Text

NPDES Permit Renewal Application - MO-0098001
	ML13240A306
Person / Time
Site:	Callaway
Issue date:	08/01/2013
From:	Pozzo J; Ameren Missouri
To:	Wieberg C; Office of Nuclear Reactor Regulation, State of MO, Dept of Natural Resources
Shared Package
ML13240A345	List: ML13240A302; ML13240A303; ML13240A304; ML13240A305; ML13240A307; ULNRC-06027, Callaway Energy Center NPDES Permit Renewal Application - MO-0098001; ULNRC-06027, Callaway, Unit 1, Transmittal of NPDES Permit Renewal Application; ULNRC-06027, Drawing NPDES-001, NPDES Storm Water Information Outfalls 010-015; ULNRC-06027, Drawing NPDES-002, Storm Water Outfalls 010-015 Topographical Map & Drainage Areas; ULNRC-06027, Drawing NPDES-004, NPDES Outfalls Receiving Streams Map; ULNRC-06027, NPDES Permit Renewal Application - MO-0098001;
References
	ULNRC-06027, MO-0098001
	Download: ML13240A306 (142)
	v • d • e

{{#Wiki_filter:Ameren Services August 1, 2013 Mr. Chris Wieberg Chief, Operating Permits Section Missouri Department of Naturar Resources Water Pollution Control Branch Permit Section PO Box 176 Jefferson City, MO 65102-0176

Dear Mr. Wieberg:

RE: Callaway Energy Center NPDES Permit Renewal Application - #MO-Q098001 In accordance with State and Federal regulations, enclosed is the renewal application for Union Electric Company (d/b/a Ameren Missouri) Callaway Energy Center, Permit #M0-0098001 (one additional copy is included). We believe the application is complete with all required forms, signatures, and drawings. This application includes a set of Attachments. The attachments provide additional details regarding information required in the application forms and contain several specific requests regarding permit conditions. We appreciate your consideration of these requests. Please contact Gail Gary of my staff at 314-554-2824 should you have any questions or need additional information. )_ ~ohn C. Pozzo Managing Supervisor Water Quality Enclosure 1901 Chouteau Avenue PO Box 66149, MC 602 St. louis, MO 63166-6149 Ameren.com Enclosure to ULNRC-06027

bee: J. F. Small J. H. Howard D. L. Maschler B. F. Holderness MLM/SCW/JCP MFB/SSW/GPG WQ 3.1.1 / Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 CALLA\\A.JAY NPOES PERMIT REAPPLICATIOt..J CONTENTS ~ ~ FORMS

1.

Form A

2.

Form C

3.

Form D ATTACHMENTS

1.

Attachment A; Descrjption of Outtalls

2.

Attachment B~ Return of River Water

3.

Attachment C, Description of Intermittent Flows

4.

Attachment D, Chemical Usage

5.

Attachment E, NPDES Sampling and Analysis

6.

Attachment F, Section 311 and CERCLA Exemptions

7.

Attachment G, General Comments on Standards Setting

8.

Attachment H, Section 316(b) Demonstration Status

9.

Attachment I, Macroinvertebrate Control

10.

Attachment J, Activities, Materials and Management Practices with the Potential to Impact Storm Water Quality

11.

Attachment K, Requests for Modification of Current Permit Conditions DRAWINGS

1.

Flow Diagram and Water Balance

2.

NPDES-001, Storm Water Information

3.

NPDES-002, Topographic Map and Drainage Areas

4.

NPDES-004, Receiving Streams Map Enclosure to ULNRC-06027

~ MISSOURI DEPARTMENT OF NATURAL RESOURCES FOR AGENCY USE ONLY I~ WATER PROTECTION PROGRAM, WATER POLLUTION CONTROL BRANCH CHECK NUMBER II _.., 1 A\\ ~ FORM A-APPLiCATiON FOR CONSTRUCTiON OR OPERATING PERMIT l2!1~ UNDER MISSOURI CLEAN WATER LAW I DATE RECEIVED I FEE SUBMITTED Note ..,_ I PLEASE READ THE ACCOMPANYING INSTRUCTIONS BEFORE COMPLETING THIS FORM.

1.

This application is for: 0 An operating permit and antidegradation review public notice 0 A construction permit following an appropriate operating permit and antidegradation review public notice D A construction permit and concurrent operating permit and antidegradation review public notice 0 A construction permit (submitted before Aug. 30, 2008 or antidegradation review is not required) D An operating permit for a new or unpermitted facility Construction Permit# ____ _ 0 An operating permit renewal: permit# MO- ~ Expiration Date 211212o14 D An operating permit modification: permit# MO-Reason: 1.1 Is the appropriate fee included with the application? (See instructions for appropriate fee) D YES Ill NO

2. FACILITY NAME Ameren Missouri Callaway Energy Center ADDRESS (PHYSICAL)

Junction Highway CC & Route 0 3.0WNER CITY Fulton TELEPHONE WITH AREA COOE {573} 308-2334 FAX (573) 676-4484 STATE I ZIP CODE MO 65251 NAME Union Electric Company d/b/a Ameren Missouri E*MAIL ADDRESS TELEPHONE WITH AREA CODE (314) 554-2824 ggary@ameren.com 1--FAX-..1..(3_1_4"-) 5_54_-4_1_8_2 ---1 ADDRESS (MAILING) I CITY P.O. Box 66149 (MC-602) St. Louis 3.1 Request review of draft permit prior to public notice? [l] YES

4. CONTINUING AUTHORITY NAME SAME AS OWNER ADDRESS (MAILING)

CITY

5. OPERATOR NAME CERTIFICATE NUMBER SAME AS OWNER ADDRESS (MAILING)

CITY

6. FACILITY CONTACT NAME TITLE James F. Small Chemistry Manager

7. ADDITIONAL FACILITY INFORMATION 0NO STATE I ZIPCODE MO 63166-6149 TELEPHONE WITH AREA CODE FAX STATE I ZIPCODE TELEPHONE WITH AREA CODE FAX STATE I ZIPCODE TELEPHONE WITH AREA CODE

{573) 308-2334 FAX (573) 676-4484 7.1 Legal Description of Outfalls. (Attach additional sheets if necessary.) (See attached page) 001 ~ ~ Sec T R __ UTM Coordinates Easting (X):________ _ Northing (Y): _ ~ __County For Universal Transverse Mercator (UTM), Zone 15 North referenced to North American Datum 1983 (NAD83} 002 'l4 --~ Sec__ T __ R __ __County UTM Coordinates Easting (X): _ _ _ _ _ _ _ _ _ Northing (Y): ________ _ 003 --~ --~ Sec__ T__ R __ __County UTM Coordinates Easting (X):_ _ _ _ _ _ _ _ _ Northing (Y): ________ _ 004 X Sec T R UTM Coordinates Easting {X):____ _ _ _ _ _ i\\iOrt'hiiig (Y): _ =-=--_ _ _ _ -- __County 7.2 Primary Standard Industrial Classification (SIC) and Facility North American Industrial Classification System (NAICS) Codes. 001 -SIC 4911 and NAICS 221113 002-SIC and NAICS ___ 003 - SIC and NAICS 004 - src and NAICS MO 780-1479 (01.{)9) Enclosure to ULNRC-06027

7.1 Legal Description of Outfalls 001 NE Y.t NE~ Sec 14 T46N R8W Callaway County 002 NW~ NW~ Sec 13 T46N R8W Callaway County 003 sw~ sw~ Sec 13 T46N R8W Callaway County 007 sw y.; sw~ Sec 13 T45N R8W Callaway County 009 NW~ NW~ Sec 5 T46N R8W Callaway County 010 SW Y.t sw !4 Sec 12 T46N R8W Callaway County 011 NW~ SE ~ Sec 12 T46N R8W Callaway County 012 NE~ SE ~ Sec 14 T46N R8W CaUaway County 014 NW~ SE !4 Sec 11 T46N R8W Callaway County 015 SE Y.t NE !4 Sec 11 T46N R8W Callaway County 016 NW~ NW !4 Sec 13 T46N R8W Callaway County 017 SE~ NE~ Sec 14 T46N R8W Callaway County Note: The location ofOutfalls 002 and 016 is described at the connection to the plant discharge line. The location of Outfall 001 is described from the Discharge Monitor Tanks. Enclosure to ULNRC-06027

i 8 ADDITIONAL FORMS AND MAPS N~ECESSARY TO COMPLETE TH!S APPUCAT!ON (Complete all forms that are applicable.) A. Is your facility a manufacturing, commercial, mining or silviculture waste treatment facility? YES IZJ NO 0 If yes, complete Fonn C (unless storm water only, then complete U.S. Environmental Protection Agency Form 2F per Item C below). B.

c.

Is your facility considered a "Primary Industry" under EPA guidelines: If yes, complete Forms C and D. Is application for storm water discharges only? If yes, complete EPA Form 2F. D. Attach a map showing all outfalls and the receiving stream at 1" = 2,000' scale. E. F. Js wastewater rand applied? If yes, complete Form I. Is sludge, biosolids, ash or residuals generated, treated, stored or land applied? If yes, complete Form R. YES jj) YESO YESO YESO NOD NOilJ NOll! NO Ill

9.

DOWNSTREAM LANDOWNER($) Attach additional sheets as necessary. See Instructions. (PLEASE SHOW LOCATION ON MAP. SEE 8.0 ABOVE). NAME Mary L. Austin I CITY Wentzville I STATE I ZIPCODE MO 63385 ADDRESS 4519 Holt Road

10.

I certify that I am familiar with the Information contained in the application, that to the best of my knowledge and belief such information is true, complete and accurate, and if granted this permit, I agree to abide by the Missouri Clean Water Law and all rules, regulations. orders and decisions, subject to any legitimate appeal available to applicant under the Missouri Clean Water Law to the Missouri Clean Water Commission. NAME AND OFFICIAL TITLE (TYPE OR PRINT) TELEPHONE WITH AREA CODE Adam Heflin, Senior Vice President & Chief Nuclear Officer (573} 823-5411 DATE SIGNED BEFORE MAILING, PLEASE ENSURE All SECTIONS ARE COMPLETED AND ADDITIONAL FORMS, IF APPLICABLE, ARE INCLUDED. Submittal of an incomplete application may result in the application being returned. HAVE YOU INCLUDED: D Appropriate Fees? D Map at 1" = 2000' scale? 0 Signature? D Form C, if applicable? 0 Form D, if applicable? D Form 2F, if applicable? D Form I (Irrigation), if applicable? 0 Form R (Sludge), if applicable? Enclosure to ULNRC-06027

~ MlSSOURr DEPARTMENT OF NATURAL RESOURCES ~~ ~~~~ ~R~~~;;~~~~?ri~~~A;.~;:f~~~~~~~i~H_ !FOR AGENCY USE ONLY CHECK NO. l I a:. I L"Yl

R -

I \\..'!:/! MANUFACTURING, COMMERCIAL, MINING, DATERECEIVED IFEESUBMIITED SILVICULTURE OPERATIONS, PROCESS & STORM WATER I TE: DO NOT ATTEMPT TO COMPLETE THIS FORM BEFORE READING THE ACCOMPANYING INSTRUCTIONS 1.00 NAME OF FACILITY Ameren Missouri Callaway Energy Center 1.10 THIS FACILITY IS NOW IN OPERATION UNDER MISSOURI OPERATING PERMIT NUMBER MO..Q098001 1.20 THIS IS A NEW FACILITY AND WAS CONSTRUCTED UNDER MISSOURI CONSTRUCTION PERMIT NUMBER (COMPlETE ONLY IF THIS FACILITY DOES NOT HAVE AN OPERATING PERMfn. 2.00 LIST THE STANDARD INDUSTRIAL CLASSIFICATION (SIC) CODES APPUCAOLE TO YOUR I'ACILITY (FOUR DIGIT CODE) 4911 A. FIRST ___________.,--___ _ B. SECOND _____________________________ __ C. THIRD ________________________ __ D. FOURTH ______________________________ __ 2.10 FOR EACH OUTFALL GIVE THE LEGAL DESCRIPTION. OUTFALL NUMBER (LIST)--, _1/4 -~.-1/4 SEC __ T __ R __ _______________________ COUNTY (See attached page) 2.20 FOR EACH OUTFALL LIST THE NAME OF THE RECEIVING WATER OUTFALL NUMBER (LIST) 001,002,003,007,009,016 010,011,012,014,015 2.30 BRIEFLY DESCRJSE THE NATURE OF YOUR BUSINESS Steam Electric Power Plant (Nuclear} MO 780-1514 (06-12) PAGE1 RECEIVING WATER Missouri River Tributaries to the Missouri River (See Att. A) Enclosure to ULNRC-06027

2.10 Legal Description of Outfalls 001 NE Y4 NE Y4 Sec 14 T46N R8W Callaway <::;ounty 002 NWY4 NWY4 Sec 13 T46N R8W Callaway County 003 sw Y4. SWV4 Sec 13 T46N R8W Callaway County 007 sw Y4 sw y,. Sec 13 T45N R8W Callaway County 009 NWY4 NW Y.t SeeS T46N R8W Callaway Com1ty 010 SWY4 sw y,. Sec 12 T46N R8W Callaway County 011 NWV.. SE Y4 Sec 12 T46N R8W Callaway County 012 NE Y4 SE Y4 Sec 14 T46N R8W Callaway Cmmty 014 NW Y4 SE 'l4 Sec I 1 T46N R8W Callaway County 015 SE Y4 NE Y4 Sec 11 T46N R8W Callaway County 016 NWY4 NW Y4 Sec 13 T46N 'R8W Callaway County 017 SE 14 NE Y4 Sec 14 T46N R8W Callaway County Note: The location of Outfalls 002 and 016 is described at the connection to the plant discharge line. The location of Outfall 001 is described from the Discharge Monitor Tanks. IA Enclosure to ULNRC-06027

r A Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent and treatment units labeled to correspond to the more detailed descriptions in item B. Construct a water balance on the line drawing by showing average flows bett.veen intakes, ope;ations, treatment units, pubiic sewers and ~ outfalls. If a water baiance cannot by determined (e.g., for certain mining activities), provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall, provide a description of

1. All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water and storm water runoff.

2. The average flow contributed by each operation.

3. The treatment received by the wastewater.

Continue on additional sheets if necessary.

1. OUTFALL NO.

2. OPERATION($) CONTRIBUTING FLOW

3. TREATMENT (LIST) 001 002 003 007 009 010 011 012 014 015 016 017 MO 780.1514 (06-12)

A. OPERATION (LISl) B. AVERAGE FLOW {INCLUDE UNITS) A. DESCRIPTION (MAXIMUM FLOW) Radwaste Treatment System 0.020 (0.190) MGD

Discharge

1) Boron Recycle 0.001

2) Equipment Drains 0.0002

3) Primary Floor Drains 0.0013

4) Laundry/Hot Shower 0.0002

5) Polisher Regen Waste 0.008

6) Secondary Floor Drains 0.0093 7} Steam Generator Blowdown 0**

Cooling Tower Blowdown 5.6 (14.40) MGD Discharge Water Treatment Plant Waste 0.42 (1.6) MGD Sedimentation

1) Clarifier Slowdown 0.33 Floculation

2) Carbon Filter Backwash 0.004 Filtration 3} Oily Waste 0.023 Separation

4) Makeup De min Plant Waste 0.0072 Neutralization Sanitary Waste 0.025 {0.050) MGD Aerated Lagoons Intake Electric Heaters 0 (0.006) MGD**

Neutralization Storm Water Runoff 0.082 (4.6) Sedimentation Storm Water Runoff 0.36 (19.7) Sedimentation Storm Water Runoff 0.12 (6.6) Sedimentation Storm Water Runoff 0.087 {4.8) Sedimentation Storm Water Runoff 0.050 (2.8) Sedimentation Cooling Tower Bypass 0.80 (14.40) MGD

Discharge Ultimate Heat Sink Pond 0 (0)

No Discharge PAGE2 "'Flow Is intermittent. Average daily" flow is reported. See Section 2.40 for average for days when discharging.

- No discharge in past 25 years.

B. LIST CODES FROM TABLE A 2J, 10, 2K, 4A 2F,4A 1U,4C 1G 10 XX 2K 3B,4C 2K,4A 1U,4A 1U,4A 1U,4A 1U,4A 1U,4A 4A NA Enclosure to ULNRC-06027

2 40 CONTINUED C. EXCEPT FOR STORM RUNOFF. LEAKS OR SPILLS, ARE ANY OF iHE DISCHARGES DESCRIBED IN ITEMS A ORB INTERMITTENT OR SEASONAL? IZJ YES (COMPLETE THE FOLLOWING TABLE} n NO (GO TO S£CT!ON 2.50)

4. FLOW

3. FREQUENCY B. iOTAL. VOLUME {specify with

1. OUTFALL A. FLOW RATE (in mgd}

units) NUMBER

2. OPERAliON(SI CONTRIBUTING FLOW (fist)

C. DURAliON A. DAYS B. MONTHS (in days} (liSt) PER WEEK PER YEAR

1. LOOGTERM

2. MAXIMUM

4. l.ONGTERM

3. MAXIMUM (specify (specify AVERAGE DAILY DAILY AVERAGE average) average) 001 Radwaste Treatment 1.2 12 0.081 0.187 61 D/yr 016 Cooling Tower Bypass 3.5 12 1.3 3.2 180 D!yr I

See Attachment C, Description of Intermittent Flows 2.50 MAXIMUM PRODUCTION A. DOES AN EFFLUENT GUIDELINE LIMITATION PROMULGATED BY EPA UNDER SECTION 3{)4 OF THE CLEAN WATER ACT APPLY TO YOUR FACIUTY? IZJves {COMPLETE; 8.) 0No (GO TO SECTION 2.60, B. ARE THE LIMITATIONS IN THE APPLICABLE EFFlUENT GUIDELINES EXPRESSED IN TERMS OF PRODUCTION (OF OTHER MEASURE OF OPERATION)? Oves (COMPLETE c.) IZJNO (GO TO SECTION ~.60) C. IF YOU AI-ISWERED "YES" TO 8, USi THE QUANTITY THAT REPRESENTS AN ACTUAL MEASUREMENT OF YOUR MAXIMUM LEVEL OF PRODUCTION, EXPRESSED IN THE TERMS AND UNITS USED IN THE APPLICABLE EFFLUENT GUIDELINE AND INDICATE THE AFFECTED OUTFAI.LS.

1. MAXIMUM QUANTITY

2. AFFI:CTED C. OPERATION, PRODUCT, MATERIAL, ETC.

OUTFALLS A. QUANTITY PER DAY

e. UNITS OF MEASURE (specify)

(list outfall numt:u~rs) 2.60 IMPROVEMENTS A. ARE YOU NOW REQUJRED BY ANY FEDERAL, SlATE OR LOCAL AUTHORITY TO MEET. ANY IMPLEMENTATION SCHEDULE FOR THE CONSTRUCTION, UPGRADING OR OPERATION OF WASTEWAIER TREATMENT EQUIPMENT OR PRACTICES OR ANY OTHER ENVIRONMENTAL PROGRAMS THAT MAY AFFECT THE DISCHARGES DESCRIBED IN THIS APPLICATION? THtS INCLUDES, BUT IS NOT LIMITED TO, PERMIT CONDITIONS, ADMINISTRATIVE OR ENFORCEMENT ORDERS, ENFORCEMENT COMPLIANCE SCHEDULE LEITERS, STIPULATIONS, COURT ORDERS AND GRANT OR LOAN CONDITIONS. D YES (COMPLETE THE FOLLOWING TABLE) ll]No (GO TO 3.00)

1. IDENTIFICATION OF CONDITION

2. AFFECTED OUTFAI.LS

4. FINAL COMPLIANCE DATE AGREEMENT, ETC.

3. BRIEF DESCRIPTION OF PROJECT A. REQUIRED 8, PROJECTED

8. OPTIONAL: YOU MAY ATTACH ADDITIONAL SHEETS DESCRIBING ANY ADDITIONAL WATER POLLUTION CONTROL PROGRAMS (OR OTHER £NVIRONMENTAL PROJECTS THAT MAY AFFECT YOUR DISCHARGES) YOU NOW HAVE UNDER WAY OR ARE YOU PLANNING. INDICATE WHETHER EACH PROGRAM IS NOW UNDER WAY OR PLANNED, AND INDlCATE YOUR ACTUAL OR PLANNED SCHEDULES FOR CONSTRUCTION.

0 MARK "X" IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS A IT ACHED. MO 780*1514 {06*12} Enclosure to ULNRC-06027

3.00 INTAKE AND EFFlUENT CHARACTERISTICS A & 6. SEE INSTRUCTIONS BEFORE PROCEEDING-COMPLETE ONE TABlE FOR EACH OUTFALL-ANNOTATE THE OUTFALL NUMBER IN THE SPACE PROVIDED. NOTE: TABLE 1 IS INCLUDED ON SEPARATE SHEETS NUMBERED FROM PAGE 6 TO PAGE 7. C. US THE SPACE BELOW TO LIST ANY OF THE POLUJTANTS L!STED !N PAR! E! Of' THE !NSTRUCTIONS, WHlCH YOU KNOW OR HA"vE RtASON To BELIEVE IS DISCHARGED OR I M.A.Y BE O!SCHARGED FF!O~.. 'lANY OUTFAlL. FOR E\\lERY f'\\OLLUTAt-:T YOU lfST. BR;CFLY DESCRiBE THE REASONS YOU BEliEVE tT TO BE PHf::~~N 1 AND REPORT ANY ANALYTICAL DATA IN YOUR POSSESSION.

1. POLLUTANT

2. SOURCE

1. POLLUTANT

2. SOURCE Other than trace concentrations Asbestos Cooling Tower Fill material

- asbestos board cement may be present in Outfall 002 Strontium, Zirconium Fission & activation products produced in the reactor <1E*10 mg/day present in Outfali 001 I MO 780-1514 (!J6.12) Enclosure to ULNRC-06027

3.10 BIOlOGICAL TOXICITY TESTING DATA DO YOU HAVE ANY KNOWLEDGE OR REASON TO BELIE;VE THAT ANY BIOLOGICAL TEST FOR ACUTE OR CHRONIC TOXICITY HAS BEEN MADE ON ANY OF YOUR DISCHARGES OR ON RECEIVING WATeR IN RELATION TO YOUR DISCHARGE WITHIN THE LAST Tl-IREE YEARS? J;i'lvES (IDENTIFY THE TEST{S) ~~f..JD DESCR!SE THE!R PURPOSES SflOY¥.) 0NO \\GO TO 3.20j Annual Whole Effluent Toxicity (WET) tests are conducted in accordance with permit conditions. The last test was conducted in September 2012 and a report was issued in October 2012. 3.20 CONTRACT ANALYSIS INFORMATION WERE ANY OF THE ANAlYSES REPORTED PERFORMED BY A CONTRACT LABORATORY OR CONSULTING FIRM? llJYES (LIST THE NAME, ADDRESS AND TELL;PHONE NUMBER OF AND POLLUTANTS ANALYZED BY EACH SUCH LABORATORY OR FIRM BELOVO 0NO (GO TO 3.30) A. NAME B. ADDRESS C. TELEPHONE(ereacodeandnumoor) D. POLLUTANTSANALYZED(IfsQ TestAmerica Laboratories, Inc 13715 Rider Trail North Earth City, MO 63045 POC laboratories, Inc. 3278 North Highway 67 Florissant, MO 63033 3.30 CERTIFICATION 314-298-8566 314-595-7337 See Attachment E, NPDES Sampling & Analysis See Attachment E, NPDES Sampling & Analysis I certify under penalty of law that r have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe the information is true, accurate and complete. I am aware there are significant penalties for submitting false information, including the possibility of fine and imprisonment NAME. AND OFFICIAL TITLE {TYPE OR PRINT) TEL!;PHONE NUMBER WITH AREA CODE Adam Heflin, Senior Vice President & Chief Nuclear Officer (573) 823-5411 DATE SIGNED MO 780.1514 (06-12) Enclosure to ULNRC-06027

1. POLLUTANT

b. Chemical Oxygon Domand (COO}

c. Total Organic Carbon {TOC}

d. Total $uspeodod SQ!ids (TSSJ

e. Ammonia (as N)

(Wint(lrj h, TOOll)(lralure (summer) i.pH

a. MAXIMUMOAilYVAlUE (1)

(2)t.4ASS CONCENTRATION <120 <96 92 74 24 19 15 12 45 36 VAI.Ue0.096 VALUE VAlUE 26.0 MINIMUM 7.21 (1) CONCENTRATION 94 14 VALUl: 0.094 VALUE 25 VALUE 33 Callaway Energy Center Outfall 001 {l}MA$$ 74 11

LONG TERM AVRG. VALUE (t~}

(1) CONCENTRATION 18 6.4 VALUE 0.081 (2)MA$S 12 4.3 Form C

d. NO. OF ANALYSES 12 1

1 61 1 61 6 6 61 a.CONCEN-

b. t.4ASS TRATION mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 l'bs/d mg/1 Ibs/d MGD oc oc STANDARO UNITS

a. tONG TE~M AVERAGE VALUE

{1) (2)MASS CONCENTRATION VALUE VALUE VALUE Outfall No. 001

b. NO OF ANALYSES "X" in column 2-a for eaeh pollutant ~u mow or have r~

to boliovo is present. Mllllt *x-in column 2-b for each pollutant ~u believe to be llbsent. lr ~marie column 2-a for any pollutant, you muat provide the 11)$(J"s or at least ooo analysis for lhat pollutam. ComPlete ono l<<blo for ~ 1ch ouffa!l. Soo too &dditiollal detaifs and I'EtqtjrC~molll$.

1. POLLUTANT AND CASNO.t~*VI1iloblal

a. Bromide (241l5s.67-9)

b. Chlorine, Total Residual X

X X X X X

a. MAXIMUM DA!L Y VALUE c*ONCemRATION

(:!)MASS (1} (2)MASS CONCENT 0.50 0.40 0.01 0.008 0.090 0.071 <0.1 <0.080 <0.050 <0.040

c. LOHG TERM AVRG VALUE

d. NOOF

a. CONCENTRATION

b. MASS

a. LONG TERM AVERAGE Vft.tUE b.NOOF

((8~ AHAI.VSES ANALYSE;$ (1) (2)MASS (1} /2; CONCENTRATION CONCENTRATION M4.~iS 1 mg/t lbs/d 0.039 0.026 12 mg/1 lbs/d mg/1 lbs/d 1 mg/1 fbs/d Page6 Enclosure to ULNRC-06027

Callaway Energy Center Outfall 001 ~- AIIARK"X,.

3. EFFLUENT

4. UNITS S. INTAKE f-~

1. POI.LUTAttT ANO

a. MAXIMUM DAJL Y VALUE

b. MAXIMUM 30 DAY VALUE

~. LONG TERM AVRG VA!..UE

d. HOOF

a. LONG TERM AVERAGE II AWE I>. NO OF CA$ H0.11~~~

a.

b.

(i*~! ~~ ANALYSES ~. CONCENTAA110N

b. MASS ANAI.YSES aSLIEVED BELIEVED PR5$ENT ASSENT (11 (2)MA$$

(1) i2)MASS (1) (1l (:2) CONCS:NTRATION CONCSNTAATION CONCENTRATION (2)MASS CONCENTRATION MJtSS

g. Nitrogon, Total OrgMic

{~N) X <0.20 <0.16 1 mg/1 lbs/d

11. Oil aoo Grow.HJ X

<5.0 <4.0 7 5.5 3.0 2.0 12 mg/1 lbs/d

i. Pho!lphorus (asP) Total X

0.27 0.22 1 mg/1 fbs/d (7723-14-Q)

j. Rooioactivlly (1}Aiplla, Total X

4.6 1 pCi/1 (2} Beta. Tala! X 2330 1 pCi/1 {:>)Radium, T<1lal X I {4} Radium 226, X T<1tal ~-SUlfate (a$ $04) X 1300 1040 1 mg/1 lbs/d {141,10$.79-ll) !. Sulfide {asS) X

m. SUlfite~~ 503)

X f14~3)

n. $\\W~llnts X

o. Aluminum. Tolsl X

0.12 0.10 1 mg/1 lbs/d (1429-W.&l

p. S.!!flum, Tols X

0.051 0.041 1 mg/1 lbs/d (7<t40.al!-~)

q. Soroo. Total X

55u 44 41 32 19 13 61 mg/1 lbs/d (744(!..4~-tl}

r. Co~ll. Total X

<0.002 <0.0016 1 mg/1 lbs/d (7 4404a.4) {74s~S:s}. X 0.82 0.66 1 mg/1 lbs/d

t. Ml!gll9Sium. TP1al X

9.0 7.2 1 mg/f lbs/d (7439-%-4j

u. Molybdenum. Total X

0.091 0.073 1 mg/1 lbs/d (7439-00-7)

v. Mangaoose, Total X

0.022 0.018 1 mg/1 lbs/d (7439-00-5)

w. Tin. Total X

0.0022 0.0018 1 mg/1 lbs/d {7440-31-5)

x. T!!Mium. Total(7440-X

<0.005 32.0} <0.0040 1 mg/1 lbs/d Page7 ~A commercial lab was not located equipped to analyze surfactants for a potentially radioactive sample. If surfactant data is considered essentiar, at DNR's request we will attempt to arrange for a special analysis. Note that a test conducted for the 1995 reapplication revealed no substantial surfactants (<0.025 mg/1}.

- The effluent boron concentration could be as high as 1000 mg/1 for Outfall 001 (see Attachment A).

i Enclosure to ULNRC-06027

a. MAXIMUM DAILY VALUE (1)

(2}MASS (1) CONCENTRATION CONCSNTRATION <6.0 <170

b. Choollcal Oxygen Oemand 57 1600 (COO)

c. TQt:al Orgalllc Carbon (TOC}

17 490

d. Total Suspended Solid$

59 1700 143 (TSS)

e. Ammonia (as N) 0.19 5.5

f. Flow VALUE 3.46 VALUE 6.7

g. T001~ra1ure(v.inter)

VALUE 19.3 VALUE 24

h. Tem~ralur& (summtll')

VALUE VAI.UE 33 i,pH MINIMUM MAXIMUM MINIMUM 7.37 7.75 Callaway Energy Center Outfall 002 Fonn c

a. LONG TERM AVRG. VAlUE

d. NO. OF

{ld~~ ANALYSES (2)MASS (1) (2}MAS$ CONCENTRATION 1 1 7990 71 3430 52 1 VALUE 5.8 365 VALUE 22 182 VALUE 29 183 Continuous a.CONCEN-

b. MASS TRATJON mg/J lbs/d mg/1 lbs/d mg/1 Jbs/d mg/1 fbs/d mg/f lbs/d MGD oc I 0c STANDARD UNITS

a. LONG TERM AVERAGE VAlUE (1)

(2)1'MSS CONCENTRATION VALUE VALUE VALUE Outfall No. 002

b. NO OF ANALYSES PARTS. Mark "X" in column.2-a tor ~ch pollutanl you koow or hava reason lo bflliovo i$ present. Mark *x-in column 2-t> tor each pollutant you believe to bo ~t. If you mark column 2*a foc any pollutant you m\\ISI provid& lhe results of ai!GeSI 011e analysis lor that pollutaot Complete 011e table for e.Jdh outfall. ~tho ln&tructions for additional <l&lall$ and roquirements.

1. POllUTANT AND ll. MAXIMUM DAIL V VALUE

b. MAXIMUM 30 DAY VALUE

e. LONG TERM AVRG VALUE

d. NOOF

a. CONCENTRATION

b. MASS

a. LONG TERM AVERAGE VAL!JE

b. NO OF (t~}

flf~

ANALYSES ANALYSES CASNO./>f.......W..J

a.

b.

BEUEVEO BELIEVED PRESENT ABSENT (1) (2)MASS {1~ (2)MASS (1) {2) CONCENTRATION CONCENTRATION CONCENTRATION IV ASS

a. Bromid&

X 3.1 89 1 mg/1 lbs/d (24959-67 -9} X <0.05 <1.4 0.083 4.6 0.062 3.0 365 mg/1 lbs/d X X X 1.1 32 1 X 7.8 220 1 mg/1 Jbs/d Page6 Enclosure to ULNRC-06027

Callaway Energy Center Outfall 002 2, MARK"X"

3. EFFLUENt

4. UNITS 5.1NtAK!!v~

1. PO~LUT ANT AND

<t. MAXIMUM OAILY VALUE

b. MAXIMUM 3C DAY VALUE

e. LONG TERM AVRG VALUE

d. HOOF

a. CONCENTRATlON

b. MASS

a. LONG TERM AVERAGE VALUE

b. NOOF

(;AS NO. !la~1

a.

b.

ill~ {d-~) ANALYSES ANALY$5$ BELIEVED BELIEVED PRtiSElNT ASSENT (1) {2)MASS (1} (2)MASS {1) {2iMASS \\1) (2) CONCcNTRA TION CONCeNTRATION CONCENTRATION CONCENiRA T!ON MASS

g. Nilrogen. io!al Organic X

2.5 72 1 mg/1 lbs/d (al!N) It Oil arx:! Gre~~M~ X <4.8 <140 <5.0 <280 1.9 92 4 mg/1 lbs/d \\ t ~rusc(uP}Total X 2.3 66 1 mg/1 lbs/d (7723-14-0) j.Rtldiet>ctivily (1 i Aiplla. Total X 15 1 pCi/1 i2) ~a. Tolsl X i 21 1 pCi/1 (3} Radium, Total X (41 Radium 226. X Total I

k. Sullato (as S04) 1 mg/1 lbs/d (148Q8*71l*S)

X 990 29000 $Uifl(!<;(!l$ Sj X

m. $ullilo{A$S03)

X ( 14265-45*3)

n. Sunll\\:lants X

0.20 5.8 1 mg/1 lbs/d

o. Aluminum, Tolai X

2.8 81 1 mg/1 lbs/d {742ll-00.5) p, S$ium, TQlai X 0.31 8.9 1 mg/1 lbs/d l7440.3t;.3} q.Soroo, Totlll X 0.33 9.5 1 mg/1 lbs/d lf44().42-6}

r. CQ!><lll, Total X

<0.002 <0.058 1 mg/1 lbs/d {'1441)..48-4)

s. Iron. Tole!

X 2.7 78 1 mg/1 fbs/d (743~)

t. 1\\iagi'IOOlum, Tel$

X 71 2000 1 mg/1 lbs/d {7439-95-t)

u. Mclybdooum, Tolal X

0.0090 0.26 1 mg/1 lbs/d (743t;.lJ8..7;

v. Msngaooae, T<otal X

0.15 4.3 1 mglf lbs/d (7439-00..S}

w. Tin, Total X

<0.002 <0.058 1 mg/1 lbs/d \\7440.31*5/

x. Titanium. Tolsl (7440.

X 0.037 1.07 1 mg/1 rbs/d 32-6) Pag;a7 Enclosure to ULNRC-06027

1. POU.UTANT

a. MAXIMUM DAILY VALUE (1)

(2)MASS CONCENTRATlON

a. Bioctwnl\\:al 15 1.80 OX'I'Q(Hl Demand {BOO)

b. Chemical Oxygen Demand 37 4.44

{COO)

c. Total Orgtmic Carton (TOC) 8.8 1.06 d, Total SU$ptlf1ded Solids 38 4.56

{TSS)

e. Ammonia (M N) 0.025 f Flow

g. Tompocalure {winter)

MAXIMUM 9.15 Callaway Energy Center Outfall 003

b. MAXJMUM 30 DAY VALUE (1-}

(1) CONCENTRATION VALUE VALUE VAlUE MINIMUM (2)MASS

c. LONG TERM AVRG. VALUE (L-J (1}

CONCENTRATION (.~}MASS VALUE VAllJE VALUE Form c d.HO.OF ANAlYSES 1 1 1 1 1 1 4 4 a.CONCEN*

b. MASS TRATION II lbs/d mg/1 lbsld mg/1 lbs/d mg/1 fbs/d mg/1 lbs/d MGD oc oc ST ANDAAD UNITS

a. LONG TERM AVERAGE VALUE:

(1) (2}MASS CONCENTRATION <6.0 <570 26 2500 5.9 560 1500 140000 0.55 52 VALUE 11.37 VALUE 8.5 VALUE 22.7 Outfall No. 003

b. NO OF ANAL YSSS 1

1 1 1 1 1 4 1 PARTS

Mark "X" in oolumn 2-a lor each pollutant you know Qr llavo roaoonlo bo!ieve is pr-111. Marll *x; in column 2-b for each polllllanl you bali eve to be all$elll. If you lllafk oolumn 2-a for any pollutanl. you must provldo Cho results or at least one tll'lalysls. for tnat pollutant Complete one Iailie for !lllch olllfall See th&

instructions tor &dditiona! dolails and requirements.

1. POLLUTANT AND

a. MAXIMUM CAlLY VAlUE

b. MAXIMUM 30 DAY VAlUE

c. LONG TERM AVRG VALUE

d. NOOF

a. CONCENTRATION b,MASS

a. LONG TERM AVERAGE VALUi:

b. NO OF

/tl.mobl>lt/ (I~} ANALYSES ANALYSES CAS NO.(<-/

a.

b.

eeueveo ISEliEVED PRESENT ABSENT (1} (2}MASS (1) {2)W.SS {1) (2)MASS (1) (2} CONCENTRATION CONCENTRATION CONCENTRA TtON CONCENTRATION MASS

a. BromldG X

<0.25 <0.03 1 mg/1 lbs/d <0.25 <24 1 {24959-67-9) b.Ch4orioo. X <0.05 <0.006 4 mg/1 lbs/d TOiafR~uat

c. Color X

d. Fecal X

420 39000 1 Coliform

e. Floorkkl X

0.32 0.038 1 mg/f lbs/d 0.18 17 1 (115984-4~} f, Nitrate* X 0.12 0.014 1 mg/1 Jbs/d 2.0 190 Nitrita(as.N) Page 6 Outfall 003 is recycled back to the head of the water treatment plant for reuse. Enclosure to ULNRC-06027

Callaway Energy Center Outfall 003

2. MAAK"X"

3. EFFLUENT

4. UNITS

5. INTAKE rc-1.POLU,JTAHT AND

a. MAXIMUM OAIL Y VAI..U!

b. MAXIMUM 30 DAY VALUE

~. LONG TERM AVRG VALUE

d. HOOF

a. CONCENTRATION

b. MASS

a. LONG TERM AVERAGE VAlUE

b. NOOF CAS NO. !~4-l

a.

b.

II~) 14...-; NW.YSES ANALYSES 6EUEVEO 6El.JEVED PRESENT ASSENT (1) {2)MASS (1) (2)MASS m (2)MASS (1i (2} CONCENTRATION CONCENTRATION CONCENTAATION CONCENTRATION MA:SS I

g. Nitrogen, Total 0rga'liC X

(asN) 2.4 0.29 1 mg/1 lbs/d 3.0 28:0 1

h. Oil alld Grease X

<4.7 <0.56 4 mg/1 lbs/d <4.7 <460 4

i. Phosphorus (<IS P) Tala!

X 0.36 0.043 1 mg/1 lbs/d 2.8 270 1 (7723-14-C)

j. Radioactivily

\\1) Alpha, TQ!al X 3.8 1 pCi/1 12 1 {2} Bote, Total X 5.2 1 pCi/1 13 1 (3) Radium. Tot&! X ( 4} Radium 22t. X Total

k. Sl.lilale('.I$S04)

X 260 31 1 mg/1 lbs/d 38 3600 1 (14008-79-a) L S11tfida (asS) X

m. Slllfl!e (aa $03}

X (14265-45-3)

n. Surtactllfltt X

0.12 0.014 1 mg/1 lbs/d <0.10 <9.5 1 <;>, Alumillllm. TOOII X 0.56 0.067 1 mg/1 lbs/d 33 3100 1 (7429-00.5)

p. a&num. Tota.t X

0.083 0.010 1 mg/1 lbs/d 0.39 37' 1 (7440-39-3) q_ eoroo, Total X 170 20 1 11911 lbs/d 71 6700 1 {7440-42-S}

r. Coball. T<>t!!l X

<2.0 <0.24 1 pg/1 lbs/d 16 1500 1 {7440-48-4)

s. Iron, Total X

0.89 0.11 1 mg/1 lbs/d 38 3600 1 (1439-$-6) t Magooruum. T~al X 23 2.8 1 mg/r lbs/d 13 1200 1 (7439-95-4)

u. Molybdf)m:m. Tots!

