PLA-6606, Submittal of NRC Notification of NPDES Permit Renewal Application
| ML100950300 | |
| Person / Time | |
|---|---|
| Site: | Susquehanna  |
| Issue date: | 03/26/2010 |
| From: | Rausch T Susquehanna |
| To: | Document Control Desk, Office of Nuclear Reactor Regulation |
| References | |
| PLA-6606 | |
| Download: ML100950300 (367) | |
Text
Timothy S. Rausch PPL Susquehanna, LLC Sr. Vice President & Chief Nuclear Officer 769 Salem Boulevard Berwick, PA 18603 Tel. 570.542.3445 Fax 570.542.1504 tsrausch@pplweb.com ppI, TM MAR 2 6 Z010 U. S. Nuclear Regulatory Commission Attn: Document Control Desk Mail Stop OP1-17 Washington, DC 20555 SUSQUEHANNA STEAM ELECTRIC STATION NRC NOTIFICATION OF NPDES PERMIT RENEWAL APPLICATION Docket Nos. 50-387 PLA-6606 and 50-388 The purpose of this letter is to submit the Susquehanna Steam Electric Station NPDES permit renewal application to the NRC in accordance with Section 3.2 of the Environmental Protection Plan.-
Please contact Mr. Curt H. Saxton at (570) 542-1879 if there are any questions concerning this letter.
T.S' Attachment Copy: NRC Region I Mr. P. W. Finney, NRC Senior Resident Inspector Mr. R. R. Janati, DEP/BRP Mr. B. K. Vaidya, NRC Project Manager
Attachment to PLA-6606 NPDES Renewal Permit Application
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RENEWAL PERMIT"
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% TM February 25, 2010 Mr. Mike Brunamonti, P.E.
Chief Permits Section Water Management Program Pennsylvania Department of Environmental Protection 2 Public Squatre Wilkes-Barr-e, PA 18711-0790 SUSQUEHANNA STEAM ELECTRIC STATION APPLICATION-NPDES RENEWAL PERMIT PA-0047325 PLE-0024902
Dear Mr. Brunamonti:
PPL Susquehanna, LLC is submitting a NPDES permit renewal a pplicationh for the Susquehanna Steam Electric Station (SES), SalemrnT6wnship, Luzerne'County, PA.
The present NPDES permit no. PA-0047325 expires on September 1, 2010.
Included for Pennsylvania Department of Environmental Protection review are; 1) three copies of the application (one notarized), 2) an application fee of $500.00, payable to the Commonwealth of Pennsylvania, 3) copies of letters with certified mail receipts notifying Salem Township and Luzerne County of this renewalpermit application and 4) two copies of the Susquehanna SES, Pollution Prevention and Contingency (PPC)
Plan.
If you have any questions please call Curt Saxton at (570) 542-1879.
Sincerely, Bruce E. Rhoads Manager - Plant Chemistry Enclosure Attachment A - Requested Permit Changes Attachment B - Table of Contents - Permit Application and Supplemental Information
February 25, 2010 I
PLE -0024902 I
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J. S. Fields GENPL5 w/a J. M. Helsel B. H. Herre NUCSB3 SFC wo/a w/a I
T. V. Jacobsen A. Khanwalkar J. L. McCormick NUCE3 GENTW17 NUCSA3 w/a wo/a w/a I
R. W. Osborne J. J. Petrilla T. S. Rausch Allegheny NUCSA4 w/a w/a I NUCSB3 wo/a P. Renshaw B. E. Rhoads C. H. Saxton GENTW17 NUCSA3 wo/a w/a I NUCSA3 W/a J.
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Attachment A Requested Permit Changes
- 1. Request elimination of Internal Outfall 171 Radwaste Annual Monitoring for Oil and Grease, since the result of this analysis has always been less than detectable and it is difficult to matrix the analysis requirements with the radiological aspects to maintain the available analyses.
- 2. Request eliminating nutrient monitoring from Sewage Treatment Plant Outfall 079. The prescribed 3 year monitoring period'under. the previous permit has expired.
I I
Attachment B Table of Contents NPDES Permit Application and Supplemental Information I I Municipal and County Act 14 Notification / Documentation I II General Information Form III Completed Permit Application Modules IV Supplemental Information Provided: I
- Module 1 - Topographic Map and Water Balance Schematic
- Module 1 Item 7 - Water Treatment Chemical notes and MSDSs
- Module 3 - Additional Outfall Descriptions
- Module 12 - Stormwater Drainage Areas and Flowpaths V Appendix A - EPA 316(b) Rule (Phase II - Statement Susquehanna, LLC operation is currently in compliance per Compliance Alternative (1)(1).
IV Appendix B - Pollution Prevention and Contingency (PPC) Plan (includes Spill Prevention Control and Countermeasure (SPCC) Plan) (1/8/2010)
January 28, 2010 TM Ms. Patricia Owens Secretary, Salem Township Salem Township Municipal Building 38 Bomboy Lane PO Box 405 Berwick, PA 18603 SUSQUEHANNA STEAM ELECTRIC STATION NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT RENEWAL: PA 0047325 PLE-0024885
Dear Ms. Owens:
In accqrdande! with Act Number 14, P.L. 834, this .letter is to notify~you that PPL Susquehanna, LLc irtendsjt submit a National ,Pollutant Discharge Elimination System Permit renewal application in 'February 2010 to the Pennsylvania Department of E~n`Vir6o 'AI Protection for the Susquehanna Steam Electric Station,,(SES) located in Salem Tow-ship, Luzerne County, Pennsylvania.
if you have any questions concerning this permit renewal application, please call Curt Saxton (570) 542-1879.
Sincerely, Bruce E. Rhoads Manager - Plant Chemistry / Environmental Certified Mail Number: 7002 2410 0006 5855 1507 Copy to:
Ms. N. Green, EPA Region Ill Mr. Mike Brunamonti, PaDEP
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January 28, 2010 TM Mr. Douglas Pape, Chief Clerk Luzerne County Courthouse 200 North River Street I Wilkes-Barre, PA 18711 SUSQUEHANNA STEAM DISCHARGE NAT-1ONAL PO-LLUTANT ELECTROC STATION ELIMINATOON SYSTEM PERMOT RENEWAL: PA 0047325 PLE-0024886
Dear Mr. Pape,
In accordance with Act Number 14, P.L. 834, this letter is to notify you that PPL Susquehanna, LLC intends to submit a National Pollutant Discharge Elimination System Permit renewal application in February 2010 to the Pennsylvania Department of
.. Steam Electric Station (.SES located in Environmental Protection for' the Sdsquehanna Salem Township, Luzerne-CoUnty, Pennsylvania Ifyou have any questio'ns concerning this permit renewal application, please call Curt Saxton (570) 542-1879.
I Sincerely, I
Bruce E. Rhoads Manager - Plant Chemistry / Environmental Certified Mail Number 7002 2410 0006 5855 1491 3 Copy to:
Ms. N. Green, EPA Region Ill I Mr. Mike Brunamonti, PaDEP X-01)
RYVomplate items 1, 2, end S. Als co#mplete Item 4 If Restricted Delivery is dsIred, 12 Print your name and address on the reverse so that we car raturn the cwd to you.
r3 Attach this card to the back of the mallpiece, or on the front Ifsp**e permits.
- 3. servce Type
%certified mal E3 Express man o Registered 03 Return Receipt for Merchandise p~o. wb) 94, Oi d mai C.O.D.
~~ PA t9~w 4. Riskrlcted Delivefy? (E~dii Fee) Yes ffira70d2 '21410l 5085'55 1507 SFom3811T, Februar 204 Domestlc ReAnR~ep 10265-M0-M-16401
- Cmpet~tm1,12, and i,.4jso oornete' A r, Itm4# Restricted Delivery I dsired. gn ElPutyqur ~anddaddress on the reverse JJýdressee tac l hisýcarird to thebck ftemipee eevd~~ne so taweanrtrth art to you.. Naer~
or on' th fot'"Itspc pemis ~ dhdfedtfo tem1 I. Article to Addressed '.8If YS nte eery, addres below:
e 0 N i.At Ad ieTprE ~e a 3811 Febsar 200 PS Forml Domesti Return Recip 12 .Merchndis 1 PS Form 3811, February ý004 Domestic Retum Receipt 102595-02-M-1640;
3800-PM-WSFR0008c Rev. 3/2006 Checklist COMMONWEALTH OF PENNSYLVANIA W
r 0PennsyW Ia DEPARTMENT OF ENVIRONMENTAL PROTECTION PROTECTION BUREAU DEPAR7T4ENTOFENV1RON1ENTAL F OF WATER STANDARDS AND FACILITY REGULATION APPLOCATOON FOR NPOES PERMOT IFOR INDUSTROAL DOSCHARGOERS APPULCAINT'S v~CHECKLIST PPL Susquehanna, LLC Iease check the following list to make sure that you have included all the required information. Place a checkmark in the column provided for all items completed and/or provided.
Failure -toprovide all of the requested information will delay the processing of the application and may result in-the application being placed on hold with no action, or will be considered withdrawn and the applicationr file clOsedo Check If DEP Use item Included Only l 1. General Information Form (8000-PM-IT0001)
- 2. One original and (2) copies of application package submitted [original must be notarized]
- 3. Additional copy for Erie and Allegheny counties (if required) El
- 4. Additional copy for the river basin commission (if required) El
- 5. Application Fee - $500
- 6. Prop~er evidence of Act 14 municipality and county notification
- 7. Proof of local newspaper public notice (for new and substantially changed 0l dicags only) ______
8., jTTpogaplhic -Map ______
- 9. Industrial-Wastewater - Module 1 "10.' stiewer Treai.ment technologies- Module 2
- 11. Sources Of Wastewater sheet(s) - Module 3
- 12. Analysis Results Table(s) - Modules 4-9 _ _
m13. Hazardous Substance Table - Module 10 []
Ij714.Toxic Chemicals (Optional) - Module 11 __
- 15. Stormwater (if required) - Module 12 []
- 16. Stormwater Sampling Data Table (if required) - Module 13 _ _
- 17. No Exposure Certification (if required) - Module 14 El 18 Other: Additional Outfall description, 316B Supporting Statement, Requested Permit Changes
I r-onn SOpennsy, anT1aPTECTofJ COMMONWEALTH OF PENNSYLVANIA
-I DEPARTMENT OF ENVORONMEiNTAL PROTECTION GE!NERIAL IN IIAIN FORMI -=AUTHOI IZATION APPLOATOIN Before completing this General information Form (GIF), read the step-by-step Instructions provided in this application package.
I This version of the General information Form (GIF) must be completed and returned with any program-specific application being submitted to the Department. I INotes I LLC I
Organlzation Name or Registered Fictitious Name
'PPL Susquehanna, LLC Employer ID# (EIN) Dun & Bradstreet PD#
23-3022601 14-498-6556 I
Individual Last Name First Name Ml Suffix SSN N/A Additional Individual Last Name First Name Ml Suffix SSN I
N/A Mailing Address Line 1 769 Salem Blvd.
Address Last Line - City State Mailing Address Line 2 ZIP+4 Country I
Berwick PA 18603-0467 USA ClientIContact Last Name auscb ,Timothy First Name Mi S.
Suffix Mr.
I C-16iff'Cbntact Title Phone Ext SRVP-F-f.leif Nuclear Officer 570-542-3445 MAIIi,.Ad d r'e"s-Eml Ti!web.com . . ..
FAX 570-542-1504 I
DEP Site ID# Site Name PPL Susquehanna, LLC I
EPAiID# PAD 000765883 Estimated Number of Employees to be present at Site 1000 Description of Site Two Unit'Generating Station I
County Name Municipality City Boro Twp State Luzerne County'Name Salem .Township Municipality El City 11 Boro
.0 Twp State I El El El Site Location Line I Site Location Line 2 769 Salem Blvd.
Site Location Last Line - City State ZiP+4 I
Berwick PA 18603-0467 Detailed Written Directions to Site 7 miles North of Berwick on U.S. Route 11 I Site Contact Last Name First Name Mi Suffix Saxton Site Contact Title Services &Programs Supervisor Curtis Site Contact Firm PPL Susquehanna, LLC H Mr.
I Mailing Address Line I Mailing Address Line 2 769 Salem Blvd.
Mailing Address Last Line - City State ZIP+4 I
Berwick PA 18603-0467 Page 1 of 7 I
WNQ=PNU-OT60' Rev Uf2 Phone E878 F05X Emall Adrs 570-542-1t879 570-54*2-34 ,61 NAPCS Codes (Two- &Three-Digit Codes - List All That Apply) 6=D-0gt Code (Optional) 221 221113 Client to Site Relationship OWNOP
_-~qjftyYes 'No
- 1. W*ll this project modify an existing facility, system, or activity? El 0
- 2. Will this project involve an addition to an existing facility, system, or activIty? El 0 If _Yes" check all relevant facility types and provide DEP facility identification numbers below.
Facility Type DEP Fac 1D# Facility Type DEP Fac 10#
nl Air Emission Plant L] Industrial'Minerals Mining Operation I] Beneflili i Use6(water) _ El Laboratory Location fl Blasting Operation _ _ Land Recycling Cleanup Location Q Captive Hazardous Waste Operation _ _ MineDrainageTrmt/LandRecyProjLocation _
F1 -Coal'AshivB"eniiclal'Use Operation _ _ Municipal Waste Operation Fr Coal Mining Operation _ _ Oil & Gas Encroachment Location Coal Pillar Location _ _ 1Oi& Gas Location El Commercial Hazardous Waste Operation _ _ Oil & Gas Water Poll Control Facility El Dam Location _ _ Public Water Supply System n Deep Mine Safety Operation -Anthracite _ _ Radiation Facility n Deep Mine Safety Operation -Bituminous _ _ Residual Waste Operation 5] Deep Mine Safety Operation -Ind Minerals _ _ *StorageTank Location 5 Encroachment Location (water, wetland) _] Water Pollution Control Facility El Erosion & Sediment Control Facility _l Water Resource E] Explosive Storage Location El Other:
Latitude/Longltude Latitude .. Longitude Poi1nt off Origin Degrees Minutes Seconds Degrees Minutes ISeconds 41 5 30 -76 8 55 Horizontal Accuwacy:0Measure Feet 20.0 --or-- Meters HorizbntalAReference Datum Code El North American Datum of 1927 0] North. American Datum of 1983 El- Wrld Ge6detic Sysiem of 1984 Hboizontal Colection Method Code GPSST/SURVY Reference Point Code H20PI Ul Altit*ide" Feet 676' . -or-- Meters, A~tittude Datum Name E-l The-Natiohal'Godetic Vertical: Datumof 1929 ii [] The North American Vertical Datum of 1988 (NAVD88)
- Altitude (Vertical) Location Datum Collection Method Code GPSST/SRVEY Geometric TypeCode, POINT.
I Data Colect1io Date. 12/21/04 Source Map Scale Number 1" Inch(es) = 24,000 Feet
- -.timtira r(tc = Mhltorm
- PPL Susquehanna, LLC Project Description NPDES Permit Renewal Project Consultant Last Name First Name Ml Suffix N/A I Project Consultant Title Consulting Firm N/A IN/A Mailing Address Line I Address Last Line - City Mailing Address Line 2 sate ZIP+4 N/A Page 2 of 7
,IG88@P-PRrJ4-U 0861 Rev. 1012010D I
NA Pnn Irli FA~X Ernall Addoso I
Time Sheduies, Project moi~lestone (Optionai I
I I. Have you informed the surrounding community and addressed any []
concerns prior to submitting the application to the Department?
Yes LI No I
- 2. Is your project funded by state or federal grants? LI Yes [] No Note: If "Yes", specify what aspect of the project is related to the grant and provide the grant source, contact person and grant expiration date.
Aspect of Project Related to Grant I
Grant Source: ,_
3.
Grant Contact Person: __.................... .......
Grant Expiration Date:
Is this application for an authorization on Appendix A of the Land Use 0I Yes No0]
I Policy? (For referenced list, see Appendix A of the Land Use Policy attached to GIF instructions)
Note: If "No" to Question 3, the-application is .not subiect.to the Land Use Policy.
I If "Yes" to Question 3, the application is subject to this policy and the Applicant should answer the additional questions in.the Land Use Information section., I Note: Applicants are encouraged to submit copies of local land use appr-ovals or other evidence of compliance with local comprehensive plans and zoning ordinances.
1.
2.
is there an adopted county or wimuti-county coqmpehenslye plan?
Is there an adopted nmunlcipal or mUlt1-muhnlclp*i*'prehenslve plan?.
I Yes Yes El LI No No I
- 3. Is there an adopted county-wide zoninog odinance, municipal zoning ordinance or joIin Note:
un-UIcipall zoning ordinance
[I Yes El If the AppliCant answers "No", to6either Questions 1,2 or 3 the provisions of the PA MPC are not applicable and No I
the Aplicart doesh,6 ntneed to respond to iiestionS 4iands5 below.
If the Applicant answers to questions qYes" 112r'. 3,ýt1ie Applicant should respond to questions 4 and 5 below.
- 4. Does the-proposed project meet rh eprovisions'of the zfoning ordinance or does the proposed project have zoning approval? If zoning approval has been 0I Yes ._ No I received; attach documnenta'tiohn.
- 5. Have you attached Municipal andCounty Land UseLettrs for the project? LI Yes [1 No I
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Page 3 of 7
-le'110 fil5Ce 4 T0.0 51 Ncw. IM 0,W, Note: The PA Historical and Museum Commission must be notified of proposed projects in accordance with DEP Technical Guidance Document 012-0700-001 and the accompanying Cultural Resource Notice Form.
Of the activity will be a mining project (i.e., mining of coal or industrial minerals, coal refuse disposal and/or the operation of a coal or industrial minerals preparation/processing facility), respond to questions 1.0 through 2.5 below.
Of the activity will not be a mining project, skip questions 1.0 through 2.5 and begin with question 3.0.
1.0 Is this a coal mining project? If 'Yes", respond to 1.1-1.6. If "No", skip to L1 Yes 0I No Question 2.0. (DEP Use/48yl) 1.1 W1ll this coal mining project involve coal preparationl processing LI Yes LI No activities in which tthe total amount of coal prepared/processed will be equal toor greater than 200 tonslday? (DEP Use/4x70) 1.2 Will this coal mining project invblve coal Oprbparationl processing Li Yes 0I No actilvities in which the total amount of coal prepared/processed will be greaterlthan 50,000 tons/year? (DEP Use/4x70) 1.3 Will this coal ning, project Involve coal preparation/ processing EL Yes [I No activities in which thermal coal dryers or pneumatic coal cleaners will be used? (DEP Use/4x70) 1.4 For this coal mining project, will sewage treatment facilities be El Yes El No constructed and treated waste water discharged to surface waters?
(DEP Use/4x62) 1.5 Will this coa0 mining project invoive" the, constrUction of a permanent LI Yes [I No impoundment -meeting one or more of *the following criteria: (1) a contibuory* drakinage area exceeding 100 acres; (2) a depth of water measured by the upstream toe of the dam at maximum storage elevation exceeding 15 feet; (3) an impounding "*p*c*ty at maximum storage eleaton xcedng 0 crefet?(DE (A/3 40) 1.6 WIll this coa mi n ingprojectinvolve ulhdeirground coal mining to be LI Yes nI No conducte~d ,withln 500 feet ,of, nopl, or.gas wei:ll? (DEP Use/4z41) 2.0 *snisotL'an "a-'cbai (in'diWs*ial'mine)firftl 'g prjet? If'Yes", respond to EL Yes LI No 2.1?.6... If "No', skip to Question,3.0. (DEP Use/48y1) 2.1 Will this non-coal (Industrial minerals)ý, mining project Involve the EL Yes EL No crushing and screening of non-coal minerais other than san-d and -
graV-el? (DEP Use/4x70) 2.2 Will' this non-coal' (industrial' nerSal) 'mn ing project involve the EL Yes [I No crushing and/or screening of sand and gravel with the exception of wet sand and gravel operations (screening only) and dry sand and gravel operations with a capacity of less than 150 tons/hour of unconsolidated rmatbrlais? (DEP Use/4x70) 2.3 Will this non-coal (Industrial minerals) mining project Involve the EL Yes LI No construction, operation and/or modification of a portable non-metallic (i.e., non-coal) minerals processing plant under the authority of the General Permit for Portable Non-metaillc Mineral Processing Plants (i.e.,
BAQ-PGPA/GP-3)? (DEP Use/4x70) 2.4 For this non-coal (industrial minerals) mining project, will sewage EL Yes LI No treatment facilities be constructed and treated waste water discharged to surface waters? (DEP Use/4x62) 2.5 Will this non-coal (industrial minerals) mining project involve the LI Yes LI No construction of a permanent impoundment meeting one or more of the following criteria: (1) a contributory drainage area exceeding 100 acres; (2) a depth of water measured by the upstream toe of the dam at maximum storage elevation exceeding 15 feet; (3) an Impounding capacity at maximum storage elevation exceeding 50 acre-feet? (DEP Use/3140)
Page 4 of 7
11OM-PMro1000 £evf. 10I2OrjS I
0.0 Will your project, activity, or authorization have anything to do with i 0_ ..Yes 01 No well *a*elec to oil or gas production, have construction within 200 feet of, affect an oil or gas well, Involve the waste from such a well, or string 3.1 power lines above an oil or gas well? If 'Yes", respond to 3.1-3.3. If "No",
skip to Question 4.0. (DEP Use/4z41)
Does the oil- or gas-related project Involve any of the following: U Yes El No I
placement of fill, excavation within or placement of a structure, located in, along, across or projecting Into a watercourse, floodway or body of I water (including wetlands)? (DEP Use/4z41) 3.2 Will the oil- or gas-Felated project Involve discharge of industrial wastewater or stormwater to a dry swale, surface water, ground water or an existing sanitary sewer system or storm water system? If 'Yes",
0 Yes U No I
discuss in Project Description. (DEP Use/4z41) 3.3 Will the olil- or gas-related project Involve the construction and operation of industrial wastetreatment facilities? (DEP Use/4z41)
CU Yes n No I 4.0 Will the project Involve a construction activity that results In earth U Yes 0 No 5.0 disturbance? If '*Yes", specify the total disturbed acreage. (DEP Use/4x66) 4.0.1 TOti Disturbed Acreage Does the project Involve any of the following? 0 Yes l] No I
If 'Yes", respond to 5.1-5.3. If "No", skip to Question 6.0. (DEP Use/4xl0) 5.1 Water Obitruction and Encroachment. Projects - Does the project involve any of the following: placement of fill, excavation within or U Yes M] No I 5.2 piacement of a structure, located In, along, across or projecting into a watercourse, floodway or body of water? (DEP Use /4x10).
Wetland Impacts -Does the. project Involve any of the following:
placement of fill, excavation within or placement of a structure, located 0 Yes [] -No I
In, along, abroiss§ orý projecting into a wetland? (DEP Use/4xi 0).
5.3 Floo6dplain Projects bythe commonwealth, a Po1lticalSubdivlsion of the commonwealth or a Public Utility - Does the project involve any of the U Yes [ No I f0ollwing: placement of fill, excavation .within or placement of a 6.0 structure, located in, along, across or projecting into a floodplain? (DEP Use /4x10).
Wil0l the project Invoive discharge of stormwater or wastewater from an I] Yes [3 'No 1
indI diaD bvtIityti to a dry swale, su face water, ground water or an existing sanitary sewer system or separate storm, water system? (DEP Use/4x62)
I 7.0 Will the project Involve the construction and operation of industrial U] Yes [9 No 8.0 waste treatment facilities? (DEP Use/4x62)
Will the project involve construction of sewage treatment facilities, sanitary sewers, or sewage pumping stations? If 'Yes", indicate estimated U Yes I] No I proposed flow (gal/day). Also, discuss the sanitary sewer pipe sizes and the number of pumping stations/treatrnmnt facilities/name of downstream sewage facilities in the ProjectDescription,where applicable. (DEP Use/4x62)
I 8.0.1 Estimated ProposedFiow (gaedday) 9.0 Will the project involve the subdivision of land, or the generation of 800 gpd or more of sewage on an existing parcel of land or the generation of an additional 400 gpd of sewage on an already-developed parcel, or the U Yes [] No I
generation of 800 gpd or more of Industrial wastewater that would be discharged to an existing sanitary sewer system? (DEP Use/4x61).
9.0.1 Was Act 537 sewage facilities planning submitted and U Yes U No I
approved by DEP? If 'Yes" attach the approval letter. Approval 10.0 required prior to 105/NPDES approval.
Is this project for the beneficial use of biosollds for land application within Pennsylvania? If 'Yes" indicate how much (i.e. gallons or dry tons per U Yes El No I year). (DEP Use/4X62) 10.0.1 10.0.2 Gallons Per Year (residential septage)
Dry Tons Per Year (biosolids)
I Page 5 of 7 I
6000-P=DTO12009 111.0 Does the project involve construction, modification or rmovaO of a dam? El -Yes x No If 'Yes", identify the dam. (DEP Use/3140) 11.0.1 Dam Name 12.0 Will the project Interfere with the flow from, or otherwise impact, a dam? [] Yes 0, No If 'Yes", identify the dam, (DEP Use/3140) 12.0.1 Dam Name 13.0 Will the project involve operations (excluding during the construction El Yes [] No period) that produce air emissions (i.e., NOX, VOC, etc.)? If '*Yes", identify each type of emission followed by the amount of that emission. (DEP Use/4x70) 13.0.1 Enter all types & amounts of emissions; separate each set with semicolons.
14.0 Does the project include the construction or modification of a drinking El Yes [] No water supply to serve 15 or more connections or 25 or more people, at ieast 60 days out of the year? If 'Yes", check all proposed sub-facilities.
(D IEP Use/481),
14.s.1 Number of Persons Served 14.0.2 Number of Employee/Guests 14.0.3 Number of Connections 14.0.4 Sub-Fac: Distribution System El Yes El No 14.0.5 Sub-Fac: Water Treatment Plant 0] Yes 17 No 14.0.6 Sub-Fac: Source [I Yes 17 No 14.0.7 Sub-Fac: Pump Station 0l Yes El No 14.0.8 Sub Fac: Transmission Main El Yes El No 14.0.9 Sub-Fac: ,Storage,Facility 0l Yes El No 15.0 Will your project include infiltration of storm water or waste water to 0l Yes ED No grouhd water within onehalf mie of a, public water supply well, spring or infiltration gallery? (DEP Use/4x81) and 4x52).
16.0 Is your project to be served by an existing public water supply? If 'Yes", El Yes I] No indicate name of supplier and attach letter from supplier stating that it will serve the project. (DEP Use/4x81) 16.0.1 Suppiie,'s.Namie 16.0.2 Letter of,Approval from Supplier is Attached El Yes I] No 17.0 Will this project involve a new or increased drinking water withdrawal El Yes I] No from a stream or other water body? If 'Yes", should reference both Water Supply and Watersth6d Management. (DEP Use/4x81 and 4x10) 17;0.1- Stream Name 18.0 Will the construction or operation of this project Involve treatment, El Yes I] No storage, reuse, or disposal of waste? If 'Yes", indicate what type (i.e.,
hazardous, municipal (including infectious & chemotherapeutic), residual) and the amount to be treated, stored, re-used or disposed. (DEP/Use4x32) 18.0.1 Type & Amount, 19.0 Will your project Involve the removal of coal, minerals, etc. as part of any El Yes [] No earth disturbance activities? (DEP Use/48y1) 20.0 Does your project Involve Installation of a field constructed underground El Yes I] No storage tank? If 'Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570) 20.0.1 Enter all substances &
capacity of each; separate each set with semicolons.
21.0 Does your project involve installation of an aboveground storage tank El Yes [] No greater than 21,000 gallons capacity at an existing facility? If 'Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570) 21.0.1 Enter all substances &
capacity of each; separate each set with semicolons.
Page 6 of 7
Moo 41M-0-v WWI C Row. 1012059 I
22ADD DGoEs YGuI projjewt invoilve ainatafan of a tank gjreater' than 'ý1,i 00 gallons Which Will Contain a highly hazardous substance as defined in DEF'a 0i -Ye I] Nc~ 5 Regulated Substances List, 2570-BK-DEP2724? If "Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570) 22.0.1 Enter all substances &
I capacity of each; separate 23.0 each set with semicolons.
Does your project involve Installation of a storage tank at a new facility [] Yes 0 No I
with a total AST capacity greater than 21,000 gallons? If "Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570) 23.01. Enter all substances &
capacity of each; separate each set with semilcolons.
I 24.0 WRi!,"the Intended activity involve the use of a radiation source? (DEP Hcertity tnat u have the authority to submit t**s appoicatoon on Denaur or mne appiecant namea nerein ana that the information provided In this application Is true and correct to the best of my knowledge and information.
I Type or Print Name Timothy S... Rausch VP - Chief Nuclear OfficerTD -
SSR Si natur 1 Title Date I
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Page 7 of 7
3800-PM-WSFROO08b Application Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC A p ennsytvan a I ~pennsytvania O-.E.TF-ENVRONNTALPR.TECTON COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION I NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)
APPLICATION FOR PERMIT TO DISCHARGE INDUSTRIAL WASTEWATER I
I Before completing this form, read the step-by-step instructions provided in this application package.
Related ID#s (If Known) .... '* °..EON" Client ID# APS ID# Date Received & General Notes Site ID# Auth ID#
Facility ID#
phPPLICANT h , IDENTIFIERPu ApplicantlOperatorNam~e PPL Susquehanna, LLC
'is this an application for a:
El New permit Complete the General Information Form (GIF) 8000-PM-IT0001 and attach to the front of the application.
[ Permit Renewal List the current NPDES Permit number PA-0047325 Complete the Client and Site Sections of the GIF and attach to the front of the application.
El Permit Amendment or Permit Renewal with Amendment List the current NPDES Permit number PA List the current WQM Permit number Complete the GIF and attach to the front of the application.
_______________ ____________GENERAL lNF'ORMATlON6 1:4-A:
- 1. SIC Code NAICS Code Corresponding SIC/NAICS Description 4911 221113 Electric Utility Power Generation
- 2. Is the facility required to obtain a stormwater NPDES permit for any listed SIC code?
0 YES (Answer question 3 below.) El NO (Skip question 3.)
- 3. Is the facility applying for permit exemption under the No Exposure rule? (See Instructions)
ElYES Z NO
- 4. General Description and Nature of Business.
Two Unit Nuclear Generating Station
Permit Type Permit Number Date Issued NPDES Permit PA 0047325 September 1, 2005 Water Quality Permit - STP 4085411 October 7, 1985 Water Quality Permit - IND. 4076203 May 25, 1977 0001
3800-PM-WSFROO08b Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Application
- 6. ATTACH TOPOGRAPHIC MAP (See Instructions)
- 7. NUMBER OF OUTFALLS
- a. Industrial Wastewater Only 2 Complete Module 1 and associated Modules.
I
- b. Combined Industrial Wastewater and Stormwater 3 Complete Module 1, associated Modules and Module 12 or Module 14 (if required).
I 3
8.
- c. Stormwater Only Complete Module 12 or Module 14.
OUTFALL LOCATION: Using the same Locational Data supplied on the General Information Form under Facility Information, list the latitude and longitude of the location to the nearest ten-thousandth of a second and the name I
of the receiving water of each outfall. Where available, the receiving stream width and depth should also be provided using actual measurements or topographic map and navigational charts.
LOW FLOW I
OUTFALL LATITUDE LONGITUDE STREAM NUMBER (list) Deg Min Sec Deg Min Sec RECEIVING WATER (Name) Width (ft) Depth (ft) I 070 41 5 18.4 -76 8 34.1 Lake Took-a-While 160 3 071 41 5 12.4 -76 7 53.2 Susquehanna River 800 13 I 072 41 5 34.2 -76 8 42.8 Lake Took-a-While 160 3 073 074 41 41 5
5 33.3 28.9
-76
-76 8
8 49.6 49.3 Lake Took-a-While Lake Took-a-While 160 160 3
3 I
075 079 41 41 5
5 40.2.
13.8
-76
-76 8
7 17.5 53.4 Lake Took-a-While Susquehanna River 160 800 3
10 I
9.
080 41 5 33.4 -76 Name of Nearest Downstream Potable Water Intake 8 18.8 Lake Took-a-While Danville Water Authority 160 Distance 26 miles 3
I
- 10. WHOLE EFFLUENT TOXICITY (WET) TEST RESULTS Is there known or reason to believe that WET testing was conducted in the last 3 years on I
any of the facility's discharges, or on a receiving water in relation to a discharge? [: YES If "YES," attach any information available on the purpose and nature of such testing, and the test results.
. NO I
If "NO," all dischargers are still encouraged to perform WET testing. The DEP regional office may be contacted for appropriate protocols.
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I 0002 I
3800-PM-WSFROO08b Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Application
- 11. CONTRACTED ANALYTICAL ASSISTANCE Did a contract laboratory or consulting firm perform any of the analysis required by this application?
LI NO 0 YES (Provide information below.)
Name Analytical Laboratury Services Types of Analysis Performed:
34 Dogwood Lane All Physical Chemical BOD, COD, TSS, O&C, TOC, pH, Address MMetals, Volatiles, Organic Compounds, Acid Compounds, sMiddletown, PA 17057 Base Compounds, Nitrates, Ammonia, Priority Pollutants, and PCB's.
Phone (717) 944-5541 Name Teledyne Brown Engineering Types of Analysis Performed:
2508 Quality Lane Radiological Analysis Gross Alpha, Gross Beta Address Knoxville, TN 37931 Phone (865) 690-6819 0003
3800-PM-WSFROO08b Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC I
Application
- 12. ADDITIONAL INFORMATION: (OPTIONAL)
Additional information may be attached to expand upon any response to any questions or call attention to any other information felt should be considered in establishing permit limitations for the proposed or existing facility.
Check if additional sheets are attached.
I 0 YES [I NO I
Is the facility owner or operator in violation of any
,of compliance at this or any other facility?-
I If "YES," list, each permit, order and schedule of0comp*iance and provide compliance status. Use additional sheets to provide information on all permits.
P Program, P.ermit No. U Brief Dek&ription.6f Noncbm~pliande' I Steps Taken to Achieve Compliance Date(s) Complance Achieved I
Current Compliance Status j In Cornpliance lIn Noncompliance i
1 I cerify under' penalty of law that this document andall attachments were prepared under my direction or supervision
,in accordance with'*a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. Based on my inquiry of ,,theperson or persons who manage the system, o& those persons dtrectly responsible for gatherngthe information, the information submittedlis, to the best of my knowledge and belief, I
true, accurate, and com plete. Iram aware(that there aresignificant penalties for submitting, false information, including the possibility ofr fifeand immprison-mrent for knowiag vipations. 1 Timothy S. Rausch' Namhe,(yeoritlg y SR VP/ ChieiNuclear Officer Officiall Title I
Signa: ureDt i sorporateor professionalseal as appropriate.)
(Use Taken, sworn, and subscribed before me, this 9 day of 20 Q I Notar. Seal I
COMMONWEALTH OF PENNSYLVANIA I Notarial Seal Laurie M.Minto, Notary Public Salem Tvp., Luzeme County My Oommission Expires July 24, 2010 I
Member, P77 '_*o rA-, of Notaries I
0004
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!-jt.!.' ýi
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onn* I OF4%E$ I o i*.....
- ti.ESprings Used for WaterI SupplyWithin I0Mile of SSESI I
NOTE:
14M5ERS INDICATE AppwROXmAT LocATION OF WELLS a 112 I1MILE FIGURE 43 Water Wells Within I Mile of SSES
') 2i 0 7/
I L~ne iDraw~ aer Miioidull I off NPE Poreram~t A~ll~f~
-I I
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() Chemical Addition 0008 I
I 3800-PM-WSFRO008d Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 1 0m N E COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION INDUSTRIAL WASTEWATER MODULE 1 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APLCANTNA PPL Susquehanna, LLC
- 1. Line Drawing. Attach a line drawing and water balance of flow through the facility. (See instructions)
- 2. OUTFALLS AND ASSOCIATED WASTEWATER TREATMENT TECHNOLOGIES Complete Module 2 identifying the treatment processes associated with each outfall.
- 3. SOURCES OF WASTEWATER Attach a separate Module 3 for every outfall.
Indicate the number of Module 3s attached. 8
- 4. REQUIRED AND OPTIONAL ANALYSIS I a. Summary of Required Analysis Pollutants or Pollutant Required Discharge Contains (see Instructions) Groups which must be Number of Outfall Process Sanitary Misc. GW sampled for and Sample Events Number Waste NCCW Waste Waste Cleanup Stormwater analyzed (see instructions) 070075080 E E El El El 0 Module 13 1 071 El: El El El El 1,2,3,4,5 & PCBs 3 072 El El El 0 El El Selected Group 1 1 073. 074 El El
[j 0 El El Selected Group 1 1 079 11 El 10 El El El Group 1 1 River Intake El El El El El E] 1,2,3,4,5, & PCBs 3 (Optional)
- b. Complete the modules for the Pollutant(s) or Pollutant Group(s) identified above. A separate module must be submitted for each process wastewater and combined (process wastewater and stormwater) outfall identified in the application. List the number of modules for each Pollutant Group submitted with this application.
5 Module 4 - Pollutant Group 1 2 Module 5 - Pollutant Group 2 - Metals 2 Module 6 - Pollutant Group 3 - Volatile 2 Module 7 - Pollutant Group 4 - Acids 2 Module 8 - Pollutant Group 5 - Base/Neutral 3 2 Module 9 - Pollutant Group 6 - Pesticides 0009
3800-PM-WSFROO08d Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 1
- c. Optional Site-Specific Data Additional modules may be attached to provide any of the optional site-specific information discussed in Appendix 2. (The modules should be used to report intake water quality, upstream background or ambient water I quality, and parameter-specific coefficient of effluent variability. Space is provided at the top of the module to provide description of sampling points used.)
Optional data is attached to application. EYES ENO 3
- 5. PREPAREDNESS, PREVENTION, AND CONTINGENCY (PPC) PLANNING.
Does the facility have a PPC plan?
EDYES LNO Does the facility have any other related plans, such as a Pollution Incident Prevention (PIP) Plan, Spill Prevention I
Control and Counter Measure (SPCC) Plan or BMP Plan?
If "YES," identify and indicate date(s) implemented.
EDYES ENO I Type of Plan Date Implemented 3 PPC Plan Note: Two (2) copies provided w/Application (Updated) 1/8/2010 SPCC Plan Note: Two (2) copies provided w/Application (Updated) 1/8/2010 DEP may require the plan(s) be sabmitted with this application.
- 6. OTHER INFORMATION (OPTIONAL): Attach additional sheets describing any additional environmental pollution control programs which may affect the discharges which are underway or which are planned. Indicate whether each program is now underway or planned, and indicate the actual or planned schedules.
[] MARK "X" IF DESCRIPTION OF ADDITIONAL INFORMATION IS ATTACHED II I
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mminmmm~~
3800-PM-WSFRO008d Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module I
- 7. INFORMATION AND ANALYSIS OF EFFLUENT QUALITY FOR OTHER POTENTIALLY TOXIC POLLUTANTS
- a. Information on Chemical Additives (Read instructions carefully and use the tabular format to present the required information)
Average & Concentration Lowest Possible Whole Product Whole Product Chemical Substance or Maximum Analytical 96 Hr LC50 48 Hr LC50 Compound Trade Names Manufacturer Usage Rate Detection (mg/L) and (mgIL) and Outfall or Specific Ingredients Name and Address lbs/day In-system Effluent Units Level (Ipg/L) species9) species(1 )
Acrylic Acid Sulfonated Nalco Company 1601 Avg. 950 Acrylic Acid Copolymer 01Max W. Diehl Rd. 2,000 2,400 2,400 ug/I 1,500RanoTru Rainbow Trout DphiMga Daphnia Magna Dispersant, 3DT121 Naperville, IL 60563- (180,000 2bsyr) (4,900 mg/I) (2,800 mg/I) 32.125 1189 Hydroxy ethylidene Avg. 750 disphosponic acid Rainbow Trout. Daphnia Magna 071 (HEDP) Supercool 1393 Max 1,500 4,000 4,000 ug/I 83 (368 mg/I) (527 mg/I) 32.127 (90,000 Ibs/yr)
Solution of Quaternary Alkyl Ammonium Avg. 800 071 Compound Molluscide Max 2,000 10,600 100 ug/I 100 ug/I Bluegill Sunfish Daphnia Magna and General Biocide, (160,000 Ibs/yr) (0.32-0.59 mg/I (0.094 mg/I) 32.126 H-130 S du Br md , 21 4A g 50Rainbow Trout Daphnia Magna 071 Sodium Bromide, 32.114 Avg. 500 3,300 3,300 ug/I 125 (0.23 mg/L) Note (apni Magna Acti-Brom 1318 Max 1,000 (2) (0.71 mtg/I)
Magnesium Nitrate and GE Betz Dearborn 5-Chloro-2-methyl Inc. 4636 Somerton See Note 3 Rainbow Trout' Daphnia Magna 071/072/079 isothiazolin-1 Rd. Trevose, PA (8.7 mg/I) (2.9 mg/I) 32.53 NX-1106 19057 Nalco Company 1601 071/072/079 Glutaraldehyde 40%- W. Diehl Rd. See Note 4 i Flathead Minnow Daphnia Magna 70%, 32.70 H-550 Naperville, IL 60563- (12 mg/I) (12 mg/I) 1189 Proprietary Descaling GE Betz Dearborn In.43 oetnFlathead Minnow Daphnia Magna 071 Agent Ferroquest Inc. 4636 Somerton See Note 5 ---
LP7200Rd. Trevose, PA 1500 mg/L 1000 mg/L 19057 Nalco Company 1601 A ,
- Bentonite Clay Slurry, W. Diehl Rd. - 2,000 Max
-.071 32.128 Naperville, IL 60563- -800 (350,000 0 330,000 ug/l 100 1189 Ibs/yr) 3800-PM-WSFROO08d Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module I Manley-Regan Sodium Hypochlorite, Chemicals,532 East Avg - 5,000 Ceriodaphnia 071/079 15%32.63 Emaus St., PO Box 33,000 33,000 ug/I 400 Dubla (1.23 g/l) 280 Middletown, PA Max- 10,000 17057 AgroEvo Environmental Health, 071 Rotenone, 32.15 95 Chestnut Ridge See Note 6 Rd., Montvale, NJ 07645 SePro 071 Fluidone, 32.46 11550 N. Meridian See Note 6 --- ---
Carmel, IN 46032 Nonoxiding Biocide, GE Betz Dearborn Avg. 800 071 Quaternary Ammonium Inc. Max2000 10,600 100 ug/l 100 Rainbow Trout 2 Daphnia Magna Chloride, Spectrus 4636 Somerton Rd., mg/L 0.04 mg/L CT1300, SAMM 32.126 Trevose, PA 19053 160,000 lbs/yr Detoxifier for Avg. 2,000 071 Nonoxidizing Biocide, 100 Fathead Minnow Daphnia Magna Clay Slurry DT1400 Max435 mg/L 435 mg3L SAMM 32.128 350,000 lbs/yr Hydroxy ethylidene Avg. 750 071 disphosporic acid 83 Fathead Minnow Daphnia Magna (HEDP) Depositrol Max 1500 4000r 4000 ug mg/L BL5400 SAMM 32.127 90,000 lbs/yr Allied Corp.
071/079 SodiumNalco Bisulfite 740832.113 Chemical PO Box 1139RSector Avg - 183 500 ug/I 125 Mosquito (240/I)Fish Mosquito Fish (240 mg/L)
Morristown, NJ 07960 Allied Corp.
071 Sulfuric Acid, P.O. Box 2064R (Approx.
32.57 Morristown, NJ 435,000 lbs/yr) 079609 GE Betz Dearborn Avg - 96 lbs/day Fatheard 071 Depositrol PY5206 Inc., 4636 Somerton M 32,000 1,140 ug/I 12,000 Minnow Daphnia Magna 32.137 Rd. Trevose, PA Max - 385 31g2ih mg/L) 19057 lbs/day (1,680 mg/L) 071 Aquashade 32.135 Applied Biochemists See Note 6' 5,000 mg/I 5 ug/I 100 pHREEdom 5200 Calgon Corp. Avg 750 071 Scale Control P.O. Box 1346 Max 1500 4000 4000 ug/l 83 ---
SAMM 32.133 Pittsburg, PA 15230 - 90,000 lbs/yr MI - Mm m M m - M m - -M
1M Mm M --- Mm M M 111 M M M mm Mm M 3800-PM-WSFROO08d Rev. 312006 Applicant Name: PPL Susquehanna, LLC Module 1 (1) If LC50 Data for whole product is not available, data for the individual active ingredients may be provided.
3800-PM-WSFROO08d Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 1
- b. Specific Substances which must be identified if Known or Expected to be Present (Read instructions carefully and use the tabularformat and additional pages, where necessary, to present the required information)
Average Effluent Analytical Concentration Detection Level Outfall Chemical Substance or Compound Reason for Presence in Discharge (pg/L) (pg/L)
- c. Are any Table 2 substances identified for which a spill reporting exemption is requested? EYES DNO If "YES," complete the Hazardous Substance Table.
- d. Any other toxic chemicals known or expected to be present in the discharge.
Report any additional significant detections in effluent samples on the Other Toxic Chemicals sheets. None M M M M M - m M- - - M - mMM
MODULE 1, Item 7, Section a. Continued Note (1) Equivalent chemicals from other suppliers may be purchased. Product concentrations may change; however, the concentration of active ingredients discharged should remain about the same. Approval numbers are included for those chemicals listed in the Susquehanna Approved Materials Manual.
Other chemicals will be approved prior to their use onsite.
Note (2) Toxicity of hypobromous acid is expressed as bromine.
Note (3) Approximately 25 gallons/year of this biocide is -injected into the closed system cooling water to a maximum average concentration of 330 mg/I of product or 5.0 mg/I as active isothiazolin. Occasionally these systems are drained to the Cooling Tower basin. This product would not be expected to be detected in the Cooling Tower blowdown.
Note (4) Glutaraldehyde is added to closed cooling water systems to maintain microbiological control. A maximum concentration of 300 mg/I active or 600 mg/I product is used. Occasionally these systems are drained to the Cooling Tower blowdown. This product would not be expected to be detected in the Cooling Tower blowdown.
Note (5) The Cooling Tower blowdown is isolated when this descaling agent is used in Circulating Water System (4,000 gal/treatment). Treatment has been very infrequent.
Note (6) Rotenone and Fluridone are products used in the Emergency Spray Pond that has been permitted for use by the Pa Fish andBoat Commission- and the PaDEP. The Emergency Spray Pond is treated when needed with 1,000 lbs.
of Rotenone to a level of 5 mg/I; however, it is detoxified with potassium permanganate at a rate equal to this concentration prior to discharge and, therefore, is not expected to be present in Outfall 071. Also, 32 lbs. of Fluridone will be applied as necessary to an area of 8/10 surface acre along the pond's edge. Aquashade is used around the perimeter of the pond periodically in the summer to control algae growth.
0015
I Note (7) Miscellaneous chemicals used in very small quantities for cleaning surfaces, cooling coils, decontamination of floors, walls, and equipment, cleaning I
agents, liquid dye for flow tests, laboratory reagents and standards, etc. The
.following are some of these chemicals:
Chemicai/SAMM # Est. gal/yr. I Power Coil, A-10.29 Coil Rite, C-1 0.334 a
a I
Acti-Klean, C-10.326 a By-Pas, E-10.11 Organic Orange, E-10.35 220 110 I
Citirikleen, E-10.29 a MSA/Cleaner/Sanitizer II, E-10.8 H2 Orange2, C-10.451 288, b a
I Touch It Up, E-10.4 Corrshield NT 4204, 32.90 Zeta Lyte 15 a
50 d
I Nalco 9905, 32.81 Ethylene Glycol mixture, 16.20 Iron Oxalate, 32.129 d
c I 500 lbs./yr.
Polyfloc CP1160, 32.130 Polyfloc AP1 100, 32.131 Propylene Glycol Mixture, 16.20 20 lbs./yr.
20 lbs./yr.
c I
EPA 2000 WCI-140, B-10.27 Trisodium Phosphate, A-10.24 Sodium Hydroxide, 32.59 a
a I 500 Sodium Nitrite, 32.14 Nitric Acid, 38.89 Enriched Sodium Pentaborate, 32.138 200 lb/yr 5 I c
Rhodamine WT Dye 32.68 a I
Key
- a. Not available
- b. Ounces I
- c. Present in equipment onsite and has potential for entering storm drains.
Preventative maintenance and analysis of replacement chemicals such as Propylene Glycol will minimize any adverse impacts to the environment. I
- d. Flocculent aid used infrequently for dewatering sludge.
Some of these chemicals may be discharged to the Cooling Tower Basins/ I Blowdown, Sewage Treatment Plant, or storm drains in accordance with their Material Safety Data Sheet recommendations.
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00 1 6 I
MATERIAL SAFETY DATA SHEET r4NALCO PRODUCT 3D TRASAR(R) 3DT121 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
- 11. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3DTRASAR(R)3DT121 -afac2 fe-L.---401 APPLICATION: COOLING WATER TREATMENT COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198
- vEMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 0/1 FLAMMABILITY: 1 /1 INSTABILITY: 0/0 OTHER:
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
- 12. 1COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.
- 13. 1HAZARDS IDENTIFICATION
- EMERGENCY OVERVIEW**
CAUTION May cause irritation with prolonged contact.
Do not get in eyes,.on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water.
Wear suitable protective clothing.
May evolve oxides of carbon (COx) under fire conditions.
PRIMARY ROUTES OF EXPOSURE :
Eye, Skin HUMAN HEALTH HAZARDS -ACUTE:
EYE CONTACT:
May cause irritation with prolonged contact.
SKIN CONTACT:
May cause irritation with prolonged contact.
INGESTION:
Not a likely route of exposure. May cause gastrointestinal irritation.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1/9 n017
I IB MATERIAL SAFETY DATA SHEET
)4fNALCO SPRODUCT 3D TRASAR(R) 3DT121 I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
INHALATION:
Not a likely route of exposure. No adverse effects expected. I HUMAN HEALTH HAZARDS - CHRONIC:
No adverse effects expected other than those mentioned above. I
- 14. I FIRST AID MEASURES II EYE CONTACT:
Flush affected area with water. If symptoms develop, seek medical advice.
SKIN CONTACT:
Flush affected area with water. If symptoms develop, seek medical advice.
I INGESTION:
Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give water I to drink.
INHALATION:
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.
I NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
1
- 15. 1FIRE FIGHTING MEASURES I FLASH POINT:
EXTINGUISHING MEDIA:
Not applicable I
This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARD:
I May evolve oxides of carbon (COx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
I In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
- 16. ACCIDENTAL RELEASE MEASURES I PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so.
I Ventilate spill area if possible.
I Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access I
2/9 I
MATERIAL SAFETY DATA SHEET
)041' NALCO PRODUCT 3D TRASAR(R) 3DT121 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
Do not contaminate surface water.
- 17. 1HANDLING AND STORAGE HANDLING:
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled.
STORAGE CONDITIONS:
Store in suitable labeled containers. Store the containers tightly closed.
SUITABLE CONSTRUCTION MATERIAL:
Polypropylene, Polyethylene, PVC, Plasite 7122, Polyurethane, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.
UNSUITABLE CONSTRUCTION MATERIAL:
Mild steel, Stainless Steel 316L, Stainless Steel 304, Brass, Buna-N, EPDM, Hypalon, Neoprene, Viton
- 18. 1EXPOSURE CONTROLSIPERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:
This product does not contain any substance that has an established exposure limit.
ENGINEERING MEASURES:
General ventilation is recommended.
RESPIRATORY PROTECTION:
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: Multi-contaminant cartridge, with a Particulate pre-filter.
In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
When handling this product, the use of chemical gloves is recommended., The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from, PVC, Gloves should be replaced immediately if signs of degradation are observed.,
Breakthrough time not determined as preparation, consult PPE manufacturers.
NalcO Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/9 0019
MATERIAL SAFETY DATA.SHEET I P0NALCO PRODUCT 3D TRASAR(R) 3DT121
'EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
SKIN PROTECTION:
I Wear standard protective clothing. See general advice.
EYE PROTECTION:
I When handling this product, the use of safety glasses with side shields is recommended.
HYGIENE RECOMMENDATIONS:
Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a I
safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. I
- 19. 1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid I
APPEARANCE ODOR Yellow Neutral I
SPECIFIC GRAVITY DENSITY SOLUBILITY IN WATER 1.13 @ 60.0 °F /15.5 -C 9.4 lb/gal Complete I
pH (100.0 %)
VISCOSITY FREEZING POINT 3.0 40.0 cst @ 68.0 °F / 20.0 'C 26.6 OF / -3.0 °C I
VOC CONTENT 0.0 % Calculated Note: These physical properties are typical values for this product and are subject to change. I 110. 1STABILITY AND REACTIVITY STABILITY:
I Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
I Hazardous polymerization will not occur.
CONDITIONS TO AVOID:
Avoid extremes of temperature.
I MATERIALS TO AVOID:
Bases Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic),
potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, I
splattering or boiling and toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS:
I Under fire conditions: Oxides of carbon Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 4/9 I 0020
MATERIAL SAFETY, DATA SHEET AVNALCO (PRODUCT 3D TRASAR(R) 3DT121 EMERGENCY TELE1PHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMITREC I I 11. I TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product. The following results are for a similar product.
ACUTE ORAL TOXICITY:
Species LD50 Test Descriptor Rat 5,000 mg/kg Similar Product ACUTE DERMAL TOXICITY:
Species LD50 Test Descriptor Rabbit > 2,000 mg/kg Similar Product SENSITIZATION:
This product is not expected to be a sensitizer.
CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
I 12. - ECOLOGICAL INFORMATION I ECOTOXICOLOGICAL EFFECTS:
The following results are for a similar product.
ACUTE FISH RESULTS:
Species Exposure LC50 Test Descriptor Rainbow Trout 96 hrs 4,900 mg/I Similar Product Bluegill Sunfish 96 hrs > 5,000 mg/l Similar Product ACUTE INVERTEBRATE RESULTS:
Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs 2,800 mg/I Similar Product MOBILITY:
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; I Air Water I Soil/Sediment
<5% 30 - 50% 50 - 70%
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 ° (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/9 0021
MATERIAL SAFETY DATA SHEET I
)'NALCO PRODUCT 3D TRASAR(R) 3DT121 I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL I
This preparation or material is not expected to bioaccumulate. I If released into the environment, see CERCLA/SUPERFUND in Section 15.
113. 1 DISPOSAL CONSIDERATIONS I If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. I As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility. I
- 14. 1TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)
I specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. I LAND TRANSPORT:
Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION I
AIR TRANSPORT (ICAO/IATA): I Proper Shipping Name: PRODUCT IS NOT REGULATED DURING MARINE TRANSPORT (IMDG/IMO):
TRANSPORTATION I
Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION I 115. 1 REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in I I this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information. I NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.
I Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 6/9 0022 I
MATERIAL SAFETY DATA SHEET P4"'ALCOPRODUCT 3D TRASAR(R) 3DT121 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC CERCLAISUPERFUND, 40 CFR 117,302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The currentthresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4 /formerly Sec. 311 :
This product may contain trace levels (<0.1% for carcinogens, <1% all other substances) of the following substance(s) listed under the regulation:
Substance(s) Citations 0 Sulfuric Acid Sec. 311
- Sodium Bisulfite CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances):
None of the substances are specifically listed in the regulation.
CALIFORNIA PROPOSITION 65:
This product does not contain substances which require warning under California Proposition 65.
MICHIGAN CRITICAL MATERIALS:
None of the substances are specifically listed in the regulation.
STATE RIGHT TO KNOW LAWS:
None of the substances are specifically listed in the regulation.
NATIONAL REGULATIONS, CANADA:
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/9 0023
AWNALCO IPRODUC MATERIAL SAFETY.DATA SHEET 13D TRASAR(R) 3DT121 EMERGENCY TELEPHONE NUMBER(S)
I I
(800) 424-9300 (24 Hours) CHEMTREC WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations I
(CPR) and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION:
I Not considered a WHMIS controlled product.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
I AUSTRALIA All substances in this product comply with'the National Industrial Chemicals Notification & Assessment Scheme I
(NICNAS).
CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing I
Chemical Substances China (IECSC).
EUROPE I
The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical I
Substances and are listed on the Ministry of International Trade & industry List (MITI).
KOREA This product contains substance(s) which are not in compliance with the Toxic Chemical Control Law (TCCL) and I
may require additional review.
PHILIPPINES I
This product contains substance(s) which are not in compliance with the Republic Act 6969 (RA 6969) and may require additional review.
I
- 16. OTHER INFORMATION This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the 1
recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
I REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American I
Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM I
Version), Micromedex, Inc., Englewood, CO.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198- (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 8/9 0024 I
MATERIAL SAFETY DATA SHEET NALCO PRODUCT 3D TRASAR(R) 3DT121 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Prepared By : Product Safety Department Date issued : 06/19/2008 Version Number: 1.1 Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9/9 0025
SAFETY DATA SHEET I R114NALCO PRODUCT I
SURENCOOLE 1393 EMERGENCY TELEPHONE NUMBER(S) I (800) 424-9300 (24 Hours) CHEMTREC I1. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I I PRODUCT NAME:
APPLICATION:
SURE-COOL@ 1393 SCALE INHIBITOR (Lrcetrt, I
COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road I
Naperville, Illinois EMERGENCY TELEPHONE NUMBER(S):
60563-1198 (800) 424-9300 (24 Hours) CHEMTREC I
NFPA 704M/HMIS RATING HEALTH: 3/3 FLAMMABILITY: 1/1 INSTABILITY: 0/0 OTHER: I 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme *= Chronic Health Hazard
- 12. COMPOSITION/INFORMATION ON INGREDIENTS I
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
I Phosphonic Acid Hazardous Substance(s)
Hydroxyethylidenediphosphonic Acid CAS NO 2809-21-4 13598-36-2
% (w/w) 30.0- 60.0 1.0- 5.0 I
- 13. HAZARDS IDENTIFICATION I
- EMERGENCY OVERVIEW**
DANGER I
Corrosive. Risk of serious damage to eyes.
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water.
I Wear a face shield. Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.
Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions. I PRIMARY ROUTES OF EXPOSURE:
Eye, Skin I HUMAN HEALTH HAZARDS - ACUTE:
EYE CONTACT: I Severely irritating. If not removed promptly, will injure eye tissue and may result in permanent eye damage.
Nalco Company 1601 W. Diehl Road- Naperville, Illinois 60563-1198 -*(630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 0026 I
- ,SAFETY DATA SHEET SNA OPRODUCT SURE-COOL 1393 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I SKIN CONTACT:
Can cause moderate irritation.
INGESTION:
There may be irritation to the gastro-intestinal tract with nausea and vomiting.
INHALATION:
Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the eyes, nose, throat and lungs.
I SYMPTOMS OF EXPOSURE:
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic :
I Hydroxyethylenediphosphonic Acid (HEDP) has been reported to alter the development of the bone density by affecting bone mineralization and calcium and phosphate metabolism in animal studies.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
HUMAN HEALTH HAZARDS - CHRONIC:
I None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
No adverse effects expected other than those mentioned above.
- 14. 1FIRST AID MEASURES I EYE CONTACT:
PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get immediate medical attention.
I SKIN CONTACT:
Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Get immediate medical attention.
I Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.
INGESTION:
I IDO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. Get immediate medical attention.
INHALATION:
Remove to fresh air, treat symptomatically. Get medical attention.
I NOTE TO PHYSICIAN:
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the i patient, the physician's judgement should be used to control symptoms and clinical condition.
I Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/11 I 0021
SAFETY DATA SHEET I AWNALCO .D PRO UT SURE-COOL@ 1393 1 EMERGENCY TELEPHONE NUMBER(S)
(8UU0 0424-.0UU (4 hours) HM 'R
- 15. 1 FIRE FIGHTING MEASURES FLASH POINT: > 200 OF / > 93°C (TCC)
EXTINGUISHING MEDIA:
Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARD:
Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
- 16. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered; properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with 5
water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
Do not contaminate surface water.
- 17. 1 HANDLING AND STORAGE i HANDLING:
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,leaks, etc.) readily available.
STORAGE CONDITIONS: I Store the containers tightly closed. Store in suitable labeled containers. Store separately from bases.
SUITABLE CONSTRUCTION MATERIAL:
Buna-N, EPDM, HDPE (high density polyethylene), Polyurethane, Hypalon, Viton, Neoprene, Polypropylene, Polyethylene, PVC, Stainless Steel 316L UNSUITABLE CONSTRUCTION MATERIAL:
Brass, Epoxy phenolic resin, Mild steel, Stainless Steel 304 I
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/111 0028
SAFETY DATA SHEET PNALCO (800) 424-9300 (24 Hours) CHEMTREC S8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:
This product does not contain any substance that has an established exposure limit.
ENGINEERING MEASURES:
General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor.
RESPIRATORY PROTECTION:
Respiratory protection is not normally needed. If significant mists, vapors or aerosols are generated an approved respirator is recommended. If significant mists, vapors or aerosols are generated an approved respirator is recommended. An organic vapor/acid gas cartridge with dust/mist prefilter may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. Neoprene gloves PVC gloves Butyl gloves SKIN PROTECTION:
Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure is possible.
EYE PROTECTION:
Wear a face shield with chemical splash goggles.
HYGIENE RECOMMENDATIONS:
Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.
HUMAN EXPOSURE CHARACTERIZATION:
Based on our recommended product application and personal protective equipment, the potential human exposure is:
Moderate
- 19. 1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Clear Light yellow ODOR None SPECIFIC GRAVITY 1.41 - 1.47 @ 77 -F / 25 °C Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/11 0029
SAFETY DATA SHEET I P4NALCO i I SURE-COOL 1393 PRODUCT EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC DENSITY SOLUBILITY IN WATER 11.7 - 12.2 lb/gal Complete I
pH (1%)
VISCOSITY FREEZING POINT
<2 40 cps @ 77 OF / 25 °C
-13 F /-25 'C I
BOILING POINT 226 OF / 108 0C VAPOR PRESSURE EVAPORATION RATE Same as water Same as water I Note: These physical properties are typical values for this product and are subject to change.
- 10. 1STABILITY AND REACTIVITY I
STABILITY:
Stable under normal conditions.
I HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur. I CONDITIONS TO AVOID:
Freezing temperatures.
Avoid temperatures greater than 392 °F I MATERIALS TO AVOID:
Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling I
and toxic vapors. Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas. Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. - I HAZARDOUS DECOMPOSITION PRODUCTS:
Under fire conditions: Oxides of carbon, Oxides of phosphorus I
- 11. TOXICOLOGICAL INFORMATION The following results are for the product.
I ACUTE ORAL TOXICITY:
Species:
LD50:
Rat 2,400 mg/kg I
Test Descriptor: Product ACUTE DERMAL TOXICITY:
I Species:
LD50:
Test Descriptor:
Rabbit
> 7,940 mg/kg Product I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 5/111
': 30 I
SAFETY DATA SHEET P4NALCO SURE-COOL PRODUCT 1393 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SENSITIZATION:
This product is not expected to be a sensitizer.
CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
HUMAN HAZARD CHARACTERIZATION:
Based on our hazard characterization, the potential human hazard is: High
- 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:
The following results are for the product.
ACUTE FISH RESULTS:
Species Exposure LC50 Test Descriptor Fathead Minnow 96 hrs > 1,000 mg/I Product Bluegill Sunfish 96 hrs 868 mg/I Product Rainbow Trout 96 hrs 368 m_q/I Product Channel Catfish 96 hrs 695 mg/I Product Sheepshead Minnow 96 hrs 2,180 mg/I Product ACUTE INVERTEBRATE RESULTS:
Species Exposure LC50 EC50 -. Test Descriptor Daphnia magna 48 hrs 527 mg/l/I Product Grass Shrimp 96 hrs 1,770 mg/I Product PERSISTENCY AND DEGRADATION:
Chemical Oxygen Demand (COD): 0.263 mg/I Biological Oxygen Demand (BOD):
[ Incubation Period Value ITest Descriptor 0 mg/1 I The product is not biodegradable MOBILITY:
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/11 0031
SAFETY DATA SHEET I A411 N,iAýLCO SURE-COOL PRODUCT 1393 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; I
I Air
<5%
I Water 30 - 50%
I Soil/Sediment 50 - 70%
I The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL I
This preparation or material is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION I
Based on our hazard characterization, the potential environmental hazard is: Low Based on our recommended product application and the product's characteristics, the potential environmental exposure is: High I If released into the environment, see CERCLA/SUPERFUND in Section 15.
- 13. DISPOSAL CONSIDERATIONS I I If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets the I criteria of a hazardous waste.
Hazardous Waste: D002 I Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and federal regulations for specific requirements. I 114. I TRANSPORT INFORMATION Theinformation in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, I
and mode of transportation. Typical Proper Shipping Names for this product are as follows.
I LAND TRANSPORT:
Proper Shipping Name:
Technical Name(s):
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hydroxyethylidenediphosphonic Acid, Phosphonic Acid I
UN/ID No: UN 3265 Hazard Class - Primary:
Packing Group :
8 I
Flash Point:
AIR TRANSPORT (ICAO/IATA):
> 93 'C / > 200 *F I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 7/11 00-32 I
SAFETY DATA SHEET
) NALCO PRODUCT SURE-COOL 1393 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Technical Name(s): Hydroxyethylidenediphosphonic Acid, Phosphonic Acid UN/ID No: UN 3265 Hazard Class - Primary: 8 Packing Group: III IATA Cargo Packing Instructions: 820 IATA Cargo Aircraft Limit: 60 L (Max net quantity per package)
MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Technical Name(s): Hydroxyethylidenediphosphonic Acid, Phosphonic Acid' UN/ID No: UN 3265 Hazard Class - Primary: 8 Packing Group: III
- 15. REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information.
NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.
Hydroxyethylidenediphosphonic Acid : Corrosive, Target Organ Effect - Eye Phosphonic Acid : Corrosive CERCLA/SUPERFUND, 40 CFR 117, 302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE I1l) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard X Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/11
SAFETY DATA SHEET I
)4NALCO PRODUCT
-Il SURE-COOL 1393 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. I The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. I SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
I The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:
I When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.310 Boiler Water Additives 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods. I Limitations: no more than required to produce intended technical effect. For use at levels not to exceed 0.3% of active ingredients by weight of dry pulp or chips, or 0.5% by weight of active ingredients of wet pulp or chips. I FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311 :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.
I CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed I
components may be present at trace levels.
CALIFORNIA PROPOSITION 65:
I Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product.
MICHIGAN CRITICAL MATERIALS:
I Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.
I STATE RIGHT TO KNOW LAWS:
The following substances are disclosed for compliance with State Right to Know Laws: I Water 7732-18-5 Hydroxyethylidenediphosphonic Acid Phosphonic Acid 2809-21-4 13598-36-2 I NATIONAL REGULATIONS, CANADA:
I Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 ° (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 9/11 0034 I
SAFETY DATA SHEET ONALC
~NALCO
[PRODUCT SURE-COOL 1393 S
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION:
E - Corrosive Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on the Inventory of Existing Chemical Substances China (IECSC).
EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)
NEW ZEALAND All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.
PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).
- 16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:
" The human risk is: Moderate
" The environmental risk is: Low Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 10/11
SAFETY DATA SHEET I 04"NALCO PRODUCT SURE-COOL 1393 I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.
I This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should I
be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
I REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight CD-ROM Version), Ariel Research Corp.,
I Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS Version), Micromedex, Inc., Englewood, CO.
CD-ROM I IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
I Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO. I Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service. I Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, I
OH, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
I North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version),
I Micromedex, Inc., Englewood, CO.
