A97006, Provides Copy of Addendum to Renewal of NPDES Permit IL0002763
| ML20141L827 | |
| Person / Time | |
|---|---|
| Site: | Zion File:ZionSolutions icon.png |
| Issue date: | 05/27/1997 |
| From: | Mueller J COMMONWEALTH EDISON CO. |
| To: | NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM) |
| References | |
| ZRA97006, NUDOCS 9706020299 | |
| Download: ML20141L827 (50) | |
Text
-
1- EJ Commonweahh iilison Compan3 Zion Generating Station 4
, 101 Shiloh lioulevard Zion. IIJMPA2797 Tel847? h 2084 May 27, 1997 M l
)
ZRA97006 l l
1 U. S. Nuclear Regulatory Commission I Document Control Desk Washington, DC 20555-0001
Subject:
Zion Station Units 1 and 2 l Addendum to Renewal of NPDES Permit No. IL0002763 l NRC Deket Nos. 50-295 and 50-304
Reference:
April 25,1983 letter from F.G. Lentine ta H.R. Denton l
Commonwealth Edison Company (Comed) is the holder of National Pollutant Discharge Environmental System (NPDES) Permit No. IL0002763 for Zion Station. Comed i recently submitted an addendum to renewal of the . subject NPDES permit to the Illinois l Environmental Protection Agency. In accordance with the reference commitment to l inform the NRC of changes und violations to the NPDES permit, this letter provides a l copy of the addendum to renewal of NPDES Permit No. IL0002763.
Please direct any questions regarding this matter to Mr. R. Godley, Regulatory Assurance l Manager, at (847)746-2084, extension 2900.
' A/b, -
. H. Mueller Site Vice President Zion Station Enclosure i
cc: NRC Region ill Administrator NR C Senior Resident Inspector
(~l CC\ g lilinois Department of Nuclear Safety (IDNS)
IDNS Resident Inspector 9706020299 970527 PDR ADOCK 00000295 ll l l, k:\ comply \cg.nrc\ npdes. doc A I n.com Company L
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March 6,1997 E2(PRESS Mall Mr. Steve Nightingale, P.E.
Manager, industrial Unit, Permit Section Division of Water Pollution Control Illinois Environmental Protection Agency 2200 Churchill Road P.O. Box 19276 Springfield, Illinois 62794 9276
Subject:
Addendum to Renewal of NPDES Permit No. IL0002763. Zion Generatine Station
Dear Mr. Nightingale:
1 Please note the following material concerning the NPDES permit renewal for Zion Station. This I information is in addition to the original permit renewal submitted on August 21,1995. and supplementalinformation submitted on April 10.1996. This letter contains material primarily related to the addition or description of contributory sub-wastestreams to Outfall 00la -
Wastewater Treatment Facility, and Outfall 00lb - Radwar Treatment System Discharge. )
MSDS information relative to chemical descriptions are attached.
The station component cooling water (CCW) system operates as a closed cycle cooling system.
Occasionally, there is a need to blowdown this system. Also, leaks may occur in the system which ultimately drain to auxiliary building floor drains (which is listed as a sub-wastestream to the radwaste treatment system). For corrosion control, this water contains " CECO K" a product containing 10-20% sodium borate. I-5% potassium hydroxide,40-60% potassium nitrite, and small amount of tolyltriazole. CECO K is added to maintain a 700 ppm nitrite concentration within the CCW system. A supplemental 50% sodium tolyltriazole compound and/or a glutaraldehyde solution may also be introduced for added corrosion control. Approximately 15 gallons of the glutaraldehyde solution are added every 6 months. Additionally, small amounts of chromate (0.6 ppm) is present in this system due to historical use of a chromate based corrosion inhibitor. This chemical was replaced with the nitrite-based corrosion control program several years ago. Recently, the station has also noted elevated levels of copper (3 ppm) and iron (0.3 ppm) in the system apparently due to corrosion.
Blowdown of the 25,000 gallon CCW system to the radwaste treatment system (Outfall 00lb) l usually occurs over a three day period and typically involves about 75,000 total gallons of CCW l being discharged (at approximately 17 gpm). Discharges ofleaking CCW involve a much j smaller volume. Average flow from Outfall 001b as reported on Form 2C of the NPDES permit application is 0.031 MGD. This sub-wastestream discharges into either the Unit I (aserage flow
= 877 MGD) or the Unit 2 (average flow = 938 MGD) condenser cooling water systems prior to discharge to Lake Michigan.
l
\ l hum t.omp.my
-- . . . . . , . . . _ . -- - .. ~ .. . _ _ - _ - _ _ . _ .
r March 6.1997 Mr. Steve Nightingale, P.E.
Page 2.
Another input to Outfall 00l(b)- Radwaste Treatmem .vstem, is the u r genemted from the station's containment spray system. T1.is containment oray system war consn s of a 40 %
sodium hydroxide solution. Discharge from the containment spray system occurs approximatelv i once per month due to system testing and typically involves <5 gallons per month per unit.
Given the normally low pH in the radwaste treatment system lake discharge tanks as the result of boric acid inputs, the containment spray water often serves as a butfer.
A third sub-wastestream at Zion Station involves blowdown and/or drabing ofleakiy water from a heat exchanger which is part of the station's HVAC system. T steam / water side of this system transfers heat from the unit steam generators or auxiliary boils a closed system which contains a 50% ethylene glycol solution (soon to be replaced with pn ne glycoh This steam / water-side volume is 10,000 gallons and contains Calgon LCS- . a produ.; ;ontaining 15% sodium nitrite,4% sodium tetraborate pentahydrate, and 1% soonan hydro:. :e. Calgon LCS-20 is added to maintain a 700 ppm nitrite concentration within the 3ystem. G!uraraldehyde solution is also occasionally added (approximately 5 gallons every 6 months) for cm.usion control, along with small amounts of sodium hydroxide for pH control.
Periodically, blowdown from the steam / water side of this system may be drained to Outfall 001 a - wastewater treatment , or to Outfall 00lb - radwaste treatment (depending on draining location). Additionally, leaks involving the steam / water side, or leaks between the closed-loop and the steam / water side (evidenced by small amounts of glycol in water drained or Icaking from the steam / water side) have been known to occur Again, depending on the location of these leaks, water is routed to either wastewater treatment (Outfall 00la) or radwaste treatment (Outfall 00lb). During blowdown operations, water is typically discharged at less than 20 gpm to one of these two outfalls.
A fourth sub-wastestream is water drained from the emerg- ;y diesel generator coolingjackets.
This water, discharged to wastewater treatment (Outfall 00 o, contains the same chemicals in the same amounts as described above for the steam / water sice of the HVAC system, i.e. Calgon LCS-20, and occasionally, glutaraldehyde and sodium hydroxide.
A fifth sub-wastestream involves steam generator (secondary-side) system drainage and blowdown. In addition to discharging this water from the radwaste treatment system (Outfall 00lb), the station also has the ability to route this water to the wastewater treatment system (Outfall 001a) at approximately 50 gpm. Therefore, we request that this sub-wastestream be added as a contributory wastestream to Outfall 00la. Please refer to our addendum dated April 10,1996, for information concerning this wastestream.
Lastly, we wish to clarify information sabmitted previously relative to renewal of the NPF S permit. In the April 10,1996, permit renewal addendum letter, we provided a more comp' te description of how ammonia, hydrazine, and/or carbohydrazide are used and discharged from the secondary side steam system at Zion Station. As a point of clantication. these three chemicats may also be used in station's auxiliary boiler as well as the see ndary side system. The blowdown from the auxiliary boiler is currently listed as a sub astestream to Outfall 00la -
Wastewater Treatment Facility Dischara.
i i March 6,1997 Mr. Steve Nightingale P.E.
Page 3.
Maximum concentration of hydrazine in the auxiliary boiler is approximately 100 ppm.
l Discharges of auxiliary boiler water are typically around 30 gpm to the station's 30,000 gallon i fire & oil sump which discharges to wastewater treatment. Given mixing within the wastewater l treatment and condenser cooling water systems. we anticipate a worst case hydrazine discharpe concentration of approximately 0.04 g/L in the condenser discharge.
Also, we wish to provide additional descriptive information on Primary System Blowdown which is currently listed as a sub-wastestream to the radwaste treatment system (Outfall oolte Small amounts oflithium hydroxide (to maintain a 2-3 ppm concentration) are added to this system for pH control. Additionally, small amounts of hydrogen peroxide and hydrazine (approximately 25 liters and 2 liters, respectively) are added 2-3 times a year during unit shutdowns for corrosion control. Lastly, as you may be aware d, e to the monitoring requiremants on Outfall 001b, boric acid is added to the primary side as a reaction moderator.
This chemical is added in amounts to maintain a boron concentration of 1000-2600 ppm in the primary side.
As a summary to this submitted material, we wish to provide specific language that may be incorporated into the reissued NPDES permit. Modified or additional permit language is in bokt italicized print.
Outfall 001a Internal Waste Streams:
- 1. Fire Sump Discharge Consisting of: j
- a. Turbine building floor and equipment drains (0.2 MGD): l
- i. HVAC system discharge (intermittent) il. emergency diesel generator coolingjacket discharge (intermittent)
- b. Auxiliary boiler blowdown / drain /ieak discharge (intermittent)
- c. Foundation seepage (intermittent) l
- d. Secondary system monitoring drains (0.01 MGD) i I. secondary steam generator discharge
- e. Portable demineralizer filter backwash (0.04 MGO, when discharging)**
- f. Portable demineralizer (EDR, UF) reject (0.09MGD)"
" alternate route Outfall 001b Internal Waste Streams
- 1. Radwaste Demineralizer Treatment System Discharge Consisting of;
- a. Laboratory and sample drains
- b. Containment and auxiliary building floor and equipment drains (0.001 MGD)
- 1. HVAC system discharge * (intermittent) lii. component cooling system discharge * (intermittent) 1 iv. containment spray system discharge * (intermittent)
- c. Radwaste laundry and snower drains * (intermittent)
- d. Primary system blowdown (intermittent)
- 2. Secondary Steam Generator Discharge (intermittent)
- processed as required
i s March 6.1997 Mr. Steve Nightingale, P.E.
Page 4.
If you have questions, or require additional information concerning these u. sues, please give Mr. Doug Yowell of my staff a call at (312)394-4461.
Sincerely,
(-
.)
Jeffrey . Smith Supervisor of Water Quality l
l l
1 1
l l
js/dy/dc
! zionadd2. doc Attachment l
l cc: Mr. Blaine Kinsley, DWPC-IEPA, Permits Section i
1 4
9
.___.m . _ . - - . . _ _ _ - _ _ _ m._ . . . _ _ _ . _
.___..______.c._________.___..__.____._..,
- i
+oooooooooooo+o*co*oo4eocoowoooc* coco *cocoo*oco44c*++++*o*+
fhis is an 1SDS f rom the Commonwealth Edison MSDS Program A1. TENT I ON : Safety and Industrial Hygiene advises users to review the intended use of this information ;
with his/her aupervisor or Safety and Industrial Hygiene advisor.
- ++*********+++++****+****44***44*************************+
Contents for this MSDS
.1~. GENERAL INFORMATION
- 2. HAZAR00US INGREDIENTS
- 3. HEALTH HAZARD DATA
- 4. EMERGENCY FIRST AID PROCEDURES
- 5. SPECIAL PROTECTION INFORMATION
((gg(cp ((_ {
- 6. PHYSICAL / CHEMICAL CHARACTERISTICS *
- 7. FIRE AND EXPLOSION HAZARD DATA ;
- 8. REACTIVITY DATA
- 9. SPILL AND LEAK PROCEDURES '
- 10. SPECIAL PRECAUTIONS i
- 11. REGULATORY INFORMATION '
I l
l 01 - GENERAL INFORMATION l F ilen a rne CE009456.msd POWER GROUP 10470 UEST 164TH PLACE ORLAND PARK IL 60462-
~
BUSINESS PHONE _ _ , .. _ .__... _ ....__ _ _ - -
(700) 403-5656 FOR EMERGENCY HEALTH & SAFETY INFORMATION (800) 424-9300 TRADE NAME:
CECO K COMMENTS THE INFORMATION CONTAINED IN THIS MATERIAL
l THIS PRODUCT DOES NOT CONTAIN ANY MATERIAL SHOUN TO BE A CARCINOGEN BY THE
. NATIONAL TOXICOLOGY PROGRAM (NTP), THE INTERNATIONAL AGENCY FOR RESEARCH i
! ON CANCER (IARC) (*R OSHA. 1
( I
' THIS PRODUCT DOES NOT CONTAIN ANY MATERIAL UHICH IS SUBJECT TO THE ANNUAL REPORTING REQUIREMENTS UNDER SECTION 313 OF SARA, TITLE III. CONTACT THE EPA FOR INFORMATION REGARDING THE REPORTING REQUIREMENTS.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATING (HMIS)
HEALTH (*)' 3 i
y - . ,
p
. j - ~ . .
l 6 FLAMMnUILITY 1 j REACTIVITY O '
PERSONAL PROTECTION H (4) PERSONAL PPOTECTION RECOMMENDalIl SHt +UL D E b EUli BY PU RCri AGE RS .
WORKPLACE CONDITIONS ARE' IMPOR TAN T F .0RS IN ..PECIP [NG OEQUATh' PROTECTION. I PREPARED DY:
MARGARET L. K0 GLOW TITLE:
REGULATORY INFORMATION SPECIr. LIST DATE PREPARED:
MAY G, l'792 1 DATE PRINTED: I AUGUST 4, 1(?(72 SUPERCEDES MSDS DATED:
MSDS CONTROL i:
01HR80204(72 THIS PRODUCT'S SAFETY INFORMA'! ION IS PROVIDED TO ASSIST GUR CUSTOMERS IN 1 ASSESSING COMPLIANCE WITH HEALTH / SAFETY / ENVIRONMENTAL REGULATIONS. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE TO US .ND IS BELIEVED TO BE ACCURA TE. HOUEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY IS EXPRESSED OR TO BE IMPLIED, REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE OBTAINED FROM THE USE THEREOF, OR THE HAZARDS CONNECTED WITH THE USE OF THE PRODUCT. SINCE THE USE OF THIS PRODUCT IS WITHIN THE EXCLUSIVE CONTROL OF THE USER, IT IS THE USER'S OGLICATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. SUCH CONDITIONS SHOULD COMPLY WITH ALL FEDERAL REGULATIONS CONCERNING THE PRODUCT. POWER OROUP ASSUMES NO LI ABILITY FO'i ANY INJURY OR DAMAGE, DIRECT OR CONSEQUENCIAL, RESULTING FROM THE USE i THIS PRODUCT UNLESS SUCH INJURY OR DAMAGE IS ATTRIBUTABLE TO NEGLIGENCE Ul THE PART OF POWER OROUP.