X 6.4 0.77 1 J.IQ/1 lbs/d <5 <470 1 {7439-98-7)

v. Mangan-. T~al X

0.69 0.083 1 mg/1 lbs/d 1.5 14(1 1 (743$-00..5)

w. Tin, T<:>tal X

<2.0 <0.24 1 11911 lbs/d <2.0 <190 1 {7440.31*5) >>. Ti!.alllum, Total (1'440-X 8.2 1.0 1 JJg/1 lbs/d 330 31000 1 32-6) Page? Outfall 003 is recycled back to the head of the water treatment plant for reuse. Enclosure to ULNRC-06027

1. POLLUTANT

u. MAXIMUM OAIL 'I" VAt.Uc

{1) (2)MASS CONCENTRATION

a. Biochemical 12 1.5 Oxygen Demand (BOD)

. Chemical Oxygon Oomand 98 12

00) 20 2.5 nded Solid$

26 3.3 0.64 0.080 VALUE 0.015

g. TemPI)fllture(wint~)

VALUE 12 t;. Temperatute (wmmer} 26.3 i.pli f41NIMUM MAXIMUM 8.11 9.37 Callaway Energy Center OutfaH 007 Fonn C

b. MAXIMUM300AYVALUE

~. LONG TERM AVRG. VALUE (l*voio/)/ol (lt4I'Hitlllt}

d. NO. OF ANAlYSES (1)

(2}MASS (1) (2)MASS CONCENTRATlON CONCENTRATION 1 1 1 1 VALUE VAlUE 1 VAlUE VALUE 1 VALUE VALUE 1 MINIMUM 2 a.CONCEN* TRATION

b. MASS mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d MGD oc oc STA.NOAAO UNITS a.LONG TERM AVERAGE VALUE (1)

CONCENTRATION (2)MASS VALUE VALUE Outfall No. 007

b. NO Of' ANALYSES T B-Mark "X" in column~-~~ for IJl!d1 pollutanl you know or nave reason to bOiiovo ie Pf~. Mark "X" in column 2*b for 0t1c11 pollutam you believe Cob& absent. If you mark column 2-a fQr ~my pollulant. you mll$t J)ll:ivido the rQSUit&of at IOl!oSI *)ne IJllBiysis for thai PQIMont. Complete on& table for eaCh outfall.

ctions for additional dela~s and r"'lvir(Mllflflts.

1. POLLUTANT AND

<t. MAXIMUM OAIL Y VALUE

b. MAXIMUM 30 DAY IIAtUE

~ LONG TERM AVRG VALUE

d. NOOF

a. CONCENTRATION b, MASS

b. NO OF

~oVOtlltbll) (io"'*bbJ ANALYSES ANALYSES CASNO.(lfr'<<<ffffbbiJ

a.

b.

BELIEVED BEUEVEO PI'{ESENi ASSENT {1} 12IMASS (1) (2)MASS (1) (~)MASS (1) CONCENTRATION CONCENTRATION CONCENTRATJON CONCENTRATION a.6romido X (24959-67-!1}

b. Chlorine.

X Total Roo>dual

c. Color X

d. Focal X

1

/100ml Coliform o.Floorido X

(16984-43-6} 0.20 0.025 1 mg/f lbs/d Ill() Page6 After flowing through two wetlands for additional polishing, Outfall 007 is recycled to the head of the water treatment plant for reuse. Enclosure to ULNRC-06027

Callaway Energy Center Outfall 007

2. MAfl:l( "X"

3. EFFLUENt

4. UNit$

S.lNTAKE<oi>><>>MMI

1. POL~UTA!fr ANO

a. MAXIMUM DAILY VALUE

b. MAXIMUM 30 OAY VALUE

c. LONG TERM AVRG VALUE

d. NOOF a.CO~TlOI'l

b. MASS

a. ~ONG TE:RM AVERAGE V1\\I.:UE

b. NO OF CAS NO. !4~*-J

a.

b.

(in~) {I ~~'~'~>~DUe) ANALYSES ANALYSES SELI!M;O BELIEVED PRESENT ASSENT (1} (2}MA$$ (1) (2)MASS (1) (2}MASS (1} {2) CONCENTAATION CONCENTRATION CONCENTRATION CONCSNTRATION ~A:SS iJ. Nitrogen, Total Organic X 4.3 0.54 1 mg/1 lbs/d (as N) ltOi!andGr~ X <5.0 <0.63 1 mg/1 lbs/d

i. Pho$1'horus (asP} Total X

3.5 0.44 1 mg/1 lbs/d I (7723-14-0)

j. Radk>adMty

{1)Alpha, Total X <3.0 1 pCi/1 {2} Beta, Tch'Ji X 14 1 pCi/1 M" (3j ~ium, T<:>lal X l4l Radium :m~. X To!<ll! ~ Sulfa!e{as $04' X 58 7.3 1 mg!l fbs/d (14008..79-8) !, St.'lfids (asS} X

m. Sulfltil (asSO:>)

X (1-1265-<IS..~) Surfl\\Cta'lts X 0.22 0.028 1 mg/1 lbs/d

o. A!llmioom. Total X

0.20 0.025 1 mgll fbs/d (7429-00-S)

p. 8ari~AT~. Total

~ 0.043 0.005 1 mg/1 lbs/d {7 440<.1$-3)

q. Sa<on, Total X

0.25 0.031 1 mg/1 lbs/d (7 440-42-8) r, C¢ball, Total X <2.0 <0.25 1 jJg/1 lbs/d {7440.4$-4)

s. !ron. Total X

0.18 0.023 1 mg/1 lbs/d (7439-aS-6)

t. Magne$um, Total X

25 3.1 1 mg/1 lbs/d {7439-95-4)

u. Mo!ybdaoum. Total X

<5.0 <0.63 1 pg/1 lbs/d {743!).98-7)

v. Manganeoo. Tolal X

'0.14 0.018 1 mg/1 lbs/d {7439-96-5}

w. Tin, Total X

<2.0 <0.25 1 J,Jg/1 lbs/d \\1440-31-5)

x. Titanium. Total (7440.

X <5.0 <0.63 32-6} 1 pg/1 lbs/d Page 7 After flowing through two wetlands for additional polishing, Outfall 007 is recycled to the head of the water treatment plant for reuse. Enclosure to ULNRC-06027

1. POLLUTANT

a. MAXIMUM OAlL Y VAtuE

{1} (2)MASS CONCENTRATION II. 6ioollemical <6.0 <56 Oxygen Demand (BOO)

b. Chemi~l Oxygen D&maro 18 168

\\COO)

c. Total Organic Carbon (TOC}

6.3 59

d. Total SUSpOnded Solids 24 224

{TSS}

e. Ammonla (as N)

<0.010 <0.093 VALUE 1.12 ra(>Mnter) VALUE

h. TOOJI)ef~uro (!llrnmer}

VALUE 24 LpH MAXIMUM Callaway Energy Center Outfall 01 0 Form C

b. MAXIMUM 30 OAY VALUE

c. LONG TERM AVRG. VALUE (lotmiblllo}

{L~ II. NO. OF ANALYSES m {2}MASS {1) (2)MASS CONCENTRATION CONCENTRATION 1 1 1 1 1 VALUE 1 VALUE 1 VALUE MINIMUM 1 a.CONCEI>t-TRATION

b. MASS mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d MGD oc oc STANDARD UNIT$

a. LONG TERM AVERAGE VALUE (1)

CONCeNTRATION (2)MASS VALUE VALUE VALUE Outfall No. 010

b. NO OF ANALYSES PART a-Mark "X" in <:OI~<ml'l2*a for oocll pollutant you know Qf' have roason to believe Ia present Mark "X" in column.2-b f<lr ~

PQ!Iutanl you believe !Q be llbsent. If you mark.:o~umr; 2-a ror any pollutant. you must provide lhe C'OMIIIa of at lea81 one analy$i& for that PQUulant. Complete one Jable for <nich outfalL Seo the i~ructkms for actdlllooal detail$ ond roquiremenls.

1. POLLUTANT AND CASNO.I>t4~

a. Elr01l1id<l

{24059-67 -9) I>.Chtorine, TotaiRI)$j(jual

c. Color X

X X X

a. MAXIMUM DAILY VALUE (1)

CONCENTRATION. 140 <1.0 (2)MASS <9.3 (1) CONCENTRATION (2)MASS c;. LONG TERM AVRG VALUE {1 *..-} (1) CONCENTRATION PageS {2}MASS

d. NOOF ANALYSES 1

1

a. CONCENTRATION

b. MASS

/100m I mg/f Jbs

a. LONG TERM AVERAGE W.t.UE (1)

CONCENtRATION

b. NO OF ANALYSES Enclosure to ULNRC-06027

Callaway Energy Center Outfall 010 2, MARK"X" 3, ~FFI.UEMi 4, UNit$ S.lNiAKE l<<""'"llll

1. POI.I..UTANT ANI)

a. MAXIMUM DAII. Y ltALIJE

11. MAXiMUM 31! DAY VAI.tll

11. LONG TEAM AVRG VAI.UI

d. HOOF

a. CONCENTAA TlON

!:>.MAS$

a. l.ONG TERM A\\'eRAC>E V/\\LIJE

b. NOOF CA$ NO.{t.,_.i

a.

b.

~~'

(1.~) AHAI.YSES ANALYSE$ setc,IEVEO !C.Lill!VEO PBESENT ABS6NT \\11 (2)MASS (1) (2)1\\AASS \\1) {2)MASS (1} (2> CONCENTRATION CONCENTRATION COf.ICENTRA TlON CONCENTRATION MASS

g. Nilrogon. Tolal Organic X

<1.1 <10.3 1 mg/1 lbs/d {asN) ll. Oil ana Gro~ X <5.5 <51 1 mg/1 lbs/d L Pbo~rus{aa P) T<llal X 0.056 0.52 1 mg/1 lbs/d (7723-14..0}

j. Radioactivily

{1}Aiplla. Total X (2)6<lla. T<llal X (3} Radium. Total X {4} Radium 226. X Total lt. Sulfate {an $04) X 36 336 1 mg/1 lbs/d (1480e-7r..a) I. $ulfi<!~ ~~ S) X X I (142~S,:$) It Surt!IC!llr'll~ X {i.i!i~~j* X 0.37 3.5 1 mg/f lbsld

p. eooum. Tollil X

!7440..30..3}

q. Beron, iollil X

{7440-42*3)

r. COOall. Total X

17 440-48-4) !!'. Iron, T olal X 0.45 4.2 1 mg/1 lbs/d {7439$.6)

t. Mag~um. Total X

6.9 64 1 mg/f lbs/d (743?"95>4l

u. Molybdenurl;, Total X

(743~00-7) v.Manga~. Total X (7<139-9(;.5)

w. Tin. TOlal X

{7440-31-5)

x. Tilanium. Tolal (7440.

X 32-S} Enclosure to ULNRC-06027

Callaway Energy Center Outfall 011 form c

1. POLLUTANT

a. MAXIMUM OAJt.. Y VALUE

d. NO. OF a.CONC&:N*

n. MASS

a. LONG TERM AVERAGE VALUE TRATION ANALYSES (Z)MASS

{1) (2)M4.SS (Z)MASS (1) CONCENTRATION CONCENTRATION

a. BiocOOmical 8.0 230 1

mg/1 lbs/d Oxygen Demand (BOD)

b. Chern~ Oxygon Demand 31 910 1

mg/1 lbs/d (COD) 9.7 280 1 mglf lbs/d

d. Total Suspended Solids 45 1300 mg/1 lbs/d

{TSS) <0.010 <0.29 mg/1 lbs/d VALUE 3.51 VALUE 1 MGD VALUE VALUE VALUE 1 oc VALUE VAlUE 24 VALUE oc VALUE MUM MINIMUM 1 STANDARD UNITS PART 8-Mark "X" in column 2-a for ooct1 pollutanl you know or have rea3!:mlo believe 1$ J)f-nt Mark "X" in colUmn 2-b lor eacll pollutant you believe to be absllnt. II you marie column 2~ for any pollutant yo*.nnust J)fOViOO the r~ or at lea~ one anal)'llla for that pollutant instructions far additional <:kllails and requlremonta. {2)MASS

b. NO OF ANALYSES Enclosure to ULNRC-06027

Callaway Energy Center Outfall 011 ~. MAJI:j(~W . ~. t:Ff'I.\\J~Nt

4. UNITS

$.INTAKE(::,~ 1, POLI..t.ITAH1' AHD

11. MAXIMUM OAII. Y VAL. Uti.

b. MAXIMUM 30 CAY VAL.UI:!

c;. LONG TE!!tM jO.Vft(O VALUE

d. NOOF II. CON¢ENTRAT;;ON

b. MASS LON¢ TfRM AVSRAG!; V1\\LIJE

. CASNO.f-"-"'~1 il.

b.

jt--) ~~*~J ANAlYSE!$ SE:1.15VS:P E!i!t..liW!O PRI!!SS.NT ABSENT (1) (2)MA$$ (l) (2)MASS (1) i2}MAS$ Iii (Zi CONCI!Ni'AATION CONCEN'I'AA i'ION CONCEN'l'AATION CONCENTAA TION ~ ..... ~~s 9* N~!t>$iil1l, 'l'OIIll Ofllllllic X 1.3 38 1 mg/1 tbs/d (111!N)

h. Oil Md CreMe X

<5.3 <160 1 mg/1 lbs/d I. Pho$!)1'1¢rus(!lSP) Tolal X 0.15 4.4 1 mg/f lbs/d {7)'23-14-0) j.Raclioaclivlty {l)Alpl\\ll, Total X (:Z) 6tot&. Total X (3} Radium, TOll)t X {4) Radium 22e. X TOlal

k. Sulfate{as$04)

X 17 500 1 mg/1 lbs/d (14008-7\\).8) L Sulfide (lUI$) X

m. Sulrrta (S$ SOS)

X 1 (142~)

n. Slitf!llllar\\lll X

r*~=r* X 2.2 64 1 mg/1 lbs/d

p. S"allum. Total X

{744(.i..::l9-$) &!'~iJf X

r. Cobalt. 1' otal X

{:1'440-48-4) $.Iron. Total X 2.5 73 1 mg/1 lbs/d (7439-89-e) !. Magnowum. Total X 5.5 160 1 mg/1 lbs/d {743~95-4)

u. Mol)'tldeoom, T<:~tal X

(74$1).98-7) u t4n~""""" X {7439-§e..s:)

w. Tk,. Totlll X

{N-10..31-5)

x. Titanium, Total (744(.i..

X 3.2-6) Enclosure to ULNRC-06027

FLUENT CHARACTERISTICS (-ln>m-3o1FottnCJ

1. POLLUTANT

11. MAXIMUM OAILY VALUE (1)

{2)MASS {1) CONCENTRATION CONCENTRATION

a. Bio<:tlemi~l

<6.0 <52 Oxygen DemaOO (SOD)

b. Chemical Oxygen ~and 21 180 (COD}

. Total Orgooic Cal-bon (TOC) 4.3 37

d. TOlsl Suspended Solids 88 760

{TSS)

a. Ammonia (aa N}

0.14 1.2

f. Flow VALUE 1.04 VALUE

g. Teml)()ratura(winl<l<"}

VALUE VAlUE

h. Temper.rture(stJmmor)

VALUE 24 VALUE MAXIMUM MINIMUM Callaway Energy Center Outfall 012 Fonn C fl. LONG TERM AVRG. VALUE

d. NO. OF (Ito.....,.)

ANALYSES (2)MASS (1) {2)MASS CONCENTRATION 1 1 1 1 1 VALUE 1 VALUE 1 VALUE 1 a.CONCEN-TRATION

h. MASS mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d MGD oc oc STANDARD UNITS

a. LONG TeRM AVERAGE VAl.UE

{1) CONCENTRATION (2)MASS VALUE VAlUE VALUE Outfall No. 012

b. NO OF ANALYSES PART 8-Mark "X' ill oolumn 2-a for eacti polluteN you know or have reason ta beliova is present. Mark "X" in col1.1111n 2-b for each pollutant yotJ boliove to be a~. If you mlllk column 2-a far any pollutanl, you mU$1 provide the results of sll&allt one analySis for that pollutant.

inllo1rueliorn~ for l!ddilional delails aoo requir<Jments.

1. POLlUTANT AND

11. MAXIMUMDAILYVALUE

b. MAXIMUM 30 OAV VALUE

c. LONG TERM AVRG VALUE

d. NOOF

a. CONCENTRA TCON

b. MASS

a. LONG iERM AVERAGE V.At.UE

b. NO OF

{f...-) ~..-, ANAI.YSES ANALYSES CASNO.(I.....-) oil.

b.

BELIEVED BEliEVED PRESENT ABSENT (1) (2J~SS {1) (2)W.S$ (1) (2)MASS (1) CONCENTRATION CONCENTRATION CONCENTRA T!ON CONCENTRATION X X X X 6500 1

/100ml X

X <1.0 <8.7 1 mg/1 lbs/ PageS Enclosure to ULNRC-06027

Callaway Energy Center Outfall 012

2. MAAK"X"'

3. fi!ilFLU!NT

..t. U~ITS S.IHTA.KE 1111~

1. POi.l.li'I'Akf ANI)

11. h'IAAIM\\JM CAll. Y VAI.Uit

b. MAXIMUM~ DAY VAI..Ul

<1. LONG T!ltM AVI't4 VAI..Ul d, HOOF

11. CONCf!NTAATION

b. MA.$$

a, lONG TERM AvSAACil£ VAL..tJS ¢AS NO. t~M*~l ~-

b.

(iM~I ~~~ ANALYSES EIE!.Hil\\11!:0 l!li;t.lla'\\IE!D PFti:SeN'I' MSI:NT' \\1) (:C}W.SS (1) {~)MAS$ {i) !2)MASS (1) (2:, CONCf!I'I'I'AATION CONOiN'ffiATION ¢0NCENTAATION CONCENTAATION MAll$

g. Ni\\rogllll, Tc-tcl Org11nic

(<<11HI) X <1.1 <9.5 1 mg/1 lbs/d ll.O~alldGr-X <5.1 <44 1 mg/1 ibs/d

i. PhallpOOrus (II~ P) Total X

0.12 1.0 1 mg/1 lbs/d (7723-14-0)

j. Radiooclivity (1 t Alpha. To!al X

{2) Beta. Total X (3) fltadium. TQlal X (4) Radium 226. X iotl!t k, Su!fl.lle{:nS04) X 30 260 1 mg/1 lbs/d (14$00-7\\'i-13} l I. Sulfide (asS) X

m. Sulfl!4> (!l~ S03)

X (142(1.5.45*3}

n. Surfacllalll$

X t>.Alum!o;;m,'!'\\>t~ X 2.7 23 1 mg/1 lbs/d l74~1a0..Sj p.l!i!lfil.lm, illlfli X (:i'4110.394j

q. floron. T¢tlll X

(144o.4Z.ei '* Cot:r41t. '!'otlll X fr44()..41l-4) ill. Iron, Total X 2.5 22 1 mg/1 lbs/d (7439-89-6)

t. Ml!grt0$ium. Total X

7.7 67 1 mg/1 lbs/d (7439-95-4) <J. Moiybdooum, Total X (7439-00.?)

v. Manga-, Total X

(743Q..OO-S)

w. Tin. Total X

{1440-31*5)

x. TilaniiJill, T~al (7440.

X 3l.H!) Enclosure to ULNRC-06027

1. POLLUTANT

~. !AAXIMUMDAILYVALUE (l) (2)MASS CONCENTRATION tt.Bioohemical 9.5 67 Olr.Y!l(lll Oomand (BOO) 38 270 12 85 37 260 <0.010 <0.071 VAI..UE 0.85 VALUE VAI..UE 24 MAXIMUM Callaway Energy Center Outfall 014 Fonn C

b. MAXIMUM 3() DAY VALUE

c. LONG TE.RMAVRG. VALUE d.HO.OF

~'-1 llot<>lllblol ANALYSES (1) (2)MASS (1) (2)MASS COtlCI;NTRATION CONCENTRATION 1 1 1 VALUE VALUE 1 VALUE 1 VAlUE MINIMUM 1 a.CONCEN-TRATION

b. MASS mg/1 lbs/d mgll lbs/d mg/1 lbs/d mg/J lbs/d mglf lbs/d MGD oc oc STANDARD UNITS

a. LONG TERM AVERAGE VALUE (1)

CONCENTRATION (2}MASS VALUE VALUE VALUE Outfall No. 014

b. NO OF ANAl. YSES

Ma~ "X" in column 2*a ror~eh ponutanr. youlu1owor have r6SOOO ~o btliove is presonl, Ma~ 'X" lo column 2*b foreadl pollutanl you belkwe to bo1lbsent. If you mastc col~~tM2-.forany pollutant, y.:.u I'IIIISt prowide lhe IGIIIltl$ol a~ leatlt onaanslyeis for Ulat pollutant. Complete one table for eaeh ouUa!l etail$ aoo roqulrements.

1. POLLUtANT AND

a. MAXIMUM DAILY VALUE b ** MAXIMUM 30 DAY VALUE

c. LONG TERM AVRG VALUE

d. NOOF

a. CONCENTRATION

b. WI$$

a. LONG TERM AVERAGE VA.Ul;

b. NOOF ii-i (1-blot ANAlYSES ANALYSES CASNO.(L..-)

!1.

b.

BEUF-VEO BELIEVED PRESENT ASSENT {1) {2)W.SS (1) (2)MASS (1) (2)MASS (1) {2) CONCENTRATION CONCeNTRATION CONCENTRATION CONCENTRATION MilS$ X

b. Chlorioo, X

Tolal Ftesidual

o. Color X

d. Fecal X

3200 1

/100m I Coliform e.Fiuorkl'"

X (16984-48-8) f.Nitrata-X .0 <7.1 1 mg/1 lbs/d NilriH>(asN) Page6 Enclosure to ULNRC-06027

Callaway Energy Center Outfall 014

2. MAfti<"X..

3. EFFLUENT

4. UNITS S.INTAKE (a~~

1. Pet.LUTAN'I' AND

a. W.XtMUM OAILY VAI..UE

b. MAXIMUM 30 DAY VAI..t.lft

c. LONG TERM AVRG VAI..UE

d. NOOF

a. CONCENTRATION

b. MASS

a. LONG TERM AVI:R.AGE Vr\\LIJE

h. NO OF CA$ NO.it~~*~l

(!, 1:>. (hl"'!illlll!) lillY~) ANALYSI;$ ANAl.Y$£1:$ Elfl.L.IMO !!Ett.lEVt:O PReSENT ASSt:Ni (1) (2)MASS (1} {l)MA$$ (1) (2)MA$$ (1} {2i* CONCeNTRA'ilON COMee!NTRATION CONCENiAAiiON CONCENTR.A TION MAS iS il* Ni!ros)OI'I, TOllll C~ni<: (~N) X <1.1 <7.8 1 mg/1 lbs/d

11. Oil inc! Gt"*

X <5.1 <36 1 mg/1 lbs/d i, POO!Iphoru~ (!l$ P) Total X 0.16 1.1 1 mg/1 fbs/d {1'723--H-0)

j. Ratlklac!lvity I {1} Alpha, TOlal X

(2) Beta. Tole! X {3) R<ldivm. Total X (4) R!ldil;m 2.26. X To4al

k. $ulf<'lt(l {oo S04}

X 20 140 1 mg/1 lbs/d {14aQS..7~} L S!Midl) (a$ Sl X

m. Sulllle (a$ $03}

X (1426&45-3) n.$1Jrfu<;tar'll~ X

c. Alumii'I!Jm. Tot\\'<!

X 1.3 9.2 1 mg/1 lbs/d (742~90~) p.$arll,lll'l, Total X (744(1.39-:l) ~!o;.~~l) X

1. 0>\\~1!, T¢!01 X

{144t'J.41J..4i "* Iron, Tot~: X 2.1 15 1 mg/1 lbs/d \\1439-(!9-6)

t. Magn~. T>Ol!ll X

6.0 43 1 mg/1 lbs/d (7439-95-4)

u. Molyb<IO<l\\lfll. Tolal X

(14:!9--00.7)

v. MaJ19D-. Total X

{7439-96-S)

w. Tin, Tolal X

(744Q..l1.$}

.;, TiiSI'litirll, TO!al (7440.

X ~*6) Page7 Enclosure to ULNRC-06027

UENT CHARACTERISTICS (Wn/lituqd """'"fl't3oiFormCJ ~. MAXIMUM DAILY VALUE (1) (2)MASS CONCENTAATJON <6.0 <25

b. Chemical Ox~'900 Demand 27 110 (COO)

c. Total Organic Carbon (TOC) 8.2 34 d.. Total SU3P0r.ded Solids 4..4 18 (TSS)

e. Ammonia (as N)

<0.010 <0.041 f FlOW VALUE 0.49 VALUE VALUE VALUE VALUE 24 VALUE MAXIMUM MINIMUM Callaway Energy Center Outfall 01 5 Form C

e. LONG TERMAVRG. VALUE

d. NO. OF (I~

ANALYSES {2}MASS (1) (2)MA$$ CONCENTRATION 1 1 1 1 a.CONCEN-

b. MASS TRATJOO mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d MGD oc (lc STANDARD UNITS a.LONG TERM AVERAGE VAI.UE (1)

(2}MASS CONCENTRATION VALUE VALUE VAlUE Outfatl No. 015

b. NO OF ANAl VSE:S Mark "X'" In CQI...mo 2-a f<H' escll pollulant you knOW or have r<ll.lsonto boliave is present. Malle 'X" in column 2*b for escll pollutool you b4lliOVG!o be ablsent. If you marl< colt:nln 2-a ror any poii!Unt, yoo mU$\\ provide til& rest~ Us or at least ooo analysis for that pollutant. Com plata o~ tablo for each outfall Soolhe for additional details and requirements.

1. POLLUTANT AND

a. MAXIMUM OAIL Y VALUE

b. MAXIMUM 30 OAY VALUE

c. LONG TERM AVRG VALUE

d. NOOF

a. CONCENTRATION

b. MASS

a. LONG TERM AVERAGE VALU:

b. NO OF

{14~} r~*vM~J~tJJ ANAlYSES ANALYSES CAS NO. (io~)

a.

b.

BELIEVED 13ELIEVED PRESENT ABSENT (2}MASS (1) (:!}MASS (1} (2)MASS (1} (2) CONCI:NTRATION CONCENTRATION COHCENTRA TION Mil~; a..Bromkkt X (2495!).67-9} X X X 27 1

/100m I X

X <1.0 <4.1 1 mg/1 rbs/d Page6

Algae bloom present around edge of pond and near the point of discharge when sampled for pH.

Enclosure to ULNRC-06027

Callaway Energy Center Outfall 015

2. MARK"XM 3, EFFLUENT

.t. UNITS ~.INTAKEio!:tiO<lo!ll)

1. POI.UlTANT ANO

a. MAXIMUM DAILY VAI.UE

b. WOOMUM 30 DAY VAJ.U!:

c. tONG TERM AVRG VAJ.UE

d. NOOF

11. CONCENTRATION

b. MASS

a. L.ONG TERM AVeRAGE VALUE

b. NO OF CAS NO.I<'~-~

!L

b.

11"*~1 rt..-! ANALYSI:S ANALYSES Bf;t.lii;VE;O BEL.IE'.VEO JllRi!$eNT ASseNT {l) (:!)MASS (1) (:l)MASS (1) (2/MASS {f) (2) CONCf!N'I'IU.TION CONCeN'l'AA'I'ION CONCENTRATION CONCENTAAilON II-ASS

g. Nitr.pgom. iotl!l Otflll'\\1\\'l (lillN)

X <1.1 <4.5 1 mg/1 lbs/d h.OIIl!r.;iGr~ X <5.1 <21 1 mgll lbs/d t Ph!:>~rui>(~s P) TQl~l X <0.050 <0.21 1 mg/1 lbs/d f7?2a-14..¢} l* Rooio<ictillity (1) Alpha. T<:>tal X {2) ~a. Tolal X (3) Radium, Total X (4) Radium 226, X TOlal

k. Sulla!e {as $04}

X 20 83 1 mg/1 lbs/d (14eoa.7~) t Sulfide (a$$) X

m. Sulfi!fl (a$ S03}

X ! 14265-45-3)

n. Surfactant~>

X

o. Al\\lrniO<Jm. Total X

0.034 0.14 1 mg/1 lbs/d {7429-00-5)

p. Barium. Total X

{744()..3fl..3j 'l* &clron. Total X {744()..42-a)

r. C<lbait, TOllll X

{/44{1.46-4)

!i.lr~n. T<:.tal X

0.13 0.54 1 mg/1 lbs/d !143Mil-6) t M~um, Tolill (1-43S.9i5--l} X 6.4 26 1 mg/1 lbs/d u, Molybde!'Mn, Tota.f X (7 439-98-7)

v. Mllfli!OO~A~<r. Totai X

17439-00-$) w.Tiro,Tota4 X {744()..31-5)

x. Titerlium. Total {7440-X 32-8}

Enclosure to ULNRC-06027

Callaway Energy Center Outfall 016

a. MAXlMUM OAII. Y VALUE

c. t.ONG TERM AVRG. VAl.UE (I~

{1} (2)MASS (1) (2}MASS {1) (2JMASS CONCENTRATION CONCENTRATION CONCeNTRATION <6.0 18

c. Toti!ll Organic Carbon (TOC) 4.9

d. Total Suspended Solids 18 150 20 420 12 100 (TSS)

e. Ammoola (as N) 0.26 2.2 r flow VALUE Isolated*

VALUE 2.5 1.0 VALUE

g. Temperature(lllintor)

VALUE 7.1 VAlUE VALUE aturo (summer} VALUE VALUE VALUE i.pH MINIMUM MAXIMUM 7.90 8.10 MINIMUM 7.91 PART B - Malk "Y:' in column 2-a for each pollutant~ know or have roaoon to believe is ~t. Mmk "Y:' in column 2*b for each pOllutant you believe lo be absent If you mar1t column instrudioos for addiliQnal dotailo and roquiremeots.

1. POLLUTANT AND CASNO./in-!

ll. MAXIMUM DAILY VALUE e, LONG TERM AVRG VALUE <I.F~I Colifonn

e. Fluoride (16984-48-8)

8.

BELIEVED PRESENT X X X X

b.

EiEUEVEO 1\\SSENT (1) CONCENTRATION <0.25 <0.0 X X 0.191 1.8 (Ia~} (2}MASS (1) (2)MASS (f) (2}MASS CONCENTRATION CONCENTAATION <2.1 2 <0.050 <1.0 0.040 0.33 1.6 15 Page6 Form C

d. NO. OF AHALYSES 1

1 1 1 1 4 4 4

d. NOOF ANALYSES 1

4 a.CONCEN* TRATION

b. MASS mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d mg/1 lbs/d MGD oc oc STANDARD UNIT$

a. CONCeNTRATION mg/1 mg/1 mg/1 mg/1

Mass estimated based on long term average flow of 1.0 MGD when discharging. Outfall 016 was inadvertently isolated during the sampling campaign.

a. LONG TERM AVERAGE VALUE (1)

(2)MASS CONCENTRATION VAlUE VALUE VALUE

b. MASS

a. LONG TeRM AVERAGE VAJ.Ut:

(1) (:~) CONCENTRATION w.ss* lbs/d Ibs/d lbs/d Jbs/d Outfall No. 016 b, NO OF ANALYSES

b. NO OF ANALYSES Enclosure to ULNRC-06027

Callaway Energy Center Outfall 016

2. MARt\\ ~X"

3. EFFlUENT 4, UNITS 5.1NT AKE IGit!"'-'llll'

1. POllUTANT AND

a. MAXIMUM DAILY VAI.UE

b. MAXItAIM 30 OAY VAI.UE

c. lONG TERM AVRG VALUE

d. HOOF

a. CONCENTRATION

b. MASS ll. t.ONG TERM AVERAGE VALUE b.NOO!O CASNO.<f-~!

a.

b.

(I~} ~~~-} ANALYSES ANAlYSE$ aet.teveo BELIEVED PReSENT ABSENT (l} {2)MASS (1) i2)MASS (1) (2)MASS i1} (2) CONCENTRA TlON CONCENTAATlON CONCENTAATION CONCENTRATION MASS g.Ni!rog<!O, Toli!o!Orga~ \\asN) X <0.55 <4.6 1 mg/1 lbs/d

h. Oil <Wid Gr<n~oo X

<4.7 <39 <5.0 <100 3.6 30 4 mg/1 lbs/d l.l>~hon..lli<(as P} Total X 0.13 1.1 1 mg/1 fbs/d {?{2M4..Q)

j. Radioactivity (1)Alplla, T~al X

<3.0 1 pCi!J {2) 6<lta. Total X <4.0 1 pCi/1 (3) Radium. Total X (4) Radium 226, X Total

k. Sulfate (as $04)

X 43 360 1 mg/1 lbs/d \\14800-19-8) I. Sulfide (asS) X

m. Sulfite($ S03)

X ( 14265-45-3} "'* Suriooants X <0.10 <0.83 1 mg/1 lbs/d

o. Aluminum, TOial X

0.79 6.6 1 mg/1 lbs/d I (74~90-S) p.a~.T<:>tm X 0.062 0.52 1 mg/1 lbs/d (7440.39*3)

q. BO£on. Total X

0.051 0.43 1 mg/1 lbs/d (7440..12-8)

r. C¢~. Total X

<0.002 <0.017 1 mg/1 lbs/d (7440-48-4} (743~G-6) X 0.81 6.8 1 mg/1 tbs/d """""-'li*" X 8.1 68 1 mg/1 Jbs/d j{-!39-IIH) ~~~::?)111, X <0.005 <0.042 1 .mall fbs/d

74~r: ~i' X

0.060 0.50 1 mg/1 fbs/d

w. Tin. Total X

<0.002 {744().31*5) <0.017 1 mgll lbs/d

x. Tllaruum, iolal (7440.

X 0.010 0.083 1 mg/1 lbs/d i :l2-6) Page7

Mass estimated based on long term average flow of 1.0 MGD when discharging. Outfall 016 was inadvertently isolated during the sampling campaign.

Enclosure to ULNRC-06027

fFOR AGENCY USE ONLY jCrn:CtCNO NOTE: DO NOT ATTEMPT TO COMPLETE THIS FORM BEFORE READING THE ACCOMPANYING INSTRUCTIONS 1.00 NAME OF FACILITY Ameren Missouri Callaway Energy Center 1.10 THIS FACILITY IS NOW IN OPERATION UNOER MISSOURI OPERATING PERMIT NUMBER MO- 0098001 This form is to be filled out in addition to forms A and C "Application for Discharge Permit" for the Industries listed below. Adhesives and sealants Aluminum forming Auto and other laundries Battery manufacturing Coal mining Coil coating Copper forming Electric and electronic compounds Electroplating Explosives manufacturing Foundries Gum and wood chemicals Inorganic chemicals manufacturing rron and steel manufacturing Leather tanning and finishing Landfill Mechanical products manufacturing Nonferrous metals manufacturing MO 780-1516 (02-12) JNDUSTRY CATEGORY Ore mining Organic chemicals manufacturing Paint and ink formulation Pesticides Petroleum refining Pharmaceutical preparations Photographic equipment and supplies Plastic and synthetic materials manufacturing Pfastic processing Porcelain enameling Printing and pubrishing Pulp and paperboard mills Rubber processing Soap and detergent manufacturing Steam electric power plants Textile mills Timber products processing PAGE1 Enclosure to ULNRC-06027

1.30 APPLICATION FOR DISCHARGE PERMIT FORM D-PRIMARY INDUSTRIES TABLE II NPDES # (IF ASSIGNED) j OUTFALL NUMBER M0-0098001 001 If you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to determine which of the GC/MS fractions you must te Marl< X" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals. cyanides, and total phenols. Mark "X" in column 2-B for ea pollutant you know or have reason to believe is *present. Mark "X" in column 2-C for each pollutant you believe to be absent. If you mark either columns 2-A or 2-8 for. I pollutant, yo-u must provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Complet rany st ch fo e one table (all seven pages) for each outfall. See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT A. MAXIMUM OAIL Y VALUE S. MAXIMUM 30 DAY VAJ.US C. LONG TeRM AVRG. VALUE 4.UNITS 5.1NTAKC: (op

1. POLLUTANT a.ee-C.SE*

{if availablel Of avlilflabi&J D. NO. OF AND CAS NUMBER A. TEST* UE\\IED UE\\IED A.CONCEN-B. MASS A. LONG TERM AVRG. (if availabl&) INGRE* PRE* AS-(1) (1) (1) ANAL* TRATION VALUE QUI REO seNT SENT CONCENTRAnON iZ)MAS$ CONCENTRAnON (2) MASS CONa:NTRAnON (2)MASS YSES

11)

I CONCENTRAnoN M .r~al) B. NO OF ANAL* YSES METALS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total I8J 0 0 <5.0 <0.004 1 UG/l L.BS/0 . (7440-36-9J 2M. Arsenic, Total I8J 0 0 <10 <0.008 1 UG/l LBS/D (7 440-38-2) 3M. Beryllium, 1"otal I8J 0 0 <0.5 <0.000 1 UG/L LBSID (7440-41-7} 4 4M. Cadmium, Total 181 0 0 <0.5 <0.000 1 UG/L LBS/0 (7440-43-9} 4 SM. Chromium. Total r8J 0 0 24 0.019 1 UG/L LBS/D {7440-47-3) 6M. Copper, Total 181 0 D 46 0.037 1 UG/L LBS/0 (7550..50-8) 7M. Lead, Total 121 D 0 <3.0 <0.002 1 UG/L LBS/D (7439-97-6) 8M. Mercury, Total 181 0 0 0.27 0.0002 1 UG/L LBS/D (7439-97-6) 9M. Nickel, Total I8J 0 0 15 0.012 1 UG/L LBS/D _{_7440-Q2-0) 10M. Selenium, Total [8J 0 D <5.0 <0.004 1 UG/L LBS/D (7782-49-~) i 1M. Silver, Total r8J 0 0 <0.1 <0.000 1 UG/L LBS/D _(7440-22-4} 1 12M. Thallium, Total [81 0 0 <2.0 <0.002 1 UGJL LBS/D (7 440-28-0} 13M. Zinc, Total [2l 0 0 61 0.049 1 UG/L LBS/D (7 440-66-6) 14M. Cyanide, Total 0 0 0 (57-12-5) <5.0 <0.004 1 UG/L LBS/D 15M. Phenols, 121 0 D Total <50 <0.040 1 UG/L LBS/0 DIOXIN 2,3,7,8-Tetra-I I I DESCRIBE RESliL TS ch!orodibenzo-P** 0 D 121 Dioxin (1764..01-6}_ MO 7!10.1516 (C,.W) PAGE-Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S. INTAKE (oprk1na/}

1. POLLUTANT A.

II. BE* C. BE* {if available} (ifavailabfe) ANO CAS NUMBER TeST* UEIIED LIE\\1£0 D. NO. OF A.CQNCEN-B. MASS A. LONG TERM AVRG. B. NO (if available) INGRIS-PRE* AB-j1) {1} (1) ANAl* TRAi10N VALUE OF QUI REO SENT SENT CONCENTAA'tJON (2)MAS$ CONCENTRA110N (2)MASS CONCENTRA110N (211MSS YSES ANAL* (1} (Z) YSES CONCENTRA.'tJON w.ss GCIMS FRACTION -VOLATILE COMPOUNDS 1V. Acrolein 12?,1 0 D <50 <0.40 1 UG/L LBS/0 (107-02-8) 2V. Acrylonitrile !81 0 0 <:50 <0.40 1 UG/L LBS/D (107-13-1) 3V. Benzene (71-43-2) 181 D D <5.0 <0.004 1 UG/l LBS/D 4V. Bis (Chloromethyl) t8J 0 D <10 <0.008 1 UG/L LBSJO Ether ( 542-88-1) 5V. Bromoform !81 D 0 (75--25-2) <5.0 <0.004 1 UG!l LBS/D sv. Carbon Tetrachloride ~ D 0 <5.0 <0.004 1 UG/L LBS/D (56-23-5) 7V. Chlorobem:ene 12?1 0 D <5.0 <0.004 1 UG/L LBS/0 (108-90..7} SV. Chlorodibromomethane [81 0 D <5.0 <0.004 1 UG/L LBS/0 {12~48-1} 9V. Chloroethane 181 0 0 <10 <0.008 1 UG/L LBS/0 (75-00..3) 10V. 2-Chloroethylvinyl l8l D 0 <20 <0.016 1 UG/L LBS/D Ether (110-75-8) 11V. Chloroform l8l D 0 <5.0 <0.004 1 UG/L LBS/D (67-66-3) 12V. Dichlorobromomethane 12?,1 0 0 <5.0 <0.004 1 UG/l LBS/0 {75-27*4) 13V. Dichloro-0 0 D 1 UG/L LBS/0 difluoromethane (75--71-8) 14V. 1,1-Dlchloroethane 181 D 0 <5.0 <0.004 1 UG/L LBS/0 (75-34--3) 15V. 1,2-Dichloroethane 181 0 0 <5.0 <0.004 1 UGIL LBS/0 (107-06-2) 16V.1,1-Dichloroethylene rEI 0 D <5.0 <0.004 1 UG/l LBS/0 (75-35-4) 17V. 1,2-Dichloropropane [81 0 D <5.0 <0.004 1 UG/L LBS/D {78-87-5} 18V. 1,2 -Dichloropropylene 181 0 0 <5.0** <0.004 1 UG/L LBS/D (542-75-6) 19V. Ethylbenzene 181 0 0 <5.0 <0.004 1 UG/L LBS/D {100-41-4) 20V. Methyl Bromide ~ 0 D <10 <0.008 1 UG/L LBS/D (74-83--9) 21V. Methyl Chloride lEI D 0 <10 <0.008 1 UG/L LBS/D {74-87-3) PAGE3 CONTINUE C>N MOE 4

This parameter was deleted per40 CFR, Part 122, Appendix D *

.,. This parameter is 1,3 Oichloropropylene per 40 CFR, Part 122, Appendix D. Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT I NPDES #(IF ASSIGNED} M0-0098001 I OUTFALL NUMBER 001 l

t.MARK"X" 3.EFFLUENT

1. POLLUTANT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VAlUE 4.UNITS 5.1NTAKE (Ot ANO CAS NUMBER A.

B.SE* c.ae. !if available) (il.wail4b($} TEST* t.IEVEO UE\\I'EO O.NO.OF A.CONCEN-B. MASS A. LONG TeRM AVRG. (ff available) INGRE* PRE* AB-(1) (1] (1) ANAL* TRATION VAI.UE QUIRE[) SENT SENT CONCliNTRATlON (2)MASS COt.'CENTRATlON {2)MAS$ CONCENTRATION (2)1\\11\\$$ YSES (1) [ CONCENTRATION nat' B. NO OF ANAL* YSES GC.MS FRACTION-VOLATILE COMPOUNDS (continued) 22V. Methylene Chloride 181 0 0 <5.0 <0.004 (75-09-2) 1 UG/L LBS/D 23V.1.1.2.2-Tetra-f8l 0 0 chloroethaoe (79--34-5) <5.0 <0.004 1 UG/l LBS/D 24V. Tetrachloroethyiene t8l 0 D <5.0 <0.004 (127-18-4) 1 UG/L LSS/D 25V. Toluene f8l 0 0 (108-88-3) <5.0 <0.004 1 UG/L LB$/0 26V. 1,2-Trans l'8l 0 0 Diehloroethylene (155-60-5) <5.0 <0.004 1 UG/L LBS/D 27V. 1,1,1-Tri-I8J 0 0 <5.0 chioroethane (71-55--6) <0.004 1 UG/L LBS/0 28V. 1,1,2-Tri* 181 0 D <5.0 <0.004 chloroethane {79-00*5} 1 UG/L LBS/D 29V. Trichloro-IZI D D ethylene (79-01-6} <5.0 <0.004 1 UG/L LBS/D 30V. Trichloro-IZI D 0 lluoromethane (75-69-4) 1 UG/L LBS/0 31V. Vinyt IZI 0 0 <5.0 <0.004 Chloride (75-01-4) 1 UG/L LBS/D GCJMS FRACTION -ACID COMPOUNDS 1A. 2-Chlorophenol l8l D 0 <10 <0.008 1 {95-57-8} UG/L LBS/D 2A. 2,4 Dichloro 181 0 0 phenol {120-83-2} <10. <0.008 1 UG/L lBS/D 3A. 2.4-Dimethyl 181 D 0 <10 <0.008 1 UG/L LBS/D phenol (105-67-9) 4A. 4,6-Dinitro 181 0 0 <10 <0.008 1 UG/L LBS/0 Cresol {534-52-1} SA. 2.4-Dinitro- [8l D 0 <50 <0.040 1 UG/L phenol (Si-28-5) I.BS/D SA..2-Nitrophenol 181 0 D <10 <0.008 1 UG/L LBS/D (88-75-5) 7A. 4-Nitropheno4 181 0 0 <10 <0.008 1 UG/L LBS/D (100.02-7) SA. P-Chloro-M 181 0 0 <10 <0.008 1 UGIL LBS/D Cresol (59-50-7) SA. Pentachloro-181 0 0 <10 <0.008 1 UG/L LBS/D phenol (87-86-5_ 10A.Phenol l'8l 0 0 <10 <0.008 1 UG/L LBS/D (108-952) 11A. 2,4,6-Trichloro-12] 0 0 <10 <0.008 1 UG/L LBS/0 phenol (88-06-2) ~to 7KO..I516 (()<.().!) !'AGE-l CONTINUE I)N PAGE:>

"'"' Trichlorofluoromethane has been deleted per 40 CFR, Part 122, Appendix D.