I Prepared By: Product Safety Department Date issued : 07/31/2009 I
Version Number: 1.10 I
Nalco Company 1601 W. Diehl Road oNaperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access I
11/11 0036
MATERIAL SAFETY DATA SHEET tINALCO PRODUCT H-130 Microbiocide EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
- 11. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
,PRODUCT NAME: H-130 Microbiocide APPLICATION: BIOCIDETWIN-CHAIN QUATERNARY AMMONIUM COMPOUND CONCENTRATE COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 3/3 FLAMMABILITY: 2 /2 INSTABILITY: 0/0 OTHER:
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
- 12. COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
Hazardous Substance(s) CAS NO % (w/w)
Didecyl-Dimethyl-Ammonium chloride 7173-51-5 30- 60 Ethanol 64-17-5 10- 30 I 3. I HAZARDS IDENTIFICATION
- EMERGENCY OVERVIEW**
I I
DANGER Combustible. May cause tissue damage. Toxic to aquatic organisms. Corrosive. Causes severe eye and skin damage. Do not get in eyes, on skin or on clothing. Wears goggles or face shield and rubber gloves when handling.
Harmful or fatal if swallowed. Avoid contamination of food. KEEP OUT OF REACH OF CHILDREN. Corrosive to eyes and skin. Do not get in eyes, on skin or clothing. May be fatal if swallowed or inhaled. Do not swallow. Do not breathe vapour or mist.
Do not get in eyes, on skin, on clothing. Do not take internally. Keep away from heat. Keep away from sources of ignition - No smoking. Use with adequate ventilation. Keep container tightly closed and in a well-ventilated place.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Do not get in eyes, on skin or on clothing. Wear goggles or face shield and rubber gloves when handling. Harmful if inhaled. Avoid breathing vapor. Remove contaminated clothing and wash before reuse. Harmful or fatal if swallowed. Avoid contamination of food.
Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.
Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve HCI under fire conditions. May evolve ammonia under fire conditions.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 . (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1/9 0037
MATERIAL SAFETY DATA SHEET I PRODUCT fNALCO H-130 Microbiocide EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
PRIMARY ROUTES OF EXPOSURE:
Eye, Skin U
HUMAN HEALTH HAZARDS - ACUTE: I EYE CONTACT:
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. I SKIN CONTACT:
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered.
I INGESTION:
May cause bums to mouth and gastro-intestinal tract. I INHALATION:
Repeated or prolonged exposure may irritate the respiratory tract. Can cause central nervous system depression.
I SYMPTOMS OF EXPOSURE:
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic:
I A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
I
- 14. FIRST AID MEASURES First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. For eyes, call a physician. Remove and wash contaminated clothing before reuse.
If swallowed, drink promptly a large quantity of milk, egg whites, gelatin solution, or if these are not available, drink large quantities of water. Avoid alcohol. Call a physician immediately.
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed.
NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
- 15. 1 FIRE FIGHTING MEASURES FLASH POINT: 109 -F / 43 °C ( SETAFLASH)
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/9 0038
MATERIAL SAFETY DATA SHEET
-A NALCO PRODUCT I H-130 Microbiocide EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I EXTINGUISHING MEDIA:
Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water I spray or fog, thoroughly drenching the burning material.
Water mist may be used to cool closed containers.
FIRE AND EXPLOSION HAZARD:
I Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire I conditions. May evolve HCI under fire conditions. May evolve ammonia under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
I 16. 1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Notify appropriate government, occupational health and safety and environmental authorities. Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Eliminate ignition sources. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations)-
ENVIRONMENTAL PRECAUTIONS:
This product is toxic to fish and other water organisms. Do not discharge directly into lakes, ponds, streams, waterways or public water supplies.
- 17. 1HANDLING AND STORAGE HANDLING:
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid release of vapors or mists into workplace air. Keep the containers closed when not in use. Do not use in locations where vapor is likely to travel to welding flames or arcs or to other hot surfaces. Vapors are much heavier than air, this can result in uneven distribution. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
STORAGE CONDITIONS:
Store away from heat and sources of ignition. Connections must be grounded to avoid electrical charges. Store the containers tightly closed. Store separately from oxidizers. Store in suitable labelled containers.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/9 0039
MATERIAL SAFETY DATA SHEET I
)4NALCO H-130 Microbiocide PRODUCT EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
- 18. EXPOSURE CONTROLSIPERSONAL PROTECTION I
OCCUPATIONAL EXPOSURE LIMITS:
Exposure, guidelines have not been established for this product. Available exposure limits for the substance(s) are I
shown below.
ACGIH/TLV:
Substance(s)
I Ethanol TWA: 1,000 ppm, 1,880 mg/m3 OSHA/PEL:
Substance(s)
I Ethanol TWA: 1,000 ppm, 1,900 mg/m3 I
ENGINEERING MEASURES:
Use general ventilation with local exhaust ventilation.
RESPIRATORY PROTECTION:
I If significant mists, vapors or aerosols are generated an approved respirator is recommended. An organic vapor cartridge with dust/mist prefilter may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete I
respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
Neoprene gloves, Viton# gloves I
SKIN PROTECTION:
Wear impervious apron and boots. A full slicker suit is recommended if gross exposure is possible. I EYE PROTECTION:
Wear chemical splash goggles. 1 HYGIENE RECOMMENDATIONS:
Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Use good work and personal hygiene practices to avoid exposure.
I
- 19. 1PHYSICAL AND CHEMICAL PROPERTIES I PHYSICAL STATE Liquid APPEARANCE Light yellow I
ODOR SPECIFIC GRAVITY Alcoholic 0.93 @ 77 -F / 25 °C I
DENSITY 7.7 lb/gal I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/9 0040 I
MATERIAL SAFETY DATA SHEET PdNALCO PRODUCT H-130 Microbiocide EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SOLUBILITY IN WATER Complete pH (1 %) 7.0 - 8.0 VISCOSITY < 100 cps @ 77 °F / 25 'C FREEZING POINT 12 OF /
VAPOR PRESSURE 30 mm Hg @ 77 °F /25 °C VOC CONTENT 10 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change.
S10. STABILITY AND REACTIVITY STABILITY:
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
CONDITIONS TO AVOID:
Heat and sources of ignition including static discharges.
MATERIALS TO AVOID:
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Contact with reducing agents (e.g.
hydrazine, sulfites, sulfide, aluminum or magnesium dust) may generate heat, fires, explosions and toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS:
Under fire conditions: Oxides of carbon, Oxides of nitrogen, HCI
- 11. TOXICOLOGICAL INFORMATION The following results are for the product.
ACUTE ORAL TOXICITY:
Species LD50 Test Descriptor Rat 645 mg/kg Product ACUTE DERMAL TOXICITY:
Species LD50 Test Descriptor Rabbit > 4 g/kg Product SENSITIZATION:
This product is not expected to be a sensitizer.
CARCINOGENICITY:
None of the substances in. this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 0041
MATERIAL SAFETY DATA SHEET I
)4fNALCO I PRODUCT - I H-130 Microbiocide EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC 112. 1 ECOLOGICAL INFORMATION I ECOTOXICOLOGICAL EFFECTS:
The following results are for the product. I ACUTE FISH RESULTS:
Species Rainbow Trout Exposure 96 hrs LC50 2.2 mg/I Test Descriptor I Bluegill Sunfish 96 hrs 0.92 mg/I ACUTE INVERTEBRATE RESULTS: U Species Exposure LC50 EC50 Test Descriptor Daphnia magna Mysid Shrimp (Mysidopsis bahia) 48 hrs 96 hrs 0.19 mg/I 0.14 mg/I I If released into the environment, see CERCLA/SUPERFUND in Section 15. I
- 13. 1DISPOSAL CONSIDERATIONS If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets I
the criteria of a hazardous waste.
Hazardous Waste: D001 I
Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide,; pray mixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA I
Regional Office for guidance.
114. I TRANSPORT INFORMATION I I
The information in this section is for reference only and should not take the place of a shipping paper (bill' of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, I
and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT: I Proper Shipping Name: DISINFECTANTS, LIQUID, CORROSIVE, N.O.S.
Technical Name(s):
UN/ID No:
DIDECYLDIMETHYLAMMONIUM CHLORIDE UN 1903 I
Hazard Class - Primary: 8 Packing Group:
Flash Point:
II 43 °C / 109 OF I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 U
For additional copies of an MSDS visit www.nalco.com and request access 6/9 0042 I
MATERIAL SAFETY DATA SHEET
" N ALCO PRODUCT H-I30 Microbiocide EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC AIR TRANSPORT (ICAO/IATA):
Proper Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Technical Name(s): DIDECYLDIMETHYLAMMONIUM CHLORIDE, ETHANOL UN/ID No: UN 2920 Hazard Class - Primary: 8 Hazard Class - Secondary: 3 Packing Group: II IATA Cargo Packing Instructions:
IATA Cargo Aircraft Limit: (Max net quantity per package)
MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Technical Name(s): DIDECYLDIMETHYLAMMONIUM CHLORIDE, ETHANOL UN/ID No: UN 2920 Hazard Class - Primary: 8 Hazard Class - Secondary: 3 Packing Group: II
- 15. REGULATORY INFORMATION NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.
Didecyl-Dimethyl-Ammonium chloride: Corrosive Ethanol: Flammable CERCLA/SUPERFUND, 40 CFR 117, 302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product-to be hazardous. The product should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard X Fire Hazard Sudden Release of Pressure Hazard Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/9 0043
MATERIAL SAFETY DATA SHEET I
)041"'NALCO PRODUCT
-I H-130 Microbiocide EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC Reactive Hazard I
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
I SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain substances on the List of Toxic Chemicals. I TOXIC SUBSTANCES CONTROL ACT (TSCA):
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) I FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):
EPA Reg. No. 1706-186 In all cases follow instructions on the product label. I FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311 None of the substances are specifically listed in the regulation.
I CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances):
This product contains the following substances listed in the regulation:
I Substance(s)
. Ethanol Citations Sec. 111 I
CALIFORNIA PROPOSITION 65:
This product does not contain substances which require warning under California Proposition 65.
I MICHIGAN CRITICAL MATERIALS:
None of the substances are specifically listed in the regulation.
I STATE RIGHT TO KNOW LAWS:
This product is a registered biocide and is exempt from State Right to Know Labelling Laws.
I NATIONAL REGULATIONS, CANADA: I WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
I WHMIS CLASSIFICATION:
Pesticide controlled products are not regulated under WHMIS. I I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/9 0044 I
4 MATERIAL SAFETY DATA SHEET a 0NALCO PDUCT H-130 Microbiocide I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.
116. 1OTHER INFORMATION This product material safety data sheet provides health and safety information. The product is to be used in applications consistent witho0ur product literature. Individuals handling this product should be informed of the U recommended.safety'precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
REFERENCES I Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,
i Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
I IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
I Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, I OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
3 North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
i Micromedex, Inc., Englewood, CO.
Prepared By Product Safety Department Date issued: 12/30/2005
- Version Number: 1.7 Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9./9 0045
(.
MATERIAL SAFETY DATA
,R4"NALCO - I EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC
- 11. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I
gtistq OVz4 &0C&;5oMJk ~?,MoA PRODUCT NAME: ACTI-BRdM 1318 'Te-? c*Cv 1[4-01-4"O I
APPLICATION: BIOCIDE COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road I
Naperville, Illinois EMERGENCY TELEPHONE NUMBER(S):
60563-1198 (800) 424-9300 (24 Hours) CHEMTREC I
NFPA 704M/HMIS RATING HEALTH: 1/1 FLAMMABILITY: 0/0 INSTABILITY: 0/0 OTHER:
I 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
- 12. 1 COMPOSITION/INFORMATION ON INGREDIENTS I
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s). i Hazardous Substance(s) CAS NO % (w/w)
Sodium Bromide 7647-15-6 30.0- 60.0 I
- 13. 1 HAZARDS IDENTIFICATION
- EMERGENCY OVERVIEW** I CAUTION Causes moderate eye irritation.
Avoid contact with eyes, skin and clothing. Wash with soap and water after handling. Remove contaminated I
clothing and wash before reuse.
May evolve hydrogen bromide and bromine under fire conditions.
PRIMARY ROUTES OF EXPOSURE:
I Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:
I EYE CONTACT:
Can cause mild to moderate irritation. I SKIN CONTACT:
May cause irritation with prolonged contact. 1 INGESTION:
Not a likely route of exposure. No adverse effects expected.
I Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198- (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1/11 0046 I
MATERIAL SAFETY DATA SHEET P NALCO PRODUCT ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC INHALATION:
Not a likely route of exposure. Aerosols or product mist may irritate the upper respiratory tract.
SYMPTOMS OF EXPOSURE:
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic :
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
HUMAN HEALTH HAZARDS - CHRONIC:
No adverse effects expected other than those mentioned above.
- 14. I FIRST AID MEASURES IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
IF SWALLOWED: Call poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person.
IF INHALED: Remove victim to fresh air. If not breathing, give artificial respiration, preferably, mouth-to-mouth. Get medical attention.A
- 15. 1 FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA:
Not expected to burn. Keep containers cool by spraying with water. Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARD:
May evolve hydrogen bromide and bromine under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/11 0047
MATERIAL SAFETY DATA SHEET I AVNALCO PRODUCT
-I ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC
- 16. ACCIDENTAL RELEASE MEASURES I
PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by I trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities. I METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly I
with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). I ENVIRONMENTAL PRECAUTIONS:
This pesticide is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing I
prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.
I
- 17. HANDLING AND STORAGE I
HANDLING:
Avoid eye and skin contact. Do not take internally. Do not get in eyes, on skin, on clothing. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labelled. Keep the containers closed when not in use. Use with adequate ventilation.
I STORAGE CONDITIONS:
Store the containers tightly closed. Store in suitable labelled containers. I
- 18. 1 EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:
I This product does not contain any substance that has an established exposure limit.
ENGINEERING MEASURES:
I General ventilation is recommended.
RESPIRATORY PROTECTION:
Respiratory protection is not normally needed.
I HAND PROTECTION:
Neoprene gloves, Nitrile gloves, Butyl gloves, PVC gloves I I
Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/11 0048 I
MATERIAL SAFETY DATA SHEET PRODUCT N
NALCO ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SKIN PROTECTION:
Wear standard protective clothing.
EYE PROTECTION:
Wear chemical splash goggles.
HYGIENE RECOMMENDATIONS:
If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Keep an eye wash fountain available. Keep a safety shower available.
HUMAN EXPOSURE CHARACTERIZATION:
Based on our recommended product application and personal protective equipment, the potential human exposure is: Moderate
- 19. 1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Colorless ODOR None SPECIFIC GRAVITY 1.45 @ 77 °F / 25 -C DENSITY 12.1 lb/gal SOLUBILITY IN WATER Complete pH (100 %) 7.9 VISCOSITY 5 cps FREEZING POINT 7 °F / -14 'C BOILING POINT 218 OF / 103.5 'C VAPOR PRESSURE 5.6 mm Hg @ 68 OF / 20 °C VOC CONTENT 0.00 %
Note: These physical properties are typical values for this product and are subject to change.
110. 1STABILITY AND REACTIVITY STABILITY:
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
CONDITIONS TO AVOID:
Freezing temperatures.
MATERIALS TO AVOID:
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.
Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/11 0049
MATERIAL SAFETY DATA SHEET I
)4NALCO PRODUCT ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC F !I HAZARDOUS DECOMPOSITION PRODUCTS:
I Under fire conditions: None known 11i. I TOXICOLOGICAL INFORMATION I I ACUTE ORAL TOXICITY:
I Species Rat Rating : Non-Hazardous LD50
> 5,000 mg/kg Test Descriptor Similar Product I ACUTE DERMAL TOXICITY:
Species LD50 Test Descriptor Similar Product I
Rabbit > 2,000 mg/kg Rating : Non-Hazardous PRIMARY SKIN IRRITATION:
I Draize Score Test Descriptor 0.0 /8.0 Rating : Essentially non-irritating Similar Product I
PRIMARY EYE IRRITATION:
Draize Score 16.0 /110.0 Rating : -Mildly irritating Test Descriptor Similar Product I SENSITIZATION:
This product is not expected to be a sensitizer.
I CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on I
Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
HUMAN HAZARD CHARACTERIZATION:
I Based on our hazard characterization, the potential human hazard is: Low 112. I ECOLOGICAL INFORMATION SI ECOTOXICOLOGICAL EFFECTS:
The following results are for the product and a similar product. The following results are for the active components.
I The following results are for the hypobromous acid (as Br2) generated from sodium bromide and hypochlorite.
I Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 5/11 0050 I
MATERIAL SAFETY DATA SHEET A NALCO PRODUCT ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC ACUTE FISH RESULTS:
Species Exposure LC50 Test Descriptor Fathead Minnow 96 hrs > 5,000 mg/I Product Rainbow Trout 96 hrs > 1,000 mg/I Similar Product Bluegill Sunfish 96 hrs > 1,000 m/I Similar Product Fathead Minnow 96 hrs 0.097 mgll HOBr (Generated from NaBr)
Rainbow Trout 96 hrs 0.23 mg/l HOBr (Generated from NaBr)
Bluegill Sunfish 96 hrs 0.52 mg/I HOBr (Generated from NaBr)
Sheepshead Minnow 96 hrs 0.19 mg/l HOBr (Generated from NaBr)
ACUTE INVERTEBRATE RESULTS:
Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs 7,900 mg/I Active Substance (Sodium Bromide)
Ceriodaphnia dubia 48 hrs > 5,000 mgol Product Daphnia magna 48 hrs 0.038 mg/I HOBr (Generated from NaBr)
American Oyster 96 hrs 0.54 mg/I HOBr (Generated from NaBr)-
Mysid Shrimp (Mysidopsis 96 hrs 0.17 mg/I HOBr (Generated from NaBr) bahia)
ADDITIONAL ECOLOGICAL DATA:
AOX information: Product contains no organic halogens.
PERSISTENCY AND DEGRADATION:
Biological Oxygen Demand (BOD): This material is an oxidizing biocide and is not expected to persist in the environment.
Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not applicable.
MOBILITY:
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment
<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/11 0051
MATERIAL SAFETY DATA SHEET I
)4N ALCO PRODUCT ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION i Based on our hazard characterization, the potential environmental hazard is: Low Based on our recommended product application and the product's characteristics, the potential environmental exposure is: Moderate I If released into the environment, see CERCLA/SUPERFUND in Section 15.
- 13. DISPOSAL CONSIDERATIONS I If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. I As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.
I DO NOT REUSE EMPTY CONTAINER. Triple rinse the container (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incinerate. Burn only if allowed by state and local authorities. If burned, stay out of smoke.
I
- 14. TRANSPORT INFORMATION I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. I LAND TRANSPORT:
Proper Shipping Name: PRODUCT IS NOT REGULATED DURING I
TRANSPORTATION AIR TRANSPORT (ICAO/IATA): I Proper Shipping Name: PRODUCT IS NOT REGULATED DURING MARINE TRANSPORT (IMDG/IMO):
TRANSPORTATION I
Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION I
115. i REGULATORY INFORMATION I I NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are I
shown below.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 ° (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 7/11 0052 1
MATERIAL SAFETY DATA SHEET AV NALCOPRODUCT ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Sodium Bromide : Eye irritant CERCLA/SUPERFUND, 40 CFR 117, 302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE Ill) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List.
FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:
When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods., 21 CFR 176.300 Slimicides, The following limitations apply:
This product may be used to treat pulp and papermill water systems in situations requiring FDA sanction provided the bromide concentration in the water is kept below 22 ppm. The product must be used in conjunction with an oxidant such as bleach or gaseous chlorine. Follow instructions for use in pulp and papermill on the product label.
FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):
EPA Reg. No. 5185-467-1706 In all cases follow instructions on the product label.
This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/11 0053
P~NALCO ALOPRODUCTI oouot MATERIAL SAFETY DATA SHEET r0" ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S) I (800) 424-9300 (24 Hours) CHEMTREC FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4 /formerly Sec. 311 :
None of the substances are specifically listed in the regulation.
CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone I Depleting Substances) :
None of the substances are specifically listed in the regulation.
CALIFORNIA PROPOSITION 65: i This product does not contain substances which require warning under California Proposition 65.
MICHIGAN CRITICAL MATERIALS: i None of the substances are specifically listed in the regulation.
STATE RIGHT TO KNOW LAWS: I This product is a registered biocide and is exempt from State Right to Know Labelling Laws.
NATIONAL REGULATIONS, CANADA: I WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION:
Pesticide controlled products are not regulated under WHMIS.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.
INTERNATIONAL CHEMICAL CONTROL LAWS i AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification &Assessment Scheme (NICNAS).
EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. i JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).
KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 i For additional copies of an MSDS visit www.nalco.com and request access 9/11 0054 3
r1NALCO MATERIAL SAFETY DATA SHEET ou SPRODUCT-ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC THE PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).
I16. JOTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:
- The human risk is: Low
- The environmental risk is: Low Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.
This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM-Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 10111 0055
MATERIAL SAFETY DATA SHEET I A4NALCO PRODUCT ACTI-BROM 1318 EMERGENCY TELEPHONE NUMBER(S)
LI (800) 424-9300 (24 Hours) CHEMTREC Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel I
Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
I Micromedex, Inc., Englewood, CO.
I Prepared By: Product Safety Department Date issued : 05/08/2006 I
Version Number: 1.17 I
I I
I I
I I
I I
I Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 11/11 0056 1
GE Water & Process Technologies Material Safety Data Sheet ,ssue Date: 10-JUL-2008 SPECTRUS NX1106 1 Identification Identification of substance or preparation SPECTRUS NX1 106 Product Application Area Water-based microbial control agent.
Company/Undertaking Identification GE Betz, Inc.
4636 Somerton Road Trevose, PA 19053 T 215 355-3300, F 215 953 5524 Emergency Telephone (800) 877-1940 Prepared by Product Stewardship Group: T 215-355-3300 Prepared on: 10-JUL-2008 2 Hazard(s) identification EMERGENCY OVERVIEW DANGER Corrosive to skin. Skin sensitizer with delayed onset-.of symptoms.
Corrosive to the eyes. Mists/aerosols cause irritation to the upper respiratory tract.
DOT hazard: Corrosive to skin Odor: Slight; Appearance: Light Yellow To Green, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; Corrosive to skin. Skin sensitizer with delayed onset of symptoms.
ACUTE EYE EFFECTS:
Corrosive to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols cause irritation to the upper respiratory tract.
Substance or Preparation: SPECTRUS NX1 106 Page 1 0057
INGESTION EFFECTS:
May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses. 3 TARGET ORGANS:
Prolonged or repeated exposures may cause tissue necrosis and/or skin sensitization.
MEDICAL CONDITIONS AGGRAVATED:
Not known. 3 SYMPTOMS OF EXPOSURE:
Direct contact with skin will cause severe delayed skin reactions or burns if not washed off immediately-'follow first instructions.
aid I
3 Composition / information on ingredients Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed.
additional sections of this Refer to MSDS for our assessment of the potential I
hazards of this formulation.
HAZARDOUS INGREDIENTS:
Cas# Chemical Name Range(w/w%)
10377-60-3 MAGNESIUM NITRATE Oxidizer; irritant (eyes and skin) 1-5 5 26172-55-4 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE 1-5 Corrosive; toxic (by ingestion and skin absorption);
sensitizer (skin) 4 First-aid measures I SKIN CONTACT:
URGENT! Wash thoroughly with soap and water. Remove contaminated 3
clothing. Get immediate medical attention. Thoroughly wash clothing before reuse.
EYE CONTACT:
URGENT! Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive I
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 2-8 fluid ounces (60-240 mL) of milk or water. I I
Substance or Preparation: SPECTRUS NX1 106 Page 2 0058
NOTES TO PHYSICIANS:
Material is corrosive. It may not be advisable to induce vomiting.
Possible mucosal damage may contraindicate the use of gastric lavage.
5 Fire-fighting measures FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
oxides of carbon, nitrogen, and sulfur; and hydrogen chloride FLASH POINT:
> 200F > 93C P-M(CC)
MISCELLANEOUS:
Corrosive to skin UN 3265;Emergency Response Guide #153 6 Accidental release measures PROTECTION AND SPILL CONTAINMENT:
WARNING: Keep spills'and clean-up residuals out of municipal sewers and open bodies of water. Adsorb the spill with spill pillows or inert solids such as clay or vermiculite, and transfer contaminated materials to suitable containers for disposal. Deactivate spill area with freshly prepared solution of 5% sodium bicarbonate and 5%
sodium hypochlorite in water. Apply solution to the spill area at a ratio of 10 volumes deactivation solution per estimated volume of residual spill to deactivate any residual active ingredient. Let stand for 30 minutes. Flush spill area with copious amounts of water to chemical sewer (if in accordance with local procedures, permits and regulations). DO NOT add deactivation solution to the waste pail to deactivate the adsorbed material.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Dispose of in approved pesticide facility or according to label instructions.
7 Handling and storage
.HANDLING:
Contains an oxidizer. Avoid all contact with reducing agents, oils, greases, organics and acids. Corrosive to skin and/or eyes.
STORAGE:
Keep containers closed when not in use. Store between 20-10OF (-7 to 38C) for no more than 6 months. Store upright in original vented containers. Product evolves C02 slowly. Store samples in plastic bottles due to pressure build-up.
8 Exposure controls / personal protection Substance or Preparation: SPECTRUS NX1 106 Page 3 0059
I EXPOSURE LIMITS CHEMICAL NAME MAGNESIUM NITRATE I
PEL (OSHA) : NOT DETERMINED TLV (ACGIH): NOT DETERMINED 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED I I
MISC: Note-mfg. sugg. exp. limit:0.1 mg/m3 TWA;0.3mg/m3 STEL total isothiazoline).
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
I Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER U
WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use organic I
vapor cartridges and any of the following particulate respirators: N95, N99, N100, R95, R99, R100, P95, P99 or P100.
SKIN PROTECTION:
gauntlet-type butyl gloves, chemical resistant apron and I
boots-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles, face shield I
9 Physical and chemical properties I Specific Grav.(70F,21C)
Freeze Point (F)
Freeze Point (C) 28
-2 1.033 Vapor Pressure (mmHG)
Vapor Density (air=l)
~ 18.0
< 1.00 I Viscosity(cps 70F,21C) 8 % Solubility (water) 100.0 Odor Appearance Slight Light Yellow To Green I
Physical State Flash Point pH As Is (approx.)
P-M(CC)
Liquid
> 200F > 93C 3.0 1
Evaporation Rate (Ether=l) < 1.00 Percent VOC:
NA = not applicable 0.0 ND = not determined 1
10 Stability and reactivity I I
I Substance or Preparation: SPECTRUS NX1 106 Page 4 I
0060
STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with organics or reducing agents.
DECOMPOSITION PRODUCTS:
oxides of carbon, nitrogen, and sulfur; and hydrogen chloride INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 Toxicological information Oral LD50 RAT: >2,350 mg/kg NOTE - Estimated value Teratology : , NEGATIVE Dermal LD50 RABBIT: >2,700 mg/kg NOTE - Estimated value Skin Sensitization HUMAN: POSITIVE Non-Ames Mutagenicity : NEGATIVE 12 Ecological information AQUATIC TOXICOLOGY Bluegill Sunfish 96 Hour Static Acute Bioassay LC50= 12.1; No Effect Level= 6.5 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay LC50= 2.9; 10% Mortality= .6 mg/L Fathead Minnow 36 Day Early Life Stage Test LOEC= 4; No Effect Level= 1.3 mg/L Fathead Minnow 96 Hour Flow-Thru Bioassay LC50= 6.6; No Effect Level= 2.5 mg/L Rainbow Trout 14 Day Chronic Bioassay LC50= 4.6; No Effect Level= 3.3 mg/L Rainbow Trout 96 Hour Static Acute Bioassay LC50= 8.7; No Effect Level= 6.5 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay LC50= 20; No Effect Level= 12 mg/L BIODEGRADATION BOD-28 (mg/g): 0 BOD-5 (mg/g) : 0 COD (mg/g): 17 TOC (mg/g): 6 13 Disposal considerations If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
Substance or Preparation: SPECTRUS NX1 106 Page 5
("0 6 ]
I 14 Transport information DOT HAZARD: Corrosive to skin PROPER SHIPPING NAME: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(5-CHLORO-2-METHYL-4-ISOTHIAZOLIN ONE) i 8, UN 3265, PG II DOT EMERGENCY RESPONSE GUIDE #: 153 Note: Some containers may be DOT exempt, please check BOL for exact container classification i
15 Regulatory information U TSCA: i This is an EPA registered biocide and is exempt from TSCA inventory requirements.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER:
m 3876- 143 FOOD AND DRUG ADMINISTRATION:
The ingredients in this product are approved by FDA under 21 CFR 176.300.
USDA FOOD PLANT APPROVALS:
G7 SARA SECTION 312 HAZARD CLASS:
Immediate(acute);Delayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
CAS# CHEMICAL NAME RANGE 10377-60-3 MAGNESIUM NITRATE 2.0-5.0%
CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
No regulated constituents present MICHIGAN REGULATORY INFORMATION m
No regulated constituent present at OSHA thresholds 16 Other information i NFPA/HMIS CODE TRANSLATION Health Fire 3
0 Serious Hazard Minimal Hazard i
Reactivity 0 Minimal Hazard Special CORR DOT corrosive (1) Protective Equipment D Goggles,Face Shield,Gloves,Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG Substance or Preparation: SPECTRUS NX1106 Page 6 0062
EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 03-OCT-1997 ** NEW **
02-DEC-1997 15 03-OCT-1997 23-DEC-1997 15 02-DEC-1997 01-MAY-1998 15;EDIT:9 23-DEC-1997 08-APR-1999 ;EDIT:9 01-MAY-1998 17-MAY-2001 4,16 08-APR-1999 16-MAY-2006 10 17-MAY-2001 22-MAR-2007 9 16-MAY-2006 29-JUN-2007 5,6,8,10,16 22-MAR-2007 02-JUL-2008 4,8 29-JUN-2007 10-JUL-2008 7,11 02-JUL-2008 Substance or Preparation: SPECTRUS NX1 106 Page 7 0 Ur6 3
SAFETY DATA SHEET I
)4'NALCO PRODUCT -I H-550 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC
- 11. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME: H-550 I APPLICATION: MICROBIOCIDE COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road I
Naperville, Illinois EMERGENCY TELEPHONE NUMBER(S):
60563-1198 (800) 424-9300 (24 Hours) CHEMTREC I
NFPA 704M/HMIS RATING HEALTH: 3/3* FLAMMABILITY: 1/1 INSTABILITY: 0/0 OTHER:
I 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme *= Chronic Health Hazard
- 12. COMPOSITION/INFORMATION ON INGREDIENTS I
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
I Glutaraldehyde Hazardous Substance(s) CAS NO 111-30-8
% (w/w) 30.0- 60.0 I
- 13. 1 HAZARDS IDENTIFICATION I
- EMERGENCY OVERVIEW**
I DANGER Corrosive. Causes irreversible eye damage. Causes skin burns. Harmful if inhaled. May be fatal if swallowed.
Harmful if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some I
individuals. Causes asthmatic signs and symptoms in hyper-reactive individuals.
Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not swallow. Wear goggles, protective clothing, and rubber gloves. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash I
before reuse.
Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions.
PRIMARY ROUTES OF EXPOSURE:
I Eye, Skin, Inhalation HUMAN HEALTH HAZARDS - ACUTE:
I EYE CONTACT:
Corrosive. Will cause eye burns and permanent tissue damage. I Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 1/13 0064 I
NALCO IPRODUC SAFETY DATA SHEET H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SKIN CONTACT:
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
Harmful if absorbed through skin.
INGESTION:
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. May be fatal if swallowed.
INHALATION:
Irritating, in high concentrations, to the eyes, nose, throat and lungs. Inhalation of product mist or vapors may cause respiratory allergy. Inhalation of vapors may cause headache, nausea, and vomiting.
SYMPTOMS OF EXPOSURE:
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic:
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
HUMAN HEALTH HAZARDS - CHRONIC:
Prolonged inhalation of product can increase lung injury in persons with emphysema, asthma, or other lung disorders.
- 4. FIRST AID MEASURES If Swallowed:
- Call a poison control center or a doctor immediately for treatment advice. DO NOT INDUCE VOMITING.
- Do not give anything to drink.
IF IN EYES: Wash immediately and continuously with flowing water for at least 30 minutes. Remove contact lenses after the first 5 minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist. Call a poison control center or a doctor immediately for treatment advice.
IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
IF INHALED: Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for treatment advice.
NOTE TO PHYSICIAN:
Aspiration may cause lung damage. Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/13 0065
SAFETY DATA SHEET AVNALCO PRODUCT
-I H-550 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC
- 15. 1 FIRE FIGHTING MEASURES I FLASH POINT:
EXTINGUISHING MEDIA:
None I
This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARD:
U Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
I In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
- 16. 1ACCIDENTAL RELEASE MEASURES I PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is I
safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP:
I SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with I
water. Dilute the glutaraldehyde to 5% or less with water. Add sodium bisulfite (2-3 parts by weight per part glutaraldehyde). This will typically reduce the glutaraldehyde concentration to 2 ppm or less in 5 minutes at room temperature. The remaining solution can be disposed of via appropriate means. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section I
13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
This pesticide is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, I
oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge; Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant I
authority. For guidance contact your State Water Board or Regional Office of the EPA.
- 17. 1HANDLING AND STORAGE I HANDLING:
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in use. Wash thoroughly with soap and water after handling.
U Have emergency equipment (for fires, spills, leaks, etc.) readily available.
STORAGE CONDITIONS:
Store the containers tightly closed. Store separately from oxidizers. Store in suitable labeled containers.
I Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 o (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access I
3/13 0066 I
SAFETY DATA SHEET IP4NALCO A40N LC~oPRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SUITABLE CONSTRUCTION MATERIAL:
I Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.
- 18. 1 EXPOSURE CONTROLS/PERSONAL PROTECTION I OCCUPATIONAL EXPOSURE LIMITS:
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
I Substance(s) Category: ppm mg/m3 Non-Standard Unit I Glutaraldehyde ACGIH/Ceiling 0.05 ENGINEERING MEASURES:
I General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor.
RESPIRATORY PROTECTION:
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied I breathing apparatus is recommended. If significant mists, vapors or aerosols are generated an approved respirator is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: Organic vapor cartridge, with a Particulate pre-filter. In event of emergency or planned entry into i unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.
I HAND PROTECTION:
When handling this product, the use of chemical gauntlets is recommended. The-hoice of work glove-depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from Butyl gloves Nitrile Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers.
SKIN PROTECTION:
i Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure is possible.
EYE PROTECTION:
I Wear a face shield with chemical splash goggles.
HYGIENE RECOMMENDATIONS:
Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.
- 19. 1PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid I Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 o (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/13 I: 0067
I SAFETY DATA SHEET
)1NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC I
APPEARANCE Colorless ODOR Aldehyde I SPECIFIC GRAVITY 1.11-1.13 @ 77 F/125°C DENSITY SOLUBILITY IN WATER pH (100 %)
9.4 lb/gal Complete 3.1 -4.5 I
VISCOSITY 21cps @ 68°F/20°C FREEZING POINT BOILING POINT
-5.8 'F -21 °C 213 'F /100.5 °C I
VAPOR PRESSURE 16 mm Hg VAPOR DENSITY VOC CONTENT 1.1 54 % EPA Method 24 I Note: These physical properties are typical values for this product and are subject to change.
110. 1 STABILITY AND REACTIVITY I
STABILITY:
Stable under normal conditions. I HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
CONDITIONS TO AVOID:
I High temperatures Avoid extremes of temperature.
MATERIALS TO AVOID:
I Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Amines Strong Bases Strong acids HAZARDOUS DECOMPOSITION PRODUCTS:
I Under fire conditions: Oxides of carbon 111. I TOXICOLOGICAL INFORMATION I I
The following results are for the product along with results on the active substances.
ACUTE ORAL TOXICIT I
Species: Rat LD50:
Test Descriptor:
1.2 ml/kg 45% Active Ingredient I Species: Rat LD50: 1.54 -1.87 ml/kg Test Descriptor: 25% Active Ingredient I Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 5/13 I 0068
SAFETY DATA SHEET
)4NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Species: Rat LD50: 1.07 - 1.62 ml/kg Test Descriptor: 10% Active Ingredient Species: Rat LD50: 1,468 mg/kg Test Descriptor: Product ACUTE DERMAL TO) (ICITY :
Species: Rabbit LD50: 2.00 - 2.71 ml/kg Test Descriptor: 45% Active Ingredient Species: Rabbit LD50: 8.0 - 12.8 ml/kg Test Descriptor: 25% Active Ingredient Species: Rabbit LD50: 897 - 1,432 mg/kg Test Descriptor: Product ACUTE INHALATION TOXICITY:
Species: Rat LD50: > 27 mg/I (4 hrs)
Test Descriptor: Product PRIMARY SKIN IRRITATION:
Remarks: At 10% or greater, glutaraldehyde solutions may cause moderate to severe irritation, with possible necrosis after prolonged contact.
PRIMARY EYE IRRITATION:
Remarks: At levels of 0.2% and below of glutaraldehyde, no eye irritation was noted. Levels above 0.2% of glutaraldehyde produced moderate to severe irritation and corneal injury.
SENSITIZATION:
Levels of greater than 0.2% of glutaraldehyde produced allergic contact dermatitis in human studies. May cause sensitization by inhalation and skin contact.
CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 ° (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6 /13 0069
i SAFETY DATA SHEET
)4NALCO PRODUCT
-I H-550 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC HUMAN HAZARD CHARACTERIZATION: I Based on our hazard characterization, the potential human hazard is: High
- 12. ECOLOGICAL INFORMATION I
ECOTOXICOLOGICAL EFFECTS: I The following results are for the product along with results on the active substances.
ACUTE FISH RESULTS:
Species Exposure LC50 Test Descriptor I
Bluegill Sunfish 96 hrs 22.4 mg/I Product Fathead Minnow Sheepshead Minnow 96 hrs 96 hrs 10.8 mg/I 64 mg/I Product Product I
Rainbow Trout ACUTE INVERTEBRATE RESULTS:
96 hrs 24 mg/I Product I
Species Exposure LC50 EC50 Test Descriptor Daphnia magna Shore Crab Grass Shrimp 48 hrs 96 hrs 96 hrs 11.5 mg/I 930 mg/I 82 mg/I Product Product Product I
Mysid Shrimp (Mysidopsis 96 hrs 14.2 mg/I Product bahia)
American Oyster 96 hrs 1.56 mg/I Product I
Acartia tonsa 48 hrs 0.22 mg/I Product AQUATIC PLANT RESULTS:
Species Exposure EC50/LC50 Test Descriptor I
Marine Algae (Skeletonema coMatatum)
Algae (Scenedesmus 72 hrs 72 hrs 1.22 mg/I 1.7 mg/I Product Product I
subspicatus) I I AQUATIC MICROORGANISM RESULTS:
I Species f Exposure I EC50/LC50 I Test Descriptor I
Sewage Microorganisms AVIAN RESULTS:
96 hrs 34 mg/I Active Substance I
Species Exposure LC50 Test Descriptor Bobwhite Quail Mallard Duck 8 Days 8 Days 10,000 pm 10,000 ppm Active Substance Active Substance I
Mallard Duck 933 mg /kg 50% Active Ingredient MOBILITY:
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and I
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 ° (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 7/13 I 0070
SAFETY DATA SHEET PRODUCT-.
fNALCO H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment
<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Moderate If released into the environment, see CERCLANSUPERFUND in Section 15.
- 13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets the criteria of a hazardous waste.
As a pesticide waste, consult the FIFRA label for any additional handling, treatment, or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.
Metal Containers or Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or other procedures approved by state and local authorities. Plastic Containers: May be incinerated, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.
Metal Containers: Must not be incinerated. Do not cut or weld on or near metal containers.
- 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT:
Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Technical Name(s): GLUTARALDEHYDE UN/ID No: UN 3265 Hazard Class - Primary: 8 Packing Group : II Flash Point: None Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/13 0 07 1
SAFETY DATA SHEET I
) NALCO PODUCT P
H-5 50 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC I
I AIR TRANSPORT (ICAO/IATA):
Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
I Technical Name(s): GLUTARALDEHYDE UN/ID No:
Hazard Class - Primary:
Packing Group :
UN 3265 8
II I
IATA Cargo Packing Instructions: 812 IATA Cargo Aircraft Limit: 30 L (Max net quantity per package)
I MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name Technical Name(s):
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
GLUTARALDEHYDE I
UN/ID No: UN 3265 Hazard Class - Primary:
Packing Group :
8 II I
- Marine Pollutant: GLUTARALDEHYDE
- Note: This product is regulated as a Marine Pollutant when shipped by Rail, Highway, or Air in bulk quantities (greater than 119 gallons) and when shipped by water in all quantities.
I
- 15. REGULATORY INFORMATION I This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information.
I NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
I Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.
Glutaraldehyde: Corrosive, Sensitizer I
CERCLA/SUPERFUND, 40 CFR 302:
Notification of spills of this product is not required.
I SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313: I SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
1 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 9/13 I
SAFETY DATA SHEET
)4NALCO IPODUCT EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard X Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain substances on the List of Toxic Chemicals.
ACT (TSCA):
TOXIC SUBSTANCES CONTROL This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List.
FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:
When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.320 Chemicals for controlling microorganisms in cane-sugar and beet-sugar mills.
The following limitations apply:
Maximum dosage Limitation 500 PPM as product by weight of the raw cane or raw beets It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):
EPA Reg. No. 464-704-1706 In all cases follow instructions on the product label.
This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4 /formerly Sec. 311 :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.
CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances):
This product contains the following substances listed in the regulation. Additional components may be unintentionally present at trace levels.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 10/13 0 073
I SAFETY DATA SHEET NALCO PRODUCT
-I H-550 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC Substance(s) Citations I e Methanol Sec. 112 I
CALIFORNIA PROPOSITION 65:
Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product.
I MICHIGAN CRITICAL MATERIALS:
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.
I STATE RIGHT TO KNOW LAWS:
This product is a registered biocide and is exempt from State Right to Know Labelling Laws.
I Methanol Glutaraldehyde 67-56-1 111-30-8 I
NATIONAL REGULATIONS, CANADA:
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
I This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION:
I Pesticide controlled products are not regulated under WHMIS.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
Substances regulated under the Pest Control Products Act are exempt from CEPA New Substance Notification I
requirements.
AUSTRALIA I
All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA I
All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on the Inventory of Existing Chemical Substances China (IECSC).
EUROPE I
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN I
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).
I Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 o (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 11/13 I 0074
SAFETY DATA SHEET
~NALCO DUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)
PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).
- 16. OTHER INFORMATION This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight TM CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS TM CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
M T
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight TM CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS M T CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel InsightTM (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight TM CD-ROM Version), Ariel Research Corp., Bethesda, MD.
M T
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 12/13 0075
SAFETY DATA SHEET I
R4NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
PI (800) 424-9300 (24 Hours) CHEMTREC I
I Prepared By Product Safety Department Date issued
- 02/11/2010 Version Number: 1.18 I I
I I
I I
1 I
I I
I I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access I
13/13 II 00,16
Material Safety Data Sheet - FERROQUEST LP7200 Page I of 6 GE Betz GE Betz, Inc. Material Safety Data Sheet 4636 Somnerton Road Trevose, PA 19053 Issue Date: 07-JUN-2006 Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 1 PRODUCT IDENTIFICATION PRODUCT NAME:
FERROQUEST LP7200 PRODUCT APPLICATION AREA:
CHEMICAL CLEANING COMPOUND.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. This product is subject to the Pennsylvania and New Jersey Worker and Community Right to Know Law.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME TRADE SECRET INGREDIENT(EO3G);TSRN 125438 - 11017 Irritant (eyes and skin)
TRADE SECRET INGREDIENT(E195);TSRN 125438 - 5118P Irritant (eyes and skin) 124-04-9 ADIPIC ACID (HEXANEDIOIC ACID)
Potential irritant (eyes)
TRADE SECRET INGREDIENT(EO3L);TSRN 125438 - 11018 Irritant (eyes and skin)
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at Pennsylvania thresholds for carcinogens.
NON-HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME 0077 http://tsg.gesm.ge.com/gebetzmsds/BetzHTML/PRODUCTS/PA_ NJ/FERROQUEST... 10/30/2006
Material Safety Data Sheet - FEPROQUEST LP7200 Page 2 of 6 7732-18-5 WATER 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING 3 May cause moderate irritation to the skin. Severe irritant to the eyes. Vapors, gases, mists and/or aerosols cause irritation to the upper respiratory tract.
DOT hazard: Corrosive to steel Emergency Response Guide #153 Odor: Acid; Appearance: Colorless To Green, Liquid I
Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water I
POTENTIAL HEALTH EFFECTS I ACUTE SKIN EFFECTS:
Primary route of exposure; May cause moderate irritation to the skin.
ACUTE EYE EFFECTS:
Severe irritant to the eyes. 1 ACUTE RESPIRATORY EFFECTS:
Primary route of exposure;Vapors, gases, mists and/ox aerosols cause irritation to the upper respiratory tract. -
INGESTION EFFECTS:
May cause slight gastrointestinal irritation with possible nausea, vomiting, diarrhea, incoordination, mental confusion, dizziness and lethargy.
TARGET ORGANS:
Prolonged or repeated exposures may cause primary irritant I
dermatitis and/or toxicity to the lung.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
I SYMPTOMS, OF EXPOSURE: -
Inhalation may cause irritation of the respiratory tract. Skin contact may cause itching and/or redness.
I 4 FIRST AID MEASURES SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
I iI 0078 httD://tsi.2esm.2e.com/ge hetz msd./Ret7 F4TMI./PR0Tr)1CT/PA NT/'FPP01TC TPC.*T Ifl/lnl/')ni
Material Safety Data Sheet - FERROQUESI LP/200 Page 3 of 6 Thoroughly wash clothing before reuse. Get medical attention if irritation develops or persists.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes with plenty of low-pressure water for at least 15 minutes. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air, and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F > 93C P-M(CC)
MISCELLANEOUS:
Corrosive to steel UN3265;Emergency Response Guide #153 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and-absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Contains an oxidizer. Avoid all contact with reducing agents, oils, greases, organics and acids.
STORAGE:
Keep containers closed when not in use. Reasonable and safe chemical storage. Protect from freezing.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME 0079 httni/t.,zc cim ae rnmlot- hpt7 mer c[/ih7 14TMT /P1PQf) TCT*/P A MY/I'TDP-P(VT 1TQT 1flIA1 th
Material Safety Data Sheet - FERROQUEST LP720U . Page 4 of 6 I TRADE SECRET INGREDIENT(EO3G);TSRN 125438 - 11017
-I PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED I TRADE SECRET INGREDIENT(EI95);TSRN PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED 125438 - 5118P I
ADIPIC ACID (HEXANEDIOIC ACID)
PEL (OSHA): NUISANCE DUST TLV (ACGIH): 5 MG/M3 I
MISC: Note: manufacturer's recommended exposure limit: 10 mg/m3.
TRADE SECRET INGREDIENT(EO3L);TSRN 125438 - 11018 I
PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
I Adequate ventilation to maintain air contaminants below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I I
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS.OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER I
WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a I
respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as I
necessary.
EYE PROTECTION:
splash proof chemical goggles I 9 PHYSICAL & CHEMICAL PROPERTIES 1 Specific Grav.(70F,21C) 1.070 Vapor Pressure (mmHG) - 36.0 Freeze Point (F)
Freeze Point (C)
Viscosity(cps 70F,21C) 27
-3 9
Vapor Density (air=l)
% Solubility (water)
< 1.00 100.0 I
Odor Appearance Acid Colorless To Green I
Physical State Liquid Flash Point pH As Is (approx.)
Evaporation Rate (Ether=l)
P-M(CC) > 200F 1.4
< 1.00
> 93C I
NA = not applicable ND = not determined I
10 STABILITY & REACTIVITY I STABILITY:
0080 http://tsg.gesm.ge.com/ge betz msds/Betz HTML/PRODUCTS/PA NJ/FERROQUEST... 10/30/2006 I
Material Safety Data Sheet - FERROQUEST LP7200 Page 5 of 6 Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 TOXICOLOGICAL INFORMATION Oral LD50 RAT: 6,829 mg/kg Dermal LD50 RABBIT: >5,000 mg/kg NOTE - Estimated value 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Screen 0% Mortality= 1000 mg/L Fathead Minnow 96 Hour Static Screen 0% Mortality= 1500 mg/L BIODEGRADATION BOD-28 (mg/g): 447 BOD-5 (mg/g) : 336 COD (mg/g): 388 TOC (mg/g): 177 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA -
hazardous waste identification number is D002=Corrosive(pH, steel).
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 TRANSPORT INFORMATION DOT HAZARD: Corrosive to steel UN / NA NUMBER: UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153 15 REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds USDA FOOD PLANT APPROVALS:
This product contains ingredients that have been determined safe httn:]/ts.,grm ~ cnm/*e hir7 mrIc/Ttpt7 1TITMITJP*nrTTrT'DA MKTIVTiDDC tworn r in,*nn*
Material Safety Data Sheet - FERROQUEST LP7200 Page 6 of 6 I for use as a general cleaning agentor for use with steam or mechanical cleaning devices.Surfaces must be rinsed with potable
-I water.
SARA SECTION 312 HAZARD CLASS:
Immediate (acute) ;Delayed (Chronic)
I SARA SECTION 302 CHEMICALSt No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
I No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC I
ENFORCEMENT ACT No regulated MICHIGAN REGULATORY (PROPOSITION 65) CHEMICALS PRESENT:
constituents present INFORMATION I
No regulated constituent present at OSHA thresholds I
16 OTHER INFORMATION NFPAIHMIS CODE TRANSLATION I
Health Fire 2
1 0
Moderate Hazard Slight Hazard I
Reactivity Minimal Hazard Special (1) Protective Equipment CORR B
DOT corrosive Goggles,Gloves I (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG I
EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES I
MSDS status: 25-SEP-1997 27-OCT-1999 07-APR-2006 3,4 2,3,8
- NEW **
25-SEP-1997 27-OCT-1999 I
07-JUN-2006 2,8 07-APR-2006 I
I I
I I
0082 I http://tsg.gesm.ge.com/ge betz msds/Betz HTML/PRODUCTS/PA NJ/FERROQUEST... 10/30/2006
SAFETY DATA SHEET PA NALCO PRODUCT NALCO 1315 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC i
I FT ICHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME: NALCO 1315 APPLICATION: DETOXIFICATION AGENT COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 01i FLAMMABILITY: 0/0 INSTABILITY: 0/0 OTHER:
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
- Chronic Health Hazard
- 12. 1COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
Hazardous Substance(s) CAS NO % (w/w)
Bentonite 1302-78-9 5.0- 10.0 Quartz 14808-60-7 0.1- 1.0
- 13. 1 HAZARDS IDENTIFICATION . I
- EMERGENCY OVERVIEW**
CAUTION May cause irritation with prolonged contact. Inhalation of crystalline silica can cause silicosis. This material or some of its substance(s) has been shown to cause cancer in laboratory animals.
Do not get in eyes, on skin, on clothing. Do not take internally. Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Protect product from freezing.
Not flammable or combustible.
PRIMARY ROUTES OF EXPOSURE:
Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:
EYE CONTACT:
May cause irritation with prolonged contact.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 o (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access L./10 0083
SAFETY DATA SHEET P4NALCO )04"NALC PRODUCT ....... .
NALCO 1315 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SKIN CONTACT:
May cause irritation with prolonged contact.
INGESTION:
Not a likely route of exposure. No adverse effects expected.
INHALATION:
Not a likely route of exposure. Aerosols or product mist may irritate the upper respiratory tract.
SYMPTOMS OF EXPOSURE:
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic :
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
Prolonged inhalation of dust containing amorphous silica can increase lung injury in individuals with emphysema, asthma or other lung disorders.
HUMAN HEALTH HAZARDS - CHRONIC:
Prolonged exposure to amorphous silica aerosols/mists/dusts may cause respiratory disease. Inhalation of crystalline silica can cause silicosis.
- 14. FIRST AID MEASURES EYE CONTACT:
Flush affected area with water. If symptoms develop, seek medical advice.
SKIN CONTACT:
Flush affected area with water. If symptoms develop, seek medical advice.
INGESTION:
Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If symptoms develop, seek medical advice.
INHALATION:
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.
NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
- 15. FIRE FIGHTING MEASURES FLASH POINT: > 212 'F / > 100 'C ( PMCC)
EXTINGUISHING MEDIA:
Not expected to burn. Use extinguishing media appropriate for surrounding fire.
Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/10 0084
SAFETY DATA SHEET
- 4NALCO PRODUCT NALCO 1315 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC FIRE AND EXPLOSION HAZARD:
Not flammable or combustible.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
- 16. 1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Stop or reduce any leaks if it is safe to do so. Do not touch spilled material. Ventilate spill area if possible. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches orby diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
Do not contaminate surface water.
- 17. 1HANDLING AND STORAGE HANDLING:
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled.
STORAGE CONDITIONS:
Store the containers tightly closed. Protect product from freezing.
SUITABLE CONSTRUCTION MATERIAL:
Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.
- 18. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:
This product contains amorphous, colloidal or fumed silica. Should the product become dried or misted such that inhalation of the material is possible, standard hygiene practices should be utilized to ensure that exposure to respirable particles is within the regulated limits.
Country/Source Substance(s) Category: ppm mg/ m3 Inhalable (Total Dust) Nuisance Particulates (Inhalable ACGIHITWA 10 particles.)
Inhalable (Total Dust) Nuisance Particulates (Respirable ACGIH/TWA 3 particles.)
Inhalable (Total Dust) Nuisance Particulates (Respirable OSHA ZI/PEL 5 Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/10 0085
I PdNALCO SAFETY DATA SHEET
.PRODUCT j NALCO 1315 EMERGENCY TELEPHONE NUMBER(S) fraction.)
(800) 424-9300 (24 Hours) CHEMTREC I
Inhalable (Total Dust) Nuisance Particulates (Total dust.) OSHA Z1/PEL 15 Inhalable (Total Dust) Nuisance Particulates (Respirable Z3/TWA fraction.)
Inhalable (Total Dust) Nuisance Particulates (Total dust.) Z3/ITWA Inhalable (Total Dust) Nuisance Particulates (Respirable Z3/TWA 5 fraction.)
Inhalable (Total Dust) Nuisance Particulates (Total dust.) Z3/TWA 15 Silica, Crystalline Quartz, Respirable Dust (Respirable ACGIH/TWA 0.025 fraction.)
Silica, Crystalline Quartz, Respirable Dust (Respirable.) Z3/TWA Z3/TWA 0.1 Silica, Crystalline Quartz, Respirable Dust (Total dust.) Z3/TWA 0.3 ENGINEERING MEASURES: I The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces.
RESPIRATORY PROTECTION:
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: Particulate filter - HEPA. with a Particulate pre-filter. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on work conditions and what chemicals are handled. Please contact the PPE manufacturer for advice on whattype of glove.
material may be suitable. Gloves should be replaced immediately if signs of degradation are observed.
SKIN PROTECTION:
Wear standard protective clothing. I EYE PROTECTION:
Wear safety glasses with side-shields. I HYGIENE RECOMMENDATIONS:
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke.
HUMAN EXPOSURE CHARACTERIZATION:
Based on our recommended product application and personal protective equipment, the potential human exposure is:
Low I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 o(630)305-1000 I For additional copies of an MSDS visit www.nalco.com and request access 4/10 00 8b
SAFETY DATA SHEET PRODUCT NA'wNALC0 NALCO 1315 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
- 19. 1 PHYSICAL AND CHEMICAL PROPERTIES I PHYSICAL STATE Liquid APPEARANCE Green Tan ODOR None SPECIFIC GRAVITY 1.04 @ 60 -F / 15.6 -C DENSITY 8.66 lb/gal SOLUBILITY IN WATER Dispersible pH (100 %) 8.3 BOILING POINT 212 'F / 100 'C Note: These physical properties are typical values for this product and are subject to change.
- 10. STABILITY AND REACTIVITY STABILITY:
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
CONDITIONS TO AVOID:
Freezing temperatures.
MATERIALS TO AVOID:
None known HAZARDOUS DECOMPOSITION PRODUCTS:
Under fire conditions: None known
- 11. TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product.
SENSITIZATION:
This product is not expected to be a sensitizer.
CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/10 O08,7
SAFETY DATA SHEET I
A411NALC*O ! PRODUCT NALCO 1315 EMERGENCY TELEPHONE NUMBER(S) I HUMAN HAZARD CHARACTERIZATION:
(800) 424-9300 (24 Hours) CHEMTREC I
Based on our hazard characterization, the potential human hazard is: High
- 12. ECOLOGICAL INFORMATION I
ECOTOXICOLOGICAL EFFECTS:
No toxicity studies have been conducted on this product.
I MOBILITY:
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program I
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
I If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment I
<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
I ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low Based on our recommended product application and the product's characteristics, the potential environmental I
exposure is: Moderate If released into the environment, see CERCLA/SUPERFUND in Section 15. I
- 13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery 1
Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.
As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, I
disposal or recycling facility.
- 14. 1TRANSPORT INFORMATION I
The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, I and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT: I Proper Shipping Name: PRODUCT IS NOT REGULATED DURING Nalco Company 1601 W. Diehl Road- Naperville, Illinois 60563-1198 (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 6/10 0086 I
PVNALCO )04"NALI SAFETY DATA SHEET PRODUCT NALCO 1315 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC TRANSPORTATION AIR TRANSPORT (ICAO/IATA):
Proper Shipping Name PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name PRODUCT IS NOT REGULATED DURING TRANSPORTATION
- 15. REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information.
NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.
Bentonite: Exposure Limit- Compound Class Quartz : Cancer suspect agent (refer to Section 3)
CERCLA/SUPERFUND, 40 CFR 117,302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE Ill) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:
Immediate (Acute) Health Hazard X Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 ° (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/10 0089
SAFETY DATA SHEET I
)4NALCO I
NALCO cPRODUCT 1315 EMERGENCY TELEPHONE NUMBER(S) i (800) 424-9300 (24 Hours) CHEMTREC I
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
I The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR I
116.4 /formerly Sec. 311 :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels. I CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances):
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed I components may be present at trace levels.
CALIFORNIA PROPOSITION 65:
This product contains the following substances which require warning under California Proposition 65.
i Substance(s)
" Quartz
- Cristobalite Concentration
<= 1 %
< .1%
EFFECTS Causes Cancer I MICHIGAN CRITICAL MATERIALS:
I Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.
I STATE RIGHT TO KNOW LAWS:
The following substances are disclosed for compliance with State Right to Know Laws:
Quartz 14808-60-7 I
NATIONAL REGULATIONS, CANADA: I WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. I WHMIS CLASSIFICATION:
D2B - Materials Causing Other Toxic Effects - Toxic Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
I The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations. I Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 ° (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/10 0090
SAFETY DATA SHEET i IOPRODUCT NALCO 1315 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
i 16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:
I
- The human risk is: Low
- The environmental risk is: Low D Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.
This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the i recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
3 REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight CD-ROM Version), Ariel Research Corp.,
i Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
i Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO.
I Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
i Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, I OH, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO.
i Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 o (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9/10 0091
SAFETY DATA SHEET I
AWNALCO PRODUCT I
NALCO 1315 EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC Ariel Insight (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel I
Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version),
U Micromedex, Inc., Englewood, CO.
I Prepared By Product Safety Department Date issued 07/31/2009 Version Number: 1.7 I
I I
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I I
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 o (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access I
10/10 0092 I
Univar USA Inc.
6100 Carillon Point Kirkland, WA 98033 (425) 889-3400 For Emergency Assistance involving chemicals call - CHEMTREC (800) 424-9300 The Version Date for this MSDS is : 07/26/2004 PRODUCT NAME: LIQUICHLOR / SODIUM HYPOCHLORITE 9-16%
MSDS NUMBER: OX622680 EFFECTIVE DATE: 2/16/2004 SUPERSEDES: 1/15/2003 ISSUED BY: 007427 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Sodium Hypochlorite Solution (9 - 16%)
CAS#: 7681-52-9 Synonyms: Sodium Hypochlorite Solution - Trade % (9 - 19), Bleach, Javel Water, Clorox, Sunny Sol 150, Liquid Chlorine Solution, Liquid Bleach, Hypochlorite Bleach, Hypo Product Use: Bleach, disinfectant Emergency Contacts (24 hr.)
A FOR INFORMATION REGARDING ON SITE CHEMICAL EMERGENCIES INVOLVING A SPILL OR LEAK, CALL U.S.: 1-800-424-9300 - CHEMTREC Canada: 1-613-996-6666 - CANUTEC Distributed by:
Univar USA Inc.
6100 Carillon Point Kirkland, WA 98033 425-889-3400 SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredient(s) % (w/w) ACGIH OSHA CAS NO.
A Sodium Hypochlorite 9 - 16 Not established Not 7681-52-9 0.5 ppm established (as chlorine)
Sodium Hydroxide 0.3 - 4 2 mg/m3 (ceiling) 2 mg/m3 1310-73-2 SECTION 3 HAZARD IDENTIFICATION Emergency Overview: CORROSIVE! Contact with acid liberates toxic chlorine gas. Causes burns to skin, eyes, respiratory tract and mucous membranes.
0093
I Harmful or fatal if swallowed. May cause sensitization by skin contact. i Toxic to aquatic organisms. Read the entire MSDS for a more thorough evaluation of the hazards.
Potential Health Effects: I Inhalation: Mist can irritate the nose and throat. If mixed with acids, hypochlorite solutions release large amounts of chlorine gas. This gas can cause severe irritation of the nose and throat. Exposure to high levels of chlorine gas may result in severe lung damage.
Skin
Contact:
Sodium hypochlorite mist and solutions can cause skin I
irritation. In severe cases, chemical burns may result.
Eye
Contact:
Can cause severe eye irritation and permanent eye injury.
Ingestion: May cause irritation, pain and inflammation of the mouth and stomach, vomiting, shock, confusion, delirium, coma and, in severe cases, death. Perforation of the esophagus or stomach may occur.
Subchronic Effects: SKIN: Prolonged or repeated skin contact with solutions containing as little as 4-6% sodium hypochlorite can cause allergic contact
'dermatitis. Symptoms include chronic, itchy eczema. Sensitized people can react to very dilute (0.04-0.06% NaOCl) solutions that touch their skin Existing Medical Conditions Possibly Aggravated by Exposure: Skin irritation I
may be aggravated in individuals with existing skin lesions. Breathing of vapors or mists may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema and bronchitis.
Carcinogenicity: Sodium hypochlorite is not classified as a carcinogen by ACGIH (American Conference of Governmental Industrial Hygienists) or IARC (International Agency for Research on Cancer), not regulated as a carcinogen by OSHA (Occupational Safety and Health Administration), and not listed as a carcinogen by NTP (National Toxicology Program).
SECTION 4 FIRST AID MEASURES General: If you feel unwell seek medical advice (show the label where possible).
Inhalation: Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Do not use mouth-to-mouth method if victim ingested or inhaled the substance: induce artificial respiration with the aid of a i
pocket mask equipped with a one-way valve or other proper respiratory medical device. Give Cardiopulmonary Resuscitation (CPR) only-if there is no pulse AND no breathing. Obtain medical attention IMMEDIATELY.
Skin
Contact:
Immediately flush skin with running water for at least 15 - 20 minutes. Under running water remove contaminated clothing, jewelry, and shoes. If irritation persists, repeat flushing. For burns, obtain medical attention. Discard heavily contaminated clothing and shoes in a manner, which limits further exposure. Otherwise, wash clothing separately before reuse.
Eye
Contact:
Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. Do not transport victim until the recommended flushing period is completed unless flushing can be continued during transport.
Ingestion: DO NOT INDUCE VOMITING. If victim is alert and not convulsing, i
rinse mouth and give as much water as possible to dilute material. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water.
IMMEDIATELY transport victim to an emergency facility.
Note to Physicians: Symptomatic. Treatment and supportive therapy as indicated. Do NOT give acidic antidotes such as juice, soft drink, vinegar, etc. This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less than 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if I
respiration is depressed. Following exposure the patient should be kept under medical review for at least 48 hours5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> as delayed pneumoniti.o may occur.
0094
Pulmonary edema is likely and may be delayed. Steroid therapy, if given early, may be effective in preventing or alleviating edema.
SECTION 5 FIRE FIGHTING MEASURES Flash Point Not applicable. Not combustible Flammable Limits (Lower) Not applicable.
Flammable Limits (Upper) Not applicable Auto Ignition Temperature Not applicable Combustion and Thermal Decomposition Products Chlorine, sodium oxide, oxygen Rate of Burning Not applicable Explosive Power Not applicable Sensitivity to Mechanical Impact Not applicable Fire and Explosion Hazards: Sodium hypochlorite is a strong chemical oxidant, but solutions do not support combustion. Reaction with nitrogen compounds, chloroorganic compounds, or easily oxidizable compounds (reducing agents) may be explosive. This material is non-flammable but is decomposed by heat and light, causing a pressure build-up, which could result in an explosion. When heated, it may release chlorine gas. Vigorous reaction with oxidizable or organic materials may result in fire. See Section 10.
Extinguishing Media: For large fires use an all purpose type AFFF alcohol foam resistant medium expansion according to foam manufacturer's recommended techniques. The foam supplier should be consulted for recommendations regarding foam types and delivery rates for specific applications. Use carbon dioxide or dry chemical media for small fires. If only water is available, use it in the form of a fog.
Special Information: Water may be used to cool containers of Hypochlorite solution exposed to heat from a fire. This should be done from a safe distance since containers may rupture.
Move containers from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material.
Fire involving tanks or trailer loads: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from-the ends of tanks.
Evacuation: If tank or tank truck involved in a fire, ISOLATE and consider evacuation of one-half (1/2) mile radius.
Fire Fighting Protective Equipment: Firefighters should wear protective equipment and self-contained breathing apparatus with full facepiece operated in positive pressure mode in a fire involving this material. Toxic gas and vapors are produced .upon decomposition.
NOTE: Also see "Section 10 - Stability and Reactivity" SECTION 6 - ACCIDENTAL RELEASE MEASURES Spills, Leaks, or Releases:
Restrict access to area until completion of clean up. Ensure trained personnel conduct clean up.
Remove all ignition sources (no smoking, flares, sparks or flames). All equipment should be grounded and non-sparking. Ventilate area.
Wear adequate personal protective equipment. Do not touch spilled material.
Stop leak if possible without personal risk.
Small spills: Cover with DRY earth, sand or other non-combustible material.
Use clean non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. Rinse area with water.
Large spills: Prevent entry into sewers and confined areas. Dike with inert material (sand, earth, etc.). Contact fire and emergency services and supplier for advice. Collect product for recovery or disposal by pumping it into polyethylene containers. Consider in-situ neutralization and disposal.
Ensure adequate decontamination of tools and equipment followrinn clean up.
0095
i Collect contaminated soil and water, and absorbent for proper disposal.
Comply with Federal, Provincial/State and local regulations on reporting releases.
Deactivation for Small Spills: Hypochlorite can be broken down by covering it with a reducing agent such as sodium sulfite or sodium thiosulfate.
Deactivating Chemicals: Use sodium sulfite or diluted hydrogen peroxide to reduce the material. Ensure there is no chlorine residue before neutralizing with a weak solution of hydrochloric or sulfuric acid.
Waste Disposal Methods: Dispose of waste material at an approved waste treatment/disposal facility, in accordance with applicable regulations. Do not dispose of waste with normal garbage or to sewer systems.
Note: - Clean-up material may be a RCRA Hazardous Waste on disposal.
- Spills are subject to CERCLA reporting requirements: RQ = 100 lbs.
SECTION 7 - HANDLING AND STORAGE Precautions: Have emergency equipment (for fires, spills, leaks, etc.)
3 readily available. Ensure all containers are labeled. Wear appropriate Personal Protection Equipment. People working with this chemical should be properly trained regarding its hazards and its safe use.
Handling Procedures and Equipment: Avoid generating mist. Use smallest I
possible amounts in designated areas with adequate ventilation. Keep containers closed when not in use. Empty containers may contain hazardous residues. Use corrosion-resistant transfer equipment when dispensing.
