ML030990494

Application for Renewal of National Pollutant Discharge Elimination System Permit, Sections Iii.B Through Iii.C

ML030990494
Person / Time
Site:	Cook
Issue date:	03/28/2003
From:	Gebbie J Indiana Michigan Power Co
To:	Document Control Desk, Office of Nuclear Reactor Regulation
References
AEP:NRC:2401-08, MI0005827
Download: ML030990494 (203)

Text

Section III.B Outfall OQA

Water Quality Division Michigan Department of Environmental Quality- Surface DWASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B Outfall Information each outfall at the facility. Make copies of this blank section nplete a separate Section III.B. - Outfall Information (pages 26-31) for the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT __-_-_I__________I____________

NPDES PERMIT NUMBER l uu I rMLL VNUIVII1 FACILITY NAME I M10005827 I O0A Donald C Cook Nuclear Plant of this page)

1. OUTFALL INFORMATION (see page 25 for instrucbon on completion Watershed A

Lower St Joseph Receiving Water B

Lake Michigan Township County C Lake Berren Section Town Range

/4,  %

D. 06 06S 19W SW NW Labtude Longitude E. 8634' 30" 41 58' 30" F. Type of Wastewater Discharged (Check all that apply to this outfall)

El SanitaryWastewater E] Groundwater Cleanup I Storm Water (regulated)

LI Contact Cooling E Process Wastewater E] Hydrostatic Pressure Test E Storm Water (not regulated)

E Noncontact Cooling E) Storm water subject to effluent guidelines (indicate under which category)

ElOther - specify (see 'Table 8 - Other Common Types of Wastewater" in appendix)

J. What is the maximum Facility Design Flow Rate: 1 MGD Seasonal Dischargers MGY Continue with Item H.

G. What is the maximum discharge flow authorized for this outfall Continuous Dischargers 1 MGD Continue with Item I.

H Seasonal Discharge space provided below.

List the discharge penods (by month) and the volume discharged in the Discharge Volume Annual Total From Through Through Discharge Volume From Through Discharge Volume From Through Discharge Volume From Continuous Discharge 24 Hours/Day 365 Days/Year How often is there a discharge from this outfall (on the average)?

Batch dischargers must provide the following additional information:

Is there effluent flow equalization? E Yes E No Batch Peak Flow Rate Number of batches discharged per day Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

Michigan Department of Environmental Quality- Surface Water Quality Division

-WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information VASE TYPE OR PRINT

.JILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant l M10005827 l OOA

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of various industnes and the types of information each shall report in this application. For assistance call the Permits Section. All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page ii, item 8.

PROCESS INFORMATION A Name of the process contnbuting to the discharge' Steam Generator Blowdown B. SIC or NAICS code. 4911 C Describe the process and provide measures of production (see the instructions to determine the appropnate information to be reported) Steam Generator Blowdown. 1 MGD maximum flow 2247 MWE total plant electrical generation.

PROCESS INFORMATION A Name of the process contnbuting to the discharge, B. SIC or NAICS code.

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code.

C. Descnbe the process and provide measures of production (see the instructions to determine the appropnate information to be reported).

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported).

l

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION-SECTION III - Industrial and Commercial Wastewater B. Outfall Information STRUCTIONS FOR COMPLETING SECTION III, ITEM B.3.-

Carbon, Total Suspended In accordance with 40 CFR 122.21, all applicants must report CBODs, Chemical Oxygen Demand, Total Organic that reporting of data for Solids, Ammonia as N, Temperature (both summer and winter), and pH. The applicant may, however, request The request shall be one or more of these required parameters be waived Such request must be supported by adequate rationale.

included as an attachment to this application.

and expected or estimated Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges to provide reduction of data provided for proposed discharges Please include an explanation if 'Pollution Prevention' is expected specific types of discharges pollutants. See Page 8 of the appendix for a list of specific parameters for which data must be provided for parameters to report, (e g., noncontact cooling waters, gasoline groundwater cleanups, etc.). For assistance in determining the appropriate call the Permits Section.

blank spaces provided or If data are available for other parameters not listed in Section III.B.3 , the applicant shall report these data in the attach the information to this application on 81/2" x 11" paper.

check the appropriate Report all data in the units provided and for the sample types specified in the table. If more than one option is available,

= milligrams per liter, OF = degrees Fahrenheit, 'C = degrees Celsius. See box. The units are as follows: g/i = micrograms per liter, mg/I page ii number 5 for analytical requirements.

other frequency-sample To analyze for pH, temperature, total residual chlorine, oil and grease, and fecal coliform use Grab Samples unless suspended solids use 24-type analyses are available. To analyze for total BOD 5, total phosphorus, COD, TOC, ammonia nitrogen and total hour composite samples unless other frequency-sample type analyses are available to sample and analyze only For two or more substantially identical outfalls, permission may be requested from the appropriate district office is granted by the district office, on a one outfall and submit the results of the analysis for other substantially identical outfalls. If the request were not sampled are separate sheet attached to the application form, identify which outfall was sampled and descnbe why the outfalls which substantially identical to the outfall which was sampled See pages ii and iii for sampling definitions, including 'maximum daily concentration", and "maximum monthly concentration".

REPORTING OF INTAKE DATA limitations for one or Applicants are required to report intake water data when they are attempting to demonstrate eligibility for "net' effluent present in the intake waters more pollutants A "net" effluent limitation is determined by subtracting the average level of the pollutant(s) only in certain remaining after treatment which is not removed by the treatment system. NPDES regulations allow net limitations mass of the results of the circumstances (see 40 CFR Part 122.45(g)). To demonstrate eligibility, report the average concentration and/or after treatment. In analyses on the intake water. If the intake water is treated prior to use, report the intake concentrations and/or mass addition to the analytical results, the following information shall be submitted for each parameter.

is not to the same a) A statement that the intake water is drawn from the body of water into which the discharge is made. If the discharge body of water from which the water is withdrawn, the facility is not eligible for net limitations.

Limitations for b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the wastewater.

the net removal of pollutants are adjusted only to the extent that the pollutant is not removed of the extent c) When applicable (for example, when the pollutant represents a class of compounds, e g., BODs, TSS, etc.), a demonstration Limitations to which the pollutants in the intake vary physically, chemically and biologically from the pollutants contained in the discharge.

are adjusted only to the extent that the concentrations of the intake pollutants vary from the discharged pollutants.

groundwater.

Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated

7-snnI NPDES Permit M10005827 STATE OF MICHIGAN JOHN ENGLER, Governor REPLY TO-DEPARTMENT OF ENVIRONMENTAL QUALITY PLAINWELL DISTRICT OFFICE

'Better Service for a BetterEnvironments 1342 SR 89 W STE B PLAINWELLMI 49080-1915 HOLLISTER BUILDING Po BOX 30473, LANSING MI 48909-7973 INTERNET: www deq state ml us RUSSELL J. HARDING, Director January28, 1999 Mr. John P. Carlson Environmental Compliance Manager Cook Nuclear Plant One Cook Place Bridgman, Michigan 49106

SUBJECT:

Application for Renewal of NPDES Permit No. MI0005827 We have reviewed the information provided in your letter of January 25, 1999. In that letter you request that representative outfalls be used to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall 00B will be considered representative of outfalls OA and OOB.

Please feel free to contact me if you have any questions.

Sincerely, Plainwell District Office Surface Water Quality Division 616-692-6968 cc: Mr. Blair Zordell, Cook Nuclear Plant Mr. Dan Dell, Permits Section, SWQD Ms. Sylvia Heaton, GLEAS, SWQD ECP 01009 (Ray 1198)

American Electric Power Cook Nuclear Plant One Cook Place Brdgman, Ml 49106 616 465 5901 AMERICAN ELECTRIC POWER Mr. Fred Morley Surface Water Quality Division Michigan Department of Environmental Quality 1342 SR89 West Suite B - - -

Plainwell, MI 49080 January 25, 1999

Subject:

NPDES Permit No. MI0005827 Application We are currently preparing the Wastewater Discharge Permit Application to renew our current NPDES operating permit. As noted in Section III - Industrial and Commercial Wastewater, Part B. Outfall Information Item 6, paragraph 5 contains instructions to request permission to use a single sample for similar outfalls for application purposes.

We request that Outfall 001 be used as a representative sample for Outfalls 002 (Unit Two Noncontact Cooling Water) and Outfall and 003 (De-icing Mbde) for application use only. Outfalls 002 003 are substantially identical to Outfall 001. The source of each these Outfalls is Lake Michigan; similar waste streams enter Outfall prior to discharge.

In addition, we are requesting Outfall QOB (Unit Two Steam Generator Blowdown) to be used as a representative sample for Outfall OA (Unit One Steam Generator Blowdown). Outfall OOA and Outfall QOB are substantially identical discharges, with the exception that Outfall OA originates from the Unit One Steam Generators, and Outfall OOB originates from the Unit Two Steam Generators.

If you have any questions, please contact me at (616) 465-5901, ext. 1153. -

Sincerely, John P. Carlson Environmental Compliance Manager

/tlm c: Greg Danneffel - MDEQ Plainwell Sylvia Heaton - MDEQ Lansing J4

Page-Two Mr. Morley January 25, 1999 I certify under penalty of law that I have personally examined and am familiar with the information submitted on this and all attached documents, and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

D. E. Cooper Plant Manager

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information CASE TYPE OR PRINT

.ZILITY NAME . NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 O0A

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industnes that discharge process wastewater must submit the results of at least one effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testinq Requirements for Organic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 3. Existing primary industnes must also provide the results of at least one effluent analysis for any other chemical listed in Table 2 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed inTables 2 and 3 New pnmary industries that propose to discharge process wastewater must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent.

5 DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2- (2,3,5-tnchlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel); 2,4,5-tnchlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent, must submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6. All effluent analyses for dioxin and furan congeners must be conducted using EPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan congener listed in Table 6 New industries that expect to use or manufacture 2,3,5-tnchlorophenoxy acetic acid (2,4,5-T), 2- (2.3.5-trichlorophenoxy) propanoic acid (Silvex.

2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel); 2,4,5-tnchlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed inTable 6.

OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industnes, or existing pnmary industries that discharge non-process wastewater, must submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in facility effluentL In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed inTables 2 and 3.

New secondary industnes, or new pnmary industries that propose to discharge non-process wastewater, must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, must provide the results of at least one analyses for any chemical listed in Table 4 known or believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in facility effluent. In addition, submit the results of any effluent analysis performed within the last 5 years for any chemical listed in Tables 4 and 5.

New industnes, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be in facility effluent 8 INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, must provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in facility effluent that have not been previously identified in this application. Quantitative effluent data that are less than 5 years old for these chemicals must be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31. To submit additional information see page ii, item 8 If the effluent concentrations are estimated, place an E in the 'Analytical Method" column. The following fields must be completed for each data row: Parameter, CAS No, Concentration(s), Sample Type, Analytical Method, Quantification Level and Detection Level See page ii,number 5 for analytical test requirements

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~L' aboratories AMERICAN ELECTRIC POWER (AEP) Order #: 99-02-232 1 COOK PLACE Date: 03/16/99 09:23 Work ID: OUTFALL OOH - OOB (FAX)

BRIDGMAN, MICHIGAN 49106 Date Received: 02/03/99 Attn: BLAIR ZORDELL Date Completed: 03/16/99 Purchase Order: 4307976 Invoice Number: Client Code: AEP_4 ND= NONE DETECTED OHIO CERT.# 12345 SAMPLE IDENTIFICATION Sample Sample Sample Sample Description Number Description Number 02/03/99 16 OUTFALL OOB 02/03/99 01 OUTFALL 0OH 02/03/99 17 OUTFALL COB 02/03/99 02 OUTFALL OOH 02/03/99 18 OUTFALL OOB 02/03/9 9 4 03 OUTFALL 0OH 02/03/99 19 OUTFALL OOB 02/03/99 04 OUTFALL 0OH 02/03/99 20 OUTFALL OOB 02/03/99 05 OUTFALL 0OH 02/03/99 21 OUTFALL COB 02/03/99 06 OUTFALL OOH 02/03/99 22 OUTFALL OOB 02/03/99 07 OUTFALL 0OH 02/03/99 23 OUTFALL OOB 02/03/99 08 OUTFALL 0OH 02/03/99 24 OUTFALL COB 02/03/99 09 OUTFALL 0OH 02/03/99 25 OUTFALL COB 02/03/9 9 10 OUTFALL OOH 02/03/99 26 OUTFALL COB 02/03/99 11 OUTFALL OOH 02/03/99 27 OUTFALL COB 02/03/99 12 OUTFALL 0OH 28 OUTFALL COB 02/03/99 13- OUTFALL O OH 02/03/99 02/03/99 29 OUTFALL COB 02/03/99 14 OUTFALL OOH 02/03/99 30 OUTFALL OOB 02/03/99 15 OUTFALL 0OH Enclosed are results of specified samples submitted for analyses. If there are any questions, please contact Matt Lake. Our Ohio EPA Certification numbers are 836 & 837.

Any result of "BDL" indicates "BELOW DETECTION LIMIT".

. -w , a Certified By MATT LAKE Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

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$L Environmental Laboratories Page 3 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Detection Result Limit Units Analyzed BY Test Description RJE 8 1 mg/L 02/15/99 MAGNESIUM, EPA 200.7 0 .01 0 .01 mg/L 02/13/99 RJE MANGANESE, EPA 200.7 BDL 0.0002 mg/L 02/15/99 RJE MERCURY, EPA 245.1 EP METALS DIGESTION, WATER BDL 0 .01 mg/L 02/13/ 99 RJE MOLYBDENUM, EPA 200.7 BDL 0.005 mg/L 03/08/99 RJE NICKEL, EPA 249.2 BDL 0.1 mg/L 02 /13/99 RJE SELENIUM, EPA 200.7 BDL 0 .0005 mg/L 03/08/99 RJE SILVER, EPA 272.2 0.08 0.01 mg/L 02/15/99 RJE STRONTIUM, EPA 200.7 BDL 0.001 mg/L 03 /08/99 RJE THALLIUM, EPA 279.2 BDL 0.1 mg/L 02/15/99 RJE URANIUM EPA 200.7 BDL 0.02 mg/L 02/13/99 RJE ZINC, EPA 200.7 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 07A OUTFALL 00H 1 Detection Result Limit Units Analyzed LG Test Description 03/05/99 LG BDL 1 mg/L SULFIDE, EPA 376.1 BDL 0.01 mg/L 03/04/99 LG TOTAL CYANIDE, EPA 335.2 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 08A OUTFALL 00K Detection Limit Units Analvzed BY Test Description Result 0.01 mg/L 02/23/99 JB PHENOLICS, EPA 420.1 0.03 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 09A OUTFALL 00H Detection Limit Units Analyzed BY Test Description Result 0.05 mg/L 02/04/99 ML BDL CHLORINE, RESIDUAL TOTAL 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 10A OUTFALL 00H Detection Limit Units Analyzed Test Description Result 0.2 mg/L 02/05/99 LG NITRATE-NITRITE N 0.36 0.5 mg/L 02/11/99 JB ORGANIC NITROGEN BDL 0.1 mg/L 02/18/99 LG EPA 365.1 BDL PHOSPHORUS, mg/L 02/06/99 JB 0.52 0.5 TMN, EPA 351.3 Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

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Order # 99-02-232 Page 8 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 04A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE- BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2

) CHLOROETHANE BDL 10 CHLOROFORM BDL 2 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL. 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 2 VINYL CHLORIDE BDL 10 XYLENES BDL 10 SURROGATE  % RECOVERY LIMITS D4-1,2 DICHLOROETHANE 114 76 - 114 D8-TOLUENE 93 88 - 110 Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937)837-3744

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/ AT Laboratories i

Page 9 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOE 02/03/99 Lab No: 04A Method: 624 Test Code: 624 X Test

Description:

EPA 624 Collected: 02/03/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 95 86 - 115 Notes and Definitions for this Report:

DATE RUN 03/10/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020932 UNITS ug/L -

METHOD EPA 624 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

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3) = Environmental Laboratories K-K Order # 99-02-232 Page 10 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 50 PHENOL BDL 10

) ACENAPHTHENE BDL 10 BENZIDENE BDL 50 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL. 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE BDL 10 Committed to Qualily Since 1958 I 1 East Main Street DaEyton7Ohio 45426 (937) 837-3744

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Page 11 Order # 99-02-232 TEST RESULTS BY SAMPLE 03/16/99 09:23 02/03 /99 Lab No: 05A Sample

Description:

OUTFALL 00H Method: 625 Test Code: 625_AE Test

Description:

EPA 625 SEMI VOLATILES Category: AQUEOUS Collected: 02/03/99 BDL 10 BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL _ 10 BENZO (A) PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE 10 EDL CHRYSENE BDL 10 ACENAPHTHYLENE 10 BDL ANTHRACENE BDL 50

-BENZO(GHI)PERYLENE BDL 10 FLUORENE 10 BDL PHENANTHRENE 50 BDL DIBENZO(A,H)ANTHRACENE 50 BDL INDENO(1,2,3-CD)PYRENE BDL 10 PYRENE BDL 100 ETHANOL AMINE BDL 200 HYDRAZINE

%RECOVERY LIMITS SURROGATE 35 - 114 NITROBENZENE-d5 88 77 43 - 116 2-FLUOROBIPHENYL 141 90 33 -

p-TERPHENYL-d14 94 38 10 -

PHENOL-d6 32 21 - 100 2-FLUOROPHENOL 36 10 - 123 2,4,6-TRIBROMOPHENOL Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022527 UNITS us/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quailty Since 1958 (937) 837-3744 Dayton, Ohio 45426 11 East Main Street

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) _ Environmental I _ Laboratories Order # 99-02-232 Page 12 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00H 02/03/99 Lab No: 05A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT ALDRIN BDL 0.010 ALPHA-BHC BDL 0. 010 BETA-BHC BDL 0.010 DELTA-BHC BDL 0. 010 GAMMA-BHC BDL 0 . 010 CHLORDANE BDL 0 .010 4,4-DDT BDL 0 . 010 4,4-DDE BDL 0 . 010 4,4-DDD BDL 0. 010 DIELDRIN BDL 0. 010

) ALPHA ENDOSULFAN BETA ENDOSULFAN BDL BDL

0. 010

0. 01 0 ENDOSULFAN SULFATE BDL 0.10 ENDRIN BDL 0 . 010 ENDRIN ALDEHYDE BDL 0.020 HEPTACHLOR BDL 0.030 HEPTACHLOR EPOXIDE BDL 0.10 PCB-1016 BDL 1 PCB-1221 BDL 2 PCB-1232 BDL 1 PCB-1242 BDL 1 PCB-1248

• BDL 1 PCB-1254 BDL 1 PCB-1260 BDL 1 TOXAPHENE BDL 0.20 SURROGATE %RECOVERY LIMITS DBC(SURROGATE, % RECOVERY) 90 70 - 130 2,4,5,6-TCX(SURROGATE % REC.) 94 70 - 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020942 UNITS ug/L Committed to Quality Since 1958 I1I East Main Street Dayton, Ohio 45426 (937) 837-3744

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[ Environmental K>j- Laboratories Page 13 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE 02/03/99 Lab No: OBA Sample

Description:

OUTFALL 00H 608 608 Method: 608 Test Code:

Test

Description:

PCB/PESTICIDES EPA Collected: 02/03/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

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_ Laboratories Order # 99-02-232 Page 14 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 15A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER BDL 5 SURROGATE %RECOVERY LIMITS NITROBENZENE-D5 105 35 - 114 2-FLUOROBIPHENYL 120 0 43 - 116 125 33 - 141 p-TERPHENYL-d14 PHENOL-d6 40 10 - 94 2-FLUOROPHENOL 53 21 - 100 2,4,6-TRIBROMOPHENOL 150 0 10 - 123

) Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206505W UNITS uq/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

-B3 Belmonte Park

'- Environmental 1W Laboratories i

Page 15 order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE 02/03/99 Lab No:-19A Sample

Description:

OUTFALL OOB 624_X Method: 624 Test Code:

Test

Description:

EPA 624 Collected: 02/03/99 Category: AQUEOUS RESULT LIMIT PARAMETER BDL 20 ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 2 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 10 CHLOROETHANE BDL 2 CHLOROFORM BDL 2 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 10 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 2-BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 10 VINYL CHLORIDE BDL 10 XYLENES SURROGATE %RECOVERY LIMITS 112 76 - 114 D4-1,2 DICHLOROETHANE 93 88 - 110 D8-TOLUENE Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

Belmonte Park

) tA Environmental Laboratodes Order # 99-02-232 Page 16 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OQB 02/03/99 Lab No: 19A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/03/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 92 86 - 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020933 UNITS ug/L METHOD EPA 624 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 I11 East Main Street Dayton, Ohio 45426 (937)837-3744

. gBelmonte 11 Park Environmental I Laboratories Page 17 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE 02/03/99 Lab No: 20A Sample

Description:

OUTFALL 0OB Test Code: 625_AE VOLATILES Method: 625 Test

Description:

EPA 625 SEMI Category: AQUEOUS Collected: 02/03/99 RESULT - LIMIT PARAMETER BDL 10 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL SO 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 10 PHENOL BDL 10 ACENAPHTHENE BDL 50 BENZIDENE BDL 10 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 20 3,3-DICHLOROBENZIDINE BDL 10 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE '

BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10

) BIS(2-ETHYLHEXYL)PHTHALATE Committed to Quality Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

m1k Belmonte Park I U Environmental

- A Laboratories Order # 99-02-232 Page 18 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL O0B 02/03/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/03/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO (A) PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANTHRENE BDL 10

1) DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE BDL BDL 50 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-d5 86 35 - 114 2-FLUOROBIPHENYL 74 43 - 116 p-TERPHENYL-d14 91 33 - 141 PHENOL-d6 76 10 - 94 2-FLUOROPHENOL 82 21 - 100 2,4,6-TRIBROMOPHENOL 78 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/26/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022605 UNITS uq/L METHOD EPA 625 BDL BELOW DETECTION LIMIT 10 Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

-mm 1hBelmonte Park

-z-v Environmental

) Laboratories Page 19 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOB 02/03/99 Lab No: 20A EPA 608 Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES Category: AQUEOUS Collected: 02/03/99 PARAMETER RESULT LIMIT BDL 0 .010 ALDRIN BDL 0 .010 ALPHA-BHC BDL 0. 010 BETA-BHC BDL 0 .010 DELTA-BHC BDL 0 .010 GAMMA-BHC BDL 0 .010 CHLORDANE BDL 0 . 010 4,4-DDT BDL 0 .010 4,4-DDE BDL 0 .010 4,4-DDD BDL 0 . 010 DIELDRIN BDL 0.010 ALPHA ENDOSULFAN BDL 0 . 010 BETA ENDOSULFAN 4)

BDL 0.10 ENDOSULFAN SULFATE BDL 0. 010 ENDRIN BDL 0.020 ENDRIN ALDEHYDE BDL 0.030 HEPTACHLOR BDL 0.10 HEPTACHLOR EPOXIDE BDL 1 PCB-1016 BDL 2 PCB-1221 BDL 1 PCB-1232 BDL 1 PCB-1242 BDL 1 PCB-1248 BDL 1 PCB-1254 BDL 1 PCB-1260 BDL 0.20 TOXAPHENE SURROGATE %RECOVERY LIMITS 93 70 - 130 DBC(SURROGATE, % RECOVERY) 95 70 - 130 2,4,5,6-TCX(SURROGATE % REC.)

Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020943 UNITS ua/L Committed to Quality Since 1958 Dayton. Ohio 45426 (937) 837-3744 l l East Main Street

11 t Belmonte Park Environmental Laboratories K) z Order # 99-02-232 Page 20 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOB 02/03/99 Lab No: 20A EPA 608 Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES Collected: 02/03/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT

)

I Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

X1 IN Belmonte Park Wt m Environmntal

'O iBY Laboratories

Page 21 Order # 99-02-232 TEST RESULTS BY SAMPLE 03/16/99 09

23 Sample

Description:

OUTFALL IDOB 02/03/99 Lab No: 30A 1

Phosphate Sub-Out Method: Special Test Test Code: 8270 U Test

Description:

Triaryl Collected: 02/03/99 Category: AQUEOUS RESULT LIMIT PARAMETER BDL 5 TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER

'S SURROGATE %RECOVERY LIMIT 80 35 - 114 NITROBENZENE-DS B0 43 _ 116 2-FLUOROBIPHENYL 73 33 - 141 p-TERPHENYL-dl4 _ 94 PHENOL-d6 10 10 21 - 100 2-FLUOROPHENOL 4 Q 10 - 123 2,4,6-TRIBROMOPHENOL Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST MN INSTRUMENT SATURN FILE ID 0206502W UNITS uq/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

Section III.B.6 and 7 Additional Sample Data OOA aluminum (Cook Nuclear Lab)

Date Al (ug/) Date Al (ug/h) 2/3/99 220 5/4/02 5 1 5/2102 5 34 5/4/02 5 02 5/2/02 4 73 5/4/02 4.12 5/2/02 4 86 5/4/02 2 56 5/2/02 53 5/4/02 5 26 5/3/02 5 27 5/4/02 4 92 5/3/02 48 5/4/02 3 65 5/3/02 3 34 5/4/02 3 88 5/3/02 5 08 5/4/02 5 39 5/3/02 4 27 5/4/02 6 69 5/3/02 5 09 5/4/02 6 48 5/3/02 3 95 5/4/02 67 5/3/02 5 71 5/4/02 6 05 5/4/02 4 38 5/4/02 7.81 5/4/02 52 5/4/02 5 83 5/4/02 4.14 5/4/02 4.34 5/4/02 5.12 5/4/02 4 54 Max 220 l 5/4/02 3 12 Max monthly 220 00 5/4/02 3 02 Count 57 5/4/02 4 13 Method 200 7 5/4/02 3 17 5/4/02 4.66 5/4/02 3 88 5/4/02 4 73 5/4/02 4 72 5/4/02 3.75 5/4/02 2 45 5/4/02 3 22 5/4/02 3 86 5/4/02 4 52 5/4/02 202 5/4/02 2 18 5/4/02 39 5/4/02 4 26 5/4/02 1 84 5/4/02 2 95 5/4/02 4 78 5/4/02 3 52 5/4/02 2.77 5/4/02 3 96

+ + +

Page 1

( (

( (

Additional sample data OOA Manganese uGL Section III B. 6 and 7 (Cook Nuclear Lab)

Date Mn (ug/I) 5/2/02 2.65 5/3/02 2.44 5/3/02 2.51 5/4/02 2.67 5/4/02 3.19 5/4/02 3.61 5/4/02 4.21 5/4/02 4.16 5/4/02 5 5/4/02 4.2 5/4/02 3.68 5/4/02 4.31 5/4/02 6.81 5/4/02 7.12 Max 7.12

_ _Maxmonthly 4.0 l Count 14 Method 200.7 Page 1

Section III.B.6 and 7 Additional Sample Data Oa Magnesium ug I (Cook Nuclear Lab)

Date Mg (ug/l) 3/14/01 < 0.2 4/26/01 0.11 4/27/01 0.13 4/29/01 0.15 5/18/01 0.26 5/2/02 3.78 5/3/02 3.2 5/3/02 3.25 5/4/02 3.37 5/4/02 4.18 5/4/02 4.62 5/4/02 5.41 5/4/02 4.53 5/4/02 5.99 5/4/02 5.35 5/4/02 6.45 5/4/02 9.12 5/4/02 18.5 5/4/02 19.3 Max 19.3 Max monthly 6.9 Count 19 Method 200.7 Page 1 C (

C (C Non-routine sample data OOA Hydrazine ugl Section III.B.6 (Cook Nuclear Lab)

Date Hydrazine ug/L 2/16/01 999 2/17/01 34 2/18/01 254 8/29/01 34 8/30/01 87 9/5/01 205 9/15/01 124 9/15/01 121 9/20/01 104 9/26/01 116 9/27/01 122 9/28/01 16 9/28/01 10 9/29/01 2 5/5/02 80 5/8/02 126 5/9/02 118 5/16/02 102 5/28/02 119 5/30/02 109 6/5/02 131 6/6/02 106 6/7/02 1 6/8/02 1 Max 999 Monthly Max 429 Count 24 Method: ASTM D 1385 QL: 3 ug/I DL: 10 ug/I

Section III.B.6 Non-routine sample data OOA Ethanolamine (Cook Nuclear Lab) Method 300.0 Date Ethanolamine mg/I Date Ethanolamine mg/i Date Ethanolamine mg/I Date Ethanolamine mg/A Date Ethanolamine mg/I Date Ethanolamine mg/i 1/2101 6 56 1/15/01 4 66 1/27/01 12.7 2/7/01 6.62 2119101 803 3/2101 4.94 1/2101 7 38 1/15/01 4.61 1/27/01 127 2/7/01 6 59 2119/01 528 3/2101 4.89 1/2101 73 1/16/01 4.78 1/27/01 12.6 2/8/01 655 2/19/01 6.42 3/3/01 4.99 1/2/01 7.33 1/16/01 4.8 1/27/01 12.6 218/01 6 57 2119/01 5.94 3/3/01 4.99 1/3/01 9.11 1/16/01 4.75 1/28/01 10.3 218/01 6.55 2/20101 1.13 3/3101 4.95 1/3/01 92 1/16/01 4 82 1/28101 106 218/01 655 2120/01 1 04 3/3/01 4.87,.

1/3/01 9 43 1/17/01 64 1/28/01 105 2/9/01 5 87 2120101 0.96 3/4/01 4.7 1/3/01 901 1/17/01 6 39 1/28/01 106 219101 5.15 2/20101 0.99 3/4101 4.64 1/4/01 4.26 1/17/01 63 1/29101 8 12 2/9/01 515 2121/01 3.41 3/4101 4.58 1/4/01 4.48 1/17/01 6 66 1/29/01 8.04 219101 4 98 2121/01 3 43 314/01 4.52 1/4/01 4.64 1/18/01 2.63 1/29/01 8 29 2/10/01 3 89 2/21101 3.44 3/5/01 3.448 1/5101 8 89 1/18/01 2.7 1/29/01 8.19 2/10101 3 88 2121/01 3.45 315/01 3.54 17/01 2.75 1/18/01 28 1/30/01 8 08 2/10/01 3 88 2/22101 3 81 3/5/01 3 412 17/01 2.68 1/18/01 2.74 1/30/01 8 02 2/10/01 3 78 2122101 3 81 315/01 3.71 1/7/01 2.78 1/19/01 2 43 1/30/01 8 09 2/11/01 1 69 2122/01 3 74 3/6101 2 59 17/01 2.53 1/19/01 2 43 1/30/01 8 08 2/11/01 1.69 2/22101 3.73 3/6/01 246 1/8/01 3 29 1/19/01 2.41 1/31/01 8 81 2/11101 1 55 2123101 6.77 3/6/01 2.48 1/8101 3 24 1/19101 2.39 1/31/01 8 89 2111/01 1 44 2123/01 6 73 3/6/01 2.46 118101 3 27 1/20/01 2 45 1/31/01 8 58 2/12101 3.71 2123101 6 56 3/7/01 3.15 1/8/01 3 23 1/20/01 2 47 1/31/01 8.18 2112/01 3.74 2123/01 6.58 3/7/01 3.1 1/9/01 4.17 1/20/01 2.5 2/1/01 6.51 2112101 3.72 2124/01 6.734 3/7/01 3.14 119/01 4.1 1/20/01 2.48 211/01 6.22 2112101 3.7 2/24/01 6.711 3/7/01 3.12 1/9/01 4.13 1/21/01 3.03 2/1/01 6.35 2113/01 4.61 2/24/01 6.57 3/8/01 7.35 119/01 4 09 1/21/01 3 38 2/1/01 62 2113/01 4.57 2/24/01 6.548 318/01 7.38 1/10/01 8 89 1/21/01 3 48 2/2101 5 39 2113/01 4 47 2125/01 5.701 3/8/01 7.37 1/10/01 88 1/21101 34 2/2101 531 2113/01 4.5 2125/01 5 849 3/8/01 7.35 1/10/01 8 77 1/22/01 4 69 212/01 528 2114/01 5 04 2125/01 5 69 3/9/01 9.78 1/10/01 8.71 1/22101 4 75 2/2/01 52 2/14/01 4 95 2/25/01 5.652 3/9/01 9.67 1/11/01 10.45 1/22101 4.67 213/01 5 87 2114/01 4.97 2/26/01 6.651 3/9/01 9.7 1/11/01 10 37 1/22101 4.69 213/01 58 2114/01 49 2/26/01 6.701 3/9/01 9.71 1/11/01 10.56 1/23/01 4.57 213/01 5.77 2/15/01 5.21 2/26/01 6.654 3/10101 11.6 1/11/01 10.55 1/23/01 4.59 213/01 5.78 2/15101 517 2/26101 6 583 3/10101 11 6 1/12/01 7 83 1/23/01 4.62 214/01 5.7 2115/01 5.14 2/27/01 3.55 3/10/01 11.5 1/12101 7.66 1/23/01 4.63 214/01 59 2/15/01 4 91 2/27/01 3 53 3/10/01 11 5 1/12/01 7.86 1/24/01 9 22 214/01 6 1 2/16/01 1593 2/27/01 36 3/11/01 9 88 1/12/01 7.96 1/24/01 9 18 214101 59 2/16/01 1.65 2/27/01 3.59 3/11/01 9.9 1/13/01 6 07 1/24/01 9 23 215/01 5 67 2/16/01 1 21 2/28/01 5 51 3/11/01 9.63 1/13/01 5 94 1/24/01 9 25 215/01 5.73 2/16/01 5.47 2/28/01 5.57 3/11/01 9.76 1/13/01 5 88 1/25/01 5 65 215101 59 2/17/01 23.94 2128/01 5.42 3/12101 2.04 1/13/01 5.86 1/25/01 5 582 2/5/01 5 83 2/17/01 4 91 2128/01 5.44 3/12/01 2.13 1/14/01 5.7 1/25/01 5.657 216/01 6 86 2/17/01 73 3/1/01 624 3/12/01 2.03 1/14/01 5 64 1/25/01 5.624 216/01 6 79 2/17/01 608 3/1/01 6 23 3/12101 2 07 1/14/01 5.65 1/26/01 9.58 216101 6 78 2/18/01 8 06 3/1/01 622 3/13/01 4 875 1/14/01 5.66 1/26/01 9.59 2/6/01 6 85 2118/01 3 65 3/1/01 621 3/13/01 4811 1/15/01 4.58 1/26/01 9.63 2/7/01 6 73 2118/01 5 55 3/2101 4.79 3/13/01 4.787 1/15/01 4.61 1/26/01 9.65 217/01 6.6 118101 5.9 3/2101 4.82 3/13/01 ( 4.737

( C.

