ML18040B256
ML18040B256 | |
Person / Time | |
---|---|
Site: | Susquehanna |
Issue date: | 09/21/1989 |
From: | Hansell J PENNSYLVANIA POWER & LIGHT CO. |
To: | Twana Ellis LUZERNE COUNTY, PA |
References | |
PLE-11824, NUDOCS 8909270042 | |
Download: ML18040B256 (155) | |
Text
-'ACCELERATED DlRIBUTION DEMONISTTION SYSTEM REGULATORY INFORMATION DISTRIBUTION SYSTEM (RIDS)
ACCESSION NBR:8909270042 DOC.DATE: 89/09/21 NOTARIZED: NO DOCKET N FACIL:50-387 Susquehanna Steam Electric Station, Unit 1, Pennsylva 05000387 50-388 Susquehanna Steam Electric Station, Unit 2, Pennsylva 05000388 AUTH. NAME AUTHOR AFFILIATION HANSELL,J.B. Pennsylvania Power 6 Light Co.
RECIP.NAME RECIPIENT AFFILIATION ELLIS,T. Luzerne County,PA
SUBJECT:
Forwards final draft, "Susquehanna Steam Electric Station I Hazardous Matl Emergency Offsite Response Plan," for review.
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. Pennsylvania Power 8 Light Company Two North Ninth Street ~ Allentown, PA 18101 ~ 215 I 770.5151 September 21, 1989 Mr. Tony Ellis SARA Title III Planner Luzer ne County Emergency Management Agency Luzerne County Courthouse Wilkes-Barre, PA 18711 SUSQUEHANNA STEAM ELECTRIC STATION HAZARDOUS MATERIAL EMERGENCY OFF-SITE RESPONSE PLAN CCN 741326 FILE R9-6 PLE- 11824
Dear Mr. Ellis:
Pennsylvania Power and Light Company (PPItL) is submitting the final draft of the Sus uehanna Steam Electric Station Hazardous Material Emer enc Off-Site Res onse an or your review. ne a itiona copy o the P an as een enc osed for your Agency to forward to PEMA.
If you have any questions, please call Gregg Shields at (215) 770-5142, or me at (215) 770-7887.
Respectfully, ohn B.
6 l4~+
Hansell, Jr.
Senio'r Environmental Scientist-Nuclear gas/lti8664i(25) cc:,EP-A Regi on-I I.I NRC Document Control Desk NRC Region I Mr. F. I. Young, NRC Sr. Resident Inspector Mr. M. C. Thadani, NRC Project Manager Attachment i.
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HAZARDOUS MATERIAL EMERGENCY OFF-SITE RESPONSE PLAN SUSQUEHANNA STEAM ELECTRIC STATION LUZERNE COUNTY The enclosed Off-site Response Plan has been developed in accordance with the provisions of Superfund Amendments and Reauthorization Act of 1986 (SARA)
Title III, by the Local Emergency Planning Committee for the Emergency Planning District of Luzerne County. It has been written in conjunction with the emergency planners at the Susquehanna Steam Electric Station and represents 'the cooperative efforts of both the community and industrial planners in response to a hazardous emergency at the facility.
This plan was approved by the Local Emergency Planning Committee of Luzerne County on James M. Siracuse Executive Director Local Emergency Planning Committee Luzerne County This plan has been reviewed by the Pennsylvania Emergency Response Commission on James LaFleur Executive Director Pennsylvania Emergency Response Commission Harrisburg, Pennsylvania 8909270042
TABLE OF CONTENTS PAGE Purpose .
S'1 tuatl On ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~
A Situation o o o . o ~ ~ o o . . ~ o ~ ~
B. Summary of Hazardous Material Vulnerability Analysis Concept of Operations ,3 A. General 3 B. Categories of Emergencies . 3 C. Phases of Emergency Management 4 D. Emergency Notification 5 E. Emergency Procedures 8 F. Protective Actions 9 G. List of Additional Institutions/Sites at Risk . 9 H. List of Shipping Routes for SARA Substances . 9 I." Description of Method to Determine Occurrence of a Release 10 Organization and Responsibilities 10 A. General 10 B. Local Emergency Planning Committee 10 C. Assignment of Responsibilities 10 Administration and Logistics . 25 A. Availability of MSDS on Request 25 B. Document Availability to Public 26 C. Notice of Public Availability . 26 D. Toll Free Telephone Systems . 26 E. Supporting Documents 26 Authority and References 27 A. Authorities . . 27 O'. References 27 Definition of Terms 28 Training and Exercises . 28 A. Training Standards 28 B. Training ~ ~ ~ ~ ~ 28 C. Exercises . . 29
TABLE OF CONTENTS (cont'd)
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)
9.~ Plan Development and Maintenance . 29 A.~ LEPC Plans 29 B. Facility Emergency Coordinator 30 C. Facility Updates to LEPC 30 D. Planning Information 30 E. PERC Review of Plan . 30 F. LEPC Annual Review 30 G. Quarterly Review 30 H. Copies of Plan 30 I. Initial Distribution of Plan 30 J. Regional Response Team Review . 31
- 10. Enclosures . 32 11 e Tabs ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 43 A.
B.
Facility Area Map.....
Rules and By-Laws . ~ ~
44 46 C. Letters/Memoranda of Agreeme nt 48 D. Emergency Telephone Roster 50 E. Community Resoruces . 53 F. Facility Resources 61 G. Maps and Tables . . . . . . 71 H. Material Safety Data Sheets 79
Pennsylvania Power and Light Company Susquehanna Steam Electric Station 9.0. Box 467
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Berwick, PA 18603 Facility Emergency Coordinator: James M. Siracuse Shift Supervisor (24 hrs) Luzerne County Coordinator Phone: Office (717)-542-3907 Phone: Office (717) 825-1776 HAZARDOUS MATERIAL EMERGENCY OFF-SITE RESPONSE PLAN
- 1. PURPOSE To describe procedures and establish responsibilities for community planning for and response to a hazardous material (hazmat) emergency at the facility. This plan is in accordance with the requirements under Title III of Superfund Amendments and Reauthorization Act of 1986 (SARA) and the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA).
- 2. SITUATION A. Situation Susquehanna Steam Electric Station uses chlorine gas, sulfur dioxide, and sulfuric acid in its power production process. These substances and quantity on hand meet the SARA reporting criteria. An on-site accident involving any of these substances could cause an evacuation of the plant and surrounding community. Maps covering at least a 3 mile radius* of the plant showing population density in 1980 and 1990 can be found in Tab G (See Figures 1 and 2). Tables giving population density for various sectors around the plant can also be found in Tab G (See Tables 1 and 2) and may be used with Figures 1 and 2. Maps covering at least a 3 mile radius showing institutions/sites at risk can also be found in Tab,G (See Fi'gures 3 and 4).
- Radius was determined by 1987 Emergency Response Guidebook, U.S.
Department of Transportation. The evacuation distance estimate was based on fuming sulfuric acid.
Summary of Hazardous Materials Vulnerability Analysis Three extremely hazardous substances stored at the SSES exceed their Threshold Planning guantities (TPg) as described in 40 CFR 355 and are given below. Also given are the Reportable guantities (Rg) of these substances as described in 40 CFR 302 and 40 CFR 355.
Extremely Maximum Hazardous Substance EEET'TP Sulfuric Acid 775,200 lbs 1000 lbs. 1000 1 bs.
Chlorine Gas 30,000 lbs. 100 lbs. 10 lbs.
Sulfur Dioxide 3,600 lbs. 500 lbs. lb **
Material Safety Data Sheets for these extremely hazardous substances can be found in Tab H.
CI In case of an emergency involving sulfuric acid, (worst case scenario of the three extremely hazardous substances) evacuation of a three mile radius surrounding SSES could take place which would involve the following populations in various sectors (based on 1990 population estimates in Tab G, Figure 2 and Table 2).
Population Affected Sector Affected Political Subdivision s)
N 99 Conyngham Township, Salem Township NNE 101 Conyngham Township, Salem Township NE 160 Conyngham Township, Salem Township ENE 50 Conyngham Township, Salem Township E 76 Conyngham Township, Hollenback Township, Salem Township ESE 110 Conyngham Township, Hollenback Township, Salem Township SE 422 Conyngham Township, Hollenback Township, Salem Township SSE 219 Conyngham Township, Nescopeck Township, Salem Township S 204 Nescopeck Township, Salem Township ,
SSW 282 Nescopeck Township, Salem Township SW 349 Nescopeck Township, Salem Township WSW 390 Salem Township W - 91 Salem Township WNW 95 Salem Township NW 169 Conyngham Township, Salem Township NNW 52 Conyngham Township, Salem Township The dominant topographic feature in the three mile radius surrounding the SSES is the Susquehanna River and its valley. Much of this area consists of rolling hills, most of which is used for agriculture or is forested.
,In addition to the permanent population estimated to reside in the three mile evacuation radius, a transient population can also be expected to be present at any given time. Specifically, the Riverlands Recreational Area (See Tab G, Figure 4) is estimated to have a peak day-time attendance of 200 people, but is typically less than 50 people. The Riverlands Recreational Area is closed at night.
Other recreational usage in the three mile radius is limited by topography and land use. Some fishing and boating does occur on the Susquehanna River; however, this is also limited due to shallow depths.
- The Rg for sulfur dioxide is that listed in 40 CFR 355 since it is not listed in 40 CFR 302.
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- 3. CONCEPT OF OPERATIONS A. General The Pennsylvania Emergency Response Commission (PERC), with the Pennsylvania Emergency Management Agency (PENA) as the operational agency, and the Local Emergency Planning Committee (LEPC), with the Luzerne County Emergency Management Agency (LCEMA) as the operational agency, established by the Governor's Executive Order 1987-8 (Ref.
6.A.3) under the provisions of SARA Title III, provide the organizational response to hazardous material releases including:
- 1. Notification and Response The facility owner/operator initiates the response by following the prescribed notification procedures. Facility responders are joined by public responders who have been notified by the LEPC via the County Emergency Management Agency (EMA).
- 2. Containment and Neutralization The owner/operator and the public responders share the work of containment and neutralization.
- 3. Protection of Public County Commissioners, working with the County EMA, will provide for protection of the public from the consequences and impact.
- 4. Clean-up The facility owner/operator provides the planning and response capability for cleanup.
- 5. Re-entry Department of Environmental Resources (DER) determines when area is safe for reentry.
B. Categories of Emergencies Four categories have been established reflecting hazardous materials releases of varying severity. Procedures for categories controlled at the scene require different actions than those with public impact.
Planners will develop procedures to coincide with these four levels.
- 1. Category I Routine release. Totally within the facility. Contained within site. Report voluntary.
- 2. Category II Reportable quantity. Release outside of facility. Requires assistance of municipal responders. County EMC provides On-Scene Coordinator.
- 3. Category III Response requires public notification and may require protective action. PENA provides On-Scene Liaison Officer.
4, Category IV Public notification and protective action are required, PENA provides On-Scene Coordinator.
C. Phases of Emergency Management This represents a chronological listing of events, not an assignment of specific responsibilities.
Preparedness a ~ Es tab 1 i s h emergency organi zati on.
- b. Conduct hazmat vulnerability analysis.
C. Develop hazmat Off-site Response Plan.
- d. Select and train response personnel.
- e. Provide, first response equipment.
- f. Identify and locate additional resources.
9, Develop and maintain mutual aid agreements.
- h. Establish emergency notification procedures.
1 ~ Develop public warning system.
J ~ Establish protective action/evacuation procedures.
- k. Designate On-Scene Coordinators.
- l. Develop public awareness and education program.
III o Identify and designate mass care centers.
- n. Conduct training and exercises.
- 0. Continue planning.
- 2. Response a ~ Notify appropriate officials and agencies.
- b. Dispatch response teams.
C. Establish communications between site and EOC.
- d. Determine hazmat involved.
- e. Determine category of incident.
- f. Fulfill reporting requirements.
g ~ Issue appropriate public warning.
- h. Provide public protective actions guides; lo Control mitigation/containment.
Operate decontamination facilities, as necessary.
- k. Keep County EOC informed of situation.
- l. Report unmet needs.
- 3. Recovery a ~ Continue security of emergency area.
- b. Conduct cleanup operations.
c~ Continue to provide public information.
- d. Conduct re-entry operations.
- e. Conduct damage assessment.
- f. Prepare after-action reports.
g, Continue support of disaster requirements.
- h. Stand down equipment and personnel.
- l. Conduct incident critique.
J ~ Evaluate plan based on critique.
N D. Emergency Notification Reporting responsibilities under SARA and CERCLA are separate.
Reports may be required under either or both statutes. (See Enclosure 1.)
- 1. Types of Releases Requiring Notification, Sec. 304, SARA a ~ SARA/CERCLA Substance Extremely Hazardous Substance which also requires CERCLA Notice.
- b. SARA/non-CERCLA Substance (1) If not a Federally permitted release under CERCLA.
- 2) If in excess of Reportable guantity
- 3) If notification is required by CERCLA(Rg). under Section 103(a).
C. CERCLA/Non-SARA Hazardous Substance which requires CERCLA notice.
(1) I f release equals or exceeds Rg.
- 2) If not required by CERCLA because of Rg but is one pound or more.