Storage Requirements: Store in a cool, dry, well-ventilated area, out of direct sunlight. Store containers at 15 - 29 deg C (59 - 84 deg F) . Do not store above 30 deg C (86 deg F) or below freezing point. Keep containers tightly closed when not in use and when empty. Protect from damage. Vent I
caps should be checked with full personal protection. Store away from incompatible materials such as reducing materials, strong acids, nitrogen compounds, copper, nickel and cobalt. Use corrosion-resistant structural materials and lighting and ventilation systems in the storage area. This i
product has a shelf life of up to six months at 60 deg F or lower.
Outdoor storage tanks should be suitably diked or otherwise provided with an adequate means of secondary containment. Appropriate secondary containment measures should be taken to prevent spills or leaks from indoor storage I
tanks and tank-truck unloading stations from entering sewers or other channels that discharge directly to a water body or a municipad sewage system.
SECTION 8 - EXPOSURE CONTROLS t PERSONAL PROTECTION PREVENTIVE MEASURES Recommendations listed in this section indicate the type of equipment, which will provide protection against over exposure to this product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace.
Engineering Controls: Local exhaust ventilation should be applied wherever there is an incidence of point source emissions or dispersion of regulated contaminants in the work area. Ventilation control of the contaminant as close to its point of generation is both the most economical and safest method to minimize personnel exposure to airborne contaminants. The most effective measures are the total enclosure of processes and the mechanization of handling procedures to prevent all personal contact.
Smoking should be prohibited in areas in which sodium hypochlorite solution is stored or handled.
PERSONAL PROTECTIVE EQUIPMENT I Eye Protection: Wear splash resistant chemical goggles and full-face shield.
Maintain eye wash fountain and quick-drench facilities in work area.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain jacket, pants or coveralls, as appropriate, to prevent skin contact.
RECOMMENDED (resistance to breakthrough longer than 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />) : butyl rubber, natural rubber, neoprene, nitrile rubber, polyethylene, Viton. SaranexTM, 0096
ResponderTM Recommendations are valid for permeation rates reaching 0.1 ug/cm2/min or 1 mg/m2/min and over. Resistance of specific materials can vary from product to product. Breakthrough times are obtained under conditions of continuous contact, generally at room temperature. Evaluate resistance under conditions of use and maintain clothing carefully.
Respiratory Protection: A NIOSH/MSHA approved air-purifying respirator equipped with acid mist cartridges for concentrations up to 10 times the TLV. Use a supplied air respirator if concentrations are higher or unknown.
EXPOSURE GUIDELINES PRODUCT:
Sodium Hypochlorite Workplace environmental exposure level guides (WEELS) / American Industrial Hygiene Association (AIHA) / 2001 short-term time weighted average 2 mg/m3: 15 minute Sodium Hypochlorite Chlorine* Sodium Hydroxide ACGIH TWA Not established 0.5 ppm Not established OSHA PEL Not established 0.5 ppm 2 mg/m3 NIOSH IDLH Not established 10 ppm Not established ACGIH STEL Not established 1 ppm Not established OSHA STEL Not established 1 ppm as C12 Not established NIOSH (15 min. ceiling)
Not established 0.5 ppm Not established ACGIH Ceiling Not established Not established 2 mg/m3
- Chlorine may be present as a decomposition product.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Chemical Name Sodium hypochlorite Chemical Family Hypochlorous acid salt Molecular Formula Na-O-Cl Molecular Weight 74.4 Appearance Green to yellow, watery liquid Odor Pungent chlorine-like odor PH 11-13 Vapor Pressure (mm Hg at 21 deg C(69.8 deg F) 12 mmHg Vapor Density (Air = 1) No data Boiling Point Decomposes above 40 deg C (104 deg F)
Freezing Point 7.5 deg F (-13.6 deg C)
Solubility (Water) Completely Specific Gravity About 1.198 (12.5% w/w solution) @ 20 deg C (68 deg F)
Evaporation Rate Not available
% Volatile by Volume Not available SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature.
Hazardous Decomposition Products: Thermal decomposition: Chlorine, sodium oxide, oxygen, oxides of chlorine, sodium chlorate, and hydrogen.
Conditions to Avoid: Keep away from high heat, and sunlight or ultra-violet light. Do not store above 30 deg C (86 deg F). Do not allow solutions to evaporate dry. Keep away from incompatibles.
Incompatibility with other Substances: May react violently with strong acids producing chlorine gas, which is toxic. Other incompatibles include organic material, cellulose, oxidizable materials, ammonia, urea, ammonium salts, ethyleneimine, cyanides, nitrogen compounds, alcohols, metals, and metal oxides. Reacts with metals to produce flammable hydrogen gas. Metal and metal oxide catalysts decompose hypochlorites, evolving oxygen and often causing explosions. May react explosively with nitrogen containing compounds or form chloroamines, which are explosive. Alkaline hypochlorite solutions may react explosively with some chloroorganic compounds.
Corrosivity to Metals: Solutions can be corrosive to many metals.
Hazardous Polymerization: Will not occur.
0097
l SECTION 11 - TOXICOLOGICAL INFORMATION l TOXICOLOGICAL DATA Sodium Hypochlorite:
Toxicity Data: TDLo (Lowest published toxic dose) oral-woman- 1 gm/kg 45 mg/kg intravenous-man TDLo LD50 oral rat- 8910 mg/kg LD50 oral mouse- 5800 mg/kg LC50 rat- >10500 mg/m3 (1 hr) l Irritation Data: Eyes: One drop of 15% solution (pH 11.2) caused immediate severe pain. If not quickly washed off with water, it caused bleeding and swelling of the tender tissue surrounding the eye (conjunctiva) and damage with swelling to the front part of the eye (cornea). The eyes sometimes I
healed in two to three weeks with slight or no scar damage to the cornea.
Skin: A solution of 3.5% NaOCl applied to rabbit skin for 15 or 30 minutes caused severe skin damage.
Sodium Hydroxide:
Irritation data: 500 mg/24 hour(s) skin-rabbit severe; 400 pg eyes-rabbit mild; 1 percent eyes-rabbit severe; Toxicity data: 1350 mg/kg skin-rabbit LD50; 104-340 mg/kg oral-rat LD50 Mutagenicity: Sodium hypochlorite caused mutations in several short-term studies using bacteria and cultured mammalian cells. The significance of these tests is unclear. It was not mutagenic in tests (chromosome aberration l
and micronucleus) on live animals.
Reproductive Effects: High doses of NaOCl in drinking water caused a small but significant increase in abnormal sperm in mice.
Teratogenicity and Fetotoxicity: No data available I
Carcinogenicity: See Section 3, page 2.
Synergistic Materials: None known SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicological Information: Harmful to aquatic life in low concentrations.
Fish Toxicity: LC50 (48 hr) rainbow trout 0.07 mg/l.
LC50 (96 hr) fathead minnow 5.9 mg/l.
Invertebrate and Microbial Toxicity: LOEC Oncorhynchus kisutch-0.02 mg/l.
Persistence and Degradation: No data available.
SECTION 13- DISPOSAL CONSIDERATIONS Review federal, state and local government requirements prior to disposal.
Do not dispose of waste with normal garbage, or to sewer systems.
Whatever cannot be saved for recovery or recycling, including containers should be managed in an appropriate and approved waste disposal facility.
Processing, use or contamination of this product may change the waste management options.
I RCRA: Test waste material for corrosivity, D002, prior to disposal.
SECTION 14 TRANSPORT INFORMATION I TDG CLR
- DOT Shipping Name Hypochlorite Solution - with Hypochlorite Solution more than 7 percent available Hazard Class / Division chlorine 8: Corrosive 8: Corrosive i
Identification No. UN1791 UN1791 II III ERAP/RQ N/AP N/AP Note:
- TDG CLR (Clear Language Regulations) became effective August 15, 2002 IATA/ICAO Shipping
Description:
Hypochlorite solution, Class 8, UN1791, PG I
II or III is accepted for air transport.
0098 I
SECTION 15 - REGULATORY INFORMATION USA CLASSIFICATION OSHA Classification: Hazardous by definition of Hazargd Communication Standard (29 CFR 1910.1200)
SARA Regulations sections 313 and 40 CFR 372: N SARA Hazard Categories, SARA SECTIONS 311/312 (40CFR370.21):
ACUTE: Y CHRONIC: N FIRE: N REACTIVE: N SUDDEN RELEASE: N OSHA PROCESS SAFETY (29CFR1910.119) : N CERCLA SECTION 103 (40CFR302.4) : Y Reportable Quantity (RQ) under CERCLA: 100 lbs. (45.4 kg)
TSCA Inventory Status: Y Other Regulations/Legislation which apply to this product:
Right-to-Know/Disclosure Lists: Illinois, Massachusetts, New Jersey, Pennsylvania, This product does not contain nor is it manufactured with ozone depleting substances.
CANADIAN CLASSIFICATION This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR.
Controlled Products Regulations (WHMIS) Classification:
D2B: Material causing other toxic effects -Toxic E: Corrosive CEPA / Canadian Domestic Substances List (DSL) : Y WHMIS Ingredient Disclosure List: Meets criteria for disclosurie at 1% or.
greater.
EINECS Number: 231-668-3 SECTION 16 - OTHER INFORMATION National Fire Protection Association (NFPA) Rating Hazardous Materials Identification System (HMIS) Rating NFPA HMIS 4 = Extreme/Severe HEALTH 3 3 3 = High/Serious 2 = Moderate FIRE 0 0 1 = Slight REACTIVITY 1 1 0 = Minimum W = Water Reactive LEGEND ACGIH - American Conference of Governmental Industrial Hygienists CAS # - Chemical Abstracts Service Registry Number CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act CFR - Code of Federal Regulations DOT - Department of Transportation EPA - Environmental Protection Agency IDLH - Immediately Dangerous to Life and Health LC50 - The concentration of material in air expected to kill 50% of a group of test animals .0099
I L50 - Lethal Dose expected to kill 50% of a group of test animals i MSHA - Mine Safety and Health Administration NIOSH - National Institute for Occupational Safety and Health OSHA - Occupational Safety & Health Administration PEL - Permissible Exposure Limit PVC - Polyvinyl chloride RCRA - Resource Conservation and Recovery Act SARA - Superfund Amendments and Reauthorization Act of the U.S. EPA STEL - Short Term Exposure Limit TDG - Transportation of Dangerous Goods Act/Regulations TLV - Threshold Limit Value TSCA - Toxic Substances Control Act I
For Additional Information:
Contact:
MSDS Coordinator - Univar USA During business hours, Pacific Time - (425) 889-3400 NOTICE Univar USA expressly disclaims all express or implied warranties of merchantibility and fitness for a particular purpose with respect to the product or information provided herein, and shall 3
under no circumstances be liable for incidental or consequential damages.
Do not use ingredient information and/or ingredient percentages in this MSDS as a product I specification. For product specification information refer to a Product Specification Sheet and/or a Certificate of Analysis. These can be obtained from your local Univar USA Sales Office.
All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, Univar USA makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Univar USA's control. Therefore, users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes, and they assume all risks of their use, handling, and disposal of the product or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein and does not relate to its use in combination with any other material or in any other process.I 0
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0100 3
Materi Safety Data Sheet Page: I of 8 Issue Date: 07/28198 A company of Hect wt and Schering, Berlin 3 .Supersedes: 02/14/96 NUSYN-NOXFISbY 3 FISH TOXICANT SECTION I. ýCHEM*CALPRODUCT AND COMPANY I ENTI*ICATDON TELEPH*COM*NIE NUMBER : (80&0)438-5837 Nuy*ofs s a eitrdtaea Environenta fAgrEvo Health, nc.
EOPAN EITYNUER MEp*;RE~NCYM TEEHNUMBER*I**;432-650 ff ,en 1MS~dSDENTIICATIONE POCaestn COE: l4a6d41 COENUMBER, 471 PROUCTnNoxfish1aP regStMe NUS trdmr fArv nimntalHatIc PRODUCTONAME:Nu*$yrNNOXFISh9" FISh' TOxiCaNt:* a tue PRODUCT CDESCITIN B467N41h3~ hToiat saretite s pHEstICide tobtsei feismnagemend fopg~eraditonffshrm SECIOENT2.ICATONMPOSITINIINFORMI ON INGEDIEN CONCENTRATION INGREDIENTMI EXPOSURE LIMITS PERCENT BY UEIGHT Rotne CAS NUMBER:8374
- ACGIII TLV-TVA 5 .gpo3 OSNA PEL-TIiA 5 m'm3
[
Piperoy s xiatde, vecnical None established = 2.5 tfe4associated're_%Ins =5 None. establishjed' Other ingriedients, 1hctLuing: = 90 [
Aromatic petroe. sobent 100 m=p (Manufacturer recouended) < 85 SECTION,3. HAZARDS IDENTIFICATION SFatalffin.......
- Causessuh*antaIhutteporary,eye injuwy. II POTENTIAL HE.ALTH EFFECTS 0101 El
I Page: 2 of 8 issue Date: 07/28/98 Supersedes: 02/14/96 yYN-NOXFISHO FISH TOXICANT ION&3,. HAZARDS 5DENTIFICATION - Continued 1ARYM RUTE(LS1 OF ENTY 5ation, ingestion, sin and eye contact ies,sbstantial but temporary eye injury.
I
'es skin irritation.
ESTON V-i785 if swallowed.
ION.4. FIRST AID S lME
- eyelids open and flush with a steady, gentle stream of water for 15
'ts G,etmedicalattention. ...
with'splenty
, of soap and water. Get medical attention.
'areaf a intae l.arg STION ar' quniiso eggý P aer
,evmiting. Call4 physicin oPionotrlCenter.
etn solutOn ornot hite viloo.Do i
,LATION rs
-ictiofresh air. If not breathng, give artificialrespiration, rablyMi'th to mouth. Get medical-attention.
Produ 1x w spray mist is,inhaled,moderately toxic by raltioute an, slightly toxicbPy the dermal route. This product causes ritia666 sui bybut reversiblemesisorvge wpsfh eye
'11irriain -Inta flwe and-- ramntiWenwlo by symptomatic and ortve :care.
I*Oi5., FIRE IGHINNG MEASURES_.
iMAýLE PROPE"RTIES 460C TCC AND EXPLOSION HAZARDS
-away romoTsourcesof gnition.
41GUISHING MEDIA crbo dixid ordry chemical.
foa, FIGHT ING INSTRUCTIONS any.trwvrsecon 6 .' . e ed reathinappraus pressure-demand, l
SHapproIed(or lventJ 6n6 fullprotective gear. Keep upwind.
gea dea. Avoid inhalatonofsdmkeend fumes. Use wateror foam, "as a fogol container wihfodn mut o ae rma a Ice as possible. Avoid breathin aos hMABIlITrY CLA SSIFICA MINR TNG 73O.
0702
Page: 376f 8 Issue Date: 07/28/98 L Supersedes: 02/14/96 NUSYN-NOXFISbI' FISH TOXICANT L
SECTION 5. ,FJRE FIGHTING MEASURES.r Continued NFPA/OSHA Class: Ii NFPA Radng Fre): 2 L S§ECTION 6.S A RELEASE MEASURES LCCI1DENA GENERAL AND (LISPOSAL Use proper protective equipoment to minimize personal exposu (se ection) Take all necessa action to prevent and to remedy
[
tie isffct*of the.spill Ehsure tha.ttheo disposal is in compliance wi rStiatProvificial,
,'d loclf*? laidons (See Section 13 for a 6 ýRCi4 Number). Refer 'to Section 75 for applicable Reportable
_' d" rgiatMo, req ifp;$et.
LAND SPILL',OR LEAK, Sifal Splls: 'Absorb liquid with an inert absorbent-.materialssuchas.
grw ~lysawdut~,'orpe lite.' Swp "up carefily hil avodig, the dispba lb formatdon*Rinse' are, *withlaeInnapoedcmil spill ciWd.u&
of a duit ~rallamount *bf soapy water. Contain stcnair and absorb*th nsate w it in*t absorbents a:nd place into .the;same disposal L Area can be Sootaine. toaree not aow w ontaine ple sewes.
ain*[in.fi all igiiof--wi notcso Sthop anf seu an do so
,bi commas 'htoaohtandwath7erafter
" - e t.
hanlDng ahendef liqnid c e nb u sp l sh l d b Wed. i lA
~pl fW ~ s l Ainp goggleasra lmqape u t eshiewr 4rWst ordt U DoSDonot n ot bet inlathe eysns sk"inorncltig ray mst.
STORAE PRvECAUION no cnmiae eto
- onoIoena Dor waer pnfae fodr feebytoa.
Rein*CO6nT~ btyon wash befre muse cand aondt brats. Nspqrloxlst ilntsldnrso n eaaina Dontempeatue d4 w or and cltisntbego,' mnmofoeyerwe stor~din 0eaydin a 0F WORK/HGIENC PACTICES a Washn t horoughly water soapad watr afedb terhndig adbeoeeaig
-diOin or uskig, tobaccocssbl o hld mRmoeineau co n wash rmi40Oin and stbleforea reniuse. d yrwe SECTION, 8ý..EX-POSURE CONTROLS/PERSONAL PROT-EC-TION MANUFACTURING. FOMUATONANDMOTHER NONAGRICULTURAL, USES ENGINERING CNRL CSontrvolairborne C-oncentrations beliow.te.aprpit exosureguideline (see 2 o apicableý OSHA7ACGIH ExpOsur Lit) I oa Seidion 's" xi~s r
vetiation b-ie Na EYE/ACE PROTECTIO0N wear safety glasses, splash goggles or face shield.
0103
Page: 4 of 8 Issue Date: 07/28/98 Supersedes 02/14/96 NUSYN-NOXFISH2 FISH TOXICANT SECTION 8. EXPOSURE CO,4TROLSIpERSONAL PROTECTAON - Continued F
-SKIN PROTECTION Wear.chemical-resistantgloves (Neoprene, Nitrile, PVC) and other protective clothing *to avoid skin contact.
RESPIRA TORY PROTECTION Iensure goo-ventilavon. If not adequate,-use a chemical cartridge-type respiratorapprovedby the NationalInstitute of OccupationaltHelthand
'GENERAL PROTECTION":
Eye wash#facility-andsafety shower should be available.
SECTION *9ý. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE M-57r, ýbrown liquid.[
ODOR 7Mido-dor.
7BASIC PHYSICAL:PROPERTIES PHSICAL STATE: Liquid 1 VAP& PSSURE: Not evailable VAPOR DENSYAIRM): OtavailableM EVA.ORATIZ RA4TE (BL TYLACETA TE - 7): Not available SECIFIC GRAW;TYORDENSY G/ML): Not available PA~N ITY (/GAL: 8.25 80,M41 PfOIN/AMNGE, _20O0 C, MELTING/FREEZING POINTI RANGE:, 'NotaYavAble`
'SOLUB1IT& A WATR_):Mi bl
ý,SOLIBIUiYiN S1LOLVENSOlL(SECIID : Noti a variable-
-MIN-IIMM 'IGNITION ENERGY
- .MINIMUM-EXPLOSION (MJ): :N, Not availableOlSXLSaaEIYA COCENTR4NWMEC)..I applicable Not available [71
,UM/TEDOXYGENCONCENTRATION (LOC): Not available SECTION 10. STABILiTY AND REACTIVITY STABIITY: Stable CONDmONS TO AVOID (STABILITY)
None. : ..
ji INCOMPATIBLE MATERIALS Surong oxidizing and strong reducing agents.
HAZARDOUS;DECOMPOSMON PRODUCTS '
Carbon monoxide
ý and carbon dioxide.
COND.ONS TO AVOID (POLYMERIZAOnOaI A void excessive heat and ignition.sources.
HAZARDOUS POLYMERIZATION: WMI not occur.
0104
Page: 5 of 8 Issue Date: 07/28/98 Supersedes: 02/14/96 NUSiYN-NOXFISb' FISH TOXICANT SECTION 11 ., TOXOCOLOGICAL UNFORMATION ACUTE STUDIES T U NG DA TA WERE DEVELOPED WITH: Nusyn-Noxth Rsh Toxdcant EYE EFFECTS (fabbt')Moderatfely irritaing SKINWEFFECTS, nRabit:. Moderately irritating, Irritation AbsorpoRAbbt): LD5O 5> 2020,.qmkg,(slighdy,toxic)
S*nim:io 7 (.G*e Pig):"non-sensitzng ACUTjE'ýbRAL-ýýEF-FEC-TS UOral 5b03cRatemaleJ: 147 mo/kg (moderatel toxic)
OraleL-D56h04i(Rat, ine) 70.4-mg'/g (isligohtlytoxic)
OralTLDS0 (Rait ovel: 561 mng/kg (slighyxic)
ACUTEJINHAL:ATON .EF*FECTS*.. ...... ,
- -four ;(Rat, temale): .:041.rag[(hi hly toxic) 4-Hour LC5O (Rat, male): .059 mg/I (moderately toxic) 4-Hour 'LC5#(Rat, o verall): .049 mg/ (highly toxic)
NOTE: .,Thsiveffty* classifications,listed above are those of AgrEvo, and, particularly fr Statements.,,
eye irritation,may not always coincide with EPA-mandated Precautidonary TwIFbIvvwjNGdbATA`.W`ERE DEVELOPED WITH: rotenone and pioeronyl butoxfde, Ck6f&Ki,6k (CKC NOMATION)
A Rotenone was not carcinogenic when testediin rats and mice.
A46statis*ily sgnificantincreasein the number apparilinmicfedbiero!fbuexide ofat technical benign doses*livhe whichtumors.
far exceed any *ancipate dilliman intake. Independent and indu~stry toxicologk'aI ekert ;h*=haV reviwe the data agree that the findings of the study do not inoit a hheilth riskto human beings.
CARCINOGENICiTY: NTP: No IARC: No OSHA:/ No TERATGE0 Cl (BIRTH. DEFECTS)
Rotenone .Was: not ,teratogenicortetotoxic when tested in rats and mice.
REPRODUCTIE ,EFFECTS Rotenone qqadno a&verse effects on reproductionwhen tested over two sqý4 ign rats.
M UTAGENICY, (GENETIC EFFECTS)
Hotenonone was,nort muqagenic noriclastogenic when tested in the Ames Test Ye.ast T*sr, Mouse Lm phoma Test, Mouse Micronucleus Test, Chromosome Aberraion Test andrthe Mitotic Recombination Test in Yeast.
SECTION 12. ECOLOGICAL INFORMATION ENVIRONMiENT4AL PRCA'TIONS:. This p cde srdx ely toc to fish.
Fish kils are expected at recommended rates.
Game*Agen*cy before pp lying this productto public* Consult your wters to State Fish and det.ermnin~e if a when disposing of equipment washwaters.
0105
Page: 6 of88-Issue Date: 07128/98
?NUSYN-NOXFISHY FISH TOXICAS e
- SECTION 13. DISPOSAL CONSIDERATIONS Do not dontaminate water, food or feed by disposal.
A< PeticdeQ Disposal: .Pesticide wastes, are acutely hazardous. Im~proper d-..po. of exs pe. spray mx or rnsate ia woaon of p b disposad of by use according to the F
federl law.If these astes cannot dlinitrtiypo contact your statepesticide or EnvironmentalControl i6jj Ag-e-ncy, or t Hfieazardous Waste representadveat the nearest EPA Regional Office for guidance.
CointaerD:isposal: Trple rinse;(orequivalent). Thenoffer,fr recycling or reco*r*ditrWning, or punctureand dispose of in a sianitry landfill, or by Sothep o~du approvedbystate and local authorties.
RCRA INFORMATION 7RCRA HAZARDOUS WASTE INGREDIENTS: None SECTION 14. TRANSPORT INFORMATION PROPER SHIPPING NAME: Pesticides;,lquid, xic, flammable, n.o.s.
(Rotenone, petroleum dist1late)
IHAZARD CLASS: 6.71, PGI SUBSIDIARY HAZARD CLASS: 3F DOT IDEN-IFICATION NUMBER.:" UN2903 DOTSHIPPINGLABEL: Poison and/or iToxic NOTE: For transportpurposes (49 CFR Part 173.132), the calculated 1-Hour LC50 (Rat, overall)is: 196 mg/I 1 SECTION, 15-. REGULATORY INFORMATION U.S. FEDERAL REGULATORY INFORMATION EPA Registration TSCA in- entorw Number:
registered4*32-5brJ pesticide, exempt from TSCA -[
SAR4 TITLE Ilt NOTIFRCA TION AND INFORMA TION SARAio in02rediants: None Sedon 304 (CERCLI & EHS) Noneingredients (RO): None 2, Section 313 ingredfirents.:
SARA.TITLE III NOTIFICATIONS AND INFORMATION, SARA TITLE III - HAZARD CLASSES: Acute Health Hazard - "Yes' Chronic Health Hazard- 'No Fire Hazard- 'Yes' Sudden:Release of PressureHazard 'No' Reai Hazard- "No' SARA TITLE III - SECTION 313 SUPPLIERNOTIFICATION This product contains the follovwng toxic chemicals subject to te reporting requirementsof section 313 of the,Emergency Planningand Community Right-To-Know Act (EPCRA/ of 1986 and ot,40 CFR372.
CAS NUMBER INGREDIENT NAME PERCENT BY WEIGHT 5 7-03-6 PiperonylButoxide, technical = 2..
This informationmust be included on alli MSDSs that are copied and distributedfor this material.
REGULATED INGREDIENTS f 0106 [
Page:7 of 8 Issue Date: 07/28/98 Supersedes: 02/14/96 NUSYN-NOXFISH 5 FISH TOXICANT SECTION 1-5. REGULATORYOiNFORRMAT-00M --Continued REGULATED INGREDIENTS - Continued iNGREDIENT-: Rotenone
'CA9SNUMBER: ,83-.79-4 PERCENT BY WEIGHT: = 2.5 Regulations: Illinois Toxic"Substuance passachuse*tts, azkkdous Substance NeU4RJ*rosn:, s" p ca1oealth Hazardous Substanle Newh, Jersey.sWooj;01a'ce Hazarxdous Substance Pexnsyvan&WoJ~phce'HaardusSubstance INGREIE lutoxai.e,
-rouciper tecbnida.... ,
CALIFORNA* (Propositionto65):
U.S.NSTATE REGULAI*TORY' Thisproduct does not contain any chemical INFORMATION wihis known to the State of California to cause. cance'rlor birth defects or other repiroductive harm.-
CANADlANý,REGUL-AýTORY INFORMATION CPO NUMBER: None WHMIS ýClaisification for Control Product Regulations [CPR): Registered pesticide under US FIFRA regulations;exempt from CPR classification.
The MSDS contains-allCPRA requiredhazard-elatedinformation.
WHMIS HAZARDSRATING:r See HMIS rating (Section ,16)
SECTION16~.~OTHERAWNFORMATION',
HMIS HAZARD RATING - HEAL TH: 3 High.
- .- 'FIRE: 2 Moderate REACTIVITY:..0 Negligible ,
PROTTION: H NFPA HAZARD RATING HE3LTH:
U 3 High
- FIRE: 2 Moderate REAC,7VITY: 0 Negligible.
- SPECIAL:
MSDS.IDENTIFICATION'CODEINUMBER: b467473 PREPARED, BY:, Regulatdj" PH0ME: (800)438-5837 SUPERCEDES MSDS DATED: 02/14/196 DATE AND TIME OF PRINTNG: 07/28/98 11:23:44 MSDS Revision Indiaors; Revisions 'made in Section 1 j(addedVtrademarks andproduct description), Seci 2 "addd*Ote ni'nt statement)
Setion -3 j(EMergnc Over'vi eto (hnqe Flsh Pint and Fire Fighting Proce*dres and, 'd*F.alabil-y'Class~fication/Rating), Section 7 (changed text.Undereach heqding), Secon 8,(chnged text under each skin~ ~ ~ ~ ~ ~ ~ ctaba irrtaio~ toieydaaydeeth
~ ~~~~e ninaai toxiciy data, chronic toxicity data, added where the data was developed from and what animal was used in he study), Section 12 (Environmental Precautions),Section 13 (DisposalConsiderations),Secton 14 (changedDOT 0107
Page:.8 of a 77 Issue Date: 07/28/98 Supersedes: 02/14/96 AruSYN-NOXFISHO FISH TOXICANT I SECTION 16. OTHER iNFORMATION -Continued j )* i added 7-Hour LC50) Section 15 (added Reyulatory bdf and arlg fand Secdon 16 (addedHMIS PNoteCton Code an Disclaimer).
ER-'
M lZ~i AND, D IMMPU'EDWARRhANTIES
-FEXRES
~j~hisp~rmat-ni pro wdeqd ini good faith but withovt exPress or implie wrrnty Bur asumes all responsibility for safetyand use not in accoaeith labeinstruios.
I i** ,
- ,*L PPI
~I 010
Eeflrgency Phone: 317.58-a General PhOI~u: 14031-540-&M8 PA R.Numbar. 6769-Effects Date: August 25, 1994 SONA-W SRF Heirbnkn'de SGPRO pownaumn o cane, ON T. INRDINS HAZARDOUSDECOMPOSITION PRODUCS: WIiN
(% uness w~ oherwse noed emit.t vaporsait+ums.
ý-HAZW 0 g YMRIATION: Does not.occur.
1-M-pheyl-5-(3-(rifuoromnethyl)phenyl)-
- 4,(1.-!pripme...(Fluridone)
ý-CAS# 05975660-...4 ........................... ....... 5/
O h r n d n ............................................ 95%
This docuMetisrprdpusatt thl 'OSHA ENVIRONMENTAL DATA: Follow use directions Hazar- idb Com,municat1 iontan 2 CR- carefullyso tadverse effects on nontar-1910.1200). In akdd ion'4, 'th~e'r" sub's't'an'ces 'not getornm INoORER TO AVOID IMPACT ON
- 'Ha rbdýous~hp l~SH-A'Stan ý diardmay be
- listed. THREATENED OR ENDANGERED AQUATIC PLANT Wheiea ingredient shows, the identity may OR ANIMALSPECIES,-- SERS MUSTCONSULT be mad _*i*a bad~l'as provi i this s ndard. THEIR STATE FiSH AWD GM E AGENCY OR THE U.S. FISH AND WILDMFE SERVICE BEFORE MAK-U .. ..... ......
3......... ING APPLICATIONS. Do not contaminate water by I B OILING POINTT::Not Hpliable cleaningof equipment or disposal of wastes. Trees and.shrUbs' growing in water treated with SONAR may be injured. Do not:apply in tidewater or brackish water.
yAP. DIENSITY:,Not a'pplical Do notaplyin lakes, ponds, or other bodies of water pE~
yAP.~~~ plcable. where crayfish farming is performed.
USP. SOL6IN WATR: Insolule, but disintegrates in water GRAV ITY: Not applical ACTION TO TAKE FOR.SPILLS: Contain and sweep
-PMtia.lof 6 sills am dispose as waste. Large I ~~D ODOR Fint mut6dor
-. (Aqueous,50/50) 3.5 D ,NC gray to dark brown pellet spls' rOit 0 'CHEMTREC and SePRO Corporation fo assistance. Prevent runoff.
DISPOSAL METHOD: Do not contaminate water, food or feedbY trage ordisposal*. Wastes resulting from the useofthis pru may be disposed of at an
',,4
,a-F*+*.;*,.*.'
poia i, , approvedwaste.disposal facility in accordance with applicable regulations.
METHOD USED:Not applicable.
I FLAMMABLE LIMITS:
LFL*.: Not,applicable. ACUTE EXPOSURE (SONAR SRP)
UFL:ý Not applicable Eyes - Rabbit, irritant AUTO-IGNMON TEMPERATURE: No ignition up to Skin - Rabbit, 2000 mg/kg, no deaths. or toxicity, nonir-ritant 4.
Inhtalation - This formulation is not considered to be an EXTINGUISHING MEDIA: Use water, C02 or dry inhalation hazard due to pelleted nature of material 2 Cem'Is Ingestion - Rat, 500 mg/kg, no deaths or toxicity FIRE AND EXPLOSION HAZARDS: Will emit toxic Sensitization - This formulation was not tested.
vali- 0bum-s., Fluridrne technical is not a conta.ct sensitizer in guinea FIRE-FIGHTING EQUIPMENT: Wear full protective pigs.
cloting and use self-contained breathing apparatus. CHRONIC EXPOSURE (Fluddone Technical) The fol-lowing effects were reported in chronic, teratogenic, and reprbrduiv toxicity studies in laboratory animals U-STABIL : +(CONDITIONSTO AVOID) None known INCOMPATBiLTY: (SPECIFIC MATERIALS TO where expermental dosage levels and durations of exposure *ere far in excess of those likely to occur in humans.
SAVOiD) None noiwn Chronic Toxicity - Decreased survival in lifetime feed-ing study. Incr.ased liver enzyme actvity, liver weight, liver cell size, and microscopic Olver cell changes.
'rTademarkof SePRO CoGaormion 010
I Et~g~
GenrlP
.4'
",=~a r1000
-I EPA Reg. Number.6 M Effcf Date: August 25, ION94 I Mý.-S,..RP .. rbicide .SPRO Corolration CaMi, ON e-as kidney weights, and microscopic kddney cell SKIN PROTECTION: No precautions other than nor-I ig*e*tncreaed-serum enzyme leVels.
l &Rptoduction -Not teratogenic. Fetal mal work clothing should be needed.
EVE PAOTECTION: Use safety gkaes.
I hsa4t aterma y toxic doses. No effects on repro-Not mutagenic in either bacterial or. F-7ADITIO £ IFRATIN I
ge ipity.- Not listed as a'carcinogen or poten- SPECIAL PRECAUTONS TOi BE TAKEN IN HAN-n~o~ge1ry [ARa, NCNTP -WOSHA, or.ACGIH. -DUNGAND STORAGE: Keep out of reach of chil-
- sideredto be* carcinoge~nic ini lifetimre feeding I
+if:inhale: Avoid,dre.~a~fl~fswaloedabsrbd b~atingi o ldut 'or cotc skn, or trogh withsln, I eyes, or cldoing. Wash thoroughwitsp ts of chilre swimn mng in water treated with.
water'aft0eChadling. Wh e reuse.
tIoNAL FIRE PROTTION ASSOCIAdlON (NFPA 704) cl!oting'b*d le6fore I
,hnoEsymptoNs developed. (4=Extreme;. 2Mdert`
I=ih 1
rS'fght O6lnslgniflcanit) 4Y RU'TES6 OF ENTRY:. Sinr and inhalation.
SHIPPING REGUIREMENTS DOT Hazard Class:
I 7A.. . AID PIilet o~fwater an cal a MSDSlSTATUS:,Revised 1/92,
- AR INFORATION "ection
.8 I
ar'easwith plenty of soap and itiiated loti before reuse.
NOTICE: The mnod4ith aid
_"fominidhnhbre"n p!r I lie; adriminsracti- However,1no waranyexress or!peis given.~keplatory oai (-8 heapi-n1easpoonfuls) with a large w"ter.., Do notLgW anything by mouth to an rt qu sbjec to change and may differ from one Ioca-tion to anrhe; it is the bU comly wit feerl activites responsibilty to ensurehatis tteo ervnas, a"n fa laws.
I is n. tt a med- Theqg~c~f6~niiaton ismade Pr~h urpose 0f corn N !f.fdisq.mf rt.qcqurs, breathngd i.'Mdua! to
.ove yocc, get medical SARA HAZARD CATEGORY; Ts producthas, been I
not breathing, provide cardiopulmonary reviewed according to the EPA .6H ries"
,nassistance and get medical attention promulgated underiSections,31 a 3:1i2 ofthe Superiund Amedfmientand Reauhrizain 1986(SARA T'te Il1) and is considered, under applica-of I
'!EDICAL CONDITIONS GENERALLY AGGRAVAT-ble definitions, to meet the following categories:
JED Y EXOSURE: No information available.
An immediate health hazard I F8 A-,
HADIG RCUTOS EEXPOSURE GUIDELINE(S): PEL and TLV not estab- I VENTILATION:Good 1general ventilation should be sffcient for most onditions.
RESPIRATORY PROTECTION: No respiratory protec-tion should be needed when used in accordance with I
label instructions. The infornmaion Hern Is Given In Gqd, Faith, ButkNo Warrat, Express Or Implied, Is Made.
Consult SePRO Corporation For Further Informawon. I 2.
0110 Form No. A-73-MC-02(01) I
87/12/2000 22:21 5707081043 JOE CLARK S40A04/ 122/
- PAGE PfA.E 10 BETZDEARBORN MATERIAL, SAFETY DATA SHEET SBetzDearborn -
EFFECTIVE DATE: 03-MAY-2000 PRINTED DATE: 12-JUL-2000
- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : SPECTRUS CT1300 PRODUCT APPLICATION AREA: WATER-BASED MICROBIAL CONTROL AGENT.
COMPANY ADDRESS:
BetzDearborn Inc.
4636 Somerton Road, Trevose, PA 19053 Information phone number: 215 355-3300 EMERGENCY TELEPHONE (HEALTHIACCIDENT): (800)477-1940 (USA)
- 2) COMPOSITION I INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME 68424-85-1 (C12-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE Corrosive (eyes and skin);toxic (by ingestion) 64-17-5 ETHYL ALCOHOL (ETHAANOL)
Flammable liquid; irritant (eyes); potential liver and kidney toxin; may cause CNS depression No component is considered to be a carcinogen by the National Toxicology Prgram the International Agency for Research on Cancer, or the Oc.upational Safety and HeAlth Administration at OSHA thresholds for carcinogens.
PAGE 1 CONTINUED 0111
07/12/2000 22:21 5707081048 JOE CLARK PAGE 11 5 PRODUCT NAME : SPECTRUS CT1300 EFFECTIVE DATE: i3=9Y
- 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER I Severe irritant to the skin. Potential skin sensitizer. Corrosive to the eyes. Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract.
DOT hazard: Combustible liquid Emergency Response Guide #27 i Odor: Mild; Appearance: Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full facem-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water U
POTENTIAL HEALTH EFFECTS S ACUTE SKIN EFFECTS:
Primary route of exposure; Severe irritant to the skin. Potential skin sensitizer.
ACUTE EYE EFFECTS:
Corrosive to the eyes.
ACUTE RESPIRATORY EFFECTS:
Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract.
3 INGESTION EFFECTS:
Toxic; I May cause severe irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses.
TARGET ORGANS:
Prolonged or repeated exposures may cause CNS depression, skin sensitization, and/or toxicity to the liver and kidney.
MEDICAL CONDITIONS AGGRAVATED:
Not known. 5 SYMPTOMS OF EXPOSURE:
Inhalation of vapors/mists/aerosols may cause eye, nose, throat and lung irritation. Skin contact may cause severe irrtation or bums.
PAGE 2 CONTINUED 0112_)
07/12/2000 22:21 5707081048 JOE CLARK PAGE 12 PRODUCT NAME : SPECTRUS CT1 300 EFFECTIVE DATE: 03-MAY-2000
- 4) FIRST AID MEASURES SKIN CONTACT:
Remove clothing. Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician.
EYE CONTACT:
Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area. Apply necessary first aid treatment Immediately contact a physician.
INGESTnON:
Donhot feed anything by mouth to an unconscious or convulsive vicAim. Dilutec*ontens of stomach. Induce vomiting by one of the
..sta*dardme.thqds9. Immediately contact a physician.
NOTES TO PHYSICIANS:4 Nospcial inbtru tions
- 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry ch"emicalIcarbon dioxide, foam or water HAZARDOUS DECOMPOSmON PRODUCTS:
T*hral decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
130F 540 P-M(CC)
MISCELLANEOUS:
Combustible liquid NA1993;Emergency Response Guide #27 I 6) ACCIDENTAL RELEASE MEASURES PROTECTION' AND SPILL CONTAINMENT:
ventiate "ae. Use specified protc "iV equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Remove ignition sources. Flush area with water. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer I treatment facilityin accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Dispose of in approved pesticide facility or according to label instructions.
I i PAGE 3 CONTINUED o
0113 I
07/12/2000 22:21 5707081048 JOE CLARK PAGE 13 PRODUCT NAME : SPECTRUS CT1300 EFFECTIVE DATE: 034MAY-2000
- 7) HANDLING AND STORAGE HANDUNG: !
Combustible. Do not use around sparks or flames. Bond containers during filling or discharge when performed at temperatures at or above the product flash point.
STORAGE:
Keep containers closed when not in use. Reasonable and safe I
chemical storage. Protect from freezing.
- 8) EXPOSURE CONTROLSIPERSONAL PROTECTION CHEMICAL NAMEC EXPOSURE LIMITS I (C12-16)ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE PEL (OSHA): NOT-DETERMINED I
TLV (ACGIH): NOT DETERMINED I ETHYL ALCOHOL (ETHANOL)
PEL (OSHA). 1,000 PPM TLV (ACGIH): 1,000 PPM I ENGINEERING CONTROLS:
I Adequate ventilation to maintain air contaminants below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA!S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER I WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE-USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
tfespirator ir-purifyinn respirator appropriate, use a utseiscartridges I
organicr vapor and dust/mist prefilters.
SKINPROTECTION:
neoprene gloves-- Wash off after each use. Replace as I
necessary.
EYE PROTECTION:
splash proof chemical goggles I
PAGE 4 CONTINUED I 0114
07/12/2000 22:21 5707081048 JOE CLARK PAGE 14 PRODUCT NAME : SPECTRUS EFFECTIVE DATE: 03-MAY-2000CT1300 E 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav.(70F,21C) 0.965 Vapori Pressure (mmHG) 44.0 Freeze Point (F) -7 Vapor Density (air1l) < 1.00 Freeze Point (C) -22 Viscosity(cps 70F,21C) 73 % Solubility (water) 100.0 Odor Mild Appearance Colorless To Yellow Physical State Liquid Flash Point P-M(CC) 130F 54C pH As Is (approx.) 8.9 Evaporation Rate (Etherl) < 1.00 NA w not applicable ND - not determined
- 10) STABILITY AND REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBIUTIES:
I May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Ther'ialdecomposition (destructive fires) yields elemental oxides.
BETZDEARBORN INTERNAL PUMPOUTICLEANOUT CATEGORIES:
I ll) TOXICOLOGICAL INFORMATION Oral LD50 RAT: 445 mg/kg Dermal LD50 RABBIT: >1,800 mg/kg Skin Sensitization G.PIG: NEGATIVE NOTE - Active component was neither a photoallergen nor a skin sensitizer PAGE 5 CONTINUED U
I 0115
07,/12/2000 22:21 5707081048 JOE CLARK PAGE 15 PRODUCT NAME : SPECTRUS CTI 300 EFFECTIVE DATE: 03-MAY-2000
- 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY I Fathead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50' .72 mg/L No Effect Level, .41 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: .04 mg/L No Effect Level: .026 mg/L Rainbow Trout 96 Hour Flow-Thru Bioassay Test concentrations were analytically venrfied. I LC50: 2 mg/L No Effect Level: 1.2 mg/L 3 Mysid Shrimp 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
LC50: .16 mg/L No Effect Level: .03 mg/L Sheepshead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.
I LC50: 1.76 mg/L No Effect Level: 1 mg/L Menidia beryllina (Silversides) 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified. .
LC50: .62 mg/L No Effect Level: .35 mg/L Ceriodaphnia 48 Hour Static Renewal Bioassay LC50: .35 mg/L No Effect Level: .15 mglL BIODEGRADATION COD (mg/gm): 1470 TOC (mg/gm) 380 BOD-5 (mg/gm): 43 BOD-28 (mg/gm). 156 1 PAGE 6 CONTINUED 01116
07/12/2000 22:21 5707081048 JOE CLARK PAGE 16 PRODUCT NAME : SPECTRUS CT1300 EFFECTIVE DATE: 03-MAY-2000
- 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is:
DO01=ignitable.
Please.be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
- 14) TRANSPORT INFORMATION DOT HAZARD: Combustible liquid UN/ NA NUmBER: NA1993 DOT EMERGENCY RESPONSE GUIDE #: 27
- 16) REGULATORY INFORMATION TSCA:
This is an EPA registered biocide and is exempt from TSCA inventory requirements.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated Constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER:
3876- 149 '
POTABLE WATER APPROVAL:
NSF Certified maximum use for disinfection and oxidation 3_5mg/L. Maximum use for reverse osmosis and distillation 10 rag/L.
FOOD AND DRUG ADMINISTRATION:
- 21. CFR 176.300 (slimicides for wet end use)
When used in this specified application, all ingredients comprising thisprod-uct are atthorized by FDA for the manufacture of paper and paperbgardOthat may contact aqueous and fatty foo"ds"a' per'21 CFR 176.170(a)(4).
USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS:
SEC.G5"G7"'
SARA, SECTION 312 HAZARD CLASS:
Immediate(acute),;Delayed(Chronic);Fire SARA SECTION- 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 3113 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds PAGE 7 CONTINUED 0117
07/12/2000 22:21 570708104G JOE CLARK PAGE 17 PRODUCT NAME : SPECTRUS CTI300 I
EFFECTIVE DATE: 03-MAYo2000 MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds I
- 16) OTHER INFORMATION I NFPAIHMIS CODE TRANSLATION Health Fire 3
2 Serious Hazard Moderate Hazard I
Reactivity 0 Minimal Hazard Special (1) Protective Equipment NONE B
No special Hazard Goggles, Gloves I
(1) refer to section 8 of MSDS for additional protective equipment recommendations. I CHANGE LOG I EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 18-NOV-1997 ** NEW ** I 27-FEB-1998 15 18-NOV-1997 15-MAY-1998 2 27-FEB-1998 20-MAY-1998 11 15-MAY-1998 17-AUG-1998 15 20-MAY-1998 27-OCT-1998 12-NOV-1998 03-MAY-2000
- EDIT
- 9
- EDIT
- 9 12 17-AUG-1998 27-OCT-1998 12-NOV-1998 I
I I
I PAGE B I
0118
07/12/2000 22:21 5707081048 JOE CLARK 2 -7 ) PAGE 03 4
BETZEARBORN MATEIIRAL SAFETY DATA SHEET EFFECTIVE DATE: 28-JUL-1997 PRINTED DATE: 12-JUL-2000
- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : SPECTRUS DT1400 PRODUCT APPLICATION AREA: A DETOXIFYING AGENT COMPANY ADDRESS:
BetzDearbom Inc.
4636 Somerton Road, Trevose PA 19053 Information phone number: 215 355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA)
- 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME 14464-46-1 RESPIRABLE CRISTOBALITE (CRYSTALLINE SILICA)
Irritant (respiratory); probable human carcinogen (IARC-2A; NTP~anticipated); may cause long term lung disease (silicosis) 14808-60-7 RESPIRABLE QUARTZ (CRYSTALLINE SILICA)
Irritant (respiratory); probable human carcinogen (IARC-2A; NTP-anticipated); may cause long term lung disease (silicosis) 15468-32-3 RESPIRABLE TRIDYMITE (CRYSTALLINE SILICA)
Irritant (respiratory); probable human carcinogen (IARC-2A; NTP-anticipated); may cause long term lung disease (silicosis)
PAGE I CONTINUED 0119
07/12/2008 22:21 5707081048 JOE CLARK PAGE 04 PRODUCT NAME : SPECTRUS DT1400 EFFECTIVE DATE: 28-JUL-I 7
- 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION 3 May cause slight irritation to the skin. May cause moderate irritation to the eyes. Mists/aerosols may cause irritation to upper respiratory tract. 3 DOT hazard is not applicable Emergency Response Guide is not applicable Odor Slight; Appearance: Green-Bromn, Dispersion Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS3 ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
ACUTE EYE EFFECTS:
May cause moderate irritation to the eyes-ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause gastrointestinal irritation with possible nausea, vomiting, headache, dizziness, unconsciousness and injury to the kidneys and liver, Small amounts aspirated during ingestion/vomiting may cause lung injury, possibly death, TARGET ORGANS:
and/or Prolongedkidney-or repeated exposures may cause toxicity to the liver MEDICAL CONDITIONS AGGRAVATED:
Not known. I SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
l PAGE 2 CONTINUED 3 0o-20
07/12/2@00 22:21 5707081048 JOE CLARK PAGE 05 PAODUCT NAME : SPECTRUS OT1400 EFFECTIVE DATE: 28-JUL-1997
- 4) FIRST AID MEASURES SKIN CONTACT:
Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT:
Imrnediately flush eyes with water for 15 minutes. Immediately contaq oa-pysician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do hot feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
- 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA dry clheical, carbon dioxide, foam or water HACZRDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH PWINT:
> 200F > 93C P-M(CC)
- 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility in accordance with any local agreement, a permitted waste treatment facility or discharged under a permit. Product as is?- Incinerate or land dispose in an approved landfill.
I 7) HANDLING AND STORAGE HANDUNG:
Normal chemical handling.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.
I U PAGE 3 CONTINUED 0
3 0121
07/12/2000 22:21 5707081048 JOE CLARK PAGE 06 3 PRODUCT NAME : SPECTRUS DT1400 EFFECTIVE DATE: 28-JUL-197
- 8) EXPOSURE CONTROLS/PERSONAL PROTECTION CHEMICAL NAME EXPOSURE LIMITS I RESPIRABLE CRISTOBALITE (CRYSTALLINE SILICA) I PEL (OSHA): 0.05 MG/M3 TLV (ACGIH): 0.05 MG/M3 3 RESPIRABLE QUARTZ (CRYSTALLINE SILICA)
PEL (OSHA)- 0.1 MG/M3 TLV (ACGIH): 0.1 MG/M3 RESPIRABLE TRIDYMITE (CRYSTALLINE SILICA)
PEL (OSHA) 0.05 MG/M3 TLV (ACGIH). 005 MG/M3 ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure Il.imits. 3 PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 191,0.134-AND ANSI Z88_2 REQUIREMENTS MUST BE FOLLOWED WHENEVER I WORKPLACE. CONDITIONS WARRANT A RESPIRATORS *USE USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
rubber gloves- Wash off after each use. Replace as I
necessary.
EYE PROTECTION:
splash proof chemical goggles
- 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Gray. (70F,21C) 1.186 Vapor Pressure (mmHG) ~ 18.0 Freeze Point (F) 32 Vapor Density (air-1) < 1.00 Freeze Point (C) 0 Viscosity(cps'70F,21C) 2900 % Solubility (water) 0.0 Odor Slight Appearance Green-Brown Physical State Dispersion Flash Point P-M(CC) > 200F > 93C pH As Is (approx.) 7.0 Evaporation Rate (Ether=l) < 1.00 NA - not applicable NO - not determined PAGE 4 CONTINUED 0122,
07/12/2000 22:21 5787081048 JOE CLARK PAGE 07 PRODUCT NAME : SPECTRUS DT1400 EFFECTIVE DATE: 28-JUL-1997
- 10) STABILITY AND REACTMITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Wil. nodt ocqur.
INCOMPATiBILUTIES:
Ma", .re4dMth .strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZDEARBORN INTENAL PUMPOUTICLEANOUT CATEGORIES:
- 11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: >2,000 mg/kg NOTE - Estimated value Dermal LD50 RABBIT: >2,000 mg/kg NOTE - Estimated value
- 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Screen 0% Mortality: 435 mg/L Daphnia magna 48 Hour Static Screen 0% Mortality: 435 mg/L BIODEGRADATION COD (mg/gm): 64 Calculated TOC (rg/ggm): 26 Calculated BOD-5 (mg/gm): 0 Calculated BOD-28 (mg/gm): 2 Calculated
- 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is:
Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
PAGE 5 CONTINUED U
U 0123
07/12/2080 22:21 5787081048 PRODUCT NAME :SPECTRUS DTI400 JOE CLARK PAGE 08 U
EFFECTIVE DATE: 28*-JUL-1997
- 14) TRANSPORT INFORMATION DOT HAZARD:
UN / NA NUMBER:
Not Applicable Not applicable U
DOT EMERGENCY RESPONSE GUIDE 0: Not applicable U
- 15) REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
U CERCLA ANDIOR SARA REPORTABLE QUANTITY (RQ):
Treat as oil spill.
SARA SECTION 3t2 HAZARD CLASS:
D0le Cy Chronic)
SARA SECTON 302CHEMICALS;
. No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION I
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 66) CHEMICALS PRESENT:
I This product contains these chemicals known to the state of California to cause cancer or reproductive toxicity:
CAS#
14464-46-1 CHEMICAL NAME I RESPIRABLE CRISTOBALITE (CRYSTALLINE 14808-60-7 15468-32-3 SILICA)
RESPIRABLE QUARTZ (CRYSTALLINE SILICA)
RESPIRABLE TRIDYMITE (CRYSTALLINE SILICA)
I MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds I
I U
U U
PAGE 6 CONTINUED I
0124
07/12/2000 22:21 5707081048 JOE CLARK PAGE 09
, t .,
PRODUCT NAME : SPECTRUS DT1400 EFFECTIVE DATE; 28-JUL-1997
- 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health i Slight Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard special NONE No special Hazard (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES
-i--NEW-*-
MSDS status: 28-JUL-1997 ** NEW **
U PAGE 7 U
0125 U
I GE Water & Process Technologies Material Safety Data Sheet Issue Date: 10-DEC-2007 Supercedes: 15-MAR-2007 I
DEPOSITROL BL5400 I 1 Identification of Product and Company I Identification of substance or preparation DEPOSITROL BL5400 Product Application Area I
Water-based deposit control agent.
Company/Undertaking Identification GE Betz, Inc.
I 4636 Somerton Road Trevose, PA 19053 T 215 355-3300, F 215 953 5524 Emergency Telephone I
(800) 877-1940 Prepared by Product Stewardship Group: 215 355-3300 I
2 Composition / Information On Ingredients I
Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
I HAZARDOUS INGREDIENTS:
Cas# Chemical Name Range(w/w%)
I 2809-21-4 PHOSPHONIC ACID, (l-HYDROXYETHYLIDINE)BIS-Corrosive (eyes)
(HEDP) 40-70 I
10294-56-1 PHOSPHOROUS ACID (PHOSPHONIC ACID)
I 1-5 Corrosive 3 Hazards Identification I
DANGER EMERGENCY OVERVIEW I
May cause moderate irritation to the skin. Corrosive to the eyes.
Inhalation of vapor or mist may cause severe nose, throat, and respiratory tract irritation.
1 Substance or Preparation: DEPOSITROL BL5400 Page 1 0126 I
DOT hazard: Corrosive to steel Odor: Mild; Appearance: Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper firerextinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause moderate&irritation to the skin.
ACUTE EYE EFFECTS:
Corrosive to the eyes.
ACUTE RESPIRATORY EFFECTS:
Inhalation of vapor or mist may cause severe nose, throat, and respiratory tract irritation.
INGESTION EFFECTS:
May cause severe irritation or burning of the gastrointestinal tract.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin, irritation, and/or tearing of eyes (direct contact).
4 First Aid Measures SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Thoroughly wash clothing before reuse. Get medical attention if irritation develops or persists.
EYE CONTACT:
URGENT! Immediately flush eyes with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 2-6 fluid ounces (60-240 mL) of milk or water.
NOTES TO PHYSICIANS:
Material is corrosive. It may not be advisable to induce vomiting.
Possible mucosal damage may contraindicate the use of gastric lavage.
5 Fire Fighting Measures Substance or Preparation: DEPOSITROL BL5400 Page 2 0127
I FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
oxides of carbon and phosphorus FLASH POINT:
> 200F > 93C SETA(CC)
MISCELLANEOUS:
Corrosive to steel UN 3265;Emergency Response Guide #153 6 Accidental Release Measures PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and I
absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
7 Handling & Storage I HANDLING:
Acidic. Corrosive(Eyes). Do not mix with alkaline material.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.
8 Exposure Controls / Personal Protection EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID, (l-HYDROXYETHYLIDINE)BIS- (HEDP) I PEL (OSHA) : NOT DETERMINED TLV (ACGIH) : NOT DETERMINED PHOSPHOROUS ACID (PHOSPHONIC ACID)
TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:
adequate ventilation i
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR I
1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED I I
WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
Substance or Preparation: DEPOSITROL BL5400 Page 3 1288
If air-purifying respirator use is appropriate, use any of the following particulate respirators: N95, N99, N100, R95, R99, RI00, P95, P99 or P100.
SKIN PROTECTION:
rubber, butyl or neoprene gloves -- Wash off after each use.
Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 Physical & Chemical Properties Specific Grav.(70F,21C) 1.453 Vapor Pressure (mmHG) - 18.0 Freeze Point (F) < -30 Vapor Density (air=l) < 1.00 Freeze Point (C) < -34 Viscosity(cps 70F,21C) 85 % Solubility (water) 100.0 Odor Mild Appearance Colorless To Yellow Physical State Liquid Flash Point SETA(CC) > 200F > 93C pH As Is (approx.) < 1.0 Evaporation Rate (Ether=l) < 1.00 Percent VOC: 0.0 NA = not applicable ND = not determined 10 Stability & Reactivity STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
oxides of carbon and phosphorus INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 Toxicological Information Oral LD50 RAT: 2,000 mg/kg NOTE - RAT LD50: 2,400 mg/kg per alternate source Dermal LD50 RABBIT: >7,940 mg/kg NOTE - RABBIT LD50: 10,000 MG/KG ALTERNATE SOURCE Skin Irritation Score RABBIT: 0 Eye Irritation Score RABBIT: CORROSIVE 90 Day Feed Study RAT: NOEL:10,000 ppm NOTE - Hemopoeitic effects at 30,000 ppm 90 Day Feed Study DOG: .062-1%
NOTE - 2 year-feed study. Reversible anemia developed at 1% in diet.
90 Day Feed Study DOG: 20-60 mg/kg NOTE day study. No pathological effects.
Ames Assay BACTERIA: NEGATIVE Substance or Preparation: DEPOSITROL BL5400 Page 4 0129
I NOTE - +/- metabolic activation Non-Ames Mutagenicity : NEGATIVE NOTE - Mouse Lymphoma Assay +/- metabolic activation -I 12 Ecological Information I AQUATIC TOXICOLOGY Bluegill Sunfish 96 Hour Static Acute Bioassay I
LC50= 1440; No Effect Level= 880 mg/L Ceriodaphnia 48 Hour Static Renewal Bioassay (pH adjusted)
No Effect Level= 31.3; LC50= 113 mg/L Daphnia magna 48 Hour Static Renewal Bioassay (pH adjusted)
I LC50= 755; No Effect Level= 420 mg/L Fathead Minnow 96 Hour Static Renewal Bioassay (pH adjusted)
LC50= 3040; No Effect Level= 1370 mg/L Grass Shrimp (Palaemonetes pugio) 96 Hour Static Acute Bioassay I
LC50= 2675 mg/L Midge larvae (Chironomus tentans) 48 Hour Static Acute Bioassay LC50= 14850 mg/L Mysid Shrimp 48 Hour Static Renewal Bioassay (pH adjusted)
I LC50= 319 mg/L Rainbow Trout 96 Hour Static Acute Bioassay LC50= 610; No Effect Level= 250 mg/L Selenastrum (algae) 14 Day Growth Inhibition I
EC50= 39 mg/L Selenastrum (algae) 96 Hour Growth Inhibition EC50= 3 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay I
LC50= 3630; No Effect Level= 170 mg/L BIODEGRADATION BOD-28 (mg/g) : 1 i
BOD-5 (mg/g): 1 COD (mg/g):
TOC (mg/g):
300 70 I 13 Disposal Considerations I
If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is D002=Corrosive(pH, steel). I Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
I 14 Transport Information I DOT HAZARD:
PROPER SHIPPING NAME:
Corrosive to steel CORROSIVE LIQUID, ACIDIC, ORGANIC, I
N.O.S.(ORGANIC PHOSPHONIC ACID)
DOT EMERGENCY RESPONSE GUIDE #: 153 8, UN 3265, PG III Note: Some containers may be DOT exempt, please check BOL for I
exact container classification I
Substance or Preparation: DEPOSITROL BL5400 Page 5 0130 I
15 Regulatory Information TSCA:
All components of this product are included on or are in compliance with the U.S. TSCA regulations.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS:
Immediate(acute)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
No regulated constituents present MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 Other Information NFPA/HMIS CODE TRANSLATION Health 3 Serious Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special CORR DOT corrosive (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 28-JAN-1997 ** NEW **
23-JUN-1997 28-JAN-1997 03-MAY-2000 12 23-JUN-1997 27-SEP-2000 4,11 03-MAY-2000 30-MAY-2001 2,8,11 27-SEP-2000 31-MAY-2001 15 30-MAY-2001 02-AUG-2001 12 31-MAY-2001 23-AUG-2001 4, 12 02-AUG-2001 09-JUL-2002 12 23-AUG-2001 19-DEC-2006 2,5,7, 10 09-JUL-2002 15-MAR-2007 8 19-DEC-2006 10-DEC-2007 4,8 15-MAR-2007 Substance or Preparation: DEPOSITROL BL5400 Page 6 0331
SAFETY DATA SHEET PRODUCT
~NALCU NALCO 7408 I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
I 1. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: NALCO@7408 caq~aCA (o I
I APPLICATION: CHLORINE SCAVENGER I COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois I
60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC I.
NFPA 704M/HMIS RATING HEALTH: 1/2 FLAMMABILITY: 0/0 INSTABILITY:
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme *=
0/0 OTHER:
Chronic Health Hazard I
- 12. I COMPOSITION/INFORMATION ON INGREDIENTS I Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
I Sodium Bisulfite Hazardous Substance(s) CAS NO 7631-90-5
% (wlw) 30.0- 60.0 .I
- 13. IHAZARDS IDENTIFICATION I
- EMERGENCY OVERVIEW**
I WARNING Harmful if swallowed. Contains Sulfite. Causes asthmatic signs and symptoms in hyper-reactive individuals.
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact with I
eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Protect product from freezing.
Wear suitable protective clothing.
I May evolve oxides of sulfur (SOx) under fire conditions.
PRIMARY ROUTES OF EXPOSURE:"
Skin, Eye, Inhalation I
HUMAN HEALTH HAZARDS- ACUTE: I EYE CONTACT:
Can cause mild irritation.
SKIN CONTACT:
I Can cause mild irritation.
Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198-- (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 1/12 0132 I
SAFETY DATA SHEET PRODUCT
'WNALC NALCO 7408 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC INGESTION:
Not a likely route of exposure. May cause asthmatic-like attack.
INHALATION:
Irritant to respiratory system. Causes asthmatic signs and symptoms in hyper-reactive individuals.
SYMPTOMS OF EXPOSURE:
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic:
A review of available data does not.identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
HUMAN HEALTH HAZARDS - CHRONIC:
Ingestion of sulfite can cause a severe allergic reaction in asthmatics and some sulfite sensitive individuals. The.
resulting symptoms can include difficulty in breathing, flushed skin and a rash. Chronic exposure to sulfites may cause symptoms of upper respiratory disease and affect sense of taste and smell.
- 14. 1 FIRST AID MEASURES EYE CONTACT:
Get immediate medical attention. Immediately flush eye with water for at least 15 minutes while holding eyelids open.
If irritation persists, repeat flushing.
SKIN CONTACT:
Immediately flush with plenty of water for at least 15 minutes. If symptoms persist, call a physician..-
INGESTION:
Induce vomiting if the patient is fully conscious. If conscious, washout mouth and give water to drink. Get medical attention.
INHALATION:
Get medical attention. Remove to fresh air, treat symptomatically. If breathing is difficult, administer oxygen.
NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
- 15. 1FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA:
This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Keep containers cool by spraying with water. Use extinguishing media appropriate for surrounding fire.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/12
.0133
SAFETY DATA SHEET I 4NALC PRODUCT NALCO 7408 I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC FIRE AND EXPLOSION HAZARD: I May evolve oxides of sulfur (SOx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
- 16. 1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
I Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ensure adequate ventilation. Do not touch spilled material. Stop or reduce any leaks if it is I
safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP:
I SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with I
water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
I Do not contaminate surface water.
- 17. IHANDLING AND STORAGE I HANDLING:
Avoid eye and skin contact. Do not take internally. Do not get in eyes, on skin, on clothing. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Keep the containers closed I
when not in use. Use with adequate ventilation.
STORAGE CONDITIONS:
I Protect product from freezing. Store the containers tightly closed. Store separately from acids. Store in suitable labeled containers. Amine and sulphite products should not be stored within close proximity or resulting vapors may form visible airborne particles. I SUITABLE CONSTRUCTION MATERIAL:
HDPE (high density polyethylene), Brass, Neoprene, Polyurethane, Viton, Hypalon, EPDM, Polypropylene, Polyethylene, PVC, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested I prior to use.
UNSUITABLE CONSTRUCTION MATERIAL:
Stainless Steel 304, Buna-N, Epoxy phenolic resin, 100% phenolic resin liner I
I Nalco Company 1601 W. Diehl Road ° Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 3/12 0134 I
SAFETY DATA SHEET PRODUCT NALCO NALCO 7408 U _ _________ I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Exposure limits are listed for sulfur dioxide (S02) since this product evolves S02 when open to the atmosphere.
Country/Source Substance(s) Category: ppm mg/m3 Sodium Bisulfite ACGIH/TWA 5 Sulfur Dioxide ACGIH/STEL 0.25 OSHA ZI/PEL 5 13 ENGINEERING MEASURES:
General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are generated.
RESPIRATORY PROTECTION:
If significant mists, vapors or aerosols are generated an approved respirator is recommended. An approved respirator-must be worn if the occupational exposure limit is likely to be exceeded.
HAND PROTECTION:
Neoprene gloves Nitrile gloves Butyl gloves PVC gloves SKIN PROTECTION:
Wear standard protective clothing.
EYE PROTECTION:
Wear chemical splash goggles.
HYGIENE RECOMMENDATIONS:
If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before 'reuse. Keep an eye wash fountain available. Keep a safety shower available.
HUMAN EXPOSURE CHARACTERIZATION:.
Based on our recommended product application and personal protective equipment, the potential human exposure is:
Low
- 19. 1PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Yellow ODOR Pungent SPECIFIC GRAVITY 1.37 @ 77 -F /25 °C DENSITY 11.4 lb/gal BULK DENSITY 11.4 Ib/ft3 Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/12 O '35
SAFETY DATA SHEET I
)'4NALC0 PRODUCT I
NALCO 7408 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
SOLUBILITY IN WATER pH (1 %)
Complete 4.1 I
VISCOSITY 2.8 cps @ 77 'F / 25 0C FREEZING POINT BOILING POINT VAPOR PRESSURE 34 *F / 1.1 'C 219 *F / 104 °C 32 mm Hg @ 77 'F / 25 'C 76 mm Hg @ 99.9 'F / 37.7 'C I
VAPOR DENSITY VOC CONTENT 2.2 (Air = 1) 0.00 % EPA Method 24 I Note: These physical properties are typical values for this product and are subject to change.
- 10. STABILITY AND REACTIVITY I STABILITY:
Stable under normal conditions. I HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
I CONDITIONS TO AVOID:
Freezing temperatures.
MATERIALS TO AVOID:
I Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors. S02 may react with vapors from neutralizing amines and may produce a visible cloud of amine salt particles.
I HAZARDOUS DECOMPOSITION PRODUCTS:
Under fire conditions: Oxides of sulfur I
- 11. TOXICOLOGICAL INFORMATION I The following results are for a similar product.
ACUTE ORAL TOXICITY:
Species: Rat.
I LD50: 4.1 g/kg Test Descriptor: Similar Product I
ACUTE DERMAL TOXICITY:
Species:
LD50:
Rabbit 3 g/kg I
Test Descriptor: Similar Product PRIMARY SKIN IRRITATION:
I Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 5/12 0136 I
SAFETY DATA SHEET r4NALCO SPRODUCT NALCO 7408 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Species: Rabbit Draize Score: 1.018.0 Test Descriptor: Similar Product PRIMARY EYE IRRITATION:
Species: Rabbit Draize Score: 9.4 /110.0 Test Descriptor: Similar Product SENSITIZATION:
Sulfites can cause an allergic reaction in sensitive individuals.
CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
HUMAN HAZARD CHARACTERIZATION:
Based on our hazard characterization, the potential human hazard is: Low I I12. I ECOLOGICAL INFORMATION I ECOTOXICOLOGICAL EFFECTS:
The following results are for the product, unless otherwise indicated.