Non-routine sample data OOA Ethanolamine Section III.B.6 (Cook Nuclear Lab) Method 300.0 Date Ethanolamine mg/I Date Ethanolamine mg/I Date Ethanolamine mg/I Date Ethanolamine mg/A Date Ethanolamine mg/I Date Ethanolamine mg/I 4/18/01 5.94 4/29/01 6 86 5/11/01 4.21 3/14/01 5 963 3/26/01 5 61 4/7/01 6 91 7 29 4/18/01 6 4/30/01 6.23 5111/01 4.32 3/14/01 6.025 3/26/01 5 58 4/7/01 4/18/01 5 91 4/30/01 66 5/11/01 4.41 3/14/01 6.109 3/27/01 6.2 4/7/01 6 99 4/19/01 6 23 4/30/01 6 62 5/12/01 0 91 3/14/01 6019 3/27/01 6.01 4/7/01 7.1 4/19/01 6 19 4/30/01 6 58 5/12/01 1 34 3115101 6 35 3/27/01 5 87 4/8/01 7.208 7.354 4/19/01 6.11 5/1/01 6 34 5/12/01 1 34 3115/01 6 31 3/27/01 5.8 4/8/01 7.418 4/19/01 61 5/1/01 6.46 5112/01 1.23 3115/01 6.26 3/28/01 6 59 4/8/01 4/20/01 6 08 5/1/01 649 5/13/01 3.27 3/15/01 6 21 3/28/01 6.41 4/8/01 7.39 6.46 4/9/01 6 804 4/20/01 601 5/1/01 6 42 5/13/01 3.51 3/16/01 64 3/28/01 4/9/01 6.941 4/20/01 5.26 5/2/01 6 85 5/13101 349 3116/01 6.31 3/28/01 6.32 4/9/01 6 803 4/20/01 5 32 5/2/01 6.18 5/13/01 3.58 3/16/01 6.12 3/29/01 607 4/9/01 6 684 4/21/01 576 5/2/01 5.18 5/15/01 292 3/16101 6 28 3/29/01 5.91 4/21/01 5.64 5/2/01 5.1 5/15/01 282 3/17101 1.65 3/29/01 5.93 4/10/01 2.92 4/10/01 2.92 4121101 5.65 5/3/01 6 63 5/15/01 281 3/17/01 1.68 3/29/01 5.86 4/21/01 5 63 5/3/01 6 55 5115/01 2 93 3/17/01 1.65 3/30/01 5.785 4/10101 2.89 4/10/01 2.88 4/22/01 1.93 5/3/01 6.75 5/16/01 9.38 3/17/01 1.61 3/30/01 58 4/11/01 542 4/22/01 1.95 5/3/01 6.74 5/16/01 9.83 3/19/01 5.72 3/30/01 5 845 4/22/01 1.93 5/4/01 6.857 5/16/01 968 3/19/01 5.73 3/30/01 5.785 4111/01 512 3.133 4/11/01 5 53 4/22/01 1 88 5/4/01 6818 5117/01 2.57 3/19/01 5.72 3/31/01 4/23/01 3 55 5/4/01 6 93 5/17/01 2.47¢ 3/19/01 5.7 3/31/01 3.121 4/11/01 546 4/23/01 2.45 - 5/4/01 6 883 5/17/01 2.52 3/20/01 5 43 3/31/01 2.793 4/12/01 296 4/23/01 2.31 5/5/01 5.614 5/17/01 2.43 3/20/01 5.394 3/31/01 2 956 4/12/01 4 92 4/12/01 66 4/23/01 243 5/5/01 5611 5/18/01 3.69 3/20/01 5.456 411101 2.918 4/24/01 4.75 5/5/01 5.392 5/18/01 3.84 .

3/20/01 5 465 4/1/01 2 852 4/12/01 6 52 4/13/01 672 4/24/01 4.71 5/5/01 5 366 5/18/01 2.89 3/21/01 5 17 4/1101 2913 4/24/01 4 69 5/6/01 2.119 5118/01 324 3/21/01 5 17 411/01 2 92 4/13/01 6 61 4/24/01 4.7 5/6/01 2.098 5/19/01 541 ,

3/21/01 5 23 4/2/01 5 576 4/13/01 665 4/25/01 4 84 5/6/01 2.026 5/19/01 5.53 3/21/01 5 27 4/2/01 5 886 4/13/01 672 4/25/01 4 64 5/6/01 2 059 5/19/01 5.42 5.665 4/2/01 5.998 4/14/01 5 803 3/22/01 3.173 5/19/01 543 5 973 4/14/01 5 404 4/25/01 4 64 5/7/01 3/22101 5 714 4/2/01 4/14/01 6.228 4/25/01 4.61 5/7/01 3.13 5/20/01 3.58 3/22/01 5.795 4/3/01 7.56 4/14/01 6.054 4/26/01 4.11 5/7/01 3.2 5/20/01 3.77 3/22/01 5.677 4/3/01 7.61 4/26/01 4 02 5/7/01 3.12 5/20/01 3.76 6.9 4/3/01 7.6 4/15/01 4.391 3/23/01 5/20/01 4.7 7.7 4/15/01 3 838 4/26/01 4 06 5/8/01 3.92 3/23/01 6.8 4/3/01 4/15/01 3.068 4/26/01 3 98 5/8/01 3.89 5/21/01 6.66 3/23/01 6.7 4/4/01 8.32 3.796 4127101 6.08 5/8/01 3 91 5/21/01 6666, 3/23/01 6.7 4/4/01 8.16 4/15/01 4/16/01 6.142 4/27101 6.15 5/8/01 3.88 5/21/01 664 3/24/01 5.71 4/4/01 8.19 4/16/01 5.976 4/27/01 6.14 5/9/01 3.76 5/21101 666 3/24/01 58 4/4/01 8 06 4/27/01 6.14 5/9/01 3.78 5/22/01 5 46 3/24/01 5 94 4/5/01 8.33 4/16/01 4.597 4 597 4/28/01 7.13 5/9/01 3.84 5/22/01 5 34 3/24/01 5.93 4/5/01 8.22 4/16/01 5.348 4/28/01 7.17 5/9/01 3.84 5/22/01 54 3/25/01 5.37 4/5/01 8.2 4/16/01 4/17/01 629 4/28/01 7.15 5/10/01 4.62 5/22/01 5 29 3/25/01 5.52 4/5/01 8.29 4/17/01 6 37 4/28/01 7.2 5/10/01 4.61 6/1/01 4.78 3/25/01 5.5 4/6/01 7.49 4/17/01 6.44 4/29/01 6.39 5/10/01 4 64 6/1/01 4.67 3/25/01 5 33 4/6/01 8.24 4/29/01 6.79 5/10101 4.66 611/01 4.71 3/26/01 5 57 4/6/01 7.62 4/17/01 611 5.98 4/29/01 6.87 5/11/01 4.34 6/1/01 4 71 3/26/01 6 6 4/6/01 7.62 4/18/01

Section III.B.6 Non-routine sample data OOA Ethanolamine (Cook Nuclear Lab) Method 300.0 Date Ethanolamine mg/I Date Ethanolamine mg/I Date Ethanolamine mg/i Date Ethanolamine mg/i Date Ethanolamine mg/I Date Ethanolamine mg/i 6/2/01 4 28 6/13/01 522 7/7/01 2.56 8/11/01 9.27 8/23/01 3.36 9/14/01 91.16 6/2/01 4 24 6/13/01 5.2 7/8/01 3.37 8/11/01 926 8/23/01 3.33 9/14/01 90.54 6/2/01 4.18 6/14/01 5 08 7/9/01 3.59 8/12/01 8 21 8/23/01 3.31 9/15/01 95.9 6/2/01 4.06 6/14/01 5 03 7/10/01 3.49 8/12/01 8.12 8/23/01 3.28 9/15/01 100 6/3/01 12 6/14/01 5 7/11/01 3.94 8/12/01 8.11 8/24/01 4.15 9/17/01 127 6/3/01 1.19 6/14/01 4.99 7/12/01 4.57 8/12/01 8.06 8/24/01 4.2 9/20/01 91.3 6/3/01 1 17 6/15/01 5 405 7/13/01 5.102 8/13/01 64 8/24/01 4.27 9/20/01 94.3 6/3/01 1 16 6/15/01 5 347 7/27/01 5 55 8/13/01 64 8/24/01 4 21 9/20/01 70.05 6/4/01 2 65 6/15/01 5.473 7/27/01 5.41 8/13/01 647 8/25/01 3 54 9/20/01 44.6 6/4/01 263 6/15/01 5.39 7/28/01 48 8/13/01 6.44 8/25/01 346 9/27/01 86.9 6/4/01 2.64 6/16/01 525 7/28/01 4.76 8/14101 5 38 8/25/01 3.53 9/27/01 83.7 6/4/01 2.6 6/16/01 5 31 7/28/01 4.71 8/14/01 5 26 8/25/01 3.56 9/27/01 67.6 6/5/01 3 25 6/16/01 5.35 7/28/01 4.7 8/14/01 5.32 8/26/01 4 18 9/27/01 45.4 6/5/01 3 25 6/16/01 5.29 7/29/01 2 82 8/14/01 5.2 8/26/01 4.25 9/28/01 954 6/5/01 3 21 6/17/01 3.46 7/29/01 2.76 8/15/01 5.97 8/26/01 4.17 9/28/01 82.1 6/5/01 32 6/17/01 3.5 7/29/01 2 78 8/15/01 5.87 8/26/01 4.27 9/28/01 51 6/6/01 3.67 6/17/01 3.44 7/29/01 2 77 8/15/01 5.85 8/27/01 5 85 9/28/01 57.1 6/6/01 3.5 6/17/01 3.45 7/30/01 4 87 8/15/01 5.8 8/27/01 5 83 9/29/01 527 6/6101 348 6/18/01 5.17 7/30/01 4 88 8/16/01 3 32 8/27/01 59 9/29/01 22 7 6/6/01 344 6/18/01 5.184 7/30/01 4 85 8/16/01 3.38 8/27/01 5.85 9/29/01 27.6 6/7/01 4 02 6/18/01 5.135 7/30/01 4 76 8/16/01 3.29 8/28/01 9.66 9/29/01 32.1 6/7/01 4.07 6/18/01 5.106 7/31/01 5.19 8/16/01 3.26 8/28/01 9.79 9/29/01 24.6 6/7/01 3.99 6/19/01 59 7/31/01 5.18 8/17/01 2.03 8/28/01 958 9/29/01 16.6 6/7/01 4.08 6/19/01 5 89 7/31/01 5.17 8/17/01 2 8/28/01 9.7 9/29/01 19.4 6/8101 4.2 6/19/01 5 86 7/31/01 5.1 8/17/01 1.98 8/29/01 1.2 9/29/01 15.6 6/8/01 4.1 6/19/01 58 8/5/01 39 8/17/01 1.98 8/29/01 19 1 9/30/01 6 81 6/8/01 4.2 6/20/01 6 38 8/5/01 3 84 8/18/01 4.38 8/29/01 0 87 9/30/01 7.9 6/8/01 4.1 6/20/01 6 22 8/5/01 3 85 8/18/01 4.38 8/29/01 17.5 9/30/01 6.11 6/9/01 4.61 6/20/01 6.22 8/6/01 4 91 8/18/01 4.31 8/30/01 108.7 9/30/01 6 54 6/9/01 4 54 6/20/01 6.21 8/6/01 49 8/18/01 4.33 8/30/01 40.1 1/2102 15 8 6/9/01 4 51 6/21/01 5.5 8/6/01 4.86 8/19/01 3 45 8/30/01 0.48 1/2/02 15.5 6/9/01 4.55 6/22/01 4 99 8/6/01 4.86 8/19/01 3.42 8/30/01 36.7 1/2102 15.7 6/10/01 2.86 6/23/01 4.7 8/7/01 5.39 8/19/01 3.42 8/31/01 85.07 1/2/02 15.3 6/10/01 28 6/24/01 1.86 8/7/01 5.83 8/19/01 3 38 8/31/01 11.7 1/9/02 9.61 6/10/01 2 78 6/25/01 3.12 8/7/01 5.41 8/20/01 3.37 8/31/01 98 2 1/9/02 9.47 6/10/01 2 78 6/26/01 4.82 8/7/01 5 38 8/20/01 3 34 8/31/01 130 1/9/02 9 36 6/11/01 4 11 6/27/01 4.8 8/8/01 5 52 8/20/01 3.34 8/31/01 49.6 1/9/02 9.86 6/11/01 4 12 6/28/01 4 59 8/8/01 5.54 8/20/01 3 36 9/1/01 97.3 1/16/02 13 6/11/01 4 11 6/29/01 44 8/8/01 5.53 8/21/01 3 59 9/5/01 96.5 1/16/02 14 6/11/01 4.07 6/30/01 4 23 8/8/01 548 8/21/01 3.58 9/5/01 105.8 1/16/02 12.5 6/12/01 4.97 7/1/01 2.75 8/10/01 7.24 8/21/01 3.57 9/5/01 128.5 1/16/02 12.5 6/12/01 4.91 7/2/01 2.71 8/10/01 7.15 8/21/01 3.49 9/5/01 48.2 1/23/02 14.7 6/12101 4.92 7/3/01 84 8/10/01 7.19 8/22/01 3.28 9/9/01 136 1/23/02 15.2 6/12/01 4.88 7/4/01 508 8/10/01 7.18 8/22/01 3.21 9/10/01 99.4 1/23/02 15.7 6/13/01 5.3 7/5/01 2 96 8/11/01 9 03 8/22/01 3.21 9/10/01 121.7 1/23/02 15 6/13/01 5.24 7/6/01 3.18 8/11/01 9 25( 8/22/01 3.18 9/13/01 45.8 1/30/02 18.5

(

( (7 Section lll.B 6 Non-routine sample data OOA Ethanolamine (Cook Nuclear Lab) Method 300.0 Date Ethanolamine mg/l Date Ethanolamine mg/A Date Ethanolamine mg/l Date Ethanolamine mg/i 1/30/02 172 4/10/02 903 6/5/02 37.5 8/28/02 11.65 1/30/02 169 4/17/02 844 6/5/02 28 63 9/4/02 13.74 1/30/02 17.3 4/17/02 8 83 6/5/02 28.3 9/4/02 13 3 2/6/02 20.6 4/17/02 9 22 6/12/02 5.72 9/4/02 13.7 2/6/02 20.9 4/17/02 8 96 6/12/02 5 84 9/4/02 13 5 2/6/02 20.7 4/24/02 8 39 6/12/02 5.81 9/11/02 11.59 2/6/02 20 8 4/24/02 845 6/12/02 5 66 9/11/02 11 05 2/13/02 129 4/24/02 8 46 6/19/02 1.57 9/11/02 11 26 2/13/02 14 4/24/02 8 53 6/19/02 1.48 9/11/02 11.37 2/13/02 14 8 5/1/02 3 77 6/19/02 1.5 9/18/02 11.12 2/13/02 15.2 5/1/02 3 61 6/19/02 1.42 9/18/02 10.78 2/20/02 5.18 5/1/02 3.56 7/3/02 2 48 9/18102 10 86 2/20/02 5 23 5/1/02 3 54 7/3/02 2.51 9/18/02 10.56 2/20/02 5 23 5/5/02 < 8.500 7/3/02 2.51 9/25/02 12.59 2/20/02 5.19 5/5/02 < 9.700 7/3/02 2.54 9/25/02 12.12 2/27/02 14 5/5/02 < 9.200 7/10/02 4.02 9/25/02 12.23 2/27/02 138 5/5/02 < 7.600 7/10/02 4.02 9/25/02 12.02 2/27/02 14 3 5/8/02 25 8 7/10/02 3.95 10/2/02 10.8 2/27/02 14.2 5/8/02 24.8 7/10/02 4.02 10/2/02 10 2 3/6/02 11 43 5/8/02 22.2 7/17/02 6 69 10/2/02 10.5 3/6/02 11.68 5/9/02 27.76 7/17/02 697 10/2/02 10.3 3/6/02 11.58 5/9/02 24 2 7/17/02 6.48 10/9/02 7.15 3/6/02 11 88 5/9/02 27 66 7/17/02 6.51 10/9/02 7.17 3/13/02 11 2 5/9/02 22.26 7/24/02 8 06 10/9/02 7.28 3/13/02 11.1 5/16/02 21.1 7/24/02 7.88 10/9/02 7.24 3/13/02 11.1 5/16/02 22 9 7/24/02 8.13 10/16/02 12.9 . I 3/13/02 11.2 5/16/02 25 2 7/24/02 8 05 10/16/02 12.8 3/20/02 12.2 5/16/02 23.1 7/31/02 9 10/16/02 12.85 3/20/02 12.2 5/18/02 19 7/31/02 901 10/16/02 12.83 3/20/02 12.7 5/18/02 19.9 7/31/02 8.94 10/23/02 14.4 I 3/20/02 12.2 5/18/02 22.7 7/31/02 8.51 10/23/02 14.3 I i 3/27/02 1383 5/18/02 21.7 8/7/02 11 62 10/23/02 14.7 I 3/27/02 1331 5/23/02 22.9 8/7/02 11.94 10/23/02 14 3 3/27102 1308 5/23/02 25 3 8/7/02 11.82 10/30/02 11 6 10/30/02 12 I 3/27/02 1328 5/23/02 <0 500 8/7/02 11 4 4/2/02 12.3 5/28/02 20 38 8/14/02 11.34 10/30/02 11 8 4/2/02 124 5/28/02 22.11 8/14/02 11.02 10/30/02 12.1 4/2/02 12.7 5/29/02 22.8 8/14/02 11.08 11/6/02 12 99 4/2/02 12.1 5/29/02 28.7 8/14/02 11.11 11/6/02 13.41 4/3/02 11.5 5/30/02 17.7 8/21/02 11 84 11/6/02 12.79 4/3/02 11.1 5/30/02 188 8/21/02 11.26 11/6/02 13.06 4/3/02 11 5/30/02 14.7 8/21/02 11.86 4/3/02 11 6 5/30/02 29 9 8/21/02 11.43 Max 136 4/10/02 9.03 5/30/02 155 8/28/02 11.51 Monthly Avg 65 6 4/10/02 8.68 6/4/02 27.5 8/28/02 11.42 Count 972 4/10/02 8 92 6/5/02 31.2 8/28/02 11.36

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant M10005827 00A 9 WATER TREATMENT ADDITIVES Water treatment additives include any matenal that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authonzed by the DEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application.

A Are there water treatment additives in the discharge from this facility?

a71 No, proceed to item 4 E Yes B. Have these water treatment additives been previously approved" El No, continue with C. below.

C Yes. Submit a list of the previously approved water treatment additives and the date they were approved The information listed in C. 1-8 must be updated if it has changed since the previous approval C. Submit a list of water treatment additves that are or may be discharged from the facility Applicants must submit the information listed below for each additive

1. The water treatment additive Matenal Safety Data SheeL

2. The proposed water treatment additive discharge concentration.

3. The discharge frequency (i e., number of hours per day, week, etc.).

4 The outfall the water treatment additive is to be discharged from 5 The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6 The water treatment additive function (i.e , microbiocide, flocculent, etc ).

7 A 48-hour LC50 or EC50 for a North Amencan freshwater planktonic crustacean (either Cenodaphnia sp., Daphnia sp , or Simocephalus sp) 8 The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in items 7 and 8 above) is currently available in the SWQD files for the water treatment additives listed on the DEQ's Internet page http:llwww.deq state mi.us/swqlgleas/docs/wtalWTAlist.doc If you intend to use one of the water treatment additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment addibve.

10. WHOLE EFFLUENT TOXICITY TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years" If yes, identify the tests and summanze the results below unless the test has been submitted to the department in the last 5 years.

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater

- B. Outfall Information PLEASE TYPE OR PRINT NPDES or COC PERMIT NUMBER Outfall Number FACILITY NAME Donald C. Cook Nuclear Plant M10005827 OOA 9 WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Ethanolamine solution, such as 5/23/00 NPDES Permit approval 9/28195 Betz Powerline 1440, Betz Powerline 1480, Nalco 92UM001 Hydrazine Solution, such as 5/23/00 NPDES Permit approval 9/28/95 Betz Cortrol OS5035, (Formerly Betz Powerline 1205), Betz Cortrol OS5010, Nalco 19H Carbohydrazide Solution such as 3/25/94 application, 4/15/94 approval, NPDES Permit approval 9/28/95 Nalco 1250 plus, Nalco Eliminox I II 4-i I1 I

I 4

i I

i I

-I i

- I

-I

_________________________________________________________________I 32 EQP 4659-C (Rev 1/03)

Section III.B Outfall GOB

Michigan Department of Environmental Quality- Surface Water Quality Division Data WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B Outfall Information blank section nplete a separate Section III.B. - Outfall Information (pages 26-31) for each outfall at the facility. Make copies of this the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT --

NPDES PERMIT NUMBER l OUTFALL NUMBER FACILITY NAME Donald C. Cook Nuclear Plant I M10005827 I 001B

1. OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

Watershed A

Lower St Ji Receiving Water B.

Lake Michigan County C.

Berrien

/4, 1/4 D.

SW Latitude E

41 58' 30" F. Type of Wastewater Discharged (Check all that apply to this outfall)

El Contact Cooling El Sanitary Wastewater El Groundwater Cleanup El Storm Water (regulated)

Dl Hydrostatic Pressure Test [E Storm Water (not regulated)

E1Noncontact Cooling [ Process Wastewater El Storm water subject to effluent guidelines (indicate under which category)

E1 Other - specify (see 'Table 8 - Other Common Types of Wastewater' in appendix)

J. What is the maximum Facility Design Flow Rate 1 MGD Seasonal Dischargers MGY Continue with Item H G What is the maximum discharge flow authonzed for this outfall Continuous Dischargers 1 MGD Continue with Item I.

H Seasonal Discharge List the discharge penods (by month) and the volume discharged in the space provided below.

Through Discharge Volume Annual Total From From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume

1. Continuous Discharge How often is there a discharge from this outfall (on the average)? 24 Hours/Day 365 Days/Year Batch dischargers must provide the following additional information:

Is there effluent flow equalization? El Yes E No Batch Peak Flow Rate Number of batches discharged per day'.

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information VASE TYPE OR PRINT

.ILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant l M10005827 l DOB

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of vanous industries and the types of information each shall report in this application. For assistance call the Permits Section. All industnes shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge To submit additional information see page ii, item 8 PROCESS INFORMATION A. Name of the process contributing to the discharge: Steam Generator Blowdown B. SIC or NAICS code. 4911 C. Descnbe the process and provide measures of production (see the instructions to determine the appropnate information to be reported) Steam Generator Blowdown. 1 MGD maximum flow 2247 MWE tota plant electrical generation PROCESS INFORMATION A. Name of the process contributing to the discharge:

B SIC or NAICS code:

C. Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

PROCESS INFORMATION A. Name of the process contributing to the discharge B. SIC or NAICS code:

C Describe the process and provide measures of production (see the instructions to determine the appropnate information to be reported)

PROCESS INFORMATION A Name of the process contnbuting to the discharge:

B. SIC or NAICS code C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

K>

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information JTRUCTIONS FOR COMPLETING SECTION III, ITEMIB.3. .

Organic Carbon, Total Suspended In accordance with 40 CFR 122.21, all applicants must report CBOD 5, Chemical Oxygen Demand, Total request that reporting of data for Solids, Ammonia as N, Temperature (both summer and winter), and pH The applicant may, however, rationale. The request shall be one or more of these required parameters be waived. Such request must be supported by adequate included as an attachment to this application.

and expected or estimated Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges is expected to provide reduction of data provided for proposed discharges. Please include an explanation if "Pollution Prevention" for specific types of discharges pollutants. See Page 8 of the appendix for a list of specific parameters for which data must be provided in determining the appropriate parameters to report, (e.g., noncontact cooling waters, gasoline groundwater cleanups, etc ). For assistance call the Permits Section.

data in the blank spaces provided or If data are available for other parameters not listed in Section III.B.3, the applicant shall report these attach the information to this application on 8%" x 11" paper.

is available, check the appropriate Report all data in the units provided and for the sample types specified in the table. If more than one option

= degrees Fahrenheit, 'C = degrees Celsius See box. The units are as follows- pgAl = micrograms per liter, mg/I = milligrams per liter, OF page ii number 5 for analytical requirements.

unless other frequency-sample To analyze for pH, temperature, total residual chlorine, oil and grease, and fecal coliform use Grab Samples COD, TOC, ammonia nitrogen and total suspended solids use 24-type analyses are available. To analyze for total BOD 5, total phosphorus, hour composite samples unless other frequency-sample type analyses are available.

office to sample and analyze only For two or more substantially identical outfalls, permission may be requested from the appropriate district is granted by the distnct office, on a one outfall and submit the results of the analysis for other substantially identical outfalls. If the request outfalls which were not sampled are separate sheet attached to the application form, identify which outfall was sampled and describe why the pages ii and iii for sampling definitions, including 'maximum daily substantially identical to the outfall which was sampled. See concentration', and "maximum monthly concentration".

REPORTING OF INTAKE DATA effluent limitations for one or Applicants are required to report intake water data when they are attempting to demonstrate eligibility for 'net" present in the intake waters more pollutants. A 'net" effluent limitation is determined by subtracting the average level of the pollutant(s) allow net limitations only in certain remaining after treatment which is not removed by the treatment system. NPDES regulations report the average concentration and/or mass of the results of the circumstances (see 40 CFR Part 122.45(g)). To demonstrate eligibility, concentrations and/or mass after treatment. In analyses on the intake water. If the intake water is treated prior to use, report the intake addition to the analytical results, the following information shall be submitted for each parameter If the discharge is not to the same a) A statement that the intake water is drawn from the body of water into which the discharge is made.

body of water from which the water is withdrawn, the facility is not eligible for net limitations.

the wastewater. Limitations for b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the net removal of pollutants are adjusted only to the extent that the pollutant is not removed.

a demonstration of the extent c) When applicable (for example, when the pollutant represents a class of compounds, e g., BODs, TSS, etc.),

discharge. Limitations to which the pollutants in the intake vary physically, chemically and biologically from the pollutants contained inthe pollutants vary from the discharged pollutants.

are adjusted only to the extent that the concentrations of the intake groundwater.

Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated

N NPDES Permit M10005827

-STATE OF MICHIGAN U.

JOHN ENGLER, Governor DEPARTMENT OF ENVIRONMENTAL QUALITY REPLYTO, PLSiwELLDsTRICTOFFICE

'Better Service for a Better Environment' PLAINWELLMI 49080-1915 HOLLISTER BUILDING PD BOX 30473, LANSING MI 48909-7973 INTERNET. www deq state.mL.us RUSSELL J. HARDING, Director January28, 1999 Mr. John P. Carlson Environmental Compliance Manager Cook Nuclear Plant One Cook Place Bridgman, Michigan 49106

SUBJECT:

Application for Renewal of NPI)ES PermitNo. M10005827 We have reviewed the information provided in your letter of January 25, 1999. In that letter you request that representative outfalls be used to characterize effluent characteristics for similar outfalls. We approve your request as follows:

1. Effluent from Outfall 001 will be considered representative of outfalls 001, 002, and 003.

2. Effluent from Outfall OOB will be considered representative of outfalls 00A and OOB.

Please feel free to contact me if you have any questions.

Sincerely, Greor Gregoxy .anneffel-Plainwell District Office Surface Water Quality Division 616-692-6968 cc: Mr. Blair Zordell, Cook Nuclear Plant Mr. Dan Dell, Permits Section, SWQD Ms. Sylvia Heaton, GLEAS, SWQD EOP 0100e (Rev 1198)

American Electric Power Cook Nuclear Plant One Cook Place Bndgman MIl49106 6164655901

-J AMERICAN ELECTRIC POWER Mr. Fred Morley Surface Water Quality Division Michigan Department of Environmental Quality 1342 SR89 West Suite B - - -

Plainwell, MI 49080 January 25, 1999

Subject:

NPDES Permit No. MI0005827 Application We are currently preparing the Wastewater Discharge Permit Application to renew our current NPDES operating permit. As noted in Section III - Industrial and Commercial Wastewater, Part B. Outfall Information Item 6, paragraph 5 contains instructions to request permission to use a single sample for similar outfalls for application purposes.

We request that Outfall 001 be used as a representative sample for Outfalls 002 (Unit Two Noncontact Cooling Water) and Outfall 003 (De-icing Mbde) for application use only. Outfalls 002 and 003 are substantially identical to Outfall 001. The source of these Outfalls is Lake Michigan; similar waste streams enter each Outfall prior to discharge.

In addition, we are requesting Outfall 0DB (Unit Two Steam Generator Blowdown) to be used as a representative sample for Outfall OA (Unit One Steam Generator Blowdown). Outfall 0OA and Outfall GOB are substantially identical discharges, with the exception that Outfall ODA originates from the Unit One Steam Generators, and Outfall 0GB originates from the Unit Two Steam Generators.

If you have any questions, please contact me at (616) 465-5901, ext. 1153.

Sincerely, John P. Carlson Environmental Compliance Manager

/trlm c: Greg Danneffel - MDEQ Plainwell Sylvia Heaton - MDEQ Lansing

Page Two

)JMr. Morley January 25, 1999 I certify under penalty of law that I have personally examined and am familiar with the information submitted on this and all attached documents, and based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the submitted information is true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment.

D. E. Cooper Plant Manager

Number of

.ot-'

Parameter V

4"S-< >*-'? Concentration nits->

JUConcentration Analyses Grab Sample I]Grab Biochemical Oxygen Demand - five day (BODs) 82 82 mgtl 2 2 HrCo mg/l Grab COD (Chemical oxygen demand) 331 331 mg/I 2 24 Hr Comp mgEl Grab TOC (Total organic carbon) 19 9 19 9 mg/2 24 Hr Comp mg/1 El Grab Ammonia Nitrogen (as N) 43 4 43 4 2 24HraComp mg/I Grab Total Suspended Solids 1 <4 mgI 124 El 24 HrComp rngA El Grab Total Dissolved Solids NA NA NA El 24 Hr Camp MgA El Grab Total Phosphorus (as P) <0 01 <0 01 mgi 1 s 24 Hr Comp maximumn-7day counts/1 00ml Fecal Coliform Bacteria (report geometric means) NA NA c s mI NA Grab I Residual Chlonne <0 08 <0 08 E pg/i 2 Grab minimum daily mg/i Z Grab Dissolved Oxygen 0 17 E 24 Hr Comp pH minimum maximum s Grab (report maximum and minimum of individual samples) 9.75 10.28 standard units 34 El 24 Hr Comp 1:1 C-FE3 Grab Temperature. Summer

• NA NA NA l 24 Hr Comp ElF E] C Grab Temperature, Winter

• NA NA NA 24 HrComp

<5 <5 mg/I I Grab Oil & Grease mg/I Z Grab Hydrazine 271 140 mg5i24 Hr Camp Grab Ethanolamine 149 66 mg/I 1122 El 24 Hr Comp El1 Grab El 24 Hr Comp El Grab El 24 Hr Comp E Grab See Attached for additional Data E24Hr Comp ElGrab

• NA - Internal Outfall El 24 Hr Comp ElGrab E 24 Hr Comp El Grab El 24 HrComp-E Grab 24 Hr Comp

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-ASE TYPE OR PRINT

_ILITY NAME I NPDES PERMIT NUMBER l OUTFALL NUMBER Donald C. Cook Nuclear Plant l M10005827 l OOB

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater must submit the results of at least one effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Orqanic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 3. Existing primary industnes must also provide the results of at least one effluent analysis for any other chemical listed in Table 2 known or believed to be present infacility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent.

5. DIOXIN AND FURAN CONGENER INFORMATION Existing industn es that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-tnchlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-tnchlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel); 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent, must submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6 All effluent analyses for dioxin and furan congeners must be conducted using EPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-tnchlorophenoxy acetic acid (2,4,5-T); 2- (2,3,5-tnchlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-tnchlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel), 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed inTable 6 ir OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industries that discharge non-process wastewater, must submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present infacility effluent.

In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed inTables 2 and 3 New secondary industries, or new pnmary industnes that propose to discharge non-process wastewater, must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent.

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industnes, regardless of discharge type, must provide the results of at least one analyses for any chemical listed inTable 4 known or believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in facility effluent In addition, submit the results of any effluent analysis performed within the last 5 years for any chemical listed in Tables 4 and 5.

New industnes, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be in facility effluent

8. INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, must provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in facility effluent that have not been previously identified in this application Quantitative effluent data that are less than 5 years old for these chemicals must be reported NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31. To submit additional information see page ii, item 8. If the effluent concentrations are estimated, place an E in the "Analytical Method' column The following fields must be completed for each data row: Parameter, CAS No, Concentration(s), Sample Type, Analytical Method, Quantification Level and Detection Level.

See page ii, number 5 for analybcal test requirements.

Michigan Department of En( imental Quality- Water Division (7

F---' WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant Ml0005827 00B SAMPLE DATE 4 1/25/01 9/1/01 9/3/01 9/20/01 1/29/02 2/15/02 2123/02 5/14/02 5/29/02 8/3/02H 1 N 1CAS f Conc ,, ,,Conc.'k- >,Conc.,4 - ' ,Conc:3/44 ;-Conc. Conc. ,. Conc&-, ,Conc.4 -Conc.: qConc;.,, :.Sample, Analytic .n PARAMETER - No. (ug/l) (ug/1) r (ugh1) tf (ug/I) (ugh)

> (ug/ l ) K (ug/l) L Typer ' al ir , L DL Hyrazine 7803578 206 <3 188000 140100 140050 234525 8860 119 <3 19 Grab D1385 3 10 Date 2/16/01 2/17/01 2/18/01 8/29/01 8/30/01 9/5/01 9/9/01 9/13/01 9/20/01 9/27/01 Ethanolamine 141435 10580 12920 13170 6300 6740 94800 44100 45700 56700 51200 Grab 300.0 800 300 See Attached for additional data.

6 EQP 4659-C (Rev 1/03)

Section III.B.6 and 7 Additional Sample Data 00B Summary Sheet For Outfall 00B3 Sample Analytical Max of Parameter 2/3/99 3/25/02 type Max Daily Method monthly Analyses TalTable t 11 asxn> i 8e,¢ti-es;sft!> ?~ ;t }<7'X4t r @rh w,&2r*: 2 rS+

See Attached data set from Belmonte Park Laboratories.

Table3-:. l, 't + S', i ._____,- 7A' -. _

Antimony (ugA) <1 <1 Grab <1 204.2/200.7 <1 2 Arsenic (ugA) <1 <1 Grab <1 206 2/200.7 <1 2 Beryllium (ugA) <1 <0 2 Grab <1 200 7 <1 2 Cadmium (ug/l) <0 2 <0 2 Grab <0.2 213 2/200.7 <0 2 2 Chromium (ug,) <10 <2 Grab <10 200 7 <10 2 Copper (ugA) 7 <1 Grab 7 220.2/200.7 7 2 Lead (ugA) <1 <1 Grab <1 239 2/200 7 <1 2 Nickel (ug/l) <5 <3 Grab <5 249 2/200 7 <5 2 Total Phenols (ugA) <10 - Grab <10 420.1 <10 1 Selenium (ug/l) - <1 Grab <1 270 3 <1 I Silver(ugA) <0 5 <0 2 Grab <0 5 272 2/200 7 <0 5 2 Thallium -(ugA) <1 <1 Grab <1 279 2 <1 2 Zinc (ugA) <4 Grab <4 200.7 <4 1 Cyanide (mgA) <0 01 <0 01 Grab <0 01 335 2 <0.01 2 Mercury (ngA) <0 5 Grab <0 5 1631 <0 5 1 Chlorine, total residual (mgA) <0 05 <0 08 Grab <0 08 330 5 <0.08 2 Sulfate (mg/l) <10 <1 Composite <10 375 4 <10 2 Additional Data From Belmonte Park Laboratories Is attached See Attached Data set from Cook Nuclear Plant Laboratory Table 5 * - rr ^' - ^

• f -- gr _t_________

See Attached data set from Belmonte Park Laboratories.

See Attached Data set from Cook Nuclear Plant Laboratory .

( ( .

(.