NA = NOT APPLICABLE, ND = NOT DETERMINED, ( = LESS THAN, > = OREATER THAN l 02 - HAZARDOUS INGREDIENTS l
- ++++*********************
CAS N0. CHEMICAL NAME PERCENT 1303-(?d-4 SODIUM BORATE DECAHYDRATE 10-20%
1310-58-3 POTASSIUM HYDROXIDE 1-5%
7758-09-0 POTASSIUM NITRITE 40-60%
l l 03 - HEALTH HAZARD DATA l l
THRESHOLD LIMIT VALUE:
2 mg/m3 IS THE CEILING LIMIT FOR P01ASSIUM HYDROXIDE.
PRIMARY ROUTES OF ENTRY:
(
!# ' INHALATION, . SKIN CONTACT, CYU l-
' EFFECTS OF OVEREXPOSURE:
SEE EVE CONTACT, SKIN CONIACT, AND INHALAI10N FOR f.rFECIS OF OVEREXPOSURE.
CYE CONTACT UILL CAUSE EYE IRRITA TION AND MAY CAUSE DUl!NS .
SKIN CONTACT:
UILL CAUSE SKIN IRRITATION AND MAY CAUSE DURNS.
INHALATION:
INHALATION OF VAPOR OR MIST MAY PRODUCE FESPIRATORY IRRITATION.
- +++++++++++**++++++*+++******+++++*
I 04 - EMERGENCY FIRS T AID PROCEDURES I
- +++++++++++++++++*++*******++***+++*
EYES:
IMMEDIATELY FLUSH UITH PLENTY OF UATER FOR AT LEAST 15 MINUTES.
- SKIN
! UASH IMMEDIATELY UITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND l SHOES. WASH CLOTHING BEFORE REUSE. CALL A PHYSICIAN, IF NECESSARY.
I INGESTION:
CALL A PHYSICIAN PROMPTLY. 00 NOT INDUCE VOMITING. NEVER GIVE ANYTHING l
BY MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE MOUTH-TO-MOUTH RESUSCITATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN.
- +**
l l 05 - SPECIAL PROTECTION INFORMATION l RESPIRATORY PROTECTION:
FOR FIRE CONDITIONS OR EXPOSURE ABOVE TLV: UEAR NIOSH/MSHA APPROVED RESPIRATORS.
VENTILATION REQUIREMENTS:
LOCAL EXHAUST _IS_ RECOMMENDED. .._ -_ - - _ - . - - -- - -- - -
PROTECTIVE GLOVES:
RUBBER EYE PROTECTION:
UEAR SAFETY GOGGLES OTHER PROTECTIVE EQUIPMENT:
UEAR RUSSER APR0N. ,
EYE UASH FACILITY AND SAFETY SHOUER.
l 06 - PHYSICAL / CHEMICAL CHARACTERISTICS l BOILING / MELTING POINT:
>212 F VAPOR PRESSURE (MM HG):
ND VAPOR DENSITY (AIR =1):
ND I >
PERCENT VOLATILE B( VOL UhE - (.4 ) ;
AD-EVAPORATION RATE: 1
'ND pH:
L1.0 0 100%
GPECIFIC GRAVITY (H20=1):
1.264 6 73 F SOLUDILITY IN WATER:
COMPLETELY APPEARANCE AND 000R:
C L E'A R , PALE GREEN LIQUID.
- ++********+++******* '
l 07 - FIRE AND EXPLOSION HAZARD DATA l j
FLASH POINT (METHOD.USED):
NA BOILS >212 F FLAMMABLE LIMITS: 1 ND
-LOWER: i ND ,
UPPER:
ND EXTINGUISHING MEDIA:
CO2, FOAM, DRY CHEMICAL.
SPECIAL FIRE FIGHTING PROCEDURES:
UEAR NIOSH/MSHA APPROVED RESPIRATORS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NONE
- w,,*** .
l 08 - REACTIVITY DA TA l
- l STABILITY: l GTABLE.
CONDITIONS CONTRIBUTING TO INSTADILITY: i NONE.
INCOMPATIBI.ITY: ,
STRONG ACIDS, STRONG OXIDIZERS ,
HAZARDOUS ~ DECOMPOSITION PRODUCTS:
(THERHAL) NONE. ;
s
- - ******+
l 09 - SPIT.L AND LEAK PRC.CDURES l STEPS TO BE TAKEN IN CASE. MATERIAL IS RELEASED OR SPILLED:
DILUTE WITH LARGE VOLUMES OF UATER; NEUTRALIZE WITH MILD ACID. WASH e4REA WITH MILD DETERGENT AND WATER.
I
~__ ___ - _ _ _ . . - - . - - - _ _
- _ - - - ~ . - _ . ._ _ -- _ . .
i UASTE D(3POSAL METHOD: !
UILUre UITH LARGE VOLUMES OF UAIER; NEUTRALIZE WITH hILD ACID. DISPOGE OF IN ACCORDANCE UITH LOCAL, STATE AND FEDERAL EPA REGULATIONS. I I
- +++++++****+++++++*******
l 10 - SPECIAL PRECAUFIONS l u****++**++*4.++++**********
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
00,NOT GET IN EYES OR SKIN, OR ON CLOTHING. 00 NOT TAKE INTERNALLY.
AVOID GREATHING NIST OR VAPOR. KEEP CONTAINER CLOSED. WASH THOROUGHLY HANDLING.
OTHER PRECAUTIONS:
NONE,
++44**+++++++++++++++**********
l 11 -
REGULATORY INFORMATION l
- +++++****++***+************
D.O.T.:
N.A.
PROPER SHIPPING NAME:
N.A.
HAZARD CLASS:
N.A.
UN/NA ID NUMBER:
N.A. ,
T0XIC SUDSTANCES CONTROL ACT (TSCA):
THIS PRODUCT AND/OR ALL THE INGREDIENTS CONTAINED IN THIS PRODUCT HAVE BEEN REGISTERED UNDER THE T0XIC SUBSTANCES CONTROL ACT.
R.C.R.A.:
THIS PRODUCT DOES NOT MEET THE DEFINITIONS OR CONTAIN ANY SUBSTANCE APPEARING IN THC LISTINGS CONTAINED IN 40CFR261, " IDENTIFICATION AND LISTING OF HAZARDOUS WASTE."
-.-- LISTING OF HAZARDOUS WASTE." _ _
l I
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+ + + + o + c o c c o + o + + o o o o + o o o o 4 o 4 + + + 4 4 4 6 4 4 4 4 4 4 4 4 c + -+ + o + 4 4 ao+4++4co This 1.s ca n MSDS from the C o mmo nwealth E d i:s o n nSDS Program ATTENTI0rl: Safety and I n d u .i t r i a l Hygiene advises users to review the intended use of this inf o rmatio n with his/her supervisor er Safety and Industrial Hygiene advisor.
+ + + + -+ 4 4 * * + * + .+ + + 4
- 4 + + + .+ + + + 4 4 + 4 4 4 4 * * *
- 4 4 + 4 +
- 4
- 4 + 4 4 4 * * + + + + * * + +
Contents for this etSOS
- 1. GENERAL INFORMATION srb /', /"l
- 2. SECTION I af
- 3. SECTION II - HAZARDOUS INGREDIENTS
- 4. SECTION III - PHYSICAL DATA
- 5. SECTION IV - FIRE AND EXPLOSION HAZARD DATA
- 4. SECTION V - HEALTH HAZARD DATA
- 7. SECTION VI - REACTIVITY DATA G. SECTION VII - SPILL OR LEAK PROCEDURES
'7 . SECTION VIII - SPECIAL PROTECTION INFORMA TION
- 10. SECTION IX - SPECIAL PRECAUTIONS
- ++++**+++++***********+++**
l 01 - GENERAL INFORMATION l
- ++********+*********
F ilen a rne : CE009457.msd l 02 - SECTION I l
- ++++++*********
_ - - . - - -- -- - - - - - ~ ~ - - - - - - - -
l MANUFACTURER'S NAME l The Power Group, Inc. l ADDRESS /(Number, Street, City, State, and ZIP Code) 10470 U. 164th Place, Orland Park, IL EMERGENCY TELEPHONE NO.
312/403-5656 -
l CHEMICAL NAME AND SYNONYMS Sodium ToIyltriazole - 50% Uater Sol.
TRADE NAME AND SYNONYMS PUR-CORR TT-50-5 CHEMICAL FAMILY Triazole FORMULA C7H6N3NA
- +*********++++**************************
NIG l
.- . l 0 3 -- 5!: JN LI - HMARDOUS 1NGRE
>* m +++ + + + s + + s.s s + k s + + + + + + + + + + + .- we + + +
T.
PAINIC. PRESERVATIVES & .,OLVF ' f 5 % (Units) l PIGMENTS f
~
CATALYST VEHICLE SOLVENTS ADDITIVES OTHERS (Tolyltriazole 50 N/a TLV l
! ALLOYS AND METALLIC COATINGS % (Units)
BASE METAL I
ALLOYS METALLIC COATINGS i FILLER METAL i PLUS COATING OR CORE FLUX I OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS, TLV SOLIDS, OR GASES % (Units) '
Sodium Hydroxide (to raise ph to 13.5 - .3 Caustic may cause burns to eyes and skin).
l
+**********+**********************+*
l 04 - SECTION III - PHYSICAL DATA l
+++++++*****************************
BOILINO POINT (Deg. F) 760 mm Hg 212 SPECIFIC GRAVITY (H20=1) 1.19 e 25 Des. C . - . -- - - - - _
l VAPOR PRESSURE (mm Hg.)
N/A PERCENT, VOLATILE SY VOLUME (%)
N/A VAPOR DENSITY (AIR =1) ;
N/A .
)
EVAPORATION RATE ( ___ = 1) l N/A 13.5 SOLUBILITY IN WATER l complete APPEARANCE AND ODOR Clear, Red-Brown, essetntially .: d a r l es s solution. l l
k k k + + h k k k k k k k k k k v: k k k k k k k k k k k k k k & k k k k k k k k k k k k k k k k k k + k l l 05 - SECTION IV - FIRE AND EXPLOSION HAZARD DATA l l
l
4*+6**oco*o*o+++oooo+oo6444**o*a*4++4444+o*++o**++++
l FLASH POINT (Method used>
N/A FLAMMA0LE LIMITS LEL UEL EXTINGUISHING HEDIA N/A SPECIAL FIRE FIGHTING PROCEDURES N/A UNUSUAL FIRE AND EXPLOSION HAZARl)S None
- +**********************************
l 06 -- SECTION V - HEALTH HAZARD DATA l
++++++************+4*******************
THRESHOLD LIMIT VALUE Talyltriazole oral LD30 - 6.73 mg/kg Rat.
EFFECTS OF OVEREXPOSURE Caustic - may cause burns to skin and eyes.
EMERGENCY AND FIRST AID PROCEDURES Flush thoroughly with water in case of accidental excessive exposure. If eyes are involved, flush with running water for 10 minutes by the clock.
If exposure is severe, refer to doctor immediately.
- +++++*************++++**+*+++***
l 07 - SECTION VI - REACTIVITY DATA l
- +++++++***********+**************+*
STABILITY UNSTABLE e i STABLE eXl CON D I TIONS .-TO - AVO I O -- - - . - - - - - - - - - - -- - - - - - - - - - -
INCOMPATABILITY (Materials to avoid)
Mixture with acids will produce high heats of reaction.
HAZAR000S DECOMPOSITION PRODUCTS May include carbon dioxide, carbon monoxide nitrogen oxides, & hydrogen cyanide.
HAZARDOUS POLYMERIZATION MAY OCCUR e l UILL NOT OCCUR eXl CONDITIONS TO AVOIO
++++++*************************+***+***********
l 08 - SECTION VII - SPILL OR LEAK PROCEDURES l
- ++*********************
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Use suitable absorbent material and flush spill or leak with water.
WASTE DISPOSAL METHOD
r .
.- S te n a t a r y la ndf ill or incinera n in acct oanct with Fr eral, t. a 1. 0 a tu1 local regulations.
4+u*****u* m .* .*+- +*.**++n+44+*+- u4.- m e++++u
- l 09 - SECTION U [ - PECIAL PR0fECTION .NFORMATION l
- ++++.***u** . m . 4************4* u** m ue,4****4 RESPIRATORY PROTI "ON (Specify t y p r* /
N/A VENT,IL A TI ON LOCAL EXHAUST N/A SPECIAL MECHANICAL (General) NA OTHER PROTECTIVE GLOVES Use approved hand protection.
EYE PROTECTION Use approved eye protection.
OTHER PROTECTIVE EQUIPMENT N o r na l work clothes should be changed immediatels fter spill.
- m *++++++*4**+*****++***+****++****
l 10 - SECTION IX - SPECIAL PRECAUTIONS l
- m *****++++*******+*********+++++++**
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Sto res o nly in containers which are resistant to caustic solutions.
OTHER PRECAUTIONS 00 no t take internally. Avoid contact with skin and eyes Do not take internally. Avoid contact wi n sk in and ey e s .
l
- - - - ~ . - -
1
. i i
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l l
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4***4046++b4444*O4.4ew4+*44 444/4A++44&***&*****6+44*++**
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l This 1 s an et5 DS f r a in i roe C o mir.o vs..... .1 l o e' - m m j l
l A I TEi! TION : .i a r e t y and !ndustra A[ M ;
u ut.r s to r e v i e ts fhe latendeel use e
l v2th his/her aqpervinor ve r Safety Hygiene advisor.
b C 6 - 10 l l
e- + + u 4 m u * .m u m u a u 4 4 4 u * + * * * * * , *
- l l Contents for this riSDS
- t. GENERAL INFORMATION I
, 2. Section 1. PRODUCT .!DENTIFICATION 1
! 3. Section 2. INFORhATION ON INGREDIENTS
- 4. Section 3. HAZARDS IDENTIFICATION
, 5. Section 4. FIRST AID hEASURES l a. Sect 2on 5. FIRE-FIGHTIllo hEASURES
- ' ' . Section 6. ACCIDENTIAL RELEASE MEASURES 9 'i e c t i o n 7 HANDLING AND STORAGE l C. Section S. EXPOSURE CON T ROLS .' PERSONAL PROTECTION l 10. Section 1. PHYSICAL AND CHEMICAL PROPERTIES
- 11. Section 10. STABILITY AND REACTIVITY
- 12. Section 1.t . T0XICOLOGICAL INFORMATION
- 13. Section 12. ECOLOGICAL INFORMATION !
