ML062860432

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Spreadsheet File of Instructions, Materials Conversions, Results Table, Releases by Material, & Precipitate by Material, Reports
ML062860432
Person / Time
Site: Fort Calhoun 
Issue date: 10/10/2006
From:
Omaha Public Power District
To:
Office of Nuclear Reactor Regulation
References
LIC-06-0116
Download: ML062860432 (1)


Text

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Si All Mat Si this Mat Only Mass Material (kg) 570.8972 0.4 0.00 0.01 4.65 231 2.60617 0

0 Mass Element (kg) 137.5862 0.5 0.01 0.0 4.95 231 2.60617 0.02 0.02 a

0.12735 1.0 0.02 0.0 5.25 231 2.60617 0.04 0.04 b

0.03197 1.0 0.03 0.1 5.55 231 2.60617 0.09 0.09 c

0.71658 0.3 0.05 0.1 5.85 231 2.60617 0.14 0.13 d

7.5547 3.3 0.06 0.1 6.15 231 2.60617 0.15 0.15 e

-0.04084 3.3 0.11 0.2 6.45 231 2.60617 0.30 0.28 f

-2.02198 8.0 0.17 0.3 6.75 231 2.60617 0.45 0.42 5.0 0.30 0.4 7.05 231 2.60617 0.80 0.73 5.0 0.38 0.5 7.35 231 2.60617 1.01 0.92 5.0 0.47 0.6 7.5 231 2.60617 1.23 1.10 10.0 0.55 0.7 7.5 231 2.60617 1.44 1.28 10.0 0.72 0.9 7.5 231 2.60617 1.86 1.64 10.0 0.88 1.1 7.5 231 2.60617 2.28 2.01 6.7 1.05 1.2 7.5 231 2.60617 2.70 2.37 30.0 1.16 1.7 7.5 228 2.61753 2.98 2.61 30.0 1.66 2.2 7.5 225 2.629 4.17 3.63 33.3 2.16 2.7 7.5 225 2.629 5.29 4.59 4.3 2.72 2.8 7.5 225 2.629 6.53 5.65 26.0 2.79 3.2 7.5 225 2.629 6.69 5.79 176.4 3.22 6.2 7.5 225 2.629 7.65 6.62 230.3 6.16 10.0 7.5 225 2.629 14.13 12.18 189.7 10.00 13.2 7.5 223 2.63671 22.35 19.21 720.0 13.16 25.2 7.5 202.5 2.71834 28.64 24.57 1370.3 25.16 48.0 7.5 181.5 2.80737 44.47 38.29 1440.0 48.00 72.0 7.5 176.5 2.82943 63.16 54.73 1440.0 72.00 96.0 7.5 171.5 2.85185 79.58 69.19 1440.0 96.00 120.0 7.5 166.5 2.87462 92.78 81.42 7200.0 120.00 240.0 7.5 161.5 2.89776 103.23 91.88 7200.0 240.00 360.0 7.5 156.5 2.92127 103.59 92.23 7200.0 360.00 480.0 7.5 151.5 2.94517 103.60 92.23 7200.0 480.00 600.0 7.5 146.5 2.96946 103.60 92.23 7200.0 600.00 720.0 7.5 142 2.99167 103.60 92.23

Si (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Si released Integral kg Si released 0.00 139.17 124.50 124.50 124.50 0.028

-137.6 0.028 0.0 0.02 142.27 121.04 121.02 121.02 0.035

-137.5 0.035 0.1 0.04 145.45 117.67 117.64 117.64 0.067

-137.5 0.067 0.1 0.09 148.70 114.40 114.33 114.33 0.065

-137.4 0.065 0.2 0.13 152.02 111.22 111.12 111.12 0.021

-137.4 0.021 0.2 0.15 155.41 108.12 108.02 108.02 0.206

-137.2 0.206 0.4 0.28 158.88 105.12 104.93 104.93 0.200

-137.0 0.200 0.6 0.42 162.43 102.19 101.93 101.93 0.466

-136.5 0.466 1.1 0.73 166.06 99.35 98.91 98.91 0.282

-136.2 0.282 1.4 0.92 169.77 96.59 96.06 96.06 0.274

-135.9 0.274 1.6 1.10 171.65 95.23 94.62 94.62 0.270

-135.7 0.270 1.9 1.28 171.65 95.23 94.52 94.52 0.540

-135.1 0.540 2.5 1.64 171.65 95.23 94.32 94.32 0.538

-134.6 0.538 3.0 2.01 171.65 95.23 94.12 94.12 0.537

-134.1 0.537 3.5 2.37 171.65 95.23 93.92 93.92 0.359

-133.7 0.359 3.9 2.61 174.90 90.32 88.98 88.98 1.524

-132.2 1.524 5.4 3.63 178.24 85.63 83.88 83.88 1.437

-130.7 1.437 6.8 4.59 178.24 85.63 83.42 83.42 1.586

-129.2 1.586 8.4 5.65 178.24 85.63 82.91 82.91 0.203

-128.9 0.203 8.6 5.79 178.24 85.63 82.84 82.84 1.232

-127.7 1.232 9.9 6.62 178.24 85.63 82.45 82.45 8.301

-119.4 8.301 18.2 12.18 178.24 85.63 79.77 79.77 10.489

-108.9 10.489 28.7 19.21 180.52 82.61 73.82 73.82 7.994

-100.9 7.994 36.7 24.57 206.55 56.49 49.77 49.77 20.458

-80.5 20.458 57.1 38.29 239.24 37.32 31.35 31.35 24.524

-55.9 24.524 81.6 54.73 248.11 33.68 26.25 26.25 21.579

-34.4 21.579 103.2 69.19 257.45 30.34 22.19 22.19 18.239

-16.1 18.239 121.5 81.42 267.31 27.29 18.98 18.98 15.601

-0.5 15.601 137.1 91.88 277.72 24.50 16.40 16.40 67.393 66.9 0.531 137.6 92.23 288.70 21.96 14.94 14.94 61.430 61.4 0.000 137.6 92.23 300.31 19.65 13.61 13.61 55.959 56.0 0.000 137.6 92.23 312.60 17.55 12.37 12.37 50.845 50.8 0.000 137.6 92.23 324.26 15.82 11.32 11.32 46.541 46.5 0.000 137.6

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Ca All Mat Mass Material (kg) 0.0347001 0.4 0.00 0.01 4.65 231 2.60617 0

Mass Element (kg) 1000000 0.5 0.01 0.0 4.95 231 2.60617 0.01 a

-0.15969 1.0 0.02 0.0 5.25 231 2.60617 0.02 b

-0.04542 1.0 0.03 0.1 5.55 231 2.60617 0.03 c

0.95477 0.3 0.05 0.1 5.85 231 2.60617 0.05 d

5.31705 3.3 0.06 0.1 6.15 231 2.60617 0.05 e

-0.07459 3.3 0.11 0.2 6.45 231 2.60617 0.09 f

-1.10803 8.0 0.17 0.3 6.75 231 2.60617 0.13 5.0 0.30 0.4 7.05 231 2.60617 0.22 5.0 0.38 0.5 7.35 231 2.60617 0.26 5.0 0.47 0.6 7.5 231 2.60617 0.31 10.0 0.55 0.7 7.5 231 2.60617 0.35 Note= Large mass of element used 10.0 0.72 0.9 7.5 231 2.60617 0.43 because no limit to concrete assuming 10.0 0.88 1.1 7.5 231 2.60617 0.51 mass is an exposed surface.

6.7 1.05 1.2 7.5 231 2.60617 0.59 If concrete in latent debris is being 30.0 1.16 1.7 7.5 228 2.61753 0.65 included, a fraction of B2 should be 30.0 1.66 2.2 7.5 225 2.629 0.90 used.

33.3 2.16 2.7 7.5 225 2.629 1.17 4.3 2.72 2.8 7.5 225 2.629 1.46 26.0 2.79 3.2 7.5 225 2.629 1.50 176.4 3.22 6.2 7.5 225 2.629 1.72 230.3 6.16 10.0 7.5 225 2.629 3.23 189.7 10.00 13.2 7.5 223 2.63671 5.12 720.0 13.16 25.2 7.5 202.5 2.71834 6.63 1370.3 25.16 48.0 7.5 181.5 2.80737 13.90 1440.0 48.00 72.0 7.5 176.5 2.82943 31.74 1440.0 72.00 96.0 7.5 171.5 2.85185 46.14 1440.0 96.00 120.0 7.5 166.5 2.87462 57.85 7200.0 120.00 240.0 7.5 161.5 2.89776 68.21 7200.0 240.00 360.0 7.5 156.5 2.92127 117.84 7200.0 360.00 480.0 7.5 151.5 2.94517 117.85 7200.0 480.00 600.0 7.5 146.5 2.96946 118.18 7200.0 600.00 720.0 7.5 142 2.99167 133.32

Ca this Mat Only Ca (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Ca released Integral kg Ca released 0

0.000 131.04 120.92 120.92 120.92 0.000

-1000000 0.000 0.000 0.00 0.000 126.99 114.85 114.85 114.85 0.000

-1000000 0.000 0.000 0.00 0.000 123.07 109.08 109.08 109.08 0.000

-1000000 0.000 0.000 0.00 0.000 119.27 103.60 103.60 103.60 0.000

-1000000 0.000 0.000 0.00 0.000 115.58 98.40 98.40 98.40 0.000

-1000000 0.000 0.000 0.00 0.000 112.01 93.46 93.46 93.46 0.000

-1000000 0.000 0.000 0.00 0.000 108.55 88.76 88.76 88.76 0.000

-1000000 0.000 0.000 0.00 0.000 105.20 84.31 84.31 84.31 0.000

-1000000 0.000 0.000 0.00 0.000 101.95 80.07 80.07 80.07 0.000

-1000000 0.000 0.000 0.00 0.000 98.80 76.05 76.05 76.05 0.000

-1000000 0.000 0.000 0.00 0.000 97.26 74.12 74.12 74.12 0.000

-1000000 0.000 0.000 0.00 0.000 97.26 74.12 74.12 74.12 0.000

-1000000 0.000 0.000 0.00 0.000 97.26 74.12 74.12 74.12 0.000

-1000000 0.000 0.000 0.00 0.000 97.26 74.12 74.12 74.12 0.000

-1000000 0.000 0.000 0.00 0.000 97.26 74.12 74.12 74.12 0.000

-1000000 0.000 0.000 0.00 0.000 99.72 72.00 72.00 72.00 0.000

-1000000 0.000 0.000 0.00 0.000 102.27 69.92 69.92 69.92 0.000

-1000000 0.000 0.000 0.00 0.000 102.27 69.92 69.92 69.92 0.000

-1000000 0.000 0.000 0.00 0.000 102.27 69.92 69.92 69.92 0.000

-1000000 0.000 0.000 0.00 0.000 102.27 69.92 69.92 69.92 0.000

-1000000 0.000 0.000 0.00 0.000 102.27 69.92 69.92 69.92 0.000

-1000000 0.000 0.001 0.00 0.001 102.27 69.92 69.92 69.92 0.001

-1000000 0.001 0.001 0.00 0.001 104.02 68.56 68.56 68.56 0.000

-1000000 0.000 0.002 0.00 0.001 124.46 55.67 55.67 55.67 0.001

-1000000 0.001 0.003 0.00 0.002 151.37 44.36 44.36 44.36 0.002

-1000000 0.002 0.005 0.00 0.004 158.90 41.93 41.93 41.93 0.002

-1000000 0.002 0.008 0.01 0.005 166.92 39.60 39.60 39.60 0.002

-1000000 0.002 0.010 0.01 0.006 175.49 37.36 37.36 37.36 0.002

-1000000 0.002 0.011 0.01 0.008 184.65 35.22 35.22 35.22 0.009

-1000000 0.009 0.020 0.01 0.014 194.45 33.17 33.17 33.17 0.008

-1000000 0.008 0.028 0.02 0.019 204.94 31.21 31.21 31.21 0.008

-1000000 0.008 0.036 0.02 0.024 216.18 29.33 29.33 29.33 0.007

-1000000 0.007 0.044 0.03 0.029 227.00 27.72 27.71 27.71 0.007

-1000000 0.007 0.051

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Si All Mat Si this Mat Only Mass Material (kg) 0.0347001 0.4 0.00 0.01 4.65 231 2.60617 0

