ML033440215
| ML033440215 | |
| Person / Time | |
|---|---|
| Site: | LaSalle  |
| Issue date: | 10/24/2003 |
| From: | Landahl S Exelon Generation Co |
| To: | Document Control Desk, Office of Nuclear Reactor Regulation |
| References | |
| -RFPFR | |
| Download: ML033440215 (147) | |
Text
Exertn.
Exelon Generation Company. LLC www.exeloncorp.com Nudear LaSalle County Station 2601 North 21" Road Marseilles, IL 61341-9757 October 24, 2003 United States Nuclear Regulatory Commission Attention: Document Control Desk Washington, D.C. 20555 LaSalle County Station, Units 1 and 2 Facility Operating License Nos. NPF-11 and NPF-18 NRC Docket Nos. 50-373 and 50-374
Subject:
Notification of Renewal and Proposed Changes to Exelon Generation Company, LLC - LaSalle County Station NPDES Permit No. IL0048151 In accordance with the notification requirements of Facility Operating Licenses NPF-11 and NPF-18, Appendix B, Environmental Protection Plan, Section 3.2, notice is being provided of application for a 5-year renewal of the Exelon Generation Company, LLC - LaSalle County Station NPDES Permit No. IL0048151, along with proposed changes to the permit. The permit application letter, which includes the proposed permit modifications, is attached; The following permit modifications are being requested for clarification purposes only and do not reflect any new physical changes to the station.
Rename Outfall 002 - Illinois River Makeup Water Intake Screen Backwash "Illinois River Makeup Water Intake." Delete the following sentence from the outfall description: "This discharge is limited to Illinois River make-up water intake screen backwash free from other wastewater discharges." Add a list of discharges to the outfall.
Address in the permit potential discharges from the Cooling Lake dike from the Auxiliary Spillway and the Peripheral Dike Drainage Ditch.
Add discharges from the North and South Circulating Water Inlet Canal Stormwater Runoff to Outfall 001.
Add discharges from the Illinois Department of Natural Resources (IDNR) Fish Hatchery Effluents.
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October 24, 2003 U.S. Nuclear Regulatory Commission Page 2 Correct a typographical error under Outfall C01 - Wastewater Treatment System Effluent.
Add Diesel Generator Cooling Water as a discharge to Outfall C01 -
Wastewater Treatment System Effluent.
Should you have any questions concerning this letter, please contact Mr. Glen T. Kaegi, Regulatory Assurance Manager, at (815) 415-2800.
Respectfully, Susan R. Landahl Plant Manager LaSalle County Station Attachment cc:
Regional Administrator - NRC Region IlIl NRC Senior Resident Inspector - LaSalle County Station
Exe k n s, Exelon Generation Company, LLC www.exeloncorp.com -
Nuclea LaSalle County Station
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2601 North 21VRoad Marseilles, IL 61341-9757 October 24, 2003 CERTIFIED MAIL Mr. Blaine Kinsley Manager, Industrial Unit, Permit Section Division of Water Pollution Control Illinois Environmental Protection Agency.
1021 North Grand Ave. East Springfield, Illinois 62702
Subject:
Renewal of NPDES Permit No. IL0048151 Exelon Generation Company, LLC LaSalle County Station Dear Mr. Kinsley.
Exelon Generation Company, LLC - LaSalle County Station hereby submits two (2) copies of Consolidated Permit Application Forms 1 and 2C for renewal of the subject permit. Form 2C--
Part V-A pollutants reported are those required by the station's existing NPDES permit.
Pollutants categorized as GC/MS Fraction Compounds in Part V-C are not reported for any outfall as per the station's letter of request submitted and dated September 9, 2003 (See attached).
Pollutant levels for all permit-required parameters were derived from station DMR data reported for a 12-month period encompassing September 2002 through August 2003. In most cases, a single analysis was conducted for all other pollutants. All color analyses were performed as "true" (i.e. samples were centrifuged prior to analysis). Mass load values were calculated using average flows.
The following outfalls were sampled and analyzed for the permit renewal. Form 2C, Part IIB requires descriptions of wastewater treatment processes currently employed by the station.
Consequently, we are including descriptions of water treatment additives that have the potential for being discharged by way of the various outfalls. Material Safety Data Sheets'have been included where applicable.
001 - Cooling Pond Blowdown This outfall receives no treatment as a wastewater. However, average doses of 8 ppm Sodium Hypochlorite (HYPO 150) and 2 ppm Sodium Bromide (BioRidTm 40i) are applied to the circulating water/service water systems for bio-fouling control.
Additionally, the circulating water/service water systems are treated with Carbon Dioxide, Sodium Polyphosphate (Flogard POT 6102 or generic), Phosphonic Acid (1-hydroxyethylidine) bis - (HEDP) (Depositrol BL5400), and deposit control agent (Depositrol BL5323) for silt, scale and corrosion control: Ferroquest LP7200 is also used in small quantities to clear caustic injection lines. A Water Softener Regenerant Waste discharge intermittently inputs a small amount of salt solution to the Cooling Pond.
BO] - Sewage Treatment Plant Effluent This outfall may contain residual chlorine, since sodium hypochlorite is occasionally applied to the polishing ponds in order to control algae blooms. Discharge from this system is routed to the station's Cooling Pond, which is monitored for total residual oxidant (TRO) at the blowdown to the Illinois River. This intermittent use of chlorine should have no appreciable affect on the level of TRO discharged via outfall 001. Also, small amounts of Hydrosep (or equivalent bacteriostatic preservative) intermittently input into the system from periodic change out of the water in the eyewash stations. This intermittent input has had no impact on Sewage Treatment Plant operations.
COI - Wastewater Treatment Plant Effluent Industrial wastewaters are treated with cationic (Nalco 7750) and anionic polymers to aid coagulation/flocculation during treatment. Also, Sodium Hypochlorite is present in well water used to supply intermittent sand filter backwash flows, which input to the Wastewater Treatment Plant. The residual Sodium Hypochlorite in these backwashes is non-detectable at the Wastewater Treatment Plant.
101 - Reverse Osmosis System Reject Water Reverse osmosis regenerant may contain residual amounts of Permatreat 191 pretreatment polymer and Sodium Chloride. This outfall inputs into the South Site Stormwater Runoff storm drains, which discharges to the Cooling Pond at Outfall HO 1.
The following outfalls were not sampled and analyzed for the indicated reasons:
AOl-Demineralizer Regenerant Waste The use of this outfall point has not occurred for the past several years and is not anticipated. However, the system has not been removed, so the potential remains for a discharge. Therefore, analytical results from the last permit renewal application, dated August 28, 1998, have been included. While this data is not recent, we believe that the parameter values are still representative of the discharge. Should this discharge resume on an intermittent basis in the future, we will provide new Form 2C data for the Agency's review.
DOI - Cooling Water Intake Screen Backwash No chemicals are applied or utilized in this outfall. There are no wastewater treatment processes applied to the effluent, other than passing the backwash through a trash basket to collect debris removed from the screens. The trash basket is properly maintained and operated to prevent the return of the trash to the Cooling Pond. The trash is properly disposed in a permitted landfill.
EOl - Unit I and 2 Radwaste Treatment System Effluent No recent discharges have occurred that would allow sampling to take place. Therefore, analytical results submitted for the last permit renewal application, dated November 8, 1993, have been included. While this data is not recent, we believe that the parameter values are still representative of the discharge. At the next available opportunity during a discharge from this system, samples will be taken and a new Form 2C will be provided to the Agency for review.
FOI - Auxiliary Reactor Equipment Cooling and Flushing Water Receives no treatment as a wastewater. However, average doses of 8 ppm sodium hypochlorite and 2 ppm sodium bromide are applied for bio-fouling control. Discharge from this system is routed to the station's Cooling Pond, which is monitored for total residual oxidant (TRO) at the blowdown to the Illinois River.
GOl - North Site Stormwater Runoff Because of the recent dry weather, no rainfall events have occurred that would allow sampling. As soon as conditions are favorable, samples will be taken and analyzed per Form 2F and submitted to the Agency HOI - South Site Stormwater Runoff See North Site Stormwater Runoff above.
002 - Illinois River Makeup Water Intake Screen Backwash.
No chemicals are applied or utilized in this outfall. There are no wastewater treatment processes applied to the effluent, other than passing the backwash through a trash basket to collect debris removed from the screens. The trash basket is properly maintained and operated to prevent the return of the trash to the Illinois River. The trash is properly disposed in a permitted landfill.
Permit Modification Request Agency guidance relative to previous NPDES permit applications for Exelon's generating stations indicated a need to provide additional detail on contributing waste streams for each outfall. Consequently, in addition to the proceeding information required for renewal, LaSalle County Station wishes to request that the following modifications be incorporated into the new permit. Please include these requests in your deliberations regarding the reissuance of LaSalle County Station's permit.
Modification #1 Rename Outfall 002 - Illinois River Makeup Water Intake Screen Backwash "Illinois River Makeup Water Intake", delete the following sentence from the outfall description "This discharge is limited to Illinois River make-up water intake screen backwash free from other wastewater discharges.", and add the following discharges to the outfall (Refer to the attached River Makeup Intake Diagram):
Discharges Approximate Flow River Intake Screen Backwash 0.144 MGD Trench Wash 0.144 MGD Process Sampling Discharge 0.144 MGD Lake Makeup Pump Gland Leakoff, Coolers, Reliefs and Min Flow No flow when pumps are off Lake Makeup Pump Strainer Backwash Intermittent Air Compressor Receiver and Prefilter Drainage Intermittent Dewatering Pump Discharge Intermittent Fire Protection Water Intermittent River Screen House Switchyard Stormwater Runoff Intermittent River Screen House Floor Drains and Roof Drains Intermittent The reason for this change is that the Illinois River Intake Screen Backwash does not actually discharge to the Illinois River, but inputs to an intake flume, which is part of the River Screen House structure. During normal operations, there is no discharge from Outfall 002, since the Lake Makeup Pumps continuously draw in water from the river at 30,000 to 60,000 gpm and pump the discharges to the Cooling Pond. However, in the event that the Lake Makeup Pumps are shutdown for maintenance or trip off due to an abnormal condition, the above listed discharges have the potential for exiting the wing wall entrance to the intake flume and entering
the Illinois River. Normally, there is one scheduled outage in the River Screen House every year lasting approximately two weeks during which Outfall 002 would be in active use. For the above reasons, Outfall 002 is considered an intermittent outfall.
Modification #2 The station requests adding two potential discharges from the Cooling Pond dikes to the new permit (Refer to the attached Outfall Summary Diagram). These potential discharges result from design features in the LaSalle Cooling Pond dikes installed to comply with Illinois Department of Natural Resources (IDNR) dam construction regulations. The first is the Emergency Auxiliary Spillway. This spillway has never been used anytime in the past, but in the event of an emergency, it is designed to relieve excess cooling pond level by discharging the overflow to a branch of the South Kickapoo Creek at Latitude 410 15' 25"N and Longitude 88° 40' 22"W.
Secondly, the station would like to add discharges from the Peripheral Dike Drainage Ditch.
This ditch serves to intercept surface stormwater runoff and Cooling Pond seepage at the downstream toe of the dikes. It also serves as an additional inspection trench beyond the downstream toe. The Peripheral Dike Drainage Ditch discharges water into Armstrong Run at Latitude 41° 15' 36"N and Longitude 88° 37' 03"W, as well as three branches of the South Kickapoo Creek, as shown in the attached Figure 3.4-1.
Modification #3 The station requests adding the following Stormwater discharges to the Cooling Pond under Outfall 001(Refer to the attached Water Flow Schematic and map):
- 14.
North Inlet Canal Stormwater Runoff
- 15.
South Inlet Canal Stormwater Runoff The North Inlet Canal Stormwater Runoff drains the general area North of the Circulating Water Inlet Canal outside the Protected Area. There are no specific inputs into this discharge. The South Inlet Canal Stormwater Runoff drains the general area South of the Circulating Water Inlet Canal outside the Protected Area and has specific stormwater inputs from the Main Switchyard and areas around the Lake Screen House inside the Protected Area. Both stormwater runoffs are intermittent discharges.
Modification #4 The station requests adding the following discharge to the Cooling Pond under Outfall 001 (Refer to the attached IDNS Fish Hatchery Diagram):
- 16.
IDNR Fish Hatchery Effluents Discharges Approximate Flow IDNR Hatchery / Shad Net Maintenance Septic System Intermittent IDNR Hatchery Fish Tanks 0.101 MGD IDNR Fish Rearing Ponds Intermittent A fish hatchery exists on site, which is operated by the Illinois Department of Natural Resources (IDNR). The hatchery utilizes a septic tank system permitted by the LaSalle County Department of Public Health to collect and treat domestic sewage from the hatchery, as well as Exelon's Shad Net Maintenance Facility. The hatchery also continuously discharges effluents from its fish tanks nine months out of the year and discharges drainage from its fish rearing ponds in the fall. The sizes of the 16 fish rearing ponds range from 3.4 - 4.5 million gallons each. One pond can be drained over a period of 37 to 48 hours5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br />.
The effluents from the septic tank system, hatchery, and fish rearing ponds all flow into a single ditch, which discharges to the Circulating Water Intake Canal section of the Cooling Pond. This water then flows through the condenser and back to the Cooling Pond, taking approximately 5 days to travel around the pond to the Blowdown Canal. At this point, a portion of the Cooling Pond water enters the Blowdown Line, which is then discharged to the Illinois River via Outfall 001 - Cooling Pond Blowdown. Since Exelon has no direct control over the inputs to the IDNR Fish Hatchery Effluents discharge, the station requests that any monitoring or permit limitations associated with this discharge be directed to IDNR outside the scope of this permit application.
Modification # 5 In our current permit under Outfall COI - Wastewater Treatment System Effluent, there is a typographical error. The 30-Day Avg. and Daily Max. Concentration Limit values for Total Suspended Solids and Oil and Grease are placed under the wrong columns. Request relocating these limits under the correct Concentration Limit columns.
Modification # 6 Under Outfall COI - Wastewater Treatment System Effluent, add the following discharge:
- 14.
Diesel Generator Cooling Water Diesel Generator Cooling Water is periodically drained from the diesel generators for maintenance in a batch release evolution. This cooling water consists of demineralized water plus a corrosion inhibitor additive (PWR-CORR CSB - See attached MSDS). Each batch is
approximately 320 gallons in volume. Constituent concentrations before and after treatment in the Wastewater Treatment Facility (WWTF) are described as follows:
Wastestream Constituent Before Treatment After Treatment Max Concentration (ppm)
Max Concentration (ppm)
Copper (Total) 56.7 0.32 Iron (Total) 90.37 0.58 Tolytriazole 50 0.26 Total Suspended Solids (TSS)
Not Monitored 1:188 reduction Nitrite 2600 13.77 Boron 57.95 0.59 pH 10.5 8.6 Based on the above, the station believes that this discharge will have a negligible impact on the effluent from this outfall.
If you have questions concerning the information submitted, please contact Mr. Fred Bevington of my staff at (815) 415-3243.
Sincerely, Susan Landahl Plant Manager LaSalle County Generating Station Enclosures cc:
W. Buinickas / F. Bevington-LaSalle Environmental Specialists J. Bolte - Corporate Environmental Cortney Scheidt - LaSalle Engineering
Exelon Generation Co., LLC LaSalle County Station River Makeup Intake Diagram
[ I = Intermittent I
Air Compressor Receiver rand Prefilter Drains
- Lake Makeup Pump Gland Leakoff, Coolers, Reliefs and Min Flow River Screen House (RSH)
Lake Makeup Pump Strainer Back Wash Lake Make Pumps are Lake Makeup Pump Suction Bays Outfall 002 Illinois River Normal Intake Flow 30,000 - 60,000 gpm
LOCATION ACRES CJv 300'AUXILIARY A
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~~~~~~~~OPERATING tlICENSE STAGE SCALE IN FEET ENVIRONMENTAL REPORT LP-LOW POINT FIGURE 3.4-1 HP-HIGH POINT DrTDr-w-I nTL'c nfTYMAl~r-n,,.,,v-AIln PL1RUILPH L LINCL U1n¶lIPUL UIILn53 AILJ LOCATIONS FOR COOLING LAKE TEMPERATURES
Exelon Generation Co., LLC LaSalle County Station IDNR Fish Hatchery Diagram Illinois River Exelon Shad Net Maintenance Building (4 people)
IDNR Fish Hatchery (5 people)
Outfall 001 34.98 MGD Cooling Pond Approx. 5 day travel time
@ 1.2 Million gpm Add 6 chlorine
. tablets every 6 months Intermittent Ponds are typically drained in the fall. One pond drains In 36 - 48 Hours 0.101 MGD 9 months out of the year IDNR Fish Rearing Ponds (16) 3.4 - 4.5 Million gallons each I
IDNR Hatchery Fish Tanks
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APPUCATION FORPERMITTO DISCHARGEWASTEWATER-2C ram.;.EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS NPDES Consolidated Permits Proriam I. OUTFALL LOCATION For each outfall, list the latitude and longitude to the nearest 15 seconds and the name of the receiving water.
- -v A. OUTFALL B. LATITUDE C. LONGITUDE D. RECEMNG WATER (name)
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.39 46 Illinois River II. FLOWS, SOURCES OF POLLUTION,-AND TREATMENT TECHNOLOGIES --...
A.
Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions In Item B. Construct a water balance on the line drawing by showing average flowv between Intakes, opeiitioris. treatment units'arnd oufasls;"I Hswsieibabnce anriot be dkeiernlne (e.g. for certain mining activities), provide a pictorial description of the nature and amount of any source of water and any collection or treatment measures K
B.
For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, Including process wastewater, sanitary, wastewater, cooling water, and stormr water runoff; (2) The average flow contributed by each operation-and (3) The treatment received by t he wastewater.t Continue on additional sheets if necessary
-2. OPERATION(S) CONTRIBUTING FLOW -'-
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- b. AVERAGE FLOW
- a. DESCRIPTION
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TABLE 2C-I 001 Cooling Pond Slowdown (Main Cond. Cooling 34.98 MGD Evaporative Heat Dissipation, X-X Water, Clean Condensate System Flushing Discharge to Surface Water 4-A Demineralizer Regenerant Wastes House Service Water, Sewage Treatment Plant Effluent, Radwaste Treatment System Effluent, Wastewater Treatment System Effluent, Auxiliary Reactor Equipment Cooling Water, Reverse Osmosis System Reject Water Water Softener Renerant Waste Cooling Pond Intake Screen Backwash, North Site Uncontaminated Storm Runoff, South Site._.__._
Uncontaminated Storm Runoff).
A01 Demineralizer Regenerant Wastes
. Intermittent -
Equilizalion, Buffering with Clrc-OXX -
XX (Make-up Demineralizer Regenerant Waste, ulating Water or Neutralization..
2-K Off-Spec Demnineralized Water, MU Demin.
Treatment In Wastewater ;
XX Maintenance Wastewater, Unit 1 Waterbox -..
Vacuum Pump Condensate (Lake Water),
Radwaste Treatment Acid/ Caustic System Drains B01 Sewage Treatment Plant Effluent' 0.020 MGD Equalization, Activated Sludge, X-X 3-A (Sanitary Waslewater, Eyewash Station Waste-Sedimentation, 1-U water)
Sludge to Aerobic Digestion, 5-A
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-H X-X OFFICIAL USE ONLY (effluent guidelines subcategories) a:
EPA Forrfn 351 U-Z6 (R*v. Z-D5)
PAGE I UF-4 CONTIINUE UN REVERSE
CONTINIUFD FROM THF FRONT C. except for storm runoff, leaks, or spills, are any of the discharges described In Items Il-A or B intermittent or seasonal?
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- b. TOTAL VOLUME e
- 1. UTFLL
.~CONTRIBUTING FLOW julst):*.WE PRYARwhuk)
.DUATN
- 1. OtJTFALL e*
v *
.:. -M I ; -M: *E TE*
- IT2 MAXIMUM. 1. LONG TERM 2. MAXIMUM days),
NUMBER flist) t average),,
average)
AVERAGE I
- DAILY, AVERAGE
.' DAILY ',
A01 Demineralizer Regenerant Wastes -
0.047 0.047 1
E01
- Unit 1 and 2 Radwaste Treatment System 0.011 0.027 1
F01 Aux. Reactor Equip. Cooling and Flushing Water 55.58 1
002 II. River Make-Up Water Intake Screen Backwash 0.432 20 Ill. PRODUCTION A. Does an effluet qideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility?
-X IYES (complete Item ll-B) -
F INO (goito Section V) '-
B. Are limitations in the plicable effluent guideline expressed in terms of produdion (or other measure of operation) ?.
_.I.
IYES (compleie Item 11-C)
X IlNO ( oto Section AV)
C. If you answered 'yes, to Item Ill-B. list the quantity which represents an actual measurement of your level of production, expressed in terms and units.
ledin thI Il e en id' a
n d
i n
dicat the aneded n
- -e*;'
-I
'*i.
- 1. AVERAGE DAILY PRODUCTION 2.AFFECTEDE
- a. OUANTnT PER DAY.
- b. UNiTS OF MSURE c OPERATION. PROrUCT. MATERIAL C. sTC )
OUTALL (listnout
______num b eirs -:"
NA NA NA NA IV. IMPROVEMENTS A. Are you now required by any Federal; State or Local authority to meet any Implementation schedule for the constructionj upgrading or operation ofd >.'
wastewater treatment equipment or practices or any other environmental programs which may affec the discharges descrbed in this application? This.'-
includes, but is not limited to 'permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders~ an grant or loan cordd ons.
.^-;-
I l; 1
II-,
mnL.,t4 Itha f.,IAIdh tanhla
-. 'I FINO fe tqntm Ii l-'.
- 1. IDENTIFICATION OF.. 2. AFFECTED OUTFALLS -.
4.FINALCOM-CONDITION,.
- 3. BRIEF DESCRIPTION OF PROJECT' A
AGREEMENT, ETC.
-a iNO 7
- b. SOURCEOFDISCHARGE
- 8. RE-OUIRED JECTED NA NA NA NA NA IUNAL:.YOU may wisn to anacn adodional sreets descnribg any additional water pollution control programs (or orner environmental proIFO J
which may affect your discharges) you now have underway'or which you plan. Indicate whether each pirogram Is now underwa y or planned, and indicate your actual or planned schedules for construction.- '
5 F1M MARK X' IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED.,
E P F o r 3 5 2
~
y 5
.A G
O F C O TI_
O N P A G 3_:_
EPA Form 3510-210 (Rev. 2-85)
PAGE 2OF 4 CONTINUE ON PAGE 3
I EPA l.D. NUMBER (copy from Item 1 of form 1)
- I -
ILD000803643 I>
Form Appvovd. -
OMB No. 2000-0059 Approval expires 12-31-85 CONTINUED FROM PAGE 2 V. INTAKE AND EFFLUENT CHARACTERISTICS - -
A. B.& C:
See Instructions before proceeding - Complete one set of tables for each outfall -Annotate the outfall number in the space provided..
NOTE: Tables V-A V-B. and V-C are IncIuded on separate sheets numbered V-1 through V-9 D.
'Use the space below to list any of the pollutants listed In Table 2c-3 of the Instructions, whIch you know or have reason to believe Is discharged or may be discharged from any outfall. For every pollutant you list. briefly describe the reasons you believe It to be present and report any analytical data In your possession
- a. POLLUTANT
- 2. SOURCE 1.POLLUTANT
- 2. SOURCE NA NA NA NA VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS is any pollutant listed in item v-u a substance or a component oT a substance wnicn you currently use or manufacture as an intermeoaate or final product or byproduct?
I YES flist all such Dollutants below)
I-l X
NOto to Item VI-a)
EPA Form 3510-2C (Rev. 2485)
PAGE 3OF 4 CONTINUE ON REVERSE
CONTINUED FROM THE FRONT VIL. BIOLOGICAL TOXICITY TESTING DATA' Do you have knoviedge or reason to believe that any biological test for acute or chronic toxicity has been made on any of you discharges or on a receiving water in relation to your discharge within the last 3 years?
X -
1 Y
YES (identify the test(s) and describe their(purposes l
NO SectinIIIP' VilI. CONTRACT ANALYSIS INFORMATION-Were any of the analyses reported In Item V perfonned by a contract laboratory or consulting firm?.;
l E]
IYES (list the naie, address, and telephone number of. and,.
go to Sectin V9.
lluitants analved hiV iarh siuh ahnratnrv orn firm ow)*
C. TELEPHONE D. POLLUTANTS ANALYZED
- ANAME
- B.ADDRESS'(~aoenJ-(it (area code 8no.)
(it Test America 850 W. Badtlett Road, Bartlett. IL 60103 (847) 783-4960 All except pH. TRO. Oil & Grease, &
TSS IX~ CERTIFICATIO I certify under penaly of law that this document and all attachments were prepared under my direction or supervision /n accordance with a system.-;
designed to assure that qualified personnel properly gather and evaluate the Information submitted. Based on my inquiry of the person or persons who.
manage the system or those persons directly responsible for gathering the infom'ation'submitted is, to the best of my knowledge and belief, truie accurate. and complete. lam aware that there are significant penalties for submitting false information, including the possibility of fine and Imprisonrnent for knowing violations..
A. NAME & OFFICIAL TITLE (type orprint)
B. PHONE NO. (area code & no.)
Susan Landahl / Station Manager 815-415-3700 C. SIGNATURE D. DATE SIGNED EP Fo_3502 (Rv. 2.85)
PAG 4~
OF 4 EPA Form 3510-2C (Rev. 2-85)
PAGE 4OF 4
EPA ILD. NUMBER (copy from Item Ilof form 1)
I[,.
1LD000'863643' Form ApMved. -.
0MB No. 2000-0059 Approval eynimes 12-31.85 Pli-as nrint or tvne in thp unshad1ed arpaq nnIv_
FORM
-U.S.ENVIRONMENTAL PROTECTION AGENCY,,
~~~ flA ~
~
.-:,;'APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER."
L J.E~~~
EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS NPDE Consolidated Permits Program
- 1. OUTFALL
~~~2.OPERATION(S) CONTRIBUTING FLOW.
- 3. TREATMENT
- b. AVERAGE FLOW.
~~~b.LIST CODES FROM NO (list) ~..aOEAIN (1ist) bAVRGFLWa.
DESCRIPTION.
'A (nclude unfts) -~--
TAL 2C-1 C01 Wastewater Treatment System Effluent 0.021 MGD Oil/Water Separation, X*X (Turbine Building Fire and Miscellaneous Non-Equalization, Coagulation, --
X-X 2-D Ridioactive Waste Sump, Demineralizer Make-Flocculation, Sedimentation.
1-G 1-U.1 up Water Filter Backwash, Diesel Fuel Storage Multimedia Fiftatn,.
1-0 and Service Water Building Sump. Auxiliary Sludge to Drying Beds.
5-H 1-
-Boler Blowdown, Demineralizer Regenerant On-Site Storage
.X-X.
Waste, Water Softener Regenerant Waste,.......
-- Heating Bay Building Roof Area, Fire Protection....
.- System Maintenance, Service Water System
.-Maintenance, Domestic Water System Maintenance, Clean Condensate System
-Maintenance.
Laboratory Uquid Wastes.,
.Station Heat System Condensate)
D001 -. -
Cooling Water Intake Screen Backwash
.Screening,.
.I
-T..
(Cooling Pond)
E01 Unit 1 and 2 Radwaste Treatment System Intermittent Fabric Filtration. Charcoal Filtration X-X.-
X-X Effuent (Equipment Drains In the Turbine..
Equalizationj on Exchange X-X..
2-J inxiliary and Reactor Buildings; Floor Drains Reuse/Recycle of Treated Effluent 4-C,.
inthe Turbine, Radwaste. Auxiliary____
-and Reactor Buildings;..
Condensate Polisher Wastes from the Turbine
_________Building; Decontamination and Laundry Waste)..
Fol Auxiliary Reactor Equipment Cooling and
-. Intermittent.
Evaporative Heat Dissipation X-X Flushing Water
.~-
G01-North Site Storm Water Runoff (Fire Protection.. nlermittent Oil/Waler Separation X-X System Flushing IMaint..[Alt. Route], Service Sedimentation
. 1U____
Water System Flushing/ Maint. [AKt. Route],.
Domestic Water System Flushing and Maint.
(Alt. Route]. Clean Condensate System Flushing and Maint. (Alt. Route] North Site Uncontaminated Stormwater Runoff)..-____
H01 SouthJ Site Stormwater Runoff (Fire Protection... Intermittent
-Oil/Water Separation X-X
- System FlushinglMaint..[Aft. Route]. Service Sedimentation.-.
1-U Water System Flushing/Maint. [Alt. Route],...
Domestic Water System Flushing and Maint..
(Alt. Route]. Clean Condensate System -.-
-.. Flushing and Maint. [AILt Route] South Site_____
Uncontaminated Stormwater Runoff)
OFFICIAL USE ONLY (effluent guidelines sub-cate"re)
EPA i~O1 asiO-c (Nov.245)
P~~iE D ~XM AU EFA I-OrM 3510-ZE; (Rev. Z-a5)
I-Alit I Ul 4 (GUNJINUFU FRUM PAUE 1)
EPA I.D. NUMBER (copy from Item I of form t)
PlPeae rint or tvne in the unshaded areas oniv I
LD000803643 Form Appwad OMB No. 2000-0059 Approval Pynirnq 192.11.A5 FORM P
EIN U.S. ENVIRONMENTAL PROTECTION AGENCY APPUCATION FOR PERMIT TO DISCHARGE WASTEWATERs; ;- /: 9.x:\\ x.;.