- 2. Notification Procedure Following a Release, Sec. 304(b), SARA
- a. Facility Emergency Coordinator Immediately notify (see Paragraph 3.D.3 below for contents of report): (See Enclosure 2.)
(1) LEPC (County EMA) 1-717-825-1776 or 1-717-824-9949
- 2) PERC (PEMA) 1-800-HBG-PENA
- 3) National Response Center (if required) 1-800-424-8802 (see Ref. Para. 20.)
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- b. LEPC (County Emergency Management Coordinator)
Immediately notify in order:
Salem Townshi Fire Co. No. 1 Beach Haven, PA 18601 (717) 752-3677 or 3772 (2) PA State Police Shickshinny Barracks R. D. 81, Box 346 Berwick, PA 18603 (717) 542-4117 (3) Shickshinn Vol. Ambulance Assoc.
50 Furnace St.
Shickshinny, PA 18655 (717) 542-4117 (via Shickshinny PA State Police)
(4) Luzerne Count Commissioners Luzerne County Courthouse Wilkes Barre, PA 18711 (717) 825-1500 (5) Penns lvania Emer enc M t. A enc P.O. Box 3321 Harrisburg, PA 17105 (717) 783-8150 or 1-800-CPA-PEMA (6) PA DER Wi lkes-Barre Office F. William McDonnell Bureau of Solid Waste Management 90 East Union St., Second Floor Wilkes-Barre, PA 18701-3296 (717) 826-2516 (717) 826-2511 (Emergency Only)
(7) Wi lkes-Barre Scranton International Air ort Avoca, PA 18641 (717) 655-3077 Federal Aviation Administration (FAA) contact aircraft are involved.
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- c. Transportation Accident Notification In the event of a transportation accident involving the release of a SARA substance, the carrier representative will notify the 911 operator, county dispatch or the operator. This satisfies the facility reporting responsibility to the LEPC. The County EMC, acting for the LEPC, will notify, in addition to the agencies in 3.D.2.b above:
(1) PERC (PEMA EOC) 1-800-HBG-PEMA (2) National Response Center (if required) 1-800-424-8802 (3) Susquehanna Steam Electric Station Shift Supervisor 24 hr Phone: (717) 542-3907
- 3. SARA/CERCLA Release Form Contents of Emergency Notification Form for SARA/CERCLA Release a ~ Initial Report, Sec. 304(b)(2) SARA (See Enclosure 3)
Initial, immediate report will reference each of the following to the extent known at the time so long as no delay in responding to the emergency results.
(1) Chemical Name Chemical name or identity of any substance involved in the release.
(2) guantity Released Estimate of the quantity of any substance which was released into the environment.
(3) .
Specific location of the release.
(4) Date and time of the release.
(5) Duration of,the release.
(6) Medium or media into which the release occurred.
(7) Known Health Risks known or anticipated acute or chronic health risks I'ny associated with the emergency.
(8) Medical Advice Advice regarding medical attention necessary for exposed individuals, if appropriate.
(9) Protective Measures Recommended Proper precautions to take as a result of the release, including evacuation (unless such information is readily available to the facility emergency coordinator based on the Off-site Response Plan).
(10) Point of Contact The name and telephone number of the person or persons to be contacted for further information.
( 11) 'Actions taken to respond to and contain the release.
(12) Weather Condi ti ons A brief description of the weather at the scene to include preci pi tati on, temperature and wind conditions.
(13) Personnel at Scene Which facility and public responders have already arrived at the scene by the time. this report is rendered.
00 NOT DELAY REPORT TO OBTAIN FULL INFORMATION.
- b. Written Follow-up, Sec. 304(c), SARA A follow-up written emergency notice or notices will be submitted as prescribed in para. 3.D.2.a above by the facility owner/operator. It will update information included in the initial notice and provide additional information on:
( 1) Actions taken to respond "to and contain the release.
(2) Any known or anticipated acute or chronic health risks associated with the release.
(3) When appropriate, advice regarding medical attention necessary for exposed individuals.
E. Emergency Procedures Prior to the arrival of the County designated On-Scene Coordinator (OSC), the fir st responder will establish the primary command post.
Other response services will co-locate command units and operations vehicles at the site selected by the first responder. Each agency will manage its own response, permitting senior managers to coordinate activities and decisions. Upon arrival of the designated OSC, the initial responder may continue as the Organization in Charge, as determined by the OSC. In any emergency deemed
significant by PEMA, a PEMA official will proceed to the scene as On-Scene Liaison Officer. If the Governor proclaims a Disaster Emergency, a PEMA official will be designated On-Scene Coordinator.
F. Protective Actions Evacuation is sometimes, but not always, necessary. When considering evacuation versus sheltering, the following criteria should be reviewed:
- 1. guantity of release
- 2. Additional risk facilities
- 3. Distance from release
- 4. Effectiveness of precautionary measures
- 5. Duration of release
- 6. Health hazards
- 7. Property vulnerability
- 8. Type of Release
- 9. Wind direction
- 10. Sheltering factor of facility
- 11. Sheltering factor of threatened site
- 12. Availability of special transportation
- 13. Area of municipality affected
- 14. Weather
- 15. Potential for outbreak of fire G. List of Additional Institutions/Sites at Risk
- 1. Contribute to Additional Risk a ~ Sun Oil Co. Pipeline
- b. Transcontinental Gas Co. Pipelines C. Arco Co. Oil Pipeline
- d. Gasoline Storage Tanks
- e. Susquehanna Steam Electric Station These facilities are located within three miles of the SSES (See Figure 3).
- 2. Subject to Additional Risk
- a. Riverlands Nature Area
- b. St. Mary's Park These facilities are located within three miles of the SSES (See Figure 4).
There are no hospitals, nursing homes or schools with a three mile radius of the SSES.
H. List of Shipping Routes for SARA Substances
- 1. Via truck
The primary. shipping route is U.S. Route 11.
- 2. Via train - N/A
- 3. Via air - N/A
- 4. Via water - N/A I. Description of Method to Determine Occurrence of a Release
- 1. Land spill
- 2. Water spill
- 3. Gaseous release Visual confirmation. will determine if a release has occurred.
- 4. ORGANIZATION AND RESPONSIBILITIES A. General As directed by the Governor's Executive Order 1987-8 (Reference 6.A.3), Luzerne County is designated as the Emergency Planning District (EPD), functioning, consistent with PERC policy and guidelines, under the direction of the Luzerne County Board of Commissioners. The District is subsumed within the Luzerne County EMA and co-located with it. The Luzerne County EMA is designated as .
the- lead county agency responsible for coordinating the development, execution and management of programs and functions of the LEPC.
B. Local Emergency Planning Committee (LEPC)
A complete list of Luzerne County Emergency Management Agency members is on file and available at the LCEMA.
C. Assignment of Responsibilities (See Enclosure 4)
- 1. County Commissioners
- a. Direct Emergency Planning District Direct the functioning of the EPD, through the EMA, consistent with PERC policy and guidelines.
- b. Nominate, by resolution, an LEPC.
- c. Forward resolution to PERC for approval.
- 2. Local Emergency Planning Committee
- a. Appoint an LEPC Chairperson.
- b. Off-site Response Plan Develop and maintain a Hazardous Material Off-site Response Plan covering each facility in the district.
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Identify Resources Identify resources necessary to implement plans and means of obtaining them.
Coordinate Coordinate, planning for response to hazmat releases with municipal governments.
Supporting Emergency Organizations Identify and task emergency organizations to develop supporting Standing Operating Procedures (SOP).
Information Coordinator Designate an official to serve as coordinator for Right-to-Know information.
Give public notice of its activities.
Information Procedures Establish procedures to rece i ve, s tore and retri eve:
(1) .Material Safety Data Sheets (MSDS) or lists (2) Chemical Inventory Forms Information Requests Establish procedures for handling public requests for above information.
Coordinate with Industry Coordinate with and assist business and industry in the development of the Off-site Response Plan.
Conduct tests and exercises at least annually.
F Institutions/Sites at Risk Identify the additional institutions/sites at risk in the area such as hospitals, schools, shopping mails, office buildings, natural gas suppliers, environmentally sensitive areas, etc. See Paragraph 3.G.
Committee Rules Establish rules by which the Committee is to function, to include:
(1) Provision for public notification of 'LEPC activity.
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(2) Public meetings to discuss plans.
(3) Public comments.
- 4) Response to public comments.
- 5) Distribution of emergency plans.
(6) Procedures for, receiving and processing requests from the public under Right-To-Know.
- 3. Facility Owners/Operators
- a. Cooperate with LEPC Coordinate, cooperate and participate with LEPC in developing the Off-site Response Plan and procedures for responding to an accidental release.
- b. Right-To-Know Procedures Develop procedures for Right-To-Know reporting.
- c. Designate Coordinator Designate and notify LEPC of a Facility Emergency Coordinator who will:
(1) Represent the facility as a member of the LEPC.
(2) Provide historical background of previous releases and/or accidents for planning activities.
(3) Provide information on the chemical and physical properties of the facility's hazardous materials, safety and emergency response information, and hazard mitigation techniques.
(4) Coordinate facility on-site plans with LEPC.
(5) Provide to the LEPC the routes to be used to transport
,extremely hazardous materials.
(6) Maintain a facility resource list for hazmat emergencies.
(7) Conduct training program for facility personnel.
- d. Government Regulations Comply with all applicable Federal, state, county and municipal regulations pertaining to the shipment of hazardous materials to include radioactive materials.
- e. Supply shipping papers with the shipment.
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- f. Precautions to Shipper Provide information to the carrier when the shipment is subject to any special precautions required for safe shipment of the material.
- g. Telephone Contacts Provide 24-hour facility emergency telephone contacts to LEPC.
- h. Notification Notify LEPC and appropriate response organizations at time of an emergency.
- i. Provide technical assistance during emergencies.
- j. Material Safety Data Sheet (MSDS) or List (See Enclosure 2)
Submit a Material Safety Data Sheet (MSDS) for each chemical, or a list of chemicals, to:
(1) LE PC (2) PERC, Attention: Department of Labor and Industry, Room 1503, LSI Building, Harrisburg, PA 17120.
(3) Fire Department The fire department with jurisdiction over the faci1 i ty.
- k. Chemical Inventory Form (See Enclosure 2)
(1) Faci l i ty Owners/Operators Submit an emergency and hazardous chemical inventory form containing SARA Tier I information, annually, on March 1 to:
(a) LEPC (b) PERC, Attention: Department of Labor and Industry, Room 1503, LSI Building, Harrisburg, PA 17120 (c) Fire Department The fire department with jurisdiction over the facility.
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(2) Tier II Information - SARA Officials Agencies in Paragraph 4.C.3.k.(1) above may request Tier II information from a specific facility.
(3) Tier II Information - Other, Public Officials Other state, county or municipal official desiring Tier II information from a facility will make a written request 'through the PERC or LEPC.
(4) Tier II Information - Private Use PERC and LEPC will provide requested Tier II information to persons making written requests in accordance with the Right-To-Know provisions of SARA Title I II.
- 1. Toxic Chemical Release Forms (See Enclosure 2)
Submit a toxic chemical release form, annually on July 1, reflecting releases during the preceding year, to:
( 1) Administrator, Environmental Protection Agency (EPA)
(2) PERC, Attention: Department of Labor and Industry, Room 1503, LSI Building, Harrisburg, PA 17120.
- 4. County Emergency Management Coordinator
- a. Act as Coordinator for LEPC Chairperson.
- b. Work with LEPC to develop Off-site Response Plans.
- c. Designate On-Scene Coordinator (OSC).
Designate county OSC to coordinate activities at the emergency site.
- d. Notify PEMA.
Notify PEMA of Category III and IV emergencies.
- e. Organization in Charge Determine the emergency service organization that will be in charge at the site of neutralization, containment and cleanup.
- f. Identify Key Individuals Identify individuals who are assigned functional responsibilities necessary to the planning and implementation of the Off-site Response Plan.
- g. Develop Notification System Develop a system for rapid notification in priority order of county and municipal government heads, key staff, emergency forces, volunteer organizations, and institutions/sites at risk.
Develop public warning system.
Disseminate Public Information In coordination with Commissioners and the Public Information Officer, prepare and disseminate public information material on protective actions to provide clear instructions to the population at risk. Use EBS and NOAA Weather Radio.
Radiological Health Materials Assist the Department of Health in the distribution of thyroid blocking agents and other radiological health materials in cases of releases involving radiological materials.
- k. Radiological Resources If appropriate, prepare to employ emergency management radiological resources in coordination with PENA.
Reentry Procedures Prepare detailed procedures for coordinated reentry into the evacuated area.
- m. Train Hazmat Responders Provide guidance and training to those individuals, agencies, and services that wi 11 be expected to respond to hazmat incidents.
- n. Notify Shipper Notify shipper and/or consignee of transportation accidents.
- 0. Spokesperson Designate an on-scene spokesperson (public information officer).
- 5. On-Scene Coordinator
- a. Command Post 15
Establish an on-scene command post in a radio-equipped vehicle or facility.
- b. Actions Confirm there has been a release of hazardous material, and if so, direct appropriate actions as follows:
(1) Airborne Release (a) Evacuate the immediate vicinity, or take cover as appropriate.