ACUTE FISH RESULTS: _-
Species Exposure LC50 Test Descriptor Rainbow Trout 96 hrs > 100 mg/I Product Fathead Minnow 96 hrs 382 mg/I Similar Product Mosquito Fish (Gambusia 96 hrs 240 mg/I Active Substance spp.) I I ACUTE INVERTEBRATE RESULTS:
Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs 275 mg/I Product Daphnia magna 48 hrs 728 mg/I Similar Product Daphnia magna 48 hrs 119 mg/I Active Substance CHRONIC FISH RESULTS:
Species I Exposure I NOEC / LOEC I End Point I Test Descriptor Fathead Minnow 7 Days 250 mg/I / 500 mg/I Growth Product CHRONIC INVERTEBRATE RESULTS:
Species I Test Type INOEC / LOEC I End Point ] Test Descriptor Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/12 0137
SAFETY DATA SHEET I AWNALCO PRODUCT I
NALCO 7408 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
F Ceriodaphnia dubia 3 Brood 250 mg/I / 500 mg/I I Reproduction Product I MOBILITY:
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and I output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the I
approximate respective percentages; I
I Air
<5% I 30Water
- 50% I Soil/Sediment 50 - 70%
The portion in water is expected to be soluble or dispersible. I BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION I
Based on our hazard characterization, the potential environmental hazard is: Low Based on our recommended product application and the product's characteristics, the potential environmental exposure is: High I
If released into the environment, see CERCLA/SUPERFUND in Section 15.
I 113. IDISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.
I As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, I disposal or recycling facility.
- 14. 1TRANSPORT INFORMATION I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
I LAND TRANSPORT:
Proper Shipping Name: BISULPHITES, AQUEOUS SOLUTION, N.O.S.
I Technical Name(s): SODIUM BISULPHITE UN/ID No:
Hazard Class - Primary:
UN 2693 8
I Packing Group: III Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 7/12 0138 I
SAFETY DATA SHEET P4NALCO PRODUCT NALCO 7408 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Flash Point: None DOT Reportable Quantity (per package): 12,500 lbs DOT RQ Component: SODIUM BISULFITE AIR TRANSPORT (ICAO/IATA):
Proper Shipping Name: BISULPHITES, AQUEOUS SOLUTION, N.O.S.
Technical Name(s): SODIUM BISULPHITE UN/ID No: UN 2693 Hazard Class - Primary: 8 Packing Group: III IATA Cargo Packing Instructions: 820 IATA Cargo Aircraft Limit: 60 L (Max net quantity per package)
MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name: BISULPHITES, AQUEOUS SOLUTION, N.O.S.
Technical Name(s): SODIUM BISULPHITE UN/ID No: UN 2693 Hazard Class - Primary: 8 Packing Group: III 115. I REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this-information.
NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.
Sodium Bisulfite : Respiratory irritant CERCLA/SUPERFUND, 40 CFR 117,302:
This product contains the following Reportable Quantity (RQ) Substance. Also listed is the RQ for the product.
RQ Substance RQ Sodium Bisulfite 12,000 lbs SARNSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE Ill) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/12 0139
SAFETY DATA SHEET I
)01N L OPRO IDUCT1 NALCO 7408 j i EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): I Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:
X Immediate (Acute) Health Hazard i Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:
When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.310 Boiler Water Additives, 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods.
I Limitations: no more than required to produce intended technical effect. i NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances &
Non-Food Compounds):
NSF Registration number for this product is : 140967 This product is acceptable for treating boilers or steam lines where steam produced may contact edible products and/or cooling systems where the treated water may not contact edible products in and around food processing areas, excluding such use in areas where meat and poultry are processed (G9).
This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL. i FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311 :
This product contains the following substances listed in the regulation. Additional components may be unintentionally present at trace levels.
I Substance(s)
. Sodium Bisulfite Citations Sec. 311 I I
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 9/12 0140 I
SAFETY DATA SHEET
)04"NALC
'NALCO PRODUCT NALCO 7408 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.
CALIFORNIA PROPOSITION 65:
Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product.
MICHIGAN CRITICAL MATERIALS:
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels.
STATE RIGHT TO KNOW LAWS:
The following substances are disclosed for compliance with State Right to Know Laws:
Sodium Bisulfite 7631-90-5 Water 7732-18-5 NATIONAL REGULATIONS, CANADA:
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION:
E - Corrosive Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on the Inventory of Existing Chemical Substances China (IECSC).
EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS).
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 10/12 0141
SAFETY DATA SHEET I 04NALCO PRODUCT NALCO 7408
-I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL) I NEW ZEALAND All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.
I PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS).
I
- 16. 1OTHER INFORMATION I Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:
I
- The human risk is: Low I
- The environmental risk is: Low Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can I
implement an appropriate risk management process.
This product material safety data sheet provides health and safety information. The product is to be used in I
applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
I REFERENCES I
Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight CD-ROM Version), Ariel Research Corp.,
Bethesda, MD. I Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health I
Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS I
CD-ROM Version), Micromedex, Inc., Englewood, CO.
I Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 11/12 I
0142
SAFETY DATA SHEET, N4NALCO PRODUCT NALCO 7408 EMERGENCY TELEPHONE NUMBER(S)
[-..
(800) 424-9300 (24 Hours) CHEMTREC Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Prepared By: Product Safety Department Date issued: 07/31/2009 Version Number: 1.16 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 12 /12 0143
I
___.ene~al*
-I
- hemicaI Material Safety Data Sheet I I SULFURIC ACID I
TRADE NAME (PRODUCT IDENTIFIER):
SULFURIC ACID CLASSIFICATION & SYMBOL:
I CHEMICAL NAME AND/OR SYNONYM:
Sulfuric Acid (oil of Vitrol; battery acid; Hydrogen Sulfate)
Class FORMULA:
H2SO 4
_EDA CAS NO:
I 7664-93-9 PRODUCT USE:
In the manufacture of fertilizers, explosives, dyestuffs, other acids and chemicals, textiles, paper, glue, purification of petroleum, pickling of metal and hydrometallurgy.
I MANUFACTURER/IMPORTER:
General Chemical Performance Products Ltd.
SUPPLIER/DISTRIBUTOR:
General Chemical Performance Products Ltd.
I 201 City Centre Drive 201 City Centre Drive Mississauga, Ontario L5B 3A3 EMERGENCY TELEPHONE NO: 866-543-3896 Mississauga, Ontario L5B 3A3 I
-O I E
-BPREPAR I* R T PREPARED BY: PREVIOUS ISSUE DATE: 612001 General Chemical Corporation Product Safety Department 973-515-1840 CURRENT ISSUE DATE: 03-18-04 I C. T PRPERIES I
INHALATION:
Inhalation of fumes or acid mist can cause irritation or corrosive bums to the upper respiratory system, including nose, mouth, and throat. Lung irritation and pulmonary edema can also occur. LC50 (mist, animals): 20-60 mg/m 3 . See Section J.
INGESTION:
I Can cause irritation and corrosive burns to mouth, throat, and stomach. Can be fatal ifswallowed.
SKIN:
Can cause severe burns and destruction of tissue.
I EYES:
Liquid contact can cause irritation, corneal burns, and conjunctivitis. Blindness may result, or severe or permanent injury. Mist contact may irritate or burn. Eye (rabbit): 1380 ug, severe damage.
I ACUTE TOXICITY:
LD50 (rat): 255 mg/m /4hr.
3 EXPOSURE3 LIMITS:
TLV: 1 mg/m STEL 3 mg/m 3 I CHRONIC TOXICITY: Proposed change 1987 / 88 Erosion of~teeth, lesions of the skin, tracheobronchitis, mouth inflammation, conjunctivitis, gastritis. See section J. I OTHER: lBIOLOGICAL ONA EXPOSURE INDICES (BEI):
I 1
0144 I
D. *HsjA DATN MATERIAL IS AT NORMAL APPEARANCE AND COLOR: ODOR THRESHOLD:
CONDITIONS: Oily, colorless to slightly yellow, clear to turbid Odorless liquid.
LIQUID 0 SOLID El GAS L1 BOILING POINT: 310 'C SPECIFIC GRAVITY: VAPOR DENSITY:
(H20 = 1) (AIR =1)
FREEZING POINT: -27 'C for 94% 1.842 (liquid) NA (MELTING POINT):
SOLUBILITY IN WATER: pH VAPOR PRESSURE:
complete 1 % solution pH = 0.9 (MM Hg @ 20'C negligible @ ambient (PSIG)
EVAPORATION RATE: %VOLATILES BY VOLUME: MOLECULAR WEIGHT:
(Ether = 1.0) (AT 20°C) 98.08 NA NA I -E. I ITY D STABILITY: CONDITIONS TO AVOID:
Temperatures of 300 deg, C or higher: yields sulfur trioxide gas, which is toxic, corrosive, and an UNSTABLE EL STABLE 0 oxidizer..
INCOMPATIBILITY (MATERIALS TO AVOID):
Nitro compounds, carbides, dienes, alcohols (when heated): cause explosions. Oxidizing agents, such as chlorates and permanganates: cause fires and possibly explosions. Allyl compounds and aldehydes: undergo polymerization, possibly violent. Alkalis, amines, water, hydrated salts, carboxylic acid anhydridesnitrites, olefinic organics, glycols, aqueous acids: cause strong exothermic reactions. Carbonates, cyanides, sulfides, sulfites, metals such as copper: yield toxic gases.
HAZARDOUS DECOMPOSITION PRODUCTS:
Sulfur trioxide gas: See above. Also this is a fire risk if in contact with organic materials.
HAZARDOUS POLYMERIZATION: OTHER PRECAUTIONS:
WILLNOT OCCUR 0 MAYOCCUR Li ......
I CONDITIONS OF FLAMMABILITY: FLASH POINT:
Not flammable. METHOD Not applicable HAZARDOUS COMBUSTION PRODUCTS:
See Section E. Also concentrated sulfuric acid can ignite combustible materials on contact.
% BY VOL. IN AIR EXPLOSION HAZARDS:
UPPER FLAMMABLE LIMIT: Flammable and potentially explosive hydrogen gas can be generated inside metal Not applicable drums and storage tanks. Also see Section E for other explosion hazards.
LOWER FLAMMABLE LIMIT:
AUTOIGNITION TEMPERATURE:
SENSITIVITY TO MECHANICAL IMPACT:
Not applicable SENSITIVITY TO STATIC DISCHARGE:
Not applicable FIRE EXTINGUISHING PROCEDURES:
Use water spray or other suitable agent for fires adjacent to non-leaking tanks or containers of acid. Ifonly a small amount of combustibles is present smother fire with dry chemical. Do not use solid water streams near ruptured tanks or spills of sulfuric acid. Acid reacts violently with water and can spatter acid onto personnel. Wear self-contained, NIOSH-approved breathing apparatus with full facepiece. Add chemical safety goggles ifeye protection is not provided. Wear full protective clothing.
2 0145
I
- b. A -IbOS INRN I T MXUE ONL)-,
MATERIAL OR COMPONENT/C.A.S. # CONCENTRATION HAZARD DATA Not applicable I
I I
I PERSONAL PROTECTIVE EQUIPMENT:
I RESPIRATORY PROTECTION:
Generally not required when using a closed ventilation system. Where required e.g. in an emergency or a misting situation, wear NIOSH-approved respirator for sulfuric acid. Ifabove mg/m3 acid mist wear (a) gas mask with acid gas canister and also with high efficiency particulate filter; (b) high efficiency particulate respirator or (c) self-contained breathing apparatus with full facepiece.
I EYES AND FACE:
As a minimum, wear safety goggles with non-perforated side shields. Add a shield if pouring liquid. For leak, spill, other emergency and heavy handling, use chemical safety goggles and hat or optionally a full face shield and hat. Do not wear contact lenses.
I HANDS, ARMS, AND BODY:
As a minimum wear acid-resistant apron and gloves (preferably rubber). For leak, spill, other emergency and heavy handling, use chemical safety goggles and hat or optionally a full face shield and hat. Do not wear contact lenses.
I STORAGE:
Protect from physical damage. Store in cool, well-ventilated area away from combustibles and reactive chemicals. Keep out of sun and away from heat.
Keep container's upright. Ifstored in metal containers, vapors can contain explosive hydrogen gas. No smoking in storage area. I NORMAL HANDLING:
Do not get in eyes, on skin or clothing. Do not breathe vapor or mist. Use protective equipment outlined in Section H. Do not add water to acid. When diluting, always add acid to water cautiously and with agitation. Use only with adequate ventilation. Loosen closures carefully. Forbcarrying glass bottles, use rubber protective enclosures.
I ENGINEERING CONTROLS:
Closed ventilation systems (e.g. exhausted hood) for handling such as pouring liquid. Use corrosion proof construction. Provide sufficient ventilation to I
reduce vapor and acid mists to permissible levels. Packaging and unloading areas and open processing equipment may require mechanical exhaust systems. Provide eyewash and quick-drench shower facilities convenient to work areas.
ENVIRONMENTAL:
I DEGRADABILITY:
Not available.
AQUATIC TOXICITY:
42 mrg/I / 96 hr. / mosquito fish / TLm / fresh water 42.5 mg / I / 48 hr. / prawn / LC5 0 / salt water In general a pH of 5.0 or less is lethal.
I SPILL OR LEAK (ALWAYS WEAR PERSONAL PROTECTIVE EQUIPMENT):
Dilute small spills or leaks cautiously with plenty of water. Neutralize residue with alkali such as soda ash or lime. Adequate ventilation'is required for soda ash due to release of C02 gas. No smoking in spill area. Major spills must be handled by a predetermined plan. Diking with soda ash is recommended. Attempt to keep out of sewer.
I WASTE DISPOSAL:
Dispose of diluted a/o neutralized waste consistent with the requirements of local alo provincial waste disposal authorities.
I I
3 01, 4 I
C-ANJADIAN SH.IPID~NG INFORMATION:
PIN: LABEL:iivlw PIN: LABEL:
8TDGA CLASS: packing group II UN 1830 corrosive 1FIS AI MEAURE INHALATION:
Remove to fresh air. Observe for possible delayed reaction. Ifbreathing has stopped, give artificial respiration. Ifbreathing with difficulty, give oxygen, provided a qualified operator is available. Get immediate medical attention.
INGESTION:
Do not induce vomiting. Ifconscious, give several glasses of milk (preferred) or water. Get immediate medical attention.
SKIN:
Immediately flush with plenty of water, continuing for at least 15 minutes. Remove contaminated clothing while washing. Get medical attention ifskin irritation persists or there are burns. Wash clothing thoroughly before reuse.
EYES:
Immediately flush with plenty of water, lifting eyelids occasionally to facilitate irrigation, and continue for at least 15 minutes. Get prompt medical attention. Continue flushing with water if medical attention is not immediately available.
J. Chronic Toxicity (continued)-
The International Agency for Research on Cancer (IARC) classified "strong inorganic acid mists containing sulfuric acid" as category 1 carcinogen, a substance that is "carcinogenic to humans". This classification is for inorganic acid mists only and does not apply to sulfuric acid or sulfuric acid solutions. The basis for the IARC classification rests on several epidemiology studies which have several deficiencies. These studies did not account for exposure to other substances, some known to be animal or potential human carcinogens, social influences (smoking or alcohol consumption) and included small numbers of subjects. Based on the overall weight of evidence from all human and chronic animal studies, no definitive causal relationship between sulfuric acid mist exposure and respiratory tract cancer has been shown.
THIS MATERIAL SAFETY DATA SHEET IS OFFERED FOR YOUR INFORMATION, CONSIDERATION AND INVESTIGATION AS REQUIRED BY FEDERAL HAZARDOUS PRODUCTS ACT AND RELATED LEGISLATION. THE INFORMATION IS BELIEVED TO BE ACCURATE BUT GENERAL CHEMICAL CANADA LTD. PROVIDES NO WARRANTIES, EITHER EXPRESSED OR IMPLIED.
GCC-1 4
014'1
I GE Betz, Inc.
4636 Somerton Road Material Safety Data Sheet I Trevose, PA 19053 Business telephone: (215) 355-3300 Issue Date: 08-SEP-2003 I
EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 I
1 PRODUCT IDENTIFICATION PRODUCT NAME:
I DEPOSITROL PY5206 I PRODUCT APPLICATION AREA:
WATER-BASED CORROSION INHIBITOR/DEPOSIT CONTROL AGENT. I 2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the I
U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. I HAZARDOUS INGREDIENTS:
CAS CHEMICAL NAME I 1305-62-0 CALCIUM HYDROXIDE Corrosive (eyes and respiratory);
irritant,possibly corrosive(skin) severe I
No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
I 3 HAZARDS IDENTIFICATION I CAUTION EMERGENCY OVERVIEW I
May cause slight irritation irritation to the skin. May cause moderate to the eyes. Mists/aerosols may cause irritation to I
upper respiratory tract.
DOT hazard is not applicable Emergency Response Guide is not applicable I
Odor: Mild; Appearance: Pale Yellow, Liquid I
0148 I
Fire fighters should wear positive pressure self-contained breathingj apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
ACUTE EYE EFFECTS:
May cause moderate irritation to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
4 FIRST AID MEASURES SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Get medical attention if irritation develops or persists.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes with plenty of low-pressure water for at least 15 minutes. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F > 93C P-M(CC) 0149
I 6 ACCIDENTAL RELEASE MEASURES i PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste'disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Alkaline. Do not mix with acidic material.
STORAGE:
Keep containers closed when not in use. Protect from freezing. Do not store at elevated temperatures.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION i EXPOSURE LIMITS CHEMICAL NAMEI CALCIUM HYDROXIDE PEL (OSHA): 5 MG/M3 TLV (ACGIH): 5 MG/M3 ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE._
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav. (70F,21C)
Freeze Point (F) 27 1.270 Vapor Pressure (mmHG)
Vapor Density (air=l)
- 18.0
< 1.00 I
Freeze Point (C) -3 Viscosity(cps 70F,21C) 22 % Solubility (water) 100.0 Odor Mild Appearance Pale Yellow Physical State Liquid Flash Point P-M(CC) > 200F > 93C I
0150 I
pH As Is (approx.) 13.1 Evaporation Rate (Ether=l) < 1.00 NA = not applicable ND = not determined 10 STABILITY & REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 TOXICOLOGICAL INFORMATION Oral LD50 RAT: 3,050 mg/kg 28 Day Oral RAT: 1,000 mg/kg/day NOTE - No clear indications of treatment related toxicity(dose adjusted to 100% active)
Dermal LD50 RABBIT: >1,000 mg/kg NOTE - Estimated value Skin Irritation Score RABBIT: 0.3 NOTE - DOT HM181: noncorrosive Eye Irritation Score RABBIT: 3.3 NOTE - Maximum score at 48 hrs; completely reversible by day 4 Non-Ames Mutagenicity MOUSE: NEGATIVE NOTE - In Vivo Bone Marrow Micronucleus Assay 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Acute Bioassay LC50= 1635; No Effect Level= 870 mg/L Fathead Minnow 96 Hour Static Acute Bioassay LC50= 1680; No Effect Level= 1350 mg/L Mysid Shrimp 48 Hour Static Renewal Bioassay LC50= 9900; 5% Mortality= 4000 mg/L Rainbow Trout 96 Hour Static Acute Bioassay (pH adjusted)
LC50= 837; No Effect Level= 648 mg/L Sheepshead Minnow 96 Hour Static Renewal Bioassay LC50= 28300; No Effect Level= 20000 mg/L BIODEGRADATION BOD-28 (mg/g) : 9 BOD-S (mg/g) : 9 COD (mg/g): 130 TOC (mg/g): 70 13 DISPOSAL CONSIDERATIONS 0151
I If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is D002=Corrosive(pH).
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding i
the proper disposal of this material.
14 TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE 4: Not applicable 15 REGULATORY INFORMATION TSCA:
All components of this product are listed in the TSCA inventory.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS:
i This product is composed of ingredients previously approved by USDA to meet G5 and G7 classification and may be used in water for cooking/cooling or in boiler or cooling systems with no food contact.
SARA SECTION 312 HAZARD CLASS:
Immediate(acute)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION I CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds i 16 OTHER INFORMATION 3 NFPA/HMIS CODE TRANSLATION Health 1 Slight Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special ALK pH above 12.0 (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations. 3 CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES 0152 i
MSDS status: 29-JAN-1997 ** NEW **
08-MAR-1999 12 29-JAN-1997 03-MAY-2000 12 08-MAR-1999 18-MAY-2001 2 03-MAY-2000 08-SEP-2003 15 18-MAY-2001 0133
Material Safety Data Sheet I
EMERGENCY 3 FOR CHEMICAL EMERGENCY: SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT CALL CHEMTREC - DAY or NIGHT - (800) 424-9300 i Product Name: AB AQUASHADE SECTION I - GENERAL INFORMATION3 Manufacturer's Name: Applied Biochemists A division of Advantis Technologies, Inc.
W175 N11163 Stonewood Dr., Suite 234 Germantown, WI 53022 (262) 255-4449 I
Chemical Name & Synonyms:
Generic
Description:
Formula:
Water Soluble Dye Pond and Lake Dye Proprietary I
D.O.T. Proper Shipping Name: Not Regulated D.O.T. Hazard Class:
U.N. or N.A. Identification No.:
Emergency Response Guide No.:
Not Regulated None Assigned None Assigned I
Hazardous Mat'is ID System Values (HMIS):
Nat'l Fire Protection Assn. (NFPA 704M):
Health - 1 Health - 1 Flammability - 0 Flammability - 0 Reactivity - 0 Reactivity - 0 Personal Protection - B Specific Hazard - None I SECTION II - HAZARDOUS INGREDIENTS Hazardous Component(s)
Acid Blue 9 CAS# PEL TLV i 3844-45-9 Not established Not established Acid Yellow 23 1934-21-0 Not established Not established Ingredients listed in this section have been determined to be hazardous as defined in 29CFR1910.1200. Materials determined to be health hazards are listed ifthey comprise 1%or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available as provided in 29CFR1910.1200 (i) (1).
U SECTION III - PHYSICAL DATA i Boiling Point: 212°F (100 0C) Specific Gravity (water = 1): 1.0-1.1 Vapor Pressure: Not determined % Volatile (by volume): Not determined Vapor Density (air = 1): >1 Evaporation Rate: Not determined Melting Point: Not applicable pH: 5-7 Solubility in Water: Miscible in water.
Appearance & Odor: Deep blue liquid, with no noticeable odor SECTION IV - FIRE & EXPLOSION DATAi Flash Point (F): Non-flammable Method: Not applicable Extinguishing Media: Water, carbon dioxide, or foam.
Special Fire Fighting Procedures: Cool area to prevent product containers from bursting or melting. Firefighters should be equipped with self-contained breathing apparatus.
Unusual Fire & Explosion Hazards: None SECTION V - REACTIVITY DATA 3 Stability - Unstable X Stable Conditions to Avoid:
Incompatibility (Materials to Avoid):
Hazardous Decomposition Products:
None known None known None known I
Hazardous Polymerization: Will Occur X Will Not Occur Conditions to Avoid: None i I
Pagel1of 2 0 1354 I
AB AQUASHADE SECTION VI - HEALTH HAZARD DATA Acute Health Hazards: Will stain tissue. May cause eye irritation.
Chronic Health Hazards: None known Signs & Symptoms of Exposure: May cause slight eye irritation and redness. May cause slight skin irritation.
Inhalation may cause slight nausea. Ingestion may result in gastric disturbances.
Medical Conditions Generally Aggravated by Exposure: None known Emergency & First Aid Procedures: See appropriate emergency procedures below for principle route of entry.
Never give anything by mouth to an unconscious person.
Route of Entry: Inhalation: Remove to fresh air.
Eyes: Flush with large amounts of water for at least 15 minutes. Contact a physician if irritation occurs.
Skin: Wash the area with large amounts of soap and water for at least 15 minutes.
Wash clothes thoroughly before reuse.
Ingestion: Induce vomiting. Call a physician.
SECTION VII - SPILL OR LEAK PROCEDURES Personal Precautions: Wear personal protective equipment appropriate for the situation.
Methods for Cleaning Up: Contain spill. Soak up with absorbent. Place in a suitable container for disposal. Wash area with soap and water. Care should be taken when handling this product as it can stain.
Waste Disposal Methods: Dispose of in accordance with methods approved by local, state and federal regulations.
SECTION VIII - SPECIAL PROTECTION AND CONTROL MEASURES Respiratory Protection: Not normally required.
Ventilation: Not normally required.
Gloves: Rubber or plastic Eye Protection: Goggles Other Protective Equipment: None Work or Hygienic Practices: Use safe chemical handling procedures suitable for the hazards presented by this material.
SECTION IX - SPECIAL PRECAUTIONS Handling and Storage: Keep away from intense heat and open flame.
Other: KEEP OUT OF REACH OF CHILDREN THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE.
Date of Last Revision: 09/05/04 by: JHW/NPB Page 2 of 2 0155
Material Safety Data Sheet I
EMERGENCY I FOR CHEMICAL EMERGENCY: SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT CALL CHEMTREC - DAY or NIGHT - (800) 424-9300 Product Name: AB AQUASHADE SECTION I - GENERAL INFORMATION Manufacturer's Name: Applied Biochemists A division of Advantis Technologies, Inc.
W175 N11163 Stonewood Dr., Suite 234 Germantown, WI 53022 (262) 255-4449 I
Chemical Name & Synonyms: Water Soluble Dye Generic
Description:
Pond and Lake Dye Formula: Proprietary D.O.T. Proper Shipping Name: Not Regulated D.O.T. Hazard Class: Not Regulated U.N. or N.A. Identification No.: None Assigned Emergency Response Guide No.: None Assigned Hazardous Mat'ls ID System Values (HMIS):
Nat'l Fire Protection Assn. (NFPA 704M):
Health - 1 Health - 1 Flammability - 0 Flammability - 0 Reactivity - 0 Reactivity - 0 Personal Protection - B Specific Hazard - None I SECTION II- HAZARDOUS INGREDIENTS Hazardous Component(s) CAS# PEL TLV l Acid Blue 9 3844-45-9 Not established Not established Acid Yellow 23 1934-21-0 Not established Not established Ingredients listed in this section have been determined to be hazardous as defined in 29CFR1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed ifthey I
comprise 0.1% or more of the composition. Information on proprietary materials is available as provided in29CF.R1910.1200 (i) (1).
SECTION III - PHYSICAL DATA I Boiling Point: 212F (1 00-C) Specific Gravity (water= 1): 1.0-1.1 Vapor Pressure: Not determined % Volatile (by volume): Not determined Vapor Density (air = 1): >1 Evaporation Rate: Not determined Melting Point: Not applicable pH: 5-7 Solubility in Water: Miscible in water.
Appearance & Odor: Deep blue liquid, with no noticeable odor SECTION IV - FIRE & EXPLOSION DATA Flash Point (F): Non-flammable Method: Not applicable Extinguishing Media: Water, carbon dioxide, or foam.
Special Fire Fighting Procedures: Cool area to prevent product containers from bursting or melting. Firefighters should be equipped with self-contained breathing apparatus.
Unusual Fire & Explosion Hazards: None SECTION V - REACTIVITY DATA U Stability - Unstable X Stable Conditions to Avoid: None known Incompatibility (Materials to Avoid): None known Hazardous Decomposition Products: None known Hazardous Polymerization: Will Occur X Will Not Occur Conditions to Avoid: None I I
Pagel1of 2 01::*
- I
AB AQUASHADE SECTION VI - HEALTH HAZARD DATA Acute Health Hazards: Will stain tissue. May cause eye irritation.
Chronic Health Hazards: None known Signs & Symptoms of Exposure: May cause slight eye irritation and redness. May cause slight skin irritation.
Inhalation may cause slight nausea. Ingestion may result in gastric disturbances.
Medical Conditions Generally Aggravated by Exposure: None known Emergency & First Aid Procedures: See appropriate emergency procedures below for principle route of entry.
Never give anything by mouth to an unconscious person.
Route of Entry: Inhalation: Remove to fresh air.
Eyes: Flush with large amounts of water for at least 15 minutes. Contact a physician if irritation occurs.
Skin: Wash the area with large amounts of soap and water for at least 15 minutes.
Wash clothes thoroughly before reuse.
Ingestion: Induce vomiting. Call a physician.
SECTION VII - SPILL OR LEAK PROCEDURES Personal Precautions: Wear personal protective equipment appropriate for the situation.
Methods for Cleaning Up: Contain spill. Soak up with absorbent. Place in a suitable container for disposal. Wash area with soap and water. Care should be taken when handling this product as it can stain.
Waste Disposal Methods: Dispose of in accordance with methods approved by local, state and federal regulations.
SECTION VIII - SPECIAL PROTECTION AND CONTROL MEASURES Respiratory Protection: Not normally required.
Ventilation: Not normally required.
Gloves: Rubber or plastic Eye Protection: Goggles Other Protective Equipment: None Work or Hygienic Practices: Use safe chemical handling procedures suitable for the hazards presented by this material.
SECTION IX - SPECIAL PRECAUTIONS Handling and Storage: Keep away from intense heat and open flame.
Other: KEEP OUT OF REACH OF CHILDREN THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION, NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE.
Date of Last Revision: 09/05/04 by: JHW/NPB Page 2 of 2 0157
KsIS Frx-On-Demand Sto&e, JulN 2'. 4l13S-3 I pHREEdom' 5200M -- -I P.O. Box 1346 MAN Pittsburgh, PA 15230-1346 Sa P n n a y Phone-(412)494-8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: pHREEdom' 5200M CHEMICAL DESCRIPTION: Aqueous polymerlorganlc phosphonate solution PRODUCT CLASS: Scale control MSDS CODE: 0D98-11-09-93 I Section 2. INFORMATION ON INGREDIENTS I
CAS % by Chemical Name Number Weiht OSHA PEL ACGIH TLV Sodium salt of phosphonomethylated diamine 103016* None established None established 1 Phosphorous acid 13598-36.2 - 1 None established None established OTSCA Accession number.
The specific Identity of some ingredients Is being withheld for confidential business purposes. However, all known potential health effects from exposure to these ingredients are being addressed.
Section 3. HAZARDS IDENTIFICATION *
- EMERGENCY OVERVIEW ********4**********
WARNING!
May cause eye irritation.
PRIMARY ROUTES OF ENTRY: Eye and skin contact. Inhalation TARGET ORGANS: Eyes. skin, central nervous system I MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Unknown POTENTIAL HEALTH EFFECTS:-
EYE CONTACT: This product may produce Irritation upon contact with the eye.
MSDS Code: 0198-11-09-93 Issue Date: 11/9/93 Continued on Page 2 0.58I I l
itSDS faxOn-Debaad 5yte July 14. 13585
,,ý pHREEdom' 5200M SKIN CONTACT: This product may produce mild irritation upon contact with the skin.
INGESTION: Swallowing this product may cause gastrointestinal upset with nausea, vomiting, and diarrhea.
INHALATION: Inhalation of product mist or vapor may irritate the nose, throat, and respiratory tract.
Prolonged exposures to high levels may cause weakness, CNS depression, and drowsiness.
SUBCHRONIC, CHRONIC:
No applicable Information was found concerning any potential health effects resulting from subchronic or chronic exposure to the product.
CARCINOGENICITY:
NTP:
.No Ingredients listed In this section*
IARC:
- No Ingredients listed In this section*
OSHA:
- No Ingredients listed In this section*
Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, Immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid.
SKIN CONTACT: Not expected to require first aid measures.
INGESTION: Not an expected route of overexposure.
INHALATION: Not an expected route of overexposure.
Section 5. FIRE-FIGHTING MEASURES FLASH POINT: > 200"F This product Is not by definition a "flammable liquid" or a "combustible liquid*.
LOWER FLAMMABLE LIMIT; Not available UPPER FLAMMABLE LIMIT: Not available AUTO-IGNITION TEMPERATURE: Not available EXTINGUISHING MEDIA. Use water spray or fog, alcohol-type foam, dry chemical or carbon dioxide.
FIRE-FIGHTING INSTRUCTIONS: Exercise caution when fighting any chemical fire. A self-contained breathing apparatus and protective clothing are essbntial.
Use water to keep fire-exposed containers cool.
FIRE & EXPLOSION HAZARDS: Product emits toxic gases under fire conditions.
DECOMPOSITION PRODUCTS: Thermal decomposition or combustion may produce carbon monoxide, carbon dioxide, nitrogen oxides, phosphorus oxides, sulfur oxides, ammonia.
MSDS Code. 0D98-111 93 CP.*"2. :5._
Issue Date: 11/9/93 Continuedon Page 3 01.59 7
julu el"1320j, I
KiDS FDXiJflUOftKfla bijutem r.
I pHREEdom h' 6200M NFPA RATINGS: Health =1 Flammability - 0 Reactivity - 0 Special Hazard - None I Hazard ra*ing scale: 0-Minimal I -Slight 2-Moderate 3-Serious 4-Severe Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wearing appropriate personal protective equipment, contain spill, collect onto Inert absorbent and place Into suitable container.
Section 7. HANDLING AND STORAGE I U
HANDUNG: Avoid contact with eyes.
Avoid breathing vapor or mist.
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the product and ensure prompt removal from skin and clothing.
I Use with adequate ventilation.
Wash thoroughly after handling.
Keep container dosed when not in use. I STORAGE: No specific information.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION I
PERSONAL PROTECTIVE EQUIPMENT: I EYE/FACE PROTECTION: Chemical splash goggles SKIN PROTECTION: Chemical resistant gloves recommended as a good Industrial hygiene practice.
RESPIRATORY PROTECTION: If airborne concentrations become irritating, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
I ENGINEERING CONTROLS: Use local exhaust ventilation at elevated temperatures or if mists are generated.
WORK PRACTICES: An eye wash station should be accessible In the Immediate area of use.
I I
Section 9. PHYSICAL AND CHEMICAL PROPERTIES I
BOILING POINT: Not available SOLUBILITY IN WATER: Complete VAPOR PRESSURE: Not available SPECIFIC GRAVITY: 1.16 - 1.20 0 25*C I VAPOR DENSITY (air-i): Not available pH: 4.2 - 5.2 0 25"C
%VOLATILE BY WEIGHT: - 74 FREEZING POINT; Not available I
APPEARANCE AND ODOR: Clear, pale yellow liquid.
I MSDS Code: 0I98-11-09-93 ConAne3on Page53 Issue Date: 11/9/93 Contnueon Page 4 0160 I
I
"so 5rm'vn-uetand Soisiea July t* 50-ItS--'
pHREEdom' 5200M Section 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: No specific Information.
INCOMPATIBILITY: Strong oxidizers DECOMPOSITION PRODUCTS: Thermal decomposition or combustion may produce carbon monoxide, carboh dioxide, nitrogen oxides, phosphorus oxides, sulfur oxides, ammonia.
Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT:
No informalion available on the formulated product.
Section 12. ECOLOGICAL INFORMATION ON PRODUCT:
No information available on the formulatedproduc.
Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would not be considered a RCRA Hazardous Waste.
DISPOSAL, Dispose of Inaccordance with local, state and federal regulations.
Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION:
Class/DIvision: Not restricted Proper Shipping Name. Not applicable Label: None Packing Group: Not applicable ID Number Not applicable Section 15. REGULATORY INFORMATION OSHA Hazard Communication Status: Hazardous TSCA: The Ingredients of this product are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory.
MSDS Code: 0108-11409-933
- Coidn g Issue Date: 11/9/93 Continued on Page 5 0161
1505. fvOtIrDPrmnd System Jui 1-I.-1335.-"
pHREEdomIu 200M CERCLA reportable quantity of EPA hazardous substances in product:
Chemical -Name RO No ingredients of this product have CERCLA reportable quantities.
Product RQ: Not applicable (Notify EPA of product spills exceeding this amount.) I SARA TITLE IlI:
Section 302 Extremely Hazardous Substances: 3 Chemical Name CAS 4 O TPQ There are no SARA 302 Extremely Hazardous Substances in this product.
Section 311 and 312 Health and Physical Hazards: I Immediate Delayed Fire Pressure Reactivity yeys] [no] [no) [no) jno]
Section 313 Toxic Chemicals:
Chemical Name CAS# % by Weight There are no reportable SARA 313 Toxic Chemicals In this product.
I I I II Section 16. OTHER INFORMATION 3 HMIS RATINGS: Health - 1 Flammability - 0 Reactivity = 0 Personal Protective Equipment - X (to be specified by user depending on use conditions)
Hazard rating scale: 0-Minimal I -Slight 2-Moderate 3-Serious 4-Severe MSDS REVISION
SUMMARY
- Not applicable I
,.l*e this infczxwtincr and zecowraedation. set foxth hejein axe believed to be accuiste 06 of thle date bezeof, CA.IOO OZORRTION KAT' SI NO WARRANTY WITH RESPECT RZ*KVTOAND DI*CLAIMS ALL LTAB RLTTY FIROMt RELIANCE THIREON.
PREPARED BY: P.J. Maloney I
I I
MSDS Code: 0D98-11-09-93 -
Issue Date: 11/9/93 Last Page 0162 I
c~y~ (c1{~cL)
I pHREEdom T2000 I~ ~J3Y LTh)
P.O. Box 1346
-a- SIR Pittsburgh, PA 15230-1346 01" ,* 0oo bum Phone--(412)494-8000 MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME: pHREEdom T2000 CHEMICAL DESCRIPTION: Alkaline aqueous solution of organic phosphonates, acrylate terpolymer, and monoethanolarnine.
PRODUCT CLASS: Scale inhibitor MSDS CODE: 0H28-02-26-96 Section 2. INFORMATION ON INGREDIENTS CAS % by Chemical Name Number Weiaht OSHA PEL ACGIH TLV Sodium salt of phosphonomethylated diamine 103016° 8-10 None established None established Disodium hydroxyphosphonoacetate 128192-25-6 4-6 None established None established Monoethanolamine (MEA) 141-43-5 -5 TWA 3 ppm, 8 TWA 3 ppm, 7.5 mg/m 3; STEL 6 mg/m 3; STEL 63 3
ppm, 15 mg/m ppm, 15 mgtm
- TSCA Accession number.
Section 3. HAZARDS IDENTIFICATION
- EMERGENCY OVERVIEW *********************
WARNING!
May cause eye and respiratory tract irritation.
May cause allergic skin reaction.
PRIMARY ROUTES OF ENTRY: Eye and skin contact, inhalation, skin absorption TARGET ORGANS: Eye. skin, central nervous system MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Unknown MSDS Code: 0H28-02-26-96 Page 1i6 (o Issue Date: 03/06/96 Continued on Page 2 0163
'5)/' 3" Ig pHREEdom T2000 POTENTIAL HEALTH EFFECTS:
I EYE CONTACT: This product may produce irritation upon contact with the eye.
SKIN CONTACT: Prolonged or repeated exposure may cause irritation resulting in rashes and dermatitis.
1 By OSHA definition, pure monoethanotamine is toxic by skin absorption. Prolonged or widespread skin contact may result in the absorption of harmful amounts of material. There is no evidence that the ethanolamines can cause allergic contact dermatitis. However, neutralized I
hydroxyphosphonoacetic acid has recently been reported to be a skin sensitizer in a guiriea pig study. Therefore, the product, which contains 4 - 6% disodium hydroxyphosphonoacetate, may cause an allergic skin reaction in sensitive individuals. I INGESTION: Swallowing this product may cause gastrointestinal irritation, nausea, vomiting, and diarrhea. I INHALATION: Inhalation of product mist or vapor may result in irritation with coughing and discomfort of the nose, throat, and chest. Prolonged exposures to elevated concen trations may cause weakness, CNS depression and drowsiness. In animal experiments, subacute high level exposures to monoethanolamine vapor and mist produced pulmonary damage, lethargy, and I
some non-specific degenerative changes in the liver and kidneys. Lab tests have found monoethanolamine to be a central nervous system (CNS) stimulant at low doses, and a CNS depressant at lethal doses.
I SUBCHRONIC, CHRONIC:
No applicable information was found concerning any potential health effects resulting from subchronic or chronic exposure to the product.
I Prolonged or repeated exposure to monoethanolamine may cause liver and kidney damage. Long-term inhalation of monoethanolamine vapors has caused nerve damage in laboratory animals. Oral intake of monoethanolamine during pregnancy has caused embryotoxicity and maternal toxicity in rats. Exposures I
having no effect on the mother should have no effect on the fetus.
There is evidence that no embryofetotoxicity or teratogenicity was produced in rats or rabbits when MEA I
was administered by skin contact. In spite of the widespread use of rFonoethanolamine in industry, no reports of injury to workers have been found.
CARCINOGENICITY:
I NTP:
IARC:
.No ingredients listed in this section*
I "No ingredients listed in this section*
OSHA:
- No ingredients listed in this section* U Section 4. FIRST AID MEASURES EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical aid.
SKIN CONTACT: In case of contact, immediately wash skin with soap and plenty of water. Remove I
contaminated clothing. Seek medical aid if symptoms occur. Wash clothing before reuse.
I MSDS Code: 0H28-02-26-96 Page 2 d-*
Issue Date: 03106196 0164 Continued on Page 3 I
i pHREEdom T2000 INGESTION: Not an expected route of overexposure.
INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical aid.
Section 5. FIRE-FIGHTING MEASURES FLASH POINT: Not determined The flash point is expected to be > 200 OF.
LOWER FLAMMABLE LIMIT: Not available UPPER FLAMMABLE LIMIT: Not available I AUTO-IGNITION TEMPERATURE: Not available EXTINGUISHING MEDIA: Use water spray or fog, alcohol-type foam, dry chemical or carbon dioxide.
FIRE-FIGHTING INSTRUCTIONS: Exercise caution when fighting any chemical fire. A self-contained breathing apparatus and protective clothing are essential.
i Use water to keep fire-exposed containers cool.
FIRE & EXPLOSION HAZARDS: Product emits toxic gases under fire conditions.
3 DECOMPOSITION PRODUCTS: Thermal decomposition or combustion may produce carbon monoxide, carbon dioxide, ammonia, nitrogen oxides, sulfur oxides, and phosphorus oxides.
NFPA RATINGS: Health = I Flammability = 1 Reactivity = 0 Special Hazard = None Hazard rating scale: 0 = Minimal 1 ==Slight 2 = Moderate 3 - Serious 4 = Severe I Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL*IS RELEASED OR SPILLED: Ventilate ared of spill. Wearing appropriate personal protective equipment, contain spill, collect onto inert absorbent and place into suitable container. Do not allow to contaminate sewers and waterways. Spilled product may make floor slippery; spills should be cleaned up immediately to prevent falls.
I Section 7. HANDLING AND STORAGE HANDLING: Avoid contact with eyes, skin and clothing.
Avoid breathing vapor or mist.
Use with adequate ventilation.
Drums should be opened in well-ventilated areas.
Wash thoroughly after handling.
Keep container closed when not in use.
- STORAGE: No specific information.
MSDS Code: 0H28-02-26-96 Page 30L66 Issue'Date: 03/06/96 Continued on Page 4 0165
IpHREEdom T2000
-I Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION I PERSONAL PROTECTIVE EQUIPMENT:
I EYE/FACE PROTECTION: Chemical splash goggles SKIN PROTECTION: Chemical resistant gloves and protective clothing RESPIRATORY PROTECTION: If airborne concentrations exceed published exposure limits, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR I
1910.134).
ENGINEERING CONTROLS: Provide ventilation to minimize exposure. Use local mechanical exhaust I ventilation at sources of air contamination such as open process equipment.
I Section 9. PHYSICAL AND CHEMICAL PROPERTIES I BOILING POINT: Not available SOLUBILITY IN WATER: Complete I VAPOR PRESSURE: Not available SPECIFIC GRAVITY: 1.174 - 1.194 @ 250 C VAPOR DENSITY (air= 1): Not available pH: 10.0-11.0 @250 C I
%VOLATILE BY WEIGHT: " 78 FREEZING POINT: Not available APPEARANCE AND ODOR: Clear to slightly hazy, dark gold to brown liquid with pungent odor.
I Section 10. STABILITY AND REACTIVITY I
CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: No specific information.
HAZARDOUS POLYMERIZATION: Will not occur I
INCOMPATIBILITY: Strong oxidizers and acids DECOMPOSITION PRODUCTS: Thermal decomposition or combustion may produce carbon monoxide, carbon I
dioxide, ammonia, nitrogen oxides, sulfur oxides, and phosphorus oxides.
Section 11. TOXICOLOGICAL INFORMATION I
ON PRODUCT:
No information available on the formulated product.
U I
MSDS Code: 0H28-02-26-96 Page 4O (0 Issue Date: 03/06/96 0 166 Continued on Page 5 0- __ - M
'76(
p:HREEdom T2000 ON INGREDIENTS:
Oral LD5 0 Dermal LDs 0 Inhalation LCso Chemical Name (rat) (rabbit) Not available Sodium salt of phosphonomethylated diamine Not available Not available Not available Disodium hydroxyphosphonoacetate Not available Not available Not available Monoethanolamine (MEA) 1720 mg/kg 1000 mg/kg Section 12. ECOLOGICAL INFORMATION ON PRODUCT:
No information available on the formulated product.
ON INGREDIENTS:
Chemical Name Aquatic Toxicity Data Monoethanolamine 96 hr LC5o (fathead minnow): 125 ppm 24 hr LCso (Daphnia magna): 140 ppm 96 hr LCso (bluegill sunfish): 75 ppm 96 hr LC6o (rainbow trout): 150 ppm Section 13. DISPOSAL CONSIDERATIONS RCRA STATUS: Discarded product, as sold, would not be considered a RCRA Hazardous Waste.
DISPOSAL: Dispose of in accordance with local, state and federal regulations.
Section 14. TRANSPORT iNFORMATION DOT CLASSIFICATION:
Class/Division: Not restricted Proper Shipping Name: Not applicable Label: None Packing Group: Not applicable ID Number: Not applicable Section 15. REGULATORY INFORMATION OSHA Hazard Communication Status: Hazardous TSCA: The ingredients of this product are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory.
CERCLA reportable quantity of EPA hazardous substances in product:
Chemical Name R.Q No ingredients of this product have CERCLA reportable quantities.
Product RQ: Not applicable (Notify EPA of product spills exceeding this amount.)
MSDS Code: 0H28-02-26-96 Page 516 0 Issue Date: 03/06196 Continued on Page 6 0167
SpHREEdom T2000 SARA TITLE III:
Section 302 Extremely Hazardous Substances: i Chemical Name CAS # TPB There are no SARA 302 Extremely Hazardous Substances in this product. I Section 311 and 312 Health and Physical Hazards:
Immediate Delayed Fire Pressure Reactivity 1yes) [no] [no] [no] [no]
Section 313 Toxic Chemicals:
Chemical Name CAS# % b# WeiahI There are no reportable SARA 313 Toxic Chemicals in this product.
Section 16. OTHER INFORMATION HMIS RATINGS: Health - 1 Flammability = 1 Reactivity = 0 Personal Protective Equipment = X Ito be specified by user depending on use conditions)
I Hazard rating scale: 0 - Minimal 1 =Slight 2 = Moderate 3 =Serious 4=Severe MSDS REVISION
SUMMARY
- Not applicable White this information and recousendations set forth herein are beLieved to be accurate as of the date hereof, CALGON CORPORATION MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE. THEREON.
PREPARED BY: P.J. Maloney I
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I MSDS Code: 0H28-02-26-96 Page 60-6 (f Issue Date: 03/06/96 0168 Last Page
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Page 1 of 3 MATERIAL SAFETY DATA SHEET BBJ Environmental Solutions, Inc.
6802 Citicorp Blvd., Suite 500 Tampa, FL 33619 800-889-2251
- 1. PRODUCT IDENTIFICATION PRODUCT NAME PRODUCT CLASS Power Coil Cleane Industrial Cleaner II. INGREDIENTS INGREDIENT % BY WT. CAS REG. NO.
Ammonium Biflouride <10.0 1341-49-7 Water >80.0 7732-16-5 Non hazardous surface active agents <10.0 Trade Secret I11.PHYSICAL DATA BOILING POINT: 212°F SPECIFIC GRAVITY: 1.00-1.10 at250 C FREEZING POINT: 32"F. May turn milky at <40'F. VAPOR PRESSURE: (mm Hg) = 17.5 VAPOR DENSITY: Not known APPEARANCE: Clear PH@ 250 C: 4.5 - 5.0 SOLUBILITY IN WATER BY WT.: Complete EVAPORATION RATE: Not known ODOR: Mild IV. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: Not Combustible FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: Carbon dioxide, dry SPECIAL FIRE HAZARDS: None chemical or foam. Do not use sand.
V. REACTIVITY DATA STABILTY: Stable Hazardous polymerization will not occur.
INCOMPATIBILITY: Strong acids, bases and glass containers.
HAZARDOUS DECOMPOSITION PRODUCTS: NH 3 if in contact with alkalis. Hydrogen Fluoride if heated to decomposition or exposed to acids.
CONDITIONS TO AVOID: Do not use with any other cleaning agent or household chemicals, including ammonia, acids, alkalis, bleaches, or chlorine cleaners VI. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb with saw dust or dry lime and sweep. Do not use sand. Do not flush into sewer or bodies of water.
DISPOSAL METHOD: Deposit in containers and dispose in an approved landfill.
0169
I MSDS - Power Coil Clean - Page 2 of 3 -I VII. HEALTH HAZARD DATA ACUTE TOXICITY: Oral LD~o > 1,900 mg/Kg of body weight. Dermal LD50 >2,000 mg/Kg of body weight.
I Inhalation LC0 >2.0 mg/L CARCINOGENICITY: Not a known carcinogen.
I EFFECTS OF OVEREXPOSURE: Will irritate eyes. Will dry skin with frequent or prolonged contact INGESTION: May cause irritation. Do not induce vomiting. Give milk of Magnesia or Milk. Call physician I
if discomfort persists.
EYE: Flush with water for 15 minutes. Call a physician, if irritation persists. I SKIN: Can cause irritation or burns. Rinse off with plenty of water immediately following contact I
INHALATION: May cause irritation of upper respiratory tract.
VIII. PROTECTIVE EQUIPMENT I
VENTILATION Use with adequate ventilation.
RESPIRATORY PROTECTION The use of an N95 rated respirator is recommended.
I PROTECTIVE CLOTHING EYE PROTECTION Protective gloves (plastic or rubber).
Wear goggles when handling this product.
I IX. OTHER SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE heat. Do not store below 40'F.
Keep from freezing and excessive I SPECIAL COMMENTS When applying the product to the coils in gas furnaces, the burners should be covered to avoid dripping on the burner tubes. If this precaution is not observed, ionization type smoke I
detectors may go off on the first use of the furnace after application.
PREPARED BY: Dr. Vladimir Mischutin, PhD DATE: January 31, 2003 I
AMENDED: June 4, 2003 I
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0170 I
MATERIAL SAFETY DATA SHEET MSDS 0221 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION HMIS CODES PRODUCT NAME Health 2 Coil-Rite Flammability 0 Reactivity 0 PRODUCT CODES PPI B 82612, 82614, 82618 CHEMICAL FAMILY Organic/Inorganic USE Coil Cleaner MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.
The RectorSeal Corporation Chemtrec 24 Hours 2601 Spenwick Drive (800) 424-9300 Houston, Texas 77055 USA DATE OF PREPARATION TECHNICAL SERVICE TELEPHONE NO.
August 13, 2002 (800) 231-3345 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT CAS No. INGREDIENT UNITS 1-5 111-76-2 Glycol Ether EB ACGIH TLV 25 ppm OSHA PEL 25 ppm Section 3 -- HAZARDS IDENTIFICATION
SUMMARY
OF ACUTE HAZARDS Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and other CNS effects at high concentrations. Skin irritation, dermatitis, and defatting.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS INHALATION Nasal and respiratory irritation, dizziness, narcosis, headache, nausea, CNS depression, and unconsciousness.
EYE CONTACT Watering, blurred vision, inflammation, and irritation which can result in corneal injury.
SKIN CONTACT Irritation, dermatitis.
INGESTION Nausea, vomiting; CNS depression; irritation of gastrointestinal tract, liver and peritoneal wall; lung congestion.
SUMMARY
OF CHRONIC HAZARDS Skin irritation, contact dermatitis, and defatting.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin, respiratory system, cardiovascular system, gastrointestinal system, liver, or kidneys may have increased susceptibility to excessive exposure.
Section 4 -- FIRST AID MEASURES If INHALED: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt 071
I If on SK IN:
action is essential.
Immediately wash with soap and water.
any contaminated clothing.
Remove and wash -I If If in EY'ES:
SWALL OWED:
Flush eyes with large amounts 6f water for 15 minutes.
Get medical attention if irritation persists.
If swallowed, call a physician immediately. Only induce I
vomiting at the instruction of a physician.
anything by mouth to an unconscious person.
Never give I
Section 5 -- FIRE FIGHTING MEASURES FLASH 'POINT LEL UEL I
None N/D N/D EXTINGUSING MEDIA Non-flammable. Use agents appropriate for surrounding fires.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece I
breathing apparatus and other protective clothing. Hazardous decomposition products possible (see Section 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS: None I Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
of ignition.
Remove all sources Use absorbent materials to prevent footing hazard and to contain.
I Ventilate area with natural or explosion-proof, forced air ventilation.
flushing into sewers, drains, waterways, and soil.
and respiratory protection during cleanup.
Avoid Wear protective clothing I Section 7 -- HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and I
upright when not in use. Do not store near heat, sparks, or open flames.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing.
Empty containers may contain residues; treat as if full and observe all products precautions. Do not reuse empty containers..
I Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION (SPECIFY TYPE):
I In confined, poorly ventilated areas, use NIOSH/MSHA approved air purifying or supplied air respirators during soldering operations until fumes have dissipated.
VENTILATION - LOCAL EXHAUST: Acceptable I
SPECIAL: Explosion proof MECHANICAL (GENERAL):
OTHER: N/A PROTECTIVE GLOVES:
Acceptable Wear rubber gloves.
I EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
recommended.
WORK/HYGIENIC PRACTICES:
Chemical resistant coveralls Where use can result in skin contact, wash exposed I
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
I Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT:
SPECIFIC GRAVITY (H20 = 1):
212 F (100 C) @ 760mm Hg 0.99 I
VAPOR PRESSURE (mm Hg): 17 @ 68 F (20 C)
MELTING POINT:
VAPOR DENSITY (AIR = 1):
N/A
<1 I 0 172 I
EVAPORATION RATE (ETHYL ACETATE = 1): >1 APPEARANCE/ODOR: Green Liquid / Mild Odor SOLUBILITY IN WATER: Soluble Section 10 -- STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: None INCOMPATIBILITY (MATERIALS TO AVOID): Heat, sparks and open flames.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
Section 11 -- TOXICOLOGY INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
TOXICOLOGY DATA Ingredient Name Glycol Ether EB Oral-Rat LD50:470 mg/kg Inhalation-Rat TCLo:200 ppm/6H Section 12 -- Ecological Information ECOLOGICAL DATA Ingredient Name Glycol Ether EB Food Chain Concentration Potential None WATERFOWL TOXICITY N/A BOD 26%
AQUATIC TOXICITY 1000 ppm/24 hr/brine shrimp/TLm Section 13 -- DISPOSAL CONSIDERATIONS Waste Classification: Non-regulated liquid waste.
Disposal Method: Dispose of in accordance with local, state and federal regulations.
Section 14 -- TRANSPORTATION INFORMATION DOT: Non-regulated OCEAN (IMDG) : Non-regulated AIR (IATA) : Non-regulated WHMIS (CANADA) : Non-regulated Section 15 -- REGULATORY INFORMATION REGULATORY DATA Ingredient Name Glycol Ether EB SARA 313 Yes TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A Section 16 -- OTHER INFORMATION 0173
I This document is prepared pursuant to the OSHA Hazard Communication i Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001 I I
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0174i
ACTI-KLEAN
- Material Safety Data Sheet SECION1 -PRODUCT IDENTIFIER PRODUCT: ACTIX-LEAN AIC-1, AK-5, AK-55 NFPA Ratinga:
Healths I SUPP:,IER: Virginia gliP Firet 0 4100 Platinum Wa~ React; 0 Dallan,'Texas 792.37 Sgecial: --
- 0ULEAST o 4=EXTREME Phone; 800-527-7960 Emergency Phone; 800-527-7960 Hmrs PERSONAL PROT: C Prepared: 6/91 ISECTION 1I - HAZARDOUS INGREDIENTS HAZARDOOUS 4OMIPG14k!S(CAS Numaber) EXPOSURE LIKITS Ethylene gLycaL monobutyt ether (111-76-2) ------ OH TWA (SKCIN) 25 ppm, ACGIII (SKIN) 25 ppmi
- D:-dec*Cericnzeo auLfLoaic acid (16--0 NODATA ESTA9LISMgD SjECTION III- P'RYSXCILL/CXEMICAL CHARACTERISTICS EOIL.ING POINT: 2120 F MZLTflJC POXNT: NA SFEC~TrIC GRAVITY (H20=1): 1.02 VA~POR PRESSURE: ND VAt" SN;ý.-:Y (Air~l) I ND
-. EVAPORATION RATE (DuAcel -:<
Sc...~~ W~ ATER: Completep:1 - 2 Ap!--.ý-ýýP---AIN ODORt Green liquid.
PLASH POINT (Method): None at baitijng point.
FLAMM'ABLE. LIMITS% Lowort RA I UpperC NA 1 EXrINGU!SHhtC MEDIA: Dry powder, carbon dioxide (C02), water fog or spray. Use extinguishing media appropriate for su.-Towndirig conditionls.
SFECi, FIRIE FIGHTING PROCEDURES. Approach fire from~ upw~ind side. Avoid breathing smoke fumes, mist. or vapors
~~on Picedownwind side. Firefighters wear protective clothing, ard ".itf contained b~reathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZAROS! Firef~ighters wear protective clothing. arnd self contained breathing apparatus.
ETIN V - REACTIVITY INFORXATIOV STA5ILUrt: PRODUCT IS, Stable tNCONtPArIBILIrY --
?4ArERIALS TO AVO10: Oxidizing Matcriats NAZAJOOVS VOCOMPaSItION aq BYPRO~ucrs: from combu%;tion: smoke, carbon monoxide, carbon dioxide. oxides of phosphorus, oxides of sulfur.
MAZARDOVS POLYMIaRIZATIONs WittI not occur.
SECTION VI - HEALTY HAZARD DATA ROUTES OF ENTRY
- INHALATION? posuible - irritant SKIN/EYES? yes irritant SKIN ABSORPTIgON? possible if skin is broken INOESTION? possible - irritant HEALTH HAZARDS ACUTE: Inhalation of vapor or mist is irritating to respiratory tract. Liquid or vapors are irritating to skin or eyes. Ingestion will cause gastrointestinal distress.
U CHRONIC: Damage to kidneys and liver (Ethylene Glycol Monobutyl Ether).
CARCINOGENICITYs LISTED IN No NTP? IARC MONOGRAPHS? No OSHA REGULATED? No S5GNS AND SYMPTOMS OF EXPOSURE: Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitic, shortnp.s of breath, headache, nausea and vomiting.
virgillia 0 175
ACTI-XLEAN bMEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: No data established.
FIRST AD PROCEDURES EYE CONTAC'rt Flush'eyes with water 15 minutoa. Get medical. attention if symptoms develop and persist.
SKIN CONTACT: Flush with water or soap and water for 15 minutes or until all traces have been removed.
pets ist. Seek medical attention if symptoms develop and INGESTIONt Do NOT induce vomiting get immediate medical attention.
INHALATION: Remove victim to fresh air and, if needed, immediately begin artificial respiration, Give oxygen if býreathing is labored. Cet emergency medical help'. Contact a physician immediately.
STEPS TO BE .;e'R ' CASE MATERIAL IS RELEASED OR SPILLSED For UAMII spills - pick up with absorbent media.
store a% ý.-ou:,tria! wOase.
SWASTE D;SPOSAL METHOD; Approved fIdwatrint wastm f*citity. Fotiow alt ipptir-bte regulation,.
PRECAUTIONS TO BE TAKFN IN NANOLING ANO STORAGE: Store oway from fooda:tuffA. Store away from basic materiats.
OTHER PRECAUTIONS: Clean up leaks/Kpitts immediately to prevent soil or water tontamination.
r VT*I I - CONTROL - -EASURES 2 :.* PROTECTION: (If concentration roachen or exceeds TLV), wear NIOSH a -i rczzirator.
VENTILATION: LOCAL. EXHAUST -Recommended, SPECIAL -Not necessary, MECHANICAL-Recomnmnded, OTHER - Not Ficcossary PROTECTIVE CLOVES: heavy rubber type EYr PROTECTION: Full face shield.
C X*%'!*rE*TIVE EQUIPMENT: SoOts, aprons, drench showers, eye wash as needed for
.- 't.-n against spills and/or splashes.
,.KH~rYGIENIC PRACTICES: Avoid contact with skin, eyes, and clothing. After handling
/W*this product, wash hands before eatinq, drinking or smokin?. If contact occurs,.
remove contaminated clothing. If neehed, take fIrt Launder contaminated clothing before reuse.
aid ac ion shown in section VI, 3
ACTI-KLEAN, Not-Regulated II EPA HAZARDS: ACUTE-yeS, CHRONIC-Yes, FLAMMABILITY-no, DDEN RELEASE OF PRESSURE-no, REACTIVE-no SARA Title III Section Chemical 323, Name Toxic Materials: CAS I Percentage 3
Ethylene Glycol CLEAN AIR ACT: not listed Monobutyl Ether 111-76-2 1 - 5%
CLEAN WATER ACTi section 311 3
STATES LISTS: Massachusetts, Now Jertey, Pennsylvania TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 Sources of the raw materials used in this mixture assure that all chemical ingredients p.resent are in compliance with Sect. 8(b) Chemical Substance Inventory, or are therwise in compliance with TSCA.
Footnotes:
NA-Plot applicable NO-Data not available CS-Canceor Suspect Agent OX-Oxidizer Cor-Corroslve CALC-Colcutoted ES1-Estimoted STEL-Short Time Exposure Limit TLY-Threshold Limit Value PIL-Pqrmirt;ýibte Exoovrce Lituit rWA-Time Weighted Average. 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> NMI$, PPI-Nflaordous Material Identification System, PersonorL Prftoction Index The data preson:ed i* true and correct to the best of our knowledge and belief, however, neither seltter nor preparer sakes any warranties, oxpress or imptic0l, concerning the infor.ation presented. The user is caution*e to perform his own halard ovatu3tion and to rely upon hii. own detormitaionm.
I SCIENTIFIC INFORMATION SERVICES CHEMICAL ASSESSMENT, RESPONSE AND EVALUATION CORPORATIONJ I
,T%,ephone 1817) 560-4631 Form .,zscitiolly the sa;me is OSHA Form 174 dotcd SCptchbor 1985 0.,te Juri y 11, VPrcpartiorn 300 20 I 76 I
- 1500 Pane 1
.. MATERIAL SAFETY DATA SHEET
.... *........ ident and address Product description: bate: May 17, 2004 ByPas International Name: BYPAS 1500 Series 3333 Production Ct
Purpose:
Multi purpose hard surface cleaner Zeeland, Ml 49464 Fax: 616-772-5400 Proprietary Formula Code: BP1600 FEergency tlephone: 1-800-424-9300 1Product Information: e61-772-5100
.Proper Shipping Name, Hazard Class, UNINdA Number Packing Group, EmergenW Responee Gulcde Number
- ~NO REGULATED...
, ,es ,,redper 49lcFR 1721 o1: . . . .. None.. .
Size for "Limited Quantity" per 49 CFR 173.1-, 15._155:. Not appli!cable
.Reot5 eQ0tiy(R* e 4 F1211 None or not possible Inone non-bulk pm.ckage Reporting required by Title III Sec 313, 40 CFR 372. 29 CFR 1910.1200 Exposure Limit Values CAS# 313 Material or Component % RQ# TWA STEL
- 732-18-5 Water '.76 6834-92-0 S1iic Acid, Disodlum Salt 1 blend Chelating Agent 3 proprietary Alcohol Ethoxylate Blend 6 015821-83-7 Propylene PNB 4 No oomponient Is listed In*THRESHOLO LIMIT VALUES AND BIOLOGICAL EXPOSURE INDICES FOR 20010 from ACGIH exoept as noted above. Components listed InTITLE III SEC 313 (EPCRA) are Indicated by "Yes' above.
California oteria: Constituents qualifying as hazardous materials, substances or waste, other than above, Ifany, have been neutralized or denatured to a non hazardous conditIon. Regulations referenced: California Health a Safety Code Ch 8.95 Sec 25501(k) & (I),CCR Title 22ý, Sec 66261.21..24,and Apmndlx X,0f 22 CCR Chapter 11, Article 4.
Emergency overview: Water based degreaser and floor cleaner, Follow label directiona.Use standard industrial good practices.
Haz.owCategones: Health Fire Pressure Reactivlt Reference 49 CFR 171.8 & 173, Immediate Yes I No I No N o-] OSHA 29 CFR 1910.1200 and DelaiA HMIS Hazard Ratsnns:
. No I XXX I XXXI XX SARA 302/3111312/313.
Health 1 Fire 0 Instabiit~y 0 Other NA NFPA Hazard Ratings: Health I Flammablity ,0+B63 Reacivty 0 Special NA Hazard Rafnts: .Least 0 Slight I Moderate: 2 High: 3 Extreme: 4 Threshold limit value: Not established on Product E TOSCA.Status: All inoedients listed .. CERCLA RQ: See S 2.
California Prop. 65: None
. .......... .. -I;' A "A " .. . . : - . .
Appearance: Blue Liquid Flash point dog. F (cc): >200 Odor: Slight Cherry Initial bolling pont deg. C: NA Specific gravity- Approx. 1 Vapor pressure 20 deg C: NA pH reaction: 11.50 Freezing point deg. C: NA
% hpos.horous: 0.00 Solublity in water: 100%
VOC content: <50 a/n Callfomia Rule 102 (66): Contains no photochamically active materials.
Reoroductive Implications: None Inaredients on cancer lists: None 91"17
I
-I General . Avoid contact with eyes and skin. Wash off Ifcame in contact With.
I Avoid breathing mists. Keep lid on containers when not in use.
Keep away from children.
I ProtecOve equipment I Fyes Skin I Safety alaeses or goggles should be worn Ifthere Is osslbility of eye contact.
I Impermeable gloves such as rubber, PVC or neoprene are recommended.
Respiratory protection I None normally required. If risk of inhalation occurs, slect and use I
equipment according to OSHA/NIOSH guidelines for nuisance mists.
Ventilation Other None I As required for worker comfort I
..... l~t . 1 -IA -A~~
-AW--_ ----- ----
Effects of chronic over exposure Eyes Skin fDetergents may cause severe Irritation.
Can cause Irritation from defattinA the skin.
I I
Inhalation [Dust and mists may be Irritating to breathing passages.
Ingestion i -,-..
J Not a likely source of chronic exposure.
NNEA New - . ,!.9fVrM,'a- .. .. .. J U
See Sec 4 Lower None Chemical limits
_Explosive Upper Stable None Flash point:
Conditions to avold:. contact with oxidizers and acids Hazardous decomposition products:
I
_____________ None known.
Hazardous
_ )/aI1~z`1n,
........~i~i...
Cannot occurAV
- 4Z .nTIM . i &-till Incompatibility: None known.
RG N Y-
- 0
.. 4 .... *
... I-......
I Fire Extinuishina media Use media appropriate to source of fire.
First Unusual hazards Eyes None IFlush with water-for at least 5 min. Seek medical attention.
I Aid Skin Flush exposed skin with water Until gone. Remove affected clothes and rinse off product. Wash clothes before reuse.
Inhalation _J Ifaffected, remove ndividual to fresh air, get medical attention at I
once if there is an discomfort.
Spills Ingestion Small I large spill I Dilute by giving large amounts of water or milk. Got medical attention. Do not Induce vomiting.
JSmall amounts may be flushed to drain. Comply with federal, I
state and local regulations on reporting spills.
Keep out of watenways. I Product as supplied has none of the characteristics of a "Hazardous waste"f.
Information presented herein has been compiled from sources considered to be accurate and reliable, but Is not guaranteed to be so. Since conditions of use are beyond our control we make no warranties, I
expressed or implied.
