PLA-5852, NRC Notification of NPDES Permit Renewal Application PLA-5852

NRC Notification of NPDES Permit Renewal Application PLA-5852

ML050400270
Person / Time
Site:	Susquehanna
Issue date:	01/28/2005
From:	Mckinney B Susquehanna
To:	Document Control Desk, Office of Nuclear Reactor Regulation
References
-RFPFR, PA-0047325, PLA-5852
Download: ML050400270 (354)

Text

Britt T. McKlnney PPL Susquehanna, LLC Vice President-Nuclear Site Operations 769 Salem Boulevard ' * %am / 4 Berwick,PA 18603 Tel. 570.542.3149 Fax 570.542.1504 mm10-=

btmckinney@pplweb.com b..

blshriver@pplweb.com JAN 2 8 2D05 U. S. Nuclear Regulatory Commission Attn.: Document Control Center Mail Station OPI-1 7 Washington, DC 20555 SUSQUEHANNA STEAM ELECTRIC STATION NRC NOTIFICATION OF NPDES PERMIT RENEWAL APPLICATION Docket Nos. 50-387 PLA-5852 and 50-388 The purpose of this letter is to submit the Susquehanna Steam Electric Station NPDES permit renewal application to the NRC in accordance with Section 3.2 of the Environmental Protection Plan.

Please contact Mr. Curtis H. Saxton at (570) 542-1879, if there are any questions concerning the renewal application.

B. T. McKinney Attachment Copy: Regional Administrator - Region I Mr. A. J. Blamey, NRC Sr. Resident Inspector Mr. R. V. Guzman, NRC Project Manager Mr. R. Janati, DEP/BRP QQDI

SUSQUEHANNA- STEAM ELECTRIC STATION

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'NATIONAL POLLUTANT DISCHARGE' ELIMINATION SYSTEM (NPDES)

• X RENEWAL PERMIT L'*~~ jfj7.7% -- APPLICATION PERMIT NO. PA 0047325 k-Bit Kg,,,

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January 6, 2005 Mr. Dino Agustini Chief Permits Section L Water Management Program Peninsylvania Department of Environmental Protection 2 Public Square Wilkes-Barre, PA 18711-0790 L SUSQUEHANNA STEAM ELECTRIC STATION APPLICATION-NPDES RENEWAL PERMIT PA0047325 CCN 741326' L .PLE-0023763

Dear Mr. Agustini:

PPL Susquehanna, LLC is submitting a NPDES permit renewal application for the Susquehanna Steam Electric Station (S ES), Salem Township, Luzerne County, PA.

The present NPDES permit no; PA-0047325 expires on July 6,2005.-

Included'for Pennsylvania Department of Environmental Protection review are; 1) three

- copies of the application (one notarized), 2) an application fee of $500.00, payable to' the Commonwealth of Pennsylvania, 3) copies of letters with certified mail receipts notifying Salem Township and Luzeme County of this renewal permit application and 4)

- two copies of the Susquehanna SES, Pollution Prevention and Contingency (PPC)

Plan.

- If you have any questions please call Curt Saxton at (570) 542-1879.

Sp.ctrely, Bruce E. Rhoads L Manager - Plant Chemistry Enclosure Attachment A - Requested Permit Changes Attachment B - Table of Contents - Permit Application and Supple-mental Information

It 6, 2005 January 6, 2005 PLE -0023763 hi I

bcc:

I Iii T. D. Belles NUCSA3 w/a M. B. Detamore GENPL5 wo/a R.

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L. Doty A. Evans GENPL5 GENTW17 wo/a wla Il J. P. Felock NUCSB2 wla J.

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S. Fields H. Herre GENPL5 SFC wia wia II L. J. Humpf NUCPT wla T. V. Jacobsen NUCE3 wia A. Khanwalkar GENTW3 wo/a;.

J. L. McCormick NUCSA3 wia B. T. McKinney NUCSB3 wo/a D. J. Morgan NUCSA3 wia W. E. Morrissey NUCSA4 w/a R. W. Osbome Allegheny w/a L. A. Ramos SSO. wo/a P. Renshaw GENPL6 wo/a B. E. Rhoads R. A. Saccone NUCSA3 NUCSB3 wla wo/a I

C. H. Saxton NUCSA3 J. P. Schmidt R. L. Takacs GENTW17 NUCSA3 wa/a wo/a Ii NUCSA3 wl/a J. R. Wolfer J. Zerance NUCPT SP&E File (CCN 773015-07A) GENN3 wo/a wia Ii DCS File NUCSA2 w/a I1

Attachment A L Requested Permit Changes

- 1. Request elimination of Internal Outfall 571 Circ Water Pumphouse Sump, since it merely returns cooling water pump seal water (domestic/well water mixed with circulating water) to the Circulating water system and is not impacted by SSES operation. It is included within the limits of Outfall 071 cooling tower blowdown.

2. Request revised monitoring frequency for Outfall 072, Service &Administration' (S&A) Sump, to be consistent with Outfalls 073 and 074, currently sampled quarterly. This sump similarly consistently showsrMinimal level of oil &grease and total suspended solids. Frequency of this discharge is related to storm events and not station operation. The S&A Sump 'collectsstormwater around the' Emergency transformers on the east side of the site, the diesel generator oil L unloading area and equipment and S&A oil storage area berm. 'Controls, treatment and visual inspection prior to'discharge are a place to ensure no contamination of this miscellaneous wastewater. Consistent increased long-term monitoring has indicated no challenges to the monitored parameters.

3. ReqUest eliminating condition or specific'edition reference to Standards Methods I of Analysis for CBOD5 in permit part C, Special Condition #11.' Ifthis special condition needs to remain recommend simply referring to complianoeawith 4OGFRI36 accepted rhethods. In the past this detail of this special condition has-icaused confusion when the Standard Method editions have changed or been-' '

updated from time to time. (Concurrence to eliminate'this specific reference.'

discussed with Dino Agustini, May 12, 2004.)

4. In Permit Part C, Special Condition 12, the last paragraph requires that accurate records of chemical usage (name of additive, quantity added, date added, and blowdown discharge volumes) be maintained, and kept on site by the permittee.

We agree and comply with this condition, however, request elimination of the wording on the lChemicalAdditive Report Form" as we have specific procedures, controls and records for chemical additions and system operation which collect and record this information and using the PaDEP example form is duplicative and unnecessary, effort. Request clarification of the special condition to eliminate that

- specific wording on the ."ChemicalAdditive Report Form"

-l Attachment B Table of Contents

!,I It NPDES Permit Application and Supplemental Information IL I Municipal and County Act 14 Notification / Documentation 11 11 General Information Form III Completed Permit Application Modules

.1 IV Supplemental Information Provided: Ii

- Module 1 - Topographic Map and Water Balance Schematic

- Module 1 Item 7 - Water Treatment Chemical notes and MSDSs ~I

- Module 3- Additional Outfall Descriptions

- Module 12 - Stormwater:Drainage Areas and Flowpaths V Appendix A - EPA 316(b) Rule (Phase II - Supporting Documentation provided I'

to illustrate PPL Susquehanna, LLC operation is currently in compliance per.

"'.Compliance Altemative (1)(1).

I.

IV Appendix B = Pollution Prevention and Contingency (PPC) Plan (includes Spill

^ Prevention Control and Countermeasure (SPCC) Plan) (11/19/04)

Ii A

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-I Ii Ii

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ii 1 December 10, 2004 p p l ?Ii s

Ms. Patricia Owens Secretary, Salem Township Salem Township Municipal Building 400 Luzeme Avenue Berwick, PA 18603 SUSQUEHANNA STEAM ELECTRIC STATION NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT RENEWAL: PA 0047325 PLE-0023750

Dear Ms. Owens:

In accordance with Act Number 14, P.L. 834, this letter is to notify you that PPL Susquehanna, LLC intends to submit a National Pollutant Discharge Elimination System Permit renewal application in January 2005 to the Pennsylvania Department of Environmental Protection for the Susquehanna Steam Electric Station (SES) located in Salemi Township, Luzeme County, Pennsylvania.

If you have any questions concerning this permit renewai application, please call Curt Saxton (570) 542-1879.

Sincerely, Bruce E. Rhoads Manager - Plant Chemistry Certified Mail Number 7001 1940 0000 2651 8118 Copy to:

Ms. N. Green, EPA Region Im Mr. Dino Augustini, PaDEP

1 December 10, 2004

p. ..

1%4 TM JI Mr. Samuel Guesto, Chief Clerk Luzerne County Courthouse Il 200 North River Street Wilkes-Barre, PA 18711 l

SUSQUEHANNA STEAM ELECTRIC STATION I' NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT RENEWAL: PA 0047325 CCN 741326-100 I PLE-0023751 I

Dear Mr. Guesto,

I1 In accordance with Act Number 14, P.L. 834, this letter is to notify you that PPL Susquehanna, LLC intends to submit a National Pollutant Discharge Elimination System Permit renewal application in January 2005 to the Pennsylvania Department of Environmental Protection for the A Susquehanna Steam Electric Station (SES) located in Salem Township, Luzeme County, Pennsylvania.

Ii If you have any questions concerning this permit renewal application, please call Curt Saxton (570) 542-1879.

Sincerely, Ii Bruce E. Rhoads Manager - Plant Cheniistry 11 Certified Mail Number: 7001 1940 0000 2651 8125 Copy to:

A' Ms. N. Green, EPA Region m Mr. Dino Augustini, PaDEP Ii Ii J

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• Complete Items 1, 2, and 3. Also complete ItRem 4 If Restricted Delivery Is desired.

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• Print your name and address on the reverse cn th-4t -w - r+ntf +1 tha #nn tn ,.

• Attach this card to the back of the mailplece, or on the front If space permits.

I 1. Article Addressed to:

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I 4. Restricted Delivery? Ptra Fee) O Yes 1 2. Article Number

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-Item 41estricted Delivery Is desired. Adisee a Print yom name and address on the reverse so that we can return the card to you. B Reived by (Pun sine) C of ivery

• Attach this card to the back of the mallplece,

! or on the front I space permits.. D de71X/D a ,

i _ 0. Isdelivery address difflerentt from item I Ysl a

1.Artcle Addressed to: If YES, enter delivery address below: ' No j LL~zeCVne Cent~y Ccr->W

• I OO flvh R; er e td 3. Service Type Itijles- SBar'%e, rA 1)7// o Certed Mail Cl Express Mal

>k:Registered E-Retum 4 Receipt for Merchandise i3 Insured Mail 0 C.O.D.

4. Restricted Deivery? Etr" Fee) 0 Yes

2. Article Number.

(i ansfer ftm service IabeO 7001 1940 0000 2 I51 81,5 I Ps Form 3811, August 20W1 Domestic Return Receipt 102595-01M-250S

I 380b-PM-WSWMOO8c 112004 I CheclIst COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT, I ,, APPLICATION FOR NPDES PERMIT

'FOR INDUSTRIAL DISCHARGERS llAPPLICANT'Sv~CHECKLISTJV~I J M A PPI-Susquehanna,LLC'-

Please check the following list to make sure that you have included all the required Informration. Place I a checkmark in the column provided for all items'completed and/or provided.

Failure to provide all of the requested information will delay the processing of the application and may l result in the application being placed on hold with no action, or will be considered withdrawn and the applIcation file closed.

Check-If -DEP Use

- Item Included- Only

1. General Information Form (8000-PM-IT0001)

2. Three (3) copies of application package submitted 0

3. Additional copy for Erie and Allegheny counties (if required) - N/A _

T 4. Additional copy for the river basin commission (if required) N/A

5. Application Fee - $500

6 Proper evidence of Act 14 municipality and county notification

7. Proof of local newspaper public notice (for new and substantially changed N/A '

discharges only)

8. Topographic Map -

9. Industrial Wastewater - Module I ' '_-__'___-_

• rlO Wastewater Treatment Technologies - Module 2 ' ' ' i _3

_Qni irr-me rV Wn--towntar Qhinafkl - KAnrii da 4 L 12. Analysis Results Table(s) - Modules 4-9 0_3

13. Hazardous Substance Table - Module 10 0 l14. Toxic Chemicals (Optional) - Module 11 'i

[15. Stormwater (if required) - Module 12 -

16. Stormwater Sampling Data Table (if required) - Module 13 17 No Exposure Certification (if required) - Module 14 - N/A ' __. __

18. Other: Additional Outfall description, 31 6B Supporting' Info, Requested 0 -

Permit Changes. -_-'

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it-8000PM-IT0001 Rev 06/07/2002 FORM COMMONWEALTH OF PENNSYLVANIA I DEPARTMENT OF ENVIRONMENTAL PROTECTION Gep GENERAL INFORMATION FORM - AUTHORIZATION APPLICATION Before completing this General Information Form (GIF), read the step-by-step instructions provided In this application It package. This version of the General Information Form (GIF) must be completed and returned with any program-specific application being submitted to the Department.

I A

%olilII LLC I yu A Organization Name or Registered Fictitious Name Employer ID# (EIN) Dun & Bradstreet ID#

PPL Susquehanna, LLC Individual Last Name First Name 23-3022601 Ml 14-498-6556 Suffix SSN A

N/A Additional Individual Last Name N/A Mailing Address Line 1 First Name Mailing Ml Address Line 2 Suffix SSN I

769 Salem Blvd.

Address Last Line - City Berwick State PA ZIP+4 18603-0467 Country USA I1 Client Contact Last Name First Name Ml Suffix McKinney Client Contact Title VP-Nuclear Site Operations Britt T Phone 570-542-3149 Mr.

Ext A Emali Address BTMckinneyO Omiweb.cor FAX 570-542-1504 Ii i___ lto= Site Name Nrma DEP Site ID#

EPA ID#

PPL Susquehanna, LLC PAD 000765883 Estimated Number of Employees to be Present at Site 1000 Ii Description of Site Two Unit Generating Station County Name Municipality City Boro Twp State Ii Luzeme Salem Township El El E PA County Name Site Location Line 1 Municipality Site Location Line 2 City Boro nO Twp El State Ii 769 Salem Blvd.

Site Location Last Line - City Berwick State PA ZIP+4 18603-0467 I1 Detailed Written Directions to Site 5 miles North of Berwick on U.S. Route 11 Site Contact Last Name Saxton First Name Curtis Ml H

Suffix Mr.

Ii Site Contact Title Services & Programs Supervisor Mailing Address Line 1 Site Contact Firm PPL Susquehanna, LLC Mailing Address Line 2 IH 769 Salem Blvd.

Mailing Address Last Line - City Berwick Phone Ext FAX State PA ZIP+4 18603-0467 Email Address Ii (570)542-1879 (570) 542-3461 chsaxtonXpplweb.com Page I of 7 Ii Ii

8000-PM4TOO01 Rev 0610712002 I

I I NAICS Codes (Two- & Three-Digit Codes - List All That Apply) 6-Digit Code (Optional) 221 ' 221113 I ,s*:

H- a lto -&- -1 -

i OWNOP --- -- - - . .. .. .

U&

MT YLUUI EJ Eld 10 .

Modification of Existing Facility Yes No

_ 1. Will this project modify an existing facility, systern, or activity? [

2. Will this project involve an addition to an existin4'fac6lity, system, or activity? [ DE. . ai .-:

If Yes'. check all relevant facility tvoes and Drovide DEP facility identification numbers below.

DEP Fac ID1# ~-.. FacilityType I Facility Type - -

DEP Fac I5T#

I -a Air Emission Plant _ _ Industrial Minerals Mining Operation Beneficial Use (water) . i .Laboratory Location 1 0 Blasting Operation _ 0. Land Recycling Cleanup Location Captive Hazardous Waste Operation . - . . E MineDrainageTrmt/LandRecyProjLocation

-O Coal Ash Beneficial Use Operation Coal Mining Operation

_.0 D a

Municipal Waste Operation Oil & Gas Encroachment Location i O Coal Pillar Location a Oil & Gas Location Loi Commercial Hazardous Waste Operation Dam Location - . .

0 0

Oil & Gas Water Poll Control Facility

.:. ___._ Public Water Supply System .

Deep Mine Safety Operation -Anthracite - Q" RadiationFaclity Deep Mine Safety Operation -Bituminous D3 Residual Waste Operation L 0o~ Deep Mine Safety Operation -Ind Minerals i_ Storage Tank Location To Encroachment Location (water, wetland)

Erosion & Sediment Control Facility Q Water Pollution Control Facility Water Resource

! a_ Explosive Storage Location  ;

1l' Other.- -

Latitude/Longitude .- . Latitude Longitude Point of Origin -Degrees , Minutes I Seconds l Degrees I Minutes I Seconds 41 15 730- '76 I8 1 55

> Horizontal Accuracy Measure Feet 20.0 -or- Meters Horizontal Reference Datum Code -E North American Datum of 1927

• 'North American Datum of 1983 -

I Wold Geodetic System of 1984 Horizontal Collection Method Code GPSST / SURVY Reference Point Code H20PI I, Altitude - Feet 676' -- -or- Meters L Altitude Datum Name -The National Geodetic Vertical Datum of 1929

- The North'American Vertical Datum of 1988 (NAVD88)

L Altitude (Vertical) Location Datum Collection Method Code Geometric Type Code . POINT .

GPSST / SRVEY Data Collection Date 12/21/04 Source Map Scale Number 1".: - lnch(es) -- =- 24,000 Feet

-or- Centimeter s) . Meters

• A Project Name - . -..

PPL Susquehanna, LLC  : -

-ProjectDescription . . -

NPDES Permit Renewal -

Project Consultant Last Name First Name .- .. Ml Suffix N/A '

Project Consultant Title . -Consulting Firm N/A L Mailing Address Line I Mailing Address Line 2 N/A Address Last Line - City State ZIP+4 NIA LPhone Ext FAX Email Address N/A Page 2 of 7

it-8000-PM-IT0001 Rev 06/07/2002 Time Schedules Project Milestone (Optional)

1. Is this application for an authorization type on the list of authorizations El Yes 0 No affected by the land use policy?

Note: If "Yes", you must complete the following Land Use Information section, unless exempted by Questions 2 or 3 below.

If 'No", skip Questions 2 & 3 below as well as the following Land Use Information section.

For referenced list, see Appendix A attached to the GIF Instructions.

2. For an Air program authorization only. All other authorizations continue LI Yes El No with Question 3 below. Will the permit authorize the construction of facilities outside an existing permitted area?

Note: If 'Yes", you must complete the following Land Use Information section unless exempted by Question 3 below.

If 'No", skip Question 3 below as well as the following Land Use Information section.

3. Have you attached or submitted municipal and county 'Early Opt Out' LII Yes a No approval letters for the project?

Note: If "Yes" to Question 3, skip the following Land Use Information section. This should only be checked "Yes" if applicant is choosing the early opt-out option. Required approval letters described in the GIF Checklist and Instructions should be attached.

If "No" to Question 3, continue with the following Land Use Information section.

Note: Applicants are encouraged to submit copies of local land use approvals or other evidence of compliance with local comprehensive plans and zoning ordinances.

1. Is there a municipal comprehensive plan(s)? E Yes 0 No

2. Is there a county comprehensive plan(s)? El Yes a No

3. Is there a multi-municipal or multi-county comprehensive plan? El Yes El No

4. Is the proposed project consistent with these plans? If no plan(s) exists, U Yes ElI No answer aYes".

5. Is there a municipal zoning ordinance(s)? O Yes O No

6. Is there a joint municipal zoning ordinance(s)? El Yes L No

7. Will the proposed project require a zoning approval (e.g., special El Yes DL No exception, conditional approval, re-zoning, variance)? If zoning approval has already been received, attach documentation.

8. Are any zoning ordinances that are applicable to this project currently the El Yes El No subject of any type of legal proceeding?

9. Will the project be located on a site that has been or Is being remediated El Yes El No under DEP's Land Recycling Program?

10. Will the project result In reclamation of abandoned mine lands through re- E Yes El No mining or as part of DEP's Reclaim PA Program?

11. Will the project be located In an agricultural security area or an area protected under an agricultural conservation easement?

12. Will the project be located In a Keystone Opportunity Zone or Enterprise E

El Yes Yes a

L No No

-I Development Area?

13. Will the project be located in a Designated Growth Area as defined by the Municipalities Planning Code?

El Yes E] No Ii i

lI Page 3 of 7 i

8000-PM4T0001 Rev 0610712002 Note: The PA Historical and Museum Commission must be notified of proposed projects In accordance with DEP Technical Guidance Document 012-0700-001 and the accompanying Cultural Resource Notice Form.'

If the activity will be a mining project (i.e., mining of coal or Industrial minerals, coal refuse disposal and/or the operation of a coal or industrial minerals preparation/processing facility), respond to questions 1.0 through 2.5 below.

If the activity will not be a mining project, skip questions 1.0 through 2.5 and begin with question 3.0.

1.0 Isthisacoalminingproject? If 'Yes", respondto1.1-1.6. If "No", skipto El Yes Ln No Question 2.0. (DEP Use/48y1) '

1.1 Will this coal mining project Involve coal preparation/ processing Eli Yes aE No activities in which the total amount of coal prepared/processed will be.

equal to or greater than 200 tons/day? (DEP Use/4x70)'-'-

1.2 Will this coal mining project Involve coal preparation/ processing O Yes a ,No activities In which the total amount of coal prepared/processed will be greater than 50,000 tons/year? (DEP Use/4x70) 1.3 Will this coal mining project Involve coal preparation/ processing [3 Yes -i No activities In which thermal coal dryers or pneumatic coal cleaners will be used? (DEP Use/4x70) 1.4 For this coal mining project, will sewage treatment facilities be O Yes . No constructed and treated waste water discharged to surface waters?;

(DEP Use/4x62) 1.5 Will this coal mining project Involve the construction of a permanent D Yes . No Impoundment meeting one or more of the following criteria: (1) a ,

contributory drainage area exceeding 100 acres; (2) a depth of water .

measiured by the upstream toe of the da'm at maximum storage elevation exceeding 15 feet; (3) an Impounding capacity at maximum storage elevation exceeding 50 acre-feet? (DEP Use/3140) . .

-1.6 Will this coal mining project Involve underground coal mining to be U Yes Li No conducted within 500 feet of an oil or gas well? (DEP Use/4z41) 2.0 Is this a non-coal (Industrial minerals) mining project? If "Yes", respond to Li Yes Eli No 2.1-2.6. If aNo", skip to Question 3.0. (DEP Use/48y1) 2.1 Will this non-coal (Industrial minerals) mining project Involve the -i Yes El -No crushing and screening of non-coal minerals other than sand and gravel? (DEP Use/4x70) ' - -

2.2 Will this non-coal (industrial minerals) mining project Involve the L Yes L No crushing and/or screening of sand and gravel with the exception of wet sand and gravel operations (screening only) and dry sand and gravel operations with a capacity of less than 150 tons/hour of unconsolidated materials? (DEP Use/4x70) 2.3 Will this non-coal (Industrial minerals) mining project Involve the - Yes [1 No construction, operation and/or modification of a portable non-metallic (i.e., non-coal) minerals processing plant under the authority of the General Permit for Portable Non-metallic Mineral Processing Plants (I.e.,

BAQ-PGPAIGP-3)? (DEP Use/4x70) 2.4 For this non-coal (industrial minerals) mining project, will sewage - L. Yes Li No treatment facilities be constructed and treated waste water discharged to',

surface waters? (DEP Use/4x62) 2.5 Will this non-coal (Industrial minerals) mining project Involve the - Yes Li . No construction of a permanent Impoundment meeting one or more of the following criteria: (1) a contributory drainage area exceeding 100 acres; (2) a depth of water measured by the upstream toe of the dam at maximum storage elevation exceeding 15 feet; (3) an Impounding capacity at maximum storage elevation exceeding 50 acre-feet? (DEP Use/3140)

Page 4 of 7

8000-PM4TOOO0 Rev 06107/2002

-1 3.0 Will your project, activity, or authorization have anything to do with a well related to oil or gas production, site development for such activity, or the waste from such a well? If"Yes", respond to 3.1-3.3. If"No", skip to El Yes 0 No A

Question 4.0. (DEP Use/4z41) 3.1 Does the oil- or gas-related project involve any of the following: D Yes L No placement of fill, excavation within or placement of a structure, located In, along, across or projecting into a watercourse, floodway or body of water (including wetlands)? (DEP Use/4z41) 3.2 Will the oil- or gas-related project Involve discharge of Industrial L Yes O No wastewater or stormwater to a dry swale, surface water, ground water or an existing sanitary sewer system or storm water system? If"Yes", I 3.3 discuss in Project Description. (DEP Use/4z41)

Will the oil- or gas-related project involve the construction and operation El Yes aI No A

of Industrial waste treatment facilities? . (DEP Use/4z41) 4.0 Will the project Involve a construction activity that results In earth El Yes 0 No disturbance? If "Yes", specify the total disturbed acreage. (DEP Use/4x66) 4.0.1 Total Disturbed Acreage 5.0 Does the project Involve any of the following: placement of fill, El Yes 0 No excavation within or placement of a structure, located In; along, across or projecting Into a watercourse, floodway or body of water (including wetlands)? (DEP Use/4x66) 6.0 Will the project Involve discharge of Industrial wastewater or stormwater 0 Yes Ei No :-

to a dry swale, surface water, ground water or an existing sanitary sewer system or separate storm water system? If "Yes", discuss in Project I 7.0 Description. (DEP Use/4x62)

Will the project Involve the construction and operation of Industrial waste treatment facilities? (DEP Use/4x62)

Li Yes, 0 - No :l 8.0 Will the project Involve construction of sewage treatment facilities, L Yes 0 No sanitary sewers, or sewage pumping stations? If"Yes", indicate estimated proposed flow (gaVday). Also, discuss the sanitary sewer pipe sizes and the number of pumping stations/treatment facilities/name of downstream sewage II facilities in the Project Description, where applicable. (DEP Use/4x62) 9.0

- 8.0.1. Estimated Proposed Flow (galday)

Was sewage planning submitted and approved? If"Yes", attach the [I Yes 0 No ii Act 537 approval letter unless the submitted application is actually requesting Act 537 approval (Approval required prior to 105/NPDES approval). (DEP Use/4x61) 9.0.1 Is Act 537 Approval Letter attached? El Yes Li No 10.0 Is this project for the beneficial use of blosolids for land application L Yes 0 No within Pennsylvania? If "Yes" indicate how much (i.e. gallons or dry tons per year). (DEP UseI4X62) 10.0.1 10.0.2 Gallons Per Year (residential septage)

Dry Tons Per Year (blosolids)

Ii 11.0 Does the project involve construction, modification or removal of a dam? L Yes 0 No If "Yes", identify the dam. (DEP Use/3140) 11.0.1 Dam Name A

12.0 Will the project interfere with the flow from, or otherwise impact, a dam? El Yes 0 No 13.0 If "Yes", identify the dam. (DEP Use/3140) 12.0.1 Dam Name Will the project Involve operations (excluding during the construction El Yes 0 No A

period) that produce air emissions (i.e., NOX, VOC, etc.)? If "Yes", identify each type of emission followed by the amount of that emission. (DEP Use/4x70)

Ii 13.0.1 Enter all types & amounts of emissions; separate each set with semicolons. Ii Page 5 of 7 IU Ii

8000-PM4TOO01 Rev 06/0712002 14.0 Is an on-site drinking water supply (well), other than individual house - Yes . No wells, proposed for your project? If "Yes", Indicate total number of people served and/or the total number of connections served, if applicable. Also, check all proposed sub-facilities. (DEP Use/4x81) 14.0.1 Number of Persons Served 14.0.2 Number of Employee/Guests 14.0.3 Number of Connections 14.0.4 Sub-Fac: Distribution System * - Yes Li No 14.0.5 Sub-Fac: Water Treatment Plant El Yes D No 14.0.6 Sub-Fac: Source ' ' El Yes L No 14.0.7 Sub-Fac: Punip Statlon' '- -Yes EI No 14.0.8 Sub-Fac: Entry Point El Yes LI No 14.0.9 Sub-Fac: Transmission Main D Yes EI No :

14.0.10 Sub-Fac: Stoiage Facility Li Yes El No-15.0 Will your project Involve purchasing water In bulk, excluding during the .I 0 Yes No i -_.

construction period? If 'Yes, name the provider. 'Also, indicate the daily number of employees or guests served. (DEP Use/4x81) 15.0.1 Provider's Name 15.0.2 Number of Emplovees/Guests 16.0 Is your project to be served by public water supply? If "Yes", indicate El Yes a No name of supplier and attach letter from supplier stating that it will serve the project. (DEP Use/4x8l) 16.0.1 Supplier's Name 16.0.2 Letter of Approval from Supplier Is Attached E Yes 0 No 17.0 Will this project Involve a new or Increased drinking water withdrawal Cl Yes 0 No from a stream or other water body? If "Yes", provide name of stream.

(DEP Use/4x81) 17.0.1 ' Stream Name 18.0 Will the construction or operation of this project Involve treatment, 0 Yes 0 No storage, reuse, or disposal of waste? If "Yes", Indicate what type (i.e.,

hazardous, municipal (including infectious & chemotherapeutic), residual) and the amount to be treated, stored, re-used or disposed. (DEPIUse4x32) 18.0.1 Type & Amount 19.0 Will your project Involve the removal of coal, minerals, etc. as part of any Cl Yes 0 No earth disturbance activities? (DEP Use/48yl) 20.0 Does your project Involve Installation of a field constructed underground 0 Yes 0 No storage tank? If "Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570) 20.0.1 Enter all substances &

capacity of each; separate each set with semicolons.

21.0. Does your project Involve Installation of an aboveground storage tank 0 Yes 0 No greater than 21,000 gallons capacity at an existing facility? If "Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570) 21.0.1 Enter all substances &

capacity of each; separate each set with semicolons.

22.0 Does your project Involve Installation of a tank greater than 1,100 gallons Li Yes ED No which will contain a highly hazardous substance as defined In DEP's Regulated Substances List, 2570-BK-DEP2724? If "Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570) 22.0.1 Enter all substances &

capacity of each; separate each set with semicolons.

Page 6 of 7

U-8000-PM4TOOOI Rev 06/07/2002 23.0 Does your project Involve Installation of a storage tank at a new facility El Yes s No with a total AST capacity greater than 21,000 gallons? If "Yes", list each Substance & its Capacity. Note: Applicant may need a Storage Tank Site Specific Installation Permit. (DEP Use/2570)

I 23.0.1 Enter all substances,&

capacity of each; separate each set with semicolons.

CER~IFO

~Tl 1

I certify that I have the authority to submit this application on behalf of the applicant named herein and that the Information provided In this application Is true and correct to the best of my knowledge and A

Information.

Type qLPrint Name Britt UAcKinney VP - Nuclear Site Operations ,1-Il Title Date 11 Page 7 of 7 I

112004 3800-PM-WSWMOOOBb 3800-PM-WSWM0008b 112004 .-~ !' Applicant Name: PPL Susquehanna, LLC

- Application .

COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL'PROTECT1ON . . :

-2BUF 1EAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES)

- APPLICATION FOR PERMIT TO DISCHARGE INDUSTRIAL WASTEWATER . I Before completing this form, read the step-by-step Instructions provided In this application package.

Related ID#s (if Known) i F':S Client ID#- APS ID# Date Received & General Notes Site ID#, Auth ID# 7 Faclity ID#, . ;, ' ;' - - - . -

, PIC at~ll~a~llI

.: '[ -

-_ ' A,

~' _ . , , ,, ._  ; , j, ,  ; ,.I.

HUUEI^UGU= I

- - - ' "' I I I . __ . - - 1 . - I . -.

Is this an application for 'a: -- - :,

New permit . .

Complete the General Information Form (GIF) 8000-PM-1T0001 and attach to the front of the application.

0 Permit Renewal ' i

- List the current NPDES Permit number PA-0047325 Complete the Client and Site Sections of the GIF and attach to the front of the application.

0 Permit Amendment or Permit Renewal with Amendment List the current NPDES Permit number PA X ,

List the current WQM Permit number' Complete the&GIF and attach to the front of the application.

GE E ~FORATMOF

1. SIC Code . NAICS

' Code , Corresponding SIC/NAICS Description '

4911 , -, . 221113 Electric Utility Power Generation , . '

2. Is the facility required to obtain a stormwater NPDES permit for any listed SIC code? -

l0 YES (Answer question 3 below.).'0  ;;'D NO' (Skip questioni 3.)

3. Is the facility applying for permit exemption under the No Exposure rule? (See Instructions)

QYES ONO ' ' "

4. General Description and Nature of Business;.

Two Unit Nuclear Generating Station

5. List all NPDES and WQM Permits issued by DEP for this facility.

-PrPermitTyp' P.ermit Number,-- Date Issued  ;  :

NPDES Permit , , . PA 0047325 , July 7, 2000 - ,

Water Quality Permit - STP 4085411 October 7, 1985 Water Quality Permit - IND. 4076203 May 25, 1977

-1I 0 001

3800-PM-WSWM0008b Application 1/2004 Applicant Name: PPL Susquehanna, LLC L

6. ATTACH TOPOGRAPHIC MAP (See Instructions)

7. NUMBER OF OUTFALLS L

a. Industrial Wastewater Only 2 Complete Module 1 and associated Modules.

b. Combined Industrial Wastewater and Stormwater 3 Complete Module 1, associated Modules and Module 12 or Module 14 (If required).

L

c. Stormwater Only 3 Complete Module 12 or Module 14.

8. OUTFALL LOCATION: Using the same Locational Data supplied on the General Information Form under Facility L

Information, list the latitude and longitude of the location to the nearest ten-thousandth of a second and the name of the receiving water of each outfall. Where available, the receiving stream width and depth should also be provided using actual measurements or topographic map and navigational charts.

LOW FLOW OUTFALL LATITUDE LONGITUDE STREAM NUMBER RECEIVING WATER (list) Des Min Sec Deg Min Sec (Name) Width (ft) Depth (ft) 070 41 5 18.4 -76 8 34.1 Lake Took-a-While 160 3 071 41 5 12.4 -76 7 53.2 Susquehanna River 800 13 072 41 5 34.2 -76 8 42.8 Lake Took-a-While 160 3 073 41 5 33.3 -76 8 49.6 Lake Took-a-While 160 3 L 074 41 5 28.9 -76 8 49.3 Lake Took-a-While 160 3 075 41 5 40.2 -76 8 17.5 Lake Took-a-While 160 3 079 41 5 13.8 -76 7 53.4 Susquehanna River 800 10 080 41 5 33.4 -76 8 18.8 Lake Took-a-While 160 3 I

9. WHOLE EFFLUENT TOXICITY (WET) TEST RESULTS Is there known or reason to believe that WET testing was conducted in the last 3 years on any of the facility's discharges, or on a receiving water in relation to a discharge? a YES O NO I If *YES," attach any information available on the purpose and nature of such testing, and the test results.

If 'NO," all dischargers are still encouraged to perform WET testing. The DEP regional office may be contacted for appropriate protocols.

iL

10. CONTRACTED ANALYTICAL ASSISTANCE Did a contract laboratory or consulting firm perform any of the analysis required by this application?

Name El NO 3 YES (Provide information below.)

Analytical Laboratory Services Types of Analysis Performed: il 34 Dogwood Lane All Physical Chemical BOD, COD, TSS, O&C, TOC, pH, Address Middletown, PA 17057 Metals, Volatiles, Organic Compounds, Acid Compounds, Base Compounds, Nitrates, Ammonia, Priority Pollutants, and PCB's.

IL Phone Name (717) 944-5541 Teledyne Brown Engineering Types of Analysis Performed:

IL 2508 Quality Lane Radiological Analysis Gross Alpha, Gross Beta Address Knoxville, TN 37931 I Phone (865) 690-6819.

002 1I Ii

I L 3800-PM-WSWM0008b 1)2004 Applicant Name: PPL Susquehanna, LLC Application

11. ADDITIONAL INFORMATION: (OPTIONAL)'

Additional Information may be attached to expand upon any' response to any questions or call attention to any other Information felt should be considered in establishing permit limitations for the proposed or existing facility.

Check if additional sheets are attached.

'YES DNO Is the facility owner or operator in violation of any DEP regulation, permit, order or schedule []YE4'-3 of compliance at this or any other facility? .  ;' 'N If "YES," list each permit, order and schedule of compliance and provide compliance status. :Use additional sheets to provide Information on all permits. '

Permit Program -- . Permit No.

Brief Description of Noncompliance ,,

Steps Taken to Achieve Complia'nc' - .' Date(s) Comnpliance Achieved . '-:

I I. ~- I . ~

_ - - . - 1. . _.

- - .I

,ian' e S u . _. I _I In C mp.i , In Noncomliance Current ComplVliance Status -' '.  ! '~' < -§ InCo'mpliance'- -' '

I. El in Noncompliance, -I. - "-

M I 1 h L I certify under penalty of law that this document and all attachmientswere prepared under my direction or supervision in accordance with a system designed to -assure that qualified personnel properly gathered and evaluated the information' submitted. Based on my Inquiry of the person or persons who manage the system, 'or those 'persons -

directly responsible for gathering the Information, the information submitted Is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submritting'false Information; Including the possibility of fine and imprisonment for knowing violations'.

Britt T. McKinney ,-.  : V.P. - Nuclearl-te Operations Na me I * - Official Ilue L Signature - Date (Use corporateorprofessionalsealas appropriate.)

L Taken, swom, and subscribed before me, this ' -i dayof 2 NotarySeal: --- -J. 7J I~JUL 1-4~

I

__Ir VN I t Notarial Seal Laurie Minto, Notary Public Salem Twp.. Luzerne County My Commission Expires July 24. 2006 Member, Pennsylvania AssociationolNotaries 003