- 11, ^Belmonte Park i .it Environne

-W Laboratories Order #: 99-02-232 AMERICAN ELECTRIC POWER (AEP) Date: 03/16/99 09:23 1 COOK PLACE (FAX)

Work ID: OUTFALL OOH - OOB BRIDGMAN, MICHIGAN 49106 02/03/99 Date Received:

Date Completed: 03/16/99 Attn: BLAIR ZORDELL Purchase Order: 4307976 Client Code: AEP_4 Invoice Number:

ND= NONE DETECTED OHIO CERT.# 12345 SAMPLE IDENTIFICATION Sample Sample Sample Sample Number Description Number Description 02/03/99 02/03/99 16 OUTFALL 0OB 01 OUTFALL DOH 02/03/99 02/03/99 17 OUTFALL DOB 02 OUTFALL OOH 02/03/9 9 02/03/99 18 OUTFALL DOB OUTFALL DOH 02/03/99 03 02/03/99 19 OUTFALL 0OB 1\~ ) 04 OUTFALL OOH 02/03/99 02/03/99 20 OUTFALL 0OB 05 OUTFALL OOH 02/03/99 02/03/99 21 OUTFALL 0OB 06 OUTFALL OOH 02/03/99 02/03/99 22 OUTFALL 0OB 07 OUTFALL 00H 02/03/99 02/03/99 23 OUTFALL OOB 08 OUTFALL DOH 02/03/99 02/03/99 24 OUTFALL 0DB 09 OUTFALL OOH 02/03/99 02/03/99 25 OUTFALL DOB 10 OUTFALL OOH 02/03/99 02/03/99 26 OUTFALL 0OB 11 OUTFALL OOH 02/03/99 02/03/99 27 OUTFALL 0OB 12 OUTFALL OOH 02/03/99 02/03/99 28 OUTFALL 0DB 13 OUTFALL OOH 02/03/99 02/03/99 29 OUTFALL 0OB 14 OUTFALL OOH 02/03 /99 30 OUTFALL OOB 15 OUTFALL OOH 02/03/99 samples submitted for Enclosed ax *e results of specified questions, please contact analyses. I:f there are any Our Ohio EPA Certification numbers are 836 & 837.

Matt Lake.

DETECTION LIMIT".

Any result of "BDL" indicates "BELOW Certified By MATT LAKE AO Committed to Quality Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

1M lb Belmonte Park

) m w Environmental Laboratories Order # 99-02-232 Page 2 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample: 01A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Sday CBOD, EPA 405.1 6 2 mg/L 02/08/99 PT SUSPENDED SOLIDS,EPA 160.2 15 5 mg/L 02/11/99 KC Sample: 02A OUTFALL 00H 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed

,, COD, EPA 410.4 BDL 5 mg/L 02/19/99 LG TOC, EPA 415.1 2.0 1 mg/L 02/09/99 JW Sample: 03A OUTFALL 00H 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection

) Test Description Result BDL Limit 0.5 Units mg/L Analyzed 02/11/99 By JB AMMONIA N, EPA 350.2 Sample: 05A OUTFALL 00H 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Sy EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 SD Sample: 06A OUTFALL 00O 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed Bvr Test Description ALUMINUM, EPA 200.7 BDL 0.05 mg/L 02/15/99 RJE ANTIMONY, EPA 204.2 BDL 0.001 mg/L 03/05/99 RJE EPA 206.2 BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 200.7 0.019 0.005 mg/L 02/13/99 RJE BARIUM, EPA 200.7 BDL 0 .001 mg/L 02/13/99 RJE BERYLLIUM, EPA 200.7 BDL 0 .05 mg/L 02/15/99 RJE BORON, EPA 213 .2 BDL 0.0002 mg/L 03/08/99 RJE CADMIUM, EPA 200.7 BDL 0.01 mg/L 02/13/99 RJE CHROMIUM, 200.7 BDL 0 .01 mg/L 02/15/99 RJE COBALT, EPA 220.2 0.004 0.001 mg/L 03/08/99 RJE COPPER, EPA 200.7 0.3 0.1 mg/L 02/13/99 RJE IRON, EPA 0.001 mg/L 03/05/99 RJE A LEAD, EPA 239.2 BDL BDL 0 .01 mg/L 02/15/99 RJE 10 LITHIUM, EPA 200.7 Committed to Quality Since 1958 11East Main Street Dayton, Ohio 45426 (937) 837-3744

-mslb Belmonte Park K> i F Environmental s- Laboratories Page 3 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Detection Result Limit Units Analyzed BY Test Description mg/L 02/15/99 RJE EPA 200.7 8 .

MAGNESIUM, mg/L 02/13/99 RJE MANGANESE, EPA 200.7 0 .01 0.01 BDL 0.0002 mg/L 02/15/99 RJE MERCURY, EPA 245.1 EP METALS DIGESTION, WATER BDL 0.01 mg/L 02/13/99 RJE MOLYBDENUM, EPA 200.7 BDL 0 .005 mg/L 03/08/99 RJE NICKEL, EPA 249.2 BDL 0.1 Mg/L 02/13/99 RJE SELENIUM, EPA 200.7 BDL 0.0005 mg/L 03/08/99 RJE SILVER, EPA 272.2 0.08 0 .01 mg/L 02/15/99 RJE STRONTIUM, EPA 200.7 BDL 0.001 mg/L 03/08/99 RJE THALLIUM, EPA 279.2 BDL 0.1 mg/L 02/15/99 RJE URANIUM EPA 200.7 BDL 0.02 mg/L 02/13/99 RJE ZINC, EPA 200.7 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 07A OUTFALL 00H Detection Result Limit Units Analyzed LY Test Description mg/L 03/05/99 LG EPA 376.1 BDL 1 SULFIDE, mg/L 0 3/04/99 LG EPA 335.2 BDL 0.01 TOTAL CYANIDE, 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 08A OUTFALL 00H Detection Limit Units Analyzed BY Test Description Result 0 .01 mg/L 02/23/99 JB EPA 420.1 0 .03 PHENOLICS, 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 09A OUTFALL OOH Detection Limit Units Analyzed By Test Description Result 0.05 mg/L 02/04/99 ML CHLORINE, RESIDUAL TOTAL BDL 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 10A OUTFALL 00H Detection Units Analvzed Bv Result Limit Test Description mg/L 02/05/99 LG 0.36 0.2 NITRATE-NITRITE N mg/L 02/11/99 JB BDL 0.5 ORGANIC NITROGEN mg/L 02/18/99 LG EPA 365.1 BDL 0.1 PHOSPHORUS, mg/L 02/06/99 JB 0.52 0.5 TKN, EPA 351.3

. AO Committed to Qulilty Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

m h Belmonte Park

) A Environmental Laboratories 'v Order # 99-02-232 Page 4 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample: 11A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BP OIL & GREASE, EPA 413.1 BDL 5 mg/L 02/04/99 PT Sample: 12A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed SF GROSS ALPHA, IN WATER BDL 3 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 4 pCi/L 03/08/99 SF RADIUM, IN WATER BDL 1 pCi/L 03/10/99 SF RADIUM-226, IN WATER BDL 1 pCi/L 03/10/99 SF Sample: 13A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BYt METHYLENE BLUE ACTIVE SUB. BDL 0.01 mg/L 02/17/99 ML SULFATE, EPA 375.4 19 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 14A OUTFALL OOH 02/03/99 Collected: 02/03/939 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed PLY ASBESTOS WATER ND 0.2 MF/L, >lOum 02/12/99 EM Sample: 16A OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Sday CBOD, EPA 405.1 82 2 mg/L 02/08/99 PT SUSPENDED SOLIDS,EPA 160.2 BDL 5- mg/L 02/11/99 KC Sample: 17A OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed COD, EPA 410.4 331 20 mg/L 02/19/99 LG TOC, EPA 415.1 19.9 1 mg/L 02/09/99 JW Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937)837-3744

FtBelmonte Park

\~ , wgrm Environmental Laboratories Order # 99-02-232 Page 5 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample: 18A OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed BY Test Description EPA 350.2 43.4 0.5 mg/L 02/12/99 JB AMMONIA N, Sample: 20A OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed By Test Description SD EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 21A Detection Result Limit Units Analyzed PlE

) Test Description ALUMINUM, EPA 200.7 0.21 0.05 mg/L 02/15/99 RJE EPA 204.2 BDL 0 .001 mg/L 03/05/99 RJE ANTIMONY, EPA 206.2 BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 200.7 BDL 0 .005 mg/L 02/13/99 RJE BARIUM, EPA 200.7 BDL 0 .001 mg/L 02/13/99 RJE BERYLLIUM, EPA 200.7 BDL 0.05 mg/L 02/15/99 RJE BORON, EPA 213.2 BDL 0.0002 mg/L 03/08/99 RJE CADMIUM, EPA 200.7 BDL 0 .01 mg/L 02/13/99 RJE CHROMIUM, EPA 200.7 BDL 0 .01 mg/L 02/15/99 RJE COBALT, EPA 220.2 0.007 0.001 mg/L 03/08/99 RJE COPPER, EPA 200.7 BDL 0.1 mg/L 02/13/99 RJE IRON, EPA 239.2 BDL 0.001 mg/L 03/05/99 RJE LEAD, EPA 200.7 BDL 0.01 mg/L 02/15/99 RJE LITHIUM, BDL 1 mg/L 02/15/99 RJE MAGNESIUM, EPA 200.7 BDL 0.01 mg/L 02/13/99 RJE MANGANESE, EPA 200.7 BDL 0 .0002 mg/L 02/15/99 RJE MERCURY, EPA!245.1 EP METALS DIGESTION, WATER 0.02 0 .01 mg/L 02/13/99 RJE MOLYBDENUM, EPA'200.7 EPA,249.2 BDL 0.005 mg/L 03/08/99 RJE NICKEL, BDL 0.1 mg/L 02/13/99 RJE SELENIUM, EPA,200.7 BDL 0 .0005 mg/L 03 /08/9 9 RJE SILVER, EPA,272.2 BDL 0.01 mg/L 02/15/99 RJE STRONTIUM, EPA;200.7 BDL 0.001 mg/L 03/05/99 RJE THALLIUM, EPPL279.2 BDL 0 .1 mg/L 02/15/99 RJE URANIUM EP; 200.7 BDL 0.02 mg/L 02/13/99 RJE ZINC, EP 200.7 Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

C-"=tBelmonte Park W IL Enxdronnertal I>

.A Laboratores Page 6 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample: 22A OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed f3x Test Description EPA 376.1 14 1 mg/L 03/05/99 LG SULFIDE, EPA 335.2 BDL 0.01 mg/L 03/04/99 LG TOTAL CYANIDE, Sample: 23A OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed BY Test Description EPA 420.1 BDL 0.01 mg/L 02/23/99 JB PHENOLICS, Sample: 24A OUTFALL GOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed f3x Test Description BDL 0.05 mg/L 02/04/99 ML CHLORINE, RESIDUAL TOTAL Sample: 25A OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed Test Description BDL 0.2 mg/L 02/05/99 LG NITRATE-NITRITE N 10.3 0.5 mg/L 02/06/99 JB ORGANIC NITROGEN EPA 365.1 BDL 0.1 mg/L 02/18/99 LG PHOSPHORUS, EPA 351.3 53.7 0.5 mg/L 02/06/99 JB TKN, Sample: 26A OUTFALL QOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed BY Test Description BDL 5 mg/L 02/04/99 PT OIL & GREASE, EPA 413.1 Sample: 27A OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed BS Test Description BDL 3 pCi/L 03/08/99 SF GROSS ALPHA, IN WATER BDL 4 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 2. pCi/L 03/10/99 SF RADIUM, IN WATER BDL 2. pCi/L 03/10/99 SF RADIUM-226, IN WATER Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

1, hBelmonte Park

) h Environmental so Laboratories Page 7 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 28A OUTFALL OOB Detection Result Limit Units Analyzed By Test Description mg/L 02/17/99 ML BDL 0.01 METHYLENE BLUE ACTIVE SUB. mg/L 02/18/99 JB BDL 10 SULFATE, EPA 375.4 ML BDL 2 mg/L 02/17/99 SULFITE, 02/03/99 Collected: 02/03/9 9 Category: AQUEOUS Sample: 29A OUTFALL OOB Detection Limit Units Analyzed By Test Description Result 0.2 MF/L, >10um 02/12/99 EM ND ASBESTOS WATER Committed to Quality Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

I IN Belmonte Park

) W Environmental Laboratories Order # 99-02-232 Page 8 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 04A Test

Description:

EPA 624 Method: 624 Test Code: 624_X Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2

) CHLOROETHANE BDL BDL 10 2

CHLOROFORM 1,l-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL. 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 2 VINYL CHLORIDE BDL 10 XYLENES BDL 10 SURROGATE %RECOVERY LIMITS D4-1,2 DICHLOROETHANE 114 76 - 114 DB -TOLUENE 93 88 - 110 Committed to Quality Since 1958 I 1 East Main Street Dayton, Ohio 45426 (°,37) 837-3744

Belmonte Park Environmental K> -) Laboratories Order # 99-02-232 Page 9 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 04A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/03/99 Category: AQUEOUS-4-BROMOFLUOROBENZENE 86 - 115 Notes and Definitions for this Report:

DATE RUN 03/10/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020932 UNITS uq/L METHOD EPA 624 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

I Belmonte Park

) = MEnvironmental iLaboratories K>

Order # 99-02-232 Page 10 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625_AE Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 50 PHENOL BDL 10

) ACENAPHTHENE BDL BDL 10 50 BENZIDENE 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL. 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE BDL 10 Committed to Quoihty Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

- -p kBelmonte Park I Environmental

'SO Laboratores Page 11 -

Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 05A Method: 625 Test Code: 625 AE Test

Description:

EPA 625 SEMI VOLATILES 02/03/99 Category: AQUEOUS Collected:

BDL 10 BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PXTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 50 BENZO(GHI)PERYLENE BDL 10 FLUORENE BDL 10 PHENANTHRENE

/ BDL 50 DIBENZO(A,H)ANTHRACENE BDL 50 INDENO(1,2,3-CD)PYRENE BDL 10 PYRENE BDL 100 ETHANOL AMINE BDL 200 HYDRAZINE SURROGATE %RECOVERY LIMIT 88 35 - 114 NITROBENZENE-d5 77 43 - 116 2-FLUOROBIPHENYL p-TERPHENYL-d14 90 33 - 141 38 10 _ 94 PHENOL-d6 32 21 _ 100 2-FLUOROPHENOL 36 10 - 123 2,4,6-TRIBROMOPHENOL Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022527 UNITS uq/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

"M ft Belmonte Park

) . Environmental Laboratories I11 Order # 99-02-232 Page 12 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 05A Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES EPA 608 Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT ALDRIN BDL 0 . 010 ALPHA-BHC BDL 0 .010 BETA-BHC BDL 0 .010 DELTA-BHC BDL 0. 010 GAMMA-BHC BDL 0 . 010 CHLORDANE BDL 0 .010 4,4-DDT BDL 0 .010 4,4-DDE BDL 0.010 4,4-DDD BDL 0 . 010 DIELDRIN BDL 0 .010 ALPHA ENDOSULFAN BDL 0. 010

) BETA ENDOSULFAN BDL 0.010 ENDOSULFAN SULFATE BDL 0.10 ENDRIN BDL 0 .010 ENDRIN ALDEHYDE BDL 0.020 HEPTACHLOR BDL 0.030 HEPTACHLOR EPOXIDE BDL 0.10 PCB-1016 BDL 1 PCB-1221 BDL 2 PCB-1232 BDL 1 PCB-1242 BDL 1 PCB-1248 BDL 1 PCB-1254 BDL 1 PCB-1260 BDL 1 TOXAPHENE BDL 0.20 SURROGATE %RECOVERY LIMITS DBC(SURROGATE, W RECOVERY) 90 70 - 130 94 70 - 130 2,4,5,6-TCX(SURROGATE % REC.)

Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020942 UNITS ua/L Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

"W Elk Belmonte Park D Environmental t-L~

Laboratories Page 13 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 05A PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Test

Description:

Collected: 02/03/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

a gh Belmonte Park

• Environmental MP Laboratories - <2 i

Page 14 Order # 99-02-232 TEST RESULTS BY SAMPLE 03/16/99 09:23 02/03/99 Lab No: 15A Sample

Description:

OUTFALL OOH Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270_U Test

Description:

Collected: 02/03/99 Category: AQUEOUS RESULT LIMIT PARAMETER BDL 5 TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER SURROGATE %RECOVERY LIMIT 105 35 - 114 NITROBENZENE-D5 120 Q 43 _ 116 2-FLUOROBIPHENYL 125 33 - 141 p-TERPHENYL-d14 40 10 _ 94 PHENOL-d6 53 21 _ 100 2-FLUOROPHENOL - 123 150 0 10 2,4,6-TRIBROMOPHENOL

) Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206505W UNITS uq/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

Il Belmonte Park

, 4 Environmental f Laboratories Page 15 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE 02/03/99 Lab No:-19A Sample

Description:

OUTFALL O0B 624_X Method: 624 Test Code:

Test

Description:

EPA 624 Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT BDL 20 ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 2 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,l-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE 2 BDL 1,1,2,2-TETRACHLOROETHANE BDL 10 CHLOROETHANE BDL 2 CHLOROFORM BDL 2 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE 2 BDL 1,3-DICHLOROBENZENE 2 BDL 1,4-DICHLOROBENZENE BDL 10 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 2 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE

• 2 BDL TRICHLOROETHENE BDL 10 VINYL CHLORIDE BDL 10 XYLENES

%RECOVERY LIMITS SURROGATE 112 76 - 114 D4-1,2 DICHLOROETHANE 93 88 - 110 j

D8-TOLUENE Committed to Quality Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

Belmonte Park A Environmental F Laboratories i

Page 16 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOB 02/03/99 Lab No: 19A Test

Description:

EPA 624 Method: 624 Test Code: 624_X Collected: 02/03/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 92 86 - 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020933 UNITS ua/L METHOD EPA 624 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

Belmonte Park

) , 5Environmental Laboratories Page 17 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00B 02/03/99 Lab No: 20A Method: 625 Test Code: 625_AE Test

Description:

EPA 625 SEMI VOLATILES Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 BDL 10 4-CHLORO-3-METHYLPHENOL 2-CHLOROPHENOL BDL 10 BDL 10 2,4-DICHLOROPHENOL 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL 50 BDL 50 2,4-DINITROPHENOL 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 50 PHENOL BDL 10 ACENAPHTHENE BDL 10 BDL -50 BENZIDENE 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 BDL 10 1,4-DICHLOROBENZENE 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE 4-CHLOROPHENYL PHENYL ETHER BDL 10 BDL 10 4-BROMOPHENYL PHENYL ETHER BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE 10 N-NITROSODI-N-PROPYLAMINE BDL BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

31 Belmonte Park

) Environmental Laboratories Order # 99-02-232 Page 18 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00B 02/03/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/03/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE. BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANTHRENE BDL 10

) DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE BDL BDL 50 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-d5 86 35 - 114 2-FLUOROBIPHENYL 74 43 - 116 p-TERPHENYL-d14 91 33 - 141 PHENOL-d6 76 10 - 94 2-FLUOROPHENOL 82 21 - 100 2,4,6-TRIBROMOPHENOL 78 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/26/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022605 UNITS uq/L METHOD EPA 625 BDL BELOW DETECTION LIMIT h

Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

= 1h Belmonte Park

. Environmental Laboratories Page 19 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00B 02/03/99 Lab No: 20A Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES EPA 608 Category: AQUEOUS Collected: 02/03/99 PARAMETER RESULT LIMIT BDL 0. 010 ALDRIN BDL 0 . 010 ALPHA-BHC BDL 0.010 BETA-BHC BDL 0 .010 DELTA-BHC BDL 0 .010 GAMMA-BHC BDL 0 . 010 CHLORDANE BDL 0. 010 4,4-DDT BDL 0.010 4,4-DDE BDL 0.010 4,4-DDD BDL 0 . 010 DIELDRIN BDL 0.010 ALPHA ENDOSULFAN

) BETA ENDOSULFAN ENDOSULFAN SULFATE BDL BDL

0. 010 0.10 BDL 0.010 ENDRIN BDL 0.020 ENDRIN ALDEHYDE BDL 0.030 HEPTACHLOR BDL 0.10 HEPTACHLOR EPOXIDE BDL 1 PCB-1016 BDL 2 PCB-1221 BDL 1 PCB-1232 1 PCB-1242 BDL PCB-1248 BDL 1 BDL 1 PCB-1254 BDL PCB-1260 0.20 BDL TOXAPHENE SURROGATE  %-RECOVERY LIMITS 93 70 - 130 DBC(SURROGATE, % RECOVERY) 95 70 - 130 2,4,5,6-TCX(SURROGATE % REC.)

Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020943 UNITS uc/L 10 Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

M Mh Belmonte Park IWAL Environmental Laboratories z Page 20 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOB 02/03/99 Lab No: 20A Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES EPA 608 Category: AQUEOUS Collected: 02/03/99 METHOD EPA 608 BDL BELOW DETECTION LIMIT V-Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

. 'k lBelmonte Park j Environmental C~ 24.M Laboratories Page 21 Order # 99-02-232 TEST RESULTS BY SAMPLE 03/16/99 09:23 Sample

Description:

OUTFALL 00B 02/03/99 Lab No: 30A Method: Special Test Test Code: 8270 U Test

Description:

Triaryl Phosphate Sub-Out Category: AQUEOUS Collected: 02/03/99 PARAMETER RESULT LIMIT BDL 5 TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER SURROGATE RECOVERY LIMITS 80 35 - 114 NITROBENZENE-D5 80 43 - 116 2-FLUOROBIPHENYL 73 33 - 141 p-TERPHENYL-d14 10 10 - 94 PHENOL-d6 4Q 21 - 100 2-FLUOROPHENOL 4 O 10 - 123 2,4,6-TRIBROMOPHENOL Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST MN INSTRUMENT SATURN FILE ID 0206502W UNITS uf/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

Facility name: NPDES Permit number: Outfall Number:

Donald C. Cook Nuclear Plant I M10005827 IOOB l Addendum to NPDES Renewal Application Section III.B.10 Toxic Pollutant Reasonable Potential Effluent Data Sampling results indicate the presence of toxic pollutants in the Cook Nuclear Plant discharges as follows:

Copper was detected in Outfall OOB (Unit 2 Steam Generator Blowdown). Based on knowledge of the plant processes, there is reasonable potential for copper to be present in these discharges.

Ethanolamine was detected in Outfall 0GB (Unit Two Steam Generator Blowdown).

Based on knowledge of the plant processes, there is reasonable potential for ethanolamine to be present in these discharges.

( (

Section III.B.6 and 7 Additional Sample Data 0013 Aluminum (Cook Nuclear Lab)

Date Al (ug/1) Date Al (ug/1) 2/19 220U 1/1 9/02 113j 8/3001-426- 1/19/02 12 2 8/30/0 -7 277 1/19/02 13 3 8/30/0 1i 6Z 1/19/02 1 8/30/0 --- MG 1/19/02 16 3 8/30101 15 7 1/1--9/02 13 5 8/30/1 18 1119/02 16.2 8/00 6 -9 1/19102 22.9 8/30/01 21 1119/02 1 8/00 7T4 1/19102 16 8UZ 8/01 1 219g 1/19102 201 8/30101 28 1/19102 2 83/1 20.5- 1/19/02 1 8/00871/19102 19 5 8/00691119102 19Z8 8311 23 5 1/19102 2.

8/30101 35.21119102 1 8/30101 29.1 1/19102 21-.3-8/30/01 37 1119102 2 8/00 c 3000 1119102 20 8 8/00 3 000 1/19102 1, 8311 37.8 1/19102 2 8/30/01 44 21119102 2 8/31/01 43 2 1/19102 1 54il9 8/31/01 9/1902 2.

8/1/1 6 1/19102 27.4 83/1 45 6 1119/02 3.

8/3101 4 9 1/19/02 -- 32 8/1/1 4. 1/19102 --- 42 9 11/2 13 7 1119/02 36 2-11/2 12.4 1/19/02 43 5 1/70221119/02 5.1-1/8/2 136 /9/02 49 3-1/18/02 13 41/19/02 5 1/18/02 12 9- 1719102 62 4 11/2 1129 1/19/02 503-1/19/ 15.

T 1119/02 5013-43 1/190= 1/9/02 50.7TF 1

T4T-1/19/02 /9O 1 9102/U 1;s b 1/19/UZ 1.

1/19/0x 15-ST 4Max 220 1/90 372 Max monthly 20 11/ 13 2 Count 87 111YUa 4-./ Methoa w zu Page 3

Section III B. 6 and 7 Additional sample data OUB Manganese uGL, (Cook Nuclear Lab)

Date Mn (ug1) 8/30/01 1.65 8/30/01 1.78 8/30/01 2 07 8/30/01 2.31 8/30/01 2.41 8/30/01 2.44 8/30/01 1.11 8/30/01 0.46 8/30/01 < 0.200 8/30/01 0.39 8/31/01 0.37 8/31/01 2.26 8/31/01 2.83 1/17/02 0.42 1/18/02 1.9 1/19/02 1.8 1/19/02 2.64 1/19/02 2.77 1/19/02 3.57 1/19/02 2.34 1/19/02 2.01 1/19/02 2.37 1/19/02 3.19 1/19/02 5.34 1/19/02 7.38 1/19/02 3.91 1/19/02 0.83 1/19/02 2.11 Max 7.38 Max monthly 2.3 l Count 28 l Method 200.7 Page 2

( c

( (

Section III.B.6 and 7 Additional Sample Data 00B Magnesium ug I (Cook Nuclear Lab)

Date Mg (ug/l) Date mg (ugIL) 1/22/01 0.7 1/19/02 1.7 1/22/01 0.6 1/19/02 3.2 1/23/01 1.5 1/19/02 1.6 1/23/01 2.9 1/19/02 1.4 1/23/01 3.1 1/19/02 1.5 1/23/01 3.3 1/19/02 3.1 1/23/01 34 1/19/02 8.7 1/23/01 3.4 1/19/02 16.2 1/23/01 3.7 1/19/02 10 2 1/23/01 3.7 1/19/02 3.9 1/23/01 4 1/19/02 54 1/23/01 4 8/30/01 0.5 Max 16.2 4.1 I 8/30/01 0.7 ax monthly 8/30/01 0.8 Count 40 8/30/01 0.9 Method 200.7 8/30/01 0.9 8/30/01 0.9 8/30/01 0.4 8/30/01 < 0.2 8/30/01 < 0.2 8/30/01 < 0.2 8/31/01 < 0.2 8/31/01 1.1 8/31/01 1.7 1/17/02 0.4 1/18/02 0.9 1/19/02 0.9 1/19/02 2_

Page 2

Section III.B.6 Non-routine sample data COB hydrazine ugl (Cook Nuclear Lab)

Date Hydrazine ug/L Date Hydrazine ug/L 1/25/01 206 5/26/02 1558 1/26/01 275 5/27/02 1285 8/30/01 310 5/28/02 1870 8/31/01 <3 5/29/02 <3 9/1/01 <3 5/30/02 719 9/1/01 10085 5/31/02 1010 9/2/01 18000 6/1/02 2740 9/2/01 92658 6/2/02 555 9/2/01 59871 7/22/02 <3 9/2/01 57710 7/28/02 16437 9/3/01 188000 7/29/02 50213 9/5/01 227626 7/30/02 14200 9/7/01 158310 7/31/02 22019 9/8/01 158220 8/1/02 13500 9/13/01 164277 8/2/02 620 9/20/01 140100 8/3/02 19 9/27/01 155939 1/18/02 42 1/20/02 80582 Max 270837 1/24/02 125000 Monthly Max 140376 1/29/02 140050 Count 53 1/31/02 99373 Method: ASTM D 1385 2/8/02 175116 QL: 3 ug/l 2/9/02 263222 DL: 10 ug/l 2/13/02 270837 2/15/02 234525 2/16/02 162647 2/21/02 113104 2/22/02 175000 2/23/02 8860 2/23/02 267 2/24/02 184 2/25/02 <3 2/26/02 <3 5/13/02 636 5/14/02 119 5/15/02 1249 c ( (

C Non-routine sample data OOB Ethanolamine Section llI.B.6 (Cook Nuclear Lab) Method 300.0 Ethanolamine mg/i Date Ethanolamine mg/i Date Ethanolamine mg/i Date Ethanolamine mg/i Date Date Ethanolamine mg/A Date 4.39 216/01 147 2/17/01 12.92 2/28/01 1/2/01 21.26 1/14/01 11.6 1/25/01 4.1 2/6/01 1446 2/17/01 12.73 2/28/01 1/2/01 22.33 1/14/01 11.3 1/26/01 1/26/01 1.22 2/6/01 1429 2/17/01 1292 3/1/01-1/2/01 23 27 1/15/01 10.7 1/26/01 3.76 2/6/01 1459 2118/01 13 17 3/1/01 1/2/01 2231 1/15/01 107 1/15/01 107 1/26/01 48 2/7/01 12.75 2/18/01 1341 3/1/01 1/3/01 27.7 107 1/27/01 3 1 2/7/0 1 13.04 2/18/01 13.1 3/1/01 1/3/01 27 6 1/15/01 1/27/01 22 2/7/01 12.74 2118/01 13.06 3/2/01 1/3/01 27.6 1/16/01 12 1/27/01 3.7 2/7/01 1275 2/19/01 13.1 3/2/01 1/3/01 28.4 1/16/01 12.1 1/27/01 36 2/8/01 15.3 2/19/01 13.3 3/2/01 1/4/01 10.16 1/16/01 11.9 1/28/01 3 36 2/8/01 162 2/19/01 13 3/2/01 1/4/01 10.4 1/16/01 12 1/28/01 3 23 2/8/01 159 2/19/01 13 3/3/01 1/5/01 8.76 1/17/01 123 1/28/01 3 33 2/8/01 158 2/20/01 14.3 3/3/01 1/5/01 8.26 1/17/01 124 3 33 219/01 17.14 2/20/01 14.5 3/3/01 1/5/01 9.14 1/17/01 12.2 1/28/01 698 2/9/01 1703 2/20/01 14.1 3/3/01 1/5/01 9.1 1/17/01 12.2 1/29/01 672 2/9/01 1673 2/20/01 14.1 3/4/01 1/7/01 7.41 1/18/01 14.7 1/29/01 1/29/01 6 57 2/9/01 1628 2/21/01 124 3/4/01 1/7/01 7.46 1/18/01 14.6 1/29/01 6.71 2/10/01 13.7 2/21/01 11.34 3/4/01 1/7/01 7.31 1/18/01 14.3 1/30/01 12 2/10/01 14.1 2/21/01 12.29 3/4/01 1/7/01 7.31 1/18/01 14 5 1/30/01 11.5 2/10/01 144 2121/01 12.31 3/5/01 1/8/01 7.76 1/19/01 15.1 1/30/01 11.2 2/10/01 14.3 2122/01 14.2 3/5/01 1/8/01 8 02 1/19/01 14 8 1/30/01 109 2/11/01 13.1 2/22/01 14.3 3/5/01 1/8/01 7 95 1/19/01 14.5 1/31/01 21 6 2111/01 133 2122101 14.1 3/5/01 1/8/01 7.88 1/19/01 14 5 1/31/01 22.1 2/11/01 13.2 2/22/01 14 3/6/01 1/9/01 993 1/20/01 159 1/31/01 21.2 2/11/01 13.1 2/23/01 13.32 3/6/01 1/9/01 10.12 1/20/01 16.2 1/31/01 21.3 2/12/01 11.19 2/23/01 1363 3/6/01 1/9/01 10.13 1/20/01 16 8.73 2/12/01 11.56 2/23/01 13.37 3/6/01 1/9/01 102 1/20/01 15.9 2/1/01 2/12/01 11.38 2/23/01 1343 3/7/01 1/10/01 10.24 1/21/01 13.9 2/1/01 9.55 9.48 2/12/01 11.37 2/24/01 12 933 3/7/01 1110/01 10.75 1/21/01 14.3 2/1/01 2/1/01 948 2/13/01 10.7 2/24/01 13.077 3/7/01 1/10/01 10.28 1/21/01 14 7.3 2/13/01 11 2/24/01 12.853 3/7/01 1/10/01 1027 1/21/01 159 2/2/01 212/01 7.4 2113/01 109 2/24/01 12.991 3/8/01 1/11/01 1059 1/22/01 135 72 2113/01 109 2125/01 11 004 3/8/01 1/11/01 1077 1/22101 138 212/01 7.3 2/14/01 11.2 2/25/01 10.785 3/8/01 1/11/01 1066 1/22/01 13.5 2/2101 10.2 2/14/01 11.4 2/25/01 10 877 3/8/01 1/11/01 1076 1/22/01 13.5 2/3/01 2/3/01 9.9 214/01 11.2 2/25/01 10.86 3/9/01 1/11/01 13.31 1/23/01 9.68 213/01 9 66 2/14/01 11 2 2/26/01 11.9 3/9/01 1/12/01 16.2 1/23/01 9.64 2/3/01 9.53 2/15/01 123 2/26/01 12.182 3/9/01 1/12/01 16.86 1/23/01 9.73 214/01 11.5 2/15/01 12.4 2/26/01 11.921 3/9/01 1/12/01 16.36 1/23/01 9.45 2/4/01 11.5 2/15/01 12.1 2/26/01 11.901 3/10/01 1/12101 16.56 1/24/01 301 2/4/01 11.4 2/15/01 12 2/27/01 1287 3/10/01 1/13/01 1247 1/24/01 3.42 2/4/01 11.2 2/16/01 1058 2/27/01 134 3/10/01 1/13/01 1286 1/24/01 2 81 2/5/01 13.86 2/16/01 1085 2/27/01 131 3/10/01 1/13/01 12.86 1/24/01 3 86 215/01 14.2 2/16/01 1082 2127/01 1307 3/11/01 1/13/01 12.93 1/25/01 2 96 215/01 13.7 2116/01 1034 2/28/01 14.07 3/11/01 1/14/01 12.1 1/25/01 25 2/5/01 1364 2/17/01 1288 2/28/01 14.27 3/11/01 1/14/01 11.7 1/25/01 2 98