MSDS prepared by: R.N. Miller 1-800-342-3577 I
I I
0178 I
MATERIAL SAFETY DATA SHEET ORGANIC ORANGE SECTION I - IDENTIFICATION COMPANY NAME Barnell, Inc.
COMPANY ADDRESS 6101 Comly Street Philadelphia, PA 19135 PHONE NUMBER 215-333-6700 EMERGENCY PHONE NUMBER 800-256-3924 EFFECTIVE DATE 0910112008 REViSED DA T`E 09101/2008 CHEMICAL NAME Orange Distillate TRADE NAME Organic Orange SECTION l -INGREDIENTS COMPONENTS PERCENT TLV (Units) PROD. CAS ..
1, 8 (9)-p-Methadiene 60>95% Not Established 6989-27-5 Nonylphenoxy 5<40% Not Established 26027-38-3 SECTION III - PHYSICAL DATA BOILING POINT (F) 175.5*C SOLUBILITY IN H20 Emulsifiable APPEARANCEIODOR Clean colorless liquid, citrus odor SPECIFIC GRAVITY (H20-1) .86 PH SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT IS Closed Cup.
EXTINGUISH MEDIA Use foam, dry chemical or CO2 FOR FIRE Minimize breathing vapor-or fumes. Cool fire exposed containem. Do not enter confined fire spaces without proper protective clothing, including self-contained air supply.
USUAL FIRE HAZARD Burning liberates carbon monoxide, carbon dioxide and smoke.
SECTION V - HEALTH HAZARD DATA OVER EXPOSURE EFFECTS Liquid may be irritating to eyes and skin. Vapor is irritating to throat and lungs.
FIRST AIR PROCEDURES EYES: Flush with plenty of water for at least 15 minutes. Seek medical attention immediately.
INGESTION: DO NOT INDUCE VOMITING. Give large quantities of water. Seek medical attention immediately. INHALATION: Remove to fresh air.
SKIN: Wash with water. If irritation develops or persists seek medical attention.
0 179
I
-I MATERIAL SAFETY DATA SHEET I
ORGANIC ORANGE I
SECTION VI- REACTIVITY DATA CHEMICAL STABILITY CONDITIONS TO AVOID Stable Excessive heat and flames. Avoid strong I oxidizing agents.
INCOMPATIBLE MATERIALS DECOMPOSITION PRODUCTS HAZARDUS POLYMERIZATION Strong acids, strong oxidizers Carbon dioxide, carbon monoxide Will not occur I
POLYMERIZATION AVOID SECTION VII - SPILL OR LEAK PROC EDURE I FOR SPILL Absorb with inert material and dispose of in WASTE DISPOSAL METHOD accordance with applicable regulations.
Dispose of according to all local, state and federalegjulations.
I SECTION VIII- SPECIAL PROTECTION RESPIRATORY PROTECTION VENTILLATION None required under normal use.
Local I
PROTECTIVE GLOVES Rubber EYE PROTECTION OTHER PROTECTIVE EQUIPMENT Chem ical goggles I HANDLING AND STORAGE S TORE IN A COOL, DRY, WELL-VENTILLATED REA.
,EEP CONTAINER CLOSED WHEN NOT IN USE.
I EEP AWAY FROM HEAT AND FLAMES.
SE WITH ADEQUATE VENTILATION.
EEP OUT OF REACH OF CHILDREN.
FEAR SAFETY GOGGLES AND RUBBER I
SECTION IX - SPECIAL PRECAUTIONS LOVES WHEN HANDLING THIS PRODUCT.
I DOT SHIPPING NAME C,ombustible Liquid, n.o.s., NA 1993, PG III DOT LABLE REQUIRED REPORTABLE QUANTITY (RQ)
NA NUMBER None Required N/A NA 1993 I
N/A UN NUMBER COMMENTS The information contained herein is furnished I
without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them to assure I
proper use of these materials and the safety and health of employees.
I I
0180 I
I PENETCNE-(74) TEL No.20156?8720 Sep 6,95 9:00 No.001 P.02 EflO. C? / 74h MATERIAL SAFETY DATA SHEET Penmnee Corpotatfon, 74 Hudson Ave., Tonay, NJ 07670 CITRIKLEEN* Page: I of 4 Date Prepaied: July 2. 1894 MSDS No.: 1&5%4076 SECTION 1 PRODUCT IDENTIFICATION & EMERGENCY INFORMATION, PRODUCT NAME: CITRIKLEEN GENERAL USE. aeuing degireahn PRODUCT DESCRIPTION: solvent emulion GENERIC INGREDIENTS: Water. drimoneno, surffafnSW. coupling agents. alkanwrilane EMERGENCY TELEPHONE NUMBERS: PENETONE 201-567-3000 CHEMTREC 600.424-9300 SECTION 2 HAZARDOUS INGREDIENT SECTION This product to hazardous as defined In 29 CFRI910. 1200.
OSHA HAZARD: FLAMMABLE. CORROSIVE OSHA HAZARDOUS INGREDIENTS EXPOSURE LIMITS 8 hrs. TWA (ppm)
D'limonene 5989-27-5 not established not established --
MSECTION3tH L INFORMT 141I43-5 3P -I SECTION 3 HEALTH INFORMATION & PROTECTION EMERGENCY OVERVIEW:
Clear amber liquid with citrus odor.
Flammn elo.Can be corrosive to eyes, skin, and respiratory tract.
POTENTIAL HEALTH EFFECTS:
EYE CONTACT:
May cause irritation or burns to eyes on prolonged contact HoIh vapor conoentrabons may be Irritating.
SKIN CONTACT:
Frequeno m prpolngeol contact may Irritate or dry the s6in, Cause deimabus or Cause bums. Skin contact may aggravate an exilting dermanitia condition INHALATION:
Ho vapor/aerosol concentratlons are irritating or mf..y cause bums to tho respiratory tredt, may cause hendadhes.
dlzlnsem, anesltleslL. drowsiness. un*oonsciousnOes, and other central nervous system effecs.
INGESTION:
Small amounts of this liquid mray be drawn into the lungs by either swallowing or vorniimg. Thi may oau*s evem and delay* health effects suOh as Inflammation of the lungs and Infection of the bronchi. lngstion may caue Irritation of ar bufrm to the digestive Watt.
0181
PENETONE-(74) TEL No.2015678720 Sep. 6.95 9:00 No.001 P.03 CITRIKLEEN Pago: 2o14 Date Propaied: July 2S. 1%4 MS0S No.: 18604079 CHRONIC:
Inflammation af mumn m r~anse r and resptrya tract may ocour upon prolongad breathing ofmiss. Ingestion of lakV amounts of dknrronee has caused kidney and liver damago in mate rats but not ir female rats or momof bolt speds.
Ikestn of large.alnounts of monoelhanoamino has caused kikh and liver damage hi laboratory animnal.
FIRST AID MEASURES:
EYE CONTACT:
Flush eas with large amounts of water. See physpIin Immediolty.
SKIN CONTACT:
Flush eWn wft large amounts o water Rimove contaminawd cloOtng and launder belore reuse. It 3ln Irnltalon develops or persists, ooMLutI physician.
INHALATION' Remove person to fresh ah. Adminir*er oxygen or artificial respirabon ae needed. Call a phpoiiWn mmediately.
INGESTION:
If walkiomd, give plenty of milk or waler. DO NOT INDUCE VOMITING. Use a stomach pump. Call a physlcian Immediataey.
WORKPLACE EXPOSURE CONTROLS:
PERSONAL PROTECTION:
Safety glasse am a rrmmiended tr all workplace conditions. Solvenl resistant govea should be used. Other protbe"iv gear, Inluding splash proot goggles or face shIeld, rubber boefs. upton, gauntets. or rain gear should be worn departg on how the product Isused, VENTILATION:
Nona needed under normal use aditIons. For encoseso areas. or where large amounts of aIe produC¢ ate being used, OIe use of Ia or other mecharical ventilation Isreominmendod An organic vapor mask should be used Itthe TLV Isexceeded and a particle mask Ifgoe product Issprayed DO NOT MIST THIS PRODUCT. Use coawe *pray only.
SECTION 4 FIRE & EXPLOSION HAZARDS FLASH POINT: 25"F PMeC, 16sF 0c0 FLAMMABLE LIMITS: notdetermined AUTOIaNION TEMPERATURE; noldetermind GENERAL HAZARD:
Flammable liquld. Can form flanvnable mixtures a or above the Bash point.
Contalners can rupture and explode under fke condItonS due to pressure and vapor buildup.
FIRE FIGHTING:
EIther allow lire to burn out under controlled conditions or oxtingutsh wvith water, foam, or dry chemical.
Cool exposed oontelners with water @pray.
HAZARDOUS COMBUSTION PRODUCTS:
Smoke, fumei, and oxides of carban. nlrogon, and sulur.
SECTION 5 SPILL CONTROL MEASURES LAND SPILL:
Eliminate soucm of lgnron. For salllspis, use absorbent maorial such as towetsor absorbent poedwer. Put all material kIt proper waste disposal containr with lid " covered olvend soed mateble maly speonleously aornbsnL For luger spils, dice spi, remover IfarIkqt and use absorbent material to dry area. Rinse area wlih waer. Put all mawrut into approprlate waste contalner,.
0182
IPENETONE-(74) TEL No.2015678720 Sep 6,95 9:00 No.001 P.04 CITRIKLEEN Page: 3of 4 ODle PNpa.d July25- .1994 MSDS No.: laflO-07S WATER SPILL:
Romove produc from walt siurfewc by slmngng or with sultabli absWO.nte. Mei product contains suriactants which will cause Itto dispose In wale. Localized high concerifionst of tis product may cause fmh Idlls, but no peraistant of klg term efMs wlM remt. Chm*l with locaf anvtronmental reo Wtoy agences for reporting requlmmrits.
SECTION 6 HANDLING & STORAGE STORAGE TEMPERATURE, OF: ambient. DO NOT STORE ABOVE 120 Dog. F. KEEP FROM FREEZING.
GENERAL: Keep way from hoat sources, open flame., and other ignition sources. Do not stofe noer stong oxidants.
SECTION 7 TYPICAL PHYSICAL & CHEMICAL PROPERTIES BOILING POINT, *F: VAPOR PRESSURE, mm Hg at 2rC:
About212 oquat to waste EVAPORATION RATE. Acetone 1: VAPOR DENSITY (Air = 1):
qua to waer equal o walter SOLUBILITY IN WATER: WT% ORGANIC VOLATILES:
emls~fabout 31)
SPECIFIC GRAVITY at 760F: pH:
o.U 102 ODOR AND APPEARANCE:
dear amber liquid wih citrus odor SECTION 8 REACTIVITY DATA GENERAL:
This pooud ia *table and hazardous polymerzation will not occur.
INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID:
Strong ooddizing agents.
SECTION 9 REGULATORY INFORMATION DEPARTMENT OF TRANSPORTATION (DOT):
PROPER SHIPPING NAME:
FLAMMABLE LIQUID. CORROSIVE, N.O.S.
(contais dimonene end athanolamlns)
HAZARD CLASS: 3 IDENTIFICATION NUMBER: UN 2924 PACKING GROUP: Ill LABEL- FLAMMABLE, CORROSIVE FLASH POINT: 12wF TCC pH: 102 TSCA: The igredcnls inthis product are listed on the TSCA inventory.
CERCLA:
Thbs product onWaln no CERCLA reportable meteriOs. Contact Iocal authortl0 to dewnVne ifth.e may be oher Iocal potring requinremits.
,*8
11 UI TEL No.2015678720 Sep II PENETONE-( 74) 6,95 9:00 No.001 P.05 I
CiTRIKLEEN Pgp: 4of4 I
Date Prepared: July28, I194 RCRA HAZARD CLASS:
MSOS No.: 16504079 I
DWIa 4010 haza"Wo waste DI0C01 mt hwardm wate SARA TITLE III: I 311/312 HAZARD CATEGORIES:
Aoule health, Civonlo hoalth, PRe 313 REPORTABLE INGREDIENTS; Diathyte6n gWolol mono(16 1 0elor CASe 112-34-5 <5 wl, NEW JERSEY RIGHT-TO-KNOW INFORMATION:
this product conains water (CASE 7732-18-5), dflimonteb (CASO ,W89-27-5), moncanolammortmum dodec mzae subfonae (CAEN 206113"T-7). noniyphlpW I ethoxaylato (CASe 9016-45-9). diaelbWO glyodo monobutyl elver (CASM 112 6), and monlltamolamine (CAWE 141-43-5).
CALIFORNIA PROPOSITION 65 INFORMATION:
Thl product does not contain any chyetIcea reoogrnzod by ioestate of Cal.forria to cause cancer and/o biM delect or reproduciv ha"m.
SCAQMD INFORMATION:
Is two a photohemtclally Ieactive rnuterla? present? Yes(
What Is ft % by volurne oapholoronirally reactivo malarlal? about 30 VAh Is the VOC comntnt? 31094 Wh IievaporpreiUre*at V(s? 0.14 mm Pg 0 20C SECTION 10 NOTES HAZARD RATING SYSTEMS:
HMIS NFPA KEY HEALTH 1 4 = SeverS FLAMMAB1LITY 2 2 3 Serious REACTIVITY 0 0 2 Moderate I = Sl*ht 0 .WrImal REVISION
SUMMARY
- SUPERSEDES ISSUE DATE:
Ciange in SectIon 6 Sepiember2.8103 I
I FOR A0011104AlL PROOUCT INPRqMATiCKi CONTACT YOURI SALES ENCOINKER FCA AWTIOIIOSAL I4CALT"IAFETY INFORMA hsON, CALL 201 6-WWO I
I THE INFORMATIM PWSEcNTEO MERSINWW VMEN COMPILED FROM SOURFCES CONSIDERED TO BEoFPENDABLE AND ACCURA1f TO THE OESTOF PENEIONES SCNOWLEOOE. THE 06ORUAlIN IqELAWS TO THIS SP'ECIFIC MATERIAL. it MAY NOT BE VALID FMR THIS MATERIAL IFUSED INCOMBNAMiN WITH ANY OTHER MATIFFOqLd OF41N ANY PROCES. IT IS THEUSE~RS RESPONSIDILIlY 10 SATISFY ONESELF AS TOTNE S&JTAtmJTV AND OMPetETVEESS OFTHIS411OIUMITION FOR HIS OWN PAMOIC"L~ USE.
I 0184 I
MATERIAL SA liY L.AIA bMLL (EB.,ltilay Similar to Fom OSHA.2),
,i
/V SECTION I DUCT NAME USA CiZ IR-SANITI~Za I
..... ULAC.DIE 8599--03 Mine Safety Applismnes Company J0j" P.......
TVPACnIRIA 600 Penn Center Boulevard . _ L.gorumo P.ou ae sar__e_
rPitt sburgh , ]Ph 1 .52 15
.- ;Ks- .. .. r d c MWiRO*EcY PHONE No. 412-273. 5500..-M I . .. l .SECTION I! - INGREDIENTS ACTIVE flTGREDIEbNTSs 54.7 SODZIU CARBONATE 497-19-8. 42.2 TRISODIm PBOSPATE 7601-54-9 10.0 ALKYL (C14, 50%1*C12, 40%j C16, 10%)
DINETMS DENZYL AMKONIUI CHLORIDES 139-08-2 2.5 XNERT INGREDIENTS: 45.3 GODMU TRIPOLYPESPRIATE 7758-29-4 SODIM DICARBONATE. 144-S5-8 NATRn 7732-18-5 SISOHMRC LINEIAR A1CONOLS (c11-cli)
POLYETBOXY ZTNANOLS 68131-40-8*
ETAL S 64-17-5 ISOBORNYL ACETATE 125-12-2 SECTION III--PHYSICAL DATA UweI POINT 1I F.) I SPECIFIC GRAVrYI H2O 1) 0.8 skPOR PRESSURE Imm 1No.) ,. %VOLATILE by VOLUME NA VAPOR DENSITY(AIRmI) EVAPORATION RATE( m.l) NA SWIlIN WATER 20% ON 1% AOOUS SOLUTIO 9.5 - 10ý5 PPEARANCE FRAGRANT BLEND OF WHITE POWDER$
AND ODOR SECTION IV- FIRE AND EXPLOSION DATA INMPOINT tMethod useo) O_2449OG) g, LMMABLE umrT8 DRYLI:CEWS L A U91e RA NOMNG MM.. WATER SPRAY (FOG). FOAM. DRY CHMICAL., CARBON DIOXIDE E=nts PROCEDURS BLANKET FIRE WITH EXTINGUISHING MEDIUM MPUSUAL FIRE AND PRODUCT. IS NONREACTIVE AND DOES NOT READILi' SUPPORT r"mo" HAZARDS 0-,m ,r*i 018b
SECTION V -HEALTH HAZARD DATA I
m I
SKIN CUNTACT WITH POWDEIt MAY CAUSE BUMNS. FLUSH AFFECTED AREA WITH CLEAN WATER.
EYE CONTACT WITH POWDER MAY CAUSE CORNEAL BURNS. AVOID RUBBING EYES BECAUSE WATER INSOLUBLE PARTICLES MAY SCRATCH CORNEA.
FLUSH EYES WITH CLEAN WATER WHILE HOLDING EYELIDS APART.
IMMEDIATELY CONTINUE I
FLUSHING FOR AT LEAST 15 MINUTES OR UNTIL IRRITATION SUBSIDES.
CONSULT PHYSICIAN AS SOON AS POSSIBLE.
INHALATION OF A LARGE ENOUGH QUANTITY TO POSE A SIGNIFICANT HEALTH I
HAZARD IS IMPROBABLE.
INGESTION OF POWDER IS HARMFUL OR FATAL.
MXL RAVW EGG WHITE, OR GELATIN SOLUTION, SHOULD INGESTION OCCURe DRINK OR LARGE QUANTITIXS OF WATER.
I AVOID ALCOHOL. CONSULT PHYSICIAN AS SOON AS POSSIBLE.
_SECTION UN.TASL. ...
V1 - REACTIVITY DATA CONDITIONS I
_,.l *..
IKAARDOUS
- LMSzAToN STABLE MAY OCCUR
! WILL NOT. OCCUR X CONDmONS AVOID NONE NONE I
HAZARDOUS OECOMPOSITION PRODUCTS NDTERMNED 1
RCOMPATISILTY (MATERIAILS TO AVOID)
OXIDIZING AGENTS SOAP AND XXIONIC SURFACTANTS DEACTTVAT! GE1MTCTfE I SECTION VII -SPILL OR LEAK PROCEDURES STEPS 7O BE TAKEN IN CASE MATERIAL S I
I RELEASED OR sPED SWEEP U?
WASTE DISPOSAL METHOD IRMOVE To SANITARY LANDFILL AWAY FRCOM WATER SUPPLIES
,DESTROY EMPTY CONTAINERS I
SECTION VIII- SPECIAL PROTECTION INFORMATION I
Pwmcrow NOT REQUIRED SPECIAL I
PROTECTION NOT REQUIRED EVE I
- o~cnoNOT REQUIRED SECTION WX- SPECIAL PRECAUTIONS I
SPECIAL HANOUNG PRECAUTIONS NOT REQUIRED I SP ECIAL SRTE PRECAUTIONS NOT REQUIRED. MINIMUM SHELF LIFE 6 MONTHS.
MAXIMUM SHELF LIFE AVOID HIGH HUMIDITY AND STORE IN
-A-CLEANo DRX PLACE.__
FOR I
I I~ TTWT
- 01. '
EnvirOx LLC MATERIAL SAFETY DATA SHEET SECTION I - PRODUCT INFORMATION PRODUCT NAME: H20range2 Concentrate 117 PRODUCT CLASSIFICATION: Water Soluble Cleaner MANUFACTURER: EnvirOx LLC P.O.Box 2327, Danville, IL 61834-2327 1938 E. Fairchild St. Danville, IL. 61832 TELEPHONE: 217-442-8596 EMERGENCY TELEPHONE: 217-431-1911 SECTION II - INGREDIENTS HAZARDOUS INGREDIENTS: Hydrogen Peroxide < 4% - CAS No. 7722-84-1 SECTION III - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: None FLAMMABLE EXPLOSIVE LIMITS % BY VOLUME: Lower: None Upper: None FIRE EXTINGUISHING MEDIA: CO2 or Dry Chemical SPECIAL FIRE-FIGHTING PROCEDURES: None known UNUSUAL FIRE AND EXPLOSION HAZARD: None known SECTION IV - PHYSICAL DATA BOILING POINT: 212 Degrees F.
SPECIFIC GRAVITY (Water=l): 1.019 SOLUBILITY IN WATER: Complete MELTING POINT: Unknown PH: 3.6 APPEARANCE: Clear ODOR: Citrus SECTION V - PRODUCT HEALTH HAZARD DATA PRINCIPAL ROUTES OF ABSORPTION:
Inhalation - Not Applicable Ingestion - May cause stomach upset Skin - May cause skin irritation if left on for long periods of time.
Eye - May cause eye irritation POSSIBLE SYMPTOMS OF OVEREXPOSURE: Dry skin or stinging sensation EMERGENCY AND FIRST AID PROCEDURES:
Inhalation - Not Applicable Ingestion - Call a doctor or get medical attention. Do not induce vomiting or give anything by mouth to an unconscious person. Drink promptly a large quantity of milk, egg whites, gelatin solution, or if these are not available, drink quantities of water. Avoid alcohol.
Skin - If irritation occurs, rinse thoroughly with water for at least 5 minutes. Apply moisturizing cream. If irritation persists, consult physician.
0187
I PRODUCT: H 2 0range2 Concentrate 117 Page 2
-I SECTION V - PRODUCT HEALTH HAZARD DATA (continued) I Eye - Flush eyes with water for at least 15 minutes holding lids apart to ensure complete irrigation. I If irritation persists, consult physician.
SECTION VI - REACTIVITY DATA I STABLE:
STABILITY CONDITIONS TO AVOID:
Yes None known I
INCOMPATIBILITY (Materials to Avoid):
HAZARDOUS DECOMPOSITION PRODUCTS-Strong Reducing Agents None known I
HAZARDOUS POLYMERIZATION: Will not occur I
SECTION VII I
SPILL, LEAK OR DISPOSAL PROCEDURES WASTE DISPOSAL METHOD: Biodegradable Product. Dispose of PRECAUTIONS IN HANDLING AND STORING:
container according to state, federal and local laws.
Store indoors. Store away from I
OTHER PRECAUTIONS TO BE TAKEN:
strong reducing agents.
None known I
SECTION VIII - SPECIAL PROTECTION INFORMATION I
VENTILATION REQUIREMENTS:
PROTECTIVE EQUIPMENT:
Local Exhaust OK None I
OTHER PROTECTIVE PRECAUTION: None I
HMIS Codes:
Health: 0 Flammability: 0 Reactivity: 0 I
The exact composition of this material is a trade secret.
The information contained herein is correct to the best of our knowledge. The I
recommendations or suggestions contained in this Data Sheet are made without guarantee or representation as to results. We suggest that you evaluate these recommendations and suggestions in your own laboratory prior to use.
responsibility for claims arising from breach of warranty, negligence, or Our I otherwise is limited to the purchase price of the material. Freedom to use any patent owned by anyone is not to be inferred from any statement contained herein. WITH REGARD TO THE MATERIAL, SELLER MAKES NO WARRANTY OF ANY KIND WHATEVER, EXPRESS OR IMPLIED, AND ALL WARRANTIES OR MERCHANTABILITY AND I
FITNESS FOR A PARTICULAR PURPOSE ARE HEREBY DISCLAIMED BY SELLER.
0188 I
01/04 By Denise Voilmer DATE: 01/04 By Denise Vollmer 0189
- =-~-*..~i'i--*i*i- ~i~m m JUN-20 96 15:10 FRIJM:SYNTEC -419-241-6943 TO:610 774 7830 -4aPr8ff__rCr_'
q4 lo-i4 'I- / 1.2, SynTech Products Corporation Material Safety Data-Sheet 520 E. Woodruff Avenue 24 Hour - Call INFOTRAC Toledo, Ohio 43624 *HMIS S1-800-535-5053 Rating H-I I*-O R-0 (419) 241-1215 Section I - Product Identification Product Name: Touch It Upa De-Contaminant*
Effective Date: 4-96
- Do NOT use this product as a skin de-contaminant Section II - Hazardous Ingredients I
Chemical Name 2 Butoxy Ethanol CAS#
111-76-2 WT%
i% +
PEL 5OPPrn TLV 50 Skin contact CARCIG No I
Propane/Butane 74-98-6/106-97-8 6-10% 1000pprn lO00ppm No
- All constituents are listed on the TSCA inventory.
I Section III - Physical Data Boiling Range:
Vapor Pressure (psig) in Can @ 757:
N.D.
65 I
Solubility in Water of Concentrate:
Specific Gravity of Concentrate:
Complete 1.036 I
% Volatile by Volume in Can: 85 Flash Point of Spray:
Appearance and Odor of Spray:
None to 150TF, Tag Open Cup White foam, perfume odor I
pH: 11-12 Section IV - Fire and Explosion Hazard Data I
Flammability as per CPSC Flame Extension Test:
Flammable Limits: LEL: N/A Non-Flammable UEL: N/A I
Extinguishing Media: Foam, dry chemical, carbon dioxide.
Special Fire Fighting Procedures: Keep containers cool. Use equipment to protect I personnel against rupturing, or venting containers.
Fire and Explosion Hazards: Above 120'F, containers may vent, rupture, or burst.
I Section V - Reactivity Data Chemical Stability: Stable I
Conditions to Avoid: Do not expose to temperatures above 120 0F.
Incompatibility (Materials to Avoid):
Hazardous Decomposition Products:
Strong oxidizers, acids or bases, selected amines.
Thermal decomposition may produce carbon I
Hazardous Polymerization:
monoxide and/or carbon dioxide.
Will NOT occur I 0190 I
- ROM: SYNTEC 419-241-5943 TO:61 0 774 7830
(,,o PMEZT2T Section V1 - Health Hazard Data Eyes:
Effects of Overexposure
-N-U096is15: Minor irritation Skin: No evidence of adverse effect from available information Ingestion: Can cause gastrointestinal irritation, vomiting, and diarrhea.
- Inhalation: Product exists as foam. Inhalation of the foam could cause asphyxiation.
Emergency and First Aid Procedures*
- Caution! Do NOT use this product as a skin de-contaminant Eyes: Flush with water for at least 15 minutes.
Skin: Wash exposed area with water and soap.
Ingestion: Do not induce vomiting. Get medical attention.
Inhalation: Treat for asphyxiation.
Section VII - Spill or Leak Procedures Steps to be taken in case container is punctured and material Is released:
Clean up area by mopping or with absorbent materials and place in closed containers for disposal. Consult federal, state, or local disposal authorities for approved disposal procedures.
Waste Disposal Method:
When used properly aerosol products do not generate hazardous waste. Empty de-pressurized containers can not be reused and should be wrapped an put in trash collection. Cans which are pressurized or contain liquid must be disposed of in a permitted waste management facility.
Consult federal, state, and local disposal authorities for approved procedures.
Section VIII - Special Protection Information Specific Personal Protective Equipment-Respiratory Protection! Under normal conditions no respiratory protection is required.
Ventilation; Normal venitlation adequate.
Protective Gloves: None required, protective gloves may be worn.
Eye Protection: None required, chemical splash goggles may be worn.
Section IX - Special Precautions Keep from freezing Keep away from children Special precautionary statement: Please read and follow the directions on the product label.
They are you best guide to using this product in the most effective way, and give the necessary safety precautions to protect your health.
The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of the information.
Prepared by J. Rose Signatureý MSDS -Touch It Up" 0191
I W GEBOU - I GE Betz, Inc.
4636 Somerton Road Material Safety Data Sheet I Trevose, PA 19053 Business telephone: (215) 355-3300 Issue Date: 29-JAN-1997 I EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 I 1 PRODUCT IDENTIFICATION I PRODUCT NAME:
CORRSHIELD NT4204 I PRODUCT APPLICATION AREA:
WATER-BASED CORROSION INHIBITOR.
I 2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the I
U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. I HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME I 7632-00-0 I
SODIUM NITRITE Oxidizer; toxic (by ingestion); potential blood toxin No component is considered" to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.
I 3 HAZARDS IDENTIFICATION I
EMERGENCY OVERVIEW I WARNING May cause moderate irritation to the skin. Severe irritant eyes. Mists/aerosols cause irritation to the upper respiratory to the I tract.
DOT hazard: ORS (when container > RQ)
Emergency Response Guide #31 I
Odor: Mild; Appearance: Light Yellow, Liquid I
0192 I
Fire fighters should wear positive pressure self-contained breathing" apparatus(full face-piece type). Proper fire-extinguishing media:
Flood with water. Use of C02 or foam may not be effective.
POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause moderate irritation to the skin.
ACUTE EYE EFFECTS:
Severe irritant to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols cause irritation to the upper respiratory tract.
INGESTION EFFECTS:
May cause gastrointestinal irritation with possible nausea, vomiting, diarrhea, incoordination, mental confusion, dizziness and lethargy.
TARGET ORGANS:
Prolonged or repeated exposures may cause CNS depression and/or toxicity to the blood.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
Causes irritation of the skin, eyes, and/or respiratory system.
4 FIRST AID MEASURES SKIN CONTACT:
Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes.
EYE CONTACT:
Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES 01 93
I FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing' apparatus (full face-piece type).
EXTINGUISHING MEDIA:
Flood with water. Use of C02 or foam may not~be effective.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F MISCELLANEOUS:
> 93C P-M(CC)
I ORS (when container > RQ)
NA3082;Emergency Response Guide #31 1 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
I Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill. 3 7 HANDLING & STORAGE HANDLING:
Contains an oxidizer. Avoid all contact with reducing agents, oils, greases, organics and acids. Do not allow to dry.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION I EXPOSURE LIMITS CHEMICAL NAME SODIUM NITRITE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED 3 ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
I SKIN PROTECTION:
rubber gloves-- Wash off after each use. Replace as 3 I
0o194 i
necessary.
EYE PROTECTION:
splash proof chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Specific Gray. (70F,21C) 1.107 Vapor Pressure (mmHG) - 18.0 Freeze Point (F) 19 Vapor Density (air=l) < 1.00 Freeze Point (C) -7 Viscosity(cps 70F,21C) 8 % Solubility (water) 100.0 Odor Mild Appearance Light Yellow Physical State Liquid Flash Point P-M(CC) > 200F > 93C pH As Is (approx.) 9.0 Evaporation Rate (Ether=l) < 1.00 NA = not applicable ND = not determined 10 STABILITY & REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B" 11 TOXICOLOGICAL INFORMATION Oral LD50 RAT: 570 mg/kg NOTE - Estimated value Dermal LD5O RABBIT: >5,000 mg/kg NOTE - Estimated value 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Daphnia magna 48 Hour Acute Toxicity (Estimated)
LC50= 1210; No Effect Level= 790 mg/L BIODEGRADATION COD (mg/g): 42 13 DISPOSAL CONSIDERATIONS 0195
I If this undiluted product is discarded as a waste, hazardous waste identification number is Not applicable.
the US RCRA
-I Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding I
the proper disposal of this material.
14 TRANSPORT INFORMATION I DOT HAZARD:
UN / NA NUMBER:
ORS (when container > RQ)
NA3082 I
DOT EMERGENCY RESPONSE GUIDE #: 31 15 REGULATORY INFORMATION I TSCA:
All components of this product are listed CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
72 gallons due to SODIUM NITRITE; in the TSCA inventory.
I SARA SECTION 312 HAZARD CLASS:
Immediate(acute);Delayed(Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds I
SARA SECTION 313 CHEMICALS:
CAS#
7632-00-0 CALIFORNIA REGULATORY INFORMATION CHEMICAL NAME SODIUM NITRITE RANGE 11.0-15.0%
I CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
I No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds I
16 OTHER INFORMATION I
NFPA/HMIS Health 2 CODE TRANSLATION Moderate Hazard I
Fire 1 Slight Hazard Reactivity Special (1) Protective Equipment 0
NONE B
Minimal Hazard No special Hazard Goggles,Gloves I
(1) refer to section 8 of MSDS for additional protective equipment recommendations. I CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES I
MSDS status: 29-JAN-1997 ** NEW **
I I
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Custom Environmental zt) bi fct'J*10"4ý1 - "
Bridge Drive Technology, Inc.
ur- I X I'VI.,
I Collegeville, (610) 409-821.0 PA 19426 I 24-Hour HealthlEnvironmental Emergency Phone: 1-BlO-973-1130 M Effective Date: 4/19/00 Material Safety- Data Sheet MSDS No: 16091 3SFCTjON I-PRODUCT IDENTIFICATION ZETA LYTE 15 I.hl1 I hCblemical Family: Copolyrner of a quaternary acrylate salt and Flammability I acrylamide. Reactivity 0 3 Protecfive Equipment x fINMIS RATING I Intended Use or Product Type: Flocculant SECT10N 2. COMPOSITION/INFORMATION ON INGREDIENTS o CAS No. CRIEMCUCA, IDENTITY EX1,oSURE LIMITS CARCINOGEN S STATUS H AcMI-I- OSIA -- MFR. IAcI NTI OS*,A A ______TWVA STEL PEL -STEL____ __
- 124-04-9 ADII'IC ACID 5 NE NE r- NE NRi 1\1R NR CPLYERCYLMDE
'~691 E ENE NE E N R N DMAEA Q.(McCl)
NE =Not Established NR Not Reviewed OSHA Hazardous Ingredient U SECTION 3. HAZARDS W1EN11FICATION Emergency Overview:
Description:
Wbite, free flowing powder with little or no odor.
Stalcnrtent ofHazards: Eye irritant I Printed: 6/20/00 Page 1 of 8 0197
93/.g/21D4 12:'12@ 31 tJ40YE8*'I' UEPI INClL I-r_-,utr KJJ Effective Date: 4/l1WOO Preautito-ary Meastres: Do not get in eyes, on skin, on clothing. Wash thoroughly after handlixng. Avoid prolonjged or repeated inhalation of dust or skin contact. Slip hazard wheni wet_
. I - L-
!II Primary Route(s) of Entry! Inhalation Signs and Symptoms of Exposure: Contact with the eye may produce irritation and/or redness. Inialed dust may cause some respiratory irritation.
Carcinogenicity: Not listed as a carcinogen by 1ARC, NTP, OSHA or ACGITI I
Medical Conditions Aggravated by Exposure: Existing respiratory conditions.
Target Organ(s): Eyes, lungs I SEON 4.o fRSTAID M EASUiRS I
Ingestion: Do not give an emetic unless directed by a physician. Never give anything by mouth to an unconscious person.
Skin: Remove coritainnated clothing and launder before reuse. Wash effected area with soap and water. I Inhalation: Remove to freslh air.
Eyes: Inunediately flush eyes with plenty of water for at least 15 minutes. Call a physician.
I
-SECTION 5. FIRE FIGHTING MEASURES Flash Point: Not Applicable I I Antoignition: Not Evaluated I
Sensitivity to Mechanical Impact: None Sensitivity to Static D)scbarge: Dust in sufficient concentration may result in an explosive mixture in air. I Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical or foam.
Fire Fighting Equipment: No special procedures. However, wetted product presents a slip hazard. Pedestrian and vehicular traffic I
must proceed with caution where wet product may exist.
Fire and Explosion Hazards: Dust in sufficient concentration can result in an explosive mixture in air. Handle to rninimize I
dusting, and eliminate open flame and other sourcc.r of ignition-Hazardous Combustion Products: Oxides of carbon and nitrogen. I Combustibility: May burn in fire.
Dust Explosivily: Dust in s:uficient concentratioln may result in an explosive mixture in air.
I Emergency Respo ne Guidebook Informiation: ,o ERG Guide cite& Handle as combustible ratcrial.
I Printed: 6/20/00 Page 2 of g 0198 I
I~l~fl~'2@tl4 22): 2U I..?
I U 4 IYJ b'- I !:*
iJUbl -- I- I -L I'll, I 1 "fety~r~e 119/00 l
- I .IIJP 6. ACCID)ENTAL RELEASE MEASURES I Accidental Release Mieasures: Pzoduct becomes slippery and difficult to handle when wet. spills are best handled while- still dry.
I Sweep up and collect dry product. Absorb wet product with vermiculite or other inert material. Then water wash area to waste treatment to eliminate slip hazard-
- SECTION 7. HIAINDIJNG AND STORAGE I Precautions: Good personal hygiene practices can iwduce potential exposure. Wash with soap and water following any contact with this product, as ivell as before breaks and meals. Shower and change clothing at end of work shift. If clothing becomes contaminated, remove and launder or dry-clean before reuse.
Storage Information: Store in cool dry location.
4" I
SEcCTION H.EXPOSURE CONTROIS I PERSONAL PROTECTION I i Skin Protection: Not nonnally required.
I Respiratory Protection: Us*. NIOSH approved dust rerpilator as required to control exposure. Follow ANSI ZBS.2.
Eye Protection: Goggles (ANSI Z87.1 std; safety glasses alone do not protect from dust).
I Engineering Controls: Provide mechanical vuntilatiorn to prevent dust concentrations, and to reduce potential exposuie.
Additional Information: Provide eyewash station(s). Select additional piotective equipment (eg apron, face hicld, etc.),
depending on conditions of use.
a SECTION 9. PHYSJCAL AND CHENUCA1, PROVERTI ES I J ETO .PYIA M)CEiA RPRIS-i rhysical Form: Granular Powder Color: White Odor: Odorless Odor Threshold: Not applicable Physical State: Solid Solubility in Water: Soluble, solubility limited by viscosity Vapor Pre.ssure: Not Applicable Specific Gravity: 0.8 - I Boiling Point: Not Applicable Melthig Point: Not Applicable Freezing Point: Not Applicable Decomposition Temperatur,: Not Evaluated Evaporation Rate: Not Applicable Vapor Density: Not Applicable VOC: Not Applicable pH: - 3.3 For 1% solution.
Coefficient of wateraoil: Not Evaluated Percent Volatile:
None expcected above trace .levels Printed: 6/20100 Page 3 of 8 0199
LIJ/jI / k.,'[)LV 2 -eZt bi U- ItYib.1 Zi~,-.---
Effective Date: 4/119/00 I SECTIONI10. STA lITY AND REAC'iVITY I
Conditions to Avoio;: Avoid wet and humid conditions.
Stability; Stable.
I Hazardous Polymerization: Will not occur. U Hazardous Decomposition Products: Themial decomposition or combustion may produce oxides of carbbou and nitrogen, various hydrocarbons, ammonia and/Lor hydrogen chloride vapor. Vapor nmay be irritating or harniftiL I Incompatibility: Sti.ong oxidants such as liquid chlorine, enriched gaseous or liquid oxygen, and sodium or calcium lypochlorite.
SECTION II-TOXICOLOGICAL UNFOILMATION I
Acute Oral Toxicity; Low oral toxicity. By analogy to simular maltrials, the acutr.LD50 (rat) is expected to be > 2000 mg/kg.
I Carcinogenicity:
Not listed as a carcinogen by IARC, N-ITP, OSHA, or ACGIH-I Reproductive Toxicity:
No data for product. No effects anticipated. I Teratogiuicity:
No data for product. No effects anticipated-1 Mutagenicity; No data for product. No effects anticipated-Eye Irritation:
I 124-04-9 ADIPIC ACID Severe- I Acute Eye Yxposuri- Effects:
69418-26-4 COPOLYMER ACRYLAMIDE: DMAEA Q.(MeCI)
Product msa cause temporatory irritation which should cease upon removal of producl. May require extensive irrigation to remove product from eye.
I Sub-Chronic:
124-04-9 ADIPIC ACID I
showed 11O Male and female rats exposed to adipic acid in the furrn of aerosol dust (126 ug/L) for 6 hours6.944444e-5 days <br />0.00167 hours <br />9.920635e-6 weeks <br />2.283e-6 months <br /> a day for 15 days signs of toxicity.
I Intraveneous L) 5:
124-04-9 ADIPIC A.CID LDS0(Mice): 680 mg/kg. 1 I11trnperitolleal LO 50:
1240-4-9 ADIPIC ACID LD50(MicE): 275 mug/kg. I Printed- 6120/01) Page 4 of 8 0200-I
I03/18/2004 22: 210 l1,I0'f*lU22 t.- I EIfective Date: 4/1P9100 SToxicologically Synergistic Products:
None known.
IEEE 12. ECOLOGICAL INFORMATION Ecological Informnt:ion:
This product contair:s cationic polymer(s) that may be toxic to aquatic organisms when tested in pure (distilled) water. Toxicity is greatly reduced by particles in natural water.
i Fish Toxicity!
124-0-4-9 ADIPWC ACID 24 hr LC50 (Bulegill sunfish): <330 mg/L.
96 hr LC50 (Fatheadr minnow): 97 rng/L.
69418-26-4 COPOLYMER ACRYLAMIDE: DMAEA Q.(MeCI)
Contains a cationic polyacrylamide. Cationic polyaciylainides are very toxic to aquatic organisms (LCSO values usually <
I ppm): hoviever, aquatic toxicity is reduced by fictors of 1 to 100 times in the presence of 5 to 10 mg/i organic carbon as is found in most surface waters.
Bioaccumulation:
124-04-9 ADMPIC ACID BCF = 0.68 SECTION 13. DISPOSAL, CONSIDERATIONS I RCRA Hazard Clash: This product, when unadulterated, is not a RCRA regulated hazardous waste.
Wsaste Disposal Method: Disposal must be arranged in accordance with local, state and federal regulations. Care must be taken to prevent environmental contamination fromn 1lje disposal of material, Tesidues and containers, SSECTIN 14-TRAINSPOR' INFORMATION I DOT:
Proper Shipping Name: NOT A DOT/IMO HJAZARDOUS MATERIAL SE-IO N REG*rLATO RY INFORMD*IATION 3 US Federal Regulations-E Chemical Weapons Convention (CWC): This product does not contain any chemicals listed under the Chemical Weapons Convention Schedules of Chemicals.
Clean Air Act -Hazardous Air Pollutants (IAP).: Tihe following chemical(s) are listed as havardous air pollutants (HAP) undei thr US. Cl-an Air Act Section 12 (40 CTR 61):
I Chenical Name: 2-Propemanide Common Name: Acrylamide U CASRN: 79.06-1 Percent in Composition: < 0.1 % by wt I Printed: 6120100 Page 5 of S a02:1-
133!1/211c22: 203 11104U' 2~LN' -,..
- Effective Date: 4/19/00 U
Clean Air Act - Ozitae Depleting Substances (ODS): This product neither cohtains, nor was manulachtred with, a Class I or Class I oz.oie depicting substance (ODS), as detirncd by die U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App. A 1-1).
I lean Water Act - Priority .Poltijtats (PP): This product does not contain any piiority pollutants li;ted under the U.S. Clean Water Act Section 307 (2)(1) Priority Pollutant List (4if) CFR 401.15).
Ocepatiormal Safety and Ilealth Act (OSIIA): This product is considered to be a hazardous cl:.mical under tie OSHA Hazard CommunicatiunStandard (29 CFR 1910-1200).
Resounrce Conserval ion and Recovery Act (RCRA): This product is not considerd to be a P or U listed hazardous waste under RCRA (40 CFR 261). I SARA Title III: Section 302 - Extremely Hazardous Substances (EHS): This product contains the following chemicals regulated under Section 302 (40 CFR 355) as extremely hazardous substances: I Chemical Name: ACRYLAMIDE CASRN: 79-06-1 Percent in Composition: < 0.1 % by wt I
SARA Title IlI: Setlion 304 - CERCLA. This product contains the following cbemicals regulated under Section 3091 (40 CFr.
302) as hazardous sul-stance(q) for ernlgercy rcleae notification ("CERCLA" List):
I Chemical Name: ADIPIC ACID CASRN: 124-04-9 Percent in Composition: <5% by wt I
Component RQ: 5000 Chemical Name: ACRYLAMIDE I
CASRN: 79-06-1 Percent in Composition: < 0.0 Component RQc 5000 1a% by Wt I
SARA Title IUl; Section 311/312 - Hazard Comminicalion Standard (UCS): This product is regulated under Section 311-312 (40 CFR 370). Acite bealth hazard. I SARA Title III: Section 313 Toxic Chemical List (TCL): This product does not contain any chemicals fir routine annual toxic chemical release reporting under Section 313 (40 CFR 372).
TSCA Section 5(c) - Consent Order / SNIJR: This product is not subject to a Section 5(e) Consent Order or Significant New Use I
Rule (SNUR)-
TSCA Section 8(b) - Inventory Status: All cheniical(s) comprising this product are rither exempt or listed on the TSCA I
inventory.
T'SCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
I export notification.
'Sta1te R-egulaý__1tioll.q: I I
California Proposition 65: The following is requiled composition information. T-hsis product contlails the bollowing chemical(s) which are currently listed on the (alifnoria list of Known Carcinogenis and Reproductive Toxilso Printed: 6120/00 Page 6 of 8 0202 I
I l , _': IuU H1:i L I Effective Dnte: 4/,19100 I Chemical Name: ACRYLAMIDE CASR.N. 79-06-1 Percent in Composition: < 0. "0 % by wt IMassachusetts Rigbt-to-Kn0ow: The following is required composition information:
I Chemical Name: ADTPIC ACID CASRN: 124-04-9 Percent in Compo:;ition: <5% by wt i Chemical Name: ACRYLAM1DTH CASRN: 79-061 Percent in Composition: < 0.10 % by wt I Nvw Jersey light-fa-Knuw. The following is required composition information:
Chemical Name: COPOLYMER ACRYLAMIDE: DMAEA Q.(MeCI) i CASRN: 69418-26-4 Chemical Name: WATER i CASjRN: 7732-18-5 Chemical Name: AD) PIC ACID CASSRN: 124-04-9 Pennsylvania Right-to-Know: The following is required composition information'.
I Clemical Name: COPOLYMER ACRYLAMIDE: DMAEA Q.(MeCI)
CASRNI: 69418-26-4 Comment: Not on Pennsylvania Hazardous Substance List I Chrmical Name: WATER CASRN. 7732-18-5 Conunent: Not on Pennsylvania Hazardous Substance List I Chemical Name: ADITPC ACID CASRX: 124-04-9 IComment: Envira H1azardous Substance nEionatal
-SECTION 16-. 01-HER INFORMIATION MSDS No: 16091 Reason Issued: New format i Prepared By: Leon Knight Approved By:
I SectionsModified: All sections. Revised foimat.
Disclaimer: The fol owing supciccdes Buyei's documients. SELLER MAKES NO PRESENTATION OR WARRANT-VY, EXPRESS OR IMPLIED, Nhi.jUDINcG OF MERCHANTAfI-IA-TY OR FITNIESS FOR A PARTICULAR PURPOSE. No statements herein are to be consmtred as inducements to inFringe any relevant paten. Under no circumstances shall Seller bc liable Printed: 6120/00 Page ,7 8o of
I~M. I*IrJ L)ULI4,Z:ZU 01 U 140Li U LI I-L I LI'11- r HkL3':_ rj j I
Effective Date: 4/1'/10 for incidental, consequential or indirect damage, l.r alleged negligence, breach of warranty, stiict liability, tort or contract arising in connection with tht product(s)_ Buyer's sole remedy artd Seller's sole liability for any claims shall be Buyer's purchase price.
Data and results are based on controlled or lab work and must be confirmed by Buyer by testing fur its Jutendcd conditions of use.
I "7he product(s) has not been tested for, and is therefore not recon mended for, uses for wicich prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within ithe human body is inten.hded. I I
I I
I I
I I
I I
I I
I I.
I Pxinted: 6120/00 Page g of 8 0204 I
MATERIAL SAFETY DATA SHEET N4NALCO PRODUCT NALCO 9905 FLOCCULANT EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC S1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: NALCO 9905 FLOCCULANT APPLICATION: FLOCCULANT COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 0/1 FLAMMABILITY: 1/ 1 INSTABILITY: 0/0 OTHER:
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme I 12. I COMPOSITION/INFORMATION ON INGREDIENTS I I Based on our hazard evaluation, none of the substances in this product are hazardous.
1 53 I HAZARDS IDENTIFICATION I1
- EMERGENCY OVERVIEW**
CAUTION May cause irritation with prolonged contact. Toxic to aquatic organisms.
Do not get in eyes, on skin, on clothing. Do not take internally. Do not breathe dust. Water in contact with the product will cause slippery floor conditions. Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water.
May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve ammonia under fire conditions. Water in contact with the product will cause slippery floor conditions. May form explosive dust-air mixtures.
PRIMARY ROUTES OF EXPOSURE :
Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:
EYE CONTACT:
May cause irritation with prolonged contact.
SKIN CONTACT:
May cause irritation with prolonged contact.
INGESTION:
Not a likely route of exposure. No adverse effects expected.
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1/10 0205
I MATERIAL SAFETY DATA SHEET
- 4NALCO NALCO 9905 FLOCCULANT PRODUCT I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC INHALATION:
I Repeated or prolonged exposure may irritate the respiratory tract.
SYMPTOMS OF EXPOSURE:
Acute :
I A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic:
A review of available data does not identify any symptoms from exposure not previously mentioned. I AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions. I HUMAN HEALTH HAZARDS - CHRONIC:
No adverse effects expected other than those mentioned above.
- 14. 1FIRST AID MEASURES I
EYE CONTACT:
Flush affected area with water. If symptoms develop, seek medical advice.
I SKIN CONTACT:
Remove contaminated clothing. Wash off affected area immediately with plenty of water. If symptoms develop, seek medical advice.
I INGESTION:
Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If symptoms develop, seek medical advice.
I INHALATION:
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.
I NOTE TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.
I
- 15. 1FIRE FIGHTING MEASURES I FLASH POINT: Not applicable EXTINGUISHING MEDIA:
Not expected to burn. Use extinguishing media appropriate for surrounding fire.
I FIRE AND EXPLOSION HAZARD:
May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions.
May evolve ammonia under fire conditions. Water in contact with the product will cause slippery floor conditions.
I May form explosive dust-air mixtures.
I Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/10 I
0206
MATERIAL SAFETY DATA SHEET PRODUCT PNALCO NALCO 9905 FLOCCULANT EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
- 16. 1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Notify appropriate government, occupational health and safety and environmental authorities. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).
METHODS FOR CLEANING UP:
Remove as much as possible with broom, scoop or vacuum, as the addition of water causes slippery floor conditions. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
Water in contact with the product will cause slippery floor conditions.
ENVIRONMENTAL PRECAUTIONS:
This product is toxic to fish. It should not be directly discharged into lakes, ponds, streams, waterways or public water supplies.
- 17. HANDLING AND STORAGE HANDLING:
Do not take internally. Ensure all containers are labeled. Avoid eye and skin contact. Avoid generating dusts.
STORAGE CONDITIONS:
Store separately from oxidizers. Keep in dry place.
SUITABLE CONSTRUCTION MATERIAL:
Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use., Do not use aluminum or mild steel., Copper
- 18. 1EXPOSURE CONTROLS/PERSONAL PROTECTION I OCCUPATIONAL EXPOSURE LIMITS:
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
ACGIH/TLV:
Substance(s)
Respirable Nuisance TWA: 3 mg/m3 Particulates Inhalable (Total) Nuisance TWA: 10 mg/m3 Particulates OSHA/PEL:
Substance(s)
Respirable Nuisance TWA: 5 mg/m3 Particulates Inhalable (Total) TWA: 15 mg/m3 (total dust)
Nuisance Particulates Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198, (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/10 02_07
I MATERIAL SAFETY DATA SHEET P4*NALCO PRODUCT -I NALCO 9905 FLOCCULANT I
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
ENGINEERING MEASURES:
General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are generated.
I RESPIRATORY PROTECTION:
Respiratory protection is not normally needed. An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. A dust respirator may be used.
I HAND PROTECTION:
Nitrile gloves, PVC gloves, Neoprene gloves, Rubber gloves, Butyl gloves, Cloth gloves I
SKIN PROTECTION:
Wear standard protective clothing. I EYE PROTECTION:
Wear safety glasses with side-shields.
HYGIENE RECOMMENDATIONS:
I Keep an eye wash fountain available. Keep a safety shower available.
HUMAN EXPOSURE CHARACTERIZATION:
I Based on our recommended product application and personal protective equipment, the potential human exposure is: Moderate
- 19. 1PHYSICAL AND CHEMICAL PROPERTIES I
PHYSICAL STATE Granular I APPEARANCE White ODOR Slight, Ammoniacal I SPECIFIC GRAVITY 0.75 DENSITY SOLUBILITY IN WATER pH (5 %)
6.2 lb/gal Partial 2.5 - 4.5 I
VOC CONTENT 1.0 % Calculated Note: These physical properties are typical values for this product and are subject to change.
I
- 10. STABILITY AND REACTIVITY I
STABILITY:
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
I Hazardous polymerization will not occur.
Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198. (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 4/10 0208 I
MATERIAL SAFETY DATA SHEET
- NALCO PRODUCT NALCO 9905 FLOCCULANT EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC CONDITIONS TO AVOID:
Avoid extremes of temperature. Moisture MATERIALS TO AVOID:
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS:
Under fire conditions: Oxides of carbon, Oxides of nitrogen, ammonia
- 11. 1TOXICOLOGICAL INFORMATION The following results are for the product.
ACUTE ORAL TOXICITY:
Species LD50 Test Descriptor Rat > 5,000 mg/kg Product Rating : Non-Hazardous ACUTE DERMAL TOXICITY:
Species LD50 Test Descriptor Rabbit > 2,000 mg/kg Product Rating : Non-Hazardous SENSITIZATION:
The results of testing on guinea pigs showed this material to be non-sensitizing.
CARCINOGENICITY:
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
HUMAN HAZARD CHARACTERIZATION:
Based on our hazard characterization, the potential human hazard is: Low 112. 1 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:
The tests for (products or similar products) were performed in clean water as set forth by USEPA (EPA/600/4-90/027). In order to evaluate the potential toxicity mitigation, the tests for (representative polymers) were performed in environmentally relevant water with dissolved organic carbon (DOC: 4.5 mg/I). The toxicity of this product is due to an external mode of action, e.g., suffocation or immobilization. In the presence of suspended material, e.g., DOC, the polymers are bound to suspended material and the bioavailability is substantially reduced. As a result, the toxicity is expected to be lower. Under normal use and discharge conditions, the LC50 values of the representative polymers tested in the presence of DOC are expected to apply to this product. However, for large spills, the clean water data is more applicable.
Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/10 0209
I MATERIAL SAFETY DATA SHEET PNALC0 PODUCT P
-I NALCO 9905 FLOCCULANT I EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
ACUTE FISH RESULTS:
Species Rainbow Trout Exposure 96 hrs LC50 0.21 mg/I Test Descriptor Similar Product I
Zebra Danio 96 hrs 1 - 10 mg/I Representative polymer tested in water with DOC I
ACUTE INVERTEBRATE RESULTS:
Species Daphnia magna I Exposure 48 hrs ILC50 0.34 mg/I EC50 0.26 mg/I Test Descriptor Similar Product I PERSISTENCY AND DEGRADATION:
Chemical Oxygen Demand (COD): 225,000 mg/I I Biological Oxygen Demand (BOD):
Incubation Period Value 5,000 mg/I Test Descriptor Product I
The organic portion of this preparation is expected to be poorly biodegradable.
MOBILITY:
I The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of I
the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment I
<5% 5-10%
The portion in water is expected to be soluble or dispersible.
> 90%
I BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.
I ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: High Based on our recommended product application and the product's characteristics, the potential environmental I
exposure is: Low If released into the environment, see CERCLA/SUPERFUND in Section 15. I
- 13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery I
Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.
Nalco Company 1601 W. Diehl Road. Naperville, Illinois 60563-1198 - (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 6/10 0210 I
MATERIAL SAFETY DATA SHEET
)4NALCO PRODUCT NALCO 9905 FLOCCULANT EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.
I i
i 114. I TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT:
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION AIR TRANSPORT (ICAO/IATA):
Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION 115. I REGULATORY INFORMATION I NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, none of the substances in this product are hazardous.
CERCLA/SUPERFUND, 40 CFR 117,302:
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/10 0211
I MATERIAL SAFETY DATA SHEET PRODUCT SNALCO NALCO 9905 FLOCCULANT I
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC I
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):
I This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
I FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:
When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 I
Components of paper and paperboard in contact with dry foods.
It is limited to use as a retention aid and flocculant employed prior to the sheet forming operation in the manufacture I
of paper and paperboard in amounts no greater than those required to produce its intended technical effect.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311 :
I None of the substances are specifically listed in the regulation.
CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :
I None of the substances are specifically listed in the regulation.
CALIFORNIA PROPOSITION 65:
I Substances known to the State of California to cause cancer are present as an impurity or residue.
MICHIGAN CRITICAL MATERIALS:
None of the substances are specifically listed in the regulation.
I STATE RIGHT TO KNOW LAWS:
None of the substances are specifically listed in the regulation.
I NATIONAL REGULATIONS, CANADA:
I WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
I WHMIS CLASSIFICATION:
Not considered a WHMIS controlled product. I CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.
I INTERNATIONAL CHEMICAL CONTROL LAWS I
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/10 0212 I
MATERIAL SAFETY DATA SHEET j041"NALC PRODUCT
- NALCO NALCO 9905 FLOCCULANT, EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).
EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).
KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)
THE PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).
- 16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:
- The human risk is: Low Low
- The environmental risk is: High Low Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.
This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.
REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9/10 0213
MATERIAL SAFETY DATA SHEET I
P4NALCO PRODUCT
-I NALCO 9905 FLOCCULANT EMERGENCY TELEPHONE NUMBER(S)
I (800) 424-9300 (24 Hours) CHEMTREC IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health I Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-I ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.
I Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
I Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO. I Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD. I The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
Micromedex, Inc., Englewood, CO.
I Prepared By Product Safety Department I
Date issued 10/24/2006 Version Number: 1.10 I
1 I
I I
I Nalco Company 1601 W. Diehl Road o Naperville, Illinois 60563-1198 . (630)305-1000 I
For additional copies of an MSDS visit www.nalco.com and request access 10/10 0214 I
THERMALTAKE TECHNOLOGY USA 525 Parriott Place OOOLeI/ YOUR ~ Cit3, of Industry, CA 91745 TEL: 626-968-9189 FAX: 626-968-1138 hittp: / ivwxvx\. the-im'tlt.,kctis', .com- i MATERIAL SAFETY DATA SHEET CUSTOMER MODEL NO. : COOLANT (PC USE)
DESCRIPTION CUSTOMER PART NO.:
ISSUDE DATE : MAR. 11, 2006 REVISED DATE VERSION B CONTENT CUSTOMER APPROVAL SIGNATURE APPROVED BY VERIFIED BY AUTHOR
I MATERIAL SAFETY DATA SHEET I
I Prlouct, name:-, 'i., PG-USP (Propylene Glycol USP) I Synoyms%!r 7
- 1, 2-Propanediol; 1,2-Dihydroxypropane; 2-Hydroxypropanol;
- ,.*,; ** *,. **'i
- ,;*:,;,**:,:**:5.j:
sopropylene Glycol; Methylothylene Glycol; Methylethyl Glycol; Monopropylene Glycol; 2,3- Propanediol; Alpha-Propylene Glycol; 1,2-I Chmial Formula*,*
Propylene Glycol.
CH3CH(OH)CH2OH I
Chemical Famil-y;i* Glycol I Product',Codes -i I
'Suppliero:- onmi'on Thermaltake Technology Emergency phone 800-988-1088 I
!nunibers" -
iquid EEmergency, NFPA RATINGS (SCALEI 0-4):I HEALTH=0 FIRE=1 REACTIVITY=0 v<e w, 3/4. Odorless, clear, colorless, hygroscopic, viscous liquid with a slightly acrid taste avoid contact with eyes. Keep container tightly closed. Wash thoroughly after handling. Handle with caution.
i al Health 0216 I
tRoute 'of Entry,* '*: *
,Effects'-
. .:..YiEyes Short term effects: May cause minor eye irritation.
SLong term effects: No information is available.
-. ,, kin Short term effects: No information available on significant adverse effects.
., ' *- Long term effects: No information available on significant adverse effects.
, Anhalation]
I Short term effects: No information available on significant adverse effects.
- r Long term effects: No information available on significant adverse effects.
S, i Short term effects: No information available on significant adverse effects.
Long term effects: No information available on significant adverse effects.
Carcioe IOSHA: N; NTP:N; IARC:N Wash eyes immediately with large amounts of water or normal saline, occasionally lifting upper and lower lids, until no evidence of chemical remains (at least 15-20 minutes). Get medical attention immediately.
Remove contaminated clothing and shoes. Wash with soap or mild detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes). *--
No expected to present a significant inhalation hazard under anticipated conditions of normal use.
Jirel symptomatically and supportively.
Jo specific antidote. Treat symptomatically and supportively.
Fi 0e-F'hi IIe rid Exls6~~zad
-ira O Slight fire hazard when exposed to heat or flame. Heat from EX sin a fire can generate flammable vapor. When mixed with air and exposed to ignition source, vapor can burn in open or explode if confined. Vapors may travel long distances along the ground before igniting and flashing back to vapor source.
Fine sprays/mists may be combustible at temperatures below normal flash point. Aqueous solutions containing less than 0217
I 95% propylene glycol by weight have no flash point as obtained by standard test methods. However aqueousI solutions of propylene glycol greater than 22% by weight, if heated sufficiently, will produce flammable vapor. Only aqueous solutions of propylene glycol less than 22% should used in sprinkler systems or other fire-fighting equipment.
Always drain and flush systems containing propylene glycol I with water before welding or other maintenance.
Dry chemical, carbon dioxide, water spray orI Jr!*,,;,*
- ,i'-i alcohol-resistant foam. For larger fires, use water spray, fog
- 7-'*or alc~hol-resistant foam. Alcohol foam.
Move container from fire area if you can do it without risk. Do-j 1'not enter fire area without proper protection. Fight fire from a safe distance/protected location. Heat may build enough pressure to rupture closed container/spreading fire/increasing risk of burns/injuries. Use water spray/fog for cooling. Avoid frothing/steam explosion. Do not scatter spilled material with high-pressure water streams. Burning
- liquid may float on water. Although water soluble, may not be practical to extinguish fire by water dilution. Dike fire-control
,, water for later disposal. Avoid breathing hazardous vapors, keep upwind. Notify authorities immediately if liquid enters t sewer/public waters.
210 F (99 C) (CC) I Lwe Flab Upoer* ammrabl Limit t ,. ,.
2.6%
12.5%
I Auto igntn FIýI~at~iility Class (COSHA)
,, 700 F (371 C) 1l11B I
{Hazair)us Combustion Products; Thermal decomposition products may include toxic oxides of (carbon.
I I
Occupational spill May contaminate water suppl ies/pol lute public waters. Evacuate/limit I Saccess. Equip responders with proper protection. Prevent flow to sewer/public waters. Stop release. Notift fire and environmental authorities. Restrict water use for cleanup. Slippery walking. Spread I
0 21_8 I
granular cover. Impound/recover large land spill. Soak up small spills with inert solids. Use suitable disposal containers. On water, material is soluble and may float or sink. May biodegrade. Contain/collect rapidly to minimize dispersion. Disperse residue to reduce aquatic harm.
Report per regulatory requirements. Keep unnecessary people away; isolate hazard area and restrict entry.
H*andling,, Hygroscopic. Use dry nitrogen or low dew point air for tank padding. Keep
- ,drums tightly closed to prevent contamination.
Stortage,* Store at 18-32 C. store away from incompatible substances.
0219
I
-I I
00.
Descrion Clear, colorless; little or Specific Graity 10361
'-7 no odor; Aromatic, sweet o' I
Mole*uilareig.ttJ 76.11 !Water Solubility Soluble MolecuIlwaFormua' J C-H3-C-H-(O-H)-C-H20 -,-Volatility "-I 100% I Boilin70-372 F (188-189 C) PH No data available Freezing Point -75 F (-59C) ,Odo&'.Threshold "' No data available I
-Vapor Pressure Vapor Dnsity .
<0.ImmHg @ 20 C 262 Evaporation *Rate-'
Viscosity 0.005 (butyl acetate=l) 58.1 cP@20 C I
Solent Slubility Soluble in alcohol, acetone, chloroform, ether, benzene many organic i',*solvents; insoluble in fixed oils .
I I
'Reactivity i¶Stable under normal temperatures and pressures.
Gond6itions to Avoid i May burn but does not ignite readily. Avoid contact with strong oxidizers, I excessive heat, sparks, or open flame.
Ha*zFa ous " Thermal decomposition products may include toxic oxides of carbon. I Polymerization J Hazardous polymerization has not been reported to occur under normal I
-* j temperatures and pressures.
- Acid*A*nhydrdes'I<* t Incompatible Ethylene Oxide Possible explosion I
Acid Chlorides
- Incompatible jNitrogen Tetr6xide J, Possible explosion Chloroformates Incompatible jPerchloriiAcid (Hot) Dangerous interaction I
'Reducing.Agent 8 - Incompatible .. Tri iso Butyl Aluminum Violent reaction OXidizes, - Fire and explosion Pics CS May be attacked Nitric Acid*<""' L Mixture forms explosive Metals (Light) Reaction forms H5lyfrILcAcid andi silver fulminate. .- ... ):'*'1 flammable hydrogen Silver Ni rate ., gas.
Acetaldenyde Violent condensation Barium Perc hlIorate te Formation of highly 1 reaction [ ___,____r_________ester explosive perchloric on refluxing.
0220
I 11 0221
I
- I log' Qctanol/Water partitidonr ,. No data available I
ýDispmsl' or
~f2~ ,.;~:
'11-ons,' I Contaminated product, soil, or water should not be I
~
4*~ designated hazardous waste. Landfill solids at permitted sites. Use registered transports. Burn concentrated liquids, diluting with clean, low viscosity fuel. Avoid flame-outs.
Assure emissions comply with applicable regulations. Dilute I aqueous waste may. Avoid overloading/poisoning plant A~
~
~
biomass. Assure effluent complies with applicable regulations.
I I
classification currently assigned.
I I
I I
I I
I for internal use only
_Authorized I
~PrepardB Weller Chen (Product Manager)
I Date: 2006/4/6 END OF DOCUMENT I
0222 I
MATERIAL SAFETY DATA SHEET IRON (III)OXALATE HEXAHYDRATE, 20% Solution C.A.S. No.: 2944-66-3 ( Solid)
PAGE 1 OF 2 DATE PREPARED: 5/14/1999 SECTION I - Manufacturer's Information BARKER INDUSTRIES, INC. EMERGENCY TELEPHONE NUMBER 2841 OLD STEELE CREEK RD. 1-800-424-9300 CHARLOTTE, NC. 28208 TELEPHONE NUMBER FOR INFORMATION EMAIL: BARKERIND@MSN. COM 1-704-391-1023 SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Iron (III) Oxalate Hexahydrate, 20% Solution SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT: N/A SPECIFIC GRAVITY: 1.12-1.14 @20"C VAPOR PRESSURE (rimmHg): N/A MELTING POINT: N/A VAPOR DENSITY (AIR = 1): N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: Soluble pH: Acidic (PPL Chem Lab: pH = 2.0)
APPEARANCE AND COLOR: Brownish-yellow Solution SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: N/A FLAMMABLE LIMITS: N/A LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Water spray or carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: AVOID BREATHING ANY FUMES OR DUST. WEAR SELF- CONTAINED BREATHING APPARATUS.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Emits toxic fumes under fire conditions..
SECTION V - REACTIVITY DATA STABILITY UNSTABLE: CONDITIONS TO AVOID:
STABLE: X INCOMPATIBILITY (MATERIALS TO AVOID)
Strong oxidizing agents.
HAZARDOUS DECOMPOSITION:
HAZARDOUS: MAY OCCUR: X CONDITIONS TO AVOID:
Toxic fumes of Carbon Monoxide or Carbon Dioxide.
POLYMERIZATION WILL NOT OCCUR: Not available.
SECTION VI - HEALTH HAZARD DATA ROUTE(S)OF ENTRY: INHALATION? X SKIN? N/A INGESTION? X HEALTH HAZARDS (ACUTE AND CHRONIC):
Acute effects: May be harmful by inhalation, ingestion, or skin absorption.
