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#REDIRECT [[W3F1-2015-0032, Annual Radiological Environmental Operating Report for the Period of January 1 Through December 31, 2014]]
| number = ML15124A010
| issue date = 04/29/2015
| title = Waterford 3 - Annual Radiological Environmental Operating Report for the Period of January 1 Through December 31, 2014
| author name = Jarrell J P
| author affiliation = Entergy Operations, Inc
| addressee name =
| addressee affiliation = NRC/Document Control Desk, NRC/NRR
| docket = 05000382
| license number = NPF-038
| contact person =
| case reference number = W3F1-2015-0032
| document type = Environmental Monitoring Report, Letter
| page count = 66
}}
 
=Text=
{{#Wiki_filter:SEntergyEntergy Operations, Inc.17265 River RoadKillona, LA 70057-3093Tel 504 739 6685Fax 504 739 6698jjarrel@entergy.comJohn P. Jarrell IIIManager -Regulatory AssuranceWaterford 3W3F 1-2015-0032April 29, 2015U.S. Nuclear Regulatory CommissionAttn: Document Control DeskWashington, DC 20555-0001
 
==Subject:==
Annual Radiological Environmental Operating Report -2014Waterford Steam Electric Station, Unit 3 (Waterford 3)Docket No. 50-382License No. NPF-38
 
==Dear Sir or Madam:==
Attached is the Annual Radiological Environmental Operating Report for the period ofJanuary 1 through December 31, 2014. This report is submitted pursuant to therequirements of Waterford 3 Technical Specification Section 6.9.1.7.This report contains no new commitments. Please contact John P. Jarrell, RegulatoryAssurance Manager, at (504) 739-6685 if you have questions regarding this information.
 
==Attachment:==
Annual Radiological Environmental Operating Report -2014tj(-CU W3Fl -2015-0032Page 2cc: Mr. Marc L. DapasRegional AdministratorU. S. Nuclear Regulatory CommissionRegion IVRidsRgn4MailCenter@nrc.govNRC Senior Resident InspectorWaterford Steam Electric Station Unit 3Frances. Ramirez@nrc.govChris. Speer@nrc.govNRC/NRR Project Manager for Waterford 3Michael.Orenak@nrc.govAllyson HowieEntergy Legal, General Sr CouncelAHowie@entergy.com Attachment toW3F1-2015-0032Annual Radiological Environmental Operating Report -2014(63 pages) w.En tergyI January 1,2014 -December 31,2014 1 Annual Radiological2014IAI f F- A 'I Qf 171 fl; Qf f;AnnrulRUI adi logcal 21 aQI 4 I 4 .IOriginator:Reviewed By:Approved By:Ann V. Dubois, Chemistry TechnicianClay M. Benton, Chemistry SupervisorNicole K. Lawless, Cl'astryManagerDatedq- -c/9-fDateDate Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric StationTABLE OF CONTENTSSUMMARY I
 
==1.0 INTRODUCTION==
51.1 Radiological Environmental Monitoring Program 51.2 Pathways Monitored 51.3 Land Use Census 52.0 INTERPRETATION AND TRENDS OF RESULTS 202.1 Air Particulate and Radioiodine Sample Results 202.2 Thermoluminescent Dosimetry Sample Results 202.3 Water Sample Results 212.4 Sediment Sample Results 212.5 Milk Sample Results 222.6 Fish Sample Results 222.7 Broad Leaf Vegetation Sample Results 222.8 Land Use Census Results 222.9 Interlaboratory Comparison Results 223.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM SUMMARY 253.1 2014 Program Results Summary 25-i -
Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTABLE 1.1TABLE 2.1TABLE 3.1LIST OF TABLESRADIOLOGICAL ENVIRONMENTAL SAMPLING PROGRAMBIENNIAL LAND USE CENSUS RESULTSRADIOLOGICAL ENVIRONMENTAL MONITORINGPROGRAM SUMMARY62326-ii -
Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationLIST OF FIGURESFIGURE 1-1FIGURE 1-2FIGURE 1-3FIGURE 2-1REMP SAMPLES WITHIN 2 MILES OF WATERFORD 3REMP SAMPLES WITHIN 10 MILES OF WATERFORD 3REMP SAMPLES WITHIN 50 MILES OF WATERFORD 3TLD RADIATION DOSE COMPARISON (BY YEAR)17181924-iii -
Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationLIST OF ATTACHMENTSATTACHMENT 1ATTACHMENT 22014 RADIOLOGICAL MONITORING REPORTSUMMARY OF MONITORING RESULTSSTATISTICAL COMPARISONS3050-iv -
Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric StationSummaryThe Annual Radiological Environmental Operating Report presents data obtained through analyses ofenvironmental samples collected for Waterford 3's (W3) Radiological Environmental Monitoring Program(REMP) for the period January 1 through December 31, 2014. This report fulfills the requirements of W3Technical Specification 6.9.1.7.During 2014, gross beta radioactivity was detected in air and drinking/surface water locations. Resultsobtained at the indicator locations were similar to those obtained at the control location. Therefore, levelscontinue to remain at background.Radiological Environmental Monitoring ProgramW3 established the REMP prior to the station becoming operational (1985) to provide data on backgroundradiation and radioactivity normally present in the area. W3 has continued to monitor the environment bysampling air, water, sediment, milk, fish and broad leaf vegetation, as well as measuring radiation directly.The REMP includes sampling indicator and control locations within a 31-mile radius of the plant. TheREMP utilizes indicator locations near the site to show any increases or buildup of radioactivity that mightoccur due. to station operation, and control locations farther away from the site to indicate the presence ofonly naturally occurring radioactivity. W3 compares indicator results with control, preoperational, andprevious years operational results to assess any impact W3 might have on the surrounding environment.In 2014, W3 collected environmental samples for radiological analysis. Based on the comparison resultsof indicator locations with control locations and previous studies, it was concluded that overall W3operations had no significant impact on plant environs. The review of 2014 data, in many cases, showedundetectable radiation levels in the environment and near background levels in significant pathwaysassociated with W3.Harmful Effects or Irreversible DamaqeThe REMP did not detect any harmful effects or evidence of irreversible damage in 2014. Therefore, noanalysis or planned course of action to alleviate problems was necessary.1 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric StationReporting LevelsW3's review indicates that no samples equaled or exceeded reporting levels for radioactivityconcentration in environmental samples, as outlined in Technical Requirements Manual (TRM)Table 3.12-2 when averaged over any calendar quarter, due to W3 effluents. Therefore, 2014 results didnot trigger any radiological monitoring program special reports.Radioactivity Not Attributable to W3The W3 REMP detected radioactivity attributable to other sources three times. These include the 25thChinese nuclear test explosion in 1980, the radioactivity plume release due to reactor core degradation atthe Chernobyl Nuclear Power Plant in 1986, and the airborne release from Dai-ichi, Fukushima followingthe Tohoku earthquake on March 11, 2011.Comparison to State ProgramW3 compared REMP data to the monitoring program of the Environmental Radiological Laboratory -Department of Environmental Quality Laboratory Services Division (ERL-DEQLSD). The ERL-DEQLSDand the W3 REMP entail similar radiological environmental monitoring program requirements. Bothprograms have obtained similar results over previous years.Sample Deviations* Milk SamplesSince milk samples for indicator location MKE-3 were unavailable for all quarters of 2014, broad leafvegetation sampling was performed as required by TRM Table 3.12-1. Broad leaf vegetation resultsare in section 2.7. Milk samples were collected from one control location and analyzed for Iodine-131and gamma radionuclides. Results indicate that all measurements were below the calculated LLDs.Therefore, W3 concluded that plant operations had no significant impact on this pathway during 2014.