E,::
P.
n
- . EXISTING MANUFACTURiNG, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS NPDES Consolidated PermitsProgram
- 2. OPERATION(S) CONTRIBUTING FLOW..
- 3. TREATMENT.
- 1. OUTFALL NO (lIs)
- a. OPERIATION (list)
\\
(includv.-aDESCRIPTIOb.
AVERAGE FLOW a DESRIPIONb. LIST CODES FROM (include units)
~~~~~~~~~TABLE 2Cf-1 101 Reverse Osmosis System Reject Water 0.003 MGD Multimedia Filtration.
1-0 Reverse Osmosis I-S Electrodeionization X-X 002 Illinois River Make-up Water Intake Screen Intermittent Screening 1-T Backwash OFFICIAL USE ONLY (effluent guidelines sub-categories)';
E. Fom.1-C(e.25 AE1O CNIUDFO AE1 EPA Form 3510-2C (Rev. 2-85)
PAGE 1 OF 4 (CONTINUED FROM PAGE 1)
PLEASE PRINT OR TYPE IN THE UNSHADEO AREAS ONLY. You may repaot some or all of this Information on separate sheets (use the same format) Instead of completing these pages.
SEE INSTRUCTIONS EPA I.D. NUMBER (copy from Iteml of Form 1)
I ILD000803643 Form App tved OUB No. 2000-0059 ADDovtal erpfrs 12-31-85 V INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C)
OUTFALL NO.
001 PART A -
You must orovide the results of at least one analysis for everv nollutant In this table. Comolete one table for each outfall. See Instructions for additional details.
l ART A-Z EFLEN r--2.
EFFLUENT 3.UNITS
- 4. INTAKE
- 1. POLLUTANT
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAYVALUE
,.. c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS.
- a. LONG TERM,
- d. NO. OF I.P.OLLUTANe(ifALUE n wahvola.
ANAL-TRATION AYERAV - VALUE ANAL-(i)
(2) MASS (z}
g2) MASS
{i)
(2) MASS YSES
<() CONCEN-r 2)MASS YSES co"CrNMMR CON coMSW RATION..- snO--
- b. Chemical Oxygen Demand (COD) mg/L Ibsiuay
- c. Total Organic Carbon
, s (TOC)
T~~~c).,.
. ~~~~~~~~~~~~~~~~~~~~~mgA.'
Is/day.
d. Total Suspended Solids dI TSo mg/L -Ibs/day e.Ammonia 0.30 118.25 1
mgQi Ibs/day VALUE 85V1 ALUE VALUE 47.2 MGD VALUE
- g. Temperature VALUE 19n4 VALUE VALUE oc VALUE winter)
- n. Temperature VALUE 361 VALUE VALUE o
VALUE (summer).
._C-i~~pH
~~~MINIMUM lMAXIMUM MINIMUM lMXXIMUM
==.SADR NT X
l.pH 7 U8!A 9I.U
- 7.
STAN DARD UNITS PART B -
Mark X in column 2-a for each pollutant you know or have reason to believe Is present. Mark WX In column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant vwhich Is flmlted eIther directly, or Indirectly but expressly, In an effluent lImitatIons guIdelIne, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT
- 2. MARK
- 3. EFFLUENT
-4.UNITS
- s. INTAKE (cptbneg AND CAS.
- b. BE-C. BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER-LtM LAW M
VLU-amibii ANAL-TRATION R~
VLUE..
ANAL-('lveable)
SENT SENT (1)
(2) MASS
(')
(2) MASS (C I (2) MASS YSES
.ONCE (2) MASS YSES
- a. BromIde,-
- g.
b/a (2495947-)
X
.100; 394'
.1 mg/L_.
Itis/day (24959-7-9)
X___________
ReTsidual X
0.04 15.767
< 0.02 c 7.883 0.01 4.927 24 mglL Ibs/day
- c. Color X
5 1
Pt-Co
- d. Fecal Coliform X
- e. Fnuorlde X
0.53 209 I
mglL.
lbs/day.
l :.__._
.(16984a-84)
X 4.6-1821 i
mI D
C I. Nm-ate-Nitr~~te X
4.6 1821 g/L lbs/day, (as M)
X._____________
EPAForm 3510-2C (Rev. 2-85)
PAGE V-1
. lure 1 friur W1 Prvr-Kar_
ITEM V.B CONTINUED FROM FRONT
- 1. POLLUTANT
- 2. MARK W
- 3. EFFLUENT l
4.UNITS
- 5. INTAKE (optio AND CAS b BE-c E-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER ULEVE urVED 0
VALUE fievalebleJ ANAL-TRATION AVERAQ F VALI ANAL-(t vailabbJ) RSENT SENT CON (2) MASS I)N (2) MASS (1)
(2) MASS YSES (1)CONCEW (2) MASS YSES
- g. Nitrogen. Total X
0.69 272 mg/L lbs/day Organic (as N)
___0_69_
_272_I______
- h. Oil and Grease X
< 5
< 1971 1
mg/L lbs/day L. Phosphorus (as P), Total X
0.7 288 1
mg/L lbs/day (7723.14-0)
- 1. Radioactivity (1) Alpha, Total X
3 1
pCUL (2) Bela, Total X
15.7 1
pCUL (3) Radium, Total X
0.8 1
pCUL l (4) Raoium 226.
X
< 0.1 1
pCUL kc. Sulfate (as SO 4)
(14808k79-8)
X 94 37052 1
mg/L lbs/day I. Sulfide (as S)
X M. Suifile (as SO3) x (1426646-3)
X
- n. Surfactants X
< 0.03
< 12 1
mg/L lbs/day
- o. Aluminum. TotalX036141 (7429-90-5)
X 0.360 142 1
mg/L lbs/day
- p. Barium. Total X
0.028 11.0 1
mg/L lbs/day (7440-39-3) x008 1.
- q. Boron, Total x
0.235 93 1
m/
b/a (7440-42-8) mg/L lbs/day
.Cobalt8 Total X
<0.020
< 7.9 1
mg/L lbs/day (7440.48-4)__
s.Iroin. Total X
0.540 213 1
mg/L lbs/day (7439.9-)
___0
__40 213__
L Magnesium. Total x
21.5 8475 1
mg/L lbs/day (7439-95-4)
- u. Moltdenum.
X
<0.020
< 7.9 lmg/L bs/day Total (7439-98-7)X 0.2 C79
- v. Manganese. Total X
0.031 12 1
mg/L lbs/day (7439-96-5)_
- w. Tin. Total x
< 2.0
' 788 1
mg/L lbs/day (7440. 31-5)
__l X
0_1sNN
- x. Titanium. Total x
< 0.02
< 81 mg/L lbs/day VUD-32-6)
I I MU~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~&ATINUF On PAGE V.3 EPA Form 3510-2C (Rev. 2-85) rant V-&
1EPA I.D. NUMBER (copy from item I of form i) OUTFALL NUMBER
- l.
~~ILD000803643 l'
001
.1
- Form Approved.
CRMB No. 2000-005 ApproveI CONTINUFnl PRnU PAr.F!' nP VnV~U IJ1 ww ay O r
v r- -n m
I II ivv f
PART C -
if you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 In the Instructlons to determine wthich of the GC/MS fractions you must test for. Mark X In column 2-a for all such GC/MS fractions that apply to your Industry and for ALL toxic metals, cyanides, and total phenols. if you are not required to mark column 2-a (secondary Industries, nonprocess wastewater outfalis, and non-requIred GCIMS fractions). mark X In column 2-b for each pollutant you know or have reason to believe Is present. Mark v In column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that ponlutant. If you mark column 2b for any pollutant.
must provide the results of at least one analysis for that pollutant If you know or have reason to believe It will be discharged In concentrations of IO ppb of greater. If you mark column 2b for acroleln, acrylonitrile, 2,4 dlnitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b-you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part: please review each carefully. Complete one table (afl 7 pages) for each outfall. See
-Instructions for additional details and requirements. -
- 1. POLLUTANT 2 MARK X
- 3. EFFLUENT 4.UNITS.
- 5. INTAKE (opkaI.
AND CAS
^
TEST. b. BE-c BE-a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER O REV D.
ol a
eV M
VALUE rtfe..
ANAL-TRATION E
VALUE ANAL-(Wevalable) --
ED -
SET (2)MASS
((2)
MASS 2 MS-S
..)
(X)
CONES (2)SS YS ES METALS, CYANIDE, AND TOTAL PHENOLS IM. Antimony. Total
,.1 0
' 39
-lbslday (7440-36-0)
X
,0.0 397 mgIL
-bs/day 2M. Arsenic. Total X
' 0.0050
' 1.97 1
mgIL Ibstday
( 74 4 0 3 -2 3M. Beryllum, Total
' 0.000
' 1.9 1
mgI Ibsfday (7440-41-7)
X
'_ 0.0450 1697 mg/
lbs/day M. Cadmium, Total X.
0;030 30 9 11.8 1
mgIL lbsfday (7 4 4 0 -4 3 -9 )
5M. Chromium, Toata X
0.040
'C 16 1
mgfL Ibslday (744047.3)
X
' 0.0002 6M. Copper, Total X
' o;0i0
' 7..
1 mgI tbslday (7440-50-8)
X 00050
< 7.9 I
rg 1
m Ibiday 7M. Lead. Total X
1 (7439-92-1)
X 0.0 mg s/day X_
=_
_ 0. 0 5 0
_ _ 2 0 _1 m g,I L b s /d ay =
8M. Mercury, Total X
'C 0.002 F
0.07.8 1
mgI Ibslday-(7439-97-6) 9M. Nickel, Total X
0.010
- 3.
9
.1 mgI Ibslday=
(7440-02-0)
X 4
g/L lbsday OM.
Selenium I
Total (7782-49-2)
XC o.ooso
' 1.971mg L
I s d y_
I
.Slvrder. ota-l X
I l7i4 Sil2e4rTo X
0.040 16 mg.L
_bsday 12M. Thallium, Total
. 1' gL b ~ a 13M. Zinc, Total X
C 0.050
<C 20 1
mgiL Ibsfday (7440-6 "- )
i4M. Cyanide, Total X
< o.605
< 2.0
.1 iingl 1bslday 15M. Phenols. Total X
i.1 ngIL lbslday____
2,3,7,8-Tetra-1 jDSCRB ESULTS chlorodibenizo-P-I DlqxIA (1764-01-6 1
EPA Form 3510-2C (Rev. 2-85) t o
PAGE V-3.
7 -!.,
I I
r I
I
.II1,-..
i CONTINUE ON REVERSE
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X l
- 3. EFFLUENT 4.UNITS
- s. INTAKE (Opwan AND CAS
, IEST.
D. BI c BE.
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF ING RE-ILIEVW UEVED NUMBER OUR R IMEV (ASavalab/e)
VALU E 6 avealoel ANAL-TRATION AVE VALUE ANAL-(IevaiableJ DS SEW (2)MASS(2 MncFTASS o
(1 (2)15 COCETASSN YSES T
R A
T CONEN (2) MASS YSES GCIMS FRACTION - VOLATILE COMPOUNDS lV.Aaoiein(107-02-8)
X 2V. Aab4rWte(101.13-1)
X 3V.Benzmen(71.43-2)
X 4V.D4C(ChomeI) x EDw (54245-1)
(75-25-2) i x
- 6. Can totraure_
(5&23-5)
(10690-?n X.
8V. CnX meowu(t24-481)
X (TS0 h-3 e
x lW.2-C*oroeBtq~vfi4x e"W(l10.754) x 1iV XCor.
m.
(6716==3)
X 12V. Dkr Xr.
mpS-(15.2741.4 13V. Dh x
14V.
1-06whlr m
(75.34 )
ISV. 1,243f oroeXane (107.06-2)
I 1.1.-0i~mdrom,4an x
(7515-354)
I6V. 1,2-D4drqmm x
(78-7-5)
ISv.lI..ODktor0.
propoenW(542-7546)
X I9V Eft~bwazmane (100o.41 2W.
V Me 21V.MaedftW x
(74417-3)
PflIfl IS:lI nU DAItF VA EPA Form 3510-2C (Rev. 2-85)
PvAGE V-ffi w w n wx ws-r _
i EPA 1.0. NUMBER (copy from Item I of Form 1) OUTFALL NUMBER ILD000803643 001 I
I Fo~m Apmvvwd.
0MS No 2000-OO59 Apprtwa erpkes 12-31485 CONTNINUED FROM PAGE V.A
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT
.4.UNITS
.5.
INTAKE (opfbnal AND CAS TEST.~b. B-E. Q BE-a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG..
- d. NO. OF a.CONCEN
- b. MASS
-a. LONG TERM
- d. NO. OF IN~RE.LIEEDLtEVED NUMBER OUR~. IPRE.
AB-YLUE rfm ybeL ANAL-TRATION AVR VAU ANAL-(If valabfe) ~E EN
SENTl)CON2CMASS (2)MASSSE YSES GCIMS FRACTION -VOLATILE COMPOUNDS (co~ntinue flY. mmens e~d*~dme (
x
&ftorohw* 79-34-5) 24V. TevavdoW~,4e,W
(¶27.18.1)X 25V. Toluem (108-44.3)X eff14e(55 4O.5) j flW. T.tf1t08l~are (79.00.5) 302. Tiecflwo&uJo.
x ffllthW" (75 49 4 31V.'vfr~cdA*d GCIMS FRACTION -ACID COMPOUNDS A. 2-0tomophiaw' (9 9.574)
X_
(1204L3.7) 3A. 2,4-OlmeraffrAwn 4A. 4.6ODW~roAO-ce'eec.
(534-52.1).
(51-28.5)
(m ms795) l0A.Pht8WOpWd IlkA. ZA.4.STedd~oophus xd nNutgI l
RFVP~qP EPA FO"n 351U-2t; (NOV. Z-nl I.
I
. I 7r.
, A.,
Has_, _.M_
I I
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK l
- 3. EFFLUENT l
4.UNITS
- 5. INTAKE (optin AND CAS L TEST 8
-aE
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF (favalase.)
EC SENT (I)
(2) MASS (1)
(2)
MASS (I)
(2) MASS YSES (T)RCONCEW (2)MASS YSES NUMBER I~~
.J!+/-sl~!L...........
~
ANAL-TRATIONTRATMETATXAAL GCIMS FRACTION - BASEINEUTRAL COMPOUNDS LB. ACIWhW x
83.324)
- 38. A'ecm_
x (120.12.?)
- 48.
Benred (924715) x 5s.
senzo~a) e()
X (5-55.3)
Bemoa (a) pyr X
ra.
a.-ez~wti x
(2052992)
(1914242) x
__X_.
9ELBrm k) kWVW x
108.54s(2ch~rootvx-y)x metheAa(il-dt1oeh1) x eOWe (I 1144-4) 12_. X4 (2_0torodo prol)ehe(10240-1)
X
- 13. Sia (2.ear}wel x
pitha>e (11741.7) 141. 44k-Ite phe x
eh r(101.55.3)
I58.&AkqbZ)49t hete x
a WX 1a.
2.C ri.lh.-e s68.,-CwrnpheX t1s. Oazo8h) x ac0e5-3.72-3) 208.1.2-Okbobenze X
(95.50-1) 218. 1.3-tOkm_
raem x
(541t73
_A
_UTInui Isn PAGE V.7 EPA Form 3510-2C (Rev. 2-85)
PAGE Vff wvn l nwc vw rAw_ w-^
fEPA I.D. NUMBER (copy fom item.1 of Form 1) OUFLUMBER 1
I 1~~LD000803643
)0UTALN CONTINUED FROM PAGE V.6 FormAppmowd.
0MB Ao. 2OW-0059 Appmvaf
- expbws 12-31-85
- 1. POLLUTANT
- 2. MARK'X'
- 3. EFFLUENT
__________4.UNITS
- 5. INTAKE (WpbnM AND CAS c.ES-E-a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG..
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER
- ZRET1 VEM VALUEL.......
'a mrobfe ANAL-TRATION E
F VALU ANAL-.
0WR-O¶IR PMt. I()
2)MS 2MAS 71 2)AS YES(1)
COC4CEN (2) MASS YSES GCIMS FRACTION -BASEINEUT RAL COMPOUNDS cotintued)_____
245. D" t hd4rttIo (944-w2) 268. MIN-WY~ ptote.
(84-74.2) 278.2.4-o~rtdtcowe 268B.2.6.Ct**eIcck (2064-20.)
298. mwoI.N-od b ~h~eft-(317.640 Hf XW 358.1.-
p4ex wtooe4 o...
37.dermlne(122-ed-)
(¶18-74.1) 408. NW4exs4O~yo..-
41a.NWeW0Ad4ftef (67.72.1) 428. WNW8vobw pr~ (621-64-x tIn8TINtIF nN RFVFRS~
EPAF0ffn3510-2G(ReV.Z-a5) rp%%Or-V.#
I.
.I
. I
. ;, ; I
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X'
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (opona AND CAS
, lEST.h BEI C BE-
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER OURE UEV.
ALUt.
el.
ANAL-TRATION AVERA VALU.E ANAL-( tV@/)
WED SNT SENT
{
2 1t}1 YSES T
M T
£ ON (2}
YS ES (Wavalable)
NTRA"TI5EN2 (1)
- 2) (2)
MASS C)OMCSSTRSE (IITONCEN (2) MASS YE GCIMS FRACTION - BASEINEUTRAL COMPOUNDS (Continueod 430. N-vkrogo&
ph0 (86-30-6)
X 4S& Fy-(1294M0}
x 46a. 1.2.4nTrW(9 X_
beana (120-82-1)
GCIMS FRACTION -PESTICIDES IP. Aldrin (309-00-2)
X 2P. O-BHC (319-84-6) 3P. O-BHCx (319-85-7)
X 4P. I0-BHC X
(58-89-9)
SP. O-BHC I
(319-86-8)
X 6P. Chlordane X
(57-74-9) 7P. 4.4'-DDT X
(50-29-3) 8P. 4.4'-DDE X
(72.55-9) 9P. 4.4-DDD X
(72-54-8) l OP. Dieldrin (60-57-1)
X li1P. 0-Endosulfan x
(115-29-7) ulan X
12P. O-Endosulfan x
(115-29-7)
X I
I I
I I
II 13P. Endosulfan X
Sulfate (1031-0748)X__
14P. Endrin x
(72-20-8)
=
X I
15P. Endri Alde-x hyde (7421-93-4)
X I
I I
I I
I I
16P. Heptachlor 6(7-44-8)
.vUTIMI ON PAGI v !
EPA Fam Riev 2n ur F
EPA Form 3510-2C (Rev. 2-85)
FAk~s V0
EPA l.D. NUMBER (copy froM Item I Of ForM 1) JOUTFALL NUMBER I
~ILD000803643'I 001 I
FoonAAWpOved, 0AIS No. 2000-0059 Appm'vaI ekpkes 12.31.85 CONmmNUg FROM PAGEr V-8
- 1. POLLUTANT
- 2. MARK '
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optnaq AND CAS a TEST. bf BE.
.BE. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER PRE-.
AtV UFVED evE h
ANAL-TRATION RAG VALUE.
ANAL-(if e)
E)
SENiT SENT Cct EN TION (2} SS
- 2) MASS I
(2)MSS YSES (1) CONCEN.
(2) MASS YSES GC/MS FRACTION - PESTICIDE i(coninuet) 17P. Hepta Epe X
(1024-U53) 18P. PCB.1242 (53469-21-9) x 19P. PCB-1254 (11097-69.1) 20P. PCB.1221 (11104-28.2) 21P. PCB-1232 X
(11141-16.5) 22P. PCB-1248 (12672-29.6) 23P. PCBE-1260 (11096.82.5)
X 24P. PCB-1016 X
(12674-11.2) 25P. Toxaphene X
(8001-35.2)
EPA Form 3510-2C (Rev. 444)
PAGE V-9 EPA Form 3510 2C (Rev. 245)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or al of this information on separate sheets (use the same format) Instead of completing these pages.
SEE INSTRUCTIONS EPA I.D. NUMBER (copy from Iteml of Form 1)
ILD000803643 Form App~ed OMB No. 2000-0059 AmPMVaeyrPies 12-31-85 OUTFALL NO.
A01 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C)
PART A -
You must *rovide the results of at least one ana-vsis for every noilutant in this table. Comnlete one table for each outfall. See Instructions for additional letails.
PART________
- 2. EFFL-ENT Yu_ trelsfaeon o Pltti ab.
EFFLUENT_
o3.UNITS
- 4. INTAKE ion
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG..
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF
- 1. POLLUTANT Jfralane)
V ANAL-TRATION
..LRUAA
.L ANAL-(-)
(2) MASS (1)
(2) MASS (1)
(2) MASS YSES (1) CONCEN-(2) MASS YSES
-_g_
bs/day_
- b. Chemical Oxygen Demand (COD)
- d. Total Suspended Solids 5.5 2.16 5.5 2.16 5.5 2.16 1
mg/L Itisday=
- e. Ammonia Ibs da-'._._.
- 1. Flow VALUE 0.047 VALUE 0.047 VALUE 0.047 MlD VALUE
- g. Temperature VALUE VALUE VALUE VALUE (winter)
-,'_l._,_._._._.
,_C
- h. Temperature VALUE VALUE VALUE Oc VALUE (summery Iu
..M U
MAX MUM STANDARD UNITS PART B -
Mark X In column 2-at eachpollutantyoukncowor have reason to believe is present. Mark X column2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which Is limited either directly, or Indirectly but expressly, In an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT
- 2. MARK X-3.
EFFLUENT - -
4.UNITS
- 5. INTAKE (opebn AND CAS
- b. Be c BE-a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER 0
l7 V
mfvtakl ANAL-
-TRATION AVERAGE VALUE ANAL-(Vaevalebl)
SENT SENTr CON C
E~lRAt(1)
(2) MASS
('I (2) MASS (1)
(2) MASS YSES (1)CONCEN (2)MASS YSES
-2495947 9)
-. X.........
t.
mg/L Ibs/day (2 959-07.9)
- b. Chlorine. Total X
mgI lbs/day Residual MgLIb____
c.Color X
-Ic Pt-Co
- d. Fecal Cofotoiit X.
- e. Fluoride.
e;6984.484)
X 0.46 0.180
_m:
1 mg/
ibsuay._____
f.Nitrate-Niflte X.
0.16 0.063
... 1 tnl lbs/day (qsfJ7~
~~
~~
-_0_
063 EPA Form 3510-2C (Rev.
245) rAUL~~~~~~~~~.....
V-iii on Rvu; EPAFOrM3510-2C(Rev.2-115),
. i t
i PAGEi Ve1 I
I I
I.
i
.L
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT
- 2. MARKWX
- 3. EFFLUENT I4.UNITS
. INTAKE (optSInAo AND CAS
- b. a-eE
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF LUEVED UEVE NUMBER M.
Nf__
(Wava!abe VALUE mi aralabl.) ANAL-TRATION AVERAGE VALUE ANAL-(lavelable)
SENT SEW
()
(2) MASS (I)
(2)MASS (1)
(2)UA5 S
(IIOcEN.
(2)UASS YSES
- g. Nitrogen. TotalX<04 0151 Organic (as N)
X c 0.40
< 0.157 1
mg/L Ibstday
- h. Oil and Grease X
1 0.392 4
mgtL lbs/day
(. Phosphous (asP), Total X
0.03 0.012 1
mg/L lbs/day (7723.14-0)x
- i. Radioactivity (1)Alpha, Total X
< 3.00 1
pCitL (2) Beta, Total X
5.00 1
pCitL (3) Radium. Total X
2.20 1
pCitL (4) Radium 226.
X 2.60 1
pCUL
- k. Sulfate (as SO,)
X 680 266.7 1
mg/L lbs/day
- 1. Sulfide (as S)
X
- m. Sulfite (as SO 3 )
X (14266-46-3)
- n. Surfactants X
< 0.07
< 0.027 1
mg/L lbs/day
- o. Aluminum. Total x
< 0.3
< 0.118 1
mg/L lbs/day.
(7429.90-5)
- p. Barium, Total X
< 0.1
< 0.039 1
mg/L lbs/day (7440-39-3)
- q. Boron. Total X
0.31 0.122 1
mg/L lbs/day (7440-42-8)
- r. Cobalt. Total X
< 0.05
< 0.020 1
mg/L lbs/day (7440-48-4)
- s. Iron. Total X
0.82 0.322 1
mg/L lbs/day (7439-89-6)
- t. Magnesium. Total X
15.4 6.040 1
mg/L lbs/day (7439.95-4 )
Total (743yd98n)
X.
< 0.2
<0.078 I
mg/L Ibstday
- v. Manganese, Total x
< 0.003 c 0.001 1
mg/L lbs/day (7439-96-5) w.Tin. Total X
< 0.8
< 0.314 1
mg/L lbstday (744G-31-5)
- x. Titanium. Total X<
0.8
< 0.314 1
mg/L lbs/day
.(7DN-32-6)
I n~~~n~~~,,
£~~~~~~~~fnlNtwNI nN PAGE V-3 EPA Form 3510-ZC (ROV. Z-85) r^%Jr V-x
EPA I.D. NUMBER (copy from Item I of Form 1) OUTFALL NUMBER I I.LD000803643
.1 A01 Form Appmved.
OAE8CU No. 2O000O059 Appw'ovl
- rpkss 12-31-85 CONTINUED FROM PAGE 3 OF FORM 2-C PART C -
if you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 In the Instructlons to determine which of the GCIMS fractions you must test for. Mark X' In column 2-a for all such GCIMS fractions that apply to your Industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary IndustrIes, nonprocess wastewater outfalls. and non-required GCIMS fractions), mark X In column 2-b for each pollutant you know or have reason to believe Is present. Mark *X In column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe it will be discharged In concentrations of 10 ppb of greater. If you mark column 2b for
,tacroleln, acrylontrile. 2,4 dinitmrphenol, or 2-methyl4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherwise. for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions for additional detanls and requirements.
- 1. POLLUTANT
- 2. MARK X Il_
- 3. EFFLUENT 4.UNITS S. INTAKE (otobns AND CAS TEST-b. -BE-E-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER am.
pr.
7 hb e
)VALUE i
!favleb ANAL-TRATION AVERAE VALUE ANAL-
()
(2)MASS (1)
(2) MASS (1)
(2)MASS YSES(
YSES
_~~~~~~~~~~~c~~~O CONCENrrRnO0 COWCENMTM noMTMAwO METALS, CYANIDE, AND TOTAL PHENOLS 2M. Antlmony, Total X
I 0.5 c 0096 1
mg/L lbs/day (7440-.36.)
X_0.c 0.01 2M. Arsenic Total X
' 0.00 0.0004 1
mg/L Ibs/day (7440-38-2) 3M. Beryllium. Total X
0.022 0.008 1
r7440-41o9)
X 0.004 0.004 I
mg/L lbs/day 4M. Cadmium. Total X
0.00029 0.00008 mg/I lbs/day (744043-9)
^
X 0.0010 c 0;0004 I
mg/L bs/day 5M. Chromium. Total X 0.022 0.0086 I
mg/L Ibs/day._
(7440-47-3) 6M. Copper, Total 000 (7440-50-8)
~
X0.004 0021 mg/I lbs/day________
7M. Lead, Total X
=0.005
' 0.0020.1.mg/.
lbs/day 4_mglL__
(7439.92.1)i a
X
-c 0005
-0.0020
.4 mglL Ibstday 8M. Mercury. Total X
0 (7439-97-6)
X0009 0004mt b/a 9M. N~~~ckel. Total ~~~~0.029
'0.011
.1 mg/I' lbs/day (7440-02-0) 10M. Selenium,.
m[
Total (782-49.2) X
<'0.001
.0 41 mgI lbs/day_____
1 M. Sliver. Total --
X X
- -0.000 0.6002 mg/I lbs-day (7440-22-4) l I
I_,tN UOR S
12M. ThallIum. Total x'001
.041
'mg/I lbs/day (7440-28-0)
X_
13M. 23nc. Total X-1 0.36 0.141
.mg/L.
lbs/day____
I4PA.Cyande,
~al X'
'0.008' -
0.003
'4
- mg/L lbs/day (57-12-5) 15M. Phenols. Total X
.0 002.4 mgI lsdy___
DIOXIN-.---*
2,3.7.8-Tetra-X.
~
IDESCRIBE RESULTS chlorodibenzo.
1 I
Oloxift (i764.01T8 i...........I
.,nmul o c%
Drurpwa.
EPA Form 3510-2C (Rev. 2-85)
I -
PAGE V-4 I-.-..--
I.
- 1. :
I
I
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X_
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optiona AND CAS a T3 t t
-B&
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER ttsst RE rvEON LIEVED (VALUE
_avabe ANAL-TRATION AVERAC VYALU E ANAL-(NavableR SENT SENT
()
(B
- 2) MASS (I)
(2) MASS (2)
YSES
.(1)
CONCE (2) MASS YSES GCIMS FRACTION -VOLATILE COMPOUNDS IV. Aaeok (107-024)
X 2V.Aae(10v7-t3-I }X...
NV.Benzene (7143.2)
X WV.tBi (CwX
.)
Erw(542248-I)
Sv. an)10oimx (75-25.2)
By. Carton tetad~ordex (5-234) x Nv. CN oOOa z (10840-7)
X aV. Clilrod~romfo.
maheo (1244&1)
X (1750-0)
IIV. Ctkwormx (6748.3) x 12V. D
-r_
mW" (75-27-4) moth (75-71-4) 14V. 1.1-,40ihlro39l48n (75.344,)
x 1sV. t24 e
dXoroem (107.62)
W8. I.l-4dk~wvod1vien (75.35.4)
X ITV. 1242iddropropuen (78.7-5)
ISV. -vokttoro.
