ML20005A396

To Process Control Program

ML20005A396
Person / Time
Site:	Crane
Issue date:	06/24/1981
From:	METROPOLITAN EDISON CO.
To:
Shared Package
ML20005A395	List: ML20005A394 ML20005A396
References
PROC-810624, NUDOCS 8106300281
Download: ML20005A396 (22)

Text

79 PROCESS CONTROL PROGIL\\M i

l 8.106300A%l 1

a PROCESS CONTROL PROGRAM Table of Effective Pages Rev. 2 2 2

2 2a 2

3 2

4 2

5 2

6 2

7 2

8 2

9 2

10 2

11 2

12 2

13 2

14 2

15 2

16 2

17 2

18 2

i

c A'

TABLE OF CONTENTS Process Control Program Section Title P. age 1.0 PUR?OSE 1

2.0

~ SYSTEM DESCRIPTION 1

2.1

. WASTE FEED SYSTDi 1

2.1.1 CONCENTRATED WASTE 1

2.1.2

. BEAD RESIN & POWDERED' RESIN 1

2.1.3' OILY WASTE 2

2.2 CEMENT FEED SUBSYSTEM 2

2.2.1 EMULSIFIER FEED 2

2.3 MIXING 2

2.4 VENT AIR FILTER SUBSYSTEM 3

3,0 COLLECTION AND ANALYSIS 07 SAMPLES 3

3.1 CENERAL REQUIREMENTS 3

3.2 COLLECTION OF SAMPLES 4

3.2.1 RADIOLOCICAL PROTECTION 4

3.2.2 WASTE SOLIDIFICATION DATA SHEET 4

3.2.3 COLLECTION OF SAMPLES 4

4.0 TEST SOLIDIFICATION AND ACCEPTANCE CRITERIA-5 4.1 WASTE CONDITIONING S

4.2 TEST SOLIDIFICATION 6

4.3 SOLIDIFICATION ACCEPTABILITY 6

4.4 SOLIDIFICATION UNACCEPTABILITY 6

4.5 ALTERNATE SOLIDIFICATION PARAMETER 7

WASTE SOLIDIFICATION DATA SHEET 8/9 SOLIDIFICATION DATA TABLES 10 CONCENTRATED WASTE (Evaporated Bottoms) 11 SOLIDIFICATION CALCULATION SHEET 12 WASTE SOLIDIFICATION DATA SHEET FOR OILY WASTE 13 WASTE CALCULATION DATA SHEET FOR OILY WASTE 14-17 POWDERED RESINS 18 Appendix A

HYDRAULIC MIXER DRIVE ASSEMBLY B

FLEXICON CEMENT FEED SYSTEM C

VOLUME REDUCTION AND SOLIDIFICATION OF POWDERED RESINS USING THE HNDC DEWATERING AND SOLIDIFI-CATION SYSTEM D

LINER LOADING PROCEDURE E

POWDERED RESIN TRANSFER & DEWATERING SYSTEM F

RESIN SOLIDIFICATION PROCEDURE

Revision 2 li! TMAN NUOLEAR & DEVELOFME?C C RPCRATION PR00EE5 COl,i10L PROGRAM Ine:ntaine-Solidi'i:a:icn i.C Du-ncst 1.1 Tne puncse Of the P-ocess Centroi Program (P C) for incontainer solidifict;isn is :: provice a orogram wnien will assure a solidifiec product with ne free iicuid prier to transp

.a:icn for dispesai.

The prc' gram c':nsists of cree major ste:s, wnich are:

a.

Pr::edures f:r : lle: ing and analy:ing sam:les; b.

Procecures for solidifying samples; Criteria for e-ecess parameters fer a::e::ance er reje: icn c.

. ts solidified wasta.

2.0 Svstem Descri:tien The systems described herein are designed :: handie the s lidification of licuics, evaccrator botums, c:her con:entratec liccies, contaminated oil spent resin, filter sludge and c ner miscellaneous wastes. Concentrated

:cids are processed at elevated tem:eratures as recuired :: kee:.:ne sai s in.sch::.icn. The varicus coerations are as ces:ribed beicw.

2.1 Waste Feed Sv: tem 2.1.1 Concen ra ed Waste fEva:crs = r B::::msi The waste feed system consists Of a rogressive cavity ocsitive dis: lace. ment pum:, tha-is ca-. of the TMI-1 urea formaldehyde solidifica:icn system, and a waste su;oly 11ne :: : nvey waste to One fill head. The pum:

takes su::icn fr = :ne ::n=en:ra ed waste re i uiaticr.

ni;ing and Dum:s One waste int: :ne liner.