- 14. Section 13. DISPOSAL CONSIDERATIONS l
- 15. Sectton 14: TRANSPORr INFORMATION l
- 16. Section 15. REOULor0RY INFORMATION
- 17. Section 16. OTHER INFORMATION I
l l l ;
i
- +++++********+++*****
l 01 - DENERAL INFORMATION i
- - --- m u u u u * *. * * * .+ * * * * * * * * * + + - - - - - - - - - -
F i l en a rn e : CE009879.MSD CALGON CORPORA TION P.O. Dox 1316 Pittsburgh, PA 15230-1346 24 Hour Emergency Telephone .
(412)777-8000 MSDS Code:
0559-07-22-94 Issue Date:
l 07/31/95 While this information and reconsmendations set forth herein are believed to be accurate a s of the date hereof, CALGON CORPORATION MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON.
PREPARED BY:
P.J. Maloney
ODD 6444*4404*kk4*** 4 4
- 4 4 k k 6 .E' k k 4 k O 4 4 ,e 4 + 4 l 02 - fi cc t i o n 1. iDUCT IDENTIFICA ON i 4+k6*aek**k444****44 **444444k44k4+* <kk**
PRODUCT NAME:
LCS-20 MHEMICAL DESCRIPTION:
- .queout 114 a l i n ,+ toletion l PRODUCT CLASS:
( Uatpr treatment l MSDS CODE:
i t
0559-07-22-94 k+****wA++444**+44*********k+***++++***********
l 00 - Section 2. INFORMATION ON INGREDIENTS l
+***+++++++******++k+***********++*k*****+*++,-
CAS T by Chemical Name Number Weight 2 odium ni tr itc 7632-00-0 15 S o d iu rn tetraborate pentahydrate 1217?-04-3 4 Sadium hydroxide 1310-73-2 approx.1 Chemical Name OSHA PEL ACCIH TLV Sodium nitrite None established None establinhed S o d iu rn tetrabc.ato pentahydrate TWA 10 mg/m2 TWA 1 mg/m3 Godium hydrox fe Celling 2 mg/m3 Ceiling .' mg/m3
- +++***+****+++*******+++***+*********+*
l 04 - Section 3. HAZARDS IDENTIFICATION l
- u.+ m ++++++ m +****+**+*+*++++++n******+
l
~~~~ - -~ ~ - - -- ~ ~~~ ~ ~ ~ - ~ ~ ~ ~ ~
- ~ EM E R G EN C Y ~D V E R V I C U ^ --'- - ~ ~ ~ ~ l DANGER!
May cause severe eye and skin Jamage.
'~ a y be harmful if swallowed or af mist inhaled.
May cause respiratory tract irritation. ;
Nitr itets may react with organic amines in the body to form carcinogenic ;
nitrosamines. J PRIMARY POUTES OF ENTRY:
Eye and skin contact, ingestion, inhalation of mint TARGET ORGANS:
Eye, skin, mucous membranes, blood MEDICAL CONDITIONS AGGRAVATED BY EXPOSUPE:
Individuals with pre - existing d i s e a ss e s f the cardiovascular cy t t c*n cnd bo ne rna r ro w may have increased suuep- bility to the toxic effects of excessive exposure to nitrites.
POTENTIAL HEALTH EFFECTS:
EYE CONTACT: This product may cause irreversible eye damage upon contact depending on the length of exposure, solution concentration and first aid l
l l
l
IN e sj *.$ (l } t J:Id 8.Di4 T AC T ; i h .t s product may preduc ew r f ir ' t .i t i e n upuo c o n t. a c t utih the n in. [f not r oeno ved p r e nip t l y , c u r r. - .n a y e :. u l :. . S u d l u :n nitrite and u ti t u ne tetraborite p e n t a hy ri r a t t. ria j 1e absorbed t h r t, 4 9 h d o rsa g f d :; r. i n to amounts that may produce sy si t em i c toxicity limilar to that produced by inJeitien, if Pho area -
e<posure a r. i areu u n t .buorbed are large. No 3 i l e r <J i t sk in reaction is e :, p ec t ed .
1 INGESTION: Ingestien 'i t h i sa product may cause < e vi: r e irritation er ourns or'the mucous membranes of the mouth, throat, esophagua; and stomach. This product would be considered to I.e to xic ty Argestion becausc as little as une g r a in of sodium nitrite may be fatai to humans. Ingestion of large amount'! th a ;f cause nausea, wmiting, headaches, cy a n c : .t s (bluish skin resulting from reduced o xygen-ca r ry i ng capacity of the blood due to methemoglobin production), weakness, ahortneus of breath, a marked fall in blood pressure, collapse, convulsions, coma, and possibly death. Nitrites ;
have been shown to convert in the sto machs o f lab animals to potentially carcinogenic nitrosamines.
INHnLaflON: Product m1st may irritate the respiratory tract, if inhaled.
Large amounts may cause systemic effects, u tiltrates and borates are readily absorbed by lung ticnue.
GUBCHRONIC, CHRONIC:
No applicable information uas found concerning any potential health effects resulting from subchronic or chronic exposure to the product.
R iep e a t e d small doses of nitrites cause a fall in blood pressure, rapid pulse, headache, and visual disturbances. Nitrites have been implicated in an increased incidence of cancer They may react with organic amines in the body to form carcinogenic nitrosamines.
I Repeated or prolonged exposure to n i t r i t e s r.say cause mGthemoglobinemia (decreased o xygen-carrying capacity of the blood). Pregnant wa rne n should minimize exposure to nitrites since the developing fetus may be adversely affected by the nitrite-induced methemoglobinemia.
l Chronic absorption of small amounts of tetraborates causes mild gastroenteritis and dermatitis. Neither type of systemic poisoning has b ete n reported to occur occupationally.
CARCINOGENICITY:
NTP: No ingredients listed in this I;ec t io n IARC: No ingredients listed in this section OSHA: No ingredients listed in this nection l +++++u++++++++unu**+**+u*++*n+*+++
i l 05 - S ec tio n 4. FIRST AID MEASURES l
,+++++o+ m *o m +++* m **++ m +++++++
EYE CONTACT:
In case of contact, immediately flush eyes with plenty of uater for at ;
least 15 minutes. Seek medical aid i mm e d i a t e 1.y . l SKIN CONTACT:
In case of contact, immediately flush skin with plenty of water for at
l .- ..no i '. e .3 ,
r, t c. 9 t :! uh1la e e n,o t tn; e-ue n.. i et :lotn.. :1 h o e s . .ek llel i. c a ( .11 .lemed i a t e 1 y 'J -i : ! t '* '
.9 , 3 t' o r e reuse, INGESTION:
If s wa ll o wed , do NOT .tnduce "o r ,
i m) . Give large quan t :t ic: ci vater, i %ek ca m j i c a l :.1A immediately v.er ejive anything by a,0 v t h to an unconscioun person.
[NHALATION:
If inhaled, r emo ve to fresh a l .: [ i' not breathing, g i vic artificial respiration. If breathing is ' f i c 'J L t . 91ve oxygen. Seek medical aid.
M
- k
- k * * *
- d d 4 .- k*k*+*****44*******k*********
I 06 - Section 5. FIRE-FIGHTING MEASURES l
- +++++*4*+++++*************++******
FLASH POINT:
> 200 Dog. F 1
This product is not by definiti. a " f l :. .:n a b l e liquid" or a " combustible I liquid". If all the water in t '- proder is allowed to evaporate, !
however, it :t h o u l d ba noted thar ' odium itritc is a strong oxidizer. I LOUER FLAMMADLE LIMIT:
Not available UPPER FLAMMAHLE LIMIT:
- Not available AUTO-IGNITION TEMPERATURE
Not available l l EXTINGUISHING MEDIA:
l Use extinguishing media appropriate for the s u r r o u n a .t n g fire, l l
i FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when fighting any chemical fire. A self-contained I breathing apparatus and protective clothing are essi .ial.
FIRE & EXPLOSION HAZARI)S : ;
Product emits toxic gases under fire conditions. I DECOMPOSITION PRODUCTS: ;
Thermal decomposition or combustion may produ:e nia 'jen oxides and I disodlurn oxide.
- -NFPA-RATINGS.
Health = 3 Flammability = 0 Reactivity = 0 Special Hazard = None j Hazard rating scale:
0= Minimal .
l 1= Slight 2=hoderate 3= Serious 4= Severe
+********+********.++++****+++******--*******.****
l 07 - Section 6. ACCIDENTIAL RELEASE MEASUPES l
- ++****+++++++++******************************
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
i 1
. _ _ _ . - . . _ . _ _ . _ _ . ~ _ _ . . _ _ - . . _ _ _ _ . . - _
'*Uoaring appropriate p it r o o n a l p r o t ec t io i. 'l u .t e w? n t , a n t a t r. 'i l: :!1, .:. t' ' ect l- onto non-combustible absorbent ~ lik e aa nd or earth sna place toto Luit ble l cantainer, keep c o rnbu c t i t: l e s (wood, paper, . 21. utc.) away from Epilled matertal. Prevent entry into revers and e a t.e r e.n y s .
l j + + + 4 4 + + + .+ + + + + + & + 4 + + A * + + + + 4 4 4 + + + + + + + + 4 4 & + +
l l 00 ~ Gec t io n 7. HANDLING AND STORAGE l
- ++++44444**4*++++4**+44***************+*
HANDLING:
! Do not get in eyes, on skin or clothing Avoid breathing mist.
Use with adequate ventilation.
Wash thoroughly a t' t e r handling.
Keep container closed when not in use.
STORAGE:
Do not store near combustible materinin.
Product must be maintained at OG Deg. F or higher. Protect t' r o m low temperatures.
l l
l **++***********++****************++*****+*****+*************
l 09 - Sectio n 8. EXPOSURE CONTROLS / PERSONAL PR0fECTION l
- +++++*********************************+++******+*******
PERSONAL PROTECTIVE EQUIPMENT:
EYE / FACE PROTECTION: Chemical splash goggles and face shield SKIN PROTECTION: Chemical resistant gloves and pro tective clo thing RESPIRATORY PROTECTION: If airborne concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
ENGINEERING CONTROLS:
Use local exhaust ventilation where mist or spray may be generated.
WORK PRACTICES:
_ _ .Ey e wa s h -_ s t a ti o n a n d_ saf e ty--sh o we r -sh o u l d -b e -a c c e s s 2 b l e-i re--t he-imined ia te - ---
area of use.
+++++u++++++******++++**+++**++++++***++++***+****** l l 10 - Sectio n 9. PHYSICAL AND CHEMICAL PROPERTIES I
- +++++++*******+4************************ !
l BOILING POINT: i i Not available l SOLUBILITY IN UATER:
l Complete i
UAPOR PRESSURE:
l Similar to water SPECIFIC GRAVITY:
1.16 0 23 Deg. C 4
VAPOR DENSITY (air =1).
Similar to water pH:
l
. - ~. . . _. _ . . - - . _ - - . , .. ,- . -- . . .
= s p p rm .t . t,
~
'!dl. a l' I LE .:V 11E I GH T :
ca p p r o 2: , 70 FPEEZIMG POIN f :
Hot a v a l .L a b l e APPEARANCE AND 000M:
Clear, yellow liquid.
&** u 4 u **+4++ u +44*+++44*++****++ u u .44**-&#.
, l 11 - Sect ; a n 10. GTABILITY AND REAL.i'VITY l 4**4*++**A4+.++kh*+***A********444***&***+****
CHEMICAL OTABILITY:
Stable HAZARDOUS P OL 'i nE R I;.' AT I ON :
Will not occur CONDITIONS TO AVOID:
Keep from contact with clothing and other ccmbustibl- qterials. Protect fram law tempera. 'es.
INC(H1P AT I B ILI TY :
O tre .9 reducers, .cids, amines DEC0i 7SITION PRODUCTS:
Ther el decomposition or c o ribu t t ie n nea y produce nitrogen e x i cle s and d i so d l u rn ovide.
I **A4*444******4****+k4*4**********Ak***********
I i 12 - S ect io n 11. T0XICOLOGICAL INFORMATION l
- +u u* u**.4+u*u *u*+4*44**uw++u ***u ***+* 1 I
ON PRODUCT:
No information available on the formulated product.
ON INGREDIENTS:
Oral LD50 Dermal LD 50 Inhalation LC50 Chemical Name (rat) (rabbit) (rat)
! ~-"~~S o d i u m n i t r i t e ~ ' ~~ ~ ~ G5 "m g / k 9 N o t ~ a va i l a b l e -5500,2 9/m3/ 4 H -- )
S o d iu rn tetraborate l p r.s n t a hy d r a t e 3.2 - 3.4 g/kg > 2 g/kg Not available S o d i u rn hydroxide 140-340 .ng / k g 1350 mg/kg Not available l
+++++++++++++++o***u 4***********+*********
I 10 -- S ec t i o n 12. ECOLOGICAL INFORMATION l
- +++****+***u ***+******++**************+++
.ON PRODUCT:
Aquatic toxicity data:
48 hr LC50 (Daphnia magna): 560 ppm j 76 hr LC50 (fathead minnow): 940 ppm !
48 hr LC50 (mysid shrimp): 004 ppm ;
7-day NGEC (mysid shrimp): 50 rpm 7-day LGEC (mysid shrimp): 100 ppm
. 76 hr LC50 ( sheep shead ru n n o w) : 5400 ppm i
-day HOEC (sheepshead ra i n n o v ) .5^0 ppm
~ ~ flay Lil2C 5She9pShead m 1 H n 3 w .' : O rpm i
1
+ + 4 A A A 4 + + 4 A * .* *
- 6 + + 4 *
- A
- 4 4 + * * + + + + + + + 4 + + + w w +
- 4
- i l 14 - Section 13. DISPO9AL CCNSIDERATIONS l l i * + .4 .+ 4 + + u 4 + + + + + 4 + 4 4 + + + + + + + + + + .+ *
- 4 4 4
- 4
- 4 + + + & +
s RCRA S TA TUS :
If the pH is greater than or equal t c. 12.5, cl i s c a r d ed product uould be corisidered a RCRA Ha z a rdo u s IJast e b a sed on the characteristic of corrosivity. The EPA Ha z a r do u s LJa st e Number vould be D002. l OISPOSAL: 1 Dispose of in accordance with local, state and federal regulations, j Provent entry into sewers or waterways. I i
i u**u.u**++ n*4.**4+++4*+**+++**++.64****++*
l 15 - Section 14: TRANSPORT INFORMATION l l u..+u.++.+++++.u+.++********++++++++.A4*a+***++
00T CLASSIFICAFION:
C la s s/ D ivisio n : 6.1 (RQ at beginning at Proper Shipp2ng Name if shipped in container > 667 lb) 1 Proper Shipping Name: Toxic liquid, inorganic, n.o.s. (contains Sodium <
1 nitrite) l Label: Poison '
l Packing Group: III ID Number: UN 3287 l l
++**++++*+++++****************************** l l 16 -- S ec t i o n 15. REGULATORY INFORMATION l
- ++++****+**********+****++++************++*
, , _ , _ . _ . _ _ . _ _ _ . _ _ _ _ - _ _ - _ _ - _ . - . . - - - -- - - - - -- -- - ~ ~~
OSHA Hazard Communication Status:
Hazaraoun TSCA:
The instredients of this prcduct are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory. (Sodium tetraborate i pentahydrate is not on the TSCA Inventory, but its anhydrous form in listed under CAST 1330-43-4.)
