL LIUUIDeN.O.S. CM 229 MlULAND A 74 4e660
*936545 ConwUSIVt SULlueN.O.S. CM 229 MlVLANU A 16 728
*93e5=o COHHubivt SULlueNeu.5. (LUMPOUNOSe>ATLH LM 229 MIULAND A 1 . --
---32
*93654u CHLMICAL MIT CM 229 MIOLAND A 1 34
*93b355 DYt INTEHMEDIATEeL10UlO CM 229 MIDLAND A 6 411 4936557 tt A T IEHYeLLECTHIC STUH AGE ewe T w l T M - --- C H -- 229 MIOLAND A- - - -- - 3 $3
*s30561 DISINFECIANT,LluulD (COHNUSIVE) CM 249 MIDLAND A 2 42 M. M. Luut SUM 2,552 192 109 695011u 249 M10 LAND A 11 484 495u1Ju 229 MIDLAND A 231 4,169 49501*U -- -- - - - - - --
- 229 M I U L A N D - ---- - A - 119 1e948 4950150 249 MIDLAND A 414 5,066 M. M. Cout SUM 775 11 667 FINAL 101AL5 18 075 le371 7b0 367 MttuMUS TOTAtto ntv0HI PH00uttu uV PHUuMAM 'HAlMAll' ..
,_yp, ,. a _- , - - - - - -----
I I I I I . I I I . I DOMESTIC COMM0DM MOVDENTS AT MILE 35 OHIO RIVER I
- I
!I l I I I l I l l l B-i i
APPENDII B I DONESTIC COMMODITY MOVENENTS AT MILE 35 CALENDAR YEAR 1977
~SHORT TONS TYPE VESSEL COMMODITY 4 101i 4225220.
4 1061 151,837 1091 . 43,253 I 4 4 4 1121 1411 9.317.,069 i,283.552 9,054 4 1442 4 1451 11.645 I 4 1491 231.525 4 1499 61,505 36,541. I 4 -20Ai - 4 2631 3,G75 4 2810 3,780
- 4. __. 2ali =1,400 4 281S .12,000 4 2819 75,864 4 2821 9,136 I 4 2822 S,384 4 2879 13,515 4 29.ia 33t159 4 2920 43,852 I 4 4
4 3011 3241. 3251 98,255 233-3,766 I 4 4 4 3271 3311 3312 112,344 54,403 3,291 4 3314 '70,134 I 4 4 4 3315. 3316 3317 151,723_ 469,773 519,551 140.262 I 4 4 4 3318
~
3319 3321 5 0 ',"a 7 4 10,601 4 3322 21,199
~ -
4 3323' 32 167 4 3324 .12,221 4 3411 56,036
'46,582 I
~
4 3~511 4 3611 3,931 4 3711- 30 4 3911 ~672 4 4011 264,286 4 4012 1,347 4 4029 .107d9d 4 4118 300 T/V TOTAL 13,920,322 5 13.11 46,621., - -. _ B-1
1 l I D OM E S T TC "C O Hit 0 D I T170 V E N E N T S777t IEE 35
~
CALENDAR' YEAR 1977 IYFin/ESSEL COMMODITY SRORT70NS 5 20'14 2,748 3 2810 477871 I -5 5 5 2811 2813 2817' 219,438 138,452 259/752 5 2818 98,345 2819 200,474 I 5 a 2821 39,525 5 2891 7,034 I 5 5 5 2911 2912 2913
.I,008 125 3 0 2 ,'18 T 26,934 899,399 I 5 2
~5 2914 2915 2916 9797f45 362,156 5 2917 95,326 5 29f8 3f3 T418 5 2991 6:281 5 4011 1,344
'T/V TOTil $,134,875 GRAND TOTAL 19,055,197 I
I - I - I - I . I . I . 8-2 - - -
I DOMEST!C CONM00ITY HOVEttENTS A7 HILE 35 CALENDAR YEAR 1978
- ~
TYP'E T/ES'SEL COM.10DITY SHORT TCNS 2 29'4 1 2,4d
'T/V TOTAL 2,417 4 0103 1,267 0111 3,316 I
4-4 10.11 371,_4S.4 4 1351 2,992 4 1061 250,089 I 4-4 4 1091 1121 1442 8,864,944 1,819,392 48.,7_45 21,662 I 4 1_451 4 .1491 310,864 4 .1499 92,815 4 20d1 3.8_f,716 I 4 4 4 2049 2061 2411 1,369 1,610 827 I 4-4 4 2631 2810 2813 7,499 2,400 7,440 4 28i7 f,'7 4 4 I 4 4 4 2318 2819 2871 i 20,400 37,123 87817' I 4 4 4 2879 291.4 2917 3,969 1,,,335
.1,296 4 2918 10,112
- 4 2920 94,797 4 3241 f007737 4 3251 12,673
! 4 3271 174,600 4 3291 30,198 I 4 3311 43,929 4 4,336 l m 3312-1"i7,809 lg 4 4 4 3314 3315 3316 218,430 379,974 'E 4 4317 475,948-
-~
5 4 3318 214,445 4 3319 62,240~ ~ 4 332'1 ~2 T798 4 3322 17,615 4 3323 50,577 j 4 iji4 4,ff5
- E 4 3411 31,201 l5 4 3511 71,,31,8, ,
8-3 __ , , , _ , , , _ _- , , , , , , , _ , _ ,,,_
___a .J I CCHESTIC'~CCNH00!TY MOVEMENTS ~iT HILE 35 CALENDAR YEAR 1978 TYPE ~VESEEL COMMODITi SHORT TCNS' I 4 36il .1,760 4 J731 50 I 4 4 4
-3911 4015 4'012 127 317,180 ff335 4029 2,933 I 4 4 4118 9,00_0
'T/V'TCTAL .i4,375,412 a 106~1 f7422 5 1121 1,636 5 1311 23.028 -
5 f491 17620 5 1499 1,413 5 2014 3,299 a 2810' 33T423 5 2311 264.729 5 2813 129,127 I 3 5 5 2317 2818 2819 205,105' 129,100 310,321 F 2821 - ~697295' I 5 5 a 2,891 2911 2912 7 030 i,007,456 244,778 - I 5 5 a 2913 2914 2915 51,737
, 662,223 17353,'415' 5 2916 357,545 I 5 2
2917 2913 77,903 357~,322
~ ~ ~ - - ~
5 2920 1,516 I 5 a 5 2921 2991 3314 2 452 2Sif15 1,653 I 3315 5 , 1,361 5 3316 17367 5 3317 3.365 5 3318 1,550 a 3324 ~ 17221 5 3411 232 77V T TXL 573717 69 6 4051 1,400 T/V TOTAL 1,400 I GRAND TOTAL B-4 i9,750,598
\ NI WATERBORNE cot."JERCE OF THE UNITED STATES,1978 I
COMMCDITY CLASS!TICAIJON FOR DO.\lESTIC WATERDOANE COMMERCE Co e gg,, y, ,, C e Iten Na me Group 01-Continued Croup 20-Continued 0129 Tield crops, not else.here classified 2041 Wheat finur and semolina 0131 Tresh fruits and tree nuts, except bananas and 2042 Prepared animal feeds p;ar.tains 2049 Grain mill products, not elsewhere classified 0132 Pananas and plantains 206l Sugar I 0133 Coffee, green and roasted 0134 Cocca beans 0141 Tresh and frozen vegetables (including instant) 0151 Live animals illvestocH except zoo animals, cats, dogs, etc. 2062 Mola s se s 2081 Alcoholic beverages 2091 Ve getaSle oils, all g rades : marga rine and shortening 2092 Animal oils and fats, not elsenhere classified, in. cluding marine 0161 Ar.ir-als and a nimal pr oduct s, not elsem be re 2094 Groceries cla s sifie d 2095 tce 0191 %scel:aneoas farm products 2099 Miscellaneous food products Group 08-Torest Products Croup 21-Tobacco Products I 0841 Crade rubber and allied gums 0863 Tc, rest prodacts, not elsewhere clas sified Group 09-Tresh fish and Other Marine Products 2111 Tobac o manufactures Croup 22-Basic Textiles 2211 Easic textile predacts, except te.vtile fibers 0911 Tresh fish, escept shellfish 2212 Temile fibers, not elsewhere clas sified 0912 Shell!:sh, except prepared or preserved 0913 Me na sen Group 23- Apparel and Other Tinished Tevtile 0931 Ma-ir.e shells, ur,manufactu red Products, including Knit Group 10-Metallic Ores 2311 Apparel and other finished textile products, in-cluding lusit 1011 fron ore and concentrates - 1021 Cepper cre and concentrates Group 24-Lumber and Wood Products 10!! Saux.te and other alumism ores and concert utes Except Turniture 1061 Ma .pnese cres and conce.-erates 1991 Mrie rrous snetai ntes and concentrates. not else. 2411 Logs where classified 2412 Rafted logs 2413 Tuel wood, charcoal, and wastes Group 11-Coal 2414 Timbe r, posts, pole s, piling, and other wood in the rough i121 Coal a .d lignite 2415 Pulpwood, log I Group 13-Crude Petroleum 1311 Crude petroleum 2416 Wood chips, staves, moldings, and excelsior 2421 Lumber 2431 Veneer, plywood, at:d other worked wood 2491 Wood manufactures, not elsewhere classified Group 14-Non-neta11tc Minerals, Except Tuels Group 25-Turniture and Tixtures 1411 Limestone f1as and calcareous stone 2511 Turniture ard fixtures 1412 Bailding stone, unworked 1442 Sand, gravel and crushed rock Group 26-Pulp. Pape r and Allied Products 1451 Clay, ceramic ar.d refractory materials I 1471 Phc.sphate rock 1479 Natara! f e r till a e r mat e rials , not els ewhe re 1491 esalt clas sified 14 % Sal;hur, dry 2611 Pulp 2621 Standard newsprint paper 263I Paper ar d pape rboard 2691 Pulp, pape r ar.d pape rboa whe re classified rd products, not else-la?) S, ! phar, liqaid 1494 Cypsu .. c rude and plaste rs Group 27-Printed Matter 1459 2 r.me:allie mme rals, except foels, not else-rhere classified 2711 Trinted matter Group 10-Ordnance and Acces sories Group 28-Chemicals and Allied Products 1911 Ordr.ar ce and accessories 2810 Sodium hydroxide ! caustic sodal 28tl Crude products f rom coal ta r, pa t rolm m, and Group 20-Tood and PCndred Products natural gas, excert benzene and telaene 2812 Dyee, organic pi grwnt, dyeing and tartnir g ~ 2011 Meat, f resh, chilled, or f rozen mate rials 2012 Meat and meat pr or!u ct s prepared or preserved, 2 A 13 Alcohols i r. cl a eg canned meat pro.dacts 2$1f Rad 4uactive and associated mate rials, including 2014 tad *, a-unal f at s and oils wastes 2015 M.n.ai ky -p rocucts, net elsewhe re clas sified 2$17 Penzene and tsluene. c rude and commercialty pure 2021 Da:ry predacts, except dried milk and cream 23!8 Sulphu ric acid 2022 Dried milk a-d c ream 2319 liasic chemicals and ba sic chemical products.not 2031 Tish ard fish p:edacts, including shellfish, pre- elsewhere cla ssified pared or preserved 2821 Plastic materials recenerated cellulose and syn-2034 Vege:aues ard preparations. canned and et erwise thetic resins, including fil m, sheeting, and prepared and preserved f aminates I 203rr T r ust s and fruit and vegetable juices, c anned and e othe rMse prepared or preserved See footeete at end of Com nodity Classification. 2 822 ~ Sy-thetic rubbe r 2823 Synthetic (man. rude) libe r B-5 I
. INTRODUCTION IX CohlhlODITY CLASSIFICATION FCR DOhtESTIC WATEliBORNE COMMERCE C e U item Name ,' Item Name C oup 28-Contmued Group 33-Continued 2831 Drugs (biological products, medicinal chemicals. 3321 Nonferrous me t a l s primary smelter products, botanical p r o d u c t s and p h a r m a c e u t i c a l basic shapes wire. cast:ngs and forgings.except pre pa rationa l copper. lead, sinc and aluminum 2848 ' Soap. detergents, and cleaMag preparations; per- 3322 Copper and copper alloys.whether or not refined, fumes, cosmetics and other toilet preparations unworked 2851 Paints. varnishes, lacquers, enamels, and allied 3323 Lead and ainc including alloys. unworked products 3324 Aluminum and alumir.um alloys. unworked 2861 Gum and vsod chemicals 2871 Nit r o g e n ou s c h e mi c al , fertilize rs, exc ept Group 34-Pabricated Metal Products.
I nueures 2872 Petassic cher-ucal fertilis e rs. e::c e pt mixt ur e s 2673 Phosphatic chemical fe rtilizers, eicept rr.ixtures 2876 Ins e cticitie s , f u a g i e i ci e s , pe stic hd e a , and disinfe ctant a Except Ordnance. Machtnery, and Transportation Equipment 3411 Pabricated metal prc ducts, e a c e pt ordnance, machinery, and transportation eevipment 2879 Tertilizers andiertilizer materials. not elsewhere I clas sified 2691 Miscellanesus chemical preducts Croap 29-Petroleum and Coal Products Group 35-Machinery. Except Electrical 3511 Machinery, except electrical Group 36-Electrical Machir. cry. 2911 Gasolir.e. including natural gasoline Equipment and S. pplies 2012 Jet feel 2913 Kerosene 3611 Electrical machinery, eqMpment and supplies 2914 Dsstillata fael oil 2915 Residual hel oil Group 37-Transportation Eqalpmert 2916 Lu5: .ating oils and greases 2917 Naphtha, mineral s pirits, solvents, not els ew here 3711 Motor vehicles, parts and equipmcet cla s sif:ed 3721 Aircraft and pa rts 2916 Asphalt, t.r. and pitches 3731 shirs and boats 2920 Coke, incladir.g petroleum coke 3791 Miscellaneous transportation ertuipment 2921 Liquefied petroleum gases, coal gase s, n atu r al I gas, ar# natural gas licuids 2951 Asphal: budding materials 2991 Petroleum and coal products, not els ewhe r e clas sified Group 38-Instruments. Phtorrachte and Optical Goods, watches and Clocks 3811 Inst rume nt s, photographic and o p t i c a l good s , watches and clocks I Croup 30-Rubber and Misce!!aneous Plastics Prod. cts Group 39-Miscellaneous Prodac s of Manufacturing 3011 Rubber and miscellaneous plastics products 3911 Miscellaneous products of manafacturing Group 31-Leather ard Leather Products Group 40 Waste and Scrap Mate:.ials 3111 Leather and leather products 4011 1ron and steel scrap 4012 Nonferrnus metal scrap Croap 32-Stone. Clay Class, and 4022 Textile waste, s c r ap. and sweepings Concrete P ' ducts 4024 Faper waste ard scrap 4029 Waste and scrap, net elsewhere classified 3211 Glass ar.d glas s products 3241 Building cement Group 41-Specia! Items 3251 Structs ral clay proScts, includng refractories 2271 Lime 4111 Water 3281 Cut sto-* and stone prodacts 4112 Mis c ella neous s hipme nt a not identifiable by 3291 Mis ce!!ar.evus r.onmetallic r.dre ral predacts commodity 4113 LCL freight Group 33-Prirrary Metal Products 4l18 Materials us ed in m ate rw ay improve ~.ent. Covern. ment materials 3311 Pig iron 9999" De;artment of Defense controlled cargo and spe-3312 Slag cial category items 3333 C Ae (co.1 and petr-leumi. petrolcam pitches and asphalts, a nd r ap'tna and seh e nts
- Statistics on salt in this publicatten are included 3314 Iron ar f steel ingers, and e*he r prima ry forms, s. .th "Nar.r etalhc mine ra! s. exc m fucts , net els e v he re including clanks for tube and pipe , and sponge cla s s ified.' commodity code 10 9, tc a vo;d du elosure iron of individua! company operations.
3315 Iron and steel bars. rods.antles. shaaes and sec. " tiens, inc h.diep sheet pihr g Ca r t oe s e spo rtu! on De. pa r trr.e r.t c.f D< fe r.s e con-3316 Iron and steel plates and sceets trolled vessels (other than gouds for 'he e s e c f 11. S. 3317 Iren and secci pipe and tube Armed Forces stroad) a r4 non- Depa rt:r ent ci Defense 3318 Te r toalloys shipments of military en.poner.! : errs .a r.br eviatec SCL) 3319 Primary iron and steel products, not elsewhere for v hich ccmmodsty detad to not furnished to the Corps classified, including castin;s in the rough cf Ergir.ee rs. I B-6
_-.m .- - --- - I I , I I I I I ursso1xc g
, s10. & m srsa . vires. x0ost I
I I I I I I I I " I
> / APPENDIX C STONE & WEBSTER " VAPOR" MODEL I The Stone & Webster Engineering Corporation (S&W) computer program used tpf calculate the time history of toxic vapor ccncentratio~ns in the control' room as a result of a toxic chemical spill, is based on tbc methodology described in NUREG-0570, " Toxic Vapor Concentrations in the Control Room Following a Postulated Accidental Release." ' ~ In a postulated accident, the entire contente of the largest single storage container is released resulting in a toxic vapor cloud and/or plume which is conservatively assumed to be transported by the wind directly toward the , control room intake. The formation of the toxic cloud or plume is depencNnt ,3 upon both the chemical nature of the release and the ambient environmental I characteristics. The entire amount of a chemical stored as a gas is treated as a puff or cloud which has a finite volume determined from the quantit 3- ( and density of the stored chemical. A toxic substance stored as a liquid-with a boiling point below the ambier.t temperature forms an instantaneous ~ puff due to flashing (rapid gas formation) of some fraction of the quantity , stored. The remaining liquid forms a puddle which quickly spreads into a
~
thin layer on the ground, subsequently vaporizing and forming a ground-level vapor plume. A liquid that has a boilink ~peint above the ambient temperature g forms a puddle which evaporates by torced convection renalting in a ground-5 level plume with no flashing involved. In all casen the puff snd/5r ., ground-level plume is dispersed by at.mospharic turbulem e as it is trans-ported by the wind toward the control room intake. ,- In the evaluation of liquid spills, the vaporizatica or evatioration lif the spill is a function of its surface area. This area is estimated by assuming that the initial shape of the spill is in the form of a cylinder with the-height equal to the radius of the base. The surface nrsa can then bs calculated by the following equation: A(t) = n {r g2 + 2t [gV, (p - p)] } (C-1) n P1 l I C-1
^
- z. ,
[ uhe're : A = surface area of the spill (cm 2) I
~
ct . = initial radius of the spill (cm) g = gravitational acceleration (cm/sec z) V = volume of the spill sfter flashing (cm 3) I', p p
= density of the liquid (g/cm 3)
= density of air (g/cm 3) t = time (sec) 3 The area does not e::pand indefinitely but reaches a maximum size depending on the vaporization or evaporation rate. Since the contour of the ground cannot normally be well described, the maximum surface area is conventional-ly calculated by assuming a spill thickness of I cm.
