ML17363A378
| ML17363A378 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 05/14/2015 |
| From: | Vania I TestAmerica Labs - St. Louis |
| To: | Office of Nuclear Material Safety and Safeguards |
| References | |
| HEM-17-70 160-11391-2 | |
| Download: ML17363A378 (16) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-11391-2 Client Project/Site: HDP For:
Perma-Fix Environmental Services Inc.
2800 Solway Road Knoxville, Tennessee 37931 Attn: Brian Miller Authorized for release by:
5/14/2015 4:01:03 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP TestAmerica Job ID: 160-11391-2 Page 2 of 16 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
4 Receipt Checklists.........................................
5 Definitions/Glossary.......................................
6 Method Summary.........................................
7 Sample Summary.........................................
8 Client Sample Results......................................
9 QC Sample Results........................................
14 QC Association Summary...................................
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Case Narrative Client: Perma-Fix Environmental Services Inc.
TestAmerica Job ID: 160-11391-2 Project/Site: HDP Job ID: 160-11391-2 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Perma-Fix Environmental Services Inc.
Project: HDP Report Number: 160-11391-2 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 04/17/2015; the samples arrived in good condition, properly preserved and, where required, on ice. The temperature of the coolers at receipt was 20.0 C.
RADIUM-226 BY GAMMA SPEC (21 DAY INGROWTH)
Samples L10-14-01-B-E-S-00 (160-11391-1), L10-14-02-B-E-S-00 (160-11391-2), L10-14-03-B-E-S-00 (160-11391-3),
L10-14-04-B-E-S-00 (160-11391-4), L10-14-05-B-E-S-00 (160-11391-5), L10-14-06-B-E-S-00 (160-11391-6), L10-14-07-B-E-S-00 (160-11391-7), L10-14-08-B-R-S-00 (160-11391-8), L10-14-09-B-E-S-00 (160-11391-9) and L10-14-06-B-E-Q-00 (160-11391-10) were analyzed for Radium-226 by gamma spec (21 day ingrowth) in accordance with EPA GA_01_R. The samples were leached on 04/17/2015, prepared on 04/21/2015 and analyzed on 05/12/2015.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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10 11 TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 phone 314.298.8566 fax Client Contact Perma-Fix Environmental Services 2800 Solway Road Knoxville, TN 37931 (865) 690-0501 Phone (865) 539-9868 FAX Project Name: Hematite Decommissioning Project Site: Westinghouse Hematite, MO P 0#832953 Sample Identification L 10-14-01-B-E-S-OO L 10-14-02-8-E-S-OO L 10-14-03-B-E-S-OO L 10-14-04-8-E-S.-OO L 10-14-05-8-E-S-OO L 10-14-06-8-E"S-OO L 10-14-07-8-E-S-OO L10-14-08-B-R-S-OO L 10-14-09-8-E-S-OO L 10-14-06-8-E-Q-OO Chain of Custody Record Regulatory Program: 0 DW QNPDES 0RCRA 0 Other:
Project Manager: Brian Miller Site
Contact:
Ellen Jakub loate: 04/17/2015 Tel/Fax: (314) 810-3333 Lab
Contact:
Ivan Vanya
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COC No: 041715-FSS1 of 1
COCs Sampler:
For Lab use Only:
Walk-in Client:
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Lab Sampling:
Job I SDG No.:
Sample Specific Notes:
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Possible Hazard Identification:
Sample Disposal ( A fee may be assessed if samples are retained longer than 1 month)
Are any samples from a listed EPA Hazardous Waste? Please List any EPA Waste Codes for the sample in the Comments Section if the lab is to dispose of the sample.
0 Non-Hazard 0 Flammable D Skin Irritant 0 PoisonB 0
Unknown 0 Return to Client D rnsposa1 by t.ab 0 Archive for _
Months Special Instructions/QC Requirements & Comments: Potential for Radi.ological Contamination Custody Seals Intact 0
Yes 0
No Custody Seal No.:
I Cooler Temp. (°C): Obs'd:
Corr'd:
Therm ID No.:
Date/Time:
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- 1 R~sion: 3 !
- Login Sample Receipt Checklist Client: Perma-Fix Environmental Services Inc.