>pyeu (542.754)
X (100-41.4) 21V. me"l aorwe x
1 flfl
-llJt 1 lb UAdC %1-EPA4.4 For 3502 (Rv 2-5 1'U EPA Form 3510-2C (Rev. 2-85)
PAWE V-4 I -
~EPA 9.0. NUMBER (copy from Item I of Frm. 1) jOUTFALL NUMBER I.
Form Appm'ved~
OUB No 2000-059 AppmwsI empk'ss 12-31-85 r-flUT1P~ttfl irnflU DAMT: V.LA
- 1. POLLUTANT
- 2. MARK X 3_____
_EFFLUENT_
4.UNITS
- 5. INTAKE (ofbt afl AND CAS ma TEST-b. BE.
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF 8. CONCEN
- b. MASS a LONG TERM
- d. NO. OF NUMBER ~~~~~~~~
"~~~~'~~
'~~~~
~
~
~ ~~
~~VLUEFmebe ANAL-TRATION A
RQE AU ANAL.
(if evelable)
EDSNTSNT___AS_2_MS
()MAS YS(I)
CONCEN.
- (2) MASS YSES GCIMS FRACTION -VOLATILE compOUNDS (continud).
24V.Tetrad4x0WB,4eme 25V.To~ueWb(l05.883)X 26V. 1.2.Traw4-dhlor0.
x 28V. 1.1.1.Trktd*roelhw*
.X 2W. Tjct~mdkroet,-en (75.014)
GCIMS FRACTION -ACID COMPOUNDS________
2A. 2.4-CNorpherd
.X (120.83.2) 3A. 2.4-0DkreBhenc4 IAk 2.4-.OMf~lh~ecl X
(51.28.).
IA. 2-N~tvmpaw (8875.5)
(1500.27) 10&PhieM(108.95.2)
-X-CONTINUE ON REVERSE EPA Form 3510-2C (Rev. 2-85) -
.; I I -r^..
.-
k
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK W
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (opionaso AND CAS TEST.
b.8E-c 8E
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF INGR UVDIUEVED NUMBER QUIP AS U
U.
(i
.VALUE I' eiveleble)
ANAL-TRATION AVE RAG ALUE ANAL-SENT I s~a I (I)
(2)&WM~
(I)
(2) MASS (1)
(2) MASS YSS(l)CO I.
(2) MASS YE (Iavaable)
ED SEW CONCETRATI S
CCENTRATION M
YSES N
YSES GCIMS FRACTION - BASEINEUTRAL COMPOUNDS
- 28. Acavoptho4en (83-2-9) x.
(208-98")
- 38. Arac^efv (2012 x7 A
4*. 84(izdeu (924745)
X soo(a) &~vabcane (5&55.3) x
- 68. 8erz (a) pyrrwnX_
(li1.24-2) 100. Di (2d
.y) x
((111-98d2)
X 128. SW5 (2gNomla p
4-)
xs(10240.1) 138. Be=(24
.)
X4.w x
pftuem (1171-7) 148, 4-(I1 -444) x 041W (101 5.5!
- 3)
X_
1213. is (2-d 4t0i~s (85 8 aw (1024__
138. Bi 2-CNsW i~i51s (96h8t 2
O 178.4CIw0W$1Iw, ws 700t572-3)
( 2 1 8- 0 1.)
V ta GUt (53-70.3)
X__
208. 1.0-O2c4) f x
(_v50n1).
21B. IA3-0d00UUW5sn x
(541-73-1) r'nL~~~~~~~~~~~~~~~~~V M1LJII 1 All VAr-.D VL1 EPA Form 3510-2C (Rev. 2-85)
If"Av V0
-v w
ucv row w-
CONTINUED FROM PAGE V.8 EPA I.D. NUMBER (copy from Item I-of Form 1) 1OuTALL NUMBER I
FottAppmved.
0JW8 No. 2000-0059 ApmovaI D~NPs 12-37-85.
- 1. POLLUTANT
- 2. MARKWX
- 3. EFFLUENT 4.UNITS_
- 5. INTAKE 10otfbns AND CAS LT.sT-I 1-
- a. MAXIMUMDiAILY VALUE
- b. MAXIMUM 30 DAY VALUE
-c.LONG TERM AVRG.
- d. NO. OF a.CONCEN
- b. MASS
-a.
LONG TERM
- d. NO. OF NUMBER LREVOLIVD_________f I
L
-VALJUE I jvrar ANAL.
TRATION RAG.VYtUE ANAL-DUIR-I Ps!- I Afl.
(if mvable)
ED SETSN
~ 1)T 2
AS()MS 2
AS(I)
CONE (2) MASS YE GCIMS FRACTION -BASEINEUTRAL COMPOUNDS (cniued) 238.3Z.TDldkro bw~ednzo (91-44.1)'
2480 4~tW.
-x
-~f (131.11.3)
X1 (W&620-2) 318. Pkour&W*e~
328.Fluor e. (W6 -73 )
338.1t0ediwob~er""~
(116-74.1)
Petde (77-47.4) 3M. H4aadti0~
(67-72.1) x 378.1 bde I(i.2.3-cd),..
X.
pyi-e (193-39-5) 3918.
NnV it6er a (91.20.3) 41s. N.N6,0*"eft146v4 of IN (62.75-9) 4 5
j4 J x
N0_
pro~mW-614l f-mmu~~~~~~~~~~~i'~rl Wr nu pc1WDQ I
EPA Foml 3510-2C (Rev.- 2-a 5)
""r- !,.
.1 I I
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (oplonal AND CAS cTEST. b BE-I 8E-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER NG p UEVEt3 UEVED (flava VALUE mis avlbly)
ANAL-TRATION AVERAr _ VALUE ANAL-(wavalabI.)
ED SMTS WNT TT CONC MATT SSN (r)
(2)}
MASS (z)W2 YSES (1)
(2)
MYYSES GCIMS FRACTION -BASEINEUTRAL COMPOUNDS fc)inuen 438 N-N&osod-sefl4W8(6-0-6)
X
"_. Ph.anthre 45.Pyre(e1129.00
)
X
- 6813 2.4-Tnlr-b88a. en128om2-1) x GC/MS FRACTION -PESTICIDES 1 P. Aldiin (309-00-2)
X l
==
=
l 2P. 0-BHC (319-84-6)
A 3P. o-BHC x
(319-85-7) 4P. O-BHC x
5P. 0-BHC x
(319-86-8) 6P. Chlordane x
(5 7.9) 7P. 4.4'-DDTx (50-29-3) l 8P. 4,4 -DDE x
(72.55-9) 9P. 4.4~-DDD x
(72-544) l OP. Diledrin x
(60-57-1) 11P. O-Endosulfan I (115-29-7) 12P. O-Endosulfan x
(115-29-7) 13P. Endosulfan l
Sulfate (1031-074) l 14P.Endrln x
(72.20-8) 15P. Endrin Alde-x hyde (7421-93-4) 16P. Heplachbor x
(76-444)
I AU DA.g 1V.0 EPA Form 3510-2C (Rev. 2485) rAur Vt0 wvn @ znuc vn rovi w-w
EPA I.D. NUMBER (copy from Item I of Form 1) OUTFALL NUMBER I.LD000803643' A01 I
Fom Appoved.
OCU No. 2000-0059 Apprval eomfs 12-31485 CONTINUED FROM PAGE V.8
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (opWbno l
AND CAS
- a. TEST. b. BE-c.8E.
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER I m. I PRE.
AS.
palable)
VLUEi m1al ANAL-TRATION RAGE VALUE ANAL-(if waulabe)
J sEDj SENT SEN
(
(2) MASS
(
(2)MASS (1)
I
- 2) MASS YSES (t)CONCEN.
(2) MASS YSES Ct3NCENIRAXION
~CONICP(MT-ON CONCNRTION TRATM3t GCIMS FRACTION
- PESTICID (continued)
I lP.
H"pWad*t Epoiwde V
(104-5) 1tP. PCB-1242 (53469-21-9) x 19P. PCB.1254 (11097-69-1) x 20P. PCB.1221x (11104.28-2)
X 21P. PCB-1 232 X
(11141-16-5) 22P. PCB-1248 x
(12672-29-6) 23P. PCB-1260 (11096-82-5) 24P. PCB-1016 (12674-11-2) 25P. Toxaphene X
(8001-35-2)
EPA Fofm 3510-2C (Rev. 4.84)
PAGE V-9 EPA Form 3510 2C (Rev. 2485)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or an of this Information on separate sheets (use the same format) Instead of completing these pages.
SEE INSTRUCTIONS W
i EPA LD. NUMBER (copy from Item i of Form 1)
Fom Appvend 110000803643 OMa No. 20004059 I_
LD0834 Appdevaf aes 12431-85 OUTFALL NO.
l01 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C)
PART A -
You must provide the results of at least one analysis
- 1. POLLUTANT
- 4. INTAKE lodionan
- a. MAXIMUM DAILY VALUE
- 4. INTAKE foot 1017 80
-t
~I
- ~
rmR5.....
ANAL-veAc!
TRATION
... a. LONG TERM 1"aVERA9F VAUE (I}
CNC£N(21FA^SS
- d. NO. OF ANAL-
-I,,
it) MAZIb
- ll 121 MA5b I) 00 (2) MASS cotrrTPON LGEMENTRATI(W
- rFUcr7 I
at.
_.,,.rei (2)~~~~~~~2 MASS
- a. Carbonaceos Biochemical Oxygenoemand(CBOD) 12.0 1.44
'10.1 1.22
< 6.8-
' 0.81-24 mgQL Ibs/day
- b. Chemical Oxygen.
Demand (COD)
._gb/a_
- e.
Total Organic Carbon d..
I (Toc) m g Q I lbs/day
- d. Total Suspended Sollds 32.0 3.85 21.5 2.59 10.6
' 1.27 24 mg/I Ibs/day
- e. Ammonia 0.30 0.04 I
mg/Q Ibs/day VALUE VALUE VALUE VALUE-
- f. Fw -VALUE 0.074 0.023 VALUE 0.014 MGD
- g. Temperature VALUE VALUE VALUE O
VALUE (winter,
- -_;_:_._C
- h. Temperature VALUE VALUE VALUE
-c VALUE (summeIrVAU l pH
.. i
... MINIMU MAXIMUM MINAXIMUM XIMUM 24 STANDARD UNITSTS_
PART B -
Mark *X in column 2-a for each pollutant you or have reason to believe is present. Mark
- in column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which Is limited either directly. or Indirectly but expressly. In an effluent limitations guideline you must provide the results of at least one analysis for that pollutant.' For other pollutants for which you mark column 2a. you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT
- 2. MARK X'
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (opbnl AND CAS
- b. BE.
C. BE.
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER.
LIEVM. UEVEDO 2t 19I)
VALUE i mi1 ANAL-TRATION AVERAGE VALUE ANAL-
' ati9l9eJ sM sENT I' (2)
(2)MASS 2
-MASS (1)
(2)tMASS (1)
CONCE (2)M YSES SENT ssN OW NTRTMTYSENSSE
- a. Bromide m
(24959-67-9)
-_...X..m sb.Chlone. Total X
. ;.0.30
.0.036 mg/L lbs/day-Residual
- c. Color X
10-
.I _
Pt-Co-
- d. Fecal Coilform X
92.00 (16984.48.8~
X 0.36-0.043 I.
mg/I Ibs/day I; Nlrate.
te X
.40.00 4.812 mg/
lbs/day XrA I-arm S~1U-L~
~iiuv.
~a~J PAUE V-i CONTINUE ON REVERSE rrA rarm.53lu-ZU tKov. Z-051 FAUft V-1 CONTINUE ON REVERSE
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT
- 2. MARK X l
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (otin AND CAS b BE-G BE-
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF LIEVED LIEVED Ifo NUMBER PRE.
AD___
(aVae 1 VALUE i FiY ANAL-TRATION AVERAC E VALUE ANAL-(tava abie)
SENT SENT (0)
N (2) MASS
)
(2) MASS (I)
(2) MASS YSES (1) CONCEH (2)MASS YSES
- g. Nitrogen, Total x
1.87 0.225 1
mgtL lbs/day Organic (as N)
- h. Oil and Grease X
' 5
' 0.602 1
mg/L lbs/day I. Phosphorus (as P), Total 5.28 0.635 1
(7723-14-0) 5.28
___0_635
______mg/L lbs/day J. Radioactivity (1) Alpha, Total X
3 1
pCU/L (2) Beta, Total X
36.0 1
pCi/L (3) Radium, Total X
1.2 1
pCUL (4) Hadiu 226.
X 0.4 1
pCi/L Total
- k. Sulfate (as SO)
X 212 25.5 1
mg/L Ibs/day I. Sulfide (as S)
X
- m. Sutlite (as SO3)
X (14266-46-3)
- n. Surfactants X
' 0.03
' 0.004 1
mg/L lbs/day o.Alumium. Total X
'0.10
' 0.012 1
mg/L lbs/day
- p. Barium, Total X
' 0.02
' 0.002 1
mg/L lbs/day (7440-39-3)
X
=
00
'.2m/
Idy
- q. Boron, Total X
0.31 0.037 1
mg/L lbs/day (7440-42)8)
- r. Cobalt Total X
' 0.02
' 0.002 1
mg/L lbs/day 740-48-4) s.v ron, Total X
0.11 0.013 1
mg/L lbs/day (7439498M )
- t. Magnesium, Total X
34.9 4.20 1
mg/L lbs/day (7439.95-4)
- u. Molybdenum.
X
.0
< 0.2 1
mg/L lbs/day Total (7439-8.7)
X
' 0.020
' 0.002
.1.
mg/L bs/
d a y
- v. Manganese. Total X00
.0 gL lsdy___
(7439-96-5) 006 008I mL Ibda
- w. Tin. Total X
< 2.0
< 0.24 1 1
mg/L lbs/day (7440 5) 1__
- x. Titanium, Total
' <0.020
< 0.002 1
ImI lb/ay (7440.32-6) 1 I__
I__
EPA Form 3510-2C (Rev. 245)
PAGE V-2 CON IINUE ON PAGE Ve4
IEPA 1..
NUMBER (copy from ftem 1 of Form 1) IOUTFALL NUMBER I
ILD000803643 I.
01 I
F&M Appmveod OAIB No. 2OO-0059 Aptroval expkes 12-31-85 CONTINUED FROM PAGE 3 OF FORM 2-C PART C -
if you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark X' In column 2-a for all such GC/MS fractions that apply to your Industry and for ALL toxic metals. cyanides., and total phenols. If you are not required to mark column 2-a (secondary Industries, nonprocess wastewater outfalls, and non-required GC/MS fractions), mark v in column 2-b for each pollutant you know or have reason to beHeve Is present. MarkX' in column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe It will be discharged In concentrations of 10 ppb of greater. if you mark column 2b for acroleln, acrylonitrle, 2.4 dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (an 7 pages) for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE fops AND CAS
.TEEST b. BE. A BE.
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG..*-
- d. NO. OF a. CONCEN -b. MASS
- a. LONG TERM..
- d. NO. OF NUMBER OURw.
IPRE. I &,ITVA U
ANAL-TRATION AVRPEVL ANAL..
Pif UVB~.o).
tt)CCS4CEN.
(2)
MASs YSE.)
(2) MASS
- 0)
(2)
MASS (1
)CO N-(2)
MASS METALS, CYANIDE, AND TOTAL PHENOLS IM. Antimony, Total X,
< 0.1
' 0.012
.bs/day (7440-38-2)
X 0.0 0006 1
mg/L bs/day 2M. Arsenic. Total x-005 ~
000 (744D-38-2)
X
< 0.005
'0.0006 I
mg1 lbstdy 3M. Beryllium, Totai X
0.0305 0.0006 1 ;
mg/.
lbsldy (7440-41-7)
X
' 0.040
<0.0006 I
.1gl bsdy M. Cadmium. Total
'0.000
' 0.003 mg/
lbs/day (74403-94-)
X
<0.000 0.0001 I
mgL lbs/day SM. Chromium. Tta X
o.o02
' 0.0048 1
mg/L Ibs/day (7440.47-3)
___a_
6M. Copper. Total X
' 0.00
'0.00 g/L bs/day (7440-50-8)
____0_020 0,002 i_
__g___lbs___y 7M. Lead.78Total2.
X 0.001
'0.0001 I
mg/L lbs/day (7439.92-1)
'0.00020 0.00002 I
mg/L lbs/day (7439.97 46) 9M. Nickel. Total-mgI (7440-02-0)
X
' 0.010 0.0012 bs/day 40M.
Selniu Tot X
0.00.00.00 1
mg/L
- lbs/day IIM. Silver. Total X
'0.0050
' 0.0001 I
mg/L lbs/day (7440-22-4)
____0_0400 0_0048
_iil
_bs__dy_
12M. Thaillum, Total
.'.1
.02-
~
(7440-28-0)
________0_012 I____
mg/I.
lbs/Iday 13M. 2inc. Total X.
0.07-0.008 I
mIU lsdy___
(7440 )
14M. Cyanide. Total 0.0.
I m/.
-lbda (57.1 2-5)
' 0.001___
I mg/L Abs/day____
ISM. PhenolsTotal X
0.061 0.007 mg/L lbs/day DIOXIN 2.3,7.8-Tetra-DESCRIBE RESULTS chlorodibenzoP P..i.
X Dioxin (1764-01-)
_--nO I Nut ON EiiD EPA Form 351 O-2C (Rev.
245) rA~~~~~~~~~~...i.
rV*Jli Macrc EPA Foffn 3510-2C (Rev. 2-85) -
'Aut: V-3 bun
.an1s va - -- -- --
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK WX
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optionso AND CAS
, TEST, b. BE, c-BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER OcM PRE-VEUEVED (IRV val)
VAL UEi F avalae ANAL-TRATION AVERAG VALUE ANAL-(7avaiab le)
ED SENT SENT I ER)
(2) MASS IO)
(2) UASS (I)
(2) MASS YSES (1) CONCEN-(2) MASS YSES GC/MS FRACTION -VOLATILE COMPOUNDS IV. Artoein (107.024) x 2V. Acr1owrft (07.I3.1)
X 3v.
1zerne (71-43-2)
I I
x 4V, 0W (CWMo) x Erer (542-88-)
W.
Ofa or (TS-M) x TV. Crw (10.90-7)
X tV. Ct2wo4xom.
me.thV(1244-51)
X t2V. Cidoroou 4
m (75-27.4) tWV. D2 x
eW_ (I1.7 )
I I4V. 1ltOXdor (675-4-3)
(10~o7.52) e I6V. t2Dktrabra X
(758754)
I4V. 1.31O4hr PropRefb(542.1546)
_X IWV E
eN X_
I_
2IV.MI~4SA.1e x
(78448)
(EF47orm)
(Re.
X I Iflul a
ru r.c v
S EPA Form 3510-2C (Rev. 2-85)
PAGE VA
%.%r I INU Umr_
W rm~r v-;a
EPA I.D. NUMBER (copy from Item I of Form 1) jOUTFALL N UMBER I
11~IL0000803643 Bol I
Form Appmved.
CRIB No. 200M0-SAppmwI expkas 12-31-85 CONTINUED FROM PAGE V-4
- 1. POLLUTANT
- 2. MARK 'X
__________3.
EFFLUENT 4.UNITS
- 5. INTAKE otn AND CAS
- 3. TEsT-T b. E.BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER I~OMRE PRE-E ALEVD[__VALUE____
i Fl......
ANAL-TRATION R
~
-ANAL-EDIR SEN SEW (2) MASS
()
(2) MASS (I)
(2)UMASS YSS(I)CONCEN.
(2) MASS YE (fi-vlabfe) 1 SENT 1 MT YESTRTX YE GCIMS FRACTION - VOLATILE COMPOUNDS (contin ~-
UdhyMrnewdft(75x 23V. 1.12.2-T~vs.
24V. TeadoeDqt4ewW 25V. Toluemie (100-8-)
2OV. i.2-Trwm-dkhomrox 28V. 1.1.246&Trdioell"n (79 00 5)
X_
30V. Trkdhl8oro.
(75.01.4) 4x GCIMS FRACTION -ACID COMP'OUNDS_________________
2A. 2.4-01dforonherdx 3.2.4 Omei~pfd (10547.9) 4A. 4.6-04r0.Ocresdx (534.52.1) 5A. 2.4-DWnfto~h&
(51.28-)&
m_
8A.2J& rpwv (8 8 4-7 5 5N_
11A.2.4.6?rildimorohv (8 -0 8.2) r-~~~~~~~~~~~~enMTINIJI OM RFVFR~qF EPA ForM 3510-2C (Rev. 2-85),. -
I PAGE V-5
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK W
- 3. EFFLUENT l
4.UNITS
- 5. INTAKE (opt!224 AND CAS
& TEST.
b BE-c BE
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER W GRE-IEVED UEVED (f
VALUE favelablel ANAL-TRATION AVERAC E VALUE ANAL-
- CUP, PRE.
A&
~~~~~~~~~~~~~~~~~~~~~~~~~(1)
CONCEN-(2) MAS YSES (favalabd)
ED SNT SENT Cm N(2)
MASS (1)
(2) MASS Y.)
(2) MASS YSES GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS (832-9)
X 2B.Awac
?"
(20_9_)
x (12012.7) x 4a. Bwzdm (9247-5)
X (5-5.3 (50-324)
TB. 3.4-8w.fluw&wt x
(205.99-2)
(191.24.2) 9s. Benzo (k) hmwwX (207-M) 108. B4 (2doroto.y) v meoom(111.9-1 118.B s(2-Choro Q
x sow (I114-4")
128.04s (2-d~aaso.
p)ethW(I10240.1)
X 138. B0 (2-exyl) v oD tw a 1 1741.?)
14S. 4-8 Tpharr4 phwy nw (O101-55.3) 15&8-w1Dez~4pltte x
(158.7) 188. 2-C~orunsphw~uu x
178.c44hlor 4ph 0" erw (7005-72-3)
I1&Cl-9 x
1 M. DO=z (a).)
arftacne(53-70-3)
X 208.l.2WAod.nue x
(95-50.1) 218.1.3 OiDO0,oeb~n2 x
(541.73-1)
C.
a CONTINUE ON PAGE V.7 EPA Form 3510-ZC; (R9V. Z-B5) rnXQ Vs
1EPA I.D. NUMBER (copy from Item I of Form 1)
OUFL UMBER I
Form APPMved.
0O48 No. 2000-059 AppiovM erpkes 1231485 CONTINUED FROM PAGE V.6 1.1POLLUTANT
- 2. MARK X
__________3.
EFFLUENT 4.UNITS
- 5. INTAKE loptbM)
AND CAS a.S:bE.~B.~
MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG..
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER OU.
PRE ~...LLUE.
i mge ANAL-TRATION LERAG VALUE1L.
ANAL-(78lavlaw)
ED SENT~
s OWlr (2) 11 MASS (2) MASS (2) MAS YSES (1 ONE (2)MAS YSES GCIMS FRACTION - BASEINEUTRAL COMPOUNDS jotinued)
_______R______
(106-46-fl 24B. D"eh~ PIWhsIe..
(64-66-2)..4 273. 2.4-ODk irt~kM -
(60620-2) 308. 1.2.O~w,hen4.-
nydva-r*e(122-66-f 3206-4F0) 338. HIxwhad4b x
(87-w63)-~X_
3S8. Helad~wocd0-..
pe& 4at*e (77.47.4) 37B.trW1et (1.2.3-CM.
x 0 f 4
(193-39-5) 39B.59I Na.0 404 x
pepAwn(216.)
.mc,)e EPA. Fom 510.C(Rv.24)E'Iw*
EPA Foffn 3510-2C (Rev. 2-85) -
PAUL V-T u-.-
-1.
I
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optina AND CAS
[ TEST
- b. BE-
. BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER NGRE-A B.E (If VALUE Iievablel ANAL-TRATION AVERAG VALUE ANAL-(iavaiable)
ED SENT SENT
)TF (2) OWN (1)
(2) MASS (1)
(2) MASS YSES (1 CONCEN (2) MASS YSES GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS ontinued) 438. N-N&rmod.-
PtW1V~wne (364o)
X 45B.(Pyren1290)
X 468. 1.2.4-;T ao.
=
GCIMS FRACTION -PESTICIDES I P. Aidrin (309-00-2)
X 2P. OJ-BHC 1,
(319-84-6)
A 3P. O-B3HCx (319-85.7)
X 41P. 0-BHC x
(58-89-9) 5P. 30BHC X
(31986-8)
X 6P. Chiardane X
(57..74-9) 7P.4,4-DDT x
(50-29-3) 8P. 4.4-DDE x
(72-55-9) 9P. 4.4'-DOD x
(72-54-8)
X IlOP. Dieldrin x
(60-57-1)
=
X 12P. O-Endosulfan x
(115-29-7) 12P. 0-Endosulfan x
(115-29-7) 13P. Endosulfan Sulfate (1031-07-8)
X 14P. Enduln x
(72-20-8)
X 15P. Endrin Aide-x hyde (7421-934)
X 16P. Heptachlor x
76-44-8)
CONI N
U ON PAGE v_
rnkrTimiJI AU n
PAA.F V.A EPA Fonn 3510-2t; (ROV. Z-ON r^%rwe v 0 wv
EPA I.D. NUMBER (copy fromnItem I of Form 1) OUTFALL NUMBER ILD000803643 B01 I
Form Appv CUBAhSN.
2OW-O059AAppmva eqpbs 12-31-85 CONTINUED FROM PAGEF V-8
- 1. POLLUTANT
- 2. MARK'X 3 EFFLUENT 4.UNITS
- 5. INTAKE (opfb i AND CAS DJEST[ b.
- c. BE-
- a. MAXIMUM DAILY VALUE b.MAXIMUM30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER NO A BE.
y i
U Fmale/
ANAL-TRATION AVERAG E
VALUE ANAL-(1velable)
E S
SEN s
~
Ts (I)
(2) ASS (1)
(2) MASS (I
(2) MASS YSES (1)CONCEN (2) MASS YSES GCIMS FRACTION - PESTICIDE (conlinud).
t7P. Hetadfor Epox X
(1024-57.3) 18P. PCO-1242 X
(53469.21-9) 19P. PCB.1254 (11097-69.1) x 20P. PCB-1221 (11104.28.2) x 21P. PCB-1232 x
(11141.16-5).
22P. PCB-1248 X
(12672-29-6) 23P. PCB-1260 X
(11096-82.5) 24P. PCB-1016 (12674-11-2) 25P. Toxaphene X
(8001.35s2)
___x LPA FOnM 351 0-CG (Rev. 444)
PAGE V*9 EPA Form 3510-2C (Rev. 245)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this Information on separate sheets (use the same format) Instead of completing these pages.
SEE INSTRUCTIONS EPA I.D. NUMBER (copy from teml of Form 1)
Form Approved I 1LD000803643 j 0MB~~~OU No. 2000-0050 ILD000803643 Aproval eyps 12-3158S V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C)
OUTFALL NO.
C01 DART A -
V- -...
6
-1A. ok-
-#.# 1-*
-h-l.
- 1. #kI.
- ~~~~~~~~~~~~~~~~~hl.
the.
f-h
-W~~~~~~~11 Q-f-
Mift~~~~~af Anfaile~~~
folS fl -
S Ll SSuat ~JSVSJ Ux SCe S coutat, CL S~a u edi vit arn 05505010 ILS CYCS 7 VUJ1Stlt t II11 0
I CSJSlul. sJ5551J50 VSl
- OS.5 5515 -JC1S tw55~l. 5J' 0%S urluvu nB s:_
~~2.
EFFLUENT 3.UNITS
- 4. INTAKE otfli
- . POLUTANTa.
MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF
- 1. POLLUTANT f y_
VALUE ffrmiabi ANAL-,
TRATION AYAVERAC ;VALUE _
ANAL.
I (M)
(2) MASS (I)CONCiEN (2)MASS YSES CONCFrRN~MTN cONCENMT.
.N C...,..,......WRATMO
- a. Biochemical Oxygen Demand (SOD) mgQ Ibsiday
- b. Chemical Oxygen Demand (COD) mgQL Ibsiay
- d. Total Suspended Sanids d.(Total Suspended svnds 5.0 0.59 5.0 0.59 5.0 0.59 12 mgQL Ibs/day
- e. AmmonIa 0.30
< 0.04 1
mgQL Ibs/day._
VALUE VALUE VALUE
~~~~~~~~~~~~~~~~VALUE I. Flow v
- VALUE 0.053 VALUE 0.021 VALUE 0.014 MGD
- 9. Temperatur VALUE VALUE VALUE VALUE (winter)
- h. Temperature VALUE VALUE VALUE
.c VALUE (summer)
}
MINIMUM MAXIMUM
- 52
.~A&Ifl~U
.MA I. pH
, M I
NIM UM ~ lMA~lMUM 7.4 l 8.4 52.
STANDARD UNITS 4
PART B -
Mark *X In column 2*a for each pollutant you know or have reason to believe Is present. Mark X In column 2-b for each pollutant you believe to be absent. If you mark column 2a tor any pollutant which Is limited either directly, or Indirecitly but expressly. In an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT
-2.
MARK 'X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optbrie AND CAS
- b. BE C BE.
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER ME.
Ia (1)
VALUE kamlabowl ANAL- -
TRATION VRAQF VALUE ANAL-(t avalati) s~riS sErT rce (2) MASS (1)
(2) MASS YSESC EN-(2) MASS YSES a.2Br4 de--
X mg/l.
Ibsiday
- b. Chlorine. Total -X mgL Ibs/day Residual c.color X
1 Pt-Co d.Fecal Colform X
e.Fluoride (19Fluorlde
-.X 0.40 0.047 1
mg/L.
Ibs/day V.
Nitrate-Nirite.X 0.66 _
0.078 -
mg/L Ibs/day._.