Spills involving liquius with boiling points below the ambient tamperature produce an instantaneous puff release with the mass given by the following I- - heat balance equation:
~
MCp (T a -T)=M H (C-2) .W b vo v where:
'M = total initial mass of the liquid (g)
I> C = heat capacity of the liquid (cal /g C) TP = ambient temperature ( C) T* = normal boiling point of the liquid ( C)
'M: = mas; of flashed liquid (g)
H" e heat 1of vaporization of the liquid (cal /g) For compressed gases such as liquid nitrogen or helium, T, is set equal to the actual storage temperature of the liquid. J W The remaining liquid in the low-boiling point spill vaporizes by absorption of heat from long-wave atmospheric radiation, short-wave solar radiation, convection of air, and ground conduction. The value of the atmospheric and solar radiation flux (g ) isr conservatively assumed to be 275 cal /m -sec 2 which is the . highest noon value occurring on June 1 and July 1 at a latitude of 30 N. The heat flux due to forced convection (q ) is calculated using c the following relationship: I,- N ' c.,
& - ~
+ !
b
4 I . I- - qc =hc (T a-Tb ) (C-3) vhere: hc = heat transfer coefficient determined to be 1.6 cal /m a-sec- C at a wind speed of 1 m/sec. Heat transfer due to conduction from the earth's surface (qd) is calculated according to the expression: I ' ( qd ( e~ b lI where:
! T, = ground temperature ( C) assumed to be the same as the air tempera-
. ture l The vaporization rate of the liquid (dm /dt) can then be determined f rom the total heat transfer to the liquid according to the following equation:
dm v= A(t) [qr +hc (T a-Tb) + 197 (Te-Tb )/tb] (C-5) 7 dt H v The spill of the liquid with a boiling point above the ambient temperature evaporates by forced convection when exposed to the wind, forming a ground- / - level plume. In this case, an evaporation rate is calculated using the formula: I dM v /dt = hd M A(t)(P s -Pa)(T + 273) (C-6)
)
E where: 4 , h . (/ e c (cm/sec) d M = molecular weight (g/ mole) P = saturation vapor pressure at T s P = actual vapor pressure of the liqu(mm of Hg) id (mm of Hg) Re = Reynold's number = LU p/p Sc = Schmidt number = p/DP 4 C-3
I L = characteristic length (cm) g = density of air (g/cm 3) u = mean wind speed (cm/sec) I p D
= viscosity of air (g/cm-sec)
= diffusion coefficient (cm2 /sec)
The value of the parameter L is chosen to be the diameter of the spill area A(t) which decreases with time as the liquid evaporates. If the diffusion I coefficient D is not known for a particular substance, a value of 0.2 cm2 /sec is used. Given the amount of a toxic substance released as a puff and the emission rate from a spill, the downwind concentration due to dispersion by atmospheric turbulence is calculated by assuming that the material is distributed in the puff or plume in a Gaussian manner. For an instantaneous puff release with an initial finite volume, the chemical concentration in the puff is described by the following equation: I X(x, y, z, h) =
- exP I-h(X2 + ya ))
U U U (2n) ! xI yI zI xI yl
*{exp[- (z-h)2} + exp[- (z+h)2]} (C-7)
I f2 zI g zI 2 where: X = concentration (g/m 3) 1 Q = source strength (g) l "xI, yI, zI = adjusted standard deviations of puff concentration in l the downwind (x), crosswind (y), and vertical (z) directions from the puff center respectively (m) j h = height of source above ground (m) l The initial volume of the puff is accounted for by adjusting the standard deviations of concentration in the following manner: lI U
=
U + U o xI xI (C-8) l 5 g a yI 2
=
a yI 2 + a o 2 l o 2 zI = g zI a+ g o 2 I I
I o 2 g 2 xI = yI where:
' ~~ i
, o =
o [il2h 3/2 yo 4 pV)j /3(,) py = density of the plume (g/cm 3) The value of x in the exponential term of (C-7) is determined by: x=x 9
-Ot (C-9) where x, is the distance between the source of the spill and the receptor.
The diffusion equation for a continuous ground-level plume release is given by: lI X(x, y, z, h) = Q' exP I-h(y*)} 2nu o o a 2 y z y
-{exp[- (z-h)2} + exp[- (z+h)2]} (C-10) 2 iI o a 2 z z where:
I Q' = continuous source strength (g/sec) o,o =* standard deviations of plume concentration in the y and z Y directions respectively The finite inigial2 size of the spill is accounted for by replacing a with Y (o y2 + oyo ) , where o yo is approximated by: I a Yo i 2 n*/4.3 and r is the radius of the spill. The values of the dispersion coefficients I (o and o ) *in (C-7) and (C-10) are taken from the Pasquill-Gifford curEes. I The concentration (C,) of a toxic substance outside the control room at the air intake vent can now be determined from the combination of the puff and
, ground-level plume concentrations at time t., according to:
l C,(tj) = MV9 (puff)(X/Q)tj+ (dM y/dt)tg (plume)(X/Q') (A-12) The concentration inside the control room (Cr) t time t is calculated by: Cr ('i) = C (tj -1) + [C,(t g) - C (t -1)][1-exp(-Wat/Vc)] (A-13) f I C-5 I
I where: W = control room ventilation rate (m 3/sec) I V AE
= control room volume (m )3
= calculational time step (t. - t.
t 1-1) The habitability of the control room is evaluated by comparing the calcu-lated chemical concentrations inside the control room with known human I toxicity limits. These limits are determined to be the lowest concentration of a chemical that could interfere with an operator's ability to function properly and are obtained from Regulatory Guide 1.78 and other appropriate references. The control room is considered to be uninhabitable when toxic limits are exceeded by estimates of control room concentration. I The input data required for the program include the chemical's physical properties, control room parameters, meteorology, distance from the spill to the control room intake, quantity of chemical released, and toxicity limits. I For chemicals stored as gases, the only physical parameter needed is the density of the gas. For low-boiling point liquids, the boiling point, puff density, heat of vaporization, specific heat and liquid density are required as input. The assessment of normal boiling point liquids requires the liquid density, molecular weight, saturation vapor pressure, and diffusion coefficients as inputs to the analysis. I I I I I I I C-6
4 s - --a - es..w - m-___ __ _,, . - - - ---- i
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!I APPENDIX D I DEMONSTRATION OF CHEMICAL CONCENTRATION AND PROBABILITY CALCULATION PROCEDURES I
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I APPENDIX D [ DEMONSTRATION OF CHEMICAL CONCENTRATION AND PROBABILITY CALCULATION PROCEDURES I . Ref. I A. BVPS - Unit 2 Control Room Parameters Used
- 1. Control room air space - 59,000 ft2 (1,671 m 3)
- 2. Ventilation rate - 200 ft / 3min (0.094 m 3/sec)
B. Meteorological Condition Assumed (worst case) (1)
- 1. Wind speed - 0.5 m/sec j
I 2. Stability class - G
- 3. Temperature - 40 C I 4. Wind direction - oriented to directly impact the control room intake C. Chemical Sources
- 1. Onsite (example: ammonium hydroxide)
I a. Largest single container - 415 gal (4.1 x 105 g) (represents 29 percent solution of ammonia) I b. Distance from intake - 200 ft (61 m)
- c. Chemical properties I liquid density - 0.9 g/cm 3 l (6)
I D-1
!I 1 1 vapor pressure - 1,070 mm of Hg (7) ! l molecular weight - 35.1 g/ mole (6) a !. diffusion coefficient - 0.2 cm 2/sec (1) l t i toxic limit - 0.03 g/m 3 (4) l 2. Arco Polymers, Inc. (example: toluene) !I a. largest single container - 5,000 tons (4.5 x 109 g) (9) I b. distance from intake - 7,320 m (8) I c. Chemical properties liquid density - 0.866 g/cm 3 (1) vapor pressure - 55 mm of Hg (1) molecular weight - 92.1 g/ mole (1) diffusion coefficient - 0.092 cm 2/sec I (1) toxic limit - 0.8 g/m 3 (3)
- 3. Bruce Mansfield Station (example: sulfuric acid)
I a. largest single container - 20,000 tons (1.39 x 108 g) (10) I b. distance from intake - 3,050 m (8) I c. Chemical properties liquid density - 1.83 g/cm 3 (1) I D-2 I
I vapor pressure - 0.001 mm of }{g
- molecular weight - 98.1 g/ mole (1) diffusion coefficient - 0.2 cm 2/sec (1) toxic limit - 0.001 g/m 3 (3)
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- 4. Conrail (example: chlorine)
- a. amount transported - 60 tons (5.43 x 107 g) App. A I b. distance from intake - 648 m (8)
- c. Chemical properties
! vapor density - 2.49 x 10' g/cm 3 (1) l boiling point - -34.1 C (1) heat of vaporization - 68.8 cal /g (1) l I specific heat - 0.226 cal /g C (1) toxic limit - 0.045 g/m 3 (2) I 5. Barge (example: naptha)
- a. amounted transported - 4,500 tons (4.10 x 109 g) (11)
I b. distance from intake - 240 m (8) I c. Chemical properties liquid density - 0.60 g/cm 3 (5) I D-3
I vapor pressure - 134 mm of Hg (5)
- molecular weight - 78.lg/ mole (5) diffusion coefficient - 0.2 cm 2/sec (1) toxic limit - 0.4 g/m 3 (4)
I D. " VAPOR" program input and output (see attached printout)
- 1. First page contains a printout of input variables used.
I 2. Remaining pages contain outside and inside chemical concentrations as a function of time. E. Chemical concentration plots (see attached Figures D-1 through D-5) l 1. Vertical axis is chemical concentration in g/m3 on a logarithmic scale
- 2. i arizontal axis is elapsed time af ter the postulated accident
- 3. Thin line represents the outside chemical concentration (g/m 3)
- 4. Thicker line represents the inside control room concentration (g/m3 )
F. Probability Calculation I 1. Onsite chemical (not applicable) i 2. Arco Polymers, Inc. (toluene exceeds toxic limit) l lI l I D-4
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- a. Accident event probability - 10 event /yr (NRC - suggested value for storage tanks personal communication with Mr. Ken Murphy during 2/81)
I b. Wind direction range calculation: a plume width of i2 standard deviations (o ) for a G-stability plume is assumed the toluene concentration anywhere within this plume width is conservatively assumed to cause a habitability problem I the width of this plume at a distance of 7,320 m (distance from source to intake) is calculated to be 616 m (40 or 4 x 154 m) based on Pasquill-Gifford dispersion coefficients. drawn on a 7.5-minute U.S.G.S. map of the site area, this plume is determined to make contact with the intake for wind directions of 59 -65 azimuth. I c. Wind direction frequency for the sector bounded by 59-65 azimuth - 0.020 (based on 1976-1978 onsite meteorological data at 35 ft level)
- d. Probability calculation:
_4 _6 10 event /yr x 0.020 = 2 x10 event /yr I 3. Bruce Mansfield I - No chemical is determined to cause a habitability problem. Therefore, the probability is not calculated I i D-5
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- 4. Conrail (chlorine exceeds toxic limit)
- a. Accident event probability - 1.5 x 10 ~9 event / vehicle mile (from WASH-1238 for railroad accidents)
I b. Shipment frequency - 16.7/yr (25 x 12 months /18 months - see Appendix A) I Cc,nrail node report for 18-months period:
- c. Track length within 5 miles of the site (from 7.5 minute U.S.G.S. maps):
Upwind Sector - NE NNE N NNW NW WNW W WNWk Track - Length (mi) 3.25 1.41 0.32 0.18 0.19 0.34 0.75 4.24
- d. Wind direction frequency (1976-1977 onsite data at 35 ft level)
I Upwind Sector - NE NNE N NNW NW WNW W WNW I Frequency (%) - 4.1 3.3 5.2 3.5 4.4 4.1 7.7 4.1 I e. Probability calculation (product of factors a-d): I Sector Probability (event /yr) NE 1.5 x 10 ~9 event /mi x 16.7 cars /yr x 3.25 mi x .041 = 0.333 x 108 NNE 1.5 x 10 ~9 event /mi x 16.7 cars /yr x 1.41 mi x .033 = 0.116 x 108 D-6
I N 1.5 x 108 _ event /mi x 16.7 cars /yr x 0.32 mi x .052 = 0.416 x 10 9 I NNW 1.5 x 109 event /mi x 16.7 cars /yr x 0.18 mi x .035 = 0.158 x 109 I NW 1.5 x 109 event /mi x 16.7 cars /yr x 0.19 mi x .044 = 0.209 x 109 WNW 1.5 x 109 event /mi x 16.7 cars /yr x 0.34 mi x .041 = 0.349 x 109 W 1.5 x 109 event /mi x 16.7 cars /yr x 0.75 mi x .077 = 0.144 x 108 WNW* 109 event /mi x 16.7 cars /yr x 4.24 mi x .041 = 0.4351.5 x_8 x 10 TOTAL = 0.114 x 107 (see Table 5)
- 5. Barge (naptha exceeds toxic limit)
- a. Accident event probability - 1.6 x10 9 event / vehicle mile (from WASH-1238 for barge accidents)
- b. Shipment frequency - 60/yr (86,615 tons /yr + 1,450 tons /
vessel = 60 vessels /yr: average of tonnage shipped for years 1977 and 1978 from Appendix B, commodity 2917)
- c. River length assumed to be the same as track length (see Section 4c)
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- d. Wind direction frequency is the same as given in section 4d
- e. Probability calculation (product of factors a-d):
Sector Probability (event /yr) I NE 1.6 x 109 _ event /mi x 60 vessels /yr x 3.25 mi x .041 = 0.128 x 10 7 l NNE 1.6 x 109 event /mi x 60 vessels /yr x 1.41 mi x .033 = 0.447 x 10 8 I D-7 I
I N 1.6 x 109 , event /mi x 60 vessels /yr x 0.32 mi x .052 = 0.160 x 10 8 NNW 1.6 x 109 _ event /mi x 60 vessels /yr x 0.18 mi x .035 = 0.605 x 10 9 4 l NW 1.6 x 109 event /mi x 60 vessels /yr x 0.19 mi x .044 = 9 O.803 x 10 1.6 x 109 event /mi x 60 vessels /yr x 0.34 mi x .041 = I WNW , 8 , 0.134 x 10 W 1.6 x 109 event /mi x 60 vessels /yr x 0.75 mi x .077 = 0.554 x 108 WNW* 1.6 x 109 event /mi x 60 vessels /yr x 4.24 mi x .041 = 0.167 x 107 TOTAL = .438 x 10~7 (see Table 6) I
- Track and river lengths for WNW sector are presented twice due to the bend in the river which causes it to pass through this sector at two ,
different locations. 4 i a I I I iI e-e
I REFERENCES FOR APPENDIX D
- 1. NUREG-0570: " Toxic Vapor Concentrations in the Control Room Following a Postulated Accidental Release." U.S. Nuclear Regulatory Commission, June 1979.
- 2. U.S. Atomic Energy Commission, Regulatory Guide 1.78, " Assumptions for I Evaluating the Habitability of a Nuclear Power Plant Control Room During a Postulated Hazardous Chemical Release, June 1974.
- 3. Patty, F.A. (ed.), " Industrial Hygiene and Toxicology," Vols. I and II.
Interscience Publishers, New York, 1958, 1963, and 1978.
- 4. Documentation of the Threshold Limit Values for Substances in Workroom Air with Supplements, American Conference of Governmental Industrial Hygienists, Cincinnati, OH, Vol. 3, 1971.
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- 5. The International Technical Information Institute, " Toxic and Hazardous Industrial Chemicals Safety Manual for Handling and Disposal with Toxicity and Hazard Dat.:," Tokyo, Japan, 1979.
I 6. Letter to E. Puch (S&W) from J. Salah (Allied Chemical, P.O. Box 1087R, Morristown, N.J.) dated 4/7/81
- 7. Perry, R. H. and Chilton, C. H., Chemical Engineer's Handbook, 5th Ed.,
McGraw Hill Book Co., 1973.
- 8. U.S. Geological Survey 7.5 minute topographic maps, Midland and Beaver quadrangles.
- 9. Letter to E. G. Nelson (S&W) from B. J. Knauff (Arco Polymers, Inc.)
I dated 2/12/79. I D-9
i j 10. Letter to E. G. Nelson (S&W) from D. R. Billheimer (Pennsylvania Power ! Company) dated 12/18/78. i
- 11. Letter to E. G. Nelson (S&W) from W. H. Combs (Department of the Army) dated 6/13/78).