The waste pum:

is manually ::ntmliec and 'i:w is dis:cntinuec unen a predetermined level is rea:nec in the liner.

2.1. 2 Sead Resin 1 2: wee ~ Resin Tne waste fee: syster. =nsis.s :f M*-1 esin recir-cula:icn heses a :a:nec :: -he resir :iscesai an

ewater e u-. ::nne ci:ns :n me :::sice wall Of =e Auxilia y Builcing.

Resin may :e :i a::ec ci =er =

ne dis csai liner Or :a:k :: :ne esin.ank via = e P00R BRiGINAL

Revis =n 2 dewat:r return conntetien. Tne r: sin ' low to ne ifner is s:coced when the resin slu ~y reatnes a c~ece:e mined level.

A dewatering pums coerating curing the fili cy:le cewaters :ne liner until icss ef.fiew is ce:e::ec. Tne cewater pum, a positive displacemen: att coerated dia:nram pum:, is s.:: ed.

Tne resin fiew is resta.ed and continued until ne crece:emined level is rea:ned. The cewater su== ts restarted. The fill and cewater c ::ecure is repea:ed until the dewatering :y:le n: icnge-brings :ne resin level down belew.ne nrede:eminec level.

Based en liner si:e used, a crede:eminec cuan:ity of water is added back into tne liner througn :ne cewatering elemen:

to fluff -he bed to relieve any bed pa xing.

Liners used for pcweered resin have see:ial bett = designs

. :o preclude plugging of :ne dewatering elemen.s.

2.1.3 Oilv Waste Due to the icw activity levels ass::iated with efi wastes, the liners in which the ef1 is :: be solidified can be filled by hand or with a s=all cum:. The liner is filled : a ;-ese: level (detemined visually). The quantity of evaporator be:tems te emined by the verifica:icn test is added as des:-iced in secticn 2.1.1.

2.2 Cemerr

Feed Subsystem Cement and chemical additives are bat:h leaced int: One shi; ping

. container, wne-e the actual mixing c=urs, by means of a s: ew ::nveycr.

Tnis subsystem consists'cf:

a.

Cement hopper with discharge acapter b.

Screw feeder and drive mc = r c.

Container inlet valve As a function of waste volume and container si:e, the accrecriate amount of cemen an: additives for a single bat:n are :re-loace:

int: the cement h=cer wnich, through tne dis:ha ge acac:Or, me a-s ne cement to the screw feeder.

Cement is ::nveyed th-cugh :ne flexibie s:rew feeder :: :ne ::c cf ne container, wne e it passes through the container iniet valve and falls by gravity into.ne ratwaste wnile :ne :ixing blaces are tu-ning.

Dusting is minimi:ed my =re-icading the :emen hee:er with a knew volume Of :ement, as ce:e-mine: by :ne Wasta Solidift: :icn Oa.a Sheet.

anc by :ne use of a cu:: =ilect:r as a feature of One vent air 'iiter su: system (see 2.4).

Tne :emen: container inle: valve and ne ven: line are an inte.;ral ca-cf :ne =ntainer 'U1 hee: assam:1y.

2 P00R ORIGINAL

.__f

Rovision 2 2.2.1 kulsifie-Feed (O'ly Waste On1v}

Licuid e=uirifier is acde: using a smail pcsitive dis: lace-ment pu=:.

Tne cuantity of e=ui:ifier received is aste-=1ned througn verifica:icn testing.

2.3 Mixin; Each liner is su::lfed witn an inte-nal mixing cevice desiened :

provice tnorougn cixing cf :ne entire liner conten.s.

A mixing motor mounted on :ne :co cf :ne liner prior :: One filling coera icn is star:e6 prior Oc :ne aedition of ement.

Mixing continues for aco-eximately twenty minutes er until the mc:Or automatically trips off cue :: high resistance :: =ixing.

The mix:u e will be ::c;.letely fir = within 4 neu-s and be suitaole for transport.

O e

e M e

T O

&u 90 i

P00R ORIGINAL

.m-9 m,

Revision 2 2.4 Ven: Air Fil:e Subsvs:e=

The fill head also 'ncludes and albowed ven: line. The vent line is hard piped :o the edge of :he cask where hoses can be connecce'd to allow the air being vented fre= che cask :o be conveyed :o che ven: air fil:er. This uni: uses flat fabri filters to re=ove particulates from the ven ai.

