ML071900447

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Orise Interim Report for Completed Analysis for Samples from Set Twenty, from the Indian Point Power Station, Buchanan, Ny, Dtd 04/27/07
ML071900447
Person / Time
Site: Indian Point Entergy icon.png
Issue date: 04/27/2007
From: Condra D
Oak Ridge Institute for Science & Education
To: Kottan J
NRC Region 1
References
FOIA/PA-2007-0324, IR-06-007, RFTA 06-001
Download: ML071900447 (10)
v • d • e


Text

OAK RIDGE INSTITUTE FOR SCIENCE AND EDUCATION Distribution approval and concurrence :

Technical Management Team Member Quality Manager A p d 27,2007 Initials,

A Mr. Jim Kottan U.S. Nuclear Regulatory Commission Regon I 475 Allendale Road IGng of Prussia, PA 19406

SUBJECT:

INTERIM REPORT FOR COMPLETED ANALYSES FOR SAMPLES FROM SET TWENTY, FROM THE INDIAN POINT POWER STATION, BUCHANAN, NEW YORK

[INSPECTION REPORT NO. 050-247/2006-0071 [RFTA NO. 06-0011

Dear Mr. Kottan:

The Oak Rtdge Institute for Science and Education (ORISE) received set 20, consisting of 10 water samples, associated with the Indian Point Power Station on January 29, 2007. Sample analysis was initiated based on your previous direction for handling samples from this licensee. Sample identification and collection data for the samples addressed in this report are presented in Table 1. Gamma spectroscopy, the hard-to-detect betas (iron-55, nickel-63, and tritium), technetium-99, total radiostrontium, alpha spectroscopy, plutonium-241, and carbon-14 data are provided in Tables 2 through 8, respectively. The pertinent procedure references are provided in each specific table.

ORISE's Quality Control (QC) requirements were met for these analyses. The QC files are available for your review upon request. Additional reports wdl follow after the completion of the requested analyses.

ORISE has removed the Ni-59 data due to problems with the calculation associated with the concentration of this radionuclide. ORISE is discontinuing the reporting of Ni-59 data und ths problem can be resolved.

My contact information is listed below. You may also contact Wade Ivey at 865.576.9184 with any questions or comments.

Sincerely, Dale Condra, Manager Laboratory RDC:wPI:km Enclosures C:

T. Carter, NRC/FSME/DWMEP 758 E. Abelquist, ORISET E. Ihox-Davin, NRC/FSME/TWFN 8A23 S. IGrk, ORISE w

M. Roberts, NRC Regon I J. White, NRC R e g 0 3 File 1697 Voice: 865.241.3242 Fax: 865.241.3248 E-mail: Dale.Condra @orau.org

TABLE 1 ORISE Sample ID 1697W0124" 1 697M0073b SAMPLE IDENTIFICATIONS AND COLLECTION DATA INDIAN POINT POWER STATION BUCHANAN, NEW YORK NRC Region I Collection Collection Sample ID Date Time MW-30 74' 006 1/16/2007 13:40 MW-30 74' 006 1/16/2007 13:40 1697~0125 1697M0074 1697W0126 1697M0075 MW-30 88' 003 1 /16/2007 13:50 MW-30 88' 003 1 / 16/2007 13:50 MW-31 53' (002) 1 /18/2007 9:13 MW-31 53' (002) 1/18/2007 9:13 1697W0127 1697M0076 1697W0128 1697M0077 1697W0129 1697M0078 MW-31 67' (002) 1/18/2007 9:25 MW-31 67' (002) 1 / 18/2007 9:25 MW-31 89' (002) 1/18/2007 9:16 MW-31 89' (002) 1/18/2007 9:16 MW-32 62' (001) 1/19/2007 9:30 MW-32 62' (001) 1 / 19/2007 9:30 1697W0132 I

MW-32160'(001)

I 1/19/2007 I 9:50 1697W0130 1697M0079 1697W0131 1697M0080 MW-32 92' (001) 1/19/2007 9:40 MW-32 92' (001) 1/19/2007 9:40 W - 3 2 140' (001) 1/19/2007 9:45 MW-32 140' (001) 1/19/2007 9:45 T h e W in the ORISE sample identification represents a water matrix.