Enclosure to ULNRC-06027

CONTINUED FROM TH£ FRONT 2.MARK"X" 3.EFFLUENT

1. POLLUTANT A. MAXIMUM OAII. Y VALUE

19. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNfT:S

5. INTAKE (op'tioiUiQ A.

B. Be* C. BE* (ifavaUallle) (if available}* AND CAS NUMBER TEST* UEVI:D UEWD D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG. B. NO (if available} INGRE* PRE* AS. ANAL-QlllREO SENT SENT (1) {l}MASS (1) (2)MASS (1) (2)MASS lRATJON VALUE OF CONCENTRAnoN CONCENTRATION CONCENTRATION YSES CONC~~TlON (2! ANAL* MMiS YSES GC/MS FRAC1lON-BASEJNEUTRAL COMPOUNDS 1 B. Acenaphthene 181 0 0 (83-32-9) <10 <0.008 1 UG/l LBS/D

28. Acenaphtytene 181 0

0 <10 <0.008 (208-96-8) 1 UG/L L8S/D

38. Anthracene l8l 0

0 (120-12-7) <10 <0.008 1 UG/L LBS/D

48. Benzidine 181 0

0 {92-87*5} <100 <0.080 1 UG/L LBS/0

58. Benzo (a)

I81 0 0 <10 <0.008 Anthracene (56-55-3) 1 UG/L LBS/D

68. Benzo (a}

Pyrene (50-32-8) L8l 0 0 <10 <0.008 1 UG/L LBS/0 78.3,4 Benzofluoranthene 181 0 0 <10 <0.008 (205-99-2) 1 UGIL LBS/D

88. Benz:o (ghi) tEl 0

0 <10 <0.008 1 UG/L lBS/D Perylene (191*24-2)

98. Benzo (k}

IZI 0 0 <10 <0.008 1 UG/L LBSID Fluoranthene (207-08-9) 108. Bis (2-Chloroethoxy) IZI 0 0 <10 <0.008 1 UG/L Methane (11Hl1~1) LBS/D 118. Bis (2-Chtoroethyl) IZI 0 0 <10 <0.008 1 UG/L LBS/D Ether (111-44-4} 126. Bis (2*Chloroisopropyl) !8J 0 0 <10 <0.008 1 UG/l LBS/D Ether {39638-32*9) 138. Bis {2-Ethylhexyl) l2l 0 0 <10 <0.008 1 UG/L LBS/D Phthalate (117.S1-7} 148. 4-8romophenyl 181 0 0 <10 <0.008 1 UG/L LBS/0 Phenyl Ether (101-55-3) 159. Butyl Beru:yl 121 0 D <10 <0.008 1 UG/l LBS/D Phthalate (85-68-7) 168. 2-Chloronaphthalene t2l 0 0 <10 <0.008 1 UG/L L.BS/D (91-58-7) 178. 4-Chlorophenyl [8J 0 0 <10 <0.008 1 UG/L LBS/D Phenyl Ether (7005-72-3} 188. Chrysene [21 0 0 <10 <0.008 1 UG/L LBS/D {218-01-9} 198. Dibenzo (a.h) C8I 0 0 <10 <0.008 1 UGIL LBS/D Anthracene (53-70-3) 208. 1.2 -Dichlorobenzene fg] 0 0 <10 <0.008 1 UG/L LBS/D (95-50-1) 21 B. 1,3 -Dichlorobenzene 181 0 0 <10 <0.008 1 UG/L LBS/D (541-73-1) - 1\\10 1li!J-lSI6< (6-04) PAGES CONTINUE ON PAGE C> Enclosure to ULNRC-06027

CONTIN!JF.D FROM PAGF. 5 .I. NPDES #(IF ASSIGNED) M0-0098001 I OUTFAlL NUMBER 001 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE(

1. POLLUTANT A.

B. BE* C. BE* . (if available) (if available} D. NO. OF AND CAS NUMBER TEST* UEVEO LIEVED A.CONCEN* B. MASS A. LONG TERM AVR (if av.affable) INGRJ;. PRE* AS- {1) (1) {1) ANAL* TRATION VALUE QI.JI~EO SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MA$S CONCENTRATION (2}MASS YSES (1) CONCENTRATION 0 ptional) B. NO OF -~ ANAL-lASS YSES G GC/MS FRACTlON -BASE/NEUTRAl COMPOUNDS (continued) 228. 1, 4-0ichlorobenzene !81 0 0 <10 <0.008 1 UG/L LBS/0 (106-46-7) 238. 3. 3'-Dichlorobenzidine 181 0 0 <50 <0.040 1 UG/L LBS/D (91-94-1) 248. Dlethyl Phthalate (84--66-2} 181 0 0 <10 <0.008 1 UG/L LBS/D 258. Dimethyt Phthalate l8i 0 0 <10 <0.008 1 UG/L LBS/D (131-11-3) 266. Di-N-butyl Phthalate [8J 0 0 <10 <0.008 1 UG/L LBS/0 (84-74-2) 276. 2.4-Dinitrotoluene 181 0 0 <10 <0.008 1 UG/L LBS/0 (121-14-2) 288. 2,6-Dinitrotoluene [gj 0 0 <10 <0.008 1 UG/L LBS/0 (606-20-2) 298. Di-N-Cetyl Phthalate [gj 0 0 <10 <0.008 1 UG/L LBS/D {117-84-0) 306. i,2-Diphenylhydrazine 181 0 0 <10 <0.008 1 UG/L LBS/D {as Azobenzene) (122-66-7) 316. Fluoranthene [g) 0 0 <10 <0.008 1 UG/L LBS/0 {206-44-D) 326. Fluorene [81 0 0 <10 <0.008 1 UG/L LBS/0 (86-73-7) 338. Hexachlorobenzene [8J 0 0 <10 <0.008 1 UG/L LBS/0 (87-68-3) 348. Hexachlorobutadiene l8i 0 0 <10 <0.008 1 UG/L LBS/D (87-68-3) 358. Hexachloro-IZI 0 0 <10 <0.008 1 UG/L LBS/0 cyclopentadiene {77*47-4} 366. Hexachloroethane IZI 0 0 <10 <0.008 1 UG/L LBS/0 (67-72-1} 378. lndeno (1,2,3-c-d) l8J 0 D <10 <0.008 1 UG/L LBS/D Pyrene {193-39-5} 38B. !sophorone l8J 0 0 <10 <0.008 1 UG/L LBS/D (78-59-1} 396. Naphthalene IZI 0 0 <10 <0.008 1 UG/L LBS/D (91-20*3) 408. Nitrobenzene [8l 0 0 <10 <0.008 1 UG/L LBS/D (98-95-3) 418. N-Nftro* 1'81 0 0 <10 <0.008 1 UG/L LBS/D sodimethy!amine (62-75-9) 426. N-Nitroso I8'J 0 0 <10 <0.008 1 UGIL LBS/D N-Propylamine ( 621-84-7) MO 180-t5!6 (6-04} P GE6 A CONTJNl jE ON PAGE? Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAJL Y VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKE ('r>ptlone/)

1. POlLUTANT P~

e;e~;. C.SE-Iff available} (if available} AND CAS NUMBER TEST* l!EVE:O l.IEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVP.G. B. NO (if <Jvaflable) INGRE* PRE* Aa. {1) {1) (1i ANAL* TRATION VALUE OF QUII~EO SENT SENT CONCENTRATION {2}MASS CONCENTRATION (2}MASS CONCENTRATION (2)MASS YSES ANAL* (1} (2) YSES CONCENTRATION MASS GCIMS FRACTION-BASE/NEUTRAL COMPOUNDS (continued) 436. N-Nitro- ~ D 0 <10 <0.008 1 UG.fl LBS/D sodiphenylamlne (86-30-6) 44B. Phenanthrene ~ D 0 <10 <0.008 1 UG/L LBS/D (85..01-8) 458. Pyrene r23 0 0 <10 <0.008 1 UG/L LBS/D (129-00..0} 46B. 1,2,4-Tri ~ 0 0 chlorobenzene ( 120-82-1 } <10 <0.008 1 UG/L LBS/D GCIMS FRACTION* PESTICIDES 1P.Aidrin [J D IZI (309-00-2} 2P. a-SHC 0 0 ~ (319-84-6) 3P. !3-BHC 0 0 [gJ (319-84-6} 4P. Y*BHC 01 0 [81 (58-89-9} 5P. o-BHC D 0 181 (319-86-8} 6P. Chlordane 0 0 181 (57-74-9} 7P. 4,4'-DDT 0 0 f8l (50*29-3) 8P. 4.4'-DDE 0 0 ~ {72-55-9) 9P. 4.4'-DDO 0 D ~- (72-54-8) 1 OP. Dieldrin 0 0 181 (60-57-1) 11 P. a-Endosulfan 0 0 IZJ (115-29-7} 12P. (3-Endosultan 0 0 ~ (115-29-7) 13P. Endosulfan Sulfate 0 0 £81 (1031..07-8) 14P.Endrin 0 D 181 (72*20*8) 15P. Endrin Aldehyde 0 0 181 (7421-93-4) 16P. Heptachlor 0 0 £81 (76-44-8) MO 7&G-b 16 (tHl4) PAGE7 CONTINUED ON rAGE:; Enclosure to ULNRC-06027

CONTINIJED FROM PAGF.. 7 l NPOES #{IF ASSfGNED) M0-0098001 l OUTFALL NUMBER 001

2. MARK "X" 3.EFFLUENT I

A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C.LONG TERM AVRG. VALUE

4. UNIT~;

5.1NTAKE{

1. PQLLUT ANT A.

B. BE* C. BE-(if available} (if available} AND CAS NUMBER TEST* LIEVEO LIEVED D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVR (if available) INGRE* PRE* AB-(1) {1) (1) ANAL* TRATION VALUE ouuu:o SENT SENT CONCENTRATION (2}MASS CONCENTRATION {2)MASS CONCENTRATION (2)MASS YSES {1) CONCENTRATION G. 1tional) B. NO OF '(2') ANAL* lASS YSES GCIMS FRACTION - PESTICISES (continued) 17P. Heptachlor D 0 I8J Epoxide (1024-57-3) 18P. PCB-1242 0 0 I8J (53469-21-9} 19P. PBC-1254 0 0 [2J (11097-69-1) 20P. PCB-1221 0 0 181 (11104-28-2) 21P. PCB-'1232 0 0 181 I (11141-16-5) 22P. PCB-'!248 0 0 181 (12672-29-6) 23P. PCB-1260 0 0 [81 (11096-82-5} 24P. PCB-1016 0 0 [81 (12674-11-2} 25P. Toxaphene 0 0 [8J (800'1-35-2) l MO 780-1516 (6-04) P GE8 A Enclosure to ULNRC-06027

1.30 APPLICATION FOR DISCHARGE PERMIT FORM D-PRIMARY INDUSTRIES TABLE II NPOES # {JF ASSIGNED) I OUTFALL NUMBER M0-0098001 002 If you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to determine which at the GCIMS fractions you must t Mark "X" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "X" in column 2-B forE~ est for. ach pollutant you know or have reason to befieve is present. Mark "X" in column 2-C fur each pollutant you believe to be absent. If you mark either columns 2-A or 2-pollutant. you must provide the results of at least one analysis for that pollutant Note that there are seven pages to this part, please review each carefully. Compl 8.for any table (a// seven pages) for each outfall. See instructions fur additional details and requirements. !te one 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VAlUE C. LONGTERMAVRG. VALUE 4.UNIT$ 5.1NTAKE(

1. POLLUTANT B. BE-c.ae-(If available\\

(if available} D. NO. OF AND CAS NUMBER A. TEST* LIEVED LIE.VED A.CONCEN* B. MASS A. LONG TERM AVR (if available) tNGRE-PRE* AS-(1) ANAL* TRATION VALUE QUIRED SENT SENT (1) (2} MASS {2)MASS (1) (2)MASS YSES CONCENTRATIOH CONCENTRATION CONCENTRATION (1) CONCENTRATION METALS1 CYANIDE, AND TOTAL PHENOlS ptional) B. NO OF

-w-ANAL*

lJlASS YSES 0 1M. Antimony, Total 0 0 l25l <5.0 <0.14 1 UG/L LBS/D (7 440-36-9) 2M. Arsenic, Total 0 ~ 0 10 0.29 1 UG/L LBS/0 (7440~38-2) 3M. Beryllium, Total 0 0 l25l <0.5 <0.014 1 UG/L LBS/D (7440-41-7) 4M. Cadmium. Total 0 0 I8J <0.5 <0.014 1 UG/L LBS/0 {7440-43-9) 5M. Chromium, Total 0 0 181 <10 <0.29 1 UG/L LBS/D (7 440-4 7-3) 6M. Copper. Total 0 ~ 0 33 0.95 1 UG/1. LBS/0 {7550-50-8} 7M. Lead, Total 0 I2?J 0 3.0 0.087 1 UG/L LBS/D {7439-97-6) SM. Mercury, Total 0 0 ~ <0.2 <0.006 1 UG/L LBS/0 (7439-97-6) 9M. Nickel, Total 0 181 0 12 0.35 1 UG/L LBS/0 {7 440-02-0) 10M. Selenium, Total 0 [8] 0 5.5 0.16 1 UG/L LBS/D (7782-49-2) 11M. Silver, Total 0 [8] 0 0.13 0.0037 1 UG/L LBS/D {7 440-22-4) 12M. Thallium, Tota! 0 0 [8] <2.0 <0.058 1 UG/L LBS/D (7 440-28-0) 13M. Zinc, Total 0 [8l 0 18 0.52 1 UG/L LBS/0 (7 440-66-6} 14M. Cyanide, Total 0 0 1:81 (57-12-5) 15M. Phenols. 0 0 ~ Total DIOXIN 2,3,7,8-Tetra-I I I DESCRIBE RESULTS chlorodibenzo-P-0 0 [8l Dioxin {1764-01--6} M0780.15i6(6-D4) G ') PA E. Enclosure to ULNRC-06027

CONTlNUED FROM PAGE 3 2.MAAK"X" 3.E:FFLUEf\\rr A. MAXIMUM OAILY VALUE B. MAXIMUM 30 DAY VALUE C.l.ONG TERM AVRG. VAlUE

4. UNITS S.INTAKE (Qptional)

1. POtLUT ANT

/4,.

e. BE*

c.ee. lif available) (if available} AND CAS NUMBER TEST* LlEVEO UEVEO O.NO.OF A.CONCEN-B. MASS A. t.ONG TERM AVR<;i. B. NO {If available) INGRE. PRE* AS* (1) (1j {1) ANAl.* TRATION VALUE OF QOIREO SENT SENT (2)MA$S (2)MASS (2)MAS$ YSES CONCENTRATION COOCENTRA'TlON CONCENTRATION (1) -~ ANAL-CONCENTAA'TlON MASS YSES GC/MS fRACTION*- VOLATilE COMPOUNDS 1V. Acrolein 0 0 0 (107-02-8) 2V. Acrylonitrile 0 0 § (107-13-1) 3V. Benzene 0 0 IZI (71-43-2) 4V. Bis (Chioromethyf) 0 0 IZI Ether (542-88-1) 5V. Bromoform 0 0 l8l (75-25-2) 6V. Carbon Tetrachloride 0 0 181 (5$-23-5) 7V. Chlorobenzene D 0 121 (108-90-7) 8V. Chlorodibromomethane 0 0 [8) (124-48-1) 9V. Chloroethane 0 0 l8l (75-00-3) 10V. 2-Ghloroethylvinyl 0 0 l8l Ether (110~75-S) 11V. Chloroform 0 0 t8l (67-66-3) 12V. Dichlorobromomethane 0 0 [gl (75-27-4) 13V. Dichloro-D 0 181 difluoromethane (75*71-8) 14V. 1,1-Dichloroethane D 0 [<J (75-34-3) 15V. 1,2 - Dichroroethane 0 0 ~ (107*06-2) 16V. 1,1-Dichloroethylene 0 0 ~ {75~35-4) 17V. 1,2 - Dichloropropane D 0 181 {78-87-5) 18V. 1.2 -Dlchloropropylene 0 0 lZl (542*75-6} 19V. Ethylbenzene 0 0 181 (100-41-4} 20V. Methyl Bromide 0 0 IZI {74-83-9) 21V. Methyl Chloride 0 D [83 (74-87-3) MO 780-l:.16 (6-04) PAGE3 CONTI!' UEONPA 4 Enclosure to ULNRC-06027

I NPOES #(IF ASSIGNED) I OUTFALL NUMBER l CONTINUED FROM THE FRONT M0-0098001 002 2.MARK"X" 3.EFFLUENT A. MAXIMUM OAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKEto 1.POtLUTANT A. B. BE* C. BE* (If available) (if availsbl&) AND CAS NUMBER TEST* LIEVEO LIEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRI:7 {if availabte) lNGRE* PRE* AB-(1} (1) (1} ANAL* TRATION VALUE QUIREO SENT SENT CONCENTRATION (2)MASS CONCENTRATION !'!)MASS CONCEtffRATION (2)MASS YSES (1) CONCENTRATION plionai) B. NO OF "'('2')' ANAL* lASS YSES GC.MS FRACTION-VOLATILE: COMPOUNDS (continued) 22V. Methylene Chloride 0 0 181 (75-09-2) 23V. 1,1,2,2-Tetra-0 0 ~ chloroethane (79-34~5) 24V. Tetrachloroethylene 0 D 181 (127-18-4} 25V. Toluene 0 0 181 (108-88-3) 26V. 1,2-Trans 0 0 [21 Dichloroethylene (156-60-5) ') 27V.1,1,1-Tri-0 0 181 chloroethane {71-55-6) 2BV. 1,1,2-Tri-0 0 181 chloroethane {79-00-5} 29V. Trichloro-D 0 ~ ethylene (79-01-6} 30V. Trichloro-D D 181 fluoromethane (75-69-4) 31V. Vinyl 0 D 181 Chloride {75-01-4} GC/MS FRACTION-ACID COMPOUNDS 1 A. 2 - Chlorophenol 0 0 181 (95-57-8) 2A. 2.4 - Dichloro-0 0 [gl phenol {120-83-2) 3A. 2.4 - Dimethyl - D 0 181 phenol (105-67-9) 4A. 4.6-Dinitro- 0* 0 D ~ Cresol {534-52-1) 5A. 2.4-Dinitro - 0 0 ~ phenol {51-28-5) 6A. 2-Nitrophenol 0 0 [8J (88-75-5) 7A. 4-Nitrophenol 0 0 181 (100*02*7) 8A. P - Chloro - M 0 0 [8J Cresol (59-50-7) 9A. Pentachloro - D D 181 phenol (87-86-5 10A. Phenol 0 0 I.8J (108-952) 11A. 2,4,6 - Trich!oro-0 0 181 phenol (88*06-2} MO 7$0-1516 (6*04) PAGF.4 CONT!Nll EON PAGE:> Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAIL V VALUE B. MAXIMUM 30 DAY VAlUE C. lONG TERM AIJRG. VALUE 4.UNITS 5.1NTAKE (optlonai)

1. POLLUTANT A.

e.ae-C.&* (if available} (if avat7able) Al\\!0 CAS NUMBER TEST* UE\\IEO LIEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG. B. NO {if avail<~biEJ) INGRe* PRE* ~ {1) {1) (1) ANAL* TRATION VALUE OF QUIRF.O SENT SENT CONCENTRATION {:>:)MASS CONCENTRATION (.2)MASS CONCENTRATION (2)JMSS YSES

-m-ANAL*

(1) YSES CONCENTRATION IAASS GC/MS FRACTION - BASFJNEUTRAL COMPOUNDS

18. Acenaphthene 0

0 r&1 (83-32-9)

28. Acenaphtylene 0

0 l8l (208-96-8)

36. Anthracene 0

0 r&1 (120-12-7)

48. Benzidine 0

0 f8i (92-87-5) SB. Benzo (a) 0 0 r&1 Anthracene {56-55-3)

68. Benzo (a}

0 0 121 Pyrene (50-32*8)

78. 3.4 - Benzotluoranthene 0

0 (g) (205-99-2)

88. 8enzo (ghi}

0 0 r&1 Peryrene (191-24-2)

98. Benzo (k)

D 0 £81 Fluoranthene (207-08-9) 1 OB. Sis (2-Chloroethoxy) 0 0 181 Methane {111-91-1) 11 B. Bis (2-Chloroethyl) 0 0 181 Ether ( 111-44-4) 128. Bis {2-Chloroisopropyl} D 0 r&1 Ether (39638-32-9) 13B. Bis {2~Ethy1hexyl) 0 0 (81 Phthalate (117-81-7) 14B. 4-Bromophenyl 0 0 r&1 Phenyl Ether(101*55-3) 158. Butyl Benzyl 0 0 [81 Phthalate (85-68-7) 166. 2-Chloronaphthalene 0 0 l81 {91-58-7) 178. 4-Chlorophenyl D 0 121 Phenyl Ether (7005-72-3) i8B. Chrysene 0 0 ~ {218-Q1-9} 196. Dibenzo {a.h} 0 0 (81 Anthracene (53-70-3} 2013. 1.2 - Dichlorobenzene 0 0 (8} {95-50-i) 218. 1,3 - Dichlorobenzene D 0 r&1 (541-73-1) MO 780-1516 (6*0.:1} PAGES CO IT NlJE ON ?A E Nl G 6 Enclosure to ULNRC-06027

CONTINHF.D FROM PAGD<: 5 l NPDES # (IF ASSIGNED) M0-0098001 I OUTFALl NUMBER 002 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.INTAKEl

1. POLLUTANT A.

B. BE* C. BE-(if available) (if avaiiable) AND CAS NUMBER TEST* LIEVEO LIEVED D. NO. OF A.COHCEN* B. MASS A. LONG TERM AVR~; (if available) INGR£. PRE* AS-(1) {1) (1) ANAL* TRATION VALUE QUIRED SENT SENT CONCENTRATIOf4 (2)MASS CONCENTAATION {2}MASS CONCEHTRATIOf4 (2)MASS YSES {1) COf4CENTRATION 0: ptionat) B. NO OF '12')"' ANAt* lASS vses GCJMS FRACTION-BASE/NEUTRAL COMPOUNDS (continued) 228. 1, 4-Dichlorobenzene 0 0 (gl (106-46-7} 238. 3. 3'-Dichlorobenzidine 0 0 [81 (91-94-1) 248. Diethyl Phthalate 0 0 [81 (84--66-2) 256. Dimethyl Phthalate 0 0 (gl (131-11-3) 268. Di-N-butyl Phthalate 0 0 1.8] (84-74-2) 278. 2,4-Dinltrotoluene 0 0 r8'l {121-14-2) 288. 2,6-Dinitroto!uene 0 0 181 (606-20-2) 29B. Di-N*Octyl Phthalate D 0 [8] {117-84-Q) 308. 1,2-Diphenylhydrazine 0 0 [81 (as Azobenzene) (122-66-7) 318. Fluoranthene 0 0 181 (206-44..(1) 326. Fluorene 0 0 181 (86*73-7) 338. Hexachlorobenzene D 0 [81 (87-68-3) 348. Hexachlorobutadiene 0 0 181 {87-68-3} 35B. Hexachloro-0 0 181 cyc!opentadiene {77 *47 -4} 368. Hexachloroethane 0 0 IZI (67-72-1) 378. lndeno (1,2,3~c-d) 0 0 IZl Pyrene (193-39-5) 386. Jsophorone 0 0 ~ {78-59-1) 396. Naphthalene 0 0 l8l (91-20-3) 408. Nitrobenzene 0 0 ~ (98-95-3) 41 B. N*Nitro-0 0 ~ sodimethylamine {62-75-9) 428. N*Nitroso 0 0 l8l N-Propylamine {621-64-7) E6 CONTI NV M07SO.l516{6.()4} PAG EON PAGE? Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X"

3. EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VAlUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE (optional)

1. POlLUTANT A.

a.m:;. C. BE* (If available) (if available} AND CAS NUMBER TEST* LIEVEO UE\\IED D. NO. OF A.COt.ICEN* B. MASS A. LONG TERM AVRG. B. NO {If available) INGRE-PRE* .A8-(1} (1) (1) ANAL* TRATION VAlUE OF QUIRED SENT SENT COiiCE:NTRATtON {l}W.SS CONCEN'MATION (2)MASS CONCENTRATION (2)MASS YSES ANAL* (1) {2) YSES CONCENTRATION I.tASS GC/MS FRACTION-SASE/NEUTRAL COMPOUNDS (continued) 438. N-Nitro-0 0 IZJ sodiphenylamine (86-30-6) 44Ei. Phenanthrene 0 0 ~ (85.01-8) 45B. Pyrene 0 0 l8l (129-00-0) 468. 1,2,4-Tri 0 0 l8l chlorobenzene { 120-82-1) GCIMS FRACTION M PESTICIDE:$ 1P. Aldrin 0 0 t8i (309-00-2) 2P. Q.BHC 0 0 ~ (319-84-6) 3P.13-BHC 0 0 l8l (319-84-6) 4P. y-BHC 0 0 iZI (58-89-9) ~ SP.o-BHC 0 0 iZI (319-86-8) 6P. Chlordane D ~ 0 X (57-74-9) ?P. 4,4'-DDT 0 0 183 {50-29-3) SP. 4,4'-DDE 0 0 183 (72-55*9) 9P. 4.4'-DDD 0 0 ~ (72-54-8) 10P. Dieldrin 0 0 ~ (60-57-1) 11 P. a-Endosulfan 0 0 ~ (115-29-7} 12P. 1)-Endosultan 0 0 l2?J {115-29-7) 13P. Endosulfan Sulfate 0 0 1:81 (1031-07-8) 14P.Endrin 0 0 l8l (72-20-8} 15P. Endrin Aldehyde 0 0 !ZI (7 421-93-4} 16P. Heptachlor 0 0 1:81 {76-44*8) MO 780-1516 {6-04) PAGE 7 <J~ CONTINUED ON PAG~ 3 Enclosure to ULNRC-06027

(;ONTINIJRD FROM PAGE 7 1 NPDES #{IF ASS/GNE!D) I OUTFALL NUMBER M0-0098001 002 2.MARK"X" 3, EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.lNTAKE(o

i. POLlUTANT A.

a. BE*

C. BE* Jif available* (if availabl&) D. NO. OF AND CAS NUMBER TEST* UEVE!> LIE \\'ED A..CONCEN* B. MASS A. LONG TERM AVRG {if available) INGRE* PRE* A£1. (1) (1} (1) ANAl~ TRAT!ON VALUE QUIREO SEN! SENT CONCENTRATION (2)MAS$ CONCENTRATION (2}MASS CONCENTRATION (2)MASS YSES (1) CONCENTRATION ptional) B. NO OF

~ ANAL-lllASS YSES GCIMS FRACTION-PESTICtSES (continued) 17P. Heptachlor 0

0 181 Epoxide {1024-57-3) 18P. PCB~1242 0 0 181 {53469-21-9) 19P. PBC-1254 0 0 IZJ (11097-69-1} 20P. PCB-1221 0 0 181 (11104-28*2} 21P. PCB-1232 0 0 IZJ {11141-16*5) 22P. PCB-1248 0 0 IZJ {12672-29-6) 23P. PCB-1260 0 0 181 (11096-$2-5} 24P. PCB-1016 0 0 181 (1267 4-11-2) 25P.Toxaphene 0 0 IZI (8001-35-2) MO 7S0-15l6 (6-04) PAGES Enclosure to ULNRC-06027

APPLICATION FOR DISCHARGE PERMIT FORM 0- PRIMARY INDUSTRIES TABLE II NPDES # (/F ASSIGNED) I OUTFALL NUMBER M0-0098001 003 1.30 If you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to detennine which of the GC/MS fractions you must test fl,r. Mark ~x" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "Xn in,column 2-B for each pollutant you know or have reason to believe is present. Mark "X" in column 2-C for each pollutant you believe to be absent. If you mark either columns 2-A or 2-B for any pollutant, you must provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. CompJete ant~ table (all seven pages) for each outfall. See instructions for additional details and requirements.

2. MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 6.JNTAKE (optiOnnl)

1. POLLUTANT B. BE*

c.ae. _111 avai~bl&) (ifwallab/11) D. NO. OF AND CAS NUMBER A. TEST* uel/£0 UEVEb A.CONCEN-B. MA.')S A. LONG TERM AVRG. B. NO (Jf wlikilable) INORS-PRE* AS. {t) (1) (1) ANAL* TRAliON VALUE OF QUI REO SENT SENT CONCENTftATION (2)MASS CONCENTRATION (2lt.!ASS CONCEN'I'RAnOH l2)MASS VSES ANAL* (1) (2~ VSES CONCENTRAnON MAsS METALS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total ~ 0 0 <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 1 {7440-36-9) 2M. Arsenic. Total ~ 0 0 <10 <0.001 1 UG/L LBS/D 15 1.4 1 . {7 440-38-~ 3M. Beryllium. Total ~ 0 0 <0.5 <0.001 1 UGIL LBS/D 1.4 0.13 1 (7440-41-7) 4M. Cadmium, Total ~~ 0 0 <0.5 <0.001 1 UG/L LBS/0 0.81 0.077 1 (7 440-43-9) 5M. Chromium, Total ~ 0 0 <10 <0.001 1 UG/L LBS/D 40 3.8 1 (7440-47-3) 6M. Copper, Total 181 0 D 5.5 0.0007 1 UG/L LBS/D 30 2.8 1 (7550-50-8} 7M. Lead, Total ~ 0 D c:3.0 <0.001 1 UG/L LBSID 22 2.1 1 {7439-97-6) SM. Mercury, Total ~ 0 0 <0.2 <0.001 1 UG/L LBS/0 <0.2 <0.01 1 {7 439-97 -6) 9 9M. Nickel, Total l8l 0 0 <5.0 <0.001 1 UG/L LBS/D 39 3.7 1 (7 440-02-0) 1OM. Sefenium. Total 181 0 0 <5.0 <0.001 1 UG/L LBS/D 5.1 0.48 1 {7782-49-2) 11M. Silver. Total f2:l D 0 0.34 0.0000 1 UGIL LBS/D 0.21 0.020 1 {7440-22-4) 4 12M. Thalfium, Total [2] 0 0 <2.0 <0.001 1 UGIL LBS/0 0.92 0.087 1 (7440-28-0) 13M. Zinc, Total [2] 0 0 3.6 0.0043 1 UG/L LB$/D 110 10 1 (7440*6~6) 14M. Cyanide, Total ~l 0 0 <5.0 <0.001 (57~12-5) 1 UG/L LBS/D <5.0 <0.47 1 15M. Phenols, [81 0 0 <50 <:0.006 Total 1 UG/L LBS/D c:SO <4,7 DIOXIN 2,3,7,8-Tetra-I I ~ I DESCRIBE RESULTS chlorodibenzo-P-0 D Dioxin (1764-01-6} 0 PA E2 Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3

2. MARK"X" 3.EFFLUENT A. MAXIMUM OAIL Y VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS S.INTAKE (oplior.al)

1. POLLUTANT A.

B. BE* c.ae-lilavaifablel (ifavailablei AND CAS NUMBER TEST* UEVEO UEVEO D. NO. OF A.CONCCN* B. MASS A. LONG TERM A\\IRG. B.. NO (if available) INGRE* PRE* AB- {1) {1)

11)

ANAl.* TRATION VALUE OF Ql.IIRED SE~ SENT CONCENTRATION (2)MASS CONCENTRAilON (2)14ASS CONCENTRA110N (2)MASS YSES ANAL* {t) 121 YSES CONCENTRATION MASS GCIMS FRACTION-VOLAnLE COMPOUNDS 1V. Acrolein IE! 0 0 <50 <0.006 1 UG/L LBS/0 <50 <4.7 1 (107-02-8) 2V. Acrylonitrile £81 0 0 <50 <0.006 1 UG/L LBS/0 <50 <4.7 1 (107-13-1) 3V. Benzene 181 0 0 <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 1 (71-43-2) 4V. Bis (Chlorometh.)li) ~' 1 UG/L LBS/D <10 <0.95 1 Ether (542*8S..1) £81 0 0 <10 <0.001 5V. Bromoform 181 0 0 <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 1 (75-25-2} sv. Carbon Tetrachloride I8J D 0 <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 1 (56-23-5) 7V. Chlorobenzene [8J 0 D <5.0 <0.001 1 UG/l LBS/D <5.0 <0.47 1 (108-90-7) 8V. Chlorodibromomethane t2l 0 0 <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 1 {124-4S..1) 9V. Chloroethane l8l 0 0 <10 <0.001 1 UG/l LBS/D <10 <0.9!) 1 {75-00-3) 10V. 2-Chloroethylvinyl [8J D 0 <5.0 <0.001 1 UG/L LBSID <5.0 <0.47 1 Ether (110-75-8) 11V. Chloroform r81 0 0 <5.0 <0.001 1 UG/l LBS/D <5.0 <0.4~' 1 (67-66-3} 12V. Dichlorobromomelhane l8l D 0 <5.0 <0.001 1 UG/L LB$/D <5.0' <0.4i' 1 {75-27-4) 13V. Dichloro-0 0 0 1 UG/L LBS/D 1 difluoromethane (75-71-8) 14V. 1,1 - Dichloroethane [8J D 0 <5.0 <0.001 1 UG/L LBS/0 <5.0 <0.47 1 (75-34-3} 15V. 1,2 - Dichloroethane [8J D D <5.0 <0.001 1 UG!L LBS/D <5.0 <0.47 1 (107-\\io-2) 16V. 1,1 - Dichloroethylene 123 0 0 <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 1 {75-35-4} 17V. 1,2-Dichloropropane l8l 0 0 <5.0 <0.001 1 UG/l LBS/D <5.0 <0.47 1 (78-87-5) 18V. 1,2 -Dichloropropylene t2J D 0 <5.0** <0.001 1 UG/l LBS/0 <5.0** <0.47 1 (542-75-6) 19V. Eth~benzene [8J 0 D <5.0 <0.001 1 UG/L LBS/0 <5.0 <0.47 1 (100-41-4) 20V. Methyl Bromide [8J 0 0 <10 <0.001 1 UG/L LBS/D <10 <0.95 1 (74-83-9) 21V. Methyl Chloride [8J 0 0 <10 <0,001 1 UG/L LBS/D <10 <0.95 1 (74-87-3) MO nm-1.:>16 ((r{>-1) PAGE3 CONTINUE ON PAGE 4

This parameter was deleted per 40 CFR. Part 122, Appendix D.
- This parameter is 1,3 Diehloropropylene per 40 CFR, Part 122. Appendix D.

Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT I NPDES # (IF ASSIGNED) M0-0098001 J OUTFALL NUMBER 003 I

2. MARK"X" 3.EFFLUENT A. MAXIMUM DAII.. Y VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS

6. INTAKE (optional)

1. POU.UTANT A.

8.8E* C. BE-fit.waJiablel {if ava11ablel AND CAS NUMBER lSST* UIM:I> UE\\IEO D. NO. OF A.CONCEN-B. MAS$ A. LONG TERM AVRG. B. NO (if av:lilabht) INGRE. PRE* AB-m 11> (1) ANAL-TRA110N VALUE OF QIJIRECI SENT SENT CONCENTRATION (2)MASS CONCEM'RA'OON (ZIIIASS CONCENTRATION C2)MASS YSES ANAL* (11 (2) YSES CONCEM'RATION MASS GC.MS FRACnON -VOLATILE COMPOUNDS (continued) 22V. Methylene Chloride ~ 0 D <5.0 <0.001 1 UG/L LBS/0 <5.0 <0.47 (75-09-2) 1 23V. 1,1,2,2-Tetra-(gJ D D <5.0 <0.001 chloroethane (79-34-5) 1 UG/L LBS/0 <5.0 <0.47 1 24V. Tetrachloroethylene I:2J D 0 <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 {127-18-4} 1 25V. Toluene 18J 0 0 <5.0 <0.001 (108-88-3} 1 UG/L LBS/D <5.0 <0.47 1 26V. 1,2 -Trans 18] 0 D <5.0 <0.001 1 UG/L LBSIO Dichloroothy!ene ( 156-60..5) <5.0 <0.47 _1 27V.1,1,1-Tri-l8l 0 D <5.0 <0.001 1 UG/L LBS/D <5.0 chloroethane (71-55--6) <0.47 1 28V. 1,1,2-Tri-l8l 0 D <5.0 <0.001 1 UG/L LBS/D <5.0 <0.47 chioroothane {79-.00..5) 1 29V. Trichloro-t8l D D <5.0 <0.001 1 UG/l LBS/D <5.0 ethylene (79-01-6) <0.47 1 30V. Trid'lloro-t81 D D 1 UG/L LBS/D fluoromethane {75-69-4) 1 31V. Vinyl £81 D 0 <5.0 <0.001 1 UG/L LBSID <5.0 <0.47 1 Chloride (75--01-4) GC/MS FRACTION -ACID COMPOUNDS 1A. 2-Chlorophenol ~ 0 D <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (95-57-8} 2A. 2.4-Dichloro-C?J 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 phenol {120..83-2) 3A. 2.4-Dimethyl- ~ 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 phenol {1 05-67-9) 4A. 4.6-Dinitro ~ 0 D <10 <0.001 1 UG/L LBS/D <11 <1.0 1 Crescl (534-52-1) 5A. 2.4-Dinitro-gJ D 0 <50 <0.006 1 UG/L LBS/D <56 <5.3 1 phenol (51-26-5} SA. 2-Nitrophenol ~ D 0 <10 <0.001 1 UG/L LBS/D <11 <1;0 1 (88-75-5) 7 A. 4-Nitrophenol ~ D 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (100..02-7) 8A. P-Chloro-M ~ 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 '1 Cresol (59-50.7) 9A. Pentachloro- ~ 0 D <10 <0.001 1 UGJL LBS/D <11 <1.0 '1 phenol {87-86-5_ 10A.Phenol ~ 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 'I (108-952) 11A. 2,4,6 - Trichloro- ~ D D <10 <0.001 1 UG/L LBS/D <11 <1.0

t phenol {88-06-2}

PAGE-l CONTINUE ON I ACJE. 5

"* Trichloroffuoromethane has been deleted per40 CFR. Part 122. Appendix D.