* Air SamplesThe air sample locations listed below failed to meet the requirement for sample continuity. Asdescribed in footnote (1) of TRM Table 3.12-1, deviations are permitted from the required samplingschedule due to malfunction of sampling equipment and other legitimate reasons.Location Sample Period Explanation of DeviationAPQ-1 04/28/14 -05/12/14 Sample pump running at lowcapacity2 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric Station* Missed SamplesOne TLD located at station N-1 was missing at the time of the first quarter exchange. TLDs located atstations G-4, J-2 and N-1 were missing at the time of the second quarter exchange.+ Required Lower Limit of Detection (LLD) ValuesAll LLDs during this reporting period were within the acceptable limits required by the W3 TRM.* Unavailable ResultsW3 received analytical results in adequate time for inclusion in this report. In addition, W3's reviewidentified no missing results.* Program ModificationsNo program modifications were made during 2014.3 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric StationAttachmentsAttachment 1 contains results of air, TLD, water, sediment, milk, fish and broad leaf vegetation collectedin 2014. TLDs were analyzed by Stanford Dosimetry. All remaining samples were analyzed by TeledyneBrown Engineering, Inc. Attachment 1 also contains Teledyne's participation in the interlaboratorycomparison program during 2014.Attachment 2 contains statistical comparisons of:" TLD measurements from stations grouped by distance" TLD radiation dose to historical data by location" Gross beta activity measurements on air particulate filters* Gross beta activity measurements in surface/drinking water samples4 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric Station1.0 Introduction1.1 Radiological Environmental Monitoring ProgramW3 established the REMP to ensure that plant operating controls properly function to minimizeany associated radiation endangerment to human health or the environment. The REMP isdesigned for:* Analyzing important pathways for anticipated types and quantities of radionuclides releasedinto the environment.* Considering the possibility of a buildup of long-lived radionuclides in the environment andidentifying physical and biological accumulations that may contribute to human exposures." Considering the potential radiation exposure to plant and animal life in the environmentsurrounding W3." Correlating levels of radiation and radioactivity in the environment with radioactive releasesfrom station operation.1.2 Pathways MonitoredThe airborne, direct radiation, waterborne and ingestion pathways are monitored as required byW3 TRM Table 3.12-1. A description of the W3 REMP utilized to monitor the exposure pathwaysis described in Table 1.1 and shown in Figures 1-1, 1-2 and 1-3.Section 2.0 of this report provides a discussion of 2014 sampling results with Section 3.0providing a summary of results for the monitored exposure pathways.1.3 Land Use CensusW3 conducts a land use census biennially, as required by Section 3.12.2 of the TRM. Thepurpose of this census is to identify changes in uses of land within five miles of W3 that wouldrequire modifications to the REMP and the Offsite Dose Calculation Manual (ODCM). The mostimportant criteria during this census are to determine the location in each sector of the nearest:1) Residence2) Animal milked for human consumption2 23) Garden of greater than 50 m (500 ft ) producing broad leaf vegetation.W3 conducts the land use census by:" Field surveys in each meteorological sector out to five miles in order to confirm:, Nearest permanent residence: Nearest garden and approximate size> Nearest beef cow> Nearest food product> Nearest milking animal" Identifying locations on maps, measuring distances to W3 and recording results on datasheets." Comparing current census results to previous results.5 Annual RadiologicalEnvironmental Ooeratina Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesAirborne Radioiodine and ParticulatesThree samples from close to the three APQ-1 (NW, 0.81 Miles) -(West bank) Continuous sampler operation Radioiodine Canister 131SITE BOUNDARY locations, in different Located in soybean/sugarcane field off with sample collection bi- analysis bi-weekly.sectors, in or near sectors having the LA 18 east of LA 18/3141 intersection.highest calculated annual average weekly, or more frequently ifground level D/Q. APF-1 (ESE, 0.35 Miles) -(West bank) required by dust loading. Particulate Sampler -GrossLocated on north side of Secondary beta radioactivity analysisMeteorological Tower. following filter change. GammaAPC-1 (NE, 0.67 Miles) -(East bank) isotopic analysis of compositeLocated inside Little Gypsy Cooling Water (by location) quarterly.Intake Structure fence.Radioiodine and ParticulatesOne sample from the vicinity of a APP-I (WNW, 0.84 Miles) -(West bank)community having the highest Located in soybean/sugarcane field oncalculated annual average ground level Short St. in Killona.D/Q.Radioiodine and ParticulatesOne sample from a control location, as APE-30 (E, 25.2 Miles) -(West bank)for example 15 -30 km distant and in Located on roof of Entergy Office buildingthe least prevalent wind direction, on Delaronde St. in Algiers. (Control)6 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation An inner ring of stations, one in each A-2 (N, 1.27 Miles) -(East bank) Located Quarterly Gamma dose quarterly.meteorological sector in the general on pole on LA 628 at Zephrin L. Perrilouxarea of the SITE BOUNDARY. Fire House.B-I (NNE, 0.75 Miles) -(East bank)Located on fence west of Little Gypsy.C-1 (NE, 0.67 Miles) -(East bank) Locatedon fence at Little Gypsy Cooling WaterIntake structure.D-2 (ENE, 1.24 Miles) -(East bank)Located on pole on levee at west entranceto Bonnet Carre Spillway.7 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation An inner ring of stations, one in each E-1 (E, 0.41 Miles) -(West bank) Located on Quarterly Gamma dose quarterly.meteorological sector in the general pole on LA 18 east of Waterford 3 plantarea of the SITE BOUNDARY. entrance.F-2 (ESE, 1.15 Miles) -(West bank) Locatedon fence on LA 3142 south of LA 18.G-2 (SE, 1.26 Miles) -(West bank) Locatedon fence on LA 3142 north of railroadoverpass.H-2 (SSE, 1.54 Miles) -(West bank) Locatedon fence on LA 3142 north of LA 3127/3142intersection.8 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation An inner ring of stations, one in each J-2 (S, 1.38 Miles) -(West bank) Located on Quarterly Gamma dose quarterly.meteorological sector in the general fence south of LA 3127 west of LA 3127/3142area of the SITE BOUNDARY. intersection.K-I (SSW, 1.06 Miles) -(West bank) Locatedon stop sign at entrance to Entergy EducationCenter on LA 3127.L-1 (SW, 1.06 Miles) -(West bank) Locatedon gate on LA 3127 west of LA 3127/3142intersection.M-1 (WSW, 0.76 Miles) -(West bank)Located on south gate of Waterford 1 and 2.N-1 (W, 0.98 Miles) -(West bank) Located onpole at comer of Railroad Avenue and SchoolHouse Road.9 Annual RadiologicalEnvironmental Oeeratina Reoort2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation An inner ring of stations, one in each P-1 (WNW, 0.84 Miles) -(West bank) Located Quarterly Gamma dose quarterly.meteorological sector in the general on fence enclosing air sample station APP-I.area of the SITE BOUNDARY.Q-1 (NW, 0.81 Miles) -(West bank) Locatedon fence enclosing air sample station APQ-1.R-1 (NNW, 0.51 Miles) -(West bank) Locatedat Waterford 1 and 2 Cooling Water IntakeStructure.TLDsAn outer ring of stations, 1 in 10 of the A-5 (N, 4.59 Miles) -(East bank) Located onmeteorological sectors in the 6 to 8 km pole at intersection of Oswald Avenue and USranges from the site. 61.10 Annual RadiologicalEnvironmental ODeratina Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation An outer ring of stations, 1 in 10 of the B-4 (NNE, 3.75 Miles) -(East bank) Located Quarterly Gamma dose quarterly.meteorological sectors in the 6 to 8 km on pole near weigh station on US 61.ranges from the site.D-5 (ENE, 4.09 Miles) -(East bank) Locatedon gate on shell road north of US61/LA48intersection.F-4 (ESE, 3.53 Miles) -(West bank) Locatedon pole behind house at 646 Aquarius St. inHahnville.11 Annual RadiologicalEnvironmental Ooeratino Reoort2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation An outer ring of stations, 1 in 10 of the E-5 (E, 4.08 Miles) -(East bank) Located on Quarterly Gamma dose quarterly.meteorological sectors in the 6 to 8 km fence on Wesco Street off LA 48.ranges from the site.G-4 (SE, 3.30 Miles) -(West bank) Locatedon pole on LA 3160 north of railroad track.H-8 (SSE, 8.13 Miles) -(West bank) Locatedon pole in front of Hahnville High School.P-6 (WNW, 5.58 Miles) -(West bank) Locatedon fence at LA 640/railroad track intersection.Q-5 (NW, 5.01 Miles) -(West bank) Locatedon pole on LA 18 across from Mississippi Rivermarker 137.12 Annual RadiologicalEnvironmental ODeratina Reoort2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation An outer ring of stations, 1 in 10 of the R-6 (NNW, 5.52 Miles) -(East bank) Located on Quarterly Gamma dose quarterly.meteorological sectors in the 6 to 8 km fence on LA 3223 near railroad crossing.ranges from the site.TLDsThe balance of the stations to be in F-9 (ESE, 8.18 Miles) -(East bank) Located onspecial interest areas such as fence north of railroad tracks on Jonathan Street.population centers, nearby residences,schools, and in 1 or 2 areas to serve G-8 (SE, 7.74 Miles) -(West bank) Located onas control stations. back fence of Luling Entergy Office.E-15 (E, 11.7 Miles) -(East bank) Located onfence on Alliance Avenue.13 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesDirect TLDsRadiation The balance of the stations to be in J-15 (S, 11.7 Miles) -(West bank) Located on pole Quarterly Gamma dose quarterly.special interest areas such as near LA 631/Hwy 90 intersection in Des Allemands.population centers, nearby residences,schools, and in 1 or 2 areas to serve E-30 (E, 25.2 Miles) -(West bank) Located atas control stations. entrance to Entergy office on Delaronde St. in Algiers.(Control)Waterborne Surface WaterOne sample upstream SWP-7 (WNW, 7.37 Miles) -(West bank) Located at Composite sample over Gamma isotopic analysisSt. John Parish Waterworks in Edgard. (Control) one quarter period, quarterly. Composite forSWF-2 (ESE, 1.51 Miles) -(West bank) Located at tritium analysis quarterly.One sample downstream Dow Chemical Plant drinking water canal.SWE-5 (E, 4.59 Miles) -(East bank) Located at St.Charles Parish Waterworks in New Sarpy.SWK-1 (SSW, 0.49 Miles) -(West bank) Located at40 Arpent Canal south of the plant.14 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesWaterborne Drinking WaterOne sample upstream DWP-7 (WNW, 7.37 Miles) -(West bank) Located Composite sample over one 1-131 analysis on eachat St. John Parish Waterworks in Edgard. (Control) month period when 1-131 composite when the doseDWF-2 (ESE, 1.51 Miles) -(West bank) Located at analysis is performed, quarterly calculated for the consumption ofOne sample downstream Dow Chemical Plant drinking water canal. composite otherwise. the water is greater than oneDWE-5 (E, 4.59 Miles) -(East bank) Located at St. mrem per year. Composite forCharles Parish Waterworks in New Sarpy. gross beta and gamma isotopicanalyses quarterly. Compositefor tritium analysis quarterly.Sediment from ShorelineOne sample upstream SHWQ-6 (NW, 5.99 Miles) -(East bank) Locatedon LA 628 east of Reserve ferry landing. (Control) Annually Gamma isotopic analysisannually.SHWE-3 (E, 2.99 Miles) -(West bank) Located atOne sample downstream Foot Ferry landing on LA 18.SHWK-1 (SSW, 0.49 Miles) -(West bank) Locatedat 40 Arpent Canal south of plant.Ingestion MilkSamples from milking animals in the MKE-3 (E, 2.35 Miles) -(West bank) Located at the Quarterly Gamma isotopic and 1-131three locations within 5 km distance Zeringue's house on LA 18 in Taft.having the highest dose potential. If analysis quarterly.there are none, then, one samplefrom milking animals in each of thethree areas between 5 to 8 kmdistant where doses are calculatedto be greater than 1 mrem per year.15 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 1.1Radiological Environmental Sampling ProgramExposure Requirement Sample Point Description, Sampling and Type and FrequencyPathway Distance and Direction Collection Frequency Of AnalysesIngestion MilkOne sample from milking animals at a MKA-31 (N, 31.2 Miles) -(East bank) Located at Quarterly Gamma isotopic and 1-131control location 15 -30 km distant and 18736 Sisters Road, Ponchatoula, LA. (Control) analysis quarterly.in the least prevalent wind direction.Fish and InvertebratesOne sample of each commercially and FH-2 (Distance/Direction Not Applicable) -Sample in season, or Gamma isotopic analysisrecreational important species in vicinity Downstream of the plant discharge structure. annually if they are not on edible portion.of plant discharge area. seasonalFH-3 (Distance/Direction Not Applicable) -(Westbank) Waterways downstream of plantdischarge directed to 40 Arpent Canal.One sample of same species in area FH-1 (Distance/Direction Not Applicable) -not influenced by plant discharge. Upstream of the plant intake structure. (Control)BroadleafSamples of one to three different kinds BLQ-1 (NW, 0.83 Miles) -(West bank) Located near Quarterly Gamma isotopic and 1-131of broadleaf vegetation grown nearest air sample station APQ-1. analysis.each of two different off-site locations ofhighest predicted annual average BLB-1 (NNE, 0.81 Miles) -(East bank) Located westground level D/Q if milk sampling is not of Little Gypsy on LA 628.performed.One sample of each of the similar BLE-20 (E, 19.7 Miles) -(West bank) Located onbroadleaf vegetation grown 15 -30 km property of Nine Mile Point in Westwego. (Control)distant in the least prevalent winddirection if milk sampling is notperformed.16 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationFIGURE 1-117 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationFIGURE 1-218 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationFIGURE 1-3RE10 toMP Samples Within St ... H010" N50OMilesof Waterford-3REast Baton Rouge olQ~Qrn/ ~ ,,St Tdlw&#xfd;ny/ /i~~;i~St <.. I aft.fesc 11I F--L G'I. ~+0Lf~ce 10 .20 Mi le4/K1019 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric Station2.0 Interpretation and Trends of Results2.1 Air Particulate and Radioiodine Sample ResultsSamples of airborne particulate and radioiodine were collected at four indicator locations and onecontrol location and analyzed for gross beta radionuclides, Iodine-1 31 and gamma radionuclides(quarterly air particulate filter composites only). W3 did not detect any gamma radionuclides inthe quarterly air particulate composites or Iodine-1 31 in the radioiodine cartridges during thereporting period as has been the case in previous years. Indicator gross beta air particulateresults for 2014 were similar to those background levels obtained in previous years of theoperational REMP and well below preoperational levels as seen below. Results are reported as3annual average pCi/miMonitoring Period ResultPreoperational 0.0801983-2013 0.0202014 0.020Table 3.1, which includes gross beta concentrations for 2014, provides a comparison of theindicator and control means. It further emphasizes that the airborne pathway continues to remainat background levels. In addition, as shown in Attachment 2, the standard "t" test was used tocompare average gross beta activity from each indicator station to the average gross beta activityat the control station. The results from this test show the average activity detected at all indicatorstations is statistically the same as the average activity detected at the control station. Therefore,W3 concluded that plant operations had no significant impact on this pathway during 2014.2.2 Thermoluminescent Dosimetry Sample ResultsThe average exposure rates during 2014 are consistent with those from the preoperationalprogram and the previous five years of operation as seen in Figure 2-1. In particular, thepreoperational survey indicates that exposure rates ranged between 11 and 33 mrem/standardquarter with an average of 20 mrem/standard quarter. The range during the previous five years ofoperation was 9 to 16 mrem/standard quarter with an average exposure rate of 12mrem/standard