__ _ 1

-, PWS 24C~I ~6&T1ALL OrDj~ai

~PROPERM&C~tI

~~~ 1 IIII LA~TrUDE '41G04Wo41O06#OQ evqI~

LoNGfTUDE 761VI5't76*01~15-FIGURE 4-1 Topographic Map SSES 004

I I

I I 1

iI i

FIGURE 4-2 k-1a2 i MIE *..;-,

0 Springs Used for Water SupplyWithin 1 Mile of SSES 005

111 13L 1711 LIL 2I lI1 LATITUDE 41' 05' 30" 55"-i3

. I LONGITUDE 76' 08' RDT456 / an .

TOWNSHIP 01 4 (i l/}

\ ffi l TOWNSHIP 5 136 RD T450 0 13

• NOTE:

NUMBERS NDICATE APPROXIMATE LOCATION OF WELLS FIGURE 4-3 i

1 MILE 0

12 Water Wells Within 1 Mile of SSES 3

006 If

Line Drawing Per Module 1 of NPDES Permit Application

Susuehanna River.

i MGD I TV Sample J) Chemical Addition I ..

Jnte Yata averaged over years 2002, 2003, 2004 were used to determine river water withdrawal, Consumptive use, and blowdown back to the river.

007

- iI-3800-PM-WSWM0008d 1/2004 Applicant Name: PPL Susquehanna, LLC Module 1 COMMONWEALTH OF PENNSYLVANIA I

!MLPl DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT li INDUSTRIAL WASTEWATER MODULE 1 l Before completing this form, read the step-by-step instructions provided in Appendix 1.

I PPL Susauehanna. LLC

1. Line Drawing. Attach a line drawing and water balance of flow through the facility. (See instructions) 11

2. OUTFALLS AND ASSOCIATED WASTEWATER TREATMENT TECHNOLOGIES Complete Module 2 identifying the treatment processes associated with each outfall.

3. SOURCES OF WASTEWATER A

Attach a separate Module 3 for every outfatl.

Indicate the number of Module 3s attached. 8 Il

4. REQUIRED AND OPTIONAL ANALYSIS

a. Summary of Required Analysis -1

. . Pollutants or Pollutant Required Disch Contains (see t Groups which must be Number of Outfall Process Sanitary Misc. GW sampled for and Sample Events Number Waste NCCW Waste Waste Cleanup Stormwater analyzed (see instructions) 070 075 080 071 0

0 E

[

F E

Oa El El El 0

El Module 13.

1,2,3,4,5,& PCBs 1

3

..l El El El 072 073, 074 El El El El 0 E El Selected Group 1 Selected Group 1 1

1 11 079 El El 01 E El Group 1 1 River Intake El El El El El El 1,2,3,4,5, & PCBs

b. Complete the modules for the Pollutant(s) or Pollutant Group(s) identified above. A separate module must be 3 (Optional) .1 submitted for each process wastewater and combined (process wastewater and stormwater) outfall identified in the application. List the number of modules for each Pollutant Group submitted with this application.

5 Module 4 - Pollutant Group 1 1

2 Module 5 - Pollutant Group 2 - Metals 2 Module 6 - Pollutant Group 3 - Volatile 2 Module 7 - Pollutant Group 4 - Acids 2 Module 8 - Pollutant Group 5 - Base/Neutral I

-9 - Mnhiln Q - PnIhiitnnt lrni in A - Pa~tirn;iHP /Pr.RC nnlvl I_

008 L

I

3800-PM-WSWM0008d 1/2004 Applicant Name: PPL Susquehanna, LLC Module I

c. Optional Site-Specific Data Additional modules may be attached to provide any 'of the optional site-specific information discussed in Appendbx 2. (The modules should be used to report Intake water quality, upstream background or ambient water quality, and parameter-specific coefficient of effluent variability. Space is provided at the top of the module to provide description of sampling points used.)i Optional data is'attached to application. 0 YES E NO

5. PREPAREDNESS, PREVENTION, AND CONTINGENCY (PPC) PLANNING.

Does the facility have a PPC plan?

O YES . DNO Does the facility have any other related plans, such as a Pollution Incident Prevention (PIP) Plan, Spill Prevention Control and Counter Measure (SPCC) Plan or BMP Plan?

- YES Y- NO-If OVF( I iricntifv and indicatA datehs) imnIcmented Type of Plan Date Implemented PPC Plan Note: Two (2) copies provided w/App.ication 11/19/2004 (Updated)

SPCC Plan Note: Two (2) copies provided w/Application .11/1912004 (Updated)

DEP may require the plan(s) be submitted with this application.

I 6. OTHER INFORMATION (OPTIONAL): Attach additional sheets describing any additional environmental pollution control programs which may affect the discharges which are'underway or which are planned. Indicate whether each program is now underway or planned, and indicate the actual or planned schedules.

El MARK "X" IF DESCRIPTION OF ADDITIONAL INFORMATION IS ATTACHED 009

3800-PM-WSWM0008d 1/2004 Module 1 Applicant Name: PPL Susquehanna, LLC

7. INFORMATION AND ANALYSIS OF EFFLUENT QUALITY FOR OTHER POTENTIALLY TOXIC POLLUTANTS

a. Information on Chemical Additives NOTE(l) Equivalent Chemicals may be purchased from other suppliers.

(See Notes 1 - 8 attached)

(Read Instructions carefully and use the tabular format to present the required Information)

Chemical Substance or Concentration Lowest Possible Whole Product Whole Product-Average & Maximum Analytical Compound Trade Names or Manufacturer Usage Rate 96 Hr LC50 48 Hr LC5o Outfall Specific Ingredients Name and Address lbs/day Detection (mg/L) and (mg/L) and In-system Effluent Units Level (pg[L)

Acrylic Acid Suitfonated specles"I speclest11 Nalco Company 1601 W. Avg. 950 071 Acrylic Acid Copolymer Diehl Rd. Naperville, IL Max 2,000 Dispersant, 32.125 PCL-401 2,400 2,400 IgJ/ 1,500 Rainbow Trout Daphnia Magna 60563-1189 (180,000 ibslyr) (4,900 mg/) (2,800 mg/i)

Hydroxy ethylidene Avg. 750 071 disphosponic acid (HEDP, Max 1,500 32.127 PCL-57 4,000 4,000 8gIRainbow Trout Daphnla Magna (90, lbsr) mg) (527 mg/)

Solution of Quatemary Alkyl Avg. 800 071 Amonium Compound Max 2,000 01 Moliuscide and General 10,600 100 100 gg l(0.32-0.59 mgi) Daphnia Magna Biocide, 32.126 H-130 (160,000 ibslyr) 03059m ) (094g) 071 01H-940Sodium Bromide, 32.114 Avg. 1,000 500 1

Max 3,300 3,300 .gRainbow (0.23 mg/1)Trout Daphnia Magna

'"125 07rng1 Magnesium Nitrate and 5- Betz Dearborn Inc.RanoTru

__________ __________N ote (2) ( . 1 mgl 071/072/079 Chioro2-rmethyi-4* l 4636 Somerton Rd. DphlMga isothiazolin-1, 32.53 Trevose, PA 19057 See Note 3 X a.7 m )ut

~NX -1 106 (2.aphn9 a Mag/ a 87mA(29MA 071/072/079 Glutaraldehyde 40%-70%, Nalco Company See Note 4 32.70 H-550 1601eW.viei Rd. See5Note498 Flathead Minnow Daphnia Magna (12mg/I) (12 mg/i)

Propietay Dscalng Aent Betz Dearborn Inc.

071 Betz 860 4636 Somerton Rd. See Note 5 _ - -

Betz 860Trevose, PA 19057 -

Nalco Company 1601 W. Avg - 2,000 071 Bentonite Clay Slurry, 32.128 Diehl Rd. Naperville, IL Max- 8,000 0 330,000 Pg 100 .

60563-1189 (350,000 lbs/yr) .

Manley-Regan Chemicals Avg - 5,000 071/079 Sodium Hypochlorite, 15%, Ceriodaphnia 32.63 532 East Emaus St. 33,000 33,000 PO Box 28 Max- 10,000 pg/I 400 Dubla

____ _____ ____ ____ ____ M iddletown, PA 17057 M x- 1 , 0 (1.23 mg/g)

AgroEvo Environmental 071 Rotenone, 32.15 Health See 95 Chestnut Ridge Rd. See Note 6 -o- -

Montvale, NJ 07645 071 01Fluridone, 32.46 3SePro 11550 N. Meridian See Note 6 --

0 I-A 0

L . 1 =_ =_ I , _ _ 6 _ __ _ i _ Iii

I-- F-3800-PM-WSWM0008d I- i-- I I- i-- r - i- F- r-- F -- r-- I - F - [---- I--- I7 --

1/2004 Applicant Name: PPL Susquehanna, LLC Module 1 Allied Corp.Av-18 0711079 Sodium BisulfTle, 32.113 Chemical Sector Av Chlorkill 8816 PO Box 1139R 130 500 125 Mosquito Fish Max - 400 Mosquito Fish Morristown, NJ 07960 (240 mg/I) (240 mg/I)

Allied Corp. Apo.4500 071 Sulfuric Acid, 32.57 P0 Box 2064R (Appr.435,000 Morristown, NJ 079609 . . .

2-(Tert-butyiamlno)-4-Chloro- FMC Corp.

071 6-(Elthylalno)sTzne At75 MarketSo RanbworotcesslMan (13,800 lbsTwe 67,000 2,200 _

Terbuthylazine (AlgIcIde) 175Mrept er (3.8 mg/I) (39 mg/I)

___________________ hiladelohla, PA 19103 2-phosphono-1,2,4- Bayer Corp. Product 071 butanetricarboxylic acid R aqueous solution (corrosion Safety & Reg. Affairs (864 lbs. Four 4000 131 100 Bayer Road . times a year) . . (,Ra0nbow Trout Iinhibitor) Pittsburgh, PA 15205-9741 Betz Dearborn Inc. Avg. - 96 lbs/day 071 Depositrol PY5206 4636 Somerton Rd. Fathead Minnow Daphnia Magna 32,000 1.140 1pg/ 12,000 (1.680 mg/I)

- Trevose, PA 19057 Max- 385 lbs/day (1.635 mgA) 071 .

Aquashade, 32.135 Applied Blochemists See Note 6 5,000 mg/I 5 ug/A 100 071/0721079 Miscellaneous Various See Note 7 - -

(1) If LC50 Data for whole product is not available, data for the individual active ingredients may be provided.

. I. - .. I- . .

0 I"a , .

3800-PM-WSWMo008d 112004 Applicant Name: PPL Susquehanna, LLC Module 1

b. Specific Substances which must be identified if Known or ExDected to be Present (Read Instructions carefully and use the tabular format and additional pages, where necessary, to present the required Information)

Average Effluent Analytical Outfall Chemical Substance or Compound Concentration Detection Level Reason for Presence in Discharge (pg/L) (pg/L)

c. Are any Table 2substances identified for which aspill reporting exemption is requested?

0YES JNO If "YES," complete the Hazardous Substance Table.

d. Any other toxic chemicals known or expected to be present in th~4q1g.,,

NONE Report any additional significant detections in effluent samples on the Other Toxic Chemicals sheets.

0 I--

N 1,I 6 - ==  := ~ - === ~ = = = ~ == ~ == ~ == ~ _~I-

~ =

MODULE I, Item 7. Section a. Continued

-' .N Note (1) Equivalent chemicals from other suppliers may be purchased.. Product concentrations may change; however, the concentration of active ingredients discharged should remain about the same'. -Approval numbers are included for those chemicals listed in the Susquehanna Approved Materials Manual.

Other chemicals will be approved prior to their use onsite.

Note (2) Toxicity of hypobromous acid is expressed as bromine.

Note (3) Approximately 25 gallons/year of this biocide is injected into the close~d system cooling water to a maximum average concentration of 330 mg/i of product or 5.0 mg/l as active isothiazolin. Occasionally these systems are drained to the Cooling Tower basin. This product would not beexpected to be detected in the Cooling Tower blowdown. -

Note (4) Glutaraldehyde is added to closed cooling water systems to maintain microbiological control. A maximum concentration of 300 mg/l active or 600; mg/l product is used. Occasionallysthese systems are drained to the Cooling-Tower blowdown. This product would not be expected to be detected in the' :.

Cooling Tower blowdown. -

Note (5) The Cooling Tower blowdown is isolated when this descaling agent is used ir:

Circulating Water System (4,000 galtreatment). Treatment has been very infrequent.

Note (6) Rotenone and Fluridone are products used in the EmergencySpray Pond that-has been permitted for use by the Pa Fish and Boat Commission and the PaDEP. The Emergency Spray Pond is treated when needed with 1,000 lbs.

of Rotenone to a level of 5,mg/l; however, it is detoxified with potassium permanganate at a rate equal to this concentration prior to discharge and, therefore, is not expected tobe present in Outfall 071. Also, 32.lbs. of. -

Fluridone will be applied as necessary to an area of 8/10 surface acre along the pond's edge. Aquashade is used around the perimeter of the pond periodically in the summer to control algae growth.

013

II

-1 Note (7) Miscellaneous chemicals used in very small quantities for cleaning surfaces, cooling coils, decontamination of floors, walls, and equipment, cleaning 11 agents, liquid dye for flow tests, laboratory reagents and standards, etc. The following are some of these chemicals:

Al Chemical/SAMM i Est. gal/Vr.

Power Coil, A-10.29 a .I Coil Rite, C-10.384 a Acti-Klean, C-10.326 By-Pas, E-10.11 a

220 A Organic Orange, E-1 0.35 110 Citirikleen, E-10.29 MSANCleaner/Sanitizer II, E-10.8 a

288, b Il Rhodamine WT Dye, 32.68 a Spartan SD-20, C-10.167 Touch It Up, E-10.4 a

a II 601-Nami-Lo, C-10.74 a Powerline PPL10, 32.90 Cobratec TT-50-S, 32.87 50 a.

.. I Yellow/Green liquid dye, 32.42 a .,

Clarifloc C-9490 polymer, 32.109 10-15, c f ".' . -

Nalco 9905, 32.81 220, c Ethylene Glycol mixture, 16.20 Iron Oxalate, 32.129 Polyfloc CP1 160, 32.130 z00 ibs./yr.

20 lbsiyr.

l Polyfloc AP1 100, 32.131 20 lbs./yr. . t

.A Propylene Glycol Mixture, 16.36 a, d EPA 2000 WCI-1 40, B-1 0.27 a Trisodium Phosphate, A-20.24 a Sodium Hydroxide, 32.59 Sodium Nitrite, 32.14 500 200 lblyr I1 Nitric Acid, 38.89 5 Borax, 32.62 Boric Acid, 32.61 15 10 II Kev

a. Not available

-I

b. Ounces

c. Flocculent aid used infrequently for dewatering sludge

d. Present in equipment onsite and has potential for entering storm drains.

i Preventative maintenance and analysis of replacement chemicals such as Propylene Glycol will minimize any adverse impacts to the environment.

Some of these chemicals may be discharged to the Cooling Tower Basins/

Blowdown, Sewage Treatment Plant, or storm drains in accordance with their Material Ii Safety Data Sheet recommendations.

014 Ii I

S5AIIIM 32.12-5

.a MATERIAL SAFETY DATA SHEET I ... ...

PRODUCT -

o NALCO PCL-401

.. .I-,; EMERGENCY-TELEPHONE NUMBER(S)

-(800) 424-9300 (24 Hours) CHEMTREC l1. lCHEMICAL PRODUCT AND COMPANY IDENTIFICATION .

PRODUCT NAME: PCL-401 APPLICATION: WATER TREATMENT COMPANY IDENTIFICATION: . Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S):' (800) 424-9300 (24 Hours) 'CHEMTREC NFPA 704MIHMIS RATING HEALTH: 0/1 FLAMMABILITY: 1/1 INSTABILITY: 0/0 OTHER:

0 = Insignificant 1 = Slight 2 = Moderate 3 = High' 4 = Extreme -

12. l.COMPOSITION/INFORMATION ON INGREDIENTS, . ,..

Based on our hazard evaluation, none of the substances In this product are hazardous.

3. l HAZARDS IDENTIFICATION

• EMERGENCY OVERVIEW"*

CAUTION May cause irritation with prolonged contact Do not get In eyes, on skin, on clothing.' Do not take Internally.i; Use with adequate ventilation." In case of contact with eyes, rinse Immediately with plenty of water and seek medical advice. After contact with skin, wash Immediately with plenty of water. - .. .. - -

Wear suitable protective clothing.

May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (N Ox) and sulfur (SOx) under fire conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin ' .- '

HUMAN HEALTH HAZARDS - ACUTE:

EYECONTACT: - - ., -: .P - ` -  :;

May cause irritation with prolonged contact SKIN CONTACT:

May cause irritation with prolonged contactL*. . '

INGESTION:

Not a likely route of exposure. No adverse effects expected.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000 1/9 i

.t0, 015

-ii MATERIAL SAFETY DATA SHEET PRODUCT IL 0tNALCO PCL-401 II EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC Ii INHALATION:

Not a likely route of exposure. No adverse effects expected.

SYMPTOMS OF EXPOSURE:

Il Acute:

A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic:

A review of available data does not identify any symptoms from exposure not previously mentioned.

Il AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

11

4. FIRST AID MEASURES I1 EYE CONTACT:

Flush affected area with water. If symptoms develop, seek medical advice SKIN CONTACT:

I1 Flush affected area with water. If symptoms develop, seek medical advice.

INGESTION:

Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If symptoms 11 develop, seek medical advice.

INHALATION:

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

Ii NOTE TO PHYSICIAN:

Based on the individual reactions of the patent, the physician's judgement should be used to control symptoms and I'

clinical condition.

5. l FIRE FIGHTING MEASURES l I' FLASH POINT:

EXTINGUISHING MEDIA:

None A

This product would not be expected to bum unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

Ii May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) and sulfur (SOx) under fire conditions.

Ii SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 IU (630)305-1000 016 -I 1

. MATMPLAI QACITV flATA QBJ=T PRODUCT - - -

It NALCO PCL-401i '

i EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC. .. .

6. - ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Do not touch spilled material. Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure ControlslPersonal Protection). Stop or reduce any leaks If It is safe to do so. Ventilate spill area If possible. - - -;

METHODS FOR CLEANING UP: . , ;,

SMALL SPILLS: Soak up spill with absorbent material. Place residues Ina suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste' hauler-for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

Do not contaminate surface water.

7. HANDLING AND STORAGE HANDLING:

Avoid eye and skin contact Do not take Intemally. Ensure all containers are labelled. Keep the containers closed when not In use. -- - .

STORAGE CONDITIONS:

Store the containers tightly closed.

SUITABLE CONSTRUCTION MATERIAL:

PVC, Buna-N, HDPE (high density polyethylene), Polyurethane, Polypropylene, Polyethylene, Stainless Steel 304, -

Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to'use.

UNSUITABLE CONSTRUCTION MATERIAL:

Brass, Hypalon, Viton, Neoprene, EPDM '  ; .

8. EXPOSURE CONTROLS/PERSONAL PROTECTION . ,

OCCUPATIONAL EXPOSURE LIMITS:

This product does not contain any substance that has an established exposure limit.  ;

ENGINEERING MEASURES:

General ventilation Is recommended.

RESPIRATORY PROTECTION:

Respiratory protection Is not normally needed. ,.. ., .;. , . .

HAND PROTECTION:.-.

• r Neoprene gloves, Nitrile gloves, Butyl gloves, PVC gloves. ... .' .

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305.1000 d.?'4+t,;

,319 017

MATERIAL SAFETY DATA SHEET PRODUCT JI

)NALCO PCL-401 Ii EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC SKIN PROTECTION:

Wear standard protective clothing.

EYE PROTECTION:

Ii Wear chemical splash goggles. Wear chemical splash goggles.

HYGIENE RECOMMENDATIONS:

Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing Il and thoroughly wash the affected area. Launder contaminated clothing before reuse.

9. l PHYSICAL AND CHEMICAL PROPERTIES Il PHYSICAL STATE APPEARANCE Liquid Light yellow I1 ODOR None Il SPECIFIC GRAVITY 1.16- 1.20 SOLUBILITY IN WATER pH 0 VISCOSITY Complete 4.2-5.0 20 -160 cps Ii FREEZING POINT 25 F /

VAPOR PRESSURE VOC CONTENT Same as water 0.00 % EPA Method 24 Ii Note: These physical properties are typical values for this product and are subject to change.

10. I STABILITY AND REACTIVITY 1

STABILITY:

Stable under normal conditions. I' HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur. .1 CONDITIONS TO AVOID:

Freezing temperatures.

MATERIALS TO AVOID:

Ii Strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS:

Under fire conditions: Oxides of carbon, Oxides of nitrogen, Oxides of sulfur I'

11. I TOXICOLOGICAL INFORMATION JI The following results are for the product

• 11 l

m a v 1Z 1 Mi-l1:71

%dCUwityallyIOU a VV. ulten1 i S-- am fi; muau - 1,4p"erville, 111115 vauj-d n -~~s Iwnolo I

-. ; F 1. , A

') .. '. 0 i. )

(630)305-1000 4/9 018 1

Ii

MATERIAL-SAFETY DATA SHEET PRODUCT-

^NALCO PCL-401 EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) CHEMTREC . *.-

ACUTE ORAL TOXICITY:

Species LD50 Test Descriptor

Rat 5 g/kg Product Rating: Non-Hazardous ACUTE DERMAL TOXICITY:

Species LD50 Test Descriptor Rabbit - 2 g/kg, Product; - -

I I Rating: Non-Hazardous ,

SENSITIZATION: : - A_

This product is not expected to be a sensitizer.-

CARCINOGENICITY:

None'-of thesubstances in this product are listed as carcinogens by the Intemational Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference'of Governmental Industrial Hygienists (ACGIH).  ;

I 112. l ECOLOGICAL INFORMATION -

ECOTOXICOLOGICAL EFFECTS:

The following results are for the product.  : - -  ;

ACUTE FISH RESULTS:

Species Exposure LC50 Test Descriptor Rainbow Trout 196 hrs 4,900 mg/l Product Bluegill Sunfish - 96 hrs - > 5,000 mg/l Product Rating: Essentially non-toxic .

ACUTE INVERTEBRATE RESULTS: "

Species I Exposure LC50 EC50 Test Descriptor Daphnia magna 1 48hrs - 2,800 mg/l - Product Rating: Essentially non-toxic MOBILITY:

The environmnental fate Was estimated using a level Ill figacity iodel embedded in the EPI (estirmation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level IlIl model does not require equilibrium between the defined media. The information provided Is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material Is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; 1

Air

<5% + Water 30-50% -I Soil/Sediment 50- 70%

The portion in water is expected to be soluble or dispersible.

Nalco Company 1601 W. Diehl Road . Naperville, Illinois 60563-1198 (630)305-1000 5/9 x . ,, - *C

. I:f,10p i i, 019

__ I

• NALCO MATERIAL SAFETY DATA SHEET PRODUCT I' PCL-401 II EMERGENCY TELEPHONE NUMBER(S)

(800) 424.9300 (24 Hours) CHEMTREC I

BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate. A If released into the environment, see CERCLNSUPERFUND in Section 15.

13. l DISPOSAL CONSIDERATIONS Ii If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.

As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, Il disposal or recycling facility. I

14. l TRANSPORT INFORMATION I Il The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name I Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING I1 TRANSPORTATION MARINE TRANSPORT (IMDGAMO): Ii Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION I 115. @REGULATORY INFORMATION I NATIONAL REGULATIONS, USA:

A OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, none of the substances in this product are hazardous. ii CERCLAISUPERFUND, 40 CFR 117, 302:

Notification of spills of this product is not required.

II Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 Ii

• ( ;020 (630)305-1000 619 Ii

MATERIAL SAFETY DATA SHEET A ALC

~NALCO PRODUCT PCL-401 EMERGENCY TELEPHONE NUMBER(S)

(800) 424.9300 (24 Hours) CHEMTREC SARNtSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 '(TITLE l1l) - SECTIONS 302,311, 312, AND 313: '

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):,

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation'has found that this product Is not hazardous under 29 CFR 1910.1200.

Under SARA 311 and 312, the EPA has established threshold quantifies for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever Is lower, for extremely hazardous substances and 10.000 pounds for all other hazardous chemicals.

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the Ust of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):. -.

The substances in this preparation are Included on or exempted from the TSCA 8(b). Inventory (40 CFR 710)

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 formerly Sec. 307,40 CFR 116.4 /formerlySec. 311: -  : -  :.

None of the substances are specifically listed In the regulation.

CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volable Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and 11Ozone Depleting Substances):

None of the substances are specifically listed In the regulation.

CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under Califomia Proposition 65.

MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed in the regulation.

STATE RIGHT TO KNOW LAWS: -:.,

None of the substances are specifically listed In the regulation.

NATIONAL REGULATIONS, CANADA: -^

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS): ,.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the Information required by the CPR.

WHMIS CLASSIFICATION:,--.:;--:

Not considered a WHMIS controlled product.

Nalco Company 1601 W. Diehl Road ,-Naperville, Illinois 60563-1198 i~ j-9 (630)305-1000 -

7/9021

~NALC MATERIAL SAFETY DATA SHEET

)4"NALCO PRODUCTl PCL-401l EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.

INTERNATIONAL CHEMICAL CONTROL LAWS AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme II (NICNAS) and are listed on the Australian Inventory of Chemical Substances (AICS).

EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.

THE PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine 11 Inventory of Chemicals & Chemical Substances (PICCS).

16. OTHER INFORMATION 11 This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be Informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. A REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (AMel Insight# CD-ROM Version), AMel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight# CD-ROM Version), Adel Research Corp., Bethesda, MD.

Registry-of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 8/9 022 l

. .M.- .MATERIAL SAFETY AFE. DT DATA S SHEET I PRODUCT

^NALCO PCL-401 -

I

.. EMERGENCY-TELEPHONE NUMBER(S)

(800) 424.9300 (24 Hours) CHEMTREC AMel Insight# (An Integrated guide to Industrial chemlcals covered under major regulatory and advisory programs),

NorthrAmerican Module, Westem European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Adel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),'

Micromedex, Inc., Englewood, CO.

Prepared By: Product Safety Department Date issued: 02126/2004 Version Number: 1.4

.I "l .'

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1 000 9/9 023

-- 5A1"1- . .. IYZ7 MATERIAL SAFETY DATA SHEET PRODUCT IL 0tNALCO PCL-57 IL EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCTNAME: PCL-57 APPLICATION: SCALE INHIBITOR COMPANY IDENTIFICATION: Nalco Energy Services, L.P.

.1 P.O. Box 87 Sugar Land, Texas 77487-0087 .1 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH: 2/3 FLAMMABILITY: 111 INSTABILITY: 0/0 OTHER:

Il 0 = Insignificant I = Slight 2 = Moderate 3 = High 4 = Extreme

2. l COMPOSITIONIINFORMATION ON INGREDIENTS A

Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s). I Phosphonic Acid Hazatdous Substance(s)

Hydroxyethylidenediphosphonic Acid CAS NO 2809-21-4 13598-36-2

% (wlw) 60.0- 100.0 1.0- 5.0 Il

3. l HAZARDS IDENTIFICATION I I

'EMERGENCY OVERVIEW**

DANGER A Corrosive. May cause tissue damage.

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash I

immediately with plenty of water.

Wear a face shield. Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.

Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

D EYE CONTACT:

Corrosive. Will cause eye bums and permanent tissue damage. D Nalco Energy Services, L.P. P.O. Box 87

• Sugar Land, Texas 77487-0087 I

4.

.*s-(281)263-7000 1/11 024 I

I

O

~~~~~-

JC , . :l

.MATERIAL SAFETY DATA SHEET PRODUCT.

PCL 578 -!

EMERGENCYTELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

,~~~~~~~~~ . X ;--- -, _ *---**;*-

SKIN CONTACT: . . . .... ' . . - ... -

May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. -. ' - - '

INGESTION:

Not a likely route of exposure. Corrosive; causes chemical bums to the mouth, throat and stomach.

INHALATION:

Not a likely route of exposure. Irritating, in high concentrations, to the eyes, nose, throat and lungs. - -

SYMPTOMS OF EXPOSURE:

Acute: 4' " "

A review of available data does not Identify any symptoms from exposure not previously mentioned.'

Chronic:

Hydroxyethyienediphosphonic Acid (HEDP) has been reported to alter the development of the bone density by affecting bone mineralization and calcium and phosphate metabolism In animal studies'.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data'does not identify any worsening of existing conditions. -

HUMAN HEALTH HAZARDS - CHRONIC:, ' ' ' .

None of the substances Inthis product are listed as carcinogens by the Intemrational Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). ., * .

No adverse effects expected other than those mentioned above.  ;

14. -FIRST AID MEASURES - - -

EYE CONTACT:

PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get immediate medical attention.

SKIN CONTACT:

Immediately flush with plenty of water for at least 15 minutes. For a large splash,' flood body under a shower.

Remove contaminated clothing. Wash off affected area Immediately with plenty of water. Get Immediate medical attention. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.

INGESTION:

DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. Get Immediate medical attention.

INHALATION:

Remove to fresh air, treat symptomatically. Get medical attention. - - ,,

NOTE TO PHYSICIAN:

Probable mucosal damage may contraindicate the use of gastric lavage. Based on the Individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

Nalco Energy Services, LP. P.O. Box 87

• Sugar Land, Texas 77487-0087 (281)263-7000t.

2 11 C.27 jf  ; 025

MATERIAL SAFETY DATA SHEET PRODUCT 04NALCO PCL-57 IL EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC 11

5. l FIRE FIGHTING MEASURES I IL FLASH POINT: > 200 0F /> 93 -C (TCC) .I EXTINGUISHING MEDIA:

Not expected to bum. Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas: May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions. At SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. l ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by III trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to.do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, property labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). I 11 ENVIRONMENTAL PRECAUTIONS:

Do not contaminate surface water.

A

7. l HANDLING AND STORAGE I HANDLING: ii Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.

I STORAGE CONDITIONS:

Store the containers tightly closed. Store in suitable labelled containers. Store separately from bases.

Ii UNSUITABLE CONSTRUCTION MATERIAL:

Product is corrosive to aluminum. Aluminum should not be used for feed, storage, or transportation systems. Ii Ii Nalco Energy Services, L.P. P.O. Box 87

• Sugar Land, Texas 77487-0087 (281)263-7000 3 /1 011 A

026 Ii

-  ; -MATERIAL SAFETY DATA SHEET

, NALC n PRODUCT PCL-57"

, . 7

.EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) - CHEMTREC

18. l EXPOSURE CONTROLS/PERSONAL PROTECTION

. . . I .. I.-

OCCUPATIONAL EXPOSURE LIMITS: .- --

This product does not contain any substance that has an established exposure limit ENGINEERING MEASURES:

General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor._.,

RESPIRATORY PROTECTION:

If significant mists, vapors or aerosols are generated an approved respirator is recommended. An organic vapor/acid gas cartridge with dust/mist prefilter may be used. In event of emergency or planned entry Into unknown  :

concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, Institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. Respiratory protection Is not normally needed. If significant mists, vapors or aerosols are generated an approved respirator is recommended. .

HAND PROTECTION: .  : .  ;

Neoprene gloves, PVC gloves, Butyl gloves SKIN PROTECTION:

Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure Is possible.

EYE PROTECTION:- - .

Wear a face shield with chemical splash goggles. . -  :  ;

HYGIENE RECOMMENDATIONS: .

Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Lquid APPEARANCE Clear Ught yellow - .I ODOR None SPECIFIC GRAVITY 1.41 - 1.47 @ 77 eF /25 eC DENSITY 11.7 - 12.2 lb/gal SOLUBILITY IN WATER Complete pH (1 %) <2 VISCOSITY 40 cps @ 77 TF I 25 'C FREEZING POINT -13 eF / -25 *C BOILING POINT 226 F/ 108 -C VAPOR PRESSURE Same as water EVAPORATION RATE Same as water Nalco Energy Services, LP. P.O. Box 87 Sugar Land, Texas 77487-0087 (281)263-7000,

e.., lu 0i}4/11 027

MATERIAL SAFETY DATA SHEET PRODUCT Il AWNALCO PCL-57 A

EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC ii Note: These physical properties are typical values for this product and are subject to change.

10. ISTABILITY AND REACTIVITY I1 STABILITY:

Stable under normal conditions. II HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

I1 Freezing temperatures.

Avoid temperatures greater than MATERIALS TO AVOID:

392 *F 11 Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors. Contact with reactive metals (e.g. aluminum) may result in the generation of flammable

-i hydrogen gas. Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS:

Ii Under fire conditions: . Oxides of carbon, Oxides of phosphorus I ll. I TOXICOLOGICAL INFORMATION I Ii The following results are for the product ACUTE ORAL TOXICITY:

ii Species LD50 Test Descriptor Rat 2,400 mg/kg Rating: Non-Hazardous Product Ii ACUTE DERMAL TOXICITY:

Species Rabbit LD50

> 7,940 mg/kg Test Descriptor Product 11 Rating: Non-Hazardous PRIMARY SKIN IRRITATION:

Draize Score Test Descriptor

.1 0.0 /8.0 Product Rating: Practically non-irritating PRIMARY EYE IRRITATION:

Draize Score 39 1110.0 Rating: Moderately irritating Test Descriptor I

Nalco Energy Services, LP. P.O. Box 87

• Sugar Land, Texas 77487-0087 Ii (281)263-7000 5111 028 A A

TNALCO M

IPRODUCT MATERIAL SAFETY DATA SHEET PCL-57-'

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __._. I

-. r ..... EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) .CHEMTREC . *-.- --

SENSmZATION: . -  : ,.:

This product Is not expected to be a sensitizer.

CARCINOGENICITY:

None of the substances Inthis product are listed as carcinogens by the Intern atonal Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). ' * '

HUMAN HAZARD CHARACTERIZATION: .

Based on our hazard characterization, the potential human hazard is: High - .

12. l ECOLOGICAL INFORMATION  :; - . - , -

ECOTOXICOLOGICAL EFFECTS: . x - , , l The following results are for the product.. ^ - . .* .. -

ACUTE FISH RESULTS:

Species Exposure LC50 - Test Descriptor Fathead Minnow 96 hrs > 1,000 ma/l Product Bluegill Sunfish 96 hrs 868 rg/ Product Rainbow Trout 96 hrs 368 mg/l Product -

Channel Catfish 96 hrs 695 mg - Product Sheepshead Minnow 96 hrs 2,180 mg/I Product -

Rating: Essentially non-toxic  ; *.  ;

ACUTE INVERTEBRATE RESULTS:

Species Exposure LC50 EC5.Test Descriptor -

Daphnia magna - 148 hrs 520 mr/v - I. Product Grass Shrimp 96 hrs 1,770 mgA Product Rating: Essentially non-toxic - .

PERSISTENCY AND DEGRADATION:

Chemical Oxygen Demand (COD): 0.263 mg/i Biological Oxygen Demand (BOD)

Incubation Period Value Test Descriptor .

O mgI The organic portion of this preparation is expected to be inherently biodegradable.

MOBILITY:

The environmental fate was estimated using a level IlIl fugacity model embedded In the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total Input and output. The level IlIl model does not require equilibrium between the defined media. The Information provided Is intended to give the user a general estimate

.. , .. I. .-.I :I .

of the. environmental

_ .. f. I ..

fate of this product under the defined conditions of Nalco Energy Services, LP. P.O. Box 87 . Sugar Land, Texas 77487-0087 (281)263-7000 6111

- "; i 029

-II-MATERIAL SAFETY DATA SHEET

)1NALCO

.1 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC Al the models. If released into the environment this material is expected to distribute to the air, water and soilsediment in the approximate respective percentages; I Air I Water I Soil/Sediment

.1

} <5% l 30-50% l 50 - 70% l The portion in water is expected to be soluble or dispersible. 11 BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate. I1 ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low If released into the environment, see CERCLANSUPERFUND in Section 15.

.1

13. l DISPOSAL CONSIDERATIONS I I1 If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets the criteria of a hazardous waste. I Hazardous Waste: D002 Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and federal 11 regulations for specific requirements.

114. I TRANSPORT INFORMATION I l

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name I Hazard Class may vary by packaging, properties, I' and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT: 1 Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Technical Name(s):

UN/ID No:

Hazard Class - Primary:

HYDROXYETHYLIDENE DIPHOSPHONIC ACID UN 3265 8

A Packing Group: 11 Flash Point: > 93 C /> 200 OF

.1 AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Technical Name(s): HYDROXYETHYLIDENE DIPHOSPHONIC ACID Nalco Energy Services, LP. P.O. Box 87 Sugar Land, Texas 77487-0087 1

(281)263-7000

t. -

.)0 7/11 030

.1

MATERIAL SAFETY DATA SHEET PRODUCT

)ONALCO PCL-57 i

--EMERGENCY.TELEPHONE NUMBER(S)

• (800) 424-9300 (24 Hours) CHEMTREC *  ! . . .

UN/ID No: UN 3265 -

Hazard Class - Primary:

Packing Group:

IATA Cargo Packing Instructions: 812 IATA Cargo Aircraft Umit: 30 L; (Max net quantity per package)

MARINE TRANSPORT (IMDGIIMO):

¢ . ..

Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Technical Name(s): HYDROXYETHYLIDENE DIPHOSPHONIC ACID UN/ID No: UN 3265 Hazard Class - Primary: 8.

Packing Group:

115. l REGULATORY INFORMATION I s

NATIONAL REGULATIONS, USA: - -

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) islare shown below.

Hydroxyethylidenediphosphonic Acid: Corrosive to eyes, Target Organ - Bone PhosphonicAcid: Corrosive CERCLNSUPERFUND, 40 CFR 117,302:

Notification of spills of this product Is not required.

SARANSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE ll) - SECTIONS 302,311, 312, AND 313: 'F....' '

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous.' The product 'should be reported under the following indicated EPA hazard categories:  ;

X Immediate (Acute) Health Hazard X Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard . - X ... . . -

Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely, hazardous substances and 10,000 pounds for all other hazardous chemicals.

Nalco Energy Services, LP. P.O. Box 87.- Sugar Land, Texas 77487-0087 (281)263-7000 '

8/11 031

MATERIAL SAFETY DATA SHEET PRODUCT A1NALCO PCL-57 I

EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) _CHEMTREC It SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):

.1 The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act: .1 When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.310 Boiler Water Additives It Limitations: no more than required to produce intended technical effect FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311:

None of the substances are specifically listed in the regulation.

It CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and If Ozone Depleting Substances):

None of the substances are specifically listed in the regulation.

I CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed in the regulation.

Ii STATE RIGHT TO KNOW LAWS:

The following substances are disclosed for compliance with State Right to Know Laws:

Water 7732-18-5 Hydroxyethylidenediphosphonic Acid 2809-21-4 Phosphonic Acid 13598-36-2 NATIONAL REGULATIONS, CANADA:

-1 WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

.1 WHMIS CLASSIFICATION:

E - Corrosive Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been 1

reported in accordance with the New Substances Notification Regulations.

INTERNATIONAL CHEMICAL CONTROL LAWS Nalco Energy Services, L.P. P.O. Box 87 - Sugar Land, Texas 77487-0087 1

(281)263-7000

'r..:> i i 9/ 11 I

032

... . .. , . ; .. , - ~. .

-- 'MATERIAL SAFETY DATA SHEET I . NALCO PRODUCT PCL-57 _ *1

. 7-A. .-  : , ......

-- , -EMERGENCYTELEPHONENUMBER(S)

-(800) 424-9300 (24 Hours) CHEMTREC -

AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS) and are listed on the Australian Inventory of Chemical Substances (AICS).

.,~. . . , , -

i . EUROPE - ., . l . -

L The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.

JAPAN All substances Inthis product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & Industry List (MITI).

i KOREA All substances In this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals Ust (ECL)

THE PHILIPPINES All substances Inthis product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).

16. OTHER INFORMATION This product material safety data sheet provides health and safety Information. The product Is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this Information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.

REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents.and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Adel Insight# CD-ROM Version), Ariel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Adel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Nalco Energy Services, LP. P.O. Box 87, Sugar Land, Texas 77487-0087 (281)263-7000 10/11 I

. . 1j tj 033

MATERIAL SAFETY DATA SHEET PRODUCT ANALCO PCL-57 Ii EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

,I Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

AMel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

-1 North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), AMel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

AL Micromedex, Inc., Englewood, CO.

-Il Prepared By: Product Safety Department Date issued: 02126/2004 A

Version Number: 1.3 11 I1 I

I 1

1 II I1 Nalco Energy Services, L.P. P.O. Box 87

• Sugar Land, Texas 77487-0087 (281)263-7000 11/11 -1 I1

.-.> MM 1-% 4174.0 JA_%4 I.- MATERIAL SAFETY DATA SHEET PRODUCT

• NALCO I~~

I .

I 1.,.1- I H-130 MICROBIOCIDE

.-. . EMERGENCY-TELEPHONE NUMBER(S)

. . 1  % A12A Onnf IDA tj_-% = TD -

- . .- - NOW'4A4UU tZ noun)~ VnCm I Iii-l1. lCHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: H-130 MICROBIOCIDE APPLICATION: BIOCIDETWIN-CHAIN QUATERNARY AMMONIUM COMPOUND CONCENTRATE COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois

-. 60563-1198 -

EMERGENCY TELEPHONE NUMBER(S): (800)424-9300(24 Hours) CHEMTREC NFPA 704M/HMIS RATING -*

HEALTH: 3/3 FLAMMABILITY: 2/2 INSTABILITY: 0/0 OTHER:

0 -Insignificant I Slight 2= Moderate 3 = High 4= Extreme

2. COMPOSITIONIINFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).

Hazardous Substance(s) CAS NO  % (w/w)

Didecyl-Dimethyl-Ammonium chloride 7173-51-5 , 30- 60 Ethanol 64-17-5 - 10- 30

. I;.- j.

13. l HAZARDS IDENTIFICATION -- .. .. - - I ... .... .. - - I __ -

• • EMERGENCY OVERVIEW" DANGER Combustible. May cause tissue damage. Toxic to aquatic organisms. Corrosive. Causes severe eye and skin damage. Do not get in eyes, on skin or on clothing. Wears goggles or face shield and rubber gloves when handling.

Harmful or fatal if swallowed. Avoid contamination of food. -KEEP OUT OF REACH OF CHILDREN. Corrosive to eyes and skin. Do not get In eyes, on skin or clothing. May be fatal if swallowed or Inhaled. Do not swallow. Do not breathe vapour or mist.

Do not get in eyes, on skin, on clothing. Do not take Intemally. 'Keep away from'heat. Keep away from sources of ignition - No smoking. Use with adequate ventilation. Keep container tightly closed and In a well-ventilated place..

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash Immediately with plenty of watery Do'not get In eyes,' on skin or on clothing. Wear goggles or face shield and rubber gloves when handling. Harmful if inhaled. Avoid breathing vapor. Remove contaminated clothing and wash before reuse. Harmful or fatal if swallowed. -Avoid contamination of food. -

Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots.' -

Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve HCl under fire conditions. May evolve ammonia (NH4) under fire conditions.

I.. . I , . . . . . I ., 4 -.. . .I . - - - . . 1 Nalco Company 1601 W. Diehl Road.* Naperville, Illinois 60563-1198 (630)305-1000; i .., - 1/10 035

- _ it-

_NALCO MATERIAL SAFETY DATA SHEET if 04"NALCO PRODUCT f H-130 MICROBIOCIDE l EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC .1 PRIMARY ROUTES OF EXPOSURE:

Eye, Skin 1 HUMAN HEALTH HAZARDS -ACUTE:

EYE CONTACT:

May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid I

administered. ii SKIN CONTACT:

May cause severe irritation or fissue damage depending on the length of exposure and the type of first aid administered.

INGESTION:

May cause bums to mouth and gastro-intestinal tract.

INHALATION:

Repeated or prolonged exposure may irritate the respiratory tract. Can cause central nervous system depression.

SYMPTOMS OF EXPOSURE: l Acute:

A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic:

A review of available data does not identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

4. l FIRST AID MEASURES First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. For eyes, call a physician. Remove and wash contaminated clothing before reuse.

If swallowed, drink promptly a large quantity of milk, egg whites, gelatin solution, or if these are not available, drink large quantities of water. Avoid alcohol. Call a physician immediately.

NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition. - I

5. l FIRE FIGHTING MEASURES FLASH POINT: 109 ¶F 143 @C ( SETAFLASH)

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 11 (630)305-1000

. 2/10 036

. MATERIAL SAFETY DATA SHEET

. PRODUCT-RB,

• .NALC-0 . H-130 MICROBIOCIDE

. I .

• - EMERGENCY TELEPHONE NUMBER(S) v : (800)424-9300(24Hours) CHEMTREC EXTINGUISHING MEDIA: . . -. . .

Foam, Carbon dioxide, Dry powder, Other extinguishlng agent suitable for Class B fires, For large fires, use water spray or fog, thoroughly drenching the burning 'material.

Water mist may be used to cool closed containers.

FIRE AND EXPLOSION HAZARD:

Combustible Liquid; may form combustible mixtures at or above the flash point Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of.: -;

ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve HCI under fire conditions. May evolve ammonia (NH4) under fire conditions. --

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Notify appropriate govemment, occupational health and safety and environmental authorites. Restict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel.

only. Ventilate spill area If possible. Do not touch spilled material. Eliminate Ignition sources' Stop'or reduce any leaks If it is safe to do so. Use personal protective equipment recommended In Section 8 (Exposure Controls/Personal Protection).'

METHODS FOR CLEANING UP: ' -' - '

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated In Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

This product Is toxic to fish and other water organisms. Do not discharge directly Into lakes, ponds, streams, waterways or public water supplies.

7. HANDLING AND STORAGE . . . ... - .

HANDLING:

Do not get in eyes, on skin, on clothing. Do not take Intemally. Use with adequate ventilation. Avoid release of vapors or mists Into workplace air. Keep the containers closed when not in use: Do not use in locations where - '^'

vapor is likely to travel to welding flames or arcs or to other hot'surfaces. Vapors are much'heavier than air,'this can -

result In uneven distribution. Have emergency equipment (for fires, spills, leaks, etc.) readily available.

STORAGE CONDITIONS:

Store away from heat and sources of Ignition. Connections must be grounded to avoid electrical charges. Store the containers tightly dosed. Store separately from oxidizers. Store in suitable labelled containers.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 - - -

(630)305-1000 3/10' at) )037

MATERIAL SAFETY DATA SHEET PRODUCT 11

) NALCO H-130 MICROBIOCIDE

.1 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC ji

18. l EXPOSURE CONTROLS/PERSONAL PROTECTION I OCCUPATIONAL EXPOSURE LIMITS:

Exposure guidelines have not been established for this product Available exposure limits for the substance(s) are 11 shown below.

ACGIHITLV:

Ii Substance(s)

Ethanol OSHA/PEL:

TWA: 1,000 ppm, 1,880 mglm3 I

Substance(s)

Ethanol TWA 1,000 ppm, 1,900 mglm3 Ii ENGINEERING MEASURES:

Use general ventilation with local exhaust ventilation. -1 RESPIRATORY PROTECTION:

If significant mists, vapors or aerosols are generated an approved respirator is recommended. An organic vapor cartridge with dust/mist prefilter may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete I'

respiratory protection program including selection, fit testing, training, maintenance and inspection.

HAND PROTECTION:

Neoprene gloves, Viton# gloves 11 SKIN PROTECTION:

Wear impervious apron and boots. A full slicker suit is recommended if gross exposure is possible.

l EYE PROTECTION:

Wear chemical splash goggles.

HYGIENE RECOMMENDATIONS:

Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Use good work and personal hygiene I1 practices to avoid exposure.

9. l PHYSICAL AND CHEMICAL PROPERTIES .1 PHYSICAL STATE Liquid APPEARANCE Ught yellow 1

ODOR Alcoholic SPECIFIC GRAVITY DENSITY 0.93 @ 77 ¶F 125 -C 7.7 lb/gal ii Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 t ., , a ;J (630)305-1000 4/ 10 038 ii

-U

MATERIAL-SAFETY DATA SHEET PRODUCT -

.NALCC ,, '.; .' 0 MICROBIOCIDE

-. ' -EMERGENCY.TELEPHONE NUMBER(S)

- - (OUU) 4Z4-VJUU (Z4 HOUr) U. M I KLU

12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:

The following results are for the product.

ACUTE FISH RESULTS: ._._a,__

Species Exposure LC50 Test Descriptor Rainbow Trout - 196 hrs 2.2 m Bluegill Sunfish - 96 hrs 0.92 mg ----

Rating: Very toxic ACUTE INVERTEBRATE RESULTS:

Species Exposure LC50 EC50 Test Descriptor -

Daphnia magna 48 hrs 0.19 mg/I Mysid Shrimp (Mysidopsis 96 hrs 0.14 mg/I bahia)

Rating: Verytoxic If released Into the environment, see CERCLNSUPERFUND In Section 15.

113. l DISPOSAL CONSIDERATIONS . '....-

If this product becomes a waste, It could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, It should be determined If the waste meets the criteria of a hazardous waste. -- - -  : .

HazardousWaste: D001 - .

Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate Is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance.

1 14. I TRANSPORT INFORMATION I The information In this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name I Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:  :; - - -

Proper Shipping Name: DISINFECTANTS, LIQUID, CORROSIVE, N.O.S.

Technical Name(s) - ' - --: !DIDECYLDIMETHYLAMMONIUM CHLORIDE UN/ID No: -. UN1903 ' "-

Hazard Class - Primary: 8 Packing Group: 11, Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000-6/10 'i

.. .i . .

039

_ _ __ _ __ _ _ t1 MATERIAL SAFETY DATA SHEET PRODUCT -1 0tNALCO H-130 MICROBIOCIDE I

EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC II SOLUBILITY IN WATER Complete pH (1 %)

VISCOSITY FREEZING POINT 7.0 - 8.0

<100cps @ 77°F/25°C 12 OF/

II VAPOR PRESSURE 30 mm Hg @ 77 F /25 0 C VOC CONTENT 10 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change.

Il I

10. STABILITY AND REACTIVITY STABILITY:

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

-1 Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

D Heat and sources of ignition including static discharges.

MATERIALS TO AVOID:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,

.1 permanganate) may generate heat, fires, explosions and/or toxic vapors. Contact with reducing agents (e.g.

hydrazine, sulfites, sulfide, aluminum or magnesium dust) may generate heat, fires, explosions and toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS:

I Under fire conditions: Oxides of carbon, Oxides of nitrogen, HCI l 11. I TOXICOLOGICAL INFORMATION l

-1 The following results are for the product.

I1 ACUTE ORAL TOXICITY:

Species LD50 Test Descriptor Rat 645 mg/kg Product 11 ACUTE DERMAL TOXICITY:

Species LD50 Test Descriptor Rabbit > 4 g/kg Product 11 SENSITIZATION:

This product is not expected to be a sensitizer.

I1 a

CARCINOGENICITY:

None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Govemmental Industrial Hygienists (ACGIH).

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 11 (630)305-1000

• ,5/10

-E 040 B

MATEA- SA E S

.MATERIAL-SAFETY DATA SHEET

)041. ,.....

.. q I.

PRODUCT

NALCO H-130 MICROBIOCIDE EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) .CHEMTREC

-4~,' 9`

Flash Point:

DOT Reportable Quantity (per package): :1,000 lbs '

DOT RQ Component: " ETHANOL AIR TRANSPORT (ICAOJIATA):

Proper Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.

Technical Name(s): DIDECYLDIMETHYLAMMONIUM CHLORIDE, ETHANOL UN/ID No: UN 2920 Hazard Class - Primary: 8 Hazard Class - Secondary: 3 Packing Group:

IATA Cargo Packing Instructions:

IATA Cargo Aircraft Limit:  :,(Max net quantity per package)

MARINE TRANSPORT (IMDGAIMO):

Proper Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.

. Technical Name(s): DIDECYLDIMETHYLAMMONIUM CHLORIDE, ETHANOL UN/ID No: 'UN 2920 Hazard Class - Primary: 8I Hazard Class - Secondary: 'i3 v ;

Packing Group:

l 15. l REGULATORY INFORMATION -1I -I-,

NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:;- - -

Based on our hazard evaluation, the following substance(s) In this product is/are hazardous and the reason(s) Is/are shown below. , -.. -. ..

Didecyl-Dimethyl-Ammonium chloride: Corrosive'-

Ethanol: Flammable CERCLNSUPERFUND, 40 CFR 117,302: -

I_ This product contains the following Reportable Quantity (RQ) Substance. Also listed is the RO for the product. If a reportable quantity of product is released, it requires notification to the NATIONAL RESPONSE CENTER,..

WASHINGTON, D.C. (1-800424-8802). '

RO Substance 1 0R0 l Ethanol '1,000 lbs 1 0,000 lbs SARAISUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE Ill) - SECTIONS 302,311, 312, AND 313:

Nalco Company 1601 W. Diehl Road.- Naperville, Illinois 60563-1198 (630)305-1000 '

7/10 041

0tNALCO MATERIAL SAFETY DATA SHEET PRODUCT L H-130 MICROBIOCIDE L

EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

CHEMTREC L

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

I Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories:

X Immediate (Acute) Health Hazard I

Delayed (Chronic) Health Hazard X Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard I

Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely I-IL hazardous substances and 10,000 pounds for all other hazardous chemicals.

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) I FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):

EPA Reg. No. 1706-186 In all cases follow instructions on the product label. -

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307,40 CFR 116.4 1 formerly Sec. 311:

None of the substances are specifically listed in the regulation.

.I CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and 11Ozone Depleting Substances):

This product contains the following substances listed in the regulation:

I1 Substance(s)

. Ethanol Citations JSec. 111 I CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

-1 MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed in the regulation.

D STATE RIGHT TO KNOW LAWS:

This product is a registered biocide and is exempt from State Right to Know Labelling Laws.

1 Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 8/10 1D 042 1

MATERIAL SAFETY DATA SHEET A4LC

~NALCO L

PRODUCT

. . H-13 MICROBIOCIDE EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC NATIONAL REGULATlONS,'CANADA: -

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified In accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the Information required by the CPR.

WHMIS CLASSIFICATION:

Pesticide controlled products are not regulated under WHMIS.

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances In this preparation are listed on the Domestic Substances Ust (DSL), are exempt, or have been reported In accordance with the New Substances Notification Regulations.

116. OTHER INFORMATION This product material safety data sheet provides health and safety Information. The product Is to be used in applications consistent with our product literature. Individuals handling this product should be Informed of the recommended safety precautions and should have access to this Information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to Insure safe workplace operations. Please consult your local sales representative for any further Information.

L T l REFERENCES eshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), AMel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

L_ IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, Intemational Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-

- ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Aiel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Ariel Insight# (An integrated guide to Industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), AMel Research Corp., Bethesda, MD.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000

9/10 -i 043

MATERIAL SAFETY DATA SHEET PRODUCT JI 0NALCO H-130 MICROBIOCIDE

.1 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC Ii The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO. -1 Prepared By: Product Safety Department 11 Date issued: 02/28/2004 Version Number: 1.6

-1 11.

D 11

.I I

Ii Ii Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 10/10 Ii 044 iM

19 - - - - . I MATERIAL SAFETY DATA SHEET PRODUCT

^NALCO . H-940 MICROBIOCIDE

.. EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC

. I . . .....

11. ICHEMICAL PRODUCT AND COMPANY IDENTIFICATION I PRODUCT NAME: H-940 MICROBIOCIDE APPLICATION: INDUSTRIAL LIQUID MICROBIOCIDE COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800)424-9300(24 Hours) CHEMTREC NFPA 704MIHMIS RATING HEALTH: 1/1 FLAMMABILITY: 0 / 0 '-'"INSTABILITY: 010 OTHER:

0 = Insignificant I = Slight 2 = Moderate 3 = High 4 = Extreme

2. COMPOSITIONIINFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s). n s as h d C S 1 Hazardous Substance(s) CAS NO  % (w/w)

Sodium Bromide 7647-15-6 30.0 -' 60.0

3. l HAZARDS IDENTIFICATION

-~~~ ~ ~ - .*MREC

,VRIE*

-- ~ - ~ **EMERGENCY OVERVIEW**-

WARNING Irritation may develop from eye and skin exposure. Avoid contact with eyes. Wear gloves and safety goggles.

Wash contaminated clothing before reuse.

Avoid contact with eyes, skin and clothing. Wash with soap and water after handling. Remove contaminated clothing and wash before reuse.

May evolve hydrogen bromide and bromine under fire conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

EYE CONTACT: -

Can cause mild to moderate irritation.