Job Number: 160-11391-2 Login Number: 11391 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
N/A Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
N/A Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Qualifiers Rad Qualifier Description U
Result is less than the sample detection limit.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method Method Description Laboratory Protocol DOE GA-01-R Radium-226 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 7 of 16 1
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Sample Summary TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID Client Sample ID Received Collected Matrix 160-11391-1 L10-14-01-B-E-S-00 Solid 04/14/15 16:15 04/17/15 10:20 160-11391-2 L10-14-02-B-E-S-00 Solid 04/14/15 16:20 04/17/15 10:20 160-11391-3 L10-14-03-B-E-S-00 Solid 04/14/15 16:30 04/17/15 10:20 160-11391-4 L10-14-04-B-E-S-00 Solid 04/14/15 16:35 04/17/15 10:20 160-11391-5 L10-14-05-B-E-S-00 Solid 04/14/15 16:45 04/17/15 10:20 160-11391-6 L10-14-06-B-E-S-00 Solid 04/14/15 16:50 04/17/15 10:20 160-11391-7 L10-14-07-B-E-S-00 Solid 04/14/15 17:00 04/17/15 10:20 160-11391-8 L10-14-08-B-R-S-00 Solid 04/15/15 11:25 04/17/15 10:20 160-11391-9 L10-14-09-B-E-S-00 Solid 04/15/15 11:30 04/17/15 10:20 160-11391-10 L10-14-06-B-E-Q-00 Solid 04/14/15 16:50 04/17/15 10:20 TestAmerica St. Louis Page 8 of 16 1
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Client Sample Results TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-11391-1 Client Sample ID: L10-14-01-B-E-S-00 Matrix: Solid Date Collected: 04/14/15 16:15 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.13 (2+/-)
0.192 (2+/-)
1 05/12/15 16:02 04/21/15 10:38 pCi/g 0.0871 RL MDC 0.154 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.426 0.482 0.461 1.35 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.0738 0.135 0.103 0.841 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.0636 0.170 0.0787 1.16 Lead 212 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.0777 0.145 0.0916 1.08 Lead 214 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.239 2.35 1.24 19.5 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 16:02 1
1.17 0.711 0.708 U
-0.575 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.0738 1.00 0.135 0.103 0.841 Radium 226 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.0871 0.192 0.154 1.13 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.774 0.293 0.276 0.924 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.228 0.150 0.149 U
0.111 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 16:02 1
0.103 0.0608 0.0608 U
-0.00138 Americium 241 pCi/g 04/21/15 10:38 05/12/15 16:02 1
5.22 3.15 3.15 U
2.27 Protactinium 234m Tl-208 0.365 0.0545 0.0664 0.0408 pCi/g 04/21/15 10:38 05/12/15 16:02 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-11391-2 Client Sample ID: L10-14-02-B-E-S-00 Matrix: Solid Date Collected: 04/14/15 16:20 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.19 (2+/-)
0.198 (2+/-)
1 05/12/15 16:03 04/21/15 10:38 pCi/g 0.127 RL MDC 0.156 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.419 0.481 0.456 1.47 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.0720 0.175 0.119 1.23 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.0846 0.175 0.0856 1.18 Lead 212 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.0793 0.181 0.114 1.35 Lead 214 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.262 2.00 1.15 16.0 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 16:03 1
1.43 0.279 0.274 U
0.444 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.0720 1.00 0.175 0.119 1.23 Radium 226 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.127 0.198 0.156 1.19 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.878 0.568 0.553 1.23 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.272 0.163 0.163 U
0.0839 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 16:03 1
0.0858 0.0506 0.0506 U
0.000801 Americium 241 pCi/g 04/21/15 10:38 05/12/15 16:03 1
5.80 3.43 3.42 U
2.26 Protactinium 234m Tl-208 0.419 0.0569 0.0716 0.0390 pCi/g 04/21/15 10:38 05/12/15 16:03 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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Client Sample Results TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-11391-3 Client Sample ID: L10-14-03-B-E-S-00 Matrix: Solid Date Collected: 04/14/15 16:30 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.27 (2+/-)
0.176 (2+/-)
1 05/12/15 16:05 04/21/15 10:38 pCi/g 0.115 RL MDC 0.122 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.438 0.527 0.504 1.53 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.0842 0.154 0.0955 1.17 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.0722 0.172 0.0737 1.19 Lead 212 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.0781 0.174 0.0943 1.41 Lead 214 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.215 2.25 1.03 19.8 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.708 0.424 0.423 U
0.247 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.0842 1.00 0.154 0.0955 1.17 Radium 226 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.115 0.176 0.122 1.27 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.790 0.289 0.270 0.975 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.254 0.0605 0.0605 U