_as _:.:
_...____,,...rnN l~FONR~E EPA Form 3510.2C (Rev. 2-85)
PAuG V-1
-11.nu Ian
-nc.-
n I.
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT
- 2. MARK W
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optin)
AND CAS
- b. BE-
- c. BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER UEVE UEED_____
(lvIf VALUE raambs ANAL-TRATION 1ANAL-SENT SENT
~(I)
(2)MASS (I)
(2) MASS (I)
(2)MASS YSESO________2_
-~
(if -auNe)
SENT UECScENTru 2
CQNrFNTRATz W CCWeENTRATION
(
YSES TRATIO 1-s ~
YSE5
- g. Nitrogen. Total X
< 0.50
'0.059 1
Organic (as N)
< 0__
_ 059__
__l_____
- h. Oil and Grease X
7.7 0.905 5.3 0.622885 2.7 0.318298 12 mglL lbs/day
- 1. Phosphorus (as PJ, Tobl
< 0.10
< 0.012 mg/L lbs/day Radioactivity (1) Alpha, Total X
7.4 I
pCi/L (2) Beta. Total X
19.0 1
pCi/L (3) Radium, Total X
4.1 1
pCUL (4) Radium 226.
X 2.6 1
pCi/L Total
- k. Sulfate (as SO4) 152 1.
(;4808-79-8)
X 152 17.9 1
mg/L lbs/day
- i. Sufide (as S)
X
- m. Sulfite (as SO)
X.
(14266-46-3)
- n. Surfactants X
< 0.03
< 0.004 1
mg/L lbs/day.
(i429A90u5)m X
< 0.1
< 0.012 1
mg/L lbs/day i Baium. Total 3
0.03 0.004 1
mg/L lbs/day (7440-39-3) x_
- q. Boron. Total x
0.28 0.033 1
mg/L lbs/day.
(7440-42 48)
- r. Cobalt. Total X
< 0.020
< 0.002 1
mg/L lbs/day (7440-484)
- s. Iron, Total X
< 0.10
< 0.012 1
-mg/L lbs/day (7439-89-6)
L Magnesium. Total X
27.1 3.18 1
mg/L lbs/day (7439-95.4)
- u. Molybdenum.
lb/a Total (7439y98e7)
X
< 0.020
< 0.002 1
mg/L Ibs/day
- v. Manganese. Total x
< 0.01
< 0.001 1
mg/L lbs/day (7439-96-5)
- w. Tin. Total
< 2.0
< 0.235 1
mg/L lbs/day (7440-31-5) n I
I IX
' 0.020 0.002
_1gbiTFV
- x. Titanium, Total
< 0.020
< 0.002 1
MgIL lbs/day (71440-32 46)
I__
I_
f~~~~~~~~~~~~~~~~~-AUT111uIC ic A DAfl-C W EPA Foffn 3510-2C (Rev. 245)
PAUL V-it won l *nw; van roux me
lEPA I.D. NUMBER (copy from Item 1 of Form 1) OUTFALL NUMBER I
ILD000803643 I
COI l
Form Approved.
CUIB Nob.
2000.0059 Approvaf exrpkes 1231-85 IflUnt#JIICfn C~nU 0AE-'='1 flC CnDU 71r PART C -
it you are a primary industry and this outfall contains process wastewater. refer to Table 2c-2 In the Instructions to determine which of the GC/MS fractions you must test for. Mark X in column 2-a for an such GCIMS fractions that apply to your Industry and for ALL toxic metals, cyanides. and total phenols. If you are not required to mark column 2-a (secondary Industries, nonprocess wastewater outfalls. and non-required GCIMS fractions). mark X. In column 2-b for each pollutant you know or have reason to believe Is present. Mark X In column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant you must provide the results of at least one analysis for that pollutant if you know or have reason to belleve It will be discharged In concentrations of 10 ppb-of greater. If you mark column 2b for acroleln, acrylonitrile, 2.4 dinltrophenol. or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfan. See Instructions for additional detalns and requirements.
- 1. POLLUTANT
- 2. MARK
&C
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (opfbns AND CAS
. TEST-rb. -E C BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER
..IZ
. r
','R [
U 1aEVE.-s)
VALUE Lael ANAL-TRATION AERA V.ALUE ANAL-ffevdable)
ED(1)
(2)MASS D)
(2)MAS5.--
(1)_
(2) MASS YSES (1)CONCEN -
(2)MASS YSES METALS. CYANIDE AND TOTAL PHENOLS 1M.AntImony Total X
< 01
' 0.012 (7440-36-0)
X_
g L b t a 2M. Arsenic, Total X
0.005
< 0.0006 (7440-38-2) 1.006 mgIL lbs/day_
3M. Beryllium. Total X
_0.005
' 0.001
.1 mglL Ibs/day (7440-41.7) 4M. Cadmium. Total X
=
' 0.030
' 0.00353 1
mg/L Ibs/day (7440p43-9) rc 0.020
' 0.002 I
.g1L lbstday 7M. Chromium Total X 0.040
< 0.0047 1
mg/L Ibs/day (7 4 4 0-4 7 -3 )
6M. Copper. Total.
X
=
0.0020
'00002 1
mglL Ibs/day
=
(7440-50-8)
___0_020
____mg_
L__lbs
_day 7M. Lead. Total X
<0.001
<0.0001
.1 mg/L Ibs/day (7439.9.1) p782-49-2)-
X_
'_ 0.005
- 0.
.mI/
8gM.sMerury. Total.
X
=
' 0.00020
< 0.0002 1
mg/L lbs/day (7439-974)
X 0.010 0.00 1 2 g
I/.
p94M.
Mckel. Total X
=
'.0.010
< 0.00 1 1
mglL lbs/day (7 4 4 0-0 2 -0 ) '_
oM Selenium..
X 0.005 0.000 1
mg/L Ibs/day II M. Silver, Total X
<0.0400' < 0.0047
~~mgIL lbslday-(7440-224)X 0, 00
< 0 0 4 12M. Thanllum. Total X
0.010
'<0.0012 1
mgtL Ibsiday 13M.Zlnc Total X
-0.0 50
< 0.0 12m gIL Ibslday 1M M
m Total xj 0
gi b l a DIOXIN=
2,3.7.8-Tetra-1
-D.ESCRIBE RESULTS chlorodloenzo-P.
X I DIoxIn (1764-014)
EPA_
_or 35 0- C (
.2.5 v-J ON I U N E E S EPAFomI35I0-2C(R*v.2-85),
rAlic V-j
'r, rAMTtNtIR flN RFWRSF
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (od Irt AND CAS E
nT. t-C. B sE-
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER wGRE LIEVED LIEVED (avaiebh)
VALUE Mevdtabile ANAL-TRATION AVERAGE ANAL-(davelable)
ED SENT SENT (I)
(2 UMASS (I)
(2) MASS (1)
(2) MSs YSES (1) CONCEN-(2) tASS YSES GCIMS FRACTION -VOLATILE COMPOUNDS tV.Aa'oiein(107-02-8)
X 2V. Aabto*k (107.13.1)
X
- v. Banzene (71.43-2)
X 4V.
Big (CCMt) x Etm (542-41) 5v. BCoiom X
(75-25.2) x 6W. Carbon tetladvow~ex (5-23-5)
____x I
Wv. C Dcooane (I1&D-90.)
X 1V. Chorodibroo methan (124-48-1)
X W
tooeth~ane s_
(7l5W23) x eft10V.25-8)
=iV C orI(om (674-3w)
X t7V. t 2ixbo methane (75-27-4) 13V. DktiorA~
metane {(75-714) 14V. I 1-0doh ae x
I
=
(75-34.)
CONT I
N U E ON PAGE ISV. 1.2.Oichroedane (107.06 2) 1SV. 1.j-0voorhs4anex (7&5.354) l7V. l.2-DiNW~r0P-n (7&8-7.5)
ISv. t,3-obcilwo-WopVW*e (542-75.)
X__
(100.41.4) 21V.MethdWftd A
l~~~~~~~~~~~~~~fl~~~~~~UTILJII~
ig u PAtIr Vq EPA ForM 3510-Z2 (KeV. Z-85)
PAGE V-9 wvn W w^vc _§^ rA
- w-_
~EPA I.D. NUMBER (copy from Item 1 of Form 1) IOUTFALL N UMBER I
ILD000803643 I
COI I
Form Apwmved.
0MB8 ft. 2000-0059 Approvel skpkes 12-31-85 CONTINUED FROM PAGE V.4
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (Dptkbna AND CAS
- a. TET E
BE,
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER NORE LFEVE VA.....LUE fmleteL.
ANAL-TRATION AE rnVALUME..
ANAL-(imwlable DSN 1)()MS
- 1)
~
1)AS()
2)AS(1)CONCEN-(2) MASS YE GCIMS FRACTION -VOLATILE COMPOUNDS (Continue.-.________
2V. met4avye doowide, 24V.,"Teqr*joqIje x
28V. 1.2-Trw*4b-ddro.
27'V. 1.1.1.Trkd4orahaw (71 554) x 39V. Tred4m~roet-4 (79-014 (7-69 x
31v. T,1 dcdft ovo GCIMS FRACTION -ACID COMPOUND:S 2A. 2.4-0ktd~orphw" 3A 2,4-bfrneti4tA*Ww (14 8 - )
(5'34-52.1) 6k 2-WRvphefli
-x 9A. Pe.~adOOMO(W'ed 10A.Pi IMd1895-2) 7__
p~~~~~~~~~~~~~~~~~~--
nuTluII it u arwaC.r EPAFo"n35l0-2C(R&v.2-85) -
I'Arih V-D i
__'... I---
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (oppt AND CAS TEST. b. BE-c BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER NGERE. UEVEO t.lEVED (itvai V
fALUE f evalab ANAL-TRATION AVERAC VAL ANAL-(wlavsleta)
EO SENT SENT I (1)
(2) MSS C
- 1)
(2)MA.SS C
(1)
(2 MA55 YSES (1)cR 4 (2)bASS YSES GCIMS FRACTION - BASEINEUTRAL COMPOUNDS 18.ACOWWWOh x
(83-32-9)
X 281. AcWW*plw*~en (20-964) x (tB.2 Art~r.7
=
=
e=
(120.12.?)
- 43. BrznSiWe (9247.5)
X (58.55.3)
SB. Be=zo (a) pyr x
Til 3 4or %z&%iene (20&9%.2) x.
IB. Ben-r (hl) pery.X (191-24-2) 918. Benzo (k)f ene X.
(201-08.9)
- 10. Bis (24roIu=-y)x rndMae(111.91.1)
I X
l1L[Bs(2-ciftroe"i~)x W(I 1B 1-442y)
X eh(11144-4) 128. B4 (2-c4 oio.
M"p)) 6(hw (102460.1)
X____
13B. B4s (2-"V4) rthaweS(11741.r7) 14B. 44-W*rA Ph" X
e0er (101-55-3) t5S.S*l b" ptWtae X
18S. 2ClotW4Whmee X_
(91-584T) r (er70057243) 188CIY4l X
(218-01.9) 19E.04-682 (aJh) 20B. 1.2-D4kx8buZwU X
(95.50.1)
I _
XI I
I __
21t. 1.3.
mvten X
a f.flIrfJtTINEI Nm PAGE V.7 EPA Form 3510-ZC (Rev. Z-a5) rj%%OC V-0
_lw a W_ _6w @ A__ w-f
EA.0. NUMBER(oyfo Item lof Form 1) OUFLUMBER r
I~~LD000803643
)1.OUTFALlN Fo~m Approved.
0MB No. 2000-0059 Appr'oval
- x*eas 12-31485 enwiNt1iIm F~om PAE.F V.A
- 1. POLLUTANT
- 2. MARK.X,
- 3. EFFLUENT
__________4.UNITS
- 5. INTAKE (oWbnf AND CAS r
ES.b.B.
E-
- s. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER
~~~~R. ~~~*
E'VE
_______ALE__Fmabe ANAL-TRAT10N AEA
- VLE ANAL.
NUMBltiER OM(I)PE (2) MASS (1)
(2) MASS (I)
(2) MASS YS(I)
CONCEN-(2) MASS YE GCIMS FRACTION -BASEINEUTRAL COMPOUNDS (cntned) 22.1.40 icorobam" r3a.3,Z4k:0d 0-om
- I b~Azs~n (91.94-1)
(8448.2) 218. Difrre8~p~dhaitsx (131.11.3) 288. MGN-btjty4 Pt-tujo (84_74_2). r 1
I 278. 2.4-Ol,*0t~owk x
(12114.2 288. 2.8 0k**fcr4*wl 298- 04.Ncd~ pIWte x
Ilydras n (122-48-7) 318. Fkjraitwhee.
(2 18.444) 328. F~ftiwe(80-73-7)-
X.
338. Mew-x
.~w (148.Hft4 *0&M)
(5748.3)-X 358. HaxadiffocyrSo.
DWS"Me~ (7741.4) 378.lNOW (1Z2-ttd).
X py-e(193-39-),
- x 408. Nitrobsima (18.93)
X~rwimlt4 w TI-4 (62.754)
.X_
428.N*IWivsod.N..
p p 4 11 W ( 82 1-4 7)_
EPA Form 3510-2C (Rev. 2485)
PArit: 'J.
ofI
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE optona AND CAS L TEST. beE-c BE-
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER NG REI UEVE I
UED (laVi YaVALUE atevala..e.
ANAL-TRATION AVERAG VALUE ANAL-( avaluble)
ED SENT SENT 1
lC (2) MASS (C )
(2)EMASS YSES (I)CON (2)MASS YSES J.-I -
COC.TAT I.
CNCN AONTATINi.
GCIMS FRACTION - BASEINEUTRAL COMPOUNDS (continueO 438. N-N~reC X
e-4 (86-3_)
44B. PhlgW e
X (85.014) 45B. Pyrom (129.00-0)
X
- 46.
1.2.4-Tu clvoro.
benMsm(120421) x GCIMS FRACTION -PESTICIDES IP. Aldrin X
(309-00-2)
X_
2P. O-BHC v
(319-84-6) 3P. O-BHC x
(319-85-7) 4P. O-BHC (5849-9)
X 5P. O-BHC (319-86-8)
X 6P. Chiordane
=
(57.74.9) 7P. 4,4-DDT x
(50-29-3)
X 8P. 4.4-DDE
=
x (72-55-9) 9P. 4.4~-DDD x
(72-54-8) lOP. Dieldrin x
(60-57-1) 11P. o-Endosulfan I
(115-29-7)
X 12P. 0-Endosulfan X
(115-29-7) 1 13P. Endosulfan r
Sulfate (1031-07-8)
X 14P. En~dn x
(72.20-8) 15P. Endrin Aide-X hyde (7421-93-4) 16P. Heptachlor X
(76 449) elrnu..,.c ru.
n nrc vo EPA Form 3510-2C (Rev. 2-85)
PAGE V-8
%,Wm I Imr.u
%in rfUQ V.,
EPA I.D. NUMBER (copy from Item 1 of Form I) OUTFALL NUMBER ILD000803643' C01 I
Form, Appmved.
OMIB Wo 2000-OD5 App'vvsl
&Vkw 12-31-85 CONTINUED FROM PAGE V-8 I. POLLUTANT
- 2. MARK 'X
- 3. EFFLUENT
- ___4.UNITS
- 5. INTAKE (pfb AND CAS a...
TEST-.
BE G. BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER An t*IEVE.
VALUE__
_ab__
ANAL-TRATION AYVER YALUE ANAL-(fvable)b )
(2) MASS YSES GCIMS FRACTION
- PESTICIDES (con tusc) t7P, Hetsd# Epmede (1024.57.3) x 18P. PCB-1242 x
(53469-21-9) 19P. PCB-1254 x
(11097.691)
X 20P. PCB-1221 x
(11104-28-2) 21P. PC8-1232 x
(11141-16-5)
X 22P. PCB-1248 (12672-29-6)
X 23P. PCB-1260 x
(11096-82-5) 24P.PC8-1016 X
(12674-11-2) 25P. Toxaphene (8001-35-2) t PA rorr
.31U-CL.C JKOV. 4-04)
P.Aut V-Y EPA Form 3510-2C (Rev. 245)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this Information on separate sheets (use the same formrt) Instead of completing these pages.
SEE INSTRUCTIONS
- EPA I.D. NUMBER (copy from Item I of Form 1)
FoiApproved ILD000803643 OUrB No. 200059It-Ax V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 ofForm 2-C)
IPART A.
You must provide the results of at least one analysis for every pollutant In this table.
OUTFALL NO.
E01
- 2. EFFLUENT
- 4. INTAKE todbnsf
- 1. POLLUTANT
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE
, -. 7 "a~l '
tir e
a A - -
I
.AU h.-.J P
I
~
~
~
I ~LL~~b~ I-Z-
- a. NU. Ur-ANAL-YSES
- a. CONCEI, TRATION
- a. LONG TERM IAVERAGE
(!MAE (1) CONCEN.
(2) M4A-IS
- d. NO. OF ANAL-YSES (2) MASS (1)
(2) MASS (1)
(2) MASS
- b. Chemical Oxygen Demand (COD) mg/L lbs/day.
- c. Total Organic Carbon (Toe)
.n mg/L lbs/day
- d. Total Suspended Solids 2.5 0.23 1.5 0.14
< 1.2 c 0.11 24 nig/L, lbs/day
- e. Ammfonla mg/L lbs/day f.Fbzw VALUE 0027 VALUE 0017 VALUE 0011
=M D
VALUE
- g. Temperature VALUE VALUE L
-UE VALUE=
( w i n t e r )_
- h. Temperature VALUE VALUE VALUE -
VALUE (Summed I.pH M-INIMUMU7IMU MUM IMAXIMUM M
STANDARD UNITS PART B-Markc X in column 2-8 for each pollutant you know or have reason to believe is pr sent. Mark X In column 2-b for each pollutant you believe to Re abst. If you mark column 2a for any pollutant wMich is limited either directly, or Indirectly but expressly, In an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you marl column 2a, you must provide quantitative data or an explanation of their presence In you discharge. Complete one table for each outfall. See Instructions for additional details and requirements.
- 1. POLLUTANT.
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE frprbnae AND CAS B. BE-C
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS B. LONG TERM
- d. NO. OF NUMBER WEEVED u tbVEO -1e VALUE ANAL-TRATION ERAr VALUE ANAL-(tat/le)
SENT S
(1)
(2)MASS (1)
(2) MASS (IT (2)U ASS YSES (1) CONCE14-(2) MASS YSES
- a. Bromide mgI...
lbs/day (24959 467-9)
- b. Chlorine, Total X
X
~~~~~~~~~~~~~~~~~rfiill-lbs/day-R e s id u a l_
c.Color X
5 Pt-Co
- d. Fecal Conform
=
X-l
- a. Fluoride X
1.00
< 0.092 I
i 1
mg/L Ibs/day
- f. MitrateNtrlte X
1.80 0.165 1
-mg/I Ibs/day (as )g__
EPA Form 3510-2C (Rev. 2-35)
P'AGEt V-1
%'r1 nirlur-%
un lrv~nn.
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT
- 2. MARK KW
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (option AND CAS b,-
c eE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER UEVEO UrED (daval*14)
VALUE Fa valableL ANAL-TRATION AVERAG VALUE l ANAL-(d avalauis)
OE (1)
(2)MAsS (I)
(2) MASS (C )
(2I MASS YSES (1) CONCEW (2) MASS YSES
- g. Nitrogen. Total x03
.2 Organic (as N)
X 0.30 0.028 1
mg/L lbs/day
- h. Oil and Grease X
9 0.826 3.9 0.358001
' 2.4
'0.220308 1
mg/L lbs/day
- 1. Phosphorus (as P), Total X032 0291 m/
lbda (7723-1440)
X 0.32 0.029 1
mg/L Ibs/day i-Radioactivity (1) Alpha, Total X
< 3 1
pCUL (2) Beta, Total X
210.0 1
pCi/L (3) Radium. Total X
9.0 1
pCi/L Total B
X
<0.3 1
pCUL
- k. Sulfate (as SO4) 8 0.734 1
mg/L Ibs/day (14808.79-8)
I. Sulfide (as S)
X M. Sulfite (as So,)
(14266-46-3)
- n. Surfactants X
< 0.20
' 0.018 1
mg/L lbs/day
- o. Aluminum. Total X
'0.20
' 0.018 1
mg/L lbs/day (i49-390-T)
X
' 0.20
< 0.018 1
mg/L lbs/day (7440-39-3)
X 0.20
'0.018 I
mg/L Ibs/day
- q. Boron. Total
<0.20
' 0.018 1
mg/L lbs/day (744042-8)
X02 10
_0.119 1
mg/L Ibs/day
- r. Cobalt. Total X
0.55 0.05 1
mg/L lbs/day (744048l4)
X
<0.040
<0.004 1
mg/L lbs/day v; Iron, Total X
1.30 0.119 1
mg/L lbs/day (7439.89-6)
- w. Manesnium. To X
.030
<0.003 1
mg/L lbs/day Total(7439-.9-7)
X
'<0.5
' 0.046 1
mg/L lbs/day
,(7440-32.5)
EPA Form 3510-2C (Rev. 245)
PAGE V-2 GUN I INUtE ON PAGEC V-4
EPA 1.0. NUMBER (copy hfom item I of Form 1) OUTFALL NUMBER ILD000803643 E01
-1 Form Approved.
OAIB ft,. 2000-005sgAPPrvov expivs 12-31485 CONTINUED FRt3M PAnFn n F FnRM Ir PART C -
If you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 In the Instructions to determine which of the GC/MS fractions you must test for. Mark X In column 2-a for al such GC/MS fractions that apply to your Industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary Industries, nonprocess wastewater outfalls. and non-required GC/MS fractions), mark X In column 2-b for each pollutant you know or have reason to believe Is present. Mark X' In column 2-c for each pollutant you belleve Is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe it wmll be discharged In concentrations of 10 ppb of greater. If you mark column 2b for acroleln. acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherise, for pollutants for which you mark column 2b, you must either submit at least one analysis or brlefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions for additional detalls and requirements
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optbnar)
AND CAS
.,^E!7T Lb.ED
&BE
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.- - d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER R. PREI A.L E
i I
ANAL-TRATION AVERAG ANAL-ffevalable)
ED SENT (2) MASS (1)
(2)
(SS.
(2)
YSES
.1)
CONCEN (2) MASS YSES
~~~~~~~~COKtENMTRAIh 5CKNM~TM
.M fl..T"AI METALS, CYANIDE, AND TOTAL PHENOLS 1 M. Antimony. Total g
lb (7440-36-0)
X
_c 0.5 I
.g/L Ibs/day 2M. Arsenic. Total x'I m/
b/a (7440-38-2)
X 0.003 1
00003 mg/L Ibs/day 3M. Beryllium. Total X
o.0 05 c 0.0005
.1
___44041_7 mg1I lbs/day 4M. Cadmium. Total X
0.0120 0.00110 (7440-43-9)
X
=
=0.0120 0.0018..
1 mg/L lbs/day 5M. Chromium. Total X
0.020
< 0.0018 1
mg/L lbs/day (7440-47-3)
Xm/
b/a 6M. Copper. Total..
(7440-50-8)
XI 0.030
< 0.0030 I
mg/L lbs/day 7M. Lead. Total
-X 020 0.26 12Nt.
Tnamum~otal X- -- < 0.030 c
0.00266.
1 mg/L I bs/day..=
(7439-92-1)m/,b/dy____
(7439-97-6)
X
< 0.35 0.032 I
mg/L Ibs/day 9M. Nickel Total X
0.00
< 0.003.
1 mg/L bs/day
._=
(7440-02-0) 003I mgL lbda 10M. Selenium,.
nI b/a Total (sn82-49-2) X c 0.004 0.000 1
mg/L bs/day
~~~wj Total~
' 0.0100
'0.0009 I
mg/L lbs/day c2. hloroibezo.
lTltall 12M.hallium. Total
(
1 744-6
)
0.030
< 0.0028 I
mg/I lbs/day (7440-28-0) 13M.
inc. otal
-X 0.35
-0.032 1
mg/I lbs/day (7440-68-)
lAM.Cyande.
otal X
'.0.005
<'0.0005 I
mg/I lbs/day (57-12-5) 15M. Phenols, Total
.0 0.0005 I
mg/I b/a 2,.7.8-e aX IDESCRIBE RESULTS chlorodibenzo-P-X Dioxin (1764-01-6) t
__j__
I I
EPA Form 3510-2C (Rev. 2-85)
PAGE V-3
%.%Jrll II "WQ %in
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optiail AND CAS L &
TesT
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER ING RE. LIEVED1 LIEVED (avalableJ VALUE Wevalabhl ANAL-TRATION AVERAQE VALULIE ANAL-ff-if able) lED SENT SENT rnrJFcNTRATKON (2)5 CONCENRATIO (2) MASS E
(RA)
(2) MASS YSES (t) CONCEN.-
(2) MASS YSES GCIMS FRACTION -VOLATILE COMPOUNDS 1V. Aaok*%n(107.0-8)
X 2V. Ahykre (107.13-1)
X 3V.Berzaene(7143-2)
X 4V. B9S (CNrf)
X.
Etnf (5424.81 )
5V. B0orm (15-25.2)
WV.
Carbon 1waldatorld i
(W.23-5) td X_
TV, Chlrdentwe ll (108-907.)
X 8V. C Hioronoo-me14t-ar(_24.48-)
X OV..
2 Cooethane (MOD0-3)
W V2-Ctorodh~4vk1$
arRU (110-15.)
liv. CN0rotr (r7.8*.3)
X 12V.
hbx n(75T27-4) 13V. Dkdhwodcro-x mwew(75.71-84 x
14V. 1.1-gicVoro14e (75343) lSV. 12
.D_
X eI II (107-06-2)
X 16V. 1.1-Oichl oroe ylen (15.354)
IN. 1.2-0IcflWopro~ef (147.5) l ISV. 1--DUichlr-pwy4a (542-754)
X (100-414)
X 2OV. MWtiY brumlex 21V.M" 4ctif x
(74 47.3) x (7A V-t atrt w.. '
PAGE V-4 CONTINUE ON PAGE V-5
_5
-1
I IEPA LE0. NUMBER (Copy trmM iteM Io Of Ofm 1) 1OUTFALL NUMBER I
Forn, Appievod.
OMfB No. 2000-0059 Appm'val OSPhUS 12-31-85 coTiN~l~upn FRMM PAnO: V.A
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT J__________
__N.
- 5. INTAKE (option n
a AND CAS a TEST-c.BE.
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF B. CONCEN
- b. MASS a. LONG TERM
- d. NO. OF NUMBER O~ER A&
ff VAWLU mnm~la ANAL-TRATION AVA E VLUE..
ANAL-(if mabalatI ED ISEW 2MS 2 AM()()MS (I)CONCEN.
(2) MASS YSES GCIMS FRACTION - VOLATILE COMPOUNDS (Contlnud________
2V. Meyl, dtoeriwdeF(
23v. l.l.22-That.
x
?5V.To~uen(l0&W83)X 26V. 12.Tru'S%&doro.X 27v.1.5.1)T~tico w
2W. 1.1.2_Teid4wodwefx 29V. Tfld&J hylww (7 9 1-01 )
3OV. Trtctivofuoro.x ff*M " ( 549.4)._
31V. VN dftrift GCIMS FRACTION -ACID COMPOUNDS__
iA. 2-CNomh&Wd 2A. 2.44D)kSoro~~lix (120-83.)-'
(10"-6.9)
(534.52.1)
-X_
Ok 2-NNeo.
btii (100-02-7)
X_
(59-50-7) 10A. Pho Id (10&95-2)
.X llA.2.4.6-TI4tt Ci Xph.
(88-082) rnk___
__IC
__nu_
EPA Foffn 3510-2C (Rev. 2.85)
I
. PAW: V-3 ' '-
I
-1.
I I
I
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARKX'
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (option AND CAS
, TEST.
b.Ec BE,
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER OU4 RE UEVED UEVED (f avable)
VALUE firavaleblet ANAL-TRATION AVERAGE VALUE ANAL-(davalable)
ED SENT SENT (I)
(2)MASS (1)
(2)MASS
()
(2)MASS YSES (1 CONCEN-(2) MASS YSES GCIMS FRACTION - BASEINEUTRAL COMPOUNDS
- 18. Ac&Px~
2a. Acnnaplphylr x
(206-98e)
(120_12__
=
__X
=_=__=_
- 48. BOMOe (9247-5)
X
- 58. Suaz (a) lvcnX (5&&55-3)
- 68. Bzao (a) pr X
(50-324)
- 8. 3.4-8w90criw X
(205-992) e8Bo nzoghp WM I
I (191.2-2) x_
- 96. BS.zom(k) bwane (20.08-9)
- 10. Bis (2davehtax r
mem" v 1119.)
x ghet(IIl.44.4)
X 128. W (2-dcoroiso_
pbyI)eUW(10240.l)
X 138. 8fs (2.eWrt~eil)x ptale (11741-.
_)
i48.4-8JoIW epfr96lp x
ather(101-55-3) 158. B*l be4 ptitho~e
_X (8548)
X I_
1 SS. 24h~orona*ene X
(91.58-7) ea wi (1005-12-3) 198LDm Oez(0~)
alw arcale(S3.70.3)
X_
208. l.2-Oork0ubne X
(95-50 )-1) 218. 1,3.Oicorobomemd EPA Foffn 3510-2C (Rev. 2-85)
PAGEh V-6 I.VFV I INs Ur. V rfV.
v-1
EPA IC.E NUMBER (COpy 'M iteml70of-071 ) 1OUTIFALL NUMBERK
.1 F"m AAprved.