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M M M M M M M M M - M TOXIC CHEHICALane At0f0MIUH HYDR 0x *** SOURCE: ONSITE CHEHICAL TYPE : HIGH BOILING POINT STABILITY CLASS : G APPROX. NUttBER OF DATA POINTS : 350 INCREHENT OF OUTPUT REQUESTS : 100 TEMPERATURE (C) : 4.000E+01 HIND SPEED (H/SEC) : 4.900E-01 RECEPTOR HEIGHT (H) : 0.0 SOURCE HEIGHT (H) : 0.0 LIQUID DENSITY (G/CC) : 9.000E-01 VENT FLCH RATE (CitS) : 9.440E-02 i CONTROL R00f t AIR SPACE (H3) : 1.671E+03 SUBSTAttCE INITIAL HASS (G) : 4.100E+05 RECEPTOR DISTAriCE (H) ' d.100E+01 CENTERLINE DISTANCE (H) : 0.0 LIttIT NAttE LIHIT VALUE T0XIC LIMIT 3.000E-02 (G/H3) SAT. VAP. PRE?S. AT TA (HH HG) : 1.070E+03 DIFFUSION COEFFICIENT (CH2/S) : 2.000E-01 HOLECULAR HEIGHT (G/HOL) : 3.510E+01 TIHE REQUIRED (SEC) TO REACH THE HAX SPILL AREA IS 5.97 f
W W W M- M W M M M m C0llPUTED CONCENThaTIONS FROH TIHE Tm 0.0 (SECS) TO TIME Ta 5.338E+05 (SECSI DATA POINT TIME ARRAY HAXIHUH CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION NUH3ER (SECS) (GH/H3) (GVH3) (GH/H3) 1 0.0 0.0 0.0 0.0 2 124.5 2.123E+00 2.123E+00 1.488E-02 3 126.4 2.426E+01 2.426E*01 1.750E-02 4 128.3 3.971E+01 3.971E*01 2.186E-02 5 130.3 5.204E+01 5.204E+01 2.766E-02 6 130.5 5.281E+01 5.281E+01 2.806E-02 7 132.5 5.274E+01 5.274E+01 3.404E-02 8 134.5 5.271E+01 5.271E+01 4.010E-02 9 136.6 5.268E*01 5.268E+01 4.625E-02 10 138.7 5.265E+01 5.265E+01 5.249E-02 11 140.8 5.263E*01 5.263E+01 5.882E-02 12 143.0 5.260E+01 5.260E*01 4.525E-02 13 145.2 5.257E+01 5.257E+01 7.177E-02 14 147.4 5.254E+01 5.254E+01 7.839E-02 15 149.7 5.251E+01 5.251E+01 8.510E-02 16 152.0 5.248E+01 5.24SE+01 9.191E-02 17 154.3 5.245E+01 5.245E+01 9.882E-02 18 156.7 5.242E+01 5.242E+01 1.058E-01 19 159.1 5.238E+01 5.238E+01 1.129E-01 20 161.5 5.235E+01 5.235E*01 1.202E-01 21 164.0 5.232E+01 5.232E+01 1.275E-01 22 166.5 5.229E*01 5.229E+01 1.349E-01 23 169.1 5.225E*01 5.22SE+01 1.425E-01 t3 24 171.7 5.22P'+01 5.222E+01 1.501E-01
- 3. 25 174.3 5.218E+01 5.218E+01 1.579E-01 h) 26 177.0 5.215E+01 5.215E+01 1.657E-01 27 179.7 5.211E+01 5.211E+01 1.737E-01 28 182.5 5.208E*01 5.208E+01 1.818E-01 29 185.3 5.204E+01 5.204E+01 1.901E-01 30 188.2 5.200E+01 5.200E*01 1.984E-01 31 191.1 5.496E+01 5.196E+01 2.069E-01 32 194.0 5.192E*01 5.192E+01 2.154E-01 33 197.0 5.189E+01 5.189E*01 2.242C-01 34 200.0 5.185E+01 5.185E+01 2.330E-01 35 203.1 5.181E+01 5.181E+01 2.419E-01 36 206.2 5.176E+01 5.176E+01 2.510E-01 37 209.4 5.172E+01 5.172E+01 2.603E-01 38 212.6 5.168E*01 5.168E+01 2.696E-01 39 215.9 5.164E+01 5.164E+01 2.791E-01 40 219.2 5.159E+01 5.159E+01 2.887E-01 41 222.5 5.155E+01 5.155E+01 2.985E-01 42 226.0 5.151E+01 5.151E+01 3.084E-01 43 229.4 5.146E+01 5.146E+01 3.184E-01 44 233.0 5.141E+01 5.141E+01 3.286E-01 45 236.6 5.137E+01 5.137E+01 3.389E-01 46 240.2 5.132E+01 5.132E+01 3.494E-01 47 243.9 5.127E+01 5.127E+01 3.600E-01 48 247.6 5.122E+01 5.122E*01 3.708E-01 49 251.4 5.117E*01 5.117E+01 3.817E-01
M M '^ W M M M & M M M M M ' M M- M M M COMPUTED CCNCENTRATIONS FRON TIME T= 0.0 (SECS) TO TIME T= 5.338E+05 (SECS) DATA POINT TIME ARRAY HAXIMUtl CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION te.RtBER (SECSI ( Gt1/H3 ) ( Gtt/fl3 ) (GIVH3) 50 255.3 5.112E*01 5.112E+01 3.928E-01 51 259.2 5.107E+01 5.107E+01 4.040E.01 52 263.2 5.102E+01 5.102E+01 4.154E-01 53 267.3 5.097E+01 5.097E+01 4.270E-01 54 271.4 5.091E+01 5.091E+01 4.387E-01 55 275.6 5.086E+01 5.086E+01 4.506E-01 56 279.8 5.080E+01 5.080E+01 4.627E-01 57 284.1 5.075E+01 5.075E+01 4.749E-01 58 288.5 5.069E*01 5.069E+01 4.873E-01 59 292.9 5.063E*01 5.063E+01 4.998E-01 60 297.4 5.058E+01 5.058E+01 5.126E-01 61 302.0 5.052E*01 5.052E+01 5.255E-01 62 306.6 5.046E+01 5.046E+01 5.386E-01 63 311.3 5.040E+01 5.040E+01 5.519E-01 64 316.1 5.033E+01 5.033E+01 5.653E-01 45 321.0 5.027E+01 5.027E+01 5.790E-01 66 325.9 5.021E+01 5.021E+01 5.928E-01 67 330.9 5.014E+01 5.014E+01 6.069E-01 68 336.0 5.008E+01 5.008E+01 6.211E-01 69 341.2 5.001E+01 5.001E+01 6.355E-01 70 346.4 4.994E+01 4.994E+01 6.501E-01 71 351.8 4.987E+01 4.987E+01 6.649E-01 72 357.2 4.980E+01 4.980E+01 6.799E-01 e 73 362.7 4.973E+01 4.973E+01 6.952E-01 8 74 368.2 4.966E+01 4.966E+01 7.1C6E-01 d 75 76 373.9 379.6 4.959E+01 4.959E+01 7.262E-01 4.952E+01 4.952E+01 7.421E-01 77 385.5 4.944E+01 4.944E+01 7.5P1E-01 78 391.4 4.937E+01 4.937E*01 7.744E-01 79 397.4 4.929E+01 4.929E*01 7.909E-01 80 403.5 4.921E+01 4.921E+01 8.076E-01 81 409.7 4.913E+01 4.913E+01 8.245E-01 02 416.0 4.905E+01 4.905E+01 8.417E-01 83 422.4 4.897E*01 4.897E+01 8.591E-01 84 428.9 4.889E+01 4.889E+01 8.767E-01 85 435.5 4.880E+01 4.880E+01 8.946E-01 86 442.2 4.872E+01 4.872E+01 9.127E-01 87 449.0 4.863E+01 4.863E*01 9.310E-01 88 455.9 4.855E+01 4.855E+01 9.496E-01 89 462.9 4.846E+01 4.846E*01 9.684E-01 90 470.1 4.837E+01 4.837E+01 9.874E-01 91 477.3 4.828E+01 4.828E+01 1.007E+00 92 484.6 4.818E+01 4.818E+01 1.026E+00 93 492.1 4.809E+01 4.809E+01 1.046E+00 94 499.6 4.799E+01 4.799E+01 1.066E+00 95 507.3 4.790E*01 4.790E+01 1.087E+00 96 515.1 4.780E+01 4.780E+01 1.107E+00 97 523.1 4.770E*01 4.770E+01 1.128E+00 98 531.1 4.760E+01 4.760E+01 1.149E*00 99 539.3 4.750E+01 4.750E+01 1.170E+00
m m m M M M M M M M M m m m m m a COMPUTED CONCENTRATIONS FROH T1HE Tm 0.0 (SECS) TO TIME T 5.338E+05 (SECS) DATA POINT TIME ARRAY HAXDfuH CONCENTRATION OUTSIDE CO'fCENTRATION INSIDE CONCENTRATION NUHBER ISECS) (GH/H3) (GH/H3) ( GH/l(31 100 547.6 4.739E+01 4.739E+01 1.192E+00 101 556.0 4.729E+01 4.729E+01 1.214E+00 102 564.5 4.718E+01 4.718E+01 1.236E+00 103 573.2 4.707E+01 4.707E+01 1.259E+00 104 582.0 4.696E+01 4.696E+01 1.281E+00 105 591.0 4.685E+01 4.685E+01 1.304E.00 106 600.1 4.674E+01 4.674E+01 1.328E+00 107 609.3 4.663E+01 4.663E+01 1.351E+00 108 618.6 4.651E+01 4.651E+01 1.375E+00 109 628.2 4.639E+01 4.639E+01 1.399E+00 110 637.8 4.627E+01 4.627E+01 1.424E+00 111 647.6 4.615E+01 4.615E+01 1.449E+00 112 657.6 4.603E+01 4.603E+01 1.474E+00 113 667.7 4.591E+01 4.591E+01 1.499E+00 114 678.0 4.578E+01 4.578E+01 1.525E+00 115 688.4 4.565E+01 4.565E+01 1.551E+00 116 699.0 4.552E+01 4.552E+01 1.577E+00 117 709.7 4.539E*01 4.539E+01 1.604E+00 118 720.6 4.526E+01 4.526E+01 1.631E+00 119 731.7 4.512E+01 4.512E+01 1.658E+00 120 743.0 4.499E+01 4.499E+01 1.685E+00 121 754.4 4.485E+01 4.485E+01 1.713E+00 y 122 766.0 4.471E+01 4.471E+01 1.741E+00 a 123 777.8 4.451Ee01 4.457E+01 1.770E+00 D 124 789.7 4.4 4.2 E + 01 4.442E+01 1.799E+00 125 801.9 4.428E+01 4.428E+01 1.828E+00 126 814.2 4.413E+01 4.413E+01 1.857E+00 127 826.7 4.390E+01 4.398E+01 1.887E+00 128 839.4 4.383E+01 4.383E+01 1.917E+00 129 852.3 4.367E+01 4.367E+01 1.948E+00 130 865.5 4.352E+01 4.352E+01 1.978E+00 131 878.8 4.336E+01 4.336E+01 2.010E+00 132 892.3 4.320E+01 4.320E+01 2.041E+00 133 906.0 4.304E+01 4.304E+01 2.073E+00 134 919.9 4.287E+01 4.287E+01 2.105E+00 135 9,4.1 4.271E+01 4.271E+01 2.137E+00 136 948.4 4.254E+01 4.254E+01 2.170E+00 137 963.0 4.237E+01 4.237E+01 2.203E+00 138 977.8 4.219E+01 4.219E+01 2.237E+00 139 992.9 4.202E+01 4.202E+01 2.270E+00 140 1008.1 4.184E+01 4.184E*01 2.304E+00 141 1023.6 4.166E+01 4.166E+01 2.339E+00 142 1039.4 4.148E+01 4.148E+01 2.374E+00 i 143 1055.3 4.129E+01 4.129E+01 2.409E+00 144 1071.6 4.111E+01 4.111E+01 2.444E+00 145 1088.1 4.092E+01 4.092E+01 2.480E+00 146 1104.8 4.073E+01 4.073E+01 2.516E*00 147 1121.8 4.053E*01 4.053E+01 2.553E+00 148 1139.0 4.034E+01 4.034E+01 2.590E+00 l 149 1156.5 4.014E+01 4.014E+01 2.627E+00 1
m W W W M m M M M M M m W W W m m m COHPUTED CONCENTRAT10ttS FROH TIME Tm 0.0 (SECS) TO TIHE Tm 5.338E+05 (SECS) DATA POINT TIME ARRAY HAXIHUH CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION NtA!BER (SECS 1 ( CtVH3 ) (GH/H3I ( GIVH3 ) ISO 1174.3 3.994E*01 3.994E+01 2.664E+00 151 1192.4 3.973E+01 3.973E+01 2.702E+00 152 1210.7 3.953E+01 3.953E+01 2.740E+00 153 1229.3 3.932E+01 3.932E+01 2.779E+00 154 1248.2 3.911E+01 3.911E+01 2.817E*00 155 1267.4 3.889E+01 3.889E+01 2.856E+00 156 1286.9 3.868E+01 3.868E+01 2.896E+00 157 1306.7 3.846E*01 3.846E+01 2.936E+00 158 1326.8 3.824E+01 3.824E+01 2.976E+00 159 1347.2 3.801E*01 3.801E+01 3.016E+00 160 1367.9 3.778E+01 3.778E*01 3.057E+00 161 1388.9 3.756E+01 3.756E+01 3.098E+00 162 1416.3 3.732E+01 3.732E+01 3.139E+00 163 1432.0 3.709E+01 3.709E+01 3.180E+00 164 1454.0 3.685E+01 3.685E+01 3.222E+00 165 1476.4 3.661E+01 3.661E*01 3.264E+00 166 1499.1 3.637E+01 3.637E+01 3.307E+00 167 1522.1 3.612E+01 3.612E+01 3.350E+00 168 1545.5 3.588E+01 3.588E+01 3.393E+00 169 1569.3 3.562E+01 3.542E+01 3.436E+00 170 1593.4 3.537E+01 3.537E+01 3.479E+00 171 1617.9 3.511E+01 3.511E+01 3.523E+00 p 172173 1642.8 1668.1 3.486E+01 3.459E+01 3.486E+01 3.567E+00 g 3.459E+01 3.611E*00 (n 174 1693.7 3.433E+01 3.433E+01 3.656E+00 175 1719.8 3.406E+01 3.406E*01 3.701E+00 176 1746.2 3.379E+01 3.379E+01 3.745E+00 177 1773.1 3.352E+01 3.352E+01 3.791E+00 178 1800.3 3.324E+01 3.324E+01 3.836E+00 179 1828.0 3.297E+01 3.297E+01 3.881E+00 180 1856.1 3.269E+01 3.269E+01 3.927E+00 181 1884.6 3.240E*01 3.240E+01 3.973E+00 182 1913.6 3.212E+01 3.212E+01 4.019E+00 183 1943.1 3.183E+01 3.183E+01 4.065Ee00 184 1972.9 3.153E+01 3.153E+01 4.112E+00 185 2003.3 3.124E+01 3.124E+01 4.158E+00 186 2034.1 3.094E+01 3.094E+01 4.205E+00 187 2065.4 3.064E+01 3.064E+01 4.251E+00 188 2097.1 3.034E+01 3.034E+01 4.298L+00 189 2129.4 3.004E+01 3.004E*01 4.345E+00 190 2162.1 2.973E+01 2.973E+01 4.392E+00 191 2195.3 2.942E+01 2.942E+01 4.439E+00 192 2229.1 2.911E+01 2.911E+01 4.486E+00 193 2263.4 2.879E+01 2.879E+01 4.533E+00 194 2298.2 2.847E+01 2.847E+01 4.580E+00 195 2333.5 2.815E+01 2.815E+01 4.627E+00 196 2369.4 2.783E+01 2.783E+01 4.674E+00 197 2405.8 2.751E+01 2.751E*01 4.721E+00 198 2442.8 2.718E+01 2.718E+01 4.768E+00 199 2480.4 2.685E+01 2.685E+01 4.815E+00
M M M M M M M M M M M M M M M M M m e COMPUTED CCHCENTRATIONS FROH TIME T= 0.0 (SECS) TO TIME Tm 5.338E+05 (SECS) DATA POINT TIME ARRAY HAXIHUH CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION NUMBER tSECS) tGH/H3) tGH/H3) tGH/H3) 200 2518.5 2.652E+01 2.652E+01 4.861E+00 201 2557.3 2.618E+01 2.618E+01 4.908E*00 202 2596.6 2.585E+01 2.585E+01 4.954E+00 203 2636.5 2.551E+01 2.551E+01 5.001E+00 204 2677.1 2.517E+01 2.517E+01 205 5.047E+00 2718.2 2.483E+01 2.483E+01 5.093E+00 206 2760.0 2.448E+01 2.448E+01 207 5.138E+00 2002.5 2.414E*01 2.414E+01 5.184E+00 208 2845.5 2.379E+01 2.379E+01 209 5.229E+00 2689.3 2.344E*01 2.344E+01 5.274E+00 210 2733.7 2.309E+01 2.309E+01 5.319E+00 211 2978.8 2.274E+01 2.274E+01 5.363E+00 212 3024.6 2.238E+01 2.238E+01 5.407E+00
- 213 3071.2 2.203E+01 2.203E+01 5.451E+00 214 3118.4 2.167E+01 2.167E+01 5.494E*00 215 3166.3 2.131E+01 2.131E+01 5.537E+00 216 3215.0 2.095E+01 2.095E401 5.579E+00 217 3264.5 2.059E+01 2.059E+01 218 5.621E+00 3314.7 2.023E+01 2.023E+01 5.662E+00 219 3365.6 1.987E+01 1.987E+01 220 5.703E+00 3417.4 1.951E+01 1.951E+01 5.744E+00 3469.9 1.915E+01 1.915E+01 5.783E+00
['221 222 3523.3 1.878E+01 1.878E+01 5.822E+00
- 223 3577.5 1.842E+01 1.842E+01 5.861E+00 224 3632.5 1.806E+01 1.806E+01 5.899E+00 225 3688.3 1.769E+01 1.769E+01 5.936E+00 226 3745.0 1.733E+01 1.733E+01 5.972E+00 227 3802.6 1.697E+01 1.697E+01 6.008E+00 228 3861.1 1.660E+01 1.660E+01 6.043E+00 229 3920.5 1.624E+01 1.624E+01 6.077E+00 230 3980.7 1.SS8E*01 1.588E+01 6.111E+00 231 4042.0 1.552E+01 1.552E+01 6.143E*00 232 4104.1 1.516E401 1.516E+01 6.175E+00 233 4167.2 1.480E+01 1.480E+01 6.205E+00 234 4231.3 1.444E+01 1.444E+01 6.235E+00 235 4296.4 1.409E+01 1.409E+01 6.264E+00 236 4362.4 1.373E+01 1.373E+01 6.292E+00 237 4429.5 1.338E+01 1.338E+01 6.319E+00 238 4497.6 1.303E+01 1.303E+01 6.344E+00 239 4566.8 1.268E+01 1.268E+01 6.369E+00 200 4637.0 1.233E+01 1.233E+01 6.393E+00 241 4708.3 1.199E+01 1.199E+01 6.415E+00 202 4780.7 1.165E*01 1.165E+01 6.436E+00 243 4854.2 1.131E+01 1.131E+01 6.457E+00 244 4928.9 1.097E+01 1.097E+01 6.476E+00 245 5004.7 1.064E+01 1.064E+01 6.493E*00 246 5081.6 1.031E+01 1.031E+01 6.510E+00 247 5159.8 9.986E+00 9.986E+00 6.525E+00 248 5239.1 9.664E+00 9.664E+00 6.539E+00 249 5319.7 9.346E+00 9.346E+00 6.552E+00