CERCLA reportable quantity of EPA hazardous substances in product:
Chemical Name RQ God 2um nitrite 100 lb Sodium hydroxide 1000 lb Product RQ:
667 lb l (Notify EPA of product spills exceeding this a :n o u n t . ) l SARA TITLE III:
Section 302 Extremely Hazardous Substances:
l l
l 1
_;c ~ . . - . . . - . . . - - . . =
.' C h.e m a c a l M a nne 0 i Pfl No ingredient! !.i S t e d in tht ction SectAon 311 a n d 312 li.ea .l t h a n. y a i c a .! Har rilz Immed i:1te yes Delayed yes Fire no pressure no Reactivity no Section 313 To x ic C hemica s s :
Chem'ical Name CAS 1 A by LJeight S o d i u rn nitrite 7632-00-0 15 4***************4*******************4**
l 17 - S ec tio n 16. OTHER INFORMATION l
++*************************************
llMIS RATINGS:
Health r- 3' >
Flammability = 0 Reactivity =0 Personal Protective Equ2pment = X (to be .pecified by user depending on ;
use conditions)
(*) There are potential chronic health e r'f ec t s to censider.
Hazard rating scale:
0= Minimal 1= Slight 2= Moderate 3= Serious 4= Severe MSDS REVISION
SUMMARY
i Supersedes MSDS issued on 2/9/94. The MSDS has been changed Sect- .i s 14 and 15, i 1
4 9
40*44444444444444h*6A4**444*A $444444A44444 A 4 4 A .4
- 4 4 4 4 4 e 4 w = 4 .-
rht2 t 's . .i n MSDS from t he C o mmu nsaea l th Edi';on nSOS Program A1TENTION: Safety and 1. n d it u t r i a l Hygiene advises users to r ev i ets the intended itse of this tnformation ta i t h hi2/her cupervidor cr afety and Industrial Hygiene advisor.
l + * *
- 4 4 4 4 4 4 .+ 4 4 4 4 4 4
- 4
- 4 + + + * * * *
- 4. * * * * * *
- 4 *
- 4 4 4 * + + + + + + + 4 4 4 4 * * *
- Contents for this MSDS 2.
O tE AL Section 1.
R TION PRODUCT IDENTIFICATION h[v/*ta v 6,
- 3. Section 2. INFORMATION ON INGREDIENTS 4 Section 3. HAZARDS IDENTIFICATION
- 5. Section 4. FIRST AID MEASURES
- 6. Section 5. FIRE-FIGHTING hEASURES
- 7. Section 6. ACCIDENTAL RELEASE MEASURES
- 8. Sec t io n 7 HANDLING AND STORAGE
- 7. Section G. EXPOSURE CONTROLS / PERSONAL PROTECTION l 10. Section 9. PHYSICAL AND CHEMICAL PROPERTIES
- 11. Section 10. STABILITY AND REACTIVITY l 12. Section 1.1 . T0XICOLOGICAL INFORMATION
- 13. Section 12. ECOLOGICAL INFORMATION
- 14. Section 13. DISPOSAL CONSIDERATIONS
- 15. S e c t. i o n 14. TRANSPORT INFORMATION
- 16. Section .15 . REGULATORY INFORMATION
- 17. .S ec t i o n 16. OTHER INFORMATION i
l
- +
- I 01 - GENERAL INFORMATION l l __ _ _ ___ _
--_-+**++***********************------- --
F i l en a rn e : CE010746.msd H-300 Microbiocide l CALGON CORPORATION P.O. Box 1346 Pittsburgh, PA 15230-1346 .
Phone (412)494-8000 MSDS Code:
-0801-07-17-92 l Issue Date:
l 04/10/96 l
l While this information and recommendations set forth herein are believed to be accurate as of the date nereof, CALGON CORPORATION MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON.
PREPARED BY:
P.J. Maloney
.~ .
l
++++++,&u4 s ,.4.+. -444+AAA****+4*. *++,.*****
I 02 ioct a 1 PPODUCi fDENI ~TCAfION l
+44 4*++++*44*++*4****4+**++4 4a**. 4++++++++ -
1 PRODUCT NAME:
H-300 Microblocide CHEHICAL 1)ECC R I PTION :
l Glutaraldehyde, 4 5,*: aqueous solution PRODtJC T CL."iss : l l
Diccide 1
- MSDS CODE:
0801-07 .17 472 u .4. u++ u + u + * + .4 4
- u w w a + 4
- 4 u * * *
- u A
- u + * * * * * *
- i l 03 -- S ec t i o n 2. INFORMATION ON INGREDIENTS l l u .A u + u o u a u
- u * +.A u * * *
- u * * *
- u * * *
- u
- u *
- CAS % by
..~. h e m i c a l flame t'u mb er Ueight OSHA PEL ACGIH TLV Glutacaldehyde 111-30-8 45 Ceiling 0.2 ppm, Ceiling 0.2 ppm, 0.8 mg/m3 0.82 ng/m3
+% +++u +++******+ % ++++*******++*****+++++
l 04 - Section 3. HAZARDS IDENTIFICATION l u*+ a++.* +u ++ u*4*+++********++**+++ -++
EMERGENCY OVERVIEW DANGER!
Hay cause severe eye and skin damage.
Harmful if inhaled.
May be fatal if swallowed.
.._._ H a r mf.u l .i f .a b s o r b ed ..t h r o u g h skin. __ . _ _ ___ ___ .__ _ _ _ _ _
Prolonged or frequently repeated skin contact may cause allergi 4 actions in some Individuals.
Causes asthmatic signs and symptoms in hyper-reactive individua .
PRIMARY ROUTES OF ENTT'(:
Eye and skin contact, inhalation, sk in absorption, ingostion TARGET ORGANS:
Eye, skin, mucous membranes MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Skin contact may aggravate an existing dormatitis. Inhalation e *satorial may aggravate asthma and inflammatory or fibrotic pulmonary disea;2.
POTENTIAL HEALTH EFFECTS:
EYE CONTACT: Liquid will cause a severe and persistent conjuncti tis, seen as excess redness and marked swelling of the conjunctiva witt. profuse l discharSe. Severe corneal injury may develop, which could permanently
! impair vision if prompt first-aid and medical treatment are not obtained.
Vapor will cause stinging sensations in the eye with excess tear i
~ , . . ._ -- . . - . . .. . . - - . . .
1.- .
! "reducti:t b l i r.k .i n g , .nd restar'> a , light e : < i: ' icdors! uf 'ne l
.a n J u ne:t iva .
l< f d CONTACT Prior contact utth the product util cauue itching with mild
'a moderate local redness and possibly swelling. i' r o l o n g e d contact may result in pain, severe redness and swelling, uith ulceration, tissue destruction, and possibly bleeding into the inilameo area. Glutaraldenyde may be absorbed threugh intact kin. therefore, protenged er videtpreac contact with the product .n a y r
- f: u l t in the absorption af potentially j harmful amounts cf material and na y affset the central nirvous rysten
! P r'o d u c i n g headache, dizziness. and dullness, this product may cause allergic contact dermatitis in a small portion of i n d .i v i d u a l s .
Sensitization reactions usually result from contact with the liquid, but l occasionally there may be a reaction to 9.lutaraldehyde vapor.
i INGESTCON: Swallowing this product may cause ino der a te to marked I
irritation or chemical burns of the mouth, throat, esophagus, and stomach, uith discomfort or pain in the mouth, throat, chest, and abdomen, nausea, v o m .t t i n g , diarrhea, d i z :: i n es s , faintness, drovainess, weakness, thirst, circulatory collapse, and coma.
INHALATION: Product vapor 't s ir ri t a ting to the respir a to ry tract, causing stinging mensations in the nose and throat, discharge from the nose, possibly bleeding from the nose, ceughing, chest discomfort and tightness, difficulty with breathing, and headache. Severe exposure may cause central n er vo u s system depression with diz:1 ness and drowsiness. The odor threshold of glutaraldehyde is 0.04 ppm whereas the irritation threshold is 0.3 ppm. If vapors are concentrated enough to be irritating, the TLV is probabLy being exceeded. Inhalation of product can cause signs and symp to ms of an asthmatic attack in hyper-reactive individuals.
GU0 CHRONIC, CHRONIC:
Repeated skin contact may cause a cumulative dermatitis.
CARCIN00ENICITY: ,
NTP: No ingredients listed in this s ti c t i o n IARC: No ingredients listed in this section OSHA: No ingredients listed in this section l
l
+++++++++4k+*++++++++++++++*+++++++++++ l l
l 05 - Section 4. FIRST A10 MEASURE 31 '
m **++u+u++o ++ m +++++++++u+++++++
EYE CONTACT:
(n case of contact, imm'ediately flush eyes with plenty of water for at least 15 minutes. Do not remove contact lenses, if worn. Seek medical i aid immediately.
l SKIN CONTACT:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Seek medical aid immediately. LJ a s h clothing before reuse.
INGEC TICiv :
00 NOT INDUCE VOMITING. Do not g .t v e anything to drink. Seek medical advice with urgency. Note to Physician: Aspiration may cause lung damage. Probable mucosal damage may contraindicate the use of gastric lavage.
1 1
.- I HolALc. I f GN :
~
.' f i re h a l e d , remave to ' rest .r. If t b r e a t h :t n 9 , g i v. : r t i f . c .L a l
" p ': r 1 *. t t, n . If breathing diffic . give oxygen. rk ined ic a l i
1.t d .
{
! ++4-*******.41 - + ++ + +4 4 * *# *i.< * *4 A* * * + * + -+.++ s#-
l l ~ 2act: ," / I T'E -F I Gil f ING .'IE ASU RES !
l > +. r .. r w a
- s u
- r * + r r r s
- r + + -s * * + + * + s * * + < + Va * + 4 * +
l l FLASH '0 IllT :
Nong.
Non-flammabic (aqueous d o l u t i .i n ) : After uater evaporates, remaining raa t er t a l will burn.
l LOUER FLAMMADLE LIMIT:
l Mot determined UPPER FLAMMADLE LIMIT:
j ?!o t determined AUTO-IGNITION TEMPERATURE:
Not available
! EXTINGUISilING MEDIA:
Use alco ho l-type o r all-purpose-type t'o a m , appliad b ., manu .turer'n r ec o mrae n d ed techniques for large fires. Use carbo n d i o x i d .. or dry chemical media for small firen.
FIRE-FIGHTING INSTRUCTIONS:
^
Exercise cau tio n when fighting any chemical fire. , .s el f-c o n t a i n ed breathing apparatus and protective clothing are essential.
FIRE & EXPLOSION HAZARDS:
No unusual hazards.
l DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion may produce carbon monoxide and carbon moHaXide.
NFPA RATINOS:
Health = 3 Flammability =0 Reactivity =0 Special Hazard = None
- Hazard" rating ~acale.
0= Minimal 1= Slight 2=ri o d e r a t e 3= Serious 4= Severe
&A**********************************************
l 07 -
S ec tio n 6. ACCIDENTAL RELEASE MEASURES l
+++++*******+u***++************+**************+
STEPS TO DE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Wear suitable protective equipment. Toxic to fish; avoid discharge to
- natural waters. Very low concentrations (10 ppm or less) can be degr. d l in a biological treatment system. Thus, small spills can be flusned L. h l large quantities of water. Large quantities or " slugs" can be harmful to the t r e a t rne n t 's y s t e m . Thus, large spills should be collected for l
l l _ _ _ . _ _.
t
)
- I i . o d 1 i p a s .) [ . 't .h i ', 3(, $
s ep ,Oqi t, b l ( - t O . l O r C 0 ( H ii) t n D ( ( C p 1 1.I. d d r.)attir1h1 b' l
. ar et a l . c, , i i c u t : c, r .. . c. u e o u , .!tum ' _ d e n r t ) .3 3r . i t b a s t e.,
. ammontum I phosphate io lu tio n. Dep?ndtn9 un conditloos, considerable h e a r, and fumne l .an h9 1 t b .f r a t e d by the d ec o n t ain t n ii t i o n reaction. l 1
4 O k k 4 4 h k 4 4 4 4 4 4 4 k 4 4 k 4 k 4 k k h 4 k 'E % 4 4 k 4 4 0 0 4 M e'r k 4 l 00 - iection 7. !!ANDL ING 6,NO 'ITORAGE j k k u u w 4 + + mu u u u 4 k k + 4 k 4 4 o 4 k 4 u # k u w a H A N I?L I N G :
It is a violation of F ed e r a .L law te u . t .
h 1.2 product to is raa n n e n inconsistent with its labeling. l Do not get in eyes, on skin er clothlug.
Avoid breathing vapor. 1 Use with bdequate vent ila tio n . j Wash thoroughly after handling. Keep container closed when not in use. '
Remove contaminated clothing and wash before reuse. l Discard c o n t ania n a t ed leather articles luch as s h o e <: and belt. '
STORAGE:
Glutaraldehyde solutions can be stored and handled in baked phenolic-lined steel, polyethylene, stainless steel, ur reinforced epoxy plastic equipment. For short storage times (up to about 1 month), temperatures of up to 100 Deg. F (38 Dec. C) can be tolerated but the preferred rnaximum storage t empe r a tu r e is about SO Deg. F (27 Des. C). i l
- ++++********k+k**+kk+6*++***4k+k++++***&++kk4k&+*&4kA****
l 09 - Section S. EXPOSURE CONTROLS / PERSONAL PROTECTION I l l
bhk+k4kkkkkkkkkhkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkhsk l PERSONAL PROTECTIVE EQUIPt1ENT' EYE / FACE PROTEC TION: Chemical splash goggles and face shield SKIN PROTECTION: Chemical resistant g lo ves and protective clothing ,
. _ _ _ l R eco rntne n d ed _ s l o ve . ma te r i a l s . i nc lu d e _r u b b e r.,- . n i t r.i le._I N B R ) , _ b u ty l , _a n d __. _ _.
polyethylene )
RESPIRATORY PROTECTION: If airborne concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134), j ENGINEERING CONTROLS: ;
General (mechanical) room ventilation is expected to be satisfactory.if l this rnaterial is k ep t in covered equipment or if the solution is highly diluted. However, if vapors are strong enough to irritate the nose or eyes, the exposure limits are probably being exceeded and special ventilation may be required.