3.0 Collee:1on and Analvsis of Samoles 3.1 Ceneral Recuire=ents 3.1.1 A4 required by :he Radiologica'

'"'"en: Technical Speci-fica:1ces for 77R's and 3R7's the PC? shall be used :o veri'y the solidification of a: leas: one :- resenta:ive ces: spec 1=e f c= at leas: every :en:h ba::a of each type of ve: radioac:1ve was:e (e.g. evapora:or bo:::ss, boric acid solucion, sodiu= rul' ace solu:1:ns, resis and precoa:

sludge).

3.1.2 For :he purpose of :he PCF a ba:ch is defined as cha:

quas:1:7 of was:e required to 'ill a disposable liner :o che vasta level 1 di:a:or.

3.1.3 If any :es: speci=en fails :o solidify, the ba::h under shall be suspended until such :ise as addi:ional ces:

tes:

spect= ens can be ob:a'ned, al:er:acive solidi'ica: ion para-se:ars can be de:er=ined 's accordance vi:h the ? ocess Con::el ? ogra=, and a subsequen: :es: verifies solidifica-tien. Solidift:2:1:n of :he ba::h say : hen be resu=ed using the alter:a:e solidi'1:2:ica para =ecers decernised.

3.1.4 I" :he ini:ial tes: spec'=en fre= a batch of vas:e f ails to ver1#7 solidi'ication the: represenca:ive :es: speci= ens shall be collec:ed f== each c:ssecu:ive ba:ch of the sa=e cype of was:e u=:11 three (3) consecutive ini:ial :es speci-mens de= ens::a:e sodd" -a:izns. The ? ocess Cent:ot ? :gra=,

shall be nodified as requires :o assure solidi:a:1:n of sub-seques: ba:ches of was:e.

3.1.5 For high ac:1vi:7 was:as, such as spen: resi: :: ased prec:a:,

where hardli:g of sa=cles could resul: in per3occei radia ::

espesures which are 1 :: sisten: r.:h : e M t?.a principle.

e-prese::a: ve nen-raci: active sa==las vi1* be :es:ed.

These ss=olas snoulc be as :1:se :: ::e ac::a' was:e as: : e= :a;

pe;.les as pessibie. Ty

1

21 ::er:enee ::::e: ie: ss:.:

small be use: :: st=ula:e : e scen: bea: ress: 1:: ::e a:p::-

pr.a:e si: af a:u.:n :s a:1: ;cucares :esi: scall be usec ::

si=ula: used pre::a:.

P00R ORIGINAL om

Revissen 2 All Chemicals used to condi: ion or solidify was:e or s1=ula:ed 3.1.6 was:e is solidift:a: Loc ces:s shall be represen:ative of :heIf ac:ual chemicals :o be used is full scale solidifica:icn.

che=icals of a diff eren: type or fro: a differen: =anufac:urer are used, :he new sacerial shall be :es:ed :o verify 1: pr: duces l

l a solid produe: prio: to full scale solidification.

3.2 Collee

ion of Sa= oles 3.2.1 Radiological ? oceetic:

3.2.1.1 C = ply vi:h ap:11:able Radia:1on Work Per:1:s.

sa=ples which use ac:ual vaste shall be disposed of by 3.2.1.2 Tes:

solidificacion 1 ' :he disposal liner.

3.2.1.3 A Was:e Solidifica:io: Da:4 Shee: vill be =ain:ained for each

es: sa=ple solidif'ed. Each Da:a Sheet vill con:ais perti:en:

inf cma:1cs on :he :es: sa=ple and the ba::h su=bers of vasces folidified based cc each :ss: sa=ple.

3.2.2 Waste Solidifica:1ce Da:a Shee:

The Vasca Solidifica:1c Oaca Shee: vill c ::ais per:1:e - ' 8

_a:10:

on :he charac: eristics of :he :es sa=ple solidified so as :o verify solidift:2: ice of subsequen: ba:ches of si='lar vastes vi:heut re-ces;ing.

sa ple da:a for c: ces: 2:ed vas:e vill 1: elude, bu: =c:

3.2.2.1.a The :es:

ce=s:1-necessarily be li:1:cd c,~ the :ype of was:e solidified, maje cuas:s, per:e:: solids, pE, vele=e of sa=ple, a=ces: of cil in sa=ple and the ratic of :he sz=ple volu=e to :he final vole =e of :he solidi-fled adue:.

sa=ple da:a for spe:: rests and used precca: vill i=clude, 3.2.2.1.b The :ss:=ecessarily be li=izad :o, :he :ype of vaste sol lified, bu: no:

volu=e of sa=ple and ratio of sa=ple volu=e to che f sal vele=a of the solidified produe:.