Enclosure to ULNRC-06027

CONTINUED FR0!\\1 THE FRONT

2..MARK"X

3. EFFLUENT A. MAXIMUM DAitYVAl.UE

8. MAXIMt.JM 3{1 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS

&.INTAKE (optiomtf)

1. POLLUTANT A.

e.aE-c.ae. (if available) (if available) AND CAS NUMBER TEST-UEVEO UE\\IED D. NO. OF A. CONCEN* B. MASS A. LONG TERM AVRG. B. NO {if avsilabla) JNGRE-PRE* AB-m (1) (1) ANAL* TRATlON VALUE OF QUI RED SENT SENT CONCEHTRAnON (2)MASS COHCENTRA'I'ION (%)MAS$ CONCENTRAnON {Z)MASS YSES ANAL* (11 (2:) YSES CONCENTRAnON MASS - GC/MS FRACTION-BASEJNI:UTRAL COMPOUNDS

16. Acenaphthene fgl 0

0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (83-32-9) 2B. A<:enaphtylene 12l 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (208-96-8)

38. Anthracene 181 0

0 <10 <0.001 (120..12-7) 1 UG/L LBS/D <11 <1.0 1 4B. Benzidine 18] 0 D <100 <0.012 1 UG/L LBS/D <110 <10 1 (92-87-5)

58. Benzo {a)

(gl 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 Anthracene (56-55--3)

58. 6enz.o (a}

181 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 Pyrene (50-32*8) 7B. 3.4-Benzonuoranthene 181 D 0 <10 <0.001 1 UG/l LBS/D <:11 <1.0 1 (205-99--2)

88. Benzo (ghi)

~ 0 0 <10 <0.001 1 UG/l LBS/D <11 <1.0 1 Perytene (191-24-2)

98. Benzo (k) 181 0

0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 Fluoranthene (207-08-9} 108. Bis (2-Chloroethoxy) E8l D 0 <10 <0.001 1 UG/l LBS/D <11 <1.0 1 Methane {111*91~1) 118. Bis (2-Chloroethyl} [gJ 0 0 <0.001 1 UG/L LB$/0 <11 <1.0 1 Ether (111*44-4) <10 126. Sis (2-Chloroisopropyf) 181 0 D <10 <0.001 1 UG/l LBS/0 <11 <1.0 1 Ether (39638-32*9} 138. Sis (2-Ethylhexyl) ~ 0 0 <10 <0.001 1 UG/L LSS/D <11 <1.0 1 Phlhalate (117-81-7) 148. 4-Bromophenyl 12] 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 Phenyl Ether {1 01-55-3) 156. Butyl Benzyl l8J 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 Phthalate {85-68-7) 168. 2-Chloronaphthalene t8l D 0 <10 <0;001 1 UG/L LBSJD <11 <1.0 1 (91-SS-7) 178. 4-Chlorophenyl [8j 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 Phenyl Ether (7005-72-3) 188. Chrysene t8l 0 0 <10 <0.001 1 UG/L LBS!D <11 <1.0 1 (218-01-9) 198. Dibenzo (a.h) t8l 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 Anthracene (53-70..3) 208. 1,2-Dichlorobenzene t2l 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 (95-50..1) 218. 1,3-Dichlorobenzene 181 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 I (541-73.1} CONTINUE ON MGE 1, MO :nw-bl<> ((,...(~) PAvc5 Enclosure to ULNRC-06027

CONTINHF:r> fROM PAGF. 5 I NPDES #(IF ASSIGNED) M0-0098001 I OUTFALL NUMBER 003 2.MARK"X" l.EFFLUENT A. MAXIMUM DAlL V VAlUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS

5. li'ITAKE (OPiional)

1. POlLUTANT A.

6.6E-C. BE-lif availabJe) {if available) D. NO. OF AND CAS NUMBER TEST* L.IEVEO LIEVED A.CONCEN* B. MASS A. LONG TERM AVRG. B. NO (If availabfe) INGRE* PRE* AS-(1} (1) {1} ANAL* TRATION VALUE OF Ql.IIREP SENT SENT CONCENTRATION [2)MASS CONCENTRATION (2:)MASS CONCENTRATION (~)~ YSES c:~ ANAL* (1) YSES CONCENTRATION MftSS GCIMS FRACTION - BASEJNEUTRAL. COMPOUNDS (continued) 226. 1, 4-Dichtorobenzene f8J 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (106-46-7) 23B. 3, 3'-Dichlorobenzldine ~ 0 0 <50 <0.006 (91-94-1) 1 UG/L LBS/0 <56 <5.3 1 24B. Oiethyl Phthalate (81 0 0 <10 <0.001 1 UG/L LBS/0 <11

~1.0 1

(84-66-2) 258. Dimethyl Phthalate [81 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 (131-11-3) 26B. Di-N-butyl Phthalate rgj 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 (84-74-:2) 278. 2.4-Dinitrotoluene l8l 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (121-14-2) 288. 2,6-0initroto!uene l8l 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (606*20~2) 29B. Di*N-Octyl Phthalate ~ 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 (117-84-0) 30B. 1,2-Diphenylhydrazine ~ 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (as Azobenzene) (122-66-7) 316. Fluoranthene ~ 0 0 <10 <0.001 1 UG/L LBS/D <11 <:1.r0 1 (206-44-0) 32B. Fluorene ~ 0 0 <10 <0.001 1 UG/L LBS/D <11 <:1.0 1 {86-73-7) 338. Hexachforobenzene 12$] 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 {87-68-3) 348. Hexachlorobutadiene IZI 0 0 <10 <0.001 1 UGIL LBS/D <11 <1.0 1 (87-68-3) 358. Hexachloro-IZJ 0 0 <10 <0.001 1 UG/l LBS/0 <11 <1.0 1 cyclopentadiene (77-47-4) 368. Hexachloroethane IZI 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 (67-72-1) 378. lndeno (1,2,3-c-d} 181 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 Pyrene (193*39-5) 388. lsophorone 181 0 0 <10 <0.001 1 UG/L lBS/D <11 <1.0 1 (78-59-1) 398. Naphthalene l8l D 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 (91-20-3} 406. Nitrobenzene l8l 0 0 <10 <0.001 1 UG/l LBS/0 <11 <::1.0 1 (98-95-3) 41B. N-Nitro- [81 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 sodimethylamine (62-75-9) 428. N*Nitroso r8l 0 0 <10 <0.001 1 UG/L LBS/0 <11 <1.0 1 N-Propylamine (621-64-7} MO tS0-1516(6-04) P GE6 A CONTINUE ON PAGE ':l' Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X" J.EFFLUE:NT A. MAXIMUM DAILY VALUE

8. MAXIMUM 30 DAY VALUE C. lONG TERM AVRG. VALUE 4.UNITS

5. INTAKE (;':Jptional)

1. POLLUTANT A.

B. BE* c.ae-(If available) (if available} ANO CAS NUMBER TEST* UEVED LIEVED D. NO. OF A.CONCEN-B.I\\AASS A. LONG TERM AVR(;. B. NO (if available} INGflE* PRE* AS-(1) (1) (1) ANAl* TRATION VALUE OF QIJIREO SENT SENT CONCENTRATION (2)1.fASS CONCENTRATION (2)MASS CONCENTRATIOH (2)MASS YSES -~ ANAL* (1) YSES CONCENTRATION MASS GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS (continued) 438. N-Nitro* sodiphenyiamine (86-30*6) 181 0 0 <10 <0.001 1 UG/l LBS/D <11

~1.0 1

448. Phenanthrene ~ {85-Di*B} 1:81 0 0 <10 <0.001 1 UG/l LBS/D <11 <1.0 1 4SB. Pyrene (129-00-Q) l2J 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 468. 1-.2.4-Tri chlorabenzene { 120-82-1) l8l 0 0 <10 <0.001 1 UG/L LBS/D <11 <1.0 1 GC/MS FRACTION

PESTICIDES 1P. A!drin

{309-00-2) 0 0 l8l 2P. o:SHC (319-84-6) 0 0 I8J 3P. 13-BHC {319*84-6) 0 0 l2J 4P. y-BHC 0 0 I8J (58-89-9) 5P. 5*8HC 0 0 t8J (319-86-8) 6P. Chlordane 0 I8J 0 X (57-74-9} 7P. 4.4'*DDT 0 0 I8J {50-29-3} 8P. 4,4'*DDE 0 0 [81 (72-55-9) 9P. 4.4'-DDD 0 0 l2J {72-54-S) 1 OP. Dieldrin 0 0 ~ (60-57-1} 11P. a*Endosulfan 0 0 (gl (115*29*7) 12P. ~Endosultan 0 0 [81 (115-29~7) 13P. Endosulfan Sulfate D 0 I8J (1031-{)7~8} 14P.Endrin 0 D l2J (72-20*8) 15P. Endrin Aldehyde 0 0 I8J (7 421*93*4) 16P. Heptachlor 0 0 I8J (76-44-8) MO 7&0-1516 (6*04) PAGE7 CONTINUED ON P.'\\GE ~: Enclosure to ULNRC-06027

C.ONTrMJF.D FROM PAGE 7 2.MARK"X"

1. POLLUTANT A.

e. as-C. BE*

AND CAS NUMBER TEST* LIEVED ueveo (If available) INGRE* PRE* AS-QUIRED SENT SENT GCIMS FRACTION-PESTICISES (continued) 17P. Heptachlor I Epoxide (1024~57-3) 0 0 181 18P. PCB-1242 0 0 181 (53469-21-9) 19P. PBC-1254 0 0 [gf (11097-69-1) 20P. PCB-1221 0 0 [8] ( 11104-28-2) 21P. PCB-1232 0 0 [8J ( 11141-16-5) 22P. PCS-1248 0 0 [83 {12672-29*8) 23P. PCB-1260 0 0 181 (11096-82-5) 24P. PCB-1016 0 0 18'1 (12674-11-2} 25P.Toxaphene 0 0 18'1 (8001-35-2) I _____j MO 780.!~ 16 {6*04) I NPDES #(IF ASSIGNeD) M0-0098001 I OUTFALL NUMBER 003 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE (If available} (If available) (1) {1} (1) CONCENTRAnOH (2) MASS CONCENTRATION {2}MASS CONCENTRAnON (2)MASS PAGES

4. UNITS D. NO. OF A.CONCEN*

B. MASS ANAL* TRATION YSES S.INTAKS (c> p 1!ionaQ A. LONG TERM AVR(o. VALUE {1} CONCENTRATION

~

( MJ ISS B. NO OF ANAL* YSES Enclosure to ULNRC-06027

1.30 APPLICATION FOR DISCHARGE PERMIT FORM D - PRIMARY INDUSTRIES TABLE II NPDES #(IF ASSIGNED) I OUTFALL NUMBER M0-0098001 007 If you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to determine which of the GC/MS fractions you must 1 Mark "X" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark uxn in column 2-B fore st for.

ch e

a pollutant you know or have reason to believe is present. Mark "X" in column 2-C for each pollutant you believe to be absent. rf you mark either columns 2-A or 2-B pollutant~ you must provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Campi for any table (all seven pages) for each outfalL See instructions for additional details and requirements. teone e 2.MARK.. X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 D~r VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKE (*:J

1. POLLUTANT B. BE*

c.ee. {If available (if available) D. NO. OF AND CAS NUMBER A. TEST* LIEVED LIEVEO A.CONCEN* B. MASS A. LONG TERM AVR<; (if available) INGRE* PRE* AB-(11 (1) (1) ANAL* TRATION VALUE QIJIRED (2)MASS ~2)MASS (2}MASS YSES SENT SENT CONCENTRATION CONCENTRATION CONCENTRATION (1} CONCENTRATION 1tlonsl) 6.NO OF -~ ANAL* ASS YSES M METALS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total 0 0 [8l <5.0 <0.001 1 UG/l LBS/0 (7440-36-9) 2M. Arsenic, Total 0 0 [8l <10 <0.001 1 UG/l LBS/0 (7 440-38-2} 3M. Beryllium. Total 0 0 181 <0.5 <0.001 1 UG/L LBS/0 (7440-41-7} 4M. Cadmium, Total 0 0 [8l <0.5 <0.001 1 UG/L LBS/D {7440-43-9} SM. Chromium, Total 0 0 181 <10 <0.001 1 UG/L LBS/D (7 440-47 -3) 6M. Copper. Total 0 (81 0 2.7 0.0003 1 UG/l LBSIO (7550-50-8) 7M. Lead, Total 0 0 181 <3.0 <0.001 1 UGIL LBS/0 {7439-97-6) 8M. Mercury, Total 0 0 l8l {7 439-97 -6) 9M. Nickel, Total 0 0 181 <5.0 <0.001 1 UG/L LBS/0 {7 440-02-0) 10M. Selenium, Total 0 D [8J <5.0 <0.001 1 UG/L LBS/D {7782-49-2) 11M. Silver. Total 0 0 l8l <0.1 <0.001 1 UG/L LBS/D (7440-22.;4) 12M. Thallium, Total 0 0 £81 <2.0 <0.001 1 UG/L LBS/D . (7440-28-D) 13M. Zinc. Total 0 r8l 0 13 0.0016 1 UG/L LBS/D (7440-66-6) 14M. Cyanide, Total 0 0 IZ1 {57-12*5) 15M. Phenols, 0 0 [8l Total DrOXIN 2,3,7,8-Tetra-I I £81 I DESCRIBE RESULTS chlorodibenzo-P-0 0 Dioxin (1764-01-6) MO 780-1516 {6-04) PAGE2 Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3 2.MARK"X" 3.EFFLUENT A. MAXIMUM OAIL V VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE (optional}

1. POLLUTANT A.

e.ee-C. BE* (if avaifablr:} (if availableJ AND CAS NUMBER TEST* UEVED LIEVED D. NO. OF A.CONCEN* B. MASS A. tONG TERM AVRG. B. NO (if available) lNG RE* PRE* As. (1} (1) {1} ANAL* TRATION VALUE OF QUIRI:D SENT SENT CONCEHTRATlOO (2)MA$S CONCENTRATION (2) IIMSS CONCEHTRATtON {2)MASS YSES

m--

ANAL* (1) YSES CONCENTRATION !<lASS GC/MS FRACTION -VOLATILE COMPOUNDS 1V. Acrolein 0 0 181 (107-02-8} 2V. Acrylonitrile 0 0 !81 (107-13-1) 3V. Benzene 0 0 1'81 {71-43-2) 4V. Sis (Chloromethyl) 0 0 t8l Ether {542-88-1) 5V. Bromofol'fl'l 0 0 l8J (75-25-Z) 6V. Carbon Tetrachloride 0 0 IZ1 {56-23*5) 7V. Chlorobenzene 0 0 [81 (108-90-7) 8V. Chlorodibromomethane 0 0 [81 (124-4~H) 9V. Chloroethane 0 0 !81 (75-00-3) 10V. 2-Ch!oroethylvlnyl 0 0 18! Ether {110-75-8) 11 V. Chloroform 0 0 IZl (67-66-3) 12V. Dichlorobromomethane D 0 rgJ (75-27-4) 13V. Dichloro~ 0 D rgJ difluoromethane {75-71~8) i 4V. 1,1 - Dichloroethane 0 0 I8J (75-34-3} 15V. 1,2-Dichloroethane D 0 r8J {107-06-2) i6V. 1.1 - Dichloroethylene 0 0 [81 {75-35-4) i7V. 1,2.- Dichloropropane 0 0

18)

(78-87-5) 18V. 1,2 -Dlchloropropylene 0 0 [8] (542-75-6) i9V. Ethylbenzene 0 0

18)

(100-41-4) 20V. Methyl Bromide 0 0 t8l {74-83-9) 21V. Methyl Chloride 0 0 [81 (74-87-3) MO 780- t516 (6-04} ) IAGE3. CONTINUE ON PAGE; 4 Enclosure to ULNRC-06027

l NPDES # (IF ASSIGNED) I OUTFALL NUMBER I CONTINUED FROM THE FRONT M0-0098001 007 2.1\\tARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 D~i VAt..UE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE (o~

1. POllUTANT A.

B. BE* C. BE* (if available (if ava;table} AND CAS NUMBER TEST* LJEVEO l.IEVED D. NO. OF A.CONCEN~ B. MASS A. LONG TERM AVRC[ (if availab((l} INGRE* PRE* AB- {1) (1) {1} ANAL* TRATION VALUE QUIRE CO SENT SENT CONCENTRATION (2)1\\aASS CONCENTRATION (2)MAS$ CONCENTRATION (2)MASS VSES (1} CONCENTRATION 1tionaJ) B. NO OF om-- ANAL* ~ss YSES GC.MS FRACTION -VOlATiLE COMPOUNDS (continued) 22V. Methylene Chloride 0 0 [81 {75-09-2} 23V. 1.1.2.2 -Tetra-0 0 l8l chloroethane (79-34-5) 24V. Tetrachloroethylene 0 0 [81 (127-18-4} 25V. Toluene 0 0 t8J (108-88-3) 26V. 1,2-Trans 0 0 1&1 Dichioroethylene ( 156-60-5) 27V. 1,1,1-Tri-0 0 181 chloroethane {71-55-6) 28V. 1.1.2 - Tri-0 0 I8J chtoroethane (79-00-5) 29V. Trichloro-0 0 l81 ethylene (79.01-6} 30V. Trichloro-0 0 181 fluoromethane (75-69-4) 31V. Vinyl 0 0 f8l Chloride (75-01-4) GC/MS FRACTION-ACID COMPOUNDS 1A. 2 - Chlorophenol 0 0 121 (95-57-8) 2A. 2.4 - Dichloro - 0 0 l8l phenol {120-83-2) 3A. 2,4 - Dimethyl-0 0 l8l phenol (105-67*9} 4A. 4,6-Dinitro 0 0 I8J Cresol (534-52-i) 5A. 2.4 - Dinitro - 0 0 I8J phenol (51*28-5) 6A. 2-Nitrophenol 0 0 I8J (88-75-5) 7 A. 4-Nitrophenol 0 0 181 (100*02-7) SA P - Chforo - M 0 0 181 Cresol (59-50-7) 9A. Pentachloro - 0 0 f8l phenol (87 5 10A. Phenol 0 0 r8l (108-952) 11A. 2.4,6-Trichloro-0 0 1'.81 phenol (88-06-2) MO 7S0-1 :> 16 (6-04) p

4 AGE CONTINU EON PAGE~

Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X" J.EFFt..UENT A. MAXIMUM DAILY VALUE B. MAXIMUM SO DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE lOJ)tiOnaf)

1. POLLUTANT A.

s.se. C. BE* (if available) (if available) AND CAS NUMBER TEST* llE\\II;O !.I EYED D. NO. OF A.CONCEN-B. MASS A. LONG TERM AVRG. 6.NO (if avalfabh1) INGRE* PRE* AS.. (1) (1) (1) ANAL* TRATION VALUE. OF QUIREO SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)1'AASS YSES ANAL* (1) (2) VSES CONCEHTRA TION MASS GC/MS FRACTION -BASE/NEUTRAL COMPOUNDS 1 B. Acenaphthene 0 0 IZI (83-32-9)

28. Acenaphtyiene 0

0 l8l {208-96...S) 3B. Anthracene 0 0 l8l (120-12-7)

48. Benzidine 0

0 181 (92--87-5}

58. Benzo (a) 0 0

f8l Anthracene (56-55-3) 6B. Benzo (a) 0 0 !El* Pyrene (50*32-8}

78. 3.4 - Benzofluoranthene 0

0 181 (205-99~2)

88. Benzo (ghi) 0 0

[8'.1 Perylene {191-24-2)

98. Benzo {k) 0 0

l8l Fiuoranthene (207-QS-9) lOB. Bis (2-Chloroethoxy) 0 0 IZI Methane (111*91~1) 118. Sis (2*Chloroethyl) 0 0 IZI Ether (111-44-4} 128. Bls (2-Chloroisopropyl} 0 0 181 Ether { 39638-32-9) 136. Sis (2wEthylhexyl) 0 0 l'8J Phlhalate (117 --81-7} 148. 4-Bromophenyl 0 0 IZI Phenyl Ether(101*55-3) 158. Butyl Benzyl 0 0 181 Phthalate (85-68-7) 168. 2-Chloronaphthalene 0 0 123 (91-SB-7) 178. 4-Chloropheny! 0 0 IZl Phenyl Ether (7005-72-3) 18B.Chrysene 0 0 [8'.1 {:218*01-9) 198. Oibenzo (a.h) 0 0 [8l Anthracene (53-70-3) 208. 1,2 - Dichlorobenzene 0 0 [81 (95-50-1) I 218. 1,3-Dichlorobenzene 0 0 IZl {541-73-1) MO 7SO*l:J 16 (6*04) PAGE' CONTINUE ON PAGE 6 Enclosure to ULNRC-06027

C.ONTJNIJRD FROM PAGE 5 I NPDES # (IF ASSIGNED) I OUTFALL NUMBER l M0-0098001 007 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAIL. Y VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS

5. INTAKE {<l

1. POLLUTANT A.

B. BE* C. BE-(if available) (if ava#able} AND CAS NUMBER TEST* LIE\\1£0 liEVED D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG. (if availablt!t) INGRE* PRE* AS. {1) (1) (1) ANAl* TRATION VALUE QUIRED SENT SENT CONCENTRATION (2)MASS CONCENTRATION {2)1\\fASS CONCENTRATION (2)MASS YSt:S (1) CONCENTRATION 1tional) S.NO OF

~ ANAl*

ASS YSES GC/MS FRACTION-BASE/NEUTRAl COMPOUNDS (continuoo) 228. 1, 4-Dichlorobenzene 0 0 t8l (106-46-7} 238. 3, 3'-Dichlorobenzldine 0 0 t8l (91-94-1} 24B. Diethyl Phthalate 0 0 [81 {84-66-2) 256. Dimethyl Phthalate 0 0 t8l {131-11-3} 268. Di-N-butyl Phtha~ate 0 0 IZJ (84-74-2) 278. 2.4-Dinitrotoluene D 0 r8l (121-14-2) 28B. 2,6-Dinitrotoluene 0 0 r8l {606-20-2} 298. Oi-N-Octyl Phthalate 0 D l2j (117-84-Q} 30B. 1.2-Diphenylhydrazine D D 181 (asAzobenzene) (122-66-7) 318. Fluoranthene 0 0 181 {206-44-Q) 326. Fluorene 0 0 181 (86-73~7} 338. Hexachlorobenzene 0 0 181 (87-68-3) 348. Hexachlorobutadiene 0 0 181 {87~68-3) 358. Hexachloro-0 0 181 cyclopentadiene (77-47-4) 368. Hexachloroethane 0 0 181 (67-72-1) 37B.lndeno (1,2,3-c-d) 0 0 181 Pyrene (193-39-5) 388. lsophorone (J 0 181 (78-59-1) 398. Naphthalene 0 0 181 (91-20-3) 408. Nitrobenzene 0 0 181 . (98-95-3) 418. N-Nitro-0 0 (gJ sodimethylamine {62-75-9) 428. N-Nitroso 0 0 181 N-Propylamine {6.2Hi4-7) M07SO*bl6{6-04) PAGE6 CONTINU EONPAGEi Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2:.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 3(1 DAY VALUE C. LONG TeRM AVRG. VALUE

4. UNITS 5.1NTAKE (optionafj

1. POLLUTANT A

B. BE* C. BE* (if available) (if available} AND CAS NUMBER TEST.. liE \\lED LIE\\IEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG. B. NO (If availabkl) INGRE-PRE* AS* (1) (1)

11)

ANAL* TRATION VALUE OF QUI REO SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION {2)MASS YSES ANAL* (1) (2) YSES CONCENTRATION MASS GCIMS FRACTION -BASE/NEUTRAL COMPOUNDS (continued) 438. N-Nitro* 0 0 (gj sodiphenyfamine (86-30-6) 448. Phenanthrene 0 0 (gj (85-01-8) 458. Pyrene 0 0 181 (129-00-0) 468. 1,2,4-Tri 0 0 1&1 chlorobenzene ( 120-82*1) GC/MS FRACTION *PESTICIDES 1P.A!drin 0 0 181 (309-00-2) 2P. a.SHC 0 0 181 (319--84-6) 3P. 13-BHC 0 0 I2J (319-84-6) 4P. y-BHC 0 0 181 {58-89-9) 5P. o-8HC 0 0 181 {319-86-8} 6P. Chlordane 0 0 t:?J (57~74-9) 7P. 4,4'-DDT 0 0 IZJ (50-29-3} 8P. 4,4'-0DE 0 0 ~ {72*55-9} 9P. 4,4'-DDO 0 0 ~ (72-54-8) 10P. Dieldrin 0 0 ~ (60-57-1) i1P. a-Endosulfan 0 0 IZI (115-29-7) 12P. ~-Endosultan 0 0 t8J {115-29-7) 13P. Endosulfan Sulfate 0 0 (gj (1031..{}7-8) 14P.Endrin 0 0 181 (72-20-8) 15P. Endrin Aldehyde 0 0 181 {7421-93-4) 16P. Heptachlor 0 0 l8l (76-44-8} - MO 7&0-1:>16 (6*04) PAGE7 I I ~ CONTINUED ON PAGJ. S Enclosure to ULNRC-06027

CONTINiiF.D FROM PAGE 7 I NPDES #(IF ASSIGNED} l OUTFALL NUMBER M0-0098001 007 Z.MARK"X"

3. EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE(o

1. POLLUTANT A.

B. BE* C.EIE* (If available) {if available} AND CAS NUMBER TEST* lii:\\IEO UEVEO O.NO.OF A.CONCEN* B. MASS A. LONG TERM AVRGi. (if.available) INGRE* PRE* AB-(1) (1) (1) ANAL* TRATION VALUE QUJREO SENT SENT CONCENTRATION (2)MASS CONCEHTRATlON (2)MAS$ CONCENTRATION (2}MASS YSES (1) CONCENTRATION 'tiona I) B. NO OF

~ ANAL*

ASS YSES GC/MS FRACTION.. PESTJCISES (continued} 17P. Heptachlor 0 0 181 Epoxide (1024-57-3) 18P. PCB-1242 0 0 E8l (53469*21*9) 19P. PBC-1254 0 0 181 (11097-69-1) 20P. PCB-1221 0 0 1:81 (11104-28-2) 21P. PCB-1232 0 0 1:81 (1114H6-5) 22P. PCEI-1248 0 0 181 (12672-29-6} 23P. PCEH260 0 0 [gl (11 096-82-5) 24P. PCB-1016 0 0 181 (12674-11-2) 25P.Toxaphene 0 0 E8l (8001-35-2) MO 780-l.;. 16 (6-04} PAGES Enclosure to ULNRC-06027

1.30 APPLICATION FOR DISCHARGE PERMrT FORM D-PRIMARY INDUSTRIES TABLE II NPDES #(IF ASSIGNED) I OUTFALL NUMBER M0-0098001 010 If you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to determine which of the GC/MS fractions you must t Mark "X in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "X" in column 2-B fore

t for.
h pollutant you know or have reason to believe is present. Mark "X" in column 2-C for each pollutant you believe to be absent. If you mark either columns 2-A or 2-B *Dr any et

ac f et pollutant, you must provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Com pi ~~one table (a!/ seven pages) for each outfall. See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

1. POLLUTANT a.eE-C. BE*

jif available} (if available) AND CAS NUMBER A. TEST* LIEVEO LIEVEO (ff available} lNGRE* PRE* AS-('I) QUIRED (1) i1) SENT sENT CONCENTRATION (2)MASS CONCeNTRATION (2)MAS$ CONCENTRATION (.2}MASS METAlS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total 0 0 ~ {7 440-36-9) 2M. Arsenic, Total 0 I 0 ~ (7 440-38-2} 3M. Beryllium, Total 0 0 1'81 {7440-41-7\\ 4M. Cadmium, Total 0 0 rgj {7 440-43-9) SM. Chromium, Total D 0 181 (7440-47-3) 6M. Copper, Total 0 0 IZI (7550-50-8) 7M. Lead, Total 0 0 1'81 (7439-97-6) 8M. Mercury, Total 0 D IZl {7 439-97 -6) 9M. Nickel, Total 0 D 181 (7440-02-0) 10M. Selenium, Total 0 0 t8l {7782-49-2) 11M. Silver, Total 0 0 l'8l {7440-22-4) 12M. Thallium, Total D 0 l'8l (7440-28-0) 13M. Zinc, Total 0 0 1:81 (7 440-66.-6) 14M. Cyanide, Total D 0 l'8l (57-12-5} 15M. Phenols, 0 D l'8l Total DIOXIN 2,3,7,8-Tetra-DESCRIBE RESULTS chlorodibenzo-P-0 0 [8] Dioxin (1764-01-6) MO 780.1516 (6.Q4) PAGE2 4.UNITS D.NO.OF A.CONCEN* B. MASS ANAL* TRATION YSES S.INTAKE(o Jon a f) pt A. LONG TERM AVRCi VALUE (1) CONCENTRATION ~r ( MA ss B. NO OF ANAL* YSES Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3 2.MARK"X"

t. POLLUTANT A.

s.ee. C. BE* AND CAS NUMBER resr. LIEVEO LIEVED (if ¢tva/fable) lNG RE* PRE* A!:J.. QUIREO SENT $ENT GC/MS FRACTION -VOLATILE COMPOUNDS 1V. Acrolein 0 0 IZl (107-Q2...a) 2V. Acrylonitrile (107-13*1) 0 0 ~ 3V. Benzene 0 0 [81 (71-43-2) 4V. Bis ( Chforomethyl) 0 0 IZI Ether (542...a8-1) 5V. Bromoform 0 0 £&! (75-25-2) 6V. Carbon Tetrachloride 0 0 ~ (56-23*5) 7V. Chlorobenzene 0 0 t8l (108-90-7) 8V. Chlorodibromomethane 0 0 IZJ (124-48-1) 9V. Chloroethane 0 0 t8l {75..()0-3) 10V. 2:-Chloroethylvinyl 0 D r81 Ether ( 11 0-75*8) 11V. Chloroform D 0 t81 (67-$6-3} 12V. Dichlorobromomethane 0 0 IZI (75-27-4} 13V. Dichloro-0 0 t8J difluoromethane (75-71 *8) 14V. 1.1 - Dichloroethane (75-34*3) 0 D (8] 15V.1,2 Oichloroethane D 0 181 (107-06-2) 16V. 1,1 - Dichloroethylene 0 0 fZI (75-35-4) 17V. 1,2 - Oichloropropane D 0 18] {78-87-5} 18V. 1.2 --Dichtoroprop}liene 0 D !81 (542-75-6) 19V. Ethylbenzene 0 0 l2J (100-41-4} 20V. Methyl Bromide 0 0 18] (74-83-9) 21V. Methyl Chloride 0 0 12] {74-Bi-3) MO 780-1516 (6-04) 3.EFFLUENT A. MAXIMUM DAtL Y VALUE

8. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE (if available}

(if available) D. NO. OF (1) (1} (1) ANAL-CONCENTRATION (2)MASS CONCENTRATION {:t)!MSS CONCENTRATION (2)MASS YSl::S .. c_ PAGE. 4.UN!TS A.CONCEN* B. MASS TRATION 5.1NTAKE( optional) A. LONG TERM AVRC) VALUE (1) CONCENTRATION (2) MASS B. NO OF ANAL-YSES CONTIN! JEONt>AGE4 Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT l NPDES #(IF ASSIGNED} M0-0098001 I OUTFALL NUMBER 010 I 2.MARK"X" 3.EFFLUENT A. MAXIMUM OAII. Y VALUE

6. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

1. POLLUTANT A.

B. £IE* C. BE* (If available) flf available) AND CAS NUMBER TEST* LIEVEO UEVEO (if available} INGRE* PRE* As. !1) (1) (1) QUIREO SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)W..SS CONCENTRATION (2}MASS GC.MS FRACTION-VOLA TILE COMPOUNDS (continued) 22V. Methylene Chloride D D 181 {75*09~2) 23V, 1.1,2,2-Tetra~ 0 0 I'Zl chloroethane (79-34-5) 24V. Tetrachloroethylene 0 0 f8l (127-18-4) 25V. Toluene 0 0 181 (108*88*3) 26V. 1,2-Trans 0 0 f8l Dlchloroethylene (156-60-5) 27V. 1.1.1-Tri-0 0 1&1 chloroethane (71-55-6) 28V. 1,1,2 - Tri* 0 0 l8l chloroethane (79-00-5) 29V. Trichloro-0 0 1&1 ethylene (79.()1..0.) 30V. TrichiOf(:'J-0 0 ~ fluoromethane {75-69-4) 31V. Vinyl 0 0 l8l Chloride (75-01-4) GC/MS FRACTION-ACID COMPOUNDS 1A. 2-Chlorophenol 0 0 l8l (95-57-8) 2A. 2,4-Dich!oro-D 0 IZI phenol (120-83-2) 3A. 2,4 - Dimethyl - D 0 l8l phenol (105-$7-9) 4A. 4,6-Dinitro 0 D 121 Cresol (534-52-1) 5A. 2.4 ~ Dinitro - 0 D l8l phenol {51*28-5) 6A. 2-Nitrophenof 0 0 ~ (88~75-5) 7 A. 4-Nitropheno! 0 0 fZJ (100-02-7) 8A. P - Chtoro - M 0 0 f8l Cresol (59*00*7) 9A. Pentachloro - 0 0 f8l phenol {$7*86*5 10A. Phenol 0 0 181 (108-952) 11A. 2,4,6-Trichloro-0 0 l8l phenol (88*06~2} MO 780*b 16 (6..Q4) PAGE4 4.UN!T$ O.NO.OF A.CONCEN* B. MASS ANAL* TRATION YSES 5.1NTAKE{o p *'ional) A. LONG TERM A\\IR(; VALUE (1) CONCENTRATION

~

{ w ISS B. NO OF ANAL* YSES 0 IN C NT LEONPAGE5 Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X"

3. EFFLUENT A. MAXIMUM DAILY VALUE B. MAXfMUM 30 DAY VAlUe C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE(4

1. POLLUTANT A.

a.ae-(:.BE* (if available} (if available) AND CAS NUMBER TEST* f.IE\\IEO LJEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVR{ (if available) INGRE* PRE* AS- {1) (1) (1) ANAL* TRAftON VALUE QUIREO SENT SENT CONCENTRATION (2)MASS CONCENTRATION {2)MASS CONCENTRATION {2}MASS YSES (1) CONCENTRATION lptional) S.NO OF .{2) ANAL* MAS$ YSES GC/MS FRACTION -BASE/NEUTRAL COMPOUNDS 1 B. Acenaphthene (83-32-9) 0 0 t8J

28. Acenaphtylene (208*96-8) 0 0

[8J

38. Anthracene (120-12-7) 0 0

(21

48. Benzidine 0

0 f2l (92--87-5)

58. Benzo (a)

D D ~ Anthracene (56-55-3}

68. Benzo (a}

0 0 j'gJ Pyrene (50*32-8)

78. 3.4 - Benzofluoranthene 0

0 IZl (205-99-2)

88. Benzo (ghi}

D D 181 Perylene (191-24-2) 9B. Benzo (k} D 0 181 Fluoranthene {207-()8-9) 108. Bis (2-Chloroethoxy) 0 0 181 Methane (111-91-1) 11 B. Bis (2-Chloroethyl} 0 0 l'8l Ether (111-44-4) i 28. Bis {2-Chloroisopropy!} 0 0 t8l Ether (30038*32-9) 138. 8is (2-Ethylhexyl} 0 0 t8l Phthalate (117-$1-7) 148. 4-Bromophenyl 0 0 r8l Phenyl Ether (101-55-3) 158. Butyl Benzyl 0 0 181 Phthalate {85-68*7} 166. 2-Chloronaphthalene 0 0 l8l {91-58-7) 178. 4-Chiorophenyl 0 0 I2?J Phenyl Ether (7005-72-3} 188. Chrysene 0 0 181 (218-01*9) 198. Dibenzo (a.h) 0 0 12] Anthracene (53-70*3) 208. 1,2 - Dichlorobenzene 0 0 181 (95-50-1) 21 B. 1,3 - Dichlorobenzene 0 0 181 (541-73-1) PAGES CONTINI JE ON PAGE<* Enclosure to ULNRC-06027

f:ONTINlJf:D FROM PAGF. 5 l NPDES # (IF ASSIGNED) M0-0098001 I OUTFALL NUMBEH 010 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAfL Y VALUE B. MAXIMUM30 DAY VALUE C. LONG TERM AVRG. VALUE

1. POLLUTANT A.

B. BE-C. BE* {if available) {if avaifable} AND CAS NUMBER TEST* LIE \\lED LIE\\IED (if availabff.l) INGRE* PRE* AS-(1} (1) {1) QUIREO SENT SENT CONCENTRATION {2)MASS CONCENTRATION (2)W.SS CONCENTRATION (2)MASS GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS (continued) 228. 1, 4-Dichlorobenzene 0 0 181 {106-46-7) 238. 3. 3'-Dichlorobenzidine D 0 181 (91-94-1) 248. Diethyl Phthalate D D [81 (84-66-2) 258. Dimethyl Phthalate 0 D I8J (131-11-3) 268. Di-N-butyl Phthalate 0 D I8J (84-74-2) 278. 2.4-Dinitrotoluene 0 D l8l (121-14-2} 288. 2.6-Dinitrotoluene 0 0 r8J (606-20-2) 298. Di-N-Octyl Phthalate 0 0 !81 (117-84-0) 308. 1,2-Diphenylhydrazine D 0 ~ (as Azobenzene) (122-66-7) 318. Fluoranthene D D ~ (206-44-0) 328. Fluorene 0 D I8J (86*73*7) 33B. Hexachlorobenzene 0 0 I8J (87-68-3) 348. Hexach!orobutadiene 0 D 181 (87-68-3) 358. Hexachforo-0 0 t8l cyclopentadiene {77-47-4) 368. Hexachloroethane 0 0 i8l (67-72-1) 378. lndeno (1,2,3-c-d} 0 0 ~ Pyrene ( 193-39-5) 388. lsophorone 0 0 i8l {78-59-1) 398. Naphthalene D D ~ (91-20-3) 408. Nitrobenzene 0 D 181 {98-95*3) 418. N-Nitro* 0 0 l8J sodimethylamine (62-75-9) 428. N-Nitroso 0 D 181 N-Propylamine (621-64-7) MO 780*1516 (6-04) PA 'E6 G 4.UNITS D. NO. OF A.CONCEN* B. MASS ANAL* TRATION YSES s.rNTAKE( op 1~ionaJ) A. LONG TERM AVRC> VALUE (1) CONCENTRATION ':~ ( MJ ISS S.NO OF ANAL* YSES CONT!NL H08PAOE7 1 Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X" A. MAXIMUM DAILY VALUE

1. POLLUTANT A.

13.81;* c.se. AND CAS NUMBER TEST* LIEVED l.IEVEO (if avil!llable) IlliG RE* PltE*

\\B.