bThe M in the ORISE sample identification represents the filtrrrd fraction of the preceding water sample 1697M0081 1697W0133 1697M0082 Indian Point Power Station MW-32 160' (001) 1 /19/2001 9:50 MW-32 197' (001) 1/19/2007 9:55 MW-32 197' (001) 1 / 19/2007 9:55 projects/l697/l)atn Tables/2007-04-27 Data Tables Set 20

TABLE 2 ORISE Sample ID CONCENTRATIONS OF SELECTED GAMMA EMITTING RADIONUCLIDES IN WATER SAMPLES BY GAMMA SPECTROSCOPY CP1, REVISION 15 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide Concentrationsa I NRC Region I Sample ID CO-58 CO-60 cs-134 1697W0124 1697W0125 1697W0126 1697W01.27 1697W0128 MW-30 74' 006 2.2 k 3.3b 2.2 4 2.9 -1.0 4 3.1 MW-30 88' 003 0.6 4 2.4 1.2 4 2.3 0.6 4 2.4 W - 3 1 53' (002) 1.2 4 2.9 2.6 4 3.1 0.8 4 3.0 MW-31 67' (002) 0.3 k 3.1 4.1 4 3.0 3.6 k 3.8 MW-31 89' (002)

-2.6 k 2.6 1.4 k 2.4 0.0" k 2.3 1697W0130 1697W0131 1697W0132 1697W0133

~~~~~

%e range of MDCs for the selected radionuclides is 3.5 pCi/I, to 5.9 pCi/L.

'Unccrtainties represent the 95% confidence level, based on total propagated uncertainties

'Zero values are due to rounding.

~~

~~

W - 3 2 9 2 ' (001) 0.5 k 3.0 3.9 k 3.0 1.0 k 3.1 MW-32 140' (001)

-2.5 4 3.2 2.6 k 3.2 -0.4 4 3.3 MIX-32 160' (001)

-0.1 4 2.3 1.1 4 2.8 2.0 4 2.4 MW-32 197' (001)

-0.4 k 3.4 1.9 4 3.3 1.6 k 3.4 cs-137

-1 0.3 ? 2.2

-11 0.7 4 5.5 11 2.4 4 2.4 Indian Point Power Station projects/l697/Data Tables/2007-04-27 Data Tables Set 20

TABLE 3 ORISE NRC Region I Sample ID Sample ID CONCENTRATIONS OF HARD-TO-DETECT BETA EMITTING RADIONUCLIDES I N WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide Concentrationsa (pCi/L)

Fe-55b Ni-63" H-3d 1697W0131 1697W0132 1697W0133 Indian Point Power Station MW-32 140' (001)

-9 k 19, 33 3.8 f. 5.4, 9.0 10,480 k 550

, 320 MW-32160'(001)

-10 k 19, 33 9.3 k 5.4, 9.0 10,520 2 550

, 320 MW-32197'(001)

-2 k 19, 33 5.1 k 5.4, 9.0 11,000 k 570, 320 projects/l697/Data Tables/2007-04-27 Data Tables Set 20

TABLE 4 ORISE Sample ID 1697WO 124 CONCENTRATIONS OF TECHNETIUM-99 (Tc-99)

I N WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP5, REVISION 16; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK NRC Region I Tc-99 Concentrationsa Sample ID

@ W L )

MW-30 74' 006 5

+

Ihb 37 1697W0125 1697W0126 MW-30 88' 003 15 2 16 27 MW-31 53' (002) 7 k 16,

27 1697W0127 1697W0128 MW-3 1 67' (002) 10 k 16,

27 MW-3 1 89' (002) 7 i-16 27 1697W0132 I MW-32 160'(001) I 17 i-16 27 11 1697W0129 1697W0130 1697W013 1 1697W0133 I MW-32 197Y001) I 11 k 16 27 11

~

\\

7 MW-32 62' (001) 12 k 16,

27 MW-32 92' (001) 9 k 16,

27 MW-32 140' (001) 12 16.