The Waste Solidifics:1c Da:a Shee: vill i= 1ude the 32::h Nc=ber.

3.2.2.2 34::h 7olu=e, and Oa:e Solidified, for each ba::h solidified based :n sacole dese:1bec.

.1.2 pilee

::n :f !a=:les 2.2.3.;

I spera::: se:::=s s-all be kept heste: :: :shss:ed :: '20 7. ;::::

:as:i:g.

3.2.3.2 Tse sa=p;es small :e taxas f:: analysis.

Ea=s le si:ss shal'. Se c:=-

Pacible vi:h :te 3:: dar: si:e sa=cle use: f: :te : sci:ac: v. 7 anal +s s r:c :he sa ::: f:: ::s ::e= ::i L al-sis.

f ::e radi:-

sc:iv :7 level; ::2 :oh; :o pe-- -

si:e sa=sles :: he :aken f

en r-* **e sa=:.es. all se :ssan vi: ::e :ss 1:3 ::::e::ed

?.e:1:

sc::::i ;iv.

!a==ie s :ss s :11 he :e:er- -se :y ne ;.:::

physics staff.

1 i

?

P00R ORIGINAL

^

Revision 2 3.2.3.3 Samoles should be drawn a: leas: six hours crice to tne planned waste solidificaiten Orc:ecure :: allow ace:uate time to c =:lete :ne required testing and verifica:icn of solidifi:aiten.

3~.2.3.4 The tank containing tne waste to be s:lidified snoulc be mixec by re:ir:ulating :ne tank contents for a: least one volume change prior :: sam: ling := as:ure a re:resentative sam:le.

If tne contents of ecce than one tank are :: be solidified 3.2.3.5 in tne same liner :nen re:resentative sa=cles of each tank should be drawn. These sa=:les shotic be of su:n si:e tna:

wnen mixed together tney form samples of standard si:e as prescribed in Se::icn 3.2.3.'2.

If the centents of a carti-cular tank re:rtsents X% of tne :::al waste cuantity to be solidified then the sa= pie of that tank shoulc be of suen si:e :: represent X% f ne ::=p0 site samples.

4.0 Test solidification and A::e :ance Criteria 4.1 Waste Cenditioninc 4.1.1 Prior to the test sa=:le solidificai :n :ne pH of the sample sna11 be adjusted to a range f 5 :: E if Mets: Beads are used or a range of 8 te 10 if :ney are no: used.

4.1.2 F r Ber. Acid (including Evapers::r Bott =s) wastes it is re==rnended that sodium hydroxice be used t: adjus: the pH.

4.i'.1 If f:a=ing is apparent curing the s:lidification testing the sa=:le should be treated with an anti-fcaming agent.

The cuantity cf anti-foaming agent require: sna11 be re:Orced.

~

4.1.4 If an oil film or layer apoetr: on :ne surface of the eva: Orator b :::=s sam:le, or if oily waste is :: be solidtfied, an e=usifier snall be added to pretreat the waste sa=:le as f:llows:

4.1.1.1 A11cw one sample :: stand undis turced until :ne water /cii interface is clearly discerna:1e and deter =ine the :er:ent; by volume, cf One sa=rie tna; is oil.

If this vel;=e is greater :

40 percent. Use ne Weste Calculation Ca:a Shee :: determine the cuantity cf licuic to aed. Wnen :ne corre:: cil :: water

~'

ratic is reached, measure and record the pH.

4.1.0.?

Pricr :: the tes sa=:le solidi'icati:n, the Oily waste is treated witn a crece:er=ine: Ouantity cf e=uisifier.

For nis a :licatien, Mays:1776 is used at a ra:ic of I ar e=ulsifier :: 5.1 parts 011 by volume. The emulsifier nas a censity Of one.

4.1.4.3 After :ne a=uisifier is increugniy mixed int: One sa=:le a cuantity of Me:sc Beads the deign: cf wnien is twice :ne weign:

i cf :ne emulsifier use: is mixed in :ncr:ugnly unti; :ne Me:s Beads have ::::letely diss:ived. P00R ORIGINAL

4.2 Test Sc11di!+:aiton Revision 2 i

4.2.1 Any sa=cle :: de solidified snail be :re:reatec as sce:ified in Section 4.1.

4.2.2 Test s:lidification should be ::ndu::sc esing a 1000 ='..

. dis:esal beaker er si=ilar size c:n:ainer.

Mixin; snould be a ::::lished by stirring wi:n a rigid stirrer until a homogeneous mix:ure is obtained, but in no case for less : nan five (E) =inutes.