(b) Keep all persons upwind of the release.
(c) Request air samples for laboratory analysis when possible.
(d) Control all food and drinks in the area which might have been contaminated.
(e) Use respirators when necessary.
(2) Surface Mater Contamination (a) Isolate area; do not allow public access.
(b) Determine if water is used as a potable water source.
(c) Prohibit human consumption.
(d) Request appropriate samples and laboratory analysis (3) Land Spill (a) Isolate the incident area from public access.
(b) Confine the spill to as small an area as possible.
(c) Monitor the areas.
(d) Obtain laboratory samples.
c~ Coordinate actions of response teams on the scene.
- d. Recommend Category of Emergency to EMC.
- e. Taskings to Staff 16
Assign command post staff personnel to assume the following duties:
(1) Law enforcement coordinator (2) Communicatio'ns assistant (3) Any other staff position that may be required to properly coordinate the operation
- f. Supervise and Assist Supervise hazmat recovery and supply technical support needed by industry or recovery team.
- g. Communications Establish and maintain communications with all on-scene response teams and the county EOC.
- h. Brief field personnel as they arrive on scene Liaison Request that on-scene representatives maintain contact with the command post.
J ~ Perimeters Establish the following perimeters, depending on the circumstances: (See Tab G, Figure 5)
( 1) Contamination Area Area around the accident/fire that could contain contamination.
(a) Access to the area requires:
- 1) Proper authorization
- 2) Appropriate protective clothing
- 3) Proper monitoring equipment
- 4) Established time limit in the area
- 5) Personnel record of time in the area (2) Contamination Reduction Zone A buffer perimeter used as a holding area for personnel and equipment waiting to relieve those
-within the contamination area.
(a) The following conditions will be established:
- 1) Safe distance from contamination area to minimize exposure from released materials.
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- 2) No eating, drinking, or smoking within this perimeter.
- 3) Decontamination prior to leaving perimeter.
(3) Command and Support Zone A clean area containing the following:
(a)'learly marked command post.
(b) Backup resources within this zone.
(c) On-scene spokesman for liaison with media and government.
(d) Emergency medical center,'f required.
(e) Sanitation facilities for extended response.
(f) Monitoring station for all personnel to be checked for contamination.
(g) Access Control Points (ACP).
- k. Time Keepers Designate time keepers for each zone to check personnel into and out of the zone and to advise them of the following policies:
(1) Eating, drinking, and smoking.
(2) Maximum time allowable within each zone.
(3) Types of protective clothing required within each zone. ~
- 4) Contamination monitoring on leaving zone.
- 5) Directions to decontamination station if ~
needed. ~
- 1. Monitor Changes Monitor any changes in accident characteristics and evaluate threat to emergency response personnel, traveling public, and nearby residents.
- m. Relocate Perimeters Relocate zone perimeters based on evaluation of changing characteristics.
- n. Additional Expertise Request additional county, state, or federal expertise based on evaluation of changing characteristics.
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- 0. Decontamination Points If required, select and operate decontamination points for chemicals, toxins and radiation. A decontamination point consists of the following:
(1) Change area.
(2) Wash-down procedures.
(3) Plastic bags for contaminated clothing.
(4) Decontamination equipment required.
- 5) Personal showers.
- 6) Scrub-down shuffle boxes.
(7) Changing of self-contained breathing apparatus tanks.
(8) Location of monitoring equipment.
(9) Replacements for damaged or contaminated clothing. (
(10) Respirator replacement cartr idges.
(11) Backup personnel.
- 12) Communications with personnel on scene.
- 13) Garbage cans.
(14) Rest area, with stools for those in a protective clothing.
- 6. Fire and Rescue Chief a ~ Direct Responders Direct fire company(s) and/or hazmat response teams responding to hazardous material emergencies.
- b. Consult with Chemical Emergency Transportation Center (CHENTREC) ( 1-800-424-9300) co Communications Establish communications between the fire command post, the county EOC, and the on-scene command post.
- d. Special Equipment Provide specialized equipment for use in control, containment, and stabilization of the emergency site.
- e. Render any life saving assistance necessary.
Protective Equipment Until assessment has been made, the following protective equipment is recommended inside the hazard area:
( 1) Pressure-demand, self-contained breathing apparatus."
19
(2) Chemical resistant clothing (overalls and long sleeved jacket, coveral 1 s, hooded, one or two piece chemical splash suit, disposable chemical resistant coveralls).
(3) Chemical res i s tant gloves.
(4) Chemical resistant boots (steel toe and shank).
(5) Hard hat or- face shield.
(6) Two-way radio (intrinsically safe).
- g. Stay Upwind Work upwind from the fire and keep out of smoke as much as possible.
If appropriate, extinguish the fire as quickly as possible.
Restrict personnel exposure as much as possible.
Radioactive Materials Do not move or remove any radioactive materials without the consent of the On-Secne Coordinator.
- k. Monitor for Contamination Ensure that all personnel and equipment are monitored for possible contamination prior to leaving the scene.
Keep command post informed.
- 7. Police Chief a ~ Noti fy Penn syl vani a State Po1 i ce (PSP )
Notify the nearest State Police Station and maintain communications.
- b. Restrict access to the accident area.
c~ Maintain Integrity of Area Prohibit the removal of packages, shipping containers, or wreckage.
- d. Detour vehicles and pedestrians, if necessary.
- e. Keep everyone upwind of smoke and dust.
- f. Liaison Provide a designated law enforcement representative to the command post.
20
- g. Provide the following:
(1) Radio-equipped vehicle to provide backup communications.
(2) Traffic control.
(3) Crowd control.
(4) Security of perimeter as established by On-Scene Coordinator.
- h. Evacuation If evacuation of residents is required, provide the county ENC with the following:
(1) Route alerting.
(2) Security for the evacuated area.
(a) Coordinate with PSP and/or National Guard, if mobilized by Governor.
(b) Maintain traffic control.
(c) Assist in evacuation.
(d) Establish Access Control Points (ACP).
(e) Establish Traffic Control Points (TCP).
(f) Use special precautions as directed by On-Scene Coordinator during entry into the site area due to the effects of the hazardous materials.
(g) Keep all persons a safe distance from the accident area until the extent of the hazard is determined. (Suggested distance is 2,000 feet, unless otherwise notified.)
- 8. Responding Health/Nedical Services Officer a ~ Provide emergency medical services to include:
(I) Emergency medical facilities established outside the vulnerable area.
(2) Prehospital care for the sick or injured.
(3) Identification of the causes of sickness or injuries.
21
(4) Conduct of rescue operations for injured.
(5) Communications Communications with county EOC between emergency medical personnel in the field and hospital medical staff.
(6) Transfer Victims Transfer and/or evacuation of victims or bedridden patients with appropriate records.
(7) Liaison Designation of a representative to maintain communications with the command post, advise and assist the On-Scene Coordinator, and coordinate the activities of the medical emergency response personnel.
(8) Request additional ambulances as necessary.
- b. Decontamination Facility Obtain from EOC name of closest hospital emergency rooms capable of decontamination (including radiation decontamination).
- c. Antidote Information Obtain from County Health/Medical Services- Officer a list of area hospitals capable of providing antidotes for major toxic chemicals.
- d. Medical Advice Provide advice to On-Scene Coordinator on health hazards during hazardous materials emergencies.
- e. DER Coordination Coordinate with DER representative in determining air pollution and toxic gases during a release.
- f. Review plans for equipment and training requirements.
(1) Training All individuals working on the SSES site, inside the protected (fenced) area, are provided with instructions on warning signals, assembly areas and evacuation routes as part of General Employee Training (GET). GET also includes Right-to-Know Training and Hazard Communication information.
22
PPSL also has a Fire Safety Program which includes a Fire Safety Training Program. The SSES Fire Brigade Training includes a 16 hour1.851852e-4 days <br />0.00444 hours <br />2.645503e-5 weeks <br />6.088e-6 months <br /> Hazardous Naterial Response Course conducted at the Harwood Fire School. The Fire Brigade devotes one quarter each year to hands-on training at the Harwood Fire School which includes practice sessions on fighting various types of fires, donning of protective equipment and emergency breathing apparatus.
PP8L provides training annually to local off-site suppor t organizations. These local organi zati ons are encouraged to become familiar with the SSES, key station personnel, and are invited to attend training conducted by or for PPSL.
Ini'tial core training for local fire companies and ambulance associations includes:
o Interface with the Site Security Force o Basic health physics indoctrination and training o SSES facility layout Fire companies also receive training in the following areas:
o On-site fire protection system equipment o Differences between on-site fire fighting equipment and fire company supplied equipment o Communications system o Review of sections of the SSES Emergency Plan and Emergency Plan Implementing Procedures o The on-site Nuclear Emergency Response Organization with emphasis on the interface between the SSES fire brigade and fire company personnel Annually, local ambulance associations are invited to attend specialized training regarding the handling of contaminated/injured victims.
The SSES Fire Brigade holds drills each quarter and a fire drill is conducted annually which includes local fire company support. Alternatively, medical and fire drills involving offsite support may be integrated within annual drills required by the Nuclear Regulatory Commission.
In addition to the hazardous material training of the Fire Brigade, hazardous waste workers and chemistry 23
personnel involved in spill response, receive formal training on hazardous chemical spill response and fundamentals of personal protection for hazardous material. Training is conducted annually and includes both "Hands-On" training and classroom training.
Results are formally documented for this and all training by the Nuclear Training Group.
(2) Emergency Equipment The SSES has an extensive supply of equipment on-site available for use during an emergency, including a spill response trailer. Emergency equipment is listed and described in Tab F - Facility Resources.
- 9. On-Scene Spokesperson
- a. Gather Information Gather information from the various on-scene response personnel, condense it, and pass it on to the county public information officer for approval.
- b. Release of Information Act as single point-of-contact with media and municipal governments.
C. Coordinate with facility public relations officer.
- 10. Transportation Officer a ~ Provide liaison to EMA.
- b. Mass Transportation Obtain mass transportation vehicles and drivers for evacuation of residents.
co Recommend alternative routes for traveling public.
- 11. Public Works/Engineering Officer a ~ Coordinate provision for sanitation services at the scene.
I
- b. Designate a representative to:
24
~'
(1) Advise and assist the On-Scene Coordinator.
(2) Maintain communications with the command post.
(3) Coordinate debris removal.
(4) Coordinate provision for heavy equipment and operators.
- c. Provide assistance as requested by On-Scene Coordinator.
- d. Shut Off Utilities Coordinate termination of electrical power and gas to facility during emergency.
- e. Assess sewer contamination after emergency.
- 12. School District Representative
- a. Provide liaison with EMA.
- b. Provide county EMC with list of schools in the risk zone
- c. Direct school evacuations planning.
- d. Coordinate school bus unmet needs during evacuations.
- e. Hos't Schools/Mass Care Centers Provide list of schools that may be used as host schools or mass care centers during emergencies.
- 13. Department of Environmental Resources (DER)
- a. Conducts environmental monitoring of:
(1) All hazardous materials, including air, water, soil, livestock, vegetation and environmentally sensitive areas.
(2) Washdowns or runoffs,including natural water paths, culverts, storm drains, and surface waters.
(3) Site cleanup.
. b. Determine when area is 'safe for reentry.
- 5. ADMINISTRATION AND LOGISTICS A. Availability of MSDS on Request 25
- 1. LEPC If the facility owner submits a list of chemicals, the LEPC may request an MSDS for any chemical on the list.
- 2. Public Upon written request, the LEPC will make available an MSDS to any person in accordance with prescribed procedures. If the LEPC does not have the MSDS, it shall be requested from the facility owner and made available to the requester.
B. Document Availability to Public The following documents will be made available to the public during normal working hours at the Luzerne County Emergency Management Agency:
- 1. Off-site Response Plans
- 2. MSDS
- 3. Lists of chemicals submitted in lieu of MSDS Chemical inventory form
- 5. Toxic chemical release form
- 6. Follow-up emergency notice C. Notice of Public Availability LEPC will annually publish a notice in local newspapers that the Off-site Response Plan, MSDS and inventory sheets have been submitted. This notice should also announce that members of the public who wish to review the above may do so at the prescribed location.
D. Toll Free Telephone Systems
- 1. CHEMTREC 1-800-424-9300
- 2. National Response Center 1-800-424-8802
- 3. National Agricultural Chemicals Assn.
(Pesticides/Insecticides), 1-800-424-9300
- 4. PEMA 1-800-HBG-PEMA
- 5. PENA Area Office
- a. Eastern 1-800-EPA-PEMA
- b. Central 1-800-CPA-PEMA
- c. Western 1-800-WPA-PEMA E. Supporting Documents
- 1. Facility area map (Tab A)
- 2. Rules and by-laws (Tab B)
- 3. Letters/memoranda of Agreement (Tab C)
Emergency telephone roster (Tab D)
- a. Participating agencies
- b. Technical personnel 26
Pl C. Response personnel
- d. CHEMTREC
- e. Facility personnel
- f. Community assistance
- 9. Volunteer groups
- h. State agencies
- l. Media
- 5. Community Resources (Tab E) a ~ Fire depar tments/hazmat teams
- b. Police/sheriff C. Emergency medical/paramedic services
- d. Emergency management services e; List of vehicles
- f. List of equipment
- g. Medical care sites with decontamination facilities
- h. -Public health agency 1 ~ Environmental agency Public works/transportation departments
- k. Red Cross
- l. Mass care centers
- m. Chemical manufacturers
- n. Commercial cleanup contractors
- 0. Mitigation resources (foam, sand, lime)
- 6. Facility Resources (Tab F) a ~ List of technical aspects
- b. List of equipment c~ List of vehicles
- d. Medical care systems
- e. Clean up and recycling capabilities
- 7. Maps and Tables (Tab G)
- 6. AUTHORITY AND REFERENCES A. Authorities Superfund Amendments and Reauthorization Act of 1986 (SARA), Public Law 99-499, October 17, 1986.