WORK PRACTICES: l Eye wash station and safety shower should be accessible in the immediate I area of use.
UNSATISFACTORY NATERIALS OF CONSTRUCTION:
Glutaraldehyde solutions are incompatible with many commonly used materials of construction such as steel, galvanized iron, aluminum, t i n ,.
and :: i n c .
I L
.- s
+ + u + 4 4. 4 4 4 * * * + 4. + u a A n a 4a- 4.s a 4 4 4 o* *
- u ,4 a u + o + +++
10 - 1ectton 9 PHY : CAL 'ND CIEHfCAL PROPERf 'S
, l 4 + 4 4 4 4 + 4 4 e
- 4 * * * * * .e ., 4 4 A .* .4 4
- 4 4 4 44444444+*44***+44+44*44 BOILING POINT:
215.7 Deg. F (102.1 Deg. C) 9 740 ram!
4 PO R PRESSURE:
~
14.7 mmHg G 20 Deg.
VAPOR DENSITY (air = 1)
> 1
% UCLATILE DY UEIGHT:
Not available SOLUDILITY IN UATER:
Complete 9PECIFIC ORAVITY:
1.11 - L.13 0 00/20 Deg. C pH:
3.7 - 4.5 G 25 Deg. C FPEEZING POINT:
1.4 Deg. F (-17 Deg. C)
APPEARANCE AND ODOR:
Clear, coloriers, slightly viscous liquid with sharp odor.
- ++************+******++***********k******
l 11 - Section 10. STADILITY AND REAriIVITY l
+***4**+*-+******+++*******++++****++*4*******+
CHEMICAL STADILITY:
Stable HAZARDOUS POLYMERI ATION:
Will not occur CONDITIONS TO AVOID:
A vo id high temperature and evaporation of water. Altho'agh p o lyme r i:: . ion ,
may o c e tt r , it is not hazardous, {
--I N C OM P A T I D I L-I T Y . ,
l Alkalies cataly:e an a ldo l-type co n d en sa t:t e n reaction which s exo tr :rmic but not expected to be violent.
DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion may produce carbon dioxide and c Son j monoxide.
+***+++++++*4************.***********4********+* I l 12 - Section 11. TOXI"' OGICAL INFORMATION l l 4*****************4.***** 4 ++++**+*************
ON PRODUCT:
Toxicological data en inhalation effects: An NTP inhalation study
! indicated that glutaraldehyde exposure in rats and mice resulted in a I spectrum of necrotic, inflammator s, and regenerative lesions in the ur er respiratory tract. The no-observed-adverse-effect level for respirato-y lesions in rats was 125 parts per billion. The study, however, did not
,- a,
.;tect .n- rc-ebrerved-)dvcr * < r' r e c t tevel . l.r mt: ' n f l a rr,ma t i e n . :,
raund to the icontal nat .1 , a L I *a g o s r' ihe mou.' it ;oacentrations as low
- r. .,2.0 j)p h .
f o 4 Lco le g 1Ca l d a r. a en chr n.tc <. f f a c t n
,tudies :n h u an a n a t, a ve shown that glatar71 der de is neither phototoxic nor a photosensitizer. iubchronic crtul.1ng wa t e r studien an ratu, mice and dogs ustag concentrat: ant up to 1000 ppm chowed no evidence far any target
'rgan tocicity. In vttro studies t' c r geno to xici ty using a variety of assays h1ve given resulta varying from no activity to we a l: ly Fasitive:
however. all in vivo :. tudies for genotoxicity have been uniformly m ea n t i v a . Several developmental toxicity studies have demonstrated that at ma t rer n a lly nontoxic doses, glutaraldehyde does not produce fetotoxic, jmbr3otoxic or teratogenic effects.
In a chronic (2-year) continuous drinking uater combined chronic t o x ie. i t y -o n c o g e n ic i ty study using Fischer J44 rats, there was no evidence for non-oncogenic target organ toxicity. The enly possible oncogenicity-related finding was an increase in the incidence o# large granular cell lymphocytic l eu l: emi a in female, but not male, rats. The pattern or the rasponse suggests that it does not represent direct chemical carcinogenic activity but, rather, a modifying influence o n the express sio n of this spontaneous and commonly occurring neoplasm in the j i'icher 344 rat.
ON INORCDIENTS: '
Oral LD50 Dermal LD50 Inhalation LC50 i i
Chemical N ame (rat) (rabbit) (rat)
Giutaraldehydie L34 mg/k9 2560 mg/l: 9 4GO mg/m3/4H
++k*++k+++kw++++++++k++++++++******++++*****
l 13 - Section 12. ECOLOGICAL INFORMATION l khk&kkk+k+kkkkkk++kkkkkkkkk+kkkkkkkkk+******
ON PRODJCT:
l Environmental data: This product is toxic to fish. Do not discharge
_ effluent containing this product into lakes, streams, ponds,_e<stuaries,___ _
oceans, or other waters unless in accordance with the requirements of a tJ a t io n a l Pollutant 9ischarge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not d i is c h a r g e effluent containing this product to sewer systems without p r ev.t o u s ly notifying the local sewage treatment plant authority. For guidance contact your State Water Doard or Regional Office of the EPA.
ON INGREDIENTS: l Chiemical Name Aquatic Toxicity Data l Glutaraldehyde (50% active 96 hr LC50 (bluegill sunfish): 22 ppm solution) ?6 hr LC50 (rainbow trout): 24 ppm 48 hr LC50 (Daphnia): 12 ppm I 96 hr LC50 (fathead minnow): 12 ppm 96 hr LC50 (sheepshead minnow): 64 ppm 96 hr LC50 (mysid shrimp): 14 ppm
, , ru4.s ,. ,,-- .. ... +- .
sa- + , -
- i. .a ! 0 . P O S r.l ".".. PA' 3Mf; !
4A4AAd ad44H 44.- 44+4-.&*4+4J *44A4444* 4kH+
PC T? A '3 T A T U'3 :
Discarded product, au so (d . wo u .l d not !o c o n g ., arsd .. :C , ': sr-Maste.
DISPOSAL:
Pesticide vastc1 are acu tely hazardous. Impra :r dispor ! c' +ac i pestictde, spray mixture, or r i n s a ':. e 1. a vio . tion of. eral l a t. If these wastes cannot be di3poind of by : acco: ding io .1 instr.ctions,
- onlact your State Pesticide or Envir o nment 31 C s a t r o l Ao y, or the Hazardout Waste representative at the nearest EPA R e:; t e n a Office for guidance.
- +++++u +44*++u ++u*u ***+***+++4*+u++++
l 15 - S ec t io n 14. TRANSPORT INFORMATION !
- ++*++++++.444*+++*4**++****+44*44********
DOT CLASSIFICATION:
Class / Division: 9 Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (centainn Glutaraldehyde)
Label: Corrosive Packing Group: II ID Number: UN 3265
- ++++*u **+++++++++********+**********+*+
l 16 - Section 15. REGULATORY INFORMA TION l
- +++44**u+++++++++++************+****++***
l OSHA Hazard Communication Statun:
Hazardous
_. _.TSCA: -
The ingredients of this product are listed on the To xic Subs tar. es Co ntro l Act (TSCA) Chemical Substances Inventory.
CERCLA reportable quantity of EPA hazardous substanct.s in produr Chemical Name RQ No ingredients of this product have CERCLA reportable quantitic Product RQ:
Not applicable (Notify EPA of product spills exceeding this a trio u n t . )
'i A R A TITLE III:
. i Section 302 Extremely Hazardous Substances:
Chemical Name CAS 4 RQ TPQ There are no SARA 302 Extremely Hazardous Substances in this pr< duct.
Section 111 and 312 Health and Physical Hazards:
__ _ _ _ _ . ~ _ ._ ~ . . . . . . _ . - _ . _ . _ _ _ _ _ . _ . _ _ _ . _ _ .
.- a I!nmediate Pelayed Fire P e r tnet r o PeactiVLi f Ea s yes ao .o 10 1 Coction 213 foxic Chemicals:
Chemic:11 Name CAST '4 by IJ e i g h t l
There are no reportable SARA 013 l'oxic Chemicain :n h t :: r. r e d u c t .
6.++4**4.o 4*+-+**+ m ++++++*+++++++*+++++
l 27 - Section 16. OTHER INi ort 1ATION I
- h***k**A+*4*k***+***&********++++*****
lItiIS RATINGS:
Health = 3(6)
Flammability =0 Reactivity = 0 Personal Protective Equipment = X (to be specified by user depending on use conditions)
'+) There are potential <. h r e n i c h s rs l t h ef f e c t f: to consider, hazard rating scale:
0 = Minimal
! 1 = Slight 2 = Hoderate 3 = Serious
, 4 = Severe ,
l rdSOS REVISION
SUMMARY
l Scoersedes MSDS issued on 04/27/95. The hSDS has been changes in Sections
, 3, 7, 13 , 11, 12, 13 and 14. -
I t
i I
l I
k 8
l 9
l I
l
.' e to+(44&,.... . 4. ... . , , . . .
4 ., ; , 4 ., 3 # , ., , , # # ., , 4 , ( .4 4 4 # 4 4 4 , 4 4 4 This 1I an hSDG trom t h ct ' a irimo ro w e :a i t h li .l l : s n i tS DS Progrim ATTENTION: Safety and I n du s t r i a .! Hygiene si d vi c e s users to review the i. n t e n d e d use of this in f o rma tio n with his/her i u p .e r v i a :t r .r Safety and Industrial Hygien9 advisor.
+ + 4 4 *
- 4 * * * * * * *
- 4 4 4 4 & 4 4
- 4 *
- 4 A A A A 4
- 4
- A .4
- A 4 * *
- 4 .A A A
- 4 * ) A n * * * .6 4 4 Contents for this MSDS 1.
2.
GENERAL INFO RMA TION SECTION I - PRODUCT IDENTIFICnTION hO
- 3. SECTION II - COMPONENTS
- 4. SECTION III - PHYSICAL DATA
- 5. SECTION IV - FIRE AND EXPLOSION HAZARD DATA
- 6. SECTION V - HEALTH H4ZARD DATA
- 7. SECTION VI - REACTIVITY DATA G. SECTION VII - SPILL a DISPOSAL PROCEDURES
(? . SECTION VIII - INDUSTRfAL PROTECTIVE EQUIPMENT
- 10. SECTION IX - STORAGE AND HANDLING PRECAUTIONS
- 11. SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION l
- ++*********
l 01 - GENERAL INFORMATION l 4.***************************
F ilen a rne : CE009294 msd J.T. BAKER INC, 222 Red School Lane, Phillipsburg, NJ 08065 24-Hour Emergency Telephone 908-859-2151 National Response Center 800-424-8802
. . _ .Chemtroc 300-424--9300 _ _ . . . - - .- -- - - - - - - - -
National Response in Canada CANUTEC 613-996-6666 l Outside U.S. and Canada j Chemtrec 202-403-7616 '
NOTE: CHEMTREC, CANUTEC and National Response Center emergency numbers are to be used only in the event of chemical cnnergencies involving a l spill, leak, fire, exposure or accident involving chemicals. All l n o n-erne r g e n cy questions should be directed to Customer Service 1 t
(1-800-JTBAKER) for assistance.
So diurn Hydro xide, Vo lumetric Solution Effective:
l 01/04/94 Issued:
01/1I/(?4 NOTE: Uhen handling liquid products, secondary protective containers musst be used for c a r ry i n g .
M/A o Not Applic ble, .r not 11<'lu; il/ C - ilo - .i t a b l t .a rm d The :iformation i. n t h i s .13 t e r S4fety Data She+ meets the ? q u .: ements o r' t t' e U n i t e d S t a t. e s G C C ' :' A T T iL iFE sism HEAL i ACT and r .t u l - ions p r o mu l <J a t ed thereunder ? C; 1?1 .12-l 0 et. :eq i and the C idi UORi<uLACE HAZARDOUS hATT. IAL NF0f.MATION SYSTEh, This docu- t intended only as a guid. 'o appropriate precautionary ha tint if '
material by a person tr a . .ed , e :uperviced by a person i . n e- i. n ,
>/ h em i c a l handling. The user re- oonsible for determining e precautions and dangers of tt c h. ;ical for his or her p a r t i t.; u l a app)ication. Depending on us .s e , protective cIothing includin.) eyv a nt:t face guards and respirators must bc used te avoid co-*act uith material ur breathing chemical vapors / fume?. .
Exposure to this product may have serious adverte her :. h effectn. T h :t. n chemical may interact with other substances. Since '1e potential uses are
- o varied, Daker cannot varn of all of the potential 1 angers of une or interaction with other chemicals or materials. Baker warrant;s that the chemical meets the cpv-4fications set forth on the label.
OAKER DISCLAIMS ANY 0. 'R UARRANTIE5, EXPRESSED OR IMPLIED WITH RE0ARD TO THE PRODUCT GUPPLIED l-- ?EUNDER, ITC MERCHANTABILITY OR ITS FITNESS FOR A PARfICULAR PURPOSE, The user should recogni:e that this product can cause severe injury and even death, especially if improperly handled or the k nown dangers of use are not heeded. REAL ALL PRECAUTIONARY INFORMAT !. As new d o c u ine n t e d general safety information becomes available, C :. - will periodically revice this linterial Safety Data Sheet.
Note : CHEMTREC, CANUTEC, a nd t'ATIONAL RES.ONSF :4 TE R nergene telepha e numbers are to b e u sed F'NLY in the event of CHE A L E M n :.G E N C I T. involv is a spill, leak, fire, exposure or accident invo ng c micals. All non-emergency questions should be directed to C omer ervice ;
(1-800-JTBAKER) for as.:. stance ,
1 COPYRIGHT P/4 J.T. B A RE R-IN(*
(*) TRADEM.sRKS OF J f. BAKER INC. l Approved by Quality Assurance 'epartment. l i
+n+++uu. +++*****++++++**- **+++********
. l 02 - SECTION I -
PRODUCT IDENTIFICATION l
- u*+o+%+%+**u*++*+o++++++++*o*+*****
Product Name:
Sodium Hydroxide, Volumetric E 1. u t i o n Common Synonyms:
Caustic Soda Solution 1 Chemical Family: !