0.0140 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 16:05 1
0.0690 7.54 7.54 U
-0.00949 Americium 241 pCi/g 04/21/15 10:38 05/12/15 16:05 1
4.97 2.87 2.87 U
-0.666 Protactinium 234m Tl-208 0.445 0.0513 0.0687 0.0353 pCi/g 04/21/15 10:38 05/12/15 16:05 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-11391-4 Client Sample ID: L10-14-04-B-E-S-00 Matrix: Solid Date Collected: 04/14/15 16:35 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.04 (2+/-)
0.166 (2+/-)
1 05/12/15 16:38 04/21/15 10:38 pCi/g 0.106 RL MDC 0.128 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.482 0.584 0.558 1.66 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.0688 0.134 0.0999 0.865 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.0618 0.155 0.0738 1.06 Lead 212 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.0664 0.132 0.0917 0.919 Lead 214 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.321 2.28 1.21 18.8 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 16:38 1
1.19 0.216 0.211 U
0.394 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.0688 1.00 0.134 0.0999 0.865 Radium 226 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.106 0.166 0.128 1.04 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.803 0.534 0.515 1.35 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.248 0.128 0.128 U
0.109 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 16:38 1
0.0968 0.0575 0.0575 U
0.00809 Americium 241 pCi/g 04/21/15 10:38 05/12/15 16:38 1
2.04 2.87 2.76 7.80 Protactinium 234m Tl-208 0.411 0.0483 0.0644 0.0293 pCi/g 04/21/15 10:38 05/12/15 16:38 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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Client Sample Results TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-11391-5 Client Sample ID: L10-14-05-B-E-S-00 Matrix: Solid Date Collected: 04/14/15 16:45 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.15 (2+/-)
0.212 (2+/-)
1 05/12/15 16:40 04/21/15 10:38 pCi/g 0.157 RL MDC 0.176 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.417 0.453 0.440 1.04 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.0988 0.162 0.133 0.889 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.0917 0.153 0.0903 0.954 Lead 212 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.0866 0.142 0.106 0.909 Lead 214 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.472 2.49 1.50 19.4 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 16:40 1
1.34 0.214 0.211 U
0.348 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.0988 1.00 0.162 0.133 0.889 Radium 226 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.157 0.212 0.176 1.15 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.954 0.349 0.337 U
0.891 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.289 0.187 0.187 U
0.141 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 16:40 1
0.122 0.0719 0.0719 U
-0.0000512 Americium 241 pCi/g 04/21/15 10:38 05/12/15 16:40 1
7.57 2.84 2.83 U
2.59 Protactinium 234m Tl-208 0.387 0.0616 0.0736 0.0450 pCi/g 04/21/15 10:38 05/12/15 16:40 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-11391-6 Client Sample ID: L10-14-06-B-E-S-00 Matrix: Solid Date Collected: 04/14/15 16:50 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.23 (2+/-)
0.182 (2+/-)
1 05/12/15 16:41 04/21/15 10:38 pCi/g 0.132 RL MDC 0.134 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.438 0.358 0.339 1.15 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.0762 0.157 0.110 1.08 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.0745 0.164 0.0758 1.12 Lead 212 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.0769 0.157 0.102 1.15 Lead 214 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.243 2.66 1.20 23.6 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 16:41 1
1.28 0.234 0.230 U
0.402 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.0762 1.00 0.157 0.110 1.08 Radium 226 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.132 0.182 0.134 1.23 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.783 0.512 0.495 1.22 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.253 0.153 0.152 U
0.102 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 16:41 1
0.111 0.0657 0.0657 U
0.0110 Americium 241 pCi/g 04/21/15 10:38 05/12/15 16:41 1
5.13 2.80 2.78 U
3.45 Protactinium 234m Tl-208 0.421 0.0520 0.0676 0.0386 pCi/g 04/21/15 10:38 05/12/15 16:41 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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Client Sample Results TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-11391-7 Client Sample ID: L10-14-07-B-E-S-00 Matrix: Solid Date Collected: 04/14/15 17:00 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.32 (2+/-)
0.192 (2+/-)
1 05/12/15 20:40 04/21/15 10:38 pCi/g 0.0946 RL MDC 0.139 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.362 0.465 0.429 1.74 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.0734 0.147 0.104 1.02 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.0644 0.164 0.0697 1.15 Lead 212 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.0702 0.138 0.0853 1.04 Lead 214 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.274 2.46 1.10 21.9 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 20:40 1