- 2. Comprehensive Environmental Response, Compensation and Liability Act of 1980, P.L.96-510 (CERCLA or "Superfund".)
- 3. Executive Order 1987-8, Governor's Office, Commonwealth of Pennsylvania, April 20, 1987.
B. References National Response Team, Hazardous Materials Emergency Planning Guide, March 1987.
27
- 2. Federal Registers
- a. April 22, 1987, Part II, 40 CFR Part 355 and Appendix A, List of 406 Extremely Hazardous Substances.
- b. March 16,, 1987, 40 CFR Part 302, CERCLA List of 717 Hazardous Substances.
- c. June 4, 1987, Part II, 40 CFR Part '372, Toxic Chemical List, Chemical Release Reporting, Community Right-To-Know.
- d. January 27, 1987, Part III, 40 CFR Part 370, Hazardous Chemical Reporting, Emergency Planning and Community Right-To-Know (Tier I and Tier II Forms).
- 3. Susquehanna SES, Emergency Plan, Rev. 11, 10/88.,
- 4. Susquehanna SES, Preparedness, Prevention and Contingency Plan, Rev. 2, 6/88.
- 5. Susquehanna SES, Final Safety Analysis Report, Rev. 40, 9/88.
- 7. DEFINITION OF TERMS See Enclosure 5)
- 8. TRAINING AND EXERCISES A. Training Standards
- 1. PERC PEMA training programs will meet or exceed Federally imposed training standards. Revisions to existing programs wi l'l be implemented as required to meet changes in these standards.
- 2. Responders Any individual who has not received the specified training is prohibited from engaging in hazardous waste operations covered by the established standard.
- 3. Certificates Certificates of training standards will be established for each category.
B. Training
- 1. P ERG PEMA will arrange, through the PEMA Area offices, appropriate cour ses to LEPC and facility personnel at the following locations:
28
- a. State Fire Academy
- b. Emergency Management Institute, Emmi tsburg, MD
- c. National Fire Academy, Emmitsburg, MD
- 2. Faci 1 i ty Emergency Coordinators Develop training programs and schedules for:
a ~ General site workers
- b. On-site managers C. Supervisors
- d. On-site emergency response workers
- 3. County EMCs
- a. Include hazmat instruction in training programs and schedules for: ,4 (1) First responders (2) Second responders (3) Emergency medical personnel (4) Supervisory personnel
- b. . Conduct annual, on-site workshop together with team of first responders, with each facility to review:
(1) Notification procedures (2) Emergency plans (3) Training schedule
'4) Exercise programs C. Exercises
- 1. Facility Coordinator Conduct annual tabletop or simulation-type exercises with facility personnel.
- 2. LEPC Coordinator
- a. Schedule annual tabletop exercises for all 'response personnel involved in hazmat operations.
- b. Incorporate facilities into annual PEMA/County all-hazard exercise program. Exercise rotation should ensure that, each facility in the district is incorporated into scenario play a minimum of every three years.
- 9. PLAN DEYELOPMENT AND MAINTENANCE A. LEPC Plans 29
An Off-site Response Plan will be developed by the LEPC with the cooperation of the faci 1 i ty owner/operator.
Facility Emergency Coordinator The facility owner/operator will notify the LEPC of the facility representative who will participate in the planning process as the facility emergency coordinator.
Facility Updates to LEPC The facility owner/operator will promptly inform the LEPC of any relevant changes occurring at the facility as such changes occur or are expected to occur.
Planning Information Upon request from the LEPC, the facility owner/operator will promptly provide information to the Committee necessary for developing and implementing the Off-site Response Plan.
PERC Review of Plan The LEPC will forward the plan to the PERC for review and recommend revisions. To the maximum extent practicable, such review will not delay implementation of the plan.
LEPC Annual Review The plan will be reviewed annually by the LEPC one month prior to its anniversary date. Revisions, as appropriate, will be forwarded to the PERC for review prior to the anniversary date.
Quarterly Review Revisions such as names and telephone numbers will be changed as
'required. A quarterly review will be conducted to ensure accuracy. The Emergency Management Coordinator and the facility coordinator may exchange this information telephonically.
Copies of Plan Citizens desiring copies of this plan may obtain one through the LEPC which will be reimbursed for the cost of reproduction only.
Initial distribution of this plan is:
PERC County Commissioners LEPC County EMC ~
Mayor Municipal Manager or Council Municipal EMC 30
Fire Department Police Department Rescue Service School District (as appropriate)
High School (as appropriate)
Elementary School (as appropriate)
Department of Public Works Old Folks Home (as appropriate)
Day Care Center (as appropriate)
Natural Gas Plant (as appropriate)
Nunicipal Library Susquehanna Steam Electric Station J. Regional Response Team Review Upon request of the PERC, the Regional Response Team (RRT),
composed of Federal regional officials and state representatives, may review the plans and provide assistance.
31
I"
- 10. ENCLOSURES Release Reporting Decision Chart
- 2. Notification and Reports Flow Chart
- 3. Emergency Release Notification 4, LEPC Notification Coordination
- 5. Definitions 32
ENCLOSURE 1 RELEASE REPORT I NG DECISION CHART RKX KA S K TO KNU X AC3NMKNT REPORT TO HO >CERCLA RQ ? YES HAT I ONAL
't8 CFR BO2 RESPONSE SEE PARA 6 B~ 2~ B
~
CENTER
>SARA RQ ?
YES
+8 CFR 355 SEE PARA 6 ~ B ~ 2 ~ C REPORT YES TO PERC STOP BEYOND <PEl1A EOC)
HO NO FACILITY BOUNDARY REPORT
? YES TO LEPC (COUNTY EMA>
ENCLOSURE 2 NOTIFICATION AND REPORTS FLOW CHART INITIAL NOTIFICATION PERC EPA (SEC. 302)
LEPC MSDS PERC (SEC. 311) L&I LEPC (Cour. ZZ)
LOCAL 911 FIRE OR DEPT, XXX-ZGZ C~ICAL EMERGENCY INVENTORY NOTIFICATION FORM PERC FACILITY LEPC (PE+ EOC) (SEC. 304) (SEC. 312) 1-800-HBG-PE."tA PERC L&i NATIONAL WHEN RESPONSE REQUIRED LOCAL CENTER FIRE TOXIC DEPT.
1-800-424-8802 CHEMICAL RELEASE FORMS PERC (SEC. 313) LLI NOTE: L&I vf,ll provide MSDS data as requested by PERC &'EPCs.
ENCLOSURE 3 EMERGENCY RELEASE NOTIFICATION This reporting is applicable ONLY for the release of a Reportable Quantity (RQ) of any EXTREMELY HAZARDOUS SUBSTANCE or CERCLA HAZARDOUS SUBSTANCE which results in exposure to persons OUTSIDE the site boundaries. The following information is for State and County agencies and is to be reported WITHOUT DELAY to the extent the information is known at the time.
DATE, TIME OF CALL AND PERSON RECEIVING CALL:
DATE TIME NAME LERC (Luzerne County EMA) 717-825-1777 PERC (PEMA EOC) 1-800-HBG-PEMA Nat'1 Resp Center 1-800-424-8802 (if required under under CERCLA 40 CFR 302.6)
PERSON MAKING NOTIFICATION XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX RELEASE INFORMATION Start report with one or the other of these:
"This is the agencies p ~gq plant located in g
in accordance with our prior plan.
p~fi The
. 'e release includes (Choose one) "Extremely Hazardous Substance" or a "CERCLA Hazardous have a chemical d
a Title III Substance." The following information is available: (read numbers 1 through 13)
OR "This is the We 1 y f ~y, plant located in ply have had a reportable release but do response. The following information is i 1 Ti ~pit not believe available:
This call is to ig q warrants an emergency (read numbers 1 through 13).
DO NOT DELAY REPORT FOR FULL INFORMATION
- 1. CHEMICAL NAME OF SUBSTANCE RELEASED
- 2. QUANTITY RELEASED (LB)
- 3. LOCATION OF RELEASE
- 4. DATE AND TIME OF RELEASE
- 5. DURATION OF'ELEASE
- 6. RELEASE WAS INTO: AIR SURFACE WATER SEWER GROUND
- 7. ANTICIPATED ACUTE OR CHRONIC HEALTH RISKS:
- 8. ADVICE ON MEDICAL ATTENTION FOR EXPOSED INDIVIDUALS (IF APPROPRIATE)
- 9. PROPER PRECAUTIONS TO TAKE (INCLUDING EVACUATION IF APPROPRIATE)
- 10. NAME AND PHONE NO. OF PERSON TO CONTACT FOR FURTHER INFORMATION:
PHONE:
- 11. RESPONSE ACTIONS:
- 12. WEATHER CONDITIONS:
- 13. RESPONSE PERSONNEL AT SCENE:
NOTE: IF DECISION WAS MADE NOT TO NOTIFY LERC AND PERC, RECORD REASON:
ADDITIONAL INFORMATION IF TRANSPORTATION ACCIDENT
- 1. TYPE OF INCIDENT (VEHICLE, PLANT, RAIL, ETC.)
- 2. PLACARD/LABEL INFORMATION
- 3. CONTAINER TYPE
- 4. CARRIER
- 5. IDENTITY OF OWNER/SHIPPER
Enclosure 4 LEPC Notification and Coordination PEMA LEPC FAA Area ( County.'Commissioners) as (County EMC) required (Facility Coordinator)
Par 1-4 School DER On-Scene Trans On-Scene District Region Coordinator Officer Spokespe son Par 12 Par 13 Par 5 Par 10 Pa 9 Fire/Rescue Police Health/ Public works HAZMAT Chief Chief Medical Engineering Par 6 Par 7 Par 8 Par 11 xxxxxxxx Notification Notification and Coordination
P ENCLOSURE 5 DEFINITIONS
- 1. CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act regarding hazardous substance releases into the environment and the cleanup of inactive hazardous waste disposal sites commonly referred to as "Superfund."
- 2. CHEMTREC - The Chemical Emergency Transportation Center(CHEMTREC) has a centralized toll free telephone service ( 1-800-424-9300) which has been set up to provide immediate advice on the nature of the product and steps to be taken in handling the early stages of transportation emergencies when hazardous chemicals are involved. CHEMTREC promptly contacts the shipper of the material involved for more detailed information and appropriate follow-up action, including on-scene assistance when feasible.
- 3. CHLOREP - The Chlorine Emergency Plan (CHLOREP) was established by the Chlorine Institute to enable the nearest producer of chlorine products to respond to an accident involving chlorine. CHEMTREC serves as the communications link for this program.
- 4. Combustible Liquids - Any liquid having a flash point at or above 100 degrees F and below 200 degrees F.
- 5. Compressed Gases - Any material or mixture having in the container a pressure exceeding 40 psi absolute at 70 degrees F, or a pressure exceeding 104 psi absolute at 130 degrees F, or any liquid flammable material having a vapor pressure exceeding 40 psi absolute at 100 degrees F.
- 6. Corrosive Material - Any liquid or solid that causes visible destruction of human skin tissue or a liquid that has a severe corrosion rate on steel.
- 7. Etiologic Agents - Any viable microorganism, or its toxin, which causes or may cause human disease.
- 8. Explosive - Any chemical compound, mixture or device, the primary or common purpose 'of which is to function by explosion, with substantially instantaneous releases of gas and heat.
- a. Class A Explosive - detonating or otherwise of maximum hazard.
- b. Class B Explosive - function by rapid combustion rather than detonation and include some explosive devices such as special fireworks, flash powders, etc.
C. Class C Explosive - certain types of manufactured articles containing Class A or Class B explosives, or both, as components but in restricted quantities and certain types of fireworks.
E
- d. Blasting Agents - a material designed for blasting which has been tested and found to be so insensitive that there is very little probability of accidental initiation to explosion or of transition from deflagration to detonation.
- 9. Extremely Hazardous Substance - A hazardous substance identified by EPA as extremely hazardous and meeting reporting requirement under SARA.
Extremely hazardous substances (406) are listed in Part II, 40 CFR Part 355, Appendix A.
- 10. Facility - All buildings, equipment, structures, and other stationary items which are located on a single site or on contiguous or adjacent sites and which are owned or operated by the same person. For purposes of Sec. 304 SARA, includes motor vehicles, rolling stock, and aircraft.
Flammable Liquids - Any liquid having a flash point below 100 degrees F.