0MB No. 2000OMOS9AppitwaI erJ#es 12-31485 CONTINUED FROM PAGE V-fl
- 1. POLLUTANT
- 2. MARK.X,
- 3. EFFLUENT
__4.UNITS
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
.LERAG VLUE..
ANAL-(ilavulable ED SEN EN (I
- 2) MASS (1
2)A)
(2)
(2MASS YSES lt)CON(ZEP (2) MASS YSES (106-46.7)MT (06446.2)
M.-zomeo x
278. 2.4 (q-sl4tr -iun (12.4.W2) 268. 2.N-0utyl vtnex 308. 2U44rIrtoenI..
hydazt1 e 14 224.
(206-444)oh 328.
pi re I~ mm-3.)
(11674.)"
308. i.-
pxr4 318. Fkwerocwio--
3368 Had*mbeme.m 358. H~x 308. NapWoae x*
(91.20-3) 4oa. w-lroeomelm 4
smoio(62.7549) 42&.NNveiNf i_
MI-~UI~e6214-T)
~~~~~~~~~~~~~~~~~n-lkrul IC n fu OgW.ca EPA Foffn 3510-2C (Rev. 2-85) i rpkur V-f
-1. 1-I
- 1.
i I
I
- , I -.,
I
.1
'7 4
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (option AND CAS r-~
BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER NG EV (aif
.hble)
VALUEir' za1eleL.
ANAL-TRATION AVERAGE VALUE ANAL-(I avaiable)
ED SENT SENT C
O N
AIO (2)M1 YSES T2MIA S YSES GCIMS FRACTION - BASEINEUTRAL COMPOUNDS (continue) 43B. N-.N8roscd (85-014) 4M8. Plen
_(129-00) X 468.1.2.4-Trdiwo benzem (120-82-1) x GCIMS FRACTION.PESTICIDES IP. Alddn (309-00-2)
X__
2P. O-BHC v
(319-84-6)
___TI II II 3P.O-BHC x
(319-85-7) 4 4P. 4-B:HCD (58-89-9)
X 5P. o-B3HC (319-86.8)
X_
6P. Chlordane (57.74-9) iP. 4.4-DDT x
(50-29-3) 8P. 4A4-DDE x
(72-55-9) 9P. 4.4-DDD x
(72-5 4- )
lOP. Dieldrin x
(60-57.1) lI P. 0-Endosulfan (115-29-7) 12P. 0-Endosulfan x
(115-29.7) 13P. Endosulfan X
Sulfate (1031-07-8) 14P. Endrin x
(72r20-8) 15P. Endrn Alde-hyde (7421-93-4)
X 16P. Heptachor x
(76-44-8) rnuTINF fN DAfE V.0 EPA Form 3510-ZC (Rev.
Z-85) rRIJ~~~~~~~~~~.....
v-aTUII UD~r -
EPA Form 3510-2C (Rev. 2-85)
PAGE v-8 vvn a nwc vn rnvc w-w
EPA I.D. NUMBER (copy ftom ftem i of Form 1) (OUTFALL NUMBER I
ILD000803643
. I E01 F&M AApprm~'d.
CRIB No 2000OO5O AppmvsI orphs 12-31-85 CONTINUED FROM PAGF V.8
- 1. POLLUTANT
- 2. MARK X
_3.
EFFLUENT 4.UNITS
- 5. INTAKE (ope1)
AND CAS a TEST
- b. BE.
BE-
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER N
O RE. I UEVEO PA.
__VALUE ANAL-TRATION RAGE VALUE ANAL-(f avlble)
E SENT SENT
()
- 2) MASS (2)MASS (1)
(2) MASS (1)CONCEN4 (2) MSS YSES GCIMS FRACTION -PESTICIDES Jc /NC 1nued) 17P. HeI t Epoxde X
(1024.57.3) 18P. PCB.1242 v
(53469-21-9) 19P. PCB-1254 (11097-9.1)
X 20P. PCB-1221 (11104-28-2) 211P. PCB-1232 X
(11141-18-5) 22P. PCB-1248 X
(12672-29-6) 23P. PCB-1260 X
(1109682-5) 24P. PCB-1016 X
(12674-11-2) 25P.
Toxaphene X
(8001-35-2)
EPA Form 3510-2C (Rev. 4.84)
PAGE V-9 EPA Form 3510-2C (Rev. 245)
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information on separate sheets (use the same format) instead of completing these pages.
SEE INSTRUCTIONS Form Appmovd OUB No. 2000-0059 V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C)
PART A -
You must provide the results of at least one analysis for every pollutant In this table. Complete one t ni
- 2. EFFLUENT I. POLLUTANT
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE I
1i7 8vsOeI.)
c.LONG TERM AVRG.
_VALUE fr"IAfqi
- d. NO. OF ANAL-YSES a.
I vs vwvvo TRATiON
,. rr
-n r-I (2) MASS I
(1)
(2) MASS (I)
(2) MASS
- a. Biochemical Oygen Demand (BOD)
__m g/L '
lbs/day
- b. Crremical Oxygen Demand (COD) mglL Ibs/day C. Total Organic Carbon (ToC) mglL Ibs/day d TotalSuspended SolIds 5.0
' 1.96
' 5.0
' 1.96
'5.0
< 1.96 12 mg/L Ibs/day ea.
Ammonla mg/L Ibs/day VALUE VALUE
~~~VALUEMG f.Flow VALUE -
0.216 VALUE 0.065 V0.047 MGD
- g. Temperature VALUE -
-tVALUE VALUE O0
- h. Temperature V
ALUE VALUE VALUE (summer)
C I.pH
.. IIMINIMUM IMAXIMUM MINIMUM lMAXIMUM STANDARD UNITS I
PART B -
Mark X in column 2-a for each pollutant you know or nave reason to believe Is present. Mark X-in column 2-b for each pollutant you believe to be absent. It you mark column 2a for any pollutant which Is limited either directly, or Indirectly but expressly. In an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark( column 2a, you must provide quantitative data or an exiplanatIon of their presence in you discharge. Complete one table for each outfall. See Instructions for additional details ana requirements.
- 1. POLLUTANT
- 2. MARK-X l
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (optbno AND CAS be BE-l O-
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER tiSVE.f LiD v_
~
frEtaub J
OALUb I
ANAL-TRATION I.
I AVALUEI ANAL-(7"ablse),
SENT lsr _
YSES aCNTE (2) MASS YSES
- 9.
Bromide X
mg/L lbs/day (24959467-9)
- hoine,
-XlTotal X
mg/L lbs/day
- c. Coor -
X I l
l Pt-Co
- d. Fecal Coliform X
- e. Fluoride lbs/day (16984-48)
X
.g/L
- f. Nitrate-Nitrite, mg/L Ibs/day (as N)
X lg/
lbs/day Ir r ~ l iu Q VF EPA Forfn 3510-2C (Rev. 2-85)
PAGE v-1 uw
I lnw
I I I I
" 1, I
ITEM V-B CONTINUED FROM FRONT
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (opfiona)
AND CAS
- b. BE c BE
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE C.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER a
L (valabtl)
VALUE avele ANAL-TRATION AVERAG VALUE ANAL-(iavaiable)
SENT SENT C2)
MASS (1)
(2) MASS (1)
(2) MASS YSES (IjCONcE Pi"ASS YSES
- g. Nitrogen, Total Organic (as N) mg/L lbs/day
- h. Oil and Grease X
mg/L Ibs/day
- i. Phosphorus (as P). Total X
mg/L lbs/day (7723-14-0) xm/
b/a
. Radioactivity (1) Alpha, Total X
pCi/L (2) Beta. Total X
pCi/L (3) Radium, Total X
pCi/L (4) Radium 226.x T4-otaliuum226 x
pCi/L r
- k. Sulfate (as SO )
x mg/L Ibs/day (14808-79-8)
I. Sulfide (as S)
X
- m. Sulfite (as SOJ) x (1426646-3)
- n. Surfactants X
mg/L lbs/day
- o. Aluminum. Total x
mg/L Ibs/day (7429-90-5) l
- p. Barium, Total X
mg/L lbs/day (7440-39-3)
- q. Boron. Total X
mg/L lbs/day (7440-42-8)
- r. Cobailt. Total X
mg/L lbs/day (7440-48-4)
- s. Iron. Total X
mg/L lbs/day (7439-89-6)
- t. Magnesium. Total X
mg/L lbs/day (7439-95-4)
- u. Molybdenum, X
mg/L
.bs/day Total (7439-98-7)
- v. Manganese, Total x
mg/L Ibs/day (7439-96-5)
- w. Tin. Total X
mg/L Ibs/day (7440-31-5)
- x. Titanium, Total x
mg/L Ibs/day (744D-3246)
COTI_
ON lbs/da f~~~~~~~~~~~flM~~~~~~nTtIMt It: nN PArF* V-1 EPA Form 3510-2G (Rev. 2-55) rlajr V-x
-as w llS-
EPA I.D. NUMBER (copy fom item 1 of Form 1) OUTFALL NUMBER I.
ILD000803643
.OI 101 Form Appmvod.
0$/S No. 2000J-OAM Appnmvsf 0,gv 12431485 relM~fimiIow conu nArflC i2 fC rf%0'5DII '
-nu... r---
I--
-un I
PART C -
If you are a primary Industry and this outfan contains process wastewater, refer to Table 2c-2 in the Instructions to determine which of the GCIMS fractions you must test for. Mark X In column 2-a for all such GCIMS fractions that apply to your industry and for ALL toxic metals, cyanides. and total phenols. If you are not required to mark column 2-a (secondary Industries, nonprocess wastewater outfalis, and non-required GC/MS fractions), mark X' In column 2-b for each pollutant you know or have reason to believe Is present. Mark v in column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe It will be discharged In concentrations of 10 ppb of greater. If you mark column 2b for acroleln, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged. Note that there are seven pages to this part; please review each carefully. Complete one table (an 7 pages) for each outfall. See
-____-___-___Instructions for additional details and requirements.
1, POLLUTANT
- 2. MARK
- 3. EFFLUENT i
4.UNITS
- 5. INTAKE (opbn AND CAS Z TEST.
- b. f c-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER I
N O
- r.
AR.
MD XJZ
)VALUE rANAL-TRATION 5 VALUE ANAL-(Tavalable)
Et s
SENr l
)
(2)MASS (1
2 ()
(12)l MA SS YSES
( )CONCEN-(2 5MASS YSES METALS, CYANIDE, AND TOTAL PHENOLS
__l I M. Antimony, Total (744i -3 6-0) l
~
v_______.
m g/L lbs/day l_:_=
2M. Arsenic, Total (7440-38-2)
=
=
X
=
mg/L lbs/day
=
3M. Beryllium. Total xm
/
b/ a (7440-41.7)
X
.mg/L bsday 4M. Cadnium, Total X
mg/L lbs/day (7440.43.9)
X
___I______
5M. Chromium, Tot
-X mg/L lbs/day.
(7440-47-3)
X 6M. Copper, Total mg/I lbs/day Gru&284)
X
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~mg/
itlbs/day' (7440-50-8) 7M. Lead. Total x
X~~~~~~~~~~-
~~~~~~~~~mg/I lbs/day (7439-92.1).
8M. Mercuiy. Total X
mg/
lbs/day (7439-97-6)_
9M. Nickel, Total'
..X.
._!.,._mg[L l
(7440-02-0)lbdiy IOMSeIenium.
T otal (77 82 -4 9-2) tIIM. Silver, Totalx-m /
lb da (744 0-22-4) 12M. Thafllum, Total x
mgI
- lbs/day-(7440-28-0)-
mgSCRIBE RESULTS 13M. Zinc, Total X.m
/
b / a (7440-66-6) 14M. Cyanide, Total
'(57-112-5)
X.m
/
b / a ISM. Phenols. Total
.'mg/I'-
lbs/day DIOXIN chiorodlbenzo-P-EC Dioxin (1764.01-8)*
- EPA Fomi 3510-2C (Rev. 2485)
FAWit: V-3 t,
.I..
I-.-..--
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK X l
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (opioan AND CAS a *EST-D. BE-c BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER No LE LIEVED (itE.
l AB i
lble)
VALUE tf nalab/e)
ANAL-TRATION AVERAG VALUE ANAL-OUIR-I RE I 2)MAS (2)M____
CONCE__
(2_MAS (lavalable)
ED SENT l SENT (1)
(7) MAsS CE)
(2) MASS (I
O (2) MSS YSES YSES GCIMS FRACTION -VOLATILE COMPOUNDS Wv. Acolem (107.02-8) x 2V.Acr4onddle(107.13-1)
X 3V. czense(71-43.2)
X 4V.IS (Ctiorurna) x Eter (5424881)
WV.
8vornolormx (75.25.2) 6V.
Carbon tetrachiode x
(56-2334)X V. CWzene XI (IM9sD7) x SV. Chlorodibomo.
mehane(124-48-l)
X WV. Chwoelflarlx (75-00-3) 1OV. 2OC v
eawI (110-75-8)
IV. C7hlordorm X
(87 48.3) 12V. D4Otadwromo.
meaane(75-27-4) 13V. D X
o me se.(5-718)
.I.
14V. 1.1Dohlfomu x
(75-34-3) 1WV.
1.24 o roole x
(107-082)
(75-35.4).
I T. 1.2-DItcoro~p"u (7847-5)
Mrtlard (542-75-6)
X I W. EUyenza X
(100- 1-4)
"v.me"i~ bromide x_______
21V. MaUe dX uld
( 14 4 7.3 )
X_
r nT]L l g N
PA G E V.!
EPA FofTn 3510-2C (Rev. 2-85) rPuGc V-4 kvn ffi nuc v
rowx w-w
IEPA I.D. NUMBER (copy fmrnMH Ie Of otOrM 1) jOUTFALL NUMBER I
Fom Appovv.d OMB th 200O-O59 Apovaf exptms 12-31-85 e~flunu8ttil WanU.DMflC 11-A I. POLLUTANT
- 2. MARK
__________3.
EFFLUENT 4.UNITS S. INTAKE (Optbnoo AND CAS TEST. t. BE.
. E
- a. MAXIMUMDbAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
'.NO. OF NUMBER O~tR PRE UFi MI*
ANAL-TRATION RA ANAL-(if nvalabM) w I sENT
)
2)MAS 1)(2 MSS(2 MSS(1)c C
CEN-(2) MAS YSES GCIMS FRACTION -VOLATILE COMPOUNDS (Continue) 23V. I.t.2.2.Talre-diwa~*'~ (79-34.5)x_________
24V. T"Nrd*Ow~i~mn (127.1 64).
26V. 1.2-Trm'4dt-d*,.
27rV. l.1.1-Trktd~ovePw x
(71.55.6) 29V. 112Trldfrtbg~eM" 20V. TArbd hyW*~.
(75.014)
GCIMS FRACTION -ACID COMPOUNDS 1A. 2-Ctiorephandx 2A. 2.4-Oldtmovptw~d (120.3-7) 3A.2.4-0tIn45hoph4
-rd (10567.9) 4A..,-krO4..eD Sk 2.4-Dn*vpterdx (51.28-5)
?A. 4.NIktopI&edx (100.02.7) 8a. P.CNdrM-W2)
(59 z.58 7 -&_
9A.P.1nd4~~~~~~~~~~~~~~~W~~~4
- X -~CO NU O
R VE S EPA Form 3510-2C (Rev. 2-85) -
r^%sr.
.. 4
.1. I
. I..,
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK W
- 3. EFFLUENT
._l_4.UNITS
- 5. INTAKE (opton AND CAS TEST.
t BE.
caE.
- a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER wI R *IEW LUEV (fI
_vabe)
VALUE l evaiabial ANAL-TRATION AVERAGE VALUE ANAL-NUMBaERJ.
(2) MASS 1)(2)UMASS (I)
(2) MASS YSES (1 C(N4CEN-(2) MASS YSES ff aiut01e)
ED SENT SENT CON EN(T)RATtONr
~
C~FTO CONCENTRAtTMO YE TRATI(W
<>~s YE GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS IlS.
Acwnaptwnefl (83.32-9)
M.S An.a.-
(120-127ne x
- 48. euzdltne (9247.5)
X
- 58. Benzo (a) wacneeXe (56.55-3)
- 68. Benzo (a) pyrene 1
X (50.3248) 7B. 344-nzeaniheyrnhene X
(205-99-2) 8a. Bemzo (gh) pa'w4ene X
(191-24-2) sa. SmUo (k) F>Jors lOB. Bis (2dreOm-y)
X l1Bs.Bs (2.mt4) x 12B. Bis (2-dorwox poy4) emI (10240.1)
- 13. Bi (2-e )
x ph8s178a-n-81.7) 148.4a&M4P" 0x ehV (101.55.3) 158. &utl barwyl phte x
lW.2-0h7wwrX
_~
18arys. ene
=
=
x 191. Db58.
?)
h)
X avi (7053.70.3) 20B. 1.24.Dsmzene X
215. l30(dkoibenzenl x
(541-73-1)
F T _-I EPA For 3510-2C (Rev. 2-85)
PAGE W-CUN I INUE: ON PAGE V-7
CONTINUED FROM PAGE V.0 EPA I.D. NUMBER (copy from item I of Form 1) ~OUTFALL NUMBER Fofm Appfny'ed.
CRIB No. 2000-OOSOApp'mWs
.rpkes 12.31-85.
I. POLLUTANT
- 2. MARK X
- 3. EFFLUENT
__________4.UNITS S. INTAKE (Wbtna AND CAS
& TEST-b.BE QE
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS a LONG TERM
- d. NO. OF NUMBER INO RE.
LIEVMD(~E ANAL.
TRATION
.AERAG rmVAU ANAL-NUMD.SIBER (ASAB (I) CONCEN-(2) MA YSE GCIMS FRACTION -BASEINEUTRAL COMPOUNDS (cntned1_____
228. 14~~n
- 23. 3.7-Ot" 0"*
2e7a.n 2
9144.1) 244. mocvh~ pot~~o (31B.11.3)~
278. 2.4- ~Ajnerax 288.H2.6 mdft0W""
358. He4-N~c~ ~meyd o-dmfrie- (¶27.64.)
338. WOW
(¶16.741) 348. NHwud*MOa6~
(8746.3) praff e (77-47.4) 388. (so-wNeaod EPA Form 3510-2C (Rev. 2-85)
PAGE V-7 t
%IVR I frium VrIl Kcvrnar.
I.
6 I
I
. I
, I
CONTINUED FROM THE FRONT
- 1. POLLUTANT
- 2. MARK 'X' l
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (ofkbn AND CAS SEST.
B-BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF NUMBER OUIR.
AIB-D (If (vaale AL.UEo x ael ANAL-TRATION AVERA ANAL-(d avalableJ ED SENT
- 2) MASS (2) MASS (1)
(2) MASS YSES T1TION (2) MASS YSES GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS continued) 438. N-Nsoi-
~~a ~~~
x (8$O01-8) 458..Pyren 1294M)
X 46B. 12.4 Tdtho (1en~2042.1)
X.
GCIMS FRACTION -PESTICIDES IP. Aldrin (309-00-2)
X 2P. O-BHC l
(319-84-6) 3P. o-BHC x
(319-85-7)
X 4P. O-BHC x
(58-89-9)_
5P. O.BHC (319-86-8) 6P. Chlordane x
(57-74-9) 7P. 4.4-DDT x
(50-29-3) 8P. 4,4'-DDE x
(72-55-9) 9P. 4.4'-D0D x
(72-54-8) 0P. Dle7Dlddn x
(60-57-1)
I1P. O-Endosulfan x
(115-29-7) 12P. O-Endosulfan (115-29-7) 13P. Endosulfan Sulfate (1031-07-8)
X
___l 14P. Endrin x
(72-20-8) 1sP. Endrln Aide-x hyde (7421-93-4) l l
l 16P. Heptachblor x
(76R44-8)
_GE CDlh C,-., 194fl,3t' iI3-7-
PAGE V-8 CONTINUE ON PAGE V-9
-r rva
-. e-^
s._
EPA I.D. NUMBER (copy from Item I of Form 1) OUTFALL NUMBER ILD000803643 101
.1 Porn AA~~ved.
0O.1gNo. 2000.OO5OApp.'ovsf expkes 12-41-85 CONTINUED FROM PAGE V-B
- 1. POLLUTANT
- 2. MARK X
- 3. EFFLUENT 4.UNITS
- 5. INTAKE (ocrbnan AND CAS a TEST b rBE-c.BE-
- a. MAXIMUM DAILY VALUE
- b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG.
- d. NO. OF a. CONCEN
- b. MASS
- a. LONG TERM
- d. NO. OF ING RE. I LIEVED IEVEM Djl NUMBER OUR.
PRE.
A1.
.LUE
_r___ebb?
ANAL-TRATION RAGE VALUE ANAL-(I'avble)
ED SEW SEW (1)
(21 MASS
())
(2RA MASS
(
(2) MASS YSES
)CO (2) MASS YSES GCIMS FRACTION - PESTICIDES (continued) t 71. Heptadm Epoide X
1024-57.3) 18P. PCB-1242 (53469-21-9)
X I9OP.
PCB-1254 x
(11097-69-1)
X 20P. PCB-1221 X
(11104-28-2) 211P. PCB-1 232 (11141-16-5)
X 22P. PCB-1248 X
(12672-29-6) 23P. PCB-1260 X
(11096-82-5) 24P. PCB-1016 X
(12674-11-2) 25P. Toxaphene X
(8001-35-2)
PAUL V-g EPA Fomn, 3510-2C (Rev. 2-85)
Exekon.
Exelon Generation Company, LLC www.exeloncorp.com Nuclear LaSalle County Station 2601 North 21" Road Marseilles, IL 61341-9757 September 9, 2003 CERTIFIED MAIL Ms. Beth Unser Permit Writer, LaSalle Station
]EPA Permit Section Illinois Environmental Protection Agency Water Pollution Control, Permit Section #15 1021 North Grand Avenue East Springfield, Illinois 62794-9276
Subject:
Renewal of NPDES Permit No. IL0048151 LaSalle County Generating Station.
Dear Ms. Unser:
Exelon Nuclear Generation, LaSalle Nuclear Generating Station, would like to request an exemption from the sampling and analysis for pollutants categorized as GC/MS Fraction Compounds in Part V-C of the Consolidated Permit Application for the subject NPDES permit application. Relief from this sampling requirement was requested and granted by the Agency in February 1998 in preparation for the previous NPDES permit application, per 40 CFR, Part 122, Subpart B, Section 122.21. Based on the above information, we believe that this request is appropriate and would like to thank you in advance for your consideration in this matter.
Sincerely, Susan Landahl Plant Manager, LaSalle Generating Station Exelon Generation Company, LLC cc:
J. Bolte - Corporate Environmental
EXELON GENERATION COMPANY, LLC LASALLE COUNTY STATION WATER FLOWSCHEMA TIC 10/24/03 LECEN1J FLOWYPATH OUTFALL NUMBER SAMPLING POINT NO RECENTrDISCMRGE *
(A VERAGE FLOWRATE - MGD)
I ILLINOIS RIVER
'i MATERIAL SAFETY DATA SHEET SODIUM HYPOCHiLORITE 12.5%
Rowell Chemical Corporation 15 Salt Creek Ln. Suite 205 Hinsdale, II. 60521 For information, please contact the Rowell Chemical facility in Willow Spr gs at (708) 839-1871 or the Rowell Chemical Corporate office in Hinsdale, IL. at 920-8833.
In the event of a transportation emergency, Call CHEMTREC: (800) 424-9300-c3a Section I - Identification Trade Name:
Chemical Name:
Formula:
DOT Shipping Name:
DOT Hazard Class:
UN/NA Number DOT Label:
DOT Placard:
Reportable Quantity:
HYPO 150 Sodium Hypochlorite Solution NaOCI Hypochlorite Solution Corrosive Material UN 1791 Corrosive Corrosive Sodium Hypochlorite: 100 lbs/45.4 Kg 7681-52-9 There is no NFPA designation for sodium hypochlorite.
Section 11 - Hazardous Ingredients Material Sodium Hypochlorite
- Sodium Hydroxide Inert ingredients
% By Weigh 12.5-15.6 0.2-2.0 Balance
-CAS-No.-
7681-52-9 1310-73-2 7732-18-5 TLVIPEL Not applicable 2 mg/M Not applicable This substance is a chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
Carcinogenicity Status: NTP-No, IARC-No, OSHA-No.
Section Ill - Physical Data Appearance:
Yellow-green liquid Boiling Point:
219 oF (104 oC) for 12.5% NaOCI by wt.
Freezing Point:
-11 oF (-24 oC) for 12.5% NaOCI by wt.
Odor.
Chlorine pH:
12.5 -13.5 S.U.
Viscosity (Cs):
2.15 @ 23 oC for 12.5% NaOCI by wt.
Percent Volatile by Volume:
Variable water plus products of decomposition Solubility in Water:
Complete Specific Gravity (Water--):
1.224 @ 20 oC for 14.15% NaOCI by wt.
Vapor Pressure (mm Hg): Variable water plus products of decomposition 2128195 MSDS Sodium Hypochlorite 12.5%
Page I
re Section IV - Fire And Explosion Data Flash Point (Test method): Not applicable Auto'lgnitioh Temperature: Not applicable Flammable Limits In Air (Volume %): Not applicable Extinguishing Media: Flood with water or carbon dioxide (C02)
Special Fire Fighting Procedures: Use National Institute' of Occupational Safety & Health (NIOSH) certified gas mask with canister for chlorine or use self-contained breathing apparatus.
Unusual fire and explosion hazards: material is strong oxidizer. Contact with combustibles may initiate or promote combustion. Acid and heat accelerate combustion Decomposition products may include chlorine.
Section V - Health Hazard Information Medical conditions aggravated by exposure:
No aggravation of a medical condition has been found to be caused by sodium hypochlorite (Sax: Merck).
Routes of Exposure:
Inhalation: Fumes from spills are very irritating to mucous membranes. Very little hazard from properly stored solution.
Skin
Contact:
Severe irritant, reddening of skin, skin damage.
Skin Absorption: Same as skin contact.
Eye
Contact:
Severe irritant; corrosive.
Ingestion: Causes irritation of membranes of the mouth, throat, and stomach pain and possible ulceration. LD50 (oral, rat) for 12.5%
NaOCI is above 5 glkg body weight.
-Effects of Overexposure:
Acute Overexposure:
Swallowing: See "ingestion" under routes of exposure.
Skin
Contact:
Irritant, reddening of skin, skin damage.
Inhalation: Fumes from spills are very irritating' to mucous membranes.
Eye
Contact:
Extreme irritant, corrosive.
2/28/95 MSDS Sodiumr Chronic Overexposure:
Eye: Can cause damage.
Skin: Can cause damage, chemical bum.
Emergency And First Aid Procedures:
Eyes: Immediately flush with water for at least fifteen (15) minutes. Get medical attention.
Skin: Remove soaked clothes. Wash with plenty of soap and water for at least fifteen (15) minutes.. Inhalation: Remove to fresh air.
Call physician, if exposure is severe.
Ingestion: if conscious, drink large quantities of milk, or gelatin solution, or if these are not available, drink large quantities of water. Do not give vinegar or other acids. Do not induce vomiting. Get prompt medical attention.
Section VI - Reactivity Data Conditions Contributing to Instability:
Solutions are fairly stable in concentrations below 10%. Stability decreases with concentration, light, heat, fire, decrease in pH, metallic impurities such as nickel, cobalt, copper, and iron. Naturally decomposes with age.
Incompatibility.
Acids, alcohols, amines, ammonia,'chlorinated isocyanurates, combustibles, cyanides, detergents, ethers, hydrocarbons, oxidizable materials, reducing agents. Corrosive to most metals.
Decomposition Products:
Contact with acid releases chlorine -gas:
natural decomposition product is oxygen.
Thermal decomposition, or burning, may produce hydrochloric acid. Contact with ammonia may release hazardous gases.
Other decomposition products are hypochlorous acid, sodium chlorate, sodium chloride.
Conditions Contributing To Hazardous Polymerization:
None, does not polymerize.
a i
Hypochlorite Page 2
se ion VII - Spill Qr Leak Procedures Steps To Be Taken If Material Is Released Or Spilled:
Contain in diked area. Neutralize with sodium bisulfite or ferrous salt solution. Place neutralized material in DOT specification approved container(s). Flush area With large amounts of water. Comply with all Federal, State and Local reporting requirements. Clean up personnel must wear proper protective clothing.
Waste Disposal:
Contact Federal, State, County and Local environmental regulators for guidance regarding proper disposal.
Section Vill - Special Protection Information Ventilation Requirements:
Local Exhaust is recommended.
Specific Personal Protective Equipment:
Respiratory. Use National Institute of Occupational Safety and Health (NIOSH) or Mine Safety and Health Administration (MSHA) approved respirator appropriate for this product when permissible exposure limits are exceeded.
Eyes: Use chemical goggles and face shield.
Gloves: Use rubber or neoprene gloves.
Other: Use rubber splash apron and rubber boots. Safety shower and eye wash fountain should be located nearby.
Section IX-Special Precautions Precautions To Be Taken In Handling:
Dariger This product is corrosive and may cause severe skin irritation or chemical bums to broken skin. Causes eye damage. Do not get in eyes, on skin or on clothing. Wear goggles and face shield and rubber gloves when handling this product. Wash after handling. Avoid breathing vapors. Vacate poorly ventilated areas as soon as possible.
Do not return until odors have dissipated.
Proper Storage And Disposal Requirements Store in a cool, dry area away from direct sunlight. In case of spill, floor area with large quantities of water. Rinse empty container thoroughly with water and either return to manufacturer or discard by placing in trash collection or burning in an approved landfill.