SKIN CONTACT: -

May cause Irritation with 'prolonged contact.

~~~- ' .K.*. t Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198

. .. . 1-. .- (630)305-1000 ' . - ;

119 - -

045

_ _ n-MATERIAL SAFETY DATA SHEET PRODUCT IL 4tNALCO H-940 MICROBIOCIDE IL EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC A

INGESTION:

Not a likely route of exposure. No adverse effects expected.

INHALATION:

A Not a likely route of exposure. Aerosols or product mist may irritate the upper respiratory tract SYMPTOMS OF EXPOSURE:

Acute:

I1 A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic:

A review of available data does not identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

4. lFIRST AID MEASURES Eye contact: Flush eyes with cold water for at least 15 minutes. If irritation persists, seek medical attention.

Skin contact Prolonged contact can produce skin irritation. If skin contact occurs, wash with cold water for 15 minutes.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition. I

5. FIRE FIGHTING MEASURES 11 FLASH POINT: None EXTINGUISHING MEDIA:

Not expected to bum. Keep containers cool by spraying with water. Use extinguishing media appropriate for Ii surrounding fire.

FIRE AND EXPLOSION HAZARD:

May evolve hydrogen bromide and bromine under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. lACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate unti clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 2/9 046 I

MATERIAL SAFETY DATA SHEET PRODUCT

NALCO H-940 MICROBIOCIDE EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) . CHEMTREC METHODS FOR CLEANING UP:

SMALL SPILLS: -Soak up spill with'absorbent material: Place residues In a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose -of material In compliance with regulations indicated In Sections 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

This pesticide Is toxic to fish and aquatic organisms. 'Do not discharge effluent containing this product Into lakes, streams, ponds, estuaries, oceans or other waters, unless In accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified In writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.

7. HANDLING AND STORAGE HANDLING:

Avoid eye and skin contact Do not take internally. Do not get in eyes,'n skin, on'clothing. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure 'all containers are labelled. Keep the containers closed when not in use. Use with adequate ventilation.

STORAGE CONDITIONS, Store the containers tightly closed. Store In suitable labelled containers. Store in a cool well ventilated area away from direct sunlight - -

8. l EXPOSURE CONTROLS(PERSONAL PROTECTION - ;

OCCUPATIONAL EXPOSURE LIMITS:

This product does not contain any substance that has an established exposure limit.

ENGINEERING MEASURES:

General ventilation is recommended.

RESPIRATORY PROTECTION:

Respiratory protection Is not normally needed.

HAND PROTECTION:

Neoprene gloves, Nitrile gloves, Butyl gloves, PVC gloves SKIN PROTECTION: ' . .....

Wear standard protective clothing.

EYE PROTECTION:

Wear chemical splash goggles.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 3/9 047

MATERIAL SAFETY DATA SHEET PRODUCT I ANALCO H-940 MICROBIOCIDE IL EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC JI HYGIENE RECOMMENDATIONS:

If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Keep an eye wash fountain available. Keep a safety shower available. ,1

9. l PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid ii APPEARANCE ODOR Colorless None Il SPECIFIC GRAVITY DENSITY 1.43 @ 77 F /25 @C 11.9 lb/gal II SOLUBILITY IN WATER Complete pH (100 %)

FREEZING POINT BOILING POINT 5.5- 9.0

-10 OF -23.3 °C 218 F/ 103.5 *C I

VAPOR PRESSURE Same as water VOC CONTENT 0.00 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change.

10. I STABILITY AND REACTIVITY STABILITY:

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

ii Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

Ii High temperatures MATERIALS TO AVOID:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, Ii permanganate) may generate heat, fires, explosions and/or toxic vapors. Strong acids HAZARDOUS DECOMPOSITION PRODUCTS:

Hydrogen bromide, Bromine II

11. lTOXICOLOGICAL INFORMATION Ii The following results are for the product and a similar product.

ACUTE ORAL TOXICITY:

Species LD50 Test Descriptor Rat > 5,000 mglkg Product Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 I

(630)305-1000 4/9 048 Ii

-I

.- MATERIAL SAFETY DATA SHEET

^NALCO PRODUCT

.H-940 MICR 6OBIOCIDE t

.-  :: EMERGENCY TELEPHONE NUMBER(S)

-(800) ; 424-9300 (24 Hours) CHEMTREC Rating: Non-Hazardous '. - '

ACUTE DERMAL TOXICiTY:

Species LD50 Test Descriptor Rabbit > 2,000 mg/kg Produ'ct '

Rating: Non-Hazardous PRIMARY SKIN IRRITATION:

Draize Score Test Descriptor I 0.4 18.0' Similar Pioduct Rating: Minimally irritating PRIMARY EYE IRRITATION:

Draize Score - - Test Descriptor  :

10.8 /110.0 Similar Product Rating: Practicallynon-Irritating SENSITIZATION:

This product is not expected to be a sensitizer.

CARCINOGENICITY: - ' - -

None of the substances in this product are listed as carcinogens by the Intemational Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). ' *  ;-

HUMAN HAZARD CHARACTERIZATION:

Based on our hazard characterization, the potential human hazard Is: Low

12. l ECOLOGICAL INFORMATION .

ECOTOXICOLOGICAL EFFECTS:

The following results are for the product -. . .i.- -  :

ACUTE FISH RESULTS:

Species Exposure LC50 I Test Descriptor Bluegill Sunfish l 96 hrs l > 100 mg/I l Product Rainbow Trout 96 hrs . > 00mgA Product Rating: Essentially non-toxic ACUTE INVERTEBRATE RESULTS: ..

l Species, - ' Exposure l LC50- - EC50 I Test Descriptor Daphnia magna 48 hrs > 1,000 mgA Product Rating: Essentially non-toxic PERSISTENCY AND DEGRADATION:

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 5,9 049

U -

MATERIAL SAFETY DATA SHEET It

)041"NALCO PRODUCT H-940 MICROBIOCIDE IL EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC IL Biological Oxygen Demand (BOD): This material is an oxidizing biocide and is not expected to persist in the environment.

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION It Based on our hazard characterization, the potential environmental hazard is: Low If released into the environment, see CERCLNSUPERFUND in Section 15. 11 113. 1 DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery I

I IL Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.

Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. .1 DO NOT REUSE EMPTY CONTAINER. Triple rinse the container (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incinerate. Bum only if allowed by state and local authorities. If burned, stay out of smoke.

11 114. I TRANSPORT INFORMATION I Ii The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. I LAND TRANSPORT:

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION l1 AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING D

MARINE TRANSPORT (IMDG/IMO):

TRANSPORTATION II Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION 11 l15. lREGULATORY INFORMATION NATIONAL REGULATIONS, USA:

Ii OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.

D li Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000 6/9 I 050 I

L -MATERIAL SAFETY DATA SHEET

)0LCO PRODUCT

• A .1 H-940 MICROBIOCIDE

. . E -MERGENCY TELEPHONE NUMBER(S)

. - (800) 4249300 (24 Hours) CHEMTREC- -

Sodium Bromide: Eye Irritant L CERCLANSUPERFUND,40 CFR 117,302:

Notification of spills of this product is not required.

SARAISUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE ill) - SECTIONS 302,311, 312, AND 313:

SECTION 302- EXTREMELY HAZARDOUS SUBSTANCES (46 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous. The product should be reported under the following

- indicated EPA hazard categories: -

X Immediate (Acute) Health Hazard

- Delayed (Chronic) Health Hazard d  ::' ':.  :

Fire Hazard . -' ;

Sudden Release of Pressure Hazard j- - Reactive Hazard -

Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever Is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

L' This product does not contain substances on the List of Toxic Chemicals.

L TOXIC SUBSTANCES CONTROL ACT (TSCA): - . ' .:

This product is exempted under TSCA and regulated under FIFRA. The Inerts are on the Inventory List.

K FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):

EPA Reg. No. 1706-217-- - ----

In all cases follow Instructions on the product label.

L FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307,40 CFR 116. / formerly Sec. 311:

None of the substances are specifically listed In the regulation. -

CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and 11Ozone DepleUng Substances): . .

None of the substances are specifically listed in the regulation;;

CALIFORNIA PROPOSITION 65: - . . '

This product does not contain substances which require warning under California Proposition 65.

L MICHIGAN CRITICALMATERIALS: - i .. * .,

None of the substances are specifically listed in the regulation.'

Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000

[L 7/9 051

- a -

MATERIAL SAFETY DATA SHEET I

0tNALCO PRODUCT H-940 MICROBIOCIDE IL EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC IL STATE RIGHT TO KNOW LAWS:

This product is a registered biocide and is exempt from State Right to Know Labelling Laws. It NATIONAL REGULATIONS, CANADA:

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

IL This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION:

Pesticide controlled products are not regulated under WHMIS.

16. OTHER INFORMATION 11 This product material safety data sheet provides health and safety information. The product Is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe II workplace operations. Please consult your local sales representative for any further information.

REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Mel Insight# CD-ROM Version), ArMel Research Corp.,

I1 Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM -1 Version), Micromedex, Inc., Englewood, CO. -1 IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington. D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

11 Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (AMel Insight# CD-ROM Version), Mel Research Corp., Bethesda, MD.

D Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO. ii Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel 1

Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 8/9 1

052

MATERIAL SAFETY DATA SHEET PRODUCT 0'NALCO H-940 MICROBIOCIDE EMERGENCY TELEPHONE NUMBER(S) . I (800)424-9300(24 Hours) CHEMTREC II The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO. -

Prepared By: Product Safety Department Date Issued: 02/28/2004 Version Number: 1.5.

. - f % .

. I I ' .I Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 9/9 053

SAMV-H 32.53 11 Wt GE Betz Ii GE Betz, Inc. Material Safety Data Sheet 4636 Somerton Road Trevose, PA 19053 Business telephone: (215) 355-3300 Issue Date: 17-MAYs2001 Il EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 1 PRODUCT IDENTIFICATION .1 PRODUCT NAME:

SPECTRUS NX1O06

-1 PRODUCT APPLICATION AREA:

WATER-BASED MICROBIAL CONTROL AGENT.

.1 2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the II U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. This product is subject to the Pennsylvania

_l Il and New Jersey Worker and Community Right to Know Law.

HAZARDOUS INGREDIENTS:

CAS# CHEMICAL NAME 10377-60-3 MAGNESIUM NITRATE Oxidizer; irritant (eyes and skin)

I1 26172-55-4 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE Corrosive; toxic (by ingestion and skin absorption);

sensitizer (skin)

Ii No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration at Pennsylvania thresholds I1 for carcinogens.

NON-HAZARDOUS INGREDIENTS: 11 CAS# CHEMICAL NAME 7732-18-5 WATER 3 HAZARDS IDENTIFICATION 11 11 Ii 054 Ii

EMERGENCY OVERVIEW DANGER Corrosive to skin. Skin'sensitizer with delayed onset of symptoms.

Corrosive to the eyes. Mists/aerosols cause irritation to the upper respiratory tract.

... : 1 - t...............

DOT hazard: Corrosive to skin Emergency Response Guide #153 Odor: Slight; Appearance: Light Yellow To Green, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type).fProper fire-extinguishing media:

dry chemical, carbon dioxide, foam or water POTENTIAL UZALTE EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; Corrosive to skin. Skin sensitizer with delayed onset of symptoms.

ACUTE EYE EFFECTS:

Corrosive to the eyes.

ACUTE RESPIRATORY EFFECTS:

Mists/aerosols cause irritation to the upper respiratory tract.

INGESTION EFFECTS:

May cause severe irritation .or burning of mouth, throat, and.

gastrointestinal tract with severe chest and abdominal pain,.,

nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses.

TARGET ORGANS:.

Prolonged or repeated exposures may cause tissue necrosis and/or skin sensitization.. -

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF EXPOSURE:

Direct contact with skin will cause severe delayed skin reactions or burns if not washed off immediately- follow first aid instructions.  :

4 FIRST AID MEASURES SKIN CONTACT:

URGENT! Wash thoroughly with soap and water. Remove contaminated clothing. Get immediate medicalfattention. Thoroughly wash clothing before reuse. -

EYE CONTACT:

URGENT! Immediately flush eyes' with plenty of low-pressure water for at least 20 minutes while removing contact lenses. Hold eyelids apart. Get immediate medical attention.

INRAILATION:

If nasal, throat or lung irritation develops - removelto fresh air 055

and get medical attention. IL INGESTION:

Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.

Dilute contents of stomach using 3-4 glasses milk or water.

1 NOTES TO PHYSICIANS:

Material is corrosive. It may not be advisable to induce vomiting.

Possible mucosal damage may contraindicate the use of gastric L lavage.

5 FIRE FIGHTING MEASURES f FIRE FIGHTING INSTRUCTIONS:

Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).

EXTINGUISHING MEDIA:

dry chemical, carbon dioxide, foam or water 11 HAZARDOUS DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

FLASH POINT:

> 200F > 93C P-M(CC)

MISCELLANEOUS:

Corrosive to skin UN3265;Emergency Response Guide #153 6 ACCIDENTAL RELEASE MEASURES .1 PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.

Do not add decontaminant solution to waste drum containing biocide or adsorbent. Decontaminate floor residual with 10% metabisulfite solution. Use 10 volumes of solution to one volume of spill.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementsa permitted waste treatment facility or discharged under a permit. Product as is - Dispose of in approved pesticide facility or according to label instructions.

7 HANDLING & STORAGE HANDLING:

Contains an oxidizer. Avoid all contact with reducing agents, oils, greases, organics and acids. Corrosive to skin and/or eyes.

STORAGE:

Keep containers closed when not in use. Store between 20-1OOF for no more than 6 months. Store upright in original vented containers.

Product evolves C02 slowly. Store samples in plastic bottles due to pressure build-up. < 1.00 8 EXPOSURE CONTROLS / PERSONAL PROTECTION D EXPOSURE LIMITS CHEMICAL NAME MAGNESIUM NITRATE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED 056

5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED MISC: Note-mfg. sugg. exp. limit:0.1 mg/m3 T1WA0.3mg/m3 STEL total isothiazoline).

ENGINEERING CONTROLS:

Adequate ventilation to maintain air contaminants below exposure limits.

PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION: -

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use a respirator with organic vapor/acid gas cartridges and dust/mist prefilters.

SFIN PROTECTION:

gauntlet-type butyl gloves, chemical-resistant-apron-- Wash off after each use. Replace as necessary.

EYE PROTECTION: -

splash proof chemical goggles, face shield 9 PHYSICAL & CHEMICAL PROPERTIES Specific Grav.(70F,21C) 1.033 Vapor Pressure (mmHG) - 18.0 Freeze Point (F) 28 Vapor Density (air=l) < 1.00 Freeze Point (C) -2 Viscosity(cps 70F,21C) 8  % Solubility (water) 100.0 Odor slight -

Appearance Light Yellow To Green Physical State Liquid Flash Point P-M(CC) > 200F > 93C pH As Is (approx.) 3.0

• Evaporation Rate (Ether=l) < 1.00 "

NA* not applicable ND = not dot ermined 10 STABILITY & REACTIVITY STABILITY:

Stable under normal storage conditions.

HAZARDOUS POLYMERIZATION:

Will not occur.

INCOMPATIBILITIES:

May react with strong oxidizers.

DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yi elds elemental oxides.

INTERNAL PUMPOUT/CLEANOUT CATEGORIES: . -

'By ~~~. ., ', ~. i-.-

11 TOXICOLOGICAL INFORMATION 057

Oral LD50 RAT: >5,000 mg/kg Teratology : NEGATIVE Dermal LD50 RABBIT:

NOTE - Estimated value Skin Sensitization HUMAN:

>2,000 mg/kg POSITIVE

.1 Non-Ames Mutagenicity NEGATIVE 12 ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Bluegill Sunfish 96 Hour Static Acute Bioassay LC50= 12.1; No Effect Level= 6.5 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay LC50= 2.9; 10% Mortality= .6 mg/L Fathead Minnow 36 Day Early Life Stage Test LOEC= 4; No Effect Level= 1.3 mg/L Fathead Minnow 96 Hour Flow-Thru Bioassay LC50= 6.6; No Effect Level= 2.5 mg/L Rainbow Trout 14 Day Chronic Bioassay

-f LC50= 4.6; No Effect Level= 3.3 mg/L Rainbow Trout 96 Hour Static Acute Bioassay LC50= 8.7; No Effect Level= 6.5 mg/L Sheepshead Minnow 96 Hour Static Acute Bioassay I

LC50= 20; No Effect Level= 12 mg/L BIODEGRADATION BOD-28 (mg/g): 0 BOD-5 (mg/g): 0 COD (mg/g): 17 TOC (mg/g): 6 13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is 1

Not applicable.

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14 TRANSPORT INFORMATION DOT HAZARD: Corrosive to skin UN / NA NUMBER: UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153 15 REGULATORY INFORMATION TSCA:

This is an EPA registered biocide and is exempt from TSCA inventory requirements.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER:

3876- 143 FOOD AND DRUG ADMINISTRATION:

058

The ingredients in this product are approved by FDA under 21 CFR 176.300.

USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS:

SEC.G7 SARA SECTION 312 HAZARD CLASS:

Irnmediate(acute);Delayed(Chronic)"-

SARA SECTION 302 CHEMICALS:

No regulated constituent present at OSHA'thresholds' SARA SECTION 313 CHEMICALS: - - an -

CAS# CHEMICAL NAME -'RANGE

'10377-60-3 MAGNESIUM NITRATE 2.0-5.0%

CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINI WATER AND TOXIC _

ENFORCEHENT ACT (PROPOSITION 65) CHEDCALS PRESENT:

No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION -

No regulated constituent present at OSHA thresholds 16 OTHER INFORMATION .

NFPA/HMIS CODE TRANSLATION .

Health 3 Serious Hazard Fire 0 - Minimal Hazard -

Reactivity -O Minimal Hazard '

Special CORR DOT,corrosive (1) Protective Equipment D -Goggles ,Face ShieldGloves, Apron (1) refer to section 8 of MSDS for additional protective -equipment

- recommendations.

CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: .- SUPERCEDES MSDS s1tatus: 16-MAR-1998 ** NEM **

01-MAY-1998 ;EDIT:9 16-MAR-1998

-, 08-APR-1999 ;EDIT:9 01-MAY-1998

, , , ,17-MAY-2!001 4,16 - 08-APR-1999 fX>-. . ---

. ,§ -

059

-ydl.

MATERIAL SAFETY DATA SHEET It AWNALCO PRODUCT H-550

.t EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Houm) CHEMTREC It l1. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: H-550 It APPLICATION:

COMPANY IDENTIFICATION:

MICROBIOCIDE Nalco Company II 1601 W. Diehl Road Naperville, Illinois 60563-1198 It EMERGENCY TELEPHONE NUMBER(S):

NFPA704M/HMIS RATING (800)424-9300(24 Hours) CHEMTREC II HEALTH: 3/3 FLAMMABILITY: 1/1 INSTABILITY: 0/0 OTHER:

o = Insignificant 1 =Slight 2 =Moderate 3 = High 4 = Extreme

2. l COMPOSITIONIINFORMATION ON INGREDIENTS I1 Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).

It Glutaraldehyde Hazardous Substance(s) CAS NO 111-30-8

% (wAv) 30.0 - 60.0 -1

3. l HAZARDS IDENTIFICATION I 11

• • EMERGENCY OVERVIEW' DANGER Corrosive. Causes irreversible eye damage. Causes skin bums. Harmful if inhaled. May be fatal if swallowed. 11 Harmful if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Causes asthmatic signs and symptoms in hyper-reactive individuals.

Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not swallow. Wear goggles, protective clothing, and rubber gloves. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash

.1 before reuse.

Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions.

PRIMARY ROUTES OF EXPOSURE:

II Eye, Skin, Inhalation HUMAN HEALTH HAZARDS - ACUTE: D EYE CONTACT:

Corrosive. Will cause eye bums and permanent tissue damage. I1 1

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 1/ 12 Ii 060

-MATERIAL A

SAFETY A.-AET .

DATA SESHEET

' NALCO PRODUCT-H-550  :

I..... .- -.

EMERGENCY-TELEPHONE NUMBER(S)

- ,.. (800)424-9300(24 Hours). CHEMTREC SKIN CONTACT:

May cause severe Irritation or tissue damage depending on the length of exposure and the type of first aid administered. Prolonged or frequently repeated skri contact may cause allergic reactions in some individuals.

INGESTION: ........-.

Not a likely route of exposure. Corrosive; causes chemical bums to the mouth, throat and stomach.

INHALATION:

Irritating, In high concentrations, to the eyes, nose, throat and lungs. Inhalation of product mist or vapors may cause respiratory allergy.

SYMPTOMS OF EXPOSURE: .*- - .*

Acute:

A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic: - , .

A review of available data does not identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS: - -  : - .

A review of available data does not identify any worsening of existing conditions.

HUMAN HEALTH HAZARDS- CHRONIC:

Prolonged inhalation of product can Increase lung injury in persons with emphysema, asthma, or other lung disorders.

4. lFIRST AID MEASURES .  : -. .  ; I EYE CONTACT:

Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open. * -

SKIN CONTACT:- . I f a l 1 m F al a Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area Immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.

INGESTION: - - - -,

Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink.

INHALATION:, - ¢..,

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.  : -. --

IF IN EYES: Immediately flush with plenty of waterfor at least 15 minutes. Get immediate medical attention.

IF ON SKIN: Immediately wash with plenty of soap and water. Get medical attention.

IF INHALED: Remove to fresh air. If breathing is difficult, administer oxygen. If symptoms persist, call a physician.

IF SWALLOWED: DO NOT INDUCE VOMITING. Do not give anything to drink. Seek medical advice with urgency.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 -

(630)30-0iooo 2/12 061

--- It-MATERIAL SAFETY DATA SHEET 0rNALCO PRODUCT It H-550

.1 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC NOTE TO PHYSICIAN:

Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

5. lFIRE FIGHTING MEASURES l ii FLASH POINT: None EXTINGUISHING MEDIA:

This product would not be expected to bum unless all the water is boiled away. The remaining organics may be I

ignitable. Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions. I SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. lACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate govemment, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Dilute the glutaraldehyde to 5% or less with water. Add sodium bisulfite (2-3 parts by weight per part glutaraldehyde). This will typically reduce the glutaraldehyde concentration to 2 ppm or less in 5 minutes at room temperature. The remaining solution can be disposed of via appropriate means. Contact an approved waste hauler

-1 for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

This pesticide is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. D

-1 Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 I

3/12 062 I

MATERIAL SAFETY DATA SHEET PRODUCT - -.-

I NALCO H-550:

EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC .. .

7. l HANDLING AND STORAGE . .

HANDLING:

Do not get in eyes, on skin, on clothing. Do not take Intemally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed when not In use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.

STORAGE CONDITIONS: .. -

Store the containers tightly closed. Store separately from oxidizers. Store in suitable labelled containers.

SUITABLE CONSTRUCTION MATERIAL:

Compatibility with Plastic Materials can vary; we therefore recommend that compatibility Is tested prior to use.

UNSUITABLE CONSTRUCTION MATERIAL:

Aluminum, Tin, Zinc, Steel 1 .z I 1

18. wEXPSURE CONTROLS/PERSONAL PROTECTION . , . . . ..... . .1 OCCUPATIONAL EXPOSURE LIMITS:

Exposure guidelines have not been established for this product. 'Available exposure limits for the substance(s) are ;

shown below.

ACGIH/TLV:

Substance(s)

Glutaraldehyde CEILING: 0.05 ppm, 0.2 mglm3 0.05 pprm, 0.2 mg/m3 OSHAIPEL:

Substance(s)

Glutaraldehyde CEILING: 0.2 ppm, 0.8 mglm3 ENGINEERING MEASURES:

General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor.

RESPIRATORY PROTECTION:

If significant mists, vapors or aerosols are generated an approved respirator is recommended. A dust, mist, fume cartridge may be used. In event of emergency or planned entry Into unknown concentrations a positive pressure; full-facepiece SCBA should be used. If respiratory protection Is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. . .. . .

! li , , -

HAND PROTECTION: ' - -

BUTYL GLOVES, NEOPRENE GLOVES, Viton# gloves- - --I I . . I i SKIN PROTECTION: ' - - 'I Wear chemical resistant apron, chemical splash goggles, Impervious gloves and boots.' A full slicker suit Is ' '

recommended if gross exposure is possible.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1 000' - ' ' :'

4112 063

_-II-MATERIAL SAFETY DATA SHEET PRODUCT IL 0NALCO H-550

-1 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC Ii EYE PROTECTION:

Wear a face shield with chemical splash goggles.

HYGIENE RECOMMENDATIONS:

It Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.

.I

9. l PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid I APPEARANCE Colorless ODOR Aldehyde

-1 SPECIFICGRAVITY DENSITY SOLUBILITY IN WATER 1.11-1.13 @ 77 0F/25°C 9.4 lb/gal Complete Ii pH (100 %) 3.1-4.5 VISCOSITY FREEZING POINT BOILING POINT 21 cps @ 68 F /20 C

-5.8 OF I -21 `C 213 OF/ 100.5 0C I

VAPOR PRESSURE 16 mm Hg VAPOR DENSITY VOC CONTENT 1.1 54 % EPA Method 24 I' Note: These physical properties are typical values for this product and are subject to change.

10. STABILITY AND REACTIVITY I1 STABILITY:

Stable under normal conditions. I HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur. I1 CONDITIONS TO AVOID:

Freezing temperatures.

MATERIALS TO AVOID:

II Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. I1 HAZARDOUS DECOMPOSITION PRODUCTS:

Under fire conditions: Oxides of carbon 1

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 5/12 Ii 064 I

.. MATERIAL SAFETY DATA SHEET PRODUCT - . .

'INALCO H-550  :.

. IEMERGENCY TELEPHONE NUMBER(S)

.1-I- (800) 424.9300 (24 Hours) CHEMTREC I-l II. I TOXICOLOGICAL INFORMATION-,- - . ; I The following results are for the product ACUTE ORAL TOXICITY  : -- - . .-

Species - - -LD50 - - Test Descriptor Rat 1,300 mg/kg Product Glutaraldehyde Rat 1.2 mI/kg 45% Active Ingredient Rat - 1.54 -1.87 m/lkg - ---25% Active Ingredient Rat 1.07 -1.62 mI/kg 10% Active Ingredient Rating: Harmful.

ACUTE DERMAL TOXICIlY: -

Species LD50 Test Descriptor - . . - ' , . 11 Rabbit 897 mg/kg Product Glutaraldehyde Rabbit 2.00 - 2.71 mI/kg 45% Active Ingredient Rabbit 8.0 - 12.8 ml/kg 25% Active Ingredient Rating: Harmful -.

ACUTE INHALATION TOXICITY:

Species - LC50 Test Descriptor Rat - 0.48 mg/I 0 Product- - - -

Rating: Very Toxic PRIMARY SKIN IRRITATION: At 10% or greater, glutaraldehyde solutions may cause moderate to severe irritation, with possible necrosis after prolonged contact--- -

PRIMARY EYE IRRITATION: At levels of 0.2% and below of glutaraldehyde, no eye irritation was noted. Levels above 0.2% of glutaraldehyde produced moderate to severelirritation and comeal Injury. -

SENSITIZATION: - -. --

Levels of greater than 0.2% of glutaraldehyde produced allergic contact dermatitis in human studies. May cause sensitization by inhalation and skin contact  ;- - -- -

CARCINOGENICITY: .:

None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or-the American Conference of Governmental Industrial Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION: - - :; l Based on our hazard characterization, the potential human hazard Is: High

i I . . . . . .' i'.11.1C.

. . ..; . .. I. .. . .. i ."

112. l ECOLOGICAL INFORMATION: .1 . . I 1. .. . . I ECOTOXICOLOGICAL EFFECTS:

The following results are for the product along with results on the active substances.'-.

, *11 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305.1000 '

6/12 065

MATERIAL SAFETY DATA SHEET PRODUCT I

AWNALCO H-550 It EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC II ACUTE FISH RESULTS:

Species Bluegill Sunfish Fathead Minnow Exposure 96 hrs 96 hrs LC50 22.4 mg/I 10.8 mg/I Test Descriptor Product Product II Sheepshead Minnow 96 hrs 64 mg//l Product Rainbow Trout 96 hrs 24 mgI Product Rating: Slightly toxic ACUTE INVERTEBRATE RESULTS:

Species Exposure LC50 EC50 Test Descriptor .1 Daphnia magna Shore Crab 48 hrs 96 hrs 11.5 mgn_

930 mg/I Product Product II Grass Shrimp 96 hrs 82 mg/_ Product Mysid Shrimp (Mysidopsis 96 hrs 14.2 mg/I Product bahia)

American Oyster 96 hrs 1.56 mg/I Product Acartia tonsa 48 hrs 0.22 mg/I Product Rating: Slightly toxic AQUATIC PLANT RESULTS:

Species Exposure EC50/LC50 Test Descriptor II Marine Algae (Skeletonema 72 hrs 1.22 mg/I Product costatum)

Algae (Scenedesmus 72 hrs 1.7 mg/I Product subspicatus)

Rating: Toxic AQUATIC MICROORGANISM RESULTS: .1 Species l Exposure l EC50/LC50 l Test Descriptor Sewage Microorganisms 96 hrs 34 mg/1 Active Substance 11 AVIAN RESULTS:

Species Bobwhite Quail Exposure 8 Days LC50 10,000 ppm ITest Descriptor Active Substance D

Mallard Duck 8 Days 10,000 ppmr Active Substance Mallard Duck 933 mg/kg 50% Active Ingredient MOBILITY:

The environmental fate was estimated using a level IlIl fugacity model embedded in the EPI (estimation program 1

interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soillsediment D

in the approximate respective percentages; I Air I Water I Soil/Sediment I D

<5% 1 30 - 50% 1 50 - 70% 1 Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198

-1 (630)305-1000 7/ 12 D 066 Ii

MATERIAL SAFETY DATA SHEET I NALUCo PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC --

The portion in water is expected to be soluble or dispersible. '

BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Moderate '

If released into the environment, see CERCLANSUPERFUND InSection 15.

13. DISPOSAL CONSIDERATIONS---

If this product becomes a waste, it Is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since It does not have the characteristics of Subpart C, nor is It listed under Subpart D.

As a non-hazardous waste, It Is not subject to federal regulation.' Consult state'or local regulation for any additional handling, treatment or disposal requirements. 'For disposal, contact a properly licensed waste'treatment, storage, disposal or recycling facility.

ACONTAINER DISPOSAL: Metal Containers or Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of In a sanitary landfill, or other procedures approved by, state and local authorities. Plastic Containers: May be Incinerated, or, if allowed by state and local authorities, by; burning. If burned, stay out of smoke. Metal Containers: Must not be incinerated. Do not cut or weld on or near metal containers.

14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows;' . - ' '-

LAND TRANSPORT:

- .I -

- . - , . 1, Proper Shipping Name: -_CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Technical Name(s): GLUTARALDEHYDE UN/ID No: UN 3265 Hazard Class - Primary: 8 8 -  ;

Packing Group:

Flash Point: None -

AIR TRANSPORT (ICAOIIATA):

Proper Shipping Name:  : *.CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Technical Name(s): -* GLUTARALDEHYDE -- '

UN/ID No: UN 3265 Hazard Class - Primary: 8 Packing Group: II Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305'1000 7.

8/12 067

_____ _______ ______ ______-U-MATERIAL SAFETY DATA SHEET PRODUCT IL 0tNALCO H-550 It EMERGENCY TELEPHONE NUMBER(S)

IATA Cargo Packing Instructions:

(800) 424-9300 (24 Hours) 812 CHEMTREC It IATA Cargo Aircraft LUmit:

MARINE TRANSPORT (IMDG/IMO):

30 L (Max net quantity per package)

.1 Proper Shipping Name:

Technical Name(s):

UN/ID No:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

GLUTARALDEHYDE UN 3265 II Hazard Class - Primary:

Packing Group:

8 II II

15. REGULATORY INFORMATION NATIONAL REGULATIONS, USA: -1 OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below.

.1 Glutaraldehyde: Corrosive, Sensitizer CERCLA/SUPERFUND, 40 CFR 117,302:

.1 This product contains the following Reportable Quantity (RQ) Substance. Also listed is the RQ for the product RQ Substance Methanol RQ 5,000 lbs I

SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE ll) - SECTIONS 302,311, 312, AND 313:

1 SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance. ii SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories: I' X

X Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard Fire Hazard I'

Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

D The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

D Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 D

(630)305-1000 9/12 Il 068 Ii

MATERIAL SAFETY DATA SHEET

'INALCO PRODUCT,'

I A&i4 H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC SECTION 313-LIST OF TOXIC CHEMICALS (40 CFR 372) * ' ' '

This product contains the following substance(s), (with CAS # and % range) which appear(s) on the List of Toxic L Chemicals Hazardous Substance(s) CAS NO '  % (ww) -

Methanol 67-56-1 1.0- 5.0 TOXIC SUBSTANCES CONTROL ACT (TSCA):.

This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory Ust FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):

EPA Reg. No. 464-704-1706 - ' ('IFR')'

In all cases follow Instructions on the product label.

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.151 formerly Sec. 307,40 CFR116.4/formerlySec311: ' '

None of the substances are specifically listed in the regulation.

CLEAN AIR ACT,-Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and 11Ozone Depleting Substances):

This product contains the following substances listed In the regulation:

Substance(s) Citations i* Methanol Sec. 111, Sec. 112 CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

MICHIGAN CRITICAL MATERIALS:*

None of the substances are specifically listed in the regulation.

STATE RIGHT TO KNOW LAWS: ' '

This product is a registered biocide and Is exempt from State Right to Know Labelling Laws.:

.Methanol , 56-1 Glutaraldehyde 111-30-8

- NATIONAL REGULATIONS, CANADA:

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION:

Pesticide controlled products are not regulated underWHMIS.

• Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 10/12 069

MATERIAL SAFETY DATA SHEET PRODUCT I

)NNALCO H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations. t INTERNATIONAL CHEMICAL CONTROL LAWS AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).

I CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing II il Chemical Substances China (IECSC).

11 EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. II JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).

11 KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)

NEW ZEALAND This product's trade name is registered with the Environmental Risk Management Authority (ERMA).

THE PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine

-1 Inventory of Chemicals & Chemical Substances (PICCS).

16. l OTHER INFORMATION ii This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should I

be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information.

REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), Ariel Research Corp.,

Bethesda, MD. ii I

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO. Ii Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 A

J 11/12 070

MATERIAL SAFETY 'DATA SHEET

• NALCO IPRODUCT

., i .

EMERGENCY TELEPHON E NUMBER(S)

- I -- - (800) 424-9300 (24 Hours) CHEMTREC IARC Monographs on the Evaluatioriof the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency fcr Research on Cancer.

Integrated Risk Infomiation System, L .-Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO. ' '

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human' Services,:

Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z. Toxic and Hazardous Substances, Occupational Safety' and Health Administration (OSHA), (Adel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc.,' Englewood, CO.

Ariel Insight# (An Integrated guide to Industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.' - -

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Prepared By: Product Safety Department Date issued: 04/22/2004 Version Number: 1.9

.C , , I

.2

. , -7 " - -

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000

.12/12i 071

- BETZDEARBORN MATERIAL 'F4etwidj1-t&

Il

. SAFETY DATA SHEET EFFECTIVE DATE

25-FEB-1997 PRINTED DATE: 25-FEB-1 997 I1

- 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION It PRODUCT NAME: BETZ 860 Al PRODUCT APPLICATION AREA: WATER-BASED DEPOSIT CONTROL AGENT.

COMPANY ADDRESS:

-BetzDearborn Inc.

.1 4636 Somerton Road, Trevose, Pa. 19053 Information phone number: (215) - 355-3300 A EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA)

.1

- 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD GOMMUNICATION STANDARD is listed. Refer to I1 additional sections of this MSDS for our assessment of the potential

-. hazards of this formulation. Il HAZARDOUS INGREDIENTS:

CAS# CHEMICAL NAME I TRADE SECRET INGREDIENT(E195) ;TSRN 125438 -

Irritant (eyes) -

5118P A

TRADE SECRET INGREDIENT(122); ;TSRN 125438 - 5214P Potential irritant (eyes)

TRADE SECRET INGREDIENT(222);TSRN 125438 - 5238P D

Oxidizer; corrosive; pulmonary damage; dental erosion Ii No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the.. 11 Occupational Safety and Health Administration at OSHA thresholds for carcinogens.

1 l1 ii PAGE 1 CONTINUED Ii 072 j1

F PRODUCT NAME: BETZ 860 I

EFFECTIVE DATE: 25-FEB-1 997

3) HAZARDS IDENTIFICATION

.,I.

L

• .*******E**E****G******NY*****E***V******,*********************4***************

........................ EMERGENCY........................OVERVIEW................................

. 1

_ WARNING May cause slight irritation to the skin. Severe irritant to the eyes. Vapors; gases, mists and/or aerosols cause irritation to the I upper respiratory tract. ' - ..

L DOT hazard: Corrosive to steel Emergency Response Guide'#154 -

.F Odor: Acid; Appearance: Yellow'To Dark Brown,`Liquid Fire fighters should wear positive pressure self-contained breathing IF apparatus(full face-piece type). Proper fire-extinguishing media: -  :..

dry chemical, carbon dioxide, foam or water '.

• • 4*4***4**P****ENT***I*A*L**4E***F**********4F****4*****4**************4********,***4*41 POTENTIAL HEALTH EFFECTS . .~ . F ACUTE SKIN EFFECTS:

L.;

F I I - I Primary route of exposure; May cause slight irritation'to the skin. 1 5 , , "

ACUTE EYE EFFECTS: 'S, Severe irritant to the eyes.

ACUTE RESPIRATORY EFFECTS:

Primary route of exposure;Vapors, gases, mists and/or-aerosols

--. L..

... .t .,~1 cause irritation to the upper respiratory tract.

INGESTION EFFECTS:

May cause slight gastrointestinal irritation.

k. .[

TARGET ORGANS:

Prolonged or repeated exposures may cause primary irritant II.1. I! 1: .1 ...I

. Li

. . I dermatitis and/or toxicity to-the lu'n6g. ' -

. : , I I MEDICAL CONDITIONS AGGRAVATED:

Not known. -'-. . ' ' - i- '- '.: '

SYMPTOMS OF EXPOSURE:

Inhalation may cause irritation of the respiratory tract. Skin

' - I.-:

contact may cause itching and/or redness.

L LI i 2 l :AG E 2 CONTINUED

.  ! i 073 L

- -U-PRODUCT NAME: BETZ 860 EFFECTIVE DATE: 25-FEB-1997

4) FIRST AID MEASURES SKIN CONTACT:

Remove contaminated clothing. Wash exposed area with a large 1'I quantity of soap solution or water for 15 minutes.

EYE CONTACT:

Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.

INHALATION:

Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive victim.. Do not induce vomiting. Immediately contact physician.

Dilute contents of stomach using 3-4 glasses milk or water.

- 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS: It Fire fighters should wear positive pressure self-contained breathing '

apparatus (full face-piece type).

EXTINGUISHING MEDIA:

dry chemical, carbon dioxide, foam or water Al HAZARDOUS DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

FLASH POINT: l

> 200F P-M(CC)

MISCELLANEOUS:

Corrosive to steel UN3264;Emergency Response Guide #154

6) ACCIDENTAL RELEASE MEASURES a PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and 11 absorb on absorbent material. Place in waste disposal container.

Flush area with water. Wet area may be slippery. Spread sand/grit.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementa permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.

Il PAGE 3 CONTINUED 074 J

L EFFECTIVE DATE: 25-FEB-1997 PRODUCT NAME: BETZ 860

. ..1. .

7) HANDLING AND STORAGE :FrA, HANDLING:. i Contains anoxidizer. Avoid all contact with reducing agents, oils, . F, greases, organics and acids.

L STORAGE:

Keep containers closed when not in use. Use approved containers only. Store in cool, well-vented area; Contact with metals may release flammable hydrogen gas.

L

---

1-;

8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME TRADE SECRET INGREDIENT(E195);TSRN 125438- 5118P _. . ,

,r

, t

.PEL (OSHA): NOT DETERMINED ,

TLV (ACGIH): NOT DETERMINED ...

' i.;

-TRADE SECRET INGREDIENT(122);;TSRN 125438- 5214P M

• t- - .

a ' -.  :  !

PEL (OSHA): NUISANCE DUST ., .;  ; . _.

TLV (ACGIH): 5 MGIM3 . --  : , . .. - . --.

MISC: Note: manufacturer's recommended exposure limits 10 mg/m3.

0, E. '. . S_

' t ' 'I;>

' - .t TRADE SECRET INGREDIENT(222);TSRN 125438- 5238P t, . - .

PEL (OSHA): 5 MG/M3(10MG/M3-STEL) ' ' -' ' . ,  :'; '. [_,

TLV (ACGIH): 5 MG/M3(10MG/M3-STEL)

• L ENGINEERING CONTROLS:-

Adequate ventilation to maintain air contaminants below exposure - ,-

limits. I-.

PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION: ,

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER'

- ' ,r F

WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

An air-supplying respirator (positive pressure full ' , -

facepiece) may be needed for this product.

SKIN PROTECTION:

neoprene gloves-- Wash off after each use. Replace as I.

necessary.

EYE PROTECTION:

splash proof chemical goggles L

I!

LdAGE 4 , ' CONTINUED L

075

PRODUCT NAME: BETZ 860 It EFFECTIVE DATE: 25-FEB-1997 it

- 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F) 1.098 Vapor Pressure ('mmHG) - 18.0 lt

..Freeze Point (F) 26.00 Vapor Density (air=l) < 1.00 Viscosity (cps 70F) ND i Solubility (water)

II 100.0 Odor Acid Appearance Yellow To Dark Brown Physical State Flash Point (F)

-pH As Is (approx.)

Liquid

> 200 1.4 P-M (CC) I

. Evaporation Rate (Ether=l) < 1.00 I.

NA = not applicable ND = not determined

.1

, 10) STABILITY AND REACTIVITY STABILITY:

Stable under normal storage conditions.

I HAZARDOUS POLYMERIZATION:

Will not occur.

INCOMPATIBILITIES:

I1 May react with organics or alkaline materials.

DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:

"D" II

11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: >2,000 mg/kg 11 NOTE - Estimated value Dermal LD50 RABBIT:

NOTE - Estimated value Inhalation LC50 RAT:

>2,000 mg/kg.

>2,000 ppm/hr ii NOTE - Estimated value 1

12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY No Data Available.

BIODEGRADATION COD (mg/gm): 443

-I TOC (mg/gm): 203 BOD-5 (mg/gm):

BOD-28 (mg/gm):

381 505 II

'AGE 5 CONTINUED I1 076

-I

PRODUCT NAME: BETZ 860

-FFECTIVE DATE: 25-FEB-1997 - -. .. I . .. ... -... -. - .

113) DISPOSAL CONSIDERATIONS .iii If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is :< .

L D002=Corrbsive(pH, steel). -

Please be advised; however, that state and local requirements for

• waste disposal may be more restrictive or otherwise different from 7... F L. federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14) TRANSPORT INFORMATION L DOT HAZARD:

UN / NA NUMBER:

Corrosive to steel UN3264

.>jF DOT EMERGENCY RESPONSE GUIDE #: 154 L15) ROO REGULATORY INFORMATION TSCA: ['.

All components of this product are listed in the TSCA inventory.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

9,111 gallons due to (122);5,466 gallons due to (222);

I SARA SECTION 312 HAZARD CLASS:

Immediate(acute) ,Delayed(Chronic)

SARA SECTION 302 CHEMICALS:

CAS# CHEMICAL NAME TRADE SECRET(222)--INORGANIC ACID L

SARA SECTION 313 CHEMICALS:

CAS# CHEMICAL NAME . RANGE TRADE SECRET(222)--INORGANIC ACID 2.0-5.-O 1;ALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC

ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT: [:-

No regulated constituent present at OSHA thresholds L.

MICHIGAN REGULATORY INFORMATION 1:

No regulated constituent present at OSHA thresholds L

PAGE 6 CONTINUED 077 L

-Ii-

,,PRODUCT NAME BETZ 860 I.

- EFFECTIVE DATE: 25-FEB-1997.

.I

- 16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION 11 Health 2 Moderate Hazard Fire Reactivity i

0 Slight Hazard Minimal Hazard 11 Special. CORR DOT corrosive (1) Protective Equipment B3 Goggles, Gloves

• (1) refer to section 8 of MSDS for additional protective equipment A

recommendations.

-1 i CHANGE LOG IN EFFECTIVE DATE REVISIONS TO SECTION:

. MSDS status: 22-AUG-1995 *REVISED FORMAT SUPERCEDES

• • NEW **

II 28-SEP-1996 3,5,14 22-AUG-1995 25-FEB-1997 12 28-SEP-1996 -1 ii

,1 II I.

.1

-1 WGE -7 078 1

5AMM 3Z. 12-5 ALC -: . -MATERIAL SAFETY DATA SHEET NALC PRODUCT COAGULANT AID 35

- a EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC I1. CHEMICAL PRODUCT AND COMPANY IDENTIFiCATION PRODUCT NAME: COAGULANT AID 35 COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S):. (800) 424-9300 (24 Hours) CHEMTREC NFPA 704MI/HMIS.RATING HEALTH: 0 /1 FLAMMABILITY: I1 -INSTABILITY: 0/0 'OTHER:

0 = Insignificant I = Slight 2 = Moderate 3 = High - 4 = Extreme - -

12. l COMPOSITION/INFORMATION ON INGREDIENTS -

Our hazard evaluation has Identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).

Hazardous Substance(s) CAS NO  % (wlw)

Quartz, crystalline silica 14808-60-7 1.0- 5.0

3. HAZARDS IDENTIFICATION

• • EMERGENCY OVERVIEW" CAUTION May cause irritation with prolonged contact Inhalation of crystallinre silica can cause silicosis.

Do not get In eyes, on skin, on clothing. Do not take Internally. Do not breathe dust Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash Immediately with plenty of soap and water.

Not flammable 'or combustible: Water In contact with the product will cause slippery floor conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

EYE CONTACT:

Particles may scratch eye surfaces or cause mechanical irritation.

SKIN CONTACT:

May cause Irritation with prolonged contact INGESTION:

Not a likely route of exposure. No adverse effects expected.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 1/8 079

MATERIAL SAFETY DATA SHEET PRODUCT ., 1' 0NALCO COAGULANT AID 35 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC A

INHALATION:

Repeated or prolonged exposure may irritate the respiratory tract. May cause irritation of mucous membranes.

SYMPTOMS OF EXPOSURE:

IL Acute:

A review of available data does not Identify any symptoms from exposure not previously mentioned.

Chronic:

A review of available data does not Identify any symptoms from exposure not previously mentioned.

"I AGGRAVATION OF EXISTING CONDITIONS:

Prolonged inhalation of product can increase lung injury in persons with emphysema, asthma, or other lung IL disorders.

4. l FIRST AID MEASURES-' A EYE CONTACT:

Flush affected area with water. If symptoms develop, seek medical advice. IL SKIN CONTACT:

First aid is nomnally not required. If symptoms develop, seek medical advice.

INGESTION:

Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If symptoms develop, seek medical advice.

INHALATION:

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

NOTE TO PHYSICIAN:

I Based on the individual reactions of the patients the physician's judgement should be used to control symptoms and clinical condition.

5. I FIRE FIGHTING MEASURES FLASH POINT: None -I EXTINGUISHING MEDIA:

Not expected to bum. Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

I Not flammable or combustible. Water in contact with the product will cause slippery floor conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: -I

.1 In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

I Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 2/8 A 080 I1

MATERIAL SAFETY DATA SHEET PRODUCT

^tNALCO COAGULANT AID 35 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC l6. l ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Notify appropriate government, occupational health and safety and environmental authorities. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).

METHODS FOR CLEANING UP:

Sweep up and shovel. Reclaim Into recovery or salvage drums. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). Water In contact with the product will cause slippery floor conditions.

ENVIRONMENTAL PRECAUTIONS:

Do not contaminate surface water.

7. HANDLING AND STORAGE HANDLING:

Do not take internally. Ensure all containers are labelled. Avoid eye and skin contact -Avoid generating dusts. -

STORAGE CONDITIONS:

Keep in dry place.

I EXPOSURE CONTROLSIPERSONAL PROTECTION I.

OCCUPATIONAL EXPOSURE LIMITS:

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are , -

shown below.

ACGIHfTLV:

Substance(s)

Respirable Nuisance 1WA 3 mg/m3 Particulates i-Inhalable (Total) Nuisance TWA: 10 mg/m3 Particulates Quartz; crystalline silica TWA: 0.1 mg/m3 0.1 mg/m3

• OSHAIPEL:

Substance(s)

Respirable Nuisance TWA: 5 mglm3 Particulates Inhalable (Total) TWA: 15 mg/m3 (total dust)

Nuisance Particulates Quartz, crystalline silica 'WA: 0.1 mg/m3

- ENGINEERING MEASURES:

General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are I generated.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000 3/8 081

it MATERIAL SAFETY DATA SHEET ,

PRODUCT 04NALCO COAGULANT AID 35 11 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC 11 RESPIRATORY PROTECTION:

An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. If dusts are generated, use an approved air-purifying respirator. A dust, mist, fume cartridge may be used. If respiratory Il protection is required, Institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.

HAND PROTECTION:

lI Nitrile gloves, PVC gloves, Neoprene gloves, Rubber gloves, Butyl gloves, Cloth gloves SKIN PROTECTION:

Wear standard protective clothing.

Il EYE PROTECTION:

Wear safety glasses with side-shields.

HYGIENE RECOMMENDATIONS:

Keep an eye wash fountain available. Keep a safety shower available. I

9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Powder I

APPEARANCE ODOR Light grey None A

SOLUBILITY INWATER pH (5 %)

Insoluble 8.5 -10.5 Ii Note: These physical properties are typical values for this product and are subject to change.

10. I STABILITY AND REACTIVITY IH STABILITY:

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur. -I CONDITIONS TO AVOID:

Moisture MATERIALS TO AVOID:

Ii None known HAZARDOUS DECOMPOSITION PRODUCTS:

I Under fire conditions: None known Nalco Company.1601 W. Diehl Road - Naperville, Illinois 60563-1198 Ii (630)305-1000 4/8 I1 082 I

MATER .IA SAEYDT HE MATERIAL SAFETY DATA SHEET PRODUCT

. NALCO I 1 ., t COAGULANT AID 35 EMERGENCY-TELEPHONE NUMBER(S)

I--n -n none -e -us .. . .P=TU

• -- -U4Z- 1800u Z41nHuM NOUm) C I REX

11. TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product.

L CARCINOGENICITY:

Contains crystalline silica (quartz or cristobalite). The International Agency for Research on Cancer (IARC) has evaluated crystalline silica (inhaled Inthe form of quartz or cristobalite from occupational sources) and found It to be a human carcinogen (Group 1)based on sufficient animal data and sufficent human evidence. The National Toxicology Program (NTP) has evaluated crystalline silica and found it may be reasonably anticipated to be a human carcinogen. Overexposure to the respirable dust (less than or equal to 5 microns in size) may lead to silicosis, which is a progressive and Irreversible lung disease.

112. lECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS:

No toxicity studies have been conducted on this product.

If released into the environment, see CERCLNSUPERFUND in Section 15.

13. l DISPOSAL CONSIDERATIONS -

L If this product becomes a waste, It Is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since It does not have the characteristics of Subpart C, nor is It listed under Subpart D.

As a non-hazardous waste, It is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.

114. I-TRANSPORT INFORMATION * .- .;' l The information in this section Is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION

- I *, -, - I AIR TRANSPORT (ICAO1IATA):

!~~~ ~  : I Proper Shipping Name: PRODUCT IS NOT REGULATED DURING

-: . TRANSPORTATION -

MARINE TRANSPORT (IMDG/IMO):

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 5/8 083

-1 -- - - -

NALCO . MATERIAL SAFETY DATA SHEET I AWLCO PRODUCT- . I COAGULANT AID 35 0 EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) CHEMTREC 11 IL Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION 115. 1REGULATORY INFORMATION 1. I1 NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Ii Based on our hazard evaluation, the following substance(s) in this product Is/are hazardous and the reason(s) Is/are shown below.

Quartz, crystalline silica: Cancer suspect agent (refer to Section 3) Ii CERCLAISUPERFUND, 40 CFR,1 17, 302:

Notification of spills of this product is not required.

SARAISUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE ll) - SECTIONS 302,311, 312, AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.

X X

Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard Fire Hazard I

Sudden Release of Pressure Hazard Reactive Hazard A

Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:

When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.310 Boiler WaterAdditives, 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods.

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15) formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311:

-1 None of the substances are specifically listed in the regulation.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198

-I (630)305-1000 6/8 084 J

I

MATERIAL SAFETY DATA SHEET

~NALCO EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC CLEAN AIR ACT, Sec. 11 1(40 CFR 60, Volatile Organic Compounds). Sec. 112 (40 CFR 61, Hazardous Air

- Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances):.

None of the substances are specifically listed Inthe regulation.

L This CALIFORNIA PROPOSITION 65:

product contains the following substances which require warning under California Proposition 65. -

IConcentration IEFFECTS

-*Quartz, Substance(s) crystalline silica I5 I Causes Cancer

- MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed Inthe regulation.

LSTATE RIGHT TO KNOW LAWS:

The following substances are disclosed for compliance with State Right to Know Laws:

Quartz, crystalline silica 14808.60-7 NATIONAL REGULATIONS, CANADA:

I WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified Inaccordance With the hazard criteria of the Controlled Products Regulations.

(CPR) and the MSDS contains all the Information required by the CPR.

L WHMIS CLASSIFICATION:

D2A - Materials Causing Other Toxic Effects - Very Toxic Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances inthis preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.

1 16. 1OTHER INFORMATION This product material safety data sheet provides health and safety information.. The product isto be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this Information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further Information.

REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (AMel Insightm CD-ROM Version), Ariel Research Corp.,

Bethesda, MD.

Nalco, Company 1601 W.Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000

-718 085

MATERIAL SAFETY DATA SHEET PRODUCT I

^NALCO

.. S .

COAGULANT AID 35 It EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) CHEMTREC Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM 11 Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Ii Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Il Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service. Il Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Arel Insight# CD-ROM Version), AMel Research Corp., Bethesda, MD. A Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Ariel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

Ii North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Adel lnsight#'CD-ROM Version), Ariel Research Corp., Bethesda, MD.

A The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewbod, CO.

A Prepared By: Product Safety Department Date issued: 02/21/2004 J

Version Number: 1.6 Ii A

11 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 I

(630)305.1 000 8/8 J

086 I

-- T - FOR INFORMATION ONLY Expires On:

i.4swigncu ...

73263(E. /9 p/a5-SODIUM EWPOC:oMIRE SOLtION

>,-lm-MANUFACEUREWS NAME: MA:EREGAN C-E. CALS DION O EE (US mC EMERGENCY TLEPONE NMBER: 80"424-300 (Chmemfec)

• 4 Ho ndzy,7danyavk ADDRESS: - 532 EAST EMAuJS sTnumT P.O. BOX280

• MIDDLETOWN, PA 17057

... 800-283-0326 DATE OF REVISION: Septemberl9, 1998 2 -CoMnpnosMonAfrtfonrnriiotn tr TRADE NAME: SODIM MOCHLORXTE 15% Cli VOL ConDonel.tr:

Sociam HiypocthorireSolmdon - C4SNmber: 7681-52-P CONTAINS: CAS N-LMMBFU PERANTAGI PEUILV-SOURCE Sodium Hydroxide 1310-73-2 . 2to2.4 PM 81-2m&0) OSBA TLhV 8hr2mp(3) CZehrACGIH Chloie (Avaable) 7782-50-5 - A ox. r 10 OSHA (EL)

• TWA-0.5ppm STL- I ppm ACGIH (ILV)

TWA - 0 ppm STEL- I ppm Watew 2732-18-5 .AP-r- 89 I "..

• +*tt*r+*t~ttttttt*t********.t~wt~t************ I *+e**

SynmqmCommanNamcs § .hiozine BIeahb, Soda Bleaci, Liquid CIlozine ChCmial FomMla- Nbc!

DOT PopppNm a. 3OcaIorite Soiutlons DOT *d Claw -m-DOT D Numbev. U- 791 DOTPadg Group:-

DOT Hbardous Subtanea I off 0, ('Sodm Hypodhlorie)'

OTAMaiDesPomhxtu+/- N/A AddtrnID es =i~ nReuri  ; - -N/A Pap1e5 of 5 087

Assigned to: ??7? FOR INFORMATION ONLY E O pne 2 of5 Ii 3 P 299a-11 Bomlngpobw (@760 mnzHg Decoipossab~yw I10 DeS C(MODeg F) Al

.Frcezing polnt Weigt%

10 12 Freeg Point Deg P

-3 7

Il Vapl= PresSUr Teperature Deg F 4&2 .

aHn 3.7 PSIA 0.071 Il 60.8 8.0 0.1S 60 89.6 118.4 12.1 31.1 100.00 .

0.23 0.60

.9:3 D

Specific Gmvity. Approxiniately l.li A SolubilityinMD~z (ByWei&) 100%

9-12 D AppmnceOdoz. Colorless to lighyellow-green liquid waithneoi=lke odor.

I 4- Km =rr-naan Fmt 7TtA M P-cedura EYES: Imediatly flish eys with flowing water for at least 15 mhnutes. Washing cyes with one (1) minute is essenti to achieve maximum effectiveness.

SERIAE ICALAT I7H0NZ EDJTELy.

D SKIN., Skin conM=rm y cause severe irrtation. Flush tboroughly ith cool water under

• sower ite r:mzvg cont8miated clothing and shoes. Disiard non-rdbber.

shoes. Wash clothing beafiv es . Cotintz to flush until medical attention amves

• SEEZ MEDICAL A27ZN7OND0WE4TZY. D RINALAMMION: Remove to frsh air. Ibreating is dificlt, hae a qualified person administer

.oyeM. Ifiespiaion stops, give m hUtobzn; GET £ DrAITEM AC;AL{TTA E ON.

h resusitad=on.

. I II INGES11ON; N~ever giie asntg by mouth to aaumconscios perso If SWa11OVMd, DO NOTF VDUCE OMMOYG. Give large quandties ofmll- Ifthese are not availab'ol, give large qntitiesf water. If vomit otcrs spoteLsly keep airwy clear and give more milk or wat Avoid vcmiting, lava or aciic atidot GETMM CAL 472W Il I7JON1fl DL.I F. l Dion TO Sodium Hypochlorfte Isan alkmline corromive. For exposure by' fngestion do not we emests, lavage or acidic anidotes. Diuxte immedlitely by gvig mf1k mcited Ice cream, beaten egg wthte; starch pastc or antacids such as milk of magnes, almninum bydroide gel or mgnesium triscite gel Avoid sodium bicarbonate because of carbon dioxide release. Sodium thiosulte solution may prove beneficial by reducing Kmreacted materiaL 088

Assigned to:???? -FOR INFORMATION ONLY ExpWes On:l

. . . eo5

_' 3saf

• INHAA77ION. Iala~on ofhypoulor aadd ftmcs may cause e esr cpi ct i Dt SKN: Skin 0ntamy ca s=s ee irtaionad c b=i.

_ EYn CONTACT: Eyc conmtac m ca severe fizftion, bums anudo? cotrosion.

INGESIION: 1Qgestion=ay.cauSePint ardnflamC of e ou an digestie system, bw and perfoffrion ofthe wsbhagus or sto=m=h, vomiting, irctOry col12ps.t confuiion, delirium and omt EiCS OP OVEREXPOSURE: -

ACUTE: Courosye and strongl iaitatg to he eyes, ld, ad spfirory trct Inhalio of fumes may cause pulmonary edem. Ikgestion may cause burns to the mou&

L CHRON.C CHRONIC: '

and sve tnt and abdomizal distess.

,1 D0>ala.

L s- Fire xrd '1niv,,to )Tr=zrd Da: -.

FLAdi PON (-.es: method): - Won-Flmlee-  :

AUOIGNlllOI TEMPERAIURE: None FLtAMABYLAMiTS INAMR None

• NIA MEL TEL;. N./A EXflNGUISTIG MEPILA, Use water spray, fog, foam, dry chemicaL or carbon dioxide or ag=its stitable fornmatials in surrmdn ae.

SPECAL mE PITING PROCEDURES: Avoid fincs fim spilled or exposed liquid, dfut copiously. verte arnd bc pepared to use respiratoyprotectior ifneeded. Use slf-contaned braing apparatus andhfll prativeeqaipmet Acid contamination w pwoducc very irritating fumes gimi to chi 'ine.

UNUSUAL FIRE AND ExpLOSIONHAZARD:' Product decomposes when heated =nd may cause contains to npture or explode. Vigorous reaction spossible with organic mateiatls or oxidizbng lageatsanddrmytCsult infIY

- CONDMONS CONTRIBUING TO INSEAM lY: Srg oidizer, stiy decrewses with concerh, begt, lisht decre in inpHfdand ePR INCOMPAIBUMY: A*void cont i=vio wtevymeals, h ucngagets, etbe4,*mmoniandzcids HAZARDOUS DEOOMPOTN PRODUCTS: Acid fumes c DTIONs CONTBusuG To RAZARDOS PoLY uzATIVN Mateia is not Inown t

-o merze.z 089

Expirez On: ?

d FOR INFORmATION ONLY ---- O-

- Speia Emffau VnMLAJIONREqUIR4s RBM TR- 'M SU Dea Mb rviego fzio lslca xas a onso used as p caluioazveasw e ab ontamts may oacir.

M.E:.Wcr chbical sa ewggles phs fiunce shield to Protect asgist splashng wiiapproptri GLOVS: W mpervius glovesxh asrubber, neoprenc zrvinyl.

O0TE CLOT JGL ANDEQUlPiME We.a im iousptctive clotiginclu g e apron or run.

suit and boots to avoid bodily conact Eye wash ficilfyr ad rgecy shcw:r should bi in c0sa promhity.

- larndflny'andStra,,,e HNDaNG ANp STORAGEPJECAVInONS: Do not store adjacent to chemicals thatmay ret ifspillag1e occxs. Comply with DOT repuations when sbipped. Ifclosrdcon.an co_: >.ct v- ce-sc dtcc03>osiou po:d0:rs(yom ys, dcc~pos.iron). 30o to-r.'e:oa! rIx orlCC3'.: Win'h w amor4*

bydrcczrbons, acids, -1cobol's c: Ct3e1.

DO NOT REUSE CONsTANERSt Product resdues ay rean n contabe All JlaBeed p:ecamiowmust be observed. Dspose ofcothaiver in c -- ner meeting governamnt regulzi~os.

PRODUCTDSPOSAL: Productshould b copletelyrmovedftor containem Materi t annotbewused or chemca]y reprocessed should be disposed of i a manner meetiag governmeat regup ion .

STEpS To 3B TAxIWMATEPJAL 3S P4ELASED$CRSMPL.- Do io? aOwsiled mateda to e sewars or s Flush Wh water to dilute as mucb as pomble and p'p imto pokyathylene conub= for m

disposmL Aoid et and ccmaoo id cdmatal Donot 2u c se mate s as sawdstto absorb Sodium Hypochlofite Sol&tion.

WAShDMIPOSALMETOD cc h agenssuchas biites rf altsoins. Som hoar wi be produced. Kep on alkline side and Mate with copious Inonr Of waw. Main endproduct is salt W-Ater.

Comply Wid al applicable goMve regulawions= . ,,

II - Thxecogo~etrl rflormaIoxn,.**

TOXICOLOGY DATA.-

The wxicity and c rosivity of Sodim Hypochlorie is a fimrtton of cfceir3L IndasftW grades of hgeaconenuutinns tan bousehold blae arc more toxic and r=sIve.

Aq~Todc~ty~tin~-

Pim e s 1.19 ppm.

96hr. LC0S

. Sodium ocb 124 Oral LDS) TesaRcaslt 5.0 . .

Sodiuznypodhloti Q1 5.25% (Ra, OMulD50) TestResult: 13.0 gft 090

Expires On:

FOR INFORMATION ONL

. I x I.,

• i.4ddrwmz11j&

s blend does not cob am substance subjct to the TIhshold Plnnig Quantity MO rUirc esfSeCtd 313 of tiVac ' -

CONTAiNERDISPOSA'L: Izpos iaJcstoedf . Rc==mmed cn= kg roorimeans to pr imautborized reuse, NSF IS: NSmaim=Difiu* WaterUsc COnce=21ion, IOOxaIlas Sodi'n= ypod2:ozh.

Tbe finished d ng Watcr shold kb me~tiwozdf r d fectic by-products in.

-waccordhncewi ste and US. E.P.A. regulatons and dcline& Levels of clolite ion end chlorateion sjhonidno: eced 10 ppb. -. -- .

USDA APPROVAL This product is accepable as a sanizer for all surfaceswt always reqtizg &

rinse i ofEcial cstbishnns operating inder the Federal m 4apouty, shell egg and egs iroducts inpcctonpograwi. . I Secvon 31 1 of The Cean Water Act lists this product as a hazardous substnce wbich, ifdiscbarged to, sat, nayroqui immediate rsc to mibg3ate dgSerto publie h ealia.nd we!d . _ .J.s of 10C L p SSO2 o---

=c:n%-. ust brpct.d :o zc X'2onal Rtsrons- Cznter at he-loto" g-r. SD -42 Matexdai is contained. ot a crmposite list as regqurd tmder 101 (14) of CERC---

L Sodium Rypochlodtit Solution is regulated by the 7JSPA uder the Federal b'secticide. Fangcide and RodenticideAcd ( A) as apesticeldcPoduct. -

DiSCLAMA: The infomufon ad reowmdatios tre offrr for the uszs csderation ai cranntjoS, and it Is tite useea aupokn-lty to satisj~IIatht thbey are svnible and Complete for it partiular wae. If bqyer relbels this prodanc, goa CouQ should be cosulted to iure proper bes.tb, safety snd other rcasry informaidon Is Iucluded oan te contalner.

Mankey-Rcg2n CbemircAs prvrIdes no Wartants, ther e*p*rsed or implIed, nd asmes no responsiblity for the sectn or complteness of the data contained hertl-.

Trebbov infortoni compie wit the OSA's hard comun tion stndard 29CMl91.1200. The standard =ust be co3snhetd 1ou specisc t,.ul. e.. ...

091 L

I IL-9 AgrEvoo Material Safety Data Sheet IL A company of Hoechst and Schering, Berlin '9Za.fS Page: 1 of 8 Issue Date: 07/28/98 Supersedes: 02114196

.1 11 NUSYN-NbXFISH9 FISH TOXICANT..

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Il AqrEvo Environmental Health 95 Chestnut Ridge Road Montvale, NJ 07645 I1 COMPANY CONTACT: Regulatoty Department TELEPHONE NUMBER: (800)438-5837 EMERGENCY TELEPHONE NUMBER IdUQ4il-0660

-I PRODUCT NAME: NUSYN-NOXFISHR PRODUCT CODE: B467413 CHEMICAL NAME: Mixture; a.L.'s, rotenone and piperonyl butoxide FISH TOXICANT D

EPA REGISTRY NUMBER: 432-550 MSDS IDENTIFICATION CODEINUMBER:- B467413 Nusyn-Noxfish is a registeredtrademarkof AgrEvo EnvironmentalHealth, Inc. Ii PRODUCTDESCRIP770T : Nusyn-Noxfish Fish Toxicant is a restricteduse pesticide to be used in fisheries managementfor the eradication of fish from lakes, ponds, reservoirs and streams.

SECTION 2. COMPOSITIONIINFORMATION ON INGREDIENTS CONCENTRATION INGREDIENT NAME - EXPOSURE LIMITS PERCENT BY WEIGHT Rotenone CAS NUMBER: 83-79-4 AbGIH TLV-fl1A 5 V/m3.

OSHA PEL-TUA 5 mg/M3

= 2.5 _i Ii Piperonyl Butoxide, technical None established = 2.5 CAS NUMBER: 51-03-6 Other associated resins None established = 5 Other ingredients, including:

Ii Aronatic petroleun solvent 100 ppD (Manufacturer recomomended) < 85 CAS NUMBER: 64742-94-5 D

SECTION 3. HAZARDS IDENTIFICATION A clearto brown fiquid with a nild odor.

• Fatalif inhaled.