- 12. Flammable Solids - Any solid material, other than an explosive, which is liable to cause fires through friction, retained heat from manufacturing or processing, or which can be ignited readily, and when ignited burns so vigorously and persistently as to create a serious hazard.
- 13. HIT - Hazardous Information Transmission program provides a digital transmission of the CHEMTREC emergency chemical report to first responders at the scene of a hazardous materials incident. The report advises the responder on the hazards of the materials, the level of protective clothing required, mitigating action to take in the event of a spill, leak or fire, and first aid for victims. HIT is a free public service provided by the Chemical Manufacturers Association. Reports are sent in emergency situations only to organizations that have preregistered with HIT and have a computer available with Modem. Call CHEMTREC 1-800-9300.
- 14. Hazardous Material (Hazmat) - Refers generally to hazardous substances, petroleum, natural gas, synthetic gas, acutely toxic chemicals and other toxic chemicals. The Secretary of Transportation, U.S. Department of Transportation has determined that a hazardous material is a substance or material which is capable of posing an unreasonable risk to health, safety and property when transported in commerce. Hazardous materials include, but are not limited to:
a ~ Explosives Radiological materials c~ Etiologic (disease carrying) agents
- d. Flammable liquids or solids
- e. Combustible liquids or solids
- f. Poisons or poison gases
- 9. Oxidizing or corrosive materials
- h. Irritants 1 ~ Compressed gases
- 15. Hazardous Substance - A substance identified as hazardous and meeting reporting requirements under CERCLA. CERCLA hazardous substances (717) are listed in 40 CFR, Part 302.
- 16. Hazardous Waste - Any garbage, refuse, sludge from an industrial or other waste treatment plant, sludge from a water supply treatment plant, or air pollution control facility and other discarded material including solid, liquid, semisolid or contained gaseous material resulting from municipal, commercial, industrial, institutional, mining, or agriculture operations, and from community activities, or any combination of these factors which, because of its quantity concentration, or physical, chemical, or infectious characteristics may:
- a. Cause or. significantly contribute to an increase in mortality or morbidity in either an individual or the total population; or
- b. Pose a substantial present or potential hazard to human health or the environment when improperly treated, stored, transported, disposed of or otherwise managed.
- 17. Irritants - A liquid or solid substance which, upon contact with fire or when 'exposed to air, gives off dangerous, or intensely irritating fumes, but not including any poisonous material.
- 18. LEPC - Local Emergency Planning Committee responsible for preparing hazardous material plans and reports in accordance with SARA Title III.
- 19. MSDS - Material Safety Data Sheet is a document that provides detailed information on chemical substances.
- 20. NRC - National Response Center, a communications center for activities related to response actions, is located at Coast Guard headquarters in Washington, DC. The toll-free number (800-424-8802) can be reached 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> a day for reporting actual or potential'ollution incidents.
- 21. NRT - National Response Team, consisting of representatives of 14 government agencies, is the principal organization for implementing the National Contingency Plan (NCP). When the NRT is not activated for a response action, it serves as a standing committee to develop and maintain preparedness, to evaluate methods of responding to discharges or releases, to recommend needed changes in the response organization, and to recommend revisions to the NCP. The NRT may consider and make recommendations to appropriate agencies on the training, equipping, and protection of response teams; and necessary research, development, demonstration, and evaluation to improve response capabilities.
- 22. Organic Peroxide - An organic compound the bivalent-o-o structure and which may be considered a derivative of hydrogen peroxide where one or more of the hydrogen atoms have been replaced by organic radicals.
- 23. ORM - Other Regulated Materials - Any material that may pose an unreasonable risk to health and safety or property when transported in commerce and does not meet any of the definitions of the other hazard classes.
- 24. Oxidizers - Any substance such as chlorate, permanganate, inorganic peroxide, or a nitrate that yields oxygen readily to stimulate the combustion of organic matter.
- 25. PENA - Pennsylvania Emergency Nanagement Agency to include the headquarters in Harrisburg and the three Area offices (Eastern, Hamburg; Central, Selinsgrove; Wester, Indiana).
- 26. PERC - Pennsylvania Emergency Response Commission - Responsible for overall policy and direction of statewide emergency planning and notification activities and organization consistent with the provisions of SARA.
- 27. Pesticide Safety Team Network (PSTN) - Consists of approximately 40 emergency teams located throughout the country operated by the National Agricultural Chemical Association. Teams will respond to hazardous emergencies involving agricultural chemical pesticides. CHEMTREC serves as the communications link for this program.
- 28. Poison A - Poisonous gases or liquids of such nature that a very small amount of the substance mixed with air is dangerous to life.
- 29. Poison 8 - Substances, liquids or solids (including pastes and semisolids), other than Class A Poisons or irritation materials, which are known to be toxic to man as to afford a hazard to health or which in the absence of adequate data on human toxicity, are presumed to be toxic to man. t
- 30. Pyrophoric Liquids - any material, or combination of materials, that spontaneously emits ionizing radiation and having a specific activity greater than 0.002 microcuries per gram.
- 32. Release -,Any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping, leaching, dumping, or disposing into the environment (including the abandonment or discarding of barrels, containers, and other closed receptacles) of any hazardous chemical, extremely hazardous substance, or toxic chemical.
- 33. RRT - Regional Response Teams composed of representatives of federal agencies and a representative from each state in the federal region.
During a response to a major hazardous materials incident involving transportation or a fixed facility, the OSC may request that the RRT be convened to provide advice or recommendations in specific issues requiring resolution. Under the NCP, RRTs may be convened by the chairman when a hazardous materials discharge or release exceeds the response capability qvailable to the OSC in the place where it occurs; crosses regional boundaries, or may pose a substantial threat to the public health, welfare, or environment, or to regionally significant amounts of property.
Regional contingency plans specify detailed criteria for activation of RRTs. RRTs may review plans developed in compliance with Title III, if the Local Emergency Planning Committee so requests.
- 34. SARA - The "Superfund Amendments and Re-authorization Act of 1986." Title III of SARA includes detailed provisions for community planning to respond to hazardous material releases.
- 35. Spill - Accident allowing material to flow or escape from containment.
- 36. Spontaneously Combustible Materials (Solid) - Any solid substance, (including sludges and pastes) which may undergo spontaneous heating or self-ignition under conditions normally incident to transportation or which may, upon contact with the atmosphere, undergo an increase in temperature and ignite.
- 37. Superfund - The trust fund established under CERCLA to provide money the OSC can use during a cleanup.
- 38. Title III - The "Emergency Planning and Conmunity Right-to-Know Act of 1986.". S'pecifies requirements for organizing the planning process at the state and municipal levels for specified extremely hazardous substances; minimum plan content; requirements for fixed facil'ity owners and operators to inform officials about extremely hazardous substances present at the facilities; and mechanisms for'aking information about extremely hazardous substances available to citizens.
- 39. Toxic: Chemicals - Toxic chemicals identified as chemicals of concern by states of New Jersey and Maryland (329 chemicals/chemical categories).
This list of chemicals is subject to Toxic Chemical Release Reporting under SARA, Title III, Section 313.
- 40. Mater Reactive Materials (Solid) - Any solid substance (including sludges and pastes) which, by interaction with water, is likely to become spontaneously flammable or to give off flammable or toxic gases in dangerous quantities.
gasrpb8287i/1(25)
- 11. TABS A. Facility Area Map B. Rules and By-Laws C. Letters/Memoranda of Agreement D. Emergency Telephone Roster E. Community Resources F. Facility Resources G. Maps and Tables H. Material Safety Data Sheets
8 TAB A FACILITY AREA MAP
West Nanticoke ec Nanticoke 239 na hon a"e gas Shickshinny N
~
Beach Haven Ber wick escopeck 93 80 Conyngham 0
0 l 2 3 4 5 ttti/ae Hasleton Susquehanna Steam Electric Station Area Map
TAB B RULES AND BY-LAMS 46
/
RULES AND BY-LAWS The rules and by-laws for this plan have not been established. These are scheduled to b'e written as a cooperative effort between the Luzerne County Emergency Management Agency (LCEMA) and the Susquehanna Steam Electric Station (SSES).
Procedures for handling hazardous material emergencies can be found in the Susquehanna Steam Electric Station Preparedness, Prevention and Contingency Plan, Sections 10-17, Section 19 and Appendix A.
47
TAB C LETTERS/MEMORANDA Of AGREEMENT
Letters of Agreement Letters of. Agreement have been established with those State and Local agencies as well as local and industry support service groups that are responsible to ensure a high level of emergency preparedness for the SSES. These agreements have been established to assure all parties are aware of their commitment to SSES and the public in the vicinity of the SSES during an emergency.
The following list of agencies and support groups have signed letters of agreement:
A enc /Su ort Grou Pennsylvania Emergency Management Agency Pennsylvania DER/BRP GE BWR Emergency Support Radiation Management Corp.
Luzerne County Commissioners Columbia County Commissioners Berwick Hospital Geisinger Medical Center Shickshinny Volunteer Ambulance Assoc.
Nescopeck Volunteer Ambulance Assoc.
Hobbie Volunteer Fire Co. Ambulance Pond Hill-LilyLake Ambulance Association East Berwick Hose Co. $ 2 Salem Township Fire Co. 41 Shickshinny Fire Department Reliance Fire Co.
Institute of Nuclear Power Operations Safety Light Corporation These letters of agreement provide for:
o Coordination of planning efforts by State and local agencies; industry support groups; fire ambulance and hospital support services; and Pennsylvania Power and Light Co.
o Appropriate emergency response to assure employee and public safety dur'ing an emergency'ondition at SSES.
Mutual notification capabilities.
o Appropriate training and exercising of emergency response capabilities.
o Fire, first aid and medical support.
o Environmental monitoring and assessment support.
o Other 'emergency support services as deemed necessary The Manager-Nuclear Services is responsible for renewing letters of agreement every two years where applicable. In some instances, where the letter of agreement is for a specified duration longer than 2 years, letters need not be renewed end of the specified duration.
until'he Copies are maintained and controlled within SRMS to assure appropriate review and updating takes place.
l TAB D EMERGENCY TELEPHONE ROSTER 50
P OFFSITE AGENCIES ANI: (203) 677-7305 DER/BRP P.O. Box 2063 AMERICAN NUCLEAR SOCIETY Harrisburg, PA 17120 555 N. Kensington Ave. 787-2480 or 787-3479 LaGrange Park, ILL 60525 BRP Rad - CTN'4964 Telephone: (312) 352-6814 BRP Technical - CTN 4965 Telecopier: (312) 353-0499 EAST BERWICK HOSE COMPANY f2 BECHTEL POWER CORPORATION 5th and Central Avenue Security Control Center Berwick, PA 18603 415) 768-3840 752-3577, 752-3678, or 752-3772 415) 768-3841 (415) 768-3842 EPRI A. David Rossin BERWICK HOSPITAL Office: (415) 855-2061 701 East 16th Street Home: (415) 948-7939 Berwick, PA 18603 EPRI Security: (415) 855-2321 759-5000 GEISINGER MEDICAL CENTER BIO LAB PROJECT DIRECTOR Danville, PA 17822 Laboratory 717-542-2191 Emergency Dept. 1-271-6591 Director 717-683-5268 Life Flight 1-271-6666 Backup 717-683-5275 GENERAL ELECTRIC CEMA BWR Emergency Support
. Court, House (408) 971-1038 West Main Street Bloomsburg, PA 17815 HOBBIE VOLUNTEER FIRE COMPANY 1-784-6300 or CTN 4955/4956 R.D. g2 Wapwallopen, PA 18660 COUNTY CORONER 379-3086 or 379-3013 Dr. George Hudock, Jr.
Court House 825-1664/1665 HUNLOCK CREEK AMBULANCE ASSOCIATION Mercy Hospital (Office) 826-3474 P.O. Box 35 Home 287-3418 Hunlock Creek, PA 18621 Chief Deputy Coroner 542-7514 Court House 825-1664/1665 Business 693-1130 INPO Home 693-0709 1100 Circle 75 Parkway, Suite 1500 Assistant Deputy Coroner Atlanta, GA 30339 Court House '825-1664/1665 Emergency Response Center Business 823-7157 (404) 953-0904 or (404) 952-0922 Home 822-0967
IN LCEMA PHILADELPHIA ELECTRIC COMPANY Control'enter, Courthouse Mutual Radiological Support Wilkes-Barre, PA 18711-1001 Peach Bottom Power Station 8 am-5 pm - 825-1776 (717) 456-7014 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> service - 824-9944 Courthouse SW - 825-1500 POND HILL-LILYLAKE AMB. ASSOC.
CTN 4906/4907/4908 R.D. $ 1 Wapwallopen, PA 18660 NATIONAL WEATHER BUREAU 379-3337 (717) 655-'9331 or RELIANCE FIRE COMPANY (717) 457-6377 501 West Third Street Berwick, PA 18603 NESCOPECK AMBULANCE ASSOCIATION 752-5621 Warren Street Nescopeck, PA 18635 SAFETY LIGHT CORPORATION 1-784-7911 4150 Old Berwfck Road Bl oomsburg, PA 17815 PEMA (717) 784-4344 P.O. Box 3321 After 5 pm John Watts 925-2887 Harrisbur g, PA 17105 1-783-8150 or CTN 4960/4961 SALEM TOWNSHIP FIRE COMPANY NO. 1 Beach Haven, PA 18601 PENNSYLVANIA GAS AND WATER COMPANY 752-3577 or 752-3772 Operating control of pipeline 829-8624, 823-3211, or 825-7053 SHICKSHINNY AREA VOLUNTEER FIRE COMPANY Distribution System 81 North Main Street 829-8734 or 800-432-8017 Shickshinny, PA 18655 542-4155 PENNSYLVANIA STATE POLICE Shickshinny Barracks SHICKSHINNY VOLUNTEER AMBULANCE ASSOC.