quarter.A comparison of the indicator results to the control results, as seen in Table 3.1, shows that theaverage indicator is slightly higher than that of the control. As shown in Attachment 1, Table 2.1,several indicator locations are higher than the control by a few mrem with a maximum differenceof six mrem.As shown in Attachment 2, Table 2.1, the standard "t" test was used to compare averageexposure rates for TLD stations located in groups 0-2 miles and 2-5 miles from the plant to those> 5 miles. The results indicate that the average exposure rates 0-2 miles from the plant arestatistically the same as >5 miles while those 2-5 miles are statistically higher.The differences between indicator locations and the control, and TLD stations grouped bydistance from the plant are expected due to a variety of factors not related to W3 plant operationsthat can affect background radiation in the vicinity of each TLD station. Direct radiationmeasurements at each TLD station have remained statistically the same in 2014 as previousyears of operation as evidenced on Attachment 2, Table 2.2. In addition, Radiological GaseousEffluents for 2014 were only a small fraction of the limits and are not expected to have any impacton environmental TLD measurements.20 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric Station2.3 Water Sample ResultsAnalytical results for 2014 drinking/surface water samples were similar to those reported inprevious years.DrinkinqlSurface WaterDrinking water samples also serve as surface water samples for W3. Therefore, monthly andquarterly gamma spectroscopy and tritium analyses of drinking water also satisfy the surfacewater sampling requirement.Composite drinking/surface water samples were collected from two indicators and one controllocation and analyzed for Iodine-1 31, gamma radionuclides and tritium. Results indicate that allmeasurements were below the calculated LLDs.Although gross beta was detected in the drinking/surface water samples, results for the indicatorlocations were below preoperational years and slightly above previous operational years as seenbelow. Results are reported as annual average pCi/I.Monitoring Period ResultPreoperational 7.01983-2013 4.72014 5.4Table 3.1, which includes gross beta concentrations for 2014, provides a comparison of theindicator and control means. It shows that the waterborne pathway continues to remain atbackground levels. In addition, as shown in Attachment 2, the standard "t" test was used tocompare average gross beta activity from indicator stations to the average gross beta activityfrom the control station. The results from the test show the average activity detected at oneindicator station is statistically the same as the average activity detected at the control station andone indicator station is statistically higher than the mean for the control location. Results areconsistent with historical data stated above. Therefore, W3 concluded that plant operations hadno significant impact on this pathway during 2014.Surface WaterSurface water samples were collected from one indicator location and analyzed for gammaradionuclides and tritium. Results indicate that all measurements were below the calculatedLLDs. Therefore, W3 concluded that plant operations had no significant impact on this pathwayduring 2014.2.4 Sediment Sample ResultsSediment samples were collected from two indicator locations and one control location andanalyzed for gamma radionuclides. Results indicate that all measurements were below thecalculated LLDs. Therefore, W3 concluded that plant operations had no significant impact on thispathway during 2014.21 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric Station2.5 Milk Sample ResultsSince milk samples for indicator location MKE-3 were unavailable for all quarters of 2014, broadleaf vegetation sampling was performed as required by TRM Table 3.12-1. Broad leaf vegetationresults are in section 2.7. Milk samples were collected from one control location and analyzed forIodine-1 31 and gamma radionuclides. Results indicate that all measurements were below thecalculated LLDs. Therefore, W3 concluded that plant operations had no significant impact on thispathway during 2014.2.6 Fish Sample ResultsFish samples were collected from two indicators and one control location and analyzed forgamma radionuclides. Results indicate that all measurements were below the calculated LLDs.Therefore, W3 concluded that plant operations had no significant impact on this pathway during2014.2.7 Broadleaf Vegetation Sample ResultsBroadleaf vegetation samples were collected from two indicators and one control location andanalyzed for Iodine-1 31 and gamma radionuclides. Results indicate that all measurements werebelow the calculated LLDs. Therefore, W3 concluded that plant operations had no significantimpact on this pathway during 2014.2.8 Land Use Census ResultsIn compliance with the Waterford 3 0DCM and TRM, the land use census was conductedSeptember 22 -September 24, 2014. The nearest residence, garden, beef cow, food productand milk animal in each sector within a five mile radius of the plant was located by visualinspection and verbal inquiry.Two new garden locations (sectors P and Q) were identified in 2014. Residence, milk cow, andgoat locations remained unchanged for 2014. Beef cows located in sector E at a distance of 2.9miles from the plant have been removed. A soybean field is located in sector N at a distance of0.6 miles from the plant. Based upon the locations identified in this survey, the locationsidentified in previous surveys and the locations currently being used to calculate dosecommitments from liquid and gaseous effluents released from W3, no REMP sampling locationchanges are necessary. Results of the 2014 biennial census are shown in Table 2.1.2.9 Interlaboratory Comparison ResultsTeledyne Brown Engineering, Inc. analyzed interlaboratory comparison samples for W3 to fulfillthe requirements of Section 5.7.2 of the ODCM. Attachment 1 contains these results.22 Annual RadiologicalEnvironmental Ooerating Report2014Waterford 3 Steam Electric StationTABLE 2.1Biennial Land Use Census ResultsSector Direction Distance from Plant in MilesMilk Beef FoodResidence Garden Cows Cows Goats ProductsA N 1.3 1.7 A 4.8 A 4.1B NNE 1.1 1.3 A A A 1.3C NE 0.9 1.0 A A A AD ENE 0.9 3.2 A A A AE E 2.2 2.2 **2.3 2.3
* 3.2 0.3F ESE 3.1 2.2 A 2.3 A 0.3G SE 4.0 4.1 A 2.4 A 0.3H SSE A A A A A 0.3J S A A A A A 0.5K SSW A A A A A 0.5L SW A A A A A 0.5M WSW A 1.4 A 1.2 A 0.5N W 1.0 1.1 A 1.0 A 0.6P WNW 0.9 0.9 A A A 0.6Q NW 0.9 0.8 A A A 0.6R NNW 3.0 3.0 A 4.9 A 2.6A Indicates that nothing was found in the sector within a five mile radius ofWaterford 3* Animals were located at this distance from Waterford 3, but the milk is notcurrently used for human consumption** Samples are being obtained from animals at this location (MKE-3) for REMP23 Annual RadiologicalEnvironmental ODeratina Reoort2014Waterford 3 Steam Electric StationFIGURE 2-1TLD Radiation Dose Comparison By Year4035J302Z20I5E0E 10504035302520151050YEAR24 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric Station3.0 Radiological Environmental Monitoring Program Summary3.1 2014 Program Results SummaryTable 3.1 summarizes the 2014 REMP results. W3 did not use values reported as less than thelower limit of detection (< LLD) when determining ranges and means for indicator and controllocations.25 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTABLE 3.1Radiological Environmental Monitoring Program SummaryName of Facility: Waterford 3 SES Docket No: 50-382Location of Facility: St. Charles. Louisiana Reporting Period: January -December 2014Sample Type Type & Number LLD b Indicator Locations Location with Highest Annual Control Number of(Units) Of Analyses a Mean (F ) c Mean Locations Nonroutine[Range ] Mean (F) c Results e[ Range]Mean (F )CLocation d [ Range ]Airborne Particulates GB 130 0.01 0.020 ( 104 / 104) APF-1 0.021 ( 26 / 26) 0.020 ( 26 / 26) 0(pCi/m3) [0.008-0.042] (ESE, 0.35 mi.) [0.013- 