M M M M M M M M M M M W M M M M m COMPUTED CONCENTRATIONS FROH TIHE T= 0.0 (SECS) '.'O TIHE Tm 5.338E+05 (SECS) DATA POINT TIME ARRAY HAXIHUH CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION NUHDER (SECS 1 (GH/H3) ( Git /H3 ) ( GH/$t3 ) 850 5401.5 9.031E*00 9.031E+00 6.564E+00 251 5484.5 8.721E+00 8.721E+00 6.574E+00 252 5568.9 8.415E+00 8.415E+00 6.582E*00 E53 5654.5 8.114E+00 8.114E+00 4.590E+00 254 5741.4 7.817E+00 7.817E+00 6.596E+00 255 5829.7 7.525E+00 7.525E+00 6.600E+C0 256 5919.4 7.238E+00 7.238E+00 6.604E*00 257 6010.4 6.955E+00 6.955E+00 6,605E+00 258 6102.8 6.678E*00 6.678E+00 l6.606E+00[ - M ER112 M UB 259 6196.7 6.406E+00 6.406E+00 6.605E+00 260 6292.0 6.140E+00 6.140E+00 6.602E+00 261 6388.7 5.879E+00 5.379E+00 6.598E+00 262 6486.9 5.624E+00 5.624E+00 6.593E+00 263 6586.7 5.375E+00 5.375E+00 6.586E+00 864 6688.0 5.131E+00 5.131E+00 6.578E+00 265 6790.8 4.894E+00 4.894E+00 6.568E+00 266 6895.2 4.662E+00 4.662E+00 6.557E+00 267 7001.3 4.437E+00 4.437E+00 6.544E+00 268 7108.9 4.218E+00 4.218E+00 6.530E+00 b 269 7218.2 4.005E+00 4.005E+00 6.515E+00 270 7329.2 3.798E+00 3.798E+00 6.498E+00 271 7442.0 3.597E*00 3.597E+00 6.479E+00 f 272273 7556.4 7672.6 3.403E+00 3.403E+00 6.459E+00 a 3.216E+00 3.216E+00 6.438E+00
%J 274 7790.6 3.034E+00 3.034E+00 6.415E+00 275 7910.4 2.859E+00 2.859E400 6.391E+00 276 8032.0 2.691E+00 2.691E+00 6.366E+00 277 8155.5 2.528E+00 2.528E+00 6.339E+00 278 8280.9 2.372E+00 2.372E+00 6.311E+00 279 8408.2 2.223E+00 2.223E+00 6.282E+00 280 8537.5 2.079E+00 2.0795+00 6.252E+00 281 8668.8 1.942E+00 1.942E+00 6.220E+00 282 8802.1 1.811E+00 1.811E+00 6.187E+00 283 8937.5 1.685E*00 1.685E+00 6.152E+00 284 9074.9 1.566E+00 1.566E+00 6.117E+00 285 9214.4 1.453E+00 1.453E+00 6.080E+00 286 9356.1 1.345E+00 1.345E+00 6.042E+00 287 9500.0 1.243E+00 1.243E+00 6.004E+00 288 9646.1 1.146E+00 1.146E+00 5.964E+00 289 9794.4 1.055E+00 1.055E+00 5.923E+00 290 9945.0 9.688E-01 9.688E-01 5.881E+00 291 10097.9 8.878E-01 8.878E-01 5.838E+00 292 10253.2 8.117E-01 8.117E-01 5,794E+00 293 10410.9 7.405E-01 7.405E-01 5.749E+00 E94 10571.0 6.738E-01 6.738E-01 5.703E+00 295 10733.5 6.116E-01 6.116E-01 5.657E+00 296 10898.5 5.537E-01 5.537E-01 5.609E+00 297 11066.1 5.000E-01 5.000E-01 5.541E+00 298 11236.3 4.502E-01 4.502E-01 5.512E+00 299 11409.1 4.042E-01 4.042E-01 5.463E+00
m mW W M M M M M M M M M M M M M M M COMPUTED CONCENTRATIONS FROH TIME T= 0.0 (SECS) TO TIHE T= 5.338E+05 (SECS) DATA POINT TIHE ARRAY HAXIHUH CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION NtD1BER (SECS) (GM/H3) (GWH3 ) (CH/H3) 300 11584.5 3.617E-01 3.617E-01 5.412E+00 301 11762.6 3.228E-01 3.228E-01 5.361E+00 302 11943.5 2.871E-01 2.871E-01 5.319E+00 303 12127.2 2.544E-01 2.544E-01 5.258E+00 304 12313.7 2.247E-01 2.247E-01 5.205E+00 305 12503.0 1.977E-01 1.977E-01 5.152E+00 306 12695.3 1.733E-01 1.733E-01 5.098E+00 307 12890.5 1.513E-01 1.513E-01 5.044E+00 308 13088.7 1.315E-01 1.315E-01 4.989E+00 309 13289.9 1.138E-01 1.138E-01 4.934E+00 310 13494.3 9.803E-02 9.803E-02 4.878E+00 311 13701.8 8.404E-02 8.404E-02 4.822E+00 312 13912.5 7.167E-02 7.167E-02 4.766E+00 313 14126.4 6.079E-02 6.079E-02 4.710E+00 314 14343.6 5.128E-02 5.128E-02 4.653E+00 315 14564.2 4.299E-02 4.299E-02 4.596E+00 316 14788.2 3.592E-02 3.582E-02 4.530E+00 317 15015.6 2.964E-02 2.964E-02 4.481E+00 318 15246.4 2.436E-02 2.436E-02 4.423E+00 319 15480.9 1.987E-02 1.987E-02 4.365E+00 320 15718.9 1.608E-02 1.608E-02 4.307E+00 321 15960.6 1.290E-02 1.290E-02 4.249E+00 f-4 322 16206.1 1.026E-02 1.026E-02 4.190E+00
" 323 16455.3 8.076E-03 8.076E-03 4.132E+00 324 16708.3 6.294E-03 6.294E-03 4.073E+00 325 16965.2 4.851E-03 4.851E-03 4.015E+00 326 17226.1 3.694E-03 3.694E-03 3.956E+00 327 17491.0 2.777E-03 2.777E-03 3.897E+00 328 17759.9 2.059E-03 2.059E-03 3.839E+00 329 18033.0 1.504E-03 1.504E-03 3.780E+00 330 18310.3 1.080E-03 1.080E-03 3.721E+00 331 18591.9 7.621E-04 7.621E-04 3.662E+00 332 18877.7 5.272E-04 5.272E-04 3.604E*00 333 19168.0 3.568E-04 3.568E-04 3.545E+00 334 19462.8 2.357E-04 2.357E-04 3.487E+00 335 19762.0 1.516E-04 1.516E-04 3.428E+00 336 20065.9 9.462E-05 9.462E-05 3.370E+00 337 20374.5 5.708E-05 5.708E-05 3.312E+00 338 20687.8 3.313E-05 3.313E-05 3.253E+00 339 21005.9 1.840E-05 1.840E-05 3.195E+00 340 21328.9 9.709E-06 9.709E-06 3.138E*00 341 21656.9 4.825E-06 4.825E-06 3.080E+00 342 21989.9 2.233E-06 2.233E-06 3.023E+00 343 22328.0 9.487E-07 9.487E-07 2.965E+00 344 22671.4 3.627E-07 3.627E-07 2.908E+00 345 23020.0 1.214E-07 1.214E-07 2.852E+00
, 346 23374.0 3.422E-08 3.422E-08 2.795E+00 347 23733.4 7.641E-09 7.641E-09 2.739E+00 348 24098.3 1.225E-09 1.225E-09 2.683E+00 349 24468.9 1.179E-10 1.179E-10 2.628E+00 l
m a m M M M M M M M M M W W W M M m a CCHPUTED CONCENTRATIONS FROH TIHE Tm 0.0 (SECS) TO TIME Ta 5.330E+05 (SECS) DATA POINT TIME ARRAY HAXIHUll CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION NUMBER (SECS) (GH/H3) (GH/H3) (GH/H3) I 350 24845.1 4.663E-12 4.663E-12 2.572E*00 351 25227.2 2.588E-14 2.588E-14 2.517E+00 352 25615.1 1.811E-20 1.811E-20 2.463E+00 353 26009.0 0.0 0.0 2.409E+00 354 26408.9 0.0 0.0 2.355E+00 355 26815.0 09 0.0 2.301E+00 356 27227.3 0.0 0.0 2.248E+00 357 27646.0 C.d 0.0 2.196E+00 358 28071.1 0.0 0.0 2.144E+00 339 28502.8 0.0 0.0 2.092E+00 360 28941.1 0.0 0.0 2.041E+00 361 29386.1 0.0 0.0 1.990E+00 362 29838.0 0.0 0.0 1.940E+00 363 30296.8 0.0 0.0 1.890E+00 364 30762.7 0.0 0.0 1.841E+00 365 31235.7 0.0 0.0 1.793E+00 366 31716.0 0.0 0.0 1.745E+00 367 32203.7 0.0 0.0 1.697E+00 368 32698.9 0.0 0.0 1.650E+00 369 33201.7 0.0 0.0 1.604E+00 370 33712.3 0.0 0.0 1.559E+00 371 34230.7 0.0 0.0 1.514E+00 y 372 34757.0 0.0 0.0 1.469E+00 a 373 35291.5 0.0 0.0 1.426E+00 so 374 35834.2 0.0 0.0 1.383E+00 375 36385.2 0.0 0.0 1.340E+00 376 36944.7 0.0 0.0 1.298E+00 377 37512.8 0.0 0.0 1.257E+00 378 38089.7 0.0 0.0 1.217E+00 379 36675.4 0.0 0.0 1.178E+00 380 39270.1 0.0 0.0 1.139E+00 381 39873.9 0.0 0.0 1.100E+00 382 40487.1 0.0 0.0 1.063E+00 383 41109.7 0.0 0.0 1.026E+00 384 41741.8 0.0 0.0 9.902E-01 385 42383.7 0.0 0.0 9.549E-01 385 43035.5 0.0 0.0 9.204E-01 387 43697.2 0.0 0.0 8.866E-01 388 44369.2 0.0 0.0 8.536E-01 , 389 45051.4 0.0 0.0 8.213E-01 i 390 45744.2 0.0 0.0 7.898E-01 391 46447.7 0.0 0.0 7.590E-01 [ 392 47161.9 0.0 0.0 7.290E-01 1 393 47887.1 0.0 0.0 6.997E-01 ! 394 48623.5 0.0 0.0 6.712E-01 , 395 49371,1 0.0 0.0 6.435E-01 396 5013L3 0.0 6.164E-01 ( 397 50901.1 0.0 0.0 0.0 5.902E-01 398 51683.8 0.0 0.0 5.646E-01 399 52478.6 0.0 0.0 5.398E-01
M & S S S U U U U S S O O O S .S Y & M COMPUTED CONCENTRATIONS FROH TIME Tm 0.0 (SECS) TO TIHE T= 5.338E+05 (SECS) DATA POINT TIME ARRAY HAXIMUH CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCEh9ATION HUHDER (SECS) ( Gtt/H3 ) (GH/H3) ( GIf/H3 h 400 53285.6 0.0 401 54105.0 0.0 5.158E-01 0.0 0.0 4.924E-01 402 54937.1 0.0 403 0.0 4.698E-01 55701.9 0.0 0.0 4.479E-01 404 56639.7 0.0 405 57510.6 0.0 4.267E-01 0.0 0.0 4.062E-01 406 58395.0 0.0 0.0 407 3.864E-01 59293.0 0.0 0.0 3.673E-01 408 60204.8 0.0 0.0 3.489E-01 499 61130.$ 0.0 410 0.0 3.311E-01 62070.7 C.0 0.0 3.140E-01 411 63025.2 0.0 0.0 41? 2.975E-01 63994.4 0.0 0.0 2.816E-01 415 64978.4 0.0 0.0 2.664E-01 414 65977.6 0.0 415 0.0 2.518E-01 66992.2 0.0 0.0 2.378E-01 416 68022.3 0.0 417 0.0 2.243E-01 69068.2 0.0 0.0 2.114E-01 418 70130.3 0.0 419 0.0 1.991E-01 71208.7 0.0 0.0 1.874E-01 420 72303.7 0.0 0.0 1.761E-01 421 73415.6 0.0 0.0 1.654E-01 [ 422 na 423 74544.5 75690.8 0.0 0.0 0.0 1.552E-01 C) 424 0.0 1.454E-01 76854.7 0.0 0.0 1.362E-01 425 78036.5 0.0 426 0.0 1.274E-01 79236.5 0.0 0.0 1.190E-01 427 80455.3 0.0 428 0.0 1.111E-01 81692.2 0.0 0.0 1.036E-01 429 82948.4 0.0 430 0.0 9.652E-02 84223.9 0.0 0.0 8.981E-02 431 85519.1 0.0 432 0.0 6.347E-02 86834.1 0.0 0.0 7.749E-02 433 88169.4 0.0 0.0 7.184E-02 434 89525.2 0.0 435 0.0 6.656E-02 90901.9 0.0 0.0 6.158E-02 436 92299.7 0.0 437 0.0 5.690E-02 93719.1 0.0 0.0 5.252E-02 438 95160.2 0.0 0.0 4.841E-02 439 96623.6 0.0 0.0 4.457E-02 440 98109.4 0.0 0.0 4.098E-02 441 99618.0 0.0 0.0 3.763E-02 442 101149.9 0.0 443 0.0 3.451E-02 102705.2 0.0 0.0 3.161E-02 444 104284.6 0.0 445 0.0 2.891E-02 105888.3 0.0 0.0 2.641E-02 446 107516.6 0.0 447 0.0 2.409E-02 109169.9 0.0 0.0 2.194E-02 448 110848.6 0.0 0.0 1.995E-02 449 112553.1 0.0 0.0 1.812E-02
m m m M M M m m M M m W W W m M m a C0!!PUTED CONCENTRATIONS FRott TIME T= 0.0 (SECS) TO TIlfE T: 5.338E+05 (SECS) DATA POINT TIME ARRAY HAXIHUH CONCENTRATION CUTSIDE CONCENTRATICH INSIDE CONCENTRA. ION nut (BER (SECSI (GH/H3) ( Gt f/tf3 ) ( Git /l13 ) 450 114283.9 0.0 0.0 451 116041.2 1.643E-02 0.0 0.0 1.488E-02 452 117825.6 0.0 0.0 453 119537.5 1.34EE-02 0.0 0.0 1.214E-02 454 121477.2 0.0 455 123345.3 0.0 1.094E-02 0.0 0.0 9.848E-03 456 125242.1 0.0 0.0 457 127168.0 e.e4eE-03 0.0 0.0 7.935E-03 458 129123.4 0.0 459 131109.1 0.0 7.105E-03 0.0 0.0 6.351E-03 460 133125.2 0.0 461 135172.4 0.0 5.667E-03 0.0 0.0 5.048E-03 462 137250.9 0.0 463 139361.5 0.0 4.489E-03 0.0 0.0 3.984E-03 464 141504.4 0.0 465 143680.4 0.0 3.530's-03 0.0 0.0 3.122E-03 466 145e89.8 0.0 467 148133.2 0.0 2.755E-03 0.0 0.0 2.427E-03 468 150411.2 0.0 469 152724.2 0.0 2.134E-03 0.0 0.0 1.873E-03 470 155072.7 0.0 471 0.0 1.640E-03 157457.4 0.0 0.0 1.433E-03 j3 472 159878.7 0.0 0.0 1.250E-03 A) 473 162337.3 0.0 F' 474 0.0 1.088E-03 164833.6 0.0 0.0 9.448E-04 475 167368.3 0.0 476 169942.1 0.0 8.187E-04 0.0 0.0 7.079E-04 477 172555.4 0.0 478 175008.7 0.0 6.108E-04 0.0 0.0 5.257E-04 479 177903.1 0.0 400 180638.8 0.0 4.515E-04 0.0 0.0 3.868E-04 481 183416.6 0.0 402 0.0 3.306E-04 186237.1 0.0 0.0 2.819E-04 483 189101.1 0.0 484 192009.0 0.0 2.398E-04 0.0 0.0 2.035E-04 485 194961.7 0.0 4e6 0.0 1.722E-04 197959.7 0.0 0.0 1.454E-04 487 201003.9 0.0 488 0.0 1.224E-04 204094.9 0.0 0.0 1.028E-04 489 207233.4 0.0 490 210420.2 0.0 8.609E-05 0.0 0.0 7.190E-05 491 213656.0 0.0 492 0.0 5.959E-05 216941.5 0.0 0.0 4.974E-05 493 220077.6 0.0 494 223664.9 0.0 4.120E-05 0.0 0.0 3.402E-05 495 227104.4 0.0 496 230596.7 0.0 2.801E-05 0.0 0.0 2.300E-05 497 233142.8 0.0 498 237743.4 0.0 1.882E-05 0.0 0.0 1.536E-05 499 241399.4 0.0 0.0 1.249E-05
m m W W W W W W M M M m W e m m e m e CottPUTED CONCENTRATIONS FROH TIME T= 0.0 (SECS) TO TIME T: 5.338E+05 (SECS) DATA POINT TIttE ARRAY HAXIlfUH CONCENTRATI0tl OUTSIDE C0fCENTRATION INSIDE CONCENTRATION NUtSER (SECS 1 ( GH/tt3 ) ( GtVit3 I ( CtVtf3 ) 500 245111.6 0.0 0.0 1.013E-05 501 248880.8 0.0 0.0 8.185E-06 502 25270C.0 0.0 0.0 6.594E-06 503 256594.1 0.0 0.0 5.294E-06 504 260539.9 0.0 0.0 4.236E-06 505 264546.4 0.0 506 0.0 3.378E-06 268614.6 0.0 0.0 2.684E-06 507 272745.2 0.0 0.0 2.125E-06 508 276939.4 0.0 509 0.0 1.677E-06 281198.2 0.0 0.0 1.318E-06 510 285522.4 0.0 0.0 1.033E-06 511 289913.1 0.0 0.0 8.057E-07 512 294371.2 0.0 0.0 6.263E-07 513 298898.0 0.0 0.0 4.850E-07 514 303494.4 0.0 0.0 3.741E-07 515 308161.4 0.0 0.0 2.874E-07 516 312900.2 0.0 0.0 2.199E-07 517 317712.0 0.0 0.0 1.675E-07 518 322597.7 0.0 0.0 1.271E-07 519 327558.5 0.0 0.0 9.604E-08 520 332595.6 0.0 0.0 7.226E-C8 521 337710.2 0.0 0.0 5.412E.00 7 522 342903.4 0.0 0.0 4.036E-08 y 523524 348176.4 0.0 0.0 2.996E-08 353530.6 0.0 0.0 2.214E-08 525 358967.1 0.0 0.0 1.628E-08 526 364487.2 0.0 0.0 1.192E-08 527 370092.2 0.0 0.0 8.685E-09 528 375783.4 0.0 0.0 6.297E-09 529 381562.1 0.0 0.0
, 4.543E-09 530 387429.6 0.0 0.0 3.261E-09 531 393337.4 0.0 0.0 2.329E-09 532 399436.8 0.0 0.0 1.655E-09 533 405579.2 0.0 0.0 1.170E-09 534 411816.2 0.0 0.0 8.222E-10 535 418148.9 0.0 0.0 5.749E-10 536 4 4579.1 0.0 0.0 3.998E-10 537 431108.2 0.0 0.0 2.764E-10 538 437737.7 0.0 0.0 1.901E-10 539 444469.1 0.0 0.0 1.299E-10 540 451304.0 0.0 0.0 8.832E ') .
541 458244.1 0.0 0.0 5.967F-11 542 465290.8 0b 0.0 .4.007E-11 543 472445.9 0.0 0.3 2.6 75E-11 544 479711.1 0.0 ' 0.0 e 1.??4E-11 545 487087.9 _ 0.0 0.0 J.170E-11 546 494578.2' O0 0.0 7.6f 0E-12 547 502183.7 0.0 0.0 4.984E-12 548 509906.2 rJ. 0 0.0 3.222E-12 549 517747.4 0 . *J 0.0 2.069E-12
\
_ - - -- - ,. ._ ~ . _ . - _. - ._
, i q g '-
Q M M M M & ' ^ 1 j
* ;! I
)
COMPUTED CONCENTRATIONS FRON TIME T= 0.0 (SECSI TO TIME T= 5.338E+05 (SECSI - DATA POINT TIME ARRAY HAXIMUM COfCENTRATICH tOfBER OUTSIDE CONCENTRATION INSIDE CONCENTRATION ' l (SECS 3 (GH/H3) ( git /H3 ) i ( GWH3 ) i 550 525709.2 0.0 ! 0.0 1.319E-12 551 533793.4 0.0 0.0 8.355E-13 l l E U
______y-__.___ . _ _ _ _ _ . _ _ _ _ . ._ - ..-_ .._ _ .. . . . . . - . . . - - a m. M M - M M M m ,' M.~ - M .m M M M M M M , T
\.
TO!!IC CHE*11CAlma. TOLL'EtiE .'" SOURCE: ARCOI POLYMERS,INC. . CHEttICAL TYPE I HIGH DOILING POIttT STABILITY CLASS 3 G APFROX."tMBER OF DATA POINTS : 350 ItiCREttENT CF OUTPUT REQUESTS 100 TEMPERATURE (C) : 4.000E*01 hit 0 SPEED (H/SEC)
- 4.900E-ul
, RECEPTOR HEIGHT ('t)
- 0.0 SOURCE HEIGHT (H)
- 0.0 ~
LIQUID DEllSITY (G/CCI ' 8.660E-01 VENT FLOH RATE (CMS) 9.440E-02 i CONTROL R00f t AIR SPACE (H3 )
- 1.671E+03 SUBSTA*lCE ItlITIAL MASS (G) I 4.540E+09 RECEPTCR DISTANCE III)
- 7.320E+03 CENTERLINE DISTA!4CE (H)
- 0.0 LIMIT ttA!1E LIMIT VALUE ,
T0XIC LIltIT 8.000E-01 (G/H3 ) SAT. VAP. PRESS. AT TA (ifH HG)
- 5.500E*01 DIFFUSICH COEFFICIENT (CH2/S) 9.200E-02 tt0LECULAR HEF ( G/ItCL ) '
9.210E+01 TIltE REQUIRED. 'TO REACH THE ttAX. SPILL AREA IS 652.00
?