Product or rinseate that cannot be used should be diluted with water and disposed of in a sanitary sewer. Do not contaminate food, or feed by storage, disposal or cleaning of equipment. Store in an upright position.
Other Precautions:
Strong Oxidizing Agent: Mix only with according to label directions. Mixing this product with gross filth such as feces, urine, etc. or with ammonia, acids, detergents or other chemicals may release hazardous gases irritating to eyes, lungs and mucous membranes.
Additional Regulatory Concerns:
EPA: May not be used for disinfection or sanitizing without prior approval by EPA/
Repackagers must obtain EPA registration and establishment numbers.
FIFRA. This product is regulated under the Federal Insecticide, Fungicide, and Rodenticide Act. (FIFRA) if used as a disinfectant or sanitizer.
TSCX Included in the Toxic Substances Control Act (TSCA) Inventory or chemical Substances.
MSDA Prepared By:
Rowell Chemical Corporation 15 Salt Creek Ln. Suite 205 Hinsdale, II. 60521 (708) 920-8833 Issue Date: 10/8/93 Revision Date: 12/22/94 SMG Printed on: 2/28195 The information herein is given in good faith but no warranty, expressed or implied is made.
2/28/95 MSDS Sodium Hypochlorite Page 3
-~
MAYS CHEMICAL CO. INC BioRidTM 40i w
NM T~q875 E 112t Sreet FiJe: MSDS: C-127 Bow'i TETRA Chicago, IL 60628 (773)928-364 TETRA Technologies, Inc.
Material Safety Data Sheet This MSOS Shat cotnpfls a
~he fic ne foin Spcnfid by A2NS! Z4OO.I.-1993 SECTION 1: CHEMICAL PRODUCT - COMPANY IDENTIFICATION TETRA Technologies, TIcorporated 25025 1-45 North The Woodlands, Texas 77380 (218) 367-1983 (800) 327-7817 (800) 424-9300 - CKEMTREC (24 Hour Emergency Response)
SUBSTANCE: Sodium Bromide Solution TRADE NAMES/SYNONYMS: BioRidT' 40i, Liquid Sodium Bromide, NaBr CEICAL FAMIY: Inorganic Salt MSDS CREATION DATE: 03 AUG 98 MSDS REVISION DATE: 03 AUG 98 SECTION 2: COMPOSITION, INFORMATION ON INGREDIENTS COMPONENTS: Sodium Bromide, Water CAS NUMBER: 7647-15-6 (Sodium Bromide), 7732-18-5 (Water)
RTECS NEIER: VZ3150000 (Sodium Bromide)
PERCENTAGE:
Sodium Bromide 1 - 46%
Water 54 - 99%
PROBABLE CONTAMlNJANT: Sodium Chloride SECTION 3: HAZARDS IDENTIFICATION NEA RATINGS: (SCALE 0-4): HEALTH-0, FMRE=0, I-EACTlVlY=O EMRGENCY OVERVIEW: Odorless, colorless, clear liquid. May cause skin, respiratory tract and eye initation. Do not get in eyes, on slin or on clothing. May be harmful if swallowed but not an expected pathway in an industrial environment. Keep container tightly closed. Wash thoroughly aft& handling.
Use only with adequate ventilation.
I of 8
1 MAYs CHEMICAL co.itic BioRidT" 40i "OjI9 7 S E 12th Sreet FBile: MdS:C-lam Chicago, IL 60228.
Pilc: MSDS: C-127 w
t o
(773)92e-3844 TETRA Technologies, Inc.
Materal Safety Data Sheet Tis MSDS Shad cunplc wkh the ste fmrs soccified by ANSI Z400.1-1993 POTENTIAL HEALTH EFFECTS:
UiIALATION:
Short Tern Effects: May cause irritation Long Term Effects: No information available.
SKIN CONTACT:
Short Term Effects: No information available.
Long Term Effects: No information available.
EYE CONTACT:
Short Term Effects: May cause irritation, Additional effects may include tearng.
Long Terim Effects: No inflnnation available.
INGESTION:
Short Term Effects: May cause nausea, vomiting, digestive disorders, headache and kidney damage.
Long Term Effects: No information available.
CARCINOGEN STATUS:
OSHA: No NTP: No IARC: No SECTION 4: FIRST AID MEASURES INHALATION. Remove from eposure area to fresh air immediately. If breathing has stopped, perfn=n artificial resuscitation. Keep person comfortable and at rest. Treat symptomatically and supportively.
Get medical attention immediately.
SKIN CONTACT: Remove contaminated clothing and shoes immediately. Wash affected area with soap or mild detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes). In cases of burns, cover area loosely witb sterile, dry dressing Get medical attention immediately.
EYE CONTACT: Flush eyes immediately with large amounts of water or normal saline solution, occasionally lifling upper and lower lids until no evidence of chemical remains (approximately 15-20 minutes). Get medical attention immediately.
INGESTION: Treat symptomatically and supportively. Get medical attention immediately. If vomiting occurs, keep head lower than hips to prevent aspiration.
NOTE TO PHYSICIAN: Antidote:
Antidote should be administered by qualified medical personnel. No specific antidote has been recommended. Treat symptomatically and supportively. The following antidote has been recommended for bromide poisoning. However, the decision as to whether the severity of poisoning requires administration of any antidote and actual dose required should be made by qualified medical personnel.
2 of 8
AAYS CHEMICAL CO. INC WChao, IL 60B28 BioRid` 40i w
TEtA (773 926-3644 File: MSDS: C-127 TETRA Telhnologies, Inc.
Material Safety Data Sheet Ibih MSDS She" cmpliesi vwi the sve formœt spedfid by ANSI ZA001 -1993 BROM]DE POISONING: Give sodium chloride, 1 gram orally every hour in water or as salt tablets; for severe involvement in which oral medication is impossible, give normal saline, 1 liter every 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> intravenously to a maximum of 2 liters daily. Sodium chloride therapy must be continued until the blood bromide level drops below 50 mg/dL. Simultaneous administration of diuretics is also usefifl (Driesbach, Handbook ofPoisoning, 12th Ed.).
SECTION 5: FIRE FIGHTING MEASURES MIRE AND EXPLOSION HAZARD: Negligible fire hazard when exposed to heat or flame.
EXT11MGUJSHING MEDIA: Dry chemical, carbon dioxide, water spray or rzguarfoam. Forairger fires, use waker 5pTay, fog or regular foam.
F EFIGHTING: Move container(s) from fire area if you can without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Extinguish fire using agent suitable for type ofsurrounding fire and/or chemicals. Do not use water directly on material. Avoid breathing corrosive vapors; keep upwind. Dike area to prevent runoff and contamination of water sources.
BRAZA1DOUS COMBUSTION PRODUCT: Thermal decomposition products may include toxic and corrosive funes of bromnine, hydrogen bromide and sodium oxide. Product may react with some metals (aluminum, zinc, tin, etc.) to release flammable hydrogen gas.
SECTION 6: ACCIDENTAL RELEASE MEASURES OCCUPATIONAL SPILL: Do not touch spilled material. Stop leak if you can without risk. For small spills, take up with sand or other absorbent material and place in containers.for disposaL Move containers from spill area For larger spills, dike far ahead of spill for later disposal. Keep unnecessary people away. Isolate hazard area and deny entry.
SECTION*7: HANDLING AND STORAGE Observe all federal, state and local regulations when storing this product. Store in a tightly closed-container.
Store away fronm incompatible materials.
30f8
MAYS CHEMICAL CO. INC A_______
87 5 E 112tl Sreet BioRidT" 40i Chicago, IL 60628 JEW xETRA (773)928
-M File: MSDS: C-127 TETRA Technologies, Inc.
Material Safety Data Sheet This MSDS Shed cvmes wtIh the rtvie are fc eced be SANSIZ 400.1-1 9 SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS: No occupational exposure limits established by OSHAMACGIH(NIOSH.
'VENT LATION: Provide local exhaust ventilation system.'
EYE PROTECTION: Wear safety glasses with splash shields or safety goggles/shield to prevent contact with this product.
EMERGENCY WASH FACILITIES: Where there is any possibility that an employee's eyes and/or skin may be exposed to this product, the employer should provide an eye wash fountain and quick drench shower within the immediate work area for emergency use.
CLOTHING: Employee must wear appropriate protective (impervious) clothing and equipment to prevent repeated or prolonged skin contact with this product GLOVES: Ern.ployee must wear approriate protectivegloves to prevent coxact.wih thbis product-RESPIRATOR: The respirator selected must be based on contamination levels found in the work place and specific to the job assignment. Do not exceed the worldng limits of the respirator. Respirators must also be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). These respirators are ranked from.minimU to maximum respiratory protection as listed below:
- Any dust and mist respirator with a fWll facepiece;
- Any air-purifying full facepiece respirator with a high-efficiency particullate filter, wAny powered air-purifying respirator with a tight-fitting facepiece and high-efficiency particulate
- filter,
- Any Type 'C' supplied-air respirator with a full facepiece operated in pressure-demand or other positive-pressure mode or with'a full facepiece, helmet or hood operated in continuous-flow mode;
- Any self-contained breathing apparatus with a full facepiece operated in pressure-dcmand or other positive-pressure mode.
FOR F7REFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR EALTH CONDITIONS: Any self-contained breathiiDg apparatus that Jas a full facepiece and is opated in.a pressure-demand or other positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with adi auxiliury self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
4of8
M~AYS CHEMICAL CO. INC 87.5 E 112th Sreet BioRidT 40i Chicago, IL 60828 Fioic:MDS C-12 AU -
(773)028-3644 FLIC: MDS: C-127 IS-TETRA low TETRA Technologies, Inc.
Material Safety Data Sheet Whis MSDS Shed ca plies wikh the svvie ormt spfid bV ANSI Z400.1.1993 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES DESCPTION: Odorless, colorless, clear liquid.
FORMULA: NaBr MOLECULAR WEIGHT: 102.90 (for pure NaBr)
'BO IG PO
,T:
.Not determined.
SPECIFIC GRAVITY: 1.007-1.522 @ 68°F (20°C)
WATER SOLUBILITY: Miscible with water in all proportions.
SOLVENT SOLUBILITY: Slightly to moderately soluble in alcohol.
SECTION 10: STABILITY AND REACTITY REAC'IVITY: Stable under normal temperatures and pressures. Can evolve }hdrogen bromide and/or bromine when strongly heated.
CONDITIONS TO AVOII: Vapors may accumulate in tanks and hopper cars.
IINCOMPATIBILITIES:
Strong acids, strong oxidizers and metal salts.
- AZARDOUS DECOMPOSITION: Thermal decomposition products may include toxic and corrosive fumes of hydrogen bromide, bromine and sodium oxide.
POLYMERIZATION: Hazardous polymerization has not been reported to oeccwr under normal temperahures and pressures.
SECTION 11: TOXICOLOGICAL INFORMATION TOXICITY DATA (SODIUM BROME):
LD, 0: 3500 ng/lkc rat, oral LDso: 2900 ngk& rat, subcutaneous Mutagenic data and tumorigenic data-see Registry of Toxic Effects of Chemical Substances (RTECS) file.
CARCINOGEN STATUS: None.
LOCAL EFFsCrS: Sodium Bromnide is an eye, mucous membrane and skin irritant.
ACUTE TOXICITY LEVEL: Moderately toxic by ingestion.
TARGET EFFECTS: No data available.
INHALATION:
Acute Exposure: Inhalation of mist may cause irritation with coughing and shortness of breath.
Chronic Exposure: No data available.
Sof8
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'Ltt-MLJAL UV.
INC 875 E 112th Sreet
________caoILWMBioRidTm~
40i A
e2 T7E38-R44 File: MSDS: C-127 w.~~~~~~
TERA Technologies, Inc.
Material Safety Data Sheet Ibis MSDS Shea cnilia wkh the svlae Ibrmna We~fled by ANSI Z40.1-903 SKIN CONTACT:
Acute Exposure: Single, short exposure not likely to cause significant skin irritatiom However, direct contact with dust or solutions may cause severe irritation, erythema, blistering, exfoliation, ulceration, necrosis and scarring. The degree of irritation depends on the concentration and duration of contact.
Chronic Exposure: Effects depend on concentration and duration of exposure. Repeated or prolonged contact with corrosive substances may result in dermatitis or effects similar to those in acute exposure.
EYE CONTACT:
Acute Exposure: Direct contact may cause irritation with redness and pain and superficial injury.
Tearing and eye discharge may also occur.
Chronic Exposure: Repeated or prolonged exposure may result in conjunctivitis.
INGESTION:
Acute Exposure: Poisoning by acute exposure is rare because bromides irritate the gastric rzucosa when ingested in large'amounts as a single dose and cause immediate abdominal pain, nausea and vomiting.
Chronic Exposure: Repeated or prolonged ingestion of bromides may cause 'bromism' which most frequently affects the gastrointestinal system, the central nervous system, and the skin. Gastintestinal disturbances may include nausea and vomiting from gastric irritation, foul breath, weight loss, dehydration, and constipation. Neurological manifestations may include headache, decreased memory, impaired intellectual capacity, and ataxia. Discontinuation of exposure will normally result in reversal of symptoms. Maternal exposure may result in hypotonia in neonates.- May cause abdominal spasms and nausea. Overdose may cause gastrointestinal tract or cardiovascular irregularities.
SECTION 12: ECOLOGICAL INFORMATION ENVIRONMENTAL IMPACT RATING (0-4): No data available.
ECOTOX[CITY DATA:
Fish Toxicity: 16,000,000 pg/L, 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br />(s), I.Cso (Mortality), Guppy (Poecilia reticulato) lIwertebrate Toxicity: 5,700,000 - 10,800,000 pgfL, 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br />(s), EC-" (Immobilization), Water flea (DaPhnia magn)
DEGRADABILITY: No data available.
LOG BIOCONCJENTRATION FACTOR (RC.): No data available.
LOG OCTANOLUWATER PARTITION COEFFICtENT: No data available.
- SECTION 13: DISPOSAL INFORMATION Observe all federal, state and local regulations when disposing of this substance.
6 of 8
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-TETRIA T:ETRA Technologii MAYS CHEMICAL CO. INC 875 E 112thSreet Chicago, IL 60628 BioRidT" 40i (M)Ja28344 File: MSDS: C-127 es, Inc.
Material Safety Data Sheet Mis MSW Shea c-mvlics wih h t stvle fru by I
Z SECTION 14: TRANSPORT INFORMATION US DOT Shipping Name-ID Number. No classification assigned.
Air Tranwport IATAMCAO: No classification assigned.
Maritime Transport MDG: No classification assigned.
land Transport ADR/RID: No classification assigned.
SECTION 15: REGULATORY INFORMATION United States:
40 CFR 302.4 40 CFR 355.30 40 CFR 355.40 40 CFR 372.65 40 CFR 370.21 29 CFR 1910.119 TSCA STATUS:
CERCLA SEC17ON 103:
SARA SECTION 302:
SARA SECTION 304:
SARA SECTION 313:
Yes No No No NO SARA HAZARD CATEGORIES, SARA SECTIONS 311/312 ACUTE HAZARD:
CHRONIC HAZARD:
FIRE HAZARD:
REACTIVITY HAZARD:
SUDDEN RELEASE HAZARD:
OSHA Process Safety STATE REGULATIONS:
CALIFORNIA PROPOSMON 65:
No No No No No No No Foreign:
CANADIAN DOMESTIC SUBSTANCE LIST (DSL)
NON-DIOMESTIC SUBSTNACE LIST (NDSL)
EUROPEAN REGULATIONS (EINECS)
AUSllAN INVENTORY of CHEMICAL SUBSTANCES (AICS)
JAPAN INVENTORY STATUS (ENCS)
KOREA (ECL)
Yes No Yes Yes Yes Yes 7?f8
,A MAYS CHEMICAL CO. INC 875 E 112th Srei BioRid~ 40i
____Chicago.
IL 60828 File: MISDS: C-127 (773)923644F TETJRA Technologies, Inc.
Material Safety Data Sheet Thu USDS Sheet comwlie with the vvie (mom soedried by ANSI Z400.1-1993 SECTION 16: OTHER INFORMATION Individuals handling this product should be informed of the recommended safety precautions and should have access to this information.
This information relates to the specific product designated and may not be valid for such product used in combination with any other materials or in any other processes. Such information is to the best of our knowledge and belie, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuacy, reliability, or completeness. It is the user's responsibility to satisfy themselves as to the suitability and completeness of such information for their own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warTanty against patent infringement TETRA Technologies, Incoiporated reserves the right to refise shipment of this product to any consumer who fails to demonstrate the ability to consistently handle and use it safely and in compliance with all applicable laws, rules and regulations. Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling systems that come in contact with it.
Customers are responsible for compliance with local, state and federal regulations that may be pertinent in the storage, application and disposal of this product.
8of 8
(Rhodia SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2127196
.
- 1. PRODUCTAND COMPANYDESCRIPTION
- RHODIA INC.
RHODIA PHOSPHATE PRODUCTS CN 7500 259 Prospect Plains Road Cranbury NJ 08512-7500 i
Emergency Phone Numbers:
FOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT CONTACT: CHEMTREC (800-424-9300 within the United States or 703-527-3887 for international collect calls) oriRhodia CAERS (Communication and Emergency Response System) at 800-916-3232.
For Product Information:
(800) 243-5052 Chemical Name or Synonym:
SODIUM POLYPHOSPHATE SOLUTION
- 2. COMPOSITION/INFORMA TION ON INGREDIENTS OSHA Component CAS Reg Number Hazard Percentage SODIUM POLYPHOSPHATES 68915-31-1 N
30 -
50 ALTERNATE CAS # (SODIUM HEXAMETAPHOSPHATE) 10124-56-8 N
WATER 7732-18-5 N
50 -
70
- 3. HAZ74RDS IDENTIFICATION A.
EMERGENCY OVERVIEW:
Physical Appearance and Odor:
colorless / liquid, odorless.
Warning Statements:
Based on currently available data, this product does not meet the regulatory definition of a hazardous substance. However, good industrial EmXofndge~.J
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jhodia SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27196
- 3. HAZARDS IDENTIFICATION (Continued) hygiene practices should be used in handling it.
B. POTENTIAL HEALTH EFFECTS:
Acute Eye:
May cause irritation.
Acute Skin:
May cause slight transient irritation, on prolonged contact.
Acute Inhalation:
Low acute inhalation toxicity.
Acute Ingestion:
Ingestion of large quantities may cause nausea, vomiting, diarrhea, abdominal cramps, decreased blood pressure, decreased heart rate, coma.
Chronic Effects:
This product does not contain any ingredient-designated by IARC, NTP, ACGIH or OSHA as probable or suspected human carcinogens.
- 4. FIRSTAID MEASURES FIRST AID MEASURES FOR ACCIDENTAL:
Eye.Exposure:
Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek medical attention if irritation develops or persists or if visual changes occur.
Skin Exposure:
In case of contact, immediately wash with plenty of soap and water for at least 5 minutes. Seek medical attention if irritation develops or persists. Remove contaminated clothing and shoes. Clean contaminated clothing and shoes before re-use.
Inhalation:
If respiratory irritation or distress occurs remove victim to fresh air.
Seek medical attention if respiratory irritation or distress continues.
Ingestion:
If victim is conscious and alert, give 2-3 glasses of water to drink and E~n d,,fY ~Paggetnl2
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SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96
~~~~~~~~~~~~~~~
.~~~~~~~~~~~~~~
- 4. FJRSTAID MEASURES, (Continued) induce vomiting by touching back of throat with a finger. Do not induce vomiting or give anything by mouth to an unconscious person.'Seek immediate medical attention. Do not leave victim unattended. Vomiting may occur spontaneously. To prevent aspiration of swallowed product, lay victim on side with head lower than waist. If vomiting occurs and the victim is conscious, give water to further dilute the chemical.
MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE:
Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema or bronchitis. Skin contact may aggravate existing skin disease.
NOTES TO PHYSICIAN:.
All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.
Ingestion of large quantities of phosphate salts (over 1.0 grams for an adult) may cause an osmotic catharsis resulting in diarrhea and probable abdominal cramps. Larger. doses such as 4-8 grams will almost certainly cause these effects in everyone. In healthy individuals most of the ingested salt will be excreted in the feces with the diarrhea' and, thus, not cause any systemic toxicity. Doses greater than 10 grams hypothetically may cause systemic toxicity. Treatment should take into consideration both anionic and cation portion of the molecule.'The following treatments should be considered for the specific group(s) of phosphate salts found in this product:
--All phosphate salts, except calcium salts, have a hypothetical risk of hypocalcemia, so calcium levels should be monitored.
-- Ammonium salts have a hypothetical risk of ammonia toxicity. In
' addition to calcium levels, ammonia and phosphate levels should be monitored.'
-- Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. In addition to calcium levels, potassium and phosphate levels should be monitored. Also consider continuous EKG monitoring to detect hyperkalemia.
-- Sodium salts have a hypothetical risk of hypernatremia.
In addition to calcium levels, sodium and phosphate levels should be monitored.
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SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96
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- 5. FIRE FIGHTING MEASURES FIRE HAZARD DATA:
Flash Point:
Not Applicable Extinguishing Media:
Not combustible. Use extinguishing method suitable for surrounding fire.
Special Fire Fighting Procedures:
Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing.
Unusual Fire and Explosion Hazards:
Not combustible.
Hazardous Decomposition Materials (Under Fire Conditions):
oxides of phosphorus oxides of sodium
- 6. ACCIDENTAL RELEASE MEASURES Evacuation Procedures and Safety:
Wear appropriate protective gear for the situation. See Personal Protection information in Section 8.
Containment of Spill:
Dike spill using absorbent or impervious materials such as earth,.sand or clay. Follow procedure described below under Cleanup and Disposal of Spill..
Cleanup and Disposal of Spill:
Absorb with an inert absorbent. Sweep up and place in an appropriate closed container (see Section 7: Handling and Storage). DO NOT RETURN MATERIAL TO ITS ORIGINAL CONTAINER.
Environmental and Regulatory Reporting:
Prevent material from entering public sewer system or any waterways.
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2/17/00 Supersedes Date:
2/27/96 He.U
- 7. HANDLING AND STORAGE Minimum/Maximum Storage Temperatures:
Not Available Handling:
Keep containers closed when not being used.
Storage:.
Store in an area that is cool, dry.
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Introductory Remarks:
These recommendations provide general guidance for handling this' product. Because specific work environments and material handling practices vary, safety procedures should.be developed for each intended application. While developing safe handling procedures, do not overlook the need to clean equipment and piping systems for maintenance and repairs. Waste resulting from these procedures should be handled in accordance with Section 13: Disposal Considerations.
Assistance with selection, use and maintenance of worker protection equipment is generally available from equipment manufacturers.
Exposure Guidelines:
No exposure limits were found for this product or any of its ingredients.
Engineering Controls:
Where engineering controls are indicated by use conditions or a potential for excessive exposure exists, the following traditional exposure control techniques may be used to effectively minimize employee exposures: local exhaust ventilation at the point of generation.
Respiratory Protection:
When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations.
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Conitrevonat t~ge
QIhodia SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (Continued)
Eye/Face Protection:
Eye and face protection requirements will vary dependent upon work environment conditions and material handling practices. Appropriate ANSI Z87 approved equipment should be selected for the particular use intended for this material.
It is generally regarded as good practice to wear a minimum of safety glasses with side shields when working in industrial environments.
Skin Protection:
Skin contact should be minimized through use of-gloves and suitable long-sleeved clothing (i.e., shirts and pants). Consideration must be given both to durability as well as permeation resistance.
Work Practice Controls:
Personal hygiene is an important work practice exposure control measure and the following general measures should be taken when working with or handling this material:
(1) Do not store, use, and/or consume-foods, beverages, tobacco products, or cosmetics in areas where this material is stored.
(2) Wash hands and face carefully before eating, drinking, using tobacco, applying cosmetics, or using the toilet.
(3) Wash exposed skin promptly to remove accidental splashes of contact with this material.
- 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical properties here represent typical properties of this product. Contact the business area using the Product Information phone number in Section 1 for its exact specifications.
Physical Appearance:
colorless / liquid.
Odor:
odorless.
En&ofrPwge..~
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hodia SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96 r
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- 9. PHYSICAL AND CHEMICAL PROPERTIES (Continued)
~pH:
5.5 to 8 at 1 wt/wtt.
Specific Gravity:
1.5 at 20 C (68 F).
Water Solubility:
miscible Melting Point Range:
Not Available Boiling Point Range:
Not Available Vapor Pressure:
Not Available Vapor Density:
Not Available
- 10. STABILJ1YAND REACTIVITY Chemical Stability:
This material is stable under normal handling and storage conditions described in Section 7.
Conditions To Be Avoided:
none known' Materials/Chemicals To Be Avoided:
none known Tle Following Hazardous Decomposition Products Might Be Expected:
Decomposition Type: thermal oxides of phosphorus oxides of sodium Hazardous Polymerization Will Not Occur.
Avoid The Following To Inhibit Hazardous Polymerization:
not applicable Eu&ndofY'ge. 7
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Rhodia SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96 V__MMTX~~
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- 11. TOXICOLOGICAL INFORMATION
- Acute Eye Irritation:
Toxicological Information and Interpretation eye -
eye irritation, rabbit.
Mildly irritating. Unwashed.
eye -
eye irritation, rabbit.
Non-irritating. Washed. Data for sodium polyphosphates.
Acute Skin Irritation:
No test data found for product.
Acute Dermal Toxicity:
No test data found for product.
Acute Respiratory Irritation:
No test data found for product.
Acute Inhalation Toxicity:
No test data found for product.
Acute Oral Toxicity:
Toxicological Information and Interpretation LD5O - lethal dose 50k of test species, 3053 Data for sodium polyphosphates.
Chronic Toxicity:
This product does not contain any substances OSHA, NTP, IARC or ACGIH to be "probable" or carcinogens.
mg/kg, rat.
that are considered by "suspected" human
- 12. ECOLOGICAL INFORMATION Ecotoxicological Information:
No data found for product.
Chemical Fate Information:
No data found for product.
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SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96
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- 13. DISPOSAL CONSIDERATIONS Waste Disposal Method:
Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate, Please be advised that state and.local requirements for waste dispobal may be more restrictive or otherwise different from federal laws and regulations.
Consult state and local regulations regarding the proper disposal of this material.
EPA Hazardous Waste -
NO
- 14. TRANSPORTATIONINFORMATION Transportation Status: IMPORTANT! Statements below provide additional data on listed DOT classification.
The listed Transportation Classification does not address regulatory variations due to changes in package size, mode of shipment or other regulatory descriptors.
US Department of Transportation Shipping Name:
NOT REGULATED 1$. REGULA TORYINFORMATION Inventory Status Inventory Status UNITED STATES (TSCA) y CANADA (DSL) y EUROPE (EINECS/ELINCS)
Y AUSTRALIA (AICS) y JAPAN (MITI) y SOUTH KOREA (KECL) y Y = All ingredients are on the inventory.
E = All ingredients are on the inventory or exempt from listing.
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SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96
- 15. REGULATORYINFORMATION (Continued)
P = One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All other ingredients are on the inventory or exempt from listing.
N = Not determined or one or more ingredients are not on the inventory and are not exempt from 'listing.
FEDERAL REGULATIONS Inventory Issues:
All functional components of this product are listed on the TSCA Inventory.
SARA Title III Hazard Classes:
Fire Hazard NO Reactive Hazard NO Release of Pressure NO Acute Health Hazard NO Chronic Health Hazard '-
NO SARA Extremely Hazardous Substances (EHS)/CERCLA Hazardous Substances Ingredient CERCLA/SARA RQ SARA EHS TPQ ALTERNATE CAS # (SODIUM HEXAMETAPHOSPHATE) 5000 lbs OTHER FEDERAL REGULATIONS:
FDA Status:
This product meets the compositional requirements of:
21 CFR 182.6760 SODIUM HEXAMETAPHOSPHATE STATE REGULATIONS:
This product does not contain any components that California Proposition 65.
are regulated under
- 16. OTHER INFORMATION National Fire Protection Association Hazard Ratings-NFPA(R):
'0 Health Hazard Rating--Minimal 0 Flammability Rating--Minimal 0 Instability Rating--Minimal National Paint & Coating Hazardous Materials Identification System-HMIS(R):
.r n ~ o f ~ a g e J
~ C o ~ t i n u e d.~ o n ~ e x-g-.
C j Rhodia SODIUM POLYPHOSPHATE GLASSY SOLUTION Material Safety Data Sheet Date Prepared:
2/17/00 Supersedes Date:
2/27/96 00 C.
0cc00C0X.
- 16. OTHER INFORMATION (Continued) o Health Hazard Rating--Minimal 0 Flammability Rating--Minimal 0 Reactivity Rating--Minimal Reason for Revisions:
Regulatory Review and Update.