Section III.B.6 Non-routine sample data QOB Ethanolamine (Cook Nuclear Lab) Method 300.0 Ethanolamine mg/A Date Ethanolamine mg/I Date Ethanolamine mg/I Date Ethanolamine mg/I Date Ethanolamine mg/A Date Ethanolamine mg/i 14 01 3/11/01 12.8 3/23/01 12.5 4/3/01 6.52 4/14/01 3.154 4/25/01 9.71 14.09 3/12/01 11.96 3/23/01 12 7 4/3/01 6.51 4/14/01 3.185 4/26/01 7.92 15.5 3/12/01 12.41 3/23/01 12 3 4/3/01 66 4/15/01 4.391 4/26/01 8.12 15.75 3/12/01 12 31 3/23/01 12 4 4/4/01 8.59 4/15/01 14047 4/26/01 7.5 15.48 3/12/01 12 13 3/24/01 12.96 4/4/01 8.06 4/15/01 11 253 4/26/01 8.08 15.39 3/13/01 7.604 3/24/01 12.93 4/4/01 8.74 4/15/01 7.664 4/27/01 6.97 14 3/13/01 7.971 3/24/01 12.74 4/4/01 867 4/16/01 8.68 4/27/01 5.44 14 3/13/01 7.42 3/24/01 12.92 4/5/01 9 09 4/16/01 5.574 4/27/01 6.89 138 3/13/01 7.42 3/25/01 13.55 4/5/01 9.18 4/16/01 8.252 4/27/01 7.12 13.9 3/14/01 8.136 3/25/01 13.39 4/5/01 8.8 4/16/01 8.621 4/28/01 8.73 13.8 3/14/01 8 153 3/25/01 13.07 4/5/01 8 93 4/17/01 6.51 4/28/01 8 99 14.1 3/14/01 8 039 3/25/01 13.25 4/6/01 11 4 4/17/01 8.63 4/28/01 8 73 13.6 3/14/01 8.025 3/26/01 14.39 4/6/01 11.3 4/17/01 9.46 4/28/01 8.79 13.6 3/15/01 10.3 3/26/01 14.61 4/6/01 11.2 4/17/01 9.21 4/29/01 11.34 12.36 3/15/01 10 39 3/26/01 14.5 4/6/01 11 2 4/18/01 962 4/29/01 11.47 12.69 3/15/01 10 15 3/26/01 14.35 4/7/01 11.3 4/18/01 9 84 4/29/01 11.43 12.59 3/15/01 10 11 3/27/01 13.5 4/7/01 11 3 4/18/01 9.67 4/29/01 11.48 12.62 3/16/01 11.65 3/27/01 13.5 4/7/01 11 6 4/18/01 9.66 4/30/01 123 14 3/16/01 11.92 3/27/01 13.8 4/7/01 11 4 4/19/01 11.01 4/30/01 1228 14.5 3/16/01 11.82 3/27/01 13.5 4/8/01 8.592 4/19/01 11.47 4/30/01 11.94 14.4 3/16/01 11.84 3/28/01 13 5 4/8/01 8 884 4/19/01 11.28 4/30/01 11.68 14.1 3/17/01 12.6 3/28/01 13 8 4/8/01 8 62 4/19/01 11.15 5/1/01 13.7 12.98 3/17/01 13 3/28/01 13 5 4/8/01 879 4/20/01 15.89 5/1/01 13.7 1328 3/17/01 12.72 3/28/01 13 6 4/9/01 9 689 4/20/01 16.07 5/1/01 13 7 1305 3/17/01 12.95 3/29/01 12.85 4/9/01 9.9 4/20/01 1586 5/1/01 138 1308 3/18/01 14.83 3/29/01 13.72 4/9/01 9.7 4/20/01 16.06 5/2/01 14.65 12.19 3/18/01 14.94 3/29/01 13.56 4/9/01 9 67 4/21/01 16.7 5/2/01 14.75 12.38 3/18/01 14.78 3/29/01 13 53 4/10/01 12.95 4/21/01 17 5/2/01 14.45 12.38 3/18/01 14.65 3/30/01 12 422 4/10/01 13.22 4/21/01 167 5/2/01 14.37 12.25 3/19/01 13.22 3/30/01 13.116 4/10/01 12.44 4/21/01 167 5/3/01 15.09 135 3/19/01 13.65 3/30/01 13 044 4/10/01 1309 4/22/01 14.21 5/3/01 15.04 13.8 3/19/01 13 69 3/30/01 12.91 4/11/01 12.68 4/22/01 1428 5/3/01 15.03 135 3/19/01 13 49 3/31/01 12.859 4/11/01 1267 4/22/01 13.78 5/3/01 14.95 13.5 3/20/01 13.193 3/31/01 12 825 4/11/01 12.36 4/22/01 14.24 5/4/01 14.662 13.4 3/20/01 13 4 3/31/01 12 977 4/11/01 1304 4/23/01 11 82 5/4/01 15 014 136 3/20/01 13 3 3/31/01 13 041 4/12/01 186 4/23/01 11.98 5/4/01 14.554 13.2 3/20/01 13 39 4/1/01 13.713 4/12/01 184 4/23/01 11.74 5/4/01 14.698 13.4 3/21/01 12.1 4/1/01 14.137 4/12/01 184 4/23/01 10.73 5/5/01 7.636 13.3 3/21/01 12 6 4/1/01 13.906 4/12/01 174 4/24/01 10.5 5/5/01 7.653 13.4 3/21/01 12 6 4/1/01 14.23 4/13/01 6 07 4/24/01 10.2 5/5/01 7.569 13.1 3/21/01 12 5 4/2/01 7.931 4/13/01 604 4/24/01 10.1 5/5/01 7 66 13 3/22/01 12.184 4/2/01 8 215 4/13/01 599 4/24/01 10.3 5/6/01 4.175 12.4 3/22/01 12.594 4/2/01 7.89 4/13/01 5.77 4/25/01 9.34 5/6/01 4.349 12.9 3/22/01 12.42 4/2/01 8 205 4/14/01 3.053 4/25/01 957 5/6/01 4 288 12.6 3/22/01 12.554 4/3/01 6.48 4/14/01 3 352 4/25/01 9.48 5/6/01 4.324

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Section III.B.6 Non-routine sample data OOB Ethanolamine (Cook Nuclear Lab) Method 300.0 Date Ethanolamine mg/A Date Ethanolamine mg/I Date Ethanolamine mgA Date Ethanolamine mgA Date Ethanolamine mgA Date 5/6/01 1.5 5/19/01 9 62 5/30/01 12 04 6/10/01 8.95 6/22/01 11 61 7/7/01 5/7/01 667 5/19/01 9 84 5/30/01 12 05 6/10/01 8.92 6/22/01 11.77 7/8/01 571/01 6 34 5/19/01 9 68 5/30/01 11.96 6/11/01 10 4 6/22/01 12.06 7/8/01 5/7/01 6.37 5/19/01 9.61 5/31/01 12.73 6/11/01 10 62 6/23/01 10 8 7/9/01 5/7/01 6.54 5/20/01 8 59 5/31/01 13.03 6/11/01 10.31 6/23/01 10.73 7/9/01 5/8/01 7.97 5/20/01 8 63 5/31/01 12.74 6/11/01 10 31 6/23/01 10.83 7/10/01 5/8/01 8.1 5/20/01 8 78 5/31/01 12.85 6/12/01 11 6/24/01 10.64 7/10/01 5/8/01 7.94 5/20/01 8 51 6/1/01 12.21 6/12/01 10 96 6/24/01 10.36 7/11/01 5/8/01 7.75 5/21/01 7 59 6/1/01 12.19 6/12/01 10 93 6/24/01 10 45 7/11/01 5/9/01 8 54 5/21/01 7.72 6/1/01 12 11 6/12/01 11.12 6/25/01 11 7/12/01 5/9/01 8.47 5/21/01 7.89 6/1/01 12 28 6/13/01 10 82 6/25/01 11 7/12/01 5/9/01 841 5/21/01 7.62 6/2/01 11 49 6/13/01 11 04 6/25/01 11.3 7/13/01 5/9/01 8 32 5/22/01 5 98 6/2/01 11.85 6/13/01 10 86 6/26/01 11.6 7/13/01 5/10/01 8.1 5/22/01 6 13 6/2/01 11.74 6/13/01 10 9 6/26/01 11.4 7/13/01 5/10/01 8.19 5/22/01 5 85 6/2/01 11.93 6/14/01 11.7 6/26/01 11.55 7/14/01 5/10/01 7.92 5/22/01 5 87 6/3/01 8 33 6/14/01 11.4 6/27/01 12 05 7/14/01 5/10/01 7.96 5/23/01 6 98 6/3/01 8 45 6/14/01 11.7 6/27/01 11.95 7/14/01 5/11/01 8.1 5/23/01 7 06 6/3/01 8 37 6/14/01 11.7 6/27/01 11.94 7/15/01 5/11/01 8.25 5/23/01 6.91 6/3/01 8 52 6/15/01 13.3 6/28/01 12 02 7/15/01 5/11/01 7.87 5/23/01 6 95 6/4/01 8 03 6/15/01 13 4 6/28/01 11.91 7/15/01 5/11/01 7.93 5/24/01 7.25 6/4/01 8.19 6/15/01 13 2 6/28/01 11.98 7/16/01 5/12/01 9.36 5/24/01 6 84 6/4/01 8 03 6/15/01 13 6/29/01 11.56 7/16/01 5/12/01 9.18 5/24/01 7 43 6/4/01 8.12 6/16/01 12.48 6/29/01 11 47 7/16/01 5/12/01 9 32 5/24/01 7.29 6/5/01 7.95 6/16/01 12.32 6/29/01 11.3 7/17/01 5/12/01 9 09 5/25/01 8 58 6/5/01 8.15 6/16/01 12.46 6/30/01 12 2 7/17/01 5/13/01 10.18 5/25/01 8.71 6/5/01 7.78 6/16/01 12.46 6/30/01 12 08 7/17/01 5/13/01 10.46 5/25/01 8 82 6/5/01 8 01 6/17/01 12.4 6/30/01 12 7/18/01 5/13/01 10.37 5/25/01 8.79 6/6/01 7 82 6/17/01 12.3 7/1/01 8 58 7/18/01 5/13/01 10.37 5/26/01 9 51 6/6/01 8 17 6/17/01 12.3 7/1/01 8 65 7/18/01 5/15/01 16.66 5/26/01 9.74 6/6/01 8.17 6/17/01 12 4 7/1/01 8 82 7/19/01 5/15/01 1679 5/26/01 9.67 6/6/01 8.18 6/18/01 12.52 7/2/01 7.36 7/19/01 5/15/01 16.72 5/26/01 9.89 6/7/01 8.94 6/18/01 12.59 7/2/01 7.51 7/19/01 5/15/01 1684 5/27/01 11.1 6/7/01 8.75 6/18/01 12 31 7/2/01 7.58 7/20/01 5/16/01 20 5/27/01 11 4 6/7/01 8 84 6/18/01 12.32 7/3/01 7.57 7/20/01 5/16/01 20.4 5/27/01 10 9 6/7/01 8.68 6/19/01 12.34 7/3/01 7.52 7/20/01 5/16/01 199 5/27/01 10 8 6/8/01 8.75 6/19/01 12 58 7/3/01 7.4 7/20/01 5/16/01 20 5/28/01 10.76 6/8/01 8.83 6/19/01 12.18 7/4/01 10 22 7/21/01 5/17/01 14.15 5/28/01 11.12 6/8/01 8.77 6/19/01 12.1 7/4/01 9.76 7/21/01 5/17/01 14 51 5/28/01 10.8 6/8/01 8.69 6/20/01 11.76 7/4/01 9.31 7/21/01 5/17/01 14.19 5/28/01 10 68 6/9/01 8.15 6/20/01 12.3 7/5/01 13.1 7/21/01 5/17/01 14.4 5/29/01 10 89 6/9/01 8 22 6/20/01 12 01 7/5/01 13.1 7/22/01 5/18/01 7.95 5/29/01 11 01 6/9/01 8 07 6/20/01 12.15 7/5/01 13 7/22/01 5/18/01 7.89 5/29/01 10.8 6/9/01 8 09 6/21/01 11 99 7/6/01 13 05 7/22/01 5/18/01 7.98 5/29/01 10.78 6/10/01 8.67 6/21/01 11 82 7/6/01 13.05 7/22/01 5/18/01 7.95 5/30/01 11.91 6/10/01 8.97 6/21/01 12 7/7/01 9.18 7/23/01

Section III.B.6 Non-routine sample data 00B Ethanolamine (Cook Nuclear Lab) Method 300.0 Ethanolamine mg/I Date Ethanolamine mg/I Date Ethanolamine mg/i Date Ethanolamine mg/A Date Ethanolamine mg/I Date Ethanolamine mg/I 8.92 7/23/01 12.24 8/3101 13 8/29/01 6.26 9/9/01 44.1 2/2/02 18.8 6.99 7/23/01 12.13 8/3/01 13 8/30/01 6.74 9/9/01 53 2/2/02 20.2 7.03 7/23/01 12.18 8/4/01 13 8/30/01 6.6 9/13101 45.7 2/8/02 44.6 4 52 7/24/01 12.98 8/4/01 13.2 8/30/01 6.69 9/13/01 38.7 2/8/02 39.4 4.463 7/24/01 13.16 8/4/01 13.1 8/31/01 16.19 9/13/01 48.7 2/9/02 78.2 3.67 7/24/01 13 8/4/01 13.1 8/31/01 41.78 9/13/01 38 6 2/10/02 31.8 3.61 7/24/01 13.03 8/5/01 12.86 8/31/01 18 95 9120/01 56 7 2/10102 34.2 4.19 7/25/01 12.78 8/5/01 13.02 8/31/01 20 76 9/20101 42.9 2/10102 35 4.16 7/25/01 12.99 8/5/01 13 9/1/01 2 77 9120/01 48.6 2/13102 81 6 4.74 7/25/01 12 82 8/5/01 12 9 9/1/01 6 07 9/27/01 51 2 2/13102 41 9 4.64 7/25101 12.97 8/6/01 12 22 9/1/01 2 33 9/27/01 46.8 2/13/02 42.8 6.176 7/26/01 12 79 8/6/01 12.58 911/01 3 29 9/27/01 54.1 2/13102 38.7 6.17 7/26/01 13.11 8/6/01 12.16 9/1/01 8.8 1/2/02 13 2 2/15102 64 6.18 7/26101 12.8 8/6/01 12.11 9/1/01 35.2 1/2/02 13.7 2/15/02 37.8 7.68 7/26/01 12.82 8/7/01 10.73 9/1/01 30.1 1/2/02 13 2 2/15/02 39 2 7.61 7/27/01 12.34 8/7/01 10.84 9/1/01 26 4 1/2/02 13 2/15/02 33.8 7.62 7/27101 12.33 8/7101 10.72 9/2/01 18 6 1/9102 8 89 2/16102 34.4 9.58 7/27/01 12.41 8/7101 10.72 9/2/01 88 119/02 8 63 2/21/02 < 1 1.000 9.8 7/27/01 12.57 8/8/01 10.59 9/2/01 74.7 1/9/02 8 64 2/21/02 9.14 9.85 7/28/01 11.6 8/8/01 10.54 9/2/01 57.9 1/9/02 8 57 2/21/02 9 32 11.6 7128/01 11.7 8/10/01 10.9 9/2/01 48.8 1/16/02 13 2/21/02 14.6 11.57 7/28/01 11.5 8/10/01 11 9/2/01 149 1/16/02 13 2/23/02 9.13 11.6 7/28/01 11.7 8110101 10.8 9/2/01 129 1/16/02 12 8 2/23/02 11 6.09 7/29/01 12.4 8/10/01 10.8 9/2/01 100.2 1/16/02 12.6 2/23/02 9.5 6.04 7/29101 12.4 8/11/01 10.3 9/2/01 44.4 1/18/02 21.3 2/23/02 14.2 6 01 7/29/01 12.3 8/11/01 10.2 9/2/01 148 1/18/02 21.7 2/24102 51.9 10.02 7/29/01 12.3 8/11101 10.1 9/2/01 128 1/18/02 20.5 2/24102 61.7 10.25 7/30/01 12.8 8/11101 10.3 9/2/01 95 1/18/02 20 9 2/24102 51.2 10.12 7/30/01 12.9 8/12/01 6.44 9/2/01 48 6 1/20/02 22.1 2/24/02 26 8 8.52 7/30/01 12.6 8/12/01 6.61 9/2/01 142 1/20102 15 6 2/27/02 4.48 8.19 7/30/01 12.6 8/12/01 6 51 9/2/01 127 1/20102 20.6 2/27/02 4.18 8.66 7/31/01 12.56 8/12/01 6.5 9/3/01 56.7 1/20102 23.8 2/27/02 3.99 8.75 7/31/01 13.25 8/13/01 9.21 9/3/01 47.4 1/24/02 20.6 2/27/02 4.02 8.83 7/31/01 12.59 8/13/01 9 26 914/01 102 1/24102 18 4 3/6/02 7.57 8.57 7/31/01 12 56 8/13/01 9 04 9/4/01 113 1/24102 17.5 3/6/02 7.57 8.63 8/1/01 12.11 8113/01 9 19 9/4/01 125 1/25/02 17.4 3/6/02 7.6 9.78 8/1/01 12 25 8/25/01 7 07 9/4101 97.7 1/29/02 20 6 3/6/02 8.58 9.86 8/1/01 12.15 8/26/01 7 81 9/5/01 94 8 1/29/02 21.9 3/13/02 7.02 9.71 8/1/01 12.16 8/26/01 7 84 9/5/01 108 1/29102 21.6 3/13/02 7.36 9.74 8/2/01 11.9 8/27/01 7.92 9/5/01 117 1/29/02 20.5 3/13/02 6.86 10.9 8/2/01 12.2 8/27/01 7 86 9/5/01 89 1/31/02 18.7 3/13/02 6.95 11.1 8/2/01 12 8/28/01 7 58 9/7/01 68.6 1/31/02 18.2 3/20/02 5.9 10.9 8/2/01 12 8/28/01 7.45 9/7/01 53.8 1/31/02 18.1 3/20/02 5.65 11 8/3101 13 8/29/01 6.3 9/8/01 52.5 1/31/02 20.78 3/20102 5.53 12.13 8/3/01 13 2 8/29/01 6 22 9/8/01 41 2/2/02 22.3 3/20/02 5.56 C

( I Section II.B.6 Non-routine sample data 00B Ethanolamine (Cook Nuclear Lab) Method 300.0 Date Ethanolamine mg/l Date Ethanolamine mg/l Date Ethanolamine mg/I 3/27/02 8.28 6/5/02 7.11 8/28/02 8 44 3/27/02 8.12 6/5/02 7 29 8/28/02 8.38 3/27/02 8.49 6/5/02 7.54 9/4/02 9 64 3/27/02 8 27 6/12/02 8 29 9/4/02 8 94 4/2/02 9.98 6/12/02 8.66 9/4/02 99 4/2/02 10 6/12/02 8 25 9/4/02 9.74 4/2/02 10 6/12/02 8.29 9/11/02 9 67 4/2/02 10.1 6/19/02 7.1 9/11/02 10 4/3/02 10.2 6/19/02 7.07 9/11/02 9 81 4/3/02 10.3 6/19/02 7.28 9/11/02 9 92 4/3/02 10.4 6/19/02 7.31 9/18/02 7.53 4/3/02 103 7/3/02 2.69 9/18/02 7.89 4/10/02 6.92 7/3/02 2.77 9/18/02 7.68 4/10/02 7.14 7/3/02 2.76 9/18/02 7.62 4/10/02 69 7/3/02 2.75 9/25/02 1234 4/10/02 68 7/10/02 7.18 9/25/02 1242 4/17/02 6 09 7/10/02 7.33 9/25/02 1231 4/17/02 6.22 7/10/02 7.15 9/25/02 12.41 4/17/02 6.18 7/10/02 7.27 10/2/02 8.3 4/17/02 6.15 7/17/02 9.47 10/2/02 83 4/24/02 6.76 7/17/02 9.74 10/2/02 82 4/24/02 7.01 7/17/02 9.12 10/2/02 83 4/24/02 7.14 7/17/02 9 53 10/9/02 9 69 4/24/02 7 07 7/24/02 8 38 10/9/02 9 65 5/1/02 109 7/24/02 8 97 10/9/02 948 5/1/02 11 3 7/24/02 849 10/9/02 9 39 5/1/02 11.1 7/24/02 8 27 10/16/02 1254 5/1/02 11 7/31/02 3 03 10/16/02 1261 5/8/02 643 7/31/02 6 29 10/16/02 13 5/8/02 6.41 7/31/02 8 92 10/16/02 12.3 5/8/02 646 7/31/02 809 10/23/02 139 5/8/02 623 8/7/02 7.71 10/23/02 142 5/15102 <0 500 8/7/02 7.7 10/23/02 14.1 5/15/02 <0 500 8/7/02 7.71 10/23/02 138 5/15/02 <0 500 8/7/02 7.7 10/30/02 133 5/15/02 0500 8/14/02 547 10/30/02 13.2 5/22/02 5 86 8/14/02 61 10/30/02 12.7 5/22/02 6.19 8/14/02 6 15 10/30/02 13 5/22/02 556 8/14/02 647 11/6/02 11.49 5/22/02 565 8/21/02 11 47 11/6/02 11.2 5/29/02 *0.500 8/21/02 11 94 11/6/02 11.67 5/29/02 6.53 8/21/02 11 53 11/6/02 11.2 5/29/02 1 42 8/21/02 11 87 5/29/02 2.59 8/28/02 8.11 Max 149 6/5/02 7.11 8/28/02 8.28 Monthly Avg 66 3 Count 1122

I Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant l M10005827 l 00B 9 WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authonzed by the DEQ under separate correspondence The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application.

A. Are there water treatment additives in the discharge from this facility?

[I No, proceed to item 4 E Yes.

B. Have these water treatment additives been previously approved?

Z No, continue with C below.

[ Yes Submit a list of the previously approved water treatment additives and the date they were approved. The information listed in C. 1-8 must be updated if it has changed since the previous approval C Submit a list of water treatment additives that are or may be discharged from the facility. Applicants must submit the information listed below for each additive.

1. The water treatment additive Matenal Safety Data Sheet

2. The proposed water treatment additive discharge concentration.

3. The discharge frequency (i e , number of hours per day, week, etc)

4. The outfall the water treatment additive is to be discharged from

5. The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6 The water treatment additive function (i e, microbiocide, flocculant, etc.).

7. A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Cenodaphnia sp., Daphnia sp , or Simocephalus sp.)

8. The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323 1057(2)(a) of the Water Quality Standards Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow The required toxicity information (descnbed in items 7 and 8 above) is currently available in the SWQD files for the water treatment additives listed on the DEQ's Internet page http://www.deq.state.mi.us/swqlgleas/docslwtalWTAlist.doc. If you intend to use one of the water treatment additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment addibve.

10 WHOLEEFFLUENTTOXICITYTESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years?

If yes, identify the tests and summarize the results below unless the test has been submitted to the department in the last 5 years NO I

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME l NPDES or COC PERMIT NUMBER Ouffall Number Donald C. Cook Nuclear Plant M10005827 00B 9 WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Ethanolamine solution, such as, 5123/00 NPDES Permit approval 9128/95 Betz Powerline 1440, Betz Powerfine 1480, Nalco 92UM001 Hydrazine Solution, such as, 5/23/00 NPDES Permit approval 9/28/95 Betz Cortrol OS5035, (Formerly Betz Powerline 1205), Betz Cortrol OS5010, Nalco 19H Carbohydrazide Solution such as: 3125/94 application, 4115/94 approval, NPDES Permit approval 9128195.

Nalco 1250 plus, Nalco Eliminox 32 EQP 4659-C (Rev 1/03)

Section III.B Outfall 00C

Michigan Department of Environmental Quality- Surface Water Quality Division DA- WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information section

-omplete a separate Section III.B - Outfall Information (pages 26-31) for each outfall at the facility Make copies of this blank kJ of the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT NPDES PERMIT NUMBER l OUTFALL NUMBER FACILITY NAME I Donald C Cook Nuclear Plant l M10005827 I 00C

1. OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

Watershed A. I. ,-.

I Lower t. J, Receiving Water B

Lake Michigan County C

Bemen

/4, /4 0.

SW Latitude E.

41 58'30' F. Type of Wastewater Discharged (Check all that apply to this outfall)

M Sanitary Wastewater n Groundwater Cleanup E] Storm Water (regulated)

E] Contact Cooling E Process Wastewater a Hydrostatic Pressure Test D1 Storm Water (not regulated)

E] Noncontact Cooling 1l Storm water subject to effluent guidelines (indicate under which category)

El Other - specify (see 'Table 8 - Other Common Types of Wastewater' in appendix)

J What is the maximum Facility Design Flow Rate: 0 043 MGD Seasonal Dischargers MGY Continue with Item H.

G. What is the maximum discharge flow authorized for this outfall:

Continuous Dischargers 0 043 MGD Continue with Item I.

H. Seasonal Discharge List the discharge periods (by month) and the volume discharged in the space provided below Through Discharge Volume Annual Total From From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume

1. Continuous Discharge How often is there a discharge from this outfall (on the average)? 24 Hours/Day 365 Days/Year Batch dischargers must provide the following additional information:

Is there effluent flow equalization? LI Yes [l No Batch Peak Flow Rate Number of batches discharged per day, Minimum Average Maximum Batch Volume (gallons)

I Batch Duration (minutes)

I I

I-I I I

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information nLEASE TYPE OR PRINT ACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER '

Donald C. Cook Nuclear Plant M10005827 00C

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility Page 7 of the appendix contains an abbreviated list of vanous industnes and the types of information each shall report in this application. For assistance call the Permits Section. All industnes shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page ii, item 8.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Plant Heating Boller Blowdown B. SIC or NAICScode 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Plant Heating Boiler Blowdown. 0 043 MGD Maximum flow. 2247 MWE total plant electrical generation.

PROCESS INFORMATION A. Name of the process contributing to the discharge B SIC or NAICS code C. Descnbe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A. Name of the process contnbuting to the discharge:

B SIC or NAICS code:

C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A. Name of the process contributing to the discharge, B. SIC or NAICS code C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

. . )

Division Michigan Department of Environmental Quality- Surface Water Quality WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information ISTRUCTIONS FOR COMPLETING SECTION III,- ITEM B.3.

V.

Oxygen Demand, Total Organic Carbon, Total Suspended In accordance with 40 CFR 122.21, all applicants must report CBOD5, Chemical applicant may, however, request that reporting of data for Solids, Ammonia as N, Temperature (both summer and winter), and pH. The be supported by adequate rationale. The request shall be one or more of these required parameters be waived. Such request must included as an attachment to this application.

provided for existing discharges and expected or estimated Report available discharge data for the parameters listed. Actual data shall be if 'Pollution Prevention" is expected to provide reduction of data provided for proposed discharges Please include an explanation which data must be provided for specific types of discharges pollutants. See Page 8 of the appendix for a list of specific parameters for assistance in determining the appropriate parameters to report, (e.g., noncontact cooling waters, gasoline groundwater cleanups, etc.) For call the Permits Section shall report these data in the blank spaces provided or If data are available for other parameters not listed in Section III.B.3., the applicant attach the information to this application on 81/2" x 1" paper.

If more than one option is available, check the appropriate Report all data in the units provided and for the sample types specified in the table.

per liter, OF = degrees Fahrenheit, "C = degrees Celsius. See box. The units are as follows: Vg/l = micrograms per liter, mg/I = milligrams page ii number 5 for analytical requirements.

coliform use Grab Samples unless other frequency-sample To analyze for pH, temperature, total residual chlonne, oil and grease, and fecal TOC, ammonia nitrogen and total suspended solids use 24-type analyses are available. To analyze for total BODs, total phosphorus, COD, hour composite samples unless other frequency-sample type analyses are available.

the appropriate distnct office to sample and analyze only For two or more substantially identical outfalls, permission may be requested from outfalls. If the request is granted by the district office, on a one outfall and submit the results of the analysis for other substantially identical and descnbe why the outfalls which were not sampled are separate sheet attached to the application form, identify which outfall was sampled and iii for sampling definitions, including 'maximum daily substantially identical to the outfall which was sampled. See pages ii concentration", and "maximum monthly concentration".

REPORTING OF INTAKE DATA to demonstrate eligibility for 'net" effluent limitations for one or Applicants are required to report intake water data when they are attempting average level of the pollutant(s) present in the intake waters more pollutants A 'net" effluent limitation is determined by subtracting the NPDES regulations allow net limitations only in certain remaining after treatment which is not removed by the treatment system.

the average concentration and/or mass of the results of the circumstances (see 40 CFR Part 122.45(g)). To demonstrate eligibility, report the intake concentrations and/or mass after treatment. In analyses on the intake water. If the intake water is treated prior to use, report each parameter:

addition to the analytical results, the following information shall be submitted for the discharge is made. If the discharge is not to the same a) A statement that the intake water is drawn from the body of water into which limitations.

body of water from which the water is withdrawn, the facility is not eligible for net is reduced by treatment of the wastewater. Limitations for b) A statement of the extent to which the level of the pollutant in the intake water not removed.

the net removal of pollutants are adjusted only to the extent that the pollutant is e g , BOD 5, TSS, etc.), a demonstration of the extent c) 'When applicable (for example, when the pollutant represents a class of compounds, from the pollutants contained in the discharge. Limitations to which the pollutants in the intake vary physically, chemically and biologically from the discharged pollutants.

- are adjusted only to the extent that the concentrations of the intake pollutants vary the intake characteristics of contaminated groundwater.

Note: Applicants for groundwater remediation discharges should also report

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

°LEASE TYPE OR {PR{INT ACILITY NAME NPDES PERMIT NUMBER IFALL NUMBER '

Donald C. Cook Nuclear Plant I M10005827 I 0OCC I __ ____ -

3. WASTEWATER CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for completing this page are on the facing page.

l Check this box if additional information is included as an attachment. To submit additional information see page ii, item 8 Maximu11~ aximuml

-Daily-'

y -Monthly, Number of.

,Parameter' Cocnrai *Concentration ^ s Cnits- Analyses Sample Type-Mg/I [l Grab Biochemical Oxygen Demand - five day (BOD5) 4 4 mg/I 2 E 24 Hr Comp El Grab COD (Chemical oxygen demand) 10 10 mgI 2 E 24 Hr Comp TOC (Total organic carbon) mgA 17 Grab 3 3 2 0 24 Hr Comp Ammonia Nitrogen (as N) mg/I 171 Grab 0 08 0 08 2 E 24 Hr Comp mg/I Z Grab Total Suspended Solids 17.8 89 14 El 24 Hr Comp Total Dissolved Solids NA NA NA E] 24 Hr Comp Total Phosphorus (as P) <0.1 <0.1 mg/I 1

El 1

Grab 24 Hr Comp maximum-7day cut/0m Fecal Colifomi Bactena (report geometric means) NA NA countsl10ml NA Grab Z mg/l ital Residual Chlonne <0.08 <0 08 E lig/l 2 Grab minimum daily 10m Grab Dissolved Oxygen 0 mgn 22 El 24 Hr Comp pH minimum maximum s u Grab (report maximum and minimum of individual samples) 78 97 standard units 22 El 24 Hr Comp Temperature, Summer 'NA NA E °F NA 2Grab E°F EOC - Grab Temperature, Winter NA NA NA E 24 Hr Comp Oil & Grease <5 <5 mg/l 1 Grab g3 Grab Hydrazine 0.04 0013 m 22 El 24 Hr Comp mg/l Grab Ethanolamine 16.1 11 3 mgI 20 24 Hr Comp ElGrab El 24 Hr Comp El Grab See Attached for additional Data El 24 Hr Comp El Grab NA - Intemal Outfall El 24 Hr Comp El Grab

_ 24 Hr Comp E Grab El 24 Hr Comp El1 Grab

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ E l 24 H r C &

El Grab

_ _ ___ ___ ___ _ _ _ _ _ _ _ _ _ El 24 Hr Com p

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-'-EASE TYPE OR PRINT NPDES PERMIT NUMBER OUTFALL NUMBER V ACILITY NAME Donald C. Cook Nuclear Plant lMiM0005827 00C

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION analysis for selected organic pollutants Existing primary industries that discharge process wastewater must submit the results of at least one effluent Category), and all the pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial effluent analysis for any other chemical listed in Table identified inTable 3. Existing primary industries must also provide the results of at least one 2 known or believed to be present in facility effluent listed in Tables 2 and 3 In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical for any chemical listed in New primary industnes that propose to discharge process wastewater must provide an estimated effluent concentration Tables 2 and 3 expected to be present In facility effluent.

5 DIOXIN AND FURAN CONGENER INFORMATION propanoic acid, (Silvex, 2,3,5-Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-tnchlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel); 2,4,5-TP); 2-(2,4,5-trichlorophenoxy)

(TCDD) is present in tnchlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin and furan congeners listed in Table 6. All effluent analyses for facility effluent, must submit the results of at least one effluent analysis for the dioxin dioxin and furan congeners must be conducted using EPA Method 1613.

furan congener listed in Table 6 In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and propanoic acid (Silvex, New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-tnchlorophenoxy)

(Erbon), 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel), 2,4,5-2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloroproplonate (TCDD) is present in trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin 6.

facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed in Table R. OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION must submit the results of at least one effluent Existing secondary industries, or existing pnmary industries that discharge non-process wastewater, analysis for any chemical listed in Tables 2 and 3 known or believed to be present infacility effluent listed in Tables 2 and 3 In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical must provide an estimated effluent New secondary industries, or new primary industries that propose to discharge non-process wastewater, concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION listed in Table 4 known or All existing industries, regardless of discharge type, must provide the results of at least one analyses for any chemical listed in Table 5 known or believed to believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical analysis performed within the last 5 years for any chemical listed in be present in facility effluent In addition, submit the results of any effluent Tables 4 and 5 listed in Tables 4 and 5 expected to New industnes, regardless of discharge type, must provide an estimated effluent concentration for any chemical be in facility effluenL 8 INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED concentration for any toxic or otherwise New or existing industries, regardless of discharge type, must provide a measured or estimated effluent in facility effluent that have not been previously identified in this application. Quantitative injurious chemicals known or believed to be present effluent data that are less than 5 years old for these chemicals must be reported

31. To submit additional information NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page The following fields must be see page ii, item 8 If the effluent concentrations are estimated, place an E in the "Analytical Method' column Method, Quantification Level and Detection Level completed for each data row: Parameter, CAS No., Concentration(s), Sample Type, Analytical See page ii, number 5 for analytical test requirements.

Michigan Department of En\ imental Quality- Water Division F- WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME l NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 00C SAMPLE DATE 4 5/30/02 5/30/02 5131/02 611/02 611/02 6/2/02 10/17/02 10/18/002 10/18/02 10/19/02 ,

CAS -Conc.,,, - Conc.' Conc.,-. I Conc., ,-,Conc.. Cone Conc Conc. conc Conc, _Sample, 'Analytic, PARAIVETEF~I%;I,- `-2 NugI). (u(uh)i/gl)

J '(gI)---(uh) (ug/I) ~(ug/I),7 [<u/)&4~L ' ~Type :all 7,I `____L_

Hyrazine 7803578 12 15.3 13 5.1 87 40 <2.0 8 63 <3.0 Grab D1385 3 10 Ethanolamine 141435 700 600 600 <500 4000 3900 2200 13100 16100 13600 Grab 800 300 See Attached for additional data.

c ( O EQP 4( - -C (Rev 1/03)

( C C Additional Sample Data O0C Section III.B.6 and 7 Summary Sheet For Outfall 00C Sample Analytical Max o 2/1199 5/14/01 type Max Daily Method monthly Analyses Parameter Table -7 See Attached data set from Belmonte Park Laboratories.'

2 <1 Grab 2 204.2/200.7 2 2 Antimony (ug/)

<1 <1 Grab <1 206 2/200.7 <1 2 Arsenic (ug/l)

<1 <0 2 Grab <1 200.7 <1 2 Beryllium (ug/l)

<0 2 <0 2 Grab <0.2 213.2/200.7 <0 2 2 Cadmium (ug/l)

<10 <2 Grab <10 200.7 <10 2 Chromium (ug/l) 12 10 Grab 12 220.2/200.7 12 2 Copper (ug/l)

<1 <1 Grab <1 239.2/200.7 <1 2 Lead (ug/l)

<5 <3 Grab <5 249 2/200 7 <5 2 Nickel (ug/l)

<10 - Grab <10 420 1 <10 1 Total Phenols (ug/l) 2 Grab 2 270 3 21 Selenium (ug/l) -

<0.5 <0 2 Grab <0.5 272.2/200 7 <0.5 2 Silver(ug/l)

<1 <1 Grab <1 279 2 <1 2 Thallium -(ug/l)

- <4 Grab <4 200 7 <20 1 Zinc (ug/l)

<0 01 0.01 Grab 0 01 335 2 0.01 2 Cyanide (mg/l)

<0 5 Grab <0 5 1631 <0.5 1 Mercury (ng/l) -

<0 05 <0 08 Grab <0 08 330 5 <0 08 2 Chlonne, total residual (mg/l) 113 Composite 113 375 4 113 2 Sulfate (mg/l)

Additional Data From Belmonte Park Laboratories Is attached.

Additional Data From Belmonte Park Laboratories Is attached.

See Attached data set From Cook Nuclear Plant Laboratory.

OOC data NPDES Application Section III.B.6&7 Table 5 data for Outfall OOC l

Analyzed by Cook Plant Lab.