Volumetric Solutio ns and Co nce? rates Formula:
NaOH in H2O Formula Ut.:
1 l
!8 . ' '
CA3 8o.
131.) . .. >
HIOSH/HTECG Ho..
UD4'/00000 Product Use:
Laboratory Reagent Product Codes:
5633,5664,3663 PRECnUTIONARY LADCLING BAKER S AF'- T -D A T A ( * ) System HEALTH 2 MODERATE FLAMMABILITY 0 NONE REACTIVITY 1 GLIGHT CONTACT 2 MODERATE Laboratory Protective Equipment GOGGLES LAD COAT VLNT HOOD PROPER GLOVES U.S. Precautionary Labeling CAUTION!
HAReiFUL IF SUALLOWED. CAUSES IRRITATION. MAY CAUGE BURNS.
Do not get in eyes, on skin, on clothing. Avo id breathing vapor. Keep in tightly closed container. Use with ndequate ventilation. Wash thoroughly after handling.
International Labeling Avoid contact with eyes. After contact with skin, wash immedintely with plenty of water. Keep container tightly closed.
l SAF-T-DATA (*) S to rage Co lo r Code:
Grange (general storage)
- ++*******.+**+.****************
l 03 - SECTION II - COMPONENTS l
- u*********************
Component CAS No. Weight % OSHA /PEL ACCIH/TLV Codium Hydroxide 1310-73-2 <0.3 2 mg/m3 2 mg/m3 Water 7732-13-5 >99 N/E N/E l
h************A*********************+
l 04 - SECTION III - PHYSICAL DATA l
- +*********.4*******************+
Boiling Point:
N/A Melting Point:
N/A Specific Gravity: (H20=1)
N/A Solubility (H2O):
Complete (100%)
.- 1 61 :
,oA Odof ['l t r e tt h o 1. d a ppm >.
(f/ A i:ooffictent U rs t e r /011 Die bur 'oo:
N/A Vapor Pressure ( mmlig ) -
iJ/ A V1por Density (air =1):
N/A Evaporation Rate:
N / A'
% Volatiles b/ Volume: (21 Deg. C) approx. 100 Phycical State:
Liquid Appearance & Odor:
Clear, .:alorless liquid. Odorles.r.
- 4******44**+++++********4**********A-l 05 - SECTIOt1 IV - FIRE AND EXPLOSION HAZARD DATA l
& * * *
- 4 4 -4 4
- 4
- 4 A A A
- 4 4 4 4 * * * * * *
- A
- 4 4 A + 4 4 4 * + 4 4 4 4 * * * * * * * *
- Flash Po int (Clo sed Cup):
N/A Autoignition Temperature:
N/A Flammable Limits:
Upper - N/A Louer = N/A Fire Extinguishing Media Use ex t ingu itshing media appropriate for sti r r o tt n d i n ,, fire.
Special Fire-Fighting Procedures None identified.
Unusual Fire & Explosion Hazards None identified, j
- T o x i c r a s e s - P r o d u c e d - - - --- - -- - - -- - --
-1 l
none .t. d e n t if i e d Explosion Data-Sensitivity to Me.;hanical Impact None identified.
. Explosion Data-Sensitivity to Static D i s,c h a r g e )
None i d e n t i f' i e d .
+++*******++***************************
l 06 - SECTION V - HEALTH HAZARD DATA 1
- +4**********+*************************
Threshold Limit Value (TLV/TUA):
2 mg/m3 TLV (Celling) i: fer Sodium hydroxide.
Sho r t-Term E xpo sure Limit (STEL):
Not Established Permitssible E xpo sure Limit (PEL):
. - - - ~ . . ._ - . . . -. - -.. - - .-
- '119 / m3 PEL (Ce211ng) la rer G o o i t. o. h y d r o >. i d e .
. To xici ty of components Intr aperi ta ncal ho use LD30 t' o r Sodium Hydro;alde # m 'l: 9 Intraperitoneal house LD50 far !J a t e r 190 g/kg Intravenous House LD50 t' o r Water .:D g/kg Carcinogenicity:
NTP: No IARC: No
- List: No USHA Reg: No Carcinogenicity:
None identified.
Reproductive Effects None identified.
Errec ts of Overexposure INHALATION: irritation of mucous inembrane SKIN CONTACT: severe irritation er burns CYE CONTACT: severe irritation or burns SKIN ABSORPTION: none identified INGESTION: gastrointestinal irritation, nausea, .omiting
- CHRONIC CFFECTS: none identified Target Organs eyes, skin, respiratory system, lungs l Medical Co ndit io ns Generally Aggravated by Exposure none identified '
Primary Routes of Entry l inhalation, ingestion, eye contact, skin contact ;
Emergency and First Aid Procedures 1 INGESTION: CALL A PHYSICIAN. If cua11oued, do NOT induce vomiting. If !
conscious, give large esmounts of water. I INHALATION: If inhaled, remove to fresh air. If not breathing, give i
artificial respiration. If breathing is difficult, give oxygen. '
l SKIN CONTACT: In case of co 'act, immediately flush skin with plenty of l l
. __. u a t e r f o r_ a t._ l ea s t .15. ;ni n u t es _.uh i le_r emoy i n g_ c o n t a min a t ed . c lo.t h i.n g...a n d _._ _ __
shoes. Wash clothing before re-use.
l EYE CONTACT: In case of eye contact, immediately flush with plenty of
- water for at least 15 minutes.
l
- SARA / TITLE III HAZARD CATEGORIES and LISTS l
Acute: Yes l Chronid: Yes Flammability: No Pressure: No Reactivity: No E x t r ern e ly Hazardous Substance:
No CERCLA Hazardous Substance:
l Yes Contains Sodium Hydroxide (RQ = 1000 LBS) l SARA 313 T o x ic C hetnicals :
Yes Contains Sodium Hydroxide Generic Class:
Generic Cla ss Remo ved from CFR: 7/1/91 I
.- i s C '. [ .. eu n t o r y I YOs 1
. I t.Ae ,&4 -++4+y +++&*4&&++++4*A***+&
' 0' -
TION ! OfACT!VITY DATA l
++++4um uu+44uu4*u*4+++n*u,+
5tatility:
Gtable Hazardous Polymer 12ation:
Will ci a t occur Conditions to A vo ld :
heat Incompatibles:
strong acids, most common metals, co mbu s t i b l er nr a t e r i a l u , organic
- na t e r i a l s , zinc, aluminon, magnerium, paroaldos, hslogenated hy dro carbo ns Decemposition Products:
none tJentified 4*******++**-+*+++u u +u +4*+u*4+++**4+*4A****+***
i 00 - SECTION VII -- EPILL & DISPOSAL PROCEDURES I
++4+ u*+u4.*-45*++**u#4***++++**+44**u *44*+++++*+
S teps to be Taken in the Event of a <? pill or Discharge Uear nel f- c o n ta in ed breathing apparatus and full protective cleihing.
Stop leak if you can do so .s i t h o u t risk. Ventilate area. Carefully neutralize spill with dilute. HC1. Flunh area with flooding amounts of water. (Use caution.)
J.T. i? a k e r NEUT R ACI T ( R )-:1 or GuCAIh(R) caustic neutralizers are r ec o mtn e n d ed for spills of this product.
Disposal Procedure Dispose in accordance with all applicable federal, state, and local environmental regulations.
EPA Hazardous Waste Number:
- DOO2 -(C o r r o sive -Waste)' - - - - ---- -
u*+**+u*+**++ a**++++u***++++++*****+*4*+****++****A l 07 - SECTION VIII - INDUSTRIAL PROTECTIVE EQUIPMENT l
- ++4**#*************+44*******************++********
Eje/ Skin Protection:
This is a laboratory-use product fer which no industrial protective eq u i p rn e n t has been designated.
++**************************A****************+++******
l l 10 - SECTION IX - STORAGE AND HANDLING PRECAUTIONS l
- ++++++*********44*++++4******************+****+*****
SAF-T-DATA (*) Storage Color Code:
Grange (gereral storage)
_ _ _ _ _ . _ . ~ _- _. _. - - . _ . . - _ . . ._ ___
- t e r a g e P w q u i r e ni :. n t 1 I:ee p centbaner tightly c ' t s e t1. 3uttabic for any general chemical t i o r .vj e l acna.
k O dk k 4 4 4 4 4 4 % 4 -k 4 4 4 4 d k 4 k 4 ad 4 4 4 d d 4 d d d 4 4 4 k k 'k N k -k N 4 k 4 4 4 4 d 4 I O O N 'k k444444%Agf l L1 - 9ECfl0N X - r P A;rrs PO R T A r !ON Dars M D ADDITIOt#iL INFORMATION [
u u + 4 k u o k u k u .+ u 4 . .+ 4 u .k .+ u * # u n u i 4 4 u A 4 u * .4 + 4 4 4 u 4 .*
- u u + ,,. u .k l l
00mestic (D.O.T.)
P r tr p e r Shipping Name: Chemicals, n.o.a. (Non-regulated)
Regulatory Re.erences: 49CFR 172.101 International ( I . fi 0 . >
Proper Shipping Name: Chemicals, n.o.s. (Non-regulated) l Marine Pollutants: No )
Regulatory Rererences: 49CFR PART 176; IMDG Code l AIR (I.C.A.O.) l Proper Shipping Name: Chemicals, n o,s. (Non-regulated)
Peculatory
References:
49CFR PARf 175; ICAO Ue believe the transporLation data and references contained herein to be I factual and the opinion of qualified experts. The data is meant as a guide to the overall classification of the product and is not package nize specific, nor should it be taken as a warranty or representation for ishich the company a :! s u ms s legal responsibility.
l d
The information is offered solely for your consideration, investigation, and verification. Any use of the information must be determined by the l user to be in acco rda nce saith applicable Federal, State, and Local laws I and regulations. See shipper requirements 49CFR 171.2, Certification 172.204, and employee training 49 CFR 173.1(b).
U.S. Customs Harmonization Number:
28151200007 28151200007 I
l l
I i
I
k k h 4 O 4
- 4 O O k 4 6 4 0 4 4 4 4 4 4 4 4 4 4 4 4 ( f f .4 f 4 ,p f f g ,g 4f44444464$40444g 4444 This .1 s J.i n WO3 from ihe Commonisea1th ~ : li .o n iSDS o rogena ATTFNTION: Safety and I ndit ut r ia l flyg t en e advicea users to cr+ view the intended use of this information
- s i t h his/h+r supervicar er 9arely and Industrial Hygiene advisor, k * + 4 4 4 4 4 4 + 4 4 4 4 4 4 + + 4 4
- 4 4
- 4 + ,, & * .4 4
- A 4 * + +
- 4 4 4 L A
- 4 4 4 4
- 4 4 A e + + * * + +
Contents for this MSDS 1.
2.
General Information I - PRODUCT IDENTIFICATION gg
- 3. II - HAZARDOUS INGREDIENTS (__
p#f'
- 4. III - PHYSICAL DATA
- 5. IV - FIRE AND EXPLOSION HAZARD DATA
- 6. V - REACTIVITY DATA
- 7. VI - HEALTH HAZARD DATA G. VII - SPILL OR LEAK PROCEDURES
?. VIII - SPECIAL PROTECTION INFORMATION
- 10. IX - SPECIAL PRECAUTIONS
- +++4+++****+++**++*+++***
l 01 - General Information l
- +++4************4 VULCAN CHEMICALS Division of Vulcan Materials Company (ESSENTIALLY SIMILAR TO FORM OSHA-20)
SEE IMPORTANT NOTICE ON BOTTOM OF OTHER SIDE 24 Hour Emergency Phone (316) 524-5751
.DATE: .N o vemb e r_1 ?S
UMC 0239 NOTICE: Vulcan Chemicals believes that 4. h e information contained on this Material Safety Data Sheet is accuratti. The suggested procedures are based en experience as of the date of publication. They are not necessarily all-inclusive nor fully adequate in every circumstance.
Also, the suggestions should not be confused with nor followed in v i o l a t i o 'n of applicable laws, regulations, rules or insurance requirements.
- +++.4***+4****+******************
I 02 - I - PRODUCT IDENTIFICATION l
+++++*+++++++++****++*4************
MANUFACTURER'S NAME AND ADDRESS: Vulcan Materials Company, Chemicals Division, P.O. Box 7689, Birmingham, AL 35253-0689 CHEMICAL NAME: So diuin Hydro xide so lu tio n (50% & 73%)
CHEMICAL FORMULA: NaOH TRADE NAME AND SYNONYMS: Caustic, Caustic Soda, Lye
. + 4. 4 4 -. 4 4 6 e 4 g .4 4 - % e
- wf. 4w.
l 03 I - !:AZA; ,US .dGRt9IE TS i
+*k+. 4+*+4++4+ ++4++44+4 4444 ^4*A MA TE RI AL OR COMPONENT %(wt) PEL tUniti/
, uw ,*u*****u*uw*4++u++
! 0- - CII -- PHYSICAL DATA l k * + w .- + + + + + + + k +
- 4 L*+444 64***4 DOILINO POINT (degree F ). 50% Solution - 293 degrees F 73% !?olution = 37? degrees F SPECIFIC GRAVITY (H20=1): 50% 0 60 degree.s F= 1.53 73% G 140 degrees F = 1 . 7'
VAPOR PRESSURE (mm Hg ): 6.3 PERCENT., VOLATILE PY VOLUME (%): N/A UAPOR DENSITY (AIR =1): N/A EVA P0 i? A T I ON RATE: N/A SOLUBILITY IN WATER: Complete APPEARANCE AND ODOR: C o l e r l e si s to slightly colered, c d o r l ei: s liqu: d.
.+++.**+++w +o +*+u o u ++o ++++++**++++++++++
l 03 - IV - FIRE AND EXPLOSION 1-iAZARD DATA l
+w ++u u u+++u u++4+++++u*++++++u+44**u FLASH POINT (Method used): Nonflammable FLAMMABLE LIMITS: N/A L6we Uppe . N/A EXTIFGUISHING MEDIA: N/A SPECIO.L FIRE FIGHTING PROCEDURES: Adding water to caustic solution generates large amounts of heat.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Will react with some metals, i.e.
a l u m i n tnn ,~ t~1 n and :1nc, t o~ Fe l'e ss e ~ f 15 mm ab'l e h y d ~r~o g e rrg s s .
u*u*+u***uw+++*+*4******
I 06 - V - REACTIVITY DATA l
- ++++4*****++****+*
STABILITY:
UNSTAULE:
STABLE: X CONDITIONS TO AVOID:
INCOMPATIBILITY (Materials to avoid): Acids, flammable liquids, organic (
halogenated compounds. Cantact raith nitro compounds usay form thock-sensitive salts.