4.2.3 Fcr the test sclidification of resin, measure in : :ne mixing vessel 100=1 ef wa:er and add a suf#i:ient cuan:ity of dewatered resin :: yield a 400=1 =ix ure. The degree cf c = a::icn of :ne resin will determine the veiume of resin recuired.

the For the test solidification of pre::a: sludge, measure int:

4.2.4

=ixine vessel 4C0=1 of waste at a maxi =u of 300 w/c solics.

4.2.5 For the test solidifica:icn of C:n=en: rated Waste (Eva:orater Bc:::=s), measure inte the mixine vessel 400=1 of wasta.

4.2.6 For the :es solidifica:icn cf C:n=entrated Waste and Oily Waste be sclidified including the cily waste measure 320ml cf the waste ::

Measure cc: the recuired anc pretreatmen: chemicals into the beaker.

- quantities of cement and Mets: Beads as shown beicw. Vclu=es are for locse, unec= carted material.

' Waste Cement Mets: Bea:s crars

_=l cra=s

_mi

~ Resins 362 240 35 24 Filter Siudge 340 226 34 23 Eva:orat:r B :::=s 533 257 5E 2:

Evaporator 300::=s & Oil 432 297 4.2.7 Mix the cemen; and Mets: 3eads t:ce:ner and slowly add this =ixture ::

the tes sample while ti is being stirred. (Omi this step if 4-Me se Beads we e added previcusly.)

4.2.8 After ten (10) =inutes cf mixing an: a h:=cgeneous =ixture is obtained allow :ne waste :: stand f:r a =ini=u= cf 30 =inutas.

4.3 Solidi'ication A :ectablility, The f=11 ewing criteria define an a::e::able sclidificati:n Or cess and or::sss parametars.

4.2.1 The sa= le solidification is ::nsicere: acce::atie if there is nct visual er drainable free water.

4.2.2 The sa=:le s lidificait:n is ::nsicered at:e::able if c:en visual ins:e::icn -he waste a : ears :na: f: would neld its sha:e i#

removec fr = :ne beaker and its res's:s penetrati:n by a ri;i: stick.

4.4 Seli:i'icatien Unae:e::acility 4.4.1

f -he waste fails any :f -he ci-eria se: for:n in Se::icn 4.2

-he solidifi:stion will be ter=e: unat:e :a:1e and a new set f P00R BRIGINAL

Revision 2

)

solidification :arame:ers will need :: be ' established under the ore:edures in Se::icn 4.5.

4.4.2 If the tes: sclidifica:icn is una::e: able :nen the sane tes orocedure mus: ce fellowed en ea:n su:secuen: Da :t of ne same tyce cf waste until :nree :ensecutive tes; saceles are solidified.

4.5 Alternate Solidifica ice Parameters 4.5.1 If a test sample f ails to provice ac:ectacie solidificaiten of wasta the following cro:ecures snoulc be followed.

(1) Mix squal volumes Of dry cement and water to ensure that the problem is not a bad ba ch of ement.

(2) Add additi:nai caustic solution :: raise the pH above S.

(3) If the waste (o:ner thar waste cil) is only partially sciidified, us

.lcwer waste :: cement and Me se ra ics.

Using the re::==enced quan;ities cf cement and Me:s Beads, redu:e ne wasta sa=:le volume by 25m1 until tne a::e:: ability cirteria cf Section 4.3 are met.

(4)

If the waste oil mixture is only partially solidified try using icwer waste t: cement ratics.

Reduce tne cuantity of waste by 20=1. and the emulisifier by 1 =1., (This will resul:

in a slign:1y higner :encentration of emulsifier in the waste) and croceed with :nc test solidificai :n.

Continue with similar redu::icns until a satisfa:: ry produ:: is a:nieved.

O e

E e

l P00R ORIGINAL.

C._,.

Revision 2 W.._....,...,......,.....

3.-

sv._

um: w.u > - 2 :- -. i e u..

] Type of Waste - F.esir., ?~.vcere: P.esin, Concer..ra a: Waste v a,.,w. r a.. s. =,.....

Sample N :

Eatch tic:

5:= pie Voiume, el:

Weight % Solids':

PHI 2:

Quenti y of Oil' %^:

C"one.- Ms '.- C... ~.'... a. r. ~ c..

.s 3

Cement Ratic (!/f Waste')

Quantity of Cement Added:

3 Additive ~-Ratio (!/ft' Mas.e }

Quantity Of Additive Added:

-..a.

u....,.

2.,.s....

p.