0.0311 [0.011 -0.030]GS 20Cs-1 34 0.05 <LLD N/A N/A <LLD 0Cs-1 37 0.06 <LLD N/A N/A <LLD 0Airborne Iodine 1-131 130 0.07 <LLD N/A N/A <LLD 0( pCi/m3)Indicator TLDs Gamma 120 (f) 12(116/120) L-1 14(4/4) N/A 0(mrem/Std. Qtr) [8.9-15.0] (SW, 1.06 mi.) [14.2-14.6]Control TLDs Gamma 4 (f) N/A N/A N/A 10(4/4) 0(mrem/Std. Qtr) [9.3 -10.2]26 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTABLE 3.1Radiological Environmental Monitoring Program SummaryName of Facility: Waterford 3 SES Docket No: 50-382Location of Facility: St. Charles, Louisiana Reporting Period: January -December 2014Sample Type Type & Number LLD b Indicator Location Location with Highest Annual Mean Control Number of(Units) of Analyses a Mean ( F ) c Locations Nonroutine[Range] Mean (F) c Results e[ Range ]Mean ( F ) cLocation d [ Range ]Surface Water & Gross Beta 12 4 5.4(8/8) DWF/SWF-2 5.6(4/4) 4.4(4/4) 0Drinking Water [4.1 -6.9] (ESE, 1.51 mi.) [4.5 -6.9] [3.5 -4.8]( pCi~ll)1-131 40 1 <LLD N/A N/A <LLD 0H-3 12 2000 <LLD N/A N/A <LLD 0GS 12Mn-54 15 <LLD N/A N/A <LLD 0Fe-59 30 <LLD N/A N/A <LLD 0Co-58 15 <LLD N/A N/A <LLD 0Co-60 15 <LLD N/A N/A <LLD 0Zn-65 30 <LLD N/A N/A <LLD 0Zr-95 15 <LLD N/A N/A <LLD 0Nb-95 15 <LLD N/A N/A <LLD 0Cs-134 15 <LLD N/A N/A <LLD 0Cs-137 18 <LLD N/A N/A <LLD 0Ba-140 15 <LLD N/A N/A <LLD 0La-1 40 15 <LLD N/A N/A <LLD 027 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTABLE 3.1Radiological Environmental Monitoring Program SummaryName of Facility: Waterford 3 SES Docket No: 50-382Location of Facility: St. Charles, Louisiana Reporting Period: January -December 2014Sample Type Type & LLD b Indicator Locations Location with Highest Annual Mean Control Locations Number of(Units) Number Mean (F) c Mean (F) c Nonroutineof Analyses a [Range] [Range] Results eMean (F ) cLocation d [Range]Surface Water H-3 4 3000 <LLD N/A N/A N/A 0(pCi/I)GS 13Mn-54 15 <LLD N/A N/A N/A 0Fe-59 30 <LLD N/A N/A N/A 0Co-58 15 <LLD N/A N/A N/A 0Co-60 15 <LLD N/A N/A N/A 0Zn-65 30 <LLD N/A N/A N/A 0Zr-95 15 <LLD N/A N/A N/A 0Nb-95 15 <LLD N/A N/A N/A 0Cs-1 34 15 <LLD N/A N/A N/A 0Cs-1 37 18 <LLD N/A N/A N/A 0Ba-1 40 15 <LLD N/A N/A N/A 0La-140 15 <LLD N/A N/A N/A 01-131 15 <LLD N/A N/A N/A 0Shoreline GS 3Sediment Cs-134 150 <LLD N/A N/A <LLD 0(pCi/kg dry)Cs-1 37 180 <LLD N/A N/A <LLD 028 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTABLE 3.1Radiological Environmental Monitoring Program SummaryName of Facility: Waterford 3 SES Docket No: 50-382Location of Facility: St. Charles. Louisiana Reporting Period: January -December 2014Sample Type Type & Number LLD b Indicator Location Location with Highest Annual Mean Control Number of(Units) of Analyses a Mean (F ) C Locations Nonroutine[Range] Mean (F) C Results e[Range]Mean ( F ) cLocation d [Range ]Milk 1-131 4 1 < LLD N/A N/A <LLD 0(pCi/I)GS 4Cs-1 34 15 < LLD N/A N/A <LLD 0Cs-1 37 18 < LLD N/A N/A <LLD 0Ba-140 15 < LLD N/A N/A <LLDLa-140 15 < LLD N/A N/A <LLD 00Fish GS 13(pCi/kg wet) Mn-54 130 <LLD N/A N/A <LLD 0Fe-59 260 <LLD N/A N/A <LLD 0Co-58 130 <LLD N/A N/A <LLD 0Co-60 130 <LLD N/A N/A <LLD 0Zn-65 260 <LLD N/A N/A <LLD 0Cs-1 34 130 <LLD N/A N/A <LLD 0Cs-1 37 150 <LLD N/A N/A <LLD 0Broadleaf Vegetation 1-131 12 60 <LLD N/A N/A <LLD 0(pCi/kg wet)GS 12Cs-1 34 60 <LLD N/A N/A <LLD 0Cs-1 37 80 <LLD N/A N/A <LLD 0a GB = Gross beta; 1-131 = Iodine-131; H-3 = Tritium; GS = Gamma scan.b LLD = required lower limit of detection based on Waterford 3 TRM.c Mean and range based upon detectable measurements only. Fraction of detectable measurements at specified locations is indicated in parenthesis (F).d Locations are specified (1) by name and (2) degrees relative to reactor site.e Non-routine results are those which exceed ten times the control station value. If no control station value is available, the result is considered non-routineif it exceeds ten times the preoperational value for the location.f LLD is not defined in Waterford 3 TRM.29 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric Station* = ,Attachment 12014 Radiological Monitoring ReportSummary of Monitoring Results30 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTABLE OF CONTENTSTABLE 1.1TABLE 1.2TABLE 1.3TABLE 2.1TABLE 3.1TABLE 3.2TABLE 3.3TABLE 3.4TABLE 3.5TABLE 4.1TABLE 5.1TABLE 6.1TABLE 7.1TABLE 8.1AIR PARTICULATE FILTERRADIOIODINE CARTRIDGEAIR PARTICULATE FILTERTHERMOLUMINESCENT DOSIMETERSDRINKING/SURFACE WATERDRINKING/SURFACE WATERDRINKING/SURFACE WATERDRINKING/SURFACE WATERSURFACE WATERSEDIMENTMILKFISHBROADLEAF VEGETATIONINTERLABORATORY COMPARISON323334353637383940414243444531 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 1.1Sample Type: Air Particulate FilterAnalysis: Gross BetaUnits: pCi/m3End Date APF-1 APQ-1 APP-1 APC-1 APE-30(Indicator) (Indicator) (Indicator) (Indicator) (Control)Required LLD01-06-1401-20-1402-03-1402-17-1403-03-1403-17-1403-31-1404-14-1404-28-1405-12-14(l)05-25-1406-09-1406-23-1407-08-1407-21-1408-04-1408-18-1409-02-1409-15-1409-29-1410-13-1410-27-1411-11-1411-24-1412-08-1412-22-140.010.0250.0130.0220.0200.0210.0150.0170.0180.0190.0230.0290.0130.0220.0180.0160.0230.0190.0310.0140.0170.0190.0240.0250.0290.0210.0300.010.0240.0130.0200.0210.0210.0160.0210.0160.0210.0290.0220.0130.0170.0160.0180.0210.0190.0230.0150.0150.0150.0230.0210.0280.0190.0290.010.0270.0130.0220.0210.0160.0150.0150.0170.0180.0220.0210.0130.0160.0170.0190.0230.0200.0160.0100.0180.0190.0240.0220.0220.0170.0290.010.0290.0150.0210.0190.0200.0150.0210.0160.0170.0230.0250.0120.0180.0100.0160.0240.0210.0180.0080.0160.0190.0220.0190.0200.0200.0420.010.0280.0160.0220.0210.0180.0150.0230.0180.0200.0240.0220.0110.0200.0190.0180.0230.0240.0160.0130.0200.0170.0220.0240.0240.0190.030(1) Low volume due to sample pump running at low capacity32 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTable 1.2Sample Type: Radiolodine CartridgeAnalysis: Iodine-131Units: pCi/m3End Date APF-I APQ-1 APP-1 APC-1 APE-30(Indicator) (Indicator) (Indicator) (Indicator) (Control)Required LLD -00.0.0701-06-1401-20-1402-03-1402-17-1403-03-1403-17-1403-31-1404-14-1404-28-1405-12-14(")05-25-1406-09-1406-23-1407-08-1407-21-1408-04-1408-18-1409-02-1409-15-1409-29-1410-13-1410-27-1411-11-1411-24-1412-08-1412-22-14< 0.027< 0.036< 0.029< 0.037< 0.025< 0.042< 0.011< 0.040< 0.025< 0.028< 0.033< 0.023< 0.029< 0.028< 0.037< 0.009< 0.034< 0.019< 0.034< 0.011< 0.026< 0.044< 0.015< 0.026< 0.043< 0.0270.07< 0.026< 0.034< 0.028< 0.035< 0.024< 0.039< 0.027< 0.038< 0.009< 0.032< 0.030< 0.021< 0.026< 0.026< 0.033< 0.021< 0.033< 0.032< 0.012< 0.010< 0.024< 0.040< 0.035< 0.044< 0.039< 0.0240.07< 0.010< 0.033< 0.027< 0.034< 0.023< 0.038< 0.026< 0.036< 0.023< 0.025< 0.030< 0.009< 0.026< 0.026< 0.033< 0.021< 0.033< 0.033< 0.032< 0.010< 0.013< 0.042< 0.037< 0.045< 0.040< 0.0250.07< 0.025< 0.034< 0.011< 0.036< 0.024< 0.039< 0.027< 0.038< 0.024< 0.027< 0.031< 0.022< 0.028< 0.010< 0.037< 0.022< 0.034< 0.033< 0.032< 0.010< 0.025< 0.042< 0.037< 0.033< 0.018< 0.0300.07< 0.025< 0.019< 0.028< 0.019< 0.010< 0.021< 0.027< 0.020< 0.024< 0.026< 0.013< 0.022< 0.011< 0.022< 0.019< 0.009< 0.018< 0.034< 0.032< 0.004< 0.024< 0.023< 0.037< 0.046< 0.041< 0.014(1) Low volume due to sample pump running at low capacity33 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTable 1.3Sample Type: Air Particulate FilterAnalysis: Gamma IsotopicUnits: pCi/miLocation Quarterly Cs-1 34 Cs-1 37CompositeRequired LLD -0.05 0.06APF-1 (Indicator) 1st < 0.002 < 0.003APQ-1 (Indicator) 1st < 0.002 < 0.001APP-1 (Indicator) 1st < 0.002 < 0.002APC-1 (Indicator) 1st < 0.003 < 0.002APE-30 (Control) 1st < 0.003 < 0.003APF-1 (Indicator) 2nd < 0.003 < 0.003APQ-1 (Indicator) 2nd < 0.004 < 0.005APP-1 (Indicator) 2nd < 0.004 < 0.004APC-1 (Indicator) 2nd < 0.004 < 0.004APE-30 (Control) 2nd < 0.002 < 0.002APF-1 (Indicator) 3rd < 0.003 < 0.003APQ-1 (Indicator) 3rd < 0.003 < 0.002APP-1 (Indicator) 3rd < 0.003 < 0.002APC-1 (Indicator) 3rd < 0.002 < 0.002APE-30 (Control) 3rd < 0.002 < 0.002APF-1 (Indicator) 4th < 0.003 < 0.003APQ-1 (Indicator) 4th < 0.004 < 0.003APP-1 (Indicator) 4th < 0.003 < 0.003APC-1 (Indicator) 4th < 0.005 < 0 .004APE-30 (Control) 4th < 0.003 < 0. 