0 Mass Element (kg) 1000000 0.5 0.01 0.0 4.95 231 2.60617 0.02 0.00 a

1.05597 1.0 0.02 0.0 5.25 231 2.60617 0.04 0.00 b

0.01483 1.0 0.03 0.1 5.55 231 2.60617 0.09 0.00 c

0.11862 0.3 0.05 0.1 5.85 231 2.60617 0.14 0.00 d

3.50061 3.3 0.06 0.1 6.15 231 2.60617 0.15 0.00 e

-0.01713 3.3 0.11 0.2 6.45 231 2.60617 0.30 0.00 f

-0.74261 8.0 0.17 0.3 6.75 231 2.60617 0.45 0.00 5.0 0.30 0.4 7.05 231 2.60617 0.80 0.00 5.0 0.38 0.5 7.35 231 2.60617 1.01 0.00 5.0 0.47 0.6 7.5 231 2.60617 1.23 0.00 10.0 0.55 0.7 7.5 231 2.60617 1.44 0.00 Note= Large mass of element used 10.0 0.72 0.9 7.5 231 2.60617 1.86 0.00 because no limit to concrete assuming 10.0 0.88 1.1 7.5 231 2.60617 2.28 0.00 mass is an exposed surface.

6.7 1.05 1.2 7.5 231 2.60617 2.70 0.00 If concrete in latent debris is being 30.0 1.16 1.7 7.5 228 2.61753 2.98 0.00 included, a fraction of B2 should be 30.0 1.66 2.2 7.5 225 2.629 4.17 0.00 used.

33.3 2.16 2.7 7.5 225 2.629 5.29 0.00 4.3 2.72 2.8 7.5 225 2.629 6.53 0.00 26.0 2.79 3.2 7.5 225 2.629 6.69 0.00 176.4 3.22 6.2 7.5 225 2.629 7.65 0.00 230.3 6.16 10.0 7.5 225 2.629 14.13 0.00 189.7 10.00 13.2 7.5 223 2.63671 22.35 0.00 720.0 13.16 25.2 7.5 202.5 2.71834 28.64 0.00 1370.3 25.16 48.0 7.5 181.5 2.80737 44.47 0.00 1440.0 48.00 72.0 7.5 176.5 2.82943 63.16 0.00 1440.0 72.00 96.0 7.5 171.5 2.85185 79.58 0.00 1440.0 96.00 120.0 7.5 166.5 2.87462 92.78 0.00 7200.0 120.00 240.0 7.5 161.5 2.89776 103.23 0.00 7200.0 240.00 360.0 7.5 156.5 2.92127 103.59 0.01 7200.0 360.00 480.0 7.5 151.5 2.94517 103.60 0.01 7200.0 480.00 600.0 7.5 146.5 2.96946 103.60 0.01 7200.0 600.00 720.0 7.5 142 2.99167 103.60 0.01

Si (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Si released Integral kg Si released 0.00 27.17 30.59 30.59 30.59 0.000

-1000000 0.000 0.00 0.00 27.45 30.23 30.23 30.23 0.000

-1000000 0.000 0.00 0.00 27.73 29.88 29.88 29.88 0.000

-1000000 0.000 0.00 0.00 28.02 29.52 29.52 29.52 0.000

-1000000 0.000 0.00 0.00 28.31 29.18 29.18 29.18 0.000

-1000000 0.000 0.00 0.00 28.60 28.83 28.83 28.83 0.000

-1000000 0.000 0.00 0.00 28.89 28.49 28.49 28.49 0.000

-1000000 0.000 0.00 0.00 29.19 28.16 28.16 28.16 0.000

-1000000 0.000 0.00 0.00 29.49 27.83 27.83 27.83 0.000

-1000000 0.000 0.00 0.00 29.79 27.50 27.50 27.50 0.000

-1000000 0.000 0.00 0.00 29.95 27.34 27.34 27.34 0.000

-1000000 0.000 0.00 0.00 29.95 27.34 27.34 27.34 0.000

-1000000 0.000 0.00 0.00 29.95 27.34 27.34 27.34 0.000

-1000000 0.000 0.00 0.00 29.95 27.34 27.34 27.34 0.000

-1000000 0.000 0.00 0.00 29.95 27.34 27.34 27.34 0.000

-1000000 0.000 0.00 0.00 30.04 26.81 26.81 26.81 0.000

-1000000 0.000 0.00 0.00 30.13 26.29 26.29 26.29 0.000

-1000000 0.000 0.00 0.00 30.13 26.29 26.29 26.29 0.000

-1000000 0.000 0.00 0.00 30.13 26.29 26.29 26.29 0.000

-1000000 0.000 0.00 0.00 30.13 26.29 26.29 26.29 0.000

-1000000 0.000 0.00 0.00 30.13 26.29 26.29 26.29 0.000

-1000000 0.000 0.00 0.00 30.13 26.29 26.29 26.29 0.000

-1000000 0.000 0.00 0.00 30.20 25.95 25.95 25.95 0.000

-1000000 0.000 0.00 0.00 30.88 22.57 22.57 22.57 0.001

-1000000 0.001 0.00 0.00 31.64 19.38 19.38 19.38 0.001

-1000000 0.001 0.00 0.00 31.83 18.66 18.66 18.66 0.001

-1000000 0.001 0.00 0.00 32.02 17.96 17.96 17.96 0.001

-1000000 0.001 0.00 0.00 32.22 17.27 17.27 17.27 0.001

-1000000 0.001 0.00 0.00 32.43 16.60 16.60 16.60 0.004

-1000000 0.004 0.01 0.01 32.64 15.95 15.95 15.95 0.004

-1000000 0.004 0.01 0.01 32.85 15.31 15.31 15.31 0.004

-1000000 0.004 0.02 0.01 33.07 14.69 14.68 14.68 0.004

-1000000 0.004 0.02 0.01 33.27 14.14 14.14 14.14 0.004

-1000000 0.004 0.02

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Al All Mat Mass Material (kg) 0.0347001 0.4 0.00 0.01 4.65 231 2.60617 0

Mass Element (kg) 1000000 0.5 0.01 0.0 4.95 231 2.60617 0.00 a

2.35338 1.0 0.02 0.0 5.25 231 2.60617 0.00 b

0.06829 1.0 0.03 0.1 5.55 231 2.60617 0.00 c

-0.70953 0.3 0.05 0.1 5.85 231 2.60617 0.01 d

9.23778 3.3 0.06 0.1 6.15 231 2.60617 0.01 e

0.05404 3.3 0.11 0.2 6.45 231 2.60617 0.01 f

-3.34577 8.0 0.17 0.3 6.75 231 2.60617 0.02 5.0 0.30 0.4 7.05 231 2.60617 0.04 5.0 0.38 0.5 7.35 231 2.60617 0.05 5.0 0.47 0.6 7.5 231 2.60617 0.07 10.0 0.55 0.7 7.5 231 2.60617 0.09 Note= Large mass of element used 10.0 0.72 0.9 7.5 231 2.60617 0.12 because no limit to concrete assuming 10.0 0.88 1.1 7.5 231 2.60617 0.16 mass is an exposed surface.

6.7 1.05 1.2 7.5 231 2.60617 0.19 If concrete in latent debris is being 30.0 1.16 1.7 7.5 228 2.61753 0.23 included, a fraction of B2 should be 30.0 1.66 2.2 7.5 225 2.629 0.64 used.

33.3 2.16 2.7 7.5 225 2.629 1.01 4.3 2.72 2.8 7.5 225 2.629 1.36 26.0 2.79 3.2 7.5 225 2.629 1.40 176.4 3.22 6.2 7.5 225 2.629 1.61 230.3 6.16 10.0 7.5 225 2.629 2.88 189.7 10.00 13.2 7.5 223 2.63671 4.35 720.0 13.16 25.2 7.5 202.5 2.71834 4.82 1370.3 25.16 48.0 7.5 181.5 2.80737 5.75 1440.0 48.00 72.0 7.5 176.5 2.82943 6.59 1440.0 72.00 96.0 7.5 171.5 2.85185 7.34 1440.0 96.00 120.0 7.5 166.5 2.87462 7.95 7200.0 120.00 240.0 7.5 161.5 2.89776 8.46 7200.0 240.00 360.0 7.5 156.5 2.92127 10.54 7200.0 360.00 480.0 7.5 151.5 2.94517 12.24 7200.0 480.00 600.0 7.5 146.5 2.96946 13.62 7200.0 600.00 720.0 7.5 142 2.99167 14.73

Al this Mat Only Al (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Al released Integral kg Al released 0

0.00 6.63 5.88 5.88 5.88 0.000

-1000000 0.000 0.00 0.00 0.00 6.95 6.10 6.10 6.10 0.000

-1000000 0.000 0.00 0.00 0.00 7.29 6.34 6.34 6.34 0.000

-1000000 0.000 0.00 0.00 0.00 7.64 6.58 6.58 6.58 0.000

-1000000 0.000 0.00 0.00 0.00 8.01 6.83 6.83 6.83 0.000

-1000000 0.000 0.00 0.00 0.00 8.40 7.09 7.09 7.09 0.000

-1000000 0.000 0.00 0.00 0.00 8.80 7.36 7.36 7.36 0.000

-1000000 0.000 0.00 0.00 0.00 9.23 7.64 7.64 7.64 0.000

-1000000 0.000 0.00 0.00 0.00 9.68 7.93 7.93 7.93 0.000

-1000000 0.000 0.00 0.00 0.00 10.14 8.23 8.23 8.23 0.000

-1000000 0.000 0.00 0.00 0.00 10.38 8.38 8.38 8.38 0.000

-1000000 0.000 0.00 0.00 0.00 10.38 8.38 8.38 8.38 0.000

-1000000 0.000 0.00 0.00 0.00 10.38 8.38 8.38 8.38 0.000

-1000000 0.000 0.00 0.00 0.00 10.38 8.38 8.38 8.38 0.000

-1000000 0.000 0.00 0.00 0.00 10.38 8.38 8.38 8.38 0.000

-1000000 0.000 0.00 0.00 0.00 10.19 7.68 7.68 7.68 0.000

-1000000 0.000 0.00 0.00 0.00 10.00 7.03 7.03 7.03 0.000

-1000000 0.000 0.00 0.00 0.00 10.00 7.03 7.03 7.03 0.000

-1000000 0.000 0.00 0.00 0.00 10.00 7.03 7.03 7.03 0.000

-1000000 0.000 0.00 0.00 0.00 10.00 7.03 7.03 7.03 0.000

-1000000 0.000 0.00 0.00 0.00 10.00 7.03 7.03 7.03 0.000

-1000000 0.000 0.00 0.00 0.00 10.00 7.03 7.03 7.03 0.000

-1000000 0.000 0.00 0.00 0.00 9.88 6.63 6.63 6.63 0.000

-1000000 0.000 0.00 0.00 0.00 8.65 3.53 3.53 3.53 0.000

-1000000 0.000 0.00 0.00 0.00 7.48 1.78 1.78 1.78 0.000

-1000000 0.000 0.00 0.00 0.00 7.21 1.50 1.50 1.50 0.000

-1000000 0.000 0.00 0.00 0.00 6.95 1.26 1.26 1.26 0.000

-1000000 0.000 0.00 0.00 0.00 6.70 1.06 1.06 1.06 0.000

-1000000 0.000 0.00 0.00 0.00 6.45 0.89 0.89 0.89 0.000

-1000000 0.000 0.00 0.00 0.00 6.21 0.74 0.74 0.74 0.000

-1000000 0.000 0.00 0.00 0.00 5.97 0.62 0.62 0.62 0.000

-1000000 0.000 0.00 0.00 0.00 5.74 0.51 0.51 0.51 0.000

-1000000 0.000 0.00 0.00 0.00 5.53 0.43 0.43 0.43 0.000

-1000000 0.000 0.00

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Ca All Mat Mass Material (kg) 86.3648734 0.4 0.00 0.01 4.65 231 2.60617 0