4...

r1..

Product A::ectable:

Yes E

(If no, refer to Se::icn 4.5 and Omcasd as dire:'.ac)

Radienu:'licas Present:

(Ise:: pes & Cencentrations)

Addi-iona*. ba :hes solidified based en this sa=:le sciidificatier.:

Bat:h Bat:5 Batch Bat:h No.

Vol.

Cate No.

Vcl.

Da'.e

. Sat:h Bat:n

- u..,.

u. a. l -

D. *a.

8 9

9 5

3

[

P00R ORIGINAL 8

Revision 2

?!otes l If pH adjustment is required, note chemical used, quantity used and pH after adjustment.

2 et required for spent resin or used precoat.

tt 3 ultiply the grams of cement (Metso) per el of waste by 62.4 to convert M

to pounds of cement (Petso) per cubic foot of wasta. For the ratios given in Section 4.2.6, cement-to-waste ratios are 56.4 pounds per cubiq foot for resin, 53.1 pounds per cubic foot powdered resin and 911 pounds per cubic foot for boric acid. Note that the cement ratio for resin is per cubic foot of waste; 1.e., resin plus water.

This is equivalent to 75.3 pounds of cecent per cubic foot of dewatered resin.

O s

k e

P00R ORIGINAL

Revisi:n 2 j

56. '. 7 m *L. '. 'M' L 'L w 't.'

"w n'

• A n

' sv LnD

.. ;.... ;, p.

For t..e three was e typ.es investigated in this eti::ittien, bead resin, p~.vdered resin cr.d 12 w/: beri: acid and licensed czsk payictd is li.iting in all cases for the M*:-100 Series 1, Hil-iC0 Series 2 and Hti-1005.

Weigh; is limiti..g for t.he HN.-005 and

• '.-..---'j.

W.= 1' y n'. 4. s n.o. a W... '..7

..1.v #.ar "or..=.... a. d "..as =.

va r= -.

.>ww a

1 o

w f:: r fc - the Hi4-500.

B:.AD e.r :..n.

HN-lCO HN-1005 HM-200

.HN-500 Series 1 Series 2 Usable Liner Vcltee, ft-149 149 149 64 72 Max. Solidified Waste 3

Volume ft' 127.2 122.0 149 64 72

'i ta-7.. Resin Volume Dewatered, ft3 71.7 CE.7 84.0 35.1 40.5

'.siter Added at Max. Resin Y:1, gal 179 172 210 S0.3.

IC2 r...

s.

=, e..

.e.

53x..

~2 iso

.n.:e we..... sw..s. 7cun.2 i f:3 bags 57 55 67 29 32

..s,. S t,

> u.., a

,w 540 517 e33 272 305 P..:r.ds 1 f:3 bags 5.7 5.5 5.7 2.9 3.2 Ma::. Radiatien Level

~m0

.~s / S. e, r...

I, I2 3

owV vne a

.. ww. * *.

e 1

-10 P00R BRIGINAL

~

Revision 2 C0tCE!!? RATIO WAs I 'IVAPOP.AT?r, 50 70MS)

Ht:-100 Hii-1005 HM-200 H5-500 Series 1 Series 2 Usable Liner Volt:me, ft.3 155 155 155 62 79 Max. 5slidified Wasta Vol. f:3 105.5-

'701.2 125.9 55.8 79

~

.!ux. Was a Vol, ft3 74.5 71.4 25.5 45.4 55.E Cc:an: Added at Max. Hasta Vol.

P:unds 6733 6501 8153 4225 5080 1 ft:3 bags 72 59 57 45 54 H.G. Added at tiax. Waste Vol.

P:unes 575 550 815 422 508 1 f:3 bags 7.2 5.9 E.7 4.5 5. t.

Max. P.ad. Level R/h en Cen:c:t 12 12 5

800 100

~"~

P00R ORIGINAL

SOLIDIFICATION CALCULAT!0il'5M5 5

• i Liner Ca;;a:ity:

(1) 1:r.ste/?r:du:: Ratic:

(1) 3

!/M (3)

Cement P.atier.:

Additive:

. ~

Additive Ratic:

f/ft-(A)

. Volu=e of Dewatered.cr Concent ated Haste:

(1)'x (2) =

(5)

~

Cement Quari ity (5)x (3)=

(6)

' ~

Add'-ive Quantity (7)

(5) x (4) =

Guar.tity of Hater t: be added - galler.s (Resin only)

-(5) x 2.5 = _

(E) u.-

Divide the Quand y Of Hater t: Se added (5) by the supply flowrate (5) to de ert::ime hew 1:ng water should be pumped t ra disposal liner.