Ethanolamine Hydrazine Date mg/L ug/L 8/30/01 9/19/01 = -

10/1/01 12/14/01 =

12/15/01 12/18/01 5/13/02 1 31 =

5/14102 2.1 <3 0 5/15/02 2 3 14.1 5/16/02 1.9 <3 0 5/16/02 5/16/02 5/25/02 5/26/02 06 14.5 5/27/02 06 6.3 5/27/02 11.3 5/28/02 < 0.5 8 5 5/28/02 <05 74 5/28/02 5/28/02 06 138 =

5/29/02 09 13 9 5/30/02 06 15 3 5/30/02 07 12 5/31/02 0 6 13 5/31/021 12.4 _

6/1/02 < 0.5 5.1 6/1/02 4 8.7 _

6/2/02 3 9 40 -

6/2/02 10/17/02 2 2 <2 0 10/18/02 13 1 8 10/18/02 161 6 3 10/19/02 =

10/19/02 136 <30 Max 161 40 Max Monthly 11 3 13 Count 20 22 Min - -

Page 1

Belmonte Park K) Environrmetal Laboratories Order #: 99-02-060 AMERICAN ELECTRIC POWER (AEP) 1 COOK PLACE Date: 03/16/99 09:22 BRIDGMAN, MICHIGAN 49106 Work ID: OUTFALL 001 - O0C Date Received: 02102/99 Attn: BLAIR ZORDELL Date Completed: 03/16/99 Purchase Order: 4307976 Client Code: AEP_4 Invoice Number:

ND= NONE DETECTED OHIO CERT.# 12345 SAMPLE IDENTIFICATION Sample Sample Sample Sample Number Description Number Description 02/01/99 24 OUTFALL 00G 02/01/ 99 01 OUTFALL 001 02/01/99 25 OUTFALL 00G 02/01/99 02 OUTFALL 001 02/01/99 26 OUTFALL COG 02/01/99 03 OUTFALL 001 02/01/99 27 OUTFALL 0OG 02/01/99 OUTFALL 001 02/01/99 28 OUTFALL OCG 02/01/99 05 OUTFALL 001 02/01/99 29 OUTFALL COG 02/01/99 06 OUTFALL 001 02/01/99 30 OUTFALL 0OG 02/01/99 07 OUTFALL 001 02/01/99 31 OUTFALL O0C 02/01/99 08 OUTFALL 001 02/01/99 32 OUTFALL OOC 02/01/99 09 OUTFALL 001 02/01/99 02/01/99 33 OUTFALL O0C 10 OUTFALL 001 02/01/99 34 OUTFALL OOC 02/01/99 11 OUTFALL 001 02/01/99 35 OUTFALL OOC 02/01/99 12 OUTFALL 001 02/01/99 02/01/99 36 OUTFALL O0C 13 OUTFALL 001 02/01/99 37 OUTFALL OOC 02/01/99 14 OUTFALL 001 02/01/99 02/01/99 38 OUTFALL OOC 15 OUTFALL 001 02/01/99 39 OUTFALL OOC 02/01/99 16 OUTFALL OOG 02/01/99 40 OUTFALL O0C 02/01/99 17 OUTFALL COG 02/01/99 02/01/99 41 OUTFALL OOC 18 OUTFALL OOG 02/01/99 02/01/99 42 OUTFALL O0C 19 OUTFALL COG 02/01/99 02/01/99 43 OUTFALL OOC 20 OUTFALL 00G 02/01/99 02/01/99 44 OUTFALL OOC 21 OUTFALL COG 02/01/99 45 OUTFALL OOC 02/01/99 22 OUTFALL COG 02/01/99 23 OUTFALL OOG Committed to Quality Since 1958

- Dayton, Ohio 45426 (937) 837-3744 I11 East Main Street

Belmonte Park Environmental Laboratories Order # 99-02-060 Page 2 03/16/99 09:22 Enclosed are results of specified samples submitted for analyses. If there are any questions, please contact Matt Lake. Our Ohio EPA Certification numbers are 836 & 837.

Any result of "BDL" indicates "BELOW DETECTION LIMIT".

922 Certified By MATT LAKE Ii, Committed to Quality Since 1958 11 East Main Street Dayton. Ohio 45426 - (937) 837-3744 -

Belmonte Park

1. < Environmental.

)

1A Laboratories Page 3 Order # 99-02-060 TEST RESULTS BY SAMPLE 03/16/99 09:22 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 01A OUTFALL 001 Detection Limit Units Analyzed BY Test Description Result 2 mg/L 02/08/ 99 PT EPA 405.1 3 5day CBOD, 5 mg/L 02/11/99 KC BDL SUSPENDED SOLIDS,EPA 160.2 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 02A OUTFALL 001 Detection Limit Units Analyzed BY Result Test Description mg/L 02/19/99 LG 6 5 COD, EPA 410.4 mg/L 02/09/99 Jw 4.5 1 TOC, EPA 415.1 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 03A OUTFALL 001 Detection Units Analyzed BY Result Limit Test Description 0.5 mg/L 02/11/99 JB EPA 350.2 BDL AMMONIA N, 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 05A OUTFALL 001 Detection Units Analyzed BY Result Limit Test Description - SD EPA 625 SEMI VOL. EXTRACT - SD EXTRACTION, EPA 608 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 06A OUTFALL 001 Detection Units Analyzed By Result Limit Test Description mg/L 02/12/99 RJE 0.05 0.05 ALUMINUM, EPA 200.7 mg/L 03/05/99 RJE BDL 0.001 ANTIMONY, EPA 204.2 mg/L 03/05/99 RJE BDL 0.001 ARSENIC, EPA 206.2 mg/L 02/11/99 RJE 0.021 0.005 BARIUM, EPA 200.7 mg/L 02/11/99 RJE BDL 0.001 BERYLLIUM, EPA 200.7 mg/L 02/12/99 RJE 0.07 0.05 BORON, EPA 200.7 mg/L 03/08/99 RJE BDL 0.0002 CADMIUM, EPA 213.2 mg/L 02/11/99 RJE BDL 0.01 CHROMIUM, EPA 200.7 mg/L 02/11/99 RJE BDL -- 0.01 COBALT, EPA 200.7 mg/L 03/08/99 RJE BDL 0 .001 COPPER, EPA 220.2 mg/L 02/11/99 RJE BDL 0.1 IRON, EPA 200.7 mg/L 03/05/99 RJE BDL 0 .001 LEAD, EPA 239.2 mg/L' 02/12/99 RJE 0.01 0 .01 LITHIUM, EPA 200.7 Committed to Quality Since 1958 (937) 837-3744 Dayton, Ohio 45426 11 East Main Street

Belmonte Park Environmental a) Laboratories Order # 99-02-060 Page 4 03/16/99 09:22 TEST RESULTS BY SAMPLE Detection Test Description Result Limit Units Analyzed BRt MAGNESIUM, EPA 200.7 11 1 mg/L 02/12/99 RJE MANGANESE, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE MERCURY, EPA 245.1 BDL 0.0002 mg/L 02/11/99 RJE METALS DIGESTION, WATER EP MOLYBDENUM, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE NICKEL, EPA 249.2 BDL 0.005 mg/L 03/0 8/9 9 RJE SELENIUM, EPA 200.7 BDL 0.1 mg/L 02/11/99 RJE SILVER, EPA 272.2 BDL 0.0005 mg/L 03/08/99 RJE STRONTIUM, EPA 200.7 0.12 0 .01 mg/L 02/12/99 RJE THALLIUM, EPA 279.2 BDL 0 .001 mg/L 03/05/99 RJE URANIUM EPA 200.7 BDL 0.1 mg/L 02/15/99 RJE ZINC, EPA 200.7 BDL 0.02 mg/L 02/11/99 RJE Sample: 07A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By SULFIDE, EPA 376.1 BDL 1 mg/L 03/05/99 LG TOTAL CYANIDE, EPA 335.2 BDL 0.01 mg/L 03/04/99 LG Sample: 08A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection

-- OC X Result Limit Units Analyzed PHENOLICS, EPA 420.1 BDL 0.01 mg/L 02/23/99 JB Sample: 09A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By CHLORINE, RESIDUAL TOTAL BDL 0.05 mg/L 02/03/99 ML Sample: 10A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY NITRATE-NITRITE N 0.38 0.2 mg/L 02/05/99 LG ORGANIC NITROGEN BDL 0.5 mg/L 02/11/99 JB PHOSPHORUS, EPA 365.1 0.37 0.1 mg/L 02/18/99 LG TKN, EPA 351.3 BDL 0.5 mg/L 02/06/99 JB

'\ J Committed to Quality Since 1958 11 East Main Street 1 E Dayton, Ohio 45426 (937) 837-3744

Belmonte Park u ^Environmental

- = Laboratories Page 5 Order # 99-02-060 TEST RESULTS BY SAMPLE 03/16/99 09:22 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 11A OUTFALL 001 Detection Units Analyzed By Result Limit Test Description 5 mg/L 02/10/99 PT EPA 413.1 BDL OIL & GREASE, 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 12A OUTFALL 001 Detection Limit Units Analyzed BV Result 3 Test Description pCi/L 03/08/99 SF IN WATER BDL GROSS ALPHA, 4 pCi/L 03/08/99 SF IN WATER BDL GROSS BETA, 1 pCi/L 03/10/99 SF IN WATER BDL RADIUM, 1 pCi/L 03/10/99 SF IN WATER BDL RADIUM-226, Collected: 02/01/99 Category: AQUEOUS Sample: 13A OUTFALL 001 02/01/99 Detection Units Analyzed BM Result Limit Test Description 0.01 mg/L 02/17/99 ML BDL METHYLENE BLUE ACTIVE SUB. 10 mg/L 02/18/99 JB EPA 375.4 BDL SULFATE, 2 mg/L 02/17/99 ML BDL SULFITE, 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 14A OUTFALL 001 Detection Units Analyzed BE Result Limit Test Description 0.2 MF/L, >lOum 02/12/99 EM ND ASBESTOS WATER 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 16A OUTFALL 00G Detection Limit Units Analyzed BYr Result PT Test Description 2 mg/L 02/08/99 EPA 405.1 4 5day CBOD, mg/L 02/11/99 KC BDL 5 SUSPENDED SOLIDS,EPA 160.2 Collected:-02/01/99 Category: AQUEOUS OUTFALL OOG 02/01/99 Sample: 17A Detection Units - Analyzed BY Result Limit -

Test Description mg/L 02/19/99 LG BDL 5 mg/ L COD, EPA 410.4 02/09/99 JW 2.1 1-TOC, EPA 415.1 Committed to Quality Since 1958 (937) 837-3744I

- Dayton, Ohio 45426 11 East Main Street

Belmonte Park Environmental 11Laboratories Order # 99-02-060 Page 6 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 18A OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY AMMONIA N, EPA 350.2 BDL 0.5 mg/L 02/11/99 JB Sample: 20A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed PLY EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 SD Sample: 21A *OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By ALUMINUM, EPA 200.7 BDL 0.05 mg/L 02/12/99 R3~'

ANTIMONY, EPA 204.2 BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 206.2 BDL 0.001 mg/L 03/05/99 RJE BARIUM, EPA 200.7 0.022 0.005 mg/L 02/11/99 RJE BERYLLIUM, EPA 200.7 BDL 0.001 mg/L 02/11/99 RJE BORON, EPA 200.7 0.06 0.05 mg/L 02/12/99 RJE CADMIUM, EPA 213.2 BDL 0.0002 mg/L 03/0 8/99 RJE CHROMIUM, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE COBALT, EPA 200.7 BDL 0 .01 mg/L 02/11/99 RJE COPPER, EPA 220.2 BDL 0 .001 mg/L 03/08/99 RJE IRON, EPA 200.7 BDL 0.1 mg/L 02/11/99 RJE LEAD, EPA 239.2 BDL 0.001 mg/L 03/05/99 RJE LITHIUM, EPA 200.7 BDL 0.01 mg/L 02/12/99 RJE MAGNESIUM, EPA 200.7 12 1 mg/L 02/12/99 RJE MANGANESE, EPA 200.7 BDL 0 .01 mg/L 02/11/99 RJE MERCURY, EPA 245.1 BDL 0.0002 mg/L 02/11/99 RJE METALS DIGESTION, WATER EP MOLYBDENUM, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE NICKEL, EPA 249.2 BDL 0.005 mg/L 03/08/99 RJE SELENIUM, EPA 200.7 BDL 0.1 mg/L 02/11/99 RJE SILVER, EPA 272.2 BDL 0.0005 mg/L 03/08/99 RJE STRONTIUM, EPA 200.7 0.14 0.01 mg/L 02/12/99 RJE THALLIUM, EPA 279.2 BDL 0.001 mg/L 03/05/99 RJE URANIUM EPA 200.7 BDL 0.1 mg/L 02/15/99 RJE ZINC, EPA 200.7 BDL 0.02 mg/L 02/11/ 99 RJE Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

A a a Belmonte Park Environmental Laboratores Page 7 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 22A Detection Result Limit Units Analyzed BY Test Description BDL 1 mg/L 03/05/99 LG SULFIDE, EPA 376.1 BDL 0.01 mg/L 03/15/99 LG

' TOTAL CYANIDE, EPA 335.2 OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 23A Detection Result Limit Units Analyzed BY Test Description BDL 0.01 mg/L 02/23/99 JB PHENOLICS, EPA 420.1 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 24A OUTFALL OOG Detection Result Limit Units Analyzed By Test Description BDL 0.05 mg/L 02/03/99 ML CHLORINE, RESIDUAL TOTAL 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 25A OUTFALL OOG Detection Limit Units Analyzed Bar Test Description Result 0.50 0.2 mg/L 02/05/99 LG NITRATE-NITRITE N JB BDL 0.5 mg/L 02/11/99 ORGANIC NITROGEN LG BDL 0.1 mg/L 02/18/99 PHOSPHORUS, EPA 365.1 BDL 0.5 mg/L 02/06/99 JB TKN, EPA 351.3 OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 26A Detection Result Limit Units Analyzed BY Test Description PT BDL 5 mg/L 02/10/99 OIL & GREASE, EPA 413.1 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 27A OUTFALL OOG Detection Limit Units Analyzed fix Test Description Result 3 pCi/L 03/08/99 SF GROSS ALPHA, IN WATER BDL 4 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL BDL 1 pCi/L 03 / 10 / 99 SF RADIUM, IN WATER 1 pCi/L 03/10/99 SF RADIUM-226, IN WATER BDL Committed to Quality Since 1958

- - Sic/95 Dayton, Ohio 45426 I (937) 837-3744 11 East Main Street

I Belmonte Park I . By Environmental Laboratories Order # 99-02-060 Page 8 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 28A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By METHYLENE BLUE ACTIVE SUB. BDL 0.01 mg/L 02/17/99 ML SULFATE, EPA 375.4 113 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 29A OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed f3x ASBESTOS WATER ND 0.2 MF/L, >lOum 02/12/99 EM Sample: 31A OUTFALL OOC 02/01/99 Collected: 02/01/909 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BLY Sday CBOD, EPA 405.1 4 2 mg/L 02/08/99 PT SUSPENDED SOLIDS,EPA 160.2 BDL 5 mg/L 02/11/99 KC Sample: 32A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Blx COD, EPA 410.4 BDL 5 mg/L 02/19/99 LG TOC, EPA 415.1 BDL 1 mg/L 02/09/99 JW Sample: 33A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Bv AMMONIA N, EPA 350.2 BDL 0.5 mg/L 02/11/99 Sample: 35A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed PLY EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 SD Committed to Quality Since 1958 I - A11 East Main Street  ; Dayton, Ohio 45426 (937) 837-3744

Belmonte Park Ki ^ Environmental

) = Laboratories Page 9 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE OUTFALL 00C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 36A Detection Result Limit Units Analyzed Bv Test Description BDL 0.05 mg/L 02/12/99 RJE ALUMINUM, EPA 200.7 204.2 0.002 0.001 mg/L 03/05/99 RJE ANTIMONY, EPA 206.2 BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 200.7 BDL 0.005 mg/L 02/11/99 RJE BARIUM, EPA BDL 0.001 mg/L 02/11/99 RJE BERYLLIUM, EPA 200.7 200.7 BDL 0.05 mg/L 02/12/99 RJE BORON, EPA 213.2 BDL 0.0002 mg/L 03/08/99 RJE CADMIUM, EPA 200.7 BDL 0 .01 mg/L 02/11/99 RJE CHROMIUM, EPA BDL 0 .01 mg/L 02/11/99 RJE COBALT, EPA 200.7 0.012 0.001 mg/L 03/08/99 RJE COPPER, EPA 220.2 BDL 0.1 mg/L 02/11/99 RJE IRON, EPA 200.7 BDL 0.001 mg/L 03/05/99 RJE LEAD, EPA 239.2 BDL 0 .01 mg/L 02/12/99 RJE

-k LITHIUM, EPA 200.7 BDL 1 mg/L 02/12/99 RJE MAGNESIUM, EPA 200.7 0 .01 0.01 mg/L 02/11/99 RJE MANGANESE, EPA 200.7 BDL 0.0002 mg/L 02/11/99 RJE MERCURY, EPA 245.1 EP METALS DIGESTION, WATER mg/L BDL 0.01 02/11/99 RJE MOLYBDENUM, EPA 200.7 mg/L BDL 0.005 03/08/99 RJE NICKEL, EPA 249.2 mg/L BDL 0.1 02/11/99 RJE SELENIUM, EPA 200.7 mg/L BDL 0.0005 03/08/99 RJE SILVER, EPA 272.2 mg/L BDL 0 .01 02/12/99 RJE STRONTIUM, EPA 200.7 mg/L BDL 0 .001 03/05/99 RJE THALLIUM, EPA 279.2 mg/L BDL 0.1 02/15/99 RJE URANIUM EPA 200.7 mg/L BDL 0.02 02/11/99 RJE ZINC, EPA 200.7 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 37A OUTFALL OOC Detection Result Limit Units Analyzed PL Test Description BDL 1 mg/L 03/05/99 LG SULFIDE, EPA 376.1 EPA 335.2 BDL 0 .01 mg/L 03/04/99 LG TOTAL CYANIDE, OUTFALL 00C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 38A Detection Result Limit Units Analyzed BV Test Description BDL 0.01 mg/L 02/23/99 JB PHENOLICS, EPA 420.1 Committed to Quality Since 1958 Dayton, Ohio 45426, (937) 837-3744 11 East Main Street

I Belmonte Park Environmental Laboratories Order # 99-02-060 Page 10 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 39A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed CHLORINE, RESIDUAL TOTAL BDL 0.05 mg/L 02/03/99 ML Sample: 40A OUTFALL 00C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By NITRATE-NITRITE N BDL 0.2 mg/L 02/05/99 LG ORGANIC NITROGEN BDL 0.5 mg/L 02/11/99 JB PHOSPHORUS, EPA 365.1 BDL 0.1 mg/L 02/18/99 LG TKN, EPA 351.3 BDL 0.5 mg/L 02/06/99 JB Sample: 41A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By OIL & GREASE, EPA 413.1 BDL 5 mg/L 02/10/99 PT Sample: 42A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY GROSS ALPHA, IN WATER BDL 3 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 4 pCi/L 03/08/99 SF RADIUM, IN WATER BDL 1 pCi/L 03/10/99 SF RADIUM-226, IN WATER BDL 1 pCi/L 03/10/99 SF Sample: 43A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection .

Test Description Result Limit Units Analyzed METHYLENE BLUE ACTIVE SUB. BDL 0.01 mg/L 02/17/99 ML SULFATE, EPA 375.4 BDL 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 44A OUTFALL O0C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By-ASBESTOS WATER ND 0.2 MF/L, >10um 02/12/98 Eta Committed to Quality Since 1958 I11 East Main Street Dayton, Ohio 45426 (937? 837-3744

4 nBelmonte Park

. = ^ Environmental Laboratories Page 11 order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE 02/01/99 Lab No: 04A Sample

Description:

OUTFALL 001 Method: 624 Test Code: 624 X Test

Description:

EPA 624 Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT BDL 20 ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 2 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,l-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 10 CHLOROETHANE BDL 2 CHLOROFORM BDL 2 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 10 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 2 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRIcHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 10 VINYL CHLORIDE BDL 10 XYLENES SURROGATE %RECOVERY LIMITS 112 76 - 114 D4-1,2 DICHLOROETHANE 88 - 110 -

KJ. D8-TOLUENE 94 -

Committed to Quallty Since 1958 (937) 837-3744 -

11 East Main Street Dayton, Ohio 45426

Belmonte Park hi~ =^Environmental Laboratories Order # 99-02-060 z Page 12 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 04A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/01/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 96 86 - 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020934 UNITS uq/L METHOD EPA 624 BDL BELOW DETECTION LIMIT 9

Committed to Quality Since 1958 11- East Main Street Dayton, Ohio 45426 (937) 837-3744

Belmonte Park B Environmental Laboratories Page 13 Order # 99-02-060 03/16/99 09:22 =ST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A WOLATILES Method: 625 Test Code: 625 AE Test

Description:

EPA 625 SEMI 02/01/99 Category: AQUEOUS Collected:

PARAMETER RESULT LIMIT BDL 10 2,4,6-TRICHLOROPHEDL BDL 10 4 -CHLORO-3 -METHYLPEENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENCL BDL 10 2,4-DIMETHYLPHENOI BDL 10 2-NITROPHENOL BDL 50 4-NITROPHENOL 2,4-DINITROPHENOL BDL so BDL 50 2-METHYL-4 ,6-DINIIROPHENOL BDL 50 PENTACHLOROPHENOL BDL 10 PHENOL J. ACENAPHTHENE BDL 10 BDL so BENZIDENE BDL 10 1,2,4-TRICHLOROB ZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS (2 -CHLOROETHYTUETHER BDL 10 2-CHLORONAPHTHALM BDL 10 1,2-DICHLOROBENZEIE BDL 10 1,3-DICHLOROBENZEZE BDL 10 1,4 -DICHLOROBENZEIB BDL 20 3,3 -DICHLOROBENZIINE BDL 10 2,4-DINITROTOLUE53 10 BDL 10 2,6-DINITROTOLUES FLUORANTHENE BDL 10 4-CHLOROPHENYL PESNYL ETHER BDL 10 4-BROMOPHENYL PBMYL ETHER BDL 10 BDL 10 BIS(2-CHLOROISOPEZPYL) ETHER BIS(2-CHLOROETHOXfl METHANE BDL 10 HEXACHLOROBUTADIEE BDL 10 HEXACHLOROCYCLOPESADIENE BDL 10 BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE

-BDL 10 N-NITROSODIMETHYIMINE BDL 10 N-NITROSODIPHENYIMINE BDL 10 N-NITROSODI-N-PRCMIAMINE t ',#, BIS (2 -ETHYLHEXYL)MITHALATE BDL Cornnitted to Quality Since 1958 layton, Ohio 45426 (937) 837-3744,

- 11 East Main Street

Belmonte Park j F Environmental Laboratores Order # 99-02-060 Page 14 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/01/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANTHRENE BDL 10 DIBENZO(A,H)ANTHRACENE BDL 50 INDENO(1,2,3-CD)PYRENE BDL 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-d5 85 35 - 114 2-FLUOROBIPHENYL 72 43 - 116 p-TERPHENYL-d14 95 33 - 141 PHENOL-d6 46 10 - 94 2 FLUOROPHENOL 74 21 - 100 2,4,6-TRIBROMOPHENOL 50 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022524 UNITS ua/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958

-_ I- 11 East Main Street Dayton, OhEo 45426 (937) 837-3744

Belmonte Park "j Environmental

- Laboratories Page 15 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE 02/01/99 Lab No: 05A Sample

Description:

OUTFALL 001 Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES EPA 608 Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT BDL 0 . 010 ALDRIN BDL 0 . 010 ALPHA-BHC BDL 0. 010 BETA-BHC BDL 0 . 010 DELTA-BHC BDL 0. 010 GAMMA-BHC BDL 0. 010 CHLORDANE BDL 0 .010 4,4-DDT BDL 0 . 010 4,4-DDE BDL 0 .010 4,4-DDD BDL 0. 010 DIELDRIN BDL 0 .010 ALPHA ENDOSULFAN BDL 0 . 010 BETA ENDOSULFAN BDL 0.10 ENDOSULFAN SULFATE BDL 0 .010 ENDRIN BDL 0 .020 ENDRIN ALDEHYDE BDL 0.030 HEPTACHLOR BDL 0 .10 HEPTACHLOR EPOXIDE BDL 0 .10 PCB-1016 BDL 0.20 PCB-1221 BDL 0 .10 PCB-1232 BDL 0.10 PCB-1242 BDL 0 .10 PCB-1248 BDL 0.10 PCB-1254 BDL 0 .10 PCB-1260 BDL 0.20 TOXAPHENE SURROGATE WRECOVERY LIMITS 90' 70 - 130 DBC(SURROGATE,  % RECOVERY) 93 70 - 130 2,4,5,6-TCX(SURROGATE % REC.)

Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020913 KJ, UNITS ug/L Committed to Quality Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

I Belmonte Park

'SEnvironmental Laboratories Order # 99-02-060 Page 16 03/16/99 09

22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT J

IIJ Committed to Quality Since 1958 I11 East Main Street ESDayton, Ohio 45426 (937) 837-3744

Belmonte Park V_1^Environmental

-J - Laboratories Page 17 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 15A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT BDL 5 TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER SURROGATE 9RECOVERY LIMITS 65 35 - 114 NITROBENZENE-D5 78 43 - 116 2-FLUOROBIPHENYL p-TERPHENYL-d14 113 33 - 141 25 10 - 94 PHENOL-d6 30 21 - 100 2-FLUOROPHENOL 93 10 - 123 2,4,6-TRIBROMOPHENOL Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206501W UNITS ua/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 1lEast Main Street

Belmonte Park Environmental J- Laboratores Order # 99-02-060 Page 18 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00G 02/01/99 Lab No: 19A Test

Description:

EPA 624 Method: 624 Test Code: 624_X Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2 CHLOROETHANE BDL 10 CHLOROFORM BDL 2 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 2 VINYL CHLORIDE BDL 10 XYLENES BDL 10 SURROGATE %RECOVERY LIMITS D4-1,2 DICHLOROETHANE 113 76 - 114 D8-TOLUENE 92 88 - 110 Committed to Quality Since 1958 E st Mn r,I I1I1 East Main Street ,Dayton, Ohio 45426 (937) 837-3744

f , Belmonte Park Environmental Laboratores Page 19 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE 02/01/99 Lab No: 19A Sample

Description:

OUTFALL OOG 624_X Method: 624 Test Code:

Test

Description:

EPA 624 Collected: 02/01/99 Category: AQUEOUS 93 86 - 115 4-BROMOFLUOROBENZENE Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020935 UNITS ui/L METHOD EPA 624 BDL BELOW DETECTION LIMIT V01 Committed to Quality Since 1958 Dayton, Ohio 45426 - (937) 837-3744 11 East Main Street

Belmonte Park 1 EnvErironmental Laboratories Order # 99-02-060 Paga 20 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AB Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 50 PHENOL BDL 10 ACENAPHTHENE BDL 10 BENZIDENE BDL so 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL- 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE BDL 10

- Committed to Quality Since 1958 11 Pnst Momn Street Davton, Ohio 45426 (937) 837-3744

Belmonte Park

\ 3 E nvirorirnn l Laboratores Page 21 Order # 99-02-060 03/16/99 09:22 'EST RESULTS BY SAMPLE 02/01/99 Lab No: 20A Sample

Description:

OUTFALL OOG Test Code: 625_AE Method: 625 Test

Description:

EPA 625 SEMI 1OLATILES Category: AQUEOUS Collected: 02/01/99 BDL 10 BUTYL BENZYLPHTHAJTE BDL 10 DI-N-BUTYL PHTHALME BDL 10 DI-N-OCTYL PHTHAI=

BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATI BDL 10 BENZO (A) ANTHRACEN3 BDL 10 BENZO(A)PYRENE BDL 10 3,4 -BENZOFLUORANEENE BDL 10 BENZO (K) FLUORANTE3E BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE -

BDL 50 BENZO (GHI) PERYLE3&

BDL 10 FLUORENE BDL 10 PHENANTHRENE BDL 50 DIBENZO(A,H)ANTHE=DNE BDL 50 INDENO(1,2,3-CD) RENE BDL 10 PYRENE BDL 100 ETHANOL AMINE BDL 200 HYDRAZINE SURROGA7l %RECOVERY LIMITS 35 - 114 NITROBENZENE-M 64 65 43 - 116 2-FLUOROBIPHEML 77 33 - 141 p-TERPHENYL-4 94

- PHENOL45 35 10 -

33 21 - 100 2-FLUOROPHENEL 65 10 - 123 2,4,6-TRIBROMOPHEML Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022525 UNITS u2/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Li_ -l Corritted to Quality Since 1958

- (937) 837-3744 -

,1-1 East Main Street ..- £myton, Ohio 45426 -

Belmonte Park Environmental Laboratories Order # 99-02-060 z Page 22 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00G 02/01/99 Lab No: 20A Test

Description:

PCB/PZSTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ALDRIN BDL 0 .010 ALPHA-BHC BDL 0 . 010 BETA-BHC BDL 0 . 010 DELTA-BHC BDL 0 . 010 GAMMA-BHC BDL 0 .010 CHLORDANE BDL 0 . 010 4,4-DDT BDL 0 .010 4,4-DDE BDL 0 .010 4,4-DDD BDL 0 .010 DIELDRIN BDL 0 .010 ALPHA ENDOSULFAN BDL G.010 BETA ENDOSULFAN BDL 0 . 010 ENDOSULFAN SULFATE BDL 0 .10 ENDRIN BDL 0 .010 ENDRIN ALDEHYDE BDL 0.020 HEPTACHLOR BDL 0 .030 HEPTACHLOR EPOXIDE BDL 0 .10 PCB-1016 BDL 0 .10 PCB-1221 BDL 0.20 PCB-1232 BDL 0.10 PCB-1242 BDL 0.10 PCB-1248 BDL 0.10 PCB-1254 BDL 0.10 PCB-1260 BDL 0 .10 TOXAPHENE BDL 0 .20 SURROGATE %RECOVERY LIMITS DBC(SURROGATE, U RECOVERY) 89 70 - 130 2,4,5,6-TCX(SURROGATE % REC.) 94 70 - 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020914 UNITS uq/L Committed to Quality Since 1958 11 East Main Street Dayton,aOhio 45426 (937) 837-3744

Belmonte Park Environmental

- Laboratores Page 23 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00G 02/01/99 Lab No: 20A EPA 608 Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES Collected: 02/01/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT

--/ 14 Committed to Quality Since 1958

' Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

Belmonte Park 4j =

Environmental Laboratories Order # 99-02-060 Page 24 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 30A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER BDL 5 SURROGATE RECOVERY LIMITS NITROBENZENE-DS 60 35 - 114 2-FLUOROBIPHENYL 78 43 - 116 p-TERPHENYL-dl4 115 33 - 141 PHENOL-d6 28 10 - 94 2-FLUOROPHENOL 35 21 - 100 2,4,6-TRIBROMOPHENOL 85 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206504W UNITS uq/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 1 1 Frict hMrirn 1trimst Davton. Ohio 45426 (937)837-3744

Belmonte Park B.J

. Environmental Laboratories O #Page 25 0

order 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE 02/01/99 Lab No: 34A Sample

Description:

OUTFALL OOC Method: 624 Test Code: 624_X Test

Description:

EPA 624 Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT BDL 20 ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 2 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 10 CHLOROETHANE BDL 2 CHLOROFORM BDL 2 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 10 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 2 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE 2 BDL TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 10 VINYL CHLORIDE BDL 10 XYLENES SURROGATE %RECOVERY LIMITS 114 76 - 114 D4-1,2 DICHLOROETHANE

- D8-TOLUENE 94 88 - 110 j --

Committed to Quality Since 1958 Dayton, Ohto 45426 (937) 837-3744 .

11 East Main Street

I B Belmonte Park Ad Environmental Laboratories Order # 99-02-060 Page 26 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL O0C 02/01/99 Lab No: 34A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/01/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 93 86 - 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020936 UNTTS uatL METHOD EPA 624 BDL BELOW DETECTION LIMIT 9

ICommitted to Quality Since 1958 11 East Main Street Dayton, OhEo 45426a7 (937) 837-3744

Belmonte Park K ., Environmental

% ' = Laboratories Order # 99-02-060 Page 27 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 50 PHENOL BDL 10 ACENAPHTHENE BDL 10 BENZIDENE BDL 50 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHAIENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 BDL 10 N-NITROSODIPHENYLAMINE N-NITROSODI-N-PROPYLAMINE BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE BDL 10 Committed to Quailiy Since 1958

-Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

Belmonte Park

. = Environmental

> 1) Laboratories Order # 99-02-060 z Page 28 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00C 02/01/99 Lab No: 35A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/01/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANTHRENE BDL 10 DIBENZO(A,H)ANTHRACENE BDL so INIENO(1,2,3-CD)PYRENE BDL 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-dS 77 35 - 114 2-FLUOROBIPHENYL 66 43 - 116 p-TERPHENYL-d14 82 33 141 PHENOL-d6 62 10 - 94 2-FLUOROPHENOL 71 21 - 100 2,4,6-TRIBROMOPHENOL 66 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022526 UNITS uq/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Qualilty Since 1958 11 East Main Street Dayton, Ohioae-45426E - -

I-(937) 837-3744

C i Belmonte Park j EnxLvirories Laboratories 11 Page 29 Order # 99-02-060 TEST RESULTS BY SAMPLE 03/16/99 09:22 02/01/99 Lab No: 35A Sample

Description:

OUTFALL OOC Test Code: 608 608 Method: 608 Test

Description:

PCB/PESTICIDES EPA Category: AQUEOUS Collected: 02/01/99 RESULT LIMIT PARAMETER BDL 0 . 010 ALDRIN BDL 0 .010 ALPHA-BHC BDL 0 .010 BETA-BHC BDL 0 .010 DELTA-BHC BDL 0 .010 GAMMA-BHC BDL 0 . 010 CHLORDANE BDL 0.010 4,4-DDT BDL 0 .010 4,4-DDE BDL 0 . 010 4,4-DDD BDL 0 .010 DIELDRIN BDL 0 . 010 ALPHA ENDOSULFAN BDL 0 . 010 BETA ENDOSULFAN BDL 0 .10 ENDOSULFAN SULFATE BDL 0 . 010 ENDRIN BDL 0.020 ENDRIN ALDEHYDE BDL 0 .030 HEPTACHLOR BDL 0.10 HEPTACHLOR EPOXIDE BDL 0.10 PCB-1016 BDL 0.20 PCB-1221 BDL 0.10 PCB-1232 BDL 0.10 PCB -1242 BDL 0.10 PCB-1248 BDL 0.10 PCB-1254 BDL 0 .10 PCB-1260 BDL 0.20 TOXAPHENE SURROGATE %RECOVERY LIMITS 93 70 - 130 DBC(SURROGATE, % RECOVERY) - 130 92 70 2 ,4,5,6-TCX(SURROGATE % REC.)

Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC 5

FILE ID A02091 UNITS Uq/L Committed to Quality Since 1958 (937) 837-3744 11East Main Street Dayton, Ohio 45426

Belmonte Park Environmental I.--) J Laboratories Order # 99-02-060 Page 30 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT j

K>

Committed to Quality Since 1958 I11 East Main Street Dayton, Ohio 45426Et (937) 837-3744

Belmonte Park Environmental we4 Laboratories Page 31 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE 02/01/99 Lab No: 45A Sample

Description:

OUTFALL OOC 8270 U Sub-Out Method: Special Test Test Code:

Test

Description:

Triaryl Phosphate Category: AQUEOUS Collected: 02/01/99 PARAMETER RESULT LIMIT BDL 5 TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER SURROGATE %RECOVERY LIMITS 63 35 - 114 NITROBENZENE-D5 70 43 - 116 2-FLUOROBIPHENYL 100 33 - 141 p-TERPHENYL-d14.

25 10 - 94 PHENOL-d6 38 21 - 100 2-FLUOROPHENOL 83 10 - 123 2,4,6-TRIBROMOPHENOL Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206503W UNITS ua/

METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

Facility name: NPDES Permit number: Outfall Number:

Donald C. Cook Nuclear Plant MI0005827 00C Addendum to NPDES Renewal Application Section III.B.10 Toxic Pollutant Reasonable Potential Effluent Data Sampling results indicate the presence of toxic pollutants in the Cook Nuclear Plant discharges as follows:

Copper was detected in Outfall OOC (Plant Heating Boiler Blowdown). Based on knowledge of the plant processes, there is reasonable potential for copper to be present in these discharges.