HAZARDOUS DECOMPOSITION PRODUCTS: None .
HAZARDOUS POLYMEPIZATION: l l
l MAY OCCUR: l l UILL NOT OCCUR: X l CONDITIONS TO AVOID:
i l
I
- . - . =. . -. . - - .
< .a -
l l r 4 -4 + a & 4 1. A*44++44+4444+442 .4A*e- '
l 07 - l
- ! MAL TH HAJARO DATA !
4 444*4 &++4&444++#44+++++**4++++
OSHA PERT 11GSIBLE EXPUSURE LIMIT: ? mg/m3 :3 haur TUA (C9 CFP Part l'? l o .100 0 )
- ACGIH
- 2 mg/m3 ceiling.
l EFFECTG OF OVEREXPOSUPE:
j INHALATION: C a u s t. i c micts i. a n causs de:tructive burne of the mucoun l membrines. Gevere pneunionitis a:)y occur.
l SKIN CONTACT / ABSORPTION: Caustic liquid will cause akin irritation.
! Prolonged exposure will cause severa burns with scarring.
INGESTION: Swallowing will canne severe burns of the mouth, throat l snd stomach. May result in death in extreme cases.
l EYES: Contact with eyes causes rapid tissue destruction leading to permanunt ey e damage and possible blindness.
EMERGENCY AND FIRST AID PROCEDURES:
EYES AND GKIN: Uash eyes immedittely with large amounts of water, lifting the lower and upper eyelida occasionally. Det medical attention immediately.
INHALATION: rio vie p e r s o n to fresh air. If breathing ctops, administer artificial respiration. Get medical attention immediately.
INGESTION: If person is consc2ous, give large quantities of water to dilute caustic. Do not Induce nmiting. Det medical a t tentio n immediately.
- +*** m *+++++++++4*****++++** m +
l 08 - VII - SPILL OR LEAK PROCEDURES l k*****A4****+44******A****************+
STEPS TO BE TAKEN IN CASE MATERIAL IG RELEASED OR SPILLED: Cleanup personnel must have proper protective equipment. Completely contain all spilled material. Reclaim into closed containers if possible. May be diluted with water and neutrali;:ed with dilute hydrochloric acid.
WASTE DISPOSAL METHOD: Dispose or in approved landfill or contact approved disposal waste disposal firm. Must comply with federal, state, local regulations._ _ ___ ._. . _ _ _ - - _ _ _ _ _ _ . - _
- ++++++ m **+***++*+ m *+********+++++***++***
l 09 - VIII - SPECIAL PROTECTION INFORMATION l A**k*******+++****+**+************************ j SPECIAL PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY: NIOSH-approved self-contained breathing apparatus for exposures above OSHA PEL.
EYE: Chemical goggles which are dust and splashproof.
SKIN: Impervio us clo thing, rubber gloves and shoes.
OTHER: Safety shower and eyewash fountain should be locaged in the immediate work area.
VENTILATION REQUIREMENTS: Use ventilation or exhaust to maintain exposure below OSHA PEL.
- +***+*A********************
i l 10 - IX - SPECIAL PRECAUTIONS l j *********************************
l
.--u, . - - -- . - ~ - + . . . ~ u.- -
ng. n. , n .na w.u. a. - .-__a .u- - - - - - - - - -au_.i .,.~.<n>
- .a.. .-s .+a __ . -..a.x.- --~ . >-.
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,1 l [g', f.) ( { g-ll e '
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Soda 90 1:4tions with watsr, Ji l o w l y :i de 1e 1st sa . . ntle
' l 1 ' f ' II '"I Cf ') ') i t. ;*s t 1 r. j , *e c c n F. r <* 1 !b( 3pg . , ns i :[ t
- h. , t . .: h e r a t #Xl .
O rilER PPECM.f rIONS : Contact if a.. tar ;da 1,.- a, w l . . i o r. .tth . ,
and lsverage predtict; nico ,
.I tt e ;c , t c a c c i. ittene - f .. bo rno no x ide das i n ecloted vesL.1= *
"r :es l
I P
.I i
- - < - ~ -- - ee- ~ - . -- - - . . . . . _ _ _ , . . _ . _ . . _ . . . . _ , _ . . . - . . , _ _ _ . _ _ _ _ . , - -
l I
l 1
l l
l l
l r
1 i
i 1
s * *e 4 k 4 4 4' k E O 4 4 *
- 4 h 4 4 4 4 4 4 4 4 4 4 4 4 4 4 * + 4 4 ( k 4 4 4 4 4 4 4 4 A' 4 . 4 di s4 & 4 <w 4 Y w .e 4 4 4 i'e i x t! :-n o "? DS *
. r t he C o mmo n W'a i f.h .7 J 'i :: o 1 <. ' , 0 ; P r o g r ;i m
- v. T T E N T I N ' .arsty .nd l odtt S c r : ; ! Hygiene adv'.see u s e r <a to r e v i er,i the i n t e n .:l ea Se r this information with his/her supervisor or Saroty and I n d tt s t r i a l
- Hy9ien9 !s d V i s o r
+ + * + 4 * * + + + 4 * * + + 4.
- 4 4 4 4 4 .A A A + 4
- A 4 4 4 4 * +
- 4 4
- 4 + 4 4 + 4. 4 + 4 4
- 6 4 + +
- 4 A 4
- C o n t e n t -:3 for this MSDS
- l. Hazard Summary ,. g f e
.? General Information .
- 3. Hazmat Ident Y U;',. ,
- 4. F ire and E x p l o s t. ,i n
'5 . Peactivity/ Chemistry
- o. Health
- 7. Enviro nwn t O. On Call P e s o ti. r c < > :
- 7. Disclaimer
+ + + 4 4.*.+ + +.+.+ + + + + + 4 * * * + + 4 l 01 - HAZARD
SUMMARY
l
- ++(+*************+****
CHEMICAL NAME/FORhULA LITH 1UM HYOROXIDE MONOHYORATE. LiOH+H20. REV.12/87 8 GENERAL HAZARD RATING !
. __.n00EPATE ._ . _ . _ _ ___ _
_.__i KEY HAZARD CORROSIVE, '3 0 I S O N .
==r====================l HSDS RATING SYSTEH : ======================= ,
1 l EXPLOSION NONE !
)
- FIRE NONE )
- ._..._._.___._.._._._.________.__.._.._._._-._; . l 1 REACTIVITY NONE
1 l CORROSIVITY HIGH ! I l
! OXIDIZER ACTION NONE ! ;
1
- __--..--___..__._____._.____._____----_.__-_.____._.-._._; i l OVERALL HEALTH HIGH l l RESPIRATORY HIGH
- i l l SKIN MODERATE l l l l EYE HIGH : l l
l ORAL .HIGH l
- ENVIRONMENTAL MODERATE !
====u====-=======l (c) 1987 MSDS, INC =================
- +++.+**++++*****.+++++****+++
l .. ..
l 02 - Reil 'NFORh 10W i i
t as ,.
- u + + +4. < t+u,,+4 4++
CHEMIC AL 18At1E/FO Rhlit. A LITHIUh HYDROXIDE r)ON0 HYDRA 1r. Lu iA H20. '? E V .12 / 8 7 3 ,
CENERAL HAZAPD UAFING riO DE P A TE l UHITE ,C RYS T AL L INE INORGANIC SOL 10. ' FRY :! "ITAi1 . TO K 1 H , EYES , r" SE/TH PO A -
LUNGS. NOT CARCINOGENIC, MUTAGENIC, OR TERAr00EN C, DUi IS POISONOUS. ACRIO 000R. SIGNIFICANT llAZARDS DUE 'fD FORROSIVENESS, IFRITANT ACTION. REACTS VIO-LENTLY UITH tiANY ACIDS. HAY CORRODE COME RUUBERS, .' L AS T I C S , COATINGS. MAY CREA1E SIGNIFICANT ENVI RONijENT AL PROBLEMS DUE TO GROUND WATER POLLUTION, AD- '
UERSE pH EFFECTS IN SOIL OR UATER RUN-OFF MAY 8E A MAJOR PROBLEM & SHOULD DE CONTROLLED. USE PRECAUTIONS AS GRIN,LUNO. & EYE EXPOSURE MAY CAU9E IRRI-
! TATION. Si1PPRESS FIRES USING UATER STREAht 3PPAY, FOAM, CO2, DRY CHEMICAL.
FIRE PRODUCTS MAY BE T0XIC & IRRIfANT. GIHks & COMPLETELY MIXES WITH UATER.
DUST CS Fi AMMABLE. SHIPPED IN FIGREDOARD r ?UMS. PLACARDED 2680, l759. HAZARD ,
RATING 15 r0RROSI.E SOLID. USED CONiiFl:CIALLY TO .iAVE PHOTOGRAPHIC DEVELOPER, ,
MANUFACTURE r.F _ITHIUM LALTO, CATAL.,T, ESTERIFICATION, PREP 6ParION OF SOAPS
'a GREASES.
l l l
+ + + & A 1. 444.++++ 4,+++++
l l 03 - HAZMAT IDENT l dr + + 4 4 4 4 + + k h 4 4 A 4 4 + + + + 4 )
l l
NAMES AND NUMBERS I CHEMICAL NAMEeFORMULA l LITHIUn HYDROXIDE MON 0H'r DRATE . L10H*H20. REV.12/07 8 -
l OENERAL HAZARD RATING MODERATE GENERIC NAMES /SYNONfMS/ TRADE NAMES LITHIUt1 HYDROXIDE.
l I l U0 T P RO PE R_ 'iH I F.P ING.._N AME _ . _ . __ _ _ _ _ _ . _ . . _ _ _ _. _ ___ _.
LITHIUM HYDROXIDE MON 0 HYDRA TE DDT HAZARD CLASm CORROSIVE SOLIO EDS ACCESS NO. 21S3 00T GUIDE /84 NO. 40 STCC ....... NONE DOT ID NO. ... 0680 UN/NA NO. ..... MERCK/10 NO. ... 5360 CAS NO. 1S1066S SAX /6 NO. NONE RTECS/NIOSH QJ:6307080 PHYSICAL CHARACTER NORMALLY A SOLID & HANDLED AS A SOLID. 000R THRESHOLD UNKNOUN. MOLECULAR UT.
41.96. MELTING PT. NA. BOILING PT. NA. SPECIFIC GRAVITY 1.51. VAPOR PRESSURE MIL. VAPOR DENSITY NA. EXTREMELY CORROSIVE & DECOMPOSITION PRODUCTS ARE ALSO CORROSIVE. STABLE,DUT MAY VIOLENTLY AL TER OR DECOMPOSE WHEN EXPOSED TO HEAT, i j UATER, FIRE, DUS1 ACIDS.
a=============:r==;w,==============,.=====================ww======== nan ====:r l FOR CHEMICAL REACTIVITY, DEHAVIOR WITH UAfER AND OTHER SUBSTANCES !
! SEE SECTION 5, " REACTIVITY / CHEMISTRY". !
l
=====nnn==================================================================== ;
COMPONENTS / ADDITIVES / IMPURITIES LITFT 'M Hf DROXIDE MON 0 HYDRA TE TO 79.9% PURE
_ . _ _ . _ - _ -_ _ _-. __ _ . __- = - _
I PACCAGIWO/ TRANSPORT Pl. AC A R E '. u g NO Re1 A L Li B f 0 RE D .% TR ANSPOR TED IN FTUREEGARO 'N Ui15 , inALL OM fAri'Ei3.
HEEDS SPEC (AL CARE IN HAtIDLING AS IS COF:POSIVE l PLACAR0ED: DOT 2600; Hrc 3/0/0, COPPOSIVE 10L10. '
HAZARD LADELINO: CORPOSIVE, HY 0l?iPECO P I C .
i
+ + + nu v. r .s +. ws + + .s. .s. & vs +
! 04 FIPE/ EXPLOSION l
+ + +.+ s +..s + +.s. s + + & + + + + + + n l HAZARDS CHEMICAL NAME/ FORMULA LITHIUM H(OROXIDE NON0HYORATE. LiOH4H20. FEV.12/87 9 FIRE HAZAR0 EXPLOSIVE HAZARD I NONE NONE DOT GUIDE TEXT - FIRE OR EXPLOSIVE
- STANDARD PHRASE FF SOME OF THESE nATERIALS nAY CURN GUT HONE OF THEM 10 NITE READILY.
FLAMMA0LE, FOISONOUS OASES MAY ACCUMULATE IN TANKS AND HOPPER CARS, SOME-OF THESE MATERIALS MAY IGNITE COMBUSTIBLES (U000, PAPEF, DIL, ETC.).
FLASH POINT AUFO-IGNITION FLAhMABILITY LIMITS NF..F NF..C NF..F NF..C NF.% TO NF.A IN AIR m:m=== nun ====================================================================
l FOR ADDITIONAL FHYSICAL INFORMATION, SEE SECTION 3, "HAZMAT IDENT". ! ^
- FOR CHEMICAL INFORMATION, SEE SECTION 5, " REACTIVITY / CHEMISTRY". :
======================================a.===================================== ,
ADDITIONAL COMMENTS j
_. MAY FORM HAZ.AR00US . AE ROGOLS . _00ES_NOTJOLYliERIZE 3_00ES. HOT _CLEVE.MMOKE_GR _ . '
PLUME FROM A FIRE IS A MODERATE HAZARD. WINO UILL OIRECT a PRECIPITATICN WILL STRIP T0XINS FRON VAPOR PLUME OR SMOKE CLOUU.
00T GUIDE TEXT - FIRE EMERGENCY ACTION
- STANDARD PHRASE CF SMALL FIRES '
DRY CHEMICAL, CO2, UATER SPRAY, OR FOAM.
LARGE FIRES : MATER SPRAY, FOG, OR F0Ah, SOME OF THESE MATERIALS MAY REACT VIOLENTLY UITH UATER. MOVE CONTAINER FROM j FIRE AREA IF YOU CAN 00 IT WITHOUT PISK. COOL CONTAINERS THAT ARE EXPOSED l TO FLAMES WITH UATER FROM THE SIDE UNTIL UELL AFTER FIRE IS OUT.
l
nunu=========================================================n======
l0 ANGER! SEE SECTION 5, " REACTIVITY / CHEMISTRY" BEFORE BRINGING UATER OR ANY! ,
l OTHER SUSSTANCE INTO CONTACT WITH THIS MATERIAL. SEE SECTION 6, !
l l " PROTECTIVE EQUIPMENT / ACTION" BEFORE APPROACHING THIS MATERIAL. I !