00334 Annual RadiologicalEnvironmental Operatincl Report2014Waterford 3 Steam Electric StationTable 2.1Sample Type: Thermoluminescent DosimetersAnalysis: Gamma DoseUnits: mrem/Std. Qtr.Indicator LocationsStation 1st Qtr '14 2nd Qtr '14 3rd Qtr '14 4th Qtr '14 Annual Mean '14A-2A-5B-1B-4C-1D-2D-5E-1E-5E-1 5F-2F-4F-9G-2G-4G-8H-2H-8J-2J-1 5K-1(1) L-1M-1N-1P-1P-6Q-1Q-5R-1R-6131213149121111121011141211111113131113111410(2)10131313101012 1311 1312 1413 149 1013 1311 1211 1112 1310 1012 1214 1412 1312 11(2) 1211 1211 1214 13(2) 1113 1311 1114 1510 10(2) 1410 1013 1413 1313 1510 1010 10Control Location2nd Qtr '14 3rd Qtr '141312131491312121311131513111111111311131114101410131213101013121313913121112101214131111111213111311141014101313131010Station 1 st Qtr '144th Qtr '14 Annual Mean '14E-30 10 9 10 10 10(1) Location with highest annual mean(2) No data -TLDs missing at time of exchange35 Annual RadiologicalEnvironmental ODeratina ReDort2014Waterford 3 Steam Electric StationTable 3.1Sample Type: Drinking/Surface WaterAnalysis: Gross BetaUnits: pCi/IQuarterly DWF/SWF-2 DWE/SWE-5 DWP/SWP-7Composite (Indicator) (Indicator) (Control)Required LLD 4 4 41 st. 6.92 6.03 4.812na 5.61 5.09 4.713rd 4.45 4.07 3.484th 5.55 5.36 4.4936 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 3.2Sample Type: Drinking/Surface WaterAnalysis: Iodine-131Units: pCi/ICollection SWK-1 DWF/SWF-2 DWE/SWE-5 DWP/SWP-7Date (Indicator) (Indicator) (Indicator) (Control)LLD01-27_14(l)01-27-1402-25-1403-25-1404-23-1405-20-1406-17-1407-15-1408-12-1409-10-1410-07-1411-04-1412-02-1412-30-1415< 5.55< 2.70< 3.62< 4.35< 4.36< 3.28< 3.88< 3.59< 2.59< 5.59< 3.37< 5.54< 4.23I< 0.44< 0.57< 0.58< 0.63< 0.67< 0.72< 0.69< 0.50< 0.84< 0.63< 0.07<0.16< 0.65I< 0.50< 0.40< 0.69< 0.74< 0.62< 0.66< 0.71< 0.70< 0.45< 0.90< 0.53< 0.80< 0.24< 0.59I< 0.43< 0.61< 0.64< 0.61< 0.65< 0.72< 0.62< 0.63< 0.76< 0.65< 0.59<0.18< 0.61(1) Duplicate sample37 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric Station, = ,Table 3.3Sample Type: Drinking/Surface WaterAnalysis: Gamma IsotopicUnits: pCi/ILocation Collection Mn-54 Co-58 Fe-59 Co-60 Zn-65 Nb-95 Zr-95 Cs-134 Cs-137 Ba-140 La-140DateRequired LLD
* 15 15 30 15 30 15 15 15 18 15 15DWFISWF-2 (Indicator) 1st < 2.36 < 2.22 <4.63 < 2.22 < 4.56 < 2.31 < 4.03 < 2.31 < 2.53 < 9.09 < 2.69DWE/SWE-5 (Indicator) 1st < 2.52 < 2.41 < 4.74 < 2.55 < 5.54 < 2.46 < 4.36 < 2.41 < 2.74 < 9.26 < 2.64DWPISWP-7 (Control) 1st < 2.81 < 2.53 < 5.57 < 2.85 < 4.86 < 2.58 < 4.58 < 2.75 < 2.89 < 11.40 < 3.02DWF/SWF-2 (Indicator) 2nd < 2.72 < 2.75 < 5.79 < 2.59 < 4.94 < 2.89 < 5.11 < 2.55 < 2.85 < 14.11 < 4.28DWE/SWE-5 (Indicator) 2nd < 2.36 < 2.28 < 4.63 < 2.52 < 5.40 < 2.29 < 5.18 < 2.76 < 3.39 < 14.10 < 5.36DWPISWP-7 (Control) 2nd < 2.47 < 2.79 < 5.81 < 3.01 < 4.84 < 3.05 < 5.22 < 2.65 < 3.18 < 13.10 < 3.96DWF/SWF-2 (Indicator) 3rd < 2.14 < 2.03 < 3.51 < 2.62 < 4.20 < 2.29 < 4.24 < 1.82 < 2.46 < 12.00 < 3.86DWE/SWE-5 (Indicator) 3rd < 1.90 < 2.49 < 4.45 < 2.10 < 3.68 < 1.87 < 4.45 < 1.74 < 1.65 < 11.30 < 4.05DWP/SWP-7 (Control) 3rd < 2.65 < 2.39 < 4.80 < 2.67 < 4.89 < 2.49 < 4.52 < 2.19 < 2.53 < 14.40 < 4.56DWF/SWF-2 (Indicator) 4th < 1.76 < 2.00 < 4.22 < 1.83 < 3.70 < 2.04 < 3.23 < 1.68 < 1.84 < 12.50 < 3.97DWE/SWE-5 (Indicator) 4th < 1.98 < 1.91 < 4.50 < 1.97 < 3.98 < 2.12 < 3.51 < 1.66 < 2.00 < 12.90 < 4.09DWPISWP-7 (Control) 4th < 1.73 <2.04 < 4.87 < 1.96 < 3.96 < 1.97 < 3.55 < 1.79 < 2.00 < 13.70 < 4.5438 Annual RadiologicalEnvironmental ODeratina ReDort2014Waterford 3 Steam Electric StationTable 3.4Sample Type: Drinkinl/Surface WaterAnalysis: TritiumUnits: pCi/IQuarter DWF/SWF-2 DWEISWE-5 SWK-1 DWP/SWP-7(Indicator) (Indicator) (Indicator) (Control)Required LLD -2000 2000 3000 20001st < 588 < 592 < 593 < 5992nd < 620 < 628 < 616 < 6193rd < 583 < 581 < 579 < 5764th < 547 < 519 < 546 < 54639 Annual RadiologicalEnvironmental ODeratina Report2014Waterford 3 Steam Electric StationTable 3.5Sample Type: Surface WaterAnalysis: Gamma IsotopicUnits: pCi/ILocation Collection Mn-54 Co-58 Fe-59 Co-60 Zn-65 Nb-95 Zr-95 Cs-134 Cs-137 Ba-140 La-140DateRequired LLD 15 15 30 15 30 15 15 15 18 15 15SWK-1 01-27-14 < 2.78 < 2.91 < 5.57 < 2.67 < 5.13 < 2.86 < 4.93 < 2.80 < 2.99 < 14.80 < 4.01(Indicator) 02-25-14 < 2.13 < 2.05 < 4.72 < 1.83 < 4.17 < 2.26 < 3.99 < 2.12 < 2.41 < 8.90 < 2.1803-25-14 < 2.70 < 2.82 < 5.55 < 2.68 < 5.22 < 2.57 < 4.52 < 2.60 < 2.84 < 10.30 < 3.9604-23-14 < 2.19 < 2.54 < 5.49 < 2.96 < 5.43 < 2.60 < 4.37 < 2.37 < 2.42 < 12.90 < 3.8505-20-14 < 3.56 < 2.95 < 6.77 < 3.53 < 6.16 < 3.48 < 6.31 < 3.35 < 3.33 < 14.70 < 4.0306-17-14 < 1.83 < 1.76 < 3.72 < 1.83 < 3.67 < 1.82 < 3.22 < 1.66 < 1.91 < 8.97 < 2.7807-15-14 <2.50 <2.63 <5.14 <2.99 <5.11 <2.50 <3.99 <2.63 <2.74 <10.90 <4.1608-12-14 < 1.74 < 1.88 < 3.97 < 1.95 < 3.92 < 1.83 < 3.25 < 1.85 < 1.93 < 9.60 < 3.1109-09-14 < 1.52 < 1.52 < 3.01 < 1.52 < 2.91 < 1.70 < 2.69 < 1.47 < 1.56 < 6.98 < 2.1810-07-14 < 2.61 < 2.58 < 5.66 < 2.78 < 4.71 < 2.97 < 4.58 < 2.66 < 2.80 < 14.00 < 4.1811-04-14 < 1.49 < 1.67 < 3.30 < 1.81 < 3.98 < 1.84 < 3.04 < 1.53 < 1.44 < 8.94 < 1.4712-02-14 < 2.94 < 2.91 < 5.80 < 2.93 < 5.74 < 3.38 < 5.58 < 2.86 < 3.39 < 14.60 < 4.8712-30-14 < 3.85 < 3.60 < 7.28 < 3.55 < 7.27 < 3.88 < 6.53 < 3.66 < 4.04 < 14.30 < 4.0840 Annual RadiologicalEnvironmental Operatincl Report2014Waterford 3 Steam Electric StationTable 4.1Sample Type: SedimentAnalysis: Gamma IsotopicUnits: pCi/kg (dry)Location Collection Cs-134 Cs-1 37DateRequired LLD 150 180SHWK-1 (Indicator) 03-17-14 < 39.0 < 50.0SHWE-3 (Indicator) 03-17-14 < 73.7 < 84.4SHWQ-6 (Control) 03-17-14 < 23.8 < 49.441 Annual RadiologicalEnvironmental Operatincl Report2014Waterford 3 Steam Electric StationTable 5.1Sample Type: MilkAnalysis: Iodine-131 and Gamma IsotopicUnits: pCi/ILocation Collection 1-131 Cs-134 Cs-137 Ba-140 La-140DateRequired LLD-*MKE-3 (Indicator) (1)03-13-14(1)06_12_14(1)09-11-14(1) 12-10-14MKA-31 (Control) 03-13-1406-12-1409-11-1412-10-14In/an/an/an/a< 0.49< 0.75< 0.65< 0.31isn/an/an/an/a<3.10< 0.22< 2.28<2.1318n/an/an/an/a4.273.513.183.2615n/an/an/an/a< 14.60< 14.20< 13.20< 12.50isn/an/an/an/a<4.19< 2.21< 3.26< 3.09(1) Sample not available. Cows not producing enough milk. See page 2 for details.42 Annual RadiologicalEnvironmental Ooeratina Report2014Waterford 3 Steam Electric StationTable 6.1Sample Type: FishAnalysis: Gamma IsotopicUnits: pCi/kg (wet)Location Collection Species Mn-54 Co-58 Fe-59 Co-60 Zn-65 Cs-134 Cs-137DateRequired LLD 130 130 260 130 260 130 150FH-1 (Control) 11-05-14 Buffalo < 64.4 < 44.8 < 133.0 < 67.4 < 125.0 < 52.6 < 54.711-05-14 Carp <60.5 <70.9 <149.0 <61.3 <133.0 <48.1 <61.711-05-14 Catfish < 71.3 < 73.2 < 152.0 < 80.9 < 140.0 < 73.2 < 75.411-05-14 Drum <70.5 <98.2 <181.0 <76.5 <173.0 <94.6 <91.0FH-2 (Indicator) 11-05-14 Buffalo < 54.8 < 61.3 <90.7 < 53.6 < 126.0 < 65.0 < 63.811-05-14 Carp <60.7 <78.0 <103.0 <53.2 <118.0 <66.1 <68.511-05-14 Catfish < 64.4 < 63.6 < 133.0 < 67.1 < 141.0 < 87.3 < 84.211-05-14 Drum <68.9 <78.9 <151.0 <63.5 <98.4 <60.9 <58.9FH-3 (Indicator) 10-31-14 Buffalo < 78.0 < 76.7 < 180.0 < 73.0 < 215.0 < 84.0 < 82.510-31-14 Carp < 64.3 <69.4 < 120.0 < 79.3 < 153.0 <61.2 < 72.910-31-14 Catfish < 60.9 < 50.7 < 135.0 < 52.2 < 93.6 <49.1 < 62.810-31-14 Mullet < 48.2 < 61.0 < 104.0 < 64.2 < 124.0 < 56.1 <48.611-04-14 Mullet <66.8 <63.4 <164.0 <74.7 <159.0 <74.5 <76.143 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTable 7.1Sample Type: Broad Leaf VegetationAnalysis: Iodine-131 and Gamma IsotopicUnits: pCi/kg (wet) .Location Collection 1-131 Cs-1 34 Cs-1 37DateRequired LLD 60 60 80BLQ-1 (Indicator) 03-12-14 < 25.7 < 16.6 < 17.1BLQ-1 (Indicator) 06-11-14 < 33.9 < 19.7 < 21.0BLQ-1 (Indicator) 09-10-14 < 34.9 < 21.8 < 19.5BLQ-1 (Indicator) 12-15-14 < 31.3 < 25.5 < 33.5BLB-1 (Indicator) 03-12-14 < 32.2 < 18.1 < 27.4BLB-1 (Indicator) 06-11-14 < 32.7 < 17.9 < 21.7BLB-1 (Indicator) 09-10-14 < 34.1 < 19.2 < 22.7BLB-1 (Indicator) 12-15-14 < 26.5 < 19.7 < 20.9BLE-20 (Control) 03-12-14 < 36.1 < 23.9 < 25.2BLE-20 (Control) 06-11-14 < 33.6 < 