Mass Element (kg) 1.86548127 0.5 0.01 0.0 4.95 231 2.60617 0.01 a

1.82949 1.0 0.02 0.0 5.25 231 2.60617 0.02 b

0.06821 1.0 0.03 0.1 5.55 231 2.60617 0.03 c

-0.47088 0.3 0.05 0.1 5.85 231 2.60617 0.05 d

3.67611 3.3 0.06 0.1 6.15 231 2.60617 0.05 e

0.02616 3.3 0.11 0.2 6.45 231 2.60617 0.09 f

-0.96191 8.0 0.17 0.3 6.75 231 2.60617 0.13 5.0 0.30 0.4 7.05 231 2.60617 0.22 5.0 0.38 0.5 7.35 231 2.60617 0.26 5.0 0.47 0.6 7.5 231 2.60617 0.31 10.0 0.55 0.7 7.5 231 2.60617 0.35 10.0 0.72 0.9 7.5 231 2.60617 0.43 10.0 0.88 1.1 7.5 231 2.60617 0.51 6.7 1.05 1.2 7.5 231 2.60617 0.59 30.0 1.16 1.7 7.5 228 2.61753 0.65 30.0 1.66 2.2 7.5 225 2.629 0.90 33.3 2.16 2.7 7.5 225 2.629 1.17 4.3 2.72 2.8 7.5 225 2.629 1.46 26.0 2.79 3.2 7.5 225 2.629 1.50 176.4 3.22 6.2 7.5 225 2.629 1.72 230.3 6.16 10.0 7.5 225 2.629 3.23 189.7 10.00 13.2 7.5 223 2.63671 5.12 720.0 13.16 25.2 7.5 202.5 2.71834 6.63 1370.3 25.16 48.0 7.5 181.5 2.80737 13.90 1440.0 48.00 72.0 7.5 176.5 2.82943 31.74 1440.0 72.00 96.0 7.5 171.5 2.85185 46.14 1440.0 96.00 120.0 7.5 166.5 2.87462 57.85 7200.0 120.00 240.0 7.5 161.5 2.89776 68.21 7200.0 240.00 360.0 7.5 156.5 2.92127 117.84 7200.0 360.00 480.0 7.5 151.5 2.94517 117.85 7200.0 480.00 600.0 7.5 146.5 2.96946 118.18 7200.0 600.00 720.0 7.5 142 2.99167 133.32

Ca this Mat Only Ca (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Ca released Integral kg Ca released 0

0.00 8.31 19.54 19.54 19.54 0.001

-2 0.001 0.00 0.00 0.00 8.71 19.89 19.89 19.89 0.001

-2 0.001 0.00 0.00 0.00 9.13 20.26 20.25 20.25 0.002

-2 0.002 0.00 0.00 0.00 9.57 20.63 20.62 20.62 0.002

-2 0.002 0.01 0.00 0.00 10.03 21.00 20.99 20.99 0.001

-2 0.001 0.01 0.00 0.00 10.51 21.38 21.38 21.38 0.006

-2 0.006 0.01 0.01 0.01 11.02 21.77 21.76 21.76 0.006

-2 0.006 0.02 0.01 0.01 11.55 22.17 22.15 22.15 0.015

-2 0.015 0.03 0.02 0.02 12.11 22.58 22.53 22.53 0.010

-2 0.010 0.04 0.03 0.03 12.70 22.99 22.94 22.94 0.010

-2 0.010 0.05 0.04 0.04 13.00 23.20 23.13 23.13 0.010

-2 0.010 0.06 0.04 0.04 13.00 23.20 23.12 23.12 0.020

-2 0.020 0.08 0.06 0.06 13.00 23.20 23.10 23.10 0.020

-2 0.020 0.10 0.07 0.07 13.00 23.20 23.07 23.07 0.020

-2 0.020 0.12 0.08 0.08 13.00 23.20 23.05 23.05 0.013

-2 0.013 0.14 0.09 0.09 12.84 22.62 22.46 22.46 0.058

-2 0.058 0.19 0.13 0.13 12.68 22.05 21.83 21.83 0.057

-2 0.057 0.25 0.17 0.17 12.68 22.05 21.76 21.76 0.063

-2 0.063 0.31 0.21 0.21 12.68 22.05 21.69 21.69 0.008

-2 0.008 0.32 0.22 0.22 12.68 22.05 21.68 21.68 0.049

-1 0.049 0.37 0.25 0.25 12.68 22.05 21.62 21.62 0.329

-1 0.329 0.70 0.47 0.47 12.68 22.05 21.24 21.24 0.422

-1 0.422 1.12 0.75 0.75 12.57 21.68 20.38 20.38 0.334 0

0.334 1.46 0.98 0.98 11.51 18.09 16.56 16.56 1.030 1

0.410 1.87 1.25 1.25 10.45 14.86 13.08 13.08 1.548 2

0.000 1.87 1.25 1.25 10.20 14.15 12.41 12.41 1.544 2

0.000 1.87 1.25 1.25 9.96 13.46 11.77 11.77 1.464 1

0.000 1.87 1.25 1.25 9.72 12.80 11.15 11.15 1.387 1

0.000 1.87 1.25 1.25 9.47 12.16 10.55 10.55 6.563 7

0.000 1.87 1.25 1.25 9.24 11.54 9.98 9.98 6.206 6

0.000 1.87 1.25 1.25 9.00 10.95 9.43 9.43 5.862 6

0.000 1.87 1.25 1.25 8.77 10.37 8.89 8.89 5.531 6

0.000 1.87 1.25 1.25 8.56 9.88 8.43 8.43 5.244 5

0.000 1.87

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Si All Mat Si this Mat Only Mass Material (kg) 86.364873 0.4 0.00 0.01 4.65 231 2.60617 0

0 Mass Element (kg) 16.936152 0.5 0.01 0.0 4.95 231 2.60617 0.02 0.00 a

5.20122 1.0 0.02 0.0 5.25 231 2.60617 0.04 0.00 b

0.10404 1.0 0.03 0.1 5.55 231 2.60617 0.09 0.00 c

-1.50553 0.3 0.05 0.1 5.85 231 2.60617 0.14 0.01 d

7.46511 3.3 0.06 0.1 6.15 231 2.60617 0.15 0.01 e

0.16247 3.3 0.11 0.2 6.45 231 2.60617 0.30 0.02 f

-2.55813 8.0 0.17 0.3 6.75 231 2.60617 0.45 0.03 5.0 0.30 0.4 7.05 231 2.60617 0.80 0.07 5.0 0.38 0.5 7.35 231 2.60617 1.01 0.10 5.0 0.47 0.6 7.5 231 2.60617 1.23 0.12 10.0 0.55 0.7 7.5 231 2.60617 1.44 0.15 10.0 0.72 0.9 7.5 231 2.60617 1.86 0.21 10.0 0.88 1.1 7.5 231 2.60617 2.28 0.27 6.7 1.05 1.2 7.5 231 2.60617 2.70 0.33 30.0 1.16 1.7 7.5 228 2.61753 2.98 0.37 30.0 1.66 2.2 7.5 225 2.629 4.17 0.54 33.3 2.16 2.7 7.5 225 2.629 5.29 0.70 4.3 2.72 2.8 7.5 225 2.629 6.53 0.87 26.0 2.79 3.2 7.5 225 2.629 6.69 0.90 176.4 3.22 6.2 7.5 225 2.629 7.65 1.03 230.3 6.16 10.0 7.5 225 2.629 14.13 1.95 189.7 10.00 13.2 7.5 223 2.63671 22.35 3.14 720.0 13.16 25.2 7.5 202.5 2.71834 28.64 4.06 1370.3 25.16 48.0 7.5 181.5 2.80737 44.47 6.18 1440.0 48.00 72.0 7.5 176.5 2.82943 63.16 8.43 1440.0 72.00 96.0 7.5 171.5 2.85185 79.58 10.38 1440.0 96.00 120.0 7.5 166.5 2.87462 92.78 11.35 7200.0 120.00 240.0 7.5 161.5 2.89776 103.23 11.35 7200.0 240.00 360.0 7.5 156.5 2.92127 103.59 11.35 7200.0 360.00 480.0 7.5 151.5 2.94517 103.60 11.35 7200.0 480.00 600.0 7.5 146.5 2.96946 103.60 11.35 7200.0 600.00 720.0 7.5 142 2.99167 103.60 11.35

Si (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Si released Integral kg Si released 0.00 57.72 35.78 35.78 35.78 0.001

-17 0.001 0.00 0.00 62.02 40.03 40.03 40.03 0.002

-17 0.002 0.00 0.00 66.65 44.79 44.79 44.79 0.004

-17 0.004 0.01 0.00 71.61 50.11 50.11 50.11 0.004

-17 0.004 0.01 0.01 76.95 56.06 56.05 56.05 0.002

-17 0.002 0.01 0.01 82.68 62.72 62.71 62.71 0.018

-17 0.018 0.03 0.02 88.84 70.17 70.15 70.15 0.020

-17 0.020 0.05 0.03 95.46 78.50 78.47 78.47 0.054

-17 0.054 0.11 0.07 102.58 87.82 87.76 87.76 0.038

-17 0.038 0.14 0.10 110.22 98.26 98.17 98.17 0.042

-17 0.042 0.19 0.12 114.25 103.93 103.81 103.81 0.045

-17 0.045 0.23 0.15 114.25 103.93 103.79 103.79 0.090

-17 0.090 0.32 0.21 114.25 103.93 103.73 103.73 0.090

-17 0.090 0.41 0.27 114.25 103.93 103.68 103.68 0.090

-16 0.090 0.50 0.33 114.25 103.93 103.62 103.62 0.060

-16 0.060 0.56 0.37 109.84 97.19 96.86 96.86 0.251

-16 0.251 0.81 0.54 105.55 90.85 90.38 90.38 0.234

-16 0.234 1.04 0.70 105.55 90.85 90.24 90.24 0.260

-16 0.260 1.30 0.87 105.55 90.85 90.09 90.09 0.033

-16 0.033 1.34 0.90 105.55 90.85 90.07 90.07 0.203

-15 0.203 1.54 1.03 105.55 90.85 89.96 89.96 1.370

-14 1.370 2.91 1.95 105.55 90.85 89.17 89.17 1.774

-12 1.774 4.68 3.14 102.77 86.82 84.16 84.16 1.379

-11 1.379 6.06 4.06 77.44 53.68 50.86 50.86 3.163

-8 3.163 9.22 6.18 56.88 31.77 28.32 28.32 3.351

-4 3.351 12.58 8.43 52.69 27.90 23.43 23.43 2.914

-1 2.914 15.49 10.38 48.75 24.45 19.24 19.24 2.393 1

1.446 16.94 11.35 45.05 21.38 15.99 15.99 1.989 2

0.000 16.94 11.35 41.58 18.65 13.56 13.56 8.433 8

0.000 16.94 11.35 38.32 16.24 11.43 11.43 7.108 7

0.000 16.94 11.35 35.28 14.11 9.57 9.57 5.950 6

0.000 16.94 11.35 32.43 12.23 7.95 7.95 4.941 5

0.000 16.94 11.35 30.02 10.73 6.67 6.67 4.149 4

0.000 16.94

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Al All Mat Mass Material (kg) 86.3648734 0.4 0.00 0.01 4.65 231 2.60617 0