(B)+

cal /=in (9) =

_ min::tes (iC) e g

e h

P00R ORIGINAL

~

Revis-lon 2 Bat:h H::

i S? ? e NO:

Da e:

WAIT! 50LIDIFICA :07; DAT* SHEET FOR OILY WASTE Volume % Oils:

5 (itaximu-

/ 40'. :y v:iume) sample Volume, m1:

J Major Com;csition of Ncn-oil Ccmhenent:

~

Quantity of Emulsifier Added, ml:

pH Quanti y cf Me:s Beads Acded, ml:

Addi:icnal fietso acced to raise pn aseve E, gt:

Quantity of Ccmen-Added, c=s:

Final Produe: to Waste Ratic (Volumetri:)

Produe: Acceptability:

A :sp;able Una :eptable If unacce;;able note wny:

Radienu:lides Present.

Iso:: pes and Concentra:icns (1) If -tne percent of oil in the sample exceed the maximum cliewable quanti y the sam:le shall be diluted as required (See the Waste Cal:ula:icn Ca:a Shem.:).

This new mixture will be thercugnly mixed, tes a: f:r 5 cil an: a new sample taken fr:m this mixture as per Secti:n 4.2.3.

The volume of dilu: ant required will be record:d.

P00R ORIGINAL

Revision 2

z..a..w..,.,.

,r. n p... y.

9u.~.n.

.e p...-n.

Olt v.,.. knen-m.;

Comple e Section A ocir if the initial st=ple shows cil in e;;cass of 405 by vclume, otuerwisc go := sectic: 3.

q.-_. A,3,. 3 Step

• Original sa=ple vele=e

=1.

., (1)

Volu=e % cil L: sz=p;e G.

(as dect=al draction(2)

Step 2 Sa=ple vold=e (=1) =ultiplied by (2): ' =

(=1) x 0..

_, =

(=1)

(3)

Step 3 Divide (3) by 0.4:

+ 0.4 =

(4)

Step 4 Substract original sa=ple volu=e (1) frc= (4) to ge:

quantity of liquid needed Ic dilute st=ple to 405 oil by volume:

(4)

(1)=

c1 (5)

.e

-. 1, i.a S ep i Vcle=e of waste in liner, gallons :

(6)

(HN-100 liner contains 17.62 gzilons/ inch).

The tilewable waste depth ic 42. inenes.

Step 2 If the velu=e perceu cil is grez er tht: 40% it is necessary :c deter =ine the a=our; cf liquid (i.e.

w;;er) that must be'acded to the liner to reduce the percent oil to less thin 40% (If the fluid level 1: the liner is close to 42 inches such -hz:

the addition cf any liquid wculd raise the fluid level above the 42 inch level proceed to Step 3).

Take the quzatity cf liquid, (5), added Oc the test sa=ple in Sectic: A L:d divide it by the Original sample vclu=e (1).

Multiply this dec;=t1 f raction increase ' by the volume of f.' uid 1:: the liner to obtal.n the quantity of lit;ua d ncoded to diluto Lhc ennt.onts of the 11nc.- Lo less th an 40'~ o il by v ol um'.

c

/Di mi

. c.

in

,s.

r-a

(.,.

l P00R ORIGINAL

Revisicn 2 o

Calcult:e new fluid level in liner.

Add (7) to (5)

~

and divide by 17.62 galloss/inct anc add this increased depth :

the origi::1 fluid depth.

(GT-(75 ralle:s =

_4 ches (e) g icss/L=cn a,.c2

( 8 ) =us not e::ceed 42 i= ch es..If it does dc =ct add any liquid :: the liner bu: proceed 00 Step 3.

If the fluid level (5) is less than or equal to 42" add l

the quLsti 7 of liquid eticciated in (7) to the 11:er and proceed to Step 4.

Step 3 -

This step is o be cc=pleted c=1y whe: the qut :ity c f oil L: the liner exceeds 40% by vclume L=d diluti:g wi:t water would raise the fluid level above 42 inches.

~

Multiply the origina.' sa=ple velt=e (1) by 0.4:

(1)( ml ) x 0.4 =

(9)

Subt ract (9) frc= (3) above:

(3) -

(9) =

=1 (10)

... Divide (10) by the original st=ple volunie (1) to obt-1: the deci= 1 fractional decrease in sample oil vclu=e to bM:; the pe.-cent oil dow: to 40 by vclu=e.