Causes eye and skin irritation. Material is irritating to mucous membrants and upper respiratory tract.
Chronic effects: Damage to the kidneys, target organ(s): Kidneys, nerves EMERGENCY AND FIRST AID PROCEDURES:
INHALATION: IF EXPOSED TO IRON (III) OXALATE FUMES, REMOVE PERSON TO A WELL VENTILATED AREA. TREAT ACCORDING TO SYMPTOMS AND SEEK MEDICAL ATTENTION.
SKIN CONTACT: REMOVE CONTAMINATED CLOTHES. WASH CONTACTED AREA WITH MILD SOAP AND WATER FOR AT LEAST 15 MINUTES. DRY AND SEEK MEDICAL ATTENTION IF SKIN IRRITATION OCCURS AND PERSISTS.
0223
I EYE CONTACT:
EYELIDS RINSE EYES IMMEDIATELY WITH WATER MAKING SURE TO OCCASIONALLY LIFT THE (15-20 MINUTES). CONSULT A PHYSICIAN. - I INGESTION: IF THE VICTIM IS CONSCIOUS, GIVE THEM TWO TO FOUR GLASSES OF WATER AND PROVOKE VOMITING BY PLACING A FINGER DEEP IN THE THROAT. KEEP VICTIM WARM AND RESTED. CONSULT A PHYSICIAN. I SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
I RECOVER THE PRODUCT AND PLACE IN APPROPRIATE CONTAINERS. THE CONTAINERS SHOULD BE LABELED, CLEAN, DRY AND FITTED WITH A COVER. SWEEP AND/WASH DOWN THE SURFACE EXPOSED TO THE PRODUCT. VENTILATE THE AREA WHILE CLEANING. I WASTE DISPOSAL METHOD:
DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL.REGULATIONS.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
I STORE AS FAR AS POSSIBLE FROM NON-COMPATIBLE SUBSTANCES. PLACE IN A COOL, DRY AND WELL VENTILATED AREA. KEEP CONTAINERS CLOSED WHEN NOT IN USE. OBSERVE AND FEDERAL, PROVINCIAL OR LOCAL RULES RELATIVE TO THE STORAGE OF THIS PRODUCT.
I SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION:
WEAR NIOSH APPROVED DUST MASK.
I PROTECTIVE GLOVES:
PVC CHEMICAL RESISTANT EYE PROTECTION:
SAFETY GLASSES/GOGGLES I
VENTILATION: IT IS RECOMMENDED TO USE POSITIVE DISPLACEMENT AIR EXTRACTOR AND/OR A MECHANICAL VENTILATION SYSTEM AND/OR A VENTILATION SYSTEM COMPLETE WITH AN AIR TREATMENT ENCLOSURE TO MEET THE PUBLISHED EXPOSURE LIMITS NORMS.
I OTHER PROTECTIVE CLOTHING OR EQUIPMENT: IF THE CONCENTRATION IS OVER 250 MILLIGRAMS/CUBIC METER- REQUIRES AN AIR PURIFIER RESPIRATOR WITH FULL FACIAL UNIT I
COMPLETE WITH HIGH EFFICIENCY PARTICLE FILTER, POSITIVE PRESSURE OR STANDARD RESPIRATOR COMPLETE WITH FULL FACIAL UNIT.
SECTION IX - DOT INFORMATION I
Corrosive Liquid, acidic, inorganic, 8, UN3264, PGIII, Corrosive n.o.s., (Ferric Oxalate 20%) I I
I I
The information provided herein has been given in good faith by Barker Industries, Inc. No warranty, either expressed or implied is given for I
the information contained in this report.
I 0224 I
Company logo GE Betz Canada, Inc. Material Safety Data Sheet 3451 Erindale Station Road Mississauga, Ontario L5C 2S9 Issue Date: 20-AUG-2003 Business telephone: (905) 279-2222 EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 1 PRODUCT IDENTIFICATION PRODUCT NAME:
POLYFLOC CP1160 PRODUCT APPLICATION AREA:
FLOCCULANT.
2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the WHMIS Regulations is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
Product contains no hazardous ingredients reportable under WHMIS regulation No component is considered to be a carcinogen by the U.S. National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC) or under WHMIS.
3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW May cause slight irritation to the skin. Potential eye irritant due to mechanical action only. Dusts may cause irritation to the upper respiratory tract.
Odor: None; Appearance: White, Powder Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
0225
I ACUTE EYE EFFECTS:
Potential eye irritant due to mechanical action only.
ACUTE RESPIRATORY EFFECTS:
Dusts may cause irritation to the upper respiratory tract.
INGESTION EFFECTS:
May cause slight gastrointestinal irritation.
i TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
4 FIRST AID MEASURES i SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Get medical attention if irritation develops or persists.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes with plenty of low-pressure water for at least 15 minutes. Get medical attention if irritation persists after flushing.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES i FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition. (destructive fires) yields elemental oxides.
FLASH POINT:
I
> 200F > 93C P-M(CC) 6 ACCIDENTAL RELEASE MEASURES I I
I I
0226 i
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
The waste characteristics of the absorbed material, or any contaminated soil, should be determined in accordance with provincial regulations.
Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement or discharged under provincial regulations.
Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Normal chemical handling.
STORAGE:
Keep containers closed when not in use. Keep dry.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS Consult local authorities for acceptable provincial values.
Product contains no hazardous ingredients reportable under WHMIS regulation ENGINEERING CONTROLS:
Adequate ventilation to maintain dust concentrations below the exposure limit of 10 mg/m3(PEL/TLV) for nuisance dusts.
RESPIRATORY PROTECTION:
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
SKIN PROTECTION:
rubber gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
airtight chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES Density 43.200 lb/cu. Vapor Pressure (mmHG) < 0.1 Freeze Point (F) NA Vapor Density (air=l) < 1.00 Freeze Point (C) NA Viscosity(cps 70F,21C) NA Solubility (water) - 2.0 Odor None Appearance White Physical State Powder Flash Point P-M(CC) > 200F > 93C pH 0.5% Sol. (approx.) 4.2 Evaporation Rate (Ether=1) < 1.00 NA = not applicable ND = not determined 10 STABILITY & REACTIVITY 0227
I STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
-I Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
I Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT "A1l CATEGORIES: I 11 TOXICOLOGICAL INFORMATION I Oral LD50 RAT:
Carcinogenicity DOG:
>5,000 mg/kg NEGATIVE NOTE - One year dog study had no adverse effects.
I Carcinogenicity RAT: NEGATIVE NOTE - Two year rat study had no adverse effects.
Dermal LD50 RABBIT: >2,000 mg/kg NOTE - Non-toxic even at high dose levels I
Eye Irritation Score RABBIT:
NOTE - Mechanical irritation Skin Sensitization G.PIG: NEGATIVE I 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Renewal Bioassay I
LC50= 158; No Effect Level= 15 mg/L Fathead Minnow 96 Hour Static Renewal Bioassay LC50= 5.9; No Effect Level= 2.3 mg/L I
BIODEGRADATION BOD-28 (mg/g) :
BOD-5 (mg/g) : 122 165 I COD (mg/g) : 1100 TOC (mg/g):
13 DISPOSAL CONSIDERATIONS 200 I
Incinerate or bury in approved landfill. Please be advised that there may be additional local or provincial requirements relating to the disposal of waste. Consult provincial and local regulations regarding I
the proper disposal of this material.
14 TRANSPORT INFORMATION I Transportation of Dangerous Goods:
Proper Shipping Name: Not Regulated I
15 REGULATORY INFORMATION I
I I
02"28 I
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
CEPA:
All components of this product comply with substance notification requirements under CEPA.
WHMIS CLASSIFICATION:
NOT REGULATED FOOD AND DRUG ADMINISTRATION:
21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods) 16 OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 1 Slight Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special NONE No special Hazard (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 07-MAY-1997 ** NEW **
20-APR-1998 ;EDIT:9 07-MAY-1997 26-MAY-1999 12 20-APR-1998 01-JUN-1999 15 26-MAY-1999 24-AUG-2000 01-JUN-1999 20-AUG-2003 24-AUG-2000 0229
I 0 GE ae
- I GE Betz, Inc. Material Safety Data Sheet I 4636 Somerton Road Trevose, PA 19053 Issue Date: 24-AUG-2000 I Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 I 1 PRODUCT IDENTIFICATION I PRODUCT NAME:
POLYFLOC AP1100 I
PRODUCT APPLICATION AREA:
FLOCCULANT.
I 2 COMPOSITION / INFORMATION ON INGREDIENTS I Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
I HAZARDOUS INGREDIENTS:
This product is not hazardous as defined by OSHA regulations.
I No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for I
carcinogens.
3 HAZARDS IDENTIFICATION I
EMERGENCY OVERVIEW I I
CAUTION May cause slight irritation to the skin. May cause moderate irritation to the eyes. Dusts may cause irritation to the upper respiratory tract.
DOT hazard is not applicable I
Emergency Response Guide is not applicable Odor: None; Appearance: White, Powder Fire fighters should wear positive pressure self-contained breathing I
apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical/C02/foam or water--slippery condition; use sand/grit.
I 0230 I
POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
ACUTE EYE EFFECTS:
May cause moderate irritation to the eyes.
ACUTE RESPIRATORY EFFECTS:
Dusts may cause irritation to the upper respiratory tract.
INGESTION EFFECTS:
May cause slight gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
4 FIRST AID MEASURES SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Get medical attention if irritation develops or persists.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes with plenty of low-pressure water for at least 15 minutes. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions 5 FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical/C02/foam or water--slippery condition; use sand/grit.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F > 93C P-M(CC) 6 ACCIDENTAL RELEASE MEASURES 0231
I PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.
-I Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE HANDLING:
Normal chemical handling.
STORAGE:
Keep containers closed when not in chemical storage. Keep dry.
use. Reasonable and safe U
8 EXPOSURE CONTROLS / PERSONAL PROTECTION I EXPOSURE LIMITS This product is not hazardous as defined by OSHA regulations.
ENGINEERING CONTROLS:
adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.
I SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
I airtight chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES I Density 42.000 lb/cu. Vapor Pressure (mmHG) < 0.1 Freeze Point (F) NA Vapor Density (air=l) < 1.00 Freeze Point (C) NA Viscosity(cps 70F,21C) NA % Solubility (water) 1.0 Odor None Appearance White Physical State Powder Flash Point pH S% Sol. (approx.)
Evaporation Rate (Ether=l)
P-M(CC) > 200F 7.0
< 1.00
> 93C I
NA = not applicable ND = not determined I
10 STABILITY & REACTIVITY STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"A" 11 TOXICOLOGICAL INFORMATION Oral LD50 RAT: >5,000 mg/kg 28 Day Oral RAT/DOG: NEGATIVE NOTE - Rat two-year feed: no adverse effects. Dog one-year feed:
no adverse effects.
Dermal LD50 RABBIT: >2,000 mg/kg NOTE - Non-toxic at high dose levels Skin Irritation Score RABBIT: NEGATIVE Eye Irritation Score RABBIT: SLIGHT Skin Sensitization G.PIG: NEGATIVE 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Bluegill Sunfish 96 Hour Static Screen 0% Mortality= 300 mg/L Ceriodaphnia 48 Hour Static Acute Bioassay LC50= 5; No Effect Level= 1.6 mg/L Daphnia magna 48 Hour Static Screen 0% Mortality= 500 mg/L Fathead Minnow 96 Hour Static Screen 0% Mortality= 500 mg/L Rainbow Trout 72 Hour Static Screen 0% Mortality= 100 mg/L BIODEGRADATION BOD-28 (mg/g) : 22 BOD-5 (mg/g) : 1 COD (mg/g) : 2970 TOC (mg/g) : 680 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 TRANSPORT INFORMATION 0235
I DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable 15 REGULATORY INFORMATION TSCA:
All components of this product are listed CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
in the TSCA inventory.
No regulated constituent present at OSHA thresholds i
FOOD AND DRUG ADMINISTRATION:
21 CFR 176.110 (acrylamide - acrylic acid resins)
All ingredients comprising this product are authorized by FDA for the manufacture of paper and paperboard that may contact U
aqueous and fatty foods as per 21 CFR 176.170(a) (4).
USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS:
SEC.G6,LI SARA SECTION 312 HAZARD CLASS:
Product is non-hazardous under Section 311/312 SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:
I No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION I CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds 16 OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health Fire Reactivity 1
1 0
Slight Hazard Slight Hazard Minimal Hazard I
Special NONE No special Hazard (1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.
CHANGE LOG I EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 28-JAN-1997 ** NEW **
01-JUL-1997 15 28-JAN-1997 27-MAY-1999 15 01-JUL-1997 24-AUG-2000 4 27-MAY-1999 I
0234 i
THERMALTAKE TECHNOLOGY USA The ~mQftake 525 Parriott Place City of Industtr,, CA 91745 TEL: 626-968-9189 FAX: 626-968-1138 hotp:/ iwwwv.thierrnatakcusei.coni /
MATERIAL SAFETY DATA SHEET CUSTOMER MODEL NO. : COOLANT (PC USE)
DESCRIPTION CUSTOMER PART NO.:
ISSUDE DATE : MAR. 11, 2006 REVISED DATE VERSION B CONTENT CUSTOMER APPROVAL SIGNATURE APPROVED BY VERIFIED BY AUTHOR 0235
I
-I MATERIAL SAFETY DATA SHEET I
I
- mi0- --. '0 -
I
- 0i Product nam.e PG-USP (Propylene Glycol USP)
!synonymn, 1, 2-Propanediol; 1,2-Dihydroxypropane; 2-Hydroxypropanol; Isopropylene Glycol; Methylethylene Glycol; Methylethyl Glycol; I S -Monopropylene Glycol; 2,3- Propanediol; Alpha-Propylene Glycol; 1,2-
- J Propylene Glycol. I Ch m'ý'mla uia fCH3CH(OH)CH2OH Chemical Famly Glycol I i
Supplier Informat ion Thermaltake Technology Emergency phone 800-988-1088 I I
.ingredient... CAS Nubre ,riY egt I
GT 99.
I
___________________57__55-PropyleneGlyco 55-6:~
Dipropylene Glcol Others~ f , ; LT 0.Q1r2 I
!S.tate :.and Liquid I 6e' NFPA RATINGS (SCALE 0-4): HEALTH=0 FIRE=1 REACTIVITY=0 I Odorless, clear, colorless, hygroscopic, viscous liquid with a slightly acrid taste avoid contact with eyes. Keep container tightly closed. Wash thoroughly after handling. Handle with caution.
I H'
L Potential I Eff&is.
Health I 0236
Short term effects: May cause minor eye irritation.
Lona term effects: No information is available.
Short term effects: No information available on significant adverse effects.
Long term effects: No information available on significant adverse effects.
Short term effects: No information available on significant adverse effects.
i Long term effects: No information available on significant adverse effects.
Short term effects: No information available on significant adverse effects.
Long term effects: No information available on significant adverse effects.
-' II JOSHA: N; NTP:N; IARC:N Wash eyes immediately with large amounts of water or normal saline,
, occasionally lifting upper and lower lids, until no evidence of chemical remains (at least 15-20 minutes). Get medical attention immediately.
ij Remove contaminated clothing and shoes. Wash with soap or mild j detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes).
- I No expected to present a significant inhalation hazard under anticipated conditions of normal use.
AlI Treat symptomatically and supportively.
.11No specific antidote. Treat symptomatically and supportively.
_ _ _ '.esde Fire and~Explosion Hazard Slight fire hazard when exposed to heat or flame. Heat from
~ ~
fire can generate flammable vapor. When mixed with air and exposed to ignition source, vapor can burn in open or explode if confined. Vapors may travel long distances along the ground before igniting and flashing back to vapor source.
~.L .~
Fine sprays/mists may be combustible at temperatures below 3/4 Y normal flash point. Aqueous solutions containing less than 0237
I
-I
.~ ~
~-~y .~
95% propylene glycol by weight have no flash point as
/ obtained by standard test methods. However aqueous solutions of propylene glycol greater than 22% by weight, if I
~ ~
~c heated sufficiently, will produce flammable vapor. Only aqueous solutions of propylene glycol less than 22% should I used in sprinkler systems or other fire-fighting equipment.
7-Always drain and flush systems containing propylene glycol with water before welding or other maintenance.
I Extiniu;ihg Media Dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For larger fires, use water spray, fog I
Firefighting
~
~
~,
Q~ ->
or alcohol-resistant foam. Alcohol foam.
Move container from fire area if you can do it without risk. Do I
not enter fire area without proper protection. Fight fire from a K'~-~. ~
safe distance/protected location. Heat may build enough I j 4-4 7 pressure to rupture closed container/spreading
~
~
fire/increasing risk of burns/injuries. Use water spray/fog for cooling. Avoid frothing/steam explosion. Do not scatter I
spilled material with high-pressure water streams. Burning I
~
~-~-
liquid may float on water. Although water soluble, may not be practical to extinguish fire by water dilution. Dike fire-control
~ water for later disposal. Avoid breathing hazardous vapors, keep upwind. Notify authorities immediately if liquid enters I
sewer/public waters.
K- "-~
210 F (99 C) (CC) I 2.6%
12.5% I 700 F (371 C)
II1B I
,azard6ous.6mbustionrod'ucts Thermal decomposition products may include toxic oxides of carbon. I n *-- - ""-- lI I
Occupational spill May contaminate water supplies/pollute public waters. Evacuate/limit access. Equip responders with proper protection. Prevent flow to I
- ?--*-*:
I sewer/public waters. Stop release. Notift fire and environmental authorities. Restrict water use for cleanup. Slippery walking. Spread I 0238 I
granular cover. Impound/recover large land spill. Soak up small spills S. -, , with inert solids. Use suitable disposal containers. On water, material is
, ",o'< - *'-1 soluble and may float or sink. May biodegrade. Contain/collect rapidly Ito minimize dispersion. Disperse residue to reduce aquatic harm.
... ,, . . Report per regulatory requirements. Keep unnecessary people away; isolate hazard area and restrict entry.
l~adhn-*-.,-vHygroscopic Use dry nitrogen or low dew point air for tank padding. Keep dustightly closed to prevent contamination.
[*)J] Store at 18-32 C. store away from. incompatible substances.
0239
I T* T
-I Description
_ _ __ _ IIno odor; Aromatic, sweet Clear, colorless; little or Specific, Gravity 1.0361 I Molecular 76.11 Water Solubility Soluble MolC-ular Formula C-H3-C-H-(O-H)-C-H20 'YVlatility 1100%
Boiling Point. 370-372 F (188-189 C) No data available Freezing Pint -75 F (-59C) lOdor-Thre!shold No data available
.Vapor ressure <0.1mmHg @ 20 C jE-Vap6rati66.nfRate,, 0.005 (butyl acetate=1)
VaprDensity*
D 2.62 jv 58.1 cP@20 C Solvent Solubility Soluble in alcohol, acetone, chloroform, ether, benzene many organic
- -:- solvents; insoluble in fixed oils.
H
- zareou~s~i'* -Thermal decomposition products may include toxic oxides of carbon.
Pol.erizationi I;**:
Hazardous polymerization .has not been reported to occur under normal ac viytbludrora temperatures and pressures.
AvDeChlorides Inomatbl Acid Anhyd*"nds. Incompatible pEthslen iayinclude Possible explosion
- Acid; -Ch16rie'*i e_ " Incompatible Ns Nitrogen Tetroxide Possible explosion Chloroorrnate. ý2jj Incompatible Rerhoric Acid (Hot) Dangerous interaction
,Reducing Agents _1Incompatible Tr iso-Butyl Aluminumq Violent reaction OXidizers Fire and explosion P*,astics . . . . May be attacked Nitri idi . ; Mixture forms explosive Metals (Light) Reaction forms rHydrofluoric Acid and silver fulminate. . . flammable hydrogen Slver Nitrate . gas.
Acetaldenydei,* Violent condensation Barium:,Pechlorate Formation of highly reaction ,explosive perchloric ester on refluxing.
0240
H I
H 110 rgrý..a hft.Tr.-.POM
- Environmental lImp'act Rating'(0-4),j No data available Acute Aquatcoxicity No data available Degradability,;l :*;7fj ' . No data available Log~ ~iconoentrate Factore(BGF)I No data available 0241
I
- I
- Log Octanol/Waiter partition , No data available 9b efficienit I
I Contaminated product, soil, or water should not be designated hazardous waste. Landfill solids at permitted sites. Use registered transports. Burn concentrated liquids, I
diluting with clean, low viscosity fuel. Avoid flame-outs.
Assure emissions comply with applicable regulations. Dilute I
aqueous waste may. Avoid overloading/poisoning plant biomass. Assure effluent complies with applicable regulations.
I I
ITranspcirt In orlnlat~ibro No classification currently assigned.
I I
I I
I I
I lAuthorized for internal use only I
Prepared By: 1WellerChen (Product Manager)
I Date: 2006/4/67 END OF DOCUMENT I
0242 I
WESTERN CHEMICAL INTERNATIONAL, INC.
2939 N. 67TH PLACE, SCOTTSDALE, AZ 85251 Tel.: 480-990-9487 Fax: 480-946-6174 HAZARD RATING ATERIAL SAFETY DATA SHEET AY BE USED TO COMPLY WITH OSHA'S HAZARD COMMUNICATION STANDARD (HSC) 29 1HEALTH 1I REACTIVITY0 IFLAMMABILITY 2 SPECIAL CFR 1910.1200, STANDARD MUST BE CONSULTED FOR SPECIFIC REQUIREMENTS i .O.T. CLASSIFICATION: Liquid Cleaning Compound D.O.T. CLASSIFICATION:Liquid Cleaning Compound KECTION I - Identification I roduct Name:
reparer: EPA 2000" M. Michaels #WCI-140 Emergency Date Prepared:Phone: CHEM TEL, INC 1-800-255-3924 12/10/06 U
SECTION II- Hazardous Ingredients/Identity Information Y THEM. AGENCIES INVESTIGATED INCLUDE THE E.P.A., F.D.A., NATIONAL CANCER INSTITUTE, NATIONAL SCIENCE FOUNDATION, ADMINISTRATION), ANDTHE NATIONAL TOXICOLOGY ROGRAM. THE FORMULATION IS A TRADE SECRET AND COMPLIES WITH 29CFR XV11-1910.1200, SECTION(I), -TRADE SECRETS.-
[iciple Components CAS # OSHA PEL. ACGIH TLV Other LIPHATIC HYDROCARBONS 64742-47-8 200 200 ARAFFINIC HYDROCARBONS 64742-88-7 200 200 D-LIMONENE (CITRUS TERPENES) 5989-27-5 100 100 LPA -2000" formula is a trade secret and complies with 29 CFR 1910.1200, Section (i) Trade Secrets.
VOC (Volatile organic compounds) is within Air Quality Emission Standards (California-All Districts).
o ingredients listed under Cal. State Drinking & Toxic Chemical Enforcement Act (1986).
SHA Hazard Class 29 CFR 1910.1200 - NON HAZARDOUS LIQUID. RCRA Hazardous Waste Class 40 FR 261.2 - NON HAZARDOUS WASTE. TCLP Waste Class 40 CFR 261.4 - NON HAZARDOUS WASTE.
TCLP Waste Class 40 CFR 261.4 - NON - HAZARDOUS WASTE.
USECTION III - Physical/Chemical Characteristics oiling Point: 320-360 DEG. F Specific Gravity 0.81 apor Pressure (mm Hg): at 25 DEG. C <1 Ph 6.8-7.6 Vapor Density (Air=l): >1 Evaporation Rate: Butyl Acetate = 1 <1 m olubility in Water: Insoluble ppearance and Odor: Non viscous liquid-clear color. Pleasant citrus.odor.
SECTION IV - Fire and Explosion Hazard Data
[lash Point: 154 DEG. F (145 DEG. F TCC/Pensky-Martens) lammable Limits: Lower: N/D Upper: N/D Extinguishing Media: C02, Dry Powder, Foam Ipecial Fire Fighting Procedure: Class B Procedures Unusual Fire and Explosion Hazards: Keep away from sparks & open flames.
E Do not use welding torch on or near drum.
SECTION V - Reactivity Data Stability: Stable I onditions to Avoid: Open flames, welding arcs, or other high temperature sources.
Incompatibility (Materials to avoid): Oxidizing agents Hazardous Polymerization: Will not occur I azardous Decomposition or By Products: None Known Conditions to Avoid: None known
I SECTION VI - Health Hazard Data Route(s) of Entry:
INHALATION: Not in normal use SKIN: Possible, if prolonged INGESTION: Not in normal use Health Hazards (Acute and Chronic): Product has low vapor presure and should not present a hazard under normal working conditions.
Signs and Symptoms of Exposure: Product considered safe under normal usage.
Overexposure, however, may result in the following:
EYES: Irritation. SKIN: Irritation INGESTION: Gastro-intestinal irritation INHALATION: Dizziness Carcinogenicity: Not listed in NTP or IARC Monograph. Not regulated by OSHA.
Medical Conditions Generally Aggravated by Exposure: None Known Emergency and First Aid Procedures:
SKIN: Wash with soap and water.
EYES: Flush with water for 15 minutes. If irritation persists, seek medical attention.
INHALATION: Remove to fresh air; if breathing difficult, get medical attention.
INGESTION: Do not induce vomiting; get medical attention.I SECTION VII - Precautions for Sale Handling and Use Steps to Be Taken in Case Material is Released or Spilled: Allow small spills to evaporate. Larger spills should be I collected and disposed of properly in accordance with regulations.
Waste Disposal Method: EPA 2000 has a high BTU value. Waste product can, therefore, be mixed with normal waste oil for burning as industrial fuel. It can also be recycled or reclaimed.
Precautions to Be Taken in Handling and Storing:
Store in cool, dry area away from heat. i Keep container tightly closed when product is not being used.
SECTION VIII -Control Measures I Respiratory Protection (specify type): Not required if TLV kept below PPM.
Ventilation: Local Exhaust: Adequate Mechanical (general): Adequate Special: None Other: None I Protective Gloves: NITRILE / PVC Eye Protection: Goggles I safety glasses i Other Protective Clothing or Equipment: Not Required Work/Hygienic Practices: Keep eye wash in vicinity. Wash with soap &water before handling food.
i NOTICE: WE BELIEVE THAT THE INFORMATION CONTAINED ON THIS MATERIAL SAFETY DATASHEET IS ACCURATE. THE SUGGESTED PROCEDURES ARE BASED ON EXPERIENCE AS OF THE DATE OF PUBLICATION. THEY ARE NOT NECESSARILY ALLINCLUSIVE NOR FULLY ADEQUATE IN EVERY CIRCUMSTANCE. ALSO, THE SUGGESTIONS SHOULD NOT BE CONFUSED WITH NOR FOLLOWED IN VIOLATION OF APPLICABLE LAWS, REGULATION, RULES OR INSURANCE REQUIREMENTS. NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE IS MADE. 0244 I
M A T E R I A L S A F E T Y DATA SHEET Page:- 1 PRODUCT NAME: TSP NFPA CODES: H F R MSDS CODE: 620N 2 0 0 I/II DOT SHIPPING NAME AND LABELING: CLEANING COMPOUND - NOT REGULATED SECTION I - MANUFACTURER IDENTIFICATION EFFECTIVE: 08/17/2001 MANUFACTURER'S ADDRESS NAME:: SAVOGRAN 259 LENOX STREET POBOX 130 I NORWOOD, MA 02062-0130
- PHONE : 781-762-5400 NAME OF PREPARER : MARK A. MONIQUE SECTION II - HAZARDOUS INGREDIENTS UNDER OSHA HAZARD COMMUNICATION STD I WEIG~HT INGREDIENTS CAS NUMBER PERCENT I Trisodium Phosphate EXPOSURE Dodecahydrate GUIDELINES NOT LISTED 10101-89-0 75% - 80%
Sodium Sesquicarbonate 533-96-0 20% - 25%
EXPOSURE GUIDELINES NOT LISTED I SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS SPECIFI(C GRAVITY: 60-75LBS/FT3 INITIAL BOILING POINT: NA VAPOR DENSITY: NA VAPOR P]RESSURE (CALCULATED): NA EVAPORATION RATE: NA MATERIAlL V.O.C. (% BY WT.): 0.
PERCENT VOLATILE: 0. SOLUBILIITY IN WATER: MODERATE PH (1% IN H20) : 11-12 APPEARANCE AND ODOR: WHITE CRYSTALLINE SOLID SECTION IV - FIRE AND EXPLOSION HAZARD DATA I FLASH FLAMMABLE POINT: NA LIMITS IN AIR BY METHOD VOLUME-:USED: NO DATA LOWER: NO DATA UPPER: NO DATA EXTINGUISHING MEDIA: NONFLAMMABLE SPECIAL FIREFIGHTING PROCEDURES:
SOLUTIONS IN WATER ARE MODERATELY TO STRONG ALKALINE. WEAR FULL PROTECTIVE CLOTHING.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NONE
~~TION V - REM~TIVTTY DATA I STABILITY:
STAO STABLE ... ...
V.. .. ... . .. ..
CONDITIONS TO AVOID:
MATERIAL IS HYGROSCOPIC AND TENDS TO CAKE UNDER DAMP CONDITIONS.
INCOMPATIBILITY (MATERIALS TO AVOID):
SOLUTIONS IN WATER ARE HIGHLY ALKALINE AND MAY PRODUCE HYDROGEN GAS WHEN IN 0245
I MATERIAL SAFETY DATA SHEET TSP Page:-2 CONTACT WITH ALUMINUM. WILL REACT WITH ACIDS TO FORM CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
SECTION VI - HEALTH HAZARD DATA I-INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
INHALATION OF DUST CAN CAUSE NASAL AND RESPIRATORY IRRITATION. i SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
SKIN: IRRITATING, MAY CAUSE CHEMICAL BURNS AND DERMATITIS. EYE CONTACT CAN CAUSE SEVERE IRRITATION, BURNING AND TRANSIENT INJURY TO CORNEA.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
NONE INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
MAY CAUSE IRRITATION AND CHEMICAL BURNS TO THE GASTROINTESTINAL TRACT. ,
HEALTH HAZARDS (CHRONIC):
NO CHRONIC EFFECTS EXPECTED I CARCINOGENICITY: NTP: NO IARC MONOGRAPHS: NO OSHA REGULATED: NO MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: i NONE EMERGENCY AND FIRST AID PROCEDURES:
- SKIN CONTACT**: REMOVE CONTAMINATED CLOTHING AND WASH SKIN THOROUGHLY WITH WATER. IF IRRITATION OCCURS GET MEDICAL ATTENTION PROMPTLY. THOROUGHLY WASH CONTAMINATED CLOTHING BEFORE REUSE. **EYE CONTACT**: FLUSH EYES WITH PLENTY OF RUNNING WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS APART TO ENSURE COMPLETE IRRIGATION OF ALL TISSUE. GET MEDICAL ATTENTION PROMPTLY.**INHALATION**: IF i
ILLNESS OCCURS, REMOVE PATIENT TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF BREATHING HAS STOPPED, START ARTIFICIAL RESPIRATION. CALL PHYSICIAN IMMEDIATELY.**SWALLOWING**: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF SWALLOWED DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER (IF AVAILABLE GIVE SEVERAL GLASSES OF MILK). IF VOMITING OCCURS SPONTANEOUSLY KEEP AIRWAY CLEAR AND GIVE MORE WATER. GET MEDICAL ATTENTION PROMPTLY. IF SYMPTOMS INDICATE, APPLY TREATMENT AS APPROPRIATE FOR CORROSIVE ALKALI SUBSTANCE.
I SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE-i STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
SWEEP UP MATERIAL AND TRANSFER TO CONTAINERS. REMAINING RESIDUE MAY BE WASHED AWAY WITH WATER.
WASTE DISPOSAL METHOD:
SMALL QUANTITIES MAY BE DEPOSITED IN GENERAL TRASH AND RESIDUE FLUSHED DOWN I
DRAIN WITH WATER. LARGE SPILLS MUST BE DISPOSED OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. I 0246 I
M A T E R I A L S AF ET Y D A T A S H E E T I TSP Page:-3 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
STORE IN DRY PLACE. MOISTURE CAN CAUSE CAKING.-KEEP AWAY FROM ACIDS OF ALL TYPES. WATER SOLUTIONS CAN BE CORROSIVE TO ALUMINUM AND GENERATE HYDROGEN.
IOTHER PRECAUTIONS:
AVOID CONTACT WITH MATERIAL. DO NOT EAT, DRINK OR SMOKE WHEN HANDLING THIS MATERIAL.
I -------- ~SECTION VIII - CONTROL MEASURES =---------------------
IRESPIRATORY PROTECTION:
WEAR NIOSH/MSHA APPROVED DUST RESPIRATOR, IF DUST IS FORMED.
VENTILATION:
PROVIDE SUFFICIANT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO I MAINTAIN EXPOSURE BELOW LEVEL OF OVEREXPOSURE.
PROTECTIVE GLOVES:
USE DUST PROOF GLOVES.
IEYE PROTECTION:
USE DUST PROOF GOGGLES IF DUST IS IRRITATING EYES.
IOTHER PROTECTIVE CLOTHING OR EQUIPMENT:
NONE I--SECTION IX - DISCLAIMER JUDGEMENT OF POTENTIAL HAZARDS OF THIS PRODUCT IS BASED ON INFORMATION AVAILABLE IABOUT INDIVIDUAL COMPONENTS LISTED UNDER SECTION II - INGREDIENTS. DIRECT TESTING OF MIXTURE HAS NOT BEEN DONE. INFORMATION GIVEN HEREIN IS BELIEVED TO BE ACCURATE AND IS GIVEN IN GOOD FAITH; HOWEVER, NO WARRANTY EITHER EXPRESSED OR IMPLIED IS MADE. IT IS STRONGLY SUGGESTED THAT USERS CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT AND APPLICABLE TO THEIR SITUATIONS.
0247
I
-II! MATERIAL SAFETY DATA SHEET Preparedto U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
- I BASIC CHEMICAL SOLUTIONS I I
PART I What is the material and what do I need to know in an emergency? I
- 1. PRODUCT IDENTIFICATION BCS SODIUM HYDROXIDE LIQUID I
TRADE NAME (AS LABELED):
(1%-50%) I CHEMICAL NAME/CLASS: Sodium Hydroxide Solution PRODUCT USE: Metal finishing, neutralization, industrial cleaners, chemical I processing.
SUPPLIER/MANUFACTURER'S NAME:
ADDRESS:
BASIC CHEMICAL SOLUTIONS Corporate Office I
525 Seaport Blvd.
Redwood City, CA 94063 I BUSINESS PHONE: 800-411-4227 EMERGENCY PHONE: CHEMTREC: 800-424-9300 I
DATE OF PREPARATION:
DATE OF REVISION:
May 7, 2003 July 5, 2006 I
Si usted no entiende las Hojas de Informacion de Seguridad sobre Materials, busque a alguien para que se la explique a usted en detalle.
(If you do not understand the Material Safety Data Sheet, find someone-to explain it to you in detail.)
I
- 2. COMPOSITION AND INFORMATION ON INGREDIENTS I CHEMICAL NAME CAS # %w/w EXPOSURE LIMITS IN AIR TLV mg/m 3 ACGIH STEL mg/m3 I
PEL mg/m3 OSHAm STEL Img/m3 m
IDLH mg/m OTHER mg/m3 I Sodium Hydroxide 1310-73-2 1-50 2, C NE 2, C NE 10 NIOSH REL: 2 Water and other ingredients. The other ingredients Balance (Vacated 1989 PELs)
DFG MAKs: 2 The components present in the balance of this product do not contribute any I
are each present in less than 1 percent concentration significant, additional hazards. All hazard information pertinent to this product in this product. has been presented in the remaining sections of this Material Safety Data Sheet, per the requirements of Federal Occupational Safety and Health Hazard Communication Standard (29 CFR 1910.1200).
I NE = Not Established. C = Ceiling Limit. See Section 16 for Definitions of Terms Used.
NOTE: All WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-1993 format.
I BCS Sodium Hydroxide 1% - 50% M.S.D.S.
PAGE 1 OF 8 I
0248 I
- 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: This product is a clear to turbid liquid solution. This solution is corrosive, and can be damaging to contaminated tissue. Ingestion of large quantities can be fatal. In the event of fire or spill, adequate precautions must be taken. This solution reacts with water to generate heat. If involved in a fire, this product may decompose to produce sodium oxides and a variety of other compounds (i.e. carbon monoxide and carbon dioxide). Emergency responders must wear the proper personal protective equipment suitable for the situation to which the are responding.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: This solution can damage skin, eyes, mucous membranes, and other contaminated HAZARDOUS MATERIAL INFORMATION tissue. Burns may not be immediately painful or visible. SYSTEM INHALATION: If mists or sprays of this solution are inhaled, this product may cause pulmonary irritation, irritation of the mucus membranes, coughing, and a HEALTH (BLUE) 3 sore throat. Damage to the tissues of the respiratory system may occur.
CONTACT WITH SKIN or EYES: Severe irritation and/or burns can occur following eye exposure. Contact may cause impairment of vision and corneal damage possibly blindness. Skin contact may result in a "soapy" feel and cause FLAMMABILITY °D reddening, discomfort, and irritation. Prolonged exposure may result in ulcerating burns which could leave scars.
SKIN ABSORPTION: Skin absorption is not anticipated to be a significant route of over-exposure to any component of this product. [REACTIVITY f 1 INGESTION: Though ingestion is not anticipated to be a significant route of over-exposure to this product, if ingestion does occur burning and irritation of the mouth, throat, esophagus, and other tissues of the digestive system will occur immediately upon contact. Ingestion of large quantities may be fatal.
IPOTECTIVEEQUIMENT IQ INJECTION: Though injection is not anticipated to be a significant route of over-exposure to this product, if it occurs, may cause local reddening, tissue swelling, and discomfort.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. I I I I ACUTE: This solution is corrosive, and can burn and damage eyes, skin, For routine industrial applications mucous membranes, and any other exposed tissue. If inhaled, irritation of the respiratory system may, occur, with coughing, and breathing difficulty. Though unlikely to occur during occupational use, ingestion of large quantities may be fatal.
CHRONIC: Repeated skin contact with this product may result in dermatitis (inflammation and reddening of the skin).
PART II What should I do if a hazardous situation occurs? _
- 4. FIRST-AID MEASURES SKIN EXPOSURE: If the product contaminates the skin, immediately begin decontamination with running water. Minimum flushing is for 15 minutes. Remove contaminated clothing, taking care not to contaminate eyes. Washing with large amounts of clean water should continue until affected skin surface no longer feels slippery. Victim must seek medical attention.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gentle running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Do not attempt to neutralize. Oils or ointments should not be used at this time. Victim must seek immediate medical attention.
INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Victim should drink milk, egg whites, or large quantities of water. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow.
Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if necessary.
Take copy of label and MSDS to health professional with victim.
BCS Sodium Hydroxide 1% - 50% M.S.D.S.
PAGE 2 OF 8 0249
I
- 5. FIRE-FIGHTING MEASURESn Not flammable.
FLASH POINT, °C(method):
AUTOIGNITION TEMPERATURE, °C: Not flammable.
FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): Not applicable. NFPA RATING Upper WUEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: FLAMMABILITY Water Spray: YES Carbon Dioxide: YES Foam: YES Dry Chemical: YES 0 Halon: YES Other: Any "ABC" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Not considered flammable or HEALTH 3 1 REACTIVITY combustible. Does not support combustion. However, contact with water or acids may generate sufficient heat to ignite nearby combustible materials. Contact with aluminum, tin or zinc will result in the generation of heat and release of hydrogen gas. Run-off from fire control may cause pollution. Keep fire-exposed containers cool with water spray to prevent rupture due to excessive heat. High pressure water hose OTHER may spread product from' broken containers increasing contamination. When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (including carbon monoxide, carbon dioxide and sodium oxides). Products of combustion are irritating to the respiratory tract and may cause breathing difficulty. Symptoms may be delayed several hours or longer depending upon the extent of exposure.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural fire fighters must wear Self-Contained Breathing Apparatus and full protective equipment. If possible, prevent run-off water from entering storm drains, bodies of water, or other environmentally sensitive areas. n
- 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned i procedures. Proper protective equipment should be used. In case of a spill, clear the affected area, protect people, and respond with trained personnel.
The proper personal protective equipment for incidental releases (e.g.-1 L of the product released in a well-ventilated area) use impermeable gloves, specific for the material handled, goggles, face shield, and appropriate body protection. In the event of a large release, use impermeable gloves, specific for the material handled, chemically resistant suit and boots, and hard-hat. Self Contained Breathing Apparatus or respirator may be required where engineering controls are not adequate or conditions for potential exposure exist. When respirators are required, Select NIOSH/MSHA approved based on actual or potential airborne concentrations in accordance with latest OSHA and/or ANSI recommendations.
Absorb spilled liquid with polypads or other suitable absorbent materials. Neutralize residue with citric acid or other caustic neutralizing agent. Decontaminate the area thoroughly. Test area with litmus paper to confirm neutralization. Place all spill residue in a suitable container. Dispose of in accordance with Federal, State, and local hazardous waste disposal regulations (see Section 13, Disposal Considerations).
I PART III How can Iprevent hazardous situationsfrom occurring
- 7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash hands after handling this product. Do not eat or drink while handling this material. Remove contaminated clothing immediately.
Discard contaminated clothing items, or launder before re-use. Inform anyone handling such contaminated laundry of the hazards associated with this product. Use ventilation and other engineering controls to minimize potential exposure to this product.
1 I
BCS Sodium Hydroxide 1% -50% M.S.D.S. I PAGE 3 OF 8 n n,9;n
- JV I
- 7. HANDLING and STORAGE (Continued)
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Avoid breathing mists or sprays generated by this product. It is best to never add water to this product, always add product, with constant stirring, slowly to surface of lukewarm (80-100 *F, 27-38 'C) water, to assure product is being completely dispersed as it is added.
Only trained personnel can add water to this product. Never add more product than can be absorbed by solution while maintaining temperatures below 200 'F(93 °C) to prevent boiling and spattering of caustic solution. Use in a well-ventilated location.
For Non-Bulk Containers: Open containers slowly, on a stable surface. Containers of this product must be properly labeled. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Material should be stored in secondary containers, or in a diked area, as appropriate. Store containers away from incompatible chemicals. Keep container tightly closed when not in use. Wash thoroughly after using this material. Storage areas should be made of fire-resistant materials. If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. Empty containers may contain residual liquid, therefore, empty containers should be handled with care.
Bulk Containers: All tanks and pipelines which contain this material must be labeled. Perform routine maintenance on tanks or pipelines which contain this product. Report all leaks immediately to the proper personnel.
Tank Car Shipments: Tank cars carrying this product should be loaded and unloaded in strict accordance with tank-car manufacturer's recommendation and all established on-site safety procedures. Appropriate personal protective equipment must be used (see Section 8, Engineering Controls and Personal Protective Equipment.). All loading and unloading equipment must be inspected, prior to each use. Loading and unloading operations must be attended, at all times. Tank cars must be level, brakes must be set or wheels must be locked or blocked prior to loading or unloading. Tank car (for loading) or storage tank (for unloading) must be verified to be correct for receiving this product and be properly prepared, prior to starting the transfer operations. Hoses must be verified to be clean and free of incompatible chemicals, prior to connection to the tank car or vessel. Valves and hoses must be verified to be in the correct positions, before starting transfer operations. A sample (ifrequired) must be taken and verified (ifrequired) prior to starting transfer operations. All lines must be blown-down and purged before disconnecting them from the tank car or vessel.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out safely, Always use this product in areas where adequate ventilation is provided. Decontaminate equipment before maintenance begins by a triple-rinse with water followed, if necessary, by using caustic neutralizing agent and an additional rinse. Collect all rinsates and dispose of according to applicable Federal, State, or local procedures.
- 8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: If required use a corrosion-resistant ventilation system separate from other exhaust ventilation systems to ensure that there is no potential for overexposure to sprays, or mists of this product and that exposures are below those in section 2 (Composition and Information on Ingredients). Ensure eyewash/safety shower stations are available near areas where this product is used.
RESPIRATORY. PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed in Section 2 (Composition and Information on Ingredients). If respiratory protection is needed, use only protection authorized in 29 CFR 1910.134, or applicable State regulations. If adequate ventilation is not available or ifthere is potential for airborne exposure above the exposure limits (listed in Section 2) a respirator may be worn up to respirator exposure limitations, check with respirator equipment manufactures recommendations/limitations. For a higher level of protection use positive pressure supplied air respiration protection or Self Contained Breathing Apparatus or ifoxygen levels are below 19.5% or are unknown.
EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS:
Positive pressure, full-facepiece Self Contained Breathing Apparatus; or positive pressure, full-facepiece Self Contained Breathing Apparatus with an auxiliary positive pressure Self Contained Breathing Apparatus.
EYE PROTECTION: Splash goggles or safety glasses. Face-shields are recommended when the operation can generate splashes, sprays or mists.
HAND PROTECTION: Wear appropriate gloves for routine industrial use. Use appropriate gloves for spill response, as stated in Section 6 of this MSDS (Accidental Release Measures).
BODY PROTECTION: Use body protection appropriate for task. Cover-all, rubber aprons, or chemical protective clothing made from natural rubber are generally acceptable, depending upon the task.
BCS Sodium Hydroxide 1%- 50% M.S.D.S.
PAGE 4 OF 8 0251
I
- 9. PHYSICAL and CHEMICAL PROPERTIES Physical and chemical properties for various concentrations of Sodium Hydroxide, the main component of this product are as follows:
Series 10 I 20 1 30 I 50
- PHYSICAL STATE:
BOILING POINT @ 760 mm Liquid II 110°C 1130C 1190C 1400C Hg:
FREEZING POINT:
VAPOR PRESSURE mm Hg
-12'C 10'F 135
-26°C -14'F 110 00C 32'F 76 120C 53.6°F 13 I
@ 60'C:
SPECIFIC GRAVITY @ 15.6° C
DENSITY - Ib-gal @ 15.6°C:
1.11 9.26 1.22 10.17 1.33 11.09 1.53 12.76 I
VAPOR DENSITY: Not Determined EVAPORATION RATE (water= 1):
pH:
Similar to or slower than water depending upon weight percent.
14.0 pH @ 7.5% solution I
SOLUBILITY in H20 - % by Completely Soluble wt:
ODOR THRESHOLD: Not available. I APPEARANCE AND COLOR: This product is a clear light straw to turbid liquid solution.
HOW TO DETECT THIS SUBSTANCE (warning properties): Litmus paper will turn blue-purple upon contact with this solution even with low concentrations. 1 STABILITY: Stable.
- 10. STABILITY and REACTIVITY I
DECOMPOSITION PRODUCTS: Thermal decomposition products of this solution can include carbon monoxide, carbon dioxide, and sodium compounds.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product reacts with strong acids. Additionally, it is incompatible with organic halogen compounds, organic nitro compounds, aluminum, zinc, tin, and other metals. Avoid contact with leather and I
wool. Reactions with various food sugars may form carbon monoxide.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid exposure or contact to extreme temperatures and incompatible chemicals.
I PART IV Is there any other useful information about this material?
I
- 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: Additional toxicology information for components greater than 1 percent in concentration is provided below.
I SODIUM HYDROXIDE:
Eye Irritancy (monkey) = 1%solution, 24 hr, Severe.
Skin Irritancy (rabbit) = 500 mg, 24 hr, Severe.
I Eye Irritancy (rabbit) = 4 g, Mild.
Eye Irritancy (rabbit) = 1% solution, Severe.
Eye Irritancy (rabbit) = 50 :g, 24 hr, Severe.
Eye Irritancy (rabbit) = 1 mg, 24 hr, Severe.
I Eye Irritancy (rabbit) = 100 mg with rinse, Severe.
Cytogenic Analysis System (grasshopper, parenteral) = 20 mg LD60 (intraperitoneal, mouse) = 40 mg/kg.
LDLo (oral, rabbit) = 500 mg/kg. I BCS Sodium Hydroxide 1% - 50% M.S.D.S.
PAGE 5 OF 8 0252?
-11. TOXICOLOGICAL INFORMATION (Continued)
SUSPECTED CANCER AGENT: The components of this product's ingredients are not found on the following lists:
FEDERAL OSHA Z LIST, NTP, IARC, CAL/OSHA; and therefore are not considered to be, nor suspected to be, cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: This product is severely irritating to contaminated tissue.
SENSITIZATION TO THE PRODUCT: No component of this product is known to be a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components on the human reproductive system.
Mutaaenicitv: This product is not reported to produce mutagenic effects in humans. Mutation data is available for the Sodium Hydroxide (component of this product), obtained during clinical studies on animal tissues exposed to high doses of this compound.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratoqenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
A mutaaen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through generationallines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generationallines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generationallines. A reproductive toxin is any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES: Currently there are no Biological Exposure Indices (BEIs) associated with the components of this product.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Skin disorders can be aggravated by over-exposure to this product.
Inhalation of this products mists may aggravate respiratory conditions.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate over-exposure to this product.
- 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The components of this product are relatively stable in the environment; they may degrade, after time, into other organic and inorganic constituents. Additional environmental data is available for the components of this product as follows:
SODIUM HYDROXIDE: Kow = too low to be measured. Water solubility = 9 g/0.9 ml water. BOD: None.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is harmful to plant and animal life if this product is released into the environment. As with all chemicals, work practices should be aimed at eliminating environmental releases.
EFFECT OF CHEMICAL ON AQUATIC LIFE This product can substantially raise the pH of an aquatic environment and can be extremely toxic to fish and aquatic plants. As with all chemicals, work practices should be aimed at eliminating environmental releases. Additional aquatic data for the components of this product is available as follows:
SODIUM HYDROXIDE:
LCioo (Cyprimus carpio) = 180 ppm/24 hra25 0C TL, (mosquito fish) = 125 ppm/96 hr (fresh water)
TL, (bluegill) = 99 mg/L/48 hr (tap water)
- 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local regulations. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
EPA WASTE NUMBER: D002 (Characteristic, corrosive), applicable to wastes consisting only of this solution.
BCS Sodium Hydroxide 1%- 50% M.S.D.S.
PAGE 6 OF 8 0253
I
- 14. TRANSPORTATION INFORMATION THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE. U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Sodium Hydroxide solution HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive Material)
UN IDENTIFICATION NUMBER: UN 1824 PACKING GROUP: II DOT LABEL(S) REQUIRED: Corrosive NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 154 MARINE P5OLLUTANT: This product does not contain any components which are designated by the Department of Transportation to be Marine Pollutants. (49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS CONSIDERED AS DANGEROUS GOODS. Use the above information for the preparation of Canadian Shipments.
Note: The latest DOT information is provided, please verify all DOT information as it is subject to change without notice.
- 15. REGULATORY INFORMATION SARA REPORTING REQUIREMENTS: The components of this product subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act are as follows.
SoimHdroxide No Yes No SARA Threshold Planningq Quantity: Not applicable. I TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
CERCLA REPORTABLE QUANTITY (RQ): Sodium Hydroxide = 1000 lbs.
OTHER FEDERAL REGULATIONS: Not applicable.
U STATE REGULATORY INFORMATION:
denoted below:
Alaska - Designated Toxic and Hazardous Components of this product are covered under specific State regulations, as Minnesota . List of Hazardous Pennsylvania - Hazardous Substance List:
I Substances: Sodium Hydroxide. Substances: Sodium Hydroxide. Sodium Hydroxide.
California - Permissible Exposure Limits for Chemical Contaminants: Sodium Hydroxide.
Florida - Substance List: Sodium Missouri - Employer Information/Toxic Substance List: Sodium Hydroxide.
New Jersey - Right to Know Hazardous Substance List: Sodium Hydroxide.
Rhode Island - Hazardous Substance List:
Sodium Hydroxide.
Texas - Hazardous Substance List:
Sodium Hydroxide.
I Hydroxide. North Dakota - List of Hazardous West Virginia Substance List: Sodium Illinois - Toxic Substance List: Sodium Hydroxide.
Kansas - Section 302/313 List: Sodium Chemicals, Reportable Sodium Hydroxide.
Quantities: Hydroxide.
Wisconsin - Toxic and Hazardous Substances: Sodium Hydroxide.
I Hydroxide.
CALIFORNIA PROPOSITION 65 No component of this product is on the California Proposition 65 lists.
LABELING (Precautionary Statements): DANGER! CORROSIVE MATERIAL! LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. MAY CAUSE LUNG DAMAGE. REACTS I
VIOLENTLY WITH ACIDS. REACTS WITH WATER TO GENERATE HEAT. AVOID SPATTERING BY SLOWLY ADDING TO SOLUTION. Do not get into eyes, on skin or clothing. Avoid breathing spray or mist. Do not take internally. Use with adequate ventilation and employ respiratory protection when exposed to the mist or spray. When handling, wear chemical splash goggles, face shield, rubber gloves and protective clothing. Do not transfer to unlabeled containers. Use with adequate ventilation. Wash 1
thoroughly after handling, Keep container closed when not in use. FIRST-AID: In case of contact, immediately flush skin or eyes for at least 15 minutes. If inhaled, move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Do not induce vomiting. IN CASE OF FIRE: Use water, dry chemical, C0 2, or alcohol foam. IN CASE OF SPILL: Dike area to I
contain spill. Only trained personnel equipped full acid- protective gear should be permitted in this area. Spilled material may be absorbed into an appropriate absorbent material. Spills should be removed using a vacuum truck. Neutralize remaining traces of material with any dilute inorganic acid or citric acid and then flush with water. If necessary a liberal covering of sodium bicarbonate should then be applied and then rinsed with water. Do not wash into storm or sanitary sewer system.
1 TARGET ORGANS: Skin, eyes and respiratory system.
I BCS Sodium Hydroxide 1%- 50% M.S.D.S.
PAGE 7 OF 8 I
I 0254
- 15. REGULATORY INFORMATION (Continued)
WHMIS SYMBOLS: E- Corrosive Material
- 16. OTHER INFORMATION INFORMATION SOURCE: CHEMICAL SAFETY ASSOCIATES, Inc.
PREPARED BY: BASIC CHEMICAL SOLUTIONS THIS INFORMATION IS DRAWN FROM RECOGNIZED SOURCES BELIEVED TO BE RELIABLE. BASIC CHEMICAL SOLUTIONS MAKES NO GUARANTEES NOR ASSUMES ANY LIABILITY IN CONNECTION WITH THIS INFORMATION. THE USER SHOULD BE AWARE OF CHANGING TECHNOLOGY, RESEARCH, REGULATIONS AND ANALYTICAL PROCEDURES THAT MAY REQUIRE CHANGES HEREIN. THE ABOVE DATA IS SUPPLIED UPON THE CONDITION THAT PERSONS WILL EVALUATE THIS INFORMATION AND THEN DETERMINE ITS SUITABILITY FOR THEIR USE.
DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. TOXICOLOGICAL INFORMATION:
Some of these which are commonly used include the following: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented.
CAS #: This is the Chemical Abstract Service Number which uniquely Definitions of some terms used in this section are: LD5 o - Lethal Dose identifies each constituent. It is used for computer-related searching. (solids & liquids) which kills 50% of the exposed animals; LC50 : Lethal Concentration (gases) which kills 50% of the exposed animals; ppm EXPOSURE LIMITS IN AIR: concentration expressed in parts of material per million parts of air or ACGIH - American Conference of Governmental Industrial Hygienists, a water; mg/m 3 concentration expressed in weight of substance per volume professional association which establishes exposure limits. of air; mg/kg quantity of material, by weight, administered to a test TLV - Threshold Limit Value - an airborne concentration of a substance subject, based on their body weight in kg. Data from several sources are which represents conditions under which it is generally believed that used to evaluate the cancer-causing potential of the material. The nearly all workers may be repeatedly exposed without adverse effect. sources are: IARC - the International Agency for Research on Cancer; The duration must be considered, including the 8-hour Time Weighted NTP - the National Toxicology Erogram,, RTECS - the Registry of Toxic Average (TWA), the 15-minute Short Term Exposure Limit, and the Effects of Chemical Substances OSHA and CAL/OSHA. IARC and NTP instantaneous Ceiling Level. Skin adsorption effects must also be rate chemicals on a scale of decreasing potential to cause human cancer considered. with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.
OSHA - U.S. Occupational Safety and Health Administration. Other measures of toxicity include TDLo, the lowest dose to cause a PEL - Permissible Exposure Limit - This exposure value means exactly symptom and TCLo the lowest concentration to cause a symptom; TDo, the same as a TLV, except that it is enforceable by OSHA. The OSHA LDLo, and LDo, or TC, TCo, LCLo, and LCo,. the lowest dose (or Permissible Exposure Limits are based in the 1989 PELs and the June, concentration) to cause death. BEI - Biological Exposure Indices, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: represent the levels of determinants which are most likely to be observed 40191). Both the current PELs and the vacated PELs are indicated. The in specimens collected from a. healthy worker who has been exposed to phrase, "Vacated 1989 PEL," is placed next to the PEL which was chemicals to the same extent as a worker with inhalation exposure to the vacated by Court Order. TLV.
IDLH - Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape within 30-minutes REGULATORY INFORMATION:
without suffering escape-preventing or permanent injury. The DFG - MAK This section explains the impact of various laws and regulations on the is the Republic of Germany's Maximum Exposure Level, similar to the material. EPA is the U.S. Environmental Protection Agency. WHMIS is U.S. PEL. NIOSH is the National Institute of Occupational Safety and the Canadian Workplace Hazardous Materials Information System. DOT Health, which is the research arm of the U.S. Occupational Safety and and TC are the U.S. Department of Transportation and the Transport Health Administration (OSHA), NIOSH issues exposure guidelines called Canada, respectively. Other acronyms used are: Superfund Recommended Exposure Levels (RELs). When no exposure guidelines Amendments and Reauthorization Act (SARA); the Toxic Substance are established, an entry of NE is made for reference. Control Act (TSCA); Marine Pollutant status according to the DOT; California's Safe Drinking Water Act (Proposition 65); the FLAMMABILITY LIMITS IN AIR: Comprehensive Environmental Response, Compensation, and Much of the information related to fire and explosion is derived from the Liability Act (CERCLA or Superfund); and various state regulations.
National Fire Protection Association (NFPA). LEL - the lowest percent of This section also includes information on the precautionary warnings vapor in air, by volume, that will explode or ignite in the presence of an which appear on the materials package label.
ignition source. UEI - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source.
BCS Sodium Hydroxide 1% - 50% M.S.D.S.
PAGE 8 OF 8 0255
I Material Safety Data Sheet Sodium nitrite I ACC# 21410 II Section 1 - Chemical Product and Company Identification 1 MSDS Name: Sodium nitrite Catalog Numbers: AC196620000,.AC196620025, AC217600000, AC217600010, AC424350000, I
AC424350020, AC424350050, AC424355000, S80187, S93374, NC9151301, NC9155411, NC9790812, S338-3, S347-10, S347-250, S347-3, S347-500 Synonyms: Nitrous acid, sodium salt.
I Company, Identification:
Fisher Scientific 1 Reagent Lane I
Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 I
For International CHEMTREC assistance, call: 703-527-3887 I
ISection 2 - Composition, Information on IngredientsI CAS# Chemical Name Percent EINECS/ELINCS I
7632-00-0 Sodium nitrite >97 231-555-9 I
Section 3 - Hazards Identification EMERGENCY OVERVIEW 1
Appearance: white to light yellow crystals.
Danger! May be fatal if inhaled. Strong oxidizer. Contact with other material may cause a fire.
1 Harmful if swallowed. Causes eye, skin, and respiratory tract irritation. ,May cause methemoglobinemia. Hygroscopic (absorbs moisture from the air). Air sensitive. This substance has caused adverse reproductive and fetal effects in animals. I Target Organs: Blood, cardiovascular system, smooth muscle.
Potential Health Effects I
Eye: Causes eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin: Causes skin irritation. May be absorbed through the skin.
Ingestion: Harmful if swallowed. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. Causes digestive tract I
irritation. Ingestion may cause weakness, muscular incoordination, fine tremors, loss of reflexes, convulsions and possible death from circulatory collapse. Ingestion may cause a decrease in blood pressure, rapid pulse and visual disturbances.
I Inhalation: May be fatal if inhaled. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, tachycardia, dyspnea (labored breathing), and death. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and I
upper airway obstruction caused by edema.
0256
Chronic: May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Animal studies have reported the development of tumors. Sodium nitrate may react with secondary or tertiary amines to form nitrosamines (certain nitrosamines are cancer suspect agents).
Section 4 - First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. SPEED IS ESSENTIAL, OBTAIN MEDICAL AID IMMEDIATELY.
Notes to Physician: Absorption of this product into the body may cause cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood). Moderate degrees of cyanosis need to be treated only by supportive measures: bed rest and oxygen inhalation. If cyanosis is'severe, intravenous injection of Methylene Blue, lmg/kg of body weight may be of value.
IF -' Section 5- Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Use water with caution and in flooding amounts. May explode from heat or contamination. May accelerate burning if involved in a fire.
Extinguishing Media: Use water only! Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. For large fires, flood fire area with water from a distance. Do NOT use dry chemicals, C02, Halon or foams.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 1; Special Hazard: OX Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Keep combustibles (wood, paper, oil, etc.,) away from spilled material.
I[ I 0257
I II Section7- Handling and Storage I
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Handle under an inert atmosphere. Store protected from air. Use only in a chemical fume hood.
Storage: Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store under an inert atmosphere. Avoid storage on wood floors.
II Section 8- Exposure Controls, Personal Protection 1 I
I Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits I
I Chemical Name Sodium nitrite I ACGIH none listed NIOSH none listed I OSHA - Final PELs none listed I OSHA Vacated PELs: Sodium nitrite: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's I eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI I
Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
I I Section 9- Physical and Chemical Properties I
Physical State: Crystals Appearance: white to light yellow Odor: odorless I
pH: - 9 Vapor Pressure: Not available.
Vapor Density: Not available.
I Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 320 deg C Freezing/Melting Point:271 deg C I
Decomposition Temperature:320 deg C Solubility: Soluble.
Specific Gravity/Density: 2.168 I
Molecular Formula:NaNO2 Molecular Weight: 69.00 I
0258 I
IL Section 10- Stability and Reactivity Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Unstable if heated, may explode at temperatures greater than 533 0 C.
Conditions to Avoid: Ignition sources, dust generation, exposure to air, exposure to moist air or water, temperatures above 320 0 C.
Incompatibilities with Other Materials: Reducing agents, acids, amines, chlorates, permanganates, cyanides (e.g. potassium cyanide, sodium cyanide), metals as powders (e.g.
hafnium, raney nickel), hypophosphites, sulfites, tannic acid, organic matter, antipyrine, ammonium salts, acetanilide, iodides, mercury salts, moisture, air, activated carbon, vegetable astringents.
Hazardous Decomposition Products: Oxides of nitrogen, irritating and toxic fumes and gases.
Hazardous Polymerization: Will not occur.
Il Section 11 - Toxicological Information RTECS#:
CAS# 7632-00-0: RA1225000; RA1425000 LD50/LC50:
CAS# 7632-00-0:
Draize test, rabbit, eye: 500 mg/24H Mild; Inhalation, rat: LC50 = 5.5 mg/m3/4H; Oral, mouse: LD50 = 175 mg/kg; Oral, rabbit: LD50 = 186 mg/kg; Oral, rat: LD50 = 180 mg/kg; Carcinogenicity:
CAS# 7632-00-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: Oral, rat: TDLo = 2190 gm/kg/2Y-C (Tumorigenic - Carcinogenic by RTECS criteria
- Gastrointestinal - tumors).; Oral, rat: TD = 91 gm/kg/2Y-C (Tumorigenic - equivocal tumorigenic agent by RTECS criteria - Skin and Appendages - tumors and Reproductive - Tumorigenic effects -
testicular tumors).; Oral, rat: TD = 40 gm/kg/56W-C - (Tumorigenic - neoplastic by RTECS criteria
- Liver - tumors).
Teratogenicity: Oral, rat: TDLo = 660 mg/kg (female 1-22 day(s) after conception) Effects on Embryo or Fetus - fetal death and Effects on Newborn - growth statistics (e.g.%, reduced weight gain).; Oral, rat: TDLo = 10280 mg/kg (female 1-22 day(s) after conception and lactating female 20 day(s) post-birth) Effects on Newborn - weaning or lactation index (e.g., # alive at weaning per
- alive at day 4).; Oral,mouse: TDLo = 280 mg/kg (female 1-14 day(s) after conception) Specific Developmental Abnormalities - blood and lymphatic systems (including spleen and marrow).
Reproductive Effects: Oral, mouse: TDLo = 1200 mg/kg (female 6-15 day(s) after conception)
Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea).; Oral, mouse: TDLo = 1680 mg/kg (male 14 day(s) pre-mating) Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females).; Oral, mouse: TDLo = 840 mg/kg (male 14 day(s) pre-mating)
Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count).
Mutagenicity: Unscheduled DNA Synthesis: Human, HeLa cell = 6 mmol/L.; DNA Inhibition:
Human, Fibroblast = 2000 ppm.; DNA Inhibition: Human Cells - not otherwise specified = 725 umol/L.
Neurotoxicity: No information found.
Other Studies:
0259
I
-I I Section 12 - Ecological Information I
Ecotoxicity: Fish: Rainbow trout: LC50 = 0.19 -0.39 mg/L; 96 Hr; Flow-through bioassayFish:
Mosquito Fish: TLm =8.1 ppm; 24 Hr; Highly turbid waterFish: Creek chub: Critical range = 400- I 2000 ppm; 24 Hr; Detroit River No data available.
Environmental: In water sodium nitrite dissociates completely and under aerobic conditions the nitrite ions are oxidized to nitrates.
Physical: No information available.
I Other: Harmful to aquatic life in very low concentrations.
I I Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a I
hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
I RCRA U-Series: None listed.
I I Section 14 - Transport Information US DOT Canada TDG I
I Shipping Name:
Hazard Class:
UN Number:
SODIUM NITRITE 5.1 UN1500 SODIUM NITRITE 5.1(6.i)
UN1500 I
Packing Group: III III I
I Section 15 - Regulatory Information US FEDERAL I
TSCA CAS# 7632-00-0 is listed on the TSCA inventory.
I Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule.
I Section 12b None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule I
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs CAS# 7632-00-0: 100 lb final RQ; 45.4 kg final RQ I
SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ.
SARA Codes CAS # 7632-00-0: acute, chronic, flammable.
I 0260 I
Section 313 This material contains Sodium nitrite (CAS# 7632-00-0, >97%),which is subject to the reporting requirements of Section 313 of SARA Title III and. 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7632-00-0 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE CAS# 7632-00-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.
California Prop 65 California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols:
TON Risk Phrases:
R 25 Toxic if swallowed.
R 8 Contact with combustible material may cause fire.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S 61 Avoid release to the environment. Refer to special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7632-00-0: 2 Canada - DSL/NDSL CAS# 7632-00-0 is listed on Canada's DSL List.
Canada - WHMIS This product has a WHMIS classification of C, DiB, D2B.
Canadian Ingredient Disclosure List CAS# 7632-00-0 is listed on the Canadian Ingredient Disclosure List.
IF - - Section 16 - Additional Information MSDS Creation Date: 7/02/1999 Revision #6 Date: 6/18/2004 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantabilityor any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particularpurposes. In no event shall Fisherbe liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisherhas been advised of the 0261
1 possibility of such damages. I I
I I
I I
I I
I I
I I
I I
I I
I 0262 I
MSDS Number: N3660 ***** Effective Date. 05/06/05 ***** Supercedes: 07/02/02 24 HowEitwr ojy Tolphono2 900. $0-1$1 C OEMTOE, 1-4*,4300 M SDS Mateial Safety Data Shee t / 4,0 .66f OsjIleids U'.S.sntd' ci M-ds Ch rlein-~ OS5738 Fim M111o~r'o~i Siir W, 222 Rod S6hool LnCH I 1Mlimc
-alinkro'dt.