Mass Element (kg) 1.68411503 0.5 0.01 0.0 4.95 231 2.60617 0.00 a

3.72351 1.0 0.02 0.0 5.25 231 2.60617 0.00 b

0.14041 1.0 0.03 0.1 5.55 231 2.60617 0.00 c

-1.69396 0.3 0.05 0.1 5.85 231 2.60617 0.01 d

10.35371 3.3 0.06 0.1 6.15 231 2.60617 0.01 e

0.17064 3.3 0.11 0.2 6.45 231 2.60617 0.01 f

-4.17804 8.0 0.17 0.3 6.75 231 2.60617 0.02 5.0 0.30 0.4 7.05 231 2.60617 0.04 5.0 0.38 0.5 7.35 231 2.60617 0.05 5.0 0.47 0.6 7.5 231 2.60617 0.07 10.0 0.55 0.7 7.5 231 2.60617 0.09 10.0 0.72 0.9 7.5 231 2.60617 0.12 10.0 0.88 1.1 7.5 231 2.60617 0.16 6.7 1.05 1.2 7.5 231 2.60617 0.19 30.0 1.16 1.7 7.5 228 2.61753 0.23 30.0 1.66 2.2 7.5 225 2.629 0.64 33.3 2.16 2.7 7.5 225 2.629 1.01 4.3 2.72 2.8 7.5 225 2.629 1.36 26.0 2.79 3.2 7.5 225 2.629 1.40 176.4 3.22 6.2 7.5 225 2.629 1.61 230.3 6.16 10.0 7.5 225 2.629 2.88 189.7 10.00 13.2 7.5 223 2.63671 4.35 720.0 13.16 25.2 7.5 202.5 2.71834 4.82 1370.3 25.16 48.0 7.5 181.5 2.80737 5.75 1440.0 48.00 72.0 7.5 176.5 2.82943 6.59 1440.0 72.00 96.0 7.5 171.5 2.85185 7.34 1440.0 96.00 120.0 7.5 166.5 2.87462 7.95 7200.0 120.00 240.0 7.5 161.5 2.89776 8.46 7200.0 240.00 360.0 7.5 156.5 2.92127 10.54 7200.0 360.00 480.0 7.5 151.5 2.94517 12.24 7200.0 480.00 600.0 7.5 146.5 2.96946 13.62 7200.0 600.00 720.0 7.5 142 2.99167 14.73

Al this Mat Only Al (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Al released Integral kg Al released 0

0.00 0.92 1.81 1.81 1.81 0.000

-2 0.000 0.000 0.00 0.00 1.01 2.04 2.04 2.04 0.000

-2 0.000 0.000 0.00 0.00 1.11 2.30 2.30 2.30 0.000

-2 0.000 0.000 0.00 0.00 1.22 2.58 2.58 2.58 0.000

-2 0.000 0.001 0.00 0.00 1.35 2.91 2.91 2.91 0.000

-2 0.000 0.001 0.00 0.00 1.49 3.27 3.27 3.27 0.001

-2 0.001 0.002 0.00 0.00 1.64 3.68 3.68 3.68 0.001

-2 0.001 0.003 0.00 0.00 1.81 4.14 4.13 4.13 0.003

-2 0.003 0.006 0.00 0.00 1.99 4.66 4.65 4.65 0.002

-2 0.002 0.008 0.01 0.01 2.19 5.24 5.23 5.23 0.002

-2 0.002 0.010 0.01 0.01 2.30 5.56 5.54 5.54 0.002

-2 0.002 0.012 0.01 0.01 2.30 5.56 5.54 5.54 0.005

-2 0.005 0.017 0.01 0.01 2.30 5.56 5.53 5.53 0.005

-2 0.005 0.022 0.01 0.01 2.30 5.56 5.52 5.52 0.005

-2 0.005 0.026 0.02 0.02 2.30 5.56 5.51 5.51 0.003

-2 0.003 0.030 0.02 0.02 2.20 4.98 4.94 4.94 0.013

-2 0.013 0.042 0.03 0.03 2.10 4.46 4.40 4.40 0.011

-2 0.011 0.054 0.04 0.04 2.10 4.46 4.38 4.38 0.013

-2 0.013 0.066 0.04 0.04 2.10 4.46 4.37 4.37 0.002

-2 0.002 0.068 0.05 0.05 2.10 4.46 4.36 4.36 0.010

-2 0.010 0.078 0.05 0.05 2.10 4.46 4.35 4.35 0.066

-2 0.066 0.144 0.10 0.10 2.10 4.46 4.26 4.26 0.085

-1 0.085 0.229 0.15 0.15 2.04 4.14 3.83 3.83 0.063

-1 0.063 0.292 0.20 0.20 1.49 1.89 1.64 1.64 0.102

-1 0.102 0.394 0.26 0.26 1.05 0.80 0.60 0.60 0.071

-1 0.071 0.465 0.31 0.31 0.96 0.65 0.44 0.44 0.055

-1 0.055 0.519 0.35 0.35 0.88 0.52 0.32 0.32 0.039

-1 0.039 0.559 0.37 0.37 0.81 0.42 0.23 0.23 0.028

-1 0.028 0.587 0.39 0.39 0.74 0.34 0.16 0.16 0.098

-1 0.098 0.684 0.46 0.46 0.67 0.27 0.09 0.09 0.053

-1 0.053 0.737 0.49 0.49 0.61 0.21 0.04 0.04 0.026

-1 0.026 0.763 0.51 0.51 0.56 0.17 0.01 0.01 0.009

-1 0.009 0.772 0.52 0.52 0.51 0.14 0.00 0.00 0.000

-1 0.000 0.772

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Si All Mat Si this Mat Only Mass Material (kg) 0 0.4 0.00 0.01 4.65 231 2.60617 0

0 Mass Element (kg) 0 0.5 0.01 0.0 4.95 231 2.60617 0.02 0.00 a

1.17043 1.0 0.02 0.0 5.25 231 2.60617 0.04 0.00 b

0.10511 1.0 0.03 0.1 5.55 231 2.60617 0.09 0.00 c

-0.07315 0.3 0.05 0.1 5.85 231 2.60617 0.14 0.00 d

7.41106 3.3 0.06 0.1 6.15 231 2.60617 0.15 0.00 e

0.17893 3.3 0.11 0.2 6.45 231 2.60617 0.30 0.00 f

-1.93332 8.0 0.17 0.3 6.75 231 2.60617 0.45 0.00 5.0 0.30 0.4 7.05 231 2.60617 0.80 0.00 5.0 0.38 0.5 7.35 231 2.60617 1.01 0.00 5.0 0.47 0.6 7.5 231 2.60617 1.23 0.00 10.0 0.55 0.7 7.5 231 2.60617 1.44 0.00 10.0 0.72 0.9 7.5 231 2.60617 1.86 0.00 10.0 0.88 1.1 7.5 231 2.60617 2.28 0.00 6.7 1.05 1.2 7.5 231 2.60617 2.70 0.00 30.0 1.16 1.7 7.5 228 2.61753 2.98 0.00 30.0 1.66 2.2 7.5 225 2.629 4.17 0.00 33.3 2.16 2.7 7.5 225 2.629 5.29 0.00 4.3 2.72 2.8 7.5 225 2.629 6.53 0.00 26.0 2.79 3.2 7.5 225 2.629 6.69 0.00 176.4 3.22 6.2 7.5 225 2.629 7.65 0.00 230.3 6.16 10.0 7.5 225 2.629 14.13 0.00 189.7 10.00 13.2 7.5 223 2.63671 22.35 0.00 720.0 13.16 25.2 7.5 202.5 2.71834 28.64 0.00 1370.3 25.16 48.0 7.5 181.5 2.80737 44.47 0.00 1440.0 48.00 72.0 7.5 176.5 2.82943 63.16 0.00 1440.0 72.00 96.0 7.5 171.5 2.85185 79.58 0.00 1440.0 96.00 120.0 7.5 166.5 2.87462 92.78 0.00 7200.0 120.00 240.0 7.5 161.5 2.89776 103.23 0.00 7200.0 240.00 360.0 7.5 156.5 2.92127 103.59 0.00 7200.0 360.00 480.0 7.5 151.5 2.94517 103.60 0.00 7200.0 480.00 600.0 7.5 146.5 2.96946 103.60 0.00 7200.0 600.00 720.0 7.5 142 2.99167 103.60 0.00

Si (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Si released Integral kg Si released 0.00 29.41 1601.52 1601.52 1601.52 0.000 0

0.000 0.000 0.00 31.63 1812.23 1812.23 1812.23 0.000 0

0.000 0.000 0.00 34.01 2050.65 2050.65 2050.65 0.000 0

0.000 0.000 0.00 36.57 2320.44 2320.44 2320.44 0.000 0

0.000 0.000 0.00 39.33 2625.73 2625.73 2625.73 0.000 0

0.000 0.000 0.00 42.29 2971.18 2971.18 2971.18 0.000 0

0.000 0.000 0.00 45.47 3362.08 3362.08 3362.08 0.000 0

0.000 0.000 0.00 48.90 3804.40 3804.40 3804.40 0.000 0

0.000 0.000 0.00 52.58 4304.92 4304.92 4304.92 0.000 0

0.000 0.000 0.00 56.54 4871.30 4871.30 4871.30 0.000 0

0.000 0.000 0.00 58.63 5181.84 5181.84 5181.84 0.000 0

0.000 0.000 0.00 58.63 5181.84 5181.84 5181.84 0.000 0

0.000 0.000 0.00 58.63 5181.84 5181.84 5181.84 0.000 0

0.000 0.000 0.00 58.63 5181.84 5181.84 5181.84 0.000 0

0.000 0.000 0.00 58.63 5181.84 5181.84 5181.84 0.000 0

0.000 0.000 0.00 58.52 4926.10 4926.10 4926.10 0.000 0

0.000 0.000 0.00 58.40 4680.90 4680.90 4680.90 0.000 0

0.000 0.000 0.00 58.40 4680.90 4680.90 4680.90 0.000 0

0.000 0.000 0.00 58.40 4680.90 4680.90 4680.90 0.000 0

0.000 0.000 0.00 58.40 4680.90 4680.90 4680.90 0.000 0

0.000 0.000 0.00 58.40 4680.90 4680.90 4680.90 0.000 0

0.000 0.000 0.00 58.40 4680.90 4680.90 4680.90 0.000 0

0.000 0.000 0.00 58.33 4523.13 4523.13 4523.13 0.000 0

0.000 0.000 0.00 57.53 3145.02 3145.02 3145.02 0.000 0

0.000 0.000 0.00 56.68 2115.90 2115.90 2115.90 0.000 0

0.000 0.000 0.00 56.47 1917.95 1917.95 1917.95 0.000 0

0.000 0.000 0.00 56.25 1735.81 1735.81 1735.81 0.000 0

0.000 0.000 0.00 56.04 1568.47 1568.47 1568.47 0.000 0

0.000 0.000 0.00 55.82 1414.95 1414.95 1414.95 0.000 0

0.000 0.000 0.00 55.60 1274.33 1274.33 1274.33 0.000 0

0.000 0.000 0.00 55.38 1145.72 1145.72 1145.72 0.000 0

0.000 0.000 0.00 55.15 1028.28 1028.28 1028.28 0.000 0

0.000 0.000 0.00 54.94 931.48 931.48 931.48 0.000 0

0.000 0.000

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Al All Mat Mass Material (kg) 0 0.4 0.00 0.01 4.65 231 2.60617 0