(1) QUIREO SENT SENT CONCENTRATION (2)MA$S GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS (continued) 436. N-Nitro-sodiphenylamine (86-30-6) 0 0 121 448. Phenanthrene (85-01-8) 0 0 (81 458. Pyrene (129-00*0) 0 0 f.8l 468. 1,2,4-Tri chlorobenzene ( 120-82w 1 ) 0 0 181* GC/MS FRACTION

PESTICIDES 1P. Aldrin 0

0 cgJ (309-00-2) 2P. a..SHC 0 0 121 {319-84-6) 3P. }3*8HC 0 0 181 (319-84-6) 4P. y-BHC 0 0 181 (58-89-9) 5P o-8HC 0 0 i2?J (319-86-8) 6P. Chlordane 0 0 181 (57-74-9) 7P. 4,4'-0DT 0 0 IZI (50-29-3) 8P. 4.4'-0DE 0 0 181 (72-55-9) 9P. 4.4'-000 0 0 181 (72-54-8) 10P. Dieldrin 0 0 181 {60-57-1) 11 P. o-Endosulfan 0 0 181 {115-29-7} 12P. !3-Endosultan 0 0 181 (115-29-7) 13P. Endosulfan Sulfate 0 0 (8J (1 031-07-8) 14P. Endrin 0 0 [81 {72-20-8) 15P. Endrin Aldehyde 0 0 181 (7421-93-4} 16P. Heptachlor 0 0 181 (76-44-8) 3.EFFLUENT

8. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

_{if available) (If available) D. NO. OF (1) {1) ANAL* CONCE.NiRATION (2)MA$$ COHCENTRAnoN (2)MASS YSES PAGE7

4. UNITS A.CONCEN*

E!.MASS TRATION 5.1NTAKEt< ~ptfonal) A. LONG TeRM AVR(; VALUE (1} CONCENTRATION CONT!NUI!D ON PAGJ (2) MASS B. NO OF ANAL* YSES Enclosure to ULNRC-06027

CONTINI JED FROM PAGE 7 I NPDES #(IF ASSIGNED) MOw0098001 I OUTFALL NUMBER 010 l 2.MARK"X" S.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKE (oplional)

1. POLLUTANT A.

B. BE-C. BE-(if available) (If available) AND CAS NUMBER TEST* UEVEO LtEVEO D. NO. OF A.CONC.EN* B. MAS~ A. LONG TERM AVRG. B. NO (if available} INGRE-PRE* AS-(1) (1} (1) ANAl* TRATION VALUE OF OUIREO SENT SENT CONCENTRATION (2)MAS$ CONCENTRATION (l}MASS CONCENTRATION (2)MASS YSES ANAL* I (1) .(;!) COf.ICENTRATION MASS YSES GC/MS FRACTION - PESTICISE$ {continued) 17P. Heptachlor D D ~ Epoxide (1024-57-3) 18P. PCB-1242 0 D [81 { 53469-21-9) 19P. PBC-1254 0 0 [8] (11097-69-1) 20P. PCB-1221 0 0 181 (11104-28-2) 21P. PCB-1232 0 0 r8! {11141-16-5} 22P. PCB-1248 D D ~ {12672-29-6) 23P. PCB-1260 0 I D r8! (11 096*82-5) 24P. PCB-1016 0 0 r8! (12674-11-2) 25P.Toxaphene 0 0 r8! (8001-35*2) I I MO 7SO*l~ 16 (6-04) Enclosure to ULNRC-06027

1.30 APPLICATION FOR DISCHARGE PERMIT FORM D-PRIMARY INDUSTRIES TABLE II NPDES #(IF ASSIGNED) I OUTFALL NUMBER M0-0098001 011 If you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to determine which of the GC/MS fractions you must t e a Mark "X" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "X" in column 2-B for e poUutant you know or have reason to berieve is present. Mark "X" in column 2-C for each pollutant you believe to be absent. If you mark either columns 2-A or 2-B st for. ch for any poJiutant, you must provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Com pi e te one table (a// seven pages) for each outfall. See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE (_,

1. POLLUTANT B. BE*

C. BE* (if available} (if availabteJ D.NO.DF AND CAS NUMBER A. TEST* LIEVED LIEVED A.CONCEN-B. MASS A. LONG TERM AVRG (if available) INGRE* PRE* A8-(1) {1) (f) ANAL-TRATION VALUE QUIRED SENT SENT (2}MASS {2)MA$S f2)MASS ttfonal) B. NO OF CONCENTRATION CONCENTRATION CONCENTRATION YSES {f)

m---

ANAL* YSES CONCENTRATION ASS METALSt CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total 0 0 {ZJ (7 440-36-9} 2M. Arsenic, Total D D 181 (7440-38-2} 3M. Beryllium, Total 0 0 L'8l (7440-41-7} 4M. Cadmium, Total 0 0 j'gl ( 7 440-43-9) 5M. Chromium. Total 0 0 j'gl (7440-47-3) 6M. Copper, Total 0 0 [8J (7550-50-8) 7M. Lead, Total 0 0 181 {7439-97-6) 8M. Mercury, Total 0 D f8l (7439-97-6) 9M. Nickel. Total 0 0 f8l (7440-02-0} 10M. Selenium, Total 0 0 181 (7782-49-2) 11M. Silver, Total 0 0 181 (7440-22-4} 12M. Thallium, Total 0 0 ~ (7440-28-Q) 13M. Zinc, Total 0 0 181 (7 440-66-6) 14M. Cyanide. Total 0 0 181 (57-12-5' 15M. Phenols, 0 0 1:81 Total DIOXfN 2,3,7,8-Tetra-DESCRIBE RESULTS chlorodibenzo-P-0 0 1&1 Dioxin {1764-01-6) MO 780*1516 (6-04) PAGE2 Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3 2.MAR.K"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVR.G. VALUE

4. UNITS

5. INTAKE (optional)

1. POLLUTANT A

s.ae-C.BI;* Uf av<Jiiable) (if avaiJable) AND CAS NUMBER TEST* LIEVEO l.IEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG. B. NO (if available) lNGRE* PRE* AB-(1) (1) (11 ANAl-TRATION VALUE OF QUlRel) SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCE!rrRATlON (2)MASS YSES -~ ANAl* (1} CONCENTRATION MASS YSES GC/MS FRACTION-VOlATILE COMPOUNDS 1V. Acrolein 0 0 181 (107.()2-8) 2V. Acrylonitrile 0 0 181 (107-13-1) 3V. Benzene 0 0 (gl (71-43-2) 4V. Bis (Chforomethyfj 0 0 IZl Ether (542-88-1} 5V. Bromoform D 0 [8l (75-25-2) 6V. Carbon Tetrachloride 0 0 [81 (56-23-5} 7V. Chforobenzene 0 0 [8J (108-90-7) 8V. Chlorodibromomethane 0 0 181 (124-48-1) 9V. Chloroethaoe 0 0 [81 (75-Q0-3) 10V. 2-Chloroethylvinyl 0 0 lBl Ether (110-75-8) 11V. Chloroform 0 0 181 (67-66-3) 12.V. Oichforobromomethane 0 0 181 (75~27-4) i3V. Dichloro* 0 0 lBl difluoromethane (75*71-8) 14V. 1,1 - Dich!oroethane 0 0 l8l (75-34-3) '15V. 1,2-Dichloroethane 0 0 !8l (107..(16-2) 16V. 1,1 - Dichloroethylene 0 0 l8l (75-35-4} 17V. 1,2.. Dichloropropane 0 0 [81 {78-87-5) 18V. 1,2 -Dichroropropylene 0 0 l8l (542-75-6} 19V. Ethylbenzene ! 0 0 (81 (100-41-4) 20V. Methyl Bromide 0 0 IZl (74-83*9) 21V. Methyl Chloride 0 D ~ (74-87~3) MO 780*1.5!6 {Cl-04) PAGE3 CONTINUE ON PAGE 4 Enclosure to ULNRC-06027

l NPOES #(IF ASSIGNED) I OUTFALL NUMBER I CONTINUED FROM THE FRON1' M0-0098001 011 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE (Clp/iOnal)

1. POLLUTANT A.

B. BE* C. BE* (if available) {if avsll8ble} AND CAS NUMBER TEST* LIEVEO LIEVEO D. NO. OF A.CONCEN* B. MASS A. lONG TERM AVR<~. B. NO {if avsllable) IHGRE* PftE* A8-(1} (1) (1) ANAL* TRATION VALUE OF QUIREO SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS YSES -m-ANAL* (1} YSES CONCENTRATION MASS GC.MS FRACTION-VOLATILE COMPOUNDS (continued) 22V. Methylene Chloride 0 0 l8l (75-D9-2) 23V. 1,1,2,2-Tetra-0 0 r8l chloroethane {79-34-5) 24V. Tetrachloroethylene 0 0 181 (127-18-4) 25V. Toluene 0 0 l8J (108-88-3) 26V. 1,2 -Trans 0 0 f8l Dichloroethylene (156-{)0-5) 27V. 1,1, 1 - Tri - 0 0 l8l chloroethane (71-55-6) 28V. 1.1.2-Tri-0 0 (8J chloroethane (79-00-5) 29V. Trich!oro-- 0 0 f8l ethylene {79-Q1-6) 30V. Trichloro-0 0 f8l tluoromethane (75-69-4) 31V. Vinyl 0 0 l:8l Chloride (75-01-4} GC/MS FRACTION -ACID COMPOUNDS 1 A. 2-Chlorophenol 0 0 lZJ (95-57-8} 2A. 2,4 - Dichloro-0 0 f8l phenol (120-83*2) 3A. 2.4 - Dimethyl - D D 181 phenol (105-67-9) 4A 4,6-Dinitro 0 D l:8l Cresol ( 534-52-1 ) 5A. 2,4 - Dinitro - D 0 f8l phenol (51*28-5) SA. 2*Nitrophenol 0 0 181 (88-75-5) 7A. 4-Nitrophenol 0 0 181 (100-02-7) 8A. P - Chloro - M 0 0 181 Cresol (59-50-7) 9A. Pentachforo - 0 D 181 phenol (87-86-5 10A. Phenol 0 0 181 (108-952} 11 A. 2,4,6 - Trichloro-0 0 ll?.l phenol (88-06-2) MO 780-lS 16 {6-04) p AG E4 CONTINUE ON PAGE S Enclosure to ULNRC-06027

CONTiNUED FROM THE FRONT 2.MAAK"X"

3. EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKE (optional)

1. POLLUTANT A.

B. BE* c.ae* (if avai/able) (if available) AND CAS NUIJIBER TEST* liE \\leO I.IEifED D. NO. OF A.CONCEN-B. MASS A. LONG TERM AVRG. B. NO (ifavailablfiJ INGRE-PRE* AB-(1} (1) (1) ANAL* TRATION VALUE OF (WIREO SENT SENT CONCE:NTRAllON {2)MASS CONCENTRATION (2)MASS CONCENTRAllON (2>MASS YSES "'('2') ANAL* (1) YSES CONCENTRATlOH MASS GC/MS FRACTION - BASe/NEUTRAl COMPOUNDS 1B.Acenaphthene 0 0 ~ (83-32-9) 2B. Acenaphtylene 0 0 l8l (208-96-8)

38. Anthracene 0

0 (81 (120-12-7)

48. Benzidine 0

0 r8l (92-87-5)

58. Benzo (a) 0 0

lZJ Anthracene (56-55-3) 6B. Benzo (a) 0 0 ~ Pyrene (50-32-8)

78. 3,4 - 8enzofluoranthene 0

0 r8l (205-99-2)

88. Benzo (ghi}

0 0 IZl Peryfene (191-24-2}

98. Benzo (k) 0 0

r8l Fluoranthene (207-08-9) 108. Bis {2-Chloroethoxy} 0 0 121 Methane (111-91*1) 1 '1 B. Bis {2-Ghioroethyl) 0 0 121 E1her (111-44-4) 12B. Bis (2-Chloroisopropy!) 0 0 !ZJ Ether (39638-32*9) 136. Bis (2*Ethy!hexyl) 0 0 !ZJ Phthalate (117..S1-7) 146. 4-Bromophenyl 0 0 0 Phenyl Ether (101-55-3) 156. Butyl Benzyl 0 0 l8l Phthalate (85-68*7) 168. 2-Chloronaphthalene 0 0 l8l (91-58-7) 178. 4...Chlorophenyl 0 0 l8l Phenyl Ether{7005-72-3) 18B.Chrysene 0 D 18! (218..01-9) 198. Dibenzo (a.h} 0 0 !8l Anthracene (53-70-3) 208. 1,2 - Dichlorobenzene 0 0 (81 (95-50~1} 21 B. 1,3-Dichlorobenzene 0 0 181 (541-73*1} MO 780-1516 {6-04) PAGES ' IN A CONTIN *. E ), P OE6 Enclosure to ULNRC-06027

CONTINlJED FROM PAGf: 5 I NPOES# (IF ASSIGNED) I OUTFALL NUMBER M0~0098001 011 2.MARK"X"

3. EFFLUENT A. MAXIMUM OAIL Y VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKE (01

1. POLLUTANT A,

B. BE* C. BE* {if available) (if available) D. NO. OF AND CAS NUMBER TeST* LIEVS) liEVED A.CONCEN* lB. MASS A. LONG TERM AVFW. {if available) INGRE* PRE* JIIS.. (1} [1) (1) ANAL-TRATION VALUE QUIREO' SENT SENT CONCENTRATION {2}MASS CONCE:NTRATION (2)MA$$ COHCf.NTRATtON (2)MASS YSES (1) COHCEffTRATION )tiona!) B. NO OF

w-ANAL-lASS YSES GC/MS FRACTlON -BASE/NEUTRAL COMPOUNDS (continued) 22B. 1. 4-Dichlorobenzene 0

0 l8J (106-46-7) 236. 3, 3'-Dichlorobenzidine 0 0 IZI (91-94-1) 248. Diethyl Phthalate 0 0 l8J (84-66-2) 258. Dimethyl Phthalate 0 0 181 (131-11-3) 268. Di-N-butyl Phthalate 0 0 1:21 (84-74-2) 278. 2,4-Dinitrotoluene 0 0 l8l (121-14-2) 288. 2,6-Dinitrotoluene 0 0 181 (606-20-2) 298. Di-N-Octyl Phthalate 0 0 IZl (117-84-Q} 306. 1,2-Diphenylhydrazine 0 0 ~ {as Azobenzene) (122-66-7) 318. Fluoranthene 0 0 l8l (206-44:.0} 326. Fluorene 0 0 l8l (86-73~7) 338. Hexach!orobenzene 0 0 [81 {87-68-3) 348. Hexachforobutadiene 0 0 l8l (87-68-3} 358. Hexachloro-0 0 [81 cyclopentadiene {77-47*4} 368. Hexachloroethane 0 0 (gl (67-72-1) 378. lndeno (1,2,3-c-d) 0 0 121 Pyrene (193-39-5) 38B. lsophorone 0 0 121 (78-59-1) 398. Naphthalene 0 0 121 {91-20*3} 408. Nitrobenzene 0 0 121 (98-95-3) 41 B. N-Nitro-0 0 181 sodimethyfamine (62-75-9} 426. N-Nltroso 0 0 181 N-Propylamine {621-64-7) MO 7$0*1~16 {Q*04) PAGE6 CONT!NU EONFAGE7 Enclosure to ULNRC-06027

CONTiNUED FROM THE FRONT 2.MARK"X" 3.EfFLUENT A. MAXIMUMDAilYVAlUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS

5. INTAKE 1l:

1. POLLUTANT A.

13. BE*

C.SE* (if available) (If available) AND CAS NUMBER TEST* LIEVEO LIE \\lEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG (if available) JMGRE* PRE* AS-(1) (1) (1) ANAL-TRATION VALUE QUIREIO SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION {2}MASS YSES (1) COHCENTAATION lltional) B. NO OF

~ ANAL*

tASS YSES GCJMS fRACTION-BASE/NEUTRAL COMPOUNDS (continued) 438. N*Nitro-0 0 I2Sl sodiphenylamine (86-30-6) 448. Phenanthrene 0 0 ~ (85-01-8) 458. Pyrene 0 0 ~ (129-Q0-0) 468. 1.2,4-Tri 0 0 181 chlorobenzene (120-82-1) GC/MS FRACTION* PESTICIDES 1P. Aldrin D 0 t8l (309-00-2} 2P. a-BHC 0 0 !81 (319-84--6} 3P. ~-8HC 0 0 r8l {319-84-6) 4P. y-8HC 0 0 fZI (58-89-9) 5P. o-BHC 0 0 l8l (319-8-8) 6P. Chlordane 0 0 l8l (57-74-9} 7P. 4,4'-DDT 0 0 IZI (50-29-3) 8P. 4,4'-DDE 0 0 ~ (72-55-9} 9P. 4,4'-DDD D 0 l8l (72-54--8} 10P. Oieldlin 0 D ~ (60-57-1) 11 P. a-Endosuifan 0 0 ~ (115-29*7} 12P. [3-Endosuttan 0 0 l8l (115-29-7) 13P. Eno'osulfan Sulfate 0 0 18] {1031-07-8) 14P. Endrin 0 0 181 {72-20*8) 15P. Endrin Aldehyde 0 0 l8l (7 421-93-4) 16P. Heptachlor 0 0 1:81 (76-44-8) MO 7&0-1.) l(} C6*041 PAGE7 CONTINUED ON PAGl Enclosure to ULNRC-06027

CONTINlJIF..O FROM PAGf. 7 I NPDES #(IF ASSIGNED) ~ OUTFALL NUM6EH M0-0098001 011 2.MARK"X"

3. EFFLUENT A. MAXIMUM DAILY VALUE.

B. MAXIMUM 30 DAY VALUE C. LONG 'TERM AVRG. VALUE 4.UNITS

5. INTAKE (ct 1.POlLUTANT A.

B. BE* C. BE* (if available) {if available) AND CAS NUMBER TEST* LIEVI!!O LIEVI!!O D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVR(.;. (if available) INGRE* fiRE. AS-(1) (1) (1) ANAl* TRATION VALUE O:UlREO sENT SENT CONCEHtRAT10N i2}MASS CONCENTRATION {~)MASS CONCENTRAllON (2)MASS YSES (1) CONCENTRAT10N tiona I) B. NO OF i~ ANAL* MlS YSES p GC/MS FRACTION - PEST!CISE$ (continued) 17P. Heptachlor 0 0 I8J Epoxide (1024*57-3) 18P. PCB-1242 0 0 181 (53469-21*9) i9P. PBC-1254 0 0 jgl {11097-69-1} 20P. PCB-1221 0 0 181 (11104-28-2) 21 P. PCB-1232 0 0 I8J (11141-16*5) 22P. PCB-1248 0 0 I8J (12672-29-6) 23P. PCB-1260 0 0 [81 (11096*82*5) 24P. PCB*1 016 0 0 181 (12674-11-2) 25P. Toxaphene 0 0 [81 (8001-35-2) MO 780-!516 (6-0<1} PAGES Enclosure to ULNRC-06027

I I 1.30 APPLICATION FOR DISCHARGE PERMIT FORM D - PRIMARY INDUSTRIES TABLE II NPDES #(IF ASSIGNED) OUTFALL NUMBER M0-0098001 012 If you are a primal)! industry and this outfall contains process wastewater, refer to Table A in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "X" in column 2-B for each pollutant you know or have reason to believe is present. Mark "X" in column 2-C for each pollutant you believe to be absent. If you mark either columns 2-A or 2-EI for any pollutant, you must provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Compl1::te one table (a// seven pages) for each outfall. See instructions for additional details and requirements. 2.MARK"X" 3,EFFLUENT A. MAXIMUM DAII.. Y VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKE {c*ptionm)

1. POLLUTANT B. BE-C. BE*

(if available} (if availabl&} AND CAS NUMBER A.. TEST* liE \\lEO llEVeD D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG. 8.NO (if available) INGRE* PRE* A9-(1} ANAL* TRATION VALUE OF QUIRED* SENT SENT (1) (2}MASS (1} (2)MASS (2)MASS YSES CONCENTRATION CONCENTRATION CONCCHTRATION (1) (2} ANAl* CONCENTRATION

IAASS YSES METALS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total 0

0 181 (7440-36-9) 2M. Arsenic, Total 0 0 [8] (7440-38-2) 3M. Beryllium, Total 0 0 181 {7440-41-7} 4M. Cadmium. Total 0 0 ~ (7 440-43-9) 5M. Chromium, Total 0 0 181 (7440-47-3) 6M. Copper, Total 0 0 181 (7550-50-8} 7M. Lead, Total 0 0 t:8l (7439-97-6) 8M. Mercury, Total 0 0 t:8l {7439-97-6) 9M. Nickel, Total 0 0 [8] (7 440-02-0) 10M. Selenium, Total 0 0 181 (7782-49-21 11M. Silver, Total 0 D 181 {7440-22-4) 12M. Thallium, Total 0 0 ~ (7 440-28-0) 13M. Zinc, Total 0 0 ~ (7 440-66-6) 14M. Cyanide, Total 0 0 rZI (57-12-5} 15M. Phenols, 0 0 !21 Total oaoxeN 2,3,7,8-Tetra-DESCRIBE RESULTS chlorodibenzo-P-0 0 t8l Dioxin (1764-01-6) ') MO 780-15l6 (6*04) PAGE* Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3

2. MARK"X"

3. EFFLUENT

1. POLLUTANT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 OAYVAL.UE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKE: (optional)

AND CAS NUMBER A. S.SE* C. BE-(if available! (if available} TEST* Lt!NEO LIEVEO O.NO.OF (If available) INGRE* PRE-AS- {1} ANAL* A.CONCEN* B. MASS A. LONG 'l'ERMAVHG. B. NO QUlRED SENT SENT (2)MA$S (1) (2)MASS (1) TRATION VALUE OF CONCENTRATION CONCEN'I'RATION CONCENTRATION (2) 1M$$ YSES (1) (2) ANAL* GC/MS FRACTION -VOLATILE COMPOUNDS CONCENTRATION MASS YSES 1V. Acrolein (107-02-8} 0 0 181 2V. Acrylonitrile 0 0 121 (107-13-1) 3V. Benzene (71-43-2) 0 0 181 4V. Bis {Chloromethyl} D 0 181 Ether (542*88-1) 5V. Bromoform 0 D 181 (75-25-2) 6V. Carbon Tetrachloride 0 D 181 (56-23-5) 7V. Chlorobenzene 0 0 181 {108-90-7) $V. Chlorodlbromomethane 0 0 181 {124-48-1) 9V. Chloroethane 0 0 181 (75..00-3) 1 OV. 2-Chloroethylvinyl 0 0 0 Ether (110-75*8) 11V. Chloroform {67-66-3) 0 0 !8J 12V. Dichlorobromomethane 0 0 181 (75-27-4) 13V. Dichloro-0 0 181 difluoromethane (75-.71-8) 14V. 1,1 - Dichloroethane 0 0 181 (75-34-3) 15V. 1.2 Dichloroethane 0 0 181 (107-()6-2) 16V. 1,1 - Dichloroethylene 0 0 181 (75*35-4) 17V. 1,2-Dichloropropane 0 0 r8l I (78-87-5} 18V. 1,2 -Dichloropropylene 0 0 (81 {542-75-6) 19V. Ethylbenz:ene 0 0 181 (100-41-4) 20V. Methyt Bromide 0 "0 181 (74-83-9) 21V. Methyl Chloride 0 0 [81 {74-87-3) M078

6 6- '

0 151 ( 04) PAGE;\\ CONTlNUE ON PAGI: 4 Enclosure to ULNRC-06027

I NPDES #(IF ASSIGNED) ~ OUTFALL NUMBER l CONTINUED FROM THE FRONT M0-0098001 012 2.MARK"X"

3. EFFLUENT A. MAXIMUM DAILY VALUE

a. MAXIMUM 30 DAY VALUE C. L()NG TERM AVRG. VALUE

4. UNITS 5.1NTAKI;(

1.POLLUTANT A. e.ec-c.ee- {If available} (if available} AND CAS NUMBER TEST* LIEIIED LIE\\IEO D.NO.OF A.CONCEN* B. MASS A. LONG IERMAVR (if available} INGRE:* PRE* AS-(1) (1} (1) ANAL-TRATION VALUE QUIREO SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS YSES (1) CONCENTRATION G optional) B. NO OF -~ ANAl..* MASS vses GC.MS FRACTION-VOLATILE COMPOUNDS (continued) 22V. Methylene Chlor1de 0 0 ~ (75-09-2) 23V.1,1,2.2-Tetra-0 0 l8l chloroethane (79-34-5) 24V. Tetrachloroethyiene 0 0 l8l (127-18-4) 25V. Toluene 0 0 181 (108-88-3} 26V. 1,2-Trans 0 0 181 Dichloroethylene (156-60*5) 27V. 1,1,1-Tri-0 0 181 chloroethane (71-55-6) 28V. 1,1,2-Tri-0 0 121 chloroethane (79-00-5) 29V. Trichloro - 0 0 £8l ethylene (79..01-6) 30V. Trichloro-0 0 181 tluoromethane (75-69-4) 31V. Vinyl 0 0 IZI Chloride (75-01-4) GC/MS FRACTION-ACID COMPOUNDS lA. 2-Chlorophenol 0 0 ~ (95-57-8} 2A. 2,4-Dichforo - 0 0 [gJ phenol (120-83-2) 3A. 2,4 - Dimethyl-0 0 I2SJ phenol (105-67-9} 4A 4,6 - Dinitro - 0* 0 0 fZ.I Cresol (534-52-1) SA, 2.4-OJ nitro-0 0 lEI phenot (51*28-5) 6A. 2-Nitrophenol 0 0 lEI (88-75-5) 7 A. 4-Nitrophenol 0 0 IZI (100-02-7) 8A. P-Chforo - M 0 0 [gJ C;esol {59-50-7) 9A. Pentachloro - 0 0 l8l phenol {87-86-5_ 10A. Phenol 0 0 l8l (108-952) 11A. 2,4,6 ~ Trichloro-0 0 fZ.I phenol (88-00-2) MO 7SO*l516 {6-i'l4) !> AGE<! CONTIN UEONI>AGE5 Enclosure to ULNRC-06027

CON'fiNUIED FROM THE FRONT 2.MARK"X"

1. POllUTANT A.

e.ar:;- C. BE-AND CAS NUMBER res*r. I..IEVEO LlE\\fED (if <J.vas1abfe} INGP.E* PRE* A.B. IRED SENT St:NT GC/MS FRACTION ~BASE/NEUTRAL COMPOUNDS 1 B. Acenaphthene {83-32-9} 0 0 ~

28. Acenaphtylene (208-96-$)

0 0 (81

38. Anthracene (120-12*7}

0 0 ~

48. Benzidine (92-87-5) 0 0

[??J

58. Benzo (a) 0 0

t8l Anthracene (56*55-3)

68. Benzo {a}

0 0 IZl Pyrene (50-32-8)

78. 3,4 - Benzofluoranlhene 0

0 (E) {205-99-2)

88. Benzo (ghi)

D 0 (E) Perylene (191*24-2)

98. Benzo (k) 0 0

I2J Fluoranthene (207-QS-9) i OB. Bis {2-Chloroethoxy) D 0 1:81 Methane {111*91-1) 11 B. Bis (2-Chloroethyl) 0 0 IZI . Ether (111-44-4) 128. Bis (2-Chloroisopropyl) 0 0 1:81 Ether (39638-32-9) 138. Sis (2-Ethylhexyl) 0 0 181 Phthalate (117-81-7} 148. 4-Bromophenyl 0 0 ~ Phenyl Ether {101-55-3) 158. Butyl Benzyl 0 0 l2l Phthalate (85-68-7} 168. 2-Chloronaphthalene 0 0 IZl (91-58-7) 178. 4-Chlorophenyl 0 0 ~ Phenyl Ether (7005*72-3) 188. Chrysene 0 D

18)

(218-01-9) 198. Dibenzo (a.h) 0 0 fZI Anthracene (53-70-3} 208. 1,2 -Dichlorobenzene 0 0 181 (95-50-1} 21 B. 1,3 - Dichlorobenzene 0 0 [gJ (541-73-1} MO 7SO-IS1(>(6*04i 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. t.ONG TERM AVRG. VALUE {If avaifablel (if available) D. NO. OF (1) (1) {1) ANAL* CONCENTRATION (l!)MASS CONCENTRATION {2)MASS CONCENTAATION (2}MASS YSES PAGES 4.UNITS A.CONCEN* B. MASS TRA'RON S.INTAKE (optional) A. LONG TERMAVF: VALUE [1) CONCENTRATION CONTJ G. (2) MASS B. NO OF ANAL* YSES Enclosure to ULNRC-06027

CONTINHF:O fROM PAGF; 5 I NPOES #(IF ASSIGNED) M0-0098001 l OUTFALL NUMBER 012 2.MARK"X" 3.EFFLUENT A. MAXIMUMDAILYVALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNOTS 5.JNTAKJ!(

1. POlLUTANT A.

B. BE* c.ae-(if available) (if available) D. NO. OF AND CAS NUMBER TeST* LIEVEO u~o A.CONCEN- £!.MASS A. LONG TJ:;RM AV.':?. (if available) INGRE* PRE* A6- {1} (1) (1. ANAL-TRATION VALUE QutRED SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS YSES (1) CONCENTRATlOlli G optional) B. NO OF

m-ANAL*

1~$ YSES GC/MS FRACTION-BASEJNEUTRAL COMPOUNDS (continued) 228. 1, 4-Dichlorobenzene 0 0 l8l (106-46*7) 238. 3, 3'-Dichlorobenzidine 0 0 l81 {91-94-1} 24R Diethyl Phthalate 0 0 l81 (84-66-2) 258. Dimethyl Phthalate 0 D t8l (131-11-3) 268. Di-N-butyl Phthalate 0 0 181 (84-74-2) 278. 2.4-0initrotoluene 0 0 l81 (121-14-2) 288. 2,6-0initrotoluene 0 0 181 (606-20-2) 298. Oi-N-Octyi Phthalate 0 D 1:81 {117-84-0) 308. 1.2-Diphenylhydrazine 0 0 [83 (as Azobenzene) ( 122-66-7) 31 B. Fluoranthene 0 0 l8l (206-44-0) 328. Fluorene 0 0 l8l (86-73-7) 336. Hexachlorobenzene 0 0 l81 (87-68-3} 346. Hexachlorobutadiene 0 0

~

(87-68-3) 358. Hexachloro* 0 0 IZ1 cyclopentadiene ( 77-4 7-4) 368. Hexachloroethane 0 0 I2SI {67-72-1) 378. lndeno {1,2,3-c*d) 0 0 l8l Pyrene (193-39-5} 388. lsophorone 0 0 181 (?i~-59-1) 396. Naphthalene 0 0 121 {91-20-3) i 408. Nitrobenzene 0 D l:8l (98-95*3) 41 B. N-Nitl'o-0 0 [8J sodimethylamine (62-75-9) 428. N-Nitroso 0 0 I2SI N-Propyiamine (621-64-7) MO 780-IS!t'l (6*04~ PAGE6 CONTll'. Ut;:*ON PAGE 7 Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.MARK"X" A. MAXIMUM DAIE.YVALUE

1. POlLUTANT A.

a.eu:;. c.ae-AND CAS NUMBER TEST* UEVEO LIEVEO {if available) INGRE-PRE* AS.. {1) QUIREO SENT SENT COOCENTRA'OON {2}MASS GCIMS FRACTION... BASE/NEUTRAL COMPOUNDS (continued) 438. N-Nitro-sodfphenylamine (86-30*6) 0 0 181 448. Phenanthrene (85..01-8) 0 0 t:8I 458. Pyrene 0 0 £81 (129-QO..Q) 468. 1,2,4-Tri D 0 ~ ch!orobenzene { 120-82-1) GC/MS FRACTION-PESTICIDES 1P.Aidrio 0 0 ~ (309..00-2) 2P. o-BHC 0 0 ~ (319-84-6} 3P. 13-BHC 0 D 181 (319-84-$) 4P. y-BHC 0 0 123 (58-89-9} 5P. o-BHC 0 0 181 (319-86-8} 6P. Chlordane 0 0 18] (57-74-9) 7P. 4,4'-DDT 0 0 r8l {50*29*3) 8P. 4.4'-DDE 0 0 (8l {72-55*9) 9P. 4,4'-DDD 0 0 [81 (72-54-8} 10P. Dieldrin 0 0 [81 (60-57-1) 11 P. a-Endosulfan 0 0 [81 (i 15-29-7) 12P.f3-Endosullao 0 0 ~ (115-29-7) 13P. Endosulfan Sulfate 0 0 1:81 (1031...07-8) 14P. Eodrin 0 0 jgl (72-20-8) 15P. Endrin Ardehyde 0 0 [gl (7421-93-4) 16P. Heptachlor 0 0 1:81 (76-44-8) M07SO.bl6(6-04) 3.EFFLUENT

a. MAXIMUM 30 DAY VALUE C. LONG TERM AV~f* VALUE (if available}

(if available D. NO. OF (1) (1) ANAL* CONCENTRATION i2lMASS CONCENTRATION (2)MAS$ YSES PAGE7 4.UNrrs A.CONCEN* B. MASS TRATION 5.1NTAKE( optional) A. LONG TERM AVR: G. VALUE (1) CONCENTRATION {2) MASS CONTINUED ON PA< :ms B. NO OF ANAL* YSES Enclosure to ULNRC-06027

CONTTMlRO FROM PAGE 7 I NPDES #{IF ASSIGNE:D) M0-0098001 I OUTFALL NUMBER 012 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE (

1. POLLUTANT A.

6.6E* c.ee-(if available) . (if avallabii'J) AND CAS NUMBER TEST* LIEVEO UEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVR {If available} INGRE* PRE* AS- {1) (1) {1) ANAL* TRAnON VALUE QUIREO SENT SENT CONCENTRATION (:t)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS YSES I (1) CONCENTRATION 0 ptianal) B. NO OF .12')" ANAL-IMSS YSES G GC/MS FRACTION - PESTICISES (continued) 17P. Heptachlor 0 0 C8J Epoxide (1024-57-3) 18P. PCB-1242 0 0 l2l {534$9-21-9) 19P. PBC-1254 0 0 l2l (11097-69*1) 20P. PCB-1221 0 0 181 {11104-28-2) 21P. PCB-1232 0 0 [8] {1114H6-5) 22P. PCB-1248 0 D t8l (12672-29*6) 23P. PCB-1260 0 0 l'8l (11098-82*5) 24P. PCB-1016 0 0 I8J (12674-11-2) 25P. Toxaphene 0 0 l25J (8001-35-2) I l MO 780*1~16 (6-WJ Enclosure to ULNRC-06027

APPliCATION FOR DISCHARGE PERMIT FORM D - PRIMARY INDUSTRIES NPDES #{IF ASSIGNED) M0-0098001 TABLE tl I OUTFALL NUMBER 014 1 30 If you are a primary industry and this outfall contains process wastewater refer to Table A in the instructions to determine which of the GC/MS fractions you must t<< Mark "X" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "X" in column 2-B for e ~st for.

~.ch poflutant you know or have reason to believe is present. Mark "X>> in column 2-C for each pollutant you believe to be absent. ff you mark either columns 2-A or 2-*

pollutant, you must provjde the results of at least one analysis for that potrutant. Note that there are seven pages to this part, please review each carefully. Compl for any 8 table (all seven pages) for each outfall. See instructions for additional details and requirements. ~te one 2:.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE

6. MAXIMUM 30 o~r VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE(

1. POLLUTANT B. BE*

C. BE* (if available (if available) D.NO.OF AND CAS NUMBER A TEST* LIEVEO ueveo A.CONCEN* B. MASS A. LONG TERM AVF: (if available} INGRE* PRE* AB-(1} (1) ANAL* TRATION VALUE QUIREO SENT SENT (1) (2)MASS (2)MASS {2}MASS YSES CONCENTRATION CONCENTRATION" CONCENTRATION (1) CONCENTRATION ,ptional) B. NO OF

~ ANAL*

IAASS YSES 0 G METALS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total 0 D l8l (7440-36-9) 2M. Arsenic, Total 0 D l8l (7 440-38-2) 3M. BeryiHum, Total 0 0 l8l (7 440-41-7) 4M. cadmium, Total D 0 ~ (7440-43-9} SM. Chromium, Total D 0 l8l (7440-47-3} 6M. Copper, Total 0 0 l8l (7550-50-8) 7M. Lead, Total 0 D l8l {7439-97-6} SM. Mercury, Total (7439-97-6) 0 0 l8l 9M. Nickel, Total 0 0 l8l (7440-02-0) 10M. Selenium, Total 0 D l8l (7782-49-2) 11M. Silver, Total 0 D l8l {7440-22-4) 12M. Thallium. Total D D l8l {7440-28-0) 13M. Zinc, Total 0 0 l8l (7 440-66-6) 14M. Cyanide, Total 0 0 12:1 {57-12-5) 15M. Phenols, 0 0 l8l Total DIOXIN 2,3,7,8-- Tetra-I I I DESCRIBE RESULTS chlorodibenzo-P-0 I 0 l8l Dioxin (1764-01-6) MO 780-1516 (6*04) PAGE2 Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3 2.MARK"X" 3.EFFI..UENT A. MAXfMUM OA!LY VALUE B, MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE. (optional}

1. POLLUTANT A.

S.BE* C.E!E* (if available) (if available} AND CAS NUMBER TEST-I.IEVEO LIE.VEO O.NO.OF A.CONCEN-B. MASS A. LONG TERM AVRGi. B. NO (if available) INGRE.~ PRE* AS-(1} (1) (1) ANAL* TRATION VALUE OF QUI REI:> SENT SEMI" CONCEHTRA110M (2) MASS CONCENTRATION (2)MA$$ CONCENTRATION (2)MAS$ YSES

--w-ANAL*

(1) YSES CONCENTRATION MASS GC/MS FRACTION-VOLATILE COMPOUNDS 1 V. Acrolein 0 0 ~ (107-Q2-8) 2V. Acrylonitrile 0 0 181 (107-13-1) 3V,Benzene 0 0 r8.1 {71-43*2) 4V. Bis (Ch/oromethyl) 0 0 I2SI Ether {542...S8-1) 5V. Bromoform 0 0 I2SI (75-25-2) 6V. Carbon Tetrachloride 0 0 r8.1 (56-23-5) 7V. Chlorobenzene 0 0 r8.1 (108-90-7) SV. Chforodibromomethane 0 0 l8J (124-48-1) 9V. Chloroethane 0 0 181 (75-Q0-3) 10V. 2-Chloroethylvinyi 0 0 l8l Ether (110-75-8} 11V. Chloroform 0 0 [81 (67-66-$) 12V. Dichlorobromomethane 0 0 lEI (75~27-4) 13V. Dlchloro-0 0 lEI difluoromethane (75-71-8) 14V.1.1-Dichloroethane 0 0 l8l (75-34-3) 15V. 1,2 ~ Dichloroethane 0 0 ~ (107-06-2} 16V. 1,1-Dichloroethylene 0 0 l2l (75-35-4) 'i 7V. 1,2 -Diehl oro propane 0 0 IZl (78-87-5) 18V. 1,2 -Dichloropropylene 0 0 rzJ {542-75-6) 19V. Ethyl benzene 0 0 l8l (100*41-4} 20V. Methyl Bromide 0 0

18l

{74-83*9) 21V. Methyl Chtoride 0 0 i8J (74-87-3} MO 7&0.!516 (6-04) PAGE> CONTI ~UE ON ?AGE 4 Enclosure to ULNRC-06027

I NPDES #(IF ASSIGNED) I OUTFAll NUMBER l CONTINUED FROM THE FRONT M0-0098001 014 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE

a. MAXIMUM 30 D~i VALUE C. tONG TERM AVRG. VALUE

1. POLLUTANT A.

a.ae. C.SE* (if available (if available} AND CAS NUMBER TEST* LIEVED LtEVED (If available) INGRE* PRE* AS-(1) (1) (1) QUIREO SENT SENT COHCENTRA liON (2)MASS CONCEHTRATlON (2)MA$S CONCENTRATION (2}MASS GC.MS FRACTION-VOlATILE COMPOUNDS (continued) 22V. Methylene Chloride (75-09-2) 0 D 181 23V. 1.1.2,2-Tetra-0 0 181 chloroethane (79-34-5} 24V. Tetrachloroethylene 0 0 181 (127-18-4) 25V. Toluene 0 0 181 (108-88-3) 26V. 1,2-Trans 0 0 [8J Dichloroethylene (156-60-5} 27V.1.1,1-Tri-0 0 181 chloroethane (71*55-6) 28V. 1,1,2-Tri* D 0 181 chloroethane (79-00-5) 29V. Trichloro-0 0 181 ethylene {79.01-6) 30V. Trichloro-0 0 181 fluoromethane (75-69-4} 31V. Vinyl 0 D 181 Chloride {75.01-4) GC/MS FRACTION-ACID COMPOUNDS 1 A. 2 - Chlorophenol 0 0 181 (95-57-8) 2A. 2,4 - Dichloro-0 0 181 phenol (120-83*2) 3A. 2.4 - Dimethyl - 0 0 [81 phenol ( 1 05-67 *9) 4A. 4,6 - Oinitro 0 0 181 Cresol (534-52-1) SA. 2.4-Oinitro-0 0 IZl phenol (51-28-5} 6A. 2-Nitrophenol 0 0 12?1 {88-75-5) 7 A 4-Nitrophenol 0 0 181 (100-02-7} SA. P-Chloro - M 0 0 181 Cresol ( 59-50-7) 9A. Pentachloro - 0 0 [8J phenol (87-86-5 10A. ?henof 0 0 181 (108~952) 11A. 2.4.6-Trichloro-0 0 181 phenol (88*06*2) MO 780-1516 (6-04) PAGE4

4. UNITS"'

D. NO. OF A.CONCEN* B. MASS ANAL* TRATION YSES 5.1NTAKE{' A. LONG TERM AVR~ VALUE (1} CONCENTRATION (2) MASS

a. NO OF ANAL*

YSES CONT!N~ SEON PAGES Enclosure to ULNRC-06027

CONTiNUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE

8. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4, UNITS S.INTAKE {*'Jptional}

1.POLLUTANT A. a.ee-c.aE-(if avaffabtel . (if available} AND CAS NUMBER TEST-LIE'Itl;C t.I!OVED D. NO. OF A.COI\\ICEN* B. MASS A. LONG TERM AVRG. B. NO {if available) INGRE-i>RS* AS-j1} {1} (1) ANAL-TRATION VALUE OF QUIREO SENT SENi CONCENTRATION: (2jMASS CONCENTRATION (2}MASS CONCENTRATION (2}MASS YSES -"(i") ANAl.* (1) YSES CONCENTRATIOt; MASS GC/MS FRACT80N-BASE/NEUTRAL COMPOUNDS 1 B. Acenaphthene 0 D l8l (83-32-9)