Ethanolamine was detected in Outfall OOC (Plant Heating Boiler Blowdown). Based on knowledge of the plant processes, there is reasonable potential for ethanolamine to be present in these discharges.

KU

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

/ PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant M10005827 00C 9 WATER TREATMENT ADDITIVES the facility to condition or Water treatment additives include any material that is added to water used at the facility or to a wastewater generated by treat the water.

NPDES permit does not Approvals of water treatment additives are authorized by the DEQ under separate correspondence. The issuance of an constitute approval of the water treatment additives that are included in this application A. Are there water treatment additives in the discharge from this facility?

l No, proceed to item 4.

El Yes B. Have these water treatment additives been previously approved?

D- No, continue with C. below.

listed in C 1-8 must be El Yes Submit a list of the previously approved water treatment additives and the date they were approved. The information updated if it has changed since the previous approval information listed below for each C. Submit a list of water treatment additives that are or may be discharged from the facility Applicants must submit the additive 1 The water treatment additive Material Safety Data SheeL

2. The proposed water treatment additive discharge concentration.

3 The discharge frequency (i e, number of hours per day, week, etc).

4 The outfall the water treatment additive is to be discharged from.

5 The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6. The water treatment additive function (i e, microbiocide, flocculant, etc )

sp)

7. A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Cenodaphnia sp , Daphnia sp , or Simocephalus a minimum 8 The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets of tests that would meet this requirement include a 96-hour LC50 for requirement of Rule 323 1057(2)(a) of the Water Quality Standards Examples a rainbow trout, bluegill, or fathead minnow treatment additives listed The required toxicity information (described in items 7 and 8 above) is currently available in the SWOD files for the water state.mi.us/swq/gleasidocslwta)WTAlist.doc. If you intend to use one of the water treatment on the DEQ's Internet page http:llwww.deq additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD additive.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment

10. WHOLE EFFLUENT TOXICITY TESTS within the last three years" Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges last 5 years If yes, identify the tests and summarize the results below unless the test has been submitted to the department in the

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME l NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant I M10005827 00C

9. WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Ethanolamine solution, such as. 5/23/00 NPDES Permit approval 9/28/95 Betz Powerline 1440, Betz Powerline 1480, Nalco 92UM001 Hydrazine Solution, such as 5/23/00 NPDES Permit approval 9/28/95 Betz Cortrol OS5035, (Formerly Betz Powerline 1205), Betz Cortrol OS5010, Nalco 19H Carbohydrazide Solution such as 3/25/94 application, 4/15/94 approval, NPDES Permit approval 9/28/95 Nalco 1250 plus, Nalco Eliminox i

i i

I I

I 4

-i I

+

-I-I1 I

1-1-

i K'j 32 EQP 4659-C (Rev 1/03)

Section III.B Outfall QOG

Michigan Department of Environmental Quality- Surface Water Quality Division DAid WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information blank section mplete a separate Section III.B. - Outfall Information (pages 26-3 1) for each outfall at the facility. Make copies of this the application for additional outfalls as necessary.

PLEASE TYPE OR PRINT NPDES PERMIT NUMBER OUTFALL NUMBER FACILITY NAME Donald C Cook Nuclear Plant M10005827 - Q0OG 1 OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

Watershed A. Lower St. Joseph Receiving Water B Lake Michigan C County Township Berrien Lake D. /4,1/4 1/4Section Town Range SW NW 06 06S 19W Latitude ngitude E. ~A- I

'F. Type of Wastewater Discharged (Check all that apply to this outfall) a] Contact Cooling El Sanitary Wastewater Eli Groundwater Cleanup El Storm Water (regulated)

[] Noncontact Cooling E Process Wastewater El Hydrostatic Pressure Test E] Storm Water (not regulated)

El Storm water subject to effluent guidelines (indicate under which category)

El Other - specify (see 'Table 8 - Other Common Types of Wastewater' in appendix)

J. What is the maximum Facility Design Flow Rate 0 366 MGD Seasonal Dischargers MGY Continue with Item H G What is the maximum discharge flow authonzed for this outfall Continuous Dischargers 0 366 MGD Continue with Item I H. Seasonal Discharge List the discharge penods (by month) and the volume discharged in the space provided below.

DIs Volume From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume I Continuous Discharge How often is there a discharge from this outfall (on the average)? 24 Hours/Day 365 Days/Year Batch dischargers must provide the following additional Information:

Is there effluent flow equalization? El Yes 1l No Batch Peak Flow Rate Number of batches discharged per day Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATERbDISCHARGE PERMIT APPLICATION -"

SECTION III - Industrial and Commercial Wastewater B. Outfall Information CASE TYPE OR PRINT

.CILITY NAME - , NPIES PERMIT NUMBERl OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 l QOG

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of various industries and the types-of information each shall report in this application. For assistance call the Permits Section. All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page ii, item 8.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Reverse Osmosis system reject B. SlCorNAICScode. 4911 C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported) Reverse osmosis system reject flow 0 366 MGD maximum flow, 2247 MWE total plant electrical generation.

PROCESS INFORMATION A. Name of the process contributing to the discharge B. SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropnate information to be reported)

PROCESS INFORMATION A Name of the process contnbuting to the discharge:

B SICorNAICScode C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported),

PROCESS INFORMATION A. Name of the process contnbuting to the discharge.

B. SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported).

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information.

iSTRUCTIONS FOR COMPLETING SECTION 111, ITEM B.3. e-A Carbon, Total Suspended In accordance with 40 CFR 122.21, all applicants must report CBODs, Chemical Oxygen Demand, Total Organic that reporting of data for Solids, Ammonia as N, Temperature (both summer and winter), and pH. The applicant may, however, request The request shall be one or more of these required parameters be waived Such request must be supported by adequate rationale.

included as an attachment to this application.

or estimated Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges and expected to provide reduction of data provided for proposed discharges. Please include an explanation if 'Pollution Prevention' is expected types of discharges pollutants See Page 8 of the appendix for a list of specific parameters for which data must be provided for specific For assistance in determining the appropriate parameters to report, (e.g , noncontact cooling waters, gasoline groundwater cleanups, etc )

call the Permits Section.

blank spaces provided or If data are available for other parameters not listed in Section lll.B 3 , the applicant shall report these data in the attach the information to this application on 81/2" x 11' paper.

check the appropriate Report all data in the units provided and for the sample types specified in the table. If more than one option is available, 0

= degrees Fahrenheit, C = degrees Celsius. See box. The units are as follows. pg/l = micrograms per liter, mgA = milligrams per liter, IF page ii number 5 for analytical requirements.

frequency-sample To analyze for pH, temperature, total residual chlonne, oil and grease, and fecal coliform use Grab Samples unless other phosphorus, COD, TOC, ammonia nitrogen and total suspended solids use 24-type analyses are available. To analyze for total BOD 5, total hour composite samples unless other frequency-sample type analyses are available.

analyze only For two or more substantially identical outfalls, permission may be requested from the appropriate district office to sample and the district office, on a one outfall and submit the results of the analysis for other substantially identical outfalls If the request is granted by were not sampled are separate sheet attached to the application form, identify which outfall was sampled and describe why the outfalls which

'maximum daily substantially identical to the outfall which was sampled See pages ii and iii for sampling definitions, including concentration", and 'maximum monthly concentration".

REPORTING OF INTAKE DATA limitations for one or Applicants are required to report intake water data when they are attempting to demonstrate eligibility for 'net' effluent present in the intake waters more pollutants. A 'net" effluent limitation is determined by subtracting the average level of the pollutant(s) only in certain remaining after treatment which is not removed by the treatment system. NPDES regulations allow net limitations of the results of the circumstances (see 40 CFR Part 122.45(g)) To demonstrate eligibility, report the average concentration and/or mass report the intake concentrations and/or mass after treatment In analyses on the intake water. If the intake water is treated pnor to use, addition to the analytical results, the following information shall be submitted for each parameter.

is not to the same a) A statement that the intake water is drawn from the body of water into which the discharge is made. If the discharge body of water from which the water is withdrawn, the facility is not eligible for net limitations.

wastewater. Limitations for b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the the net removal of pollutants are adjusted only to the extent that the pollutant is not removed.

of the extent c) When applicable (for example, when the pollutant represents a class of compounds, e.g., BOD 5, TSS, etc.), a demonstration Limitations to which the pollutants inthe intake vary physically, chemically and biologically from the pollutants contained in the discharge.

are adjusted only to the extent that the concentrations of the intake pollutants vary from the discharged pollutants.

groundwater.

Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated

Michigan Department of Environmental Quality- Surface Water Quality Division

-WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information DLEASE TYPE OF RPRINT ACILITY NAME - NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant I M10005827 I DOG I ___

3. WASTEWATER CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for completing this page are on the facing page E Check this box if additional information is included as an attachment To submit additional informabon see page ii, item 8.

,'-,um 'X,,4,,* MAxim . Maxm ->.

DailyMontfilMonthly Number of._;

Parameter Concentration

Cocentation Units- Analyses Sam mg/I lI Grab Biochemical Oxygen Demand - five day (BOD 5) 4 4 mg/2 D 24 Hr Comp mg/I li Grab COD (Chemical oxygen demand) 8 8 2 24 Hr Comp mg/l L1 Grab TOC (Total organic carbon) 3 3 m/ 2 24 Hr Comp mgA 2 Grab Ammonia Nitrogen (as N) <0.5 <0 5 2 3 24 Hr Comp mg/l Z Grab Total Suspended Solids 2 <4 g102 El 24 Hr Comp NANA g/i L Grab Total Dissolved Solids NA NA mg/lNA 24 Hr Comp mg/l [1 Grab Total Phosphorus (as P) <0 1 <0.1 1 S 24 Hr Comp maximum-7day counts/i O0mI Fecal Coliform Bacteria (report geometric means) NA NA NA Grab 1 mg/I tal Residual Chlorine 0 21 0 21 l l g/i 2 Grab minimum daily UoU Not

!emg/I El Grab -I Dissolved Oxygen NA NA El 24 Hr Comp pH minimum maximum stnad nt Grab (report maximum and minimum of individual samples) 32 69 standard units25 24 Hr Comp IV'IOF El]o-C Z Grab Temperature, Summer 766 76 6 4 L 24 HrComp oF E~l -C Grab Temperature, Winter 44 2 44.2 2 Li24 Hr Comp Oil & Grease <5 <5 mg/l 1 Grab Li1 Grab Li 24 Hr Comp I] Grab Li24 HrComp

. Grab See Attached for additional Data 24 Hr Comp El Grab a_ 24 Hr Comp l Grab L 24 Hr Comp lI Grab 24 Hr Comp

__EL ____

8 Grab 24 Hr Comp El Grab

_ _ _ _ __ __ _ __ __ __ _ _ _ __ __ __ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ EL 24 H r Corr El Grab -I

_ __ __ __ _ __ __ __ _ __ __ __ _ __ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ElI 24 H rC o m

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

&EASE TYPE OR PRINT

,CILITY NAME 7-- NPDES PERMIT NUMBER OUTFALL NUMBER Donald C Cook Nuclear Plant - M10005827 l OOG 4 PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater must submit the results of at least one effluent analysis for selected organic pollutants identified inTable 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 3 Existing primary industries must also provide the results of at least one effluent analysis for any other chemical listed in Table 2 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3 New primary industries that propose to discharge process wastewater must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent 5 DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-tnchlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-tnchlorophenyl) phosphorothionate (Ronnel), 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent, must submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6 All effluent analyses for dioxin and furan congeners must be conducted using EPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan congener listed in Table 6 New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon), 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel); 2,4,5-trichlorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6 OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries, or existing primary industnes that discharge non-process wastewater, must submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in facility effluent In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed in Tables 2 and 3.

New secondary industnes, or new primary industries that propose to discharge non-process wastewater, must provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in facility effluent

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industnes, regardless of discharge type, must provide the results of at least one analyses for any chemical listed in Table 4 known or believed to be present in facility effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in facility effluent In addition, submit the results of any effluent analysis performed within the last 5 years for any chemical listed in Tables 4 and 5.

New industnes, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be in facility effluent

8. INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, must provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in facility effluent that have not been previously identified in this application Quantitative effluent data that are less than 5 years old for these chemicals must be reported NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31. To submit additional information see page ii, item 8 If the effluent concentrations are estimated, place an E in the Analytical Method' column The following fields must be completed for each data row Parameter, CAS No, Concentration(s), Sample Type, Analytical Method, Quantification Level and Detection Level See page ii, number 5 for analytical test requirements.

Michigan Department of Enm imental Quality- Water Division F- WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 OOG SAMPLE DATE 4 w.

2

, ' Conc. 'Conc. Conc.% '

UConc. Conc.

C K Conc Conc.' rConc. Conc.'

-;CAS; Conc. Sample8 AnalytIc .

PARAMETER1, ' 'ug/l)

(No;> (ug1)' u (ug1) ' (ug/l)

(ug1)k r(ug/l) (ug/l): (ug/l) . (ug/l) 'Type ;- 5aI 7' OL ' L See Attached for additional data.

( ( 5 EQP( '-C (Rev 1/03)

( (7 Additional Sample Data OOG Section III.B.6 and 7 Summary Sheet For Outfall OOG Analytical Max # of Sample 3121/02 5130102 type Max Daily Method monthly Analyses Parameter _ 2/1/99 See Attached data set from BeImonte Park Laboratories.

<1 - Grab <1 204 2/200.7 <1 2 Antimony (ug/) <1 2 <1 Grab 2 206.2/200.7 2 3 Arsenic (ug1) <1

<0.2 . Grab <1 200 7 <1 2 Beryllium (ug/l) <1

<0.2 Grab <0 2 213 2/200 7 <0 2 2 Cadmium (ug/) <0 2

<2 Grab <10 200 7 <10 2 Chromium (ug/l) <10 1 1 Grab 1 220 2/200 7 1 3 Copper (ugA) <1

<1 - Grab <1 239 2/200.7 <1 2 Lead (ug) <1

<3 Grab <5 249 2/200.7 <5 2 Nickel (ugA) <5 Grab <0 01 420 1 <0 01 1 Total Phenols (ug/) <0 01 -

<1 Grab <1 270 3 <1 1 Selenium (ug/I)

<0.2 Grab <0 5 272 2/200.7 <0 5 2 Silver(ugAl) <0 5

<1 Grab <1 279 2 <1 2 Thallium -(ug/) <1

<4 Grab <4 200.7 <4 1 Zinc (ug/) -

<0 01 Grab <0 01 335 2 <0 01 2 Cyanide (mg/I) <0 01 -

1 51 2 08 Grab 2.08 1631 2 08 2 Mercury (ngA) -

V!jW'tl'g-,b A .t, gt;' t-.h 7 = -* 9 a Table 4 9r-tvrt'Ai5 ;t,55,,s,5a .1 ..... ,

0 21 - Grab 0 21 330 5 0.21 2 Chlonne, total residual (mg/I) <0 08 113 174 234 Composite 234 375.4 234 3 Sulfate (mg/)

Additional Data From Belmonte Park Laboratories is attached.

Tablew:Z A _ _ __ _ _ _ _ _  ; - 5 0 - } T;,

See Attached data set from Belmonte Park Laboratories.

I Belmonte Park

) Environmental K>

Laboratores AMERICAN ELECTRIC POWER (AEP) Order #: 99-02-060 1 COOK PLACE Date: 03/16/99 09:22 BRIDGMAN, MICHIGAN 49106 Work ID: OUTFALL 001 - OOC Date Received: 02/02/99 Attn: BLAIR ZORDELL Date Completed: 03/16/99 Purchase Order: 4307976 Invoice Number: Client Code: AEP_4 ND= NONE DETECTED OHIO CERT.# 12345 SAMPLE IDENTIFICATION Sample Sample Sample Sample Number De!scription Number nD-e--ri nt-i n

,01 OUTFALL 001 02/01/99 24 OUTFAI 0OG 02/01/99 02 OUTFALL 001 02/01/99 25 OUTFAI 0OG 02/01/99 03 OUTFALL 001 02/01/99 26 OUTFAI OOG 02/01/99 04 OUTFALL 001 02/01/99 27 OUTFAI OG 02/01/99 05 OUTFALL 001 02/01/99 28 OUTFAI DOG 02/01/99 06 OUTFALL 001 02/01/99 29 OUTFAI DOG 02/01/99 07 OUTFALL 001 02/01/99 30 OUTFAI DOG 02/01/99 08 OUTFALL 001 02/01/99 31 OUTFAI OOC 02/01/99 09 OUTFALL 001 02/01/99 32 OUTFAI OOC 02/01/9 9 10 OUTFALL 001 02/01/99 33 OUTFAI 0OC 02/01/99 11 OUTFALL 001 02/01/99 34 OUTFAI OOC 02/01/99 12 OUTFALL 001 02/01/99 35 OUTFAI O0C 02/01/99 13 OUTFALL 001 02/01/99 36 OUTFAI OOC 02/01/99 14 OUTFALL 001 02/01/99 37 OUTFAI 0OC 02/01/99 15 OUTFALL 001 02/01/99 38 OUTFAI OOC 02/01/99 16 OUTFALL 0OG 02/01/99 39 OUTFAI OOC 02/01/99 17 OUTFALL OOG 02/01/99 40 OUTFAI 0OC 02/01/99 18 OUTFALL OOG 02/01/99 41 OUTFAI OOC 02/01/99 19 OUTFALL DOG 02/01/99 42 OUTFAI 0OC 02/01/99 20 OUTFALL DOG 02/01/99 43 OUTFAI 0OC 02/01/99 21 OUTFALL DOG 02/01/99 44 OUTFAI OOC 02/01/9 9 22 OUTFALL 0OG 02/01/99 45 OUTFAI OOC 02/01/99 23 OUTFALL 0OG 02/01/99 4)

Committed to Quality Since 1958 11 East Main Street DaytonaOhio 45426 (937) 837-3744

, Belmonte Park Environmental Laboratories Page 2 Order # 99-02-060 03/16/99 09:22 submitted for Enclosed are results of specified samples please contact analyses. If there are any questions, numbers are 836 & 837.

Matt Lake. Our Ohio EPA Certification DETECTION LIMIT".

Any result of "BDL" indicates "BELOW 92'I

-JQQ-Certified By MATT LAKE Committed to Quality Since 1958 (937) 837-3744 11 East Main Street Dayton, Ohio 45426

I Belmonte Park I) Environmental Laboratories Order # 99-02-060 Page 3 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 01A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Ply Sday CBOD, EPA 405.1 3 2 mg/L 02/08/99 PT SUSPENDED SOLIDS,EPA 160.2 BDL 5 mg/L 02/11/99 KC Sample: 02A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BfY COD, EPA 410.4 6 5 mg/L 02/19/99 LG TOC, EPA 415.1 4.5 1 mg/L 02/09/99 NEW Sample: 03A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed fly AMMONIA N, EPA 350.2 BDL 0.5 mg/L 02/11/99 JB Sample: 05A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed ax EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 SD Sample: 06A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By ALUMINUM, EPA 200.7 0.05 0.05 mg/L 02/12/99 RJE ANTIMONY, EPA 204.2 BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 206.2 BDL 0.001 mg/L 03/05/99 RJE BARIUM, EPA 200.7 0.021 0.005 mg/L 02/11/99 RJE BERYLLIUM, EPA 200.7 BDL 0.001 mg/L 02/11/99 RJE BORON, EPA 200.7 0.07 0.05 mg/L 02/12/99 RJE CADMIUM, EPA 213 .2 BDL 0.0002 mg/L 03/08/99 RJE CHROMIUM, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE COBALT, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE COPPER, EPA 220.2 BDL 0 .001 mg/L 03/08/99 RJE IRON, EPA 200.7 BDL 0.1 mg/L 02/11/ 99 RJE

) LEAD, EPA 239.2 BDL 0.001 mg/L 03/05/99 RJE J LITHIUM, EPA 200.7 0.01 0.01 mg/L. 02/12/9 9 RJE Committed to Quality Since 1958 I11East Main Street Dayton, Ohio 45426 (937)837-3744

- - I Belmonte Park

- = Environmental Laboratories Page 4 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Detection Result Limit Units Analyzed ;iy Test Description EPA 200.7 11 1 mg/L 02/12/99 RJE MAGNESIUM, EPA 200.7 BDL 0 .01 mg/L 02/11/99 RJE MANGANESE, 245.1 BDL 0.0002 mg/L 02/11/99 RJE MERCURY, EPA WATER EP METALS DIGESTION, 200.7 BDL 0 .01 mg/L 02/11/99 RJE MOLYBDENUM, EPA EPA 249.2 BDL 0.005 mg/L 03/08/99 RJE NICKEL, EPA 200.7 BDL 0.1 mg/L 02/11/99 RJE SELENIUM, 272.2 BDL 0.0005 mg/L 03/08/99 RJE SILVER, EPA EPA 200.7 0.12 0 .01 mg/L 02/12/99 RJE STRONTIUM, 279.2 BDL 0 .001 mg/L 03/05/99 RJE THALLIUM, EPA EPA 200.7 BDL 0.1 mg/L 02/15/99 RJE URANIUM 200.7 BDL 0.02 mg/L 02/11/99 RJE ZINC, EPA OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 07A Detection Result Limit Units Analyzed Bly Test Description BDL 1 mg/L 03/05/99 LG SULFIDE, EPA 376.1 EPA 335.2 BDL 0 .01 mg/L 03/04/99 LG TOTAL CYANIDE, OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 08A Detection Result Limit Units Analyzed Bly Test Description BDL 0 .01 mg/L 02/23/99 JB PHENOLICS, EPA 420.1 OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 09A Detection Result Limit Units Analyzed By Test Description BDL 0.05 mg/L 02/03/99 ML CHLORINE, RESIDUAL TOTAL OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 10A Detection Result Limit Units Analyzed BY Test Description 0.38 0.2 mg/L 02/05/99 LG NITRATE-NITRITE N 0.5 mg/L- 02/11/99 JB ORGANIC NITROGEN BDL 0.37 0.1 mg/L 02/18/99 LG PHOSPHORUS, EPA 365.1 BDL 0.5 mg/L 02/06/99 JB TKN, EPA 351.3 Committed to Quality Since 1958 Dayton. Ohio 45426 (937) 837-3744 11 East Main Street

I Belmonte Park

) Environmental IJ Laboratories Order # 99-02-060 Page 5 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 11A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection OIL & GR E .AS Result Limit Units Analyzed pv OIL & GREASE, EPA 413.1 BDL 5 mg/L 02/10/99 PT Sample: 12A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY GROSS ALPHA, IN WATER BDL 3 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 4 pCi/L 03/08/99 SF RADIUM, IN WATER BDL 1 pCi/L 03/10/99 SF RADIUM-226, IN WATER BDL 1 pCi/L 03/10/99 SF Sample: 13A OUTFALL 001 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By METHYLENE BLUE ACTIVE SUB. BDL 0 .01 mg/L 02/17/99 ML SULFATE, EPA 375.4 BDL 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 14A OUTFALL 001 02/01/99 Collected: 02/01/519 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BE ASBESTOS WATER ND 0.2 MF/L, >lOum 02/12/99 EM Sample: 16A OUTFALL DOG 02/01/99 Collected: 02/01/999 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Sday CBOD, EPA 405.1 4 2 mg/L 02/08/ 99 PT SUSPENDED SOLIDS,EPA 160.2 BDL 5 mg/L 02/11/99 KC Sample: 17A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed COD, EPA 410.4 BDL 5 mg/L 02/19/99 LG TOC, EPA 415.1 2.1 1 mg/L 02/09/99 JW

)

Committed to Quality Since 1958 I11East Main Street Dayton, Ohio 45426 (937) 837-3744

Belmonte Park 31 LEnvironraental Laboratories Page 6 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 18A Detection Result Limit Units Analyzed iBv Test Description EPA 350.2 BDL 0.5 mg/L- 02/11/99 JB AMMONIA N, OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 20A Detection Result Limit Units Analyzed By Test Description SD EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Sample: 21A Detection Result Limit Units Analyzed Rly Test Description EPA 200.7 BDL 0.05 mg/L 02/12/99 RJE ALUMINUM, EPA 204.2 BDL 0.001 mg/L 03/05/99 RJE ANTIMONY, BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 206.2 0.022 0.005 mg/L 02/11/99 RJE BARIUM, EPA 200.7 EPA 200.7 BDL 0 .001 mg/L 02/11/99 RJE BERYLLIUM, 0.06 0.05 mg/L 02/12/99 RJE BORON, EPA 200.7 BDL 0.0002 mg/L 03 /08/99 RJE CADMIUM, EPA 213.2 EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE CHROMIUM, BDL 0.01 mg/L 02/11/99 RJE COBALT, EPA 200.7 220.2 BDL 0.001 mg/L 03 /0 8/99 RJE COPPER, EPA BDL 0.1 mg/L 02/11/99 RJE IRON, EPA 200.7 BDL 0 .001 mg/L 03/05/99 RJE LEAD, EPA 239.2 BDL 0.01 mg/L 02/12/99 RJE LITHIUM, EPA 200.7 12 1 mg/L 02/12/99 RJE MAGNESIUM, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE MANGANESE, EPA 200.7 BDL 0.0002 mg/L 02/11/99 RJE MERCURY, EPA 245.1 EP METALS DIGESTION, WATER BDL 0 .01 mg/L 02/11/99 RJE MOLYBDENUM, EPA 200.7 mng/ L BDL 0 .005 03/08/99 RJE NICKEL, EPA 249.2 mg/L BDL 0 .1 02/11/99 RJE SELENIUM, EPA 200.7 mg/L BDL 0.0005 03/08/99 RJE SILVER, EPA 272.2 mg/L 0.14 0 .01 02/12/99 RJE STRONTIUM, EPA 200.7 mg/L BDL 0 .001 03/05/9 9 RJE THALLIUM, EPA 279.2 mg/L 200.7 BDL 0 .1 02/15/ 99 RJE URANIUM EPA mg/L BDL 0 .02 02/11/99 RJE ZINC, EPA 200.7 Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

• s l Belmonte Park s = Environmental Laboratores Order # 99-02-060 Page 7 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 22A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed LG SULFIDE, EPA 376.1 BDL 1 mg/L 03/05/99 LG TOTAL CYANIDE, EPA 335.2 BDL 0.01 mg/L 03/15/99 LG Sample: 23A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY PHENOLICS, EPA 420.1 BDL 0.01 mg/L 02/23/99 JB Sample: 24A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY j CHLORINE, RESIDUAL TOTAL BDL 0.05 mg/L 02/03/99 ML Sample: 25A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY NITRATE-NITRITE N 0.50 0.2 mg/L 02/05/99 LG ORGANIC NITROGEN BDL 0.5 mg/L 02/11/99 JB PHOSPHORUS, EPA 365.1 BDL 0.1 mg/L 02/18/99 LG TKN, EPA 351.3 BDL 0.5 mg/L 02/06/99 JB Sample: 26A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BP OIL & GREASE, EPA 413.1 BDL S mg/L 02/10/99 PT Sample: 27A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY GROSS ALPHA, IN WATER BDL 3 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 4 pCi/L 03 /08/99 SF RADIUM, IN WATER BDL 1 pCi/L 03/10/9 9 SF RADIUM-226, IN WATER BDL 1 pCi/L 03/10/9 9 SF Committed to Quolity Since 1958 I11 East Main Street Daytont Ohio 45426 (937) 837-3744

Belmonte Park t Environmental Laboratories OrderA#99-02-060 Page 8 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 28A OUTFALL 00G 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By METHYLENE BLUE ACTIVE SUB. BDL 0 .01 mg/L 02/17/99 ML SULFATE, EPA 375.4 113 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 29A OUTFALL OOG 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY ASBESTOS WATER ND 0.2 MF/L, >lOum 02/12/99 EM Sample: 31A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection JJ Test Description Result Limit Units Analyzed BY 5day CBOD, EPA 405.1 4 2 mg/L 02/08/99 PT SUSPENDED SOLIDS,EPA 160.2 BDL 5 mg/L 02/11/99 KC Sample: 32A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed PLx COD, EPA 410.4 BDL 5 mg/L 02/19/99 LG TOC, EPA 415.1 BDL 1 mg/L 02/09/99 JW Sample: 33A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed AMMONIA N, EPA 350.2 BDL 0.5 mg/L 02/11/99 Sample: 35A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 SD Committed to Quality Since 1958 I1I East Main Street Dayton, Ohio 45426 (937) 837-3744

I I

Belmonte Park

) = Environmental Laboratories Order # 99-02-060 Page 9 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 36A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By ALUMINUM, EPA 200.7 BDL 0.05 mg/L 02/12/99 RJE ANTIMONY, EPA 204.2 0.002 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 206.2 BDL 0.001 mg/L 03/05/99 RJE BARIUM, EPA 200.7 BDL 0.005 mg/L 02/11/99 RJE BERYLLIUM, EPA 200.7 BDL 0 .001 mg/L 02/11/99 RJE BORON, EPA 200.7 BDL 0.05 mg/L 02/12/99 RJE CADMIUM, EPA 213.2 BDL 0.0002 mg/L 03/08/99 RJE CHROMIUM, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE COBALT, EPA 200.7 BDL 0 .01 mg/L 02/11/99 RJE COPPER, EPA 220.2 0.012 0.001 mg/L 03/08/99 RJE IRON, EPA 200.7 BDL 0.1 mg/L 02/11/99 RJE LEAD, EPA 239.2 BDL 0.001 mg/L 03/05/99 RJE LITHIUM, EPA 200.7 BDL 0.01 mg/L 02/12/99 RJE MAGNESIUM, EPA 200.7 BDL 1 mg/L 02/12/99 RJE MANGANESE, EPA 200.7 0 .01 0.01 mg/L 02/11/99 RJE MERCURY, EPA 245.1 BDL 0.0002 mg/L 02/11/99 RJE METALS DIGESTION, WATER EP MOLYBDENUM, EPA 200.7 BDL 0.01 mg/L 02/11/99 RJE NICKEL, EPA 249.2 BDL 0.005 mg/L 03/08/99 RJE SELENIUM, EPA 200.7 BDL 0.1 mg/L 02/11/99 RJE SILVER, EPA 272.2 BDL 0.0005 mg/L 03/08/99 RJE STRONTIUM, EPA 200.7 BDL 0.01 mg/L 02/12/99 RJE THALLIUM, EPA 279.2 BDL 0 .001 mg/L 03/05/99 RJE URANIUM EPA 200.7 BDL 0.1 mg/L 02/15/99 RJE ZINC, EPA 200.7 BDL 0.02 mg/L 02/11/99 RJE Sample: 37A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed Bl SULFIDE, EPA 376.1 BDL 1 mg/L 03/05/99 LG TOTAL CYANIDE, EPA 335.2 BDL 0.01 mg/L 03/04/99 LG Sample: 38A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By PHENOLICS, EPA 420.1 BDL 0 .01 mg/L 02/23/99 JB JIw Committed to Quality Since 1958 I1I East Main Street Dayton, Ohio 45426 (937) 837-3744

lK bBelmonte Park Environmental J Laboratories Order # 99-02-060 i Page 10 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample: 39A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed CHLORINE, RESIDUAL TOTAL BDL 0.05 mg/L 02/03/99 ML Sample: 40A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed NITRATE-NITRITE N BDL 0.2 mg/L 02/05/99 LG ORGANIC NITROGEN BDL 0.5 mg/L 02/11/99 JB PHOSPHORUS, EPA 365.1 BDL 0.1 mg/L 02/18/99 LG TKN, EPA 351.3 BDL 0.5 mg/L 02/06/99 JB Sample: 41A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS J Test Description Result Detection Limit Units Analyzed BP OIL & GREASE, EPA 413.1 BDL 5 mg/L 02/10/99 PT Sample: 42A OUTFALL 00C 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed SF GROSS ALPHA, IN WATER BDL 3 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 4 pCi/L 03/08/99 SF RADIUM, IN WATER BDL pCi/L 03/10/99 SF RADIUM-226, IN WATER BDL 1 pCi/L 03/10/99 SF Sample: 43A OUTFALL OOC 02/01/99 Collected: 02/01/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY METHYLENE BLUE ACTIVE SUB. BDL 0.01 mg/L 02/17/99 ML SULFATE, EPA 375.4 BDL 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 44A OUTFALL OOC 02/01/99 Collected: 02/01/539 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY ASBESTOS WATER ND 0.2 MF/L, >lOum 02/12/98 EM Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

I I I II I I, - I I Belmonte Park

) = Environmental Laboratories Order # 99-02-060 Page 11 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 04A Test

Description:

EPA 624 Method: 624 Test Code: 624_X Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2

) CHLOROETHANE CHLOROFORM BDL BDL 10 2

1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 2 VINYL CHLORIDE BDL 10 XYLENES BDL 10 SURROGATE %RECOVERY LIMITS D4-1,2 DICHLOROETHANE 112 76 - 114 D8-TOLUENE 94 88 - 110 Committed to Quality Since 1958 I11East M ain Street DaytonaOhio 45426 (937) 837-3744

Belmonte Park

) = Environmental.

Laboratories Order # 99-02-060 Page 12 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 04A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/01/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 86 - 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020934 UNITS ua/L METHOD EPA 624 BDL BELOW DETECTION LIMIT

)'

Committed to Quality Since 1958 I1I East Main Street Dayton, Ohio 4542E (937) 837-3744

Belmonte Park

, = Environmental I-I.