Jaem,~ JTBaker.o 11.O1EýCl4EWTrm6 CANUE erlwwm 0EMCAS PhIllipuburg. NJ, 1018665 tl~ 0* v,~~1ae All ounrneqwtcy q*&lio tbould bedodu~ed lo Cu xrC,8,icS~e ~-O-S.5i rai~i NITRIC ACID, 50-70%
- 1. Product Identification Synonyms: Aqua Fortis; Azotic Acid; Nitric Acid 50%; Nitric Acid 65%; nitric acid 69-70%
CAS No.: 7697-37-2 Molecular Weight: 63.01 Chemical Formula: HNO3 Product Codes:
J.T. Baker: 411D, 412D, 5371, 5796, 5801, 5826, 5856, 5876, 5896, 9597, 9598, 9600, 9601, 9602, 9603, 9604, 9606, 9607, 9608, 9610, 9616, 9617, 9670 Mallinckrodt: 1409, 2704, 2716, 6623, H862, H988, H993, H998, V077, V633, V650
- 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Nitric Acid 7697-37-2 50 - 70% Yes Water 7732-18-5 30 - 50% No
- 3. Hazards Identification 0263
I Emergency Overview POISON! DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE. 3 SAF- .T-DATA(tm) Ratings (Provided here for your convenience)
Health Rating: 4 - Extreme (Poison)
Flammability Rating: 0 - None Reactivity Rating: 3 - Severe (Oxidizer)
Contact Rating: 4 - Extreme (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code: White (Corrosive)
Potential Health Effects I Nitric acid is extremely hazardous; it is corrosive, reactive, an oxidizer, and a poison. I+
Inhalation:
Corrosive! Inhalation of vapors can cause breathing difficulties and lead to pneumonia and pulmonary edema, which may be fatal. Other symptoms may include coughing, choking, and irritation of the nose, throat, and respiratory tract.
Ingestion: I Corrosive! Swallowing nitric acid can cause immediate pain and bums of the mouth, throat, esophagus and gastrointestinal tract.
Skin
Contact:
Corrosive! Can cause redness, pain, and severe skin bums. Concentrated solutions -cause deep ulcers and stain skin a yellow or yellow-brown color.
Eye
Contact:
Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe bums and permanent eye damage.
Chronic Exposure:
Long-term exposure to concentrated vapors may cause erosion of teeth and lung damage.
3 Long-term exposures seldom occur due to the corrosive properties of the acid.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, eye disease, or cardiopulmonary diseases may be more susceptible to the effects of this substance.
I I
- 4. First Aid Measures Immediate first aid treatment reduces the health effects of this substance.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give 0264,
oxygen. Call a physician.
Ingestion:
DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin
Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Eye
Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
- 5. Fire Fighting Measures Fire:
Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Can react with metals to release flammable hydrogen gas.
Explosion:
Reacts explosively with combustible organic or readily oxidizable materials such as:
alcohols, turpentine, charcoal, organic refuse, metal powder, hydrogen sulfide, etc. Reacts with most metals to release hydrogen gas which can form explosive mixtures with air.
Fire Extinguishing Media:
Water spray may be used to keep fire exposed containers cool. Do not get water inside container.
Special Information:
Increases the flammability of combustible, organic and readily oxidizable materials. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or othfer positive pressure mode.
- 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.
J. T. Baker NEUTRASORB or TEAM 'Low Na+' acid neutralizers are recommended for spills of this product.
0265
I
- 7. Handling and Storage I Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage.
Protect from physical damage. Keep out of direct sunlight and away from heat, water, and incompatible materials. Do not wash out container and use it for other purposes. When diluting, the acid should always be added slowly to water and in small amounts. Never use hot water and never add water to the acid. Water added to acid can cause uncontrolled boiling and splashing. Containers of this material may be hazardous when empty since they I
retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. I
- 8. Exposure Controls/Personal Protection 3 Airborne Exposure Limits: I
-OSHA Permissible Exposure Limit (PEL):
2 ppm (TWA), 4 ppm (STEL)
-ACGIH Threshold Limit Value (TLV):
2 ppm (TWA); 4 ppm (STEL)
I Ventilation System: I A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices,most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. Nitric acid is an oxidizer and should not come in contact with cartridges and canisters that contain oxidizable materials, such as activated charcoal. Canister-type respirators using sorbents are ineffective.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
I Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. I
- 9. Physical and Chemical Properties 3 Appearance: I Colorless to yellowish liquid.
Odor:
Suffocating, acrid.
0266 I
Solubility:
Infinitely soluble.
Specific Gravity:
1.41 pH:
1.0 (0.1M solution)
% Volatiles by volume @ 21C (70F):
100 (as water and acid)
Boiling Point:
122C (252F)
Melting Point:
-42C (-44F)
Vapor Density (Air=l):
2-3 Vapor Pressure (mm Hg):
48 @ 20C (68F)
Evaporation Rate (BuAc=l):
No information found.
- 10. Stability and Reactivity Stability:
Stable under ordinary conditions of use and storage. Containers may burst when heated.
Hazardous Decomposition Products:
When heated to decomposition, emits toxic nitrogen oxides fumes and hydrogen nitrate.
Will react with water or steam to produce heat and toxic and corrosive fumes.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
A dangerously powerful oxidizing agent, concentrated nitric acid is incompatible with most substances, especially strong bases, metallic powders, carbides, hydrogen sulfide, turpentine, and combustible organics.
Conditions to Avoid:
Light and heat.
- 11. Toxicological Information Nitric acid: Inhalation rat LC50: 244 ppm (N02)/30M; Investigated as a mutagen, reproductive effector. Oral (human) LDLo: 430 mg/kg.
-- -----\Cancer Lists\-------------------------------------------------------
--- NTP Carcinogen---
Ingredient Known Anticipated IARC Category Nitric Acid (7697-37-2) No No None Water (7732-18-5) No No None 0267
I I
- 12. Ecological Information I
Environmental Fate:
No information found.
Environmental Toxicity: I No information found.
I
- 13. Disposal Considerations I
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate I analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
I
- 14. Transport Information I Domestic (Land, D.O.T.) I Proper Shipping Name: NITRIC ACID (WITH NOT MORE THAN 70% NITRIC ACID)
Hazard Class: 8 I
UN/NA: UN2031 Packing Group: II Information reported for product/size: 6.5GL I
International (Water, I.M.O.)
I Proper Shipping Name: NITRIC ACID Hazard Class: 8 UN/NA: UN2031 Packing Group: II I
Information reported for product/size: 6.5GL I
- 15. Regulatory Information I Ingredient
\Chemical
Inventory Status - Part 1\--------------
TSCA EC Japan Australia I 0268 I
Nitric Acid (7697-37-2) Yes Yes Yes Yes Water (7732-18-5) Yes Yes Yes Yes
-- -----\Chemical Inventory Status - Part 2\----------------------------------
-- Canada--
Ingredient Korea DSL NDSL Phil.
Nitric Acid (7697-37-2) Yes Yes No Yes Water (7732-18-5) Yes Yes No Yes
-- ----- \Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------ SARA 313 ------
Ingredient RQ TPQ List Chemical Catg.
Nitric Acid (7697-37-2) 1000 1000 Yes No Water (7732-18-5) No No No No
-- -----\Federal, State & Internat~ional Regulations - Part 2\----------------
-RCRA- -TSCA-Ingredient CERCLA 261.33 8(d)
Nitric Acid (7697-37-2) 1000 No No Water (7732-18-5) No No No Chemical Weapons Convention: No TSCA 12(b) : No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: No (Mixture / Liquid)
Australian Hazchem Code: 2PE Poison Schedule: S6 WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
- 16. Other Information NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0 Other: Oxidizer Label Hazard Warning:
POISON! DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED.
INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Do not breathe vapor or mist.
Use only with adequate ventilation.
Wash thoroughly after handling.
Keep from contact with clothing and other combustible materials.
Do not store near combustible materials.
04269
I
-I Store in a tightly closed container.
Remove and wash contaminated clothing promptly.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 I
minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases get medical attention immediately.
Product Use:
Laboratory Reagent.
Revision Information:
No Changes.
Disclaimer:
Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information I
must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
Prepared by: Environmental Health & Safety I Phone Number: (314) 654-1600 (U.S.A.)
I 027'0I
EAGLE PICHER TECHINOLOGIES LLC SODIUM PENTABORATE, ENRICHED MATERIAL SAFETY DATA SHEET Preparedto U.S. OSHA, CMA, ANSI, andCanadianWHMIS Standards
- PART I What is the materialand what do I need to know in an emergency?
m I 1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): SODIUM PENTABORATE, ENRICHED CHEMICAL NAME/CLASS: Inorganic Boron Compound SYNONYMS: None PRODUCT USE: Various Uses SUPPLIER/MANUFACTURER'S NAME EAGLE-PICHER TECHNOLOGIES LLC ADDRESS: PO Box 798, Quapaw, OK 74354 EMERGENCYPHONE: 1-918-673-2201 01-918-673-2201 (International)
BUSINESS PHONE: 1-918-673-2201 DATE OF PREPARATION: May 06, 2003
- 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # WW/O EXPOSURE UMITS IN AIR ACGIH-TLV OSHA-PEL NIOSH OTHER TWA STEL TWA 3 STEL IDLH
_ mg/m mg/rm3 mg/mn rngm 3 mg/rng 3 mmrng Sodium Pentaborate 200443-98-7 100 10 NE 15 (Total NE 2000 NIOSH REL:
Currently there are no exposure Dust) TWA =10 limits for Sodium Pentabor&e. The limits given are for Boron Oxide NE = Not Established_ N)TF I1V: AL L WHMIS rouirhwd infr~im i' included in anomrooate sections based on the AN5RI 74flA 1-1i;cR f~rnmim Thk*
product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
- 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: This product consists of an odorless white powder. Health Hazards: Inhalation of dusts from this product may be irritating to the respiratory system. Contact with the skin may cause irritation, especially if contact is prolonged. Eye contact will cause irritation due to mechanical irritation. Flammability Hazards: This product is not flammable. Exposure by inhalation or ingestion may cause symptoms of boron toxicity. If exposed to extremely high temperatures, this product can decompose to generate irritating vapors and toxic gases (e.g. boron oxides). Reactivity Hazards: This product is not reactive. Environmental Hazards: Negligible. Emergency Recommendations: Emergency responders must wear personal protective equipment suitable for the situation to which they are responding.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The primary routes of occupational overexposure are inhalation of dusts or fumes if heated to high temperatures and contact with skin and eyes. The symptoms of overexposure to this product, via route of exposure are as follows:
INHALATION: Inhalation of dusts of this product may be irritating to the nose and throat. Symptoms of can include coughing and sneezing and are expected to be alleviated upon breathing fresh air. Boron compounds are known to be absorbed via mucous membranes. Symptoms of exposure may include those described under "Ingestion" and may include adverse effects on the central nervous system, rash, vomiting, convulsions and anemia.
CONTACT WITH SKIN or EYES: Skin contact may cause irritation. If contact is prolonged, symptoms may include pain, itchiness and reddening. Contact with the eyes can cause pain, tearing and redness. Prolonged or repeated skin overexposures may cause dermatitis (dry red skin).
SKIN ABSORPTION: Solutions of boron compounds may be absorbed via intact skin, although the rate of absorption is slow and toxic effects are less likely. Absorption through damaged skin is rapid and complete.
INGESTION: Though not anticipated to be a significant route of occupational exposure, ingestion of large quantities of this product may cause anorexia, weight loss, vomiting, mild diarrhea, skin rash, alopecia (hair loss), convulsions and anemia. Boron poisoning causes depression of the circulation, persistent vomiting, and diarrhea, followed by profound shock and coma. The temperature becomes sub-normal and a scarietina-forrn rash may cover the entire body.
Shedding of the skin may occur in the area of the rash. (continued on following page) 0271
EAGLE PICHER TECHNOLOGIES LLC
- 3. HAZARD IDENTIFICATION SODIUM PENTABORATE, ENRICHED I INGESTION (continued): In severe poisoning with boron compounds, oliguria, anuria and tubular necrosis may occur along with lethargy, HAZARDOUS MATERIALIDENTIFICA11ON SYSTEM I
twitching of facial muscles and extremities, and cyanosis.
INJECTION: Though not anticipated to be a likely route of occupational exposure, injection of this material (via puncture or laceration by, a contaminated object) may cause local reddening, tissue swelling, and l IEALTH HAZARD (BLUE) I I discomfort in addition to the wound.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
1'
-LAMMABIlTY HAZARD (RED) 0 I
ACUTE: Acute exposure to Sodium Pentaborate by inhalation, and skin or eye contact may irritate contaminated tissues. Ingestion of Sodium Pentaborate may result in depression of circulatory system, central nervous system effects, vomiting, diarrhea, shock or coma. Absorption I
PHYSICALHAZARD (YELLOW)I0 through the mucous membranes may occur, causing adverse effects on central nervous system or rash.
CHRONIC: Chronic ingestion of this product may give rise to anorexia, I
loss of strength, confusion, rash and alopecia (hair loss). Prolonged or _PROTECTIVE EQUIPNEfff_
repeated skin overexposures may cause dermatitis (dry red skin). Refer to Section 11 (Toxicological Information) for additional information. I TARGET ORGANS: ACUTE: Skin, eyes, respiratory system, central nervous system. CHRONIC: Skin, intestines, liver, and kidney, male reproductive system. I For Routine Industrial Ue and Handling Applications See Section 16 for Definition of Ratings I PART II What should I do if a hazardous situationoccurs? I
- 4. FIRST-AID MEASURES Contaminated individuals should be taken for medical attention if they feel unwell or if adverse effects occur. Take copy of label and MSDS to physician or health professional with contaminated individual.
SKIN EXPOSURE: If this material contaminates the skin, begin decontamination with running water. Recommended I
flushing;is for 15 minutes if any sign of skin irritation develops. Contaminated individual should seek immediate medical attention if any adverse exposure symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open contaminated individual's-eyes while under gently running-water.
I Use sufficient force to open eyelids. Have contaminated individual "roll" eyes. Minimum flushing is for 15 minutes. Do not interrupt flushing. Contaminated individual must seek medical attention.
INHALATION: If this product is inhaled, remove contaminated individual to fresh air.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT I
INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. If victim is conscious, rinse mouth with water immediately. Never induce vomiting or give diluents (milk or water) to someone who is unconscious.
having convulsions, or unable to swallow. If vomiting occurs, lean patient forward or place on left side (head-down I
position, if possible) to maintain an open airway and prevent aspiration.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
overexposure to this product.
Skin disorders may be aggravated by prolonged RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.
I
- 5. FIRE-FIGHTING MEASURES FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable FLAMMABLE LIMITS (in air by volume, 0)
Lower. Not applicable.
Upper: Not applicable.
02272172
- 5. FIRE-FIGHTING MEASURES (Continued)
- FIRE EXTINGUISHING MATERIALS: Use extinguishing material suitable to the surrounding fire. NFPA-RATING Water Spray: YES Carbon Dioxide: YES Foam: YES Dry Chemical: YES
____ YES r: Any "ABC" Class UNUSUAL FIRE AND EXPLOSION HAZARDS: When involved in a fire, this product may decompose and produce irritating vapors and toxic I gases, including boron oxides. HEAL&TH 1 R0ACIVIY Explosion Sensitivity Sensitivity to Mechanical Impact: Not applicable.
to Static Discharge: Not applicable.
E SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural fire-fighters must wear Self-Contained Breathing Apparatus (SCBA) and full protective equipment. OTE
-Move fire-exposed containers from area of the fire if it can be done See Section 16 for without risk to fire-fighters. Keep fire exposed containers cool with water Definition of Ratings spray. If possible, fire-fighters should control fire run-off water to prevent environmental contamination. Decontaminate fire response equipment thoroughly.
- 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Small releases can be swept-up or cleaned-up using a damp sponge or polypads, avoiding generation of dusts. Responders should wear gloves, goggles, and suitable body protection during the clean-up I of small spills. Larger, uncontrolled releases should be responded to by trained personnel using pre-planned procedures.
Proper protective equipment should be used. In case of a large spill (e.g. > 100 kg), clear the affected area, protect people, and respond with trained personnel. Minimum Personal Protective Equipment should be Level B: gloves (rubber I gloves, nitrile gloves, or latex gloves), labcoat, Tyvek or similar clothing and goggles. Ifdusts are created during clean-up the use of a Air-Purifying respirator with high efficiency particulate filter is recommended. Self-Contained Breathing Apparatusmust be selected if releases occur in confined or poorly-ventilated areas, or in situations in which the level of oxygen is below 19.5% or is unknown. Sweep-up or vacuum spilled solid (an explosion-proof vacuum should be used).
Rinse area with soap and water solution, followed by a water rinse. Place all spill residue in appropriate container which is property labeled. Seal the container immediately and dispose of in accordance with U.S. Federal, State and local regulations and those of Canada and it's provinces (see Section 13, Disposal Considerations).
PART III How can I prevent hazardoussituationsfrom occuning?
- 7. HANDLING and STORAGE I WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product IN YOU. Wash thoroughly after using this material. Avoid dusts generated by this product. Do not eat, smoke, apply cosmetics, or drink while handling this material. Use ventilation and other engineering controls to minimize potential exposure to dusts of this product. Remove contaminated clothing immediately. Wipe-down area routinely to avoid the accumulation of dusts.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Open bottles carefully. Empty containers may contain residual material and should be handled with care. Store this product in a cool, dry location, away from direct sunlight, sources of intense heat. Store away from incompatible I chemicals (see Section 10, Stability and Reactivity). Inspect all incoming containers before storage to ensure they are properly labeled and not damaged. All equipment used in the handling of this material should be electrically grounded.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if necessary. Collect all rinsates and disposal of in accordance with U.S. Federal, State and local regulations and those of Canada and its provinces.
- 8. EXPOSURE CONTROLS - PERSONAL PROTECTION INTERNATIONAL EXPOSURE LIMITS FOR COMPONENTS: Currently, there are no international exposure limits for Sodium Pentaborate. Please refer to exposure limits given in Section 2 (Composition and Information On Ingredients).
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposures are below limits provided in Section 2 (Composition and Information on Ingredients). Prudent practice is to ensure eyewash/safety shower stations are available near areas where this product is used.
The following information on appropriatePersonalProtective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada. Please reference appricable regulationsand standardsfor relevant details.
0 27 3
EAGLE PICHER TECHNOLOGIES LLC SODIUM PENTABORATE, ENRICHED
- 8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
RESPIRATORY PROTECTION: None needed under normal circumstances of use. Maintain airborne contaminant concentrations below guidelines listed in Section 2 (Composition and Information on IngredieRts) if applicable. If.
respiratory protection is needed, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), or equivalent U.S. State standards, and Canadian CSA Standard Z94.4-93.
Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998). The following are NIOSH respiratory guidelines for boron oxide, a decomposition product of Sodium Pentaborate.
BORON OXIDE I CONCENTRATION RESPIRATORY PROTECTION Up to 50 mg/mr: Any Dust and Mist Respirator.
Up to 100 mg/m 3 : Any Dust and Mist Respirator except single-use and quarter-mask respirators, or any Supplied-Air Respirator (SAR).
Up to 250 mg/rn: Any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator (PAPR) with a dust and mist filter.
Up to 500 mg/m 3 : Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any PAPR with a tight-fitting facepiece and a high-efficiency particulate filter , or any Self-Contained 2mgrn 3: Breathing Apparatus (SCBA) with a full facepiece, or any SAR (with a full facepiece.
Up to 2000 mAny Supplied-Air Respirator (SAR) that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
I Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any appropriate escape-type, SCBA.
EYE PROTECTION: Splash goggles or safety glasses may be worn if operations can generate airborne particulates of this product. If necessary, refer to U.S. OSHA 29 CFR 1910.133 and appropriate Canadian Standards for further information.
HAND PROTECTION: Wear light-weight plastic or rubber gloves for routine industrial use. Check gloves for leaks prior to use. If necessary, refer to U.S. OSHA 29 CFR 1910.138 and appropriate Standards of Canada.
BODY PROTECTION: If necessary, use body protection appropriate for task (e.g., Tyvek suit, rubber apron). If necessary, use body protection appropriate for task (e.g., Tyvek suit, rubber apron). If splashes or sprays are anticipated, use rubber boots. If necessary, refer to appropriate Standards of Canada. If a hazard of injury to the feet I exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee's feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
- 9. PHYSICAL and CHEMICAL PROPERTIES RELATIVE VAPOR DENSITY (air = 1): Not determined. EVAPORATION RATE (nBuAc = 1): Not determined.
SPECIFIC GRAVITY (water = 1): 1.72 MELTING/FREEZING POINT: Not determined.
SOLUBILITY IN WATER: 15.4% BOILING POINT: Not determined.
VAPOR PRESSURE (,, 2140°C: 1.56X10-5 ATM pH: Not applicable.
ODOR THRESHOLD: Not applicable. MOLECULAR WEIGHT:
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable.
APPEARANCE, ODOR AND COLOR: Sodium Pentaborate is a white, odorless powder.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance of this product is a distinguishing characteristic in event of accidental release.
- 10. STABILITY and REACTIVITY STABILITY: Stable at normal temperature and pressure.
DECOMPOSITION PRODUCTS: The products of thermal decomposition of this material include irritating vapors and toxic gases (e.g., oxides boron).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Sodium Pentaborate is incompatible with strong oxidizers, strong acids and strong caustics.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible chemicals.
0274-
EAGLE PICHER TECHNOLOGIES LLC SODIUM PENTABORATE, ENRICHED EAGLE PICHER TECHNOLOGIES LLC SODIUM PENTABORATE, ENRICHED I PART IV Is there any other useful information about this material?
U 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: There are no specific toxicology data currently available for Sodium Pentaborate.
SUSPECTED CANCER AGENT: Sodium Pentaborate is not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and CAL/OSHA, and therefore is neither considered to be nor suspected to be cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: Prolonged dermal exposure may cause irritation. Contact with the eyes may be irritating.
SENSITIZATION TO THE PRODUCT: Sodium Pentaborate is not known to be skin or respiratory sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information conceming the effects of Sodium Pentaborate on the human reproductive system.
Mutagenicity: Sodium Pentaborate is not reported to cause reproductive effects in humans.
Embryotoxicity: Sodium Pentaborate is not reported to produce embryotoxic effects in humans.
Teratogenicitv: Sodium Pentaborate is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: Sodium Pentaborate is not known to cause reproductive toxicity effects.
A mutaaen is a chemical which causes permanent changes to genetic materfial (DNA) such that the changes will propagatethrough generationallines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratoqen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generationallines. A reproductive toxin is any substance which interferesin any way with the reproductive process.
BIOLOGICAL EXPOSURES INDICES (BEIs): Currently, there are no Biological Exposure Indices (BEIs) determined for Sodium Pentaborate.
- 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: Sodium Pentaborate is stable under ambient environmental conditions.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Sodium Pentaborate may cause adverse effects on terrestrial plants and animals especially if release in large quantities.
EFFECT OF CHEMICAL ON AQUATIC LIFE: Sodium Pentaborate may cause adverse effects on aquatic plants and animals if released into an aquatic environment, especially if release in large quantity.
- 13. DISPOSAL CONSIDERATIONS PREPARINGIWASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and.
local regulations. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local waste regulatory authority. Empty containers, as defined by appropriate sections of RCRA, are not RCRA hazardous wastes. Insure proper management of any residuals remaining in containers.
EPA WASTE NUMBER: Not applicable.
- 14. TRANSPORTATION INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Not Regulated HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable UN IDENTIFICATION NUMBER: Not Applicable DOT LABEL(S) REQUIRED: Not Applicable PACKAGING GROUP: Not Applicable NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): Not Applicable MARINE POLLUTANT: Sodium Pentaborate is not listed as a marine pollutant as per D.O.T. (49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: Sodium Pentaborate is not considered as dangerous goods, per regulations of Transport Canada.
INTERNATIONAL AIR TRANSPORT ASSOCIATION DESIGNATION: Sodium Pentaborate is not considered as dangerous goods, per rules of IATA.
INTERNATIONAL MARITIME ORGANIZATION (IMO): Sodium Pentaborate is not considered as dangerous goods, per rules of the IMO. Marine Pollutant: Sodium Pentaborate is not designated by the IMO to be a Marine Pollutant.
0275
EAGLE PICHER TECHNOLOGIES LLC SODIUM PENTABORATE, ENRICHED
- 15. REGULATORY INFORMATION U.S. STATE AND FEDERAL REGULATIONS:
UJ.S. SARA REPORTING REQUIREMENTS: Sodium Pentaborate is not subject to the reporing requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act.
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for Sodium Pentaborate. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
U.S. TSCA INVENTORY STATUS: Sodium Pentaborate is listed on the TSCA Inventory.
.OTHER U.S. FEDERAL REGULATIONS: Not applicable.
_U.S. STATE REGULATORY INFORMATION: Sodium Pentaborate is covered under specific State regulations, as denoted below:
Alaska - Designated Toxic and Hazardous Michigan - Critical Materials Register: None. Pennsylvania - Hazardous Substance List:
Substances: None. Minnesota - List of Hazardous Substances: None.
California - Permissible Exposure Limits for None. Rhode Island - Hazardous Substance: None.
Chemical Contaminants: None. Missouri - Employer Information/Toxic Texas - Hazardous Substance List: None.
Florida -Substance List: None. Substance List: None. West Virginia Hazardous Substance List:
Illinois - Toxic Substance List: None. New Jersey - Right to Know Hazardous None.
Kansas - Section 3021313 List: None. Substance List: None. Wisconsin Toxic and Hazardous Massachusetts - Substance List: None. North Dakota - List of Hazardous Chemicals, Substances: None.
Reportable Quantities: None.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): Sodium Pentaborate is not on the California Proposition 65 Lists.
ANSI LABELING (Z129.1): CAUTION! MAY CAUSE RESPIRATORY SYSTEM, SKIN AND EYE IRRITATION.
HARMFUL IF INGESTED. Do not taste or swallow. Avoid contact with skin or eyes. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, eye protection and appropriate body protection. FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. If inhaled, remove to fresh air. If ingested, do not induce vomiting and get medical attention. Get medical attention if any adverse reaction occurs. IN CASE OF FIRE: Use water fog, dry chemical, CO 2 , or "alcohol" foam. IN CASE OF SPILL: Sweep-up spill and place in suitable container, avoiding creation of dusts. Consult Material Safety Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL INVENTORY: Sodium Pentaborate is not listed on the DSL Inventory; it is excepted as a salt of a listed material.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION AGENCY (CEPA) PRIORITY SUBSTANCES LISTS: Sodium Pentaborate is not on the Priority Substances Lists.
CANADIAN WHMIS SYMBOLS: Not applicable.
- 16. OTHER INFORMATION PREPARED BY: CHEMICAL SAFETY ASSOCIATES, INC.
PO Box 3519, La Mesa, CA 91944-3519 (619) 670-0609 The information contained herein is fumished without warranty of any kind. Persons using this product should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of this material, the safety of health of employees and customers and the protection of the environment.
DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS It This is the Chemical Abstract Service Number that uniquely EXPOSURE LIMITS IN AIR (continued):
I identifies each constituent NIOSH RELs: NIOSH's Recommended Exposure Umits.
EXPOSURE LIMITS IN AIR: PEL-Permlssible Exposure Limit: OSHA's Permissible Exposure Umits.
CEILING LEVEL: The concentration that shall not be exceeded during any This exposure value means exactly the same as a TLV, except that it is part of the working exposure. enforceable by OSHA. The OSHA Permissible Exposure Limits are based LOQ: Limit of Quantitation. in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal MAK: Federal Republic of Germany Maximum Concentration Values in the Regis 58: 35338-35351 and 58: 40191). Both the current PELs and the workplace. vacated PELs are indicated. The phrase, *Vacated 1989 PEL," is placed NE: Not Established. When no exposure guidelines are established, an next to the PEL that was vacated by Court Order.
entry of NE is made for reference. SKIN: Used when a there is a danger of cutaneous absorption.
NIC: Notice of Intended Change. STEL-Short Term Exposure Limit* Short Term Exposure Umit, usually a NIOSH CEILING: The exposure that shall not be exceeded during any part of the workday. If instantaneous monitoring is not feasible, the ceiling shall be assumed as a 15-minute TWA exposure (unless otherwise specified) that 15-minute time-wAeighted average (TWA) exposure that should net be exceeded at any time during a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-TWA or REL-TWA.
I shall not be exceeded at any time during a workday.
02'76I
EAGLE PICHER TECHNOLOGIES LLC SODIUM PENTABORATE, ENRICHED DEFINITIONS OF TERMS (Continued)
EXPOSURE LIMITS IN AIR (continued): HAZARDOUS MATERIALS IDENTIFICATION SYSTEM TLV-Threshold Limit Value: An airborne concentration of a substance that HAZARD RATINGS (continued): .
represents conditions under which it is generally believed that nearly all FLAMMABILITY HAZARD (continued):
workers may be repeatedly exposed without adverse effect. The duration 3 (continued): Materials that on account of their physical form or must be considered, including the 8-hour.TWA-Tlme Weighted Average: environmental conditions can form explosive mixtures with air and are readily Time Weighted Average exposure concentration for a conventional 8-hr dispersed in air [e.g., dusts of combustible solids, mists or droplets of (TLV, PEL) or up to a 10-hr (REL) workday and a 40-hr workweek. flammable liquids]; Materials that bum extremely rapidly, usually by reason of IDLH-lmmedlately Dangerous to Life and Health: This level represents a self-contained oxygen [e.g. dry nitrocellulose and many organic peroxides]); 4 concentration from which one can escape within 30-minutes without (Severe Hazard-Materials that will rapidly or completely vaporize at suffering escape-preventing or permanent injury. atmospheric pressure and normal ambient temperature or that are readily HAZARDOUS MATERIALS IDENTIFICATION. SYSTEM HAZARD dispersed in air, and which will bum readily, including: Flammable gases; RATINGS: This rating system was developed by the National Paint and Flammable cryogenic materials; Any liquid or gaseous material that is liquid Coating Association and has been adopted by industry to identify the degree while under pressure and has a flash point below 22.8°C [730F] and a boiling of chemical hazards. point below 37.80C [1000F] [e.g. OSHA Class IA; Material that ignite HEALTH HAZARD: spontaneously when exposed to air at a temperature of 54.4°C [1300F] or 0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not below [e.g. pyrophoric]).
anticipated. Skin Irritation: Essentially non-irritating. Pit or Draize = "0". PHYSICAL HAZARD:
Eye Irritation: Essentially non-iritating, or minimal effects which clear in < 24 0 (Water Reactivit. Materials that do not react with water. Organic hours [e.g. mechanical irritation]. Draize = "0". Oral Toxicity L-Dw Rat < Peroxides: Materials that are normally stable, even under fire conditions and 5000 mg/kg. Dermal Toxicity LDsoRat or Rabbit < 2000 mg/kg. Inhalation will not react with water. Explosives: Substances that are Non-Explosive.
Toxicity 4-hrs LCd Rat.'< 20 mg/L); 1 (Slight Hazard: Minor reversible Injury Unstable Compressed Gases: No Rating. Pyrophorics: No Rating.
may occur, slightly or mildly irritating. Skin Irritation: Slightly or mildly Oxidizers: No "0" rating allowed. Unstable Reactives: Substances that will irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LDsa Rat. > not polymerize, decompose, condense or self-react.); 1 (Water Reactivity.
500-5000 mg/kg. Dermal Toxicity LD 50Rat or Rabbit > 1000-2000 mg/kg. Materials that change or decompose upon exposure to moisture. Organic Inhalation Toxicity LCo 4-hrs Rat > 2-20 mg/L); 2 (Moderate Hazard: Peroxides: Materials that are normally stable, but can become unstable at Temporary or transitory injury may occur. Skin Irritation: Moderately high temperatures and pressures. These materials may react with water, but irritating; primary irritant; sensitizer. P1I or Draize > 0, < 5. Eye Irritation: will not release energy. Explosives: Division 1.5 & 1.6 substances that are Moderately to severely irritating and/or corrosive; reversible corneal opacity; very insensitive explosives or that do not hav a mass explosion hazard.
corneal involvement or irritation clearing in 8-21 days. Draize > 0, < 25. Oral Compressed Gases: Pressure below OSHA definition. Pyrophorics: No Toxicity LD5o Rat > 50-500 mg/kg. Dermal Toxicity LD5,Rat or Rabbit > Rating. Oxklizers: Packaging Group III; Solids: any material that in either 200-1000 mg/kg. Inhalation Toxicity LCw 4-hrs Rat > 0.5-2 mg/L); 3 concentration tested, exhibits a mean burning time less than or e-qual to the (Serious Hazard: Major injury likely unless prompt action is taken and mean burning time of a 3:7 potassium bromate/cellulose mixture and the medical treatment. is given; high level of toxicity, corrosive. Skin Irritation: crtera for Packing Group I and II are not met. Liouids: any material that Severely iMitating and/or corrosive; may destroy dermal tissue, cause skin exhibits a mean pressure rise time less than or equal to the pressure rise bums, dermal necrosis. PIl or Dralze > 5-8 with destruction of tissue. Eye time of a1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing Irritation: Corrosive, irreversible destruction of ocular tissue; corneal Group I and II are not met. Unstable Reactives: Substances that may involvement or irritation persisting for more than 21 days. Draize > 80 with decompose, condense or self-react, but only under conditions of high effects irrversible. in 21 days. Oral Toxicity. LD 5o Rat > 1-50 mg/kg. temperature and/or pressure and have little or no potential to cause Dermal Toxicity LDsoRat or Rabbit > 20-200 mg/kg. Inhalation Toxicity significant heat generation or explosive hazard. Substances that readily LCw 4-hrs Rat ý> 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-threatening; undergo hazardous polymerization in the absence of inhibitors.); 2 (Water major or I:ermanent damage may result from single or repeated exposure. Reactivity. Materials that may react violently with water. OrganicPeroxkies:
Skin Irritation: Not appropriate. Do not rate as a "4", based on skin irritation Materials that, in themselves, are normally unstable and will readily undergo alone. Eye Irritation: Not appropriate. Do not rate as a '4", based on eye violent chemical change, but will not detonate. These materials may also Irritation alone. Oral Toxicity L05o Rat < 1 mg/kg. Dermal Toxicity LD 5oRat react violently with water. Explosives: Division 1.4 - Explosive substances or Rabbit: < 20 mg/kg ,Inha/ation Toxicity LCmo 4-hrs Rat <0.05 mg/L). where the explosive effect are largely confined to the package and no FLAMMABILITY HAZARD:' projection of fragets of appreciable size or range are expected. An 0 (Minimal Hazard-Materials that will not bum in air when exposure to a external fire must not cause virtually instantaneous explosion of almost the temperature of 815.5-C [1500"F] for a period of 5 minutes.); I (Slight entire contents of the package. CompressedGases: Pressurized and meet Hazard-Materials that must be pre-heated before ignition can occur. Material OSHA definition but < 514.7 psi absolute at 21.1°C (70*F) [500 psig].
require considerable pre-heating, under all ambient temperature conditions Pyrophorics: No Rating. Oxidizers: Packing Group IISolids: any material before ignition and combustion can occur, Including: Materials that will bum that, either in concentration tested, exhibits a mean burning time of less than in air when exposed to a temperature of 815.51t (1500*F) for a period of 5 or equal to the mean burning timne of a 2:3 potassium bromate/cellulose minutes or less; Liquids, solids and semisolids having a flash point at or mixture and the criteria for Packing Group I are not met. Unuids: any above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most ordinary combustible material that exhibits a mean pressure rise time less than or equal to the materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-Materials that must be pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose moderately heated or exposed to relatively high ambient temperatures before mixture and the criteria for Packing Group I are not met. UnstableReactives:
ignition can occur. Materials in this degree would not, under normal Substances that may polymerize, decompose, condense, or self-react at conditions, form hazardous atmospheres in air, but under high ambient ambient temperature and/or pressure, but have a low potential for significant temperatures or moderate heating may release vapor in sufficient quantities heat generation or explosion. Substances that readily f6rm peroxides upon to produce hazardous atmospheres in air, Including: Liquids having a flash- exposure to air or oxygen at room temperature); 3 (Water Reactivity point at or above 37.81C [1001F]; Solid materials in the form of course dusts Materials that may form explosive reactions with water. Organic Peroxides:
that may bum rapidly but that generally do not form explosive atmospheres; Materials that are capable of detonation or explosive reaction, but require a Solid materials in a fibrous or shredded form that may bum rapidly and create strong initiating source, or must be heated under confinement before flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that readily initiation; or materials that react explosively with water. Expiosives: Division give off flammable vapors.); 3 (Serious Hazard- Liquids and solids that can 1.2 - Explosive substances that have a fire hazard and either a minor blast be ignited under almost all ambient temperature conditions. Materials in this hazard or a minor projection hazard or both, but do not have a mass degree produce hazardous atmospheres with air under almost all ambient explosion hazard. Compressed Gases: Pressure > 514.7 psi absolute at temperatures, or, unaffected by ambient temperature, are readily ignited 21.1°(C (70*F) [500 psig]. Pyropthocs: No Rating. Oxidzers: Packing under almost all conditions, including: Liquids having a flash point below Group I Solids: any material that, In either concentration tested, exhibits a 22.8°C [73°F] and having a boiling point at or above 380C (1001F] and below mean burning time less than the mean burning time of a 3.:2 potassium 37.80C [1 000F] [e.g. OSHA Class IBand 1q]; bromate/cellulose mixture.
0 27 7 oz' 7
EAGLE PICHER. TECHNOLOGIES LLC DEFINrITONS OF 1 ERiVMS (Continued)
SODIUM PENTABORATE, ENRICHED I
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM FLAMMABILITY LIMITS INAIR: Much of the information related to fire and HAZARD RATINGS (continued):
PHYSICAL HAZARD (continued):
3 (continued): LiquLds: Any material that spontaneously ignites when mixed explosion is derived from the National Fire Protection Association (NFPA).
Flash Point - Minimum temperature at whiKli a liquid gives off sufficin-t vapors to form an ignitable mixture with air. Autolanition Temperature: The I
with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less minimum temperature required to initiate combustion in air with no other than the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture.
Unstable Reacties: Substances that may polymerize, decompose, condense or setf-react at ambient temperature and/or pressure and have a source of ignition. [EL - the lowest percent of vapor in air, by volume, that will explode or ignite in fthpresence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source.
I moderate potential to cause significant heat generation or explosion.); 4 TOXICOLOGICAL INFORMATION:
Water Reacfvkiy. Materials that react explosively with water without requiring heat or confinement. Organic Peroxides: Materials that are readily capable of detonation or explosive decomposition at normal temperature and pressures. Explosives: Division 1.1 & 1.2-explosive substances that have a, Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies, with similar compounds are presented. Definitions of some terms used in this section I
are: LDs - Lethal Dose (solids & liquids) which kills 50% of the exposed mass explosion hazard or have a projection hazard. A mass explosion is one that affects almost the entire load instantaneously. Compressed Gases:
No Rating. PyTFpbodes: Add to the definition of Flammability W4".
Oxidzers: No '4" rating. Unstable Reactives: Substances that may animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m 3 concentration expressed in weight of substance per I
volume of air; mg/kg quantity of material, by weight, administered to a test polymerize, decompose, condense or self-react at ambient temperature and/or pressure and have a high potential to cause significant heat generation or explosion.). PPE Rating B: Hand and eye protection is required for routine chemical use. PPE Rating C: Hand, eye, and body subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and [Do, or TC, TCo, LCLo, and [Co, the lowest dose (or concentration) to cause lethal or toxic I
protection may be required for routine chemical use.
I effects. Cancer Information: The sources are: IARC - the Intemational NATIONAL FIRE PROTECTION ASSOCIATION HAZARD Agency for Research on Cancer; NTP - the National Toxicology Program, RATINGS: RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and HEALTH HAZARD: 0 (material that on exposure under fire conditions would CAUOSHA. IARC and NTP rate chemicals on a scale of decreasing offer no hazard beyond that of ordinary combustible materials); I (materials potential to cause human cancer with rankings from 1 to 4. Subrankings that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury);
3 (materials that can on short exposure could cause serious temporary or (2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been I
exposed to chemicals to the same extent as a worker with inhalation residual injury); 4 (materials that under very short exposure could cause death or major residual injury).
FLAMMABILITY HAZARD: 0 Materials that will not bum under typical fire conditions, including intrinsically noncombustible materials such as concrete, exposure to the TLV.
ECOLOGICAL INFORMATION:
EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a substance will concentrate in lifeforms which 1
stone, and sand. I Materials that must be preheated before ignition can I
consume contaminated plant or animal matter. TL. =.median threshold limit; occur. Materials in this degree require considerable preheating, under all Coefficient of OiUWater Distnrbution is represented by log &w or log K,, and ambient temperature conditions, before ignition and combustion can occur 2 is used to assess a substance's behavior in the environment.
Materials that must be moderately heated or exposed to relatively high REGULATORY INFORMATION:
'ambient temperatures before ignition can occur. Materials in this degree U.S. and CANADA:
would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release
,vapor in sufficient.quantities to produce hazardous atmospheres with air. 3 Liquids and solids that can be ignited under almost all ambient temperature ACGIH: American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits..
This section explains the Impact of various laws and regulations on the I
material. EPA is the U.S. Environmental Protection Agency. NIOSH is the conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by ambient temperatures, are'readily ignited under almost all conditions. 4 Materials that will rapidly or completely vaporize at atmospheric pressure and normal National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occu*tional Safety and Health- Administration (OSHA).
WHMIS is the Canadian Workplace Hazardous Materials Information System. DOT and TC are the U.S. Department of Transportation and the I
ambient temperature or that are readily dispersed in air and will bum readily. Transport Canada, respectively. Superfund Amendments and INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire conditions. I Materials that in themselves are normally stable, but that can become unstable at elevated temperatures and Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List (DSUNDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status according to the DOT; the Comprehensive I
pressures. 2 Materials that readily undergo violent chemical change at Environmental Response, Compensation, and Uability Act (CERCLA or elevated temperatures and pressures. 3 Materials that in themselves are capable of detonation or explosive decomposition or explosive reaction, but that require a strong initiating source or that must be heated under confinement before initiation. 4 Materials that in themselves are readily Superfund); and various state regulations. This section also includes information on the precautionary warnings which appear on the material's package label. OSHA - U.S. Occupational Safety and Health Administration.
I capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures.
I I
I 0278 I
OCT 19'1999 16:50 FR C&K GIB eNUJRMTL-MTLS61-0 562 6665 TO -9161WM77205 P.02 N-T -AI U - - .
S~EL *.'".'
. .a U .&...
PRQrnTCTZ43M.& INTh&CID WHONI1T LltQUZD IPRODC Cq neal'th. a pafety Department IEZSON DAM!;
,Creuivten&1,A owl.es Color 5 1ý6.
PA Phone: 610-5 24-8765 24 Hr. Eme~rgency Phone:
CENCREC 1-0900-424-9300 CANUTC: For chemical emergeneieu in C~anaf, call CRY =TC -at I,-
1, %If HOAZAOUS COMPONMNS NON-H[AZARDOULS CM ET ACG~i ThV: ACrjgIH Soq OSIHA PEL: .OH hr NIT Trade CQTDPemnI Term Expow Term Exposmr secret value: Val=e Nuwbez':-
__ ___ __ ___ ___ __ ___ ___ ___ ___ ___ ___ 18881400-:
'dilhoride 7 N.E. NIP.-.
r deS~ : y iN~0NE.....E. 5646P, mpound564 7P' Page I Of 6 0279
OCT 19 1999 16:50 FR C&K GID ENUIRMTL-MITS6iO 582 6665 TO 91GIO7747205 P.03 I
APRODUCT:
A34S17LI00 INTRACID RHODAMINE WT IQTJUID I
4 j 170 I
I mO"
- M-Warning: Causes eye iz-rit A------- -2 M M __IMI_4 _
iaon. May cause skin I
I
- EY CONTACT
- Irritat",ng to the eyes I SjKI CONTACT: May be irritating to the Gkin, INHALATION: None known.
I INGESTION: None known I
]cn~owzOVRX
- 'LNo CHROkNICvui mmsm
- UERFFECTS:
I SCARCINOGENICZTY- NTP . No, IARC - No, 0.AO Regulated - No PRINCIPLE ROMTES OF EXPOUE: None known.
I MEDCA CNDITIONS
-'M=rCA Cdf, " OW GRVTDB MM:ITEDB E POSUPE: Not known. I
- ,?;:*~ ~~ ... ~ ~ ' .: ~ ~
.;;* ~ " ~I MINN.... US I,.,.L I
SEE:ncase of con tact., imme diately flush eyer, with plenty of water~ for at least 15 mi.nutes and se*t medical attention if MIX1 Z .f irritation persists.
nact, i mme0diately f1ush sicin with plenty of soap and water for,at I
least' 15 minutes. G~et meadical a~tt2Gn
> INALATION:
M If inhaled, rxeve to fresh air. If not breathing give artificial I
<. rdpiration, preferably mouth-to-mouth. If b eahing * ,sft'gfiult ,ve oxygen. Gt medical attentiolL I
I~NGESTION: 'i-, sauLiloved, induce vromiting inim'aediately by giving te~o'glassges of Water n~and. stic&dng fingrs dwitrat medical attentOn.
never give tonything to an umconscious, person. Get I
I Page-2 Of 6 0280 I
-7 1 _-Z 7 --' ýý ý,!ý! -ý ý,
A3ý45.17Ij2.OO INTRCID 1"DAMINE WT LIQUI7D, FLAS PMflMT k.A.
29~ ~ MOD-X IMM MALIMITS XW AIR LOMM (t):NA ftT3FGM, Mr MWASaCarbon Dioxide, Dry Chemical, Water Fog~
FIRE .FXGfftIG PROC URSt .coo exposed acontainers with .wattr spray Mone knrown.
ADPZTIW"4Z AVREhD, WLOSXN BATK: An in any fire, wear self - cantained breatiAng apparatus and ful3. protactive equipment.
A=-O T E TK IF wATrAL SRLAE OR SP=hLK: wear. appropriate safety'.
ecjuipomint, rn lenUeill Spti JmoiateYý, Preveonts, fraid enitering floor drains.
Swep owerscaef lrly inizing Vutn.Sne'alsill materialt into ipsldm a~i Ee-lwdspoalinstructions. Scrub spi I area with detergent and M.Ush with c~pjOU@
amounts Of water.
PREC&UTIONS TO BEX TAX=, IXN KAMDLI ANID STORAGE; Kteepcontainer closed when niot OTHR TOAG kAJDHMDLIGDATA: In adcord With good induitrial practilce, hahxdlc wvith care a~davoid, personal =ontact.
EXPOtIR COTROZO: Local exhaust eniaonmay be necessary to aontrol air ontatinant.s duin tt'u -ds it'ado icl .NO gasýA~/orvapors i lLIey 19 ap-qjyreppirator wit a rcectibOf aCtOr llý111-1111 io isLB0recounended. Se 14SbS section 2 for infrmation on the-hzrdu PROTECTIV 01LdO0ES, Wear cheia ingrredin reistant rber gloveýs Wand ong sleeved clothinig. I MXS: wear safety glasses or goggle to p;rotect against exposur'e.
CLOT*MZNO Wear overallsarn rohrptciecohn o 3 inmz sicir a OTME PERSONAL PROTECTION DATA: None 3ievwn.
XXGZENIC PRACTICES:,
an4~~ ~ hruhl~ ~ fe Avoid contact with, weye arid skin. -Avoid! inhalatio
~~c adig Kepr.Ws
.ep cOntainers closed whesi not in use of dusts
- ....... ..... ... 0 0 .... 10_ .... . . .....m ma. .....
U P*HYSCAL STAT E.
COLOR; ...........
ODOR: . .... ....
..... D.
. REM SOLIUHIT. IF..NT= 206) c Page 3 Qf 6 0281 I
P.05 OCT19 1999 16:51 FR C&K GIB ENVIRMTL-MTLS610 582 6665 TO 916187747285 A3453.7LI00 IWRMCIfl RHODAHMI 'WT LIQUIfl SPECIFIC dR&VITYv . ....
~.t DMSZIN PO NT 25....... ..........
II EVAP
(~U!~ RAT TA~h~) a .. BWBRTEMB3TYL ACETATE
-V ......
.. ... .... j...
I I I
-I POLY~lkTZON: will not occur H&7.ADOS 'DECOMPOSITION PAODUCTS Burning m~lpodc xdsfcaon nitrogen and/or sulfurp INCOMPAT MILITY, ( A~TMRL8n TOAVOID): None. known.
CONDITZXOB/Xp 7APD TOilAVOID: Noeko.
71RAWT R.P v m ILI ACUT ORAL LDS50 (mg/kg): -N-.o Data ACUTE D~kLLD5O (mig/kg) 2 --s Zfomati=o ACUTM 331KhLkTION LCSO' (ug/L.) .. .Ne Dat.a, IRRITAT1014 TO0'k(n eyes. zespiratOzy) R. None.
ADDITIO1)AL TOXICOLOGGY InFOMTION:.- ...- None known.
I
______ - *- mm" _
I ECOTOIICCLOG-ImA InFORmTION; No data is available at thi~s timue.
DISPOSAL OF WASTE 3ITMOD. Bury or incinrate. according to federal, state, and local q*
euatbiofa.
CONAiI IPSL Ctmtainera should be triple rinsed, according. to faderal regulations and/or good waste maPAgement praCtice.
i DOT P~ecper Shipping Name: ... xort DoT Reguilated DOT Technical NQamess. ...... ...
DOT Primazy Namazbd Class- ..... ......NA Page 4 Ok 6 0202 II
M~I IV W1~ 1b:1 FR C&I< SIB ENVIRMTL-MTS610 58M 6665 To 9+/-6107?4?205 P.06 p
A36517LI00 INTRACID RHODAMINE WT LIQUID DoT
- Ie6qeo&dy Ragazd Clasq:
- ..... ..... ........- .-.... . ........... ........ N.A.
...N.A . .
DOT PMCK- MiOG G...O. :.... .
DOT DaIG3+C RSFOiz I0 TION ................. Roeap unnecessary pople awy. Isolate area and deny entry. Stay upwind. Xeep OuV of 10W areAS. Call- CEMNEC at 1-800-424,9300 fo~r eMr-ft~ igafist~ane.
....... ... . ........... .............. or chemical emergencies in Canada, call CANUTEC at 1-6136'996;-6E6d.
- L
-: *.+L
,**Z.I *5
. .. .,-/ .:* *. . ........ . .. - . . . . . _ - . ...-. .... . . . - . ....- -- - . ....
sm BECTIW302 NneFon SARA~ (31AM12 CLUB~
T"PIATE ZETH MLZARD SARA (313) CNUICALS: THIS, PRODUCT DOES NOT.CONTAJh A ýTOXI C OMCMjjCA P;OR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SECTION 313 (40 CPR 372) 7~MOUIIT ..OFi**+ . . (313) +RPOEJRthZ CEZCAL M(%) No SARA (313) Reportable Chemicals.
RMET= NTMMT; This product is not a metallized dye.
TSCA. INY NWRY STAWTS: All. components of tiju product are inclued -on the TSCA Section 8 Inventory.
CALIFORNIA FROPOSrTION 6S ClHEICAtS: None-SSCO ( ZREGULATOTh product is not oubject GEUWN ?nmIS/mmOpw. UNI AN6INES: This product does not contain -
any compounds that would be prohibited under the cUrrent German/EuropeG
...o.- -.regula ., , ....... l'e ,+e 1 4amine compounds.
- " "-'-" ' " . .. . .. . -, ..9 .
WaS: rLAMMUILzTY 3. P4yACTMT 0 , HEALTH 2.
NO=~
Page 5 Of 6 L 0283C:.
w PRODUCT:
A34517L10Q I
INMRCID HMOAIN WT LIQUID WJAON FOR UPDATZ:- Product review. -I DISCLAMER I Crcr pton & Rnorles warrants that this product conforB to the chemical description cm the label ard is reasoiably fit o'r the specific referred t..o in -itw di*Jreet*ia ft" Ue, 6 purposes cat to inrheent risks referred to in the Material Safety pata Shee; for this product. CroVton a KMowles makes no ather e~tses or
+/-Mplied iazra.nty. In no. case shall Cro ton & knovis be lrab .je or cwase i.
special, ori indfredt damages resul~tinag from t'he use or handling of this product.
00E94PO/dP
~ K' I
i~w I"
I Page 6 of 6 0234 I
U
3800-PM-WSFR0008e Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC WS pennsylvania 10 OF ENVIRONMENTAL DEPARTMENT ON PROTECTIC COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION WASTEWATER TREATMENT TECHNOLOGIES MODULE 2 APPLICANT NAME I PPL Susquehanna, LLC Method for Handling and Disposal of Solid or Liquid Outfall Treatment Unit Description Residue Resulting from Treatment Number (list in sequence) (list in sequence) 070 Sedimentation (setting) Cleanfill Discharge to Surface Water N/A 071 Sedimentation Landfill, or soil amendment Disinfection (chlorination) N/A Dechlorination N/A Discharge to Surface Water N/A 171 Filtration Radioactive Waste Landfill Ion Exchange Radioactive Waste Landfill Neutralization N/A 072 Oil & Grease Removal Recycled Discharge to Surface Water N/A 073 Oil & Grease Removal Recycled Discharge to Surface Water N/A 074 Oil & Grease Removal Recycled Discharge to Surface Water N/A 075 Sedimentation (Setting) Cleanfill Discharge to Surface Water N/A 079 Grinding N/A Screening Landfill Equalization NA Activated Sludge Aerobic Digestion / Landfill Neutralization NA 1 0235
3800-PM-WSFROOOe Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC I
Module 2 i
Disinfection (Chlorine)
Dechlorination N/A N/A I Discharge to Surface Water N/A I
080 Sedimentation (Settling) Cleanfill Discharge to Surface Water N/A I I
I I
I I
I I
I 1
I I
I I
0286 I
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 070 S-2 Pond pennsytvanial COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION
-ENT PROTECTION BUREAU O.FNVIRONMFETAL OF WATER STANDARDS AND FACILITY REGULATION SOURCES OF WASTEWATER MODULE 3 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLIANTNAME PPL Susquehanna, LLC LL BER 070 S-2 Pond
- 1. Process Wastewater
- a. Describe process and type of wastewater.
N/A
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application.
- c. Discharge Occurs. _ hrs/day; _ days/wk; _ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM
- 2. All Other Wastewater Contributing to this Ouffall
- a. Describe the wastewater.
N/A
- b. Source(s).
c.
3 Discharge Occurs. _ hrs/day; rate as:
_ days/wk; _ days/yr; During which months?
_ months/yr.
Report the discharge The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM 0287
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 070 S-2 Pond
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater
- a. Source(s).
- b. Discharge Occurs. _ hrs/day; _ days/wk;_ days/yr;_ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term averaqe discharge rate. MGD
- 4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution.
0288
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC I Module 3 Outfall 071 Cooling Tower Blowdown r ~
pennsytvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION EPA-hENTOF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION I SOURCES OF WASTEWATER MODULE 3 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICNNWNAME PPL Susquehanna, LLC IOUTFALL NUMBER o: 071 Cooling Tower Blowdown
- 1. Process Wastewater
- a. Describe process and type of wastewater.
Cooling Water Blowdown from Circulating Water and Emergency Service Water (ESW) System operation.
Inculdes ESW Pond overflow to blowdown.
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application. Continuous Operation
- c. Discharge Occurs. 24 hrs/day; 7 days/wk; 365 days/yr; 12 months/yr.
- During which months? All rate as:
Report the discharge The maximum daily discharge rate. 17.80 MGD The monthly average discharge rate. 13.85 MGD The long-term average discharge rate. 13.85 MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM
- 2. All Other Wastewater Contributing to this Outfall
- a. Describe the wastewater.
Outfall 171 - Liquid Radwaste Discharge to CT Blowdown and 371 Neutralization Basin internal discharge to Circ Water
- b. Source(s). Volume of Liquid radwaste discharge 171 to Cooling Tower Blowdown.
- c. Discharge Occurs. 0-6 hrs/day; 1-7 days/wk; 60 days/yr; 12 months/yr.
During which months? All Report the discharge rate as:
The maximum daily discharge rate. .073 MGD The monthly average discharge rate. 0.036 MGD The loncq-term average discharge rate. 0.036 MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM 0289
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 071 Cooling Tower Blowdown
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater
- a. Source(s).
- b. Discharge Occurs. 24 hrs/day; 7 days/wk; 365 days/yr; 12 months/yr.
During which months? All Report the discharge rate as:
The maximum daily discharge rate. 17.87 MGD The monthly average discharge rate. 13.89 MGD The longq-term average discharge rate. 13.89 MGD
- 4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution.
0290
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 072 S&A Sump 1 pennsyLvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION DEPA*ThEW BUREAU OF WATER STANDARDS AND FACILITY REGULATION OFENRONMNTAlPROTECION 3 SOURCES OF WASTEWATER MODULE 3 I Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT NAME PPL Susquehanna, LLC OUTFALL NUMBER 072 S&A Sump
- 1. Process Wastewater
- a. Describe process and type of wastewater.
N/A
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application.
- c. Discharge Occurs. _ hrs/day; __ days/wk; _ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term averaqe discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM
- 2. All Other Wastewater Contributing to this Outfall
- a. Describe the wastewater.
Miscellaneous stormwater collected around Emergency Transformers, Diesel Generator oil unloading area and equipment and S&A oil storage area berm downstream of O&G separator.
- b. Source(s).
- c. Discharge Occurs. 1 hrs/day; z days/wk; 33 days/yr; 12 months/yr.
During which months? All Report the discharge rate as:
The maximum daily discharge rate. 0.010 MGD The monthly average discharge rate. 0.009 MGD The long-term average discharge rate. 0.009 MGD IFor batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM 0291
I 3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 072 S&A Sump
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater I
- a. Source(s).
- b. Discharge Occurs. 1 hrs/day; _ days/wk; 30 days/yr; 12 During which months? All months/yr. I Report the discharge rate as:
The maximum daily discharge rate. 0.010 MGD I
The monthly average discharge rate.
The long-term average discharge rate.
0.009 0.009 MGD MGD I
- 4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution. I 0292
3800-PM-WSFROOO8f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 073 U-1 Transformer Sump pennsylvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION EPARTW.T OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION 3 SOURCES OF WASTEWATER MODULE 3 Before completing this form, read the step-by-step instructions provided in Appendix 1.
SPP IANTNAME PPL Susquehanna, LLC I
OUTFALL NUMBE-- 073 U-1 Transformer Sump
- 1. Process Wastewater
- a. Describe process and type of wastewater.
N/A
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application.
- c. Discharge Occurs. __ hrs/day; _ days/wk; _ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The longq-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. -- _GPM
- 2. All Other Wastewater Contributing to this Outfall
- a. Describe the wastewater.
Miscellaneous stormwater collected around U-1 Transformer(s), Lube oil storage tank berm, and oil filled circuit breakers downstream of O&G separator.
- b. Source(s).
- c. Discharge Occurs. 1 hrs/day; _ days/wk; 8 days/yr; 12. months/yr.
During which months? All Report the discharge rate as:
The maximum daily discharge rate. 0.016 MGD The monthly average discharge rate. 0.008 MGD The long-term averagqe discharge rate. 0.008 MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM 1- 0293
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfal: 073 U-1 Transformer Sump
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater
- a. Source(s).
- b. Discharge Occurs. 1 hrs/day; _ days/wk; 8 days/yr; 12 months/yr.
During which months? All Report the discharge rate as:
The maximum daily discharge rate. 0.016 MGD The monthly average discharge rate. 0.008 MGD The long-term average discharge rate. 0.008 MGD
- 4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution.
0294
3800-PM-WSFR0008f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 074 U-2 Transformer Sump VýMP pennsytvanial COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION DEPARTMEnT OFENVIRONMENTAL BUREAU OF WATER STANDARDS AND FACILITY REGULATION PROTECTION IMODULE 3 SOURCES OF WASTEWATER Before completing this form, read the step-by-step instructions provided in Appendix 1.
!APPLCANTNAME PPL Susquehanna, LLC I QUTFAILL NUMBER 074 U-2 Transformer Sump
- 1. Process Wastewater
- a. Describe process and type of wastewater.
N/A
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application.
- c. Discharge Occurs. _ hrs/day; _ days/wk; __ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The Iong-term averaqe discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. -- _GPM
- 2. All Other Wastewater Contributing to this Outfall
- a. Describe the wastewater.
Miscellaneous stormwater collected around U-2 Transformer(s), and lube oil storage tank berm downstream of O&G separator.
- b. Source(s).
- c. Discharge Occurs. 1 hrs/day; _ days/wk; 12 days/yr; 12 months/yr.
During which months? All Report the discharge rate as:
The maximum daily discharge rate. 0.016 MGD The monthly average discharge rate. 0.008 MGD The long-term averaqe discharge rate. 0.008 MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GGPM 0295
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC I
Module 3 Outfall: 074 U-2 Transformer Sump
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater I
- a. Source(s).
- b. Discharge Occurs. 1 hrs/day; _ days/wk; 12 days/yr; 12 During which months? All months/yr. U Report the discharge rate as:
The maximum daily discharge rate. 0.016 MGD I
The monthly average discharge rate.
The long-term average discharge rate.
0.008 0.008 MGD MGD I
- 4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution. U 0296
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 075 Peach Stand Pond pennsyivanla COMMONWEALTH OF PENNSYLVANIA E-.T .DEPARTMENT OF ENVIRONMENTAL PROTECTION EPARTNENT BUREAU OF WATER STANDARDS AND FACILITY REGULATION OFENVIRONMENALPROTECTION SOURCES OF WASTEWATER MODULE 3 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT NAME, .. PPL Susquehanna, LLC I OUTFALL'I NUMBER ,*. 075 Peach Stand Pond
- 1. Process Wastewater
- a. Describe process and type of wastewater.
N/A
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application.
- c. Discharge Occurs. _ hrs/day; _ days/wk; _ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate ..... GPM
- 2. All Other Wastewater Contributing to this Outfall
- a. Describe the wastewater.
N/A
- b. Source(s).
c.
3 Discharge Occurs. _ hrs/day; _ days/wk; _ days/yr; During which months?
_ months/yr.
rate as:
Report the discharge The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM 0297
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC I
Module 3 Outfall: 075 Peach Stand Pond
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater I
- a. Source(s).
- b. Discharge Occurs. __ hrs/day; __ days/wk; _ days/yr; During which months?
__ months/yr. I Report the discharge rate as:
The maximum daily discharge rate. MGD I
The monthly average discharge rate.
The long-term averagqe discharge rate.
MGD MGD I
- 4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution. 1 I
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I 0298 I
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPI Susquehanna, LLC Module 3 Outfall: 079 Sewage Treatment Plant l pennsytvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION EPA.T. PROTECTIONBUREAU ENVIRONMENTAL OF WATER STANDARDS AND FACILITY REGULATION SOURCES OF WASTEWATER MODULE 3 Before completing this form, read the step-by-step instructions provided in Appendix 1.
'APPLICANT NAME PPI Susquehanna, LLC OUTFALL NUMBER 079 Sewage Treatment Plant
- 1. Process Wastewater
- a. Describe process and type of wastewater.
N/A
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application.
- c. Discharge Occurs. _ hrs/day; _ days/wk; _ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM
- 2. All Other Wastewater Contributing to this Outfall
- a. Describe the wastewater.
Sanitary wastewater effluent from extended aeration sewage treatment plant
- b. Source(s).
- c. Discharge Occurs. 24 hrs/day; Z days/wk; 365 days/yr; L2 months/yr.
During which months? All rate as:
Report the discharge The maximum daily discharge rate. 0.056 MGD The monthly average discharge rate. 0.015 MGD The long-term average discharge rate. 0.015 MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM 0299
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPI Susquehanna, LLC I
Module 3 Outfall: 079 Sewage Treatment Plant
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater
- a. Source(s).
I
- b. Discharge Occurs. 24 hrs/day; Z days/wk; 365._ days/yr; 12 During which months? All months/yr.
I Report the discharge rate as:
The maximum daily discharge rate. 0.056 MGD I
The monthly average discharge rate.
The long-term average discharge rate.
0.015 0.015 MGD MGD I
- 4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution. I I
0300 I
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 080 C-1 Pond IPenns.ani pennsytvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION PROTECTON BUREAU DEP~nTEOF ENVIRONMENTAL OF WATER STANDARDS AND FACILITY REGULATION SOURCES OF WASTEWATER MODULE 3 Before completing this form, read the step-by-step instructions provided in Appendix 1.
IAPPLICANT'NAME' PPL Susquehanna, LLC OUTFALL NUMBER 080 C-1 Pond
- 1. Process Wastewater
- a. Describe process and type of wastewater.
N/A
- b. Production Rate.
Referring to the instructions in Appendix 1 for this question, complete a Module 15, Production Rate, for each process subject to an effluent limitation listed in 40 CFR Subchapter N (Parts 400-471). Indicate the number of completed Module 15s attached to this application.
- c. Discharge Occurs. __ hrs/day; __ days/wk; _ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. ___GPM
- 2. All Other Wastewater Contributing to this Outfall
- a. Describe the wastewater.
N/A
- b. Source(s).
- c. Discharge Occurs. _ hrs/day; _ days/wk; _ days/yr; _ months/yr.
During which months?
rate as:
Report the discharge The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:
Number of decant cycles. Cycles/day Length of each decant cycle. MIN.
Average decant discharge rate. GPM 0301
3800-PM-WSFROO08f Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC I
Module 3 Outfall: 080 C-1 Pond
- 3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater
- a. Source(s).
- b. Discharge Occurs. __ hrs/day; _ days/wk; _ days/yr; _ months/yr.
During which months?
Report the discharge rate as:
The maximum daily discharge rate. MGD I The monthly average discharge rate. MGD 4.
The long-term average discharge rate.
Stormwater MGD I Complete Module 12 or Module 14 for the stormwater contribution.
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I 0302
Page 1 of 5 ADDITIONAL INFORMATION FOR MODULE 3 ADDITIONAL OUTFALL DESCRIPTIONS 070 - The S-2 Pond, located on the South side of the Susquehanna SES site, is a storm water runoff outfall (SWRO). This SWRO outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may also contain small amounts of chlorine, which will dissipate upon mixing with storm water in the pond, before the discharge reaches Lake Took-a-while. Due to the similarity of this outfall and Outfalls 075 and 080, only Outfall 080 was sampled for this NPDES permit application.
071 - Cooling Tower Blowdown includes input from the Unit 1 and Unit 2 Cooling Towers, internal discharges, Acid Chlorine Building Sump, and Emergency Spray Pond (Spray Pond) overflow, and other miscellaneous water. The Cooling Towers and Spray Pond contain river water used for cooling station main condensers and heat exchangers.
Spray Pond discharge is based on pond level, and is dependent on make-up to the pond and rainfall. Assuming an estimated Spray Pond discharge of 250 gpm (0.36 MGD) and an average two-unit Cooling Tower discharge of 9,368 gpm (13.5 MGD),
then the pond discharge adds only an additional 2.7% to the station blowdown. This amount however, is not currently captured in the blowdown flow recorders located upstream of the Spray Pond. Therefore, it may be more accurate to revise the permit to require an estimated Flow and not recording Instrumentation for Outfall 071. We will continue to provide recorded readings from blowdown excluding the additional 250 gpm from the Spray Pond. Turbulence and river debris in the blowdown line downstream of the Spray Pond discharge have made flow recorders inoperable.
Evaporative losses in the Cooling Towers generally result in the cooling water being cycled 3 to 5 times the concentration of river water. Cooling Tower Basins each contain approximately 7 million gallons of water and the Spray Pond 25 million gallons.
In order to reduce fouling and corrosion in the Service Water and Circulating Water Systems, PPL utilizes a chemical treatment program. Chemicals included in present and proposed treatment are listed in Module 1 / Item #7 / Section a., "Information and Analysis of Effluent Quality," in this permit renewal application.
By definition closed cooling systems are not routinely discharged to the environment.
When maintenance is performed on these systems, batch discharges can be directed to the Cooling Tower blowdown (Outfall 071), Sewage Treatment Plant (Outfall 079), or other storm water outfall as described in this permit application. The following Table 1, lists Station Closed Cooling Systems and volumes.