28. Acenaphtylene 0

0 ~ (208-96..S} 3B. Anthracene 0 0 l8l (120-12-7} 4B. Benzidine 0 0 IZl (92-87-5)

58. Benzo (a) 0 0

181 Anthracene (56*55-3} $8. Benzo {a} 0 0 I2?J Pyrene {50-32-8)

78. 3.4 - Benzofluoranthene 0

0 181 (205-99-2)

88. 8enzo (ghi) 0 0

181 Perylene (191-24-2}

98. Benzo (k) 0 0

181 Fluoranthene (207..Q8-9) 106. Sis (2-Chloroethoxy} 0 0 lZl Methane {111*91-I) 11 B. Bis (2-Chloroethyl) 0 0 l8l Ether (111-44-4} 128. Bls (2-Chioroisopropyl) 0 0 IZl Ether (39638-32-9) 13B. Bis (2-Ethylhexyl) 0 0 ~ Phthalate { 117-8 1-7) 14B. 4-Bromopheny! 0 0 IZI Phenyl Ether (101-65-3) 158. Butyl Benzyl 0 0 ~ Phthalate (85-68-7) 166. 2-Chloronaphthalene 0 D ~ (91-58-7) 178. 4-Chlorophenyl 0 0 18] Phenyl Ether {7005-72-3) 188. Chrysene 0 0 181 (218-01-9} 19B. Dlbenzo (a.h) 0 0 t8l Anthracene (53-70-3) 206. 1,2-Dichlorobenzene 0 0 l8l (95-00-1) 218. 1,3-Dichlorobenzene 0 0 ~ (541-73-1) MO 78().1516 (6-04) PAGES CONTtNUE ON PAGE 6 Enclosure to ULNRC-06027

CONTINUF.D FROM PAGI;:5 I NPDES # (IF ASSIGNED) I OUTFALL NUMBER M0-0098001 014 Z.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VAlUE

8. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.!NTAKE{<

1. POLLUTANT A.

B. BE* C. BE* {if available) {if<Jvailable) AND CAS NUMBER TEST* LIEVED LIE\\'1;0 D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG (If availab~) INGRE* PRE* AB-(1) (1) {1} ANAl.* TRATfON VALUE QUI REO SENT SENT CONCENTRATION {2}MA$$ CONCENTRATION (2)MA$$ CONCENTRATION (2)MASS YSES (f) CONCENTRATION 1ptionaf) B. NO OF

~

ANAL* MASS YSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS (continued) 228. 1, 4-Dichlorobenzene 0 0 l8J {106-46-7) 238. 3, 3'-Dichlorobenzidine 0 0 l8J (9'1-94-1) 248. Diethyl Phthalate 0 0 IZI (84-66-2) 258. Dimethyl Phthalate 0 0 [8'J (131-11-3) 268. Di-N-butyl Phthalate 0 0 t8l (84-74-2} 278. 2,4-Dinitrotoluene 0 0 t8l (121-14-2) 288. 2,6-Dinitrotoluene 0 0 t8l (606-20-2) 298. Di-N-Octyl Phthalate 0 0 IZI (117-84..0) 308. 1,2-Diphenylhydrazine 0 0 I8J (as Azobenzene) (122-66*7) 31 B. Fluoranthene 0 0 l8l (206-44-0) 326. Fluorene 0 0 l8l (86-73-7) 338. Hexachlorobenzene 0 0 (2J (87-68-3) 348. Hexachlorobutadiene 0 0 1:81 (87-68-3} 358. Hexachloro-0 0 l'8l cyclopentadlene {77-47-4) 368. Hexachloroethane 0 0 t8l {67~72-1) 378. lndeno (1.2,3-c-d) 0 0 IZI Pyrene { 193-39-5) 386. lsophorone 0 0 IZI {78-59-1) 396. Naphthalene 0 0 (81 (91-20-3) 406. Nitrobenzene 0 0 18'.1 (98-95--3) 418. N-Nitro-0 0 IZI sodimethylamine (62-75-9} 426. N-Nitroso 0 0 IZI N-Propylamine {621-64-7) MO 780-1516 (6-04) PAGE6 CONTINI JEON PACE 7 Enclosure to ULNRC-06027

CONTiNUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT A. MAXIMUM OAil Y VALUE S. MAXIMUM 30 CAY VALUE C. LONG TERM AVRG. VALUE

4. UNITS 5.1NTAKE (optional}

1. POLLUTANT S.l.'lE*

C.EIE* (if avaltable) {if available] AND CAS NUMBER LIEVEO Lf!NEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVRG. B. NO {if available) PRE* All-(1} {1} {1) ANAL* TRATION VALUE OF QUIREO SENT SENT CONCENTRATION (.<!JMA$5 COHCENTRATION (2)MASS CONCSNTRATIQN (2)MASS VSES ANAL* (1) (2} YSES CONCENTRATION 11AASS GC/MS FRACTION-BASEJNEUTRAl COMPOUNDS (continued) 438. N-Nitro-0 0 121 sodiph-enylamine (86-30-6) 448. Phenanthrene 0 0 121 (85..01-8} 458. Pyrene 0 0 121 (129-00..0} 468. 1.2.4-T ri 0 0 121 chlorobenzene (120-82*1} GC/MS FRACTION " PESTICIDES 1P. Aldrin 0 0 12$1 (309-00*2) 2P. a-BHC 0 0 121 {319-84*6} 3P. !)-BHC 0 0 1&'1 (319-84-6) 4P. y-BHC 0 0 121 {58-89-9) SP. ~-BHC 0 0 121 (319-86-8) 6P. Chlordane 0 0 181 {57-74-9) ?P. 4,4'-DOT 0 0 121 {50-29*3) 8P. 4,4'-DDE 0 0 181 {72-55*9) 9P. 4,4'-DDD 0 0 t8J (72*54*8} 10P. Dieldrin 0 D [81 {60-57-1) 11 P. a-Endosulfan 0 0 121 (115-29-7) 12P. 13-Endosultan 0 0 ~ (115-29-7) 13P. Endosulfan Sulfate 0 0 ~ {1031-07-13) 14P. Endtin 0 0 181 {72-20-8} 1SP. Endrin Aldehyde 0 0 [81 (7421-93-4} 16P. Heptachlor 0 0 IZJ (76-44-8} M07&0-!516(6-04) PAGE7 z CONTINUED ON PAGt S Enclosure to ULNRC-06027

CONTINlJF.O FROM PAGF: 7 I NPDES # (IF ASSIGNED) I OUTFALL NUMBER I M0-0098001 014 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE(

1. POlLUTANT A.

B. BE* C. BE* (If available) tif available) AND CAS NUMBER TEST* LIEVED t.IEVEO D. NO. OF A.CONCEN* B. MASS A. lONG TERM AVF: (if availabfe) INGRE* PRE* Afl.. (1) (1) {1} ANAL* TRATION VALUE QUlRED SENT SEM'I' CONCENTRATION {2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS YSES (1} CONCENTRATION ptional) B. NO OF

~ ANAL-MASS YSES 0

G GC/MS FRACTION-PESTICISES (continued} 17P. Heptachlor 0 0 181 Epoxide (1024-57-3) 18P. PCB-1242 0 0 l8l (53469-21-9) 19P. PBC-1254 0 0 12$] (11097-69-1) 20P. PCS-1221 0 0 12$] {11104-28-2) 21 P. PCB-1232 0 0 C8J (11141-16-5) 22P. PCB-1248 0 0 181 (12672-29-6) 23P. PCB-1260 0 0 C8J (11096-82-5) 24P. PCB-1016 0 0 121 (12674-11-2) 25P.Toxaphene 0 0 t8l (8001-35-2) MO 7&0*1:>16 (6-04) I'ACicS Enclosure to ULNRC-06027

1.30 APPLICATION FOR DISCHARGE PERMIT FORM D-PRIMARY INDUSTRIES TABLE II NPDES #(IF ASSIGNED) I OUTFALL NUMBER M0-0098001 015 If you are a primary industry and this outfall contains process wastewater, refer to Table A in the instructions to detennine which of the GC/MS fractions you must Mark "X" in column 2-A for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "X" in column 2-B for 1st for. JCh te ea B fe pollutant you know or have reason to believe is present. Mark "X" in column 2-C for each pollutant you believe to be absent. If you mark either columns 2-A or 2** for any porlutant, you must provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Comp teone table (a// seven pages) for each outfall. See instructions for additional details and requirements. 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE(

1. POLLUTANT B. BE*

C. BE* (if available) (If available} AND CAS NUMBER A. TEST* LIEVED LIEVED D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVFt (if available) INGRE-PRE* AS-(1) (1) (1) ANAL* TRATIOH VALUE QUJREO SENT SENT CONCENTRATION (2}MASS CONCENTRATION (2)MASS CONCENTRATIOH (2)MASS YSES {1) CONCENTRATION 0 [.>tiona/} B. NO OF -~ ANAL* ASS YSES G METALS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total 0 0 ~ (7440-36-9) 2M. Arsenic, Total 0 0 121 (7440-38-2) 3M. Beryllium, Total 0 0 121 {7 440-41-7) 4M. Cadmium, Total 0 0 121 (7 440-43-9} SM. Chromium, Totaf 0 0 t8J (7 440-4 7 -3) 6M. Copper, Total 0 0 181 J7550-50-8) 7M. Lead, Total 0 0 181 (7 439--97 -6) SM. Mercury, Total 0 0 121 {7439-97-6) 9M. Nickel, Total 0 0 121 (7 440-02-0) 10M. Selenium, Total 0 0 ~ (7782-49-2) 11M. Silver. Total 0 0 181 (7440-22-4) 12M. Thallium, Total 0 0 l8l (7440-28-0) 13M. Zinc, Total 0 0 ~ (7 440-66-6) 14M. Cyanide, Total 0 0 181 {57-12-5) 15M. Phenols, 0 0 181 Total DIOXIN 2,3,7,8-Tetra ?l I 181 I DESCRIBE RESULTS chlorodibenzo-P-0 Dioxin (1764..01-6} MO 7&0-1516 (6*04} PAG E2 Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3 2.MARK"X" 3.EFFLUENT A. MAXIMUMOAILYVA!..UE B. MAXIMUM 30 DAY VALUE C. t.ONG TERM AVRG. VALUE 4.UNITS

5. INTAKE {optional)

1. POLLUTANT A..

S.S£. C.SE- {If available} {if avaitabl?}_ AND CAS NUMBeR TES'f* t.IEVEO UEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM A\\IRG. B. NO (if available) JNGRE-PRE* As. (1) (1) (1) ANAL* TRATION VAlUE OF QUIRED SENT SENT CONCENTAATION (2)MASS CONCENTRATION {2}MASS CONCENTRATION (2]MASS YSES --m-- ANAL* (1) YSES CONCENTRATION MASS GC/MS FRACTION-VOLATILE COMPOUNDS 1 V. Acrolein D D 181 (107*02*8) 2V. Acrylonitrile D D 181 (107-13-i) 3V. Benzene 0 0 181 (71-43-2) 4V. Bis (Chforomethyl) 0 0 1:81 Ether (542..SS-1} 5V. Bromoform D 0 l8l (75-25-2) 6V. Carbon Tetrachloride 0 0 12$] (56-23-5} 7V. Chlorobenzene 0 0 121 (108-90-7} BV. Chlorodibromomethane 0 0 121 (124-48-1) 9V. Chloroethane 0 0 I8J (75-Q0-3) 1 OV. 2-Chloroethylvlnyl 0 0 [8J Ether (110~75-8) 11V. Chloroform 0 0 !81 (67-66-3) 12V. Dichlorobromomethane 0 0 181 (75-27-4) 13V. Dichloro-0 D !8l difluoromethane (75-71-8) 14V. 1,1 - Dichloroethane 0 D [21 (75-34-3) 15V. 1.2-Dichloroethane 0 0 lZI (107-06-2) 16V. 1,1 - Dichloroethylene 0 0 l8l (75~35-4} 17V. 1.2 - Oichioropropane 0 0 l8l {78-87-5) 18V. 1,2 -Dichloropropylene 0 0 l8l (542-75-6) 19V. Ethylbenzene 0 0 ~ (100-41-4) 20V. Methyl Bromide 0 0 IZJ (74-83-9) 21V. Methyf Chloride 0 0 181 (74-87-3) MO 780-1:>16 (6-041 P GE3 A CONTINUE ON PAGE 4 Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT I NPDES # (IF ASSIGNED) M0-0098001 I OUTFALL NUMBER 015 I 2.MARKX" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VAlUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE (

1. POLLUTANT A.

B. BE* C. BE* (If available} (if available) AND CAS NUMBER TEST* LIE. \\fED I.IEVEO D. NO. OF A.CONCEN*

e. MASS A. LONG TERM AVFt (if avallabfe)

INGRE* AAE* AS-(1) (1) (1) ANAL-TRATtON VALUE QUI RED SENT SENT CONCENTRATION {2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS YSES (1) CONCENTRATION G. Jtional) B. NO OF ~ ANAL-lASS YSES 01 GC.MS FRACTION-VOlATILE COMPOUNDS (continued) 22V. Methylene Chloride 0 0 181 (75-09-2) 23V. 1,1,2,2-Tetra-D D 181 chforoethane {79-34-5) 24V. Tetrachloroethylene D 0 181 {127-18-4) 25V. Toluene 0 0 l8l (108-88*3) 26V. 1,2-Trans D 0 l8l Oichloroethylene ( 156-60-5) 27V. 1, 1,1 - Tri - 0 0 ~ chloroethane (71-55-6) 28V. 1.1.2-Tri-0 D 181 chloroethane (79*00-5) 29V. Trichloro - 0 0 181 ethylene ( 79-0 1-6) 30V. Trlchloro-0 0 181 fluoromethane (75-69-4) 31V. Vinyl 0 0 IZJ Chloride (75-01-4) GC/MS FRACTION-ACID COMPOUNDS 1A. 2-Chlorophenol 0 0 rzl (95-57-8) 2A. 2,4 - Dichloro-0 0 181 phenol {120-83-2} 3A. 2,4 - Oimethyt-0 0 rzl phenoi {105-137-9) 4A. 4,6 - Dinitro 0 0 181 Cresol {534-52-1} 5A. 2.4-Dinitro-0 0 181 phenol {51-28-5) 6A. 2-Nitrophenol 0 0 £8)' (88-75-5) 7A. 4-Nitrophenol D 0 12! (100*02*7} 8A. P-ChJoro - M 0 0 0 Cresol (59-50-7) 9A. Pentachloro-0 0 !21 phenol {87-86-5 10A. Phenol 0 0 121 (108-952) 1 '!A. 2.4,6-Trichloro-0 0 181 phenol (88*00*2) M07S0..15l6(6-04) PA0£:4 c ONT!N UEON PAGE;, Enclosure to ULNRC-06027

CONTINUED FROM THE FRONT 2.1\\itARK"X" 3.EFFLUENT A. MAXIMUMOAilYVALUE B. MAXIMUM 30 DAY VALUE C. tONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE (optional)

1. POlLUTANT A.

B. BE-C.Bl!* {if <Jvailable) (if available} AND CAS NUMBER res*r. LIE \\leD LIE \\!EO O.NO.OF A.CONCEN* B. MASS A. LONG TERM AVRG. B. NO {if iiiV<tilabfe) INGRE* PRE* J>.a.. (1) (1) {1) ANAL* TRATION VALUE OF QUIRE!) SENT SENT CONCENTRATION {2)MASS CONCENTRATION {2}MASS CONCENTRATION (2)MASS YSES

--m-ANAL*

(1l YSES CONCENTRATION MASS GCJMS fRACTiON-BASE/NEUTRAL COMPOUND$ 1 B. Acenaphthene 0 0 f8l (83--32-9) 2B. Acenaphtylene 0 0 !8J (208-96-8) 3B. Anthracene 0 0 l8j {120-12-7)

48. Benzidine 0

0 l8'J {92-87-5)

56. Beozo (a) 0 0

l8l Anthracene (56*55-3}

68. Benzo (a) 0 0

C8J Pyrene (50-32-8)

76. 3.4-Benzofluoranthene 0

0 t8l (205-99-2)

86. Senzo (ghi) 0 0

181 Perylene (191-24-2)

98. Benzo (k) 0 0

~ Fluoranthene {207...()8~9) 106. Bis {2-Chloroethoxy) 0 0 ('gl Methane (111-91-1) 11 B. Bis (2-Chloroethyl) 0 0 l2?l Ether { 111-44-4} 128. Bis (2-Chloroisopropyl} 0 0 l8l Ether (39638-32-9) 138. Bls (:2-Ethylhexyl) D 0 l8l Phthalate (117-81-7} 148. 4-Bromophenyl 0 0 t8l Phenyl Ether {101-55-3) 158. Butyl Benzyl 0 0 [21 Phthalate {85-68-7) 168. 2..Chloronaphthalene 0 0 [81 (91-58-7) 178. 4-Chlorophenyl 0 0 IZI Phenyl Ether (7005-72-3) 18B. Chrysene 0 0 I2?J (218-01-9} 198. Dibenzo (a.h} 0 0 IZI Anthracene {53-70-3} 208. 1.2 - Dichfo(obenzene 0 0 IZI {95-50-1) 218. 1,3-Dichlorobenzene 0 0 I2?J (541-73-1) MO 7&0-1516 (6*04) p AGE 5 CONTINUIE ON PAGE 6 Enclosure to ULNRC-06027

CONTIN(JF.II) FROM PAGE 5 I NPDES #(IF ASSIGNED) M0-0098001 I OUTFAll NUMBER 015 2:.MARK"X" 3.EFFLUENT A. fJIAXIMUM DAILY VALUE

8. MAXIMUM 30 DAY VALUE C. LOt*G TERM AVRG. VALUE 4.UNtTS 5.1NTAKE{

1. POLLUTANT A.

B. BE* C. BE-lif available) {il available} AND CAS NUMBER TEST-t.IEVED LIEVED D.iNO.OF A.CONCEN-B. MASS A. LONG TERM AVR (if available) INGRE-PRE* AS- {1} (1) (1) ANAL* TRATION VALUE QUI RED SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCEtiTAATION (2)MASS YSES (1) CONCENTRAT!ON G.

tiona!)

B. NO OF

~ ANAL-ASS VSES 0{.

GC/MS FRACTION -BASE/NEUTRAL COMPOUNDS (continued) 228. 1, 4*Dichlorobenzene 0 0 [8J (106-46-7) 238. 3, 3'-Dichlorobenzidine 0 0 [8J (91-94-1) 248. Dlethyl Phthalate 0 0 l'8l (84--66-2) I 25B. Dimethyl Phthalate 0 0 f8] {131-11-3) 268. Di-N-butyl Phthalate 0 0 f8] {84-74-2) 278. 2.4-Dinitrotoluene 0 0 [g) (121-14-2) 288. 2,6-Dinitrotoluene 0 0 181 (606-20-2) 298. Di*N-Octyl Phthalate 0 0 f8] (117-84-Q} 308. 1,2-Diphenylhydrazine 0 0 f8] (asAzobenzene) (122-66-7) 31B. Fluoranthene 0 0 f8] {206-44-D} 328. Fluorene 0 0 IZJ (86-73~7} 33B. Hexachlorobenzene 0 I 0 IZJ (87--68-3) 348. Hexachlorobutadiene 0 0 f8] {87-68-3) 358. Hexachroro-0 0 lgj cyclopenladiene (77 4} 368. Hexachloroethane 0 0 l8J (67-72-i) 378. indeno {1,2,3-c-d) 0 0 (81 Pyrene (193-39-5) 388. rsophOrone 0 0 ~ (78-59-1) 398. Naphthalene 0 0 l8l (91-20-3) 408. Nitrobenzene 0 0 f8J {98-95-3} 418. N*Nitro-0 0 l8l sodimethylamine (62-75-9) 428. N-Nitroso 0 0 ~ N-Propylamine (621-64-7) f>AOE6 CONTINI MO 780-b !6 (6*04) JEON PAGE* Enclosure to ULNRC-06027

CONTINUED FROM THE fRONT 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TfRM AVRG. VALUE 4.UNIT$ 5.1NTAKE ~tlptional)

1. POLLUTANT A.

B. BE-C. BE* (if available} (if available} AND CAS NUMBER TEST* LIEVED l.IEVED D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVR<;t B. NO (if <W.aileble) INGRI::.. PRE* AS-(1) (1) (1) ANAL* TRATIDN VALUE OF IRED SENT SENT CONCENTRATION (2)MASS CONCENTRATION (2)MASS CONCENTRATION (2)MASS YSES -~ ANAL* (1, YSES CONCENTRATION MASS GC/MS FRACTION -BASE/NEUTRAl. COMPOUNDS (continued) 438. N-Nitro-0 0 1'81 sodiphenylamine (86-30-6) 448. Phenanthrene (85*01-8) 0 0 1'81 458. Pyrene o* 0 I'ZI (129-00-0) 468. 1,2,4-Tri 0 0 181 chlorobenzene (120-82*1) GC/MS FRACTION

PESTICIDES 1P. Aldrin 0

0 I'ZI (309-00*2) 2P. a.SHC 0 0 l'8l {319-84-6} 3P.j3-BHC 0 0 1'81 (319-84-6} 4P. y-BHC 0 0 l8l (58-89-9) 5P. o...aHC 0 0 (gJ (319-86-8) 6P. Chlordane 0 0 1'81 (57-74-9) 7P. 4,4'-DDT 0 0 [gl (50-29-3) 8P. 4,4'-0DE 0 0 (gJ (72-55-9) 9P. 4,4'-DDD 0 D ~ (72-54-8} 10P. Dieldrin 0 0 ~ (u0-57-1} 11P. a-Enctosulfan 0 0 IZI {115-29-7) 12P. 1)-Endosultan D 0 181 (1'15-29-7) 13P. Endosulfan Sulfate 0 D IZI {1031.07-8) 14P.Endrin 0 0 l8J (72-20-8} 15P. Endrin Aldehyde 0 D IZI (7421-93-4) 16P. Heptachlor 0 0 L8J (76-44-8) MO 7&0-1516 {6..{)4) PAGE7 CONTINUED ON PAGE 8 Enclosure to ULNRC-06027

CONTINl !ED FROM PAGE 7 I NPDES #{IF ASSIGNED) M0-0098001 I OUTFALL NUMBER 015 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS 5.1NTAKE(

1. POLLUTANT A.

e.ee-C. BE* (if available~ (if available) AND CAS NUMBER TEST* LIE \\leO LIEVED D. NO. OF A.CONCEN-B. MASS A. LONG TERM AVF: (if available) INGRE;- PRE* AS-(1) (1} (1) ANAL* TRATION VALUE QUIRED sem SENT CONCENTRATION (2)MASS CONCENTRATION (2}MASS CONCENTRATION (2)MASS YSES (1) CONCENTRATION G. 1tional) B. NO OF

~ ANAL*

ASS YSES M GC/MS FRACTION - PESTIC1SES {conti'nued) 17P. Heptachlor 0 0 l2l Epoxide (1024-57-3} 18P. PCB-1242 0 0 (81 (53469-21-9) 19P. PBC-1254 0 0 1.'81 (11097-69-1) 20P. PCB~1221 0 0 1.'81 ( 111 04-28-2) I 21P. PCB-1232 0 0 l2l {11141-16-5) i 22P. PCB-1248 0 0 l2l {12672-29-6) 23P. PCB-1260 0 0 t8J (11096-82-5) 24P. PCB-1016 D 0 1.'81 (12674-11-2) 25P. Toxaphene 0 0 t8J (8001-35-2) ( MO 780*15 16 {6..{)4) PAGES Enclosure to ULNRC-06027

1.30 APPLICATION FOR DISCHARGE PERMIT FORM 0- PRIMARY INDUSTRIES TABLE II NPDES #(IF ASSJGNED) I OUTFALL NUMBER M0-0098001 016 If you are a primary industry and this outfall contains process wastewater, refer toTable A in the instructions to determine which of the GC/MS fractions you must test f1 Mark "Xn in column 2-A for all such GCIMS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. Mark "Xv in column 2-B for eacr

>r.

pollutant you know or have reason to believe is present. Mark "Xn in column 2-C for each pollutant you believe to be absent. If you mark either columns 2-A or 2-B for pollutant, you rnust provide the results of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Complete .any 0 ne table {a// seven pages) for each outfall. See instructions for additional details and requirements. 2..MARK"X" 3.EFFLUENT A. MAXIMUM OAIL Y VALUE B. MAXlr~!!::!!i VALUE C. LONG TERM AVRG. VALUE 4, UNITS S.INTAKE (option

1. POLLUTANT B. BE*

C. BE* (ffWallllble) D. NO. OF AND CAS NUMBER A. TEST* UEVEO UEVED A.CONCEN-- B. MASS A. LONG TERM AVRG. (if <tv<nlab!(l) INGRE* PRE-AS- {1) {1) (1) ANAl.- TRATION VALUE QUI ReO SENT SENT CONC!<NTRATION (%)MASS CONCEN'rRAllON (2}MASS CONCENTRATION (2)MASS YSES (11 (2) CONCENTRATION ~* <IS) B.MO OF ANAL-YSES METALS, CYANIOE, AND TOTAL PHENOLS 1M. Antimony, Total 181 0

o.

<5.0 <0.042 1 UG/L LBS/D (7 440-36-9) 2M. Arsenic, Total 181 0 0 <10 <0.083 1 UG/L LBS/0 (7440-38-2) 3M. Beryllium, Total lli:l 0 0 <0.5 <0.004 1 UG/L LBS/D (7440-41~7) 4M. Cadmium. Total 121 0 D <0.5 <0.004 1 UG/l LBS/0 (744()-43-9} SM. Chromium. Total 181 0 0 <10 <0.083 1 UGJL LBS/D {7440-47-3) 6M. Copper, Total ~ D D 3.5 0.029 1 UG/L LBS/D (7550-50-8) 7M. Lead, Total IZI 0 0 <3.0 <0.025 1 UG/L LBS/0 (7439-97*6) 8M. Mercury, TotaJ 181 0 D <0.2 <0.002 1 UG/L LBS/D (7439-97-6} 9M. Nickel, Total 181 0 0 <5.0 <0.042 1 UG/L LBS/0 (7440-02-0) 10M. Selenium, Total 181 0 0 <5.0 <0.042 1 UG/L LBS/D (7782-49-2) 11M. Silver, Total [8J 0 0 <0.1 <0.001 1 UGIL LBS/0 (7440-22-4) 12M. Thallium, Total ~ 0 0 <2.0 <0.010 1 UG/L LBSJD j7440-28-0} 13M. Zinc, Total ~ 0 0 12 0.10 1 UG/l LBS/D (7440-66-6) 14M. Cyanide, Total ~ 0 0 <5.0 <0.042 1 UG/L LBS/D {57-12-5) 15M. Phenols, 181 0 0 <50 <0.42 1 UGIL LBS/D Total DIOXIN 2,3.7,8-Tetra-I I l8l I DESCRIBE RESUL T5 chlorodibenzo*P-D D Dioxin (1764-01-6) PA E2 0 Enclosure to ULNRC-06027

CONTINUED FROM PAGE 3 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. L.ONG TERM AVRG. VALUE

4. UNITS 5.. INTAKE (~pti~mr/l

1. POLLUTANT A.

B. BE* c.se:. (if avaHable) .{ifavailabte) AND CAS NUMBER TEST* UEVED UEVEO D.NO,OF ACONCEN* B. MASS A LONG TERM AVRG. B. NO {If qvJ#Iabkl) II\\IGRE* PRE-AB- ,1) {1) (1) ANAL* TRATJON VALUE OF QUI RED SENT SENT CONcENTRATION iZ)MASS COI<<:ENTRAiiON (21 Nil$$ CONCENTRATJON (2)MASS YSES ANAL-(1) (2.) CONCENTRATJON MASS YSES GCIMS FRACTION-VOLAnLE COMPOUNDS 1V. Acrolein [81 0 0 (107-02-8) <50 <0.42 1 UGIL LBS/D 2V. Acrylonitrile [81 0 0 <50 <0.42 1 UG/l LBS/D (107-13-1) 3V.Benzene [81 0 0 <5.0 <0.042 (71-43-2) 1 UG/L I.BS/D 4V. Bis {Chloromethyl) (81 D 0 <10 <0.083 1 UG/L LBS/0 Ether (542-88-1) SV. Bromoform 181 0 0 <5.0 <0.042 1 UG/L LBS/D (75-25-2) 6V. Carbon Tetrachloride [81 0 0 <5.0 <0.042 1 UGfL LBS/D (56-23-5) 7V. Chloroben:zene [81 0 0 <5.0 <0.042 1 UG/L LBS/D (108-90..7) 8V. Chlorodibromomethane ~ 0 0 <5.0 <0.042 1 UG/L LBS/D (124-48-1} 9V. Chloroelhane ~ 0 0 <10 <0.083 1 UG/L LBS/0 (75-00..3) 10V. 2-Chloroethylvinyl [81 0 D <5.0 <0.042 1 UG/L LBS/0 Ether (110.75-8) 11V. Chloroform [81 D 0 <5.0 <0.042 1 UGIL LBS/D {67-66-3) 12V. Oichlorobromomethane C2l 0 0 <5.0 <0.042 1 UG/L LBS/D (75-27-4) 13V. OicNoro-0 0 0 1 UG/L LBS/D difiuoromethane (75-71--8} 14V. 1,1-Dichloroethane t8l 0 0 <5.0 <0.042 1 UG/L LBS/0 (75-34-3) 15V. 1.2-Oichloroethane (8J D 0 <5.0 <0.042 1 UG/l LBS/D (107-06-2} 16V. 1.1 - Dichloroethytene l8:l D D <5.0 <0.042 1 UG/L LBS/D (75-35-4) 17V. 1.2-Dichloropropane l2l 0 0 <5.0 <0.042 1 UG/L LBS/D {7&-87-5) 18V. 1,2 -Dichloropropylene l2l D 0 <5.0** <0.042 1 UG/L LBS/D (542-75-6) 19V. Ethylbenzene ~ 0 D <5.0 <0.042 1 UGJL LBS/D (100..41*4) 20V. Methyl Bromide [81 0 0 <10 <0.083 1 UG/L LBS/D (74-83-9} 21V. Methyl Chforide [8J 0 0 <10 <0.083 1 UG/L LBS/D (74-87-3) ~10 7lW-I:>l6 ((,.j~) PAGE3 1'1: l* '<.

This parameter was deleted per 40 CFR, Part 122, Appendix D.
- This parameter is 1,3 Dichloropropylene per 40 CFR. Part 122, Appendix D.

Enclosure to ULNRC-06027

I NPDES # (IF ASSIGNED) I OLITFALL NUMBER I CONTINUED FROM THE FI~ONT M0-0098001 016 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE

c. LONG TERM AVRG. VALUE

.... UNITS

5. INTAKE (optiO

1. POLLUTANT A.

a.ee-C. BE* {if;wallablft) {if :tiV/ll/II~J AND CAS NUMBER tEST* UEVEO UEVED D. NO. Of A.CONCEN* B. MASS [If avaJtable) lNG RE-PRE-AB-ANAL-A. LONG TERM AVRG. (1) (1} {1) TRAllON QIJIREO SENT SENT CONCENTRAnON f2)MASS CONCENTM110N fZ)MASS (2)1o1ASS YSES VALUE CONCENTRATION i1} IZI CONCENTRA110N MASS I} B. NO OF ANAl-YSES na GC.MS FRACTION -VOLATILE COMPOUNDS (continued) 2ZV. Methy!ene Chloride l'8l 0 0 <5.0 <0.042 (75-09-2) 1 UG/L LBS/0 23V. 1.1.2.2-Tetra-181 0 0 chloroethane {79-34-5) <5.0 <0.042 1 UG/L LBS/D 24V. Tetrachloroethylene r81 0 0 <5.0 <0.042 (127-18-4) 1 UG/L LBS/D 25V. Toluene [81 0 0 {10S.88w3) <5.0 <0.042 1 UG/L LBS/D 26V. 1,2-Trans 181 D 0 <5.0 <0.042 Dichloroethylene {156-60-5) 1 UG/L LBS/D 27V. 1,1,1-Tri-181 0 0 <5.0 <0.042 chloroethane (71-55-6) 1 UG/L LBS/D 28V.1,1,2-Tri-181 0 D chloroethaoe (79-0Q-5) <5.0 <0.042 1 UGiL LBS/0 29V. Trichloro-181 0 0 <5.0 ethylene (79-01-6) <0.042 1 UG/L LBS/D 30V. Trichloro-I81 0 D fluoromethane {75-69-4) 1 UG/L LBS/D 31V. Vinyl 12:1 0 0 <5.0 <0.042 1 UGJL Chloride (75-01-4) LBS/D GC/MS FRACTION-ACIO COMPOUNDS 1A. 2-Chlorophenol 181 0 0 <10 <0.083 1 UG/L LBS/D (95-57-8) 2A. 2.4-Dichloro- !81 D D <10 <0.083 1 phenol (120-83-2) UG/L LBS/D 3A. 2.4-Dimethyl- [81 0 0 <10 <0.083 1 UGIL LBS/D phenol (105-S7-9) 4A. 4,6-Dinitro 181 0 0 <10 <0.083 1 UG/L LBS/D Cresol (534-52-1) SA. 2,4-Dinilro-181 0 0 <51 <0.43 1 UG/L phenol {51-28-5) LBS/D SA. 2-Nitrophenol 18.1 0 D <10 <0.083 1 UG/L LBS/0 (88-75-5) 7 A. 4-Nitrophend 18.1 0 D <10 <0.083 1 UG/L LBSJD {100..02-7) 1---- SA. P-Chloro-M ~ D 0 <10 <0.083 1 UG/L LBS/1) Cresol (59-50-7} SA. Penlachloro - £g) 0 0 <10 <0.083 1 UG/L LBS/0 phenol {87-86-5_ 10A. Phenol tgJ 0 0 <10 <0.083 1 UG/L LBS/D (108--952) 11A. 2.4,6-Trichloro-gJ 0 0 <10 <0.083 1 UG/l LBS/D phenol (88-06-2) J 1----- 1---- .I ~~ .J-PAGE.! CONTINUE ON PAGE 5 "'*" Trichlorofluoromethane has been deleted per 40 CFR, Part 122. Appendix D. Enclosure to ULNRC-06027

CONTJNUED FROM THE FRONT 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALlJE C. LONG TERM AVRG. VALUE 4.UNITS S.IIIITAKE (optional)

i. POLLUTANT A.

B. BE* c.ae. (if available) (if avaiJableJ AND CAS NUMBER TEST* ueven UE\\IEO D. NO. OF A. CONCEN-B. MASS A. LONG TERM AVRG. B. NO (If avaifatJie) INGRe* PRE-AB-(11

11)

(1) ANAL* l'AA.TlON VALUE OF CUI RED SENT $Em" COOCENTAATION ~:t)MASS COIIICENTRATION (2)MA$$ CONCENTRAltON (Z)MASS YSES ANAL* (1) (~) YSES CONCEm"AAllON MAsS GCIMS FRACTION-BASE/NEUTRAL COMPOUNDS 1 B. Acenaphthene r2l 0 0 <10 <0.083 (83--32-9) 1 UG/L LBS/0

28. Acenaphtylene t8l 0

0 <10 <0.083 (208-96-8) 1 UG/l LBS/0

38. Anthracene t8l 0

0 (120-12*7} <10 <0.083 1 UGIL LSS/D

48. Benzidine r8.'l D

0 (92-87-5} <100 <0.83 1 UG/L LBSJD

59. Benzo (a)

[2) 0 0 <10 <0.083 1 UG/L LBS/0 Anthracene {56-55-3)

68. Benzo (a) l8J 0

0 <10 <0.083 Pyrene (50-32-8} 1 UG/L LBS/0

78. 3,4-Benzofluoranthene IZI 0

0 <10 <0.083 {205-99-2} 1 UG/L LBS/0

88. Benzo (ghi) t8l D

0 <10 <0.083 1 UG/l LBS/0 Perylene (191-24-2)

98. Benzo {k}

~ 0 0 <10 <0.083 1 UG/L LBS/0 Fluoranthene (207-08-9) 108. Bis (2-Chloroethoxy) rg) 0 0 <10 <0.083 1 UG/L LBSfD Methane {111-91-1} 118, Bis {2-Chloroethyl) 181 0 D <10 <0.083 1 UG/L LBS/D Ether (111-44-4) 128. Bis (2*Chloroisopropyl) 1'21 0 0 <10 <0.083 1 UG/L LBS/1::> Ether (39838-32-9) 138. Bis (2*Ethy!hexyl) 1'21 0 0 <10 <0.083 1 UG/L LBS!D Phthalate (117 7} 148. 4-Bromophenyl .181 0 0 <10 <0.083 1 UG/L LBS/D Phenyl Ether (1 01-55-3) 158. Butyl Benzyl [8'J 0 0 <10 <0.083 1 UG/L LBS/D Phthalate (85-68-7) 168. 2-Chloronaphthalene [g) 0 D <10 <0.083 1 UG/l LBS/D {91-58-7) 178. 4-Chlorophenyl lgj 0 0 <10 <0.083 1 UG/L LBS/D Phenyl Ether (7005-72-3) 188. Chrysene 181 0 0 <10 <0.083 1 UGIL LBS/0 (218-01-9) 198. Dibenzo (a.h) 181 0 D <10 <0.083 1 UG/L LBS/D Anthracene {53-70..3) 208. 1,2-Dichlorobenzene 1&'1 D D <10 <0.083 1 UG/L LBS/D (95-50-1) 21 B. 1,3-Dichlorobenzene ~ 0 0 <10 <0.083 1 UG/L LBS/D (541-73--1) 1\\10 78<1-ISI<* ((>-il-l) PAGES CONTINUE OJ'.: P,-\\!vE f, Enclosure to ULNRC-06027

C:ONTINlff:D FROM PAGF.: 5 I NPOES # (fF ASSIGNED) I OUTFALL NUMBER M0-0098001 016 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE 4.UNITS S.INTAKe ( 1.POLLUTANT A. B. BE* C. BE* . (if available) fif available) AND CAS NUMBER TEST* LIE liED I.IEVED D. NO. OF A.CONCEN-IB,MASS A. LONG TERM AVFl (If available) INGRE* PRE-AS-(1) (1) (1) ANAL* TRATION VALUE OUlRED SENT SENT CONCENTRAnON (2}MASS CONCENTRATION (2)MASS CONCENTRAnOH (2)MASS YSES (1) CONCENTRATION optional) B. NO OF -~ ANAL* 'MASS YSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS (conlinued) 228. 1, 4-Dichlorobenzene t8l 0 0 <10 <0.083 1 UG/L LBS/0 (106-46-7) 236. 3, 3'-Dichlorobenzidine t81 0 D {91-94-1) <51 <0.43 1 UG/L LBS/0 246. Diethyl Phthalate t8l 0 0 <10 <0.083 1 UG/L LBS/0 (84-66-2} 258. Dimethyl Phthalate IZI 0 D <10 <0.083 1 UG/L LBS/0 (131-11-3) 268. 01-N*butyl Phthalate 12! 0 0 <10 <0.083 1 UG/L LBS/0 (84-74-2) 278. 2,4-Dinitrotoluene t8l D 0 <10 <0.083 1 UGIL LBS/D (121-14-2} 288. 2,6-Dinitrotoluene 12! 0 0 <10 <0.083 1 UG/L LBS/D (606~20-2} 298. Di-N-Cetyl Phthalate 181 0 0 <10 <0.083 1 UG/L LBS/D {117-84-{)) 308. 1.2-Diphenylhydrazine ~ 0 0 <10 <0.083 1 UG/L LBS/0 (as Azobenzene) (122-6f)*7) 318. Fluoranthene ~ 0 D <10 <0.083 1 UG/L LBS/0 (206-44-D) 328. Fluorene l8l 0 0 <10 <0.083 1 UG/l LBS/0 (86-73-7) 338. Hexachlorobenzene r2l 0 0 <10 <0.083 1 UG/L LBS/0 {87-68-3) 348. Hexachlorobutadiene l8l 0 0 <10 <0.083 1 UG/L LBS/D (87-68-3) 358. Hexachloro-rgJ 0 0 <10 <0.083 1 UG/L LBS/D cydopentadiene (77 4) 368. Hexachloroethane lZI 0 0 <10 <0.083 1 UG/L LBS/D {67-72-1} 378. lndeno (1,2.3-c-d) 0 0 0 <10 <0.083 1 UG/L LBS/D Pyrene { 193-39-5) 388. lsophorone l8l 0 0 <10 <0.083 1 UG/L LBS/D (78-59-1) 398. Naphthalene rgJ 0 0 <10 <0.083 1 UG/L LBS/D {91-20-3) 406. Nitrobenzene rgJ 0 0 <10 <0.083 1 UG/L LBS/D (98-95--3) 418. N-Nitro-lZJ 0 0 <10 <0.083 1 UG/L LBS/D sodimethylamine (62-75-9) 428. N-Nitroso l8l 0 0 <10 <0.083 1 UG/L LBS/D N-Propylamine (621-64-7) MO 78(}..1516 (6*04} PAGEo CONTtN UEONPAGE7 Enclosure to ULNRC-06027

CONTINUED FROM THE F~ONT 2.MARK"X" 3.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. L()NG TERM AVRG. VALUE 4.UNITS 5.1NTAKE {optional)