Mass Element (kg) 0 0.5 0.01 0.0 4.95 231 2.60617 0.00 a

5.529 1.0 0.02 0.0 5.25 231 2.60617 0.00 b

0.2401 1.0 0.03 0.1 5.55 231 2.60617 0.00 c

-2.51326 0.3 0.05 0.1 5.85 231 2.60617 0.01 d

8.48062 3.3 0.06 0.1 6.15 231 2.60617 0.01 e

0.20749 3.3 0.11 0.2 6.45 231 2.60617 0.01 f

-3.32039 8.0 0.17 0.3 6.75 231 2.60617 0.02 5.0 0.30 0.4 7.05 231 2.60617 0.04 5.0 0.38 0.5 7.35 231 2.60617 0.05 5.0 0.47 0.6 7.5 231 2.60617 0.07 10.0 0.55 0.7 7.5 231 2.60617 0.09 10.0 0.72 0.9 7.5 231 2.60617 0.12 10.0 0.88 1.1 7.5 231 2.60617 0.16 6.7 1.05 1.2 7.5 231 2.60617 0.19 30.0 1.16 1.7 7.5 228 2.61753 0.23 30.0 1.66 2.2 7.5 225 2.629 0.64 33.3 2.16 2.7 7.5 225 2.629 1.01 4.3 2.72 2.8 7.5 225 2.629 1.36 26.0 2.79 3.2 7.5 225 2.629 1.40 176.4 3.22 6.2 7.5 225 2.629 1.61 230.3 6.16 10.0 7.5 225 2.629 2.88 189.7 10.00 13.2 7.5 223 2.63671 4.35 720.0 13.16 25.2 7.5 202.5 2.71834 4.82 1370.3 25.16 48.0 7.5 181.5 2.80737 5.75 1440.0 48.00 72.0 7.5 176.5 2.82943 6.59 1440.0 72.00 96.0 7.5 171.5 2.85185 7.34 1440.0 96.00 120.0 7.5 166.5 2.87462 7.95 7200.0 120.00 240.0 7.5 161.5 2.89776 8.46 7200.0 240.00 360.0 7.5 156.5 2.92127 10.54 7200.0 360.00 480.0 7.5 151.5 2.94517 12.24 7200.0 480.00 600.0 7.5 146.5 2.96946 13.62 7200.0 600.00 720.0 7.5 142 2.99167 14.73

Al this Mat Only Al (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Al released Integral kg Al released 0

0.00 1.25 6.19 6.19 6.19 0.000 0

0.000 0.000 0.00 0.00 1.47 7.15 7.15 7.15 0.000 0

0.000 0.000 0.00 0.00 1.74 8.25 8.25 8.25 0.000 0

0.000 0.000 0.00 0.00 2.05 9.52 9.52 9.52 0.000 0

0.000 0.000 0.00 0.00 2.42 10.99 10.99 10.99 0.000 0

0.000 0.000 0.00 0.00 2.86 12.68 12.68 12.68 0.000 0

0.000 0.000 0.00 0.00 3.37 14.64 14.64 14.64 0.000 0

0.000 0.000 0.00 0.00 3.98 16.89 16.89 16.89 0.000 0

0.000 0.000 0.00 0.00 4.70 19.50 19.50 19.50 0.000 0

0.000 0.000 0.00 0.00 5.54 22.50 22.50 22.50 0.000 0

0.000 0.000 0.00 0.00 6.02 24.17 24.17 24.17 0.000 0

0.000 0.000 0.00 0.00 6.02 24.17 24.17 24.17 0.000 0

0.000 0.000 0.00 0.00 6.02 24.17 24.17 24.17 0.000 0

0.000 0.000 0.00 0.00 6.02 24.17 24.17 24.17 0.000 0

0.000 0.000 0.00 0.00 6.02 24.17 24.17 24.17 0.000 0

0.000 0.000 0.00 0.00 5.64 22.16 22.16 22.16 0.000 0

0.000 0.000 0.00 0.00 5.28 20.30 20.30 20.30 0.000 0

0.000 0.000 0.00 0.00 5.28 20.30 20.30 20.30 0.000 0

0.000 0.000 0.00 0.00 5.28 20.30 20.30 20.30 0.000 0

0.000 0.000 0.00 0.00 5.28 20.30 20.30 20.30 0.000 0

0.000 0.000 0.00 0.00 5.28 20.30 20.30 20.30 0.000 0

0.000 0.000 0.00 0.00 5.28 20.30 20.30 20.30 0.000 0

0.000 0.000 0.00 0.00 5.05 19.14 19.14 19.14 0.000 0

0.000 0.000 0.00 0.00 3.15 10.25 10.25 10.25 0.000 0

0.000 0.000 0.00 0.00 1.88 5.19 5.19 5.19 0.000 0

0.000 0.000 0.00 0.00 1.65 4.39 4.39 4.39 0.000 0

0.000 0.000 0.00 0.00 1.45 3.69 3.69 3.69 0.000 0

0.000 0.000 0.00 0.00 1.27 3.10 3.10 3.10 0.000 0

0.000 0.000 0.00 0.00 1.11 2.60 2.60 2.60 0.000 0

0.000 0.000 0.00 0.00 0.97 2.17 2.17 2.17 0.000 0

0.000 0.000 0.00 0.00 0.85 1.81 1.81 1.81 0.000 0

0.000 0.000 0.00 0.00 0.74 1.50 1.50 1.50 0.000 0

0.000 0.000 0.00 0.00 0.65 1.27 1.27 1.27 0.000 0

0.000 0.000

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Si All Mat Si this Mat Only Mass Material (kg) 0 0.4 0.00 0.01 4.65 231 2.60617 0

0 Mass Element (kg) 0 0.5 0.01 0.0 4.95 231 2.60617 0.02 0.00 a

7.51336 1.0 0.02 0.0 5.25 231 2.60617 0.04 0.00 b

0.18619 1.0 0.03 0.1 5.55 231 2.60617 0.09 0.00 c

-2.89181 0.3 0.05 0.1 5.85 231 2.60617 0.14 0.00 d

7.17588 3.3 0.06 0.1 6.15 231 2.60617 0.15 0.00 e

0.11502 3.3 0.11 0.2 6.45 231 2.60617 0.30 0.00 f

-2.42532 8.0 0.17 0.3 6.75 231 2.60617 0.45 0.00 5.0 0.30 0.4 7.05 231 2.60617 0.80 0.00 5.0 0.38 0.5 7.35 231 2.60617 1.01 0.00 5.0 0.47 0.6 7.5 231 2.60617 1.23 0.00 10.0 0.55 0.7 7.5 231 2.60617 1.44 0.00 10.0 0.72 0.9 7.5 231 2.60617 1.86 0.00 10.0 0.88 1.1 7.5 231 2.60617 2.28 0.00 6.7 1.05 1.2 7.5 231 2.60617 2.70 0.00 30.0 1.16 1.7 7.5 228 2.61753 2.98 0.00 30.0 1.66 2.2 7.5 225 2.629 4.17 0.00 33.3 2.16 2.7 7.5 225 2.629 5.29 0.00 4.3 2.72 2.8 7.5 225 2.629 6.53 0.00 26.0 2.79 3.2 7.5 225 2.629 6.69 0.00 176.4 3.22 6.2 7.5 225 2.629 7.65 0.00 230.3 6.16 10.0 7.5 225 2.629 14.13 0.00 189.7 10.00 13.2 7.5 223 2.63671 22.35 0.00 720.0 13.16 25.2 7.5 202.5 2.71834 28.64 0.00 1370.3 25.16 48.0 7.5 181.5 2.80737 44.47 0.00 1440.0 48.00 72.0 7.5 176.5 2.82943 63.16 0.00 1440.0 72.00 96.0 7.5 171.5 2.85185 79.58 0.00 1440.0 96.00 120.0 7.5 166.5 2.87462 92.78 0.00 7200.0 120.00 240.0 7.5 161.5 2.89776 103.23 0.00 7200.0 240.00 360.0 7.5 156.5 2.92127 103.59 0.00 7200.0 360.00 480.0 7.5 151.5 2.94517 103.60 0.00 7200.0 480.00 600.0 7.5 146.5 2.96946 103.60 0.00 7200.0 600.00 720.0 7.5 142 2.99167 103.60 0.00

Si (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Si released Integral kg Si released 0.00 6.96 24.54 24.54 24.54 0.000 0

0.000 0.000 0.00 7.92 26.57 26.57 26.57 0.000 0

0.000 0.000 0.00 9.00 28.77 28.77 28.77 0.000 0

0.000 0.000 0.00 10.24 31.15 31.15 31.15 0.000 0

0.000 0.000 0.00 11.64 33.73 33.73 33.73 0.000 0

0.000 0.000 0.00 13.24 36.51 36.51 36.51 0.000 0

0.000 0.000 0.00 15.06 39.53 39.53 39.53 0.000 0

0.000 0.000 0.00 17.12 42.80 42.80 42.80 0.000 0

0.000 0.000 0.00 19.47 46.34 46.34 46.34 0.000 0

0.000 0.000 0.00 22.15 50.18 50.18 50.18 0.000 0

0.000 0.000 0.00 23.62 52.21 52.21 52.21 0.000 0

0.000 0.000 0.00 23.62 52.21 52.21 52.21 0.000 0

0.000 0.000 0.00 23.62 52.21 52.21 52.21 0.000 0

0.000 0.000 0.00 23.62 52.21 52.21 52.21 0.000 0

0.000 0.000 0.00 23.62 52.21 52.21 52.21 0.000 0

0.000 0.000 0.00 21.90 49.00 49.00 49.00 0.000 0

0.000 0.000 0.00 20.29 45.96 45.96 45.96 0.000 0

0.000 0.000 0.00 20.29 45.96 45.96 45.96 0.000 0

0.000 0.000 0.00 20.29 45.96 45.96 45.96 0.000 0

0.000 0.000 0.00 20.29 45.96 45.96 45.96 0.000 0

0.000 0.000 0.00 20.29 45.96 45.96 45.96 0.000 0

0.000 0.000 0.00 20.29 45.96 45.96 45.96 0.000 0

0.000 0.000 0.00 19.27 44.02 44.02 44.02 0.000 0

0.000 0.000 0.00 11.19 27.91 27.91 27.91 0.000 0

0.000 0.000 0.00 6.19 16.97 16.97 16.97 0.000 0

0.000 0.000 0.00 5.34 15.01 15.01 15.01 0.000 0

0.000 0.000 0.00 4.60 13.24 13.24 13.24 0.000 0

0.000 0.000 0.00 3.95 11.66 11.66 11.66 0.000 0

0.000 0.000 0.00 3.39 10.25 10.25 10.25 0.000 0

0.000 0.000 0.00 2.90 8.98 8.98 8.98 0.000 0

0.000 0.000 0.00 2.47 7.86 7.86 7.86 0.000 0

0.000 0.000 0.00 2.10 6.86 6.86 6.86 0.000 0

0.000 0.000 0.00 1.81 6.06 6.06 6.06 0.000 0

0.000 0.000

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Ca All Mat Mass Material (kg) 0 0.4 0.00 0.01 4.65 231 2.60617 0