N
g' ~~ g g g g g g g g g g CC!!PUTED C0tlCENTRATIONS FROH TIME T: 0.0 (SECS) TO TIME T= 9.550E+05 (SECSI DATA POINT TIHE ARRAY HAXIHUH CONCENTRATION OUTSIDE CONCENTRATI0!I INSIDE CONCENTRATICN nut (B2R (SECS) t Gt1/113 ) ( Gil/H3 ) iGif/H31 1 0.0 0.0 2 14938.8 0.0 0.0 1.987E-02 1.987E-02 1.133E-02 3 15109.1 2.920E+01 2.920E+00 4 15201.3 3.918E-02 4.799E+00 4.799Ee00 0.527E-02 5 15455.5 6.256E+00 6.256E+00 6 15590.8 1.457E-01 7.202E+00 7.200E+00 1.994E-01 7 15768.5 7.173E+00 7.173E+00 0 15948.3 2.691E-01 7.163E+00 7.363E+00 3.308E-01 9 16130.1 7.154E+00 7.154E+00 10 16314.0 4.084E-01 7.144E+00 7.144E+00 4.180E-01 11 16500.0 7.133E+00 7.133E+00 5.476E-01 12 16608.1 7.123E+00 7.123E+00 13 16878.3 6.171E-01 7.113E+00 7.113E*00 6.866E-01 14 17070.7 7.102E+00 7.102E+00 15 17265.3 7.559E-01 7.092E+00 7.092E+00 8.252E-01 16 17462.2 7.081E+00 7.001E+00 8.944E-01 17 17661.2 7.070E+00 7.070E+00 9.635E-01 18 17862.6 7.060E+00 7.060E+00 19 18066.2 1.032E+00 7.049E*00 7.04?E+00 1.101E+00 20 18272.2 7.037E+00 7.037E+00 1.170E+00 21 18480.5 7.026E+00 7.026E+00 1.238E+00 22 18691.2 7.015E+00 7.015E+00 1.307E+00 23 18904.3 7.00!E+00 7.003E+00 24 1.375E+00
'" 19119.8 6.992E+00 6.992E+00 1.443E+00 25 19337.7 6.980E+00 6.980E*00 26 1.511E+00 19558.2 6.968E+00 6.968E+00 1.578E+00 27 19781.1 6.956E+00 6.956t+00 28 1.646E+00 20006.6 6.944E+00 6.944E+00 1.713E+00 29 20234.7 6.932E+00 6.932E+00 30 20465.4 1.779E+00 6.919E+00 * .919E400 1.846E+00 31 20698.7 6.907E+00 . ^07E+00 1.912E+00 32 20934.6 6.894E+00 6.094E+00 33 1.97BE+00 21173.3 6.882E+00 6.682E+00 2.044E400 34 21414.7 6.86?E400 6.869E+00 35 2.109E+00 21658.8 6.856E+00 6.855E*00 2.174E+00 35 21905.7 6.843E*00 6.843E+00 2.239E*00 37 22155.4 6.829E+00 6.829E*00 2.303E+00 38 22408.0 4.016E+00 6.816E+00 39 2.367E+00 22663.5 6.802E+00 6.802E+00 2.431E+00 40 22921.8 6.788E*00 6.788E+00 2.494E+00 41 23183.1 6.775E+00 6.775E+00 2.557E+00 42 23447.4 6.761E+00 6.761E*00 43 2.619E+00 23714.7 6.746E+00 6.746E+00 2.681E+00 44 23985.1 6.732E+00 6.732E+00 45 2.742E+00 24250.5 6.718E+00 6.718E+00 2.803E+C0 46 24535.1 6.703E+00 6.703E+00 47 2.844E+00 24814.8 6.689E+00 6.689E+00 2.924E+0J 48 25097.7 6.674E+00 6.674E+00 49 2.983E+00 25303.8 6.658E+00 6.658E+00 3.042E+00
m m m M M M M M M M m m COMPUTED C0t4CENTRATIONS ERCH TIHE T= 0.0 (SECS) TO TIME T: 9.550E+05 (SECS) DATA POINT TIME ARRAY HAXIMUH CONCENTRATION OUTSIDE CONCENTRATION HUMBER (SECS 1 INSIDE CONCENTRATI0H iGtVH3 ) ( GrVH3 ) t CtVH31 50 25673.2 6.643E+00 6.643E*00 3.100E+00 51 25765.8 6.628E+00 6.628E+00 3.158E+00 52 26261.9 6.612E+00 6.612E+00 53 3.216E+00 26561.2 6.597E+00 6.597E+00 3.272E+00 54 26864.1 6.581E+00 6.5 ele +00 55 27170.3 3.328E+00 6.565Ee00 6.565E+00 3.364E*00 56 27480.1 6.549E+00 6.549E+.0 3.439E+00 57 27793.3 6.533E+00 6.533E+00 3.493E+00 SS 28110.2 6.516E+00 6.516E*00 3.547E+00 59 28130.6 6.500E+00 6.500E+00 60 3.600E+00 28754.7 6.483E+00 6.483E+00 3.652E+00 61 29082.5 6.466E*00 6.466E+00 62 3.704E+00 29414.1 6.449E+00 6.449E+00 63 3.75EE*00 29749.4 6.431E,00 6.431E+00 3.805E+00 64 30088.5 6.414E+00 6.414E+00 65 3.054E+00 30431.5 6.396E+00 6.396E+00 3.'9 03 E + 0 0 66 30778.4 6.378E+00 6.378E+00 3.?51E+00 67 31129.3 6.360E+00 6.360E+00 68 3.998E+00 31484.2 6.342E+00 6.342E+00 4.045E+00 69 31843.1 6.324E+00 6.324E+00 70 32206.1 4.091E+00 6.305E+00 6.305E+00 4.136E+00 71 32573.3 6.286E+00 6.286E+00 4.180E+00 IU 72 32944.6 6.267E+00 6.267E+00 4.223E+C0 h) 73 33320.2 6.248E+00 6.248E+00 4.266E+00 CN 74 33700.1 6.229E+00 6.229E+00 4.307E+00 75 34084.3 6.210E+00 6.210E+00 4.348E+00 76 34472.8 6.190E+00 6.190E+00 4.388E+00 77 T4865.8 6.170Ee00 6.170E*00 70 3i 53.3 4.427E+00 6.150E+00 6.150E+00 4.466E+00 79 35665.3 6.130E+00 6.130E+00 4.503E+00 80 36071.9 6.109E+00 6.109E*00 4.539E+00 81 36483.2 6.089E+00 4.089E*00 4.575E+00 82 36899.1 6.068E+00 6.060E+00 83 4.610Ee00 37319.7 6.047E+00 6.047E+00 4. 6 4!E +00 84 37745.2 6.025E+00 6.025E+00 85 4.676E*00 38175.6 6.000E+00 6.004E+00 4.708E+00 86 38610.7 5.982E+00 5.962E+00 4.739E+00 87 39050.9 5.961E+00 5.961E*00 4.769E+00 88 39496.1 5.93eE*00 5.938E+00 4.798Ee00 89 39946.4 5.916Ee00 5.916E*00 4.826Ee00 90 40401.7 5.894E+00 5.894E+00 91 4.853E+00 40862.3 5.871E+00 5.871E+00 4.890E+00 92 41323.2 5.848E+00 5.840E+00 4.905E+00 93 41799.3 5.825E+00 5.825Ee00 4.929E400 94 42275.8 5.802E*00 5.CO2E+00 4.952E+00 95 42757.8 5.778E+00 5.778E+00 96 4.974E+00 43245.2 5.754E*00 5.754E*00 97 4.995E+00 437?O.2 5.730E*00 5.730E+00 5.016E+00 58 44236.3 5.706E+00 5.106E+00 5.0352+00
?? 44741.1 5.682E+00 5.682E+00 5.053E+00
M M M M M M M M M M M M CCitPUTED C0tICENTRATI0ftS FRott TIttE T= 0.0 (SECS) TO TIlfE T: 9.550E+05 (SECS) DATA POINT TIttE ARRAY HAXIt!UH Cot 4 CENTRATION OUTSIDE CottCE!ITRATIOtt IrtSIDE COtiCEtirRATION totDER (SECS 1 ( Glt/H3 ) ( GIVit3 I ( Gtt/t!31 100 45251.2 5.65?E*00 5.657E+00 5.070E+00 101 45767.1 5.632E*00 5.632E+00 5.086E+00 102 46288.8 5.607E*00 5.607E+00 5.101E*00 103 46816.5 5.502E*00 5.582E*00 5.116E*00 104 47350.3 5.556E+00 5.555E+00 5.129E+00 105 47890.1 5.531E*00 5.531E+00 5.141E+00 106 48436.1 5.505E+00 5.50SE+00 5.152E+00 107 48988.2 5.47BE+00 5.478E+00 5.162E+00 108 49546.7 5.452E+00 5.452E+00 5.171E+00 109 50111.6 5.425E+00 5.425E+00 5.179E400 110 50682.9 5.398E+00 5.39eE+00 5.186E+00 111 51260.7 5.371E400 5.371E*00 5.192E400 112 51845.1 5.344E+00 5.344E+00 5.197E+00 113 52436.2 5.316E+00 5.316E+00 5.201Ee00 114 53034.0 5.200E+00 5.288E+00 5.203E+00 115 53638.5 5.260E+00 5.260E400 5.205E+00 116 54250.1 5.232E+00 5.232E+00 5.206E+0C )hrgiggun Veddle 117 54068.6 5.203E+00 5.203E+00 5.206E+0C 118 55494.1 5.175E+00 5.175E+00 5.205E+00 119 56126.8 5.146E+00 5.146E+00 5,203E+00 120 55766.7 5.116E+00 5.116E+00 5.200E+00 121 57413.9 5.087E+00 5.0872+00 5.196E+00 122 58068.4 5.057E400 5.057E400 5.191E+00 123 58730.5 5.027E*00 5.027E+00 5 le5E+00
-J 124 59400.0 4.997E+00 4.997E+00 5.178E+00 125 60077.2 4.967E+00 4.967E+00 5.170E+00 126 60762.2 4.936E*00 4.936E+00 5.161Ee00 127 61454.9 4.905E+00 4.905E+00 5.151E+00 128 62155.5 4.874E+00 4.874E+00 5.140E+00 129 62864.1 4.842E+00 4.842E+00 5.129E+00 130 63580.8 4.811E+00 4.811E400 5.116E+00 131 64305.7 4. 7 79E+ 00 4.779E+00 5.103E+00 132 65038.8 4.747E+00 4.747E+00 5.Ge8E+00 133 65780.3 4.714E+00 4.714E+00 5.073E+00 134 66530.2 4.682E+00 4.682E+00 5.057E+00 135 67288.6 4.649E*00 4.649E*00 5.039E+00 136 68055.7 4.616E+00 4.616E+00 5.0222+00 137 68831.6 4.582E*00 4.582E+00 5.003E+00 138 69616.4 4.549E+00 4.549E+00 4.983E+00 139 70410.1 4.51EE+00 4.515E+00 4.962E400 140 71212.7 4.981E+00 4.481E+00 4.941E*00 141 72024.6 4.447E+00 4.417t+00 4.919E+00 142 72845.7 4.412E+00 4.412E+00 4.896E+00 143 73676.2 4.378E+00 4.378E*00 4.872E+00 144 74516.2 4.343E+00 4.343E400 4.84eE+00 145 75365.7 4.308E+00 4.30BE400 4.822E+C0 146 76224.9 4.272E+00 4.272E+00 4.796E+00 147 77093.9 4.236E+00 4.236E*00 4.769E+00 148 77972.9 4.201E*00 4.201E+00 4.742E400 149 7c361.8 4.165E+00 4.165E*00 4.714E+00
m M M M M M M M CottPUTED CottCENTRATIONS FROH TIHE T= 0.0 (SECS) TO TIME T= 9.550E+05 (SECS) DATA POINT TIME ARR.4Y HAXINUH CONCENTRATICH OUTSIDE CONCENTRATION IHSIDE CONCENTRATION tlUMBER tSECS) (Git /H3) ( G* t/ H3 ) ( Glt/H3 3 150 79760.9 4.128E+00 4.128E+00 4.685E+00 151 80670.2 4.092E+00 4.092E+00 4.655E+00 152 21589.9 4.055E+00 4.055E+00 4.625E+00 153 82520.0 4.018E+00 4.018E+00 4.594E+00 154 83460.8 3.981E+00 3.981E+00 4.562E+00 155 04412.3 3.944E+00 3.944E+00 4.529E+00 154 85374.6 3.906E+00 3.906E+00 4.496E+00 157 86347.9 3.86CE+00 3.068E+00 9.463E+00 15S 87332.3 3.830E+00 3.830E+00 4.4298+00 159 88327.9 3.792E+00 3.792E+00 4.394E+00 160 89334.9 3.754E+00 3.754E+00 4.358E*00 161 90353.3 3.715E400 3.715E+00 162 4.322E400 91383.4 3.677E+00 3.677E*00 4.286E+00 163 92425.2 3.638E+00 3.638E+00 4.249E+00 164 93478.9 3.599E+00 3.599E+00 4.211E+00 165 94544.5 3.559E+00 3.559E+00 4.173E+02 166 95622.3 3.520E+00 3.520E+00 4.135E+00 167 96712.4 3.480E+00 3.480E*00 4.096E+00 168 97814.9 3.441E+00 3.441E+00 4.056E+00 169 98930.1 3.401E+00 3.401E+00 4.016E+00 170 100057.9 3.361E*00 3.361E+00 3.976E+00 171 101198.6 3.321E+00 3.321E+00 3.935E+00 fog 172 173 102352.4 103519.2 3.280E+00 3.240E+00 3.280E+00 3.893E+00 3.240E+00 3.852E+00 174 104699.4 3.199E+00 3.199E+0D 3.810E*00 175 105893.0 3.159E+00 3.159E+00 3.767E*00 176 107100.2 3.118E+00 3.118E+00 3.724E+00 177 108321.2 3.077E+00 3.077E+00 3.681E+00 178 109556.2 3.036E+00 3.036E+00 3.638E+00 179 110805.2 2.995E+00 2.995E+00 3.594E+00 180 112068.4 2.954E+00 2.95CE+00 3.550E+00 181 113346.1 2.913E+00 0.913E+00 3.505E+00 102 114638.3 2.871E+00 2.871E+00 3.461E+00 183 115945.2 2.830E+00 2.830E+00 3.416E+00 184 117267.1 0.78SE+00 2.788E+00 3.371E*00 185 110604.1 2.747E+00 2.747E+00 3.325E+00 186 119956.2 2.706E+00 2.706E+00 3.2SOE+00 137 121323.9 2.664E+00 2.664E+00 3.234E+C0 183 122707.1 2.622E*00 2.622E400 3.18EE400 189 124106.C 2.531E+00 2.581E400 3.142E+00 190 125520.9 2.539E*00 2.539E+00 3.096E+00 191 126951.9 2.498E+00 2.490E+00 3.047E+00 172 128399.2 2.456E+0C 2.456E+00 3.003Et00 193 129363.1 2.415E+00 2.415E+00 2.956E+C0 194 131343.6 2.373E+00 2.373E+00 0.9090+00 195 132841.0 2.332E+00 2.332E+00 2.862E+00 196 134355.4 2.291E+00 2.291E+00 2.815E+00 197 135007.0 2.249E+C0 2.249E+00 2.7692+00 118 137436.1 2.208E+C0 2.200E+00 2.722E+00 199 139003.0 2.167E+00 2.167E+00 2.675E+00
M - M M CCHPUTED CottCENTRATIONS FROH TIME T= 0.0 (SECS) TO TIME T 9.550E+05 (SECS) DfTA POINT TIME ARRAY HAXItfUH CONCENTRATI0H OUTSIDE COMCEt4TRATI0tl INSIDE CONCENTRATION FEM EER (SECS) ( Git /H3 ) ( G!!/H3 ) ( Cit /113 ) 200 140587.7 2.126E+00 2.126E+00 2.62EE+00 201 142190.6 2.005E+00 2.085E+00 2.581E+00 202 143811.7 2.045E+00 2.045E+00 2.53'3 E + 0 0 203 145451.2 2.004E+00 2.004E+00 2.487E+00 234 147109.5 1.964E+00 1.964E+00 2.440E400 203 148786.7 1.923E+00 1.923E+00 2.393E+00 206 150482.9 1.883E+00 1.833E+00 2.347E+00 207 152198.4 1.E43E+00 1.843E+00 2.300E*00 208 153933.6 1.804E+00 1.804E+00 2.254E+00 209 155683.6 1.764E+00 1.764E+00 2.20EE+00 210 157463.6 1.725E+00 1.725E+00 2.162E+00 211 159258.8 1.686E+00 1.685E+00 2.116E+00 212 161074.5 1.647E+00 1.647E+00 2.070E+00 213 162910.9 1.608E+00 1.608E+00 2.024E+00 214 164768.2 1.570E+00 1.570E+00 1.979E+00 215 166646.7 1.5320,00 1.532E+00 1.934E+00 215 168546.6 1.495E+00 1.495E*00 1.089E+00 217 "70468.0
. 1.457E*00 1.457E*00 1.845E+00 218 172411.4 1.420E400 1.420E+00 1.801E+00 219 174376.9 1.384E+00 1.384E+00 1.757E+00 220 176365.0 1.347E+00 1.347E+00 1.713E*00 221 178375.7 1.311E+00 1.311E+00 1.670E400 IU 222 180409.3 1.276E+00 1.276E*00 1.621E+00 h) 223 102456.1 1.240E+00 1.240E,00 1.5SSE+00 "O 224 184546.4 1.206E+00 1.206E+00 1.543E*00 225 IE6650.4 1.171E+00 1.171E+00 1.501E+00 226 108778.3 1.137E+00 1.137E+00 1.460E+00 227 190930.6 1.104E+00 1.104E*00 1.419E+00 228 193107.3 1.070E+00 1.070E+00 1.379E+00 229 195308.9 1.038E+00 1.030E+00 1.339E*00 230 197535.6 1.006E+00 1.006E+00 1.279E+00 231 199787.7 9.738E-01 9.738E-01 1.261E+00 232 202065.4 9.425E-01 9.425E-01 1.222E+00 233 204369.1 9.117E-01 9.117E-01 1.184E+00 234 206699.1 8.815E-01 8.815E-01 1.147E+00 235 209055.6 8.517E-01 8.517E-01 1.110E+00 236 211439.1 0.224E-01 8.224E-01 1.074E+00 237 213849.6 7.937E-01 7.937E-01 1.038E+00 238 216287.7 7.655E-01 7.655E-01 1.003E+00 239 218753.6 7.378E-01 7.378E-01 9.6e5E-01 240 221247.5 7.101E-01 7.107E-01 9.347E-01 241 223769.9 6.841E-01 6.041E-01 9.014E-01 242 226321.1 6.581E-01 6.591E-01 8.de8E-01 243 220901.3 6.327E-01 6.327E-01 8.367E-01 244 231E11.0 6.078E-01 6.078E-01 c.054E-01 245 P34150.4 5.834E-01 5.834E-01 7.746E-01 245 236819.9 5.597E-01 5.597E-01 7.445E-01 247 239519.9 5.365E-01 5.365E-01 7.151E-01 248 242250.6 5.139E-01 5.139E-01 6.663E-01 249 245012.4 4.918E-01 4.918E-01 6.582E-01