1. POLLUTANT A.

B.SE-c.se-J!f avaitabk!) {if avoilablei AND CAS NUMBER TEST* UEVEO UEVEO D. NO. OF A.CONCEN* B. MASS A. LONG TERM AVR(;. S.NO (if available) INGRE* PRE* Ae-. (1} {1} {1} ANAL- !RATION VALUE OF QUI REf) SENT SENT CONCENTRATION (2}MASS CONCENTRATfON (2) MASS CONCENTRATION (2)MASS YSES ANAL* (1} (2) YSES CONCENTRATION MASS GCIMS FRACTION-BASE/NEUTRAl COMPOUNDS {continued) 438. N*Nitro-l8l 0 0 sodiphenylamine (86-30-6} <10 <0.083 1 UG/L LBS/D 448. Phenanthrene l8l 0 0 (85.01-8) <10 <0.083 1 UGJL I.BS/D 45B. Pyrene l8l 0 0 <10 <0.083 1 UG/L LBS/D ('129-00..()) 468. 1.2.4-Tri l8l 0 0 <10 <0.083 1 UG/L L.BS/0 chlorobenzene (1.20-82-1) GC/MS FRACTION-PESTICIDES 1P. Aldrin 0 0 l8l {309-00*2) 2P.a-BHC 0 0 l8l (319-84-6) 3P. !3-BHC 0 0 C8l (319-84-6) 4P. V-BHC 0 0 l8l (58-89-9) 5P. 5-BHC 0 0 l8l (319-86--8} 6P. Chlordane 0 l8l 0 X (57-74-9) 7P. 4.4'-DDT 0 0 t8J {50-29-3) 8P. 4.4' *DOE 0 0 IZl {72-55-9) 9P. 4.4'-DDD 0 0 181 (72-54-8) 1 OP. Die!drin 0 0 l8l (60-57-1) 11 P. a-Endosulfan 0 0 18] (115-29-7) 12P. 13-Endosultan 0 0 f8J (115-29-7) 13P. Enctosulfan Sulfate 0 0 181 {1031-07-8} 14P. Endrfn 0 0 18] {72-20-8) 15P. Endrin Aldehyde 0 0 f8l (7421*93*4) 16P. Heptachlor 0 0 181 (76-44-8) M07SO-bl6(6-04) J

7 I AGE CONTIJXUED ON PAOE S Enclosure to ULNRC-06027

C.ONTINIJF.D FROM PAGE 7 I NPOES # (/F ASSIGNED} l OUTFALL NUMBER M0-0098001 016 2.MARK"X" l.EFFLUENT A. MAXIMUM DAILY VALUE B. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG.VALUE 4.UNITS 5.1NTAKE(

1. POLLUTANT A.

B. BE* C. BE* Jlf available) (if available) AND CAS NUMBER TEST* LIE \\lEO LIEVED D. NO. OF A.CONCEN-B. MASS A. LONG TERM AVF: (if available) INGRE* PRE-AS-(f) {1) (f) ANAL* TRATION VALUE QUlRED SENT SENT CONCENTRATION (2)MASS COHCENTRAriON (2}MASS CONCI:NTRATION (2)MASS YSES m CONCENTRATION ptionat] B.NQ OF -~ ANAL* 1\\ofASS YSES G GCIMS FRACTION - PESTICISES (continued) 17P. Heptachlor 0 0 r8l Epoxide (1024-57-3) 18P. PCB-1242 0 D 181 (53469-21-9) 19P. PBC-1254 0 0 r8l (11097-69-1} 20P. PCB-1221 0 0 181 (11 1{)4~28-2) 21P. PCS-1232 0 0 !81 {11141-16-5) 22P. PCB-1248 0 0 181 {12672-29*6) 23P. PCB-1260 0 0 181 ( 11 096-82-5) 24P. PCB-1016 0 0 l8l (12674-11-2) 25P. Toxaphene 0 0 I8J (8001-35-2} I MO 7SO*b 16 ~6.Q4) PAGE s Enclosure to ULNRC-06027

001 - Radwaste Treatment System ATTACHMENT A Description of Outfalls NPDES Permit No. M0-0098001 This system serves to collect, process, store, recycle. and dispose of liquid radioactive waste generated at Callaway Energy Center. Five general sub-systems can be defined as described befow: The Boron Recycle System receives reactor coolant for the purpose of processing this waste stream for discharge. Boric acid is used as a neutron absorber in the primary system. The boron concentration can vary substantially in Outfall 001 based on plant operation. Also the ion exchange resin utilized in the radwaste treatment system can become rapidly saturated with boron arlowing boron to pass through the treatment demineralizers. Therefore, processing of liquid radwaste by demineralization could result in up to 1 000 mg/1 of boron being discharged in Outfall 001. This has been noted in past NPDES Permit Reapplications for Callaway Energy Center. Although the boron concentration in this Outfall may reach 1 000 mg/1 in the Discharge Monitor Tank (sample point prior to discharge), this waste stream is routed to the plant discharge line, where it mixes with a minimal flow of 3,000 gpm as required by the plants Nuclear Regulatory Commission operating license. However, with administrative controls the dilution flow is maintained greater than 5,000 gpm allowing the final effluent at the point of discharge into the Missouri River to contain less than 50 mg/1 of boron. The Liquid Radwaste System collects and processes floor and equipment drains from the containment, auxmary building, fuel building, and radwaste buildings during normal operation. However, during outages, non-radioactive drainage from equipment in these buildings may be treated by the Oily Waste System as described in Attachment C. The laundry and Hot Shower system collects waste generated from washing radioactively contaminated protective gear and clothing and personnel decontamination shower wastewater. These wastes are then transferred to the liquid Radwaste system for treatment. The Secondary liquid Waste system is used to process condensate demineralizer regeneration wastes and potentially radioactive liquid waste collected from the turbine building. The condensate demineralizer regeneration waste is divided into two waste streams; High TDS waste from the acid and caustic rinses used when chemically regenerating spent resin, and low TDS waste which results from the initial back-flushing of the unregenerated resin and the final rinsing of the regenerated resin to remove acid and caustic. Steam Generator Slowdown is normally recycled to the main condenser for reuse in the secondary cycle. Provisions also exist to discharge the treated blowdown via Outfall 001 although this has not been done in the last t'IJenty-five years. A -1 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 It should be noted that the radwaste treatment system is specifically designed for flexibility to achieve Nuclear Regulatory Commission (NRC) limitations. Actual treatment for any given batch of wastewater is dictated by the following criteria.

1. The level of radiological contamination and the corresponding NRC mandated discharge criteria.

2. The NPDES permit discharge limitations.

3. The most effective waste treatment scheme that will give the smallest volume of solid radwaste.

4. Overall wastestream management - processing and holdup rates, volumes of other wastestreams requiring treatment or storage, etc.

5. The need, feasibility, and economics of the recycle versus discharge options.

The following wastewater treatment systems are used as required to treat this waste stream for recycle or discharge in compliance with NRC requirements and are also available as auxiliary or backup treatment systems to treat this discharge for compliance with NPDES permit limitations: Evaporation and/or Mixing and/or Filtration and/or Carbon Adsorption and/or lon Exchange and/or Neutrafization and/or Reuse/Recycle or Treated Effluent. All processing in the Radwaste Treatment System is done on a batch basis except steam generator blowdown. After monitoring for radioactive content, release rates are controlled administratively to ensure that radioactive discharge criteria are met. ALPS -Advanced Liquid Processing System is a permanently installed vendor provided skid used for treatment of liquid radioactive waste. This skid consists of six vessels and a filter housing. These components may contain various resin mixtures, charcoal adsorption media and/or filter media to provide optimum treatment for the specific wastewater being processed (shown on the Flow Diagram and Water Balance). 002 - Cooling Tower Slowdown A cooling tower is utilized to dissipate excess heat to the atmosphere from the Circulating and Service Water Systems. Outfall 002 is designated as the cooling tower blowdown discharge. Slowdown from the cooling tower is necessary to maintain dissofved solids concentration in the recirculating water within acceptable operating limits. 003 - Water Treatment Plant Wastes The water treatment plant (WTP) supplies clarified river water for cooling tower makeup and other plant cooling water systems. The suspended material that is removed from the riv~r water is drawn from the bottom of the clarifiers as sludge. This sludge is routed through a sedimentation lagoon for solids removal. A single sedimentation lagoon is utilized; sedimentation lagoon #4 was constructed in the fall of 2000 (construction permit # M0 3351). Demineralizer system waste streams and oil separator discharges are also routed to A-2 Enclosure to ULNRC-06027

NPDES Permit No. M0~0098001 sedimentation lagoon #4. Sedimentation lagoon #3 receives water from the demineralizer waste sump with this flow cascadjng to lagoon #4. The demineralizer system waste stream (previously a separate discharge point, Outfall 004, which was eliminated durfng previous permitting) consists of wastes generated from resin regeneration, sand & carbon filter backwash! miscellaneous wastes from floor drainage, and wet weU overflows.* Note finally, that this lagoon also receives effluent from the Oily Waste Processing System (which also receives effluent from an oil recovery well used to remediate a historic on-site release). The supernatant from the sedimentation tagoon is designated as Outfall 003. Outfall 003 has been recycled for more than 15 years by routing it back to the head of the water treatment plant via a supernatant pump station. 007 - Sanitary Treatment Lagoons Outfall 007 is defined as the sanitary wastewater treatment system discharge. Primary treatment is provided in a conventional three-cell stabilization pond. Effluent from the finaf celr is routed (in series) to two wetland basins. Both are.. artificial" (constructed) wetlands created by conversion of fiJJed WTP (sludge) sedimentation lagoons. The supernatant from the third stabilization pond is designated as Outfall 007. The effiuent then flows through two wetlands. The connection from discharge of the final wetland to the supernatant pump station was made in conjunction with the construction of an additional WTP sedimentation lagoon (as described in a previous NPDES Permit reapplication and in the construction permit application). OutfaU 007 is recycled by routing it back to the head of the water treatment plant via the WTP supernatant pump station. Outfall 009 - Jntake Heater Slowdown The river intake structure contains two recirculating electric heaters, which are used to prevent ice formation on the intake bar screens during the winter months. Outfall 009 consists of discharges from the infrequent blowdown or drainage of these boilers. We have not discharged from this outfall ;n the past twenty-five years. The boilers are currently kept in a dry lay up condition. Outfall 010 - Storm Water Runoff Settling Pond The drainage area for the Outfalf 010 Settling Pond encompasses a total of 108 acres. Only 15 percent of the drainage area consists of impervious plant site area. These areas include the cooling water chemical control building, the quality control building, the former Unit #2 excavation and* an area plant west of the radwaste building. The remaining drainage area consists of grassy areas within the plant boundary and areas leased to the Missouri Department of Conservation (MDC). The pond has a retention time greater than 24 hours. Two 48-inch square overflow boxes are located at the north side of the settling pond. Flow enters the overflow boxes and goes under the earthen pond dam to the actual discharge/sampling location. Metal louvers have been installed on the top opening of the concrete overflow box to prevent large debris from entering the storm water discharge. Outfall 010 discharges to Logan Creek. A-3 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 Outfall 011 - Storm Water Runoff Settling Pond The drainage area for the Outfall 011 Settling Pond encompasses a total of 425 acres. Only two percent of the drainage area consists of impervious area on the plant site. These areas include the water treatment pJant, radwaste building, operation support facility, demineralizer potable water building and the circulating and service water pumphouse. The remaining drainage area consists of grassy areas, excavation surplus storage! and areas leased to the MDC. The pond has a retention time of less than 24 hours. Two 48-inch square overffow boxes are located on the north side of the settling pond. Flow enters these overflow boxes and goes under the earthen pond dam to the actual discharge/sampling location. Metar louvers have been installed on the top opening of the concrete overflow box to prevent large debris from entering the storm water discharge. Outfall 011 discharges to Logan Creek. Outfall 012-Storm Water Runoff Settling Pond The drainage area for the Outfalf 012 Settling Pond encompasses a total of 87 acres. Approximately one fourth of the total drainage area consists of impervious area on the plant site. This outfaU collects storm water runoff from most of the pJant area including the parking lots, office buildings, part of the switchyard, the turbine building, the outage maintenance facility and the Stores I building. The remaining areas consist of grassy areas. The pond has a retention time of less than 24 hours. A concrete spillway has been constructed at the south side of the settling pond where the actual sampling point is located. Outfall 012 discharges to Mud Creek. Outfall 014-Storm Water Runoff Settling Pond The drainage area for the Outfarl 014 Settling Pond encompasses a total of 100 acres. Only four percent of the drainage area consists of impervious areas on the plant site. These areas include, half of the construction parking lot, the St.ores II building and the maintenance shop annex. The remaining drainage area consists of grassy areas and land leased to the MDC. The pond has a retention time of less than 24 hours. A concrete spillway has been constructed on the north side of the pond where the actual sampling point is located. Outfall 014 discharges to Auxvasse Creek. Outfall 015-Storm Water Runoff Settling Pond The drainage area for the Outfall 015 Settling Pond encompasses a total of 60 acres. Only one percent of the drainage area consists of impervious areas) which are paved roadways. The remaining area consists of grassy areas and land leased to MDC. The pond has a retention time greater than 24 hours. A concrete spillway has been constructed on the north side of the pond where the actual sampling point is located. Outfall 015 discharges to Auxvasse Creek. NOTE: The MDC uses a minor portion of the leased land for farming and the remaining land is left in its native state for wildlife habitat. A-4 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 Outfaii Oi6-Cooiing Tower Bypass This outfall consists of clarified river water and wastewater that has been recycled through the water treatment plant It is used to moderate flow through the water treatment pJant and to provide carrier water in the discharge line if needed when discharging from Outfall 001. Outfall 017 - Ultimate Heat Sink The Ultimate Heat Sink is a cooling pond that can provide cooling water to various plant systems during other than normal conditions. Outfall 017 is the overflow from the Ultimate Heat Sink, to storm water runoff pond settling pond Outfall 011. It is a no discharge outfall. A~5 Enclosure to ULNRC-06027

ATTACHMENT B Return of River Water NPDES Permit No. M0-0098001 The Callaway Energy Center has four points at which river water is returned back to the river; none are designated as outfaUs.

1. Intake Structure Stilling Basin-The siilling basin at the intake structure predominately receives water from the excess flow of the intake pumps via the free discharge valve and returns this flow to the river. Other minor contributions include the intake sump djsct)arge and a well used to supply lube water. As this flow is not contaminated with process waste, we believe it constitutes a return of river water.

2. Intake Line Drainage - The plant has a 48 diameter line that carries Missouri River water from the intake structure to the plant, which is about five miles away. Infrequently,* it is necessary to drain this line. Usually, this only occurs about two or three times a year. The line is drained by opening the free discharge valve and/or the discharge valves for the intake pumps. This allows the water in the line to flow back to the river through the free discharge value and the de-energized intake pumps. The drainage rate is about the same as the intake rate when the pumps are operating, so it should not pick up any additional solids that may have settled out in the Une. Therefore, we believe this intake line drain back flow constitutes a return of river water.

3. Raw Water Bypass - This line diverts untreated water from the head of the water treatment plant to the plant discharge line. It is used to release excess water that is pumped from the river. The flow through this line can vary from 0 to 10,000 gallons per minute based on operating requirements. Since the line diverts and returns untreated river water, we believe it constitutes a return of river water.

4. Downstream River Sampler-Approximately 1.5 miles downstream of the intake structure is an automatic river water sampler. The sampler pumps from 1 to 2.5 GPM continuously from the river, composites a small sam plet and returns the remaining flow to the river. No pollutants are added to this flow so it is our position that this discharge flow is a return of river water.

5. Intake River Sampler-An automatic river water sampler is located at the intake structure to provide upstream sample data; This sampler pumps from 1 to 2.5 GPM continuously from the river, compos-ites a small sample, anct returns the remaining flow to the river. No pollutants are added to this flow so it is our position that this discharge flow is a return of river water.

B-1 Enclosure to ULNRC-06027

ATTACHMENT C Description of Intermittent Flows NPDES Permit No. M0~0098001 Five of the six conventional outfalls defined in this application can be considered to incfude intermittent discharges since they process and/or release wastewater intermittently. Each is described below. ROUTINE RELEASES: 001 - Radwaste Treatment - All of the subsystems described in Attachment A, except Steam Generator Slowdown (SGB), process or release discrete batches of wastewater. The frequency and magnitude of each is variable. The flows from the subsystems accumulate in the Discharge Monitor Tanks (DMTs). The discharge flow rate from the DMTs is relatively constant for each batch. The current system typically produces discharges flows of approximately 250 gpm but may discharge at 450 gpm with 2 pump operation. Only one DMT is discharged each day during normal operation with the maximum daily discharge of less than 100,000 gallons. Only very infrequently during refueling outages it is necessary to discharge two DMTs during one day with a maximum discharge of 190,000 gallons. Approximately seven tanks are discharged per month, During recovery from major plant outages and other unusual transient conditions, it may be necessary to discharge SGB. The discharge flow rate varies up to 360 gpm resulting in a maximum daify discharge flow of up to 518,400 gallons. Past operation has shown that such discharges occur very infrequently. SGB has not been discharged for more than 25 years. Since this discharge occurs so infrequently, the SGB flow was not included in the maximum flows shown in Form C, Item 2.40. Previous testing of SGB Indicates that this wastestream is of equal or higher quality than other, much more routine components of Radwaste Treatment, Outfall 001 effluent. 003 - Water Treatment Plant Wastes - For the past 15 years this outfall has been recycled back to the head of the water treatment plant for reuse so the discharge flow is zero. 007 - Sanitary Wastewater-For more than ten years this outfall has been recycled back to the head of the water treatment plant so the discharge flow is zero. 009 - Intake Heater Slowdown - Discharges from this outfall would only be anticipated in the event of extremely cold weather and are thus seasonal and intermittent. If these heaters were placed in service, jt is estimated that bJowdown would occur approximately once per week (and amount to less than 100 gallons). At the end of an operating season they would be drained, releasing approximately 6,000 gallons of wastewater. There has been no discharge from this outfall for more than twenty-five years. 016-Cooling Tower Bypass-Discharges of cooling tower bypass vary considerably. At times discharges may occur only a few times during an entire month. While during some months discharges occur afmost daily for approximately 3 hours, per day and infrequently the bypass is operated continuousiy. Cooiing tower bypass is used to control cooling tower makeup, assist in maintaining circulating and service water chemistry, and at times provide additional flpw to the discharge line during releases from Outfall 001. Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 DISCHARGES DURING PLANT OUTAGES: It is necessary to drain many systems during plant outages for inspections and maintenance. In order to ensure that this water is of the same quality as water that is discharged during operation, some additional/alternate monitoring is performed. When the cooling tower basin, and/or associated lines (between the basin and the power block) are drained, a single grab sample will be obtained and analyzed to verify compliance with Outfall 002 permit limits prior to discharge. This alternate monitoring will be performed since continuous monitoring will not be possible at all times during the draining of these systems. Various non-radioactive systems in the AuxiJiary Building have been drained in the past to floor drains in the Auxiliary Building to allow for inspection and maintenance. The floor drains from the Auxiliary Building are routed to the Radwaste System for processing and treatment. Since it is not necessary to process these non-radioactive liquid wastes through the Radwaste System, at times we divert these non-radioactive drains to the Oily Waste Processing System for treatment prior to being recycled. Recycling of this water also results in trace amounts of chemical in Outfalls 002, 003, and 016, Attachment D, Chemical Usage, Table 1, lists these chemicals. Enclosure to ULNRC-06027

ATTACHMENT D Chemical Usage NPDES Permit No. M0-009f The various chemical compounds that may occur in the discharges from Callaway Energy Center during normal operation fall into three usage categories. Bulk Usaae This group of compounds describes chemicals that are added directly to specific water systems for treatment at some regular rate or intervaL Table ~ lists these chemicals along with their predominant function and potential discharge points. Laboratory Reagents This category consists of a group of compounds stored and used in the five on;:*Site plant raboratories. The predominant characteristic of this group is the relatively low u'sage, which would resuJt in negligible levels in the effluent. Laboratory reagents may be discharged through the radwaste treatment Outfalf 001, and sanitary wastewater in Outfall 007. At the request of the Department, Ameren Missouri will provide an inventory of these chemical compounds. Other Chemical Compounds This grouping includes other chemical compounds that may be discharged and are not included in the previous fists. General housekeeping and maintenance chemicals, and erosion/corrosion products or byproducts from the Plant's infrastructure or fuel materials are not individually assessed. However, the Form C and D analytical data should reflect any contributions from routine use of these compounds. Note that 120fc, sodium hypochlorite identified in Table 1 is also used to cfean the intake well periodically. At times, we use 20%. hydrochloric acid to clean scale in the well. Less than 1 000 gallons of 12% sodium hypochlorite or 20°/o hydrochloric acid are used annually for intake well cleaning. Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 -.......... ~. ...,.~~.... - --~*--.... --~ TABLE 1 BULK CHEMICAL USAGE-CALLAWAY

1.

Ammonium hydroxide - (Reboiler/Aux. boiler) - used for pH control in recirculating water systems; Outfalls 001.

2.

Boric acid - used as a neutron absorber to provide reactivity control and corrosion inhibitor in the primary Joop; Outfall 001. n~

3.

Dispersants - (organic sulfonated copolymers) used to reduce solids deposition in process tanks and plant water systems; Outfalls 001, 002, and 003.

4.

Ethylene Glycol-used as freeze protection in recirculating water systems; Outfalls 001, 003, and 007.

5.

Hydrazine - used for dissolved oxygen control in recircolating water systems; Outfalls 001 and 003.

6.

Hydrogen Peroxide - used as a chemical shock and biocide treatment in water systems; Outfall 001 and 003.

7.

Uthium hydroxide - used for pH control in the primary loop; Outfall 001.

8.

Nitrite/borate products (solutions) " used as corrosion inhibitors in recirculating water systems~ Outfalls 001 and 003.

9.

Coagulants-propnetary organic polymers useq as coagulants in.the water treatment plant; Outfalls 002,003, & 016.

10.

Sodium hydroxide - used for regenerating demineralizer resins and for pH control in various plant and wastewater systems; Outfalls 001, 003, and 009.

11.

Sodium hypochlorite - used as a biocide in the circulating, service, water treatment, ultimate heat sink, clarifiers, and potable water systems; Outfalls 001, 002, 003, and 016.

12.

Sodium molybdate - used as a corrosion inhibitor in dosed water systems: Outfalls 001 and 003. { 13.* Sodium tolytriazole or Benzotriazole* - used as a copper corrosion inhibitor; Outfalls 001, 002, and 003.

14.

Sulfuric acid - used for regenerating deminerarizer resins and for pH control in various water and wastewater systems; Outfalls 001.002, 003, and 009.

15.

Monoethanolamine - used as a pH control in closed water systems; Outfalls 001 and 003.

16.

Sodium bromide-used in conjunction with sodium hypochtorite as a biocide in water systems; Outfalls 001, 002, and 003.

17.

Methoxypropylamine (MPA)- used as a pH control agent in closed water systems; Outfalls 001 and 003.

18.

(1 wHydroxyethylidene) diphosphonic acid (HEDP).. used to inhibit calcium carbonate scale formation in water systems and the ultimate heat sink; Outfalfs 001, 002, and 003.

19.

Dimethylarriide (DMAD) - used as a biopenetrant to improve the efficiency of biocides In controJiing bacteria that exist under deposits in piping systems; Outfalls 001, 002, and 003.

20.

Phosphoric Acfd or Pyrophosphate - used as a corrosion inhibitor ror mild steel in recirculating water systems; Outfalls 001,002, and 003.

21.

Oiethylhydroxylamine (DEHA) - oxygen scavenger and pH control used in service water system for control of microbiological induced corrosion; Outfalls 001, 002, and 003.

22.

Proprietary Methylene Bis based biocide - used in plant water systems; Outfalls 001, 002, and 003.

23.

Proprietary Quatenary ammonium compound - used as a biostat in plant water systems; Outfalls 002, 003 and 016.

24.

Poly Acrylic Acid - may be used as a dispersant in the secondary system: Outfall 001. 003, and 017 during emergencies.

25.

Ferric Sulfate-used for hydrogen sulfide consumption in the ground water sump: OutfaU 003.

26.

Trisodium Phosphate - containment sumps for accident conditions: Outfall 001.

27.

Molluscicide - used intermittently (twice/year) at the water treatment plant and intake: Outfalls 002, 003, and 016.

28.

Triazine - a biocide used at water treatment, circulating and service water systems: Outfafls 002, 003, and 016.

29.

a-Ketoglutaric Acid (AKGA) -to neutralize hydrazine in secondary liquid waste water prior to discharge: Outfall 001. ~.. =~- --~ --~* ~ ~*- - ~-~,.,., __ ~---~---* ' Enclosure to ULNRC-06027

ATTACHMENT E NPDES Sampling and Analysis NPDES Permit No. M0-0098001 The chemical analysis of the various waste streams reported in this application came from two principal sources: 1) a special sampling and analytical project conducted in February, May, and June 2013 and 2) discharge monitoring data as required by our existing NPDES permit. Plant personnel conducted the reapplication sampling effort. Power generation at the plant averaged in excess of 99% of capacity during the sampling period for all process outfalls. Samples were collected from storm water outfarls during May when the plant was shut down for refueling to ensure samples were obtained during a spring rainfall event and during June for the pH analysis that was inadvertently omitted. Note that some special sampling techniques were used as communicated to the staff in a letter dated December 4, 2012 (correspondence attached). As effluent from some outfalls is released intermittently and in batches, it was necessary to modify the default sampling requirements listed in application instructions for selected outfalls. Each sample location is discussed befow to clarify these details and to allow the data to be interpreted correctly. For the sampling project, analyses were performed by Callaway Energy Center, and two commercial laboratories: TestAmerica (St. Louis, MO) and PDC (Florissant, MO). AU analyses were conducted in accordance with Standard Methods and/or EPA methodology. Specific test methods or additional details on other aspects of the sampling or analysis program are availabfe upon request. Outfall 001 As previously defined, routine discharges from this outfall are from one of five sources: the Boron Recycle System, the Liquid Radwaste System, the Laundry and Hot Shower system, the Secondary Liquid Waste system, and the Steam Generator Slowdown system (no discharge in the past twenty-five years). While processed separately, these waste streams, are normally commingled and retained in various tanks prior to discharge (excluding Steam Generator Slowdown). Thus, discrete samples of each subsystem were not obtained. Further, Steam Generator Slowdown was recycled without discharge during our sampling project schedule as it has been for the past twenty-five years. Jn view of the above conditions and the necessity that plant operations not be excessively constrained by the testing program, the following approach was utilized. Each sampling event consisted of a single grab sample, taken from one of the well-mixed Discharged Monitor Tanks (under recirculating conditions) prior to its batch release. The majority of data shown under the "Maximum Dairy VaJuell columns in Forms C and D is from a sample taken from the Liquid Radwaste Discharge Monitor Tank jB' on June 11, 2013. Data under the "Maximum 30 Day and Long Term Average" values are based on DMR data for the three-year period, January 2010 through December 2012. Mass discharges under these headings were calculated using the appropriate long-term average flow rates. E -1 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 Outfall 002 Cooling Tower Slowdown was sampted over a 24-hour period on March 12 and 13, 2013. The discharge was maintained at a constant flow rate. Flow proportional composite and multiple grab sampres were taken as appropriate. Other than the exception listed betowt all of the data shown under the "Maximum Daily Value" columns in Forms C and D is from this sampUng event. The flow monitored during this sampling event is also shown here and was used to calculate th~ mass discharges under this heading. Data under the "Maximum 30 Day and Long Term Average" values are based on DMR data for the three-year period, January 2010 through December 2012. Mass discharges under these headjngs were calculated using the appropriate long-term average flow rates. Outfall 003 Water treatment plant wastes are routed to Sedimentation Lagoon #4 for solids removal before the supernatant is recycled back to the head of the water treatment plant or is discharged. A small waste volume from makeup demineralizer plant regenerations, the previous NPDES Outfall 004, is routed to the Water Treatment Plant sludge pump station and is also treated by the sedimentation lagoons. A 24-hour flow composite and multiple grab samples were taken from the effluent of sedimentation pond #4 during a period on March 12 and March 13, 2013 while it was being recycled back to the head of the water treatment plant. Although there was no discharge from this outfall at the time, the water quality at the sample point for Outfalr 003 would be the same as the quality of the wastewater if the Outfall had been discharging. All of the data shown under the "Maximum Daily Value.. columns in Forms C and D is from this sampling event. Note that mass discharge values were calculated based on the estimated average discharge flow rate, even though the effluent was being recycled at the time. No data were reported under the "Maximum 30 Day" and "Long Term Average" coJumnsfor this outfall since it is normally recycled and thus there is no recent historical monitoring data from DMRs. Ameren would fike to maintain this Outfall permitted to preserve authorization to discharge from the water treatment plant, should the need arise. Outfall 007 As described in Attachment A, effluent from the (sanitary waste) stabilization lagoons is routed through two artificially (constructed) wetlands. For this reapplication project, a single grab sample was coJiected on March 13, 2013 from the effluent weir at the point of discharge from the third treatment lagoon as required by our NPDES Permit, although this effluent stream was being recycled at the time of sample collection. Further polishjng is completed by pymping this effluent to the first wetland. Flow continues by gravity through the second wetland which is routed to the supernatant pump station for recycle to the head of the water treatment plant. As the detention time within the lagoons and the first wetland, both exceed 24 hours, a single grab sample was collected. Data from this sampfing event is shown under the "Maximum Daily Value" coiumn in Form C. An additional sample was collected on March 20, 2013 to obtain a pH and the waste stream temperature and flow. This analysis was inadvertently missed during the first sampling effort. E-2 Enclosure to ULNRC-06027

NPDES Permit No. MOv0098001 A third sample was collected on June 12, 2013 for a second fecal coliform analysis as the first sample taken exceeded the holding time allowed. Although there was no discharge from this outfall at the time the samples were taken, the water quality at the sample point for Outfall 007 would be the same as the quality of the wastewater if the Outfall had been discharging. Other than the exception mentioned below~ all of the data shown under the "Maximum Daily Value" columns in Forms C and D is from these sampling events. Note that mass discharge values were calculated based on the estimated average discharge flow rate, even though the effluent was being recycled at the time. No data were reported under the "Maximum 30 Day" and "Long Term Average" columns for Outfall 007 since it is normalfy recycled and thus there is no recent historical monitoring data from DMRs. Ameren would Uke to maintain this outfall permitted.

outfall 009 i

The intake electric boilers are currently in a dry lay-up condition as they have been for many years, and so it was not possible to obtain a sample from them. The last discharge from this system occurred in early 1985, so recent past discharge data are not available. We want to keep this outfall permitted in order to preserve the authorization to discharge from the electric boilers~ should extreme weather or other conditions warrant their use. Outfalls 01 0-015 As described previously, storm water runoff from all plant areas is diverted to settling ponds, prior to discharge to waters of the state via the outfalls specified in the existing permit. These outfalls are described in Attachment A and are shown on the attached site maps. All five outfalls were sampled for the permit reapplication, as described below. The DNR approved of our request for a simplified sampling protocol~ during this round of permitting (see attached letter dated December 14, 2012). Per our agreement with DNR staff, we analyzed SWR effluent for the following parameters: pH Biochemical oxygen demand Chemical oxygen demand Total suspended solids Total organic carbon Oil and Grease Ammania-N Temperature Flow rate Fecar Coliform Total Kjefdahl Nitrogen Nitrate-Nitrite as N Nitrogen, total organic Phosphorous Sulfate Aluminum Iron Magnesium E-3 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 Grab samples were taken of the storm water runoff ponds on the following dates: 5/20113 7/10/13 The May sampling date was selected based on a rainfall event that resulted in pond discharges. The flow rates for all outfalls are based on calculated runoff (using appropriate runoff coefficients) from the actual rainfall measurements. The second set of samples was obtained to obtain the effluent pH which was inadvertently omitted during the first sampling event. Samples were collected to ensure pH was obtained although storm water Outfall 014 was not discharging during this rainfall event. All of the data shown under the,.Maximum Daily Value" columns in Form C are from these sampling events for each outfall. The flow, calculated for the rainfall event triggering each of these discharges, is also shown here and used to calculate the mass discharges under this heading. No data was provided for the maximum 30 day and long term average values as routine monitoring is not required by the current Permit. Outfall 016 The cooling tower bypass was sampled over a 24-hour period on March 12 and 13, 2013. The discharge was inadvertently isolated during this sampling campaign however, samples were collected from the normal sample location and are representative of Outfall 016 should it have been discharging. Flow proportional composite and multiple grab samples were taken as appropriate. Other than the exceptions listed below, all of the data shown under the "Maximum Daily Value" columns in Forms C and D is from this sampling event. As flow was isolated during this sampling event, average flows obtained from the plant computer were used to calculate the mass discharges under this heading. Data under the "Maximum 30 Day and Long Term Average" values are based on DMR data for the three-year period, January 2010 through December 2012. Mass discharges under these headings were calculated using the appropriate long-term average flow rates. Outfall 017 This is by definition a no discharge outfall; therefore it was not sampled. Missouri River A modified composite sample (consisting of 4 aliquots, each collected approximately 6 hours apart) was taken of Missouri River water being pumped to the head of the water treatment plant for a period on March 12 and 131 2013. It is believed that this modified composite sample is representative of the river over a normal24-hour period. Data available on the Missouri River E-4 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 indicate substantial variability over ranger periods. This data is provided under the "Intake., column in Forms C and D, for OutfaU 003. AU of the data shown is from this sampling event with the exception of a grab sample collected on June 12, 2013 for fecal coliform due to the first sample not meeting the hold time requirement. General Notes fmportant note on mass discharge calculation: As described previously, mass discharges listed under the Maximum Daily Value heading, represent values calculated from the analytical data and the measured flows. during the special re-application, sampling event. Consequently, the values shown do not necessarily represent an actual maximum mass discharge value. TestAmerica Laboratories, Inc. analyzed the following parameters for Outfalls 001, 002, 003, 007, 016 and the river intake: TOC COD Ammonia (anN) Bromide Nitrate-Nitrite (as N) Total Organic Nitrogen Alpha/Beta GC/MS Volatiles GC/MS Semi-Volatiles Total Suspended SoUds Total Metals Sulfate (as 804) Phosphorus Cyanide Phenols Fluoride O&G PDC completed all Fecal Coliform, Surfactants, and the BOD analyses. They also completed analysis ofthe following parameters for storm water Outfalls 010, 011, 012, 014, and 015: BOD 5-Day TOC Total Suspended Solids Ammonia (as N) Nitrogen, T. Organic Total Kjeldahl Nitrogen COD Fecal Coliform O&G Total Phosphorus Total Sulfate Aluminum Iron Magnesium Nitrate - Nitrite (as N) pH The Callaway Energy Center chemistry staff analyzed each outfall for the remaining parameters: Temperature Flow pH Total Residual Chlorine Total Hardness Enclosure to ULNRC-06027

December 4. 2012 Mr. Chris Wieberg Department of Natural Resources Water Pollution Control Program Permit Section P.O. Box 176 Jefferson City, MO 65102-0176

Dear Mr. Wieberg:

RE: Callaway Energy Center NPDES Permit #M0.. 0098001 Reapplication Monitoring Program Ameren Services The application for renewal of the Callaway Energy Center NPDES operating permit is due next summer (August 2013). Therefore, we are beginning to compile the necessary information to initiate this project. One of the first tasks is to arrange for sample collection and analysis. At this time we are requesting your review and approval for storm water sampling as described below as wen as no sample collection for OUtfall 009 and Outfall 017. Please note that we utilized a similar process during the past two rounds of permitting for Callaway. Storm Water Runoff (SWR) Outfalls 010 through 015 In the initial round of sampling, in order to characterize storm water runoff from industrial facilities subject to EPA's uPhase I" storm water regulations, we attempted to comply with the rigorous criteria which defined both qualifying storm events and sample procedures (both first flush and ffow proportional composite samples). Such sampling efforts are very compleKand costly, yet despite our efforts they proved infeasible for a few of the storm water settling pond outfalls at Callaway. Therefore we believe an alternate sampling program (essentially the same as that approved by DNA in 2000 and again in 2007) is appropriate for this round of permitting in light of the historical data and site specific circumstances. We are confident that the approach described below will ensure representative samples of effluent from the storm water settling ponds. For this round of permitting as during the 2008 campaign, we plan to collect grab samples of effluent from each storm water settling pond (current Outfalls 010, 011. 012.014, & 015), as soon as practical following initiation of discharge after a rainfall event. We will analyze samples collected after events of at least 0.1 inch of rain. We plan to monitor rainfall continuously throughout the sampling project. in order to characterize the event {as well as the effluent}; however we see no benefit fn applying other event selection criteria. We believe the configuration of the existing settling ponds and the condition of their spillways/discharge structures support the use o1 alternate techniques. The discharge of these ponds following a rainfall event is substantially moderated by both the highly absorptive off site drainage areas and the detention/retention capacity of the ponds. Clearly, inittal effluent quality from a settling pond does not exhibit the elevated contaminant concentrations typical in first flush samples of unimpeded runoff from direct storm water conveyances. In addition, despite considerable effort, we see little benefit in collecting composite samples. As explained in the letter submitted for sampling for the 2008 reapplication oampafgn, we do not see the need to sampfe/analyze for nitrogen, phosphorousj PCBs or other parameters as explained in the letter dated October

5. 2007 for the last permit reapplication (letter attached). AU electrical oils used at Callaway are and have always been PCB-free. In addition, nitrogen and phosphorus may be present in runoff (due to nearby agricultural lands managed by the Missouri Department of Conservation. which atso drain to several of these 1901 Cllouteau Avenue PO Box 66149, MC 602 St.louis. MO 63166*6149 Ameren.com Enclosure to ULNRC-06027

ponds}. It is highfy unlikely that these contaminants would be present from plant operations. 'vVe br:tJieve the quality of storm water runoff from these outfalls can be sufficiently characterized by analyzing the "standard list ot parameters in Part A of Missouri Form Ct and therefore as during the last reapplication, we plan to limit our analyses to these parameters along with oil and grease. Outfall 009 (Intake Heater Blowdown) and 017 (Uttfmate Heat Sink) In addition, with your concurrence, we do not plan to sample Outfalls 009 and 017for this reapplication, as they had no discharges during the past permit term. Outfall 009, permitted for blowdown from electric heaters (installed in the intake, to heat water to de* ice the Intake screens and/or bar racks), has never been used although the equipment is in pJace in case of critical need. We have previously characterized the probable quality of this effluent. A special sampling and analysts program would be conducted prior to any discharge if these heaters were to be placed in service. Nonetheless, we value the existing outfaJr designation, as it continues to provide a mechanism to expeditiously authorize potential future discharges. without modification of the permit, should the need arise. Outfall 017 is classified as a no discharge outfall. We could characterize the quality of water contained in the ultimate heat sink, but since discharges are not anticipated nor authorized, we see no benefit to collect this int9rmation. Conclusions Due to a scheduled spring refueling outage, Callaway plans to begin sampling for the permit reapplication early during 2013 as soon as spring rainfatl events begin. Therefore, we would appreciate your timely response to this memo. to allow time to modify or finalize our sampling program. If you have any questions regarding this proposal, please contact me at 314-554-2824. Sincerely, ~p~ Gail P. Gary Consulting Chemist Attachment Enclosure to ULNRC-06027

Envirt>mttC~niJIJ, Safety & H~nllh JJ.I.SUJ~~1 (Pif9M) 31/.$$1.4111 (F11aimJ/~) mltDllinge~telf.t(jlfl October 5, 2007 Mr. Refaat Meftakis Department ofNatural Resources Water Pollution Control Program Permit Section P.O. Box 176 Jefferson City, MO 65102-0176

Dear Mr. Mefrakis:

RE: Callaway Plant NPDES Permit #M0-0098001 Reappllcation Monitoring Program One Ameren Plaza 1901 Chouteau Avenue PO Box 66149 St Luuls. MG 63i66-6i49 Jif.62i.J221 Bee: R. S. BouteUe M. F. BoJJinger G. P. Gary J. C. Pozzo File: WQ3.l.l As the application for renewal of our Callaway Plant NPDES operating pmnit is due next spring (April4), we have just initiated the project to compile the necessary information. One of the first tasks is to arrange for the sample coUection and analysis. On Tht1rsday, September 27 > 1 spoke with Tim StaUman regarding details of the Stonn Water Runoff(SWR) monitoring~ in order to resolve certain questions and ensure an appropriate approach for this round pennitting. He suggested that we present our specific requests to you in writing~ to facilitate their review. Please note that we utilized a similar process during the round of permitting per the attached correspondence. Storm Water Runoff (SWR) Outfalls 010 through 015 In the initial round of sampling, in order to characterize stonn water runoff from industrial facilities subject to EPA,s uPhase In stonn water reguJations, we attempted to comply with the rigorous criteria which defmed both qua1ifying storm events and sample procedures (both first flush and flow-proportional composite samp1es). Such sampling efforts are very complex and costly, yet despite our efforts they proved jnfeasible for a few of the stonn water settling pond outfalls at Callaway Plant. We believe an alternative sampling program essentiaUy the same as that approved by DNR in 2000 is appropriate again for this round of pennining in light of the historical data and site specific circumstances. We are confident that the approach described below will ensure representative samples of effluent from the storm water settling ponds. For this round of pennitting, we pJan to collect grab samples of effluent from the storm water settUng ponds (Outfa1Js 010..015), as soon as practical fo11owing initiation of discharge after a rainfaJJ event. We will analyze samples co1lected after events of at least OJ inch of rain. We plan to monitor rainfall continuously throughout the sampling project, in order to characterize the event (as well as the effluent); however we see no benefit to apply other event selection criteria. We believe the configuration of the existing settling ponds and the condition of their spillways/discharge structures support the use of a1temative techniques. The discharge of these ponds following a rainfall event is substantially moderated by both the highly absorptive off site drainage areas and the detention/retention capacity of the ponds. Clearly, initial effluent quality from a settling pond does not exhib1t the elevated contaminant concentrations typJcaJ in first flush sampJes of unimpeded runoff from direct stonn water conveyances. As well, we see Htcle benefit despite considerab)e additional effort and cost, to justify composHe samplmg. Enclosure to ULNRC-06027