Mass Element (kg) 0 0.5 0.01 0.0 4.95 231 2.60617 0.01 a

2.30159 1.0 0.02 0.0 5.25 231 2.60617 0.02 b

0.12022 1.0 0.03 0.1 5.55 231 2.60617 0.03 c

-0.82549 0.3 0.05 0.1 5.85 231 2.60617 0.05 d

1.98549 3.3 0.06 0.1 6.15 231 2.60617 0.05 e

0.09009 3.3 0.11 0.2 6.45 231 2.60617 0.09 f

-0.52443 8.0 0.17 0.3 6.75 231 2.60617 0.13 5.0 0.30 0.4 7.05 231 2.60617 0.22 5.0 0.38 0.5 7.35 231 2.60617 0.26 5.0 0.47 0.6 7.5 231 2.60617 0.31 10.0 0.55 0.7 7.5 231 2.60617 0.35 10.0 0.72 0.9 7.5 231 2.60617 0.43 10.0 0.88 1.1 7.5 231 2.60617 0.51 6.7 1.05 1.2 7.5 231 2.60617 0.59 30.0 1.16 1.7 7.5 228 2.61753 0.65 30.0 1.66 2.2 7.5 225 2.629 0.90 33.3 2.16 2.7 7.5 225 2.629 1.17 4.3 2.72 2.8 7.5 225 2.629 1.46 26.0 2.79 3.2 7.5 225 2.629 1.50 176.4 3.22 6.2 7.5 225 2.629 1.72 230.3 6.16 10.0 7.5 225 2.629 3.23 189.7 10.00 13.2 7.5 223 2.63671 5.12 720.0 13.16 25.2 7.5 202.5 2.71834 6.63 1370.3 25.16 48.0 7.5 181.5 2.80737 13.90 1440.0 48.00 72.0 7.5 176.5 2.82943 31.74 1440.0 72.00 96.0 7.5 171.5 2.85185 46.14 1440.0 96.00 120.0 7.5 166.5 2.87462 57.85 7200.0 120.00 240.0 7.5 161.5 2.89776 68.21 7200.0 240.00 360.0 7.5 156.5 2.92127 117.84 7200.0 360.00 480.0 7.5 151.5 2.94517 117.85 7200.0 480.00 600.0 7.5 146.5 2.96946 118.18 7200.0 600.00 720.0 7.5 142 2.99167 133.32

Ca this Mat Only Ca (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Ca released Integral kg Ca released 0

0.00 5.12 10.91 10.91 10.91 0.000 0

0.000 0.000 0.00 0.00 5.56 11.61 11.61 11.61 0.000 0

0.000 0.000 0.00 0.00 6.04 12.35 12.35 12.35 0.000 0

0.000 0.000 0.00 0.00 6.57 13.14 13.14 13.14 0.000 0

0.000 0.000 0.00 0.00 7.14 13.99 13.99 13.99 0.000 0

0.000 0.000 0.00 0.00 7.75 14.89 14.89 14.89 0.000 0

0.000 0.000 0.00 0.00 8.43 15.84 15.84 15.84 0.000 0

0.000 0.000 0.00 0.00 9.16 16.86 16.86 16.86 0.000 0

0.000 0.000 0.00 0.00 9.95 17.94 17.94 17.94 0.000 0

0.000 0.000 0.00 0.00 10.81 19.09 19.09 19.09 0.000 0

0.000 0.000 0.00 0.00 11.27 19.70 19.70 19.70 0.000 0

0.000 0.000 0.00 0.00 11.27 19.70 19.70 19.70 0.000 0

0.000 0.000 0.00 0.00 11.27 19.70 19.70 19.70 0.000 0

0.000 0.000 0.00 0.00 11.27 19.70 19.70 19.70 0.000 0

0.000 0.000 0.00 0.00 11.27 19.70 19.70 19.70 0.000 0

0.000 0.000 0.00 0.00 11.03 19.43 19.43 19.43 0.000 0

0.000 0.000 0.00 0.00 10.79 19.16 19.16 19.16 0.000 0

0.000 0.000 0.00 0.00 10.79 19.16 19.16 19.16 0.000 0

0.000 0.000 0.00 0.00 10.79 19.16 19.16 19.16 0.000 0

0.000 0.000 0.00 0.00 10.79 19.16 19.16 19.16 0.000 0

0.000 0.000 0.00 0.00 10.79 19.16 19.16 19.16 0.000 0

0.000 0.000 0.00 0.00 10.79 19.16 19.16 19.16 0.000 0

0.000 0.000 0.00 0.00 10.63 18.98 18.98 18.98 0.000 0

0.000 0.000 0.00 0.00 9.11 17.20 17.20 17.20 0.000 0

0.000 0.000 0.00 0.00 7.69 15.45 15.45 15.45 0.000 0

0.000 0.000 0.00 0.00 7.37 15.04 15.04 15.04 0.000 0

0.000 0.000 0.00 0.00 7.06 14.64 14.64 14.64 0.000 0

0.000 0.000 0.00 0.00 6.77 14.24 14.24 14.24 0.000 0

0.000 0.000 0.00 0.00 6.47 13.85 13.85 13.85 0.000 0

0.000 0.000 0.00 0.00 6.19 13.46 13.46 13.46 0.000 0

0.000 0.000 0.00 0.00 5.92 13.08 13.08 13.08 0.000 0

0.000 0.000 0.00 0.00 5.65 12.70 12.70 12.70 0.000 0

0.000 0.000 0.00 0.00 5.42 12.37 12.37 12.37 0.000 0

0.000 0.000

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Al All Mat Mass Material (kg) 0 0.4 0.00 0.01 4.65 231 2.60617 0

Mass Element (kg) 0 0.5 0.01 0.0 4.95 231 2.60617 0.00 a

8.96613 1.0 0.02 0.0 5.25 231 2.60617 0.00 b

0.10871 1.0 0.03 0.1 5.55 231 2.60617 0.00 c

-2.372 0.3 0.05 0.1 5.85 231 2.60617 0.01 d

6.629 3.3 0.06 0.1 6.15 231 2.60617 0.01 e

0.13222 3.3 0.11 0.2 6.45 231 2.60617 0.01 f

-2.57256 8.0 0.17 0.3 6.75 231 2.60617 0.02 5.0 0.30 0.4 7.05 231 2.60617 0.04 5.0 0.38 0.5 7.35 231 2.60617 0.05 5.0 0.47 0.6 7.5 231 2.60617 0.07 10.0 0.55 0.7 7.5 231 2.60617 0.09 10.0 0.72 0.9 7.5 231 2.60617 0.12 10.0 0.88 1.1 7.5 231 2.60617 0.16 6.7 1.05 1.2 7.5 231 2.60617 0.19 30.0 1.16 1.7 7.5 228 2.61753 0.23 30.0 1.66 2.2 7.5 225 2.629 0.64 33.3 2.16 2.7 7.5 225 2.629 1.01 4.3 2.72 2.8 7.5 225 2.629 1.36 26.0 2.79 3.2 7.5 225 2.629 1.40 176.4 3.22 6.2 7.5 225 2.629 1.61 230.3 6.16 10.0 7.5 225 2.629 2.88 189.7 10.00 13.2 7.5 223 2.63671 4.35 720.0 13.16 25.2 7.5 202.5 2.71834 4.82 1370.3 25.16 48.0 7.5 181.5 2.80737 5.75 1440.0 48.00 72.0 7.5 176.5 2.82943 6.59 1440.0 72.00 96.0 7.5 171.5 2.85185 7.34 1440.0 96.00 120.0 7.5 166.5 2.87462 7.95 7200.0 120.00 240.0 7.5 161.5 2.89776 8.46 7200.0 240.00 360.0 7.5 156.5 2.92127 10.54 7200.0 360.00 480.0 7.5 151.5 2.94517 12.24 7200.0 480.00 600.0 7.5 146.5 2.96946 13.62 7200.0 600.00 720.0 7.5 142 2.99167 14.73

Al this Mat Only Al (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Al released Integral kg Al released 0

0.00 1948.98 3.46 3.46 3.46 0.000 0

0.000 0.000 0.00 0.00 2100.98 3.79 3.79 3.79 0.000 0

0.000 0.000 0.00 0.00 2264.82 4.16 4.16 4.16 0.000 0

0.000 0.000 0.00 0.00 2441.45 4.55 4.55 4.55 0.000 0

0.000 0.000 0.00 0.00 2631.84 4.99 4.99 4.99 0.000 0

0.000 0.000 0.00 0.00 2837.09 5.47 5.47 5.47 0.000 0

0.000 0.000 0.00 0.00 3058.34 5.99 5.99 5.99 0.000 0

0.000 0.000 0.00 0.00 3296.85 6.56 6.56 6.56 0.000 0

0.000 0.000 0.00 0.00 3553.96 7.19 7.19 7.19 0.000 0

0.000 0.000 0.00 0.00 3831.11 7.88 7.88 7.88 0.000 0

0.000 0.000 0.00 0.00 3977.70 8.24 8.24 8.24 0.000 0

0.000 0.000 0.00 0.00 3977.70 8.24 8.24 8.24 0.000 0

0.000 0.000 0.00 0.00 3977.70 8.24 8.24 8.24 0.000 0

0.000 0.000 0.00 0.00 3977.70 8.24 8.24 8.24 0.000 0

0.000 0.000 0.00 0.00 3977.70 8.24 8.24 8.24 0.000 0

0.000 0.000 0.00 0.00 3738.20 7.71 7.71 7.71 0.000 0

0.000 0.000 0.00 0.00 3511.22 7.20 7.20 7.20 0.000 0

0.000 0.000 0.00 0.00 3511.22 7.20 7.20 7.20 0.000 0

0.000 0.000 0.00 0.00 3511.22 7.20 7.20 7.20 0.000 0

0.000 0.000 0.00 0.00 3511.22 7.20 7.20 7.20 0.000 0

0.000 0.000 0.00 0.00 3511.22 7.20 7.20 7.20 0.000 0

0.000 0.000 0.00 0.00 3511.22 7.20 7.20 7.20 0.000 0

0.000 0.000 0.00 0.00 3366.58 6.88 6.88 6.88 0.000 0

0.000 0.000 0.00 0.00 2155.58 4.24 4.24 4.24 0.000 0

0.000 0.000 0.00 0.00 1325.50 2.50 2.50 2.50 0.000 0

0.000 0.000 0.00 0.00 1175.01 2.20 2.20 2.20 0.000 0

0.000 0.000 0.00 0.00 1039.62 1.92 1.92 1.92 0.000 0

0.000 0.000 0.00 0.00 918.04 1.68 1.68 1.68 0.000 0

0.000 0.000 0.00 0.00 809.05 1.47 1.47 1.47 0.000 0

0.000 0.000 0.00 0.00 711.54 1.27 1.27 1.27 0.000 0

0.000 0.000 0.00 0.00 624.47 1.11 1.11 1.11 0.000 0

0.000 0.000 0.00 0.00 546.87 0.96 0.96 0.96 0.000 0

0.000 0.000 0.00 0.00 484.40 0.84 0.84 0.84 0.000 0

0.000 0.000

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Si All Mat Si this Mat Only Mass Material (kg) 0 0.4 0.00 0.01 4.65 231 2.60617 0