M _ M M M M M MI . M MM M M M COttPUTED CONCErlTRATIONS FR0tt TIME Tm 0.0 (SECS) TO TIllE T= 9.550E405 (SECS) DATA POINT TIttE ARRAY HAXItfUtt CONCENTRATION OUTSIDE CONCENTRATION INSIDE CONCENTRATION t4UttBER (SECS 1 ( Git /N3 ) ( Gt t/H3 ) ( Gt1/t13 3 250 247805.8 4.704E-01 4.704F-01 6.308E-01 251 250631.0 4.495E-01 4.495E-01 6.040E-01 252 253488.4 4.292E-01 4.292E-01 5.780E-01 253 256378.4 4.095E-01 4.095E-01 5.526E-01 254 259301.3 3.903E-01 3.903E-01 5.279E-01 255 262257.6 3.717E-01 3.717E-01 5.039E-01 256 265247.5 3.537E-01 3.537E-01 4.805E-01 257 268271.5 3.363E-01 3.363E-01 4.579E-01 258 271330.1 3.194E-01 3.194E-01 4.359E-01 259 274423.4 3.031E-01 3.031E-01 4.146E-01 260 277552.1 2.874E-01 2.874E-01 3.940E-01 261 280716.4 2.722E-01 2.722E-01 3.740E-01 262 283916.8 2.575E-01 2.575E-01 3.5465-01 263 287153.7 2.434E-01 2.434E-01 3.361E-01 264 290427.5 2.298E-01 2.298E-01 3.182E-01 265 293738.6 2.167E-01 2.167E-01 3.009E-01 266 297087.4 2.042E-01 2.042E-01 2.842E-01 267 300474.5 1.921E-01 3.921E-01 2.682E-01 265 303900.2 1.806E-01 1.806E-01 2.520E-01 269 307364.9 1.696E-01 1.696E-01 2.380E-01 270 310869.1 1.590E-01 1.590E-01 2.238E-01 271 314413.2 1.489E-01 1.489E-01 2.202E-01 I 272 317997.8 1.393E-01 1.393E-01 1.972E-01 I$ 273 321623.2 1.301E-01 1.301E-01 1.84SE-01 274 325290.0 1.214E-01 1.214E-01 1.729E-01 275 328998.6 1.131E-01 1.131E-01 1.616E-01 276 332749.4 1.052E-01 1.052E-01 1.508E-01 277 336543.1 9.771E-02 9.771E-02 1.406E-01 278 340379.9 9.063E-02 9.063E-02 1.308E-01 279 344260.6 8.394E-02 8.394E-02 1.216E-01 280 34S185.4 7.762E-02 7.762E-02 1.129E-01 231 352155.0 7.165E-02 7.165E-02 1.046E-01 282 356169.9 6.604E-02 6.604E-02 9.676E-02 283 360230.5 6.076E-02 6.076E-02 8.930E-02 284 364337.4 5.580E-02 5.580E-02 8.243E-02 285 368491.2 5.116E-02 5.116E-02 7.589E-02 286 372692.3 4.681E-02 4.631E-02 6.974E-02 287 376941.3 4.275E-02 4.275E-02 6.39eE-02 208 38123S.7 3.897E-02 3.897E-02 5.057E-02 209 385585.2 3.545E-02 3.545E-02 5.355E-02 290 389981.1 3.217E-02 3.217E-02 4.885E-02 291 394427.2 2.914E-02 2.914E-02 4.447E-02 292 393924.1 2.633E-02 2.633E-02 4.040E-02 793 403472.1 2.374E-02 2.374E-02 3.663E-02 274 408072.1 2.135E-02 2.135E-02 3.313E-02 295 412724.4 1.915E-02 1.915E-02 2.990E-02 294 417429.8 1.714E-02 1.714E-02 2.692E-02 297 422189.8 1.529E-02 1.527E-02 2.418E-02 298 427002.1 1.361E-02 1.361E-02 2.166E-02 297 431870.3 1.207E-02 1.207E-02 1.934E-02
M M M M M M M M M U* M M M tM M CottPUTED CONCENTRATIONS FRott TIltE T= 0.0 (SECS) TO TIttE T= 9.550E+05 (SECS) DATA FOINT TIllE ARRAY HAXIMUtl CONCENTRATI0tt OUTSIDE C0t1 CENTRATION INSIDE C0tiCENTRATION tfUtIBER (SECS 3 ( G!!/t13 ) ( Git /it3 ) (Gtt/t131 300 436794.0 1.068E-02 1.068E-02 1.725E-02 301 441773.8 9.419E-03 9.419E-03 1.533E-02 302 446010.4 C.280E-03 8.280E-03 1.358E-02 303 451904.4 7.253E-03 7.253E-03 1.200E-02 304 457056.5 6.332E-03 6.332E-03 1.057E-02 305 462267.3 5.507E-03 5.507E-03 9.27eE-03 306 467537.6 4.771E-03 4.771E-03 8.117E-03 307 472867.9 4.118E-03 4.118E-03 7.077E-03 30S 478258.9 3.538E-03 3.538E-03 6.14PE-03 309 483711.5 3.028E-03 3.028E-03 5.321E-03 310 489226.2 2.579E-03 2.579E-03 4.587E-03 311 494803.7 2.186E-03 2.186E-03 3.938E-03 312 500449.9 1.843L-03 1.843E-03 3.366E-03 313 506150.4 1.546E-03 1.546E-03 2.e65E-03 314 511920.9 1.290E-03 1.290E-03 2.427E-03 315 517757.3 1.070E-03 1.070E-03 2.046E-03 316 523660.1 8.821E-04 8.821E-04 1.716E-03 317 529630.3 7.224E-04 7.224E-04 1.431E-03 318 535668.6 5.875E-04 5.875E-04 1.187E-03 319 541775.6 4.744E-04 4.744E-04 9.793E-04 320 547952.2 3.801E-04 3.801E-04 8.028E-04 321 554199.4 3.020E-04 3.020E-04 6.538E-04 322 560517.7 2.379E-04 2.379E-04 5.290E-04 h" 323 566908.1 1.856E-04 1.856E-04 4.249E-04 324 573371.3 1.434E-04 1.434E-04 3.388E-04 325 579908.2 1.096E-04 1.096E-04 2.680E-04 326 586519.6 8.286E-05 8.286E-05 2.103E-04 327 593206.4 6.185E-05 6.135E-05 1.636E-04 328 599969.5 4.556E-05 4.556E-05 1.261E-04 329 606809.6 3.307E-05 3.307E-05 9.629E-05 330 613727.7 2.364E-05 2.364E-05 7.279E-05 331 620724.8 1.661E-05 1.661E-05 5.444E-05 332 627801.6 1.145E-05 1.145E-05 4.027E-05 333 634959.0 7.738E-06 7.738E-06 2.945E-05 334 642198.1 5.110E-06 5.110E-06 2.128E-05 335 649519.7 3.291E-06 3.291E-06 1.519E-05 336 656924.7 2.061E-06 2.061E-06 1.010E-05 337 664414.2 1.251E-06 1.251E-06 7.439E-06 338 671989.1 7.326E-07 7.326E-07 5.104E-06 339 679650.3 4.120E-07 4.120E-07 3.456E-06 340 687398.9 2.21*E-07 2.212E-07 2.309E-06 341 695235.8 1.125E-07 1.125E-07 1.523E-06 342 703162.1 5.367E-08 5.367E-08 9.926E-07 343 711178.7 2.373E-08 2.373E-08 6.397E-07 344 719286.7 9.573E-09 9.573E-09 4.081E-07 345 727407.2 3.444E-09 3.444E-09 2.581E-07 346 735701.1 1.072E-09 1.072E-09 1.619E-07 347 744169.6 2.755E-10 2.755E-10 1.009E-07 343 752653.8 5.451E-11 5.451E-11 6.250E-08 349 761234.7 7.357E-12 7.357E-12 3.849E-08
M ML M M M' M M M M lM M M MJ M M M CottPUTED C0ffCEtiTRATIONS FROH TIME T= 0.0 (SECS) TO TIttE Tm 9.550E+05 (SECS) , DATA POINT TIME ARRAY HAXIffUti C0tiCENTRATION OUTSIDE C0ffCENTRATION INSIDE CONCEffTRATION hut 13ER tSECS3 i Gtt/N3 ) ( Gt1/H3 ) ( G!t/tt3 ) 350 769913.4 5.38?E-13 5.389E-13 351 778691.0 2.357E-08 1.265E-14 1.265E-14 1.436E-08 352 787568.7 1.617E-17 353 796547.7 1.617E 8.693E-09 0.0 0.0 5.234E-09 354 805629.0 0.0 355 814813.8 0.0 3.133E-09 0.0 0.0 1.e65E-09 354 824103.4 0.0 0.0 357 833498.8 1.103E-09 0.0 0.0 6.48?E-10 350 843001.4 0.0 359 852612.3 0.0 3.793E-10 0.0 0.0 2.204E-10 360 862332.8 0.0 0.0 361 1.272E-10 872164.1 0.0 0.0 7.302E-11 362 082107.5 0.0 0.0 363 892164.2 4.163E-11 0.0 0.0 2.359E-11 364 902335.7 0.0 0.0 1.328E-11 365 912623.0 0.0 366 923027.7 0.0 7.424E-12 0.0 0.0 4.124E-12 367 933550.9 0.0 0.0 368 2.276E-12 944194.2 0.0 0.0 1.247E-12 369 954958.8 0.0 0.0 6.789E-13 P w to i
. - . . ~ . _ . . . _ _ . - . - . . . _ - - - - - . - . - . . . . . . _ . . - . . . -
Q M M S M~ & M & S S U Y S S T0XIC CHEltICAlmen SULFURIC ACID *ze SOURCE: BRUCE MANSFIELD CitEHICAL TYPE 3 HIGH BOILING PCIrlT STABILITY CLASS I G i APPRCX. NUllSER OF DATA POINTS
- 350 I?iCREt1ENT OF OUTPUT REQUESTS
- 100 TEHPERATURE (C)
- 4.000E+01 HIND SPEED (II/SEC) : 4.900E-01 I RECEPTCR HEIGHT (11) : 0.0 SOURCE HEIGHT (ft)
- 0.0 LIQUID DENSITY (G/CC) : 1.830E+00 i VErlT FLOH RATE (CitS)
- 9.440E-02 CCitTROL ROCil AIR SPACE (H3) 1.671E+03
} SUBSTt.NCE INITIAL HASS (G) : 1.390E+08 l RECEPTCR DISTAtlCE (11)
- 3.0SOE+03
} CENTERLINE DISTANCE (II) 3 0.0 f. t LIMIT HArtE LIMIT VALUE j TC?:IC LIttIT 1.000E-03 (G/tt3 ) 1 SAT. VAP. PRESS. AT TA (tetliG)
- I.000E-03 OIFFUSION COEFFICIENT (Cit 2/S) -
2.000E-01 HCLECULAR HEIGHT (G/tt0L) : 9.810E+01 TI!!E REQUIRE 0tSEC) TO REACH THE HAX. SPILL AREA IS 78.25 m I i i
S E E E E E E E E % E E E E' E E- E E E C0f fPUTED C0tiCErlTRATI0ttS FRott TIME T= 0.0 (SECS) TO TittE Tm 9.932E+05 (SECS) DATA POINT TIME ARRAY ttAXIt!Ulf CottCEtiTRATIOff OUTSIDE C0t4CENTRATIOtt ItiSIDE COriCEf4TRATIort llutt,ER ISECS) ( Gtt/tt3 ) (Git /tf3 ) ( Git /II3 ) 1 0.0 0.0 0.0 0.0 2 6224.5 1.596E-07 1.596E-07 4.733c-08 3 6302.7 2.486E-05 2.486E-05 1.548E-07 4 6588.8 2.486E-05 2.486E-05 5.521E-07 5 6837.8 2.486E-05 2.486E-05 9.601E-07 6 7200.4 2.486E-05 2.486E-05 1.379E-06 7 7527.2 2.486E-05 2.486E-05 1.800E-06 8 7868.8 2.486E-05 2.486E-05 2.249E-06 9 8226.0 2.486E-05 2.486E-05 2.701E-06 10 8599.3 2.486E-05 2.486E-05 3.163E-06 11 8987.6 2.486E-05 2.486E-05 3.636E-06 12 9397.6 2.486E-C5 2.486E-05 4.120E-06 13 9024.1 2.486E-05 2.486E-05 4.614d-06 14 10269.7 2.486E-05 2.486E-05 5.118E-06 15 10736.0 2.486E-05 2.486E-05 5.631E-06 16 11223.3 2.486E-05 2.486E-05 6.153E-06 17 11732.6 2.486E-05 2.486E-05 6.684E-06 18 12265.1 2.486E-05 2.486E-05 7.223E-06 19 12821.0 2.486E-05 2.466E-05 7.769E-06 23 13403.7 2.486E-05 2.486E-05 8.322E-06 21 14012.0 2.486E-05 2.486E-05 8.880E-06 22 14648.0 2.486E-05 2.406E-05 9.444E-06 p 23 15312.0 i.486E-05 2.486E-05 1.001E-05 ( 24 16007.7 2.486E-05 2.486E-05 1.058E-05 rs 25 16734.2 2.486E-05 2.486E-05 1.116E-05 26 17493.7 2.486F-05 2.486E-05 1.173E-05 27 18287.7 2.486E-05 2.486E-05 1.231E-05 28 19117.6 2.486E-05 2.486E-05 1.289E-05 27 199ES.3 2.486E-05 2.486E-05 1.346E-05 30 20892.3 2.486E-05 2.486E-05 1.403E-05 31 21840.5 2.486E-05 2.486E-05 1.459E-05 32 22831.7 2.486E-05 2.486E-05 1.515E-05 33 23868.0 2.486E-05 2.486!-05 1.570E-05 34 24951.2 2.426E-05 2.486E-05 1.625E-05 35 260PT.6 2.486E-05 2.486E-05 1.67eE-05 36 27 '. 4 2.486E-05 2.4SSE-05 1.730E-05 37 28505.0 2.486E-05 2.4G6t-05 1.782E-05 38 29798.7 2.486E-05 2.436E-05 1.831E-05 39 31151.1 2.486E 05 2.486E-05 1.87sE-05 40 32544.8 2.486E-05 2.484E-05 1.92dE-05 41 34042.8 2.486E-05 2.48dE-05 1.971E-05 42 35587.8 2.486E-05 2.486E-05 2.014E-03 43 37203.0 2.486E-05 2.486E-05 2.053E-05 44 38071.4 2.486E-05 2.486E-05 2.094E-05 45 40656.5 2.486E-05 2.486E-05 2.132E-05 46 42501.7 2.436E-05 2.486E-05 2.167E-05 47 44430.7 2.436E-05 2.486 -05 2.200t-05 a3 46447.1 2.486E-05 2.486E-05 2.230E-05 49 48355.0 2.466E-G5 2.486E-05 2.259E-05 4
p p M M M W W W W M' W W M M M W mm C0lFUTED CCitCEtITRATIONS FR0tt TIffE T= 0.0 (SECS) TO TIHE T= 9.932E+05 (SECS) DATA POINT TIME AR'tAY HAXItMt CONCENTRATION CUTSIDE CONCENTRATI0ft INSIDE CONCENTRATION tu t3ER (SECSI ( GtVH3 ) ( GtVe13 ) ( GiVII3 3 50 50758.9 2.486E-05 2.486E-05 2.286E-05 51 53062.6 2.486E-05 2.486E-05 2.310E-05 52 55470.9 2.486E-05 2.486E-05 2.333E-05 53 57983.4 2.486E-05 2.486E-03 2.353E-05 54 60620.2 2.486E-05 2.486E-05 2.371E-05 55 63371.4 2.486E-05 2.486E-05 2.3C8E-05 56 66247.6 2.486E-05 2.486E-05 2.403E-05 57 69254.2 2.486E-05 2.486E-05 2.416E-05 58 72397.3 2.486E-05 2.486E-05 2.427E-05 59 75683.1 2.486E-05 2.486E-05 2.437E-05 60 79118.0 2.486E-05 2.486E-05 2.446E-05 61 82708.7 2.486E-05 2.486E-05 2.453 E-05 62 86462.5 2.486E-05 2.486E-05 2.459E-05 63 90386.6 2.486E-05 2.486E-05 2.465E-05 64 94488.8 2.486E-05 2.486E-05 2.449E-05 65 98777.2 2.486E-05 2.486E-05 2.473I-05 66 103260.2 2.486E-05 2.486E-05 2.476E-05 67 107946.8 2.486E-05 2.486E-05 2.478E-05 68 112846.0 2.486E-05 2.486E-05 2.480E-05 69 117967.5 2.486E-05 2.485E-05 2.482E-05 70 123321.6 2.486E-05 2.486E-05 2.483E-05 71 128918.6 2.486E-05 2.486E-05 2.484E-05
$3 (a 72 134769.5 2.486E-05 2.486E-05 2.484E-05 (n 73 140886.1 2.486E-05 2.486E-05 2.485E-05 74 197280.3 2.486E-05 2.486E-05 2.485E-05 75 153964.6 2.486E-05 2.486E-05 2.486E-05 76 160952.4 2.486E-05 2.486E-05 2.486E-05 77 168257.2 2.486E-05 2.406E-05 2.486E-05 78 175893.6 2.486E-05 2.486E-05 2.486E-05 79 183876.5 2.486E-05 2.486E-05 2.486E-05 80 192221.7 2.486E-05 2.486E-05 2.486E-05 81 200945.8 2.486E-05 2.486E-05 2.486E-05 82 210065.9 2.486E-05 2.486E-05 2.486E-05 83 219599.9 2.486E-05 2.486E-05 2.406E-05 84 229566.6 2.486E-05 2.486E-05 2.486E-05 85 239985.6 2.486E-05 2.486E-05 2.486E-05 86 250877.6 2.436E-05 2.486E-05 2.486E-05 87 262263.8 2.486E-05 2.486E-05 2.486E-05 88 274166.8 2.486E-05 2.486E-05 2.486E-05 - }0%Ki2Eun V81ue 89 286610.1 2.486E-05 2.486E-05 2.486E-C5 90 299618.1 2.486E-05 2.486E-05 2.486E-05 91 313216.4 2.486E-05 2.486E-05 2.486E-05 92 327432.0 2.486E-05 2.486E-05 2.486E-05 93 342292.7 2.486E-05 2.486E-05 2.486E-05 94 357827.9 2.486E-C5 2.486E-05 2.486E-05 95 374068.2 2.486E-05 2.486E-05 2.486E-05 96 391045.6 2.486E-05 2.486E-05 2.486E-05 97 408793.4 2.486E-05 2.486E-05 2.484E-05 98 427346.8 2.486E-05 2.486E-05 2.486E-05 99 446742.2 2.486E-05 2.486E-05 2.486E-05
y em W m W m M M M M M M M M M M m CCHPUTED CONCENTRATI0tts FROH TIME T= 0.0 (SECS) TO TIME T= 9.932E405 (SECS) DATA POINT TIHE ARRAY HAXIHUtl CONCENTRATI0ft OUTSIDE COriCENTRATION INSIDE CONCENTRATI0H HUtSER (SECS) ( GN/H3 ) ( Git /tf3 ) ( GiVif31 100 467017.9 2.486E-05 2.486E-05 2.486E-05 101 488213.9 2.486E-05 2.486E-05 2.486E-05 102 510371.8 2.486E-05 2.486E-05 2.486E-05 103 533535.4 2.486E-05 2.486E-05 2.486E-05 104 557750.2 2.486E-05 2.486E-C5 2.486E-05 105 583064.1 2.486E-05 2.486E-05 2.486E-05 106 609526.9 2.486E-05 2.486E-05 2.486E-05 107 637190.7 2.486E-05 2.486E-05 2.486E-05 108 666110.1 2.486E-05 2.486E-05 2.486E-05 109 696341.9 2.486E-05 2.486E-05 2.486E-05 110 727945.9 2.486E-05 2.486E-05 2.486E-05 111 760984.2 2.4e6E-05 2.486E-05 2.486E-05 112 795522.1 2.486E-05 2.486E-05 2.486E-05 113 831627.4 2.486E-05 2.486*-05 2.486E-05 114 869371.4 2.486E-05 2.486E-OS 2.486E-05 115 908828.4 2.486E-05 2.486E-05 2.486E-05 116 950076.2 2.486E-05 2,486E-05 2.486E-05 117 993196.1 2.486E-05 2.486E-05 2.486E-05 o e