mRG.Cy OVIRVIEW *****************************

D

• May be fata if swallowed

• Harmful if absorbed through skin.

• Causessubstantialbut temporary eye injury.

• Causesskh iritaton.

ii

• Combustible mixure.

• This pesffcide is extremely toxic to fish.

POTENTIAL HEALTH EFFECTS

-I I

092 I

Page: 2 of 8 Issue Date: 07/28/98 Supersedes: 02/14/96 NUSYN-NOXFISHl FISH TOXICANT SECTION 3. HAZARDS IDENTIFICATION -_Continued L PRIMARY ROUTE(S) OF ENTRY Inhation, gestion, sn and eye contact. -,:

EYES causes substantial but temporary eye injury. -

SKIN Causes skin irritation.;

INGESTION

-May be fatal if swallo wed.

INHALATION Fatal it inhaled.

SECTION.4. FIRST AID MEASURES .

EYES

- l73dWeyelids open and flush with a steady, gentle stream of water for 15 minutes. Getmedical attention.

SKIN L Waish with plenty of soap and water. Get medical attention.

INGESTION Promptly drink a large quantity of milk, egg white, gelatin, solution or if these are not avai7able, large quantities of water. Avoid alcohol Do not induce vomiting. Cal a physician or Poison Control Center.

INHALATION Remove victim to fresh air. If not breathing, give artficial respiration, preferably mouth to mouth. Get medical attention.

NOTE TO PHYSICIAN f . .

Tnis product is highly toxic when spray mist is inhaled, moderately toxic by the oralroute and slightly toxic by the dermal route. This product causes i substantial but reversible eye irritation. Initial treatment is removal of exposure by washing, emesis or lavage and is followed by symptomatic and . . .1 I .

supportive care. . .

- ,t ,

7 I .

SECTION 5. FIRE FIGHTING MEASURES ,

FLAMMABLE PROPERTIES FLASH POINT: 115'F 460C TCC FIRE AND EXPLOSION HAZARDS Keep away from sources of ignitron.

EXTINGUISHING MEDIA

-fog, foam, carbon dioxide or dry chemical.

FIRE FIGHTFNG INSiKUCTIONS ...

As in any ftire, wear se contained breathiny' apparatus pressure-demand,

_ MSHA/NIOSH approved (or equivalent an ful protective gear. Keep upwind.

Isolate hazard area. Avoid inhalation of smoke and funes. Use water or foam to reduce fumes. Do not touch'spll7ed material. If possible, move containers from area. Extinguish only if flow can be stopped. Use flooding amounts of water as a fog. Cool containers with flooding amounts of water from as far a distance as possible. Avoid breathing vapors.

FLAMMA BIULTY CLASSIFICATION/RATING:

093

Page: 3 of 8 Issue Date: 07/28/98 Supersedes: 02/14/96 1

NUSYN-NfOXFISHr FISH TOXICANT . A SECTION 5. FIRE FIGHTING MEASURES - Continued NFPA/OSHA Class: It NFPA Rating (fire): 2 SECTION 6. ACCIDENTAL RELEASE MEASURES GENERAL AND DISPOSAL Use properprotective equipment to minimize personal.

exposure (see Section dJ. Take allnecessary action to prevent and to remedy the adverse effect of the spill. Ensure that the disposalis in compliance with all Federal, State/Provincial, and local regulations [See Section 13 for applicableRCRA Number). Refer to Section 15 for applicableReportable Quantdty {RQ) and other regulatory requirements.

LAND SPILL OR LEAK Small Spills: Absorb lquid with an inert absorbentmaterialsuch as granularclay, saw dust, or pet litter. Sweep up carefully while avoiding A

the formation of a dust cloud. Place in an approvedchemical waste container for disposal. Rinse spill area with small amount of soapy water. Contain and absorb the rinsate with inert absorbents and place into the same disposal _

container. Area can be washed with water to remove the last trace residue. Do not allow water to contaminate watersupplies or sewers.

Large Spills: Eliminate all ignition sources. Stop leak if you can do so

vithout coming into contact with spilled material. Dike far ahead of iquid spill for later dsposal. All equipment used to clean up spll should be rounded. Prevent entry into waterways, sewers, basements or confined areas.

y m appropriateauthoritiesimmediately if contaminationoccurs. Contact Ag~rEvo for further assistance if necessary.

SECTION 7. HANDLING AND STORAGE HANDLING PRECAUTIONS

• Do not breathespray mist.

• Do not get in eyes, on skin or on clothing.

• Do not use near heat or open flame.

STORAGE PRECAUTIONS

• Do not store nearnear or open flame.

• Do not contaminate water, food or feed by storage.

• Store only in originalcontainers, in a dry place inaccessible to children and pets. Nusyn-Noxfish will not solidify nor show any separationat temperaturesdown to 40OFand is stable for a minimum of one year when A

stored in sealeddrums at 70"F.

WORKIHYGIENIC PRACTICES

• Wash thoroughly with soap and water after handling and before eating, I

drinking or using tobacco.

• Remove contaminatedclothing and wash before reuse. 11 SECTION 8. EXPOSURE CONTROLSIPERSONAL PROTECTION MANUFA CT7URING, FORMULATION AND OTHER NON-AGRICULTURAL USES ENGINEERING CONTROLS Control airborneconcentrationsbelow the appropriateexposure guideline (see Section 2 for applicable OSHA/ACGIH Exposure Umits). Local exhaust ventilation may be necessary.

EYE/PA CE PROTECTION Wear safety glasses, splash goggles or face shield.

094

- il

F Page: 4 of 8 Issue Date: 07/28/98 F!

Supersedes: 02/14/96 NUSYN-NOXFISbf FISH TOXICANT F SECTION 8. EXPOSURE COffTROLSIPERSONAL PROTECTION - Continued SKIN PROTECTION r

Wear chenucal-reststant gloves (Neoprene, Nitrile, PVCJ and other protective clothing to avoid skin contact.

RESPIRA TORY PROTECTION Ensure good ventilation. If not adequate, use a chemicalcartridge-type F

respiratorapprovedby the National Institute of OccupationalHealth and Safety.

GENERAL PROTECTION vi Eye wash tacility and safety shower should be avalable.

L SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES I APPEARANCE Clear, brown liquid.

ODOR Ir 7ildodor.

BASIC PHYSICAL PROPERTIES F.

L PHYSICAL STATE. Liquid p1: Not ava7able VAPO PRESSURE: Noravai7able VAPOR DENSITY (AIR=J7): Not available EVAPORA TON RA TE (BUTYL ACETA TE 7I: Ntot available 7..

SPECIFICGRAVI7YORDENSI7Y(G/MLJ: Not available PACKING (BULK) DENSITY (LB/GALJ: 8.25*

BOJUNG POINT/RANGE. 200 0 C MELTING/FREEZINGPOINTRANGE- Notavallable SOLUBIL17Y [IN WATER): Miscible

' F SOLUBILTY IN SOLVENTS/OIL (SPECIFIED): Not avalAable DUST EXPLOSION SEVERITY DATA: Not applicable MINIMUM IGNITION ENERGY (MJJ: Not available MIN/MUM EXPLOSION CONCENTRATION (MEC): Not available LiMMTED OXYGEN CONCENTRATION (LOC): Not available L SECTION 10. STABILITY AND REACTIVITY STABILITY: Stable COND m ONS TO AVOID (STABILITY)

None.

hI INCOMPATIBLE MATERIALS Strong oxidizing and strong reducing agents.

HAZARDOUS DECOMPOSmON PRODUCTS 1..J Carbon monoxide and carbon dioxide.

CONDmONS TO AVOID (POLYMERIZATION), .

Avoid excessive heat and ignition sources.

- . I Ii HAZARDOUS POLYMERIZATION:- Wll not occur.

[1 L

095

-I

It Page: 5 of 8 Issue Date: 07/28/98 Supersedes: 02114196 NUSYN-NOXFISH" FISH TOXICANT X SECTION 11. TOXICOLOGICAL INFORMATION ACUTE STUDIES TIH FOLLOWING DATA WERE DEVELOPED WITH: Nusyn-Noxfish Fish Toxicant.

EYE EFFECTS (Rabbit) Moderately irritating SKIN EFFECTS irritation (Rabbit: Moderately irnitating Absorption (Rabbit): LD50 > 2020 mgq/kg (slightly toxic)

Sensitization (Guinea Pig): non-sensitizing ACUTE ORAL EFFECTS Oral LIDO (Rat, temaleJ: 147 mg/kg (moderately toxic)

OralLD50 (Rat, male): 704 mg/ksg (salgtly toxic)

OralLD50 (Rat, overall): 561 mg/kg (sighdtly toxic)

ACUTE INHALATION EFFECTS 4-Hour LC50 (Hat, female): .041 ma/I (hihly toxic) 4-Hour LC5O (Rat, male): .059 mg moderately toxic) 4-Hour LC5O (Rat, overall): .049 mg/l (highly toxic)

NOTE: The severity classificationslsted above are those of AgrEvo, and, particularlyfor eye irritation, may not always coincide with EPA-mandated PrecautionaryStatements.

THEFOLLOWING DATA WERE DEVELOPED WITH: rotenone andpiperonyl butoxide, the active ingredients CHRONIC (CANCER INFORMATION) A Rotenone was not carcinogenic when tested in rats and mice.

A statisticallysignificantincreasein the number of benign liver tumors appearedin mice fed piperonyl butoxide technical at doses which far exceed any anticipateddaily human intake. Independent andindustry toxicological experts who have reviewed the data agree that the findings of the study do not indicate a health risk to human beings.

CARCINOGENICITY: NTP: No IARC: No OSHA: No JJ TERATOGENICITY (BIRTH DEFECTS)

Rotenone was not teratogenicor tetotoxic when tested in rats and mice.

REPRODUCTIVE EFFECTS Rotenone had no adverse effects on reproduction when tested over two successive generations in rats.

MUTAGENICITY (GENETIC EFFECTS} -

Rotenone was not mutagenic nor ciastogenic when tested in the Ames Test, Yeast Test, Mouse Lymphoma Test, Mouse Micronucleus Test, Chromosome Aberration Test and the Mitotic Recombination Test in Yeast.

SECTION 12. ECOLOGICAL INFORMATION ENVIRONMENTAL PRECAUTIONS:S This pesticideis extremel toxic to fish. l Fish kills are expected at recommended rates. Consult your State Fish and Game Agency before applying this product to public waters to determine if a permit is needed for such an application. Do not contaminate untreated water when disposing of equipment washwaters.

0I

• 096

-I

1-'.

Page: 6 of 8 Issue Date: 07/28/98

• r Supersedes: 02/14/96 NUSYN-NOXFlSHr FISH TOXICANT F SECTION 13. DISPOSAL CONSIDERATIONS Do nbt contaminate watter, food or feed by disposal.

Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper disposalof excess pesticide, spray mixture or rrnsate is a violation of federal law. If these wastes cannot be disposed of by use according to the labelinstructions contact your state pesticide or Environmental Control Agency, or the Hazardous Waste representativeat the nearestEPA Regional Office for guidance. -

Container Disposal: Triple rinse (or equivalent). Then offer forrecycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities.

F RCRA INFORMATION RCRA HAZARDOUS WASTE INGREDIENTS: None SECTION 14. TRANSPORT INFORMATION PROPER SHIPPING NAME: Pesticides, liquid,-toxic, flammable, n.o.s.

• (Rotenone, petroleum distlflare)

UE L HAZARD CLASS: 6.1, PG I SUBSIDIARY HAZARD CLASS: 3 LI DOT IDENTIFICATION NUMBER: £1N2903 L DOT SHIPPING LABEL: Poison and/or Toxic, NOTE: For transport purposes (49 CFR Part i73.732), the calculated 1-Hour LC50 (Rat, overall) is: . 196 mg/I 1.:

L SECTION 15. REGULATORY INFORMATION EC U.S. FEDERAL REGULATORY INFORMATION.

EPA Registration Number:, 4,32-bbo TSCA Inventory: registered pesticide, exempt from TSCA SARA TITLEX IllNOTIiCATIONAND IIFORMA TIOAP Section 302 (EHS) ingred7ants: None I

Section 304 (CERCLA & EHS) ingredients (RO): None Section 313 ingredients: None SARA TITLE III NOTIFICATIONS AND INFORMATION SARA TITLE III - HAZARD CLASSES: Acute Health Hazard - OYes' Chronic Health Hazard - ~No o Fire Hazard - OYes Sudden Release of Pressure Hazard - "No' Reactivity Hazard - 'No

_ SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION.

This Product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community.

I.,

Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:

CAS NUMBER INGREDIENT NAME 5703-6 Piperonyl uuroxide, technical -.

=

-PERCENT 2.5 BY WEIGHT LII This information must be included on all MSDSs that are copied and distributed for this material. .. ..

REGULATED INGREDIENTS 097 LI

I- it Page: 7 of 8 Issue Date: 07/28/98 Supersedes: 02/14196 NUSYN-NOXFISH"- FISH TOXICANT .

SECTION 15. REGULATORY INFORMATION - Continued REGULATED INGREDIENTS - Continued INGREDIENT: Rotenone CAS NUMBER: 83-79-4 PERCENT BY WEIGHT: = 2.5 Regulations: Illinois Toxic Substance _

Massachusetts Hazardous Substance New Jersey Special Health Hazardous Substance New Jersey Workplace Hazardous Substance Pe-nnylvania Workplace Hazardous Substance-INGREDIENT: Piperonyl Butoxide, tecni cal CAS NUMBER: 51-03-6 PERCENT BY WEIGHT: = 2.5 Regulations: SARA Section 313 Toxic Chemical U.S. STATE REGULATORY INFORMATION CALIFORNIA (Proposition 65): This product does not contain any chemical which is known to the State of California to cause cancer or birt defects or other reproductive harm.

CANADIAN REGULATORY INFORMATION CPC NUMBER: None .1 WHMIS Classification for Control Product Regulatons (CPRJ: Registered pesticide under US FIFRA regulations; exempt from CPR classification.

The MSDS contains al CPR required hazard-related information.

WHMIS HAZARD RATING: See HMIS rating (Section 16) 11 SECTION 16. OTHER INFORMATION HMIS HAZARD RA TING - HEALTH: 3 High.

- FIRE: 2 Moderate

- REACTIVI7TY: 0 Negligible

- PROTECTION: H NFPA HAZARD R4T7NG - HEALTH: 3 High

-RRE: 2 Moderate

- REA CT77lVTY- 0 Negligible

.- I

- SPECIAL MSDS IDENTIFICATION CODE/NUMBER: 8467413 .

PREPARED BY: Regulatory PHONE: (800)438-5837 SUPERCEDES MSDS DATED: 02114/96 DATE AND TIME OF PRINTING: 07/28/98 11:23:44 D MSDS Revision Indicators: Revisions made in Section' 1 (added trademarks and product description), Section 2 (added Other ingredient statement),

Section 3 (Emergency Overview), Section 5 (chanqed Flash Point and Fire Fighting Procedures and added Flammability Classification/Rating), Section 7 (changed text under each heading), Section 8 (changed text under each heading), Section 9 (Basic Physical Properties), Section 11 (changed the eye, skin irritation toxicity data, added to the acute oral and inhalation toxicity data, chronic toxicit data, added where the data was developed from and hatanial as ued n te sudy), Section 12 (Environmental Precautions), Section 13 Disposal Considerations), Section 14 (changed DOT 098

Page: 8 ofS -

Issue Date: 07/28/98 Supersedes: 02114/96 L NUSYN-NOXFISir FISH TOXICANT SECTION 16. OTHER INFORMATION - Continued L Shipping Label and added 7-Hour LC50) Section '75 (added Regulatory Information) and Section 16 (added HMIS Protection Code and Disclaimer).

DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES lths intormationis pro wded in good _a u wthout express or implied bur

- warranty. Buyer assumes all responsibility for safety and use not in accordancewith label instructions.

.1 I,,  : '?

.. . ,, I I

- . . . . . i I 7 099

&MM72

,7FM9 -

Emergency Phone: 317-80-282 I

ISePRQ I General Phone: 1-317-580-8282 EPA Reg. Number. 67690-3 Effective Date: August25, 1994 SONAR* SRP Herbicide 3;2. LI(4 - SePRO Corporation

• Carmel, IN 11 L I'St; -4e111 1 >4 HAZARDOUS DECOMPOSION PRODUCTS: Wili I I emit toxic vapors as it bums.

HAZARDOUS POLYMERIZATION: Does not occur.

1-Methyl3-phenyl-5-(3-(trifluoromethyl)phenyl)-

4(1H)-pyridinone (Flurkdone)

CAS# 059756 60-4 ............................... 5%

S.

. ~~. ~ ~ .3

! . 9

. 6.................

£ Ii Other Ingredients .95%

This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR ENVIRONMENTAL DATA: Follow use directions carefullyso as to minimize adverse effects on nontar-Ii 1910.1200). In addition, other substances not get organisms. IN ORDER TO AVOID IMPACT ON

'Hazardous' per this OSHA Standard may be listed.

Where proprietary ingredient shows, the identity may be made available as provided in this standard.

THREATENED OR ENDANGERED AQUATIC PLANT OR ANIMAL SPECIES, USERS MUST CONSULT THEIR STATE FISH AND GAME AGENCY OR THE A

U.S. FISH AND WILDUFE SERVICE BEFORE MAK-BOILING POINT: Not applicable ING APPLICATIONS. Do not contaminate water by cleaning of equipment or disposal of wastes. Trees and shrnbs growing in water treated with SONAR may A

VAP. PRESS: Not applicable be injured Do not apply in tidewater or brackish water.

• Do not apply in lakes, ponds, or other bodies of water VAP. DENSITY: Not applicable. where crayfish farming is performed.

SOL IN WATER: Insoluble, but disintegrates in water ACTION TO TAKE FOR SPILLS: Contain and sweep SP. GRAVITY: Not applicable up material of small spills and dispose as waste. Large APPEARANCE: Dark gray to dark brown pellet spills report to CHEMTREC and SePRO Corporation for assistance. Prevent runoff.

ODOR: Faint musty odor DISPOSAL METHOD Do not contaminate water, food pH: (aqueous 50/50) 3.5 or feed by storage or disposal. Wastes resulting from the use of this product may be disposed of at an JI approved waste disposal facility in accordance with FLASH POINT: Not applicable METHOD USED: Not applicable applicable regulations.

Ii FLAMMABLE LIMITS:

LFL: Not appricable ACUTE EXPOSURE (SONAR SRP)

UFL. Not applicable Eyes - Rabbitk irritant AUTOIGNMON TEMPERATURE: No ignition up to Skin - Rabbit, 2000 mg/kg, no deaths or toxicity, nonir-13820 F, 7500C ritant Inhalation - This formulation is not considered to be an EXTINGUISHING MEDIA: Use water, C02 or dry inhalation hazard due to pelleted nature of material chemicals. Ingestion - Rat, 500 mg/kg, no deaths or toxicity FIRE AND EXPLOSION HAZARDS: Will emit toxic vapors as it bums.

FIRE-FIGHTING EQUIPMENT: Wear full protective Sen'sitization - This formulation was not tested.

Fluridone technical is not a contact sensitizer in guinea pigs.

iE clothing and use self-contained breathing apparatus. CHRONIC EXPOSURE (Fluridone Technical) The fol-lowing effects were reported in chronic, teratogenic, and reproductive toxicity studies in laboratory animals 1 STABILITY: (CONDITIONS TO AVOID) None known where experimental dosage levels and durations of exposure were far in excess of those likely to occur in ii INCOMPATIBILTY: (SPECIFIC MATERIALS TO humans.

AVOID) None known 1rademackofSePRO Cuportion Chronic Toxicity - Decreased survival in lifetime feed-ing study. Increased liver enzyme activity, liver weight, liver cell size, and microscopic liver cell changes.

Ii 1

100 I

E a Emergency Phone: 317-680-8282 General Phone: 1-317-5804282 L ISePRc V..,Z~

EPA Reg. Number 67690-3 Effective Date: August 25, 1994 L ON R

. S .Herbi I ... .. ..

L SONAR**. _..SRP H-e'r-bicidte, I.- -.

'i-~I.

- I .... - - - - - .. .. SePRO Corporation

• Cannel, IN Increased Wkdney weights, and microscopic Iddney cell SKIN PROTECTION: No precautions other than nor-changes. Increased serum enzyme levels. mal work clothing should be needed.

Teratology & Reproduction - Not teratogenic. Fetal -EYE PROTECTION: Use safety glasses.

deaths at maternally toxic doses. No effects on repro-ductive performance. . a] k LB Mutagenicity - Not mutagenic in either bacterial or. -

mammalian cells.

Carcinogenicity - Not listed as a carcinogen or poten- SPECIAL PRECAUTIONS TO BE TAKEN IN HAN-tial carcinogen by IARC, NCVNTP, OSHA, or ACGIH. DUNG AND STORAGE: Keep out of reach of chil-Not considered to be carcinogenic in lifetime feeding dren. Harmful ifswallowed, absorbed through sidn, or studies. if inhaled. Avoid breathing of dust or contact with sin, eyes, or clothing. Wash thoroughly with soap and SIGNS AND SYMPTOMS OF EXPOSURE: There are water after handling. Wash exposed clothing before no reports of significant exposure to SONAR SRP. In reuse.

two reports of children swimming in water treated with SONAR, no symptoms developed. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA 704)

PRIMARY ROUTES OF ENTRY: Sidnand inhalation.: - (4=Extreme; 3=High; 2=Moderate; 1=Slight Insignlnt) -

Health:2 Flarnm liabuiy1_Reactivity.0

. .3 SHIPPING REQUIREMENTS DOT Hazard Class:

Not regulated.

EYES: Flush eyes wift plenty of water and call a MSDS STATUS: Revised 1/92, Section 8 physician If Irritation develops.

SKIN: Wash exposed areas with plenty of soap and water. Wash all contaminated clothing before reuse. (Not meantTo be alindusselected regulations represented).

Call a physician if irritation develops. NOTICE. The information herein is presented ingood faith and INGESTION: Do not induce vomiting. Call a physician believed to be accurate as of the effective date shown above.-

or Poison Control Center. If available, administer acti- - However, no warranty, express or implied, Isgiven. Regulatory vated charcoal (6-8 heaping teaspoonfuls) with a large' requirements areisth tion to anofterI subject to change eburyees and may lodifferirom responsibl~ity oneKts ensure that loca-quantity of water. Do not give anything by mouth to an activities compy with federal, stale or provincial, and local laws.

unconscious person. Immediately transport to a med- The following specific information is made for the purpose of corn-

• ical care faciTty and see a physician. plying with numerous federal. state or provincial.'and local laws INHALATION: Ifdiscomfort occurs, move individual to ., and regutis. see MSD Sheet for health and safetyinfomation.

fresh air. Ifbreathing difficultt occurs, get medical ' ' SARA HAZARD CATEGORY: This product has been attention. If not breathing, provide cardiopulmonary reviewed according to the EPA 'Hazard Categories resuscitation assistance and get medical attention promulgated under Sections 311 and 312 of the' immediately. Superfund Amendment and Reauthorization Act of MIEDICAL CONDITIONS GENERALLY AGGRAVAT- 1986 (SARA Title IlIl) and is considered, under applica-ED BY EXPOSURE: No information available. ble definitions, to meet the following categores:

An immediate health hazard EXPOSURE GUIDEUNE(S): PEE and TLV not estab-lished.

VENTILATION: Good general ventilation should be sufficient for most conditions.

RESPIRATORY PROTECTION: No respiratory protec-tion should be needed when used in accordance with label instructions. The Information Herein Is Given In Good Fath,

, But No Warranty, Express Or Implied, Is Made.

.; Consult SePRO Corporation For Further Irdormation.

2 . Form No. A-73-MC-02(01) 101

I 11 -

)ri5M-fvZ;r1 MATERIAL SAFETY DATA SHEET PRODUCT AL

.NALCO ChlorKill 8816 I

EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) CHEMTREC I

1. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ChlorKIll 8816 Ii APPLICATION:

COMPANY IDENTIFICATION:

WATER TREATMENT Nalco Company Ii 1601 W. Diehl Road Naperville, Illinois 60563-1198 I EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING

.1 HEALTH: 1/2 FLAMMABILITY: 0/0 INSTABILITY: 0/0 OTHER:

0= Insignificant 1= Slight 2= Moderate 3 =High 4 =Extreme

2. COMPOSITION/INFORMATION ON INGREDIENTS Ii Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).

A Sodium Bisulfite Hazardous Substance(s) CAS NO 7631-90-5

%(w/w) 30.0 - 60.0 -I

13. l HAZARDS IDENTIFICATION -

'EMERGENCY OVERVIEW**

WARNING Harmful if swallowed. Contains Sulfite. Causes asthmatic signs and symptoms in hyper-reactive individuals.

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact I

with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water.

Wear suitable protective clothing.

May evolve oxides of sulfur (SOx) under fire conditions.

-I PRIMARY ROUTES OF EXPOSURE:

Skin, Eye, Inhalation Ii HUMAN HEALTH HAZARDS -ACUTE:

EYE CONTACT:

Can cause mild irritation. .1 SKIN CONTACT:

Can cause mild irritation. -1 Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 1/11 102 I

I

i - 1* 11;1 MATERIAL'SAFETY DATA SHEET MNALCO PRODUCT

. 1 ,'

ChloirKill 8816 t:I '

EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC INGESTION: .R Not a likely route of exposure. May cause asthmatic-like attack.

INHALATION: - .  ;

Irritant to respiratory system. Causes asthmatic signs and symptomns in hyper-reactive individuals.

I

. I SYMPTOMS OF EXPOSURE: . . --

Acute:

A review of available data does not Identify any symptoms from exposure not previously mentioned. .

Chronic: . - - . , --

A review of available data does not Identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not Identify any worsening of existing conditions. ... ...

, . I .

, I ,

HUMAN HEALTH HAZARDS - CHRONIC: -' - I -  :

Ingestion of sulfite can cause a severe allergic reaction In asthmatics and some sulfite sensitive individuals. The resulting symptoms can Include difficulty In breathing,-lushed skin and a rash. Chronic exposure to'sulfites may -

cause symptoms of upper respiratory disease and affect sense of taste and smell. ' ' - ' 'I' I I, I. ....

I L 14. I FIRST AID MEASURES I. I . I ... I ,. I,.

EYE CONTACT:

Immediately flush eye with water for at least 15 minutes while holding eyelids open. If irritation persists, repeat flushing. Get immediate medical attention. .. '.

SKIN CONTACT:

Immediately flush with plenty of water for at least 15 minutes. If symptoms persist, call a physician.

INGESTION:

Induce vomiting if the patient is fully conscious. If conscious, washout mouth and give water to drink. Get medical attention.

INHALATION:

Remove to fresh air, treat symptomatically. If breathing is difficult, administer oxygen. Get medical attention.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.

I -- . - . . I

15. I FIRE FIGHTING MEASURES - I I, FLASH POINT: I I None - (A ,':-. '

I I '- - None

• ' - *; - I . .

EXTINGUISHING MEDIA:

This product would not be expected to bum unless all the water Is boiled away. The remaining organics may be ignitable: Keep containers cool by spraying with water. Use extinguishing media appropriate for surrounding fire.- -' -'

Nalco Company 1601 W. Diehl Road -.Naperville, Illinois 60563-1198 (630)3051 000 2/11 103

MATERIAL SAFETY DATA SHEET PRODUCT AI 1NALCO ChlorKill 8816

.1 EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) CHEMTREC FIRE AND EXPLOSION HAZARD:

May evolve oxides of sulfur (SOx) under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit

6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ensure adequate ventilation. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended In Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and environmental authorities.

I METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly Il with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

II D

Do not contaminate surface water.

7. HANDLING AND STORAGE I I HANDLING:

Avoid eye and skin contact. Do not take internally. Do not get in eyes, on skin, on clothing. Have emergency I' equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labelled. Keep the containers closed when not in use. Use with adequate ventilation.

STORAGE CONDITIONS:

Store the containers tightly closed. Store in suitable labelled containers. Amine and sulphite products should not be

.1 stored within close proximity or resulting vapors may form visible airborne particles.

SUITABLE CONSTRUCTION MATERIAL:

-U HDPE (high density polyethylene), Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.

18. I EXPOSURE CONTROLS/PERSONAL PROTECTION II OCCUPATIONAL EXPOSURE LIMITS:

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Exposure limits are listed for sulfur dioxide (S02) since this product evolves S02 when open to the atmosphere.

ACGIH/TLV:

Substance(s)

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 I/

3/11 104

/~

. MATERIAL SAFETY DATA SHEET

'U NALCO PRODUCT ChlorKill 8816

... .. ....... I

EMERGENCY TELEPHONE NUMBER(S)

- (800)424-9300(24 Hours) CHEMTREC .

Sodium Bisulfite TWA 5 mg/m3 Sulfur Dioxide TWA: 2 ppm, 5.2 mg/m3 STEL: 5 ppm, 13 mg/m3

g. . .5. . .

OSHAfPEL:

Substance(s)

Sodium Bisulfite TWA. 5 mg/m3 Sulfur Dioxide TWA: 2 ppm, 5 mg/m3 STEL: 5 ppm,13 mg/m3 ENGINEERING MEASURES:

General ventilation is recommended. Local exhaust ventilation may be necessary when dusts or mists are generated.

RESPIRATORY PROTECTION:

If significant mists, vapors or aerosols are generated an approved respirator is recommended. An approved respirator must be worn If the occupational exposure limit is likely to be exceeded.

HAND PROTECTION:

Neoprene gloves, Nitrile gloves, Butyl gloves, PVC gloves SKIN PROTECTION:

Wear standard protective clothing.

EYE PROTECTION: -

Wear chemical splash goggles. -  :- ... .-

HYGIENE RECOMMENDATIONS:

If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Keep an eye wash fountain available. Keep a safety shower available.

9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Yellow ODOR Pungent SPECIFIC GRAVITY 1.37 @ 77 F /25 C DENSITY 11.4 lb/gal BULK DENSITY 11.4 lb/ft3 SOLUBILITY INWATER Complete pH (1 %) 4.1 VISCOSITY 2.8 cps @ 77 "F / 25 *C FREEZING POINT 34 OF / 1.1 *C Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 4/11 105

MATERIAL SAFETY DATA SHEET PROD UCT 1NALCO ChlorKill 8816 II -1 EMERGENCY TELEPHONE NUMBER(S)

BOILING POINT 10VUL) 219 OF/ 104 `C io I~'vungurm] I.nr-m I M=%.

-I 32 mm Hg @ 77 OF / 25 OC 76 mm Hg @ 99.9 OF / 37.7 *C VAPOR PRESSURE VAPOR DENSITY VOC CONTENT 2.2 (Air = 1) 0.00 % EPA Method 24 I

Note: These physical properties are typical values for this product and are subject to change.

110. ISTABILITY AND REACTIVITY Il STABILITY:

Stable under normal conditions.

Il HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur. I CONDITIONS To AVOID:

Freezing temperatures. Ii MATERIALS TO AVOID:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors. S02 Ii may react with vapors from neutralizing amines and may produce a visible cloud of amine salt particles.

HAZARDOUS DECOMPOSITION PRODUCTS:

Under fire conditions: Oxides of sulfur Ii

11. TOXICOLOGICAL INFORMATION -II The following results are for a similar product.

ACUTE ORAL TOXICITY:

Species LD50 Test Descriptor Rat 4.1 glkg Similar Product Rating: Non-Hazardous ACUTE DERMAL TOXICITY:

Species LD50 Test Descriptor Rabbit 3 g/kg Similar Product Rating: Non-Hazardous PRIMARY SKIN IRRITATION:

-I Draize Score Test Descriptor 1.0 /8.0 Rating: Slightly irritating Similar Product .11 Nalco Company 1601 W. Diehl Road -Naperville, Illinois 60563-1198 IU (630)305-1000 5/11 106 ii

MATERIAL SAFETY DATA SHEET PRODUCT

^NALCO ChiorKill 8816

. EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC PRIMARY EYE IRRITATION:

Draize Score Test Descriptor 9.4 /110.0 Similar Product.,-, ;. ;

Rating: Practically non-irritating . . - ^ ,.

SENSITIZATION:

- Sulfites can cause an allergic reaction In sensitive individuals.

CARCINOGENICITY: .'

None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the 'American Conference of Governmental Industrial Hygienists (ACGIH). . -

HUMAN HAZARD CHARACTERIZATION: -

Based on our hazard characterization, the potential human hazard Is: Low

_ 12. ECOLOGICAL INFORMATION -JI I ~

ECOTOXICOLOGICAL EFFECTS:

The following results are for the product and a similar product.

ACUTE FISH RESULTS:

Species Exposure LC50 -Test Descriptor Rainbow Trout 96 hrs > 100 mgI Product Fathead Minnow ' *96hrs 382 mg/I- ~

Similar Product Rating: Essentially non-toxic ACUTE INVERTEBRATE RESULTS:

Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs 728 m Similar Product Daphnia magna 48 hrs 275 mg/l Product Rating: Essentially non-toxic MOBILITY:

The environmental fate was estimated using a level iII fugacity model embedded In the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level Ill model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the 'enviroriiental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment

<5% 30 - 50% . 50 - 70%

The portion in water is expected to be soluble or dispersible.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 6/11 107

MATERIAL SAFETY DATA SHEET PRODUCT I 0NALCO ChlorKill 8816 ii EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.

ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Ii Based on our hazard characterization, the potential environmental hazard is: Low If released into the environment, see CERCLNSUPERFUND in Section 15. Ii

13. DISPOSAL CONSIDERATIONS If this product becomes a waste, It is not a hazardous waste as defined by the Resource Conservation and Recovery I1 Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor Is It listed under Subpart D.

As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a property licensed waste treatment, storage, I

disposal or recycling facility.

I14. ITRANSPORT INFORMATION

, , . I Ii The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name I Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

Ii LAND TRANSPORT:

Ii Proper Shipping Name: BISULFITES, AQUEOUS SOLUTION, N.O.S.

Technical Name(s):

UN/ID No:

Hazard Class - Primary:

SODIUM BISULFITE UN 2693 8

Ii Packing Group: III Flash Point: None Ii DOT Reportable Quantity (per package): 12,500 lbs DOT RQ Component: SODIUM BISULFITE 11 AIR TRANSPORT (ICAO/IATA):

Proper Shipping Name: BISULPHITES, AQUEOUS SOLUTION, N.O.S. -I Technical Name(s): SODIUM BISULPHITE UNAID No: UN 2693 Hazard Class - Primary:

Packing Group:

IATA Cargo Packing Instructions:

8 III 820 I'

IATA Cargo Aircraft Limit: 60 L (Max net quantity per package)

-l MARINE-TRANSPORT (IMDG/IMO):

li Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 7/11

.1 108

-l

MATERIAL SAFETY DATA SHEET

_ A LC iPRODUCT-lA ChlorKill 8816 EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hous) CHEMTREC Proper Shipping Name: BISULPHITES, AQUEOUS SOLUTION, N.O.S.

Technical Name(s): SODIUM BISULPHITE UN/ID No: UN 2693 Hazard Class - Primary: 8 Packing Group: II

- 15. REGULATORY INFORMATION -*

NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:*

Based on our hazard evaluation, the following substance(s) in this product islare hazardous and the reason(s) isfare shown below. ^ ) In t Sodium Bisulfite: Respiratory Irritant I CERCLAISUPERFUND, 40 CFR 117,302:

This product contains the following Reportable Quantity (RO) Substance. Also listed is the RQ for the product L RQ Substance Sodium Bisulfite RO 12,000 lbs SARANSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE 1II) - SECTIONS 302, 311, 1 312, AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed In Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous. The product should be reported under the following Indicated EPA hazard categories:

X Immediate (Acute) Health Hazard --

Delayed (Chronic) Health Hazard

- Fire Hazard

- Sudden Release of Pressure Hazard

- Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever Is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

L SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the List of Toxic Chemicals.

i TOXIC SUBSTANCES CONTROL ACT (TSCA):

The substances in this preparation are Included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

Nalco Company 1601 W. Diehl Road* Naperville, Illinois 60563-1198 (630)305-1000 8/11 109

MATERIAL SAFETY DATA SHEET 0NALCO PRODUCT ChlorKill 8816 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC l1 FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act:

When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 173.310 Boiler Water Additives Limitations: no more than required to produce intended technical effect.

FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307,40 CFR 116.4 / formerly Sec. 311:

1 This product contains the following substances listed in the regulation:

I CIIeoe~ I C~fain I

• Sodiu Bislte S 31I 1

• Sodiumn Bisulfite Sec. 311 I - I CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air

-I Pollutants), Sec. 602 (40 CFR 82, Class I and 11Ozone Depleting Substances):

None of the substances are specifically listed In the regulation.

~I CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed in the regulation.

A STATE RIGHT TO KNOW LAWS:

The following substances are disclosed for compliance with State Right to Know Laws:

Sodium Bisulfite 7631-90-5 Water 7732-18-5 NATIONAL REGULATIONS, CANADA:

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION:

E - Corrosive Material CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.

-I INTERNATIONAL CHEMICAL CONTROL LAWS AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS) and are listed on the Australian Inventory.of Chemical Substances (AICS). -j Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 (630)305-1000 9/11 110

-D

MATERIAL-SAFETY DATA SHEET

)01" " PRODUCT AtNALCO ChiorKill 8816 I

, r EMERGENCY-TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC CHINA L All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC). ' '

EUROPE

- The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.

JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & Industry List (MITI).

KOREA All substances In this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals Ust (ECL)

NEW ZEALAND This product's trade name Is registered with the Environmental Risk Management Authority (ERMA).

THE PHILIPPINES

_ All substances In this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).

16. OTHER INFORMATION This product material safety data sheet provides health and safety Information. The product is to be used In applications consistent with our product literature. Individuals handling this product should be informed of the L recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to Insure safe workplace operations. Please consult your local sales representative for any further information.

L REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (AMel Insight# CD-ROM Version), Adel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM

_Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Nalco Company 1601 W. Diehl Road v Naperville, Illinois 60563-1198 (630)305-1000.

10/11 111

-1 1_

MATERIAL SAFETY DATA SHEET PRODUCT H 0tNALCO ChlorKill 8816 AI EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC Title 29 Code of Federal Regulations, Part 1910, Subpart Z. Toxic and Hazardous Substances, Occupational Safety Al and Health Administration (OSHA), (AMel Insight# CD-ROM Version), AMel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, A

OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Adel Insight# (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Adel Il Insight# CD-ROM Version), ArMel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO.

I1 I1 Prepared By: Product Safety Department Date issued: 02/23/2004 Version Number: 1.6 I

I1 11 Ii Ii ii J1 Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198

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TaMiaa~ ezamiimuoialy wh& wasir. ( Add abould Always be Wed5 slwly lo WAICL Wgcr mided Ad scm elae bcaic jd socoomW spbdfqatg of ft WcaL) Sulfizoze cm get* 1mm deeoaucoa!ion smad ft.= wtmig fwemlc of1 sufl KW. -.

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• No. 9 2/86 SULFURIC AaD, CON ERATEJ)(Rv.Cw )  ::rc T ,r &S

SECTJON46.HEALTH HAZARD INFORMATIONTL '

pennmaz hkjoy. hhbam of stu at. damceli boda dat VpM morsory wad aol cli hn. SuIsca-q M , in- asd ERLs m EY2C ELMA k~cal~ numb eyes ( ~bShdi=uda~ ejels) siUa 0et grv~Xwrfrm kast is

,lui4 di a~ga if d VA ate bV b &P -~6 pif yot ' watat is n Obtain medical bodp uom aupossW MM CW I==Ucx flush affectd wejwd wit. tmavg j~f-Tg Wida boe scut of mI&or WSW. dacs pive'mk of ingeui Wiftiai1L NC=at S*Ibt by~

16DO1u acm scioaxi IF pam Do ct~ vucsvom~ If iut spontaneously, coadauc fir admnh flta& Obtain madical ictimas MM a05possmko 3.1 sai obsevavtic of patic for odebyc deaw Gaem of poaZ usy eeMa M*rI 1CALHELP-apIn ploj~b .c.m~&-

4SECFON 7. SPlLlL.LlEAK,-AN`D DISPOSAL PROCEDURES .  :.

HmdlC M*cW upln by a dckmiecd pian. Cmcow "pEnr lr -zaSW e~ '1 d 1 31301:6 maeedu1~ reala nw sd ad or rbWKW isosis nftypac anaL ptoide opticzzi vetastlatku Vas we cresuemly kritati1v Cicmip pmanl ed Fmocla agamainst ncccctc Kerp upwb&d jpBni3.r Wb. orieVkat cmb Miused t~a uch man ad oeut~ Wizb sods ash arroe If watr is nt availabwe. cwi *0auzacid mac Wm di QKPSAI- F DOWWFve4SafIdu neplMOMRunfl many aeatw hyroe Sa v i' far or

'SECTION S.SPECIAL PROTECTION INFORMATION --- ' -

ProvWd veaisAsom~h b mo ckrrmz LV requkeinbd ilwbd~plmc Wbut iias 'wesp-b u0w&# 3. a hib.

ifcaypa*ulaw erpkaku Whr Jamcmn mode Is lWd Avod y eye wid 100 I s 1,1M110 a type- spperw-aic mzr wiah o ~~ca ufy oul a fct hildwba ahab~iogay, cidaohh. such as ibber slones m~paa boots, ad sc., is scunoed bo avoid body cocact Aci aicei Operated in MI-meulst pn~wdetv ii=

Eyewash foantan wd tat dxAow wA iklurc lyps of blad shoamd be ught availl wzc: OdaSUMA ia s basOed a j c~wkss pos a spedia bazird; soft =say abt bM and anbies acbwena brimtat..

.- SECTION 9. SPECIAL PRECAUTIONS AND CMET Suthaki add icucaft ardi-m aboald be axed Is ckm vcWa~wd axgOmW s~hti~eitt&e wida goo dninae. Kerp vAcof dkedsatababZ, do wt awte above 399F (3IC) Stmap fawt~3ies we b be aepaite bous ixe Mljerials vmetalli powdefs, cwomat. cld1erah, nitrates, curbidcm aixiflnbk4s ae.:'Soda an4 m or lIns slaceld be kept il zetael 2xtgof tadc ame for emaergecy ass Pmwlct Cmntainer againstphysical dcwgp. Olicc botui meud ekam Pco~de So~ubri acid is hkWghly d 0 mst metak, apedaly below 77% 112SO4g Avoid beagflth istlcc vcapa Avoid 0eotac WM saiacar cyes. Do not Isgest Do mlt add watr In ccaaataad acid. "rm masy contaic liydww gsi.

so qpco caui~ously. Use coactbpwkxft~ Ave of il dht, ad gpit Rod vaorpof ekctkia FlzAD=

DCTF Cbsiflcli CorTo~v alYCiedaL UM)No.- UJNlUI0-- Webe Cm~osive DataScoares) Cadr 142,19.20,24,26431137-39,A, 2 CC j Nrlgdmdov cue Naomi 114

NOV. ;02'99(TUE) 10:59 HOUGHTON CHEMICAL TEL: 161 72542713 P. 002 JPN-0-9-l9 e 99'lr! FROM To El1G17,b P.82 4 2 7 13 A3ERIAULUSP"Yl-CATA- BELLAC IDE CAR, a

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I 1. CHEMIXCAL PRODLVCTICOflPANY IVE rIFICATION

.FPRODUCT :NKiME ..... . . . . . .

.......~S....... 2- CTER -RTYLAM¶INO)-4-CMLDRD -6 ~_THYLAH!INO) -

S-rRIAZIPJE; TERBlJTHYVAZlNE.

INF.GRIMA1ION. PROVIDED BY'.. fliC CORPORATION PROCESS:-ADDITIVESDhJSIO 1.735 PIAR)kET STRE ETJ PHILADELPHIA, PA -1 103I

, I (800) 545-6532 tMdRGENCY PHONE NUMBERS (S0O) 424-9300 i PLAEMIiROTHE. £303) 595-9048 CALL,.COLLECT

• C304) 7515-6:360 CALL COLL-EtT

2. COMIPpSITION/ rNFORL1ATION ON INI CAS V ANWD.COMPONENTS~.....: 2-(TiERT-RUTYLA91IN O)--CHL1oRO-6-cl:THYLAMINIO) -

S-TRIAZINE'.

CASI: .5915-41-3:

PERCENTI WATER:-

4 I CASV:- 7732-la-Z

3. HAZAR'D z'!DENTrFlCArrlON II EMIERCENcj OVERVIEW ..... PRODUCT -IS STABLE UNPER MORIRIAL 'Cl 'NDITIONS OF USE. UNDER FIRE CONDITIONS TOll SULFLUR OXIDES AND CHLORINE kOM¶PDUNDS BE RELEASED.

PRODUCT-lB SLIGHTLY jroxxc2vi sTxIOx.

4. FIRSTZ.AID NEASUREp '=!====:r==n

'EYES... . . 5... FLUJSHWIJTHlPLEmTYOGF~ WATER. GETI .1157CAL ATTENTION.11F *IRRITATr oN or.;URSAi PERSISTS.

WASH WITHN PLENTY OF SOAP AND WATE . GET MEDICAL ATTENTION IF IRRITATION -OCCURS A$1).PERSISTSS.

I iNHALATIPNI .. ... REMOVE.1TO 'FRESH AIR. IF-DREATHr DIFFrCULrY OR' DISCO¶FO~RT:AOCCURS AND) PERSISTS. 3TAIN MEDICAL I I ATTENT1ON4 .' -'

DRINK iOR'EG-.~ LASSES OF WATER AN~ INDUCE -

vomrTING, BY: 'TDUCi4lG THE- BACK OF rHE.THROAT I . .

WITH -AFINGER 'OR BY G1VINU SYR-UP IF IPECAC. I NEvER:,INDUCEVOMITINt; m, CVs ~AN+ rHING BY hOUTH I , .

ro-AN NCONSCIDUS PERSON.- CONTAt r A MEDICAL DOCTDii.

A10TE9 TU. PAYRICIAN ....... 9 4DT AVAILABLE I

PAD ICONTIJ7 FED) PAGE 01 115

Nuv. - ,j nTEFM.a I HUUUMVrUliEMIUAU TEE.9M2542713 F. 03 I

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.5.;/CANAD6 VERSION EFFECTIVE! 06/28/95 02/23196 II 9 I- I I i I

• S== -ac=0=W S. FIRE FIGHTINGS MESURES '

EXTINCUIIHiNG 1MED'IA. .,foo CARSO?* DSOXIDEv FOAl. DtYMCHEi ,~Lt WATER SPRAY SPECI-AL~ TRFIGT PROCC URES DEGRE~E qF FR O ..

N....

USE-SELF CONTAINED 1ReATMING AP !ARATVS.

DECDMPOSITION AND COMBUSTIDN PR DUCTS MlAY BE I I.11 EmPdsiaN HAZARD TOXIC.,

9 HAZARDOISDECOMPOSIT ION.. THERMAL DECOMPOSIT1* AND RuRN4Z I e AY PRODUCE

'CARDON MiONOXIDE, CA1.EON DrOXIDE !N ITRDGSM AND SULFUR OXIDES. CHLORINE COMIPOUN AND OTHER II TOXIC SPECIES.

i ' a II 6. ACCIDENTAL RELEASE MEASURES I i

PROCE-DURl FCR RELEASE.... T? ISOLATE AREA. UEAR PRESCRIBED F IRO'TECTIVE OR SP'ILL CLOTHING AND EGUIPMEWT. DIKE TC 'CONFINE SPILL.

ABSORB WITH ANS ASSORENT OR SHO%I L .WASTE INTO I AN APPROVED CONTAINER AND VISFOC i5 OF FCLLOWING THE METHOD OUTLINED PNDER THE S' kgPMSAL CONSIDERATraiS" SECIDFJ. TO DE( IONTAflINATE SPILU I AREA, TOOLS AND EQUIONiENT UWSH L TH WATER AND I ADD TO DRUMS OF WASTE ALREADY CC LLECTE0.

.1i 17. HANDLING A-RD STORAGE .

.1 0.

I.

'I I.I 'VENTILAT-IOM a AVOID DIRECT CONTACT WHEN HANDLI a THIS PRODUCT.

USE WITH GENERAL R?1 VsTsELFTro WHEN AAIRBORNE I

CONTAMINATION IS EXPJCTED.

STOcRAGE . .-. . . a.. . .. p- KEEP CONTAINERS CLOSED WREN NOT USE. PROTECT[

FROTM HEAT, FLAME AND. P4YSICAL DA lACE .

S. EXPDSURE CONTROLSZPERSONAL PR TECTItON 7]I II HE4SURES.. *A*,,*,: UNDER NORMAL CONDrTTpNSOF VSE E PoSIJRE SHOULD aI CONTROL NOT BE A SIGNIFICANT, CONCERN. l DER UNUSUAL II COITZONS THE PERSONAL PROTECTX E £rAUIPPMNT INDICATED BELOW IS RECOMMENDED.

RECOMMnENbED PERSONAL' PROTECTIVE EQUIPM NT RESPIRATORY0. qa* USE MSHA/NIOSH APPROVED ORGANIC £SP IRATaRY

-II PROTECTION WHEN AIRBDRNE VAPOR 2 EXPECED.':

USE CHEMICAL TYPE GOGGLEd OR FACE SHIELD.

USE IMPERVIOUS GLOVES*.

. Ii Ii SPECiAL' CLOTHING ... WEAR IIPERVIOUS.APRON AND1 GAUNTLE B WHEN I

AAID EQUIPMEN'T SPLASHI2NG is EXPECTED DURING LIQk ID TRANSFER.

NORMAL WORKSHOES EXCEPT IN CQNDI IONS OF SPIL"S WHERE RUBBER OVERSHOES OR BDOTS OULD BE REQURED.

II t .

I-II i PAD' I~tlNT!IOUSJD) PAGE 02

-l 116

I NV.02';99(TUE) 10:59 HOUGHTON HEMICAL TEL: 16172542713 P.004 '

3~4-9-I8 9:16' FF011 *1O

• I.:

826 17f-54P.71 3 P:. e

-"7EUALP SAFMT DATA BSELLAtCIDE CR) --32 1.I S

.f. $MC-I 5qI5, -'3 i TII V.6.ICANADA.VRSO IVE; I 9 ._M U.S./CANADA NJERSION F.FFECTIYEI 061281/95. - -,~ .PI -Et02/23196

• . P - Y 1S. C L. - D .I* I -- -

q9 PHYSICAL AND CHEMlICAL PROPERI 7ES wvm=wm=vwct

.I .

MIELIINGtFREEZING POINT...:l NOT AVAILABLE.

DarLING ,POINT. ..... NO3T AVAILABLE. .,.7. . ., . , 1.

-VAPOR PRSUE..... NDT,.'AVAxLABLtE' VAPOR. DENSITY (AIRR13,...-: PJOT*APPLICABLE. I:

-*RDoot-TEffPERATuREft.. . . d WHITE .TO .LEIGE APIJEDUS DISPERSrl m .,. . I APPEA.RANCE _AND'SATE sLIGHT CHALKY ODOR SPECIFIC GRAV*ITY>-(H2Ou1l)..f . i SOLUBlLIT`Y'?N;HZO rebY 14T; NOT.AVAILABLE  ; ii NOT, AVAILABLE

.EVAPORATlDNRATE... --...... NOT AVAILABLE . II (BUTYL. hCETATEr'13 PHt CA$ 7-iv ,,

.1 ODOR TH6HLvva-*_

NOT AVAILABLE NOT AVAILABLE I II I NOT AVAILABLE' I PARTvrTiO COEFFICIENT.....'

N-O-CTANOLi'IWATER FLASH POINlT........ NOT APPLICABLE AUTOIGNITIO3N TEMlPERATURE.: NOT AVAILABLE

• I FLAMKABLE LIftTS UPPER..z NOT APPLICABLE I I 'CA-IR) DER. NOT APPLICABLE EXPLOSI~E, PRO1I'EP.TIES'...'3 NOT APPLICABLE OXIDIZING PRDPlERTIES.....': NOT APPLICABLE-.

a.I I

• -,FAT. SbLUDILrTY

'iSOLVtNT:~ OIL)

N3T AVAILABLE I.

-I p I

10. STASILTY AND REhCTIVITY -- In STABE'.. I

'HAZARDOUS FOLYtIERIZATION0 UILL'NOT._OCCUR AVOIDXSTDRACE AT EXT klElE TEMPERA' LJRES.

11ATERIALS TOA0 D.. 6

hAJI

K ddNTAhINANTS T)4AT.'.'s NOT P.VAILABLE II

FONTRelDU~rE j in; INSTA BOLI.T'

-STRONG ACIDS AND ALK<ALIES H4AZARDOUS PTCOJ1POSITION..2 THER$IAL-'DECOMPOSITIOIN AND BURNINC "lAY PRODUCE

!i t

-PRODUCTS CARBON ?1ONOXIDE..CARVON DIOXIDE.; NITROGEN AND-SULFUR DXIDES: CHLDRNE CDMPoulmi AND OTHER' I NOZNE EI.. ..

SENSITIV'ITY TO IIECH....

IrIPACT - i I' I.

SEMSITIVIrTf TO3 ST AT ICr.. I I

_L II NONE' I

I I1 II. 'TO)XICO3LOGICAL -3NFOIMA~TIODN CZ= =30 .

-I EYE CON~TACTs... .... ag ONow]IprITA~N'T (FBBT$

I PAD. (CONT14 ED) PACE 03 I

_L 1i* 117

4271 P.005 I -

.- I I117 TO ?S42713 P. 5 11ATtI21&SAPET.DAYA BELLACIDE tR) 325 It

-- i II. MC r a.,

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P4~NTEDT; 02123,96 I

sI

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11. TOXICOLOGICAL I ORMhTioN - 2ff=m.~mvwpwUw=

4SKIN C01CTACT.q *l .. * . $&so. NON-rRRITANT (RABDX NDW-SENSIT12ER CGUI A PIC) 1NHALATIOY~s w* - 3.. I 4 .* . .. 4 LD50 > 4400 nIGeKG ,.R(BBIT)

Nbl DATA AVAILABLE LD5O 1350 Mt/KG (FRtT .

P I

.I 1.I Al

!ACJtE EFFECTS FRCIM...W90.t PRODUCT IS SLIGHTLY tOXIC BY IN 6STION. .

VE RE P)S U RE

-CHRONIC EFEECTS FROfl..._'. ANIMAL STUDIES 1NDICATED. EFFECTS ON THE LIYER, I

• OVERtE.XPdSUlRV CtFFEC1 I CONSI DERED TESTES9 TYMMUS AND STOMACH WHEN PRODUCT WAS APPLIED DERIALLY. LONG-TERM ANX [AL STUDIES 4I71 INCLUDES THE ACTIVE>INREDIENT INPICATED OXIC EFFECTS JN

• ENSTZTI1TIES. LYMPH NODES, THYMUS AND SPLEEN F ILLOWING ORAL A.

• CAJACINOGENECtTY, AND DER"AL EXPOSURE.I A SMALL .INC IASED TERATOGENICITY. INCIDENCE OF M"AMORYI TVGRS WAS IOTED IN RATS.

M?LTAGENrCITYr INHALAtION DR INCESTI ONrIV ETYML tNE CLYCOL MAY SYNERGISTI C RESULT IN CENTRAL NERVOUS SYSTEMl DEPRESSION,

• PRODUCTSP AND ANY LIVER AND KIDNEY DAM1GE AND FETO OXICITY AND niEDICAL CONDLTIONS TERATOGENICITY. :_ l GENRALLY' RECOGNJIZED AS BEIN'C AGGRAVATED svy EXPOSURE.3 I-

.ji 12. EbOLOCSCAL INFORMATION - Ia I

tIENVXROMMENTAL: FATE, . b. SELWACEBACTERIAL TOXICCTU: -

' INHIBITORY CONCENTRfTID11 Of RESP RATION OF AEROBIC WASTE WATER-,rC20. ICSOt ICao > 100 PP?

ENVIRO"NjETAL EFFECTS,... NO DATA AVAILABLE FOR THE PROVUCT INFORMATION BELOW ZS FOR TERBUTHLAZItS.E INGREDIENTs THE; AJOR !_

FISH TOXICITY - .

BLUCGILL: 96 KR LZO = 7.6 PPH RAINBOW TROUT: 96 AR LC5O = .8 PPM INVERTEBRATE TOXICITY.-

DAPMNIA JAGNAS 4S RR EC5D 33 P11 AVIAN TOXICITY. -

MALLARD DUCK:

SOEWHITE QUAIL:

ORAL LD5O > 2510 B DAY DIETARY 3 G/1(G 50 > 5620. PPM Ii MALLARD DUCK: A DAY. DIETARY LCA 5 Do20 PPM j

z I I' 13, DISPOSAL CONSIDERATIONS ii

- E== --1 WASTE DISPOSAL JIETHOD....: OPEN DUMPINC OR BURNING OF THIS I PROHISITED. AN ACCEPTABLE METHOI TO BURN IN AN INCINE0ATOR IN ACl TERIAL I8 OF' DISPOSAL .I4S DANCE WITH ALL~

I I1 LOCAL. STATE AND FEDERAL EXVIRONM NTAL LAWS, AULM. STANDARbS AND :REGUL4ATONS,-

THE APPROPRIATE REGUUiATORY AGENCIE SHOULD BE CONTACTED PRIOR TO DISPOSAL.

PAD (CONTINJ 1D) PAGE 04 118

- . .00 P

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. i 4:

14 . TRANSPORT INFORttATION '==-

I DOT PROPERISHIPP'ING'NAM1E.: NOT RECULATED AS A HAZARDOUS flA 'ERIAL':DY;-U.So DOT 4!Y. CFR 172. 101 .

XATA ........ ... NR PECdULATED -

ZInDc....... NDT RECULATED I DOT CLASSIFICATION.. NOT APPLICABLE DOT LBLI... NOT REQVIRED DOT IR~I......., NOT REQUIRED DOT PLAC.Alli..,....: NOT REQUIRED ii NOT APPLICABLE HAZARDOVS SUBSTANCE/ROD...: NOT'.APPLI.CABLE NOT AVAILARLE 1- I PRECAUTI!ONS TO BE TAKEN4.: KEEP CONTAINjER TICGhLY CLOSED. PROTECT AGAINST' IN TRANOPORTAT'ION PHYSICAL DAMAGt.

A)THER 5KrPprING., .... ... . NONE. I ... .

INFORIIATI[N I.  ; . - I  !

I5. RECuLATORY INFORHATIC.I +r=swm .~M.p

.~ - .

0SHA EXPOSURE LIfttrs SUDSTANCE CS3.,...... NONE,

'OSHA PEIL-TWA...3.... NOT APPL3CABLE NO3T APPLICABLE. I.

.1 *CIs LI .. . . .. .. ....... NOT APPLICAbLE-

'3 I GK1N' flESIDNATION.:l NOT APPILICABLE -.

Acr.1H TOii-TwA ..... NOT. APPLICAD LE STiL, .... .... . NOT APPLirCADLE

'CEILING.."...

• NOT. .PLICABLE SK1IN -DESIGN TION9: "NOT APPLIGCABLE TARGET 000Ofi 'EFFECTS.. LIVER,J~ESTES, THYMlUS, STIO1IACH e ;PLEEN CARCI!4OGENIC POTENTAL REGUJLATEDBY ;YOSHA-.....: N40 N'JO ... I LISTED O*~ 1ITP REPORT..'.,

IARC GROUYP li EA# 2B...1 U.S. EPA' REQUZRM)EN'Ts'

-RELEASE AEFORTINt II CERCLA (40D CFR :02)

LISTED SiRS'rANCE(S)...,

I40T .APPLICABLE NOT A"PL CAtLE .4 RCRA WASTE al'.- NOTA.PPLICABLE

- . I UNLISTED;SUBSTANCEISY. 10 NONE -I ,.

NOT ,APPLICAIRLE . P - I NOT' .APPLICABLE. W RCRA WFASTE NDt.0... NOT APPLICABLE i jrP SARA TITLE-111 SEC 231 (40 CMh i723.........

LISTED TOXIC CHEMICAL..: NONE 4I INVENTORY 4EPORT rNC PAD ( CONTI? UED) FACE 05;- I 119

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..- 4 U.S. (CANADA VERSION EFFECTIVE: 06/2at/5 P RINTED:' 02/23/94 '

I.

Ii

~l~o REGULATORY INFORMATION I SARA XITLE' III SEC 311J312 w===

Ai (40 CPR 370)

• SUBSTANCE(S, HAZ41RD CATEGORY..

PLANNINC: THRESHOLD.....:

....... I........,.,.: NOT. APPLICABLE DELAYED (tCHRONIC) HE4LT8 .HAZARD NOT APPLICABLE Ii I

I EMERCENCY ?LANPN4i4 S.I SARA TITLE: 1I SEC a02-303 (40 CFR 355)

LISTED SOBSTANCEtS)....; NONE II .Ii NOT APPLICABLE PLANNJNG THRESHOLD......: NOT APPLICABLE i U.S. TSCA STATUS..........: YES CCOuPONENtS)

CANADA tH4GREDIENT. DISCLOSURE LIST I

-Ii SUDSTANCE(5) .. *  :... NOT EVALUATED FOR CANADA CONTROLLED! PRODUCT,: NOT EVALUATED FOR CANADA HAZARD SYMBOLS .. NOT E'JALUATEV FOR CANADA CLASS & DIVISIONt.,  ; NOT EVALUATED FOR CANADA.

PRODUCT lDENTIFICATioN ;4: NOT EVALUATED FOR CA)ADA DoiESric SUBSTANCE LIST..: NOT EVALUATED FOR CANADA I..'

CEPA PRIORITY LIST .

CARCINOGENICITY ACOIH APOEN.DI% As:...,:

Al - CONrIRMED )4UMAN., .:i Ai - SUSPECTED HUnAN...: NO IARC ROUP'1. Olt 2,.:

LABEL LANGUAGE (US/ CANADA) FOR UNITED STATES ONLY NO NOT EVALUATED FOR CANADA ND i'

I 9

'Jr I*]

U.5.: CAUTION- HARtd:UL rF SkALI.OlED opt AMRSOEDj THROUGH THE SKIN. . 4OWCOMTAC IWItH SKI?4 AND

CLOTHING.. WASH THORPUGHLY AFTEf !iHANDLING.'

REMOVE AND WASH CONTAMI3ATED -CLI ~tHMPG Bkt-m I REUSE.

PHYSICAL........ , , . NOt APPLICABLE

'HADLINC AND STORACE...: KEEP OUT OF REACH OF CHILDREN..

DO NOT CON7AhINAlE `A'?R, FOOD STORAGE AND DISPOSAL. PROTECT I 0??3r I FEED BV' FREEZING.

' I FV.ST AbID ............  : FIRST AID IN CASE OF CONTACrt EYES: FLUSH EYES WITH PLENTY Of MATER FOR AT LEASE 15 KINUTEE. GET KEDICAL 0 7E4T ION.s IU SKIN: PLUCH SKIN UITH PLENTY Of WATER OR UJASH WITH M1ILD SOAP ANDWATER" INGESTON: JIF CONSC-OUS0 GIVE, I LENTY OF WATER AND INDUCE VOMITING BY PIAcr- IN t N BACK ~1 OF THROAT. GET 1EDI;CAL AfTENTrt c .-... A . . e - I 41.

3AI= KNUWN I

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I NOV.-02'99(TUE) 11:00 HOUGHTON CHEMICAL TEL:16172542713 P.008 I .,

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=c=wm 16. OTHER INFORmATI ;Z

,... -.. -:  : I PRODUCT .USES. * ; * * **0 . r* ALGiCitDE,. .** .. 2

2. *.. ....

.1!IPRTANTI., H~lTEAIrO '£NT'ENiED .FOR-USE IN. PRODVCTS FldR MWjCA PROLPN ED 'CDNrACT IJITM MUCOUS MEMBIRANES' .b:A~tI)l

! IMIPLAN4TATION WIHITN. THE YUMIAN SO

. SPECIFICALLY -INTgDEDf.UIILES'S TiH SF.IN1SSIED - -.-

PRO=U H~AS SEEN iTESTED ..3 A~CCOR ANCE WTI THE1 FOOD AND DRUG .ADhljIN!srRA7ZON AND. OR OTHER .i-APPLICABLE SAFETY. TEATIJG RECOUIR MENTS9. . D.ECAUS OF THE WIDE FANGE OF SUC9 PbTENTI AL USES.

FIIC lCiRPORATION -IS ?fCT ABLE *TO* COMIIEND THIS -

MATERIAL-AS, SAFE ANDI.EFFECTIVE-Vi R SUCH USES AFU INFPA70 ASSUJIES NOLIABILTYI FOR ANY SUC'i -USES. .-

A FL~fh~ULJT...4...... I  : . .

REACT2 V.T.Y . ..... ... 10 .2. . .

CDEGRtFE OF HAZ-ARD . .. . I 0 P -O HAZARD !

4 0 EVERE HAZARD r

THE CONTENTrS AND F04,AT OF THI:1S ;De A RE IN ACCORDANCE WZTH OSHA! HAZAOW COiMMU '41CAT 1.0N AND .1 CANAD.AS-WORKPLACE HAZARDOUS IKATE INFORMATION SVSTEII lHiSd).

I.I I.

I i

. i i

ii i

I!

II PAD PAGE 07 121

Bayer +3 MATERIAL SAFETY DATA SHEET *A1

.1

• AYER CORPORA!ION . I PRODUCT SAFETY & REGULATORY."AFAIRS 100 Bayer-Road Pittsburgh,-PA 15205-9741

- II TRANSPORTION'EMERGENCY . -NON-TRANSPORTAT ION CALL CE12REC: 800-424-9300 BAYER EMERGENCY PHONE...: (412) 923-1800

?rDM3V% TflPWhT. . 7ni-527-38R7 R1YW_ Tw3nFO1Tflm puRON !-annf 62-2V927

.1

1. ~CHDIC~a PRODUCT IDENTIFICATION:

PRODUCT NAME.. : Bayhibit AM Inhibitor

. I PRODUCT CODE.

... :

CHEMICAL FAMILY..;..:

CEEM~ICAt NAME  :

V801 Phosphonates 2-phosphono-1,2,4-butanetricarboxylic acid aqueous J1I solution SYNONYMS..-PTC FORMLAL. :C701109P in 220 Ii

2. COMPOSITION/INEOFOWION ON INGREDIENTS:.

INGREDIENT NAME

/CAS NUMBER EXPOSURE LIMITS CONCENTRATION (%)

EAZARDOUS INGREDIENTS

_________ - - - - - - - -___ _I

• 2-phosphono-1,2,4-butanetricarboxylic acid 37971-36-1 OSHA : Not Established Approx. 50 %

I ACGIH: NotEstablished

3. HAZARDS IDENTIFICATION:

• EMERGENCY OVERVIEW

• 11I

• 'CAUTION! Color: Colorless to yellowish, Form: Liquid;

• Odor: Very slight odor; May cause eye irritation; Contact 3

• with metals liberates flammable gas; Corrosive to steel or

• aluminum; Use cold water spray to cool fire-exposed *

• containers to minimize the risk of rupture; Irritating

• gases/fumes may be given off during burning or thermal Product Code: V801 MSDS Page 1 pii Approval date: 11/18/1998 Continued on next page

- .1 I

122

3. EA2ARDS IDENTIFICATION (Continued)

• decomposition. -  :. . ,

• POTENTIAL EEALTE EFFECTS.

ROUTE(S) oO ENTRY .................. :ye-Contact; Skin Contact; Inhalation EUMAN EFFECTS*AND SYMPTCMs OF OVEREXmoSURE:

ACUTE EFFECTSOF EXPOSURE... .: On tbeibasis of Animal Toxicity testing'(see-Section. 11) ,we wbuld expect this productto be moderately.irritating to the eyes, with symtoms as tearing, reddeiing':and' isuch swelling. '.e would also expect thi; product to be non-irritating to the.skin and to be essentially non-toxic by ingestion.

CERONIC EFFECTS OF. EXPOSURE...: Prolonged or repeated skin contact could result in skin'irritation. Possible symptoms include itching, reddening,'

swelling, rash and scaling.. Based on..animal testt.results, no'mntagenic or teratogenic effects are expected. Also, sub-chronic three (3) month'animal feeding studies were conducted withobt any adverse-effects.

CARCINOGENICITY............... This product'is not listed by NTP,I:IARC or regulated as a carcinogen by OSNA..i.. ,.

MEDICuL CONDITIoNS * : -. -.

AGGRAVATED EY EXPOSURE.... .. : Persons" with pre-existing.eye conditions may be more susceptible to the effects of overexposure to this product EXPOSURE LIMITS. Not established for thiskproduct.

L 4. FIRST AID MEASURES:

FIRST AID FOR EYES ...... :,Flush eyes.withwater forat .least 15 minutes.'

Consult a'physician if irritation persists.

L FIRST AID FORSKIN. .: Wash thoroughly with soap and water.. . Consult a physician if 'irritation develops. ., . . . -

FIRST AID FOR;INEALATION: Remove to fresh air. Consult a-,physician if

. breathing is difficult. ..

FIRST AID FOR INGESTION.: Consult a physician.. .

5 . FIRE FI GETING MEASURES: .  : - - - . - '

FIASE POINT ......... . ; -  : Greater than 212.F (lo C); DIN -51758.:

AUTO-IGNITION TEMPERATURE .... : Greater than 932 F '(500 C);"DIN 51794.

EXTINGUISEING MEDIA.  : Waterj%'Foam; Carbon Dioxide Product Code: V801 MZDS Page 2

' Approval date: 11/18/1998 . Continued on next page 123

I1_

• -X

5. FIRE FIGHTING M¢ASURES (Continued)

SPECIAL FIRE FIGHTING PROCEDURES: Under fire-conditions irritating and/or toxic gases and aerosols. may be present. Firefighters should wear full protective clothing .and self-contained breathing apparatus.' i

- -A 6.. ACCIDENTAL -RELEASE MEASURES:

.SPILL OR LEAR PROCEDURES ..........  : Utilize'recommended protective clothing and equipment. Spills -should be taken':up with, a suitable..absorbent and placed in containers. 'Spill 'area can be washed with water. Collect wash water for approved disposal. -Bayhibit AM maybe eliminated from-sewage water via precipitation by flocculation withb iron7'AIII) or aluminum s~alt. 7.11 7.

HANDLING AND STORAGE: -

STORAGE TEMPERATURE (MIN/MAX): Ambient/122 F (50 C).'

SHEIF LIFE ...................:At least two (2) years. .-

SPECIAL SENSITIVITY .......... ;None known.

BANDLING/STORAGE PRECAUTIONS: Do not store in unlined steel containers as-Bayhibit AM solution will dissolve steel and other metals, causing the generation of hydrogen gas (fla-abJle); Steel or metal containers=must-

- 11 have a complete polyethylene liner on sides, top and bottom. Repack only into approved'containers.;. Store away:from=alkalis, food and beverages.

Handle as any moderately strong 'acid would be handled.

product will not effect its quality. Keep away. from food, drink and animal Freezing of this .-3 feeds.

8.

PERSONAL PROTECTION:

-_ -_ ------- - ..1 EYE PROTECTION REQUIREMENTS ........ : Chemical'workers splash goggles. .I SKIN PROTECTION REQUIREMENTS....... : RubberPVC, Nitrile gloves, aprons and other splash protection as appropriate for the conditions of use.

Employees should wash their hands and face before eating, drinking or using tobacco products.

VENTILATION REQUIREMENTS ............ : Local exhaust ventilation at work area.

-A RESPIRATOR REQ1jREMENTS. .2,t ... : None required'under normal conditions of use.

ADDITIONAL PROTECTIVE MEASURES ..... : Safety showers and eyewash facilities-

.j should be available. Employees should be trained in the safe use and handling of hazardous chemicals.

Product Code: V801' MSDS Page 3

!'I Approval date: 11/18/1998 Continued on next page

.11

.I 124

9. PEYSICML ND CEEMICAL PROPERMIES:- -

PEYSICAL FORM ............  : Liquid COLOR ...... ... Colorless 'to -yellowisb . . -

ODOR .................. . : Very slight odor MOLECULAR WEIGET .......... : Approx. 270 for PBTC pE . .(............  :(10 SUsolution) Approx.' 1.i 681F.-(20 C) -.

BOILING'POINT........... (Initial): 212 F (100 C)

MELTING/FREEZING POINT....: Approx. 5 F (-15 C) -

VISCOSITY . ..........: (Dynamic): 15 to 25 nPasi 68 F (20 C)

SOLUBILITY IN -WAITER .. Miscible -..-

SPECIFIC GRAVITY . . 1.27 to 1.30 L 68 F (20 C).

BULK DENSITrY....^.. '..:-Not Established --

% VOLAsTILE BY VOLUME. . 50 to 55 S VaPOR PRESSURE .. .: 19.6-- 68 F (20 C); . . . . .

-107.ibar8 ,122 F (50 C) -  ;

IO.- STABILITY AND REATCTIVITY: .

STABILITY ...........  :.'.: Under normal conditions-of use and storage,/itbe product is stable. . -

EAZARDOUS POLYMERIZATION...: Will not occur.

INCOMPATIBILITIES.----_..'.- : Steel,bases, sodium hypochlosite solution and.'

strong alkalis (vigorous reaction which'generates beat due to-neutralization process). Baybibit AM may be-eadded safely to dilute-alkali solutions under controlled conditions, i.e. adding slowly with constant mixing.

INSTABILITY CONDITIONS  : (see INCOMPATIBLE MATERIALS) . - --.

DECOMPOSITION TEMPERATURE..: No decouposition b~elow 212. F (100 lC).

DECOMPOSITION-PRODUCTS  ;.: Thermal decomposition may- emit- phosphoric acid, -

carbon monoxide,_ carbon dioxide and other unidentified by-products.

11. TOXICOLOGICAL INFORMATION: ' -: -

ACUTE TOXICITY ORALLD50........... :-Greater than.6,500 mg/kg (Rat). (1)-

INHALATION LC50 ....: Aerosol concentrations of up'to 3,000 mg/th3 were tolerated without -development of -syzptoms. (2)'

EYE EFFECTS........ : Moderately irritating to rabbit eyes. (1)

SKIN EFFECTS..'.:.".'.:'Non-irritating to:rabbit skin. (24 hrs.)..1(1)

SUBCERONIC TOXICITY...: Feeding experiment/test over a three month period: In tests, doses of up'to 6,800 mg/kg were tfolerated without any adverse effect.

(2) X - - . - - -:

Product Code: V801 ' MSDS Page4-A N

Approval date: .'11/18/1998 Continued on'next page

.1.

125

IL_

.1

11. TOXICOLOGICAL INFORMATION (Continued)

CHRONIC TOXICITY ...... : Data not established for product.

MUTAGENICITY ............ Salmonella/microsome test (Ames.test): No evidence of mutagenic effects. (2)

REPRODUCTION .......... :Pregnant rats were administered.doses of up.to 1,000 _

mg/kg body weight; no evidence of possible ezbryotoxicity or teratogenicity.

i were found. (2)

(1) Tests at the Institute for Toxicology of Bayer AG. *1 (2) Tests performed with Bayhibit S. (sodium salts) Data recalculated to correspond with Bayhibit AM. .

.1

12. ECOLOGICAL INFORMATION:"'

AQUATIC TOXICITY ............. ACUTE BACTERIA.TOXICITY: No harmful effects.to Escherichia coli at 105,000 mg/1, 24 hrs.- and Pseudomonas fluorescens at 105,000 mg/l, 24 hrs. (3); DAPENIA TOXICITY: No harmful effects to daphnia

• magna Strauss at 300 mg/l, 24 hrs. (3); FISH TOXICITY: .Rainbow trout. (Salmo gairdneri) LCo = 5,300 mg/I, 48 hrs. (3); OTHER AQUATIC, TOXICITY: No harmful effect to Scenedesmus quadricauda (green algae) at 1,300.mg/l, 24 hrs. .(3);

BIOLOGICAL DEGRADATION: 17 % after 28 days (Zahn-Wellens Test) (3)

Based on experience to date, no interference to biological purification installations if product is used appropriately. (4)

NOTE:

..1'

. .I (3) Tests performed with neutralized solution - results recalculated for Bayhibit AM.

(4) Tests carried out in.the biological laboratories of the Environmental Protection Department of Bayer AG.

_711

13. DISPOSAL CONSIDERATIONS ,. .I WASTE DISPOSAL METHOD ....... : May incinerate or dispose of in closed containers at suitable deposit site if in accordance with federal, state and local environmental control regulations. Empty packing materials should be disposed of at authorized incineration installations in accordance with applicable regulations.

.. 11

14. TRANSPORTATION INFORMATION:

TECHNICAL SHIPPING NAME........

FREIGHT CLASS BULK.............

2-phosphono-1,2,4-butanetricarboxylic acid in water Cleaning or Washing Compounds, NOI, Liquid 7.]

FREIGHT CLASS PACKAGE .......... Cleaning or Washing Compounds, NOI, Liquid Product Code: V801 MSDS Page 5 _I Approval date: 11/1811998 Continued on next page t]1 II1 126

14. TRANSPORTATION INFORMATION (Continued)

PRODUCT LABEL .................. Bayhibit AM Inhibitor DOT (DOMESTIC SURFACE)

PROPERKSEIPPING NAME .: Corrosive Liquid, Acidic, Organic, N.O.S.

EAZARD CLASS OR DIVISION .: 8 JN/NAINUMBER.................-. :.UN3265 PACKING GROUP ................ :III ; .-

DOT PRODUCT RQ lbs (kgs)........: None -.

EAZARD LABELts6) ..................... : Corrosive HAZARD PLACARD(s). ....... Corrosive MO jDMDG CODE (OCEAN)

PROPER SHIPPING NAME ........... Corrosive Liquid, Acidic, Organic, N.O.S.

HAZARD CLASS DIVISION NUMBER...: 8 UN NUMBER .................  ;.:.UN3265..

PACKAGING GROUP.: II*-

HAZARD LABEL(s) Corrosive-HAZARD PLACARD(s) .. Corrosive ICAO / IAZA (AIR).

PROPER SHIPPING NAME .... ....  : Corrosive Liquid, Acidic, Organic, N.O.S.

HAZARD CLASS DIVISION NUMBER...: 8 UN NUMBER ....................... : UN3265 SUBSIDIARY RISK. ................: None -

I I PACKING GROUP .............

HAZARD LABEL(s) ...........

III

,Corrosive L RADIOACTIVE? ....................: Non-Radioactive PASSENGER AIR - MAX. QTY. . -.5.L-PASSENGER PACKING INSTRUCTION..: 818 CARGO AIR -NAX. QTY. ......... : 60.L L CARGO AIR PACKING INSTRUCTION.-.: 820 :

15. REGULATORY INFORM*WION: -

. f.

7

. . . = t .S - -: ,'

.L OSHA STATUS ............... This prbduct is-hazardous under-the criteria of the Federal OSHA Hazard Communication'Standard 29 CFR 1910.1200.

TSC'STATUS -On ... TSCAr Iniventory CERCLA REPORTABLE QUANTITY..: None. - -: -

SARA TITLE III:

SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES..: None.

L-Product Code: V801 I MSDS Page 6 Approval date: 11/18/1998 Continued on next page

• 1

/ ,;

127

I,

1

15. REGULATORY INFORMATION (Continued)

SECTION 311/312 HAzARD CATEGORIES..... Immediate Health Hazard IL SECTION 313 TOXIC CHEDICALS ........-

RCRA STATUS.................

on-e When discarded in its purchased form, this LIi product meets the criteria of corrosivity, and should be managed as a hazardous waste (EPA Hazardous Waste Number D002).

- pH is less than 2.

(40 CFR.261.20-24) 9I1 The following chemicals product specific health be applicable for state are specifically listed by individual states;. other and safety data in other sections of the MSDS may also requirements. For details on your regulatory

.I requirements you should contact the appropriate agency in your state.

COMPONENT NAME

/CAS NUMBER CONCENTRATION STATE CODE 11 2-phosphono-1,2,4-butanetricarboxylic acid 37971-36-1 Approx. 50 % PA3, NJ4 Water 7732-18-5 Cadmium 7440-43-9 Approx. 50 %

< 0.02 ppm* (1)

PA3, NJ4 CA J I Lead 7439-92-1 < 0.02 ppm* (1) CA Mercury 7439-97-6 < 0.001 ppm* (1) CA Nickel 7440-02-0 0.2 ppm* CA .

'Ii CA = California Proposition 65 NJ4 = New Jersey Other - included in 5 predominant ingredients.> 1%

PA3 = Pennsylvania Non-hazardous present at 3% or greater. -II MASSACHUSETTS SUBSTANCE LIST (MSL)

Hazardous Substances and Extraordinarily Hazardous Substances on the MSL must be identified when present in products. To the best of our knowledge, this product contains no substances at a level which could require reporting

-I under the statute.

• Please note that these were random sample analyses and content may vary from

-Ii batch to batch.

(1) Value indicated is the detection limit. .- I Product Code: V801 MSDS Page 7

_ 11 Approval date: 11/18/1998 Continued on next page

..i

.I 128

-I

-t

I . .  : .I .1 . I  :.. .. I . . . I 1S '.OTHER INFORMaTION: . -

,, '. 1 EMIS RATINGS: Health . Flammability aReactivitv-,

1 1': - - - -

0=Minimal 1=Slight 2=Mdderate 3=Serious 4=Severe Bayer's method of hazard communication is comprised of. Product Labels and Material Safety Data Sheets. EMIS ratings are provided by Bayer.as a ,customer service.

ri Section:', ..

REASON FOR ISSUE..........: Revise Zmergency Orervie6w

• Section i

PREPAPED BY ........  : A nn Cob .- --

"PPROVED Er......... . M. Mostory

'APPROV DATEL. . . 11/18/1998 i ..

SUPERSEDES DAE ........... :0930/1996

'MSDS NUMBER .............. '.-  : 01998'

! . 4iI - I , - . . . -

,. :,

- I .

L. This information is furnished without warranty, -expressed or implied, except that it is accurate to the best knowledge of Bayer Corporation. -The data-on a I this sheet relates. only to the specific material designated herein. Bayer Corporation assumes no legal responsibility for use or reliance upon these

-1 data.