21.5 < 22.5BLE-20 (Control) 09-10-14 < 41.0 < 26.0 < 24.7BLE-20 (Control) 12-15-14 < 31.0 < 24.3 < 26.244 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 8.1Sample Type: Interlaboratory ComparisonAnalysis: Gross Beta, Iodine-131, Tritium and Gamma IsotopicUnits: pCi/kg (wet)ANALYTICS ENVIRONMENTAL RADIOACTIVITY CROSS CHECK PROGRAMTELEDYNE BROWN ENGINEERING ENVIRONMENTAL SERVICESMonth/Year ID Number Matrix Nuclide Units Reported Known Ratio (c) EvaluationValue (a) Value (b) TBE/Analytics (d)March 2014 E10854 Milk 1-131 pCi/L 96.6 98.5 0.98 ACe-141 pCi/L 112 119 0.94 ACr-51 pCi/L 449 491 0.91 ACs-134 pCi/L 186 210 0.89 ACs-i 37 pCi/L 250 253 0.99 AI Co-58 pCi/L 248 268 0.93 AMn-54 pCi/L 292 297 0.98 AFe-59 pCi/L 230 219 1.05 AZn-65 pCi/L 312 323 0.97 ACo-60 pCi/L 321 337 0.95 AE10857 AP Ce-141 pCi 53.0 53.9 0.98 ACr-51 pCi 232 223 1.04 ACs-i34 pCi 100 95.3 1.05 ACs-137 pCi 122 115 1.06 ACo-58 pCi 122 121 1.01 AMn-54 pCi 135 135 1.00 AFe-59 pCi 111 99.3 1.12 AZn-65 pCi 140 147 0.95 ACo-60 pCi 187 153 1.22 WE10856 Charcoal 1-131 Pci 74.1 76.4 0.97 AJune 2014 E 10914 Milk 1-131 pCi/L 86.5 90.9 0.95 ACe-141 pCi/L 111 124 0.90 ACr-51 pCi/L 255 253 1.01 ACs-134 pCi/L 147 162 0.91 ACs-137 pCi/L 123 120 1.03 ACo-58 pCi/L 105 112 0.94 AI Mn-54 pCi/L 155 156 0.99 AFe-59 pCi/L 106 102 1.04 AZn-65 pCi/L 251 252 1.00 ACo-60 pCi/L 218 224 0.97 AE10916 AP Ce-141 pCi 95.1 92.6 1.03 ACr-51 pCi 215 190 1.13 ACs-134 pCi 122 122 1.00 ACs-137 pCi 95.1 89.8 1.06 ACo-58 pCi 88.7 84.1 1.05 AMn-54 pCi 115 116 0.99 AFe-59 pCi 72.6 76.7 0.95 AZn-65 PCi 193 189 1.02 ACo-60 pCi 179 168 1.07 AE10915 Charcoal 1-131 pCi 85.6 85.2 1.00 AE10947 Milk 1-131 pCi/L 92.0 97.6 0.94 ACe-141 pCi/L 117 126 0.93 ACr-51 pCi/L 281 288 0.98 ACs-134 pCi/L 141 158 0.89 ACs-137 pCi/L 186 193 0.96 ACo-58 pCi/L 137 143 0.96 AMn-54 pCi/L 138 142 0.97 AFe-59 pCi/L 162 158 1.03 AZn-65 pCi/L 75.2 73.0 1.03 ACo-60 pCi/L 286 297 0.96 A45 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 8.1Sample Type: Interlaboratory ComparisonAnalysis: Gross Beta, Iodine-131, Tritium and Gamma IsotopicUnits: pCi/kg (wet)Month/Year ID Number Matrix Nuclide Units Reported Known Ratio (c) EvaluationValue (a) Value (b) TBE/Analytics (d)September E10949 AP Ce-141 pCi 97.8 82.1 1.19 A2014Cr-51 pCi 212 188 1.13 ACs-134 pCi 106 103 1.03 ACs-137 pCi 131 126 1.04 AI Co-58 pCi 85.7 93.0 0.92 AMn-54 pCi 92.8 92.8 1.01 AFe-59 pCi 113 103 1.10 AZn-65 pCi 53.2 47.5 1.12 ACo-60 pCi 202 193 1.05 AE10948 Charcoal 1-131 pCi 83.9 89.8 0.93 AE10951 Soil Ce-141 pCi/g 0.208 0.186 1.12 ACr-51 pCi/g 0.398 0.425 0.94 ACs-134 pCi/g 0.216 0.233 0.93 ACs-137 pCi/g 0.398 0.365 1.09 ACo-58 pCi/g 0.197 0.211 0.93 AMn-54 pCi/g 0.242 0.209 1.16 AFe-59 pCi/g 0.238 0.233 1.02 AZn-65 pCi/g 0.117 0.108 1.08 ACo-60 pCi/g 0.447 0.438 1.02 ADecember 2014 El1079 Milk 1-131 pCi/L 85.9 95.1 0.90 ACe-141 pCi/L 205 219 0.94 ACr-51 pCi/L 402 406 0.99 ACs-134 pCi/L 156 164 0.95 ACs-137 pCi/L 194 198 0.98 ACo-58 pCi/L 122 130 0.94 AMn-54 pCi/L 220 225 0.98 AFe-59 pCi/L 183 175 1.05 AZn-65 pCi/L 287 297 0.97 ACo-60 pCi/L 224 235 0.95 AE11081 AP Ce-141 pCi 96.4 102 0.95 ACr-51 pCi 171 190 0.90 ACs-134 pCi 73.1 76.9 0.95 ACs-137 pCi 99.0 92.6 1.07 ACo-58 PC! 57.5 60.8 0.95 AMn-54 pCi 107 105 1.02 AFe-59 pCi 74.2 81.6 0.91 AZn-65 pCi 144 139 1.04 ACo-60 pCi 114 110 1.04 AE11080 Charcoal 1-131 pCi 93.5 98.2 0.95 A(a) Teledyne Brown Engineering reported result.(b) The Analytics known value is equal to 100% of the parameter present in the standard as determined by gravimetric and/or volumetricmeasurements made during standard preparation.(c) Ratio of Teledyne Brown Engineering to Analytics results.(d) Analytics evaluation based on TBE internal QC limits: A= Acceptable, reported result falls within ratio limits of 0.80-1.20. W-Acceptable withwarning, reported result falls within 0. 70-0.80 or 1.20-1.30. N = Not Acceptable, reportedresults falls outside the ratio limits of <0. 70 and > 1.30.46 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTable 8.1Sample Type: Interlaboratory ComparisonAnalysis: Gross Beta, Iodine-131, Tritium and Gamma IsotopicUnits: pCi/kg (wet)DOE's MIXED ANALYTE PERFORMANCE EVALUATION PROGRAM (MAPEP)TELEDYNE BROWN ENGINEERING ENVIRONMENTAL SERVICESMonth/Year ID Matrix Nuclide Units Reported Known Acceptance EvaluationNumber Value (a) Value (b) Range (c)March 2014 14- Water H-3 Bq/L NR 321 225-417 N (1)MAW30Cs-134 Bq/L 20.7 23.1 16.2 -30.0 ACs-137 Bq/L 28.0 28.9 20.2 -37.6 ACo-57 Bq/L 26.5 27.5 19.3- 35.8 ACo-60 Bq/L 15.6 16.0 11.2-20.8 AMn-54 Bq/L 13.5 13.9 9.7-18.1 AK-40 Bq/L NR False positive test N (2)Zn-65 Bq/L -0.201 False positive test A14-MaS30 Soil Cs-134 Bq/kg 2.02 False positive test ACs-137 Bq/kg 1300 1238 867-1609 ACo-57 Bg/kg 1069 966 676- 1256 ACo-60 Bq/kg 1.32 1.22 Sensitivity AMn-54 Bq/kg 1510 1430 1001 -1859 AK-40 Bq/kg 669 622 435 -809 AZn-65 Bq/kg 763 695 487 -904 A14-RdF30 AP Cs-134 Bq/sample NR 1.91 1.34-2.48 N (1)Cs-137 Bq/sample NR 1.76 1.23-2.29 N (1)Co-57 Bq/sample NR False positive test N (1)Co-60 Bq/sample NR 1.39 I 0.97- 1.81 N (1)Mn-54 Bq/sample NR False positive test N (1)Zn-65 Bq/sample NR False positive test N (1)14-GrF30 AP Gr-B Bq/sample 0.7507 0.77 0.39 -1.16 A14-RdV30 Vegetation Cs-134 Bq/sample 5.96 6.04 4.23-7.85 ACs-137 Bq/sample 5.06 4.74 3.32-6.16 ACo-57 Bq/sample 11.8 10.1 7.1 -13.1 ACo-60 Bq/sample 7.34 6.93 4.85 -9.01 AMn-54 Bq/sample 8.95 8.62 6.03- 11.21 AZn-65 Bq/sample 8.91 7.86 5.50-10.22 ASeptember 14- Water Cs-134 Bq/L NR False positive test N (1)2014 MaW31Cs-137 Bq/L NR 18.4 12.9-23.9 N (1)Co-57 Bq/L NR 24.7 17.3-32.1 N (1)Co-60 Bq/L NR 12.4 8.7-16.1 N (1)Mn-54 Bq/L NR 14.0 9.8-18.2 N (1)K-40 Bq/L NR 161 113-209 N (1)Zn-65 Bq/L NR 10.9 7.6-14.2 N (1)14-MaS31 Soil Cs-134 Bq/kg NR 622 435-809 N (1)Cs-137 Bq/kg NR False positive test N (1)Co-57 Bq/kg NR 1116 781 -1451 N (1)Co-60 Bq/kg NR 779 545-1013 N (1)Mn-54 Bq/kg NR 1009 706- 1312 N (1)K-40 Bq/kg NR 824 577- 1071 N (1)Zn-65 Bq/kg NR 541 379-703 N (1)47 Annual RadiologicalEnvironmental Operatinci Report2014Waterford 3 Steam Electric StationTable 8.1Sample Type: Interlaboratory ComparisonAnalysis: Gross Beta, Iodine-1 31, Tritium and Gamma IsotopicMonth/Year ID Number Matrix Nuclide Units Reported Known Acceptance EvaluationValue (a) Value (b) Range (c)September 2014 14-GrF31 AP Gr-B Bq/sample 0.977 1.06 0.53-1.59 A14-RdV31 Vegetation Cs-134 Bq/sample 7.31 7.38 5.17-9.59 ACs-137 Bg/sample 8.93 8.14 5.70- 10.58 ACo-57 Bq/sample 10.8 9.2 6.4- 12.0 ACo-60 Bq/sample 6.31 6.11 4.28- 7.94 AMn-54 Bq/sample 7.76 7.10 4.97 -9.23 AZn-65 Bq/sample 7.16 6.42 4.49- 8.35 AIn reviewing our environmental inter-laboratory crosscheck programs, we identified 1) duplication of efforts on some matrices and isotopes and 2)that we are performing crosscheck samples on some matrices and isotopes that we do not perform for clients. Since the DOE MAPEP is designed toevaluate the ability of analytical facilities to correctly analyze for radiological constituents representative of those at DOE sites, the needed changeswere made to the MAPEP program. Therefore, the following isotopes were removed from the MAPEP program:Soil -gamma -will be provided by Analytics twice per year, starting in 2015. For 2014, one soil gamma is provided by MAPEP, the 2rn soil gammais provided by Analytics.AP -gamma -is currently provided by Analytics.Water -gamma, H-3, Sr-90, uranium, gross alpha and gross beta currently provided by ERA.(1) MAPEP evaluates non-reports (NR) as failed if they were reported in the previous study(2) The K-40 in water result of 1.63 Bq/L was overlooked when reporting the data but would have passed the false positive test. NCR 14-04(a) Teledyne Brown Engineering reported result.(b) The MAPEP known value is equal to 100% of the parameter present in the standard as determined by gravimetric and/or volumetricmeasurements made during standard preparation.