R.D. 81, Box 346 50 Furnace Street Berwick, PA 18603 Shickshinny, PA 18655 542-4117, 542-4118, or 542-4119 542-4117 (via Shickshinny PSP)
Troop P Wyoming, PA 18644 TELEDYNE ISOTOPES
$ 87-2185 or 693-2442 50 VanBuren Avenue Westwood, NJ 07675 SAMPLE ANALYSIS (201) 664-7070 After hours:
Al Hogan: (201) 666-8548 Dr. Martin: (201) 391-1676 Or. Jeter: (201) 767-3359 HELICOPTER CHARTER SERVICE Horsham Valley Airways 451 Caredean Drive Horsham, PA 19044 215-674-2100 215-674-2871
TAB E COMMUNITY RESOURCES 53
11.E.l ARRANGEMENTS WITH EMERGENCY RESPONSE CONTRACTORS Attachment 11.E. 1 lists private emergency response contractors that Susquehanna could use in the event of an emergency or spill. All PPIIL facilities are furnished with this list of contractors. The list. includes each contractor's name, address, and phone number.
Attachment 11.E.1 LIST OF EMERGENCY RESPONSE CONTRACTORS PENNSYLVANIA Industrial Waste Removal, Inc (0&C) 2 - ox 141 Lewisberry, PA 17339-9537 Business Phone: (717) 938-6745 24-Hour Phone: (717) 236-0476 Home Phones: (717) 766-7659 (James Kohr)
(717) 657-3450 (Steven Kohr)
Inland Pum in and Dred e (0)
. 0. Box 140 Downingtown, PA 19335 Business Phone: (215) 269-3900 (24-Hour)
Contact:
Dale Yeager Mid-State Tradin Co. (08C) 2 5 renton venue P. 0. Box 3275 Williamsport, PA 17701 Business Phone: (717) 326-9041 Contacts: Sam Simon Julius Simon J. L. Beatt Inc. (0) est a>n treet Norristown, PA 19403 Business Phone: (215) 631-1124 Home Phones: 215) 539-0663 (Roger Beatty) 21,5) 368-0510 (Boyd Deiley)
Attachment 11.E. 1 Henr Yeska 5 Sons Inc. (0) ox Georgetown Road Nazareth, PA 18064 Business & (215) 759-3290 (Henry Yeska)
Home Phone:
1 Home Phones: (215) 759-5635 (Donald D. Siegfried)
(215) 759-0649 (Henry Yeska, Jr.)
J. Yer er Waste Oil (0)
~ ~
Pine Grove, PA 17963 Business Phone: (717) 865-4441 Mobile Dred in 5 Pum in Com an (05C) ottstown oa P. 0. Box 237 Exton, PA 19341 Business Phone: (215) 363-6677 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
Contact:
Howard A. Harris Waste Conversion (C)
Hatfield, PA 19440 Business Phone: (215) 822-8996
Contact:
Steve Lamber Petroc cle Inc. (0) ox York, PA 17405 Business Phone: (717) 843-0981 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
Contact:
George L. Cramer, Jr.
Attachment 11.E.1 NEW JERSEY Coastal Services
~8 Paulsboro, NJ 08066 Business 5 24-Hour Phone: (609) 423-2700 Mome Phones: 609) 423-7377 (Steve Weber) 609) 468-7675 (Joe Oouglas)
(609) 423-1733 (Russ Ricca)
(609) 468 4937 (Harry Shute)
SCA Chemical Waste Services, Inc. (08C) 100 Lister venue Newark, N J 07105 Business Phone: (201) 465-9100 New En land Pollution Control ox 8364 Trenton, NJ 08650 Business Phone: (609) 259-3333 Eastcoast Pollution Control Inc. (0) oug t ut e - ar- a o ut on Control)
Cenco Boulevard P. 0. Box 275 Cl ayton, NJ 08312 Business Phones: (609) 881-5100 (215) 923-2500
Contact:
John 0. Cucinotta
Attachment 11.E. 1 MARYLANO J&L Industries (08C)
EfffTE R d Ba 1 timore, MD 21220 Business Phones: (301) 488-0800 24-Hour Phone (800) 638-9116
Contact:
H. J. Brisson American Recover Com an (C) 1 01 rch treet Baltimore, MD 21226 Business Phone: (301) 355-0623 24-Hour Phone: (301) 388-0837
Contact:
Ralph Oaffin GSX Services Inc. (08C)
~ ox Laurel, MO 20707 Business Phone: (301) 953-3673 NOTES: "0" indicates oil clean-up services provided.
"C" indicates chemical clean-up services provided.
11.E.2 ARRANGEMENTS WITH LOCAL EMERGENCY RESPONSE AGENCIES AND HOSPITALS Attachment 11.E.2 lists local emergency response agencies and hospitals, their addresses and phone numbers with which arrangements have been made in the event of a spill or emergency. Additional contacts specific to radiological emergencies can be found in the Susquehanna Emergency Plan. Specific letters of agreement regarding this Section 11.E.2 can be found in Tab C of the Hazardous Material Emergency Off-Site Response Plan.
Attachment 11.E.2 LOCAL EMERGENCY RESPONSE AGENCIES ANO HOSPITALS Berwick Hos ital Shickshinn Vol. Ambulance Assoc.
701 E. 16th Street 50 Furnace St.
Berwick, PA 18603 Shickshinny, PA 18655 (717) 752-4551 (717) 542-4117 (via Shickshinny Pa State Police)
East Berwick Hose Co. No. 2 Shickshinn Area Vol. Fire Co.
5th and Central Avenue 81 North Main Street Berwick, PA 18603 Shickshinny, PA 18655 752-3677, 752-3678,or (717) 542-4155 752-3772 Geisin er Medical Center Sus uehanna SES Biolo ical Laborator Oanvi 1 1 e, PA 17822 (717) 542-2191 Emergency Oepartment (717) 271-6591 Reliance Fire Co.
Life Flight (717) 271>>6666 501 West Third St.
Berwick, PA 18603 (717) 752-5621 Hobbie Vol. Fire Co. Hunlock Creek Ambulance Assoc.
R. D. P2 P. 0. Box 35 Wapwallopen, PA 18660 Hunlock Creek, PA 18621 (717) 379-3086 or 3013 (717) 542-7514 Nesco eck Ambulance Assn. Salem Townshi Fire Co. No. 1 Warren St. Beach Haven, PA 18601 Nescopeck, PA 18635 (717) 752-3677 or 3772
(,717) 784-79.11 Pond Hill-Lil Lake Fire Co. Safet Li ht Cor oration R. 0. 41 4150-A Old Berwick Road Wapwal l o pen, PA 18660 Bl oomsburg, PA 17815 (717) 379-3337 (717) 784-4344 After 5 p.m. John Watts - 925-2887
TAB F FACILITY RESOURCES 61
EMERGENCY EQUIPMENT The Susquehanna SES has an extensive supply of equipment on-site available for use during an emergency, including a spill response trailer. Emergency equipment is described in a list in Attachment 11.F.1. This list includes the equipment's description, quantity, location and maintenance procedures (periodicity of testing, etc.). 1.F.2 is a detailed inventory of the spill response trailer. This inventory is conducted every three months by the waste yard work crew.
I Attachment 11. F.1 SUSQUEHANNA SES EMERGENCY EgUIPMBIT DESCRIPTION gUANTITY LOCATION MAINTENANCE 55-Gal. Open-Head Drums 25 each Waste Accum. Monthly Area Check 55-Gal. Closed-Head Drums 10 each Waste Accum. Monthly Area Check 55-Gal. Polyethylene-Lined 5 each Waste Accum. Monthly Closed-Head Drums Area Check 55-Gal. Drum Gaskets 12 each Waste Accum. Monthly Area Check 85-Gal. Open-Head 5 each Waste Accum. Monthly Salvage Drums Area Check Absorbent Pillows 2 pallets Waste Accum. P.M.*
Area Activated Carbon 100 lbs. Waste Accum. P.M.
for Solvent Spills Area Aerial Ladder Berwick Fire P.M.
Company Air Compressor EBS Constr'uction P.M.
Air Supply (for breathing Fixed F.P.A.-Through-air) plant air out Facility Air 5 air packs Packs-H.P. Area Backhoe EAS Construction, P.M.
Basket Stretchers Several Strategically P.M.
lgcated through-out Facility Bulldozer ESS Construction P.M.
(On Request)
Bullhorn Security P.M.
Camera/Photo equipment Plant Staff-Tech. P.M.
Section, Safety Croup
- Periodic Maintenance
Attachment 11. F. 1 OESCRIPTION gUANTITY LOCATION MAINTENANCE Chain hoist Several E&S Construction P.M.
PP&L Maintenance Chain saw 1 E&S Construction P.M.
Chemical Neutralizers Several Chemistry Oept. & N/A Waste Accumulation Area Chemical Suits Several Safety Office P.M.
Waste Accumulation Area Chlorine Leak Patch SO~ Building P.M.
Kit Cutters (Power) Off-Site Fire P.M.
Companies Oecontamination Several Throughout Plant P.M.
Equipment (Eye & Body Non-H.P.Oecon.
Washes)
Orum Plugs 20 each Waste Accum. Monthly (Assorted) Area Check, Orum Covers 10 each Waste Accum. Monthly Area Check Orum Liners 6 each Waste Accum. Monthly Area Check Ejector, smoke Fire Equ'ipment P.M.
Sheds Elevated Platform E&S Construction P.M.
Explosimeters Several PP&L Safety P.M.
Fans (Portable) Several PP&L Storeroom P.M.
Felt Pads 2 boxes Waste Accum. Monthly Area Check Firefighting Variable Throughout Plant P.M.
First-Aid Supplies Variable PP&L First-Aid P.M.
(S&A), Oispen-sary, Throughout Plant
Attachment 11. F. 1 OESCRIPTION gUANTITY LOCATION MAINTENANCE Foam Concentrate Several Fire Van P.M.
Supply Gallons Forkl i ft E&S Construction P.M.
PP&L/Storerooms Food Supply Cafeteria's S&A P.M.
Building/E&S Const.
Fuel Supply PP&L Fuel Area P.M.
Generator Trailer E&S Construction P.M.
Gloves (Assorted) 4 doz. Waste Accum. Monthly Area Check Granular Absorbent 6 bags Waste Accum. Monthly Area Check Heaters (Portable) Several PP&L Warehouse/ P.M.
Maintenance Helicopter (Medical) Agreement with P.M, Life Flight Geisinger Medical Center Hydraulic Spreaders Off-Site Fire P.M.
Companies Jack Hanmer Several E&S Construction ~
P.M.
Ja'cks Several E&S Construction P.M.
Lighting Equipment, E&S Construction/ As required Portable Maintenance/
Off-Site Fire Companies Metal Saw E&S Construction P.M.
Tool Room Neutrasorb 1 box Waste Accum. Monthly (acid neutralizer) Area Check Neutraci t 1 box Waste Accum. Monthly (caustic neutralizer) Area Check P.A. System Throughout Plant/ P.M.
Elec. Maint.-
Attachment 11.F.1 OESCRI PTION gUANTITY LOCATION MAINTENANCE Plug-N-Patch 1 kits Waste Accum. Monthly Area Check Plug Rugs 1 each, Waste Accum. Monthly Area Check Protective Covera l s 1 2 doz. Waste Accum. Monthly Area Check Radio Several OPS, Security, "
P.M.
'Safety I'.P.
Radiation Oetectors Several Area P.M.
Rolled Felt Absorbent 2 rolls Hazardous Waste Monthly Area Check S.C.B.A. (1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br />) 20 H.P., Fire P.M.
Brigade Sheds S.C.'B.A. (1/2 hour) 60 H.P., Hazardous P.M.
Waste Area (Response Trailer)
Solvent Absorbent Varying Waste Accum. Area P.M.
Submersible Pump Several PPKL Maint./EAS P.M.
Const.
Toilets, Portable Several Throughout site P.M.
Tool Several PP5L/Maint. P.M.
Box'ater Area Pump Several EKS Construction/ P.M.
Maintenance Wel ding/Cutting Several ESS Construction/ P.M.