~~~~

I a. ..

Product Code: V801. MSDS Page s8 I Approval date: 11/18/1998 . La'st page'

. .~

';I 129

I I BETZDEARBORN MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 08-MAR-I1999 PRINTED DATE: 14-JUN-1999 I

1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 4 PRODUCT NAME . DEPOSITROL PY5206 PRODUCT APPLICATION AREA: WATER-BASED CORROSION INHIBITORJDEPOSIT CONTROL AGENT.

COMPANY ADDRESS:

BetzDearbom Inc.

4636 Somerton Road, Trevose Pa. 19053

-.1 Information phone number. (21t) - 355-3300 EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800).877-1940 (USA)

2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. This product is subject to the Pennsylvania and New Jersey Worker and Community Right to Know Law. 1 HAZARDOUS INGREDIENTS:

This product is not hazardous as defined by.OSHA regulations. .

No component is considered to be a carcinogen by the National Toxicology X Program, the International Agency for Research on Cancer; or the OccupatonaI Safety and Health Administration at Pennsylvania thresholds for carcinogens. 11

• ' . 11 PAGE 1 CONTINUED I 130

PRODUCT NAME : DPOSITROL PY206 - -

EFFECTIVE DATE: 08-MAR-1999 NON-HAZARDOUS INGREDIENTS:.-

CAS# CHEMICAL NAME 7732-18-5 WATER SERE .( N TRADE SECRET tN4320) :TSR: '125438 - 6148

. . t. l ',. - .

. . I.

. I. . : -

I .

PAGE 2 CONTINUED I .

131

PRODUCT NAME : DEPOSITROL PY6206 EFFECTIVE DATE: 08-MAR-1999

3) HAZARDS IDENTIFICATION

• • • h******************************,***-******* ~*

A A..A .**************** rjL EMERGENCY OVERVIEW CAUTION 4 May cause slight irnitation to the skin. May cause slight irritation to the eyes. Mistslaerosols may cause irritation to upper respiratory tract.

DOT hazard is not applicable Emergency Response Guide is not applicable Odor Mild; Appearance: Pale Yellow, Liquid L

Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media:

dry chemical, carbon dioxide, foam. or water

• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • _A..:A :..*************..1 POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; May cause slight irritation to the skin.

ACUTE EYE EFFECTS:

May cause slight irritation to the eyes. IL ACUTE RESPIRATORY EFFECTS:

Mists/aerosols may cause irritation to upper respiratory tract.

INGESTION EFFECTS:

May cause gastrointestinal irritation with possible nausea, I vomiting, abdominal discomfort and diarrhea. IL TARGET ORGANS:

No evidence of potential chronic effects.

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF EXPOSURE:

May cause redness or itching of skin.

• 1 PAGE 3 CONTINUED 132

PRODUCT NAME : DEPOSITROL PY6206 EFFECTIVE DATE: 08-MAR-1999

. . ; .  :, . .- (4

4) FIRST AID MEASURES SKIN CONTACT:

Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes.

EYE CONTACT: .;

Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.

INHALATION:

Remove victim from contaminated area to fresh air. Apply I . .

appropriate first aid treatment as necessary. . . .1 . .

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce'vomiting. Immediately contact physician. I ... -.. :

Dilute contents-of stomach using 3-4 glasses milkor water.'

. . . . 4 .. ..

5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS: ,

Fire fighters should wear positive pressure self-contained breathing

1. apparatus (full face-piece type).

L EXTINGUISHING MEDIA:

dry chemical, carbon dioxide, foam or water I. HAZARDOUS DECOMPOSITION PRODUCTS:

-i.

Thermal decomposition (destructive fires) yields elemental oxides.

FLASH POINT:

> 200F > 93C P-M(CC)

L

'I1 6) ACCIDENTAL RELEASE MEASURES -

l PROTECTION AND SPILL CONTAINMENT-i"

'IL

.1 Ventilate area. Use specified protective equipment. Contain and II absorb on absorbent material. Place in waste disposal container.

Flush area with water. Wet area may be slippery. Spread sand/grit.

DISPOSAL INSTRUCTIONS:

.1- Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted L waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.

7) HANDLING AND STORAGE HANDUNG:

Alkaline. Do not mix with acidic material.

STORAGE:

Keep containers closed when not in use. Protect from freezing. Do not store at elevated temperatures.

PAGE 4 CONTINUED 133

I

• PRODUCT NAME : DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1 999 I'

8) EXPOSURE CONTROLSIPERSONAL PROTECTION EXPOSURE LIMITS  ;. I This product is not hazardous as defined by OSHA regulations. .I; ENGINEERING CONTROLS:

adequate ventilation -I PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:.

A RESPIRATORY PROTECTION PROGRAM THAT MEETS.OSHA'S 29 CFR

.i 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.,

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED

-I:

WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.

SkIN PROTECTION:

neoprene gloves- Wash off after each use. Replace as necessary.

EYE PROTECTION:

I' splash proof chemical goggles

9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F,21C)

Freeze Point (F) 27 1.270 Vapor Pressure (mmHG)

Vapor Density (air=1)

- 18.0

< 1.00 TI Freeze Point (C) -3 Viscosity(cps 70F,21C) 22  % Solubility (water) 100.0 _I Odor Mild' Appearance Pale Yellow Physical State Liquid Flash Point P-M(CC) > 200F > 93C pH As Is (approx.) 13.1 Evaporation-Rate (Ether=l) < 1..00 Ii NA = not applicable ND = not determined

_-I

-1I

.I PAGE 5 CONTINUED

.I I

134

'RODUCT NAME : DEPOSITROL PY5206 LFFECTIVE DATE: 08-MAR-1999 Li0) STABILITY AND REACTIVITY 1 STABILITY:

Stable under normal storage conditions.

HAZARDOUS POLYMERIZATION:

Will not occur:

INCOMPATIBILITIES:

May react with strong oxidizers.

DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

BETZDEARBORN INTERNAL PUMPOUTICLEANOUT CATEGORIES:

"9B11 L I) TOXICOLOGICAL INFORMATION Oral LD50 RAT: 3,050 mg/kg.

}28 Day Oral RAT: 1,000 mg/kg/day NOTE --No clear indications of treatment related toxicity(dose l ~~1 adjusted to 100% active)

Dermal LD50 RABBIT: .>1,000 mg/kg NOTE - Estimated value Skin Irritation Score RABBIT: 0.3 . .

NOTE - DOT HM181: noncorrosive I ,

Eye Irritation Score RABBIT: 3.3

.1 NOTE - Maximum score at 48 hrs; completely reversible by day 4.

Non-Ames Mutagenicity MOUSE: . NEGATIVE NOTE In Vivo Bone Marrow Micronucleus Assay  :.

. 1. . ,  : . -

. ..1 1 C-

.. .. . -I ,

O T_I-N E PAGE 6 CONTINUEDi 135

PRODUCT NAME .: DEPOSITROL PY5206 EFFECTIVE DATE: 08-MAR-1999

12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Acute Bioassay i LC50: 1680 mgIL No Effect Level: 1350 mg/L Daphnia magna 48 Hour Static Acute Bioassay LC50: 1635 mgIL No Effect Level: 870 mgIL Mysid Shrimp 48 Hour Static Renewal Bioassay LC50: 9900 mgIL 5% Mortality: 4000 mg/L ,

Sheepshead Minnow 96 Hour Static Renewal Bioassay LC50: 28300 mgIL No Effect Level: 20000 mg/L BIODEGRADATION COD (mglgm): 130 .

TOC (mg/gm): 70 BOD-5 (mglgm): -9 BOD-28 (mglgm): 9

13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is:

D002=Corrosive(pH).

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14) TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable A.

DOT EMERGENCY RESPONSE GUIDE #: Not applicable PAGE 7 CONTINUED 136

, 1, I IRODUCT NAME : DEPOSITROL PY5206 FFECTIVE DATE: 08-MAR-1999

. . .. , . . . 1- , 2_ .

- R.. .I I M5 REGULA.TORY INFORMATION .

, , 11

r : .

-1

11. .1 I_

TSCA K.

All components of this'product are listed in the TSCA 'inventory. - ., 1.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): . t . ,, - : -

No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS:

'Product is'non-hazardous 'under Section 3111312 '-.

SARA SECTION 302 CHEMICALS:

No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:

No.regulated constituent present at OS A thresholds' LALIFORNIA REGULATORY INFORMATION -

CAUFORNIA SAFE DRINKING WATER AND TOXIC l ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:

No regulated constituent present at OSHA thresholds

-. -.I

• MICHIGAN REGULATORY INFORMATION -sr@-  ;. s .:

No regulated constituent present at OSHA thresholds

6) OTHER INFORMATION , D.E. T N. ;

. .FI.M1

.,I . . .i . . ,

e .. . . ..... _... . ........

NFPA/HMIS'.I -~,, CODE TRANSLATION Health -1 .Slight 1 Hazard Fire 1 Slight Hazard Reactivity O - . Minimal Hazard Special ' ALK '-"I pH above i2.0 I (1) Protective Equipment -B 'Goggles,Gloves .,I I

(1) refer to section 8 of MSDS for additional protective equipment recommendations.  ;- --

-CHANGE LOG EFFECTIVE . .. .. .