Laboratories Order # 99-02-060 Page 13 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625_AE Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL 3DL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 50 PHENOL BDL 10

) ACENAPHTHENE BDL 10 BENZIDENE BDL 50 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3 -DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL- 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10

) N-NITROSODI-N-PROPYLAMINE BIS(2-ETHYLHEXYL)PHTHALATE BDL BDL 10 10 Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

K9 9 Belmonte Park

'J = Environmental Laboratories Order # 99-02-060 Page 14 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625_AE Collected: 02/01/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE - BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANTHRENE BDL 10 BDL s0 DIBENZO(A,H)ANTHRACENE BDL s0 INDENO(1,2,3-CD)PYRENE BDL 10 PYRENE ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-dS 85 35 - 114 2-FLUOROBIPHENYL 72 43 - 116 p-TERPHENYL-d14 95 33 - 141 PHENOL-d6 46 10 - 94 2-FLUOROPHENOL 74 21 - 100 2,4,6-TRIBROMOPHENOL 50 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022524 UNITS uq/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

,~1 , _ 4 Belmonte Park 3 Environmental Laboratories Order # 99-02-060 Page 15 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ALDRIN BDL 0 .010 ALPHA-BHC BDL 0 .010 BETA-BHC BDL 0 . 010 DELTA-BHC BDL 0 .010 GAMMA-BHC BDL 0 .010 CHLORDANE BDL 0 .010 4,4-DDT BDL 0 .010 4,4-DDE BDL 0 . 010 4,4-DDD BDL 0.010 DIELDRIN BDL 0 . 010 ALPHA ENDOSULFAN

) BETA ENDOSULFAN BDL BDL

0. 010

0. 010 ENDOSULFAN SULFATE BDL 0 .10 ENDRIN BDL 0. 010 ENDRIN ALDEHYDE BDL 0.020 HEPTACHLOR BDL 0.030 HEPTACHLOR EPOXIDE BDL 0.10 PCB-1016 BDL 0.10 PCB-1221 BDL 0.20 PCB-1232 BDL 0 .10 PCB-1242 BDL 0.10 PCB-1248 BDL 0 .10 PCB-1254 BDL 0 .10 PCB-1260 BDL 0 .10 TOXAPHENE BDL 0.20 SURROGATE %RECOVERY LIMITS DBC(SURROGATE, % RECOVERY) 90 70 - 130 2,4,5,6-TCX(SURROGATE % REC.) 93 70 - 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020913 UNITS uj/L Committed to Quality Since 1958 I1I East Main Street DaytonMOhio 45426 (937) 837-3744

Belmonte Park Environmental Laboratories Order # 99-02-060 Page 16 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 05A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

I Belmonte Park

) = Environmental Laboratories Order # 99-02-060 Page 17 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 001 02/01/99 Lab No: 15A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER BDL 5 SURROGATE %RECOVERY LIMITS NITROBENZENE-D5 65 35 - 114 2-FLUOROBIPHENYL 78 43 _ 116 p-TERPHENYL-d14 113 33 - 141 PHENOL-d6 25 10 _ 94 2-FLUOROPHENOL 30 21 - 100 2,4,6-TRIBROMOPHENOL 93 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206501W UNITS u./L METHOD 8270 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 I11 East Main Street Daytons Ohio 45426 (937) 837-3744

K, Belmonte Park

) Environmental Laboratories Order # 99-02-060 Page 18 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 0OG 02/01/99 Lab No: 19A Test

Description:

EPA 624 - Method: 624 Test Code: 624_X Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,l-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2

) CHLOROETHANE CHLOROFORM BDL BDL 10 2

1,l-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 2 VINYL CHLORIDE BDL 10 XYLENES BDL 10 SURROGATE %RECOVERY LIMITS D4-1,2 DICHLOROETHANE 113 76 - 114 D8-TOLUENE 92 88 - 110 Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

Belmonte Park 3 = Environmental Laboratories Order # 99-02-060 Page 19 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 19A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/01/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 93 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST 3rMM INSTRUMENT GC/MS FILE ID 9020935 UNITS uL/L METHOD EPA 624 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 I1I East Main Street Dayton, Ohio 45426 (937) 837-3744

K) Belmonte Park j =_ Environmental Laboratories Order # 99-02-060 Page 20 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG -02/01/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625_AE Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL so BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL BDL 50

)j PHENOL ACENAPHTHENE BDL BDL 10 10 BENZIDENE BDL so 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE BDL Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

I

,) I hBelmonte Park

) '^ Environmental Laboratories Order # 99-02-060 Page 21 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625_AE Collected: 02/01/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANTHRENE BDL 10 DIBENZO(A,H)ANTHRACENE BDL 50 INDENO(1,2,3-CD)PYRENE BDL 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-d5 64 35 - 114 2-FLUOROBIPHENYL 65 43 - 116 p-TERPHENYL-d14 77 33 - 141 PHENOL-d6 35 10 - 94 2-FLUOROPHENOL 33 21 - 100 2,4,6-TRIBROMOPHENOL 65 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022525 UNITS uo/L METHOD EPA 625 BDL BELOW DETECTION LIMIT

<-/

Committed to Quality Since 1958 I11 F-nc~t Mnin .tropt Davton( Ohio 45426 (937) 837-3744

Belmonte Park V Z Environmental

.J Laboratories Order # 99-02-060 Page 22 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ALDRIN BDL 0.010 ALPHA-BHC BDL 0. 010 BETA-BHC BDL 0 . 010 DELTA-BHC BDL 0 .010 0.010 GAMMA-BHC BDL 0 . 010 CHLORDANE BDL 0 .010 4,4-DDT BDL 0 . 010 4,4-DDE BDL 0. 010 4,4-DDD BDL 0. 010 DIELDRIN BDL 0 .010 ALPHA ENDOSULFAN BDL O . 010 BETA ENDOSULFAN BDL 0 . 010 ENDOSULFAN SULFATE BDL 0.10 ENDRIN BDL 0. 010 ENDRIN ALDEHYDE BDL 0.020 HEPTACHLOR BDL 0.030 HEPTACHLOR EPOXIDE BDL 0.10 PCB-1016 BDL 0.10 PCB-1221 BDL 0.20 PCB-1232 BDL 0 .10 PCB-1242 BDL 0.10 BDL 0.10 PCB-1248 0 1.

BDL 0.10 PCB-1254 PCB-1260 BDL 0 .10 TOXAPHENE BDL 0.20 SURROGATE %RECOVERY LIMITS DBC(SURROGATE, % RECOVERY) 89 70 - 130 2,4,5,6-TCX(SURROGATE % REC.) 94 70 - 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020914 UNITS ua/L Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

• . I Belmonte Park j' Environmental KJ Laboratories Order # 99-02-060 Page 23 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 20A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

I , 0 Belmonte Park Environmental Laboratories Order # 99-02-060 Page 24 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOG 02/01/99 Lab No: 30A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER BDL - 5 SURROGATE %RECOVERY LIMITS NITROBENZENE-D5 60 35 - 114 2-FLUOROBIPHENYL 78 43 - 116 p-TERPHENYL-d14 115 33 - 141 PHENOL-d6 28 10 - 94 2-FLUOROPHENOL 35 21 - 100 2,4,6-TRIBROMOPHENOL 85 10 - 123 Notes and Definitions for this Report:'

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206504W UNITS uq/

METHOD 8270 BDL BELOW DETECTION LIMIT K>)4 Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

I

), Belmonte Park r Environmental Laboratories Order # 99-02-060 Page 25 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00C 02/01/99 Lab No: 34A Test

Description:

EPA 624 Method: 624 Test Code: 624_X Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2 CHLOROETHANE BDL 10 CHLOROFORM BDL 2 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL. 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 2 VINYL CHLORIDE BDL 10 XYLENES BDL 10 SURROGATE %IRECOVERY LIMITS

) D4-1,2 DICHLOROETHANE 114 76 - 114 D8-TOLUENE 94 88 - 110 Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

Belmonte Park Environmental

- Laboratories i

Order # 99-02-060 Page 26 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 34A Test

Description:

EPA 624 Method: 624 Test Code: 624_X Collected: 02/01/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 93 115 Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020936 UNITS uq/L METHOD EPA 624 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 11 East Main Street Dayton. Ohio 45426 (937) 837-3744

Belmonte Park Environmental. K~j Laboratories Order # 99-02-060 Page 27 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL' BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL so PENTACHLOROPHENOL BDL 50

) PHENOL ACENAPHTHENE BDL BDL 10 10 /-

BENZIDENE BDL so 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL. 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE BDL 10 Committed to Qualty Since 1958 1 1 East Main Street lEayton, Ohio 45426 (937) 837-3744

1 4, Belmonte Park K' ) I xEnvironmental Laboratories Order # 99-02-060 Page 28 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/01/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10

) PHENANTHRENE DIBENZO(A,H)ANTHRACENE BDL BDL 10 SO INDENO(1,2,3-CD)PYRENE BDL 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-d5 77 35 - 114 2-FLUOROBIPHENYL 66 43 - 116 p-TERPHENYL-d14 82 33 - 141 10 - 94 PHENOL-d6 62 2-FLUOROPHENOL 71 21 - 100 2,4,6-TRIBROMOPHENOL 66 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022526 UNITS ug/L METHOD EPA 625 BDL BELOW DETECTION LIMIT KA Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

. Belmonte Park LaboEnvironentals Laboratories Order # 99-02-060 Page 29 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00C 02/01/99 Lab No: 35A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT ALDRIN BDL 0. 010 ALPHA-BHC BDL 0. 010 BETA-BHC BDL 0. 010 DELTA-BHC BDL 0. 010 GAMMA-BHC BDL 0 . 010 CHLORDANE BDL 0. 010 4,4-DDT BDL 0. 010 4,4-DDE BDL 0 . 010 4,4-DDD BDL 0. 010 DIELDRIN BDL 0 . 010

) ALPHA ENDOSULFAN BETA ENDOSULFAN BDL BDL 0 . 010 0 .010 ENDOSULFAN SULFATE BDL 0 .10 ENDRIN BDL 0. 010 ENDRIN ALDEHYDE BDL 0.020 HEPTACHLOR BDL 0.030 HEPTACHLOR EPOXIDE BDL 0 . 10 PCB-1016 BDL 0.10 PCB-1221 BDL 0.20 PCB-1232 BDL 0.10 PCB-1242 BDL 0.10 PCB-1248 BDL 0 .10 PCB-1254 BDL 0.10 PCB-1260 BDL 0 .10 TOXAPHENE BDL 0.20 SURROGATE %RECOVERY LIMITS DBC(SURROGATE, % RECOVERY) 93 70 - 130 2,4,5,6-TCX(SURROGATE % REC.) 92 70 - 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020915 UNITS uq/L Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

t ) _ Belmonte Park Environmental Laboratories Page 30 Order # 99-02-060 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 35A EPA 608 Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES Collected: 02/01/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

I I Belmonte Park Environmental A& Laboratories Order # 99-02-060 Page 31 03/16/99 09:22 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOC 02/01/99 Lab No: 45A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/01/99 Category: AQUEOUS PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER BDL S TRICRESYL PHOSPHATE ESTER BDL 5 SURROGATE %RECOVERY LIMITS NITROBENZENE-D5 63 35 - 114 2-FLUOROBIPHENYL 70 43 - 116 p-TERPHENYL-dl4 100 33 - 141 PHENOL-dG 25 10 - 94 2-FLUOROPHENOL 38 21 - 100 2,4,6-TRIBROMOPHENOL 83 10 - 123

) Notes and'Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT SATURN FILE ID 0206503W UNITS ug/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 I1I East Main Street Dayton, Ohio 45426 (937) 837-3744

Faculity name: ,NPDES - Permit number. Number.

Donald C. Cook Nuclear Plant M10005827 .OG Addendum to NPDES Renewal Application Section III.B.10 Toxic Pollutant Reasonable Potential Effluent Data Sampling results indicate the presence of toxic pollutants in the Cook Nuclear Plant discharges as follows:

Strontium was detected in Outfall 000 (Reverse Osmosis System Reject). There are no plant processes that use strontium. Strontium is a trace element (21 5' among the elements in the earth's crust) usually associated with calcium and barium minerals in veins in limestone. The chief use of strontium is in fireworks, red signal flares, or on tracer bullets. Therefore, we do not believe that there is reasonable potential for strontium to be present in these discharges as a result of plant operations. We believe that strontium is present in the intake.

I Michigan Department of Environmental Quality- Surface Water Quality Division -

WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER l OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 OO-G

9. WATER TREATMENT ADDITIVES Water treatment additives include any matenal that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the DEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application A. Are there water treatment additives in the discharge from this facility?

a No, proceed to item 4.

E Yes B. Have these water treatment additives been previously approved?

l No, continue with C. below.

3 Yes Submit a list of the previously approved water treatment additives and the date they were approved. The information listed in C 1-8 must be updated if it has changed since the previous approval.

C Submit a list of water treatment additives that are or may be discharged from the facility. Applicants must submit the information listed below for each additive.

1. The water treatment additive Matenal Safety Data Sheet 2 The proposed water treatment additive discharge concentration.

3 The discharge frequency (i e., number of hours per day, week, etc).

4. The outfall the water treatment additive is to be discharged from.

5. The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6 The water treatment additive function (i e, microbiocide, flocculent, etc )

7. A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Cenodaphnia sp , Daphnia sp, or Simocephalus sp).

8. The results of a toxicity test for one other North Amencan freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323 1057(2)(a) of the Water Quality Standards Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in items 7 and 8 above) is currently available in the SWQD files for the water treatment additives listed on the DEQ's Intemet page http:llwww.deq.state.mi.us/swqlgleas/docslwtalWTAlist.doc. If you intend to use one of the water treatment additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive

10. WHOLE EFFLUENT TOXICITY TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years?

If yes, identify the tests and summarize the results below unless the test has been submitted to the department in the last 5 years.

NO

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT-FACILITY NAME NPDES or COC PERMIT NUMBER Outfall Number Donald C. Cook Nuclear Plant - M10005827 -00G

9. WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Hydrochloric Acid (pH control) 11/14/96 change of process application, 11/25/96 approval.

NPDES Permit application approval 9128/00, 5123100 Sulfunc Acid 11/14/96 change of process application, 11/25/96 approval NPDES Permit application approval 9128/00, 5123/00 Sodium Hydroxide 11114196 change of process application, 11/25/96 approval NPDES Permit application approval 9128/00, 5/23/00 Sodium Bisulfite 11/14/96 change of process application, 11/25196 approval.

NPDES Permit application approval 9128/00, 5123/00 Citnc Acid 11/14/96 change of process application, 11/25/96 approval.

NPDES Permit application approval 9128100, 5/23/00 Phosphonc Acid 11/14/96 change of process application, 11/25196 approval.

NPDES Permit application approval 9128/00, 5123100 Tide Detergent or equivalent 11/14/96 change of process application, 11/25/96 approval.

NPDES Permit application approval 9/28/00, 5/23/00 i

1-

- i

+

4 4

i I

32 EQP 4659-C (Rev 1/03)

Section III.B Outfall OGH

Michigan Department of Environmental Quality- Surface Water Quality Division DaEi - WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information nplete a separate Section III.B - Outfall Information (pages 26-31) for each outfall at the facility Make copies of this blank section

.he application for additional outfalls as necessary.

PLEASE TYPE OR PRINT FACILITY NAME, NPDES PERMIT NUMBER l OUTFALL NUMBER Donald C. Cook Nuclear Plant l M10005827 OOlH

1. OUTFALL INFORMATION (see page 25 for instruction on completion of this page)

Watershed A.

Lower St Joseph Receiving Water B. I n - 1)1 -

County Township C. Lake Bemen

%, % l Section Town Range D. 1 06s 19W SW NW 06 Latitude Longitude E. 86 34' 30" 41 58 30" -

F. Type of Wastewater Discharged (Check all that apply to this outfall)

LI Contact Cooling E] Sanitary Wastewater LI Groundwater Cleanup [I Storm Water (regulated)

S Noncontact Cooling 3 Process Wastewater L Hydrostatic Pressure Test D Storm Water (not regulated)

ElStorm water subject to effluent guidelines (indicate under which category)

E] Other - specify (see 'Table 8 - Other Common Types of Wastewater" in appendix)

J. What is the maximum Facility Design Flow Rate 26 MGD G What is the maximum discharge flow authonzed for this outfall. Seasonal Dischargers MGY Continue with Item H.

Continuous Dischargers 26 MGD Continue with Item I.

H. Seasonal Discharge List the discharge penods (by month) and the volume discharged in the space provided below.

From - Through Discharge Volume Annual Total From Through Discharge Volume From Through Discharge Volume From Through Discharge Volume Continuous Discharge How often is there a discharge from this outfall (on the average)? 24 Hours/Day 365 Days/Year Batch dischargers must provide the following additional information:

Is there effluent flow equalization? LIYes [] No Batch Peak Flow Rate Number of batches discharged per day:

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

I Michigan Department of Environmental Quality-,Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION'.

SECTION III - Industrial and Commercial Wastewater B. Outfall Information

'ASE TYPE OR PRINT JILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827

• OOH

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE This information is used to determine the applicable federal regulations for this discharge. The information required to be reported is dependent on the type of facility. Page 7 of the appendix contains an abbreviated list of various industnes and the types of information each shall report in this application. For assistance call the Permits Section. All industries shall provide the name of each process and the SIC or the NAICS code for the process. If the wastestream is not regulated under federal categorical standards, the applicant shall report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information see page ii, item 8.

PROCESS INFORMATION A. Name of the process contnbuting to the discharge. Steam electric B. SICorNAICScode 4911 C. Describe the process and provide measures of production (see the instructions to determine the appropnate information to be reported)- See vanous contributing waste streams in Section I. Item 10.

PROCESS INFORMATION A Name of the process contnbuting to the discharge:

B. SIC or NAICS code.

C. Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported):

PROCESS INFORMATION A. Name of the process contributing to the discharge.

B. SIC or NAICS code C Describe the process and provide measures of production (see the instructions to determine the appropriate information to be reported)

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code' C. Descnbe the process and provide measures of production (see the instructions to determine the appropnate information to be reported).

PROCESS INFORMATION A. Name of the process contributing to the discharge' B. SIC or NAICS code:

C. Describe the process and provide measures of production (see the instructions to determine the appropnate information to be reported):

K>

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE-PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

- STRUCTlONS FOR COMPLETING SECTION 111, ITEM B.3. v-Carbon, Total Suspended In accordance with 40 CFR 122 21, all applicants must report CBOD 5, Chemical Oxygen Demand, Total Organic that reporting of data for Solids, Ammonia as N, Temperature (both summer and winter), and pH. The applicant may, however, request The request shall be one or more of these required parameters be waived. Such request must be supported by adequate rationale included as an attachment to this application.

and expected or estimated Report available discharge data for the parameters listed. Actual data shall be provided for existing discharges to provide reduction of data provided for proposed discharges Please include an explanation if 'Pollution Prevention" is expected specific types of discharges pollutants. See Page 8 of the appendix for a list of specific parameters for which data must be provided for etc.). For assistance in determining the appropriate parameters to report, (e.g., noncontact cooling waters, gasoline groundwater cleanups, call the Permits Section.

spaces provided or If data are available for other parameters not listed in Section III.B.3, the applicant shall report these data in the blank attach the information to this application on 8%" x 11" paper.

check the appropriate Report all data in the units provided and for the sample types specified in the table. If more than one option is available, per liter, 'F = degrees Fahrenheit, OC = degrees Celsius See box. The units are as follows: pg/I - micrograms per liter, mg/I = milligrams page ii number 5 for analytical requirements.

other frequency-sample To analyze for pH, temperature, total residual chlonne, oil and grease, and fecal coliform use Grab Samples unless suspended solids use 24-type analyses are available. To analyze for total BOD 5, total phosphorus, COD, TOC, ammonia nitrogen and total hour composite samples unless other frequency-sample type analyses are available office to sample and analyze only For two or more substantially identical outfalls, permission may be requested from the appropriate district by the district office, on a one outfall and submit the results of the analysis for other substantially identical ouffalls. If the request is granted which were not sampled are separate sheet attached to the application form, identify which outfall was sampled and descnbe why the outfalls

'maximum daily substantially identical to the outfall which was sampled. See pages ii and iii for sampling definitions, including concentration", and 'maximum monthly concentration".

REPORTING OF INTAKE DATA limitations for one or Applicants are required to report intake water data when they are attempting to demonstrate eligibility for 'net" effluent present in the intake waters more pollutants A net" effluent limitation is determined by subtracting the average level of the pollutant(s) limitations only in certain remaining after treatment which is not removed by the treatment system. NPDES regulations allow net mass of the results of the circumstances (see 40 CFR Part 122 45(g)) To demonstrate eligibility, report the average concentration and/or mass after treatment. In analyses on the intake water. If the intake water is treated priOr to use, report the intake concentrations and/or addition to the analytical results, the following information shall be submitted for each parameter.

is not to the same a) A statement that the intake water is drawn from the body of water into which the discharge is made. If the discharge body of water from which the water is withdrawn, the facility is not eligible for net limitations.

wastewater. Limitations for b) A statement of the extent to which the level of the pollutant in the intake water is reduced by treatment of the the net removal of pollutants are adjusted only to the extent that the pollutant is not removed.

of the extent c) When applicable (for example, when the pollutant represents a class of compounds, e.g , BODs, TSS, etc.), a demonstration Limitations to which the pollutants in the intake vary physically, chemically and biologically from the pollutants contained in the discharge are adjusted only to the extent that the concentrations of the intake pollutants vary from the discharged pollutants groundwater.

Note: Applicants for groundwater remediation discharges should also report the intake characteristics of contaminated

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER-DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information

-ASE TYPE OR PRTINT

...ILITY NAME I NPDES PERMIT NUMBER I OUTFALL NUMBER Donald C. Cook Nuclear Plant - M10005827 - l OOH

3. WASTEWATER CHARACTERISTICS - CONVENTIONAL POLLUTANTS - Instructions for completing this page are on the facing page.

Z Check this box if additional information is included as an attachment To submit additional information see page il. item 8.

>Max IM , -im-Maximumin

<KK~aiy+1. ~  ;. Numer of Parameter Concentration Concentration units; Analyses . S Type, mgA E] Grab Biochemical Oxygen Demand - five day (BOD 5) 26 7 26.7 mg/I2 24 Hr Comp mg/l E] Grab COD (Chemical oxygen demand) 8 07 8 07 mg/i 2 0 24 Hr Comp TOC (Total organic carbon) 2 2 mg/I 2

El E

Grab 24HrComp mg/i 17 Grab Ammonia Nitrogen (as N) 3 88 3 88 2 3 24 Hr Comp al Grab Total Suspended Solids 15 15 mg/ 2 24Hrab mp Total Dissolved Solids 4104 3108 mg/I 52 ElGrab 24HraComp Total Phosphorus (as P) 0.5 0 09 mg/l 98 24 Hr Comp maximum-7day counts/i1O0mI Fecal Coliform Bacteria (report geometric means) NA NA ____________ NA Grab E mg/I I Residual Chlorine <0.08 <0.08 El jg/I 2 Grab Dissolved Oxygen minimum daily NA NOEl so . mo .

NA Grab El 24 Hr Comp

" .-I pH minimum maximum standard units Grab (report maximum and minimum of individual samples) 24 9.1 23 El 24 Hr Comp Temperature, Summer 'NA *NA *NA 24 Hr Comp Temperature, Winter *NA *NA *NA El 24 HraComp Oil & Grease 89 6 mg/i 120 Grab mg/i I Grab Hydrazine 5 54 14 04 120 El 24 Hr Comp El Grab

_ 24 Hr Comp E Grab

________El 24HFr Comp-E Grab See Attached for additional Data 24HraCompb E Grab

• NA - Internal Outfall ________El 24 Hr Comp E Grab

_ 24 Hr Comp E Grab

____ ____ El24 Hr Camp El Grab

_ _ _ _ __ __ _ __ _ _ __ _ __ __ _ _ _ __ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ El 24 H r C amn El Grab j

Fl 24 Hr Como . a

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information BASE TYPE OR PRINT NPDES PERMIT NUMBER OUTFALL NUMBER

..ILITY NAME Donald C Cook Nuclear Plant M10005827 OOH 4 PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION for selected organic pollutants Existing primary industries that discharge process wastewater must submit the results of at least one effluent analysis Requirements for Organic Toxic Pollutants by Industrial Category), and all the pollutants identified in Table 2 (as determined from Table 1, Testing must also provide the results of at least one effluent analysis for any other chemical listed in Table identified in Table 3 Existing primary industries 2 known or believed to be present in facility effluent in Tables 2 and 3.

In addition, submit the results of all other effluent analyses performed within the last 5 years for any chemical listed for any chemical listed in New primary industries that propose to discharge process wastewater must provide an estimated effluent concentration Tables 2 and 3 expected to be present in facility effluent

5. DIOXIN AND FURAN CONGENER INFORMATION propanoic acid, (Silvex, 2,3,5-Existing industries that use or manufacture 2.3,5-trichlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-tnchlorophenoxy) 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel), 2,4,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon),

or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in tnchlorophenol (TCP) or hexachlorophrene (HCP),

the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6 All effluent analyses for facility effluent, must submit dioxin and furan congeners must be conducted using EPA Method 1613.

congener listed in Table 6 In addition, submit the results of all other effluent analyses performed within the last 5 years for any dioxin and furan propanoic acid (Silvex, New industries that expect to use or manufacture 2,3,5-tnchlorophenoxy acetic acid (2,4,5-T), 2- (2,3,5-tnchlorophenoxy) phosphorothionate (Ronnel), 2,4,5-2,3,5-TP), 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in trichiorophenol (TCP) or hexachlorophrene (HCP), or knows or has reason facility effluent must provide estimated effluent concentrations for the dioxin and furan congeners listed In Table 6 r OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION results of at least one effluent Existing secondary industries, or existing pnmary industries that discharge non-process wastewater, must submit the analysis for any chemical listed in Tables 2 and 3 known or believed to be present in facility effluent Tables 2 and 3 In addition, submit the results of all other effluent analyses performed within the last S years for any chemical listed in must provide an estimated effluent New secondary industnes, or new primary industnes that propose to discharge non-process wastewater, concentration for any chemical listed inTables 2 and 3 expected to be present infacility effluent.

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION in Table 4 known or All existing industries, regardless of discharge type, must provide the results of at least one analyses for any chemical listed and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to believed to be present in facility effluent, years for any chemical listed in be present in facility effluent In addition, submit the results of any effluent analysis performed within the last 5 Tables 4 and 5.

in Tables 4 and 5 expected to New industnes, regardless of discharge type, must provide an estimated effluent concentration for any chemical listed be in facility effluent

8. INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED for any toxic or otherwise New or existing industnes, regardless of discharge type, must provide a measured or estimated effluent concentration identified in this application. Quantitative injurious chemicals known or believed to be present in facility effluent that have not been previously effluent data that are less than 5 years old for these chemicals must be reported.

submit additional information NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on page 31. To an E in the 'Analytical Method" column. The following fields must be see page ii, item 8 If the effluent concentrations are estimated, place CAS No, Concentration(s), Sample Type, Analytical Method, Quantification Level and Detection Level.

completed for each data row Parameter, See page ii, number 5 for analytical test requirements

Michigan Department of En\ :mental Quality- Water Division F- i WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant M10005827 00_1H SAMPLE DATE 4 t

>. .vCAS2',

)Conc.- ,Conc., ,Corc. -2Conc. Conc. , -Conc. Conc. - 'Conc. f Conc.', . Conc. Sample'l Analytic '

PARAMETERt  ; , < iK > No(ug/I)n"; (ug 1) .(ug/i)w Y (ug/l) r(ug/1) (U9 /1)'" (ugAl)- (ugh/) ' Type 7< ' tai O Q L, See Attached for additional data.

( Q S EQF

\ C (Rev 1/03)

(7 (

Section III.B.6 and 7 Additional Sample Data OOH Summary Sheet For Outfall OOH Sample Analytical Max # o Parameter 213199 3126102 5130102 type Max Daily Method monthly Analyses See Attached data set from Belmonte Park Laboratories.

Table 3TiT . ________77

<1 <1 - Grab <1 204 2/200.8 <1 2 Antimony (ugtl)

Arsenic (ug/) <1 3.27 <1 Grab 3 27 206 2/200.8 3 27 3 Beryllium (ug/l) <1 <0.2 - Grab <1 200.7/200.8 <1 2 Cadmium (ug/) <0 2 <0.2 Grab <0 2 213.2/200 8 <0 2 2 Chromium (ug/) <10 <10 . Grab <10 200.7/200 8 <10 2 Copper (ug/l) 4 7.26 20 Grab 20 220 21200 8 20 3 Lead (ug/l) <1 3.49 3 Grab 3.49 239 2/200 8 3.49 3 Nickel (ug/l) <5 <5 - Grab <5 249 2/200.8 <5 2 Total Phenols (ug/) 30 - Grab 30 420 1 30 1

<1 . Grab <1 200.7/200 8 <1 1 Selenium (ug/l) -

Silver(ug/l) <0 5 <0.5 Grab <0 5 272.2/200 8 <0.5 2

<1 <1 Grab <1 279 2/200 8 <1 2 Thallium -(ug/), -

Zinc (ugA) , 17 11 Grab 17 200.7/200 8 17 2 Cyanide (mg/i) <0 005 Grab <0.005 335.2/335 3 <0.005 1 Mercury (ng/l) . 10 7 4.7 Grab 10.7 1631 10.7 2 T~ a b i bNj eS ii _ _E_

See Attached data set from Belmonte Park Laboratories.

See Attached data set.

i X Tabste, 5j,; . f ,an, l£Xj2 8;Iirae )-it See Attached data set from Belmonte Park Laboratories.

See Attached data set. III _

dr

-I A. \* . I NPDES Application Section III.B.6&7 Table 4 data for Outfall OOH Analyzed by Cook Plant Lab.

(TRS Discharge to Groundwater operating data)

Sample Analytical Date O&G mg/I Date O&G mg/I type method OL DL Jan-99 <5.0 Nov-99 <5.0 Grab USEPA 413 1 15 5

<5.0 <5 0

<50 <50

<50 <50 Feb-99 <5 0 Dec-99 <5 0

<50 <50

<50 <50

<50 <50 Mar-99 <5 0 Jan-00 <5 0

<5.0 <50

<5.0 <5.0

<50 <5.0

<50 Feb-00 <5.0 Apr-99 <5 0 <5.0

<50 <5.0

<50 <50

<50 <5.0 May-99 <5 0 <5 0 6 <50

<50 X <50

<50 <50

<5.0 Apr-00 <5.0 Jun-99 89 <5.0

<50 <5.0

<50 <50

<50 <50

<5 0 May-00 <5 0 Jul-99 <5 0 <5 0

<50 <50

<50 <50

<50 <50 Aug-99 <5.0 Jun-00 <5.0

<5.0 <5.0

<50 <5.0

<5.0 <5 0 Sep-99 <50 Jul-00 <5 0

<50 <50

<50 <50

<50 <50

<50 Aug-00 <50 Oct-99 <5.0 <5 0

<5.0 <5.0

<50 <5.0

_ <5 0 <5.0 Sep-00 <5.0 l <5 0

_ <5 0

<5 0

<5 0 Oct-00 <5 0

<5.0

<5.0

NPDES Application Section III.B.6&7 Table 4 data for Outfall OOH Analyzed by Cook Plant Lab (TRS Discharoe to Groundwater oieratinm data)

Sulfate Sulfate Analytical Date mg/I Date mg/ c3ample type method CL DL Jan-01 39 Dec-01 41 - Composite USEPA 375 4 30 10 42 41 74 42 41 41

__ _ 55 41 43 Jan-02 43 47 - 34 46 38 1550 25 196 34 Feb-01 49 Feb 27 50 26 41 __ _ _ _ _ 35 39 __ _ _ _ _ 34 Mar-01 44 Mar-02 28 125 ____ 47 33 64 3 46 36 Apr-01 37 40 45 Apr-02 44 48 28 760 23 May-01 600 23 34 __ _ _ _ _ 38 96 May-02 33 47 31 43 80 34 27 43 Jun-02 23 Jun-01 50 92 39 39 37 47 39 Jul-02 38 Jul-01 26 53 29 48 38 -35 34 20 Aug-01 37 Aug-02 29

____ 902 49 74 57 42 49 41 Sep-02 53 38 42 26_ ____ ___ 41 Sep-01 24 - 52 26 Oct-02 52 21 47 700 50 Oct-01 19 _ 61 31 70 28 Nov-02 84 38 __ _ 53 31 41 Nov-01 45 48 37 Dec-02 249 34 64 37 43

I I

I - "

NPDES Application Section III.B.6&7 Table 4 data for Outfall OOH Analyzed by Cook Plant Lab.

(TRS Discharme to Groundwater onpratbnn dta) .

Total Total Phosphorus Phosphorus - Analytical Date - mg/l Date mg/l Sample type method DL DL Jan-99 0 04 Feb-00 0.02 Composite - USEPA 365 1 0.3 0.1 0.01 <001 0.01 O 01 002 002 Feb-99 0 01 Mar-00 <0 01 001 <001 0 02 <0.01 0 01 <0.01 Mar-99 0 01 <0.01 0 01 0.02 0.02 Apr-00 0 02 001 002

<001 <001 Apr-99 0 03 0.01 I <0 01 May-00 0.01 0.02 <0 01 0.01 <0 01 May-99 <0 01 <0 01 002 001 0 02 0 01 0 02 Jun-00 0 02 Jun-99 0 02 <0.01 0 01 <0.01 0 01 <0.01

<0 01 Jul-00 0 01 001 _ <001 Jul-99 0 02 0 01 001 003 0 03 Aug-00 <0 01 "-'I 0.01 <001 0.45 0.02 0 04 0.04 Aug-99 0 01 <0 01 0 01 Sep-00 0 01 001 c<001 001 002 Sep-99 0 01 0.01 0 03 Oct-00 <0.01 002 002 0.02 <001 0 02 Oct-99 0.02 0.02

________ 0 01__ _ _ _ _ _

0 05 Nov-99 0 01

<0.01 _

002 001 Dec-99 0 01 0.01 .

0 02

<001 0.03 045 Jan-00 0 05 0.28 003 007

NPDES Application Section III.B.6&7 Table 5 data for Outfall OOH Analyzed by Cook Plant Lab.

tTRS nlqrhnrnp to Groindwater oneratino data)

Hydrazine Hydrazine Hydrazine Analytical ug/l Date ug/l Date ug/I Sample type method OL - - DL Date Oct-00 <1 0 <10 <3 Grab ASTMD 1385 3 10 -

14 4 Jul-01 <10 <3

<10 <10 <3

<10 <10 May-02 8100

<10 <3 5 Nov-00 <10 Aug-01 <3 <3

<10 <3 14040 361 <3 Jun-02 159

<10 <3 186 Dec-00 445 <3 35 37.9 <3 <3 48 Sep-01 152 Jul-02 <3

<10 196 <3 Jan-01 <10 <3 - <3

<10 347 _ _ _ 3

<10 Oct-01 266 4640

<10 341 Aug-02 <3

<10 <3 <3

<10 <3 <3 Feb-01 <10 <3 -<3

<10 Nov-01 <3 Sep-02 <3 82 ___ _ 72 11

<10 <3 22 Mar-01 <10 <3 - 8

<10 Dec-01 <3 <3

<10 <3 Oct-02 <3

<10 <3 <3 Apr-01 19 6 <3 <3

<10 Jan-02 <3 . <3

<10 <3 Nov-02 <3

<10 <3 19 5

<10 206 . 15.3

<10 14 <3 May-01 <10 Feb-02 14 Dec-02 <3

<10 9 <3

<10 <3

<10 35

<10 Mar-02 <3 Jun-01 <10 <3

<10 __ _ _ _ <3 _ _ _ _

<10 15

<10 Apr-02 4.4

<10 <3 .

Information 12-THP-6020.AD1kI.010 Rev. 5B Page 7 of 8 ANALYTICAL RESULTS Data Sheet 2 NPDES Results Page: 7 Sample Identification: / A S 6'1 A A 9 Sampler's Initials:J Sample Date: 3?-

2 2 SampleTime: nS 3-5 Received Date/Time: kj ^ Receiver's Initials: ) A Analysis Date 3 4-CALCULATIONSMElESULTS S (W. (WI) x 1000/ () ppm CDMS Trend

.(W . (S)(O)(D)

Results in Spec TD#(W -(W ppm Analysis Tim:c Equip ID. Analyst's Initials:

R - (Wr) (WI) (W (W p CDMS Trend

. (S)(1)(D)

_ _ _ Results in Spec TD (R) -(B) .,, /(V)

• R-=.

- 'r (WI - ppm

,, __,, -(W x T  !-i,

.Aalysis Timel: .Equip ID.: Analyat's Initials.

____Tis rme:

.T-al'i Equip ID.:Analyst's (iplutionFactor) qi D: 6" x (apRe Initials:

• (S)XI)D)

_Lppm_

mgeLup)

I

1 Results in Spec CDMSSGDTrend

. . * *e . R-. Results in Spec Time: - -alysi-s Equip ID.:

• Analyst's Initials: *

.SDmp ResuFto pp Reesunt pm M CDMSTrend flution Facutor pp ST#: . eslt pm (S)(l)(D)

DMmr nalysis Tim: Equip Analysis Timm Equip ID.-:

ID.: Analyst's Initials:.*RsltnSe Analyst's Initials: Results in Spec Analysis T:Analysis Time Equipment ID Results Anailyts CDMS Trend lr~~e ___ __ _ _P_

S-mH-Sults </;5- i , ~ Initials J i Spec Comments/Corrective Actions/Notifications:

Verificd C.:

-- I.at____ . _~ _ ~ 1

Procedure-Usage Level: Information 12 THP 6020 ADM.010 ATTACHMENT 2 -

NPDES RESULTS Sample Identification: T& e yb_ " 9, 1A // , 1 XZ Sampler's Initials: cz ° -.