(c) DOE/MAPEP evaluation: A=acceptable; W=acceptable with warning; N=not acceptable.48 Annual RadiologicalEnvironmental Ooeratina Reoort2014Waterford 3 Steam Electric StationTable 8.1Sample Type: Interlaboratory ComparisonAnalysis: Gross Beta, Iodine-1 31, Tritium and Gamma IsotopicUnits: pCi/kg (wet)ERA ENVIRONMENTAL RADIOACTIVITY CROSS CHECK PROGRAMTELEDYNE BROWN ENGINEERING ENVIRONMENTAL SERVICESMonth/Year ID Number Matrix Nuclide Units Reported Known Acceptance EvaluationValue (a) Value (b) Limits (c)May 2014 RAD-97 Water H-3 pCi/L 8435 8770 7610-9650 ABa-133 pCi/L 89.1 87.9 74.0-96.7 ACs-134 pCi/L 45.55 44.3 35.5-48.7 ACs-137 pCi/L 91.15 89.1 80.2-101 ACo-60 pCi/L 65.10 64.2 57.8-73.1 AZn-65 pCi/L 244 235 212 -275 AGr-B pCi/L 27.95 33.0 21.4-40.7 A1-131 pCi/L 23.75 25.7 21.3-30.3 ANovember 2014 RAD-99 Water H-3 pCi/L 6255 6880 5940-7570 ABa-133 pCi/L 46.8 49.1 40.3-54.5 ACs-134 pCi/L 88.0 89.8 73.7-98.8 ACs-137 pCi/L 99.0 98.8 88.9-111 ACo-60 pCi/L 92.5 92.1 82.9- 104 AZn-65 pCi/L 325 310 279- 362 AGr-B pCi/L 27.5 27.4 17.3-35.3 A1-131 pCi/L 15.8 20.3 16.8-24.4 N (1)(1) Iodine-131 was evaluated as failed with a ratio of 0. 778. No cause could be found for the slightly low activity. TBE would evaluate this asacceptable with warning. A rerun was not possible due to 1-131 decay. All previous ERA 1-131 evaluations since 2004 have been acceptable.NCR 14-08(a) Teledyne Brown Engineering reported result.(b) The ERA known value is equal to 100% of the parameter present in the standard as determined by gravimetric and/orVolumetric measurements made during standard preparation.(c) ERA evaluation: A=acceptable. Reported result falls within the Warning Limits. NA=not acceptable. Reported result falls outside of theControl Limit. CE=check for Error. Reported result falls within the Control Limits and outside of the WarningLimits.49 Annual RadiologicalEnvironmental ODeratina Report2014Waterford 3 Steam Electric StationATTACHMENT 2Statistical Comparisons50 Annual RadiologicalEnvironmental Operating Report2014Waterford 3 Steam Electric StationTABLE OF CONTENTSTABLE 2.1TABLE 2.2TABLE 2.3TABLE 2.4STATISTICAL COMPARISON OF 2014 TLD MEASUREMENTS FROMSTATIONS GROUPED BY DISTANCESTATISTICAL COMPARISON OF 2014 TLD RADIATION DOSE TOHISTORICAL DATA BY LOCATIONSTATISTICAL COMPARISON OF 2014 GROSS BETA ACTIVITYMEASUREMENTS ON AIR PARTICULATE FILTERSSTATISTICAL COMPARISON OF 2014 GROSS BETA ACTIVITYMEASUREMENTS IN DRINKINGISURFACE WATER SAMPLES5455565751 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationStatistical AnalysesCalculation of the Mean and Standard DeviationThe mean and standard deviation forequations:different groups of analyses are calculated using the followingn=i-S= I Xand0.5where:X = mean of sample population,S = standard deviation of sample population,n = number of samples in sample population, andXi = value of the i'th sample.52 Annual Radiological 2014Environmental Operating Report Waterford 3 Steam Electric Station* Comparing Two Sample Population MeansThe means of two sample populations are compared for statistical difference using the standard "t"test. The use of the test requires the assumption that the data within the populations are normallydistributed and that the true standard deviations of the mean are equal for both populations. Thestandard "t" test tests the hypothesis that the true means of both populations are equal. The "t" valuecan be calculated from the equation below (obtained from the CRC Standard Mathematical Tables,26th Edition (1981)):X-Y( n.= _ n+ -2  0.5 0.5.x -2 I+ JIwhere:t = calculated "t" value,X = mean of first data set,Y = mean of second data set,/ 7 = number of variables in first data set,S , = standard deviation of first data set,,7 y = number of variables in second data set, andS Y = standard deviation of second data set.The calculated "t" value is used to test the hypothesis that the true mean of the first population (m,) is equal to the true mean of the second population (m y) assuming that the true standarddeviation of.both populations are equal (m x = m y). The calculated "t" value is compared to atabular "t" value such that:a if t > t p,n then reject the hypothesis when m > m y,b. if t < -t p,n then reject the hypothesis when m. < m y,c. if t > t p/2,n then reject the hypothesis when mx = m y,where t p/2,n and t p,n are the tabular "t" values, with a preselected error (5%), confidence level (1 -lp) or(1- p/2), and degrees of freedom n = nx + ny -2. Tabular values of the "t" were obtained from theCRC Standard Mathematical Tables, 26th Edition (1981).53 Annual RadiologicalEnvironmental Ooeratina Reoort2014Waterford 3 Steam Electric StationTABLE 2.1STATISTICAL COMPARISON OF 2014 TL MASURMENTS FROMSTATIONS GROUPED BY DISTANCE..Stations Located 2- Stations L.ocated more than................ .Miles.from.the. Pant Milesfromthe Ilant 5 Miles from the PlantMean 12 13 12(mRem/std.qtr.)Standard Deviation 1.51 1.13 1.28(mRem/std. qtr.)Number in Sample 61 27 28Calculated "t" Value 1.07 2.12 NA*(comparison of stations 0-2 and 2-5miles from the plant to stations >5miles from the plant)Tabular "t" Value at 1.991 (a) 2.007(b) NA*95% Confidence(t0.025,n)(a) Results indicate the mean for stations located 0-2 miles from the plant are statistically identical to the mean for stations located more than5 miles from the plant.(b) Although the TLD stations located 2-5 miles from the plant are statistically higher than those located more than 5 miles from the plant,the quarterly doses measured in 2014 are consistent with historical data at each location as shown in Table 2.2.Not Applicable54 Annual RadiologicalEnvironmental Operatinq Report2014Waterford 3 Steam Electric StationTABLE 2.2STATISTICAL COMPARISON OF 2014 TLD RADIATION DOSE TO HISTORICAL DATA BY LOCATION..mrem/Std. Qtr.Station 1990- 2013 Avg* 1990-2013Std ev* 1990 2013 Range l 2014 Avg" 2014 Std Dov** 2014 Range22!A-2 13 1.4 10 18 13 0.4 12 13A-5 13 1.4 10 17 12 0.7 11 13B-1 13 1.4 10 19 13 0.4 13 14B-4 13 1.1 11 17 14 0.4 13 14C-1 9 1.2 7 13 10 0.5 9 10D-2 12 1.9 8 19 13 0.4 12 13D-5 12 1.4 9 18 12 0.5 11 12E-1 11 1.2 9 16 11 0.4 11 12E-5 12 1.6 9 17 13 0.5 12 13E-1_5 11 1.6 8 16 10 0.4 10 11E-30* 11 1.5 8 17 10 0.4 9 10F-2 12 1.1 10 17 12 0.7 11 13F-4 14 1.4 11 19 15 0.5 14 15F-9 12 1.4 7 17 13 0.5 12 13G-2 14 1.8 10 19 11 0.4 11 12G-4 11 1.3 9 16 11 0.5 11 12G-8 12 1.9 8 19 11 0.4 11 12H-2 13 1.2 10 18 12 0.8 11 13H-8 12 1.2 9 17 13 0.4 13 14J-2 12 1.5 10 17 11 0.0 11 11J-15 13 1.2 11 17 13 0.0 13 13K-1 11 1.2 9 16 11 0.0 11 11L-1 13 1.4 10 16 14 0.4 14 15M-1 12 1.5 9 18 10 0.0 10 10N-1 13 1.5 8 18 14 0.0 14 14P-1 10 1.2 7 15 10 0.0 10 10P-6 14 1.3 10 19 13 0.4 13 14Q-1 12 1.2 10 16 13 0.4 12 13Q-5 13 2.1 9 18 14 0.9 13 15R-1 10 1.9 6 15 10 0.0 10 10R-6 12 2.4 8 18 10 0.0 10 10* Control Location** Significant outliers were removed from data sets.PERS data indicates an average of 20 mrem for all indicator locations with a range of 11 to 33 and an average control of 18 mrem.55 Annual RadiologicalEnvironmental Operatina Reoort2014Waterford 3 Steam Electric StationTABLE 2.3Mean(1O3pCi/m3)2120191920Standard Deviation(1O'3pCiIm3)Number in SampleCalculated "t" Value(comparison of the indicator stationsto the control station)Tabular "t" Value at95% Confidence(t0,025,n)5.04260.482.011 (a)4.41260.352.011(a)4.28261.142.011(a)6.33260.542.011 (a)4.2426NA*NA*i A I(a) Results indicate the mean for the indicator stations is statistically identical to the mean for the control station.* Not Applicable56 Annual RadiologicalEnvironmental Ooeratina ReDort2014Waterford 3 Steam Electric StationTABLE 2.4*1Mean(pCilliter)5.65.14.4Standard Deviation(pCi/liter)Number in SampleCalculated "t" Value(comparison of the indicatorstations to the control station)Tabular "t" Value at95% Confidence(t0.025,n)0.8842.472.447(b)0.7041.742.447(a)0.534NA*NA*I i(a) Results indicate the mean for the indicator station is statistically identical to the mean for the control station.(b) Results indicate the mean for the indicator station is statistically higher than the mean for the control location. Results obtained in 2014 are consistentwith historical data as stated in section 2.3.* Not Applicable57}}

Latest revision as of 18:04, 18 August 2019