In our J 995 reapplication~ we analyzed the S"WR. samples for 26 parameters, based <m g~neric EPA criteria. These included parameters listed in EPA Fonn 2F, plus all other parameters listed in our pennit (for which analysis was required for any outfall), and PCBs (due to the EPA,s Steam Electric categQrical prohibition against discharge ofPCBs). Data on most of these parameters provides little relevant infonnation regarding pJant operations. For example, nitrogen and phosphorus may be present in runoff(due to the agricultural lands, managed by the Missouri Department of Conservation, which also drain to some ofthese ponds) but it is highly unlikely that these contaminants would be present from Plant operations. Likewise, we previously monitored for PCBs (and found none) due to the generic limit, despite the fact that electrical oils used at CaJJaway are and have always been PCB-free. We believe the quality of SWR from these outfalls can be sufficiently characterized by analyzing the "standard, list of parameters in Part A of Missouri Fonn Ct and thus pJan to limit our analysis to these in this reapplication. OutfaUs 009 (Intake Heater Blow down) and Ol7(ultimate Heat Sink) In addition, with your concurrence, we do not p1an to sample these two outfa11s for this reapplication, as they have had no discharges during this permit term. Outfall 009, which would be used to discharge bJowdown from electric heaters (installed in the intake, to heat water to de-ice the intake screens and/or bar racks), has never been used, a1though the equipment is in place in case of critical need. We have previously characterized the probable quality of this effluent t\\_'1d we would conduct a special sampling and analysis program before any discharge would be made, if these heaters were to be placed in service. Nonetheless, we value the existing outfaU designation, as it provides a mechanism to expeditiously authorize potential future discharges, without modification of the pennit. Outfall 017 is classified as a no discharge outfaJl. We could attempt to characterize the quality of water within the UJtimate Heat Sink, but since discharges are neither anticipated nor authorized, we see no benefit to collect such infonnation. Conclusions In order to ensure that SWR sampling data can be compiled in time for the spring reapplication deadlines, we want to attempt to sample this fall. Thus, we would appreciate your timely response to this memo, which will aJlow us to modify and/or finalize our sampling program without delay. If you have any questions regarding this proposal, please contact me at 314/550-2875 or Gail Gary at 314/554-2824 Sincerely, ~ <1-. B.Jl<.f'l Michael F. Bollinger Consulting Environmental Scientist Enclosure to ULNRC-06027

DEl' 'f A ' "n*"t. t,...l -:t l.UI Mr. Gail P. Gary Ameren Services P.O. Box 66149, MC 602 St. Louis, MO 63166-6149 [ererniah W. (fay) Nixon, Governor

Sara P;1rker Panlt>y, Dir.~ctor OF NATURAL RESOURCES www.dnr.mo.gov RE:

Callaway Energy Center NPDES Permit# M0-0098001 Reapplication Monitoring Program

Dear Mr. Gary:

Upon review of the letter sent on December 4, 2012, the Depa..rtm.ent ofNatural Resources agrees to the proposed sample collection and analysis. Stonnwater Outfalls #010, #011, #012, # 014, and #0 15 samples may be collected using '{;grab" sampling after events of at least 0.1 inch of rain. As a primary industry (40 C.P.R. Appendix A to Part 122), the facility is also required to submit Form C (APPLICATION FOR DISCHARGE PERMIT-MANUFACTURING" COMMERCIAL, MINING, SILVICULTURE OPERATIONS, PROCESS, & STORM WATER) and Form D (APPLICATION FOR DISCHARGE PERMIT PRIMARY INDUSTRIES). To complete Forms C and D the following analysis are required where applicable of each permitted outfall. If the two forms require outfall and pollutant duplication, the same analysis can be reported on each form. Form C, Part A: All applicants must provide results of at least one analysis for BOD, COD, TOC, TSS, NH3, flow, temperature, and pH. Form C, Part B; Requires applicants to mark "X" in either the "Believe Present" column or the "Believe Absent" based on your best estimate and must provide results of at least one analysis ifBelieved Present" and regulated by applicable effluent guidelines. ALL Primary Industries are required to test: Metals, Cyanide, and Total Phenols. Enclosure to ULNRC-06027

Mr. Gail Gary Callaway Energy Center Page2 In addition to the above parameters, Steam Electric Power Plants are required to complete Form D, which includes analysis for the following per 40 CFR Part 122 Appendix D, Table 1: GC/MS FRACTION-Volatile o GC/MS FRACTION - Acid GC/MS FRACTION-Base/Neutral Compounds The facility stated that the electrical oils used at Callaway Energy Center are and have always been PCB-free, so the facility may not be required to test PCBs in storm water discharge. Regardless of the statement, 40 CFR §423.16 (a) will be added as steam electric power plants' permit Special Condition- "There shall be no discharge of polychlorinated hi phenol compounds such as those used for transformer fluid". Additionally, the facility does not see the need to sample/analyze for nitrogen and phosphorus due to*nearby agricultural lands also draining to the stonnwater settling ponds. The Department will take this claim into consideration; however, applicants must still provide results of at least one a..!alysis since they believed the pollutants may be present in runoff. Addressing run-on from adjacent lands may be a best management practice that should be considered by the facility to address this.issue in the future. Outfall #009 (intake heater blowdown) has never been used and Outfall #009 does not discharge according to the facility; however, if a discharge occurs, between the date of this letter and the submission of the permit renewal application, an analysis for both outfalls must be submitted with the application. If you have any questions about this letter, please feel free to contact Joy Johnson of my staff by phone at (573) 751-6982. Thank you. Sincerely, WATER PROTECTION PROGRAM C£-.;-.- _<?1 ~ Chris Wieberg ~ ~ Chief, Operating Permits Section CW:jjj Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 ATTACHMENT F Section 311 and CERCLA Exemptions The chemicals listed below are used in water treatment processes and may be discharged in amounts exceeding their "reportable quantities~~ under 40 CFR 117 and 302 (1989). 001, 003;\\0, and 009 Sodium Hypochlorite 2,100 100,000 001,002,003,and 016 Sulfuric Acid 26,000 1,000 450,000 001.002,003, and 009 H drazine 80 1 26,000 001 and 003* Recycling of Outfall 003, Water Treatment Plant Supernatant (as described in Attachment A) may also result in trace amounts of these chemicals in Outfalls 002 and 016. Ameren Missouri requests ~xclusion under the NPDES exemptions from Section 311 and Superfund reporting for these four compounds and all others that are, as reported in this application, present in continuous or anticipated intermittent discharges (See Attachment D). These and other discharges for which exclusion are requested are exempt from Section 311 liability by 40 CFR 117.12(a)(1) if they are in compliance with the permit and 117.12(a)(2) or (3) if they are not. Discharges that are excluded from 311 reporting are also excluded from Superfund reporting. Any discharges other than those resulting from on-site spills would either result from circumstances identified in this application and be subject to neutralization treatment (see 117.12(c)) or would be continuous or anticipated intermittent discharge originating within the operating or treatment systems at the plant (see 117.12(d)). These discharges are, therefore, excluded from Section 311 and Superfund reporting requirements. F -1 Enclosure to ULNRC-06027

NPDES Permit No, M0-0098001 ATTACHMENT G General Comments on Standards Setting In anticipation of conditions that may be set in this permit renewal, Ameren Missouri requests the consideration of the following comments.

1. Mass limits - The Steam Electric Effluent Guidelines (at 40 CFR Part 423: 13(g))

specifically allow the permitting authority to express the quantity of pollutants allowt?d to be discharged as a concentration limitation instead of a mass-based rimitation. Fixed numerical mass discharge limitations necessarily impose implicit flow restrictions at the allowable concentration levels. The flow restrictions are too inflexible to cope with the flow variability conditions and the electrical reliability imperatives placed on steam electric power plants. Unlike some industries in which waste stream flow variability is the result of a single factor, like production, Callaway Energy Center has no such single parameter indicative of flow. Further, as a utility whose production is dictated by public consumption, the plant must be capable of attaining and maintaining full power production for as long as necessary. Since we feel that the concentration-based limits are sufficient and more appropriate for regulation of power plant discharges, we request that you do not impose any mass limitations -when reissuing this permit.

2. Net Credits - In a situation whereby a limitation might be set on the discharge of a priority pollutant, Ameren Missouri feels it should reflect an adjustment credit for pollutants in the intake water, because discharges are returned to the Missouri River. As complete removal of compounds in this category would not be achieved by the water treatment -systems at the Calfaway Energy Center, we hereby request an appropriate net limitation be applied as necessary. We anticipate not adverse water quality effect form net limitations.

3. WET Test Scheduling-rn accordance with permit conditions (Section D~ Other Requirementst item 6), Callaway Energy Center conducts an annual acute Whole Effluent Toxicity,(WET) test on composite samples taken from Outfalls 002 and 016. When attempting to collect these special composite samplest it simplifies the sampling procedure considerably by maintaining the Cooling Tower Slowdown (Outfall 002) and Cooling Tower Bypass (Outfall 016) at a constant flow rate over the 24-hour sampling period. This eliminates the need to adjust sample aliquots proportionally with flow. The annual WET test is completed in either the spring or fall immediately following a molluscicide treatment (and algaecide treatment if performed)~ and concurrently with the weekly circulating and service water system chemical addition. In addition, Callaway Energy Center has conducted an acute WET test every 5 years for Outfall 001 and completed a chronic WET test for OutfaH 002 every 5 years in accordance with our current permit. All WET tests conducted during the past five years for Callaway have all passed with no issues identified.

Because Liquid Radwaste (Outfall 001) and Cooling Tower Bypass (Outfall 016) flows are intermittent and discharge volumes released from Outfall 001 are a small fraction of the overall plant discharge flow, we request consideration be given to eliminating one or both of these chronic WET test requirements. Discharges from Outfall 001 occur on average about once per week during normal operation with a flow rate of 250 gpm during the discharge. Cooling G -1 Enclosure to ULNRC-06027

NPDES Permit No. M0*0098001 tower blowdown dilution ffow is maintained at greater than 5,000 gpm during this discharge. In addition, because Outfall 001 may contain a very small concentration of radioactive material, this WET test sample must be sent to an environmental laboratory which has obtained a license to receive radioactive materials. At this time, a laboratory has not been located that can conduct the required WET test for Outfall 001 and as required, has also obtained a license to receive radioactive materiaL ABC Laboratory conducted this test during 2009 (the last five year WET test for Outfall 001) and has informed Ameren they will no longer perform this analysis. Outfall 016 (Cooling Tower Bypass) is also an intermittent discharge. This stream consists of Missouri River water treated to remove river solids. If this water is not needed for cooling tower makeup, it is discharged back to the Missouri River. This bypass can occur daily or as infrequently as once per month with the maximum bypass fJow of 5000 gpm. The maximum daily frow during the past year was near 3.2 MGD with an average daily flow of near 0.8 MGD based on pJant computer data. Enclosure to ULNRC-06027

NPDES Permit No. M0~0098001 ATTACHMENT H Section 316(b) Demonstration Status The Callaway 316(b) demonstration consists of two parts,* an impingement study and an entrainment study. Part one, the impingement study, was started during the spring of 1984 and was successfully completed in the fafl of 1984. Part two, the entrainment study, was completed and submitted in June 1986. DNR correspondence dated April15, 1987, approved the 316(b) study and agreed with the concJusions of the study that the impacts from the use of the intake structure at Callaway are minimal. There have been no significant modifications or changes in the construction, design, Jocation or capacity of the cooling water intake structure. Accordingly, Ameren Missouri hereby incorporates by reference the results and conclusions of these prior studies and requests renewal of the 316(b) approval at Callaway. Enclosure to ULNRC-06027

Asiatic Clams ATTACHMENT I Macroi nvertebrate Controls NPDES Permit No. M0-0098001 Asiatic clams, CorbictJia fluminea, are a prolific nuisance macroinvertebrate with the potential to severely impact plant operations, if their population is not held in check. The Callaway Energy Center intake, water treatment plant (WTP) clarifiers and clean'Vell are considered particularly vulnerable systems. In 1996, the Plant instituted a monthly monitoring program to facilitate effective controls. Two methods are employed to control Asiatic clams: chlorination for control of juvenile clam (prior to shell development) and molluscicides to control adults. To increase the effectiveness of these treatments, water temperatures are monitored in order to determine when the temperature is suitable for the clams to spawn. A molluscicide, Bulab 6086, is added to the WTP clarifier effluent from one to six times per year, at a target concentration of 13 mg/1 (as product, in the clearwell). The treated water is allowed to soak for approximately 12 hours to provide maximum effectiveness. This procedure is usually performed during a plant intake outage, or during periods of low flow (<5000 gpm) through the WTP. During this treatment, the cooling tower makeup bypass valve (Outfall 016) is closed to prevent the release of this product directly to the plant discharge line. This bypass valve remains closed for 3 hours following the restoration of the WTP flow. The treated water in the clearwell is then routed to the cooling tower for use as makeup. Suspended solids in the tower wiJI absorb the residual active molluscicide. Therefore, there is no detectable free active product released from Outfall 002. The chlorination treatment is similar to that used with the molluscicide as described above, except that sodium hypochlorite is added upstream of the WTP clarifiers. Otherwise, the treatment follows the same basic procedure, i.e., the cooling tower makeup bypass valve is closed until the chlorine is reacted or dissipates and thus undetectable in discharges into the plant blowdown line. Zebra Mussels Callaway Energy Center has an inspection program to detect the settlement and growth of zebra mussels within systems vulnerable to macroinvertebrate fouling. Recent inspections have identified the presence of zebra mussels in the Missouri River at the vicinity of the Callaway intake. We have identified two systems that are particularly vulnerable to fouling if zebra mussels become established in the vicinity of the plant. The first system is the intake structure, which contains vulnerable equipment including screen wells, pump bays, vertical traveling screens, pumps, and trash racks. The other system, which might need treatment is the S-mile pipeline from the intake structure to the plant. Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 The following treatments are being implemented. Intake Structure - The isolated intake bays will be treated with a molluscicide as follows. An individua' intake bay will be isolated by closing all gate openings to adjacent cells and the river. The discharge valve on the intake pump in the isolated bay will be cJosed to prevent backflow from operating pumps in adjacent bays. The molluscicide will be injected into the isolated bay to achieve the manufacturers recommended concentration. The product concentration wilf be maintained for the specified time limit for effective treatment. After the treatment, the treated water will be pumped to the plant for use. This method is similar to others approved by DNR for Ameren Missouri facilities on the Mississippi River. Treatments to control fouling in the intake bays will be conducted 1 to 4 times per year. Bulab 6086 is currently utilized at a target dosage of 13 mg/1 as product for approximately 12 hours per treatment. Intake Pipeline-The intake pipefine may aJso be treated with a molluscicide. In this application, we will use a lower concentration for a longer period of time. Bulab 6086 will be feed into the combined pump discharge header at the intake,fo achieve approximately 2 mg/1 as product in the pipeline and the concentration will be maintained for a period of four weeks. One or two treatments are anticipated per year; one in the spring and one in the fall. I 2 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 ATTACHMENT J Activities, Materials and Management Practices with the Potential to Impact Storm Water Quality As described in Attachment E, reduced monitoring of storm water outfalls was authorized by DNR for this application (acknowledging the adequacy of prior characterization of these discharges). This data was entered into Missouri Forms C and D, eliminating the need to compiete EPA Form 2F; nonetheless. we believe this Attachment and the referenced drawings provide all of the required data. Routine/Permanent Significant Materials Storage The following significant materials have been identified at the Callaway Energy Center, as being in contact with storm water currently or in the last three years. They are shown on drawing NPDES~001, NPDES Storm Water Information Outfalls 010-015 and described below. Note that compass direction references are relative to "Plant North" a standardized reference designation, which is depicted on the drawing. Where possible, each item description listed below includes a number in brackets "{}" which corresponds to the drawing regend listing.

1.

Amine Storage Tank-A 6,000-gallon tank located northeast of the turbine building was installed to house ammonia hydroxide. A lined trough is located below the tank capable of holding 11 Oo/o of the tank contents. This tank is currently empty and has not been used for more than 1 0 years. {827}

2.

Caustic Storage Tank-A 101000-gallon storage tank containing sodium hydroxide is located plant northeast of the turbine building. A lined trough is below the tank capable of holding 110% of the tank contents. Caustic is unloaded from tank trucks using air pressure. {829}

3.

Demineralizer Caustic Storage Tank-A 16,000-gallon storage tank containing sodium hydroxide is located plant north of the demineralizer building. A concrete dike surrounds the tank capable of holding 110% of the tank contents. Caustic is unloaded from tank trucks using air pressure. {853}

4.

Sulfuric Acid Storage Tank - A 1 0,000-gallon storage tank containing sulfuric acid is located plant northeast of the turbine building. A lined trough is below the tank capable of holding 11 0% of the tank contents. Acid is unloaded from tank trucks using air pressure. {828}

5.

Circulating/Service Water Sulfuric Acid Tank-A 14,000--gallon storage tank containing sulfuric acid is located near the circulating and service water pump house and cooling tower basin. Containment consists of a concrete dike capable of holding 110o/o of the tank contents. Acid is unloaded from tank trucks using air pressure. {844A} J-1 Enclosure to ULNRC-06027

NPDES Permit No. M0~0098001

6.

De mineralizer Sulfuric Acid Storage Tank -A 1 0,000-gallon storage tank containing sulfuric acid is located plant north of the demineralizer building. A concrete dike surrounds the tank capable of holding 110% of the tank contents. Acid is unloaded from tank trucks using air pressure. {854}

7.

Gasoline Storage Tanks-One above ground gasoline storage tank loc~ted plant west of the Stores I building has a capacity of 2,000 gallons. A second above ground gasoline storage tank with a capacity of 500 galfons is located plant west of the Stores II buifding. A prefabricated metal containment exists around each of the tanks of sufficient size to contain approximately 110°/0 of the tank capacity. Gasoline is unloaded from tank truck using onboard truck pumps. {865}

8.

Security Diesel Storage Tank-A 3,000 gallon underground tank containing diesel fuel is located by the Main Access Facility. Diesel fuel oil is unloaded from tank trucks using onboard truck pumps. {814}

9.

Alternate Power Emergency System (APES) Diesel Generators - Four APES diesel generators are located on Highway CC south of the existing COOP substation. The APES diesel generators were installed during 201 0. Mounted under each diesel generator skid is a 3500 gallon self-contained diesel fuel oil storage tank with a secondary containment.

10.

Emergency Diesel Fuel Tanks-There are two 100,000 gaUon underground diesel fuel oil storage tanks located plant south of the Emergency Diesel building. Diesel fuel oil is unloaded from tank trucks using onboard truck pumps. Diesel fuel is used to power the emergency diesel generators during testing and as needed to supply plant power. {838}

11.

Vehicle Diesel Fuel Storage Tanks -Two above ground vehicle diesel storage tanks are located plant west of the Stores I buifding. There is a 300 galfon tank used to store #1 dieseJ and a 700 gallon tank used to store #2 diesel fuel oiL Two additional above ground vehicle diesef storage tanks are located plant west of the Stores II building for storage of #2 diesel fuel oil. Each of these two tanks has a capacity of 500 gallons. A prefabricated metal containment exists around each tank of sufficient size to contain approximately 11 0°/0 of tank capacity. Diesel fuel oil is unloaded from tank trucks using onboard truck pumps. A gas station type dispenser is used to fill diesel-powered vehicles from these tanks. {886} ,12. Auxiliary Fuer Oil Storage Tank-The auxiliary fuel oil storage tank is a 300,000-gallon carbon steer tank located plant west of the de mineralizer buifding. An earthen berm capable of containing 11 0% of the tank contents surrounds the tank. An underground transfer line from the auxiliary fuel oil transfer system fills the tank. This tank is used to supply diesel fuef oil to the auxiliary boiler and the fire protection diesel pumps. {869} Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001

13.

Circulating Water Chemical Control System Salt Storage-Two salt storage tanks (full of rock salt) are located plant north of the circulating water chemical control system building. The storage tanks and equipment have been retired in place. {818}

14.

Transformer Oil-Thirteen large power transformers are located on site. They are the main transformers (4 at 12,000 gallons), the Unit Auxiliary transformer (8,000 gallons), the Start Up transformer (9,700 gallons), the Station Service transformers (2 at 2, 770 gallons), the Alternate Energy Power Source transformer (2, 170 gallons), the Engineered Safety Features transformers (2 at 2,270) and the Safeguard transformers (9,700 and 11,500 gallons). In additiont most buildings on site have associated service transformers locatep outside (-20-30 transformers) which each contain approximately 400 gallons of oil. Most outside oil filled electrical transformers are situated on top of a concrete lined pit, which is filled with gravel. The exception to this is the Training Annex transformer and the eight 300 series site power loop transformers which do not have any containment. Any spills from these transformers would have to be contained in the drainage ditches adjacent to the transformers.

15.

Demineralized Water Tank -A 150,000-gallon stainless steel demineralized water tank is located plant southeast of the turbine building. No containment exists around this tank. The tank is filled via makeup demineralizers through underground piping. {830}

16.

Condensate Water Tank-A 466,000 gallon stainless steel condensate water tank is located plant southeast of the turbine building. No containment exists around this tank. The tank is filled from the demineralized water storage tank through underground piping. It is used to supply water to the steam generators when the plant is shutdown and during transients. During transients the tank can also be supplied by firewater. {831}

17.

Refueling Water Tank-A 419,000-gallon stainless steel refueling water tank is located plant southwest of the containment building. No containment exists around this tank. The tank is filled from the reactor makeup system through underground piping. It is used to supply water to the refueling pool during outages and to the reactor system during transients. The tank contains radioactive demineralized water with 2,350 to 2,500 . mg/1 of boron. {839}

18.

Reactor Makeup Water Tank -A 153,000-gallon stainless steel reactor makeup water tank is located plant southwest of the containment building. No containment exists around thjs tank. The tank is filled from the demineralized water tank through underground piping. It is used to supply demineralized water to the reactor system and associated support systems. {840}

19.

Demineralized Water Clear Well-The demineralized water clear well consists of a 50,000-gallon carbon steel tank located plant northwest of the demineralizer building. No containment exists around this tank. Deep well water is pumped underground to the demineralized water clear well~ which is then transferred underground to supply water to the makeup demineralizers. {855} Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001

20.

Fire Water Storage Tanks-Two 300,000-gallon carbon steel firewater tanks are rocated plant southeast of the demineralizer building. No containment exists around these tanks. These tanks are filled from the demineralizer clear well through underground piping. They are used to supply firewater to the plant for testing and fire response. {859}

21.

Neutralization Tank" The neutralization tank is a 150,000-gallon open carbon steel tank with an inner protective coating. No containment exists around thi~ tank. It receives regeneration wastewater from the makeup deniineralizer system through underground transfer lines. The water is pH adjusted with sulfuric acid and or caustic and then sent to the WTP sedimentation lagoons. {862}

22.

Discharge Monitor Tanks-Two above ground 100,000-gallon stainless steel discharge monitor tanks are located plant south of the radwaste building. The tanks are used to store plant radioactive wastewater prior to discharge. A single concrete diked area capable of holding 11 0% of the contents of one tank provides spifl containment. {879}

23.

Water Treatment Plant Sodium Hypochlorite Storage Tank-A 6,000-gallon plastic sodium hypochlorite tank is located plant south of the water treatment plant. No containment exists around this tank. It is in service from approximately April to October each year. The contents are used to chlorinate the water treatment pfant clarifiers.

24.

Gaseous Chemical Storage a) Carbon Dioxide (C02): The C02 storage tank is focated in the plant gas yard, which is plant south of the radwaste building. The primary use of C02 is to degas the main generator of hydrogen during outages. The tank has a capacity of 6 tons of liquid C02, a maximum pressure of 350 psig at 125°F. It is constructed per sectionS of the ASME pressure vessel code. {832} b) Hydrogen (H2): There are 12 tubes for storage of H2 with a total capacity of 83,232 cubic feet at 2,300 psig located in the plant gas yard. Hydrogen is primarily used as a cover gas for the main turbine generator and to maintain oxygen control in the reactor coolant system. The tubes are constructed per ASME UPV code 8, Code Case 1205 of a material that meets ASME SA372 Class 4. {833} c) Oxygen (02): An oxygen storage tube trailer provides the main source of oxygen and 8 Oxygen cylinders for backup. The cylinders each contain 330 standard cubic feet of 0 2 at 2,640 psig. They are constructed to meet DOT specification 3AA2400. The primary use of 0 2 at the plant is in radwaste systems, in the evolution of hydrogen recombination. {841} d) Nitrogen (N2): Callaway has both high and low pressure N2 with storage tanks located in the plant gas yard. There are two low pressure N2 storage tanks with a liquid capacity of 1569 gallons and 3000 gallons each. They are constructed with an inner vessel of 5083 aluminum and an outer carbon steel vessel. The primary use of low-pressure nitrogen for the pJant is to purge and blanket systems to exclude J-4 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 oxygen. High-pressure nitrogen is stored in 3 tubes with a total capacity of 24~280 cubic feet at 2,300 psig. They are designed and constructed to meet ASME code for pressure vessels. The primary use of high-pressure nitrogen is to provide a backup gas supply to rapidly close plant valves during transients. {892}

25.

Reclaimed Oil Storage Tank - The reclaim oil tank has a capacity of 10,000 gallons. Jt is an aboveground tank located within an earthen dike of sufficient size to contain 11 0°1.3 of the tank contents. The tank is filled through underground lines from the oily wastewater separator. Used oil is removed for recycle from the tank to tanker trucks by vacuum created within the trucks. {861}

26.

Oily Waste Treatment Area - This area is located southeast of the demineraJizer

building. The area consists of a building containing the oily wastewater separator and associated piping, the reclaimed oil storage tank, the equalization basin {863}, and a 29,000-gallon carbon steel underground process surge tank that supplies plant oily wastewater to the separator. All oily waste system water and oil transfers in this area are underground. Separated water is transferred to WTP sedimentation lagoon #4. {870}

27.

Auxiliary Oil Transfer (Loading) Area - The auxiliary oil transfer loading area is located plc:mt south of the auxiliary fuel oil storage tank. The area consists of a building containing pumps and piping to transfer diesel fuel oil to the auxiliary fuel oil storage tank. Diesei fuei oil is unloaded from tank trucks by pumps on the trucks or using the instafled plant equipment pumps. Transfer Jines to the auxiliary fuel oil storage tanks are underground. {864}

28.

Loading Area at Stores II-The loading area at the Stores II building consists of a standard shipping/receiving dock. Afl chemicals and other products are unloaded from trucks in their own shipping containers. There are not facilities for unloading of any bulk chemicals, fuel oil, or gasoline through pipelines to plant bulk storage tanks. {801}

29.

Misc. Materials Storage Areas w Three areas around the Stores II building exist for miscellaneous laydown areas for item such as metal, gravel piles, fill material and old concrete. One is a concrete pad and the other two are on grass/gravel covered areas. Another materials storage area exists near the outage maintenance facility. Materials stored are metal components such as pumps, and valves, structural materials made of items such as metal, wood or concrete, pipe made of materials such as carbons steel, PVC, and galvanized metal, empty portable tanks, and empty metal dumpsters. {801}

30.

Excavation Surplus Storage-Two storage areas are located plant south of the water treatment plant sfudge lagoons containing excess dirt, concrete, and asphalt from plant activities. Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 Temporary Significant Materials Storage-During the Last 3 Years The following sjgnificant materials were present on site temporarily within the fast three years. Refuel 18 and Refuel 19 The majority of additional materials stored on-site were for large equipment replacements including the four main transformers. Additional trailers to house additional staff and equipment such as scaffolding, cranes and other materials to support the refueling outages were also on-site. No other "significant materials" were stored on site during Refuel 18 and Refuel 19. A temporary Ecolochem trailer was also brought on-site during the fall of 2012 to provide make up water when the plant makeup water system was taken out of service for repairs to the neutralization tank. In addition, during 2010 *five temporary emergency diesel generators were temporarily located near the ultimate heat sink for approximately 9 months. Hazardous Wastes Callaway Energy Center is normally a small quantity generator of hazardous waste generating between 200 and 2200 lb. of hazardous waste per month. At times the quantity of hazardous waste exceeds this quantity due to infrequent activities such as equipment cleanings, etc. The waste is stored in a prefabricated Hazardous Waste Storage Building (HWSB) with containment sumps, designed specifically for storage of hazardous waste. Waste is stored in the HWSB for up to 180 days prior to disposal via an off-site vendor. Typical wastes generated are Chromium, Lead, Mercury, Silver, and solvents. The plant also currently maintains an outside sateflite accumulation area where waste paint and solvents are accumulated. These wastes are accumulated from work performed* in the plant in two separate 55-gallon drums held in a prefabricated closed spill container capable of holding 11 0 percent of the volume in both drums. Management Practices A spill prevention, control and countermeasure (SPCC) plan and implementing procedure is in place at the Callaway Energy Center. The plan provides plant personnel with the necessary information regarding the types, locations and quantities of non-radioactive oil present at Callaway Energy Center and offers guidance on the containment and reporting of oif spills. A chemical emergency response plan (CERP) and implementing procedure is also in place at the plant. This plan provides guidance and information for responding to hazardous chemical and/or oil spurs. Both plans describe various materiars management practices employed to minimize contact by these materials with storm water runoff. Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 Outdoor Vehicle Maintenance and Cleaning Areas No outdoor vehicle maintenance and cleaning areas exist on the plant site. Fertilizers. Pesticides. Herbicides. and Soil Conditjoners Herbicides are spray applied to various areas in and around the plant site as shown in drawing NPDES-001, Storm VVater lnfoimation Outfalis 010-015. Herbicides are afso applied to small areas near the intake building, the shooting range, the met tower, and the alternate emergency diesel generator yard. The herbicides used for weed control are Karmex, Oust, Signal, Roundup, and Weedar (2,4-D}. Pesticides are not used at Callaway Energy Center. In addition, no restricted use products are utilized at the facUity. Note that fertilizers, herbicides and soil conditioners which are used by the Department of Conservation on lands reased to them (yet within the plant storm water drainage areas) are not included in this summary. Authorization for Non-stormwater Components In previous appiications, we described numerous releases to storm water conveyances from sources not associated with precipitation. We also discussed our justification for these releases with representatives from DNR*s Jefferson City Regional Office, in meetings (and a during a plant inspection) preceding re-issuance of the permit. AU were approved. As a result, testing was not conducted to evaluate the presence of non-storm water discharges (as they exist and have been previously characterized and evaluated). Thus, this application does not contain the typically applicable "non-storm water source certification" (per EPA Form 2F, Item V). We h~reby request continued allowance for releases from these sources (described below), consistent with DNRrs earlier interpretation. The sources include:

1. Potable water-infrequent flushing and/or drainage of potable water lines for repairs or maintenance to the system.

2. Firewater - quarterly flushing from 40 connections required for testing and maintenance of the firewater system. Note that we treat the firewater system with a biostat, a biopenetrant and a scale inhibitor. This treatment program is designed to control microbiologically influenced corrosion to ensure integrity as required by the American Nuclear Insurers and the Nuclear Regulatory Commission. Quarterly flushes will discharge less than 50,000 gallons totaL Based on the expected concentrations and aquatic toxicity data, we do not believe there are any significant effects on the storm water runoff settling ponds from these releases. Once per three years, the entire system including the tanks, must be ffushed, releasing 700-800,000 gallons. Treatment chemicals are not added for a time prior to the~e flushes in order to ensure that residuals are very low (due to consumption within the system).

J-7 Enclosure to ULNRC-06027

NPDES Permit No. M0-009800 1

3. Manhole Pump-Outs-numerous manholes (providing access to instrumentation, piping, cables, etc.) at the plant are periodically pumped out, to remove accumulated storm water. In order to address questions regarding possible contamination due to galvanized metal corrosion, a testing program was conducted and the analytical results shared with DNR. The testing indicated that zinc concentrations were reduced significantly by maintaining water levels below galvanized supports (i.e. routine pump-outs). During 2012 we notified DNR that automatic pumping capability woufd be installed in several electrical manholes. Note that water is not pumped to the storm water conveyance if an oil sheen exists or if the pH is not between 6 and 9 (which would be indicative of a spill or leak).

4. Eye wash I Safety Shower Discharges - Releases are made from routine testing and/or emergency use of these outdoor facilities.

5. Demjneralizer Water I Essential Service Water (ESW) - during outages and other equipment maintenance activities, it is sometime necessary to provide temporary hoses to supply water to equipment. When these hoses are disassembled, residual water is released locally.

6. Air Conditioning Condensate - condensate from various building intake air cooling units is routed to building roof drains and/or to local area surfaces which in turn contribute to various storm water outfalls.

J-8 Enclosure to ULNRC-06027

NPDES Permit No. M0~0098001 The following table provides non-storm water plant related sources potentially discharged from conventional storm water drainage. Fire water test (1 000 ga~/qtr) Manhole discharges (10,000 gal/mo) Eye-wash/showers ESW ( <500 gal/event) Unit 2 Basin discharge - accumulated SWR (2. 7 MG/dewateri 011 Fire water test (24,000 gal/qtr) Fire water tank drain (800,000 gal/3yrs) Manhole discharges (15,000 gal/mo) Eye wash/shower Air conditioning condensate ESW 012 Fire water test (11,000 gal/qtr) Manhole discharges {70,000 gal/mo) Air conditioning condensate ESW 500 aa1,rev~:mn 014 Fire water test ( 17,000 gal/qtr) Air cond condensate Plant Modifications Alternate Electric Power Supply - Four additional emergency diesel generators were installed during 2010 to provide additional backup power for the plant These diesel generators are located adjacent to Highway CC south of the existing COOP substation. Modifications to the Missouri River loading dock and haul road were completed during 2012 for receipt of four new main transformers. Existing transformers were replaced with new main transformers during Refuel 19 spring 2013. Required security upgrades were made to the existing storm water culverts and manholes during 2012-2013. Main Transformers - Four new transformers were brought on-site (fall 2012) to replace the existing main transformers during Refuel19 (spring 2013). The four original transformers are expected be shipped off-site for disposal within approximately 12 months. J 9 Enclosure to ULNRC-06027

NPDES Permit No. M0~0098001 The reactor vessel head will be replaced during Refuel 20 scheduled to take place fall 2014. In addition, a temporary storage facility will be constructed on-site to store and provide a special environment to house this component for several months prior to the replacement. Independent Spent Fuel Storage Installation (ISFSI) Facility-Callaway intends to construct a dry cask spent fuel storage facility on-site by the end of 2014. As part of this project a haul road was constructed to move earthen fill material to and from a material laydown area to the Unit 2 excavation in preparation for the new spent fuel storage area. Beginning during the summer of 2013, bottom sediment will be removed from the existing Unit 2 excavation in preparation for installing native clay fill for the foundation of the ISFSI facmty. A land disturbance permit will be needed to begin this project. Concrete will also be poured for the foundation and around the in-ground storage containers covering a 160 X 108 foot storage pad for the first storage area. Additional concrete pads wHI be completed for future storage areas as needed. In addition, a concrete haul road wilf be constructed from the fuel building to the storage pad and a storage/support building will also be constructed in this area. Additional Sedimentation Lagoons - During the next few years, Callaway is expecting to construct one or two additional sedimentation lagoons adjacent to the existing water treatment sedimentation Jagoons. These lagoons contain mainly Missouri River solids. There are currently four lagoons or celfs being utilized. Clarified river water is used for plant cooling water in the service water and circulating water systems with the river solids removed bejng collected in sedimentation lagoon #4. This lagoon also receives waste water from the oily waste separator system and demineralizer waste collected in the equalization basin. Sedimentation lagoon #3 collects waste water from the de mineralizer. waste sump which cascades into sedimentation lagoon #4. The other two initially constructed lagoons have been converted to wetlands for final polishing of the sewage treatment plant effluent. The two currently operating sedimentation lagoons are expected to reach capacity within the next 1-3 years. Prior to beginning construction of any additional treatment lagoons, Ameren plans to apply for a construction permit with the*state of Missouri Department.of Natural Resources. All effluents from the existing lagoons are currently recycled to the head of the water treatment plant as they have been for the past 15 years. Potential Construction of an Additional Unit Callaway has begun the initial planning and preparations for building Small Modular Reactors (SMRs). At this time, no final decision has been made on building these additional units. However, if this project moves forward and is approved, it is anticipated that 'some initial construction may begin during the next two to five years. This will include clearing and excavation of an equipment laydown area north of and adjacent to the current plant site. Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 Significant Leaks and Spills On October 2, 2012 a significant feak occurred from the neutralization tank to the surrounding gravel area. Approximately 3,000 gaflons of pH 1.9 water spilled to the ground. The remainder of the tank contents was routed to the equalization basin to prevent further leakage to the surrounding area. Samples collected from the sedimentation lagoons, storm drains and ground near the neutralization tank following the event showed acceptable pH levels. This leak was reported to the National Spili.Response Center, the Missouri Department of Natural Resources and the Nuclear Regulatory Commission at that time. No other significant spills (meeting the criteria set forth in the regulations) have occurred at Callaway Energy Center, in the last three years. .J.. 11 Enclosure to ULNRC-06027

NPDES Permit No. M0-0098001 ATTACHMENT K Requests for Modification of Current Permit Conditions Elimination of the Five Year Wet Test for Outfall 001 and 016 All WET tests conducted during the past five years as required by the current Callaway NPDES Permit have passed with no issues identified. Because Liquid Radwaste (OutfaiJ 001) and Cooling Tower Bypass (Outfall 016) flows are intermittent and discharge volumes released from each is normaUy a small fraction of the overallplant discharge flow, we request consideration be given to eliminating one or both of these WET test requirements. Discharges from Outfall 001 occur on average about once per week during normal operation with a flow rate of 250 gpm during the discharge with a tank being released in approximately 6 hours. Coofing tower bJowdown dilution flow is maintained at greater than 5,000 gpm during this discharge. Jn addition, because Outfall 001 may contain a very small concentration of radioactive material, this WET test sample must be sent to an environmental laboratory which has obtained a license to receive radioactive material. At this time a laboratory has not been located that can conduct the required Acute WET test for Outfall 001 and has obtained the requireCI license to receive radioactive material. ABC Laboratories, Inc. conducted this test during 2009 (the last five year Acute WET test for Outfall 001) and has informed Ameren they wiJI no longer perform this analysis. OutfaU 016 is operated intermittently approximately once per day for approximately 3 to 4 hours. The flow rate varies but ranges from 1000-4000 gpm when operating. The average flow rate is near 0.80 MGD although many days of the year this outfall is not operated at afJ. Continued Use of BMPs for Storm Water Outfalls Each storm water outfall (010, 011, 012, 014, and 015) is designated and described as the discharge from a settling pond. These ponds were built to manage water quality from storm water runoff during the original Plant construction. They remain in our present permit both as artifacts of their original intended use and because a portion of the drainage into each pond includes buildings, plant yards and other amenities which meet the definition of an fndustrial Facility under federal storm water regulations (40CFR Part 122.26). While these ponds continue to provide effective sedimentation treatment for all storm water routed through them, the quality of storm water runoff from the ~~Industrial Activities" portion of the site is.maintained largely through the effective use of Best Management Practices (BMPs). These include: vegetated yards and swales, protected inlets and other conveyances, stable grade controls, general maintenance, routine housekeeping, and use of temporary controls during non-routine land disturbance activities. Routine monitoring of these storm water outfaUs was required for many years and the data collected demonstrated consistent compliance with the permit limits (for both pH and oil & grease). We believe that continued management of these outfalls using BMPs will provide protection for these effluent streams. Please note that land disturbance activities beyond those associated with routine operations at Callaway Energy Center are individually evaluated and when appropriate, separate Land Disturbance permit applications made. K -1 Enclosure to ULNRC-06027}}

ULNRC-06027, NPDES Permit Renewal Application - MO-0098001

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Dear Mr. Wieberg:

Dear Mr. Wieberg:

Dear Mr. Mefrakis:

Dear Mr. Gary:

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ULNRC-06027, NPDES Permit Renewal Application - MO-0098001

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Dear Mr. Wieberg:

Dear Mr. Wieberg:

Dear Mr. Mefrakis:

Dear Mr. Gary:

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