Sample Date: (60h Sample Time: /2k9 Received Date/Time: .-5-7 Receiver's Initials: -

A nalvsis Dante- -K- -"e CALCULATIONS/RESULTS DS KWr) .(W.) x 1000(V) = ppm . CDMS Trend

- (SXIXD)

. Results in Spec TDu - .......... W,)

............ *(W,) x 10001(V) ...... ....................... ... . ppmpe Reut nalysisTime. Equip ID.: Analyst's Initials.

r Ml R&G (W.) . ( - CDMS Trend (SXIXD)

Results in Spec

..,,(R) - (B) . ppm T#R - (w,) * (W.) B W - (W

• I) mwi-(A) - (B) I (C) _ ppm

. .......... ~~q i ID..--.----------.-...... A..i..s..1n.i.. .................. ......................................................

SS 1A) *(B) x IDOO/(C) ~ppm, SS A;-(BjxlO;(C p CDMS Tred .

(SXIXD)

Results in Spec TDu ) tA -F(B) x1 Rdi(C) / F 1ppm alysis Time: Equip ID.: Analyst's Initials 0 kD7iuton Factor) x (Sanple Reading) - rnglL(ppm) CDMS Trend o V.d rR(SXIXD)

I ~ Results in Spec TD# sDilution Factor) x (Stsandrd Reading) F' nzt/L(pptn)

Analysis Time: Equip ID.: Analyst's Initials:

~aPleTHeaue eut CDMS Trenid STD# [be~orerncal Vaiue - Stadard Temperature: Res(ult-ql~D~e Anlysis Time: Equip ID.: Analysts Initialst:

Total P Result - ppm STD#: Result - ppm CDMS Trend (SXIXD)

Analysis Time: Equip ID: Analyst's Initials: Results in Spec Analysis Analysis Time Equipmfent ID Results Analysis CDMS Trend Khp ,,. JO ,1,Initials Comments/Corrective Actions/Notifications:

)*LOQ X r201i ,-S Ii tials

• KOW Reviewters Initals: />

Page I of I P ANA c; Cm

1, - I I -N b Belmonte Park .> ,

) FV Environmental Laboratories AMERICAN ELECTRIC POWER (AEP) Order #: 99-02-232 1 COOK PLACE Date: 03/16/99 09:23 BRIDGMAN, MICHIGAN 49106 Work ID: OUTFALL OOH - OOB (FAX)

Date Received: 02/03/99 Attn: BLAIR ZORDELL Date Completed: 03/16/99 Purchase Order: 4307976 Invoice Number: Client Code: AEP_4 ND= NONE DETECTED OHIO CERT.# 12345 SAMPLE IDENTIFICATION Sample Sample Sample Sample Number De_scription Number Description 01 OUTFALL 0OH 02/03/99 16 OUTFALL OOB 02/03/99 02 OUTFALL 0OH 02/03/99 17 OUTFALL 00B 02/03/99 03 OUTFALL 0OH 02/03/99 18 OUTFALL 00B 02/03/99 04 OUTFALL 0OH 02/03/99 19 OUTFALL OOB 02/03/99 05 OUTFALL 0OH 02/03/99 20 OUTFALL 00B 02/03/99 06 OUTFALL 0OH 02/03/99 21 OUTFALL OB 02/03/99 07 OUTFALL 0OH 02/03/99 22 OUTFALL 0OB 02/03/99 08 OUTFALL 0OH 02/03/99 23 OUTFALL 00B 02/03/99 09 OUTFALL 0OH 02/03/99 24 OUTFALL 00B 02/03/99 10 OUTFALL 0OH 02/03/99 25 OUTFALL OOB 02/03/99 11 OUTFALL 0OH 02/03/99 26 OUTFALL 00B 02/03/99 12 OUTFALL 0OH 02/03/99 27 OUTFALL 00B 02/03/99 13 OUTFALL 0OH 02/03/99 28 OUTFALL OOB 02/03/99 14 OUTFALL 0OH 02/03/99 29 OUTFALL OOB 02/03/99 15 OUTFALL 0OH 02/03/99 30 OUTFALL 00B 02/03/99 Enclosed are results of specified samples submitted for analyses. If there are any questions, please contact Matt Lake. Our Ohio EPA Certification numbers are 836 & 837.

Any result of "BDL" indicates "BELOW DETECTION LIMIT".

MATT LAKE Committed to Quality Since 1958 11 East Main Street Daytona Ohio 45426 (937)837-3744

lb Belmonte Park ra Environmental J B Laboratories Order # 99-02-232 z Page 2

- TEST RESULTS BY SAMPLE -

03/16/99 09:23 OUTFALL 00E 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: OA Detection Result Limit Units Analyzed hl Test Description EPA 405.1 6 2 mg/L 02/08/99 PT 5day CBOD, 15 S mg/L 02/11/99 KC SUSPENDED SOLIDS,EPA 160.2 Sample: 02A OUTFALL DOE 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection' Result Limit Units Analyzed Test Description BDL 5 mg/L 02/19/99 LG COD, EPA 410.4 EPA 415.1 2.0 1 mg/L 02/09/99 JW TOC, OUTFALL ODE 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 03A Detection Result Limit Units Analyzed

' Test Description BDL 0.5 mg/L 02/11/99 JB AMMONIA N, EPA 350.2 OUTFALL DOE 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 05A Detection Result Limit Units Analyzed By Test Description SD EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 OUTFALL ODE 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 06A Detection Result Limit Units Analyzed By Test Description BDL 0.05 mg/L 02/15/99 RJE ALUMINUM, EPA 200.7 BDL 0.001 mg/L 03/05/99 RJE ANTIMONY, EPA 204.2 BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 206.2 0.019 0.005 mg/L 02/13/99 RJE BARIUM, EPA 200.7 BDL 0.001 mg/L 02/13/99 RJE BERYLLIUM, EPA 200.7 BDL 0.05 mg/L 02/15/99 RJE BORON, EPA 200.7 BDL 0.0002 mg/L 03/08/99 RJE CADMIUM, EPA 213.2 BDL 0.01 mg/L 02/13/99 RJE CHROMIUM, EPA 200.7 BDL 0.01 mg/L 02/15/99 RJE COBALT, EPA 200.7 0.004 0.001 mg/L 03/08/99 RJE COPPER, EPA 220.2 0.3 0.1 mg/L 02/13/99 RJE IRON, EPA 200.7 BDL 0.001 mg/L 03/05/99 RJE LEAD, EPA 239.2 BDL 0 .01 mg/L 02/15/99 RJE LITHIUM, EPA 200.7 Committed to Quality Since 1958 Dayton. Ohio 45426 (937) 837-3744 11 East Main Street

Mat Belmonte Park

M M Environmental v aw Laboratories i

Order # 99-02-232 Page 3 03/16/99 09:23 TEST RESULTS BY SAMPLE Detection Test Description Result Limit Units Analyzed By MAGNESIUM, EPA 200.7 a 1 mg/L 02/15/99 RJE MANGANESE, EPA 200.7 0.01 0.01 mg/L 02/13/99 RJE MERCURY, EPA 245.1 BDL 0.0002 mg/L 02/15/99 RJE METALS DIGESTION, WATER EP MOLYBDENUM, EPA 200.7 BDL 0.01 mg/L 02/13/99 RJE NICKEL, EPA 249.2 BDL 0.005 mg/L 03/08/99 RJE SELENIUM, EPA 200 .7 BDL 0.1 mg/L 02/13/99 RJE SILVER, EPA 272.2 BDL 0.0005 mg/L 03/08/99 RJE STRONTIUM, EPA 200.7 0.08 0.01 mg/L 02/15/99 RJE THALLIUM, EPA 279.2 BDL 0.001 mg/L 03/08/99 RJE URANIUM EPA 200.7 BDL 0.1 mg/L 02/15/99 RJE ZINC, EPA 200.7 BDL 0.02 mg/L 02/13/99 RJE Sample: 07A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By SULFIDE, EPA 376.1 BDL E mg/L 03/05/9 9 LG TOTAL CYANIDE, EPA 335.2 BDL 0.01 mg/L 03/04/99 LG Sample: 08A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed PHENOLICS, EPA 420.1 0.03 0.01 mg/L 02/23/99 JB Sample: 09A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By CHLORINE, RESIDUAL TOTAL BDL 0.05 mg/L 02/04/99 ML Sample: 10A OUTFALL OOH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY NITRATE-NITRITE N 0.36 0.2 mg/L 02/05/99 LG ORGANIC NITROGEN BDL 0.5 mg/L 02/11/99 JB PHOSPHORUS, EPA 365.1 BDL 0.1 mg/L 02/18/99 LG TKN, EPA 351.3 0.52 0.5 mg/L 02/06/99 J1B vg' K>

Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

Ii j 1 11 . -1

-I

~~~~ I, K ' 1k Belmonte Park j a Environmental As Laboratories Order # 99-02-232 Page 4 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample: 1lA OUTFALL 0OH 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed OIL & GREASE, EPA 413.1 BDL 5 mg/L 02/04/99 PT Sample: 12A OUTFALL DO0 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit - Units Analyzed SF GROSS ALPHA, IN WATER BDL 3 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 4 pCi/L 03/08/99 SF RADIUM, IN WATER BDL 1 pCi/L 03/10/99 SF RADIUM-226, IN WATER BDL 1 pCi/L 03/10/99 SF Sample: 13A OUTFALL 00E 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY METHYLENE BLUE ACTIVE SUB. BDL 0 .01 mg/L 02/17/99 ML SULFATE, EPA 375.4 19 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 14A OUTFALL 00H 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By ASBESTOS WATER ND 0.2 MF/L, >10um 02/12/99 EM Sample: 16A OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed BY 5day CBOD, EPA 405.1 82 2 mg/L 02/08/99 PT BDL 5 mg/L 02/11/99 KC SUSPENDED SOLIDS,EPA 160.2 Sample: 17A OUTFALL 0OB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Result Limit Units Analyzed By Test Description EPA 410.4 331 20 mg/L 02/19/99 LG COD, EPA 415.1 19.9 1 mg/L 02/09/99 JW TOC, 10 Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

MDl Belmonte Park Environmental J Laboratories Order # 99-02-232 Page 5 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample: 18A OUTFALL 008 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By AMMONIA N, EPA 350.2 43.4 0.5 mg/L 02/12/99 JB Sample: 20A OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analvzed Sy EPA 625 SEMI VOL. EXTRACT SD EXTRACTION, EPA 608 SD Sample: 21A OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed 0.21 0.05 mg/L 02/15/99 RJE I J ALUMINUM, EPA 200.7 ANTIMONY, EPA 204.2 BDL 0.001 mg/L 03/05/99 RJE ARSENIC, EPA 206.2 BDL 0.001 mg/L 03/05/99 RJE BARIUM, EPA 200.7 BDL 0.005 mg/L 02/13/99 RJE BERYLLIUM, EPA 200.7 BDL 0.001 mg/L 02/13/99 RJE BORON, EPA 200.7 BDL 0.05 mg/L 02/15/99 RJE CADMIUM, EPA 213.2 BDL 0.0002 mg/L 03/08/99 RJE CHROMIUM, EPA 200.7 BDL 0.01 mg/L 02/13/99 RJE COBALT, EPA 200.7 BDL 0.01 mg/L 02/15/99 RJE COPPER, EPA 220.2 0.007 0.001 mg/L 03/08/99 RJE IRON, EPA 200.7 BDL 0.1 mg/L 02/13/99 RJE LEAD, EPA 239.2 BDL 0.001 mg/L 03/05/99 RJE LITHIUM, EPA 200.7 BDL 0 .01 mg/L 02/15/99 RJE MAGNESIUM, EPA 200.7 BDL 1 mg/L 02/15/99 RJE MANGANESE, EPA 200.7 BDL 0 .01 mg/L 02/13/99 RJE MERCURY, EPA 245.1 BDL 0.0002 mg/L 02/15/99 RJE METALS DIGESTION, WATER EP MOLYBDENUM, EPA 200.7 0.02 0 .01 mg/L 02/13/99 RJE NICKEL, EPA 249.2 BDL 0.005 mg/L 03/08/99 RJE SELENIUM, EPA 200.7 BDL 0.1 mg/L 02/13/99 RJE SILVER, EPA 272 .2 BDL 0.0005 mg/L 03/08/99 RJE STRONTIUM, EPA 200.7 BDL 0.01 mg/L 02/15/99 RJE THALLIUM, EPA 279.2 BDL 0.001 mg/L 03/05/99 RJE URANIUM EPA 200.7 BDL 0.1 mg/L 02/15/99 RJE ZINC, EPA 200.7 BDL 0.02 mg/L 02/13/99 RJE K>

Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

a VI Belmonte Park j r ^ Environmental Laboratories Page 6 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 22A Detection Result Limit Units Analyzed BL Test Description 14 1 mg/L 03/05/99 LG SULFIDE, EPA 376.1 BDL 0.01 mg/L 03/04/99 LG TOTAL CYANIDE, EPA 335.2 OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 23A Detection Result Limit Units Analyzed By Test Description BDL 0.01 mg/L 02/23/99 JB PHENOLICS, EPA 420.1 OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 24A Detection Result Limit Units Analyzed Test Description BDL 0 .05 mg/L 02/04/99 ML CHLORINE, RESIDUAL TOTAL OUTFALL 00B 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 25A Detection Limit Units Analyzed fBY Test Description Result BDL 0.2 mg/L 02/05/99 LG NITRATE-NITRITE N 10.3 0.5 mg/L 02/06/99 JB ORGANIC NITROGEN LG BDL 0.1 mg/L 02/18/99 PHOSPHORUS, EPA 365.1 53.7 0.5 mg/L 02/06/99 JB TKN, EPA 351.3 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 26A OUTFALL 00B Detection Result Limit Units Analyzed BYx Test Description PT BDL 5 mg/L 02/04/99 OIL & GREASE, EPA 413.1 02/03/99 Collected: 02/03/99 Category: AQUEOUS Sample: 27A OUTFALL 00B Detection Limit Units Analyzed fix Test Description Result BDL 3 pCi/L 03/08/99 SF GROSS ALPHA, IN WATER BDL 4 pCi/L 03/08/99 SF GROSS BETA, IN WATER BDL 1 pCi/L 03/10/99 SF RADIUM, IN WATER BDL 2. pCi/L 03/10/99 SF RADIUM-226, IN WATER Committed to Quality Since 1958 Davton. Ohio 45426 (937) 837-3744 11 Cgnct Nlnini qtnnof

M &NBelmonte Park V L Environmental -

3. Laboratories Order # 99-02-232 z Page 7 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample: 28A OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By METHYLENE BLUE ACTIVE SUB. BDL 0.01 mg/ L 02/17/99 ML SULFATE, EPA 375.4 BDL 10 mg/L 02/18/99 JB SULFITE, BDL 2 mg/L 02/17/99 ML Sample: 29A OUTFALL OOB 02/03/99 Collected: 02/03/99 Category: AQUEOUS Detection Test Description Result Limit Units Analyzed By ASBESTOS WATER ND 0.2 MF/L, >lOum 02/12/99 EM

)

Committed to Qualilty Since 1958 11 East Main Street Dayton, Ohio 45426 (937)837-3744

I I -

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', *Belmonte Park

) W & Environmental AM Laboratories Order # 99-02-232 Page 8 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 04A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2

) CHLOROETHANE CHLOROFORM BDL BDL 10 2

1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE BDL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE *BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 TRICHLOROETHENE BDL 2 VINYL CHLORIDE BDL 10 BDL 10 XYLENES SURROGATE %RECOVERY LIMITS D4-1,2 DICHLOROETHANE 114 76 - 114 D8-TOLUENE 93 88 - .110 Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

Belmonte Park iiEnvironmental O Laboratories Order # 99-02-232 Page 9 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 04A Test

Description:

EPA.624 Method: 624 Test Code: 624 X Collected: 02/03/99 Category: AQUEOUS 4-BROMOFLUOROBENZENE 95 86 - 115 Notes and Definitions for this Report:

DATE RUN 03/10/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020932 UNITS U.q/L METHOD EPA 624 BDL BELOW DETECTION LIMIT

)

Committed to Quality Since 1958 11 East Main Street Dayton. Ohio 45426 (937) 837-3744

I , ,I I

Belmonte Park

) h Environmental-Laboratories Page 10 order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH -02/03/99 Lab No: O0A Method: 625 Test Code: 625 AE Test

Description:

EPA 625 SEMI VOLATILES Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 50 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 10 PHENOL BDL 10

) ACENAPHTHENE BDL 50 BENZIDENE BDL 10 1,2,4-TRICHLOROBENZENE BDL- 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10

- BDL 1,4-DICHLOROBENZENE 20 3,3-DICHLOROBENZIDINE BDL 10 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 BDL 10 FLUORANTHENE 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL- 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE - - - BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 BDL 10 NAPHTHALENE BDL 10 NITROBENZENE N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10 BIS(2-ETHYLHEXYL)PHTHALATE BDL Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

z I -1 I

= -. Belmonte Park mr , Environmental

) Laboratories Order # 99-02-232 Page 11 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No:,05A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/03/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO (A) PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANTHRENE BDL 10

) DIBENZO(A,H)ANTHRACENE INDENO(1,2,3-CD)PYRENE BDL BDL 50 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200 SURROGATE %RECOVERY LIMITS NITROBENZENE-dS 88 35 - 114 2-FLUOROBIPHENYL 77 43 - 116 p-TERPHENYL-d14 90 33 - 141 PHENOL-d6 38 10 - 94 2-FLUOROPHENOL 32 21 - 100 2,4,6-TRIBROMOPHENOL 36 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/25/99 ANALYST TC INSTRUMENT GC/MS FILE ID S9022527 UNITS uq/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

Belmonte Park C Environmental

j. Laboratories Page 12 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 05A EPA 608 Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES Collected: 02/03/99 5 - Category: AQUEOUS PARAMETER RESULT LIMIT BDL 0. 010 ALDRIN BDL 0 .010 ALPHA-BHC BETA-BHC BDL 0.010 BDL 0. 010 DELTA-BHC BDL 0 . 010 GAMMA-BHC CHLORDANE BDL 0.010 BDL 0 .010 4,4-DDT BDL 0 .010 4,4-DDE 0.010 4,4-DDD BDL 0.010 DIELDRIN BDL 0. 010 ALPHA ENDOSULFAN BDL 0 .010 BETA ENDOSULFAN BDL 0 .10 ENDOSULFAN SULFATE BDL 0.010 ENDRIN BDL 0 .020 ENDRIN ALDEHYDE BDL 0 .030 HEPTACHLOR BDL 0.10 HEPTACHLOR EPOXIDE BDL 1 PCB-1016 BDL 2 PCB-1221 BDL 1 PCB-1232 BDL BDL 1 PCB-1242 BDL 1 PCB-1248 BDL 1 PCB-1254 BDL 1 PCB-1260 BDL 0.20 TOXAPHENE SURROGATE %RECOVERY LIMITS RECOVERY) 90, 70 - 130 DBC(SURROGATE,  %

94 70 - 130 2,4,5,6-TCX(SURROGATE % REC.)

Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020942 UNITS us/L Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

- AS lb Belmonte Park j

MP Environmental I

Laboratores Order # 99-02-232 Page 13 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample Descriptionf: OUTFALL OOH 02/03/99 Lab No: 05A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/03/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT j

Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937)837-3744

' a Belmonte Park -

. M, Environmental Laboratories Page 14 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOH 02/03/99 Lab No: 15A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER BDL 5 SURROGATE %RECOVERY LIMITS NITROBENZENE-D5 105 35 - 114 120 0 43 - 116 2-FLUOROBIPHENYL

.p-TERPHENYL-d14 125 33 - 141 PHENOL-d6 40 10 - 94 53 21 - 100 2-FLUOROPHENOL

-150 0 10 - 123 2,4,6-TRIBROMOPHENOL Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST JAT INSTRUMENT. SATURN FILE ID 0206505W UNITS ug/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 I1I 9:rict lUnin (Ztrgmof Davton. Ohio 45426 (937) 837-3744

Belmonte Park Environmental

,41 Laboratories Order # 99-02-232 Page 15 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOB 02/03/99 Lab No: 19A Test

Description:

EPA 624 Method: 624 Test Code: 624 X Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT ACROLEIN BDL 20 ACRYLONITRILE BDL 20 2-CHLOROETHYLVINYL ETHER BDL 20 BENZENE BDL 2 CARBON TETRACHLORIDE BDL 2 CHLOROBENZENE BDL 2 1,2-DICHLOROETHANE BDL 2 1,1,1-TRICHLOROETHANE BDL 2 1,1-DICHLOROETHANE BDL 2 1,1,2-TRICHLOROETHANE BDL 2 1,1,2,2-TETRACHLOROETHANE BDL 2

) CHLOROETHANE BDL BDL 10 2

CHLOROFORM 1,1-DICHLOROETHYLENE BDL 2 1,2-TRANS-DICHLOROETHYLENE BDL 2 1,2-DICHLOROPROPANE BDL 2 CIS-1,3-DICHLOROPROPYLENE BDL 2 TRANS-1,3-DICHLOROPROPYLENE 3DL 2 ETHYLBENZENE BDL 2 1,2-DICHLOROBENZENE BDL 2 1,3-DICHLOROBENZENE BDL 2 1,4-DICHLOROBENZENE BDL 2 METHYLENE CHLORIDE BDL 10 CHLOROMETHANE BDL 10 BROMOMETHANE BDL 2 BROMOFORM BDL 2 DICHLOROBROMOMETHANE BDL 2 TRICHLOROFLUOROMETHANE BDL 2 CHLORODIBROMOMETHANE BDL 2 TETRACHLOROETHYLENE BDL 2 TOLUENE BDL 2 BDL 2 TRICHLOROETHENE VINYL CHLORIDE BDL 10 XYLENES BDL 10 SURROGATE %RECOVERY LIMITS D4-1,2 DICHLOROETHANE 112 76 - 114 D8-TOLUENE 93 88 - 110 K-I Committed to Qualily Since 1958 I11 East Main Street Dayton, Ohio 45426 (937) 837-3744

- I I I - I go 0E., Belmonte Park wt f Environmental .

" Laboratones Page 16 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00B 02/03/99 Lab No:.19A Method: 624 Test Code: 624 X Test

Description:

EPA 624 Collected: 02/03/99 Category: AQUEOUS 92 86 - 115 4-BROMOFLUOROBENZENE Notes and Definitions for this Report:

DATE RUN 02/09/99 ANALYST JMM INSTRUMENT GC/MS FILE ID 9020933 UNITS uq/

METHOD EPA 624 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

• Belmonte Park KI 1 Environmental e ILaboratories Order-# 99-02-232 Page 17 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 0OB 02/03/99 Lab No: 20A Test

Description:

EPA 625 SZMI VOLATILES Method: 625 Test Code: 625 AE Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT 2,4,6-TRICHLOROPHENOL BDL 10 4-CHLORO-3-METHYLPHENOL BDL 10 2-CHLOROPHENOL BDL 10 2,4-DICHLOROPHENOL BDL 10 2,4-DIMETHYLPHENOL BDL 10 2-NITROPHENOL BDL 10 4-NITROPHENOL BDL 50 2,4-DINITROPHENOL BDL 50 2-METHYL-4,6-DINITROPHENOL BDL 50 PENTACHLOROPHENOL BDL 50 PHENOL BDL 10 ACENAPHTHENE BDL 10 BENZIDENE BDL 50 1,2,4-TRICHLOROBENZENE BDL 10 HEXACHLOROBENZENE BDL 10 HEXACHLOROETHANE BDL 10 BIS(2-CHLOROETHYL)ETHER BDL 10 2-CHLORONAPHTHALENE BDL 10 1,2-DICHLOROBENZENE BDL 10 1,3-DICHLOROBENZENE BDL 10 1,4-DICHLOROBENZENE BDL 10 3,3-DICHLOROBENZIDINE BDL 20 2,4-DINITROTOLUENE BDL 10 2,6-DINITROTOLUENE BDL 10 FLUORANTHENE BDL 10 4-CHLOROPHENYL PHENYL ETHER BDL 10 4-BROMOPHENYL PHENYL ETHER BDL 10 BIS(2-CHLOROISOPROPYL) ETHER BDL 10 BIS(2-CHLOROETHOXY) METHANE BDL 10 HEXACHLOROBUTADIENE BDL 10 HEXACHLOROCYCLOPENTADIENE BDL 10 ISOPHORONE BDL 10 NAPHTHALENE BDL 10 NITROBENZENE BDL 10 N-NITROSODIMETHYLAMINE BDL 10 N-NITROSODIPHENYLAMINE BDL 10 N-NITROSODI-N-PROPYLAMINE BDL 10 BDL 10 K>

BIS(2-ETHYLHEXYL)PHTHALATE Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937)837-3744

- -M Belmonte Park.

.plan Environmental

_"001 Laboratories Order # 99-02-232 Page 18 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL 00B 02/03/99 Lab No: 20A Test

Description:

EPA 625 SEMI VOLATILES Method: 625 Test Code: 625_AE Collected: 02/03/99 Category: AQUEOUS BUTYL BENZYLPHTHALATE BDL 10 DI-N-BUTYL PHTHALATE BDL 10 DI-N-OCTYL PHTHALATE BDL 10 DIETHYL PHTHALATE BDL 10 DIMETHYL PHTHALATE BDL 10 BENZO(A)ANTHRACENE BDL 10 BENZO(A)PYRENE BDL 10 3,4-BENZOFLUORANTHENE BDL 10 BENZO(K)FLUORANTHENE BDL 10 CHRYSENE BDL 10 ACENAPHTHYLENE BDL 10 ANTHRACENE BDL 10 BENZO(GHI)PERYLENE BDL 50 FLUORENE BDL 10 PHENANITHRENE BDL 10 DIBENZO(A,H)ANTHRACENE BDL 50 INDENO(1,2,3-CD)PYRENE BDL 50 PYRENE BDL 10 ETHANOL AMINE BDL 100 HYDRAZINE BDL 200

- SURROGATE %RECOVERY LIMITS NITROBENZENE-d5 86 35 - 114 2-FLUOROBIPHENYL 74 43 - 116 p-TERPHENYL-d14 91 33 - 141 PHENOL-d6 76 10 - 94 FLUOROPHENOL 82 21 - 100 2,4,6-TRIBROMOPHENOL 78 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/07/99 DATE RUN 02/26/99 ANALYST TC

- INSTRUMENT GC/MS FILE ID S9022605 UNITS ua/L METHOD EPA 625 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

C ,11Belmonte Park Environmental Laboratores Order # 99-02-232 Page 19 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL O0B 02/03/99 Lab No: 20A Test

Description:

PCB/PESTICIDES EPA 608 Method: 608 Test Code: 608 Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT ALDRIN BDL 0 . 010 ALPHA-BHC BDL 0 . 010 BETA-BHC BDL 0 .010 DELTA-BHC BDL 0 .010 GAMMA-BHC BDL 0 . 010 CHLORDANE BDL 0 . 010 4,4-DDT BDL 0 . 010 4,4-DDE BDL 0 . 010 4,4-DDD BDL 0 .010 DIELDRIN BDL 0 . 010 ALPHA ENDOSULFAN BDL 0 .010 BETA ENDOSULFAN BDL 0. 010 ENDOSULFAN SULFATE BDL 0 .10 ENDRIN BDL 0 . 010 ENDRIN ALDEHYDE BDL 0 .020 HEPTACHLOR BDL 0.030 HEPTACHLOR EPOXIDE BDL 0. 10 PCB-1016 BDL 1 PCB-1221 BDL 2 PCB-1232 BDL 1 PCB-1242 BDL 1 PCB-1248 BDL 1 PCB-1254 BDL 1 PCB-1260 BDL 1 TOXAPHENE BDL 0 .20 SURROGATE WRECOVERY LIMITS DBC(SURROGATE, % RECOVERY) 93 70 - 130 2,4,5,6-TCX(SURROGATE % REC.) 95 70 . - 130 Notes and Definitions for this Report:

EXTRACTED 02/06/99 DATE RUN 02/09/99 ANALYST JW INSTRUMENT GC FILE ID A020943 UNITS uq/L Committed to Quality Since 1958 11 East Main Street Dayton, Ohio 45426 (937) 837-3744

m a - Belmonte Park

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Laboratories Page 20 Order # 99-02-232 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL OOB 02/03/99 Lab No: 20A Method: 608 Test Code: 608 Test

Description:

PCB/PESTICIDES EPA 608 Collected: 02/03/99 Category: AQUEOUS METHOD EPA 608 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 Dayton, Ohio 45426 (937) 837-3744 11 East Main Street

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I I 0 Belmonte Park 4 4 Environmental Laboratories Order # 99-02-232 Page 21 03/16/99 09:23 TEST RESULTS BY SAMPLE Sample

Description:

OUTFALL COB 02/03/99 Lab No: 30A Test

Description:

Triaryl Phosphate Sub-Out Method: Special Test Test Code: 8270 U Collected: 02/03/99 Category: AQUEOUS PARAMETER RESULT LIMIT TRIPHENYL PHOSPHATE ESTER BDL 5 TRICRESYL PHOSPHATE ESTER BDL 5 SURROGATE %RECOVERY LIMITS NITROBENZENE-D5 80 35 - 114 2-FLUOROBIPHENYL 80 43 - 116 p-TERPHENYL-dl4 73 33 - 141 PHENOL-d6 10 10 - 94 2-FLUOROPHENOL 4 0 21 - 100 2,4,6-TRIBROMOPHENOL 4 0 10 - 123 Notes and Definitions for this Report:

EXTRACTED 02/08/99 DATE RUN 02/11/99 ANALYST MN INSTRUMENT SATURN FILE ID 0206502W UNITS ua/L METHOD 8270 BDL BELOW DETECTION LIMIT Committed to Quality Since 1958 I1I Coct Uriin qtr,=,t f)ovton. Ohio 45426 (937) 837-3744

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K - Facility name: -NPDES Permit number. Outfall Number-lDonald C. Cook Nuclear Plant -- ^lMI0005827 - l00H1 Addendum to NPDES Renewal Application Section III.B.10 Toxic Pollutant Reasonable Potential Effluent Data Sampling results indicate the presence of toxic pollutants in the Cook Nuclear Plant discharges as follows:

Strontium was detected in Outfall OOH (Turbine Room Sump). There are no plant processes that use strontium. Strontium is a trace element (21 S among the elements in the earth's crust) usually associated with calcium and barium minerals in veins in limestone.

The chief use of strontium is in fireworks, red signal flares, or on tracer bullets.

Therefore, we do not believe that there is reasonable potential for strontium to be present in these discharges as a result of plant operations. We believe that strontium is present in the intake.

Copper was detected in Outfall OOH (Turbine Room Sump). Based on knowledge of the plant processes, there is reasonable potential for copper to be present in these discharges.

Michigan Department of Environmental Quality- Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT-- --

FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Donald C. Cook Nuclear Plant l M10005827 - l00H

9. WATER TREATMENT ADDITIVES Water treatment additives include any matenal that is added to water used at the facility or to a wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authonzed by the DEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this application A Are there water treatment additives inthe discharge from this facility?

E No, proceed to item 4.

ED Yes B Have these water treatment additives been previously approved?

LI No, continue with C below E Yes. Submit a list of the previously approved water treatment additives and the date they were approved The information listed in C. 1-8 must be updated if it has changed since the previous approval.

C Submit a list of water treatment additives that are or may be discharged from the facility Applicants must submit the information listed below for each additive.

1. The water treatment additive Matenal Safety Data Sheet 2 The proposed water treatment additive discharge concentration 3 The discharge frequency (I e, number of hours per day, week, etc)

4. The outfall the water treatment additive is to be discharged from 5 The type of removal treatment, if any, that the water treatment additive receives prior to discharge.

6 The water treatment additive function (i e , microbiocide, flocculant, etc.)

7. A 48-hour LC50 or EC50 for a North Amencan freshwater planktonic crustacean (either Cenodaphnia sp , Daphnia sp , or Simocephalus sp)

8. The results of a toxicity test for one other North Amrencan freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for a rainbow trout, bluegill, or fathead minnow.

The required toxicity information (descnbed in items 7 and 8 above) is currently available in the SWOD files for the water treatment additives listed on the DEQ's Intemet page http:llwww.deq.state.mi.us/swq/gleasldocs/wtalWTAiist.doc If you intend to use one of the water treatment additives on this list, only the information in items 1 through 6 above needs to be submitted to the SWQD.

Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive.

10. WHOLE EFFLUENT TOXICITY TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water in relation to facility discharges within the last three years?

If yes, identify the tests and summarize the results below unless the test has been submitted to the department in the last 5 years.

NO

Michigan Department of Environmental Quality-Surface Water Quality Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME l NPDES or COC PERMIT NUMBER Outfail Number Donald C. Cook Nuclear Plant l M10005827 OOH 9 WATER TREATMENT ADDITIVES Water Treatment Additive Approval Date Hydrochloric Acid (pH control) 11114/96 change of process application, 11/25196 approval.

NPDES Permit application approval 9128/00, 5/23/00 Sulfuric Acid 11/14/96 change of process application, 11/25/96 approval NPDES Permit application approval 9128100, 5/23/00 Sodium Hydroxide 11/14/96 change of process application, 11/25/96 approval NPDES Permit application approval 9128/00, 5/23/00 Sodium Bisulfite 11/14/96changeofprocessapplicaton, 11/25I96approval NPDES Permit application approval 9/28/00, 5/23/00 Citric Acid 11/14/96 change of process application, 11/25/96 approval NPDES Permit application approval 9/28/00, 5/23/00 Phosphoric Acid 11/14/96 change of process application, 11/25/96 approval NPDES Permit application approval 9128/00, 5/23/00 Tide Detergent or equivalent 11/14/96 change of process application, 11/25/96 approval NPDES Permit application approval 9/28/00, 5/23/00 Aluminum sulfate 7/20/94 Ethanolamine solution, such as 5/23/00 NPDES Permit approval 9/28/95 Betz Powerline 1440, Betz Powerline 1480, Nalco 92UM001 Hydrazine Solution, such as 5/23/00 NPDES Permit approval 9/28/95 Betz Cortrol os5035, (Formerly Betz Powerline 1205), Betz Cortrol OS5010, Nalco 19H Carbohydrazide Solution such as- 3/25/94 application, 4/15/94 approval, NPDES Permit approval 9/28/95 Nalco 1250 plus, Nalco Eliminox

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32 EQP 4659-C (Rev 1/03)

Section III.C Michigan Department of Environmental Quality- Water Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater

__ C. Signature Page LEASE TYPE OR PRINT X FAcILITY NAME NPDES PERMIT NUMBER r- -.- -n% I oiiinnssR97 I Donaid C. CooN rNdUdeatrdI

1. CERTIFICATION Rule 323 2114(1-4) promulgated under the Michigan Act, requires that this application be signed as follows:

is A. For a corporation, by a principal executive officer of at least the level of vice president, or their designated representative if the representative of the facility from which the discharge described in the permit application or other NPDES form originates.

responsible for the overall operation B. For a partnership, by a general partner.

C. For a sole proprietorship, by the proprietor.

D. For a municipal, state, or other public facility, by either a principal executive officer, the mayor, village president, city or village manager or other duly authorized employee.

Note: If the signatory is not listed above, but is authorized to sign the application, please provide documentation of that authorization.

system

'I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a designed to assure that qualified personnel properly gather and evaluate the information submitted Based on my inquiry of the person orpersons of my who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best accurate, and complete I am aware that there are significant penalties for submitting false information, including the knowledge and belief, true, possibility of fine and impnsonment for having knowledge of violations."

Print Name: J. E. Pollock

Title:

Site Vice President Representing' Indiana Michigan Power Signature, Date: 3llSI6 3 This completes Section 1II. Return the completed application (Sections l, IlIl and any attachments) to the appropriate district office. See pages 2 and 3 of the appendix for district office addresses and a map of district boundaries.

If assistance is needed completing this application, contact the Permits Section, telephone number: 517-373-8088.

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32 EQP 4659-C (Rev 1/03)