Key Legend Infonnation:
ACGIH - American Conference of Governmental Industrial Hygienists OSHA -
occupational Safety and Health Administration TLV -
Threshold Limit Value PEL -
Permissable Exposure Limit TWA -
Time Weighted.Average STEL -
Short Term Exposure Limit NTP -
National Toxicology Program
- IARC -
International Agency for Research on Cancer ND -. Not determined RPI -
Rhone-Poulenc Established Exposure Limits Disclaimer:
The information herein is given expressed or implied, is made.
in good faith but no warranty, E&fYageJ.LEndoLMSDSP.ocun1ent
ARZ1111 BOC GASES MATERIAL SAFETYDATA SHEET IPRODUCT NAME: CARBON DIOXIDE, REFRIGERATED LIQUID I
575 Mountain Avenue Murray Hill, NJ 07974 TELEPHONE NUMBER: (908) 464-8100
.24-HOUR EMERGENCY TELEPHONE NUMBER: CHEMTREC (800) 424-9300 BOC Gases Division of BOC Canada Limited 5975 Falbourne Street, Unit 2 Mississauga, Ontario LSR 3W6 TELEPHONE NUMBER: (905) 501-1700 24-HOUR EMERGENCY TELEPHONE NUMBER: (905) 501-0802 EMERGENCY RESPONSE PLAN NO: 2-0101 PRODUCT NAME: CARBON DIOXIDE, REFRIGERATED LIQUID CHEMICAL NAME: Carbon Dioxide COMMON NAMES/SYNONYMS: Carbonic Anhydride, Refrigerated Liquid TDG (Canada) CLASSIFICATION: 2.2 WHMIS CLASSIFICATION: A PREPARED BY: Loss Control (908)464-8100/(905)501-1700 PREPARATION DATE: 6/1/95 REVIEW DATES: 6/1/99 -
- 2. Composition, Information on Ingredients EXPOSURE LIMITS':
Carbon Diodde FORMULA: CO2 CAS: 124-38-9 RTECSS: FF640 I Refer to individual state orprovincial regulations, as applicable, for limits which may be more stringen, than those listed here.
2 Asstatedin29CFR 1910. SubpartZ(revisedJuly 1. 1993)
'As stated in the ACGIH 1998-1999 Threshold Limit Values for Chemical Substances and Physical Agents.
IDLH (Carbon Dioxide): 40,000 ppm OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations.
- 3. Hazards Identification EMERGENCY OVERVIEW Odorless, colorless, non-flammable liquefied gas. Maintain oxygen levels above 19.5%. Carbon dioxide exposure can cause nausea and respiratory problems. High concentrations may cause vasodilation leading to circulatory collapse. Contact with liquid product may cause frostbite in exposed tissues. Contents under pressure. Use and store below 125 "F.
MSDS: G-99 Revised: 6/1/99 Page I -of 6
I PRODUCT NAME: CARBON DIOXIDE, REFRIGERATED LIQUID ROUTE OF ENTRY:
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion Yes l
No l
Yes l
Yes l
No HEALTH EFFECTS:
Exposure Limits Irritant Sensitization Yes No No Teratogen Reproductive Hazard Mutagen No No No Synergistic Effects None reported Carcinogenicity: - NTP: No IARC: No OSHA: No EYE EFFECTS:
Contact with evaporating liquid may cause frostbite.
SKIN EFFECTS:
Contact with liquefied product may cause frostbite upon evaporation. Frostbite effects are a change in color of the skin to gray or vhite, possibly followed by blistering. Skin may become inflamed and painful.
INGESTION EFFECTS:
Ingestion is unlikely. Contact with liquid may cause frostbite.
INHALATION EFFECTS:
Carbon dioxide is a cerebral vasodilator. Inhaling large concentrations can cause rapid circulatory insufficiency leading to coma and death. Chronic, harmful effects are not known from repeated inhalation of low concentrations. Low concentrations of carbon dioxide cause increased respiration and headache.
Product may also act as asphyxiant. Effects of oxygen deficiency may include: rapid breathing, diminished mental alertness, impaired muscular coordination, faulty judgement, depression of all sensations, emotional instability, and fatigue. As asphyxiation progresses, nausea, vomiting, prostration, and loss of consciousness may result. eventually leading to convulsions, coma, and death.
Oxygen deficiency during pregnancy has produced developmental abnormalities in humans and experimental animals.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known.
NFPA HAZARD CODES Health:
3 Flammability: 0 Instability:
0 HMIS HAZARD CODES Health:
3 Flammability: 0 Reactivity:
0 RATINGS SYSTEM 0 = No Hazard I = Slight Hazard 2 = Moderate Hazard 3 = Serious Hazard 4 = Severe Hazard MSDS: G-99 Revised: 6/1199
.Page 2 of 6
I PRODUCT NAME: CARBON DIOXIDE, REFRIGERATED LIQUID I
- 4. First Aid Measures EYES:
Never introduce oil or ointment into the eyes without medical advice! In case of freezing or cryogenic "burns" by rapidly evaporating liquid. DO NOT WASH THE EYES WITH HOT OR EVEN TEPID WATER! Remove victim from the source of contamination. Open eyelids wide to allow liquid to evaporate. If pain is present, refer the victim to an ophthalmologist for further treatment and follow up. If the victim cannot tolerate light, protect eyes with a light bandage or handkerchief.
SKIN:
Remove contaminated clothing and flush affected area with cold water and soap. DO NOT USE HOT WATER. A physician should see the patient promptly if frostbite has occurred.
INGESTION:
A physician should see the patient promptly if frostbite has occurred.
INHALATION:
PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO CARBON DIOXIDE. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS. Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given mouth-to-mouth resuscitation and supplemental oxygen. Further treatment should be symptomatic and supportive.
- 5. Fire Fighting Measures Conditions of Flammability: Nonflammable Flash point:
Method:
Autoignition None I Not Applicable Temperature: None LEL(Vo): None UEL(%): None Hazardous combustion products: None Sensitivity to mechanical shock: None Sensitivity to static discharge: None FIRE AND EXPLOSION HAZARDS:
Nonflammable. Cylinder may rupture violently from pressure when involved in a fire situation.
EXTINGUISHING MEDIA:
None'required. Use as appropriate for surrounding materials.
FIRE FIGHTING INSTRUCTIONS:
Firefighters should wear respiratory protection (SCBA) and full turnout or Bunker gear. Continue to cool fire-exposed containers until well-after flames are extinguished.
- 6. Accidental Release Measures Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in container or container valve, contact the appropriate emergency telephone number listed in Section 1 or call your closest BOC location.
MSDS: G-99 Revised: 6/1/99 Page 3 of 6
I PRODUCT NAME: CARBON DIOXIDE, REFRIGERATED LIQUID
_ __ - - - -
- 7. Handling and Storage Electrical Classification:
Non-Hazardous.
This liquefied gas is noncorrosive and may be used with all common structural materials.
Dry carbon dioxide can be handled in most common structural materials. Moist carbon dioxide is generally corrosive by its formation of carbonic acid. For applications with moist Carbon Dioxide, 316, 309 and 310 stainless steels may be used as well as Hastelloy 0 A, B, & C, and Monel 0. Ferrous Nickel alloys are slightly susceptible to corrosion. At normal temperatures carbon dioxide is compatible with most plastics and elastomers.
Use only in well-ventilated areas. Carbon dioxide vapor is heavier than air and will accumulate in low areas.
Valve protection caps must remain in place unless container is secured with valve outlet piped to use point.
Do not drag, slide or roll containers. Use a suitable hand truck for container movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (<3000 psig) piping or systems. Do not heat containers by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the system.
Protect containers from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature where containers are stored to exceed 1257F (52 C).
Containers should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first out' inventory system to prevent fIll containers being stored for excessive periods of time.
For additional information, consult the Compressed Gas Association (CGA) pamphlets P-I, G-6 Carbon Dioxide, G-6.1 Standard for Low Pressure Carbon Dioxide Systems at Consumer Sites. G-6.3 Carbon Dioxide Filling and Handling Procedures for Beverage Plants, and SB-2. Never carry a compressed gas cylinder or a container of a gas in cryogenic liquid form in an enclosed space such as a car trunk, van or station wagon. A leak can result in a fire. explosion, asphyxiation or a toxic exposure.
- 8. Exposure Controls, Personal Protection ENGINEERING CONTROLS:
Local exhaust to control air contaminants to at or below acceptable exposure guidelines and maintain atmospheric oxygen at 19.5%.
EYE/FACE PROTECTION:
Safety goggles with faceshield where contact with liquid is possible.
SKIN PROTECTION:
Protective gloves of any material appropriate for thejob. Insulated gloves are recommended for cryogenic liquids.
RESPIRATORY PROTECTION:
Positive pressure air line with full-face mask and escape bottle or self-contained breathing apparatus should be available for emergency use.
OTHER/GENERAL PROTECTION:
Safety shoes, emergency showers MSDS: G-99 Revised: 6/1/99 Page 4 of 6
PRODUCT NAME: CARBON DIOXIDE, REFRIGERATED LIQUID
- 9. Physical and Chemical Properties PARAMETER VALUE UNITS nt-sicA-state {Ps.-
-iNuid.
solid).
- 49c u
rz1yla.%l sat." Jra,,
-J-uau, J
Vapor pressure at 700F Vapor density at 707F, I atm (Air 1)
Evaporation point Boiling point (CO2 Sublimes)
Freezing point PH Specific gravity Oil/water partition coefficient Solubility (1-20)
Odor threshold Odor and appearance
- 856 psia
- 1.53
- Not Available
- -109.3 OF
- -78.5
- -69.8 OF
- -56.6
- Not Available
- Not Available
- Not Available
- Very soluble
- Not Applicable
- A colorless, clear liquid which evaporates to a colorless, odorless gas.
- 10. Stability and Reactivity STABILITY:
Stable.
INCOMPATIBLE MATERIALS:
Certain reactive metals, hydrides. moist cesium monoxide, or lithium acetylene carbide diamino may ignite..
Passing carbon dioxide over a mixture of sodium peroxide and aluminum or magnesium may explode.
HAZARDOUS POLYMERIZATION:
Will not occur.
- 11. Toxicological Information REPRODUCTIVE:
Oxygen deficiency during pregnancy has produced developmental abnormalities in humans and experimental animals.
Exposure of female rats to 60,000 ppm carbon dioxide for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> has produced toxic effects to the embryo and fetus in pregnant rats. Toxic effects to the reproductive system have been observed in other mammalian species at similar concentrations.
OTHER:
Inhaling high concentrations of carbon dioxide may cause circulatory insufficiency leading to coma and death.
Chronic, harmful effects are not known from repeated inhalation of low (3 to 5 molar %/6) concentrations.
- 12. Ecological Information No data given.
MSDS: G-99 Revised: 6/1/99 PageS of 6
[PRODUCT NAME: CARBON DIOXIDE, REFRIGERATED LIQUID
___1.
- 13. Disposal Considerations Do not attempt to dispose of residual wagste or unused quantities. Return in the shipping container PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE to BOC Gases or authorized distributor for proper disposal.
- 14. Transport Information PARAMETER United States DOT Canada TDG PROPER SHIPPING NAME:
Carbon Dioxide, refrigerated liquid
. Carbon Dioxide, refrigerated liquid HAZARD CLASS:
2.2 22 IDENTIFICATION NUMBER:
UN 2187 UN 2187 SHIPPING LABEL:
NONFLAMMABLE GAS NONFLAMMABLE GAS
- 15. Regulatory Information SARA TITLE III NOTIFICATIONS AND INFORMATION SARA TITLE IlI HAZARD CLASSES:
Acute Health Hazard Sudden Release of Pressure Hazard
- 16. Other Information
'ACGIH American Conference orGovernmental Industrial Ho gienists DOT Department ofTransporlation IARC International Agency for Research on Cancer NTP National Toxicology Program OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit SARA Superfund Amendments and Reauthorization Act STEL Short Term Exposure Limit TOG Transportation of Dangerous Goods TLV Threshold Limit Value WHMIS Workplace Hazardous Materials Information System Compressed gas cylinders shall not be refilled without the express written permission of the owner. Shipment of a compressed gas cylinder which has not been filled by the owner or with his/her (written) consent is a violation of transportation regulations.
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness ofthe information contained herein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s).
MSDS: G-99 Revised: 6/1199 Page 6 of 6
, ifBetz~earborn MATERIAL SAFETY DATA SHEET Betz
Dearborn,
Division of Hercules Incorporated 4636 Somerton Road Trevose, PA 19053 Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (HEALTHIACCIDENT)
(800) 877-1940 (USA)
ISSUE DATE: 01-JUN-2001 HMIS RATINGS (See Section 16 for additional information)
HEALTH:
1 FLAMMABILITY:
0 REACTIVITY:
0 I PRODUCT IDENTIFICATION PRODUCT NAME:
FLOGARD POT6102 PRODUCT APPLICATION AREA:
WATER-BASED CORROSION INHIBITOR.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
This product is not hazardous as defined by OSHA regulations.
No component is considered to be a carcinogen by the National Toxicology Program,,the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION May cause slight irritation to the skin. May cause slight irritation to the eyes. Mists/aerosols may cause irritation to upper respiratory tract.
DOT hazard is not applicable Emergency Response Guide is not applicable Odor: None; Appearance: Colorless, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water
POTENTIAL HEALTH EFFECTS I'
ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
ACUTE EYE EFFECTS:
May cause slight irritation to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause slight gastrointestinal irritation.
TARGET ORGANS:
No evidence of potential chronic effects.
MDICAL CONDITIONS AGGRAVATED:.
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
4 FIRST AID MEASURES SKIN CONTACT:
Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water forI15 minutes.
EYE CONTACT:
Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F
> 93C P-M(CC) 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -
Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE
r
- HANDLING:
Normal chemical handling.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS This product is not hazardous as defined by OSHA regulations.
ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
I A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav.(70F,21C) 1.340 Vapor Pressure (mmHG) 22.0 Freeze Point (F) 26 Vapor Density (airsl)
< 1.00 Freeze Point (C)
-3 Viscosity(cps 70F,21C) 14
% Solubility (water) 100.0 Odor None Appearance Colorless Physical State Liquid Flash Point P-M(CC)
> 200F > 93C pH As Is (approx.)
5.5 Evaporation Rate (Ether-l)
< 1.00 NA = not applicable ND not determined 10 STABILITY& REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 TOXICOLOGICAL INFORMATION Oral LD50 RAT:
>2,000 mg/kg NOTE -
Estimated value
? rtcf n7t00Tr.
>?.nnO mn/ka
- 8..~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
NOTE - Estimated value r 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Screen 100% Mortality:
5000 mg/L 0% Mortality:
500 mg/L Bluegill Sunfish 48 Hour Static Screen 0% Mortality:
5000 mg/L Fathead Minnow 96 Hour Acute Toxicity Product toxicity determined from bioassays conducted on individual components.
LC50:
1110 mg/L No Effect Level:
590 mg/L BIODEGRADATION No Data Available.
13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 TRANSPORT INFORMATION DOT HAZARD:
UN / NA NUMBER:
DOT EMERGENCY RESPONSE GUIDE #:
Not Applicable Not applicable Not applicable 15 REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
.)No regulated constituent present at OSHA thresholds POTABLE WATER APPROVAL:
NSF certified. Maximum use 30 mg/L FOOD AND DRUG ADMINISTRATION:
21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)
USDA FEDERALLY INSPECTED NEAT AND POULTRY PLANTS:
This product contains ingredients that have been determined for phosphate potable water (G2) and in boilers or steamlines where the steam may contact food (G6)
SARA SECTION 312 HAZARD CLASS:
Product is non-hazardous under Section 311/312 SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
r j No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 OTHER INFORMATION NFPA/HMIS Health Fire Reactivity Special (1) Protective Equipment I
0 0
NONE B
CODE TRANSLATION Slight Hazard Minimal Hazard Minimal Hazard No special Hazard Goggles, Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG MSDS status:
EFFECTIVE DATE 29-JAN-1997 11-APR-1997 30-APR-1998 01-JUN-2001 REVISIONS TO SECTION:
SUPERCEDES
- NEW **
29-JAN-1997 11-APR-1997 30-APR-1998 15 8;EDIT:9 15
I V I
N.:.1.
j ISSUE DATE: 27-SEP-2000 MATERIAL SAFETY DATA SHEET Betz
Dearborn,
Division of Hercules Incorporated 4636 Somerton Road Trevose, PA 19053 Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT)
(800) 877-1940 (USA)
HMIS RATINGS (See Section 16 for additional information)
HEALTH:
3 FLAMMABILITY:
1 REACTIVITY:
0 r-__
.I.-
1 PRODUCT IDENTIFICATION PRODUCT NAME:
DEPOSITROL BL5400 I
PRODUCT APPLICATION AREA:
WATER-BASED DEPOSIT CONTROL AGENT.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CASE CHEMICAL NAME 2809-21-4 PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS- (HEDP)
Corrosive (eyes)
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the occupational Safety and Health Administration at OSHA thresholds for carcinogens.
3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER May cause moderate irritation to the skin. Corrosive to the eyes.
Mists/aerosols may cause irritation to upper respiratory tract.
DOT hazard: Corrosive to steel Emergency Response Guide #153 Odor: Mild; Appearance: Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water
POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause moderate irritation to the skin.
ACUTE EYE EFFECTS:
Corrosive to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause severe irritation or burning of the gastrointestinal tract.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not' known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin, irritation, and/or tearing of eyes (direct contact).
4 FIRST AID MEASURES SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Thoroughly wash clothing before reuse. Get medical attention if irritation develops or persists.
EYE CONTACT:
URGENT!. Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.
INHALATION:
If nasal,. throat or lung irritation develops - remove to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious-or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F
> 93C SETA(CC)
MISCELLANEOUS:
Corrosive to steel UN3265;Emergency Response Guide #153 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
pbsorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementa permitted waste treatment facility or discharged under a permit. Product as is -
Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Acidic. Corrosive(Eyes). Do not mix with alkaline material.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS- (HEDP)
NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTrVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav.(70F,21C) 1.453 Vapor Pressure (mmHG) 18.0 Freeze Point (F)
< -30 Vapor Density (air=l)
< 1.00 Freeze Point (C)
< -34 Viscosity(cps 70F,21C) 85
% Solubility (water) 100.0 Odor Mild Appearance Colorless To Yellow Physical State Liquid Flash Point SETA(CC)
> 200F > 93C pH As Is (approx.)
< 1.0 Evaporation Rate (Ether=l)
< 1.00 NA not applicable ND = not determined 10 STABILITY & REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
IpCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B".
11 TOXICOLOGICAL INFORMATION Oral LD50 RAT:
2,000 mg/kg NOTE -
RAT LD50: 2,400 mg/kg per alternate source Dermal LD50 RABBIT:
>7,940 mg/kg NOTE -
FHSA Skin Irritation Score RABBIT:
0 Eye Irritation Score RABBIT:
CORROSIVE
- 90 Day Feed Study RAT:
NOEL:10,000 ppm NOTE -
Hemopoeitic effects at 30,000 ppm 90 Day Feed Study DOG:
.062-1%
NOTE -
2 year-feed study. Reversible anemia developed at 1% in diet.
90 Day Feed Study DOG:
20-60 mg/kg NOTE -
30-day study. No pathological effects.
Ames Assay BACTERIA:
NEGATIVE NOTE - +/- metabolic activation Non-Ames Mutagenicity :
NEGATIVE NOTE -
Mouse Lymphoma Assay +/- metabolic activation 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50:
610 mg/L No Effect Level:
250 mg/L Daphnia magna 48 Hour Static Renewal Bioassay pH of test solutions was adjusted to a level of 6-9.
LC50:
755 mg/L No Effect Level:
420 mg/L Bluegill. Sunfish 96 Hour Static Acute Bioassay LC50:
1440 mg/L No Effect Level:
880 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay LC50:
3630 mg/L
.No Effect Level:
170 mg/L Fathead Minnow 96 Hour Static Renewal Bioassay pH.of test solutions was adjusted to a level of 6-9.
LC50:
3040 mg/L No Effect Level:
1370 mg/L Midge larvae (Chironomus tentans) 48 Hour Static Acute Bioassay LC50:
14850 mg/L Grass Shrimp (Palaemonetes pugio) 96 Hour Static Acute Bioassay LC50:
2675 mg/L
- 12) ECOLOGICAL INFORMATION
r..
AQUATIC TOXICOLOGY (continued) mysid Shrimp 4B Hour Static Renewal Bioassay pH of test solutions was adjusted to a level of 6-9.
LC50:
319 mg/L No Data Available.
BIODEGRADATION COD (mg/gm):
TOC (mg/gm):
BOD-5 (mg/gm):
BOD-28 (mg/gm):
300 70 1
1 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the hazardous waste identification number is :
D002-Corrosive(pH, steel).
US RCRA Please be advised; however, that state waste disposal may be more restrictive federal regulations. Consult state and the proper disposal of this material.
and local requirements for or otherwise different from local regulations regarding 14 TRANSPORT INFORMATION DOT HAZARD:
Corrosive to steel UN / NA NUMBER:
UN3265 DOT EMERGENCY RESPONSE GUIDE I: 153 15 REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS:
-Immediate (acute)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 OTHER INFORMATION inventory.
NFPA/HMIS Health Fire Reactivity Special (1) Protective Equipment 3
1 0
CORR B
CODE TRANSLATION Serious Hazard Slight Hazard Minimal Hazard DOT corrosive Goggles, Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
I' CHMi~GE LOG MSDS status:
EFFECTIVE DATE REVISIONS TO SECTION:
28-JAN-1997 23-JUN-1997 03-MAY-2000 12 27-SEP-2000 4,11 SUPERCEDES
- NEW **
28-JAN-1997 23-JUN-1997 03-MAY-2000
4.~
ISSUE DATE: 16-JAN-2001 MATERIAL SAFETY DATA SHEET Betz
Dearborn,
Division of Hercules Incorporated 4636 Somerton Road Trevose, PA 19053 Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT)
(800) 877-1940 (USA)
HMIS RATINGS (See Section 16 for additional information)
HEALTH:
I FLAMMABILITY:
I REACTIVITY:
0 I PRODUCT IDENTIFICATION PRODUCT NAME:
DEPOSITROL BL5323 PRODUCT APPLICATION AREA:
WATER-BASED CORROSION INHIBITOR/DEPOSIT CONTROL AGENT.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CASI CHEMICAL NAME 2809-21-4
- PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS- (HEDP).
Corrosive (eyes)
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING May cause slight irritation to the skin. May cause moderate irritation to the eyes. Mists/aerosols may cause irritation to upper respiratory tract.
DOT hazard is not applicable Emergency Response Guide is not applicable Odor: Slight; Appearance: Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
ACUTE EYE EFFECTS:
May cause moderate irritation to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause slight gastrointestinal irritation.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
4 FIRST AID MEASURES SKIN CONTACT:
Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT:
Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions S FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F
> 93C P-M(CC) 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is -
Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Acidic. Do not mix with alkaline material.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.
8 EXPOSURE CONTROLS I PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID, (1-HYDROXYETHYLIDINE)BIS- (HEDP)
NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
,neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav.(70F,21C) 1.256 Vapor Pressure (mmHG) 18.0 Freeze Point (F) 25 Vapor Density (air-1)
< 1.00 Freeze Point (C)
-4 Viscosity(cps 70F,21C) 90
% Solubility (water) 100.0 Odor Slight Appearance Yellow Physical State Liquid Flash Point P-M(CC)
> 200F > 93C pH As Is (approx.)
2.2 Evaporation Rate (Ether=l)
< 1.00 NA not applicable ND = not determined 10 STABILITY& REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B"
11 TOXICOLOGICAL INFORMATION Oral LD50 RAT:
>2,000 mg/kg NOTE -
Estimated value Dermal LD50 RABBIT:
>2,000 mg/kg NOTE -
Estimated value 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Acute Toxicity Product toxicity determined from bioassays conducted on individual components.
LC50:
2790 mg/L No Effect Level:
310.mg/L Daphnia magna 48 Hour Acute Toxicity Product toxicity determined from bioassays conducted on individual components.
LC50:
1180 mg/L No Effect Level:
750 mg/L BIODEGRADATION COD (mg/gm):
416 Calculated TOC (mg/gm):
152 Calculated BOD-5 (mg/gm):
9 Calculated BOD-28 (mg/gm):
31 Calculated 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 TRANSPORT INFORMATION DOT HAZARD:
Not Applicable UN / NA NUMBER:
Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable 15 REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS:
This product contains ingredients that have been determined as safe for use in cooking or cooling containers of meat and/or poultry and in systems with no food contact. (GS, G7)
SARA SECTION 312 HAZARD CLASS:
Immediate (acute)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds
-qATIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present MICHIGAN REGULATORY INFORMATION at OSHA thresholds No regulated constituent present at OSHA thresholds 16 OTHER INFORMATION INPA/HMIS Health Fire Reactivity Special (1) Protective Equipment 1*
1 0
NONE B
CODE TRANSLATION Slight Hazard Slight Hazard Minimal Hazard No special Hazard Goggles, Gloves
- (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE RE' 03-SEP-1997 16-JAN-2001 15 VISIONS TO SECTION:
SUPERCEDES
- NEW **
03-SEP-1997 MSDS status:
l ISSUE DATE: 29-JAN-1997 MATERIAL SAFETY DATA SHEET Betz
Dearborn,
Division of Hercules Incorporated 4636 Somerton Road Trevose, PA 19053 Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT)
(800) 877-1940 (USA)
HMIS RATINGS (See Section 16 for additional information)
HEALTH:
2 FLAMMABILITY:
I REACTIVITY:
0 1 PRODUCT IDENTIFICATION PRODUCT NAME:
DEPOSITROL BL5301 PRODUCT APPLICATION AREA:
WATER-BASED DEPOSIT CONTROL AGENT.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS#
CHEMICAL NAME 2809-21-4 PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS- (HEDP)
Corrosive (eyes)
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the occupational Safety and Health Administration at OSHA thresholds for carcinogens.
3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION May cause moderate irritation to the skin. May cause moderate irritation to the eyes. Mists/aerosols may cause irritation to upper respiratory tract.
DOT hazard: Corrosive to steel Emergency Response Guide #153 Odor: Mild; Appearance: Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause moderate irritation to the skin.
ACUTE EYE EFFECTS:
May cause moderate irritation to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause-redness or itching of skin, irritation, and/or tearing of eyes (direct contact).
4 FIRST AID MEASURES SKIN CONTACT:
Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT:
Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
5 FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F
> 93C P-M(CC)
MISCELLANEOUS:
Corrosive to steel UN3265;Emergency Response Guide #153 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementa permitted waste treatment facility or discharged under a permit. Product as is -
Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Acidic. Do not mix with alkaline material.
STORAGE:
Keep containers closed when not in use. Use approved containers only. Store in cool, well-vented area. Contact with metals may release flammable hydrogen gas.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID,(l-HYDROXYETHYLIDINE)BIS- (HEDP)
NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I.
RESPIRATORY PROTECTION:
.A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
-USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
-If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
rubber gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav.(70F,21C) 1.406 Vapor Pressure (mmHG) 18.0 Freeze Point (F)
< -30 Vapor Density (air=l)
< 1.00 Freeze Point (C)
< -34 Viscosity(cps 70F,21C) 80
% Solubility (water) 100.0 Odor Mild Appearance Yellow Physical State Liquid Flash Point P-M(CC)
> 200F > 93C pH As Is (approx.)
< 1.0 Evaporation Rate (Ether-1)
< 1.00 NA - not applicable ND = not determined 10 STABILITY & REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B"t
- 1 TOXICOLOGICAL INFORMATION Oral LD50 RAT:
>4,000 mg/kg NOTE -
Estimated value Dermal LD50 RABBIT:
>4,000 mg/kg NOTE -
Estimated value Eye Irritation Score RABBIT:
9.3 NOTE -
Maximum score at 48 hr; completely reversible by day 14 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 48 Hour Static Screen Toxicity estimated from product with similar formulation at a pH of 6-9.
0% Mortality:
500 mg/L Daphnia magna 48 Hour Static Screen Toxicity estimated from product with similar formulation at a pH of 6-9.
.0% Mortality:
500 mg/L BIODEGRADATION COD (mg/gm):
329 Calculated TOC.(mg/gm):
89 Calculated BOD-5 (mg/gm):
.3 Calculated BOD-28 (mg/gm):
7 Calculated 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is D002=Corrosive(pH, steel).
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 TRANSPORT INFORMATION DOT HAZARD:
Corrosive to steel UN / NA NUMBER:
UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153 15 REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
- No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS:
Immediate(acute)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
A No. regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 OTHER-INFORMATION NFPA/HMIS.
Health 2
Fire 1
Reactivity 0
Special CORR (1) Protective Equipment
. B (1) refer to section 8 of MSDS recommendations.
CHANGE LOG CODE TRANSLATION Moderate Hazard Slight Hazard Minimal Hazard DOT corrosive Goggles, Gloves for additional protective equipment EFFECTIVE DATE MSDS status: 29-JAN-1997 REVISIONS TO SECTION:
SUPERCEDES
____NE____
- NEW **
BETZDEARBORN MATERIAL SAFETY DATA SHEET BetmoearbOrn ELEECTIVE DATE: 28-APR-1997 VTED DATE: 13-SEP-1999
- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: FERROQUEST LP7200 PRODUCT APPLICATION AREA: CHEMICAL CLEANING COMPOUND.
COMPANY ADDRESS:
BetzDearborn Inc.
4636 Somerton Road, Trevose Pa. 19053 Information phone number: (218) - 355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA)
- 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formnulation.
HAZARDOUS INGREDIENTS:
i CAS CHEMICAL NAME TRADE SECRET INGREDIENT(EI95);TSRN 125438 Irritant (eyes).
TRADE SECRET INGREDIENT(122);;TSRN 125438 Potential irritant (eyes)
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
AGE I CONTINUED 5118P 5214P.
ODUCT NAME : FERROQUEST LP7200
.FFECTIVE DATE: 28-APR-1997 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW ARNING Severe irritant to the skin. Severe irritant to the eyes. Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract.
DOT hazard: Corrosive to steel Emergency Response Guide #154 Odor: Pungent; Appearance: Colorless To Green, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure;. Severe irritant to the skin.
CUTE EYE EFFECTS:
pevere irritant to the eyes.
ACUTE RESPIRATORY EFFECTS:
Primary route of exposure;Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract.
INGESTION EFFECTS:
May cause slight gastrointestinal irritation with possible nausea, vomiting, diarrhea, incoordination, mental confusion, dizziness and lethargy.