27 "The MDCs arc after the comma.

'Uncertainties represent the 95% confidence level, based on total propagated uncertainties Indian Point Power Station projects/l697/Data Tables/2007-04-27 Data Tables Set 20

TABLE 5 ORISE Sample ID CONCENTRATIONS OF TOTAL RADIOSTRONTIUM IN WATER SAMPLES BY LOW BACKGROUND BETA COUNTING AP4, REVISION 13; CP3, REVISION 2 INDIAN POINT POWER STATION BUCHANAN, NEW YORK NRC Region I Radionuclide Concentrations, Sample ID TPUs, and MDCS" (pCi/L) 1697W0124 1697W0125 1697W0126 Mw-30 74' 006 0.2 k

1.Ob 1.8 Mw-30 88' 003 0.6

f.

1.1 1.8 Mw-31 53' (002)

-0.6 1.0 1.8 1697W0127 I

Mw-31 67' (002)

I

-0.3 1.0 1.8 II 1697W0128 1697W0129 1697W0130 1697W0131 Mw-31 89' (002) 0.2 2

1.1 1.9 MW-32 92' (001)

-0.1 t

1.1 1.9 Mw-32 140' (001) 0.2 1.0 1.8 Mw-32 62' (001) 0.2 k

1.1 1.9 1697W0132 1697W0133 The MDCs are after the comma.

'Uncertanties represent the 95% confidence level, based on total propagated uncertatnhes.

Mw-32 160' (001) 0.4 1.1 1.9 Mw-32 197' (001) 0.6 1.1 1.9 Indian Point Power Station projects/l697/Data Tables/2007-04-27 Data Tables Set 20

TABLE G ORISE Sample ID 1697W0124b 1 697M0073d CONCENTRATIONS OF SELECTED ALPHA EMITTING RADIONUCLIDES IN SUSPENDED AND DISSOLVED FRACTIONS OF WATER SAMPLES AP11, REVISION 3; CP2, REVISION 12 INDIAN POINT POWER STATION BUCHANAN, NEW YORK NRC Region I MW-30 74'006 0.14 t 0.20', 0.33 -0.06 f 0.08, 0.21

-0.14 f 0.15, 0.34 0.06 f 0.06, 0.06 MW-30 74'006 0.01 f 0.02. 0.03 0.02 f 0.02, 0.03 0.00' t 0.02. 0.03

-0.01 k 0.02, 0.03 Radionuclide Concentrationsa @Ci/g of sediment in 100 mL or pCi/L for water)

Sample ID Am-241 Cm-242 Cm-243/244 Np-237 1697W0125 1697M0074 1697W0126 MW-30 88'003 0.11

  • 0.23, 0.40 0.07 f 0.12, 0.22 0.07

_+

0.21, 0.37 0.02 f 0.18, 0.34 MW-30 88'003 0.01 t 0.03, 0.05 0.01 f 0.01, 0.02 0.01

+_

0.02, 0.04

-0.02

+_

0.02, 0.04 MW-31 53'(002) 0.02 f 0.08. 0.18 0.02 f 0.04, 0.06 0.00 t 0.09. 0.21

-0.12 t 0.18, 0.39 1697M0075 1697W0127 1697M0076 11 1697W0128 I MW-31 89'(0021 I 0.00 f 0.20. 0.38 I 0.06 f 0.08. 0.14 I -0.15 t 0.19. 0.40 I -0.02

? 0.04. 0.16 MW-31 53' (002)

-0.01 t 0.01, 0.03 0.01 f 0.01, 0.01 0.000 k 0.004f, 0.006 0.00 f 0.02, 0.04 MW-31 67'(002) 0.02 f 0.19, 0.36

-0.02 ? 0.10, 0.22

-0.11 jI 0.19, 0.39

-0.21 f 0.19, 0.46 MW-31 67'(002) 0.01 ? 0.02, 0.04 0.00 f 0.01, 0.02

-0.01 f 0.02, 0.03 0.00 f 0.01, 0.02 5

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~~

~~

16971110077 MW-31 89' (002) 0.00 f 0.02, 0.04 0.00 f 0.01, 0.02 0.00 t 0.02, 0.04 0.00 t 0.02, 0.03 1697W0129 MW-32 62'(001) 0.24 t 0.21, 0.33 0.02 f 0.07, 0.15

-0.02 k 0.20, 0.40