(go),

g, (L1)

(-)

L Mul:1 ply the volume of waste in the liner (5) by this deci=11 dractic: (11).

(G) x

( 1) =

gallons (L2)

Th$s represents *.hc quantity c.* oil the must be removed Ir== the liner, and replaced by an equal vel==c of beric acid, :: bring the percent oil dos below 40 percen by volume.

To do this firs: allow.ne fluid in the liner to s: nd undisturbed for a period of 5

minutes and then pump ci2 cu; using n rubber hose i

c:: ended into the liner ::

level just below the cp I

ci the oil layer.

t i

P00R ORIGINAL

~~

~

~"~

Revision 2 S cp 4 If t.hc lab samplo showed loc 8 than 40% cil by volu=c proceed witocu an addi:100-1 st=ple and enter below the volume % cil in the itier.

Vol.% cil C.

(13) l li liguid wts added :

dilute the oil (Step 2) er cil tas re=cved (Step 3) =ix tac centents of the liner fer 15 =1:utes and res==ple te ec: fir:n the volc=e perce:: cil in the liner a=d e 'er below.

(If nc applicable enter N/A).

Rest =ple Vol.% cil 0.

(14)

Measure the fluid level in the liner.

Agai: this level =us: se: exceed 42 inches.

Finid. level

_ inches (15)

Calculate Obe quantity of oil in the liner by multiplying the fluid level (in inches) by tae gallons per inch (17.62 grilons por inchi by the perce:: cil by vclume frem either (13) or (14).

C*11cns I

inches (15) x 17.62 x 0.

(130:14) =

.n. -

t g=11cns (1G) l Step 5 T it h t h e =i::i:g =c t e r ' O.N' ' add the emulsifier Maysci 776 at 1 part e=ulsifier :c 5.1 parts oil by vclume.

To eb tin the quantity of Haysci 776 required, divide the

• gallens of cil (16 ) by 5.1.

( 1G); Ellen s gL lens c' a-

'sifier(17)

=

c. it,.,_3 3,n s c _,

gallon e=uls-1 er Continue =i::ing until the cil is cc=pletely.=ixed and the contents of the liner is a unifer= milky white in appearance.

Record the mixing time.

minutes mixing

, P00R BRIGINAL

Revision 2 S*.cp 6 Chiculate Obe quantity c. Me.so 'Jcads c be added c

the liner.

From Secti>n 4.1.3, the weight of tht Me:sc Beads is twice the weight of the emulsifier.

The censity of the en:cisilier is appic::imately e0.001 to :ht of water, 62.4 pounds per cubic foot, (S.34 pounds per gallon).

Therefera the Me:sc Deads will weigh

• wice as much as the emulsifier.

pounds pounds

-(15 )

x (17) 2 x S.34..3".

=

c..

Add the Me:sc 3eads slowly L:d cc=tinue =ixing Obe conte::s of the liner until 111 the Metso Selds bare dissolved.

Step 7 Fcr every gtlic: c'

"'A d-

-he liner add 11.2 pounds of uncompacted cement.

This is equivale::

to 83.5 pounds of ce=e:: for every cubic foot of waste.

To calculate th'e quantity of cement required multi-ply the fluid level (15) by 17.62 gallons per inch by 11.2 pounds cement per galle: of.'luid.

inches (151 x 17.62 x 11. 2 =

pounds of (19) cemet:

Conver this to cubic f eet of loose cement by dividing (19) by 34 pounds per cubic foot.

(19) pounds e.

1 su+pouncs per It '

3 This is equivalen: Oc the number of cne f:

b ags required.

Add ;be cemen; slcwly while =ining =0ntinually until all the ce=en: is added and the mining me:or trips due to high resistance to mixing or for 20 minutes nT'.cr the las bag is addec.

P00R ORIGINAL

DOWDEilED R55??'S Revision 2

'HM-100 HH-1005 Ht;-200 HN-500 Series i Series 2 Usable Liner Vol =e, 1:3 1 59 149 149 64 72 Max. Solid *3fied Waste Vol. ft 1 25.3 121.5 149 64 72

=t Max. Haste Vol. ft" 93.5 54.5 115.8 49.7 55.9 Cemant hided at Max.

Waste 'lol.

P:unds 5230 5013 6150 2 'c 0955 1 f:J bags.-

55 53 55-28 31 H.5..Added at P.ax. We.ste' Vol.

Poun!s d

523 502 515 254 257 1 ft bags 5.5 5.3 S.5 2.8

'3.1 Max. Rad Level P./hr Centact 12 12 5

500 100 1

P00R ORIGINAL

~

~

m