TARGET ORGANS:
Prolonged or repeated exposures may cause primary irritant dermatitis and/or toxicity to the lung.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
Inhalation may cause irritation of the respiratory tract. Skin contact may cause itching and/or redness.
CONTINUED
IODUCT NAME : FERROQUEST LP7200
- FECTIWE DATE: 28-APR-1997 RST AID MEASURES KIN CONTACT:
Remove contaminated clothing. Wash exposed area with a large uantity of soap solution or water for 15 minutes.
EE CONTACT:
Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
AWSH POINT:
W 200F P-M(CC)
MISCELLANEOUS:
Corrosive to steel UN3264;Emergency Response Guide #154
) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementsa permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
> HANDLING AND STORAGE HANDLING:
Contains an oxidizer. Avoid all contact with reducing agents, oils, greases, organics and acids.
ITORAGE:
.eep containers closed when not in use. Reasonable and safe Aiemical storage. Protect from freezing.
kGE 3 CONTINUED
EODUCT NAME : FERROQUEST LP7200
- FECTIVE DATE: 28-APR-1997 EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME TRADE SECRET INGREDIENT(E195);TSRN 125438 - 5118P PEL (OSHAa: NOT DETERMINED TLV. (ACGI ): NOT DETERMINED TRADE SECRET INGREDIENT(122);;TSRN 125438 - 5214P PEL (OSHA): NUISANCE DUST TLV (ACGIH): 5 MG/M3 MISC: Note: manufacturers recommended exposure limit: 10 mglm3.
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA!S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-Wash off after each use. Replace as necessary EYE PROTECTION:
splash proof chemical goggles
) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F) 1.070 Vapor Pressure (mmHG) 36.0
?reeze Point (F) 27.00 Vapor Density. (airy1)
< 1.00 Viscosity (cps 70F) 9 k Solubility (water) 100.0
)dor Pungent appearance Colorless To Green
?hysical State Liquid rlash Point (F)
> 200 P-M(CC)
,H As Is (approx.)
1.4
- vaporation Rate (Ether=l)
< 1.00 A = not applicable ND = not determined
%GE 4 CONTINUED
I I
IODUCT NAME : FERROQUEST LP7200 FECTIVE DATE: 28-APR-1997 VTABILITY AND REACTIVITY
.ABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
- 1) TOXICOLOGICAL INFORMATION Oral LD50 RAT:
6,829 mg/kg Dermal LD5O RABBIT:
>5,000 mg/kg NOTE - Estimated value
- 2) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY athead Minnow 96 Hour Static Screen 0% Mortality: 1500 mglL Daphnia magna 48 Hour Static Screen 0% Mortality: 1000 mg/L BIODEGRADATION COD (mg/gm):
388 TOC (mg/gm):
177 BOD-5 (mgfgm):
336 BOD-28 (mg/gm):
447
- 3) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number Is:
D002=Corrosive(pH, steel).
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
kGE 5
.CONTINUED
tODUCT NAME : FERROQUEST LP7200
- FECTIVE DATE: 28-APR-1997 VRANSPORT INFORMATION DOT HAZARD:
Corrosive to steel UN /
NA NUMBER:.
UN3264 DOT EMERGENCY RESPONSE GUIDE #:
154
- 5) REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA ANDIOR SARA REPORTABLE QUANTITY (RQ):
11,224 gallons due to (122);
SARA SECTION 312 HAZARD CLASS:
Immediate(acute);Delayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds ALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
- o regulated constituent present at OSHA thresholds 1ICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds
,GE 6 CONTINUED
PRODUCT NAME : FERROQUEST LP7200 EFFECTIVE DATE: 28-APR-1997 ISOTHER INFORMATION NFPAIHMIS Health Fire Reactivity Special (1) Protective Equipment CODE TRANSLATION 2
1 0
CORR B
Moderate Hazard Slight Hazard Minimal Hazard DOT corrosive Goggles, Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG lI EFFECTIVE DATE REVISIONS TO SECTION:
SUPERCEDES
.MSDS status: 29-JAN-1997 25-FEB-1997 28-APR-1997 12 3
NEW **
29-JAN-1997 25-FEB-1997 E
'AGE 7
NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 7750 Emercency Telephone Number Medical (800) 462-5378 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
(800) I-M-ALERT SECTION 01 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION TRADE NAME:
NALCO 7750 DESCRIPTION:
An aqueous mixture of an acrylamide modified terpolymer and ammonium sulfate NFPA 704M/HMIS RATING 1/1 HEALTH 1/1 FLAMMABILITY 0/0 REACTIVITY 0 OTHER O=Insignificant l=Slight 2=Moderate 3=High 4=Extreme SECTION 02 COMPOSITION AND INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical ingredients as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200.
Consult Section 15 for the nature of the hazard(s).
INGREDIENT(S)
CAS #
APPROX.%
Ammonium sulfate 7783-20-2 10-20 SECTION 03 HAZARD IDENTIFICATION EMERGENCY OVERVIEW:
CAUTION:
May cause irritation to skin and eyes.
Avoid contact with skin, eyes and clothing.
Do not take internally.
Empty containers may contain residual product.
Do not reuse container unless properly reconditioned.
PRIMARY ROUTE(S)
OF EXPOSURE:
Eye, Skin EYE CONTACT:
Can cause mild, short-lasting irritation.
SKIN CONTACT:
Can cause mild, short-lasting irritation.
SYMPTOMS OF EXPOSURE:
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
SECTION 04 FIRST AID INFORMATION EYES:____Flush___with___water____for__15__minutes._____Call___a__physician.___
EYES:
Flush with water for 15 minutes.
Call a physician.
SKIN:
Flush with water for 15 minutes.
Call a physician.
INGESTION:
Do not induce vomiting. Give water.
Call a physician.
INHALATION:
Remove to fresh air.
Treat symptoms.
Call a physician.
NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition.
CAUTION:
If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water.
SECTION 05 FIRE FIGHTING MEASURES PAGE 1
OF 7
NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000
MATERIAL SAFETY DATA SHEET NALCO NALCO 7750 Emergency Telephone Number Medical (800) 462-5378 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
(800) I-M-ALERT FLASH POINT:
None (PMCC)
ASTM D-93 EXTINGUISHING MEDIA:
Not applicable. Use extinguishing media appropriate for surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve SOx and NOx under fire conditions.
- SECTION 06 ACCIDENTAL RELEASE MEASURES IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (800) I-M-ALERT or (800) 462-5378.
SPILL CONTROL AND RECOVERY:
Small liquid spills:
Contain with inert absorbent material. USE OF ALKALINE ABSORBENT MATERIALS WILL GENERATE AMMONIA. Refer to INCOMPATABILITY in Section 10. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal.
Refer to CERCLA in Section 15.
Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal.
Refer to CERCLA in Section 15.
For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective equipment specified in Section 8 SECTION 07 HANDLING AND STORAGE Storage : Keep container closed when not in use.
SECTION 08 EXPOSURE CONTROLS AND PERSONAL PROTECTION RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant mists are generated, use either a chemical cartridge respirator with a dust/mist prefilter or supplied air.
For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a positive pressure, self-contained breathing apparatus is recommended.
VENTILATION: General ventilation is recommended.
PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding equipment, doing maintenance or handling product. Examples of impermeable gloves available on the market are neoprene, nitrile, PVC, natural rubber, Viton and butyl (compatibility studies have not been performed).
The availability of an eye wash fountain and safety shower is recommended.
If clothing is contaminated, remove clothing and thoroughly wash the affected PAGE 2 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER
- NAPERVILLE, ILLINOIS.60563-1198 AREA (630) 305-1000
,A1 NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 7750 Emergency Telephone Number Medical (800) 462-5378 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
(800) I-M-ALERT area.
Launder contaminated clothing before reuse.
HUMAN EXPOSURE CHARACTERIZATION:
Based on Nalco's recommended product application and our recommended personal protective equipment, the potential human exposure is:
LOW.
SECTION 09 PHYSICAL AND CHEMICAL PROPERTIES COLOR:
White FORM:
Liquid ODOR:
None
~~~~
~ATM
-7 DENSITY:
SPECIFIC GRAVITY:
pH (NEAT) =
VISCOSITY:
FREEZE POINT:
BOILING POINT:
FLASH POINT:
VOLATILE ORGANIC COMPOUND (VOC):
10.2 lbs/gal.
1.22 3.0-4.2 100-700 cps @ 78 Degrees F 14 Degrees F 248 Degrees F e 760 mm Hg None (PMCC)
ASTM D-93 0 lbs/gal.
EPA METHOD 24 NOTE:
These physical properties are typical values for this product.
SECTION 10 STABLILITY AND REACTIVITY INCOMPATIBILITY:
Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes.
AVOID ALKALINE MATERIALS (EG. AMMONIA AND ITS SOLUTIONS, CARBONATES, SODIUM HYDROXIDE (CAUSTIC), POTASSIUM HYDROXIDE, CALCIUM HYDROXIDE (LIME), CYANIDES, SULFIDES, HYPOCHLORITES, CHLORITES) WHICH CAN GENERATE HEAT WITH SPLATTERING OR BOILING AND THE RELEASE OF AMMONIA.
THERMAL DECOMPOSITION PRODUCTS:
In the event of combustion CO, C02,
- BOx, NOx, HCl, NH4 may be formed.
Do not breathe smoke or fumes.
Wear suitable protective equipment.
SECTIO____________________O___ICOL___________CAL______________________________
SECTION 11 TOXICOLOGICAL INFORMATION TOXICITY STUDIES:
No toxicity studies have been conducted on this product.
HUMAN HAZARD CHARACTERIZATION:
the potential human hazard is:
Based on our hazard characterization,.
LOW SECTION 12 ECOLOGICAL INFORMATION BIOCHEMICAL OXYGEN DEMAND (5-day BOD):
9,700 ppm CHEMICAL OXYGEN DEMAND (COD):
130,000 ppm TOTAL ORGANIC CARBON (TOC):
65,000 ppm AQUATIC DATA:
PAGE 3
OF 7
I NALCO CHEMICAL COMPANY ONE NALCO CENTER
- NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000
MATERIAL SAFETY DATA SHEET i f
~~~~PRODUCTl NALCO
[
NALCO 7750 Emergency Telephone Number Medical (800) 462-5378 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
(800) I-M-ALERT Results below are based on the product.
96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> static acute LC50 to Rainbow Trout = 7.3 mg/L 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> no observed effect concentration is 6.0 mg/L based on no mortality or abnormal effects.
96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> static acute LC50 to Fathead Minnow = 30 mg/L 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> no observed effect concentration is 13 mg/L based on no mortality or abnormal effects.
48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> static acute EC50 to Daphnia magna = 95 mg/L 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> static acute LC50 to Daphnia magna = 190 mg/L 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> no observed effect concentration is Less than 30 mg/L based on no mortality or abnormal effects.
96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> static acute LC50 to Mysid shrimp = 53 mg/L 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> no observed effect concentration is 19 mg/L based on no mortality or abnormal effects.
If released into the environment, see CERCLA in Section 15.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION:
Based on our Hazard Characterization, the potential environmental hazard is:
MODERATE.
Based on Nalco's recommended product application and the product's characteristics, the potential environmental exposure is:
LOW.
SECTION 13 DISPOSAL CONSIDERATIONS DISPOSAL:
If this product becomes a waste, it does not meet the criteria of a hazardous waste as "defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.
As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be deep-well injected in 'accordance with local, state and federal regulations.
SECTION 14 TRANSPORTATION INFORMATION PROPER SHIPPING NAME/HAZARD CLASS MAY VARY BY PACKAGING. PROPERTIES, AND MODE OF TRANSPORTATION.
TYPICAL PROPER SHIPPING NAMES FOR THIS PRODUCT ARE:
ALL TRANSPORTATION MODES PRODUCT IS NOT REGULATED DURING TRANSPORTATION PAGE 4
OF 7
NALCO CHEMICAL COMPANY ONE NALCO CENTER
- NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000
NALCO MATERIAL SAFETY DATA SHEET
.PRODUCT NALCO 7750 Emergency Telephone Number Medical (800) 462-5378 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
(800) I-M-ALERT SECTION 15 REGULATORY INFORMATION The following regulations apply to this product.
FEDERAL REGULATIONS:
OSHA HAZARD COMMUNICATION RULE. 29 CFR 1910.1200:
Based on our hazard evaluation, the following ingredient iA this product is hazardous and the reason is shown below.
Ammonium sulfate Irritant CERCLA/SUPERFUND, 40 CFR 117, 302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) -
SECTIONS 302, 311, 312 AND 313:
SECTION 302 -
EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 and 312 -
MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous.
The product should be reported under the following EPA hazard categories:
XX Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard Sudden release of pressure hazard Reactive hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain ingredients List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710).
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA),
40 CFR 261 SUBPART C & D:
Consult Section 13 for RCRA classification.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311:
None of the ingredients are specifically listed.
CLEAN AIR ACT, Sec. 111 (40 CFR 60), Sec. 112 (40 CFR 61, 1990 Amendments),
Sec. 611 (40 CFR 82, CLASS I and II Ozone depleting substances):
PAGE 5
OF 7
NALCO CHEMICAL COMPANY ONE NALCO CENTER
- NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000
Pd NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 7750 Emergency Telephone Number Medical (800) 462-5378 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
(800) I-M-ALERT This product does not contain ingredients covered by the Clean Air Act.
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
This product does not contain California Proposition 65.
MICHIGAN CRITICAL MATERIALS:
This product does not contain Materials Register.
any chemicals which require warning under ingredients listed on the Michigan Critical STATE RIGHT TO KNOW LAWS:
The following ingredient(s) are disclosed for compliance with State Right To Know Laws:
Ammonium sulfate
' Sodium sulfate 7783-20-2 7757-82-6 INTERNATIONAL REGULATIONS:
This is a WHMIS controlled product under The House of Commons of Canada Bill C-70 (Class D2B). The product contains the following substances, from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredients(s):
Chemical Name CAS #
% Concentration Range 10-20 Ammonium sulfate 7783-20-2 SECTION 16 OTHER INFORMATION None SECTION 17 RISK CHARACTERIZATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product.
Based on our recommended use of this product, we have characterized the product's general risk.
This information should provide assistance for your own risk management practices.
We have evaluated our product's risk as follows:
The human risk is: LOW.
The environmental risk is: LOW.
Any use inconsistent with Nalco's recommendations may affect our risk characterization.
Our sales representative will assist you to determine if your product application is consistent with our recommendations.- Together we can implement an appropriate risk management process.
This product material safety data sheet provides health and safety information.
The product is to be used in applications consistent with our product literature.
Individuals handling this product should be PAGE 6 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305.1000
e i
NALCO MATERIAL SAFETY DATA SHEET PRODUCT.
NALCO 7750 Emergency Telephone Number Medical (800) 462-5378 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
(800) I-M-ALERT informed of the recommended safety precautions and should have access to this information.
For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
SECTION 18 REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (CD-ROM version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (CD-ROM version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA).
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, Ohio (CD-ROM version),
Micromedex, Inc., Englewood, CO.
Shepard's Catalog of Teratogenic Agents (CD-ROM version),
Micromedex, Inc., Englewood, CO.
Suspect Chemicals Sourcebook (a guide to industrial chemicals covered under major regulatory and advisory programs), Roytech Publications.
(a Division of Ariel Corporation), Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, Washington (CD-ROM version), Micromedex, Inc., Englewood, CO.
PREPARED BY:
William S. Utley, PhD., DABT, Manager, Product Safety DATE CHANGED:
06/23/1998 DATE PRINTED:
03/28/1999 PAGE 7 OF 7 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1198 AREA (630) 305-1000
MATERIAL SAFETY DATA SHEET Identity: BacterloStatic Preservative Sedctlon-I Manufacturer.
Haws Corporation Telephone: (800) 766-5612 Fax: (775) 359-7424 Address:
1455 Kleppe Lane Date Prepared: July 26.2002 Sparks, NV 89431__
Sectlon'll
' Material Identification'arid Information' ':'i-Components (Chemical Names & Common Names l
OSHA ACGIH OTHER (Hazardous Components 1 % or greater, Carcinogens 0.1 % or greater)
CAS #s l
PEL TLV LIMITS Chlorohexidine Gluconate 18472-510 1-5 Propylene Glycol 10-20 iSection'll i.hysical
/.Chemical Characteristics Boiling Point: >1000C Specific Gravity (H20 1):.99 Vapour Pressure (mm Hg): N/A Melting Point: N/A Vapour Density (Air = 1): <1 Evaporatlon Rate (Water= 1): approx. 1 Solubility in Water: GOOD Water Reactive: NONE Appearance and Odour: CLEAR. WATER WHITE LIQUID Percent Volatile: 90%
.~Se'ctlo'n'iVJ..A.? FI~re'a' id'xpi ilo iHazard Data
n'tf','~i~r'3:~il':r
- 6.
- --j X i-Flash Point (Method Used)
- NON-FLAMMABLE Auto-Ignitlon Temperature: N/A Flammabilly Limits In Air % by Volume: N/A LEL: N/A UEL: N/A Extinguisher Media: CARBON DIOXIDE. DRY CHEMICALS, WATER FOG Special Fire Fighting Procedures: NONE Unusual Fire and Explosion Hazards: NONE 6SOcti-n.V..
Re -ctivity Dita" &
-:J t:
w r
-:.n-Stability Unstable: NO Conditions to Avoid: NONE Stable:
YES.
Incompatibility (Materials to Avoid): STRONG OXIDIZING MATERIALS Hazardous Decomposition Products: CARBON MONOXIDE Hazardous Polymerization May Occur: NO Conditions to Avoid: NONE Will Not Occur: YES SectionM.' 'Health'Hazard Data c?.
i Primary Routes of Entry, Inhalation: NO Ingestion: NO Skin Absorption: NO Not Hazardous: YES Carcinogen Listed In:
NTP: NO OSHA: NO IARC Monograph: NO Not Listed: YES Health Hazards:
Acute: NONE Chronic: NONE Signs and Symptoms of Exposure: EYE CONTACT - PRODUCT HAS NO EFFECT Skin
Contact:
PRODUCT HAS NO EFFECT ingestion: MAY CAUSE STOMACH DISCOMFORT IF INGESTED.
Inhalation: PRODUCT HAS NO EFFECT Section Vll-Health Hazard Data zi a : S l : <i;?
Emergency First Aid Procedures: SEEK MEDICAL ASSISTANCE FOR FURTHER TREATMENT, OBSERVATION & SUPPORT IF NECESSARY.
Eye
Contact:
NONE REQUIRED Skin
Contact:
NONE REQUIRED Inhalation: NONE REQUIRED Ingestion: DO NOT INDUCE VOMITING. GIVE VICTIM LARGE QUANTITIES OF WATER. SEEK MEDICAL HELP.
Section ViII -
Control and Protective Measures --
i E--
- .-- Th; Respiratory Protection (Specify Type)
- NOT REQUIRED Protection Gloves: NONE Eye Protection: NONE Ventilation to'be Used:
Local Exhaust: N/A Special: N/A Mechanical (General): N/A Other: USE IN WELL VENTILATED AREA.
Other Protective Clothing and Equipment:.NOT REQUIRED Hygienic Work Practices: FOLLOW INSTRUCTIONS OUTLINED ON LABEL.
Section IX-. Precautionsfor Safe Handling and Use/ Leak Procedures ws ;.;,:;i.
Steps to be taken If Material Is Spilled or Released: FLUSH AREA WILARGE AMOUNTS OF POTABLE WATER DOWN SANITARY SEWER.
Waste Disposal Methods: IN ACCORDANCE WITH MUNICIPAL, PROVINCIAL AND FEDERAL REGULATIONS.
Precautions to be Taken In Handling and Storage: STORE IN A COOL AREA.
Other Precautions and/or Special Hazards: NONE HMIS Rating:
Health: 1 Flammability: 0 Reactivity: 0 Personal Protection: 1 NFPA Rating:
Health: 1 Flammability 0 Reactivity: 0 Special:
7/02 MSDS DATA SHEET Page 2 of 2
PermaCare MATERIAL SAFETY DATA SHEET PERMATREAT 191 I IDENTIFICATION OF THE SUBSTANCEIPREPARATION AND THE COMPANY PRODUCT NAME:
PERMATREAT 191 PART No.:
PCO10 SUPPLIER:
Houseman Limited Chapel House' Alma Road Windsor SL4 3HD England TEL:
+44 (0)1753 712000 FAX:
+44 (0)1753 712001 In case of emergency contact:
Chem-Tel, Inc. (800) 255-3924 2 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT NAME CAS No.
CONTENTS HEALTH RISK (class)
(R No.)
Ingredients not classified as hazardous.
3 HAZARDS IDENTIFICATION Not regarded as a health hazard under current legislation.
4 FIRST AID M INHALATION:
INGESTION:
SKIN:
EYES:
lEASURES Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
DO NOT INDUCE VOMITINGI Rinse mouth thoroughly. Drink plenty of water. Get medical attention if any discomfort continues.
Remove affected person from source of contamination. Get medical attention if irritation persists after washing.
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
Page 1
I PERMATREAT 191 5 FIREFIGHTING MEASURES EXTINGUISHING MEDIA:
This material is not flammable. Use extinguishing media appropriate for surrounding fire.
HAZARDOUS DECOMPOSITION PRODUCTS:
Fire creates: Vapors/gases/fumes of: Carbon Dioxide (CO2). Carbon Monoxide (CO).
Oxides oft Nitrogen.
6 ACCIDENTAL RELEASE MEASURES SPILL CLEANUP METHODS:
Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. Dispose of in accordance with Local Authority regulations.
7 HANDLING AND STORAGE USAGE PRECAUTIONS:
Avoid spilling, skin and eye contact STORAGE PRECAUTIONS:
Keep in cool, dry, ventilated storage and closed containers; Avoid extremes of temperature. Recommended maximum storage limit 2 years.
8 EXPOSURE CONTROLS AND PERSONAL PROTECTION PROTECTIVE EQUIPMENT:
VENTILATION:
RESPIRATORS:
luirements.
n made, but respiratory protection may still be required under exe when excessive air contamination exists.
PROTECTIVE GLOVES:
U e
[J ves if risk of skin contact.
EYE PROTECTION:
U c approved-safety-9°9! les or face shield.
OTHER PROTECTION:
Wear appropriate clothing to prevent any possibility of skin contact HYGIENIC WORK ROUTINES: DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated.
Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. No eating or drinking while working with this material.
9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE:
Liquid.
COLOR:
Yellow.
SPECIFIC GRAVITY (Water 1):
1.36 @ 200C pH-VALUE, CONC.:
10.5 10 STABILITY AND REACTIVITY STABILITY:
Normally stable.
CONDITIONS TO AVOID:
Avoid excessive heat for prolonged periods of time.
MATERIALS TO AVOID:
Stong oxidizing agents.
HAZARDOUS DEOMPOSITION PRODUCTS:
Fire creates: Vapors/gases/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).
Oxides of: Nitrogen Page 2 PERMATREAT 191
11 TOXICOLOGICAL INFORMATION HEALTH WARNINGS:
EYE CONTACT. May cause irritation to the eye.
SKIN CONTACT. Repeated or prolonged contact may cause slight irritation to the skin.
12 ECOLOGICAL INFORMATION ENVIRONMENTAL HAZARDS: Not regarded as dangerous for the environment Do not release into surface waters.
13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS:
Dispose of in accordance with Local Authority requirements.
14 TRANSPORT INFORMATION ROAD:
UN No:
0 ROAD TRANSPORT NOTES:
Not classified for Road Transport.
RAIL:
RAIL TRANSPORT NOTES:
Not classified for Rail TransporL SEA:
SEA TRANSPORT NOTES:
Not classified for Sea Transport.
AIR:
AIR TRANSPORT NOTES:
Not classified for Air Transport.
15 REGULATORY INFORMATION LABEL FOR SUPPLY:
NOT CLASSIFIED RISK PHRASES:
Not relevant SAFETY PHRASES:
S-24/25 Avoid contact with skin and eyes.
S-36137/39 Wear suitable protective clothing, gloves and eyelface protection.
STATUTORY INSTRUMENTS:
Chemicals (Hazard Information and Packaging) Regulations.
APPROVED CODE OF PRACTICE:
Classification and Labeling of Substances and Preparations Dangerous for Supply.
GUIDANCE NOTES:
Occupational Exposure Limits EH40.
Introduction to Local Exhaust Ventilation HS(G)37 16 OTHER INFORMATION INFORMATION SOURCES:
Dangerous Properties of Industrial Materials Report, N. Sax et.al..
REVISION DATE:
1/98 REVISION No. /REPLACES SDS ISSUED:
1.0/198 SDS No.:
PC 010 In case of emergency contact:
Chem-Tel, Inc. (800) 255-3924 DISCLAIMER THE INFORMATION GIVEN IS, TO THE BEST OF THE COMPANY'S KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE.
Page 3
Material Safety Data Sheet Dober Chemical Corp.
14461 S. Waverly
- Midlothian, IL 60445 Product Name: PWR-CORR CSB I., Identification Revision Date: 2/25/03 Emergency Telephone:.
Information Telephone:
Chemical Family:
DOT Hazard Class:
DOT Shipping Name:
800/3234983 708/388-7700 Inorganic Salt Solution Corrosive Material Corrosive Liquid, Basic, Inorganic, 8, UN3266, PGII II. Hazardous Ingredients Material Sodium Nitrite Sodium Hydroxide Sodium Tetraborate TWA/Ceiline 2040%
. 5-10% 2 mg/m3 3-5% 1mg/m3
- CAS#
7632-00-0 1310-73-2 1330434 III. Physical Data Boiling Point:
Specific Gravity (H20=1):
Vapor Density. (Air=1):
% Volatile by Volume:
pH:.
Vapor Pressure:
Solubility in Water:
Evaporation Rate:
Appearance and Odor:
>212 F-1.235-1.255 @ 60 F ND ND 13.0-13.5 @ 1001%
ND Complete ND h
p Clear to slightly hazy, pale yellow liquid IV. Fire and Explosion Hazard Data Flasb Point (Test Method): NA Boils >212 F Flammable Limits in Air (% by volume): Lower= ND Upper= ND Extinguishing Media: Foam, CO2, dry chemical.
Special Firefighting Procedures: Wear NIOSH/MSHA approved self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: None
- Denotes a toxic chemical subject to SARA Title II Section 313 reporting requirements as specifaed in 40 CFR 372.
.4 Material Safety Data Sheet Dober Chemical Corp.
Product: PWR-CORR CSB Page 2 V. Reactivity Data Stability: Stable: XXX Unstable:
Conditions to Avoid: N/A Incompatibility (materials to avoid): Strong oxidizers, strong acids.
Hazardous Combustion or Decomposition Products: None.
Hazardous Polymerization: May Occur:
Will Not Occur: XXX VI. Health Hazard Data Toxicity:
2 mg/m3 is the ceiling limit for sodium hydroxide.
Ingredients Listed as Carcinogenic in NTP, IARC, or OSHA (specify): None Acute Effects Of OverexPosure Eye
Contact:
Will cause burns.
Skin
Contact:
Will cause bums.
Inhalation:
Inhalation of vapor or mist will produce respiratory irritation.
Ingestion:
Sodium nitrite is a poison by ingestion.
Principal Routes of Absorption: Skin contact, inhalation, eye.
Emereencv and First Aid Procedures Eyes:
Flush at once with plenty of water for at least 15 minutes.
Skin:
Wash immediately with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician, if necessary.
Inhalation:
Move to fresh air. If not breathing, give mouth-to-mouth resuscitation.
If breathing is difficult, give oxygen. Call a physician.
Ingestion:
Seek medical attention at once. Do not induce vomiting. Never give anything by mouth to an unconscious person.
VII. Spill or Leak Procedures Steps to be Taken if Material is Released or Spilled: Dilute with large amounts of water; neutralize with mild acid. Wash area with mild detergent and water.
Waste Disposal Method: Dilute with large volumes of water; neutralize with mild acid.
Dispose of in accordance with local, state and federal EPA regulations.
Material Safety Data Sheet Dober Chemical Corp.
Product: PWR-CORR CSB Page 3
'VII.
Special Protection Information Ventilation Requirements: General exhaust is sufficient when material is used as intended.
Recommended Personal Protective Equipment Respiratory:
For fire conditions or exposure above TLV: Wear NIOSHIMSHA approved respirators.
Eyes:
Chemical splash goggles.
Gloves:
Impervious.
Other Clothing and Equipment: Other protective clothing depending on degree of exposure. Wear rubber apron. Eye wash facility and safety shower.
IX. Special Precautions Precautions to be Taken in Handling and Storing: Do not get in eyes or skin or on clothing. Do not take internally. Avoid breathing mist or vapor. Keep container closed.
Wash thoroughly after'handling.
Other Precautions:
For industrial use only.
R.C.R.A.: This product in the neat or undiluted form has a pH of 12.5 or greater. This means that this product falls within the pH definition of "corrosive waste" as defined in 40 CFR 261, "Identification and Listing of Hazardous Waste." Should the undiluted or concentrated material be discarded, it should be classified as hazardous. The'EPA hazardous waste number is D002.
X. HMIS Ratines:
Health 3
Flammability l I Reactivity l 0 Personal Protection H
All information, recommendations, and suggestions appearing herein concerning this compound are based upon data obtained from the raw material manufacturers and/or recognized technical sources; however, Dober Chemical Corp. makes no warranty, representation, or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of the product. Since actual use by others is beyond our control, Dober Chemical makes no warranty, express or implied, as to the effects of such use, the results to be obtained or the safety and toxicity of the product. The data in this MSDS relate only to the specific product designated herein and do not relate to use in combination with any other material or in any process.