0303
Page 2 of 5 TABLE I CLOSED COOLING SYSTEMS SYSTEMS NO. OF SYSTEMS VOLUME (gal)
Units 1 & 2 Reactor Building 2 4,750 3 Closed Cooling Water Units 1 & 2 Turbine Building Closed Cooling Water 2 1,130 U Units 1 & 2 Common Gaseous 3 3,080 I Radwaste Recombiner Closed Cooling Water Units 1 & 2 Reactor Building 2 4,750 Chilled Water 3 Units 1 & 2 Turbine Building 2 6,200 Chilled Water Temporary Drywell Chiller 550 Learning Center Closed Cooling 1 650 Water Loop Control Structure Chilled Water 1 1,200 Radwaste Building 1 860. .
Chilled Water A-D Emergency Diesel Generator Jacket Cooling Water 4 710 3 E Emergency Diesel Generator Jacket Cooling Water 1 1,500 3 I
I 3
U 0304 I
Page 3 of 5 Asiatic clams have been found in the river near the Susquehanna SES and on occasion in the ESW Spray Pond. Zebra mussel adults were observed in the river at the great bend area near the New York border. PPL plans to utilize a non-oxidizing biocide listed in Module 1, Item #7, to periodically eliminate these mollusks from the plant intake piping as well as the Cooling Tower and Spray Pond. This material will be added over a 12-24 hr. period at a frequency of 2-4 times or as needed annually. This biocide will be detoxified with bentonite clay, which will be continuously added to the Cooling Tower Blowdown Line during treatment. The bentonite clay absorbs the biocide, deactivating the biocide. Extensive studies of the biocide and its detoxified by-products have been conducted by the vendor and MSDSs for these products are attached as additional information to Module 1.
During refueling outages Cooling Tower basin sediment is removed and dewatered by belt filter press. A flocculant is used to enhance the dewatering process. The filtrate from the dewatering process is discharged to the Cooling tower blowdown line. The dewatered sediment is currently transported offsite for disposal.
PPL Susquehanna, LLC has received PaDEP approval to dry Cooling and Spray Pond sediment onsite as a coproduct. Runoff from the sediment may enter the SWROs, however, this additional runoff would be negligible compared to present site runoff volume. To date we have not utilized this option to dry cooling tower and spray pond sediment.
Included in the Cooling Tower Blowdown is miscellaneous wastewater such as tanker discharges of rainwater from the Condensate Storage Tank bermed areas, water from clean system drains in the Radiological Controlled Area (RCA) and peripheral facilities associated with the station and also mop water collections near the RCA exits 100 - 300 gal/week.
During periodical maintenance (or malfunctions) at the River Intake Structure screen wash water may be returned temporarily to the river from the Debris Handling Pit. This occurs infrequency and is recorded in station operating logs, work orders and tracking records as appropriate. Previous occurrences have been evaluated as non-impacting, (i.e. no detrimental chemicals are added at the Intake Structure) and were reported to the PaDEP in DMR cover letters for information only. For consistency these occurrences will be noted in our operating records and the PaDEP notified only if deleterious affects on the environment are suspected in accordance with appropriate sections of the NPDES Permit.
During cold weather operation deicing water is routed from the River Water Makeup line to the river intake structure for deicing purposes. An option is also available to utilize warm condenser water for this purpose. Currently procedural controls are in place to limit return flow to inside the intake when this option is utilized.
During operation of the Clarified Water System, which uses river water makeup, (typically used only during outages to augment well water use) there is a minimum flow of clarified water (approximately 150 gpm) back to the circulating water system to maintain consistent clarifier operation. This clarified water has no impact of circ water 0305
I Page 4 of 5 as min flow or as pumped out of the clarified during shut down. It is clean water typically <2.0 NTUs. Solids removed as underflow during clarifier operation are collected and removed for offsite disposal. Filter backwash water is returned/recycled to the clarifier inlet for treatment. Following clarifier shutdown low volume waste is pumped to the neutralization basin (Outfall 371) for processing prior to discharge.
INTERNAL OUTFALLS 171 - Liquid Radwaste discharge includes leakage and wastewater from the radiologically controlled area and the in plant chem lab. Prior to combining with Outfall 071, this wastewater is passed through various treatment processes to reduce the concentration of radioactive materials. Approximately 90% of liquid radwaste are treated by one of two processes: filtration followed by ion-exchange demineralization, or ion-exchange demineralization followed by microstraining.
Approximately 10% of liquid radwaste is processed through the laundry drain system, which receives wastewater from equipment washdown stations and personnel decontamination facilities in the radiologically controlled area. PPL-supplied clothing is sent to an outside contractor for cleaning. Miscellaneous wastes .discharged through, this system also include service water leakage, mop water from cleaning, and leakage from various pumps and valves. This water passes through microstraining filters prior to
,sampling for discharge. Sampling of this outfall in the last 5 years for 0 & G annually and TSS have indicated all nondetectable results. PPL requests elimination of these analysis requirement specifically the annual 0 & G as it is difficult to matrix this complex analysis with the radiological aspects ofI operation.
271 - Waste Filter Bypass was previously eliminated from this-NPDES permit since it is no longer in operation.
371 - Neutralization Basin internal discharge includes inputs from the demineralizer I rinse water, chemical waste inputs from Circulating Water Pumphouse Building equipment and floor drains and clarifier sludge holdup sump decant water. There are two neutralization basins each with a capacity of approximately 18,000 gallons. The I basins are used alternately and the contents are air sparged, recirculated, and sampled prior to being directed to the suction side of the circulating water pumps. I 471 - Waste Filter was previously eliminated from this NPDES permit since it is no longer in operation. 3 571 - Circulating Water Pumphouse Building sump was previously eliminated from the NPDES permit since it receives only circulating water and seal water (well water) from circ water/service water pump operation and is not impacted by station operation.
072 - The Service and Administration (S&A) Sump receives stormwater from the emergency start-up transformer bermed areas, the diesel generator oil unloading areas and equipment, and S&A Oil Storage bermed area. The sump contains two cells, each 0306 I
Page 5 of 5 with approximately 10,000-gallon capacity. An oil and grease separator is provided upstream of the sump to remove any fuel or transformer oil leakage.
073 - Unit I Transformer Water Sump collects stormwater from the transformers, turbine lube oil, and oil circuit breaker bermed areas. This sump has two cells of approximately 8,100 gallons each. The storm water collected in this sump passes through an oil and grease separator prior to entering the sump and is visibly inspected prior to discharge.
074- Unit 2 Transformer Water sump is similar to Outfall 073. It collects stormwater from the Unit 2 transformers and lube oil storage tank berm. Due to the similarity between these outfalls only Outfall 074 was sampled to represent this discharge and Outfall 073 for the NPDES permit renewal application.
075 - The Peach Stand Pond is a SWRO that collects and conveys runoff from North drainage area including site sumps and buildings. This outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may contain small amounts of chlorine, which will dissipate upon mixing with storm water before entering Lake Took-a-while.
Discharge from this outfall goes into Lake Took-a-while located east of US Route 11.
Because this outfall and Outfalls 070 and 080 are similar, only Outfall 080 was sampled for this NPDES permit renewal application.
079 - The Sewage Treatment Plant (STP) is designed to treat 80,000 gallons per day of sanitary wastes from the gravity collection system onsite and, from grinder pump stations at the Learning Center, Riverlands Recreation Area, Environmental- Lab, West Building, and a proposed oil & grease separator at a new planned Vehicle Maintenance Garage. In certain circumstances discharges from various sumps and drains may be routed to the Sewage Treatment Plant to meet NPDES permit-limits. Sanitary wastes may contain-small amounts of miscellaneous waste water, cleaning agents, and other chemicals. Material Safety Data Sheets for these chemicals recommend treatment at STPs prior to discharge (Susquehanna, River).
080 - The C-1 Pond is a SWRO outfall located in the Central Drainage Area just East of the station's protected area. This outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may contain small amounts of chlorine, which will dissipate upon mixing with storm water before entering Lake Took-a-while. Due to the similarity of this outfall and outfalls 070 and 075, only this Outfall 080 was sampled for this permit application.
6307
3800-PM-WSFROO08g Rev. 312006 Applicant Name: PPL Susquehanna, LLC Module 4 pennsytvania DEPARTMENT PROTECTION OF ENVIRONMENTAL COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 MODULE 4 Before completing this form, read the step-by-step instructions provided in Appendix 1.
AP*LICANtJNAMi PPL Susquehanna, LLC E Outfall Number 071 (Show location of sampling point on Line Drawing)
El Intake Sampling Results - Optional (Specify Source: __ )
El Background Sampling Results - Optional (Specify Location of Sample: __ )
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information: __ )
El Bypass or Sewer System Overflow (Describe: )
- 1. LEVEL PRESENT 2. UNITS 3.
Coefficient POLLUTANT GROUP 1 a. Maximum Daily Value b. Average of Analysis of Effluent
- c. No. of a. Variability
_ 1) Concentration (2)Mass (1)Concentration (2) Mass Analysis Concentration b. Mass (CV)
Biochemical Oxygen Demand, BOD 2.4 346 0.8 105 3 mg/L lb/day Chemical Oxygen Demand, COD 35 5044 30 3951 3 mg/L lb/day Hardness (CaCO3) 335 42440 284 37400 3 mg/L lb/day Total Suspended Solids, TSS 73 10520 39 1185 3 mg/L lb/day Total Dissolved Solids, TDS 662 83900 516 67900 3 mg.L lb/day Ammonia as N .16 20.3 .09 11.9 3 mg/L lb/day Nitrate-Nitrite (as N) 2.2 273 1.63 215 3 mg/L lb/day CD Total Kjeldahl Nitrogen (TKN) 1.1 139 .037 48.3 3 mg/L lb/day Phosphorus (as P), Total 1.4 177 1.33 176 3 mg/L lb/day Temperature winter Value Value ITemperature summer Value Value pH Min. 8.68 Max. 8.74 3 Standard units Standard units l.a. Maximum Daily Value - Report the hihest daily value or daily average value from the last year of data. Report both mass and concentration.
l.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.
1.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
3800-PM-WSFR0008g Rev. 312006 ' Applicant Name: PPL Susquehanna, LLC Module 4
- 3. Level Present
- 2. EPA 5. Coefficient POLLUTANT GROUP 1 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Believed Used* Number Number of Variability Absent (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV)
Color 5 SM20- 150 92 3 CU 2120B Fecal Coliform D_
Fluoride 200 300 0.32 40.5 0.25 33.4 3 mg/L lb/day Oil and Grease 2200 1664 ND ND ND ND 3 mg/L lb/day Bromide E 600 300 1.3 162 0.75 99.2 3 mg/L lb/day Chlorine, Total Residual E] 50 330.1 ND ND ND ND 3 mg/L lb/day Sulfate [] 2000 300 143 18100 84 11030 3 mg/L lb/day Sulfide [] 1000 SM4500F ND ND ND ND 3 mg/L lb/day Sulfite El 2000 SM4500B ND ND ND ND 3 mg/L lb/day Surfactants 25 SM20- .121 17.4 .04 5.3 3 mg/L lb/day
[
SurfaEtants 25 5540C Aluminum, Total 50 200.7 1.2 173 .75 99.2 3 mg/L lb/dau Barium, Total 5 200.7 .092 11.6 .084 11.1 3 mg/L lb/day Boron, Total El 50 200.7 .070 8.86 .061 7.99 3 mg/L lb/day Cobalt, Total 2.5 200.7 ND ND ND ND 3 mg/L lb/day Iron, Total 30 200.7 3.2 461 2.5 329 3 mg/L lb/day Iron, Dissolved E] 60 200.7 1.8 259 1.6 215 3 mg]L lb/day Manganese, Total [] 2.5 200.7 .26 37.5 .20 26.8 3 mg/L lb/day 1.8-13.11E+00 2.1 E-01 -
Radioactivity (Total Alpha and Beta)
Z)2.95E+00 2j 1.08E-01 900 11 1.38E-01 9.1 9.1 E-01 E+011 3 pCi/L -
lotal Organic Carbon, TOC 1000 SM20-ladium, Total EEr 4.16E-01 5310B 904 12 3.51 E-01 1730 9.4 3.01 E-01 1230 3 mg/L lb/day 1.08E+00 1.69E+00 8.93E-01 3 pCi/L Magnesium 50 200.7 18.4 2286 18.1 2380 3 mg/L lb/day Molybdenum 10 200.7 ND ND ND ND 3 mg/L lb/day Tin, Total 10 200.7 ND ND ND ND 3 mg/L lb/day Titanium, Total E 10 200.7 ND ND ND ND 3 mg/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
M - m - - - M M M M M M m M -MM M-
- - M M - - -M M M M M M M -
3800-PM-WSFROO08g Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 4
- It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
CD 3800-PM-WSFROO08g Rev. 3/2006 ,Applicant Name: PPL Susquehanna, LLC Module 4 w pennsylvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 1.
LLC form, read the step-by-step MODULE instructions provided in Appendix 4 Before completing this Susquehanna, Before completing this PPL IApPLICANT*iAME*"*
form, read the step-by-step instructions provided in Appendix 1.
,APPL.ICANT-NAMt,*j PPIL Susquehanna, LLC El Outfall Number __ (Show location of sampling point on Line Drawing)
[D Intake Sampling Results - Optional (Specify Source: Susquehanna River)
El Background Sampling Results - Optional (Specify Location of Sample: __ )
EL Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
EL New Discharge (Basis for Information: __ )
EL Bypass or Sewer System Overflow (Describe: )
- 1. LEVEL PRESENT 2. UNITS 3.
Coefficient POLLUTANT GROUP 1 a. Maximum Daily Value b. Average of Analysis of Effluent
- c. No. of a. Variability (1) Concentration (2) Mass (1) Concentration (2) Mass Analysis Concentration b. Mass (CV)
Biochemical Oxygen Demand, BOD ND ND 3 mg/L Chemical Oxygen Demand, COD ND ND 3 mg/L Hardness (CaCO3) 106 80.7 3 mgIL Total Suspended Solids, TSS 29 10 3 mg/L Total Dissolved Solids, TDS 179 145 3 mg/L
.Ammonia as N ND ND 3 mg/L Nitrate-Nitrite (as N) 0.56 0.45 3 mg/L Total Kjeldahl Nitrogen (TKN) ND ND 3 mg/L Phosphorus (as P), Total ND ND 3 mg/L Temperature winter Value Value Temperature summer Value Value pH Min. 7.08 Max. 7.88 3 Standard units Standard units 1.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
1.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.
1.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
m -mm M m M m M M M M M M M M M M M M
M - m m m m M M M m m M M m M M m m 3800-PM-WSFROO08g Rev. 312006 Applicant Name: PPL Susquehanna, LLC Module 4
- 3. Level Present
- 2. EPA 5. Coefficient POLLUTANT GROUP 1 1. MDL Method a. Max Daily Value b. Average of Analysis C. 4. Units of Effluent Believed Used* Number Number of Variability Absent (ig/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV)
Color 5 SM20- 50 28 3 CU lb/day 2120B 50 28CUIbda Fecal Coliform _ lb/day Fluoride 200 300 ND ND 3 mg/L lb/day Oil and Grease 2000 1664 ND ND 3 mg/L lb/day Bromide El 600 300 ND ND 3 mg/L lb/day Chlorine, Total Residual F] 10 330.1 0.1 0.05 3 mg/L lb/day Sulfate Ej 2000 300 26 21 3 mg/L lb/day Sulfide El 1000 SM4-500F ND ND 3 mg/L Ib/day Sulfite 2000 SM4-500B ND ND 3 mg/L lb/day Surfactants 25 SM20- .103 .043 3 mg/L lb/day Surfactants_____5 5540C I Aluminum, Total 50 200.7 .46 .11 3 mg/L lb/day Barium, Total 5 200.7 .028 .026 3 mg/L lb/day Boron, Total 50 200.7 ND ND 3 mg/L lb/day Cobalt, Total El 2.5 200.7 ND ND 3 mg/L lb/day Iron, Total El 30 200.7 1.3 .71 3 mg/L lb/day Iron, Dissolved [] 60 200.7 0.88 0.54 3 mg/L lb/day "
Manganese, Total E] 2.5 200.7 .098 .056 3 mg/L lb/day R 1.66E+00 2.49E+00 1.11 E+00 Radioactivity (Total Alpha and Beta) E 2.95E+00 1.07E+01 5.60E+00
.otal Organic Carbon, TOC 1000 SM20- 3.9 3.0 3 mg/L lb/day IEl 5310B Radium, Total Ej 4.98E-01 904 6.20E-02 5.01 E-02 3 pCiL 8.51 E-01 2.86E+00 5.21 E+00 Magnesium 50 200.7 6.9 5.1 3 mg/L Ib/day Molybdenum El 10 200.7 ND ND 3 mg/L lb/day Tin, Total El 10 200.7 ND ND 3 mg/L lb/day _ _
Titanium, Total El 10 200.7 1 ND ND 3 mg/L Ib/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
3800-PM-WSFROO08g Rev. 312006 Applicant Name: PPL Susquehanna, LLC Module 4
- It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
-_ m-m m- m m- m m- m m- m -m - -n -m -m-
3800-PM-WSFR0008g Rev. 312006 Applicant Name: PPL Susquehanna LLC Module 4 Modu pennsytvania OEPARTMENT OFENV1RONMENTALPROTECT1ON COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 MODULE 4 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT-1AME - PPL Susquehanna LLC
[ Outfall Number 072 (Show location of sampling point on Line Drawing)
El Intake Sampling Results - Optional (Specify Source: _.)
El Background Sampling Results - Optional (Specify Location of Sample: __.)
EZ Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
[I New Discharge (Basis for Information: _ .)
El Bypass or Sewer System Overflow (Describe:
- 1. LEVEL PRESENT 2. UNITS 3.
Coefficient POLLUTANT GROUP 1 a. Maximum Daily Value b. Average of Analysis of Effluent
- c. No. of a. Variability (1) Concentration (2) Mass (1) Concentration (2) Mass Analysis Concentration b. Mass (CV)
Biochemical Oxygen Demand, BOD 4.3 0.35 4.3 0.35 1 mg/L lb/day Chemical Oxygen Demand, COD ND ND ND ND 1 mg/L lb/day Hardness (CaCO3)
Total Suspended Solids, TSS ND ND ND ND 1 mg/L lb/day Total Dissolved Solids, TDS Ammonia as N Nitrate-Nitrite (as N) ND ND ND ND 1 mg/L lb/day Total Kjeldahl Nitrogen (TKN) ND ND ND ND 1 mg/L lb/day Phosphorus (as P), Total ND ND ND ND 1 mg/L lb/day Temperature winter Value Value Temperature summer pH Min. 7.71 18.9 Value Max. 7.71 - Value 1 degrees c Standard units N/A Standard units l.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
l.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.
1.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
3800-PM-WSFROO08g Rev. 312006 -Applicant Name: PPL Susquehanna LLC Module 4
- 3. Level Present
- 2. EPA 5. Coefficient POLLUTANT GROUP 1 1.MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Believed Used* Number Number of Variability Absent (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV)
Color Fecal Coliform Fluoride Oil and Grease E 3600 1664 ND ND ND ND 1 mg/L lb/day Bromide Chlorine, Total Residual Sulfate Sulfide _ _
Sulfite Surfactants Aluminum, Total Barium, Total __
Boron, Total _ _
Cobalt, Total Iron, Total Iron, Dissolved Manganese, Total Radioactivity (Total Alpha and Beta) __
Total Organic Carbon, TOC u4Radium, Total
'-Magnesium Molybdenum __
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
m -m mm- m m----m- -m m--n ---
3800-PM-WSFROO08g Rev. 312006 'Applicant Name: PPL Susquehanna LLC Module 4 m pennsylvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 MODULE 4 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICbANT NAME- PPL Susquehanna LLC Outfall Number 074 (Show location of sampling point on Line Drawing)
El Intake Sampling Results - Optional (Specify Source: _ ,)
EL Background Sampling Results - Optional (Specify Location of Sample: __ )
0i Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information: _ .)
El Bypass or Sewer System Overflow (Describe:
- 1. LEVEL PRESENT 2. UNITS 3.
Coefficient POLLUTANT GROUP 1 a. Maximum Daily Value b. Average of Analysis of Effluent
- c. No. of a. Variability (1) Concentration (2) Mass (1) Concentration (2) Mass Analysis Concentration b. Mass (CV)
Biochemical Oxygen Demand, BOD ND ND ND ND 1 mg/L lb/day Chemical Oxygen Demand, COD 53 3.58 53 3.58 1 mg/L lb/day Hardness (CaCO 3)
Total Suspended Solids, TSS 5 0.34 5 0.34 1 mg/L lb/day Total Dissolved Solids, TDS Ammonia as N
- . Nitrate-Nitrite (as N) ND ND ND ND 1 mg/L lb/day a Total Kjeldahl Nitrogen (TKN) NO ND NO NO 1 mg/L Ib/day Phosphorus (as P), Total ND r ND ND ND 1 mg/L lb/day Temperature winter Value Value Temperature summer 15 Value Value 1 degrees c N/A pH Min. 7.9 Max. 7.9 1 Standard units Standard units 1.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
1.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.
1.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
3800-PM-WSFROO08g Rev. 312006 , Applicant Name: PPL Susquehanna LLC Module 4
- 3. Level Present
- 2. EPA 5. Coefficient POLLUTANT GROUP 1 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Believed Used* Number Number of Variability Absent (pgIL) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV)
Color 0]
Fecal Coliform 0_
Fluoride Oil and Grease 2300 1664 ND ND ND ND 1 mg/L lb/day Bromide Z Chlorine, Total Residual Sulfate Sulfide Z Sulfite E]
Surfactants 0]
Aluminum, Total 0_
Barium, Total 0_
Boron, Total 0_
Cobalt, Total 0_
Iron, Total 0 Iron, Dissolved 0 Manganese, Total 0 Radioactivity (Total Alpha and Beta) 0]
CZ)
',Radium, Total '
"1ýagnesium 0 Molybdenum 0 Tin, Total 0 Titanium, Total 0_
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFROO08g Rev. 3/2006 Applicant Name: PPI Susquehanna, LLC Module 4 M pennsytvania PROTECTION COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OFENVIRONMENTAL PROTECTION DEPARTMENTOF ENVIRONMENTAL BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 in Appendix 1.
LLC the step-by-step instructions provided MODULE 4 form, this( PPI read Susquehanna, Before completing completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT NAME IPPI Susquehanna, LLC Outfall Number 079 (Show location of sampling point on Line Drawing)
Ii Intake Sampling Results - Optional (Specify Source: _ .)
LI Background Sampling Results - Optional (Specify Location of Sample: __ )
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information:___)
El Bypass or Sewer System Overflow (Describe: _ .)
- 1. LEVEL PRESENT 2. UNITS 3.
Coefficient POLLUTANT GROUP 1 a. Maximum Daily Value b. Average of Analysis of Effluent
- c. No. of a. Variability (1) Concentration (2) Mass (1) Concentration (2) Mass Analysis Concentration b. Mass (CV)
Biochemical Oxygen Demand, BOD 4.6 0.42 4.6 0.42 1 mg/L lb/day Chemical Oxygen Demand, COD 24 2.20 24 2.20 1 mg/L lb/day Hardness (CaCO 3) 176 16.14 176 16.14 1 mg/L lb/day Total Suspended Solids, TSS ND ND ND ND 1 mg/L lb/day Total Dissolved Solids, TDS 1080 99.08 1080 99.08 1 mg/L lb/day Ammonia as N 8.99 0.82 8.99 0.82 1 mg/L lb/day Nitrate-Nitrite (as N) 65.2 5.98 65.2 5.98 1 mg/L lb/day Total Kjeldahl Nitrogen (TKN) 9.8 0.90 9.8- 0.90 1 mg/L lb/day Phosphorus (as P), Total 8.0 0.73 8.0 0.73 1 mg/L lb/day Temperature winter Value Value Temperature summer 16.5 Value Value 1 Celcius pH Min. 7.23 Max. 7.23 Standard units Standard units 1.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
1.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.
1.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
3800-PM-WSFR0008g Rev. 3/2006 -Applicant Name: PPL Susquehanna, LLC Module 4
- 3. Level Present
- 2. EPA 5. Coefficient POLLUTANT GROUP 1 1.MDL Method a. Max DailyValue b. Average of Analysis c. 4. Units of Effluent Believed Used* Number Number of Variability Absent (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 5 Color Li SM20-
~~~~2120B 75 75 1 CU Fecal Coliform 9222D 11 1 coJL100mL Fluoride 200 300 ND ND ND ND 1 mg/L lb/day Oil and Grease Li 2100 1664 ND ND ND ND 1- mg/L lb/day Bromide Li 600 300 ND ND ND ND 1 mg/L lb/day Chlorine, Total Residual Li 10 330.1 ND ND ND ND 1 mg/L lb/day Sulfate Li 2000 300 95.5 8.76 95.5 8.76 1 mg/L lb/day Sulfide 1000 SM4500F ND ND ND ND 1 mg/L lb/day Sulfite Li 2000 SM4500B ND ND ND ND 1 mg/L lb/day Surfactants 25 SM240 ND ND ND ND I mg/L lb/day Aluminum, Total El 50 200.7 ND ND ND ND I mg/L lb/day Barium, Total Li 5 200.7 .012 .001 .012 .001 1 mg/L lb/day Boron, Total Li 50 200.7 ND ND ND ND 1 mg/L lb/day Cobalt, Total Li 2.5 200.7 ND ND ND ND 1 mg/L lb/day Iron, Total Li 30 200.7 .095 .009 .095 .009 1 mg/L lb/day Iron, Dissolved Li 60 200.7 .098 .009 .098 .009 1 mg/L lb/day Manganese, Total Li 2.5 200.7 .007 .001 .007 .001 1 mg/L lb/day z( l d1.81 E+00 900 9.80E-01 9.80E-01 adioactivity (Total Alpha and Beta) Li 3.94E+00 4.13E+01 4.13E+01 1 pCi/L
'CTotal Organic Carbon, TOC El 500 SM20- 1 7.6 .70 7.6 .70 1 mg/L lb/day 2.14E-01 904 2.29E-02 2.28E-02 Radium, Total i 8.46E-01 904 6.74E-01 6.74E-01 1 pCi/L Magnesium Li 50 200.7 14.6 1.34 14.6 1.34 1 mg/L lb/day Molybdenum Li 10 200.7 ND ND ND ND 1 mg/L lb/day Tin, Total Li 10 200.7 ND . ND ND ND 1 mg/L lb/day Titanium, Total EL 10 200.7 ND ND ND ND 1 mg/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
3800-PM-WSFROO08g Rev. 3/2006 Applicant Name: PPI Susquehanna, LLC Module 4
- It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFROO08h Rev. 3/2006 , Applicant Name: PPL Susquehanna LLC Module 5 COMMONWEALTH OF PENNSYLVANIA pennsytvania DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION DEPARTMENT OF ENVIRONMENTAL PROTECTION ANALYSIS RESULTS TABLE POLLUTANT GROUP 2 MODULE 5 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANTkTAME PPL Susquehanna LLC ED Outfall Number 071 (Show location of sampling point on Line Drawing)
El Intake Sampling Results - Optional (Specify Source: .)
El Background Sampling Results - Optional (Specify Location: __ )
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information: __ )
El Bypass or Sewer System Overflow (Describe:
- 3. Level Present_______
POLLUTANT GROUP 2 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Metals Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1M Antimony, Total 10 200.7 ND ND ND ND 3 mg/L lb/day 2M Arsenic, Total 5 200.7 ND ND ND ND 3 mg/L lb/day 3M Beryllium, Total 2 200.7 ND ND ND ND 3 mg/L Ib/day 4M Cadmium, Total 1 200.7 ND ND ND ND 3 mg/L lb/day 5M Chromium Il 2.5 200.7 .003 .38 .001 .13 3 mg/L lb/day 5M Chromium VI 10 3500CrD ND ND ND ND 3 mg/L lb/day kA 6M Copper, Total 5 200.7 .009 1.14 .007 .91 3 mg/L lb/day
-\7M Lead, Total 3 200.7 P003 .43 .001 .15 3 mg/L lb/day 8M Mercury, Total .2 245.1 ND ND ND ND 3 mg/L lb/day 9M Nickel, Total 10 200.7 ND ND ND ND 3 mg/L lb/day 10M Selenium, Total 10 200.7 ND ND ND ND 3 mg/L lb day 11M Silver, Total 2 200.7 ND ND ND ND 3 mg/L Ib/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the hiahest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
- rn - -rnrn"-1-- --
m m M m M m M M- M M M M M - - m M 3800-PM-WSFROO08h Rev. 312006 Applicant Name: PPL Susquehanna LLC Module 5 POLLUTANT GROUP 2 3. Level PresentCoefficient
- 1. MDL 2. EPA a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Metals Used* Method Number of Variability (pg/L) Number Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 12M Thallium, Total 10 200.7 ND ND ND ND 3 mg/L lb/day 13M Zinc, Total 5 200.7 .017 2.45 .014 1.8 3 mg/L lb/day 14M Cyanide, Total 5 335.4 ND ND ND ND 3 mg/L lb/day 14M Cyanide, Free 5 4500CNI ND ND ND ND 3 mg/L lb/day 15M Phenols, Total 5 420.4 ND ND ND ND 3 mg/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
,,3 3800-PM-WSFROO08h Rev. 312006 . Applicant Name:
Module 5 COMMONWEALTH OF PENNSYLVANIA V pennsyLvania DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION Ad DEPRTMNT OFENVRONMENTL PROTECTIO ANALYSIS RESULTS TABLE POLLUTANT GROUP 2 MODULE 5 Before completing this form, read the step-by-step instructions provided in Appendix 1.
,A"FPLICANT NAME El Outfall Number - (Show location of sampling point on Line Drawing)
[ Intake Sampling Results - Optional (Specify Source: Susquehanna River)
El Background Sampling Results - Optional (Specify Location: __ )
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information: )
El Bypass or Sewer System Overflow (Describe: __
- 3. Level Present POLLUTANT GROUP 2 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Metals Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1M Antimony, Total 10 200.7 ND ND ND ND 3 mg/L lb/day 2M Arsenic, Total 5 200.7 ND ND ND ND 3 mg/L lb/day 3M Beryllium, Total 2 200.7 ND ND ND ND 3 mg/L lb/day 4M Cadmium, Total 1 200.7 ND ND ND ND 3 mg/L lb/day 5M Chromium III 3 200.7 ND ND ND ND 3 mg/L lb/day*
5M Chromium VI 10 3500CrD ND ND ND ND 3 mg/L lb/day 6M Copper, Total 5 200.7 0.015 2.15 .012 1.54 3 mg/L lb/day 7M Lead, Total 3 200.7 'ND ND ND ND 3 mg/L lb/day 8M Mercury, Total .2 245.1 ND ND ND ND 3 mg/L lb/day 9M Nickel, Total 10 200.7 ND ND ND ND 3 mg/L lb/day 10M Selenium, Total 10 200.7 ND ND ND ND 3 mg/L lb day 11M Silver, Total 2 200.7 ND ND ND ND 3 mg/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertairty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
- m Gim ml m - - - - - - - -
BB - -I1 - --- 1
-U M M- M M M M M M M n - m M M M M M 3800-PM-WSFROO08h Rev. 3/2006 Applicant Name:
Module 5 POLLUTANT GROUP 2 3.5. Coefficient
- 1. MDL 2. EPA a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Metals Used* Method Number of Variability (pg/L) Number Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 12M Thallium, Total 10 200.7 ND ND ND ND 3 mg/L lb/day 13M Zinc, Total 5 200.7 .023 3.31 .017 2.24 3 mg/L lb/day 14M Cyanide, Total 5 335.4 ND ND ND ND 3 mg/L lb/day 14M Cyanide, Free 5 450OCNI ND ND ND ND 3 mg/L lb/day 15M Phenols, Total 5 420.4 ND ND ND ND 3 mg/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFR0008i Rev. 3/2006 -Applicant Name: PPI Susquehanna LLC Module 6 COMMONWEALTH OF PENNSYLVANIA pennsytvania DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION DEPARTMENTOF ENVIRONMENTAL PROTECTION ANALYSIS RESULTS TABLE POLLUTANT GROUP 3 MODULE 6 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT ME PPI Susquehanna LLC
[ Outfall Number 071 (Show location of sampling point on Line Drawing)
El Intake Sampling Results - Optional (Specify Source: __ )
El Background Sampling Results - Optional (Specify Location: __ )
EL Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
EL New Discharge (Basis for Information:__ )
EL Bypass or Sewer System Overflow (Describe: __ )
- 3. Level Present POLLUTANT GROUP 3 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Volitales Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1V Acrolein 30 624 ND ND ND ND 3 ug/L lb/day 2V Acrylonitrile 5 624 ND ND ND ND 3 ug/L lb/day 3V Benzene 1 624 ND ND ND ND 3 ug/L lb/day 5V Bromoform 2 624 ND ND ND ND 3 ug/L lb/day 6V Carbon Tetrachloride 1 624 ND ND ND ND 3 ug/L lb/day 7V Chlorobenzene 1 624 ND ND ND ND 3 ug/L lb/day 8mND 8V 9\) Chlorodibromomethane 1 624 ND ND ND ND 3 ug/L lb/day 9V Chloroethane 12624 ND ND ND ND 3 ug/L lb/day 10V 2-Chloroethylvinyl Ether' 2 T624 ND ND ND ND 3 ugIL lb/day II
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
rn--rn -- 1- --- - -
- M M M M M M M M M M - - - -
3800-PM-WSFR0008i Rev. 3/2006 .Applicant Name: PPI Susquehanna LLC Module 6
_________________3. Level Present POLLUTANT GROUP 3 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Volitales Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 11V Chloroform 1 624 ND ND ND ND 3 ug/L lb/day 12V Dichlorobromomethane 1 624 ND ND ND ND 3 ug/L lb/day 14V 1,1-Dichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 15V 1,2-Dichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 16V 1,1-Dichloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 17V 1,2 Dichloropropane 1 624 ND ND ND ND 3 ug/L lb/day 18V 1, 3-Dichloropropylene 1 624 ND ND ND ND 3 ug/L lb/day 19V Ethylebenzene 1 624 ND ND ND ND 3 ug/L lb/day 20V Methyl Bromide 1 624 ND ND ND ND 3 ug/L lb/day 21V Methyl Chloride 1 624 ND ND ND ND 3 ug/L lb/day 22V Methylene Chloride 1 624 2.0 0.25 0.67 .088 3 ug/L lb/day 23V 1,1,2,2-Tetrachloroethane 1 624 ND ND ND ND 3 ug/L lb/day 24V Tetrachloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 25V Toluene 1 624 ND ND ND ND 3 ug/L lb/day 26V 1,2-Trans-dichloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 27V 1,1,1-Trichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 28V 1,1,2-Trichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 29V Trichloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 31V Vinyl Chloride 2 624 ND ND ND ND 3 ug/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration..
3.b. Average of Analysis - Determine the average of all samples taken within the past year, Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFROO08i Rev. 3/2006 Applicant Name: PPI Susquehanna LLC Module 6 COMMONWEALTH OF PENNSYLVANIA I pennsytvania DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION E DEPARTMENT OF ENVIRONMENTAL PROTECTION ANALYSIS RESULTS TABLE POLLUTANT GROUP 3 MODULE 6 Before completing this form, read the step-by-step instructions provided in Appendix 1.
.APPLICANT 'NAME:- PPI Susquehanna LLC 0I Outfall Number - (Show location of sampling point on Line Drawing)
ED Intake Sampling Results - Optional (Specify Source: Susquehanna River)
EL Background Sampling Results - Optional (Specify Location: __.)
MI Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
LI New Discharge (Basis for Information:__ )
LI Bypass or Sewer System Overflow (Describe: _ )
- 3. Level Present POLLUTANT GROUP 3 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Volitales Used* Number Number of Variability (pig/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1V Acrolein 30 624 ND ND ND ND 3 ug/L lb/day 2V Acrylonitrile 5 624 ND ND ND ND 3 ug/L lb/day.
3V Benzene 1 624 ND ND ND ND 3 ug/L lb/day 5V Bromoform 2 624 ND ND ND ND 3 ug/L lb/day 6V Carbon Tetrachloride 1 624 ND ND ND ND 3 ug/L lb/day V7V Chlorobenzene 1 624 ND ND ND ND 3 ug/L lb/day
"*8V Chlorodibromomethane 1 624 ND ND ND ND 3 ug/L lb/day 9V Chloroethane 1 624- ND ND ND ND 3 ug/L lb/day 10OV 2-Chloroethylvinyl Ether 2 .624 ND ND ND ND 3 ug/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
- ----- - --- --- r n-1
3800-PM-WSFROOO8i Rev. 3/2006 Applicant Name: PPI Susquehanna LLC Module 6
- 3. Level Present POLLUTANT GROUP 3 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Volitales Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 11V Chloroform 1 624 ND ND ND ND 3 ug/L lb/day 12V Dichlorobromomethane 1 624 ND ND ND ND 3 ug/L lb/day 14V 1,1-Dichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 15V 1,2-Dichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 16V 1,1-Dichloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 17V 1,2 Dichloropropane 1 624 ND ND ND ND 3 ug/L lb/day 18V 1, 3-Dichloropropylene 1 624 ND ND ND ND 3 ug/L lb/day 19V Ethylebenzene 1 624 ND ND ND ND 3 ug/L lb/day 20V Methyl Bromide 1 624 ND ND ND ND 3 ug/L lb/day 21V Methyl Chloride 1 624 ND ND ND ND 3 ug/L lb/day 22V Methylene Chloride 1 624 1.8 0.22 1.3 0.18 3 ug/L lb/day 23V 1,1,2,2-Tetrachloroethane 1 624 ND ND ND ND 3 ug/L lb/day 24V Tetrachloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 25V Toluene 1 624 ND ND ND ND 3 ug/L lb/day 26V 1 2-Trans-dichloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 27V 1,1,1-Trichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 28V 1,1 ,2-Trichloroethane 1 624 ND ND ND ND 3 ug/L lb/day 29V Trichloroethylene 1 624 ND ND ND ND 3 ug/L lb/day 31V Vinyl Chloride 2 624 ND ND ND ND 3 ug/L lb/day
- 3. Ifother data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the-final NPDES permit.
3800-PM-WSFROO08j Rev. 3/2006 I Applicant Name: PPI Susquehanna LLC Module 7 COMMONWEALTH OF PENNSYLVANIA pennsytvania DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION DEPARTMENTOF ENVIRONMENTAL PROTECTION ANALYSIS RESULTS TABLE POLLUTANT GROUP 4 MODULE 7 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLIcANT NAMEI PPI Susquehanna LLC 0 Ouffall Number 071 (Show location of sampling point on Line Drawing)
El Intake Sampling Results - Optional (Specify Source: _ )
El Upstream Background Sampling Results - Optional (Specify Location: __ )
[I Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information:__ ,)
El Bypass or Sewer System Overflow (Describe:
_________________3. Level Present POLLUTANT GROUP 4 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Acid Compounds Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1A 2-Chlorophenol 7.5 625 ND ND ND ND 3 ug/L ib/day 2A 2,4-Dichlorophenol 7.5 625 ND ND ND ND 3 ug/L lb/day 3A 2,4-Dimethylphenol 7.5 625 ND ND ND ND 3 ug/L lb/day 4A 4,6-Dinitro-o-cresol 7.5 625 ND ND ND ND 3 ug/L lb/day 5A 2,4-Dinitrophenol 7.5 625 ND ND ND ND 3 ug/L lb/day 43A 2-Nitrophenol 7.5 625 ND ND ND ND 3 ugIL lb/day
%7A 4-Nitrophenol 7.5 625 ND ND ND ND 3 ug/L lb/day 3A P-chloro-m-cresol 7.5 625 ND ND ND ND 3 ug/L lb/day 9A Pentachlorophenol 15.1 625 ND ND ND ND 3 ug/L lb/day 10A Phenol 7.5. 625 ND ND ND ND 3 ug/L lb/day 11A 2,4,6-Trichlorophenol 7.5 625 ND ND ND ND 3 ug/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be usedto determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.b.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
- --- rn-rn-~~- 1nr - - - --- r
m m m - m-- m-mm m -m- m - - m-m 3800-PM-WSFROO08j Rev. 3/2006 Applicant Name: PPI Susquehanna LLC Module 7 COMMONWEALTH OF PENNSYLVANIA W pennsyLvania OFENIRONMETAL DEPARTENT PROTECTON DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 4 MODULE 7 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT'NýAME] PPI Susquehanna LLC El Outfall Number 071 (Show location of sampling point on Line Drawing)
[ Intake Sampling Results - Optional (Specify Source: Susquehanna River)
El Upstream Background Sampling Results - Optional (Specify Location: ___)
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
C3 New Discharge (Basis for Information: _ .)
El Bypass or Sewer System Overflow (Describe:
- 3. Level Present POLLUTANT GROUP 4 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Acid Compounds Used* Number Number of Variability (pgIL) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1A 2-Chlorophenol 7.5 625 ND ND ND ND 3 ug/L ib/day 2A 2,4-Dichlorophenol 7.5 625 ND ND ND ND 3 ug/L lb/day 3A 2,4-Dimethylphenol 7.5 625 ND ND ND ND 3 ug/L lb/day 4A 4,6-Dinitro-o-cresol 7.5 625 ND ND ND ND 3 ug/L lb/day 5A 2,4-Dinitrophenol 7.5 625 ND ND ND ND 3 ug/L lb/day 6A 2-Nitrophenol 7.5 625 ND ND ND ND 3 ug/L lb/day 7A 4-Nitrophenol 7.5 625 ND ND ND ND 3 ug/L lb/day 8A P-chloro-m-cresol 7.5 625 ND ND ND ND 3 ug/L lb/day 9A Pentachlorophenol 15.1 625 ND ND ND ND 3 ug/L lb/day 10A Phenol 7.5 625 ND ND ND ND 3 ug/L lb/day 11A 2,4,6-Trichlorophenol 7.5 625 ND ND ND ND 3 ug/L lb/day
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFROO08k Rev. 3/2006 Applicant Name: PPL Susquehanna LLC Module 8 9 pennsyLvania COMMONWEALTH OF PENNSYLVANIA
,d DEPARTMENTOF ENVIRONMENTAL PROTECTION DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 5 MODULE 8 Before completing this form, read the step-by-step instructions provided in Appendix 1.
ýAPPUICAT, NAME.i i PPL Susquehanna LLC
[ Outfall Number 071 (Show location of sampling point on Line Drawing)
El Water Supply Sampling Results - Optional (Specify Source: __)
El Background Sampling Results - Optional (Specify Location: __ )
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information:___
LI Bypass or Sewer System Overflow (Describe: __ )
- 3. Level Present POLLUTANT GROUP 5 2. EPA b. Annual Average of 5. Coefficient
- 1. MDL Method a. Max Daily Value Analysis c. 4. Units of Effluent Base Compounds Used* Number Number of Variability W(g/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1B Acenaphthene 1.4 625 ND ND ND ND 3 ug/L lb/day 2B Acenaphthylene 1.4 625 ND ND ND ND 3 ug/L lb/day 3B Anthracene 1.4 625 ND ND ND ND 3 ug/L lb/day 4B Benzidine 28.3 625 ND ND ND ND 3 ug/L lb/day 5B Benzo(a)anthracene 1.4 625 ND ND ND ND 3 ug/L lb/day 6B Benzo(a)pyrene 1.4 625 ND ND ND ND 3 ug/L lb/day 7B 3,4-Benzofluoranthene 1.4 625 ND ND ND ND 3 ug/L lb/day 8B Benzo(ghJ)perylene 1.4 625 ND ND ND ND 3 ug/L lb/day 9B Benzo(k)fluoranthene 1.4 625 ND ND ND ND 3 ug/L lb/day 10B Bis(2-Chloro-ethoxy)methane 2.8 625 ND ND ND ND 3 ug/L lb/day 111B Bis(2-Chloroethyl)ether 2.8 625 ND ND ND ND 3 ug/L lb/day 12B Bis(2-Chloro-isopropyl)ether 2.8 625 ND ND ND ND 3 ug/L lb/day 13B Bis(2-Ethylhexylphthalate 2.8 625 ND ND ND ND 3 ug/L lb/day 14B 4-Bromophenyl Phenyl Ether 2.8 625 ND ND ND ND 3 ug/L lb/day 15B Butylbenzyl Phthalate 2.8 625 ND ND ND ND 3 ug/L lb/day 16B 2-Chloronaphthalene 2.8 625 ND ND ND ND 3 ug/L lb/day 17B 4-Chlorophenyl Phenyl Ether 2.8 625 ND ND ND ND 3 ug/L Ilb/day 3.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
W M-VOO08ko.
Module 8 31290 M ~pi~n ame-"Susq~~annaR"
- 2. 3. Level Present POLLUTANT GROUP 5 b. Annual Average EPA a. Max Daily Value of Analysis 4. Units 5.ofCoefficient effluent
- 1. MDIL Method C. of Effluent Base Compounds Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 18B Chrysene 1.4 625 ND ND ND ND 3 ug/L lb/day 19B Dibenzo(a,h)anthracene 1.4 625 ND ND ND ND 3 ug/L lb/day 20B 1,2-Dichlorobenzene 2.8 625 ND ND. ND ND 3 ug/L lb/day 21B 1,3- Dichlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 22B 1,4- Dichlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 23B 3,3'-Dichlorobenzidine 7.5 625 ND ND ND ND 3 ug/L lb/day 24B Diethyl Phthalate 7.5 625 51.0 6.46 23.1 3.04 3. ug/L lb/day 25B Dimethyl Phthalate 7.5 625 ND ND ND ND 3 ug/L lb/day 26B Di-n-butyl Phthalate 2.8 625 ND ND ND ND 3 ug/L lb/day 27B 2,4-Dinitrotoluene 2.8 625 ND ND ND ND 3 ug/L lb/day 288 2,6Dinitrotoluene 2.8 625 ND ND ND ND 3 ug/L lb/day 29B Di-n-octyl Phthalate 7.5 625 ND ND ND ND 3 ug/L lb/day 30B 1,2-Diphenylhydrazine (as Azobenzene) 2.8 625 ND ND ND ND 3 ug/L lb/day 31B Fluoranthene 1.4 625 ND ND ND ND 3 ug/L lb/day 32B Fluorene - 1.4 625 ND ND ND ND 3 ug/L lb/day 33B Hexachlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 34B Hexechlorobutadiene 2.8 625 ND ND ND ND 3 ug/L lb/day 35B Hexachlorocyclopentadiene 7.5 625 ND ND ND ND 3 ug/L lb/day 36B Hexachloroethane 2.8 625 ND ND ND ND 3 ug/L lb/day 37B Indeno(1,2,3-cd)pyrene 1.4 625 ND ND ND ND 3 ug/L lb/day 38B Isophorone 2.8 625 ND NDý ND ND 3 ug/L lb/day 398 Naphthalene 1.4 625 ND ND ND ND 3 ug/L lb/day 440B Nitrobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 41B N-Nitrosodimethylamine 2.8 625 N.D ND ND ND 3 ug/L lb/day 42B N-Nitrosodi-n-propylamine 2.8 625 ND ND ND ND 3 ug/L lb/day 43B N-Nitrosodiphenylamine 2.8 625 ND ND ND ND 3 ug/L lb/day 44B Phenanthrene 1.4 625 ND ND ND ND 3 ug/L lb/day 45B Pyrene 1.4 625 ND ND ND ND 3 ug/L lb/day 46B 1,2,4-Trichlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 3.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFROO08k Rev. 312006 Applicant Name: PPL Susquehanna LLC Module 8 pennsylvania COMMONWEALTH OF PENNSYLVANIA SDEPARTMENTOF ENVIRONMENTAL PROTECTION DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 5 MODULE 8 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT NAME PPL Susquehanna LLC El Outfall Number (Show location of sampling point on Line Drawing) 0 Water Supply Sampling Results - Optional.(Specify Source: Susquehanna River)
El Background Sampling Results - Optional (Specify Location: __.)
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information: __.)
El Bypass or Sewer System Overflow (Describe: __ __
- 3. Level Present POLLUTANT GROUP 5 2. EPA b. Annual Average of 5. Coefficient
- 1. MDL Method a. Max Daily Value Analysis c. 4. Units of Effluent Base Compounds Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1B .Acenaphthene 1:4 625 ND ND ND ND 3 ug/L lb/day 2B -Acenaphthylene 1.4 625 ND ND ND ND 3 ug/L lb/day 3B Anthracene 1.4 625 ND ND ND ND 3 ug/L lb/day _
4B Benzidine 28.3 625 ND ND ND ND 3 ug/L -lb/day.
5B Benzo(a)anthracene 1.4- 625 ND ND ND -ND 3 -ug/L lb/day 6B Benzo(a)pyrene 1.4 625 ND ND ND ND 3 ug/L lb/day c 7B 3,4-Benzofluoranthene 1.4 625 ND ND ND ND 3 ug/L lb/day 8B Benzo(ghi)perylene 1.4 625 ND ND ND ND 3 ug/L lb/day 9B Benzo(k)fluoranthene 1.4 625 ND ND ND ND 3 ug/L lb/day 1OB Bis(2-Chloro-ethoxy)methane 2.8 625 ND ND ND ND 3 ug/L lb/day 11B Bis(2-Chloroethyl)ether 2.8 625 ND ND ND ND 3 ug/L lb/day 12B Bis(2-Chloro-isopropyl)ether 2.8 625 ND ND ND ND 3 ug/L lb/day 13B Bis(2-Ethylhexylphthalate 2.8 625 ND ND ND ND 3 ug/L lb/day 14B 4-Bromophenyl Phenyl Ether 2.8 625 ND ND ND ND 3 ug/L lb/day 15B -Butylbenzyl Phthalate 2.8 625 ND ND ND ND 3 ug/L lb/day 16B 2-Chloronaphthalene 2.8 625 ND ND ND ND 3 ug/L lb/day 17B 4-Chlorophenyl Phenyl Ether 2.8 625 ND ND ND ND 3 ug/L lb/day 3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
- --- - - m m - - ---- -
S -PM-I OA00OP Iv. WW Applc Namnt S,,quIeannMLc Module 8
- 2. 3. Level Present POLLUTANT GROUP 5 EPA a. Max Daily Valb. Annual Average 5. Coefficient 1.E a. Max Daily Value of Analysis 4. Units of Effluent Base Compounds Used* Number Number of Variability (IjglL) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 18B Chrysene 1.4 625 ND ND ND ND 3 ug/L lb/day 19B Dibenzo(a,h)anthracene 1.4 625 ND ND ND ND 3 ug/L lb/day 20B 1,2-Dichlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 21B 1,3- Dichlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 22B 1,4- Dichlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 23B 3,3'-Dichlorobenzidine 7.5 625 ND ND ND ND 3 ug/L lb/day 24B Diethyl Phthalate 7.5 625 14.2 2.05 4.73 0.62 3 ug/L lb/day 25B Dimethyl Phthalate 7.5 625 ND ND ND ND 3 ug/L lb/day 26B Di-n-butyl Phthalate 2.8 625 ND ND ND ND 3 ug/L lb/day 27B 2,4-Dinitrotoluene 2.8 625 ND ND ND ND 3 ug/L lb/day 28B 2,6-Dinitrotoluene 2.8 625 ND ND ND ND 3 ug/L lb/day 29B Di-n-octyl Phthalate 7.5 625 ND ND ND ND 3 ug/L lb/day 30B 1,2-Diphenylhydrazine (as Azobenzene) 2.8 625 ND ND ND ND 3 ug/L lb/day 31B Fluoranthene 1.4 625 ND ND ND ND 3 ug/L lb/day 32B Fluorene 1.4 625 ND ND ND ND 3 ug/L lb/day 33B Hexachlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 34B Hexechlorobutadiene 2.8 625 ND ND ND ND 3 ug/L lb/day 35B Hexachlorocyclopentadiene 7.5 625 ND ND ND ND 3 ug/L lb/day 36B Hexachloroethane 2.8 625 ND ND ND ND 3 ug/L lb/day 37B Indeno(1,2,3-cd)pyrene 1.4 625 ND ND ND ND 3 ug/L lb/day A38B Isophorone 2.8 625 ND ND ND ND 3 ug/L lb/day
- .396 Naphthalene 1.4 625 ND ND ND ND 3 ug/L lb/day 40B Nitrobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 41B N-Nitrosodimethylamine 2.8 625 ND ND ND ND 3 ug/L lb/day 426 N-Nitrosodi-n-propylamine 2.8 625 ND ND ND ND 3 ug/L lb/day 436 N-Nitrosodiphenylamine 2.8 625 ND ND ND ND 3 ug/L lb/day 44B Phenanthrene 1.4 625 ND ND ND ND 3 ug/L lb/day 45B Pyrene 1.4 625 ND ND ND ND 3 ug/L lb/day 46B 1,2,4-Trichlorobenzene 2.8 625 ND ND ND ND 3 ug/L lb/day 3.a. Maximum Daily Value - Report the highestdaily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within'the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFRO0O8I Rev. 3/2006
- Applicant Name: PPL Susquehanna LLC Module 9 COMMONWEALTH OF PENNSYLVANIA pennsylvania DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION DEPARTMENTOF ENVIRONMENTAL PROTECTION ANALYSIS RESULTS TABLE POLLUTANT GROUP 6 MODULE 9 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT NAME j PPL Susquehanna LLC Ouffall Number 071 (Show location of sampling point on Line Drawing)
El Intake Sampling Results - Optional (Specify Source: Susquehanna River)
El Upstream Background Sampling Results - Optional (Specify Location: __ )
El Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing)
El New Discharge (Basis for Information: __
MI Bypass or Sewer System Overflow (Describe: __ )
- 3. Level Present POLLUTANT GROUP 6 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Pesticides Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1P Aidrin 2P Alpha-BHC 3P Beta-BHC 4P Gamma-BHC 5P Delta-BHC 6P Chlordane 7P 4,4'-DDT 8P 4,4"-DDE 9P 4,4"-DDD 10P Dieldrin 11P Alpha-endosulfan
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
- m m - m - -- - -- rn--rn--
M M M M M--mM--- m -M M m 3800-PM-WSFROO081 Rev. 3/2006 Applicant Name: PPL Susquehanna LLC Module 9
- 3. Level Present POLLUTANT GROUP 6 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Pesticides Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 12P Beta-endosulfan 13P Endosulfan Sulfate 14P Endrin 15P Endrin Aldehyde 16P Heptachlor 17P Heptachlor Epoxide 18P PCB-1242 0.50 608 ND ND ND ND 3 ug/L Ibday 19P PCB-1254 0.50 608 ND ND ND ND 3 ug/L lb/day 20P PCB-1221 0.50 608 ND ND ND ND 3 ug/L ib/day 21P PCB-1232 0.50 608 ND ND ND ND 3 ug/L Ibday 22P PCB-1248 0.50 608 ND ND ND ND 3 ug/L lb/day 23P PCB-1260 0.50 608 ND ND ND ND 3 ug/L lb/day 24P PCB-1016 0.50 608 ND ND ND ND 3 ug/L lb/day 25P Toxaphene 26P DIOXIN: 2,3,7, 8-Tetrachlorodibenzo-P- Describe Results:
Dioxin (TCDD) Describe Results:
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
,,3.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.
Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
b~.c A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background. I
- It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFROO081 Rev. 3/2006 .. Applicant Name: PPL Susquehanna LLC Module 9 COMMONWEALTH OF PENNSYLVANIA pennsyLvania DEPARTMENT OF ENVIRONMENTAL PROTECTION 7r Modu OF ENVIRONMENTAL ODEPARTMENT PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION ANALYSIS RESULTS TABLE POLLUTANT GROUP 6 MODULE 9 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPLICANT NAME PPL Susquehanna LLC El Outfall Number (Show location of sampling point on Line Drawing)
ED Intake Sampling Results - Optional (Specify Source: Susquehanna River)
El Upstream Background Sampling Results - Optional (Specify Location: ___)
r] Treatment Facility Influent Sampling Results (Show location of sampling point on Line Drawing) nl New Discharge (Basis for Information:___)
El Bypass or Sewer System Overflow (Describe: __.)
- 3. Level Present POLLUTANT GROUP 6 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Pesticides Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1P Aldrin 2P Alpha-BHC 3P Beta-BHC 4P Gamma-BHC 5P Delta-BHC 6P Chlordane 7P 4,4'-DDT 8P 4,4"-DDE 119P 4,4"-DDD __
10P Dieldrin 11P Alpha-endosulfan _
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily averagevalue from the last year of data. Report both mass and concentration.
3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
rn rn rn - - ------ - -------
mImmm m m m m nmm M--
3800-PM-WSFROOOSI Rev. 3/2006 Applicant Name: PPL Susquehanna LLC Module 9
- 3. Level Present POLLUTANT GROUP 6 2. EPA 5. Coefficient
- 1. MDL Method a. Max Daily Value b. Average of Analysis c. 4. Units of Effluent Pesticides Used* Number Number of Variability (pg/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 12P Beta-endosulfan 13P Endosulfan Sulfate 14P Endrin 15P Endrin Aldehyde 16P Heptachlor 17P Heptachlor Epoxide 18P PCB-1242 0.47 608 ND ND ND ND 3 ug/L Wbday 19P PCB-1254 0.47 608 ND ND ND ND 3 ug/L lb/day 20P PCB-1221 0.47 608 ND ND ND ND 3 ug/L ib/day 21 P PCB-1232 0.47 608 ND ND ND ND 3 ug/L Ibday 22P PCB-1248 0.47 608 ND ND ND ND 3 ug/L lb/day 23P PCB-1260 0.47 608 ND ND ND ND 3 ug/L lb/day 24P PCB-1016 0.47 608 ND ND ND ND 3 ug/L lb/day 25P Toxaphene 26P DIOXIN: 2,3,7, 8-Tetrachlorodibenzo-P- Describe Results:
26P__ Dioxin (TCDD) Describe Results:
- 3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.
3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.
' 3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.
- j 3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background.
- It is in the applicant's interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit.
3800-PM-WSFROO08m Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 10 COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION HAZARDOUS SUBSTANCE TABLE MODULE 10 Before completing this form, read the step-by-step instructions provided in Appendix 1.
.YAPPLICANTNAME PPL Susquehanna, LLC
- 1. Name of 3. Amount Per Outfall 5. Treatment Provided Table 3 Quantity 4.
Substance 2. Outfall Ib/24 hrs Frequency Duration Origin and Source a b c SodiumSoim071 5000 2xday 2hrs/Unit CoolingTower Coolig] []
Hypochlorite Chlorination 11 El 13.
El 1:1 El E] El El El- 1 Li L
[
E]
El El El
_ _ _ L
_ _1 Li L Li]
E
______ ___ _ _L El El
_ _ LEl Li El LiEL
_ _ _ __ _ _ L n_ LiEL LiEL I _ _ _ LE_ Li Ei LiELi Li EL EL 0339 -
I 3800-PM-WSFROO08n pennsyTvania Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Outfall: All (N/A)
COMMONWEALTH OF PENNSYLVANIA
-I DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION OTHER TOXIC CHEMICALS MODULE 11 I
Before completing this form, read the step-by-step instructions provided in Appendix 1.
ApplicantName. PPL Susquehanna, LLC I
'OuffallNumber All (N/A) I
- 1. GC/MS "Five Peaks" pollutants (see Appendix 1)
Group Number Chemical -Substance or MDL Average Effluent Concentration Maximum Effluent Concentration No. Samples Positive
/
I (3- 6) Compound Name (pg/L) (pg/L) (pg/L) No. analyzed I
I
- 2. Other Chemicals Average Indicate if I
Substance Reason for Presence in Discharge Concentration (pg/L)
Presence is Known (K) or Suspected (S) I I
I I
_____________ .1_____________________________________________________ ______________ It _____________________________ I
+ *1-I
+ I + I L1 If additional peaks were not available for one or more groups with the method used check here and attach an I
explanation of why the method was selected.
Provide additional sheets as necessary. I I
0340 -
3800-PM-WSFROO08o Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 12 W3pennsylvania COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION VM DEPARTMENT OFENVIRONMENTAL PROTECTION BUREAU OF WATER STANDARDS AND FACILITY REGULATION STORMWATER MODULE 12 Before completing this form, read the step-by-step instructions provided in Appendix 1.
M ý-_
ml APPLICANT NAME':J I* PPL Susquehanna, LLC
- 1. Site Plan and Stormwater Runoff. Attach a copy of your facility's site plan. (See instructions)
DEP strongly recommends the separation of stormwater and other wastewaters.
- 2. Description of Potential Pollutant Sources and Controls
- a. For each stormwater outfall, provide an estimate of the area (include units) drained to the outfall, and a list of potential pollutant(s) and sources for the outfall.
Total Area Drained Outfall Number (provide units) Potential Pollutant(s) and Sources 070 133 Acres Oil Storage in south drainage, water storage tanks, water treatment bldgs.
075 167 Acres Oil Storage in north drainage, firing range, site runoff 080 51 Acres Oil and waste storage in central drainage, water storage tanks, well treatment bldg.
- b. Describe Best Management Practices and nonstructural controls used to prevent potential pollutants in stormwater.
Inspections, container condition maintained, PPC Plan Implemented, training provided, assessments, audits, walkdowns, limit storage volume(s), utilize less hazardous approved materials whenever possible.
- c. For each stormwater outfall, provide the location and description of existing structural control measures to reduce pollutants in stormwater runoff; and a description of the treatment the stormwater receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. --
Outfall Number Control Measures 070 Rention pond, spill containment / berms, level alarms 075 Spill berms, Oil spill collar on rentention pond standpipe, leak detection alarms 080 Rentention pond, spill containments, level controls/alarms
- 3. Non-stormwater Discharges
- a. All non-stormwater discharges from these outfall(s) are identified in the Industrial Wastewater section of this application for the outfall.
EYES n NO
- b. Provide a description of the method used, the date of any testing, and the on-site drainage points that were directly observed during a test.
N/A I
- 4. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last 3 years, including the approximate date and location of the spill or leak, and the type and amount of material released.
No significant or reportable spill events in the last 3 years.
0341
iCr NORTH PPC PLAN APPENDIX B FENCING REVYISIN 9 kROTECTE 1tb'AR,EA bOUNDA.RY,~ J=;
N.. . SEAM SuS~~jA~ NIx C". ELECTRIC :'STATIO3N I I1'
. ...... PPC*,PLAN:". - I MAJOR DRAINAGE. .AREAS ANDýFLOUPATHS lREVISED-8/1704.
m -m*m Am fm i-4 F-m-mm
3800-PM-WSFROO08o Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 12
- 5. PREPAREDNESS, PREVENTION, AND CONTINGENCY (PPC) PLANNING.
Does the facility have a PPC plan? 2 YES E] NO Does the facility have any other related plans, such as a Polluti6n Incident Prevention (PIP) 0 YES E NO Plan, Spill Prevention Control and Counter Measure (SPCC) Plan or Stormwater BMP Plan?
If "YES," identify and indicate date(s) implemented.
Type of Plan Date Implemented PPC Plan Note: Two (2) Copies provided w/Application Updated 1/8/2010 SPPC Plan Note: Two (2) Copies provided w/Application Updated 1/8/2010 DEP may require the plan(s) be submitted with this application.
- 6. Additional Stormwater Information Submission
- a. Could all sampling be performed as required? EYES EINO (Explain below)
Outfall 080 was sampled representative of 070 & 075.
- b. Complete a Stormwater Sampling Data Table (Module 13) for each outfall containing stormwater.
Indicate the total number of tables submitted.
0343
Applicant Name: PPL Susquehanna, LLC I
-I 3800-PM-WSFROO08p Rev. 3/2006 13 Outfall: 080 Mfte pennsytvaLia PROTECTION OF ENVIRONMENTAL COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION DEIPARTMENT BUREAU OF WATER STANDARDS AND FACILITY REGULATION STORMWATER SAMPLING DATA TABLE MODULE.13 Before completing this form, read the step-by-step instructions provided in Appendix 1.
APPICANT NAME jPPL Susquehanna, LLC OU TFALLUMBER 080 RTAIVE UTALNUMBER(S).
- 1. Provide the results of at least one analysis for every pollutant in this table. See Appendix 1.
Maximum Values Average Values I
CAS (include units) (include units) Number Pollutant Number (if available)
Grab Sample Taken During First 30 Minutes Grab Sample Taken During First 30 Minutes of Storm Events Sampled Sources of Pollutants I
Oil and Grease Biological Oxygen Demand (BODS)
ND ND ND ND 1
I Chemical Oxygen ND ND Demand (COD)
Total Suspended 7 mg/L 7 mg/L 1 I
Solids (TSS) 7_gL7m/_
Total Kjeldahl Nitrogen Nitrate plus Nitrite ND ND ND ND 1
I Nitrogen Total Phosphorus pH (min./Max.)
ND 7.9 SU ND 7.9 SU 1
1 I
- 2. List each pollutant that is limited by an ELG which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). See the instructions for additional details and requirements.
I CAS Number Maximum Values (include units)
Grab Sample Taken Average Values (include units)
Grab Sample Number of Storm I
(if During Taken During Events Chlorine Pollutant available) First 30 Minutes
<0.05 mg/L First 30 Minutes
<0.05 mg/L Sampled 1
Sources of Pollutants Infrequent, I total residual Incidental Tank Drainage I
I I
I 0344
3800-PM-WSFROO08p Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC Module 13 Outfall: 080
- 3. List each pollutant shown in Table 3 and Pollutant Groups 1-6 that is known or believed to be present. (See Appendix 1.)
Maximum Values Average Values CAS (include units) (include units) Number Number Grab Sample Taken Grab Sample of Storm (if During Taken During Events Pollutant available) First 30 Minutes First 30 Minutes Sampled Sources of Pollutants Firing Range - bullet backstop Lead ND ND 1 material previously screened to remove fragments
- 4. Provide data for the storm event s) which resulted in the maximum values for the flow weighted composite sample.
- 1. 2. 3. 4. 5. 6. 7. B.
Total flow Duration Total rainfall Number of hours between Maximum flow rate from rain Form of Date of of Storm during storm beginning of storm during rain event event (gallons Season Precipitation Storm (in event measured and end of (gallons per minute or specify Sample (rainfall, Event minutes) (in inches) previous measurable event or specify units) units Was taken snowmelt) 10/15/10 13 hours1.50463e-4 days <br />0.00361 hours <br />2.149471e-5 weeks <br />4.9465e-6 months <br /> 0.51 130 hours0.0015 days <br />0.0361 hours <br />2.149471e-4 weeks <br />4.9465e-5 months <br /> 16.6 gpm 10374 gal Fall Rainfall
- 5. Provide a description of the method of flow measurement or estimate.
Volumetric measurement at discharge pipe into container of known quantity.
0345
3800-PM-WSFROO08p Rev. 3/2006 Applicant Name: PPL Susquehanna, LLC I
Module 13 Outfall: 080
-I 0346
Appendix A EPA 316(b) Phase II Documentation PPL Susquehanna, LLC Operation is in compliance with Phase II per Compliance Alternative (1)(i)
NPDES RENEWAL APPLICATION PERMIT NO. PA 0047325 March 2010
EPA 316(b) Rule (Phase II)
Cooling Water Intake Structure PPL Susquehanna, LLC is in compliance with the requirements of the Phase II 316(b) Rule per Compliance (1)(i). This facility is equipped with a closed-cycle recirculating system. According to the rule, having made this demonstration in the previous NPDES Permit Application, this facility is deemed to have met the applicable performance standards and will not be required to demonstrate further that this facility meets the impingement mortality and entrainment performance standards in 40 CFR 124.94(b) of the rule. The supporting data was previously submitted as required by 40 CFR 122.2(r)(2),(3) and (5).
Appendix B Preparedness Prevention and Contingency (PPC) Plan (Includes SPCC Plan)
NPDES RENEWAL APPLICATION-PERMIT NO. PA 0047325 March 2010 PPL Susquehanna, LLC (2 Copies provided to PaDEP with Original Application)
(PPL distribution, 'see Nuclear Department Waste and Chemical web site for copy of PPC Plan)