Maintenance
Attachment 11. F.2 SPILL RESPONSE TRAILER INV N Y H KL OATE:
SIGNATURE:
QUANTITY UNITS ITEM OESCRIPTION BIN ¹ SATIS- UNSATIS-FACTORY FACTORY 6 Each Protective Coveralls - Large 6 Each Protective Coveralls - X-Large 6 ~
Each Rain Coats 6 Pairs Rain Pants 6 Pairs Rain Boots 6 Each Face Shields 2 Each Full face Piece Respirators 3A 2 Each. Oust/Mist Respirators 3A 10 Each Respirator Cartridges 3A (Varying) 2, Vials pH Test Paper 3A 1 Each Hazardous Materials Emergency Response Guide 3B 1 Each NFPA Hazardous Materials Guide 3B 1 Each NIOSH/OSHA Chemical Hazards Guide 3B 1 Each Oriver's Guide on Hazardous Materials 3B 1 Each Chemical Glove Guidesheet 3B
Attachment 11.F.2 SPILL RESPONSE TRAILER H KL DATE:
SIGNATURE:
QUANTITY UNITS ITEM DESCRIPTION BIN ¹ SATIS- UNSATIS-FACTORY FACTORY 10 Each Vaporproof Splash Goggles 3B 10 Each Ventilated Splash Goggles 3B 12 Pairs Nitriflex Gloves 3C 12 Pairs Neoprene'Gloves 3C 6 Pairs Viton Gloves 3C 12 Pairs Butyl Gloves 3C
'C 12 Pairs Nitrile-Latex Gloves Rolls Spill Response Banner 4A 500 Feet Safety Flagging 4A 25 Pounds Cotton Rags 4A I
2 Roll s Paper Towels 4A 1 Sheet Spill Response Trailer Inventory 4A Each Open-Head Drum Cover 4B I
Each Open-Head 55-Gallon Drum Each Open-Head 85-Gallon Salvage Drum 4B Rol l s Felt Absorbent "4B 100 Pounds Neutrasorb 4B
1I Attachment 11.F.2 SPILL RESPONSE TRAILER INV Y HE KL DATE:
SIGNATURE:
QUANTITY UNITS ITEM DESCRIPTION BIN 0 SATIS- 'NSATIS-FACTORY FACTORY 100 Pounds Neutracit 4B 1 Each Poly-Lined 55-Gallon Drum 4C 2 Bags Gr anular Absorbent 4C 2 Bundles Hazorb Pillows 4C 1 Each Drum Pump 40 1 Each 55-Gallon Drum Gasket 40 1 Each Drum Funnel with flame arrestor 1 Each Polyethylene Long-Stem Funnel 4D 6 Each' Drum Liners Roll Visqueen 4D 1 Each Shovel 4D 2 Each Picks 40 2 Each Plug Rugs 6A 4 Kits Plug-N-Patch 6B 1 Box Plastic Fiber Mastic 6B 1 Box Sample Containers 1 Each Poly Scoop
Attachment 11.F.2 SPILL RESPONSE TRAILER INV N 0 Y CH KL IS OATE:
SIGNATURE:,
QUANTITY UNITS ITEM OESCRIPTION BIN ¹ SATIS- UNSATIS-FACTORY FACTORY Each Tool Box (assorted tools)
Each Orum Bung Wrenches 7 Each Pyromarker 1 Set Screw Drivers Each Socket Wrench Each Sockets Each Putty Knife Bag Assorted Orum Bungs Each Fire Extinguishers Exterior
1' TAB 6 MAPS AND TABLES 71
, I,aeIK&C 1.000 400
+'OO 10 ~ 00 100
~
- 1) 1
~ I II
~1 14 ll14 14 1 ~
ll~ II 44 14 Il 11 ~0 01 40 II 104 11 i 140 141 I~
44 1 11 11 1.0 l.~ 10 10
~ I I.OOI l.~ 04 400 1.000 4(a
~ I ICC'm Sy II III S Figure 1: Population Distribution 1980
Table 2: Population Distribution 1990 0-10 Miles Distance (miles)
Sector 0-1 1-2 2-3 3-4 4-5 5-10 10-Mile Total N ~8 17 47 1,133 2 '16 1,100 4,448 NNE 0 72 29 0 0 1,900 2,001 NE 0 0 160 194 362 10,500 11,216 ENE 0 14 36 68 93 1,300 1,511 E 0 54 22 42 70 1,000 1,188 ESE 23 25 62 178 169 2,100 2,557 SE 42 234 146 146 13 2,800 3,381 SSE 38 145 36 91 45 ~
3,400 3,758 S 34 141 29 139 10 1,700 2,053 SSM 4 234 44 84 118 1,000 1,484 SM 4 14 331 91 1 ~ 491 2,000 3,931 MSM 4 58 328 113 3,996 12 '00 17,399 4 29 58 94 179 1,400 1,764 M
MNM ll 10 40 68 44 91 100 0
255 93 700 900 1,150 1, 167 NM NNM 19 18 15 0 22 1.000 1,024 TOTAL 23K 1, 1113 1,777 2 ~ 47K 9.032 45, 700 60,002 ClMULATIVE 236 1,399 2,877 5,350 14 '82 60,082 TOTAL
l 1.100 I.DDD 1.0 (0 II.IDO DDD 22 102
'I 00 I
15 2 0
01 IO 10 IS Il~ I~
10 Il IS 0 II I ~ 50 20 I ~ 22 10 1.000 I SDD I
50 02 210 21 ~
I~
112 221
~ I
~ I Il I~ I 12.0 Il 2.1 I~ ~ I 120 WViWVC2 I s~s 10 2.000 2.IOI 1.000 2.100 c'b ran r<r Sg~
kNNe~
CQ S figure 2: Population Distribution 1990
Table 1: Population Distribution 1980 10 Miles Diet~ence aller)
Sector 0-1 1-2 2-3 3-4 4-5 5-10 10<<Mile Total 1 K K 1,%K 2,014 1,000 4,173 NHE 0 69 27 0 1>900 1,996 NE 0 0 149 183 344 10,600 11,276 EHB 0 14 34 64 88 1,100 1,300 E 0 52 21 40 67 900 1,080 BSE 21 24 57 168 161 1;900 2,331 SE 38 225 135 137 12 2,400 2,947 SSE 35 142 34 85 43 3,000 3,339 S 31 135 27 131 9 1,500 1; 833',360 SSW 3 225 41 79 112 900 SW 3 14 307 85 1,419 2,000 3,828 WSW 3 55 304 107 3 '02 12,300 16,571 W 3 28 54 88 170 1,300 -1,643 WNW 10 38 41 95 243 600 1,027 IW 13 66 84 0 88 800 1,051 MSM 16 17 14 0 21 900 960 TOTAL 211 1,118 1.37r 2>378 ~0,5 3 43, 100 56,723 ClMJLATIUE 211, 1>329 2,702 51030 13,623 56,723 TOTAL
NANTICOKE r r
/
r C
'\
\ N KEY:
2I l 36 L INES SUN OIL CO. PIPELINE TRANSCONTINENTAL GAS CO. PIPELINES ARCO CO. OIL PIPELINE P ~~~/ SIT GASOLINE STORAGE TANKS HILES 3
IFFLINVIL E oo C
5 oo HAZLETON figure 3: Sites Contributing to Additiona1 Risk
West Nonticoke ef gt Nonticoke 239 na han e
go5 Shickshtnny
~ St. Mary's Park R iverlands SSES ~
Beach Haven I I 8erwtck escoaeck 93 80 8I Conynqham 0
0 I 2 4 Stttllee Hazleton Figure 4: Sites Subject to Additional Risk
<<1 <<r <<rrrar<<naa w~<<rara '
KfY
~ aaraarr a +
I
\ Hot Line of Exclusion
<<sari~ a<<rr
<<roe aaro
~ aaa
~ 'I Zone I
Contamination Reduction Corridor
~ Ia ~ Iarr<<alla al ~ Access Control Points I
<<a ~
<<arae <<a
~ aoraclao ~ aa<<ar I aaaa
~ rra I~
eal
- Primary Command Post
~ r rn<< a<<I ~ Ir<<area
<<I war ~
(Support Zone)
L
~ I aarw I I
,. I ** Secondary Command Post
'l i
faarrarr
~ aarr awa <<ra<< I
~ rarsrwa w
(Support Zone)
I Iae.<<r
<<Iaa<<ar
<<rrearr<<$
aae arrl ~ Il I Ia.aaa
~ \ aa~
L Figure 5: Site Eme'rgency Work Zones la aar t 1
TAB H MATERIAL SAFETY DATA SHEETS 79
CHEM~FE' MATERIALSAFETY DATASHEET I IDENTIFICATION MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.
ADDREssrrrurnoer, slicer. Cily. Sr ~ re.end 2IPCodrr CAS NUMSER II007 664 939 CHEMICALNAME AND SYNONYMS TRADE NAME AND SYNONYMS S>>if>>ric Acid Concentrated CHEMICAt. FAMILY FORMULA Ac Ld H2S04 II CHEMSAFE'INSTRUCTIONAL CLASSIFICATION AffixAppropnate Chemsafe' lnstructiOnal Classification Label
'Rarer lo cHEMSAFET inslrucuonal boovels ior gaia regarding Ine orooerties. sooropnve sale ule and storage. ano emergency response lor this class ol substance.
III HAZARDOUS INGREDIENTS TLV AND SOURCE TLV AND SOURCE INGREDIENT NAME units) INGREDIENT NAME units 93- 1 mg/m for water. Can conta1n ow CurrentdOSHA H droaen Sulfate (H2S04) 4.im urit levels such as stanaard Bal > $
.02% max. of jrgn g Fe
~~>.~~>>H(u:
- Material is obtained by f'Tr work week, the reaction of SO~ and IV PHYSICAL DATA of 1 mg/m Boiling Point at 760 mm Hg Vapor Pressure (mm Hg at Vapor Density(Air = I)
~') C 340 Specific Gravity (Hr0 = 1)
Percent Volatile B Volume {%)
Evaporation Rate But I Acetate = t 60/60F) 1.8354 NA Completely Melting Point ('F.)
NA'a-34 Solubility In Water (% by Weight) deg C Appearanceand Dc!or Clear, colorless, hygroscopic oily liquid with no odor.
V FIRE ANO EXPLOSION HAZARD DATA Flasn Poinl IMelhod Used) Lower ILeil UOOer Iueil Flamrnsbl ~ Limils in Air I'4 by volumel t
Ealingrns ing Media i
EVen t Oug Su ur1C aC1 1S nOni amma e, 1 1S aZar OuS W en preSen 1n a xstog)sggtegE)trmegtgetc tanks of 2s04 with water to avoid rupture 1f exposed to 1re.water Do not
! e id es ec1all when diluted with can react w1 me a s to 1 crate amma e y rogen gas. u ur1c ac1 an m1s s an vapor Fire and Esplosion Hazards F' i ent and full rotective clothin Vl LOCATIONS USED AND STORED (Completed By User)
Localions Used Locations Stored While Sprmg born Regulatory Serwcos. Inc, ISRs) beii aves Inal the du a contained herein ve tactual and bollwee that the opinhhvs esprossod aro those ol dualihed ex pens. the dale ve nol lo bo taken as a wvranly or represenlauon lor which sRs assumes legal responsibility, They are offered sorely lor your consideration. investigation. and venrica.
lion. Any use ol this dale and inlormalion musl be determined by lho user lo bo in accordance with appllcacso Iodorv, slate vld local laws and regulations, CHEMSAFE'FORM S2 {Continued on reverse sidi SERVICE% NC THIRTY SPRINGBORN CENTER ENFIELD. CONNECTICUT 06082
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NO. 53 MATERIALSAFETY DATA SHEET GENIUM PUBLISHING CORPORATION 1145 CATALYN STREET SCHENECTADY, NY 12303-1836 USA (518) 317.8855 ofNIUMNJOU5MIHococt. D t Ju].y 1979 SECTION I s MATER IAL IDENTIFICATION
.TERIAL NAME CHLORINE R DESIGNATIONS: C12~CAS II 007 782 505 ESCRXPTION: A gas shipped in steel cylinders as a liquid under its own vapor pressure.
ACTURERs Available from many suppliers.
SECTION Ile INGREDIENTS AND HAZARDS HAZARD DATA Chlorine ) 99 8-hr TWA 1 ppm (C) or 3 mg/m3 *
- Current OSHA ceiling limit. ACGIH TLV (1978) is 1 ppm with a STEL of 3 ppm for up to 15 minutes exposure.
NIOSH (1976) proposed a ceiling limit of 0.5 ppm (15 minute sampling time) .
(Controversy going on whether OSHA standard should include ceiling limit or not.)
SECTION. I I I e PHYSICAL DATA
-- -34 ens y a s atm, g/liter -- 3.214 Boiling point at Vapor pressure at 20 C, mm Vapor density (Air 1) 1 atm, deg C Hg 48002.49 Gas at 1 Liquid at 3.65 atm, g/cc Molecular weight - -
<<- 1.47 70.91 1 atm, g/1 7.3 Water solubility at 20 C, Appearance a Odors A greenish-yellow gas or clear, amber-colored liquid with a suffo-cating, pungent, irritating odor. The odor recognition threshold (100'f test panel, unfatigued) is reported at 0.314 peen. The amor is easily noticed at 1.9-3.5 ppn and has been re reed as intolerable at 2.6-41 de on the observer.
SECTION I V s FIRE AND EXPLOS ION DATA LOWER UPPER as oint and Method Autoi ition Tem . Flammabilit Limits In Air Non-flammable Use extxnguxs ng m a s aopropr a e or e sur cool intact, fire-exposed containers (one ton tanks and cylinders will release chlorine when a fusible metal safety plug melts at I58-165P.) If possible, have specially trained personnel remove intact cylinders from fire area.
lorine will support the burning of most combustible materials, gust as oxygen does.