T0XIC CHEHICALune CHLORINE *** SOURCE: CONRAIL CHEttICAL TYPE : LOH BOILIttG POItiT STA3ILI1Y CLASS : G APPROX. NUl!CER CF DATA POItiTS : 3S0 INCREttCNT OF CUTPUT REQUESTS : 101 TEftPERATURE (C) : 4.000E+01 HItID SPEED (H/SEC) : 4.9COE-01 RECEPTCR HEIGHT (t!) : 0.0 SOURCE llEIGHT tif) : 0.0 LIQUID CENSITY (G/CC) : 1.000E*00 VEtiT FLCH RATE (CitS) : 9.440E-02 CONTROL RCC!! AIR SPACE (H3) ' 1.671E+03 SUBSTAtiCE ItiITIAL ttASS (G) : 5.4'20E+07 RECEPTOR DISTAliCE (It) 6.480E+02 CEitTERLINE DISTAt4CE (til : 0.0 LIttIT HAME LIttIT VALUE T0XIC LIttIT 4.500E-02 (G/H3 ) BOILIt{G POINT TEMPERTATURE (C) . -3.410E+01 PUFF DEttSITY (G/CC)
- 2.490E-03 HEAT OF VAPORIZITION (CAL /G) -6.880E+01 SPECIFIC HEAT (CAL /GC) : 2.260E-01 ItlITIAL STATE OF SUBSTAttCE : CAS IttSTANTANEOUS PUFF HASS(G) 5.430E+07 TIME REQUIRED (SEC) TO REACH THE HAX. SPILL AREA IS 0.0 Z
m W W W M M M M W W W W M W W W W W CortPUTED CoriCErf7RATZ0f tS FRoll TDtE T= 1.213E+03 (SECS) TO TIlfE T= 9.083E+04 (SECSI CATA POINT TIttE ARRAY HAXIffUlf CONCErlTRATI0tt OUTSIDE CortCEt4TRATI0t4 It4 SIDE C0tiCEriTRATI0tt t4Ut(SER (SECS) i Gt1/t13 ) ( G!t/tf3 ) ( Gl1/t13 3 1 1113.2 5.525E-04 5.525E-04 2 1129.9 0.0 6.019E-03 6.019E-03 5.690E-06 3 1146.9 5.314E-02 5.314E-02 4 1164.1 5.667E-05 3.794E-01 3.794E-01 4.262E-04 5 1181.6 2.187E+00 2.187E+00 2.588E-03 6 1199.4 1.016E+01 1.016E+01 7 1217.4 1.2782-02 3.796E+01 3.796E+C1 5.143E-02 0 1235.8 1.140E+02 1.140E+02 9 1254.3 1.692E-01 0.747E+02 2.747E+02 4.573E-01 10 1273.2 5.309E+02 5.309E+02 1.022E+00 11 3292.4 8.220E+02 8.220E+02 12 1311.0 1.910E+00 1.019E+03 1.019E+03 3.027E+00 13 1322.4 1.044E+03 1."44E+03 14 1342.3 3.653E+00 9.183E+02 9.183E+02 4.681E+00 15 1362.5 5.467E+02 6.467E+02 16 1383.0 5.412E+00 3.646E+02 3.646E+02 5.820E+00 17 1403.8 1.646E+02 1.646E+02 18 1424.9 6.014E+00 5.953E+01 5.953E+01 6.070E+00 19 1446.4 1.727E+01 1.727E+01 20 1463.1 16.092E +001 - Mb0dEQM Yalue 4.019E+00 4.019E+00 6.089E+00 21 1490.2 7.515E-01 7.515E-01 22 1512.6 6.092E+00 1.130E-01 1.130E-01 6.075E*00 23 1535.3 1.370E-02 24 1.370E-02 6.067E+00 00 1559.4 1.339E-03 1.339E-03 25 1581.9 6.059E+00 1.039E-04 1.059E-04 6.051E+00 26 1605.7 6.777E-06 6.777E-06 27 1629.S 6.043E+00 3.521E-07 3.521E-07 6.035E+00 28 1654.3 1.40CE-08 1.408E-08 23 1679.2 6.026E+00 5.126E-10 5.126E-10 6.010E+00 30 1701.5 1.444E-11 1.444E-11 31 1730.1 6.00?E400 3.333E-13 3.333E-13 6.001E+00 32 1756.1 6.323E-13 6.323E-15 5.992E+00 33 1732.5 9.890E-17 9.8?CE-17 34 1809.3 5.9S3E+00 1.279E-10 1.279E-18 5.974E+00 35 1836.5 0.0 36 0.0 5.965E+00 1864.1 0.0 0.0 37 1892.2 5.955E+00 0.0 0.0 38 1920.6 5.946E+00 0.0 0.0 39 1949.5 5.936E+00 0.0 C.0 5.927E+00 40 1978.8 0.0 0.0 41 2000.6 5.917E+00 0.0 0.0 42 2030.8 5.907E+00 0.0 0.0 43 2069.5 5.G97E+00 0.0 0.0 44 2100.6 5.037E+00 0.0 0.0 45 2132.2 5.876E+00 0.0 0.0 45 2164.2 5.86?E+00 0.0 0.0 5.655:*00 47 2196.0 0.0 0.0 5.845E+00 a0 2227.8 0.0 C.0 49 2263.4 5.834E+00 0.0 0.0 5.023E+00
g g g g g M @ E E E E E E E E CCilPUTED CCf(CEttTPATICitS FR0!! TIlfE T= 1.113E+03 (SECS) TO TZitE Y= 9.8c3E+04 (SECS) DATA POIrlT Tr.fE ARRAY tlAXIttutt C0ftCEtiTPATI0tt DUTSIDE CoriCEtiTRATI0tt It4 SIDE C0fiCEttTRATIOtt tCA13ER (SECSI t G11/tt3 ) ( Gt t/t13 I ( Gtt/ti3 ) E3 2297.4 0.0 0.0 51 2332.0 5.811E+00 0.0 0.0 5.000E+00 52 2367.0 0.0 0.0 53 2402.6 5.7a?E+00 0.0 0.0 54 2433.8 5.777E+00 0.0 0.0 5.765E+00 55 0475.4 0.0 0.0 56 2512.7 5.753E+00 0.0 0.0 57 2550.4 5.741E+00 0.0 0.0 5.727E+00 SS 2503.8 C.C 0.0 59 2627.7 5.717E+00 0.0 0.0 60 0667.3 5.704E+C0 0.0 0.0 61 2707.4 5.691E+00 0.0 0.0 5.670E+00 62 2743.1 0.0 0.0 63 2789.4 5.665E+00 0.0 0.0 5.650E+00 64 2831.4 0.0 0.0 65 2873.9 5.639E+00 0.0 0.0 5.625E+00 66 2?l7.2 0.0 0.0 5.611E+00 67 C961.0 0.0 0.0 63 3003.6 5.593E+00 0.0 0.0 5.58' 4E+ 00 69 3050.3 0.0 0.0 70 3096.6 5.56?E+00 0.0 0.0 5.555E+00 71 3143.2 0.0 0.0 72 3190.5 5.540E+00 0.0 0.0 Lu 73 3030.5 5.525E+00
- 0.0 0.0 74 32S7.2 5.511E+00 0.0 0.0 5.495E+00 73 3336.6 0.0 0.0 76 3386.0 5.400E+00 0.0 0.0 5.46EE+00 77 3437.7 0.0 0.0 73 3487.4 5.449E+00 0.0 0.0 19 3541.9 5.433E+00 0.0 0.0 5.417E+00 80 3595.2 0.0 0.0 81 3 5'19 . 2 5.401E+00 0.0 0.0 5.384E+00 82 3704.1 0.0 0.0 83 3759.8 5.367E+00 0.0 0.0 5.351E+00 C4 3016.4 0.0 0.0 C5 3a73.7 5.333E+00 0.0 0.0 5.316E+00 85 3732.0 0.0 0.0 87 3991.1 5.299E+00 0.0 0.0 5.281E+00 BS 4051.2 0.0 0.0 E9 4112.1 5.263E+00 0.0 0.0 5.245E+00 90 4173.9 0.0 0.0 91 a236.7 5.027E+00
, 0.0 0.0 5.200E+00 92 4300.4 0.0 0.0 93 5.190C+00 4365.1 0.0 0.0 5.171E+00 94 4430.7 0.0 0.0 95 4497.4 5.152E+00 0.0 0.0 5.130E+00 96 4565.0 0.0 97 4633.7 0.0 5.113E400 0.0 0.0 5.093E+00 90 4703.4 0.0 99 4774.1 0.0 5.0732+00 0.0 0.0 5.053;+00
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y a e m e e a e m W W W m M M M C2!!PUTED CCitCEtiTPATIOfiS FRott TZifE T= 1.113E+03 (SECS) TO TIttE T= 9.033E+04 (SECS) DATA FOIffT tit!! ARRAY HAXItt'Jtt C0t.'CEt41RATI0tl OUTSIDE CONCENTRATIOtt it(SIDE C0iK.tNTRAT10tl PCIfBER (SECS 1 ( Cl1/1131 (G:t/tIII (Ctt/1131 250 45476.3 0.0 0.0 5.067E-01 251 46160.2 0.0 0.0 4.875E-01 252 45054.4 0.0 0.0 4.6005-01 253 47539.1 0.0 0.0 4.503E-01 254 48274.3 0.0 0.0 4.3262-01 255 49000.4 0.0 0.0 4.152E-01 256 49737.3 0.0 0.0 3.903E-01 257 50465.3 0.0 0.0 3.81eE-01 253 51244.6 0.0 0.0 3.65eE-01 259 5:015.3 0.0 0.0 3.502E-01 260 52797.6 0.0 0.0 3.351E-01 261 53591.7 0.0 0.0 3.204E-01 262 54397.7 0.0 0.0 3.061E-01 263 55215.9 0.0 0.0 2.923E-01 264 560rI6.3 0.0 0.0 2.789E-01 265 56809.2 0.0 0.0 2.659E-01 266 57744.8 0.0 0.0 2.534E-01 267 50613.3 0.0 0.0 2.412E-01 268 59494.8 0.0 0.0 2.295E-01 269 60389.6 0.0 0.0 2.18EE-01 270 61297.9 0.0 0.0 2.073E-01 271 62219.3 0.0 0.0 1.968E-01 272 63155.6 0.0 0.0 1.066E-01 2 73 64105.4 0.0 0.0 1.76SE-01 274 65069.5 0.0 0.0 1.675E-01 275 66048.2 0.0 0.0 1.535E-01 276 67041.6 0.0 0.0 1.498E-01 277 66049.0 0.0 0.0 1.415E-01 273 49073.2 0.0 0.0 1.336E-01 277 70112.1 0.0 0.0 1.260E-01 283 71166.5 0.0 0.0 1.187E-01 281 722?6.8 0.0 0.0 , 1.117E-01 282 73323.2 0.0 0.0 1.051E-01 283 74426.0 0.0 0.0 9.872E-02 204 75545.3 0.0 0.0 9.2672-02 265 76601.5 0.0 0.0 8.691E-G2 206 77034.7 0.0 0.0 8.143E-02 207 790C5.3 0.0 0.0 7.622E-02 283 80193.6 0.0 0.0 7.127E-02 209 81399.6 0.0 0.0 6.6 57E-02 290 82623.8 0.0 0.0 6.212E-02 291 83366.4 0.0 0.0 5.791E-02 292 85127.7 0.0 0.0 5.393E-02 293 85407.9 0.0 0.0 5.017E-02 294 87707.5 0.0 0.0 4.6612-02 295 89026.6 0.0 0.0 4.327E-02 295 90365.4 0.0 0.0 4.011E-02 277 91724.4 0.0 0.0 3.7152-C2 298 93103.9 0.0 0.0 3.4?dE-02 299 94504.1 0.0 0.0 3.175E-02
. _.__ _m _ . _ _ _ - . . _ - _ _ . _ _ _ _ . . _ . . _ _ _ _ _ _ _ . _ _ _ _ _ _ _ _ _ _ _ _ . - _ . . _ - _ - _~~___.._____m.._.__._,__,.__ _ .
W W M M M M M M M M M M M M M M M M I C0!PUTED C0f 4CEliTRATIOris FRO.I TIllE T: 1.113E+03 ( SECS) TO TIl!E T= 9.683E+04 (SECS) DATA POItiT TIltE ARRAY ltAXIf fUtl CCilCEtiTRATIori OUTSIDE COflCEtiTRATI0tl IftSIDE CCriCEtiTRATI0tt tiUlGER (SECS) ( Git /It3 ) ( Gt t/tt3 ) t G!!/fl3 3 300 95725.4 0.0 0.0 2.930E-02 301 97368.1 0.0 0.0 2.701E-02 302 98832.4 0.0 0.0 2.406C-02 I i b I l 1 )
g g M W W W W M E E E E E E E E E E E T0XIC CHEttICAL*** NAPTHA **. SOURCE: BARGE i CHE!!ICAL TYPE : HIGH BOILING FOIMT
! STABILITY CL ASS
- C AFFRCX, tCt3ER OF DATA FOINTS 350 INCRENENT OF CUTFUT RICUISTS
- 100 TE!!PERATURE (C)
- 4.000E+01 H!N3 SPEED (!!/SEC) . 4.900E-01 i i
RECEPTCR HEICHT (ft) 0.0 ! SCURCE HEIGHT (ft) - 0.0 l LIQUID DEN 3ITY (G/CC) 6.000E-01
] VENT FLO:1 RATE (CilS) 9.440E-02 CONTRCL RCC t AIR S? ACE (tt3) . 1.671E+03 i' SUCSTANCE INITIAL !! ASS (G) 4.10CE+09 RECEPTOR DISTANCE (tt) . 2.40CE+0C CENTERLINE CISTANCE (t!) - 0.0 l LIttIT NAffE LIttIT VALUE ACUTE LIttIT 4.000E-01 (G/tt3 )
( SAT. VAP. PRESS. AT TA (it! HG)
- 1.340E+02
[ DIFFUSICN CCEFFICIENT (Ct!C/S) 2.000E-01 l !!CLECULAR HEIGHT (G/t!CL) 7.81CE+01 TItfE REQUIRED (SEC) TO REACH THE ttAX. SPILT. AREA IS 744.65 C w b l l
I l 4 j COMPUTED CCNCENTRATIONS FR0!i TIME T: 0.0 (SECS) TO TIME T: 6.438E+05 (SECS) i i DATA POINT TIME A9 RAY HAXIMUlf CONCENTRATION CUTSIDE CONCENTRATION INSIDE CONCENTRATION I NUMSER ISECS) ( Gtt/H3 ) (Glt/H3 ) ( Git /H3 ) 1 0.0 0.0 0.0 0.0 0 489.8 9.971E+00 9.971E+00 2.721E-01 3 498.0 4.240E+01 4.240E+01 2.916E-01 4 506.3 5.639E+01 5.639E*01 3.181E-01 I 5 514.8 6.667E+01 6.667E,01 3.498E-01 1 6 523.4 7.513E+01 7.513E+01 3.862E-01 l 7 532.2 8.248E+21 8.2485+01 4.268E-01 8 541.1 8.905E+01 8.905E+01 4.714E-01 j 9 550.1 9.507E+01 9.507E+01 5.198E-01 i 10 559.3 1.006E+02 1.006E+02 5.718E-01 l 11 568.7 1.059E+02 1.059E+02 6.275E.01 ! 12 573.2 1.108E+02 1.108E+02 6.868E-01 i 13 5S7.9 1.156E+02 1.156E+02 7.495E-01 l 14 597.7 1.201E+02 1.201E+02 8.15SE-01 ! 15 607.7 1.244E+02 1.244E+02 8.857E-01 l 16 617.9 1.286E+02 1.286E+02 9.590E-01 l 17 628.2 1.327E+02 1.327E+02 1.036E+00 ) 18 638.8 1.366E+02 1.366E+02 1.116E+00 j 19 649.4 1.405E+02 1.405E+02 1.201E+00 1 20 660.3 1.442E+02 1.442E+02 1.288E400 l 21 671.4 1.479E+00 1.479E+02 1.380E+00 l 22 682.6 1.515E+02 1.515E+02 1.475E+00 ^ 23 694.0 1.550E+00 1.530E+02 1.574E+00 IU 24 705.6 1.59EE+02 1.5SSE+02 1.677E+00 SP 25 717.4 C' 1.619E+02 1.619E+02 1.784E+0C 1 26 729.4 1.653E+02 1.653E+02 1.895E+00 l 27 741.7 1.686E+02 1.686E+02 2.010E+00 1 28 754.1 1.719E402 1.719E+02 2.129E+00 j 29 766.7 1.751E+02 1.751E+02 2.252E+00 1 30 779.5 1.783E+02 1.783E+02 2.380E+00 l 31 792.6 1.81EE+02 1.815E+02 2.510E+00 ! 32 805.8 1.846E+02 1.8465+02 2.643E+00 33 819.3 1.878E+02 1.878E+02 2.789E+00
- 34 833.0 1.909E+02 1.909E+02 2.935E+00
) 35 847.0 1.939E+02 1.939E+02 3.085E+00 36 861.1 1.970E+02 1.970E+02 3.240E+00 I I 37 875.5 2.000E+02 2.000E+02 3.400E+00 33 890.2 2.030E+02 2.030E+02 3.566E+00 ! 39 905.1 2.060Z+02 2.060E+00 3.736E+00 40 900.2 2.090E+02 2.090E+02 3.911E+00 41 935.6 2.119E+02 2.119E+00 4.092E+00 42 951.3 2.14SE+02 2.149E+00 4.2795+00 43 967.2 2.178E+02 2.176E+02 4.471E+00 44 933.4 2.207E+00 2.207E+02 4.66CE+00 45 999.9 2.236E+02 2.236E+02 4.872E+00 ,l 46 1016.6 2.266E+02 2.266E+02 5.0c1E+00 47 1033.6 2.295E+02 2.29EE+02 5.297E+00 48 1050.9 2.303E+02 2.323E+02 5.519E+00 49 1053.5 0.352E+00 2.352E+02 5.747E+03 l I l
g g g g g M E E i i j CCM?UTED CC CENTRATIOMS FROM tit!5 T= t! . 0 (SECS) TO TI!!E T= 6.438E+05 (SECS) l DATA POINT q TI!!E ARRAY HAXIMUtf CCNCENTRATICN j MUtCER (SECS) OUTSIDE Cc. CENTRATION INSIDE CCNCENTRATION (CH/H3I IGMMt3) i t G?tMf3 ) i 3 50 1086.4 2.381E+02 4 51 1104.5 2.381E+02 5.981E400 j 2.410E+02 2.410E+02 52 1123.0 2.439E+02 6.223E+00 53 1141.8 2.439E+02 6.471E+00 2.467E+02 2.46TE+02 54 1160.9 2.496E+02 6.726E+00 55 1180.4 2.496E402 6.9ESE+00 2.525E+02 2.525E+0 ) 56 1200.1 2.553E+02 7.257E+00 4 57 1220.2 2.553E+02 7.534E+00 2.582E+02 2.582E+02 53 1234.4 2.600E+02 7.818E+00 59 125S.1 2.600E+02 8.021E+00 2.575E+02 2.575E+02 60 1276.1 8.312E+00 2.574E+02 2.574E+02 61 1297.5 8.608E+00 2.572E+02 2.572E+02 62 1319.2 8.908E+00 0.571E+02 2.571E+02 63 1341.2 2.570E+02 9.212E+00 64 1363.7 0.570E+02 9.521E+00 2.548E+02 2.568E+02 65 13e6.5 9.634E+00 2.567E+02 2.567E+02 66 1409.7 2.565E+02 1.015E+01 67 1433.3 0.565E+02 1.047E+01 2.564E+02 2.564E+02 63 1457.3 1.0E0E+01 2.562E+0 2.562E+02 69 1491.7 2.560E+02 1.ll3E+01 70 1536.5 2.560E+02 1.147E+01 2.559E+02 2.559E+02 ts 71 1531.7 1.181E+01 2.557E+02 2.557E+02 b 72 1557.3 2.556E+02 2.556E+02 1.216E+01
~4 73 1533.4 1.251E+01 2.554E+02 2.554E+02 74 1609.9 1.287E+01 2.550E+02 2.552E+02 i 75 1636.8 1.323E+01
' 2.551E+02 f.55?E+02 76 1664.2 1.360E+01 2.549E+02 ' 2.54,E+02 1.397E+01
; 77 1694.1 0.547E+02 2.547E+02 1.435E+01 l 73 1720.4 2.54EE+02 l 79 1749.2 2.545E+02 1.474E+01
' 2.543E+02 2.543E+02 1.513E+01 i C3 1778.4 2.541E+02 i 81 1830.2 2.541E+02 1.552E+01 ' l 2.540E+02 2.540E+02 1.590E+01 82 1833.4 2.538E+02 2.53BE+02 1.633E+01 ! 83 IE69.2 2.5365+02 2.536E+02 l 84 1900.5 1.674E401 1 2.534E+02 2.534E*02 1.716E+01 85 1932.3 2.532E+02 86 2.532E+02 1.75aE+01 1964.6 2.530E+02 2.530E+02 87 1997.5 1.801E+01 2.527E+02 2.527E+02 1.845E+01 88 2030.9 2.525E+02 0.525E+02 1.899E+01 S9 2064.9 2.523E+02 2.523E+02 90 2099.5 1.934I+01 0.521E+02 2.521E+02 1.9795+01 91 2134.6 2.519E+02 2.519E+02 2.025E+01 92 2170.3 2.516E+02 2.516E+02 93 2 06.7 2.072E+01 2.514E+02 2.514E+02 2.119E+01 94 2243.6 0.512E+02 95 2.512E+02 2.167E+01 2281.1 2.507E+02 2.509E+02 96 2319.3 2.215E+01 2.507E+02 2.507E+02 0.26EE+01 97 2353.1 2.505E+02 93 2.505E+02 2.31EE+01 2397.6 0.502E+02 2.502E+02 99 2437.7 2.36EE+01 2.500E+0 2.500E+02 2.416E+01 l l