0 Mass Element (kg) 0 0.5 0.01 0.0 4.95 231 2.60617 0.02 0.00 a

5.95046 1.0 0.02 0.0 5.25 231 2.60617 0.04 0.00 b

0.06796 1.0 0.03 0.1 5.55 231 2.60617 0.09 0.00 c

-1.43151 0.3 0.05 0.1 5.85 231 2.60617 0.14 0.00 d

6.07665 3.3 0.06 0.1 6.15 231 2.60617 0.15 0.00 e

0.16569 3.3 0.11 0.2 6.45 231 2.60617 0.30 0.00 f

-2.17413 8.0 0.17 0.3 6.75 231 2.60617 0.45 0.00 5.0 0.30 0.4 7.05 231 2.60617 0.80 0.00 5.0 0.38 0.5 7.35 231 2.60617 1.01 0.00 5.0 0.47 0.6 7.5 231 2.60617 1.23 0.00 10.0 0.55 0.7 7.5 231 2.60617 1.44 0.00 10.0 0.72 0.9 7.5 231 2.60617 1.86 0.00 10.0 0.88 1.1 7.5 231 2.60617 2.28 0.00 6.7 1.05 1.2 7.5 231 2.60617 2.70 0.00 30.0 1.16 1.7 7.5 228 2.61753 2.98 0.00 30.0 1.66 2.2 7.5 225 2.629 4.17 0.00 33.3 2.16 2.7 7.5 225 2.629 5.29 0.00 4.3 2.72 2.8 7.5 225 2.629 6.53 0.00 26.0 2.79 3.2 7.5 225 2.629 6.69 0.00 176.4 3.22 6.2 7.5 225 2.629 7.65 0.00 230.3 6.16 10.0 7.5 225 2.629 14.13 0.00 189.7 10.00 13.2 7.5 223 2.63671 22.35 0.00 720.0 13.16 25.2 7.5 202.5 2.71834 28.64 0.00 1370.3 25.16 48.0 7.5 181.5 2.80737 44.47 0.00 1440.0 48.00 72.0 7.5 176.5 2.82943 63.16 0.00 1440.0 72.00 96.0 7.5 171.5 2.85185 79.58 0.00 1440.0 96.00 120.0 7.5 166.5 2.87462 92.78 0.00 7200.0 120.00 240.0 7.5 161.5 2.89776 103.23 0.00 7200.0 240.00 360.0 7.5 156.5 2.92127 103.59 0.00 7200.0 360.00 480.0 7.5 151.5 2.94517 103.60 0.00 7200.0 480.00 600.0 7.5 146.5 2.96946 103.60 0.00 7200.0 600.00 720.0 7.5 142 2.99167 103.60 0.00

Si (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Si released Integral kg Si released 0.00 343.34 15.17 15.17 15.17 0.000 0

0.000 0.000 0.00 359.84 17.01 17.01 17.01 0.000 0

0.000 0.000 0.00 377.14 19.07 19.07 19.07 0.000 0

0.000 0.000 0.00 395.26 21.38 21.38 21.38 0.000 0

0.000 0.000 0.00 414.26 23.98 23.98 23.98 0.000 0

0.000 0.000 0.00 434.17 26.88 26.88 26.88 0.000 0

0.000 0.000 0.00 455.04 30.14 30.14 30.14 0.000 0

0.000 0.000 0.00 476.91 33.80 33.80 33.80 0.000 0

0.000 0.000 0.00 499.84 37.90 37.90 37.90 0.000 0

0.000 0.000 0.00 523.86 42.49 42.49 42.49 0.000 0

0.000 0.000 0.00 536.30 45.00 45.00 45.00 0.000 0

0.000 0.000 0.00 536.30 45.00 45.00 45.00 0.000 0

0.000 0.000 0.00 536.30 45.00 45.00 45.00 0.000 0

0.000 0.000 0.00 536.30 45.00 45.00 45.00 0.000 0

0.000 0.000 0.00 536.30 45.00 45.00 45.00 0.000 0

0.000 0.000 0.00 516.57 42.51 42.51 42.51 0.000 0

0.000 0.000 0.00 497.41 40.14 40.14 40.14 0.000 0

0.000 0.000 0.00 497.41 40.14 40.14 40.14 0.000 0

0.000 0.000 0.00 497.41 40.14 40.14 40.14 0.000 0

0.000 0.000 0.00 497.41 40.14 40.14 40.14 0.000 0

0.000 0.000 0.00 497.41 40.14 40.14 40.14 0.000 0

0.000 0.000 0.00 497.41 40.14 40.14 40.14 0.000 0

0.000 0.000 0.00 484.94 38.62 38.62 38.62 0.000 0

0.000 0.000 0.00 370.54 25.66 25.66 25.66 0.000 0

0.000 0.000 0.00 276.30 16.43 16.43 16.43 0.000 0

0.000 0.000 0.00 256.92 14.72 14.72 14.72 0.000 0

0.000 0.000 0.00 238.62 13.15 13.15 13.15 0.000 0

0.000 0.000 0.00 221.37 11.74 11.74 11.74 0.000 0

0.000 0.000 0.00 205.11 10.45 10.45 10.45 0.000 0

0.000 0.000 0.00 189.81 9.29 9.29 9.29 0.000 0

0.000 0.000 0.00 175.44 8.24 8.24 8.24 0.000 0

0.000 0.000 0.00 161.94 7.30 7.30 7.30 0.000 0

0.000 0.000 0.00 150.50 6.53 6.53 6.53 0.000 0

0.000 0.000

Constants Value Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Ave Interval pH Ave Temp (F) 1000/T (K-1)

Si All Mat Si this Mat Only Mass Material (kg) 0 0.4 0.00 0.01 4.65 231 2.60617 0

0 Mass Element (kg) 0 0.5 0.01 0.0 4.95 231 2.60617 0.02 0.00 a

13.60515 1.0 0.02 0.0 5.25 231 2.60617 0.04 0.00 b

0.18354 1.0 0.03 0.1 5.55 231 2.60617 0.09 0.00 c

-3.81145 0.3 0.05 0.1 5.85 231 2.60617 0.14 0.00 d

15.69692 3.3 0.06 0.1 6.15 231 2.60617 0.15 0.00 e

0.34838 3.3 0.11 0.2 6.45 231 2.60617 0.30 0.00 f

-6.05941 8.0 0.17 0.3 6.75 231 2.60617 0.45 0.00 5.0 0.30 0.4 7.05 231 2.60617 0.80 0.00 5.0 0.38 0.5 7.35 231 2.60617 1.01 0.00 5.0 0.47 0.6 7.5 231 2.60617 1.23 0.00 10.0 0.55 0.7 7.5 231 2.60617 1.44 0.00 10.0 0.72 0.9 7.5 231 2.60617 1.86 0.00 10.0 0.88 1.1 7.5 231 2.60617 2.28 0.00 6.7 1.05 1.2 7.5 231 2.60617 2.70 0.00 30.0 1.16 1.7 7.5 228 2.61753 2.98 0.00 30.0 1.66 2.2 7.5 225 2.629 4.17 0.00 33.3 2.16 2.7 7.5 225 2.629 5.29 0.00 4.3 2.72 2.8 7.5 225 2.629 6.53 0.00 26.0 2.79 3.2 7.5 225 2.629 6.69 0.00 176.4 3.22 6.2 7.5 225 2.629 7.65 0.00 230.3 6.16 10.0 7.5 225 2.629 14.13 0.00 189.7 10.00 13.2 7.5 223 2.63671 22.35 0.00 720.0 13.16 25.2 7.5 202.5 2.71834 28.64 0.00 1370.3 25.16 48.0 7.5 181.5 2.80737 44.47 0.00 1440.0 48.00 72.0 7.5 176.5 2.82943 63.16 0.00 1440.0 72.00 96.0 7.5 171.5 2.85185 79.58 0.00 1440.0 96.00 120.0 7.5 166.5 2.87462 92.78 0.00 7200.0 120.00 240.0 7.5 161.5 2.89776 103.23 0.00 7200.0 240.00 360.0 7.5 156.5 2.92127 103.59 0.00 7200.0 360.00 480.0 7.5 151.5 2.94517 103.60 0.00 7200.0 480.00 600.0 7.5 146.5 2.96946 103.60 0.00 7200.0 600.00 720.0 7.5 142 2.99167 103.60 0.00

Si (ppm)

K k

R Positive release rate (mg/kg-min) interval pred release (kg)

Amount above start Mass interval kg Si released Integral kg Si released 0.00 33523.03 33.50 33.50 33.50 0.000 0

0.000 0.000 0.00 38054.44 42.62 42.62 42.62 0.000 0

0.000 0.000 0.00 43198.36 54.21 54.21 54.21 0.000 0

0.000 0.000 0.00 49037.61 68.96 68.96 68.96 0.000 0

0.000 0.000 0.00 55666.17 87.72 87.72 87.72 0.000 0

0.000 0.000 0.00 63190.72 111.59 111.59 111.59 0.000 0

0.000 0.000 0.00 71732.39 141.95 141.95 141.95 0.000 0

0.000 0.000 0.00 81428.66 180.58 180.58 180.58 0.000 0

0.000 0.000 0.00 92435.61 229.71 229.71 229.71 0.000 0

0.000 0.000 0.00 104930.39 292.21 292.21 292.21 0.000 0

0.000 0.000 0.00 111797.55 329.57 329.57 329.57 0.000 0

0.000 0.000 0.00 111797.55 329.57 329.57 329.57 0.000 0

0.000 0.000 0.00 111797.55 329.57 329.57 329.57 0.000 0

0.000 0.000 0.00 111797.55 329.57 329.57 329.57 0.000 0

0.000 0.000 0.00 111797.55 329.57 329.57 329.57 0.000 0

0.000 0.000 0.00 101180.74 281.23 281.23 281.23 0.000 0

0.000 0.000 0.00 91492.11 239.64 239.64 239.64 0.000 0

0.000 0.000 0.00 91492.11 239.64 239.64 239.64 0.000 0

0.000 0.000 0.00 91492.11 239.64 239.64 239.64 0.000 0

0.000 0.000 0.00 91492.11 239.64 239.64 239.64 0.000 0

0.000 0.000 0.00 91492.11 239.64 239.64 239.64 0.000 0

0.000 0.000 0.00 91492.11 239.64 239.64 239.64 0.000 0

0.000 0.000 0.00 85512.06 215.22 215.22 215.22 0.000 0

0.000 0.000 0.00 41773.55 68.91 68.91 68.91 0.000 0

0.000 0.000 0.00 19123.09 19.90 19.90 19.90 0.000 0

0.000 0.000 0.00 15756.51 14.62 14.62 14.62 0.000 0

0.000 0.000 0.00 12942.83 10.70 10.70 10.70 0.000 0

0.000 0.000 0.00 10598.26 7.79 7.79 7.79 0.000 0

0.000 0.000 0.00 8650.52 5.64 5.64 5.64 0.000 0

0.000 0.000 0.00 7037.51 4.06 4.06 4.06 0.000 0

0.000 0.000 0.00 5705.96 2.91 2.91 2.91 0.000 0

0.000 0.000 0.00 4610.38 2.07 2.07 2.07 0.000 0

0.000 0.000 0.00 3793.91 1.52 1.52 1.52 0.000 0

0.000 0.000

Elapsed Time (min)

Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Average Interval pH Average Temperature (F) 1000/T (K-1) 1000/T squared pHa squared Area Zn 0.1 0.400 0.00 0.01 5