Flammable gases and vapors can form explosive mixtures with chlorine.
irefighters must use self-contained breathing equipment, eye protection, and full pro-tective 'clothi when fighting fires in which chlorine is involved.
SECTION Vo REACTIVITY DATA or e xs s e stee conta rs at room temperature en . Intense oca eat 215oC) on steelwalls can cause steel to ignite in chlorine.]
It(above is a powerful oxidising agent which reacts violent1y with reducing agents and combus-tible materials. Materials such as acetylene, turpentine, other h)tdrocarbons, aamonia, hydrogen, ether, powdered metals, etc. must be kept away from chlorine.
reacts with 82S and H2O forming HClg it combines with Itsulfuryl CO and SO2 to form phosgene and chloride (toxic and corrosive materials) ~
Wet chlorine (150 ppm water) corrosively attacks most cceaen metals. Handling chlorine requires special materials technology.
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SECTION VI ~ HEALTH HAZARD INFORMATION TLV 1 ppm or 3 mg/m (C)
Chlorine believed to damage the body by local corrosive" ef fects ~onl r no systemic effects. 5-8 xtpm in aiz will be severely irritating to eyes, nose, and x'espiratory tract of most Mdividuals in a few minutes (10 ppm intolerable for avg. person).
Higher level exposures produce coughing, dyspnea, burns of the skin, conjunctivitis, pulmonary edema (may be delayed) and deatht depending on concentration and time of exposure (35-51 ppm, lethal in an hour; a few deep breaths fatal at 1000 ppm) .
Reduced respiratory capacity (especially axing smokers) and dental erosion can re-sult from chronic low level exposure. Any contact with liauid chlorine causes burns, blistering and tissue destruction.
FIRST AID: Call h sician IMMEDIATELY for an erson overex sed to chlorinel medical help is cct ~raadil available, ccatiaue tlushiae with water.
Skin
Contact:
(Treat for inhalation exposure firstl) Remove contaminated clothing under a safetv shower fresh Wash exposed skin areas thoroughlv with water.
Inhalation: Remove to air. Restore breath1ng when requizecl. Have trained person 45lllQITSt'er oxygen until victim breathes easily on his own. Keep warm and at restl In mild cases, give milk to relieve throat irritation.
SECTION Vl I t SPILL> LEAK> AND DISPOSAL PROCEDURES Establish written emergency plans and special training of personnel where chlorine is used.
Notify safety personnel. Provide ventilation. Exclude from area all except specially trained, assigned personnel with approved self-contained breathing equipment and appropriate protective clothing. Find and stop leak. (Large uncontrollable leaks require environmental consideration and possible evacuation af surrounding area.)
Hove leaking container to isolated area. Position to xelease gas not liquid.
When possible draw off chlorine to process or to disposal system.
DISPOSALc Bubble through a large volume of 15\ aqueous Na08 or other alkali. Suit-aSIy Zxspose of resulting solution. Follow Federal, State and local regulations.
SECTION VI I I t SPECIAL PROTECTION INFORMATION Provide general and local exhaust ventilation ta meet TLV requizements. Provide suit-able venting for low lying axeas. Use enclosed, isolated processing and handling whenever possible. Full face-piece zespirators must be available for non-routine and emergency usec canister gas mask below 5000 ppm in air and self-contained breathing equipment for other conditions.
Workers should be provided with chemical safety goggles and impervious gloves. Full protective clothing must be used when needed ta prevent exposure to chlorine, liqui or gas. Daily change of work clothes and showering after work shift are recommended.
Eyewash stations and chemical safety showers must he available in areas of handling and storage of chlorine.
SECTION IXe SPECIAL PRECAUTIONS AND COMMENTS Store chlorine containers in well-ventilated areas of low fire potential, away from incompatible materials (see Sec. V) and away from sources of heat and ignition. Pro-tect containers fran weather and physical damage> follow standard safety procedures for containers of compressed, corrosive gases. Provide special training to workers handling chlorine. Regularly inspect (and test) piping and containment used for chlorine service. Liquid levels should be less than 85\ of tank or cylinder capacity Use preplacement and periodic medical examsg preclude from workplace exposure to chlorine those with cardiac pulmonazy or chronic respiratory problems.
Special Reft "Chlorine and Hyhrogen Chloride", Chapter 5, National Academy of Science, Washington, DC (1976) .
hTA SOURCE(S) CODE: 2-12 '7e 19p 24e 26 APPROVALS:
Industrial Hygiene
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Sefet MEDICAL REVIEW c 12/79 GENIUM PUBLlSHING
'IR Specialty Gas Material Safety Data Sheet EMERGENCY PHONE (800) 523 9374 PRODUCT NAME IN PENNSYLVANIA(800) 322 9092 SULFUR DIOXIDE CAS ¹7446-09-5 AIR PRODUCTS AND CHEMICALS, INC. TRADK NAME AND SYNONYMS BOX 538 Sulfur Dixoide ALLENTOWN, PA 18105 CHEMICALNAME AND SYNONYMS (215) 481.8257 Sulfur Dioxide IssUE DATE March 1978 FORMULA CHEMICALFAMILY REvlsfoN DATE March 1985 SOs Inor anic Acid HEAI.TH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE UMIT 5 ppm SYMPTOMS OF EXPOSURE Sulfur dioxide is extremely irritating to the airway, eyes and skin. Depending on the intensity and duration of expo-sure, effects may vary from mild irritation to severe destruction of tissues. Symptoms of exposure may include burning sensations, coughing, wheezing, laryngitis, shortness of breath. headache, nausea, and vomiting. Penetra-tion of sulfur dioxide into the lower airway may produce bronchitis, chemical pneumonitis, and pulmonary edema.
Contact of sulfur dioxide with the eyes will cause pain, tearing, inflammation, swelling of tissue and possible de-struction of the eye. Contact of sulfur dioxide with the skin will cause severe burns or irritation of the skin. Cryo-genic burns may be caused by the liquid.
TOXICOLOGICALPROPERTIES Inhalation human TCLo:3 ppm/5 days Exposure to atmospheres contaminated with sulfur dioxide is extremely irritating. Its odor and prompt irritant ac-tion provides a warning of exposure to toxic conditions. High concentrations are extremely destructive to tissues of the airway. eyes and skin. Inhalation may have fatal consequences as a result of spasm, inflammation and edema of the larynx and bronchi; chemical pneumonitis and pulmonary edema. Exposure of the eyes to high con-centrations may result in ulceration of the conjunctiva and cornea and destruction of all ocular tissues. Contact with the skin causes severe burns. Systematic toxicity due to sulfur dioxide is not known to occur.
RECOMMENDED FIRST AID TREATMENT RESCUE PERSONNEL SHOULD AVOID UNNECESSARY EXPOSURE N
Inhalation: Move the affected person to an uncontaminated atmosphere. If exposure has been to minor concentra-tions for a limited time, usually no treatment will be required. If breathing has stopped or is impaired, give assisted respiration (e.g., mouth-to-mouth). Supplemental oxygen should be administered. Keep the victim warm and quiet.
Assure that the victim does not aspirate vomited material by use of positional drainage. Assure that mucus does not obstruct the airway. Seek medical attention at once.
~Ee
Contact:
CONTACT LENSES SHOULD NOT BE USED BY PERSONS POTENTiAt.LY EXPOSED TO SULFUR DIOXIDE. Sulfur dioxide contamination of the eyes should be treated by immediate and prolonged irrigation with large quantities of water. Assure adequate flushing of the eyes by separating the lids with fingers. Obtain medical assistance at once. (Continued on last page) their Information contained in this material safety data sheet is offered without charge for use by technically qualified personnel atwhich discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data with we believe to be reliable. but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made respect thereto. This information is not intended as a license to operate under or a recommendation to practice or infringe any patent of this Company or others covering any process, composition of matter or use.
since the company shall have no control of the use of the product descnbed herein, the company assumes no liability for loss or damage incurred from the proper or improper use of such product.
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOUDS, OR GASES Sulfur dioxide dissolves in water to form sulfurous acid, which is unstable when exposed to heat.
PHYSICAL DATA BOILING POINT UQUID DENSITY AT BOIUNG POINT 13.9'F ( 10.5'C) 89.3 Ib/ft'1430.4 kg/m')
VAPOR PRESSURE 70'F QAS DENSITY AT 70'F, 1 atnt 49.1 psia (338.5 kPa) 0.1687 Ib/fthm (2.70 kg/ma)
SOLUBILITY IN WATER FREEZING POINT Soluble 103.9'F ( 75.5'C)
APPEARANCE AND ODOR Colorless as with a stron pun ent odor.
FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) AUTO IGNITION TEMPERATURE FLAMMABLEUMITS 'Yo BY VOLUME N/A N/A LEL UEL N/A EXTINGUISHING MEDIA ELECTRICAL CLASSIFICATION N/A Nonhazardous SPECIAL FIRE FIGHTINQ PROCEDURES If sulfur dioxide containers are involved in a fire, keep cylinder cool with a water spray from a distance.
UNUSUAL FIRE AND EXPLOSION HAZARDS N/A REACTIVITYDATA STABLE CONDITIONS TO AVOID Unstable Stable INCOMPATIBILITY(Matertala to avoid)
Aluminum, zinc HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur WIII Not X Occur SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIALIS RELEASED OR SPILLED Spills of sulfur dioxide can be handled by washing down the area with water and neutralizing with alkali.
WASTf DISPOSAL METHOD Do not attempt to dispose of waste or surplus sulfur dioxide. Return all unused quantities to Air Products and Chemicals, Inc. for proper disposal.
roAir products and Chemicals. Inc, 1985
SPECIAL PROTECT(ON INFORMATION REsviRATDRY pRDTEcTIDN Ispecity type) Positive pressure self-contained breathing apparatus should be available for emergency use.
VENTILATION LOCAL EXHAUST SPECIAL (See back page)
MECHANICAL(Qen,i OTHER At work and floor level PROTECTIVE GLOVES Rubber EYE PROTECTION Safety goggles or glasses OTHER PROTECTIVE EQUIPMENT Safe shoes, safe showers, e ebaths, face shield SPECIAL PRECAUTIONS*
SP ECIAL ULSEUNQ INFORMATION D.O.T. Green Label, Nonflammable Gas SPECIAL HANDLINQ RECOMMENDATIONS Use only in a well-ventilated area. Never drop cylinders or allow them to strike each other violently. Avoid dragging or sliding cylinders. even for short distances. They should be moved by a suitable hand truck. Keep the valve pro-tection cap in place until cylinder is secured and ready for use. Always insert a trap or check-valve in the line to prevent hazardous back-flow into the cylinder. Use a pressure reducing regulator when connecting to lower pres-sure piping systems.
For additional handling recommendations consult the Air Products Specialty Gas Catalog Safety and Technical In-formation Section or Compressed Gas Association Pamphlet P-1.
SPECIAL STORAGE RECOMMENDATIONS Protect against physical damage. Store cylinders in a cool, dry, well-ventilated area of noncombustible construc-tion. Protect cylinders from excessive temperature rise by storing away from sources of heat. No part of a cylinder should be subjected to a temperature above 125'F (52'C). Store cylinders in an upright position and firmly se-cured. Segregate full and empty cylinders. Storage in subsurface locations should be avoided since sulfur dioxide is heavier than air.
For additional storage recommendations. consult the Air Products Specialty Gas Catalog Safety and Technical In-formation/ection or Compressed Gas Association Pamphlet P-1.
SPECIAL PACKAQINQ RECOMMENDATIONS Ir Anhydrous sulfur dioxide is noncorrosive to steel and other common structural metals except zinc. In the presence of moisture. however, corrosive conditions develop (SOa + HsO HsSOs). Lead, carbon, graphite and stainless steel are recommended for handling moist sulfur dioxide.
OTHER RECOMMENDATIONS OR PRKCAUTIONS Do not heat cylinders of sulfur dioxide using heat lamps, etc. to maintain internal pressure. This practice has re-sulted in ruptured safety relief devices.
'Various Government agencies (i.e., Department of Transportation, Occupational Safety and Health Administration, Food and Drug Administration and others) may have specific regulations concerning the transportation, handling, storage or use of this product which will not be reflected in this data sheet. The customer should review these regulations to ensure that he is in full compliance.
T AIN L/-,
Specialty Ges Oepartment Air Prpducts and Chemicals. Inc.
Box 538. Allentown, PA 18105 PfÃ)DVCTS (215) 481 8257 RECOMMENDED FIRST AID TREATMENT (Continued)
Skin
Contact:
Flush the affected area promptly with large quantities of water for 15 minutes. Remove contaminated clothing as quickly as possible. Except in the most minor, superficial and localized burns, cover the affected area with a sterile dressing or clean sheeting and transport for medical care. DO NOT APPLY GREASES OR OINT-MENTS. Control shock if present. Launder contaminated clothing before reuse. Contaminated footwear must gen-erally be discarded.
VENTILATION Good natural ventilation is sufficient for storage. Mechanical ventilation is necessary indoors.
Printed ln U.S.A. 320.508
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