DATE REVISIONS"TO SECTION:'- ,SUPERCEDES I MSDS status:. .21-MAY-1997 - NEW - *

• 08-MAR-1999 12 21-]MAY-1997 7AGE 8 I

137

it 5ATA 3.-135 L

Page I of 2

~~~~~ ~

.Material Safety. Data Sheet

IAL

'Ii IL

==

- ___ = =~

== ======= - ===-

- =__ - -=== =-G= =

EMERGENCY FOR CHEMICAL EMERGENCY: SPILL, LEAK, FIRESEXPOSURE OR ACCIDENT CALL CHEMTREC - DAY or NIGHT - (800) 424-9300 Product Name: AB AQUASHADE OA .t Il SECTION I - GENERAL INFORMATION

=

Manufacturers Name:

~~ ~=_____=

~ ~ ~ ~ ~

=====Q__==== ~ ~ ~

APPLIED BIOCHEMISTS

=_=_=_=__ =_=_

AI W175 N11163 Stonewood'brive Suite 234 Germantown, WI 53022-4799 (800) 558-5106 I1 Trade Name & Synonyms: 'AB AQUASHADE OA Chemical Name & Synonyms: WATER SOLUBLE DYE Generic

Description:

ORNAMENTAL APPLICATION DYE Fofnula; D.O.T, Proper Shipping Name:

U.N. or N.A. Identification #:

PROPRIETARY NOT REGULATED NOT REGULATED L I D.O.T. Hazard Class: NON-HAZARDOUS D.O.T. Emergency Response Guide: NIA HazardousMatsDsysternValues(HMIs): Health-t Flammability - 0 Reactivity - 0 Personal Protection- B Nant Fie Protecton Assn. (NFPA 704M): Health- 0 Flammability - 0 SECTION II - HAZARDOUS INGREDIENTS Reactivity - 0 Specific Hazard:

I.

Hazardous Comoonent(s) -

Acid Blue 9 CAS#

3844-45-9 PEL NOT ESTABLISHED TLV NOT ESTABLISHED I1

• Ingredients listed inthis section have been determined to be hazardous as defined in29 CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1%or more of the composition. Materials identified as carcinogens are fisted if they comprise 0.1% or more of the composition. Information on proprietary materials Isavailable as provided In 29 CFR 1910.1200 (i)

I' (1).

Boiling Point (F): 2120F (1000C)

SECTION III - PHYSICAL DATA Specific Gravity (water = 1): 1.0-1.1 Ii

.Vapor Pressure (mm Hg): NOT DETERMINED % Volatile (by Volume): NOT DETERMINED Vapor Density (air = 1): >1 Evaporation Rate:( Water = 1) <1 Melting Point (F): 32 "F pH 6.0-7.0 Solubility in Water COMPLETE Appearance & Odor DEEP BLUE LIQUID, WITH NO NOTICEABLE ODOR SECTION IV - FIRE & EXPLOSION DATA ,1 Flash Point (F): NON-FLAMMABLE Method:

Extinguishing Media: WATER, FOAM, CO2 Special Fire Fighting Procedures: COOL AREA TO PREVENT PRODUCT CONTAINERS FROM BURSTING OR MELTING.

Unusual Fire & Explosion Hazards: FIRE FIGHTERS SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS.

SECTION V - REACTIVITY DATA Stability - - Unstable X Stable Conditions to Avoid: NONE KNOWN Incompatibility (Materials to Avoid): UNKNOWN Hazardous Decomposition Products:

Hazardous Polymerization:

Conditions to Avoid:

NONE Will Occur X Will Not Occur

-=-----------------

H I.

138 I1

Page 2 of 2 AB AQUASHADE OA SECTION VI a HEALTH HAZARD DATA Acut Heah s N E - - - --_- _ - -

Acute Health Hazards: NONE KNOWN Chronic Health ~Hazards: NONE KNOWN Signs &Symptoms of Exposure: MAY CAUSE SLIGHT EYE IRRITATION AND REDNESS. MAY CAUSE SLIGHT SKIN IRRITATION. INHALATION MAY CAUSE SLIGHT NAUSEA.

INGESTION MAY RESULTIN GASTRIC DISTURBANCES.

Medical Conditions Generally Aggravated by Exposure: NONE KNOWN Chemical Listed as Carcinogen or Potential Carcinogen by:

National Toxicology Program: Yes: -No: /

IA.R.C. Monographs:t Yes: 'No: /

O.S.HA Yes: No: i -

Emergency & First Aid Procedures: FOR PRINCIPLE ROUTE OF ENTRY, SEE APPROPRIATE EMERGENCY PROCEDURES BELOW..

- .NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

.Inhalation: REMOVE TO FRESH AIR. ,-

Eyes: FLUSH IMMEDIATELY WITH LARGE VOLUMES OF WATER FOR AT LEAST 15 MINUTES. CALL A DOCTOR.

Skin: WASH AREAS THOROUGHLY WITH SOAP& WATER.

Ingestion: -INDUCE VOMITING, CALL A PHYSICIAN. -

SECTION VII -SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released orSpilled--

SOAK UP AND REMOVE TO AN APPROVE DISPOSAL CONTAINER.

WASH AREA WITH SOAP AND WATER. CARE SHOULD BE TAKEN IN HANDLING PRODUCT AS IT CAN STAIN.

Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL STATE, LOCAL AND.

FEDERAL REGULATIONS.- ---- - -

SECTION Vill - SPECIAL PROTECTION AND CONTROL MEASURES.

Respiratory Protection (Specify Type): .

Ventilation - .1Local Exhaust:: .' MECHANICAL ' -, Special Exhaust NONE Mechanical Exhaust NOT REQUIRED Other Exhaust::NONE Protective Equipment. Gloves: -RUBBER OR PLASTIC Eye Protection: GOGGLES Other Protective Equipment: NONE Work or Hygienic Practices: - USE SAFE CHEMICAL: HANDLING PROCEDURES SUITABLE FOR THE HAZARDS PRESENTED BY THIS MATERIAL. - ' i

SECTION IX. SPECIAL PRECAUTIONS Precautions to be Taken in Handling and Storage:

KEEP AWAY FROM INTENSE HEAT AND OPEN FLAME.

Other Precautions: KEEP OUT OF REACH OF CHILDREN THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPUED. IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS INTHE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE.

OJK Date d Last Revision: 5t9I98 139

I - --it S^Omi A - *,0 . Z-e It Page 1 of 2 MATERIAL SAFETY DATA SHEET .I

.. BBJ Environmental Solutions, Inc.

6802 Citicorp Blvd., Suite 500 Tampa, FL 33619 It 800-889-2251 I1 I. PRODUCT IDENTIFICATION Ii PRODUCTNAME lPRODUCT CLASSl Ii Power Coil Clean' *m Industrial Cleaner II. INGREDIENTS II INGREDIENT  % BY WT. CAS REG. NO. I1 Ammonium Biflouride - <4.00 1341-49-7 Balance-Trade Secret (non hazardous) .

A III. PHYSICAL DATA Ii BOILING POINT 212 0 F SPECIFIC GRAVITY 1.00-1.10 at 250C FREEZING POINT b0 F VAPOR PRESSURE (mm Hg) = 17.5 VAPOR DENSITY Not known APPEARANCE Clear PH@ 250C 4.99-5.2 SOLUBILITY INWATER BY WT. Complete EVAPORATION RATE Not known ODOR Mild IV. FIRE AND EXPLOSION HAZARD DATA FLASH POINT Not Combustible FLAMMABLE LIMITS N/A A Iu EXTINGUISHING MEDIA Water, water fog SPECIAL FIRE HAZARDS None.

II V. REACTIVITY DATA I

140 I

MSDS - Power Coil CleanTm Page 2 of 2

-STABLE [VI UNSTABLE [ I HAZARDOUS POLYMERIZATION MAYOCCUR []

.. 4 ZAADOUS POLYMERIZATION WILL NOT OCCUR [VI INCOMPATIBILITY None known HAZARDOUS DECOMPOSITION PRODUCTS None expected CONDITIONS TO AVOID Do not use with any other cleaning agent or household chemicals, including ammonia, acids, alkalis, bleaches, or chlorine cleaners VI. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN INCASE MATERIAL IS RELEASED OR SPILLED Flood with water DISPOSAL METHOD Flush into sewer or absorb and landfill (non hazardous)

VII. HEALTH HAZARD DATA -

. . I I j , ..

THRESHOLD LIMIT VALUE Oral >1.9 grams per Kg of body weight EFFECTS OF OVEREXPOSURE Will irritate eyes. Will dry skin if frequent or prolonged contact EYE Flush with water for 15 minutes. Call a physician, if Irritation persists.

SKIN-- Rinseoffwithwaterfollowingcontact  ; .:

INHALATION N/A -

INGESTION Drink large quantities of water. Call a physician, if irritation persists.

1 '. -"

VIII. PROTECTIVE EQUIPMENT VENTILATION Use with adequate ventilation RESPIRATORY PROTECTION None required, , ,]

PROTECTIVE CLOTHING Protective gloves (plastic or rubber) when exposure will be frequent or prolonged -

EYE PROTECTION Safety glasses where splash danger exists IX. OTHER SPECIAL PRECAUTIONS. .-

.4. . . ,.

IPRECAUTIONS TO BE TAKEN INHANDLING AND STORAGE Keep from freezing . - C . 1.

SPECIAL.. COMM S Nn. . . _ .. .. ..

PREPARED BY Herman Scriven II DATE August 18. 2000 141

it 4ATERAL SAFEYITA4AShSUT- COIL-RITrE7

. IVSM050S

.1 Vcr. N61 zSEJ70JN C -o.,C C .

1 CHEMlC4L PRODCTAV.D COMlPANYJDEWNMfC4770)f AN D er. Daft Septemnber 8, IVA A

PRODUCT N -E'CoEM .Re PRODUCT CODES. 12, 52614, =251g CHEMICAL FAMILY; Inqrwroaoaiic USE: Cod Cicaner MANUFACTURE I SUPPUER RcdrSeal 2601 Spenwidc EME=GENCY TELEPHONE NUMBERS Cherftft 24 hot= (800 424.930 RederSeal: (713)263-SW0O-1

.11 Houston, Texa 77D55 USA NON EMERGENCY TELEP1ION NU&SEMS 1cled*alSevk&- (800)221-345 SEC77OP 2 COMPOSITION /NFORMA770N ON GE N HAZARPOUS COMPONEN$

wolEther0EB CASNO.

APPROX 1.6 OSHA

.25 ippm ACGIH 1W -JOTHER Z ppm . A .

LAM S VI)

NM H2,RO A

SECTION 3 HAZARDS IDEAMFICA4ON --

SUMMARY

OF ACUTE HAZARDS brrilon to eyes. nose. and mrot drowsine, Skn 'itdon, dermats, and dbfti; .

rcosis, htmor aWd ota CNS c !eetatti concenituons.

PRIMA II Ae)UTE OF EXPOSURE =?NS AND SYMPTOMS B UTEfSl YAATO:Nasal and xs;pcatM~irritation, =S"5., narcpois hgadisl' nauua4, CNS deMresioo, Yes EY t AC SKIN CONTACT:

C :W atein bkwaed vision kiflammadmn and ird'h5on wtch can resut* incomeul0 iijwy Ittibdant, dermlng .Yc INC~TIONNausa vorntin1g; CNS depression: krltatlon of gasioirestina Vac, liver and pcrfonalwal

-- Yell NoDI I

SLUMMARY OF CHRQNIC lIAZRDS: Sdkh ilulion, duinlkls, nd. dert~ing. Posbe Irver and kidney damage..

MEDICAL CONDITIONS GENERALLY AGGRAVATED By EXPQSWRE. WnMduals with pre"ei*tra or dironc diseases of the eyms skich

_1]

SECToN 4 FIRSrAID MEASURES INHALATION: Ifo ec m yc a u e e o e vt mt ra ~ ~ tt.Give oxygen or zit eal resp~ai onas needed.

Ob~an cmegcncy mc& WIattcrV~aa Piomqt sCion is V,*e"h L Iz a~ n EYECONTACT. tlramedatey fuhwith lergo amoaurb ofwater for at leas 15 enilutmGtpfes.r eatef SKIN CONTACT: Wzai wth soap and watet. Remove contaminated dagftg INGESTION! Give targe amounts of waWe. DO NOT butuce voniitk. Kiej at resf. Get prompt medical ait P,-on.

SEC77ON 5 FRE RGfNGf MEAS

..I FLASH PONT: None FLAMMABTLtfl'UUZTh: LELI NID UEa N/D ExnrGuismNG MEDIAl Use avents suable SPECIAL FRE K;HTWG PROt:EDURES Wearse wonrounding frs.

n ruo bee piae breahing appartusand h bodY Ptectvye otpng. Hazdou dt mp'o o prducs pose (see Secon 10. Evaate area. Dike ar as un4-f may create eddi;onal e UNUSUAL FIRE AND EXPLOSION HAZARUS MaaIa wira nt $t* wnbushn.

cm Ii Si6C770N OAACCIDENTAL REESE MEASURES sTEPS To BETAKENIN CASE MATERIAL IS RELEAEP ORSPLLED: R oe llsuces ofnion. USabsorbent aiaks prevent kafo huwd ad to conlhi Ventiatse area wfi mrbnl Of tWOQnprof, fered eir venlation. AvoWd luhng kft sewe-s, drais. voefw2, and soiL Wear pmtdie eotfikg and repirataryprotction durfg ;kpms. Alo, If product Is subject to CECLA reparft (see Section 1S) notify the National Response Canter.

SEC77ON 7 STORAGEAND HANDIDNG PRECAUTION3 To OETAKEN IN HANDLIND AND STORING; Ketp ontAinr r od *i WWI when not in use. Do not sore ra he=a zparlm or open ffamc& lftrandwing tis material to othr canbnenrs, groud al containen to pvid st&c tieeiry buidup and discarge which ma' Ignite flamnmabe vapors.

OTHER PRECAUTIONS: Avod pronged or repeaed coa witl skin or c ing. Empty conainers y cona nslduesmand vapa. reat as if hill and observe all produts precauto. Do not reuse erry contairemr. KEEP OUT OF REACH OF CtoLaOL I

l Ed2 'd Page 1 of 2

-1b3SWMOfl W&OT :0T 142 SG, 02 1.Z0 J

KA TERJAL 6AFTY DATA HW COIL-RITE#

I Ver. 1462 L Ver. vato ccpbkhwgerS 199 "I SjEc7T10W R E-s PI A O YPROtEC WIN (3PECWY TY PEMI Ex Os RECNmRLSAERs0NAL PRO7fM77ON o 1 d a, ? v h t d a e s ~ O~ M H a p or d ~ p rf i g ~ mp i d u

-L VEAFTUATIOVl- LOCAL EXHAUST. Aocewp~bla MECHANCAL (GENERAL)v Prtfrable-PROTECTlVE GLOVM$: Weanrnnl~di' ab~o gl m ..

Special W'A OTHER. WA

..-- ETEPRoTECTION: Chemirca1 pha~sjh gi ea(A141Z4 . ore"ivu- ei L

'1.

OTHER PROTECTIVE CLWTUING OR EQ0lIfMWT; Cawrai re"WAMM& - --

WORM-IYENIC PRACTICES! Vwher tWecan restflt in3k6n contadL wusA ex6Wga ticroc.h~ before esl*n. ecr*S6.wmoidri, or lma~n vwok urea. Laurper c6nfmtn*WW ckcdiin before rnuse.

SECT1ON 9 PHYSICA LAND CHEM P PAL BOILnG POINT: 212-F (I Wo0) Q 760mm Hig SPECIFIC GRAVITY (H6iO .9 DM:

IL VAPOR PRESSURE (mm NO) 170 W8T PM0)

VAPOR DENSIY (AIR1): WA - -

METING POINT; W#A EVAPORATION RATE (ETHfYL ACETATE 11):I' SOWLllrY INWATER; Solul -APPE.ARANCEIODOR: Green Liquid SECTON 10S.TABILIYAND REAC~'I ST A SIUT : S zbl CONDITIONS TO AVOID): H4e'p Jk pn ines rd -i INCOMPATIFINIJ (MATERaIAL TO AVOID): O~ddtz^s O f mid bass.

HAZARDOUS DECOMPOSITION PRODUMS c0, MO,end fgrugeltvd hydracarbom HAZARDOUS POLYMERIZATION: W~i not occu.

CARCINOOMNOITY: .NTP: No IRC MONOGRAPHS'-.Nc OSHiA REGVILATED). Mo

, -s GCyooIEd I EEir 111-78-2 Ornl-at LDSO-A70m.-!c .km~g~on-RatTCLc0O ppOiV5H-SE TO 2ECOL GC L N:RMA7700 FOOD CHAW I.-.N"II .

SUBSTANc

? .

Glycol Emier ES None WA 26¶A locIDrspni24 trLb** SIh7Vpl~nn SECTON 13 DISPOSAL CONSFDERATIOJVS WASTE DISPOSAL WIETHM. Dmspose ofabobdmtkswa cd at i Qmwwtanc*if ldtee iqtw SEC7iON 14 TP.ANSPORTA17O? lJ'FORMA776N - I-D)OT: Nn.-Remuated OCEAN WOOG): Non.relvguttd AIR (LATA): Nan4Requisted IWHMIS (CANADA)! Non.Reguft~cd SECTON 15 REGULAT0RY flVogmA77oN SARA 211 75 A MWIRTI . !EIA RC AC D Glycol Ether ES Y" s *Yer III

.' - 1 - -, WA - WA Thk doavc;ier isprepmrd plrwartto I OSHAH~aw*w ComffxwruebA $randad (29 CFR .1910.120). The ifRecnaton berein Is givet it good ftith but na vmmnmnty. eepre or knplied is nrade. Censt* RectotSca! for Ii~wr in~rari: (713) 283.001

- ~Pa e oi 143 VIT'dl C-'Tc1 bS740OD038WbIGT -0T GG, 02 1.D0

'It ACTI-KLEAN (revised July2004)

Material Safety Data Sheet I SECTION I - COMPANY IDENTIFICATION PRODUCT: ACTI-KLEAN CAT. NO.: AK-i, AK-5, AK-55 II MANUFACTURED BY: TELEPHONE NUMBERS:*

Virginia KMP Corporation Office: 1-(214) 330-7731 4100 Platinum Way Emergency Only. 1-(800) 424-9300 Dallas, Texas 75237 SECTION II - HAZARDOUS INGREDIENTS OSHA Hazardous Components (29 CFR 1910.1200) EXPOSURE UMITS: 8 HR. TWA OSHA PEL ACGIH TLV I

Ethylene gylcol monobutyl ether (CAS# 111-76-2) 25 ppm (skin) 25 ppm (skin)

Dodecylbenzene sulfonic acid (CAS# 27176-87-0) NE NE SECTION III - HAZARDS IDENTIFICATIONS EMERGENCY OVERVIEW: WARNING! Eye and skin irritant Harmful if swallowed or inhaled.

POTENTIAL HEALTH EFFECTS:

INHALATION: Inhalation of vapors in high concentration may cause headache, nausea, vomiting.

EYE CONTACT: Irritation develops immediately on contact SKIN CONTACT: Irritation develops on contact INGESTION: Harmful if swallowed. May cause headache, nausea, vomiting.

CHRONIC Effects: Not established.

-I NOTE-CARCINOGENICITY: USTED IN NTP? No IARC? No SECTION IV - FIRST AID MEASURES OSHA Regulated? No I,

INHALATION:

EYE CONTACT:

Remove victim to fresh air and, if needed, Immediately begin artificial respiration. Give oxygen it breathing is labored. Get emergency medical help. Contact a physician immediately. -

Flush eyes with water for 15 minutes. Get medical attention if symptoms develop and persist Ii SKIN CONTACT: Flush with water or soap and water for 15 minutes or until all traces have been removed. Seek medical attention if symptoms INGESTION:

develop and persist Do not induce vomiting. Rinse mouth out with water. Get immediate medical attention.

SECTION V - FIRE FIGHTING MEASURES Ii FLASHPOINT (TEST METHOD):

FLAMMABLE LIMITS: NA AUTOIGNITION TEMPERATURE:

• Not flammable - aqueous solution.

LOWER: NA NE UPPER: NA A GENERAL HAZARD:

FIRE FIGHTING INSTRUCTIONS:

EXTINGUISHING MEDIA.

Approach fire from upwind side. Avoid breathing smoke, fumes, mist, or vapors on the downwind side.

Firefighters wear protective clothing and self-contained breathing apparatus.

Dry powder, carbon dioxide (CO2), water fog or spray.

Ii HAZARDOUS COMBUSTION PRODUCTS: Acrid smoke, irritating and toxic fumes of SOx,, H2S, POx.

SECTION VI - ACCIDENTAL RELEASE MEASURES. Il LAND SPILL- SMALL SPILLS: Flush to sewer with large amounts of water. 10 parts water to I part product LARGE SPILLS: Pick up with absorbent media; place In non-leaking containers for proper disposal or reuse.

WATER SPILL Notify proper authorities. Clean up leaks/spills immediately to prevent soil or water contamination.

SECTION VII - HANDUNG AND STORAGE HANDUNG: Avoid contact with skin, eyes, and clothing. After handling this product, wash hands before eating, drinking, or smoking. If contact occurs, remove contaminated clothing. If needed, take first aid action shown in section IV. Launder contaminated clothing before reuse.

A STORAGE: Store away from food stuffs.

SECTION Vill - EXPOSURE CONTROLS/PERSONAL PROTECTION 3 ENGINEERING CONTROLS: Local exhaust ventilation.

PERSONAL PROTECTION: Respiratory protection not normally needed under normal conditions of use. Use rubber or latex gloves, chemical goggles or full face shields. Use boots, aprons, drench showers, eye wash as needed for protection against spills and/or splashes.

I' SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES 3

144 3

ACTI-KLEAN (revised July2004)

VAPOR PRESSURE: ND VAPOR DENSITY (Air=1): ND SPECIFIC GRAVITY (H20-1): 1.02 EVAPORATION RATE (BuAc=1): <1 SOLUBILIUTY IN WATER: Complete , . VOC (GIL):

pH: 11-12 FREEZING POINT: ND BOILING POINT: 212 F APPEARANCE & ODOR- Green liquid.

SECTION X - STABILITY AND REACTIVITY .I L STABILITY:

CONDmONS TO AVOID:

Stable.

High temperatures. _

MATERIALS TO AVOID: Oxidizers.

HAZARDOUS DECOMPOSmON PRODUCTS: SO., H2S, P01 and from combustion - smoke and toxic fumes.

HAZARDOUS POLYMERIZATION: Will not occur. -

- - 'SECTION XI - TOXICOLOGICAL INFORMATION X1Z Ethylene Glycolmonobutylether *- TDLo: - -

TCo: 600 mg/kg (oral - wmn)

TCL6: - -195 ppn/8hr (inh - human) GIT TCLo: '100 ppm - (inh - human) NOSE, EYE, CNS LD50. , 470mg/kg 3.. . (oral-rat)

LC50: 2900 mgm .(inh - rat)

Dodecyl benzene sulfonic acid . LD5O: 50- 500 mg/kg (oral - mouse)

SECTION XII - ECOLOGICAL INFORMATION lethal

_ Harmful to aquatic life Invery low concentrations. Ethylene Glycolmonobutylether* - 1 ppm / 24 hr / brine shrimp I T m Dodecyl benzene sulfonic acid 5 -15 ppm lethal cguppy/

onc.

SECTION XIII - DISPOSAL CONSIDERATIONS - -

LDispose as hazardous waste. Classification and documentation Is required before disposal. Follow all local, state and federal regulations.

SECTION XIV -TRANSPORTATION INFORMATION ZIZZ K PROPER SHIPPING NAME: Non-regulated material, liquid HAZARD CLASS:

L IDENTIFICATION NUMBER:

DOT Emergency Guide #:

Reportable Quantity (RO):

'International:

• Non-regulated material, liquid SECTION XV - REGULATORY INFORMATION TSCA (Toxie Substance Control Act): Components of this product are listed on the TSCA Inventory.

CERCLA (Comprehensive Environmental Response, Compensation and lUability Act):'

Reportable quantity Is 1000 lbs. (dodecyl benzene sulfonic acid). Contact local authorities for other reporting requirements.-

SARA TITLE IlIl (Superfund Amendments and Reauthorization Act): Not listed.

• CALIFORNIA PROPOSmON 65: Not listed.

I SECTION XVI - OTHER INFORMATION I State Right-to-Know Programs: MA,NJ,PA -.- ' -

! NFPA Ratings ,.

. Heatft - e.4 4

. .I .

iI , . .4.

, , , ~I

,. - . I. . ..

' - 'Flammabiity: 0 Reactivity: 0X . . ou s HMIS Protective Equipment X See your supervisor Prepared by: Virginia KiMP Corporation -~.. ,-..

This Information is furnished without warranty, expressed or Implied, except that it Isaccurate to the best knowledge of Virginia KMP. The data on this L ted only to specific material designated herein. Virginia KMP assumes no legal responsibility for use or reliance upon these data.

1.45 145

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• aTERrATASAM=T'D=ATSHEEM 'SAtM E -io.,35 I .

I ORGaNIC ORINGE

'1I

.. -"!  : Ii Iff=WWWWW I

1;C!I9N.I

= ~ = E z

I VENTIMIMTON

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O'Nill. Industries, Inc.

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Ii 51.01 Coml.St. - I.

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Phila., 'Pa. 19135 (215) 333-5700 lURGENCY PHONE NU)MEL. 800-255-3924 .II EVIMSED DATE& . &. .......

9-1-02 9-1-02 Orange Distillate II i

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= %I. r I--

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3ECTXON 1I INGREDIBT ' Il

HO1GOIENs 1,8(9) -p-Methadiene PERCENT

>95%

TLV (Units)

Not PROD. CAB #

11

. I 8..75 ."  :@ r.--- e I Il established .- . ...- . '.... ,...

Il a- C.

lonylphenozy- <5S Not .4 g02-i7-38-~3 ...... '. .: -j.

nolvethoxvethwmoL QatrAblitPhd SECTION DWTMC

-PBYBIC.AL pIibv BOILING Point(?) ......... 175.59C II

a. Ix Al SOLUBILITY'IN E20........ Emulsifiable PPEARANC/O DR......... Clear colorless liquid, citrus :odor SPECIFIC GRAVITY (H20-1)...85 . -I SECTION IV --

UrLNr PeIn IRE 'AND EXPLOSION H&SARD DATA

- - - -- .I. -

.-- _mmmleaAi-Il EXTINGUISH XEDIAo.........

FOR F.IRE.0 ................

Use foam, dry chemical, ,or.CO,;

iai ze breahing vapor or fumes. Cool fire exposed containers. Do not enter confined fire-spaces withou A

proper protective clothing, including self containe UNUSM FIRE HAZARD....

air supply.

Busning liberates carbon smos.i t

t Il SECION V -. EMALTx H&,PM WLTa, .,

A JHR XPOSURE EFFECTS 'Liquid may be irritating to eyes and skin. Vapor is .

irritating, to thrpat and lungs... __ . - - .

?IRST AID PROCEDURES..... mS; Immediately flush eyes with witer for at leas

!P~9~ w P15 F -~ w ~

minutess. V.,

Seek~ medical attentionimediately...

. 3~ P _ ____ ___ _..

Wash with water. if irritation develops or persiats CA.. '

seek medical attention. INHAL&TION; Remove to fresh . I:.

air. INGESTION: DO NOT INDUCE VOMITING. Give large quantities of water. Get medical attention immediately. l

!ummUs_-ninew inmm==m=w~"======nk~X-G3====" =w-z axb%0LAW0A VLI. - ZLA 6 A:LV.LXI UAgVA

- I

!HEMICAL STABILITY ....... Stable

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148 I

1171.4715U4 j.4:55 r&& £A1 co cuut WAmz" Lswvua KL7.TERIjL SAP= DAM...i - * .'  :.-.

ORGMNC ORANG -_7Z--

ICONDITIONS TO VOID ...... ..

-,. .1 Excessive heat and flames. Avoidastrong oxidizing=

Ii agents. , ,*.:

TINCOWATIBLE )UMERALS.. Strong acideu sitrong oxidizers I I DECOMSPOSITION PRODUCTS... Carbon dioxcide,-carbon monoxide HAZARDOUS POLYNERIZATION. .Will not occur- . - - - - l.

l ~1 7 D a l f yqU ZU.z~ffiALJV1 AVUL J.....

> AT I . -

SECTION VII - SPELL OR TLEA Pr O URE rPOR SPILL ....... ........ Absorb with iiert material and.disponS dof in accordance with applicable rguilatons.--

WASTE DISPOSAL METHOD.... Diapove of according to all lopal, ;state, ani fedaral regulations. 1 -

11SECTIOM VITI SPECIAL PFosMcTION----r*- * -_

'RESPIRATORY PROTECTION... None needed under normal coid:t4io-.

IVENTYION ................. Local *- '1 PROTECTIVE GLOVES :i.......

RUI .R.e, . .

l EYE PAOTECTION......e... ,Chetmical gggles * ..... . ...-

ER FPROTECTIVE ---

,lEQUIPMENT......................!! ...,...

.F HANDLING AND STORAGE ..... STORE IN A COOL, DRY, WELL VENTILA!ED AREAS **'* .

XEEP CONTAINER CLOSED WHEN2IOT IN USE. '

KEEP AWAY PROM HEAT AND FLAME. ... * .. . ,,

.-'USE WITH ADEQUATE VENTILATION;:-. * ....

KEEP OUT. OP REACH OF CHILDREN%. ' ':

NEAR SA-ETY GOGGCLS AMD RUBBER S DIN THIS PRODUCT.

• F% . . r w~B~ws _~ - wsB~w"C*

asO---scosr=-====r-. -~C .Xw SECTION I - SPECIA -PRECA*T-ONS l -

---==_______________=====-_______________=s DOT SHIPPING NAME........ Combustible liquid, n.o.s,, NAl99{, PG III*.7"  ;,.

DOT LABEM REQUIRED ....... None required -- -i REPORTABLE QUANTITY (RQ). N/A .  ; , -

NA, IqMBER ................. NA -1993-UN 1QWUR. *.....s * . *.. N/A- . CVA -.

Fkind.

COMMENTS The information contained herein is furnished-without-warranty of Employers should use tis information only as a supplement to other F

information gathered by them to assiire pr`oper use of -these materials and the safety and health of empioyees. ..

• Vci.o0t.J.:.  ;^xio-.j2' r I - --- - .,

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.I MATERIAL SAFETY DATA SHEET :1 Penetone Ccpation. 74 Htzuson Ave. Tenafly, NJ 07B70.

CITRiKLEEN . Page: I of 4 -

DatePrepared Jy28.1994 Ii MSDS No- 1850407S' SECTION 1 PRODUCT IDENTIFICATION & EMERGENCY.INFORMATION Ii PRODUCT NAME. crTRIKUEE.

GENERAL USE: clearin9 degreasing PRODUCT DESCRIPTION: Sohleruiesion

• .ll GENERIC INGREDIENTS: wwer, dimene surfactarts. couplinagerts, aDtnoianine EMERGENCY TELEPHONE NUMBERS: PENETONE 201-5673000 CHEMTREC 800-424-930 SECTION 2 HAZARDOUS INGREDIENT SECTION This produd is hazardcus as defried in 29 CFR1910.1200.

HI OSHA HAZARD FLAMMABLE, CORROSIVE OSHA HAZARDOUS INGREDIENTS EXPOSURE UMITS 8 s. TWA (rpm)

Dtimnene CAS#

.5989-27-5 OSHA PEL not established ACGIH TLV not established

-%=E I

Monoethanoiamine 141-43-5 3 3 -

SECTION 3 HEALTH INFORMATION & PROTECTION ,.

EMERGENCY OVERVIEW:

Clear amber liquid with citrus odor.

...J Flammable. Can be corrosive to eyes, skin, and respiratory tract.

POTENTIAL HEALTH EFFECTS: ..I EYE CONTACT: .. I May cause Iritation or lins to eyes on rolonged cotact. Hi vapor conctreaions may be irritatg.

SKIN CONTACT: -

Frequent or prolonged cortact may hritale or dry the sidn, cause dermatitis or cause hbra. Sdn contact may aggravate an odsting dermatitis condtion.

INHALATION:

Highvapor/aerosol concerdations are i,.itat orrnay cause buns to the respikatorytract, may cause headadces, dzzess anesthesia drowsiness. unconsciousness, and other central nervous system effects.

INGESTION:

Srmal amouxts of this liquid may be drawn into te kigs by either swallowing or vo mtkyg This may cause severe and delayed heath effects such as irflarmnation of the lrigs and infection of the brondi. Irgestion may cause irritaion of or buns to the dgestive bad.

-I A

150 l-

CITRIKLEEN Page: 2 of 4 Date Prepared: Jy28.1994 MSDS No.: 18SO-407S C~HRONIC: . ;

-. In aon of mfosw mernbanes and respiratory bact may occur upo prolonged breathtigof mrist. Igestion of large amounts of dimonene has caused Idday and Ever damage hImae rats but not hi fenale rats or nice of both species.

Ingestion of large mouts of  : onl i has caused Iddney and Ever danage Ii laborabory arknals.

FIRST AID MEASURES:

EYE CONTACT:.r Flush eyes with large amosuns of water. See poysida Immedt SKIN CONTACT.

Fazsh sldn with large amouts of water. Remove contaninated clothing and lauderbefore reuse. If sidn iritation develops or persists. caorst physician.

INHALATION: z - . :

.Remove personto freshair. Adrnister oxyenorartfichil respration as needed. Cal a physician kIrnedaty.

INGESTION: - . o water .ON D If awd gve plenty of M orw r. DO NOT INDUCEVOMITNG. Use a stomach pmp. Cal a plidan in.dy.

WORKPLACE EXPOSURE CONTROLS:  :. -  :; I - . .-

PERSONAL PROTECTION:. - ,; ..

Safely glsses are recommended for al worplace contiions. Solved resistant gloves shoid be used Oer protective gear.

irAdingsplash proofoggles orfce shleld, niberboots, apron. gaunets. orraingearshud be worn dependng on how the prod Is used VENTILATION:

None needed under nofnl use conditons. For enclosed areas. or where large amownts of the product are being used, the use of fans or other mcharicalverftion isrecommended An orgaric vapor rnask should be used if the TLVis exceeded ad a

. ice rmaskif he prodctIssprayed. Dk NOT MlSTTHIS PRODUCT. Use coarse spray oriy.

SECTION 4 FIRE &-EXPLOSION HAZARDS -

FLASH POINT: 1257PMCC, 18Sf COC FLAMMABLE UMITS: not deternined - . -

AUTOIGNION TEMPERATURE: not detemiined GENERALHAZARD: - -

Flarnatle Iquid. Can form fanirnable rrures it or above the fhash point .

Cotainers can ruptrend eup nder fire codibons due to preswe and vapor bldup.

FIRE FIGHTING:

Ether atow fire to buxn omL urdecortroted condibiors or exbtngish with water, foam, or dry cherical.

Cool exposed containers with waler spray.

HAZARDOUS COMBUSTION PRODUCTS:.

Smoke, furnes. and oiddes of carbon, nitrogen. and sufur.--

SECTION 5 SPILL CONTROL MEASURES -

LAND SPILL.'

Elrinate sowoes of igion. For sinI spils. use absorbent material such as towels or absorbedt powders. Put al material ito proper waste disposal container'wth Ed 5g0ily covered. Solvent soaked materis may spontrieous combust. For larger spits..

dke spil, recver free iquid, and use absorbert mraterial lo dy area.Rseea wit water. Put al material kto appropriate waste coaniners.

151

A"

-ii.

CITRIKLEEN Page: 3 of 4 Date Prepared July 28.1994 AL MSDS No: 1850-407S WATER SPILL Remove product from water sirface by slkrmysing or with suitable absorbents. This product craks mufactants whiecb wli cause It to I.-I dspese In water. Locaized high concenrations of this product may cause fish klis, bI no persistent or long term effects wil rev.

Check with loal environmental reguiatory agencies for reporting requiremernts. -

.. 1 SECTION 6 HANDUNG &STORAGE STORAGE TEMPERATURE, OF: anrieri. DO NOT STORE ABOVE 120 Dej.F. KEEP FROM FREEZING.

GENERALlKeep away from heat sowces, open flames, and other igion souces. Do not store near strong ioddants SECTION 7 TYPICAL PHYSICAL & CHEMICAL PROPERTIES BOILING POINT, "F: VAPOR PRESSURE, mm Hg at 20C About 212 equal to water EVAPORATION RATE, Acetone =1: VAPOR DENSITY (Air = 1):

equal to water equal to waler SOLUBILlTY IN WATER: WT% ORGANIC VOLATILES:

errisifies abot 30 SPECIFIC GRAVITY at 756F: pH:

0.98 102 ODOR AND APPEARANCE:

dear amber kid with cirus odor SECTION 8 REACTIVITY DATA GENERAL' Tis produt is stale and hazardous polyrmenzation wi not occtr.

INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID:

Strong coddizing agents. 7:-i DEPARTMENT OF TRANSPORTATION (DOT):

.SECTION 9 REGULATORY INFORMATION 7-PROPER SHIPPING NAME:

FLAMMABLEU UQUID. CORROSIVE, N.O.S.

(cortains crimonene and edtnonamine)

HAZARD CLASS: 3 7-n IDENTIFICATION NUMBER: UN 2924 PACKING GROUP: fil .

LABEL FLAMMABLE, CORROSIVE FLASH POINT: 125FTCC pH: 10.2 TSCA: The ingjederts inthIs product are isted on the TSCA invettoay.

7L CERCLA:

Ths product contains no CERCLA reportable materials. Contact local authorities to deterrne if tere may be other local reporting requrements.

.]1 152

le I .: ,. - . .

- CITRIKLEEN , ....

Page:'4 of 4 Date Prepard Jiy 28, 1994 MSDSNo_ 1854-407S

-RCRA HAZARD CLASS:

. D001 Igtable hazardous waste D002 Corrosive hazardous waste

'SARATITLE III:

-3111312 HAZARDCATEGORIES:l.

• Acue heakh Ctronic heath. Fire . -. r - ...: _ ,'-_,

313 REPORTABLE INGREDIENTS: _-' ., - , : I  ?.

-- Deth)4ene Sccrmonob*tyl ether *CAS# t12-3"i <5wbtO/

NEW JERSEY RIGHT-TO-KNOW INFORMATION:

.. This product ca6ains water (CASS 7732-18-5). dimonene (CAS# 599-27-5), monoethanoarrunnoru dodecybenzene suforonateS(CAW 268-07-7), oeenoi edhmxylate (CAS# 96-45-9), dett mneld rnonobutA e(CASte 11245),

andli~x~ nln(CAS# 141-43-5)

CALIFORNIA PROPOSmON 65 INFORMATION:

This prod does not crt n any hernicals recognzed by the state of Calfonia to cause cancer ancuor birth defects or reprod* tive harm..

SCAQMD INFORMATION: .

Isthere a plvtocher.caly reactv material present? Yes Wht Is the % byvolune of phWtochenicaIreactie nrafedal? aboat 30 What IstheVOC content? 310 . ..  ;

What Is the vapor pressue of VOC's? 0.14 mm Hg 20WC SECTION 10 NOTES HAZARD RATING SYSTEMS: -

• . . HMIS NFPA KEY .

HEALTH ..  ; I . 1 '4 = Severe FLAMMABILITY 2 2- 3 = Seilous REACTIVITY 0 0 2 = Moderte

=Slght 0 = Ulnimal REVISION

SUMMARY

SUPERSEDES ISSUE DATE:

Change in Section 6 Septeber 28. 1993 Fo A= LF oIo~r. .. Ano oNTA.ym .i sALE-.

'FOERAD tC . IAL¶KS T ON.CCi2.1-587'- -YW.F T~E IrPFCO.AXlO~PFES8~eIM ~N H;S BEN C~rLED FROM SOLRCES ;~NCM;DTO BED-=OeBLEA1MACCL'ATE TO ThE ESTO PENET~tES

-ANYOER lo2wvN.EDGE iwOMIAMON RELATES TOTSSPEORCmATEONAL- S ITMAY T: 'M!..AL E VAUTO IF USED.IN CO-ONIO W ML7E4ALS ORINAYPRCOSS. ITISTJlEE2'S RESPONSIDUTDT0S 1SFYcESELFASTOT)ESUABTYANC LTESSSOF ThtS IWM

.A-ON FOR KS OWN FPARMlMCUR USE-. . -.

. 1. _, . .

. ... . I 153

Agsnnade in. 7777 -, *k.-.. - -.-.. -.. .. 1L.

. - . . -- FR~j IN irjrj juAIONONMLY Expires On:'

'MATERIAL SAF+/-IY L)AIA btd-iJ+/- ic>-G

.Ess~ntt.LW Singlar la Po'M 0SHA.01 ~ *j SECTION I IODMcT NAME USA C:EAIM-SANITIZER II Mine Safety Applipnlces Comnany Day L. P. Dew6599-0

.JI RAIATRR600 Penn Center Boulevard UrVoutblz Pittsburgh. PA _252rb swIt"ENCY PHON1 No. 1412-2730-SOO SECTION n. INGREDMIETS Ii

• . MEd WtR.S

".Ii

.AcTZVE 5*.7 5nRE4S:

SODnM CAIBOIThE 497-19-8. 42.2 I'

TRISOD11M PZOSPHATE 7601-54-9 10.0 ALM (C14, 50%s-C12 40%: C16, 10%)

3DITMY SENZYL AMMONIUM CLOiRXDZS 1.39-08-2 2.5 :1I IET nR ENTS . 4S.3.

SOD=I TRIPOLYPHOSPERTE 775S-29-4 SODIM BCAMON . *1-5-8 WATER 7732-18-5 10IERIC XY

• TETNO*L Z

=IMR ALCOHOLS (Cll-C15}

EOLS 68131-40-8*

11 64-17-5 ISOBOR2M ACETATE 125-12-2 Il

.____ SECTION U1 PHYSICAL DATA 711 uLNG POWNTr F.) A_ PECFIC GRATY10.1})

JI

_

• 0-8 VAPOR PAUSURE (mm HCY NA %VDLATILE MY VOWMe N 7

VAPOt OEHSITY(al) NAPAN T- NA SOWLOSTY IN WATER . 2 Os/ P 1-% AgotS SOWTzO- 9.5 -W1O.5 APPEARANCE FRAGRANT 3LEND OF WEITE POWDER$

______________SECTION IV - FIRE AND EXPLOSION DATA FLASK POINTr Ps00080 No =R 40- 1 FAMMSABLE LIM173 LI8 tool NA' VTSHIUt0NO SCIA -WATER SPRAY (G) FOAM DRY 2ICALP CARBON DIOXIDE -~II

'*KMO PAEDt BLANKET FIRE wxTs zwTINsIsING MEDIU*

1MU*UAL FiRtE AND IMPWCSi0 HAZAIRDS IPRODUCT. IS NONREACTIVE I enlmrTrMzn-v-rn.-

-AND DOES NOT READILV5? SUPPORT

-I 154

-I

-1 Asstgned to: t??? :nb INFMtMRArtnvki ntkt v

-I 1 ?? sindt:

1- --- . .. . . -1.. I .- Expires On: I l SECTION V HEALTW HAZARD DATA , I Ik -I

.Jvi Ej* 644 MN CONTACT WITH POWDE MAY CAUSE BURNS. -FLUSH AFECTE ARE& WITH CIAN WATER.

EM CONCT WITH POWDER MAY CAUSE COMNAL BURNS. AVOID RUBBING EYMS BECAUSE .WATER INSOLUBLE PhRTICLES. MAY SCRATCH CORNEA. IW4EDIATELY FWSx EYES WM CLSAN WATER WEI HOLDING ELIDS APART. O WSMIMG FOR AT LST is mJTEs OR unI IRRITATION SUB SDES.

CONSULT PHSICIAN AS WON AS POSS33LE.

XSEALATION OF A LAME ENOUGH QUANTITY TO POSE A SIGNIFICANT HERLTE M=MARD IS XMPlBL.

INGESTION OP Pow IS HuuL OR FATA. sHUDNGESON OCU, Dm I4IL2, RAW EGG WHITE, OR GELATI soUTION, OR rGE QUANTxTIES OP WATwMR.

AVOID ALCOHOL. CONSULT PHYSICIAN AS SOONAS POSSIBLE.-

• 1

• UH~TA3LE SECTION VI - REACTIVT DATA..

UNSASMCOlE ITIOI48 STANZLE AVOID 1HAZARDOUS MAY OCCJRn

• CONDmONS T WLL NOT. OCCUR "OL X

• _ VDNONE LAKWOS -

L f cNPCOmuP0AnTh

(,TER AL D)

OX3IDIZING AGENTS OAP AND Mm=O -MC

>FA SECTION .V1.SMILL OR LEAK PROCEDURES S M

.2;.

IS CAU MATEMO SWEE UP L nsL ;0OVE5SA1IzTAR DAPAWAWAY PROM WAVTR SUPPLIES DEsTrRoy 1ETID. ..- EmwwrCOgiSRgis *-*---

• __-__;__-__ L -O SECTION_111 - SPECIAL PROTECTOINFORM

.... ATON.

MA.

I RTOxrY SNOT REQUnMED I1 PR T C flON . T .. * ,.';..

NOT . _

1MAL VE PROTECTION , - T REQUIRED SECTION MX-SPECIAL' PRECATONS SPEMI.

OU- -NOT REQIRED SMSIt . . NOT PUQTRED. .nMM SHELF LIFE 6 MONVIS. . FOR MAXIHUM SHELF LIFE AVOID HIGH EtMIDITY AND ;STOREIN 1

1.ECAUTIYNS

___ __ ___ ___ A CLEAN , ~ ~ Y P ~ E i

j . wner Prn"IrIPM 155

DCr 19 199 16:50 FR CK GIB 2vIRTrL-MTLsri0 582 6G65 TO 91g187747205 P. 02

, 9fft2.*o J{ -, - '. '

A"MI~-MSM

-1

MM ~

PRODUCT NMME: INT1 CZI RHODAMM3 WT LIQUID 1.

PRODUCT CQ0P: kH34$17 L100 CHEMICAL P'AMILY; xanthe e adye R;ealth * & Safety Department DATE PRNTEW; ' 10/19/

=EV8ISXON DAT: . 09/20/ 13.99 SUPPLIED BY:

CroCpton gs P. 0. Box 341

~howleB Colors Inc. .11 Readizg, PA 19603 Phone: 610-582-5765 24 Hr. Emergeacy Phone:

CHEMTREC 1-000-424-9300 CAPNUTEC: For chemical emergencies In Cnada, call CAN= C at 1-S13- 99E6-~666.

• ,,- , ,1 HAZARDOUS COMPONENTS Ii ACGIH TLV: ACGIH Slhor OSHA Pa: OSHA Short NJ, TradE Il Component Per=ca Tam EXPOSU Te= Expos.rT E Secret CiLmt (STEL) Limi (STEL) Registratio value. . ahjc m Number: I rimncljic acid 3 -4 .9 3

N.E. F- yE_

.R

._ . t1888 1400-NON-NAZARDOUS COMONENTS I

ACGIH TLY: ACGIH Short OSHA PEU OSHA Short NJ Trade Compofetu P.rcct Term Expourc Term Exposure Secret -II Limit (STEL) Limit(STEL) Registratio I11 value: val=e:

Sodium chloride 1 17 Y N-n Number:.

18s81400- '- 11

_-N_ _N f_

17647-14-5 __ _ _ _ _ ___ _ _ _ _ _ __ _ _ _ _ _

Trade _

Seret:

Dye

_ _ _ 7 104 _ ._ -

N- _ N_ _ _ _

NZ_ _ _ ,_ 5646P,_ __

G20 ro m pound I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 5 47 - i Page 1 Of 6 156

- i AI

I OCT 19 1999 16:2S FR CVK GIB ENJIRMTL. TLSG10 52 6665 TO 91G1G?47205 P.03 PRODUCTT ,

P.34517L1O00 INTRALCID RHODAMINE WT LIQUID hiast . J 70 lNE ~ . i 17732-19-5 l.0^lll.l;-

- ^ - ~ - , .

EMERGENCY OVERVIEWti Warning: Causes eye irritation. May cause skin.

irritation. - -

EFFECTS FROM ACUTE EXPOSURE!

EYE-CO1NTACT:" -Irritating to the eyes

- fl~ CONTACT:0I May-be irritating to. the eskin.

INE1TALATION: None -known.

INGESTION: None known

..C33R=c OVZREXPOSURE EFFECTS:

.Not )mowzn.

Li CARCINOGENICITY; NTP - No, IARC -. No'. OSHA: Regulated - No PRINCIPLE ROUTES OF EXPOSURE: None known.

71L =EDICAL CONDI7TONS AGGRAVATED BY-EXPOSURE: Not known.

L.1 *-,1M , - * *; LE

.1~

fj -EYES: n case of contact. immediately flush eye;'.Vith pletnty of water for at least minutes and get medical attention if irritation Persists. .

is SKIN.: 'In CeCc of ccntact, immnediatelj flush 8km with plenty-of soap and water for 'at least 15 minutes. Get medical attention.

LAIAATION: It inhaled, remove to freal air. If not breathgin give artificial-Ii respiration, preferably mouth-to-mouth ,If breahi-ng :U difficult give oxygen. Get medical atte-ntiOn.

IL ;INGESTION:K- If'swallowed, inajcj vomit~ingim'mediately by,giving two glasees o0-water and sticking fingers down throat; never'agive' nything to an unconscious person. Get medical attentlof.

4! V

.. F .~ m;a EM.~_ 42 L Page'.'2 Of 6 157

OCT 19 1999 16150 FR C8K GIB ENVIR -L-MTLS612582 6665 TO 91617747205 P.e4 PRODUCT:.

.11

.A34517L100 INTRACID RHODAMINE WT LIQUID FLASH POINT:. N.A. . I METHOD: N.A.

IGMTZXON 1P:. bn.D FPAKHABLE LIMITS IN AIR - LOWM

• iLmmABmE LIMITS IN A=R - UPPER (.):

(%)N N.A.

N.A. 1. ..1 1TGUSIG01 FIRE PITNG MEDIA:

PROCEDURESt after. extingushing fire.

Carbon Di oxide, Dry Chemical, Water Fogs cool expo sed containers with water spray 71 UNUSUAL HAZARDS; gone know fEw.

ADDITIONAL FIRE AND EXPLOSION DATA: As in any rftre, wear self-conltained brethig apparatus and full protective equpment. Il ACTION TO BE TA8EN IF MHATERAL IS RLEIWAM OR SP=LLED: wear.appropriate safety'.

equipment. contain and clean up spill -mediately. Prevent from entering floor drains.

Sweep powders carefully minimizing dusting. Shovel all spill naterials into disposal drums and follow disposal intructions. Scrub -pill area with detergent and flush with copioUl I1 amounts of water.

Ii PRECAUTIONS TO BE TAXE N IMANDLI AND STORAGE; Keep container closed when not Ii in uwe.

OTHER STORAGE AND EDLDG DATA:

practice, hendle with care and avoid personal contact.

In accord with good industrial Ii Ii

?EPOSURE CONTROLS: Local exhaust ventilation may be necessary to control air contaminants during the use of this product.

-RESPIRATORY PROT]CTIO1q: If exposure to dust, mist, and/or 4apors is likely, a. IOSS approved respirator with.a protection factor of 10 is recomiended. SeQ MSDS section 2 for _

information on the hazardous ingredients.

PROC=CTIVE GLOVES: Wear chemical resistant rubber gloves and long sleeved clothing. Ii EYES: wear safety glasses or goggl"e to protect against exposure.

CLOTHING: Wear overalls, apron, or other protective clothin to -inimize skin contact-OTHR PiERSONAL PROTECTION DATA: None known.

HYGIENC PRACTICES: Avoid contact with eyea and akin. Avoid +/-hhalation of dusts anti vapors. wash thoroughly after handling. Keep containera closed when not in use. _i

- - II

- -- - - . ,I D

PRYSICAL STATE'. ..

COLOR: ._ .<-.__.._..Rpm ODOR; __ . _... __ ....

SOLUBILXTr IN WATETR (20C): .ISCILE

_NN U. j-Page 3 Of 6 158 . -I

OCT 19 1999 16:51 FR C&K GIB EVIRMTL-MTLS610 582 6665 TO 916107?47205 P.05 PRODUCT.'

.A3453.7L100 IIrRACID R1HOD.AMInM WT LIQUjrj SPECIFIC GRAVITY: -..

DMNITY C 256V: ... ... ND 4 -* - I

. I

_ BOLTING P03INT:

1 P~FRIM2321 P07NT: ... .

L EVAP. 'RATE (BUMTY ACETATE= 1):. z THMBAVTfL AC==AT

'1 VOC CONENT (t) .... .

VAPOR PRESSUR~E (Yzm/gg Q-20d1): .ND

...Z -, . . -

STABILITY DATA; STAE POLYMERIZATION: Will not occur -

HAZARDOUS DECOMPOSITION PRODUCTS: Burning wll produce oxides%of carbon, nitrogen and/or aulfur.

IOMPATIBILITY (ERILS TO AVOID): None .- , .

CODITIONSI/HAZADS TO AVOID: None known.

ACUTE ORAL LD50 (mg/kg):t N3i Data ACUTE DhML LD50 (mg/kg): N.0 Xnafmation ACUTE IN24hATION LC5 0 (Mg/): ... o Data IRRITATION TO -ekix', eyes- respiratory) ,:. None. - -

ADDITIORAL TOXICOLOGY INFORMTION* .. ..-gone kcnown. . .*. --

• ~~ ). . - , - - - - .~ ~ I~~

ECOTOXICOLOGICAL INFORMATION: No data is available at thictime..

, . . ,-, . .- - 'Z.

DISPOSAL OF 1ASTE METHOD: Bury, or-incinerate according to federal, states, -nd' local regulations.. . .-

CONTAhNER DISPOSAL: containera s'hould be triple rinsed, accordig. to federal regulations and/or good waste management practice.

DOT Proper Shipping Naine: . .... N Not DOT Regulated DOT Technical Name: -. .. ._

DOT Primary Razard Ctlaa: _..._. N.

Page 4 Of 6 159

OCT 19 1999 16:51 FR C&K GIB ELVIR1TL-MTLS610 582 6665 TO 916S1747205 P.06 PROOUCT: I A34517LI00 INTRACID RHODAMINE WT LIQUID DOTI SecondarY Hazard Class:.....N.A.

UN/I N8LMR: ..--. . .

DOT PAKG.GO  : . ... .G.RO.P DOT MG8NCY RSPONSE INFOPIQ TION: .. .Keep unnecesay peopie away. Isolate ll area and deny entry. stay upwind. Xeep out of low areaa. Call- C3EMMTREC at 1-800-424-9300

• for emergeney assistance.

..- For chemical emergencies in CaLnda,

_.... call cAN c .

at 1-613-996-6666. t .

SARA SECTION 302: None Found SARA. (311, 312) HAZIARD CLA.S*

IMMEDIATE HEALTH MkZARD

• :11 SARA (313) CEHZaCALS: THIS PRODUCT DOES NOT CONTAIN A TOXIC CEMICAL FOR ROUTINE ANNUAL 'TOXIC CRE1MICAL RELEASE REPORTING' UNDER SECTION 313 (40 CPR 372) .*f AMUNT OF SARA (313) RPQR:TATE CEMICA (L ) No SARA (313) Reportable Chemicals.

IETAZ CONTENT; This product is not a mnetallized dye.

• TSCA INVENTORY STATUS: All components of this product are included on the TSCA Section 8 Inventory.

CALIFORNIA PROPOSITIO1N GS CMICALS:.- None TSCA SECTION 12(B) EXPORT REGULATIONS: This product is not: woubjOct *-