105 3.1877026 10.16 25.00 ft2 1

0.500 0.01 0.02 5

105 3.1877026 10.16 25.00 199888.7 1

1.000 0.02 0.03 5

105 3.1877026 10.16 25.00 2

1.000 0.03 0.05 5

105 3.1877026 10.16 25.00 3

0.3 0.05 0.06 5

105 3.1877026 10.16 25.00 3

3.3 0.06 0.11 5

105 3.1877026 10.16 25.00 Mass Zn 7

3.3 0.11 0.17 5

105 3.1877026 10.16 25.00 lbm 10 8.0 0.17 0.30 5

105 3.1877026 10.16 25.00 1000000 18 5.0 0.30 0.38 5

105 3.1877026 10.16 25.00 23 5.0 0.38 0.47 6.25 105 3.1877026 10.16 39.06 28 5.0 0.47 0.55 7.5 105 3.1877026 10.16 56.25 33 10.0 0.55 0.72 7.5 105 3.1877026 10.16 56.25 43 10.0 0.72 0.88 7.5 105 3.1877026 10.16 56.25 Mass Zn 53 10.0 0.88 1.05 7.5 105 3.1877026 10.16 56.25 kg 63 6.7 1.05 1.16 7.5 146.15 2.9711796 8.83 56.25 453597 70 30.0 1.16 1.66 7.5 186.15 2.7871543 7.77 56.25 100 30.0 1.66 2.16 7.5 182.5 2.8029961 7.86 56.25 130 33.3 2.16 2.72 7.5 177.5 2.8249918 7.98 56.25 163 4.3 2.72 2.79 7.5 172.5 2.8473354 8.11 56.25 167 26.0 2.79 3.22 7.5 167.5 2.8700352 8.24 56.25 193 176.4 3.22 6.16 7.5 162.5 2.8931 8.37 56.25 370 230.3 6.16 10.00 7.5 157.5 2.9165384 8.51 56.25 600 189.7 10.00 13.16 3.75 77.5 3.3508945 11.23 14.06 790 720.0 13.16 25.16 0

0 3.9158527 15.33 0.00 1510 1370.3 25.16 48.00 0

0 3.9158527 15.33 0.00 2880 1440.0 48.00 72.00 0

0 3.9158527 15.33 0.00 4320 1440.0 72.00 96.00 0

0 3.9158527 15.33 0.00 5760 1440.0 96.00 120.00 0

0 3.9158527 15.33 0.00 7200 7200.0 120.00 240.00 0

0 3.9158527 15.33 0.00 14400 7200.0 240.00 360.00 0

0 3.9158527 15.33 0.00 21600 7200.0 360.00 480.00 0

0 3.9158527 15.33 0.00 28800 7200.0 480.00 600.00 0

0 3.9158527 15.33 0.00 36000 7200.0 600.00 720.00 0

0 3.9158527 15.33 0.00

pHa/(1000

/T) pHa cubed pHa squared/(

1000/T) log prediction corrosion rate (mg/m2-min) interval mg Zn released interval Kg Zn released Integral kg An released mass available Integral kg Zn 1.57 125.00 7.84 1.01434 10.3357002 76775 0

0.077 0.077 1.57 125.00 7.84 1.01434 10.3357002 95968 0.096 0.173 0.173 1.57 125.00 7.84 1.01434 10.3357002 191937 0.192 0.365 0.365 1.57 125.00 7.84 1.01434 10.3357002 191937 0.192 0.557 0.557 1.57 125.00 7.84 1.01434 10.3357002 63979 0.064 0.621 0.621 1.57 125.00 7.84 1.01434 10.3357002 639790 0.640 1.260 1.260 1.57 125.00 7.84 1.01434 10.3357002 639790 0.640 1.900 1.900 1.57 125.00 7.84 1.01434 10.3357002 1535495 1.535 3.436 3.436 1.57 125.00 7.84 1.01434 10.3357002 959685 0.960 4.395 4.395 1.96 244.14 12.25 0.033235 1.07953045 100236 0.100 4.496 4.496 2.35 421.88 17.65

-0.624154 0.23759992 22061 0.022 4.518 4.518 2.35 421.88 17.65

-0.624154 0.23759992 44123 0.044 4.562 4.562 2.35 421.88 17.65

-0.624154 0.23759992 44123 0.044 4.606 4.606 2.35 421.88 17.65

-0.624154 0.23759992 44123 0.044 4.650 4.650 2.52 421.88 18.93

-1.265172 0.05430356 6756 0.007 4.657 4.657 2.69 421.88 20.18

-1.69511 0.02017856 11242 0.011 4.668 4.668 2.68 421.88 20.07

-1.662821 0.02173599 12109 0.012 4.680 4.680 2.65 421.88 19.91

-1.616437 0.02418594 14956 0.015 4.695 4.695 2.63 421.88 19.76

-1.567512 0.02706998 2155 0.002 4.697 4.697 2.61 421.88 19.60

-1.515985 0.03048 14743 0.015 4.712 4.712 2.59 421.88 19.44

-1.461793 0.03453083 113095 0.113 4.825 4.825 2.57 421.88 19.29

-1.404871 0.03936665 168361 0.168 4.993 4.993 1.12 52.73 4.20 3.196861 1573.48046 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993 0.00 0.00 0.00 13.4943 3.1211E+13 0

0.000 4.993 4.993

Model term Value Intercept

-15.10693334 pHa

-3.670953896 1000/T (K-1) 7.303961651 pHa squared 0.103589245 pHa/(1000/T) 5.485050709

Elapsed Time (min)

Interval Duration (min)

Start of Interval (hrs)

End of Interval (hrs)

Average Interval pH Average Temperature (F) 1000/T (K-1) 1000/T squared pHa squared Area Zn 0.1 0.400 0.00 0.01 4.65 231 2.606165 6.79 21.62 ft2 1

0.500 0.01 0.02 4.95 231 2.606165 6.79 24.50 4121.3 1

1.000 0.02 0.03 5.25 231 2.606165 6.79 27.56 2

1.000 0.03 0.05 5.55 231 2.606165 6.79 30.80 3

0.3 0.05 0.06 5.85 231 2.606165 6.79 34.22 3

3.3 0.06 0.11 6.15 231 2.606165 6.79 37.82 Mass Zn 7

3.3 0.11 0.17 6.45 231 2.606165 6.79 41.60 lbm 10 8.0 0.17 0.30 6.75 231 2.606165 6.79 45.56 10000000 18 5.0 0.30 0.38 7.05 231 2.606165 6.79 49.70 23 5.0 0.38 0.47 7.35 231 2.606165 6.79 54.02 28 5.0 0.47 0.55 7.5 231 2.606165 6.79 56.25 33 10.0 0.55 0.72 7.5 231 2.606165 6.79 56.25 43 10.0 0.72 0.88 7.5 231 2.606165 6.79 56.25 Mass Zn 53 10.0 0.88 1.05 7.5 231 2.606165 6.79 56.25 kg 63 6.7 1.05 1.16 7.5 231 2.606165 6.79 56.25 4535970 70 30.0 1.16 1.66 7.5 228 2.6175346 6.85 56.25 100 30.0 1.66 2.16 7.5 225 2.6290038 6.91 56.25 130 33.3 2.16 2.72 7.5 225 2.6290038 6.91 56.25 163 4.3 2.72 2.79 7.5 225 2.6290038 6.91 56.25 167 26.0 2.79 3.22 7.5 225 2.6290038 6.91 56.25 193 176.4 3.22 6.16 7.5 225 2.6290038 6.91 56.25 370 230.3 6.16 10.00 7.5 225 2.6290038 6.91 56.25 600 189.7 10.00 13.16 7.5 223 2.6367059 6.95 56.25 790 720.0 13.16 25.16 7.5 202.5 2.7183352 7.39 56.25 1510 1370.3 25.16 48.00 7.5 181.5 2.8073678 7.88 56.25 2880 1440.0 48.00 72.00 7.5 176.5 2.8294324 8.01 56.25 4320 1440.0 72.00 96.00 7.5 171.5 2.8518466 8.13 56.25 5760 1440.0 96.00 120.00 7.5 166.5 2.8746187 8.26 56.25 7200 7200.0 120.00 240.00 7.5 161.5 2.8977575 8.40 56.25 14400 7200.0 240.00 360.00 7.5 156.5 2.9212717 8.53 56.25 21600 7200.0 360.00 480.00 7.5 151.5 2.9451707 8.67 56.25 28800 7200.0 480.00 600.00 7.5 146.5 2.969464 8.82 56.25 36000 7200.0 600.00 720.00 7.5 142 2.9916732 8.95 56.25

pHa/(1000

/T) pHa cubed pHa squared/(

1000/T) log prediction corrosion rate (mg/m2-min) interval mg Zn released interval Kg Zn released Integral kg An released mass available Integral kg Zn 1.78 100.54 8.30

-1.115084 0.07672122 12 0

0.000 0.000 1.90 121.29 9.40

-1.28664 0.05168443 10 0.000 0.000 0.000 2.01 144.70 10.58

-1.43955 0.03634544 14 0.000 0.000 0.000 2.13 170.95 11.82

-1.573814 0.02668003 10 0.000 0.000 0.000 2.24 200.20 13.13

-1.689431 0.02044413 3

0.000 0.000 0.000 2.36 232.61 14.51

-1.786403 0.01635299 21 0.000 0.000 0.000 2.47 268.34 15.96

-1.864728 0.01365437 17 0.000 0.000 0.000 2.59 307.55 17.48

-1.924408 0.01190124 36 0.000 0.000 0.000 2.71 350.40 19.07

-1.965441 0.01082826 21 0.000 0.000 0.000 2.82 397.07 20.73

-1.987828 0.01028422 20 0.000 0.000 0.000 2.88 421.88 21.58

-1.99203 0.01018521 19 0.000 0.000 0.000 2.88 421.88 21.58

-1.99203 0.01018521 39 0.000 0.000 0.000 2.88 421.88 21.58

-1.99203 0.01018521 39 0.000 0.000 0.000 2.88 421.88 21.58

-1.99203 0.01018521 39 0.000 0.000 0.000 2.88 421.88 21.58

-1.99203 0.01018521 26 0.000 0.000 0.000 2.87 421.88 21.49

-1.97755 0.01053052 121 0.000 0.000 0.000 2.85 421.88 21.40

-1.962343 0.01090579 125 0.000 0.001 0.001 2.85 421.88 21.40

-1.962343 0.01090579 139 0.000 0.001 0.001 2.85 421.88 21.40

-1.962343 0.01090579 18 0.000 0.001 0.001 2.85 421.88 21.40

-1.962343 0.01090579 109 0.000 0.001 0.001 2.85 421.88 21.40

-1.962343 0.01090579 736 0.001 0.002 0.002 2.85 421.88 21.40

-1.962343 0.01090579 962 0.001 0.003 0.003 2.84 421.88 21.33

-1.951796 0.01117389 812 0.001 0.003 0.003 2.76 421.88 20.69

-1.824093 0.01499363 4133 0.004 0.007 0.007 2.67 421.88 20.04

-1.653744 0.02219502 11645 0.012 0.019 0.019 2.65 421.88 19.88

-1.606857 0.02472537 13632 0.014 0.033 0.033 2.63 421.88 19.72

-1.557417 0.0277066 15276 0.015 0.048 0.048 2.61 421.88 19.57

-1.505362 0.03123476 17221 0.017 0.065 0.065 2.59 421.88 19.41

-1.450629 0.03542997 97672 0.098 0.163 0.163 2.57 421.88 19.26

-1.393154 0.04044327 111492 0.111 0.274 0.274 2.55 421.88 19.10

-1.332868 0.04646563 128094 0.128 0.403 0.403 2.53 421.88 18.94

-1.269703 0.05373992 148147 0.148 0.551 0.551 2.51 421.88 18.80

-1.210333 0.06161227 169850 0.170 0.721 0.721

Model term Value Intercept

-15.10693334 pHa

-3.670953896 1000/T (K-1) 7.303961651 pHa squared 0.103589245 pHa/(1000/T) 5.485050709