1.17 0.718 0.713 U
-0.724 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.0734 1.00 0.147 0.104 1.02 Radium 226 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.0946 0.192 0.139 1.32 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.799 0.309 0.284 1.16 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.191 0.120 0.118 0.241 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 20:40 1
0.0661 0.0439 0.0438 U
0.0247 Americium 241 pCi/g 04/21/15 10:38 05/12/15 20:40 1
4.64 2.68 2.68 U
0.673 Protactinium 234m Pb-210 1.38 0.527 0.551 0.684 pCi/g 04/21/15 10:38 05/12/15 20:40 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Tl-208 0.352 0.0469 0.0592 0.0363 pCi/g 04/21/15 10:38 05/12/15 20:40 1
Lab Sample ID: 160-11391-8 Client Sample ID: L10-14-08-B-R-S-00 Matrix: Solid Date Collected: 04/15/15 11:25 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.05 (2+/-)
0.170 (2+/-)
1 05/12/15 21:20 04/21/15 10:38 pCi/g 0.141 RL MDC 0.132 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.467 0.379 0.365 0.989 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.0944 0.184 0.138 1.16 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.0601 0.168 0.0816 1.14 Lead 212 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.0868 0.161 0.102 1.19 Lead 214 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.401 2.33 1.34 18.6 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 21:20 1
1.20 0.258 0.255 U
0.351 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.0944 1.00 0.184 0.138 1.16 Radium 226 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.141 0.170 0.132 1.05 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.841 0.307 0.295 U
0.809 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.254 0.156 0.155 U
0.101 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.107 0.0632 0.0632 U
-0.00124 Americium 241 pCi/g 04/21/15 10:38 05/12/15 21:20 1
5.52 3.35 3.34 U
2.49 Protactinium 234m Pb-210 1.62 0.638 0.666 0.795 pCi/g 04/21/15 10:38 05/12/15 21:20 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Tl-208 0.335 0.0501 0.0610 0.0372 pCi/g 04/21/15 10:38 05/12/15 21:20 1
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Client Sample Results TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Lab Sample ID: 160-11391-9 Client Sample ID: L10-14-09-B-E-S-00 Matrix: Solid Date Collected: 04/15/15 11:30 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.12 (2+/-)
0.221 (2+/-)
1 05/12/15 21:20 04/21/15 10:38 pCi/g 0.134 RL MDC 0.189 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.534 0.458 0.436 1.35 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.0929 0.168 0.131 1.02 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.100 0.159 0.104 0.932 Lead 212 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.0837 0.161 0.113 1.10 Lead 214 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.329 2.12 1.30 16.4 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 21:20 1
1.38 0.230 0.229 U
0.219 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.0929 1.00 0.168 0.131 1.02 Radium 226 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.134 0.221 0.189 1.12 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 21:20 1
1.08 0.925 0.911 1.57 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.302 0.157 0.157 U
0.111 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 21:20 1
0.119 0.0708 0.0708 U
0.0228 Americium 241 pCi/g 04/21/15 10:38 05/12/15 21:20 1
6.68 3.70 3.70 U
0.700 Protactinium 234m Tl-208 0.388 0.0586 0.0711 0.0396 pCi/g 04/21/15 10:38 05/12/15 21:20 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-11391-10 Client Sample ID: L10-14-06-B-E-Q-00 Matrix: Solid Date Collected: 04/14/15 16:50 Date Received: 04/17/15 10:20 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.15 (2+/-)
0.183 (2+/-)
1 05/12/15 21:21 04/21/15 10:38 pCi/g 0.107 RL MDC 0.142 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.402 0.484 0.456 1.57 Bismuth 212 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.0670 0.151 0.0999 1.10 Bismuth 214 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.0751 0.162 0.0754 1.10 Lead 212 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.0825 0.156 0.0951 1.19 Lead 214 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.310 2.51 1.17 22.1 Potassium 40 pCi/g 04/21/15 10:38 05/12/15 21:21 1
1.23 0.256 0.250 U
0.530 Protactinium 231 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.0670 1.00 0.151 0.0999 1.10 Radium 226 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.107 0.183 0.142 1.15 Thorium 232 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.868 0.306 0.290 0.937 Thorium 234 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.251 0.143 0.142 U
0.150 Uranium 235 pCi/g 04/21/15 10:38 05/12/15 21:21 1
0.104 0.0616 0.0616 U
0.0122 Americium 241 pCi/g 04/21/15 10:38 05/12/15 21:21 1