g g g g g g M M M E E E O E E I COMPU7ED CCNCENTRATICNS FROM TIME T= 0.0 (SECS) TO T1HE T= 6.4385+05 (SECS) DATA PCINT TIME ARRAY ttAXIMUtf CCNCENTRATION NUtCER OUTSIDE CONCENTRATICH INSIDE CONCENTR4 TION (SECS 1 IGM /H3) il ( G t/lf 3 ) ( G!!/f t3 3 d i 100 2473.5 2.497E+02 j 101 2.497E+02 2.468E+01 2500.0 2.494E+02 102 2.494E+CE 0.521E+01 1 0560.1 2.492E+02 2.490E+00 l 103 0605.0 2.574E+01 ' 2.489E+02 2.489E+02 2.62SE+01 104 0643.6 2.486E+02 2.486E402 l 9 105 2692.9 2.6 83 E + 01 2.4S3E+02 2.483E+02 2.73SE+01 l 106 0738.C 2.481E+02 2.491E+02 ?.794E+01 ] 107 2783.8 0.473E+02 103 0.418E+0 0.851E+01 l 2830.4 2.475E+02 2.475d+00 i 109 C877.8 0.909E+01 0.472E+00 0.472E+C2 2.967E+01 1 110 2925.9 2.469E+0 j 111 2.469E+02 3.006E+01 2974.9 2.466E+02 l 2.466E+02 3.086E+01 112 3004.7 0.463E+C2 0.463E+02 113 3075.3 3.146E+01 2.460E+02 2.46CE+02 3.00SE+01 i i 114 3106.7 2.456E+02 l 115 2.456E+02 3.270E+01 i 3179.1 2.453E+02 2.453E+02 , ' 116 3:32.3 3.33CE+01 ' 2.450E+0 0.450E+02 3.396E+01 117 3:e6.3 2.446E+02 118 2.446E+02 3.460E+01 3341.3 0.443E+02 2.443E+02 . 119 3397.3 3.525E+01 ! 2.440E+02 2.440E+02 3.591E+01
- 100 3454.1 2.436E+00 2.436E+02 ,
ts 1 1 3511.9 3.658E+01 2.432E+02 2.43 E+02 3.725E+01 [r 120 3570.7 2.429E+0: 0.409E+02 i CD 123 3630.4 3.793E+01 i 2.405E+02 2.405E+02 3.860E+01 104 3691.0 2.421E+02 ! 2.401E+C2 3.932E+01 105 3753.0 0.418E+02 0.41eE+02 4.003E+01 l 106 3615.8 0.414E+02 2.414E+02 107 387).6 4.074E+01 2.41CE+02 2.41CE+C2 4.146E+01 123 3944.5 2.406E+0 0.406E+02 ! 109 4C10.5 4.219E+01 ! 2.402E+02 2.400E+02 4.293E+01 130 4077.7 2.393E,02 2.398E+02 131 4145.9 4.367E+01 0.393E+02 2.393E+02 4.440E+01 130 4015.3 2.389E+02 2.339E+0 133 40S5.8 4.518E+01 - 2.335E+02 2.305E+02 4.595E+01 134 4357.5 2.381E+C0 I 2.361E+02 4.673E+01 135 4430.5 2.3765+02 j 136 2.376E+00 4.751E+01 45C4.6 0.37 E+0: 2.372E+CC 137 4580.0 4.S31E+01 2.367E+00 0.367E+C 4.911E+Cl 133 4656.6 2.360E+0 i 0.362E+C2 4.99 E+01 139 4734.6 0.353E+02 l 2.353E+02 5.073E+01 143 4013.8 2.353E+02 2.353E+02 l 141 4594.3 5.156E+01 I 2.340E+02 2.3482+02 5.239E+01 140 4976.0 0.343E+00 0.343E402 l 143 5039.5 5.303E+01 0.33eE+C 2.3:SE+02 5.40cE+01 144 5144.2 2.333E+02 145 2.333E+0: 5.493E+01 I 5:33.3 2.323E+02 2.303E+02 146 5317.S 5.5SOE+01 2.303E+00 2.303E+02 5.667E+01 l 147 5406.8 2.317E+02 ! 0.317E+02 5.754E+01 14S 5497.3 C.310E+0: 2.312E+C2
- 14) 5509.3 5.843E+Cl 0.306E+00 2.306E+00 5.930E*01 ;
I
g M mM W W M M M M M W W W W W W W W CC?tPUTED CCNCENTRATIONS FR0tt TIME T= 0.0 (SECS) TO TIttE T 6.438E+05 (SECS) DATA POINT tit!E MRAY HAXItMf CCNCENTRATICH CUTSIDE CCNCENTRATICH INSIDE CCNCENTRATICN NU::SER (SECS) ( Gtt/tt3 ) (G"/H3) (GH/M3) 150 5582.8 2.301E+02 2.301E+02 6.022E+01 151 5777.9 2.295E+02 2.295E+02 6.113E+01 i 152 5874.6 2.289E+02 2.289E+02 6.204E+01 153 5972.9 2.2C4E+02 2.284E+02 6.296E+01 154 6072.9 2.278E+02 2.27GE402 6.389E+01 155 6174.5 2.272E+02 2.272E+02 6.483E+01
'.56 6277.8 2.266E+02 2.266E+02 6.577E+01 157 6382.9 2.260E+02 2.260E+02 6.672E+01 153 6489.7 2.253E+02 2.253E+02 6.767E401 159 6598.3 2.247E+02 2.247E+02 6.863E+01 163 6703.7 2.241E+02 2.241E+02 6.960E+01 161 6821.0 2.234E+02 2.234E+02 7.057E+01 162 6935.1 2.227E+02 2.227E+02 7.155E+01 163 7051.2 2.221E+02 2.221E+02 7.253E+01 164 7169.2 2.214E+02 2.214E+02 7.352E+01 165 72S9.1 2.207E+02 2.207E+02 7.452E+01 166 7411.1 2.200E+02 2.200E+02 7.552E+01 167 7535.1 2.193E+02 2.193E+02 7.652E+01 168 7661.0 2.106E+02 2.186E+02 7.753E+01 169 7739.4 2.178E+02 2.178E+02 7.854E+01 170 7919.8 2.171E+02 2.171E+02 7.956E+01 7sr171 8052.3 2.163E+02 2.163E+02 8.058E+01 172 8187.1 2.156E+02 2.156E+02 8.160E+01
- 173 8324.1 2.148E+02 2.148E+02 8.263E+01 174 8463.4 2.140E+02 2.140E+02 8.366E+01 175 8605.0 2.132E+02 2.132E+02 8.469E+01 176 8749.0 2.124E+02 2.124E+02 8.573E+01 177 8895.4 2.116E+02 2.116E+02 8.676E+01 178 9044.3 2.10SE+02 2.108E+02 8.780E+01 179 9195.6 2.099E+02 2.099E+02 8.884E+01 180 9349.5 2.091E402 2.091E+02 8.98SE+01 181 9506.0 2.082E+02 2.082E+02 9.092E+01 102 9665.0 2.073E+02 2.073E+02 9.197E+01 183 9826.8 2.065E+02 2.065E+02 9.301E+01 184 9991.2 2.056E+02 2.056E+02 9.403E+01 185 10158.4 2.046E+02 2.046E+02 9.509E+01 186 10323.4 2.037E+02 2.037E+02 9.613E+01 187 10501.3 2.028Et02 2.028E+02 9.716E+01 183 10677.0 2.018E+02 2.018E+02 9.820E+01 169 10855.7 2.009E+02 2.009E+02 9.923E+01 190 11037.3 1.999E+02 1.999E+02 1.003E+02 191 11222.1 1.989E+02 1.989E+02 1.013E+02 192 11409.8 1.979E+02 1.979E+02 1.023E+02 193 11600.8 1.959E+02 1.969E+02 1.033E+02 194 11794.9 1.959E+02 1.959E+02 1.043E+02 195 11992.3 1.948E+02 1.942E+02 1.053E+02 196 12193.0 1.930E+02 1.930E+02 1.063E+02 197 12397.0 1.927E+02 1.927E+02 1.073E+02 193 12604.5 1.917E+02 1.917E402 1.083E+02 199 12615.4 1.926E+02 1.906E+02 1.093!+02
1 t m e e e e m e m e M me e W W W } j COMPUTED CCNCEtiTRATIONS FRCtf TIME T= 0.0 (SECS) TO TIME T: 6.438E+05 (SECS) DATA POINT TItfE ARRAY HAXIIV! CCMCENTRATION I. OUTSIDE CCMCENTRATION INSIDE CONCENTRATI0t1 NUMBER (SECSI (GM/H3) (GM/H3) ( Cit /H3 ) i 200 13029.9 1.895E*02 1.895E+02 201 13247.9 1.102E+02 1.CS3E+02 1.833E+02 1.112E+02 202 13469.6 1.872E+C2 1.87CE+02 1.121E+02 203 13695.0 1.661E+02 1.861E+02 204 13924.2 1.131E+02 1.849E+02 1.849E+02 1.140E+02 205 14157.2 1.eI7E+02 1.837E+02 206 14394.1 1.149E+02 1.826E+02 1.826E+02 1.153E+02 j 207 14635.0 1.814E+02 1.814E+02 208 14879.9 1.167E+02 1.801E+02 1.801E+02 1.176E+02 1 209 15123.9 1.789E+02 1.789E+02 210 1.184E+02 15382.1 1.777E+02 1.777E+02 1.193E+02 211 15639.5 1.764E+02 1.764E+02 1.201E+02 212 15901.2 1.751E+02 1.751E+02 213 1.209E+02 16167.3 1.739E+02 1.739E+02 1.217E+02 214 16437.9 1.726E+02 1.726E+02 215 1.225E+02 16712.9 1.712E+02 1.712E+02 1 1.232E+02 216 16992.6 1.699E+02 1.699E+02 l 1.239E+02 017 17277.0 1.686E+02 1.686E+02 1.247E+02 218 17566.1 1.672E+02 1.672E+02 219 1.253E+02 17360.1 1.652E+02 1.658E+02 1.260E+02 220 18153.9 1.645E+02 1.645E+02 1.267E+02
$# 221 18452.8 1.631E+02 1.631E+02 1.273E+02 AD 222 10771.8 1.616E+02 1.616E+02 1.279E+02 C3 223 19065.9 1.602E+02 1.600E+02 1.284E+02 224 19405.3 1.508E+02 1.5SSE+02 1.290E+02 225 19730.1 1.5!3E+02 1.573E+02 1.295E+02 226 20060.2 1.553E+02 1.558E+02 1.300E+02 227 20395.9 1.544E+02 1.544E+02 1.304E+02 228 20737.2 1.529E+02 1.529E+02 1.309E*02 229 21084.3 1.513E+02 1.513E+02 1.313E+02 230 21437.1 1.498E+02 1.493E+02 1.316E+02 231 21795.9 1.4S3E+02 1.423E+02 1.320E+02 232 22160.6 1.467E+02 1.467E+02 1.323E+02 233 22531.4 1.451E+02 1.451E+02 1.325E+02 t E34 22903.5 1.436E+02 1.435E402 1.320E+02 i 235 23291.9 1.420E+02 1.400E+02 1.330E+02 236 2 501.7 1.404E+02 1.404E+02 1.331E+02 l 237 24073.0 1.337E+02 1.337E+02 1.333Es 2 l 239 24460.9 1.371E+02 1 371E+02 1.333E*02 i 239 24090.5 1.355E+02 1.35E:+02 240 25307.1 1.330E+02 1.3!CE*0b IT TEM) - Maximum Value 1.;5-L+C-l 241 25730.6 1.321E+02 1.321E+02 1.334E+02 6 242 26161.2 1.304E+02 1.304E+02 1.3332+02 l 243 26599.0 1.25?E+02 1.287E+22 1.332E*02
l 244 27044.1 1.2702302 1.270E+02 1.3302+02 245 27496.7 1.233E+02 1.253E+0'i 1.32SE+02 246 27956.8 1.276E922 '
..I .236E +02 1.326E+02 247 28424.7 1.2185+02 11216E+02 1.323E+02 243 28900.3 1.2015+02 1.201E+02 1.320E+02 29334.0 239 1.1S3E+02 1.183E+02 1.315E+02 '
l - 1 - i t e l, l I _ _ . _ _ _ _ _ _ _ _ _ _ _ _ . _ _ _ . _ _ _ _ _ _ _ __Ei_ _ ______ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ . _ _ _ _ _ _ ____ ___ . _ _ _
g g g g g e e m m M m W W: M W M' M M C0!!P'CED CONOENTRATIONS FRCit TItt! I: 9.0 (SECS) TO TIME T= 6 N3GE+05 (SECS) l DATA POINT tit!E ADAY FtAXItut CCNCENTRATION OUTSIDE,CONCENTR* TION INSIDE CONCENTRATICN tut 3ER ISECS) ( GitM f3 ) ( C,H/t t3 )
- 1. s s
( Givit3 ) l 9 050 098)5.7 1.165E+02 I 1.1662+0 1.312E+72 30375.7 .' 25.1 1.148E+02' l.148E+02 1.308E+02 252 30834.0 1.130E+02 l'.130E+02
' 1.300E+02^
253 31400.8 i 1.112E+02 1.ll:E+02 1.297E+02 ' 254 31906.s3 1.094E+02 1.014E+02 1.291E+02 055 3:460.6 l.075E+02 1.0'/3E,02 1.095E+02 254 33033.6 1.057E+02 1.057E+02 1.27CE+02 257 33556.1 1.039E+02 1.039E+02 1.270E+02 258 34117.6 1.020E+0 1.020F+02
~
i.063E+02 059 34638.6 1.002E+02 2~002E+02 1.254E+0: 260 35069.1 9.834E+01 v.83cE+01 1.246E402 061 3E657.3. 9.649E+01 9.649 d+01 1.236E+02' 262 36459.4 9.46?E*01 9.462E+01 1.227E+02 063 37049.5 9.275E+01 9.275E+01 1.217E+02 264 37689.9 9.089E+01 9.083E+01 ' 265 l.206E+02 38320.6 8.901E+01 ' 8.901E+01 1.195E+0 266 38961.9 0.713E+Cl 8.713E+01 1.183E+02 067 39613.9 8.505E*01 8.7 5E+01 1.171E+02 268 40276.3 8.337E+01 8.337E+01 1.159E+02 269 4C950.8 8.14SE+01 8.148E+01 1.146E+02 270 41636.1 7.960E+01 7.960E+01 1.173E+02 271 42332.9 7.77 E+01 7.772E+31 1.119E+02 272 43041.4 7.5S4F+01 7.584E+01 1.105E+02 IU 273 43761.7 7.395E+01 7.395E+01 1.090E+02~
%n 274 44494.0 7.203E+01 7.20SE+01 1.075E+02 275 45038.7 7.000E+01 7.000E+01 1.060E+02 276 45995.7 6.833E+01 6.833E+01 1.044E+02 277 46765.5 6.646E+01 6.646E+01 1.028E+02 278 47548.0 6.459E+01 6.459E+01 279 1.012E+02 4S343.8 6.273E+01 6.273E+01 9.947E+01 083 49152.8 6.08GE+01 6.000E+01 9.774E+01 2S1 49975.4 5.904E+01 5.904E+01 9.599E+01 292 50911.8 5.700E+01 5.720E+01 9.400E+01 083 51662.1 5.537E+01 5.537E+01 9.237E+01 ES4 52526.6 5.355E+01 5.355E+01 9.052E+01 085 53405.6 5.174E+01 5.174E+01 8.864E+01 006 54099.4 4.994E+01 4.994E+01 8.674E+01 287 55208.1 4.815E+01 4.815E+01 8.481E+01 298 56130.0 4.637E+01 4.637E+01 8.28EE+01 089 57071.4 4.460E+01 4.460E+01 S.087E+01 290 53006.5 4.285E+01 4.235E+01 7.8SS2+01 291 5S997.5 4.lllE+01 4.111E+01 7.666E+01 092 59994.8 3.93SE+01 3.93SE+01 7.493E+01 293 609E3.7 3.767E+01 3.767E+01 7.27eE+01 294 620C9.4 3.598E+01 3.598E+01 7.07 E+01 095 63047.1 3.429E+01 3.429E+01 6.864E+01 096 64100.2 3.263E+01 3.263E+01 6.656E+01 097 65175.0 3.09SE+01 3.09EE+01 6.447E401 29S (6265.7 2.935E+01 2.9?5E+01 6.2372+01 297 67374.7 0.774E+01 2.774E*01 6.006E+01
COMPUTED CCtCENTRATIONS FROM TIME T= 0.0 (SECS) TO TIME T= 6.438E+05 (SECS). DATA POINT TIME ARRAY HAXIMUff CONCENTRATION OUTSIDI CCNCENTRATICH INSIDE CONCENTRATION FL?OER (SECS) ( G:t/t t3 ) ( it/H3) ( Git /It3 ) 300 68502.2 2.615E+01 2.615E+01 5.816E+0! 301 69648.6 2.458E+01 2.458E+01 5.605E+01 302 70914.1 2.!O3E+01 2.303E+01 5.395E+01 1 303 71999.1 2.150E+01 0.153E 01 5.185E+01 1 304 73204.1 0.000E+01 2.C00Et01 4.975E+01 305 74429.1 1.853E+01 1.853E+01 4. 76 6 E+ 01 306 75674.6 1.708E+01 1.70aE+01 4.55BE+01 307 76941.0 1.567E+01 1.567E+01 4.3ECE+01 308 78208.6 1.430E+01 1.430E+01 4.3476+01 i l 309 79537.7 1.297E+01 1.297E+01 3.944E+01 310 80868.7 1.168E+01 1.168E+01 3.743E+01
- 311 8 222.1 1.045401 1.045E+01 3.544E+01 312 83598.1 9.276E+00 9.076E+00 3.346E+01 j 313 84997.1 8.16EE+00 8.168E+00 3.156E+01 314 86419.4 7.130E+00 7.130E+00 2.967E+01 315 87865.6 6.167E+00 6.167E+00 2.783E+01 316 69336.1 5.082E+00 5.282E+00 0.603E+01 317 90831.1 4.400E+00 4.480E+00 2.429E+01 318 9:351.1 3.760E+00 3.760E+00 2.260E+01 319 93896.6 3.12 E+03 3.12 E+00 2.097E+01 300 95467.9 2.564E+00 2.564E*00 1.940E+01 321 97065.6 2.031E+00 2.081E+00 1.791E+01 IU 32 98690.0 1.670E+00 1.670E+00 1.648 +01 An 3 3 100341.6 1.323E+00 1.323E+00 1.513E+01 h3 324 102020.7 1.036E+00 1.036E+00 1.386E+01 305 103708.1 7.997E-01 7.997E-01 1.266E+01 306 105463.9 6.090E-01 6.090E-01 1.153E+01 327 107:28.7 4.570E-01 4.570E-01 1.04SE+01 308 199023.2 3.376E-01 3.376E-01 9.503E+00 329 110847.7 0.45 E-01 2.450E-01 8.596E+C0 330 112702.7 1.749E-01 1.749E-01 7.75EE+C0 331 114533.7 1.203E-01 1.203E-01 6.935E+00 330 116506.3 8.374E-00 8.374E-00 6.277E+00 333 118456.0 5.597E-02 5.597E-02 5.629E+00 334 1 04!8.4 3.643E-C2 3.443E-02 5.036E+00 335 10:453.8 0.303E-02 2.303E-02 4.496E+00 336 124503.0 1.40SE-02 1.40CE-02 4.006:+00 337 126536.5 8.297E-03 8.297E-03 3.56 E+00 338 108704.9 4.68 E-03 4.6e2E-03 3.161E+00 339 130353.7 2.515E-03 2.515E-03 2.7992+00 340 133049.7 1.2'35-03 1.275E-03 2.474!*00 341 135 75.3 6.037E-04 6.03?E-04 0.1SlE+00 342 137539.2 2.633E-04 0.633E-04 1.919E+00 343 139840.9 1.039E-04 1.037E-C4 1.655E+00 344 14:181.2 3.614E-05 3.614E-05 1.477E+00 345 144560.5 1.06?E-05 1.069E-05 1.291E+00 346 146979.6 0.547E-06 2.547E-06 1.106E+00 347 149439.4 4.477E-07 4.477E-07 9.799E-01 348 151940.3 4.971E-OS 4.971E-OS 8.507E-01 349 154433.1 2.544E-09 2.544E-09 7.369E-01
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