==== nun ===========================================================nu======= 4 l
l ADDITION ACTION 1
.. .o CLEAR IMMEDIATE AREA t Doui4W (NI- '.S UIPED l'OR 1 CliM.L 2prLL. ;
i: .+ + . u++ e nskrs,.+> s+ .
I C'S REAL VITY.'CHEh ~TPY l n+++ +++ . sr+.xauss. .++&+
CHEMICAL NAhE.YORMULA LII;HIUh HYDROXIDE h0N0HYORATE. LiOH4H'O. RE V .12/9',; D ,
PEACTIVITY HAZARD I NONE OXIDATION !!AZARD NONE DEHAVIOR WITH UATER REACTS UITH UATER & RELEASES EXCESS HEA1 IN THE PROCESS. SINVS, COMPLETE!.Y MIXES, % IS EXTREMELY SOLUBLE IN WATER. STABLE TN CONTAC T Ul TH NEUTRAL & AL-
'KALINE SOLUTIONS.
BEHAVIOR UITH OTHER SUBSTANCEE ;
MAY PEACT VIOLENTLY UITH MANY ACIDS, ESPECIALLY STRONG ht:MRAL ACIOS. !
OTHER C!fEMICAL CHARACTERISTICS A CORROSIVE, GUT NOT v.N OXIlsIIER. UON'T TORM POL'r HE R I Z AT I 0tl PRODUCTS, DUT MAY FORM HAZARDOUS DECOMPOSITION PRODUCTS. MAY FORM REACTIVITY, HEALTH & EN-VIRONME.iTALLY HAZARDOUS FIRE PRODUCTS, INCLUDING T0X(C AEROSOL 3.
j
++++++++ss+n+
l 06 HEALTH l
- * * + + +.+.+ + * + +
- j l
CHEMICAL NAME/ FORMULA l LITHIUM HYOROXIDE MON 0HYDitATE. LiOH*H20. REV.12/8. D l OVERALL HEALTH RATINO )
HIGH 00T GUIDE TEXT - HEALTH HAZARD
^
- S TANDARD PHRASE HH l t,0NTACT MAY 'CAUSE~ BURNSTO Sk'IM - AND EYES . IF~ INHALE D i ~iiAY DE~1 TA RMF UL . i 1 E-nAY PRODUCE IRRITA TING OR POISONOUS GASES. RUNOFF FROM FIRE CONTROL OR DILU TION UATER MAY CAUSE POLLUTION. l
nunnu============== MSDS RATING SYSTEM :===================
l OVERALL HEALTH HIGH !
! RESPIRATORY HIGH l
! SKIN MODERATE !
l EYE HIGH !
! ORAL HIGH l
= = = n n u n = = = = = = = = = = = =: = = = ; (c) 1987 MSDS, INC ==========*===========
HEALTH EFFECTS PRIMARY HEALTH HAZARD OUST INHALATION, SKIN CONTACT, POISONOUS.
EXPOSURE LIMITS TLV/STEL UNKNOWN IDLH UNKNOWN TLV/TUA UNKNOUN MAJOR SYMPTOMS /SIONS OF OVEREXPOSURE
__m . . _ _
.* *a INHALAIION: mAY PPODUCE 3C YERL 'RRITAIIGN. ijVEN ULLEFAf(ON OF HOSE, MOUTH, iiIRUA r . CAUSES MU9.CLC f u [ ra j u:0, aEH rAL C ONF US ION . :.L U R RE D VISION CHEMICAL PNEUn0NIA UITH D'ISPNEA 6 C '/ A N M I S . POSSIDL) '0hA. ,
SKIN CONTAI.r: 1 A *i CAUSE I P P C T:., r ION ULCCPATION. 'O C *a : 0 L ' DU rim.
EYE CONTACT: nAi CAUSE IRRITATION & ULCERATION, POS S t eL 't fiURNS.
[NGESTION: MAY CAUSE SEVERE E RPITA TION & ULCERA F CON OF MOU TH, TH RO A T , E S OTM.-
GUS, *LUS NAUSEA, ANOREXIA, FOMn, ELEC1ROLYTE IMBAl AN G .
CENTRAL NERVOUS GYS TEM EFFEC TS : "EE [NHALATION.
LONG-TEPM EFFEC TS : POSSIBLE R f DHI?Y DAMAGE PPOTECTIVE MEASURES '
00T GUIDE TEXT - EMERGENCY ACTION
- STANDARD PHRASE EA KEEP UNNECESSARY PEOPLE AWAY. I SOL. A l li HAZARD AREA AND DENY ENTRY. STAY r UPUIND. KEEP OUT OF LOU AREAS. UEAR SELF-CONTAINED (POSITIVE PRESSURE IF AVAILABLE) I?REATHING APPARAlUL AND FULL PROTECTIVE CLOTHING. IF UATET POLLUTION OCCURS, NOTIFY APPPOPRIATE AUTHORITIES.
A DDI TIOrML COnMENTS USE EPA LEVEL C OR EQUIVALENT PROTECTION, EYES: GOGGLES.
RESPIRATORY: SCDA OR APPROVED CANNISTER MASK.
SKIN & EXTREMITIES: IMPERMEABLE OLOVES, GOOTS, CLOTHES, A P RON , TU RNOUT S ,' SUIT .
MESISTANT MA TERI ALS: MATURAL ' UE BE R , NEO P PENE . N IT R ILE , POLYETHYLENE , PVC , V ITON ,
SARANEX, NEOPRENE-NATURAL. UNCERTAIN: DUTYL, CHLORINATED POL Y E THYL E NE , STf-RENE-GUTADIENE, NITRILE-PVC, .N I T R ILE - SU T A D IENi_ . AVOID: POLYVINYL ALCOH.01. .
FIRST AID / DECONT AMINA TION DOT GUIDE TEX T - FIRS T AID EMERGENCY ACTION
- STANDARD PHRASE FA MOVE VICTIM TO FRESH AIR. CALL EMERGENCY MEDICAL CARE. REMOVE AND ISOLATE CONTAMINATED CLorHING AND SHOES AT THE SITE. IN CASE OF CONTACT WITH
, MATERIAL,__IMMEDIATELY_ FLUSH SKIN _0R. EYES _UITH. RUNNING UATER.FOR_AT LEAST 15 r1INUTES. ItEEP VICTIM QUIET AND MAINTAIN NORMAL 00DY TEMPERATURE. '
DECONTAMINATION PERSONNEL: SHOUER UITH SOAP & UATEP.
CLOTHING: REMOVE & LAUNDER. l EQUIPMENT: HOSE OFF, RUN-OFF UATER: MAY BE TREATED & NEUTRALIZED WITH ACID, THEN DILUTED. NOT llARMFUL IF UELL DILUTED & NEUTRALIZED, l MEDICAL TREATMENT l INHALATION: MOVE TO SAFETY, INTUGATE & RESUSCITATE IF NEEDED, PROVIDE OXYGEH.
MONITOR BREATH SOUNDS FOR CHEMICAL PNEUMONIA. START IV TKO, MONITOR LEAD II
& ODTAIN BASELINE ABG's. SEEK IMMEDIATE SPECIALTY CARE IF SERIOUS.
SKIN CONTACT: UASH UITH SOAP & UATER. CH'ICK FOR CHEMICAL IRRITATION & BURHS
& TREAT AS INDICATED. SEEK SPECIALTY CARE IF SERIOUSLY AFFECTED.
EYE CONTACT: IRRIGATE EYES WITH NORMAL SALINE OR TAP UATER. DO NOT USE EYE -
DIN 1MENTS, EUr MAY PATCH EYES AS NEEDED. SEEK IMMEDIATE SPECIALTY CARE IF SERIOUSLY AFFECTED.
INCESTION: IF CONSCIOUS, GIVE CLEAR L IQUIDS, BUT 00 NOT INDUCE EMESIS WITH IPECAC. IF UNCONSCIOUS, INTUBATE TO PROTECT AIRUAY, BUT 00 NOT PERFORM LAVAGE. SEEK IMMEDIATE SPECIALTY CARE. UARNING: INDUCING EMESIS OR PER- i
)
l
FornING LAVAGE t.AY r '.i P ' U Pr " 10 P Hi .GU' -
KUICAL SURVriILLANCE IS MDIC; ICD FOR 1: ! ]NE'.' D AMeesiE , ESOPHsGEAL iTRfCTURES.
HE AL il! TPEATHENT NOTES ABSORP TIOrl: THROUGH LUNGS, MUCOUS hEMl]RANFE, SKI- EIES, GI TPACT.
DICTPICUTIQU: TO CODY UATER STORES.
UNCHANGED MATERIAL: NOT EXCRETED.
METABOLIC CONVERSION: FORMS WEUTRAL l.I r! M 10N !TCH 3 EXCRETCD VIA "IN: .
NONE FEMAING IH THE CODY UNCHAN(iE D .
STORAGE: STORE IN A COOL, DRY. UELL-VENTIL A TED AREA . NO INCOMPATIBLE MATER-IALS.
PERSONNEL: Pf0 EAT. 'O , DRINKING OR SMOKING. USE SPECIAL CLOTHING. CHANGE A SHouER UHEN CONfAMINATED. DO NOT GREATHE CUST UMICH MAY ACCUMULATE IN CLOSED SPACE 3 A PETS.
- +***+*4******4***
l 07 ENUTRONhENT l A u .u. + * + + + ; * + # + , + +
$ PILL HAZARD CHEMICAL NAME/ FORMULA LITHIUa HYDROXIDE MON 0 HYDRA TE. LiOH+H20. REV.12/87 0 ENVIR011 ENTAL HAZARD MODERATE HAZARD TO AIR, UATER, SOIL l EFFECTS ON AIR: NONE.
l EFFECTS ON WATER: POTENTIALLY SEVERE CONTAMINATION UHICH IS Nt; "ERSISTENT DUE TO HIGH SOLUDILITY OF LITHIUM.
EFFECTS ON SOIL: POTENTIALLY SEVERE CONTAMINATION, LEADING TO GROUND UATER
! POLLUTION, CUT WITH TRANSIENT EFFECTS ONLY. NOT A MAJOR HAZARD TO '0IL.
'lAZARD TO LIVING SYSTEMS l LOCAL. EFFECTS IN 1ririE DI ATE S PI.LL AREA , DUT LONO-TERM EFFECTS.^?E MINIMAL D.UE_
TO RAPID DILUTION & DISPERSAL. NO BI0 CONCENTRATION IN THE FOC~. CHAIN. NO IN-CREASE IN CHEMICAL OR BIOLOGIC OXYOEN DEMAND, ENVIRCNMENTAL ACTION - PART 1 ,
00T GUIDE TEXT - SPILL OR LEAR EMERGENCY ACTION ]
l - STANDARD PHRASE SL I DO NOT TOUCH SPILLED MATERIAL. S TOP LEAK IF YOU AN 00 IT WITHOUT RISK.
SMALL SPILLS : TAKE UP UITH SAND OR OTHER )N-CONGUSTIBLE, ABSORBENT l
l MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL SMALL DRY SPILLS : UITH A CLEAN SHOVEL, PLACE TERIAL INTO CLEAN, DRY CONTAINER AND COVER. MOVE COI TNERS FROM SPILL AREA.
t i L.ARGE 3 PILLS . DIKE FAR AHEAD OF SPILL FOR LATEr SPOSAL.
nnu======================================== r====================
l DANGER! SEE ALL SUBSECTIONS OF SECTION 6, "HE A.. TH " , BEFORE ALLOUING ':
PERSONNEL TO ENTER THE SPI'.'. ' LEAK AREA L l
l
. _ _ _ . _._-.m
~
\
I l
- l
- = = .n = = .2 = = :- r t - = .u = = -:; ,. t z am : . --.m, -: . us .. ., , : .- n m ., :. = u n = = = ., ., ;
I auIRONMEa rAL ACT[ON PART '
1400ITIONAL aCTIOH AIR F:ELEASES: h0NITOR I TUNI J OH . C L I: A R I!1hED Io lE AREA , ALLOU UING TO DISPERSE.
'JA FER RELEASES: DIME, DIVERf, ISOLATE, TREAT TN Pl AG UITH ACIDS OR !0DIUM 8[ SULFATE.
l SOIL RELEASES: TREAT IN P!.nCE UI TH ACIOS , OR F0DIUh E ICUL FIDE.
! OISPOSAL MAY BE TREATED a NEUTRALIIED WITHUUT EXPERT ASSISTANCE USING SODIUM BISUL-FATE. HAZARDOUG UAS TE L ANOFILL OISPOSAL OF THE UNTREATED MA TEPI AL IS NOT RECOMMENDED. ALDRICH CHEMICAL CATALOG RE~ COMMENDS NEUTRALIZING UITH ArIDS, DILUTING, THEN POURING 00UN SEUER.
ne=====t======= = = = :x = = = = = = = = = = = - = .* :.r m w , n n w = = = = = = = -:: = = = = = = .m = = = = = = = = = = = = = u u = = = = = =
l OANGER! SEE ALL GUBSECTIONS OF SECTION 6, " HEALTH", CEFORE ALLOUING :
- FERSONNEL TO ENTER THE GPIlL/ LEAK AREA : <
7 = .2 = rs i:2: : r: = = = = = eg .:: :x = :.:: = = x. t = = x = = :.:: = = = :::: e ~ = :: = ::= = = m. T u. n r:: a = = = = = ..:: .:: = :m = r:: rt::s; :t ;;;; n;:t: := = 22 u = = :::3 = == = =
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C!IEhICAL NAME/ FORMULA LITHIUM HYOROXIDE MONOMYORATE. LiOH*H20. REV.12/87 0 GENERAL HAZARD PATING MODERATE MAJOR MANUFACTURER HACH COMPANY (5.15) 230<533 NATIONAL RESOURCE CEN TER REGIONAL RESOURCE CENTER FEDERAL AGENCIEc STATE AGENCIES LOCAL AGENC.IES __
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Ex LOCAL CLEANUP
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l 09 DISCLAIMER l '
(*****+**********
l The information in this software was prepared by the Northridge Tox Center, 1 Northridge Hosp 2tal Medical Center, Northridge, Califorr.la from sources and ;
3 experiences deemed to be reliable and accurate. The reader is cautioned that ,
information in published sources cannot substitute for the j u d g erne n t of
] k n o wl ed g ea r'le , responsible persons at the scene. Also bear in mind that the i 4 Information published herein does not address hazards whict arise when two
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