4.84 3.36 3.32 5.08 Protactinium 234m Tl-208 0.426 0.0517 0.0678 0.0369 pCi/g 04/21/15 10:38 05/12/15 21:21 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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QC Sample Results TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-187165/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 190513 Prep Batch: 187165 Actinium 228 Analyte U
1 05/12/15 14:40 04/21/15 10:38 pCi/g 0.0379 MDC RL 0.0120 0.0120 (2+/-)
(2+/-)
MB 0.0008778 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.317 0.180 0.180 U
-0.07467 Bismuth 212 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.0479 0.112 0.112 U
-0.009559 Bismuth 214 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.0350 0.102 0.102 U
-0.01437 Lead 212 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.0325 0.0200 0.0200 U
0.01620 Lead 214 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.276 4.06 4.06 U
-0.1016 Potassium 40 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.377 0.163 0.163 U
0.05235 Protactinium 231 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.0479 1.00 0.112 0.112 U
-0.009559 Radium 226 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.0379 0.0120 0.0120 U
0.0008778 Thorium 232 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.322 0.178 0.178 U
-0.006531 Thorium 234 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.0729 0.0405 0.0405 U
0.008410 Uranium 235 1
05/12/15 14:40 04/21/15 10:38 pCi/g 0.0246 0.0138 0.0138 U
0.003455 Americium 241 1
05/12/15 14:40 04/21/15 10:38 pCi/g 2.98 1.43 1.43 U
0.2022 Protactinium 234m Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 04/21/15 10:38 05/12/15 14:40 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-187165/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 190511 Prep Batch: 187165 Americium 241 Analyte 116 87 100 101.0 101 10.5 0.519 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 34.8 34.59 3.62 0.184 pCi/g 99 87 - 120 Cobalt 60 35.6 35.00 3.53 0.0976 pCi/g 98 87 - 115 Client Sample ID: L10-14-01-B-E-S-00 Lab Sample ID: 160-11391-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 190513 Prep Batch: 187165 Actinium 228 Analyte 1
0.37 1.296 1.13 0.246 0.123 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Bismuth 212 1.35 1.435 0.407 0.305 pCi/g 0.1 1
Bismuth 214 0.841 0.9278 0.153 0.0809 pCi/g 0.30 1
Lead 212 1.16 0.9905 0.153 0.0842 pCi/g 0.54 1
Lead 214 1.08 1.070 0.152 0.0837 pCi/g 0.03 1
Potassium 40 19.5 19.23 2.38 0.299 pCi/g 0.05 1
Protactinium 231
-0.575 U 0.4055 U 0.508 0.833 pCi/g 0.80 1
Radium 226 0.841 0.9278 0.153 1.00 0.0809 pCi/g 0.30 1
Thorium 232 1.13 1.296 0.246 0.123 pCi/g 0.37 1
Thorium 234 0.924 0.9103 U 0.343 0.961 pCi/g 0.02 1
Uranium 235 0.111 U 0.07142 U 0.153 0.277 pCi/g 0.13 1
-0.00138 U 0.01120 U 0.0718 0.121 pCi/g 0.09 1
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QC Sample Results TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: L10-14-01-B-E-S-00 Lab Sample ID: 160-11391-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 190513 Prep Batch: 187165 Protactinium 234m Analyte 1
0.25 U
4.056 2.27 U 4.05 6.63 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Tl-208 1
0.01 0.3643 0.365 0.0696 0.0430 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
RER RER Total Other Detected Radionuclides TestAmerica St. Louis Page 15 of 16 1
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QC Association Summary TestAmerica Job ID: 160-11391-2 Client: Perma-Fix Environmental Services Inc.
Project/Site: HDP Rad Leach Batch: 186422 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-11391-1 L10-14-01-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-1 DU L10-14-01-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-2 L10-14-02-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-3 L10-14-03-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-4 L10-14-04-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-5 L10-14-05-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-6 L10-14-06-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-7 L10-14-07-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-8 L10-14-08-B-R-S-00 Total/NA Solid Dry and Grind 160-11391-9 L10-14-09-B-E-S-00 Total/NA Solid Dry and Grind 160-11391-10 L10-14-06-B-E-Q-00 Total/NA Prep Batch: 187165 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-21 186422 160-11391-1 L10-14-01-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-1 DU L10-14-01-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-2 L10-14-02-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-3 L10-14-03-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-4 L10-14-04-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-5 L10-14-05-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-6 L10-14-06-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-7 L10-14-07-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-8 L10-14-08-B-R-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-9 L10-14-09-B-E-S-00 Total/NA Solid Fill_Geo-21 186422 160-11391-10 L10-14-06-B-E-Q-00 Total/NA Solid Fill_Geo-21 LCS 160-187165/2-A Lab Control Sample Total/NA Solid Fill_Geo-21 MB 160-187165/1-A Method Blank Total/NA TestAmerica St. Louis Page 16 of 16 1
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