-0.04 t 0.15, 0.33 16971110078 MW-32 62'(001) 0.03 k 0.04, 0.06 0.01 t 0.02, 0.03 0.01

_+

0.03, 0.06 0.00 f 0.01, 0.02 1697W0130 MW-32 92'(001) 0.02 f 0.19, 0.37 0.04 f 0.09, 0.17

-0.20 t 0.23, 0.47 0.07 f 0.08, 0.07 1697M0079 1697W0131 16971110080

\\

I 1697M0082 I MW-32 197'(001) I 0.00 f 0.01, 0.02 I 0.000 rt 0.003, 0.018 I 0.00

_+

0.02, 0.03 I 0.00 f 0.01, 0.01 0

MW-32 92' (001)

-0.01 f 0.02, 0.04 0.00 -f 0.01, 0.02

-0.01

+_

0.02, 0.04

-0.02 f 0.02, 0.05 MW-32 140'(001) 0.03 f 0.20, 0.37

-0.06 f 0.10, 0.21 0.03 k 0.15, 0.29

-0.07 k 0.16, 0.38 MW-32 140' (001) 0.01 f 0.02. 0.03 0.02 f 0.01. 0.02 0.01 jI 0.01. 0.02

-0.01 f 0.01. 0.03 1697W0132 1697M0081 1697W0133 MW-32 160'(001) 0.08 f 0.20, 0.36

-0.07 k 0.10, 0.24 0.00 k 0.15, 0.29 0.00 f 0.10, 0.23 MW-32 160'(001) 0.02 f 0.02, 0.04 0.03 f 0.02, 0.02

-0.02 k 0.02, 0.04 0.01 f 0.02, 0.03 Mw-32 197'(001) 0.05 ? 0.13. 0.23 0.02 f 0.08. 0.17 0.05 jI 0.13. 0.25

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Indian Point Power Station projects/l697/Data lablcs/2007-04-27 Data Tables Set 20

TABLE 7 CONCENTRATIONS OF PLUTONIUM-241 IN SUSPENDED AND DISSOLVED FRACTIONS OF WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP10, REVISION 2; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK "The MDCs are after the comma.

bThe W in the ORISE sample identification represents a water matrix.

'Uncertaintics represent the 9 W o confidence level, based on total propagated uncertainties.

dThe M in the ORISE sample identification represents a 100 mL filtered fraction of the preceding water sample.

Indian Point Power Station projects/1697/Data Tables/2007-04-27 Data Tables Set 20

TABLE 8 I

CONCENTRATIONS OF CARBON-14 I N WATER SAMPLES BY LIQUID SCINTILLATION ANfiYSIS AP9, REVISION 3; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE Sample ID 1697W0124 1697W0125 1697W0126 1697W0127 1697W0128 NRC Region I Radionuclide Concentrations, Sample ID TPUs, and MDCS" (pCi/L)

MW-30 74' 006 13.0 9.5b 15.5 MW-30 88' 003 2.7

+

9.1 15.5 MW-31 53' (002) 6.0 zk 9.2 15.5 MW-31 67' (002) 3.9 k

9.2 15.5 MW-31 89' (002) 4.1

?

9.2 15.5 1697W0130 1697W0131 1697W0132 11 1697W0129 I Mw-32 62' (001)

I 9.5

+

9.3 MW-32 92' (001) 9.7

?

9.4 15.5 MW-32 140' (001) 9.5 zk 9.3 15.5 MW-32 160' (001)

-2.3

?

9.0 15.5 15.5 11 1697W0133 MW-32 197' (001) 2.9 9.1 15.5 "MDCs are after the comma buncertainties represent the 95% confidence level, based on total propagated uncertainties.

Indian Point Power Station prolects/l697/Data Tables/2007-04-27 Data Tables Set 20

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