to TSCA 12(b) Export Regulations.

GEEWIN AIES/E1TROPEAN UNION AMNS: This product does not contain any compounds that would be prohibited under the current German/European Union regulationa regarding cleavable amine compounds.

_________ -_ .11 HAZAPD ATIG SYST B1ZS: PLAMM LITY I , REA3CTVITY a , MEALTH 2 -I AiDDITINAQa INFODRUaTION:

NONE .1 Page S Of 6 160

v I2V I1f-LLIU ltb;~: t-?~LJ blkl kN-tIMIL-MlLbblki ~ b605 ~.bll.lf('4fC= s

- v PRODUCT:'

A345.17L1OQ INTRACID- RHODlMINE WT.LIQUID

. MSON FOR-UPDATE:. .Product reviewr.

DIC3.CtE3R: - Croantn & Knowles warrants that tbis product conforms to the chemical description on the label and isS reasonably fit :or te &pecrficdpucposet referred to in its directina for usZC, ubjcct to iihkrent riaka xeferzed to -in the Material Safety Data Sheer for thi& product. Crompton & Knowles makes no oter-exptress or implied iiarranty.-In no case shall Cromton & knowles be liable for conscnmitial, special. or indireet eamagasresl4t:ng from the use or Iindling of thiQ product.

4E1k OFMDS"

.. . ..... Mt . . . . .

• X

• Page 6 Of 6 I 161 I -M

Assigned to: 77?? 9 M RRftIl -

Ewres on:'

- -1. ... 1- WIVL'T - .

9"?Tm O(CmL Co., DC.

MM SAFETY DATA SHEET

/ ;d f e O &2 IL I MMMATI N FI~IucT wwl cut ja (=sIt *gpeas on label)

IWHFACTIMS ME EMEGENCY TaEL~EV M6.

Spartan Cesslc.il Co., Inc. (49)53-5551 ~.I1 Amqs (IUm, STRET, crTY, sTA1EAN zip 110 N. Westwood Ave., Toledo, ON 43M0 IPaeE) KwILFmflwS D-4J#S No1.

05362 -.I PAMMOS IWDrEfT I .1 I I Tale Z-2-A -

ICAS REISTYNO.. I S I CHEMICAL WVES) mmWI M' Lurg I QI~I1m4 I ISn NO HAZARDOUS INGREIENTS AT IX OR GREATER CONCENTRATION4 I

t SECTION Mf PHYtSICAL. DATA A

BOILING POINT SPECIIC GRAVITY (H120 -1 VAP 0~75cOr MESSE - 18

_?C_

212 OF __OC nH2 psi

__F*

1.074 FEUCET SOLID By WEIGHT Cs)

1I VAPMR ZENSflY (AIR - 1) EVWArATUM RATE (but. ace. = 1) 15-17 Unkownl

'SO IILITY IN WATER Covp~ete (1

NEAME ND MO Blue, citrus odor

JI IS MA~TERIAL: (LIQJUD) SOLID Concentrate 11.0-11.5 MA PASTE PO~WDE I SECTI04 IV I V1IE AM EXPOSION( HVARDF DATA I FLASH POINT - None NETHO UWED - ASTN - 092 FLV#Oa.E LD4rTS; - n/a EXT1)NGflf NEDIA n/a SPECIAL VilE FIGHTING MYUCEV n/a UNUSUAL FVl AND EXLOION MARDS n/a ..I 11

-I

_ _ _ . _ Ant. _

162

-. I _- 6, - ,

I , I 'A

% I i 'I,

. I

-.7dr,4- 7-

-  : I I - .

...  !"p r-

. f- LT.-

i.. t EFFECTS OF UIE1WMM C ONfl S -ID AVOWD J-lu V-IEQl1HI D . M RHFM LDOrT VALIE - Mbt established Avoid eye contact; say cazse eye irritation. * .

Li FRV A C EolRY iF INtLATION __ 'SaI m4Tm T - OT1~ C cFY)

.1; CODTIONS IERAAD BfY t6

. . J EM A1D fZS1 AID *M CUES - In case of contact Immediately flush eyes with plenty of water for at least 15 ainutes; call a physiclin.? rltih-skin with water. Wash clothing before reuse. It walowed, glve large qiantltles of water or fruit juice. Call a physician ediately. .

-SECTION VI - ICVX1Y D[TA SIAZLITY: STAME __._:

• STABLE X --. --

IMXHRTMS1 (w 5iTs i .,* )

None . , '~" '

JUR= MY am -- -

W..ERZATZON: WIL PM VDR X f

IE~O 'V-r - SR1M LtEK POEDURE STEPS TO BE TAKEN DI CSE PTER.L XS MEEASED OR LLED Flush with water to sanitary sewer systemri.

.. ZI- -. .C

%M7STE DISPS% *EMIU i :

Same as above.  ; , ..:t:

I I srxoN vII - sneAL F~TmECTIy IifTIm '. . ..- I  !

FESPIMM~ PRWahCNL (SPEIFY TYPE)I Nothing special VENlLATICN - Good general ventilation should be suficieint for most conditions. Local exfaust ventilation ry be necessary. -*,...

for s "eoperations..  : . - . . - , ~. I FMTErTMY GLOVES (SPCIY iWE) EYE FROTECTION. (SPCIF TMP)

It desired .- . ' I -esire . . -

OTHE F~TETV EQUIeir n/A LI - SCTI'z Z - S~IAECL FRECUTIGNS = , . I. - , I . .,

, .. -I -

I NoAtIIngS 1s BE TA..i Il .HWL A* ST1 ..

Nothing Specill No'.'Wng special Spartan Cheical Co., Iruc. Thoma 3. kitchael

TjLE -, I . Director ot' Pasearch fief 29 Uil MO1:=2 (OSM) I.: OA1E . arnie I, 199

,,. t- 5WREDS - Sept 20 , 1985

°SCC6/90 Copyrighted: Spartan Chemical Co., Inc. - For Use Only By Authorized Spartan Distributors.

163

ISynTech Products Corporation Material Safety Data Sheet

- 520 E. Woodruff Avenue Toledo, Ohio 43624 24 Hour - Call INFOTRAC 1-800-535-5053 It HMIS Rating H-1 F-0 R-0 (419) 241-1215 :5A*10 Section I - Product Identification It Product Name: Touch It Up De-Contaminant*

Effective Date: 02.02

• Do NOT use this product as a skin de-contaminant IL Section II - Hazardous Ingredients Chemical Name CAS# WT% PEL TLV CARCIG 2Butoxy Ethanol 111-76-2 1%+ 50ppm 50 Skin contact No Other ingredients - Trade Secret .I.

Propane/Butane 74-98-6/106-97-8 6-10%

• All constituents are listed on the .TSCA inventory._ _

1000ppm 1000ppm No

• OOncayfl$TRP,. SRFET DATA SHEET IP.D. Box 464 . a'lbridle, M 4OH0IM Q1f1;-Lb. MON-PHOSPHM~E Ph bI Ia Iph I a, PR 19127 419-665-6610 -a TrvItd . VtVlu LjRoutes of Exposure Eyeoar skin contact, I ngesti1on.

Efet-o 'erexposw-e 'P*ontact sjIth eysor ski can cause -seve~re Irritain CorcirnogenicitY Th'rt prozut' s not considered to be a. corc ino en~bg the.

-HTPJ -IRSC vr-OSA.,-

EysThoroughly irrigate at orme with~rumning water- for- at.12s 15 iirwites. Get Imftedicte-medteal'ttentiorn.

Skin Flush wiith plentyj of wtr-L] ngestion Have victim drink. large quatltles of at o ikt dI Iute -the product. DO,riT 'IiDUCEUOMI TI d flG. i '0e M IRTM IOE MMetin.fiever-giue anything by moth to onunconsci~ous oiriOnvulsinq vIctm.

Inticg~tion M

~Othet- NR S$ection VI-:REMMITY DATR St~bi~it~JStabIle *~*

Cond It Ions to Avo id hone iknonm Hzdous Decompos o hione known Products Hazardous Polymerization' JI I not occur Conditions to Avoid llone nown L] nlrxeon additional pogeCs)-

L1. 167

u Vzall

~IRIEMORAAyAki J-ONLY . . - Expires On:-

,Kswgnea lo; g rS jg. - -I .-

J2 ' 95 10:i1lVM HRRRISELRG P~PPE CO I.

• HftCO, I nc. IVITER IfL WMET DFRTR SHEEiT

1. '46I Flat Rock Road 3052-Tracy Road.

• P.O. Box 46.4 Philaelphia, PR 19127 tWalbe-Idge', DM 43465 4 1Q-655-8510-W0I tfM 17{.O fiOf-PHOSPHRTE-P=.P 3.- ii

- - SMUMRmw -- - . - ..

Section Ut t .- SPIUL OR LER PROCEDURES<

.. .... .. .(~. . . . . macmCnammsm - -- -- -- - . 1 Steps to be taken In case Sweep up. Rinse spiIl. area welI withui th r.

material Is released or spiI led 11 Waste 0isposol Method

• D ISPOSER MlUST COIIPY U IT a~1.. FEDURAL', STRTE, FM L~cAL UISPOSRL FM~ DISCXRROE LAJS.

11 .b Section U III -: SPECWRL PROThLI~iO.

.11 IFOPJFRT1OTI, Raspiratory Protection Kome requ ired II Uentilation ' Adequate ..

01 l Eye Protection Other Protectiue Equipment Rubber or ne-oprene Safetyj goggles timne rqu Ired :0:

Section . . .

Ix - SPECIRL . .

PRECAUTIONS ..I Pr'cations in Hand l ing and Storage Store in a tightlI ciazed container.

TA Other Precautions KEEP OUT OF PERCH OF CHILDREN.

HR - Hlot Rpplicabbe, uums HE - itot Established, NHD.-tnot eteriiried for this piroduct The informaticn herein Is given in good faith cTIs compi led from thteriol SSafeQt Data 11 Sheets furnished bg our suppi iers. No waarrnty, expiess or iupt led, Is made or intended.

ftny te of this information must be determined by the user to be in accordance mith _ A1 ovpl icable Federal, State, snd local lcws* and reulations.

I

.11

.ll

.1 168 L-i

I BETZDEARBORN MATERIAL - Betz-10earbo0rn7

-. SAFETY DATA SHEET '

EFFECTIVE DATE: 22-AUG-1995 i

~qo PRINTED DATE: 19-OCT-1999

1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION-'

PRODUCT NAME :.POWERLINE INHIBITOR- PPL1 0 ,

PRODUCT APPLICATION AREA. WATER-BASED CORROSION INHIBITOR. -'

COMPANY ADDRESS:

BetzDearbom 4636 Somerton Road, Trevose PA 19053 Information phone number. 215 355-3300,.

EMERGENCY TELEPHONE (HEALTHIACCIDENT): (800)-877-1940 (USA)

"., ., . , , . L- . I I

2) COMPOSITION I INFORMATION ON INGREDIENTS I I I I- - , , "

Information for specific product ingredients as required by the ..

U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential . . . . 11_ :,: r .

hazards of this formulation. 1. .

HAZARDOUS INGREDIENTS:

CAS# CHEMICAL NAME..' -'

7632-00-0 SODIUM NITRITE Oxidizer; toxic .(by ingestion);.,potential blood' toxin --

No component is considered to be a carcinogen by the National Toxicology Program., the International Agency for Research on Cancer, or the -- -

Occupational Safety and Health Administration at OSHA thresholds for carcinogens.

PAGE 1 CONTINUED 169

PROOUCrUAME

• PWERLINtINHIBITOR PPL10 EFFECTIVE DATE: 22-AUG-1 995

3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING ..--

May cause moderate irritation to the skin. Severe irritant to the eyes. Mists/aerosols cause irritation to the upper respiratory DOT hazard: ORS (when container > RQ)

Emergency Response Guide #31 .i Odor Mild; Appearance: Light Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing l apparatus(full face-piece type). Proper fire-extinguishing media: 11 Flood with water. Use of C02 or foam may not be effective.

POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; May cause moderate irritation to the skin.

ACUTE EYE EFFECTS:

Severe irritant to the eyes.

ACUTE RESPIRATORY EFFECTS:  ;

Mists/aerosols cause irritation to the upper respiratory tract INGESTION EFFECTS: . 11 May cause gastrointestinal irritation with possible nausea,

• vomiting, diarrhea, incoordination, mental confusion, dizziness and lethargy.

TARGET ORGANS: A Prolonged or repeated exposures may cause CNS depression and/or toxicity to the blood. 1 MEDICAL CONDITIONS AGGRAVATED:

Not known. I SYMPTOMS OF EXPOSURE:

Causes irritation of the skin, eyes, and/or respiratory system.

• ]

PAGE 2 . CONTINUED -I 170 ' ,1

-1 EFFECTIVE DATE: 22-AUG-1995 -  :, ,. .  : ,

4) FIRST AID MEASURES . .... - .

SKIN CONTACT:

Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes.

EYE CONTACT:

Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment. . ,

INHALATION:

Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary.

'INGESTION:

Do not feed anything by mouth to an unconscious or convulsive.

victim. Do not induce vomiting: Immediately contact physician.

Dilute contents of stomach using 3-4 glasses milk or water.

5) FIRE FIGHTING MEASURES . --  :

FIRE FIGHTING INSTRUCTIONS: '

Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type)..

EXTINGUISHING MEDIA:

Flood with water. Use of C02 or foam may not be effective.

HAZARDOUS DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

FLASH POINT:

> 200F > 93C P-M(CC)

MISCELLANEOUS: .

ORS (when container > RQ)

NA3082;Emergency Response Guide #31

6) ACCIDENTAL RELEASE MEASURES I- I I PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container. I .

Flush area with water. Wet area may be'slippery. Spread sand/grit.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be's'ent to a sanitary sewer treatment facilityin accordance with any local agreementa permitted I .. . .

"'.,I waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.-.

7) HANDLING AND STORAGE L

_I HANDLING:

Contains an oxidizer. Avoid all contact with reducing agents, oils, greases, organics and acids. Do not allow to dry.

STORAGE:

Keep containers closed when not in use. Do not freeze. Iffrozen, thaw and mix completely prior to use.

PAGE 3 CONTINUED 171

m~ .Lu rnvouTx;Ofrlsz'Elcw1 lmrDr rrru EFFECTIVE DATE: 22-AUG-1995

8) EXPOSURE CONTROLS/PERSONAL PROTECTION -1 EXPOSURE LIMITS CHEMICAL NAME-SODIUM NITRITE DTRIE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED ENGINEERING CONTROLS:

adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpait I RESPIRATORY PROTECTION:

A RESPIRATORY PROTECTION PROGRAM-THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

Ifair-purifying respirator use is appropriate, use a I

respirator with dust/mist filters.

SKIN PROTECTION:

rubber gloves- Wash off after each use. Replace as necessary.

EYE PROTECTION:

splash proof chemical goggles

9) PHYSICAL AND CHEMICAL PROPERTIES 1 Specific Grav.(70F,21C) 1.107 Vapor Pressure (mmHG) - 18.0 Freeze Point (F) 19 Vapor Density (air=1) < 1.00 Freeze Point (C) -7 Viscosity(cps 70F,21C) 8  % Solubility (water) 100.0 odor Mild Appearance Physical State Light Yellow Liquid

. i Flash Point P-M(CC) > 200F > 93C pH As Is (approx.) 9.0 Evaporation Rate (Ether=1) < 1.00 NA = not applicable ND = not determined

- I PAGE 4 CONTINUED I 172

PRODUCT NAME : POWERLINE INHIBITOR- PPL10 I .

EFFECTIVE DATE: 22-AUG-1995 . 7 '

10) STABILITY AND REACTIVITY STABILITY:

Stable under normal storage conditions. -

HAZARDOUS POLYMERIZATION:

Will not occur.

INCOMPATIBILITIES:

May react with strong oxidizers.

DECOMPOSITION PRODUCTS: . ,:

Thermal decomposition (destructive fires) yields elemental oxides.

BETZDEARBORN INTERNAL PUMPOUT/CLEANOUT CATEGORIES:

11) TOXICOLOGICAL INFORMATION '  ; -I Oral LD50 RAT: 570 mg/kg I I

. il NOTE - Estimated value- - . . I .. I ... '  :.... 1 . -. . .

. I . ..I .. .. . . n ., .

Dermal LD50 RABBIT: .- .. >5,000 mg/kg L WTr^MV'

.L.L - n:XLa: va.lue 1-

~ -.

I. . ,. ... .......

l L 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY , .

No Data Available.

BIODEGRADATION COD (mg/gm): 42 Calculated TOC (mg/gm): Inorganic, N/A- ..- -..

BOD-5 (mg/gm): Inorganic, N/A ' '

1 BOD-28 (mg/gm): Inorganic, N/A, "L13) DISPOSAL CONSIDERATIONS

.1 Ifthis undiluted product is discarded'as a waste, the US RCRA hazardous waste identification number is:

Not applicable.

l Please be advised; however, that state and local requirements for L waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

I !14)TRANSPORT INFORMATION I, - , . ;o I DOT HAZARD: I ORS (when container > RQ)

UN / NA NUMBER: NA3 082 L DOT EXERGENCY RESPONSE GUIDE #: 31 I

lPAGE 5 CONTINUED I

173

• iv LntiI'ni w* rrmuI- * -

EFFECTIVE DATE: 22-AUG-1995

15) REGULATORY INFORMATION

,11 TSCA:

All components of this product are listed in the TSCA inventory.

CERCLA ANDIOR SARA REPORTABLE QUANTITY (RQ):

IL 72 gallons due to SODIUM NITRITE; SARA SECTION 312 HAZARD CLASS: Il Immediate(acute);Delayed(Chronic)

SARA SECTION 302 CHEMICALS:

No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: .11 CAS# CHEMICAL NAME RANGE 7632-00-0 SODIUM NITRITE 11.0-15.0%

• .JI CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC

• .I ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:

No regulated constituent present at OSHA thresholds 1..I' MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds

. l

16) OTHER INFORMATION NFPAIHMIS CODE TRANSLATION Health 2 Moderate Hazard Fire Reactivity 0 Slight Hazard Minimal Hazard .I Special NONE No special Hazard (1) Protective Equipment B Goggles, Gloves _ I1 (1) refer to section 8 of MSDS for additional protective equipment recommendations.

CHANGE LOG .-

EFFECTIVE DATE MSDS status: 22-AUG-1995 REVISIONS TO SECTION:

REVISED FORMAT SUPERCEDES

• • NEW **

.1

.- I PAGE 6

.Ii 174 Ii A

.10/20/09 ME 15:11 FAX 513 482 7353 PAG - 1 002 r~~~ , .

1% MATERIAL SAFY DATA SHEEr COBRATECO 7-SOS PRODUCTCODE: XI8W'7440 Page 1 of 7

32. August 16, 1999 F

LI \ ....

SKM9N -CREMCAL PRODUCT AND COMAN ME-NCAMN A O . . I . .

1 MAWACTURER:' PMC SPECIALTIES GROLJPINC.

ADDREPSS 501 Mumay Road Cincinnati, OH 45217 ::

EMERGENCY TELEPHONE: (513) 242-3300 (USA)

FOR TRANSPORTATION EMERGENCY: (800) 424-9300 (USA)

CR.-ici NAMM AND . NYM...: Sodium Tolyltriazolc, 50% Water Solution TRADE NAAMS AND SYNONYMS: COBRAIEC Tr-50S CHEMICAL, FAMILY: Triazole FORMUIA; CAHN 3Na l ~SECTON 2CMOMON/5NFORMATION ON W-GREI)ST Material CAS No.

Sodium Tolyltriazole 64665-57-.2 *, . .. 49.5-5 1.0

.. Water .

• .I 7732-J8-5

.; . .; : ., I

.1 .48.5-50.0 Sodium Hydroxide 1310-73-2 <0.5 IlekC QuC A eopy of Teclhni*l fiulletin #: COR4.133 for addidional information.

081699 175

10/20/99 WED 15:11 FAX 513 482 7353 PtA, PG I 003 MATERIAL SAFETY DATA SHEET COBRATEC TT-SOS PRODUCT CODE: XIS1I7440 Page 2 of 7 August 16, 1999 l

. r-,Q3:IQN .3 HAZ.ARDS IDENTIFICATION

.1 POTENTIAL HEALTH EFFEUCS:

E*)~m5 OF FNTRY.1 Eye contact, skin contactlabsorption, ingestion and inhalation.

(AaT ... I MIaterial is corrosive. Contact with the eyes may severely damage delicate eye Eissue.

SKI1 Material is corrosive. Prolonged contact can be destructive to tissue.

MNFrOi Material is corrosive. Harmhfl if swallowed.

MNALATwION ..

Material is corrosive. Harmful if inhaled.

CHRON_ C E___i_/cA__ NoGE__y__1 CARCINOGENICITY: None of the components in this material are listed by 1ARC, NTP.

OSHA, or ACCTIH as a carcinogen,

• • 11

- .1 L

176

/2Z0799 WEsD 15b:1Z a 0-7

-MATMIAL SAFT DATA SHEET COB RATECe TT-50S m - . *. . PRODUCTCODE: XIS8M7440 Page 3 of 7 August 16 1999

. CMION 4 FIRST rAIDMEASURES I E ]EHALED If affected, remove from eposure Restore breathing. Keep warm and quiet GeL medical attention.

I IF ON SEIN Wash affected area thorougly with soap and water. Remove wntaminted clothing. jzwelzy. ctc.

Get medical attention.

Flush eyes with large amounts of water for 15 minutes. Get medical attention.

IF SWALLOWED Never givc anything by mouth to an unconscious person. DO NOT INDUCE VOMITrNG. Give large amounts or water. Get medical attention.-

SECTION 5 FIRE FIGTITINQ MEASURES

. ILASH POINT: INot Applicable.

AUTOIGN9ON TEMPERATURE: .:Not Applicable FLAMMABLE LIMITS iN AIR: Not Applicable EX;TXNGU1SHXNG WEDIA; Not Applicable LI SPECIAL FIRE FIGHTING PROCEDURES: Full protective equipment inciluding self-contained breathing appaatus should be used. During emergency conditions overexposure to Il decomposition products may cause a health =azard. Symptor' s ray not be immediately apparent.

Get medical attention. Water may be used to cool and protect closed containers exposed to extreme heat. --  ; 1.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode (olue Lo the

.-build-up of pressure) when exposed to extreme hea.- . -

, 177

10/20/99 WED 15:12 FAX 513 482 7J53 ML4 PC I 005 MATERIAL SAFETY DATA SHIEET COBRATEC -T50S PRODUCTCODE: X18W7440 *.1 Page 4of 7 Augast 16, 1999

.1 SCTONA A!CCIENTAL REL.EASE MEAS URERS ii.

Usc proper pronal protectivc cqiipmcnt. Isolate and securc the area and follow dhe appropriate emergency guidelines. Collect the material with inert absorbcnt and place in a covered waste dispossl container.

.JI IL I

~~INEQM&MA3N CORROSIVE MATERIAL Avoid contact with skin, eyes and clodiing. DO NOT TAKE 11 INTERNALLY. Clean up spills immediately.

Keep containers tightly closed when not in use. .Store only in containers which are resistant to Ii caustic solutions.

SECTII

._8. XPO

.ll NFPA BASED RATINGS: Health: 3, Flammability: 0, Reactivity: 0 HMIS RATINGS: Health: 3, Flanmnability: 0, Reactivity: 0, PPE: F WHMIS CLASSIEFICATION.; D-2-(B),h RESPIRATORY PROTECTION: If personal exposure cannot be controlled below 2pplicable I

exposure limits by ventilacion, wear respiratory devices approved by NlOSHlMSHA for prorection against mists and vapors.

VEiNTILATION: Local exhaust is recommended.

PROTECTIVE GLOVES: Rubber, vinyl or other impervious material if skin contact can not be avoidcd.

• Il EYE PROTECTION: Usc safety. glasscs with unperforated side shields, or full face shield when danger of splashing is great.

• 11 OTHER PROTECTIVE EQUIPMENT: Rubber apron or similar protective clothing to prevent contact with skin or clothes. 7]I EXPOSURE GUIDEIlhNlSi Sodium HIydroxidc TWA - 2 mgml7 178

10/20/ WED 15:31 999 7;9... r - -a- -. - _

MATERAL SAFETY. PATA SHET -. COBRATECO IT-0S PRODUCTCODE:XISWP7440 I1 . Page 5 of 7 August 16,1999 IS. . 9 PIIYTCAL ANP- CHEMICAl

?ON PROPERTES

-1 BOILING POINT: . . .* 100 0 C FREEZING POINT: .. C SPECC CGRAVIWTY: -1.i9 24°C.

-BULK DENSITY: .- Not Applicable VAPOR PRESSURE AT 20' C: 0.04 mm Hg

-VOT ES YVL  : - Not Applicable SOLUBILlTY IN WATER % BY WT' at 20 Miscible in all proporons

% VOLATIILE-S 33YvoL.UM:- ..-- 50% as water EVAPORATION. ATE. , .Not Applicable A3'PEARANCE AND ODOR: Clear yellow o amber solution, characterisfic odor, pH=13.5 1 10 STABII1TY AND REACTIVI

-.SRCTN STABILITY: Stable INCOMPATIBILIrY: Strong Oxidizing Agents, Strong Acids.

HA7ARDOUS DECOMPOSITION PRODUCTS: BY FIRE: Carbon Dioxide, Carbon Monoxide, Nitrgn oxides, HCN possible in reducing atmosphercs.

HAZARDOUS POLYMERIZATION: G.Will not occur.

3 ** SE ON 11 TOXICOLOGICAL INFORMATION Oral I.Ds (rat) 920 mg/kg (Male) 640 mg/kg (Female)

.,Eye and Skin Irritaant. , -, Can cause sevcrc irritation Lj 179 E

is 10/20/99 WED 15:12 FAX 513 482 7353 P)A PG 0007 COBRATEC' TT-50S

• MATERIAL SAFETY DATA SHEET PRODUCT CODE: X18WI7440 Page 6 of 7 1L August 16, 1999 11 SECTION 12 ECOIGTCAL IN1FORMATION Bluegill Sunfish (96 hr. IC.) 191.2 mg/I Daphnia Magna (48 hr. LC,) 245.7 mg1I Rainbow Trout (96 hr. Lqso) 23.7 mg/i SECTION 13 DTSPMSAL CONSIDERATJONS

.I WASTE DISPOSAL MEIHOD: Dispose of in acordance with federal, satae and local disposal regulations.

I

.. I D.O.T. SHIPPING NAME:

D.O.T. HAZARD CLASS:

U.N. NUMBER:

PACKAGING GROUP:

Caustic Alkali Liquids, n,oas. (Sodium Hydroxide) 8 UN1719 PGol.

.J1I

71 PRODUCT RQ (LBS): 1,000 lbs as Sodium Hydroxide D.O.T. LABEL: Corrosive D.O.T. PLACARD: Corrosive . 1 SECTION 15 RREGM ATORY INORMATTON U.S. FEDERAL REGULATIONS:

Sodium Tolvitriazole (CAN No. 64665-57-2) is contained on the following shemical lists, ,. 11

-1

1. TSCA Inventory LUiS

_ 11 11 180 4

MATERIAL SAFETY DATA SHEET COBRATl3:C6 'T-50S 71* PRODUCT CODE: X18W17440 Pagc 7 of 7 Augist16, 1999

.SETjIO 15 RF£JLAORY INFORMATION (CONT.)

i Sodium 7 Udroxido (CAS No. 1310-7S3-2) is contained on the following chermical lists:

1. Clean Water Act Section 311 Hazardous Substances (ref.: Suspect Chemicals Sourcebook 1997)

2. CERCLA Hazardous Substances (ref.: Sue Chemicals Sourcebook 1997) 3.' OSHA Air Contamiants -(ref.: Suspect Chemicals Sourcebook 1997) -

4. Amcrican Council of Gove e Industrial tygiensts (ACGIH) Threshbld Limit Value Chemiicals (ref.: Suspect Cheicals Siurcebook 1997)

5. OSHA Table Z1-A1 revolded] (ref.: Sunsect Chemnicals Sourcebook 1997) -

6. DOT Hazardous Materials (ref.: Susp Chemicals Sourcebook 1997)

.7. DOT Hazardous Substances Othe Than Radionuclides; and Radionuclides (ref.:

Suspect Chenicals Sourcebook 1997) .

8. Massachusetts Substance List (ref. Suspect Chemnicals Sourcebook 1997)

9. Ncw Jersey Right To Ktow Haiaidous Substance List (ref.: Suspect ChemicalS Sourcebook 1997) -- - - '

NJIS = Special Health Hazard (ref.: Suspect Chemicals Sourcebook 1997)

10. Pennsylvania Hazardous Substance List (ref.: Suspect Chemicals Sourcebook 1997)

PAIE=Environmental Hazard IRERNATIONAL REGULATIONS.-:

SodiumTolvltriaznle (CAS No. 64665-57-21 is eontained on the following chemical lisc:

1. Canadian Domestic Substanc&List SodiWum lydroxide (CAS No. 1310-73-2) is corjtained on the following chemical lists:

1. Canadian Workplace Hiiazardous Materials Inaornation System (WHMIS)

CNI = Ingredient must be disclosed at concentration of I % (rer.. Suspec Chemicals Sourcebook 1997) .

2: Canadian Domestic Substance List ION 16 0-M,R INFORM AMN RE ASON FOR ISSUE: New formar and veriication of inforination.

MSDS NUMBER: X18WT744 -

PREPARED: August 16. 1999 SU11FR1SESUS; March 3. 1998 n3 prCPad:

idtoemnit&n ctmained heecin iL (&lsd on dat 41 svfiliblc to us and is believed ts be corrcct as of thle clzjtL*

howrycr. PMC SPECIAI.EiS GROUP. INC-makcs no warramty. cxprcsscd or implied. rcgarding dic accurAcy elftheSe 6=u iar hilie r.c.ulls to be tilsIined frnm lth Lce thereof 181

I5AO4M 3Z..'f lI BRIGHT DYESrm MATERIAL SAFETY DATA SHEET FLT YELLOW/GREEN'm LIQUID CONCENTRATE IL PAGE 1OF3

.i MSDS PREPARATION INFORMATION PREPARED BY: T. P. MULDOON IL (937) 886-9100 DATE PREPARED: 1/01/02 PRODUCT INFORMATION - II MAUNFACTURED BY: KINGSCOTE CHEMICALS 3334 S. TECH BLVD. IL MIAMISBURG, OHIO 45342

.1 CHEMICAL NAME.NOT

~.......................................................NOAPIBL CHEMICALNAME CHEMICAL FORMULA ............................................. NOT APPLICABLE.

CHEMICAL FAMILY ............................................. AQ.UEOUS APPLICABLE DYE PRODUCT IL AQOUDPRU HAZARDOUS INGREDIENTS NONE PER 29 CFR 1910.1200 .I PHYSICAL DATA PHYSICAL STATE............................ LIQUID ODOR AND APPEARANCE...........................................YELLOW/GREEN, WITH NO APPARENT ODOR SPECIFIC GRAVITY.....................................................APPROXIMATELY 1.05 VAPOR DENSITY (mmnHg © 250 C) .. ,,,,,,,,,,,,,,,,,,,,,,,,-23.75 VAPOR DENSITY (AIR =1)...........................................'-0.6 EVAPORATION RATE (Butyl Acetate- 1) ............. ,.-1.8 BOILING POINT I 00 degrees C (212 degrees F) 1...........,,,,..........

FREEZING POINT ........................................ . ,,,,,,0 degrees C (32 degrees F) pH SOLUBILITY IN WATER  ; .HIGHLY 8.0 OR ABOVE SOLUBLE I:

FIRE HLAZARD CONDITION OF FLAMMABILITY,,,,,,,..........................NON-FLAMABLE MEANS OF EXTINCTION ....................................

FLASH POINT AND METHOD ..........

WATER FOG, CARBON DIOXIDE, OR DRY CHEMICAL

. ..... NOT APPLICABLE UPPER FLAMABLE LIMIT...............................NOT APPLICABLE Ii LOWER FLAMABLE LIMIT ........ ,,NOT APPLICABLE AUTO-IGNITION TEMPERATURE.................................NOT APPLICABLE HAZARDOUS COMBUSTION PRODUCTS .................... NOT APPLICABLE UNUSUAL FIRE HAZARD ............................................ NOT APPLICABLE 1

Ii 18Z Ii Ii

BRIGHT DYESTh MATERIAL SAFETY DATA SHEET FLT YELLOWiGREENm LIQUID CONCENTRATE

'PAGE 2 OF 3 EXPLOSION HAZARD L

SENSITIVITY TO STATIC DISCHARGE ........ ,,,,;NOT APPLICABLE SENSITIVITY TO MECHANICAL IMPACT ................... NOT APPLICABLE REACTIVITY DATA PRODUCT STABILITY ... .................... T..B.L....................

.T.E .

PRODUCT INCOMPATIBILITY ,,,,,......... ..................NONE KNOWN CONDITIONS OF REACTIVITY ....... -..NOT APPLICABLE HAZARDOUS DECOMPOSITION PRODUCTS ..............NONE KNOWN TOXICOLOGICAL PROPERTIES SYMPTOMS OF OVER EXPOSURE FOR EACH POTENTIAL ROUTE OF ENTRY:

INHALLATION, ACUTE ............................................... NO HARMFUL EFFECTS EXPECTED.

INHALATION, CHRONIC............................................ . NO HARMFUL EFFECTS EXPECTED.

SKIN CONTACT ,,,,,,,,,,,,,,,,_,,,,,,,,,,,,,,,_. . ............. ... WILL TEMPORARILY GIVE SKIN A YELLOW/GREEN COLOR.

EYE CONTACT ,,,,,,, .. ...............

,.. .................... ,NO HARMFUL EFFECTS EXPECTED.

INGESTION,*,_,,,...... ....................... .,.......,..... ;-,jURINE MAY BE A YELLOW/GREEN COLOR UNTIL THE DYE

-HAS BEEN WASHED THROUGH THE SYSTEM.

EFFECTS OF ACUTE EXPOSURE ....... .. NO HARMFUL EFFECTS EXPECTED EFFECTS OF CHRONIC EXPOSURE , ... NO HARMFUL EFFECTS EXPECTED L THRESHOLD OF LIMIT VALUE.._......NOT APPLICABLE CARCINOGENICITY. .. . ....... -.NOT LISTED AS A KINOWN OR SUSPECTED CARCINOGEN BY -

IARC, NTP OR OSHA.

TERATOGENICITY -----............................................ NONE KNOWN TOXICOLOGY SYNERGISTIC PRODUCTS NONE KNOWN PREVENTATIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT GLOVES,,,,,,,,,,,,,,,,,,,,,,.,,............... ... And.

. ,,_,,,,,,,RUBBER.-

RESPIRATORY . ...............

_ Cow=.

USE NISOH APPROVED DUST MASK IF DUSTY CONDITIONS

EXIST.

CLOTHING ........... _..... .... .vo

,,,,,,,,,,,,,,,,PROTECTIVE ,CLOTHING SHOULD BE WORN: WHERE CONTACTIS UNAVOIDABLE., ,

OTHER ............................... ... . ,-.HAVEACCESS TO EMERGENCY EYEWASH.

183

BRIGHT DYESTh MATERIAL SAFETY DATA SHEET FLT YELLOW/GREENTH LIQUID CONCENTRATE I

PAGE 3 OF 3 PREVENTATIVE MEASURES (CONT.)

ENGINEERING CONTROLS ............................... NOT NECESSARY UNDER NORMAL CONDITIONS, USE LOCAL VENTILATION IF DUSTY CONDITIONS EXIST.

SPILL OR LEAK RESPONSE .......................................... CLEAN UP SPILLS IMMEDIATELY, PREVENT FROM ENTERING DRAIN. USE ABSORBANTS AND PLACE ALL SPILL MATERIALS IN WASTE DISPOSAL CONTAINER. FLUSH AFFECTED AREA WITH WATER. 11 WASTE DISPOSAL .INCINERATE OR REMOVE TO A SUITABLE SOLID WASTE DISPOSAL SITE, DISPOSE OF ALL WASTES IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.

HANDELING PROCEDURES AND EQUIPMENT ............ NO SPECIAL REQUIREMENTS.

STORAGE REQUIREMENTS .........-......... ..................... STORE AT ROOM TEMPERATURE BUT ABOVE THE FREEZING POINT OF WATER.

1 SHIPPING INFORMATION............................................KEEP FROM FREEZING  ;

FIRST AID MEASURES FIRST AID EMERGENGY PROCEDURES 11 EYE CONTACT FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET SKIN CONTACT T...............................

MEDICAL ATTENTION IF IRRITATION PERSISTS.

WASH SKIN THOROUGHLY WITH SOAP AND WATER GET MEDICAL ATTENTION IF IRRITATION DEVELOPS.

i INHALATION . .IF DUST IS INHALED, MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT GIVE OXYGEN AND GET IMMEDIATE MEDICAL ATTENTION.

INGESTION.DRINK INGESTION ................................................................. DRN PLENT.Y PL TYO OF WATER WA RA AND DIDU INDUCEEV VOMITING.

M IN GET GT MEDICAL ATTENTION IF LARGE QUANTITIES WERE INGESTED OR IF NAUSEA OCCURS. NEVER GIVE FLUIDS OR INDUCE VOMITING IF THE PERSON IS UNCONSCIOUS OR HAS CONVULSIONS.

SPECIAL NOTICE ALL INFORMATION, RECOMMENDATIONS AND SUGGESTIONS APPEARING HEREIN CONCERNING THIS PRODUCT ARE BASED UPON DATA OBTAINED FROM MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES;'

i HOWEVER, KINGSCOTE CHEMICALS MAKES NO WARRANTY, REPRESENTATION OR GUARANTEE AS TO. THE ACCURACY, SUFFICIENCY OR COMPLETENESS OF THE MATERIAL SET FORTH HEREIN. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY AND SUITABILITY OF HIS OWN USE, HANDLING, AND DISPOSAL OF THE PRODUCT. ADDITIONAL PRODUCT LITERATURE MAY BE AVAILABLE UPON REQUEST. SINCE i

ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE BY KINGSCOTE CHEMICALS AS TO THE EFFECTS OF SUCH USE, THE RESULTS TO BE OBTAINED OR THE SAFETY AND TOXICITY OF THE PRODUCT, NOR DOES KINGSCOTE CHEMICALS ASSUME ANY LIABILITY ARISING OUT OF USE BY OTHERS OF THE PRODUCT REFERRED TO HEREIN. THE DATA IN THE MSDS RELATES ONLY TO SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS.

END OF MATERIAL SAFETY DATA SHEET 184

-U

.-A rig 9% 4"i 1 . - - . . . - . . - - _. .- - I

-:MATERIAL SAFETY DATA SHEET - f POJ-YPIJREIC5.

Clarifloc C-9490 Polymer One Gatehall Drive.

Parsippany, New Jersey 070S4 Phone Number: (201) 292-2900 3 IO Io EMERGENCY CONTACTS: CHEMTREC (800) 424.9300 Date Issued Jaruary25.1995 Supersedes MSDS Dated July 15. 1991 lIMIS H-ea~lh 1Fire 2 Reactivfty 0 NFPA Heakthi1Fire 2Reactivity 0

1. Identification and Physical Data Vapor Pressure at 2O C Not detem*d '

Product Name G-9490 PoyMer Vapor Density Heavier Msn ai

• Voiatili lo Org. Compounds Not deternr ed Product Class .Cationic Polyacrylarnude  % Volatile By Volume 50-7QY - -

DOT Hazard Class Comb aeLquid for bulk BoSling Range .100' C and aboae

-sipmeans only; see Sece. XIV xat Specific Gravity *1.0 (a ID Number NA 1993 Solubility In Water -10% (foms gel)

Shipping Name Combustible Liquid. nos, NA 1993, PG 111. (Contans Petroleum DistIae) Evaporation Finte Not detonrmind Melting Point Nitapplkabie Appearance and Odor Whitnliquidemulsionwkhslightorgar odor C

.11. Hazardous' Ingredients Chwni= Narne CAS Number 1TWATLV OSHA PEL STELTLV Ug~ht Hyeutiurew Petrolauff DUfa 647'2-47-8 #8 EMMY18te0 NOW-OnWXO. Btar~hed 68U412 - E1190ftwe No0C 28* WA T1Vew swnsofr fsI*fl~s is abLuu 100 DOpM Ill. Fire and Explosion Data LEL 0.9 6estimaw) Flashpoint >65IC (Setaflash Closed CuP)

Extinguishing Media Use carbon diorde or dry chemical for small fires aid fog orfoam for large fires.

Unusual Fire and Explosion Hazards When exposed to extremo heal, dosed containers may rupture due to buildup of pressure and release ignitable vapors Water ca cause extremely slippery floor surfaces.

Special. Fire Fighting Procedures Wear self-contained breathing apparatus and complete personal protective equiipmaent when erntring confined areas where Uerm potential for exposure to vapors or combustion product To on ba ow A. hlnror,?uVn efIsm hetrn i a1Crff. low r o Aabfty wtuverf D; Mumo kW Vns s0ircy or of CrVW om nr-fe FbW dom *woc aI a uabaky of ny wth' W is aoVMCrewobowt rPu Usr. Alt matu nt pay hazt w 1 bua us udth ol Ach wmo rm M ds the rtsmmswe b olIn. we te tu only h PW O 185 I

AfPR 26 '95 03:02PM POLYPLRE INC 2812925295 P.3/5 IV. Reactivity. Data Stable Ves Hazardous Polymerization? no Conditions To Avoid Avoid open flames. hot sudaces or oter ignition sources.

Materials To Avoid Strong oxidming agents Hazardous Decomposition Products .

Nommily stable. Combustion producs may include ammorra and oxides of carbon and nitrogen.

V. Health Hazard Data .

Effects of Overexposure.

Ingestion -I Cor6is eeges matrTfuhmbe X:,~ Mayr is in of asuoefnsruriaCorsrdtnt.it aspi~tdota i..ings dsg . IL rges:a or may cams pwr rran. aty ud pa yd Inhalation BreW*V2PCMM%1 crmsspkawyisystmmand D bsaqddfce& Effecs cnmcta rier*synan m"=Lyda haa~dacmieskr n and drowsrmm C Skin Absorption P--. r d 8S.

ahmsdarywrade.

as Probiged x' ,lo rrind prriod

.my srnn a ryzTKrA= UrmgI.ig or*60blhU

.11 Skin Contact con atsna tmay ass moae scihtaon. Probgec ewxsum me~ ause gyh or delaing md a9Cn ttn dri. .

Eye Contact P mctisnadswtad casa cmsevaraeyemtn. PenanridaTOVO POW gVconmcdS prolqA g.

Chronic Effects

• ~ts ao rnay aggre ore hifkA orcdfed proluma~y caseoeve opmfldn#

~tonqs of asss or adw big dixdm Repealud exP 1 an== of 8 4wzfiL I

Emergency and First Aid Procedures Eye Contact mrriedimulysh wr wetS 1 rriortgr. LUuppandbwer beyeio returnv dfchitcadL Getn a Skin Contact Wafsh sin wh sop and water. Ram anld Laudw rmrn I atdig befohn rsa. Got emical ;eirnitfd fn persi.

Ingestionl DO NOT INDUCE VOMITNG. Ivcam Is ==I=siM alort, give 2 - 3 gasses of walar3 duhk. GET rMEDIATE MEDICALATTnENlO Inhalation -l Move -tded twsh ar. Abrnirtar azidical respaabw Mreqains. Get meckal sn P d4 C Po~ DA Jam" 2518 186*

-- ri-. Co Vj CJ-9icrof &ArurpL. I C - -

VI-.Spill Or Leak Procedures Steps to Be Taken In Case Material is Released or Spilled:

Veraan a r s Du $P anm c rDsposaorrouse. Ascb iejduesnrhtrrrWc. Fl ara vtwaer. Preven? pdyrnr wuard erean ng c:=b wam. Wet p~otr rrmay 0AveryslPpY Iorra Waste Disposal.7Method ksdneras Dorace hi W0 inm n vederwaM3andL oc regaonl The r I,as30is rntat~

h usxwawwwcu RCRAmg iar.,

VII. Special Protection information

_ Respiratory Protection If Oar 3 w approved Xtn ..

Ventilation Nawn* or 9warv vwdwkn is ad= br gmm crdtom Lor mv u ? a r o b ~ c to l f s ft u i -

cp~~a t~ Cn

~t~t~ Ba~ca.rris orvapas.

L .Protective Gloves,.

JNecMne. pdlyl, butL ntsbror rSiAe glt s ars nabber  %-C C . . - . , .- - . . .

• Eye Protection -

COwafic SPIas gogg&

j Other Protective Equipment Fora vmocr=.

peratu azveai. apr and +/- brafoscovurs axrucorwdnr. AszdtysherI ye wash tardy m be avalaia Vill. Special Precautions Spifs of pro~ rrn r uiyfry. S~u zterr1res betwen OW 401C. Keepo ruinerw cI whOnrxht use IX. State R-T-K Information CheminJ Name CAS Number Cwwwlit LWt F Pewen Otma 64742-474 E Nonwj sMrnmd i Ba 69412-54 Catorc PoaycyfIe 3418-2&4 Notic Sudamra 1t&d4n Wow 7732-18-S Auramrie 74-1 Pisa 4 Juurw_. =S a_ rmn4POW 187.

25 r. -'

PPR 26 'S5 PP '95 03:03PM1 POLYPIRE 03:03P!'l POLYPU INC 2012 I!'C 2012925-dV - P . 5/5 I

X. SARA Title III Section 313 Information Not Appcable IL XI. RCRA Information IL Not regulated as a hazardous .waste. DEsposal Code Now A

XlI. CERCLA Information Not Appficabt Ii

'i XIII. Califomia Proposition 65 Information Product contains detectable amounts of acrylamide (CAS# 79-06-1) which is known to th State of California to be a carmwgmn I I

.1 XIV. Other Information An components of tis product arm listed in the TSCA inventori.

-I Acrylamide is described as reasonably anticted to be a carciogen by the National ToCoogy Prgram (NMP) and as a probftft carcnogen by the International Agency for Research on Cancer (.ARC)*

The D.O.T. defines Combustible Liquid as a hazard cas only for bulk padcagins. Le. when a single pacdaoing has a niiings I1 capacity greater than 4S0L (119 ganxs).  ;

• 11

-I

. I 1

I1

-1 POW

• d4 CdwbC C4M p"M ToNL JwWY25. = 188 I

.5AMM

-MATERIAL SAFETY DATA SHEET PRODUCT

^NALCO OPTIMER 9905

. EMERGENCY TELEPHONE NUMBER(S)

E - - (800) 424-9300 (24 Hours) CHEMTREC -

I1. I CHEMICAL PRODUCT AND COMPANY IDENTIFICATION .. 1-PRODUCT NAME: OPTIMERV 9905 APPLICATION: FLOCCULANT';

COMPANY IDENTIFICATION: I - Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 -

EMERGENCY TELEPHONE NUMBER(S): (...0 4424-9300 (800) 24 -93. (24 (24 H or -

Hours) CHEMTREC NFPA 704MIHMIS RATING  :.. I .

HEALTH: 01 1 FLAMMABILITY: 1 /1 INSTABILITY: 010 OTHER: I .I 0 = Insignificant I = Slight 2 = Moderate 3 = High 4 - Extreme

2. lCOMPOSITIONIINFORMATION ON INGREDIENTS . I Based on our hazard evaluation, none of the substances in this product are hazardous.

II a%#. I I jA7A^fnc a

intFMTIF&rATrnm I%&, W a m-a-m. a am a Na II

- Id -II ---- I I

• • EMERGENCY OVERVIEW" CAUTION May cause irritation with prolonged contact. Toxic to aquatic organisms.

Do not get in eyes, on skin, on clothing. Do not take internally. Do not breathe dust. Water In contact with the product will cause slippery floor conditions. Wear suitable protective clothing. In case of contact with eyes; rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. - - - -

May evolve oxides of carbon (COx) under fire conditions.. May evolve oxides of nitrogen (NOx) under fire conditions. Water in contact with the product will cause slippery floor conditions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin HUMAN HEALTH HAZARDS - ACUTE:

I '.' .

EYE CONTACT:

May cause irritation with prolonged contact.

SKIN CONTACT:

May cause irritation with prolonged contact.

INGESTION:

Not a likely route of exposure. No adverse effects expected.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 '

1/9 189

I IU-

& .MATERIAL SAFETY DATA SHEET NALCO PRODUCT OPTIMER 9905 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) CHEMTREC iI INHALATION:

Repeated or prolonged exposure may irrifate the respiratory tract.

SYMPTOMS OF EXPOSURE:

Acute:

A review of available data does not Identify any symptoms from exposure not previously mentioned.

Chronic: L A review of available data does not Identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not Identify any worsening of existing conditions.

4. l FIRST AID MEASURES EYE CONTACT:

Flush affected area with water. If symptoms develop, seek medical advice.

SKIN CONTACT:

Remove contaminated clothing. Wash off affected area Immediately with plenty of water. If symptoms develop, seek medical advice.

INGESTION:

Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If symptoms develop, seek medical advice.

INHALATION:

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.

NOTE TO PHYSICIAN:

Based on the individual reactions of the patient, the physician's Judgement should be used to control symptoms and clinical condition.

5.FE F N M RE .

I5. l FIRE FIGHTING MEASURES I FLASH POINT: Not applicable EXTINGUISHING MEDIA:

Not expected to bum. Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARD:

May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions.

Water in contact with the product will cause slippery floor conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 2/9 190

MATERIAL SAFETY DATA SHEET I PRODUCT:

^NALCO . OPTIMER 9905

-. EMERGENCYTELEPHONENUMBER(S)

I Ianny A')A-n'2nn {)A U-..'. P!UDIATMF1 6E . .A E MEA-S

.R.E SURE

.. S . . n. ' .

16. 1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: v-  ; .

Notify appropriate government, occupational health 'and safety and environmental authorities. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection).

METHODS FOR CLEANING UP:

Remove as much as possible with broom, scoop or vacuum, as the addition of water causes slippery floor conditions. Dispose of material In compliance with regulations indicated In Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

This product is toxic to fish. It should not be directly discharged into lakes, ponds, streams, waterways or public water supplies.

17. I HANDLING AND STORAGE .I-,. -- : , - , . ..

HANDLING: . . . _ . . . .

Do not take intemally. Ensure all containers are labelled. Avoid eye and skin contact Avoid generating dusts.

STORAGE CONDITIONS:

Store separately from oxidizers. Keep in dry place.

8. l EXPOSURE CONTROLSIPERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS:

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.

ACGIHITLV:

Substance(s)

Respirable Nuisance TWA: 3 mglm3 .

Particulates Inhalable (Total) Nuisance TWA 10 mgim3 Particulates OSHAIPEL:

Substance(s)

Respirable Nuisance TWA 5 mg/m3 Particulates Inhalable (Total) TWA: 15 mglm3 (total dust)

Nuisance Particulates ENGINEERING MEASURES:

General ventilation Is recommended. Local exhaust ventilation may be necessary when dusts or mists are generated.

RESPIRATORY PROTECTION:

Respiratory protection Is not normally needed. An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. A dust respirator may be used.

Nalco Company 1601 W. Diehl Road* Naperville, Illinois 60563-1198 .

(630)305-1000

' 9!

191

hiALCO MATERIAL SAFETY DATA SHEET I

)0A LCOPRODUCT NALCO OPTIMERO 9905 EMERGENCY TELEPHONE NUMBER(S)

(800)424-9300(24 Hours) CHEMTREC HAND PROTECTION:

Nitrite gloves, PVC gloves. Neoprene gloves, Rubber gloves, Butyl gloves, Cloth gloves SKIN PROTECTION:

Wear standard protective clothing.

EYE PROTECTION:

Wear safety glasses with side-shields.

HYGIENE RECOMMENDATIONS:

Keep an eye wash fountain available. Keep a safety shower available.

HUMAN EXPOSURE CHARACTERIZATION:

Based on our recommended product application and personal protective equipment, the potential human exposure is: Moderate II

19. 1PHYSICAL AND CHEMICAL PROPERTIES --- 1 .J PHYSICAL STATE Granular, Solid APPEARANCE White ODOR Slight, Ammoniacal SOLUBILITY IN WATER Partial pH (5 %) 2.5-4.5 Note: These physical properties are typical values for this product and are subject to change.

10. lSTABILITY AND REACTIVITY j STABILITY:

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

CONDITIONS TO AVOID: ll Moisture MATERIALS TO AVOID:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, II permanganate) may generate heat, fires, explosions and/or toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS:

Under fire conditions: Oxides of carbon, Oxides of nitrogen Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 11 92 491

- . . MATERIAL SAFETY DATA SHEET PRODUCT -- .  ;

'NALCO OPTIMER 9905 EMERGENCY TELEPHONE NUMBER(S)

- WU)

-- 4Z4-J3UU (Z4 1iourS) GEM= I KM l11. lTOXICOLOGICAL INFORMATION- ---

The following results are for the product.

ACUTE ORAL TOXICITY:

Species LD50 -Test Descriptor

Rat > 5,000 mg/kg Product Rating: Non-Hazardous '

SENSITIZATION: - , ,.

The results of testing on guinea pigs showed this material to be non-sensitizing. , ', ' ,

CARCINOGENICITY:

None of the substances In this 'product are listed as carcinogens by the Interational Agency for Research o'n Cancer (IARC), the National Toxicology Program (NTP) or the Arnerican Conference of Governmental Industrial Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION: , , ' ' , -

Based on our hazard characterization, the potential human hazard Is: Low

12. l ECOLOGICAL INFORMATION' ECOTOXICOLOGICAL EFFECTS:

The following results are for the product and a similar product.

ACUTE FISH RESULTS:

Species Exposure LCO0 Test Descriptor Rainbow Trout 96 hrs 0.21 mg/l Similar Product Rating: Very toxic -.

ACUTE INVERTEBRATE RESULTS:

Species I Exposure LC50 EC50 Test Descriptor Daphnia magna 148 hrs 0.34 mgI 0.26 mgAl Similar Product Rating: Very toxic -  : -

PERSISTENCY AND DEGRADATION:

Chemical Oxygen Demand (COD) : 225,000 mgAI -

Biological Oxygen Demand (BOD):

Incubation Period Value Test Descriptor 5,000 mqA Product Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 -

(630)305-1000 5/19' 193

^NALCO I MATERIAL SAFETY DATA SHEET PRODUCT- I OPTIMER 9905 Ii EMERGENCY TELEPHONE NUMBER(S)

Ainne AiAv.nn ruuTo~r- IAU IS-%

I ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard Is: High Based on our recommended product application and the product's characteristics, the potential environmental exposure is: Low If released into the environment, see CERCLAISUPERFUND in Section 15.

Ii

13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.

It As a non-hazardous waste, it Is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility.

Ii 114. l TRANSPORT INFORMATION, ,

• Ia Ii The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. Ii LAND TRANSPORT:

Proper Shipping Name: PRODUCT IS NOT REGULATED DURING I

TRANSPORTATION AIR TRANSPORT (ICAOIATA): I Proper Shipping Name: PRODUCT IS NOT REGULATED DURING MARINE TRANSPORT (IMDGIAMO):

TRANSPORTATION I1 Proper Shipping Name: PRODUCT IS NOT REGULATED DURING TRANSPORTATION Ii

15. REGULATORY INFORMATION A

NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:

Based on our hazard evaluation, none of the substances in this product are hazardous.

CERCLAISUPERFUND, 40 CFR 117,302:

Notification of spills of this product is not required. A Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 A

(630)305-1000 6/9 194 Ii Ii

MATERIAL SAFETY DATA SHEET

.NALCO- PRODUCT OPTIMERtE 9905 EMERGENCY TELEPHONE NUMBER(S) 7.. I

-.(800)424-9300(24 Hours) CHEMTREC SARFSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302,311, 312, AND 313:

SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200.

Under SARA 311 and 312, the EPA has established thresh61d quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever Is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. -

SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372):

This product does not contain substances on the Uist of Toxic Chemicals.

TOXIC SUBSTANCES CONTROL ACT (TSCA):  ;' '

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act: ' '

When use situations necessitate compliance with FDA regulations, this product is acceptable under: 21 CFR 176.170 Components of paper and paperboard In contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods.

It Is limited to use as a retention aid and flocculant employed prior to the sheet forming operation In the manufacture of paper and paperboard Inamounts no greater than those required to produce Its Intended technical effect" -

FEDERAL WATER POLLUTION CONTROL ACT,'CLEAN WATER ACT,40 CFR 401.15/ formerly Sec. 307,40 CFR 116A Ifomierly Sec. 311:

None of the substances are specifically listed In the regulationr.

CLEAN AIR ACT, Sec. 111 (40 CFR 60, Volatile Organic Compounds), Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and 11Ozone Depleting Substances):

None of the substances are specifically listed In the regilation.

CALIFORNIA PROPOSITION 65:'

Substances known to the State of California to cause cancer arepresent as an impurity or residue.

MICHIGAN CRITICAL MATERIALS:

None of the substances are specifically listed In the regulation.'

STATE RIGHT TO KNOW LAWS: --

None of the substances are specifically listed In the regulation.' ' -'

NATIONAL REGULATIONS, CANADA:

Nalco Company 1601 W.- Diehl Road

• Naperville, Illinois 60563-1198' (630)305-1000 7/9 195

- _110111111111

. MATERIAL SAFETY DATA SHEET II

)0LCO PRODUCT 1 I

~NALCO OPTIMER 9905 1 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours) . CHEMTREC . i WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION:

Not considered a WHMIS controlled product, IL CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances in this preparation are listed on the Domestic Substances Ust (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.

16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows:

' The human risk is: Low The environmental risk is: Low I Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process.

This product material safety data sheet provides health and safety Information. The product Is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the I recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to Insure safe workplace operations. Please consult your local sales representative for any further information. j REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight# CD-ROM Version), AMel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer. -

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198 (630)305-1000 8/9 196

MATERIAL SAFETY DATA SHEET MNALCO PRODU~CMVTEEE~~I tI~D OPTIMER*~ 9905~~*~fI~BM (800) 424-9300 (24 Hours) CHEMTREC Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Adel Insight# CD-ROM Version), Adel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnat, OH, (TOMES CPS# CD-ROM Versi6n), Micromedex,]Inc., Englewood, CO.

Ariel Insight# (An Integrated guide to industrial chemicals covered under major regulatory and advisory programs), I North American Module, Western European Module, Chemical Inventories Module and the Generics Module (AMiel Insight# CD-ROM Version), AMel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Prepared By: Product Safety Department Date issued: 02/22/2004 Version Number: 1.8

- - - - I

. I . .

Nalco Company 1601 W. Diehl Road

• Naperville, Illinois 60563-1198

(

-- 1630)305-1000 9/9 '

.. ...I.... . I ..

i97 111111M

A.si...A to: 7n77 FORM INFRMKIATIO OumNLY Expires On:

.tr 11 MATERIAL SAFEl rI I BASF Corporation Chemicals Division 100 CbMyn as"1bE4wp"by.

• Juersey 071K c01al 3160 BASF I

DATA Si PRODUCT I p latf9n..... . -

I

.I I

TRADE NO~

hi -A. de. . . . ..

.TR O. . ,-:. .

CHEMICAL I I

1. ~PEL/TtiV - SOURCE Not established

1 241-7 ntli 100 Contsins:

lEthylen Glycol 107-21-1 -95 s0 pp" Coiling OS"

.iI

1 Proprietary additlv I U Not *Stablihld SARA Title 11 Sct. 213: Listed.

I1 VOILINOMELTINQ POINT fL` O mH: u0 330F/N WA pH: 10.0-11.0 VAPOR PAE9SLIt m Hg 20 C: IS SPECIFIC GRAVITY OR DULK DENSITY: 1.123 SOWBILITY IN WAER: Cooploet*

APPEARWCE: Clear. Dyed Liqkud ODOR: Glycol INTENSITY: S1lght 11 FLASH POINT (TEST KETHOD): 202F C.O.C. AUTOGNTION TEMP: 7756F FLAMMABILITY LIMITS IN AIR IX BY VOL) LOWER: N/A UPPER: N/A EXTINGUISHING Use water fog, alcohol foam, C02 or dry chemIcal MEDIUM extinguishing media. NFPA: I/I/O SPECIAL Firofighters should be equipped i1th self-contaired FIREfIO fTING breathing apparatus and turnout gear. Avoid breathing PROCWURES vasors of heated or burnint antifreeze.

UNUSUAL FIRE Vapors trom hoaTe-5above f 1ash point) pr dLmt may trave to AND EXPLOSION a sourc of ignition and flash back.

UAADS 11

-.. ~ - _ p .*i i ES # g W

. 201-316-3000 .

CHERTREC 1300-424-9300

. Jte UOP-D V AllAY 0DS e 1%0we w

.. rl... - t-. . . - -j 198

] Assigned to: ???FOR INFORMATION ON4LY .. Expires On:,

PRODUCT NUMBER.' 51770 241-7 Arntifrimm& Formilation 1TOXICOLOGICA TEST DATA: RESULT:

• ~241-7 Antifreeze formzlation EthylenOMl1ycol

• Rat. oral 1.050 5.5 glkg.

l~menRepoted Lethal Dosi' 00cc.

lye and isanin.fitant 110ratesModerately toxic by'

• EFFECTS OF OVEREXPOSURE.'- -.-

Contact with this prodjct causes eye and slcln irritation.

RIVhalation of vapors or mist& maY be Irlitatirig to -the irespiratory 'traCt.

Which Ischaracterized by wevere abdoeiral dis'twrbanee,- entral 9eV~ousl lyrphocyto counts.

_ ~~~~chronic overexposue" may lead to liver degeneration and svr ea aae Animal studies indicate that .thyleneaglyool may be ..mbryotoxic and FiRST AID PROCEDURES:

Eyes-lsmodiately.wash eyes with Duinning waster for 15 minuIates.

If -irritation develops, constult

• physician.

ki-Wash affeacted areas with soap and Water., Remove and lxunder contaminated clothing bef ore rause. U.:irritatio eeo$

cnuta physician.>m ~ ~ eeos salowe, d~uja'jiw~k~rand in a istply induco.

Irgstin-f vomiting. Never give fluids or indiace vomiting If the victim is urconscious or having convulsIons.. Oct I tolte medical mttantitnm. -.

Irihilation-Move to f resh sir. -- AIdAn breathing, if 1*Oessary.

and got Imtediate medical attention.

"; STABUJrTY: stable.

CONTINSTO AVOID: N/A CHMIALINCOMPATIBILITY: N/A.

HAZARDOUS DECOMPOSITION PRODUj:TS:' N/A LHAZARDOUS POLYMERIZATIOIL Does not occir CONDITIONS TO AVOID: W/A CORROSIVE TO METAL' N OXIDIZER.' NO RESPIRATORY PROTECTI?~aegneae.%'a IOI/SI approveO organic vapor/mist respirator.

EYE PROTECTIOM If splashing can occur, use chemical poggles or fullI face shield.

PROTECTIVE CLOTHING: Use rubber gloves'. aprocn and shoes.

Remove contaminated clothing lamediately arid wrash bef ore reouse..

.. *..7 VENTILATIOft Local exhaust to control vapors or inists.

OTHER:. N/A ID)o1's' PAGE 2OF 4 199

Assined o: 7?? OR IFORMTIONONL Assigned to: ?7?? FOR INFORMATION ONLY On:

Expresro 3 or. /

Il1 JI PRODUCT NUMBER: 581770 UI24-7 Antifreeze Formulation ..

__-1 . .1- - - -- __- - I.-__

ENVIRONMENTAL TOXICITY DATA I.- ___1.1.__,_.__ - - -- -_ - _- - -_1_.-_ - - 1.._1-_1_.'__1_-11_ _- .1_.-1__1-.1 --- ----

~-~Iwv~j~

.I Aquatic toxicity rating: TlAW 1000-100 ppm.

SPILL AND LEAK PROCEDURES:,

SpIis. should be contained. solIdified, *nd placed in suitable containrrs For disposal. This material Is not regulated ur er RCRA or CERCL (OSUPerfund'). Clean up quickly as spills are a slipping hazd.

..JI tAZARDOUS SUBSTANCE SUPERFUND WASTE DISPOSAL METHOD-No RO Obas *JI

1 Incinerate or bury In a licensed facility.

Do not discharge into waterways. Discharge to sewer systnos with prior approvals Is acceptable.

HAZARDOUS WASTE 40CFR261:

CONTAINER DISPOSAL:

. Dispose of In licensed facility.

. HAZARDOUS WASTE NUMBER:

.I Reoowaend crushing or other meant to prevent tmauthoarizd rus.

D.O.T. PROPER SHIPPING NAM 449CFR172.101-102) HAZARDOUS SUBSTAN

• 11 (49CFR CERCLA LIST)

None, .N .

._ . .REPORTABLE QUANTITY (RO Nor*

D.O.T. HAZARD CLASSIFICATION (CFR172101-102)

PRIMARY None SECONDARY NWA Ii 11 L

D.O.T. LABELS REQUIRED 949CFR172.101-ID2) D.O.T. PLACARDS POISON CONSTITUEEN REQUIRED (CFR172.504) (49CFR172.203(K1)

None Wane N/A BILL OF LADING DESCRIPTION Ii AntIfreze Preparations, Proprietary (Ethylene lycol ase)

CC NO. 32

• LNINA CODENone DATE PREPARED: 2 5 / 86 UPDATED: 2 / 24 / 89 J.I WHILE BASF CORPORATION BELIEVES THE DATA SET FORTH HEREIN ARE ACCURATE AS OF THE DATE HEREOF. BASF CORPORATION MAKES NO WARRANTY W3TH RESPECT THERE10 AND EXPRESSLY DISCLA1MS ALL LIABILITY FOR RELlANCE THEREON.

SUCH DATA ARE OFFERED SOLELY FOR YOUR CONSIDERATION.SNVESTIGATION.

AND VERIFICATION.

711 l1 200

-I

. AsgnedFto:??? FOR INFORMATION ONLY Expires On: V iI ' - ' .  ; . . ' :d rnf . 7 PRODUCT NUMER 8770 241-7 Atfree Flaton

- 241-7 Antlfreeze Formulation WARNilK: '-' . -'" - -

_ ~~~~CONTAINS tShYL'ENE OLY0OL (CAS No. ................

1D7-21-I) .... .

CONTACT MAY CAUSE TEMPORARY EYE AND .5IN SRR5TATION.:

2WGESTION NAY RESULT IN ACUtE POISDN)NG, CFAUACTERIZED BY SEVERE.AB)OIhlW .

IDISTLRBANMES. CENTRAL INEROUS SYSTEM OEPRES-SION AND.POSSIOLt RESPIRATDRY,0R.

RENAL] FAILURE PROLONCED lIFALATDNOF YVAPORS NAY tESiUL TSN .RRITAtSON D^

_UNeD SCtOUSS. CHRONIC OVEREXPOSURE NAY LEAD.ST YiVER AND KIDNErY Dt4A3E.

tHYLEPiE GLYCOL WAS TERATOQEZC ,Zt:.LAWORATDRY ANIMAL STUDIES; F.RST AD: .

fyets-ZdIotely Wash eyes w1th rnning valor for.,I minutes.

If Irmitation develops. cosult e physician..

Skfn-Wash offaoted areas w1th soap and.water. Reove and launder cbntaminateg clothing before :ousef-lrritation develops -

g * ~~consult a physician..,. .:

Ingestion-2f siwllowad. ailute with water and amodiately Induce vomiting. Never give fluidS or Indce vomItIng If the victim Is unconscious or havirn convulslons. Get Imadlate medical

~-attent10n ;

Inholattention. to fresh ir. Atid'In breathing, if neoessary, and got Immediate medical attention.-

1.quickly MANDLING AND STORAGE: Keep containers closed. In case of spill, clean uip

1. s prodct Is slippery. -Wash away small amounts With cool water.

Absorb l-rge axounts with absorbent material or dikoand'pUffo Into drums for proper disposal. ncinerate or bury In an approved landfill mndr pildance' of local EPA. Prnnt run-off onto public land or Into waterways.

IN CASE OP tIRE: Use water tog. aloohol fom. C02 or dry chemical extir shng b dta. irer Ighters should be equipped with *lf-c-ontarId -.

brPathring apparatus and turnout gear.-_Vapors frem heated product can.travel.

to source Of Ignition and flash back. Mocfi 0~explosion tazard when -xpozad..

Ito fIWO.*.;--

EMPTY CONTATNrRS: All labeled preCautions eust be obsarved Yten handlng -

stor ip and transportgI

• pty contaIners due to product D o.. ,not dues.

reuse this container unless It is professionally cleaned and reconditioned.

DISPOSAL: Spill material. unused contents and *mpty oontilners nust-be disposed Of tn aceordance WIth 7ca, 1 stat and f-dorkl regulations. Refer .,

to owr Mt-tria1 Safety Data Sh rt for speecf IC disposal thstruetlons.

XN CASE OF CWEMICAL EMEROENCY: Call CIENTREC day or night for assistanse and Information Concerning spilled material fir exposur and other chemical accidents. 8OO-424-9300. a f ep .e -t -heica ATTENTION: This product:is sold solely lor use by industrial Institutions.

Refer to our lechnical Bulletin and Material SaFety Data Sheet rgarding afety, Usag, applications. hazards; proc dures and disposal of this product.

Concult your. supervsor for additional information.

CJ5 No.: lD7-~2t-1.

Mloen U.S.A.

Industrill arnd Perf ormance Chemicals 0259 D28 -~ - -.. ..

VtO S37PAGE 4OF 4 201

)I

.5AMAI" 32-. z97-PRI41 Il MATERIAL SAFETY DATA SHEET I1 24 HR. EMERGENCY PHONE NO: CHEM-TREC 1-800-424-9300 Manufacturor orChem im - Phone: (815)398'1788- Il 826 Aowvaft Roa Fax (815) 3981810 Rocldold.1. 81109: E-.Mai Prochoml aol.com A

SECTION 1 Product Identification CHEMICAL NAME: Iron (111) OXAlate, 20% Solution I

CAB REGISmRY NUMBER: Not assigned Il SECTION 2 Composition and Information on Ingredlents 1 INGREDIENT:

Title Compound CAB#

None asuigned 100 ACGIH (TWA)

No data OSHA (PEL)

No data IL SECTION 3 Hazards IdentificatIon IL EMERGENCY OVERVIEW: Cause. respiratory tract I1rtatim Harmful It Inhaled. Causes eye Inritaion.

Harmfti I Wallowed A

PRIMARY ROUTES Of EXPOSURf: Ingtston. Inhalation, skin, eyes.

EYE CONTACT: Dust may cause severe Irritaton d lthe eyes and could cau permanent damage to cornea.

SKIN CONTACT: Causes Irrition of the dkin.

INHALATION: Inhalation otvapor/mist can lead to Initatlon of the respiratory tract May be hamtul Inhaled.

I'l INGESTION: Moderaely toxic It Ingested.

ACUTE HEALTH EFRECTS: Severely Irritating to eyes Moderately toxic by Ingestion. Causes skin Irritation.

Irrittiang to respiratory system.-

CHRONIC HEALTH EFFECTS: Damage to bIdneys, nerves.

A SECTION 4 FIrst Aid Measures

.I EYE EXPOSURE: Immedisatly Bush the ayes with copious amounts of water (lukewarm i poesible) for at least 16 minutes. Assure flushing under eyelida. A victim may need assistanc in keeping their eylWds I"

open. Get Immediate medical attention.

SION EXPOSURE: Wash affected area with wafer. Remove contaminated clothes I nhcessary. Seek medical assittance If Irritalbon or redness perists.

INHALATION: Remaove victi to fresh air. Closely monitor the victim for signs of respiratory problems, such as IL dilMculty In breathing, coughing, wheezing, or pain. In such case seek Immediate medical assistance.

INGESTION; Seek medical assistance Imrnmedlatey. Keep the victim calm. Induce vomiting only If directed by medcal prsomnnel. It IL 202 IL 0 9;966 Si g Z 'Soya ZXNI YUH001d 90: SI (NOX) 1yo . ;I -Da IL

SECTION 8 FlreflghtIng Measures FLASH POINT: not applicable AUTOIONITION no data nEMPATURE:

EXPLOSION LIMT8: no da.a EXTINGUISHING MILDIUM: Water spray or carbon dloxide.

SPECIAL FIRIOFIHTIHN PROCEDURES: If this prut Is Invohved In a fire, fire fighters should be equlped with a NIOSH approed po$We presure aeftornlnecd brvathing apparatus and full protectIve clothing.

HAZARDOUS COMBUSTION AND DECOMPOSITON PRODUCTS: It Invotved In a firs this materIal rnay.

emit toxdc and rIntaling furo.,

UNUSUAL FIRE Ot EXPLOSTION HAZARDS: None known SECTION 6 Accidental Re1eie lMeasures SPILL AND LED PROCEDURES: In the case of a i11l, recover and'Place In a welknarked container for disposl. Use an cdety precaufton. for clan up. After removal flush contaminated area with walor. Coled wash waturfor approved disposal. Keep fo0r enterf water or ground water. ,. .d DISPOSAL. Dispos of In aordane with all waste deposal regulation.

SECTION 7 Handling and Storage HANDUNG'AND STORAGE: Store In a Ughtlysseald container.

SECTION 8 Exposure Controls and Personal Protection OY PROTECTION: - Atways war approved safety Slasa wattle shields, or safety gogglee or face ehiels.

whn handling a chmrNia o~s t"anoex In fthisoma*.t.

SKIN PROTECTION: pvc, rubber chemical rwlatane VENTILATlOtN: If poaible, handle the material In a bloa exhauat hood. -

RESPIRATOR: It ventlon Hfnot avalble, a ruspJidstorlw be worn. The use of respirators requires a Respirstor proteon Progm to be c wWith 28CFR 1010.34.

ADDITIONAL PROTECTION: Protection to avold contt with 'clothing, shoes.

I....

SECTION 9 Physlcal and Chemical Properties COLOR AND FORM: Brownlsh~yeowuh liquid t-pH; acidIc MOLECULAR WEIGHTs No Data .

MELTING POINT (DEG. C.): No Dtat SPECIFIC GRAVITY (WATER a t): 1.12- 1.14 0206og. C.

BOILING POINT: Not applicabl VAPOR PRESSURE: Not applicable VAPOR DENSITY (AIR

• 1): Not applicable

% VOLATILE 8Y VOLUME: Non volatile SOLUBILITY IN WATER: Soluble Page 2 203 C *aovy DNI yaXDov g:ST (NO)V DNIxn~90 tio ."Ci.2

ii SECTION 10 StabilIty and Reactivity STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not oa ur CONDmONS TO AVOID: No Data INCOMPATIVIUTY: Strong oxiding age-ts DCOMPOSIMON PRODUCTSi May product toxic fumes of Carbon monoxdde, carbon dioxide.

SECTION 11 Toxicological Information CARCINOGENIC EFFOCT8: No Data MUTAGENIO EFFECTS: No Data TETRATOOGNIC EFFECTSt no Da To the boo of our nowledge the toxicologial effcft of this compound hav, not boon fully Invested.

n SECTION 12 Ecological Information A ECOLOGICAL INFORMATION: No Information availablo ll SECTION 13 Disposal Considerations DISPOSAL: D lspof In accordin to local st*to and federal rogulaions.

SECTION 14 TransportatIon Information -

Corrosive Iquldackit Inorgnic, mos. Class 8,UN324, PG III, Corrosive label. 11 SECTION 15 Other Information DISCLAIMER: TIN Informtion herein Isbeloved to be Ocurate and reliable as of the date compiled. However, ProChem, Inc. make no reprMentaton, warnty, or guarantee of any Idnd wth respct to the Informraion In thIs documtnt or ary us. of the product based on the hftormnon.

DATE PREPARED: 04104 Page33*

204 oyxi MHDOiJ L0:S; (KoxS) 7 *. SI oa- A

Material Safety Data Sheet ProChen4,Inc. CMA-TREC: 1-800-42-9300 826 Roosevelt Rd. EMERGENCY: 1815-398-1788 Rocford, IL 61109 SECniONI IDENTIFICATION ProductiNami: IRON (Ii) OXALATE .

FomulEC Pe2(C204)6H20 CAS #1949-07-9 SECIION n HAZADOUS INGREDIENTS -

HAZARDOUS NREDIMTS . HAZARD DATA OSHA PEL ACGIH TLV: ;

IRON (M) OXALATE 100 Not Established Not Established SECIIONIIm PHYSICAL DATA Boiling Point: No Data Specilc Cravity-(Wkaterl): No Data Vapor Pressure (mm Hg): Not Applicable':- :-.

Precent Valatile by Volume: Not Applicable-! -

Vapor DenitY (Mim): Not Applicable -

Molecular Weight: 483.5 -*

Melting Point (C): 100 dig, C (decomposes)

Solubility In Water: Soluble in hot water -:

Appearance, Odor, an Other:

t Light green powder SECTION IV FIRE AND E(PLOSION HAZARD DATA Flash point AuboigrdtionTemp. Flamnmable limits Non -combustible Not applicable Not applicable EX77NGUISHNG MElHOD: Use extinguishing agents sultable for sizrroidlng fire.

FIRE/XPLOSION HAZARDS:

No special firefgting procedures needed. Use nol condidons which include wearing N1OSH/MSHA approved sel-contained breathing apparatus, Qlame and chemical resistant clothing; hats, boots and gloves. If without risk remove material from fire area.

SPECIAL RPlGHINGH None Known; UNUSUAL MIRE AND EXPLOSION HAZARDS:":

Upon decomposition toxic fumes of Casbon monoxide and Carbon dioxide can be released.

Combustible when exposed to prolonged heat or flame.

205 S3O0ya 092 MG6eSGO!K!O~

DNKI Vt3HoOud Lo: SI (NONC) t'o. C; D3a

.1 Wa _:r--. .* _

I D

I' SECMION V HEALTH DATA TO)aCITY: To the best of our knowledge the acute and chronic toxicity of this substance is not fully I

EFFECIS OF OVEREXPOSUE: Irritant via inhalation and ingestion, has a caustic effect on the I

moutesophagus and stcmac May cause severe damage to kidneys.

EYE CONTACT: This material causes a severe Irritant /bums to eyes. 11 SKIN CONTACT: Causes irritation to skin. May be harmful is absorbed thru skin, INHALATION: Causes irritation/caustic effect to nose, fhroat and respiratory tract I

INGESTION: Results in irritation and/or bums of the mouth and gastro intestinal tract I1 EMERGENCY AND FIRST AID PROCEDURES: Remove from exposure.

EYES: Flush with copious amounts of water for at least 15 minutes while removing any contaminated.

clothing and shoes. Assure adequate flushing of the eyes by separating eyelids with fingers. Get 11 medical attention by physician Immediately. SKIN: Remove any contaminated clothing. Wash skin with soap and water.f redness or Irritation persists, seek medical attention. INHALATION: Move patient to fresh air. If not breathing give CPR. Administer oxygen is breathingis difficult and seek medical attention InmedIately. INGETION : Seek Immedlate competent medical attention. Never I

give anyting by mouth to an unconswous pesain Do not induce vomiting.

SECON VI REACTIVtY DATA Il GENERAL REACTIVITY: Stable INCOMPATIBILIIY: Oxidizing Agents CONDITIONS TO AVOID. None Known II HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Carbon monoxide and Carbon Dioxide HAZARDOUS POLYWRIZATION: Will not occur I

Page 2 MON(OXALATE 206 9 *30Yj o;9; 96C STO o0:S; (NOW) t0o. * .*D Ii

0 SECMJONVJI SPILLPROCEDURESDISPOSAL;RQUIRMEN5 -S Wess appropriate espiratory and protetve equipment.

Try not to raise dust Absorb spill with Inert material, then place in applicable chemical waste container tightly sealed. Label drum for disposal. Clean up spills immediately, observingall. -

precautions . Retain all contaminated soilage for removal and treatment.

WASTE DISPOSAL Consult waste dispbsal facility capable of handling this type of chemical.

SECIION VM SPECIAL PROTECTION INFORMATION PROTECTIVE EQUIPMENT SUMARY:

RESPIRATORY PROTECTION: NIOSH/MSHA approved dust respirator. when proper ventilation Is not available.

VENTILATION: Chemical Fume Hood designed to have an average face velocity of at least 100 ft. per minute.

PROTECTIVE GLOVES: Rubber EYE PROTECTION: ANSI approved safetisoggles, glasses with aide shields, or face shield.

OTlIER: Protective ear suitable to prevent contamination and contact with material.

WORX/HYGIENE/MAINqNANCE PRACTICES: Safety shower/eye bath should be readily available. Use in a controlled environmet. Maintain good housekeeping and sanitation practices to avoid contact and contamination of area. Do not eat or drink in work area. Wash thoroughly after using. Do not smoke In area.

STORAGE: Make sure lld Is tightly on iottle after use.Stoie In a csol, dry well ventilated area. Store sway from oxdizing Agents. ~ -

PRECAlTIONS: IRRITANT. Causes severe itation to eye. Irritantto skin and respiratorysytem.

Wear adequate protection to avoid contact with akin, eyes, clothing. Use with Adequate ventilation ( chemical fume hood), or U adequate ventilation is not available use with approved dust respirator to keep below TLV limits. Use In a controlled environnent.

Date Prepared: 09/31/03 -  ;

Safety Dept.

Employers/employees should use ts Informnation anly as a supplement to other infoimntion gathered by them, and should make Independent judgement of suitability of this informatin to ensure proper tuee and protect the health and safety of employees. This information Isfurnished without warranty, and any use of the product or process, is the responsibility of the user.

Page3 IRON ) OXALAT2 207 L0;9 Q6D Ste OKI ?mHoova 80 9O:SI (NOx) t' . Er *osa

32 . 130 It GEBetz I

GE Betz, Inc. Material Safety Data Sheet 4636 Somerton Road Trevose, PA 19053 Issue Date: 24-AUG-2000 Il Business telephone: (215) 355-3300 EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 I`t 1 PRODUCT IDENTIFICATION I1 IF PRODUCT NAME:

POLYFLOC CP1160 PRODUCT APPLICATION AREA:

FLOCCULANT.

it 2 COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the I

U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. This product is subject to the Pennsylvania and New Jersey Worker and Community Right to Know Law.

It HAZARDOUS INGREDIENTS: 1 This product is not hazardous as defined by OSHA regulations.

No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the 1

Occupational Safety and Health Administration at Pennsylvania thresholds for carcinogens. 1 NON-HAZARDOUS INGREDIENTS:

CAS#

7732-18-5 CHEMICAL NAME WATER Ii 69418-26-4 ETHANAMINIUM,N,N,N-TRIMETHYL-2-[(l-OXO PROPENYL)OXY] - CHLORIDE, POLYMER WITH 2-PROPENAMIDE I 3 HAZARDS IDENTIFICATION

• 0*0* **** 00*0*00000 * ** ***00* 00000*

• 0000*

• 0*

• 00*

• 000000

• 0000000000* 000000000*

Ii CAUTION MMGENCY OVERVEW '

IH May cause slight irritation to the skin. Potential eye irritant due Ii 208 lI Ii

to mechanical action only. Dusts maycause irritation to the upper respiratory tract. '

DOT hazard is not applicable Emergency Response Guide is not applicable odor: None; Appearance: White, Powder ,

Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing'media:

dry chemical, carbon dioxide, foam or water -

POTZNTIAL HEALTH ETFECTS ACUTE SKIN EFFECTS: -,,-- A ,

Primary route of-exposure;'May'cause slight irritation to the skin. -

ACUTE EYE EFFECTS: . -

Potential eye irritant due to mechanical action-only. -

ACUTE PESPIRATORY EFFECTS: . -

Dusts may cause irritation to the- upper respiratory tract.

INGESTION EFFECTS:

May cause slight gastrointestinal irritation.

TARGET ORGANS:

No evidence of potential chronic effects.

2ZDICAL CONDITIONS AGGRAVATED:

Not known. --.  :- . -

SYMPTOMS OF EXPOSURE:

May cause-redness or itching of skin.'

4 FIRST AID MEASURES SrIN CONTACTS Wash thoroughly with soap and water. Remove contaminated clothing.

Get medical attention if irritation develops or persists.

EYE CONTACT:

Remove contact lenses. Hold eyelids.apart. Immediately flush eyes with plenty of low-pressure water for. at least 15 minutes. Get medical attention if irritation-persists after flushing.

.INHALATION: - . . . . . .

If nasal, throat or lung irritation develops - remove -to fresh air and get medical attention. i ,, -

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive-victim. Do not induce vomiting. Immediately contact physician.

Dilute contents of stomach using 3-4 glasses milk or water.

NOTES TO PHYSICIANS:

No special instructions 5 FIRE FIGHTING MEASURES 209

X_

FIRE FIGHTING INSTRUCTIONS:

Fire fighters 'should wear positive pressure self-contained breathing apparatus (full face-piece type).

EXTINGUISHING MZDIA:

dry chemical, carbon dioxide, foam or water AL HAZARDOUS DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

FLASH POINT:

> 200F > 93C P-M(CC) 6 ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.-'

Flush area with water. Wet area may be slippery. Spread-sand/grit. _

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementa permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.

A 7 HANDLING & STORAGE HANDLING:

Normal chemical handling.

STORAGE:

Keep containers closed when not in use. Keep dry.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION l EXPOSURE LIMITS This product is not hazardous as defined by OSHA regulations. _1 ENGINEERING CONTROLSz Adequate ventilation to maintain dust concentrations below the exposure limit of 10 mg/m3(PEL/TLV) for nuisance dusts. a PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR-1910 Subpart I RESPIRATORY PROTECTION:

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR _

1910.134 AND ANSI Z88.2'REQUIREMENTS MUST'BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. I USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.

SKIN PROTECTION:  : -

rubber gloves-- Wash off after each use. Replace as necessary. '

EYE PROTECTION:

airtight chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES 210

Density 43.:200 lb/cu. Vapor'Pressure (mmHG) < 0.1 Freeze Point (F) N Be Vapor Density (air=l) < 1.00 Freeze Point (C) N Viscosity(cps 70F,21C) N  % Solubility (water) - 2.0 Odor None Appearance Whiie Physical State Powder Flash Point P-M(CC) > 200F > 93C pH 0.5% Sol. (approx.) 4.2 Evaporation Rate (Ether-l) < 1.00 MA - not applicable ED a not determined' '

• l: . I 10 STABILITY & REACTIVITY STABILITY:

Stable under normal storage conditions.

HAZAPDOUS POLY1ERIZATIONt . . -

Will not occur.

INCOMPATIBXLIT=IS: -* - '

May react with strong oxidizers.

DECOMPOSITION PRODUCTS: '-

Thermal decomposition (destructive fires) yields elemental oxides.'

INSRNAL PUMPOUT/cLEANOUT CATEGORIES:

11 TOXICOLOGICAL INFORMATION

-Oral LD50 RAT: >5,000 mg/kg Carcinogenicity DOG: NEGATIVE NOTE - One year dog study had no adverse effects.

Carcinogenicity RAT: NEGATIVE."

NOTE - Two year rat study had no adverse effects.

Dermal LD50 RABBIT: >2,000 mg/kg NOTE - Non-toxic even at high dose'ievels ' '

Eye Irritation Score RABBIT:

NOTE - Mechanical irritation Skin Sensitization G.PIG: NEGATIVE 12 ECOLOGICAL INFORMATION AQUATIC TOZICOLOGY Daphnia magna 48 Hour Static-Renewal Bioassay LCS0= 158; No Effect Level= 15 mg/L Fathead Minnow 96 Hour Static Renewal Bioassay LC50= 5.9; No Effect Leve1P'2.3'mg/L BIODEGRADATION BOD-28 (mg/g): 165 BOD-5 (mg/g): 122 COD 4mg/g): 1100 .'

TOC (mg/g): 200 13 DISPOSAL CONSIDERATIONS 211

If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is I

Not applicable.

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from i

federal regulations. Consult state and local regulations regarding the proper disposal of this material. l, 14 TRANSPORT INFORMATION 11 DMO HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable 15 REGULATORY INFORMATION TSCA: l All components of this product are listed in the TSCA inventory.

CCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

No regulated constituent present at OSHA thresholds FOOD AND DRUG ADMINXSTRATION:

21 CFR 176.170 (components of paper and paperboard in contact with aqueous and fatty foods)

SARA SECTION 312 HAZARD CLASS:

Product is non-hazardous under Section 311/312 SA SECTIo p 302 Cno-aCALs s u No regulated constituent present at OSHA thresholds-SARA SECTION 313 CEEMXCALS:

No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMASTON I

CALIFORNIA SAFE DRXXING iWATER AND TOXIC ENFORCEXENT ACT (PROPOSITION 65) CEEfICALS PRESENT:

No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION l No regulated constituent present at OSHA thresholds 16 OTHER INFORMATION l NFPA/SMIS CODE TRANSLATION 11 Health 1 Slight Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special (1) Protective Equipment NONE B

No special Hazard Goggles,Gloves IL (1) refer to section 8 of MSDS for additional protective equipment.

recommendations. ii CHANGE LOG EFFECTIVE C S DATE REVISIONS TO ECTION: SUPERCEDES MSDS status: ll-FEB-1998 ** NEW**

212

20-APR-1998 ;EDIT:9 11-FEB-1998 26-MAY-1999 12 20-APR-1998 01-JUN-1999 26-MAY-1999 24-AUG-2000 4 01-JUN-1999

.1 .

.. I - . . .

. . 4 - -i , , 1. ; : ., -! -

213

21 SANM 3Z . i31 I

%V GE Bet 1A GE Betz, Inc. Material Safety Data Sheet 4636 Somerton Road Trevose, PA 19053 Business telephone: (215) 355-3300 Issue Date: 24-AUG-2000 A EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940 A 1 PRODUCT IDENTIFICATION It PRODUCT NAME:

POLYFLOC AP1100 IL PRODUCT APPLICATION AREA:

FLOCCULANT.

A 2 COMPOSITION / INFORMATION ON INGREDIENTS It Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. This product is subject to the Pennsylvania Ii and New Jersey Worker and Community Right to Know Law.

HAZARDOUS INGREDIENTS: Ii This product is not hazardous as defined by OSHA regulations.

No component is considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Ii occupational Safety and Health Administration at Pennsylvania thresholds for carcinogens.

NON-BAZARDOUS INGREDIENTS:

Il CAS#

7732-18-5 CHEMICAL NAME WATER Il 25085-02-3 ACRYLAMIDE/SODIUM ACRYLATE COPOLYMER 3 HAZARDS IDENTIFICATION Il EMERGENCY OVEIEW Il CAUTION May cause slight irritation to the skin. May cause moderate I1 irritation to the eyes. Dusts may cause irritation to the upper respiratory tract.

Ii 214 Ii I1

DOT hazard is'not'applicable '

Emergency Response Guide is not applicable Odor: None; Appearance: White, Powder

- .' '. :J.

Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type).'Proper fire-extinguishing media:

dry chemical/CO2/foam or water--slippery condition; use sand/grit.

OTEAHL T EFECSS ACuTE SKIN EFFECTS:

Primary route of exposure; May -cause slight irritation to the skin.

ACUTE EYE EFFECTS: .

May cause moderate irritation to the eyes.

ACUTE RESPIRATORY EFFECTS:

Dusts may cause irritation to the upper respiratory tract.

INGESTION EFFECTS:

May cause slight gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea.

TARGET ORGANS:

No evidence of potential chronic effects.

- . .;:: 1 . ,.. -. $

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF ZXPOSURE: .

May cause redness or itching of skin. '

4 FIRST AID MEASURES .

SKIN CONTACT:

Wash thoroughly with soap and water. Remove contaminated clothing.-

Get medical attention if irritation develops or persists. .

EYE CONTACT: - . . ..

Remove contact lenses. Hold eyelids apart. Immediately flush eyes with plenty of low-pressure water for at.least 15 minutes. Get immediate medical attention. '. .' .

INHALATION:

If nasal, throat or lung irritation'develops - remove to fresh air and get medical attention. ': ' ' '

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately c~ontact physician.

Dilute contents of stomach using 3.4 glasses milk or water.

NOTES TO PHYSICIANS:

No special instructions 5 FIRE FIGHTING MEASURES 215

IL_

FIRE FIGHTING INSTRUCTIONS:

Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type).

EXTINGUISHING MEDIA:

dry chemical/CO2/foam or water--slippery condition; use sand/grit.

A HAZARDOUS DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

FLASH POINT:

> 200F > 93C.P-M(CC) 6 ACCIDENTAL RELEASE MEASURES 1 PROTECTION AND SPILL CONTAnSSENT:

Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container.

Flush area with water. Wet area may be slippery. Spread sand/grit.

DISPOSAL INSTRUCTIONS:

11 Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreementa permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill.

7 HANDLING & STORAGE I HANDLING:

Normal chemical handling.

STORAGE:

Keep containers closed when not in use. Reasonable and safe chemical storage. Keep dry.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS l This product is not hazardous as defined by OSHA regulations.

ENGINEERING CONTROLS:

adequate ventilation PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION:

A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.

USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use a respirator with dust/mist filters.

STIN PROTECTION:

neoprene gloves-- Wash off after each use. Replace as necessary.

EYE PROTECTION:

airtight chemical goggles 9 PHYSICAL & CHEMICAL PROPERTIES H 216

- .I 1 Density 42. 000 lb/cu. Vapor Pressure (mmHG) < 0.1 '

Freeze Point (F) N Vapor Density (air=1) < 1.00 Freeze Point (C) N Viscosity(cps 70F,21C) N A% Solubility (water) - 1.'0 Odor None Appearance I White Physical State - , Powder-Flash Point P-M(CC) I > 200F. > 93C pH 5% Sol. (approx.) 7.0 Evaporation Rate (Ether=l) < 1.00 NA

• not applicable ND a not determined 10 STABILITY & REACTIVITY STABILITY:

Stable under normal storage conditions.

RA7APRDOUS POLYMERIZATION:

Will not occur. .

XWCOMPATIBILITIES:

May react with strong oxidizers.

DECOHPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

INTERNAL PUMPOUT/CLEANOUT CATEGORIES:

11 TOXICOLOGICAL INFORMATION Oral LDSO RAT: >5,000 mg/kg 28 Day Oral RAT/DOG: NEGATIVE -

NOTE - Rat two-year feed: no adverse effects. Dog one-year feed:

no adverse effects.

Dermal LD5O RABBIT: >2,000 mg/kg NOTE - Non-toxic at high dose levels - -

Skin Irritation Score RABBIT: NEGATIVE Eye Irritation Score RABBIT: SLIGHT Skin Sensitization G.PIG: NEGATIVE' 12 ECOLOGICAL INFORMATION AQUATIC TOXxCOLOGY Bluegill Sunfish 96 Hour Static Screen 0% Mortality= 300 mg/L.

Ceriodaphnia 48 Hour Static Acute Bioassay LC50= 5; No Effect Level= 1.6 mg/L Daphnia magna 48 Hour Static Screen 0% Mortality= 500 mg/L Fathead Minnow 96 Hour Static Screen 0% Mortality= 500 mg/L Rainbow Trout 72 Hour StaticScreen,,

0% Mortality= 100 mg/L .- , ,

BIODEGRADATION -

BOD-28 (mg/g): 22 BOD-5 (mg/g): 1 COD (mg/g): 2970 TOC (mg/g): 680 217

13 DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is :t Not applicable.

Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

14 TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE #: Not applicable 15 REGULATORY INFORMATION .t TSCA:

All components of this product are listed in the TSCA inventory.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ) l No regulated constituent present at OSHA thresholds _

FOOD AND DRUG ADMINISTRATZONz 21 CFR 176.110 (acrylamide - acrylic acid resins)

All ingredients comprising this product are authorized by FDA for the manufacture of paper and paperboard that may contact aqueous amd fatty foods as per 21 CFR 176.170(a) (4).

USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS:

SEC.G6,L1 SARA SECTION 312 EAZARD CLASS: _

Product is non-hazardous under Section 311/312 SARA SECTION 302 CEEXICALSl No regulated constituent present at OSHA thresholds l SARA SECTION 313 CEDMICALS:

No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION 4 CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:

No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION 4

No regulated constituent present at OSHA thresholds 11 16 OTHER INFORMATION NYPA/EMIS CODE TRANSLATION it Health 1 Slight Hazard Fire Reactivity Special 1

0 NONE Slight Hazard Minimal Hazard No special Hazard i

(1) Protective Equipment B Goggles,Gloves (1) refer to section 8 of HSDS for additional protective equipment -

recommendations.

218 X

- CHAN LOG

. . -f .e EFFECTIVE DATE . REV ZISIONS TOSECTION: - SUPERCEDES

____ __--- __ X___. ._____________- 7- -_____-

MSDS status: 16-MAR-1998 .. ** NEW **

27-MAY-1999 15 . 16-MAR-1998 24-AUG-2000 4 27-MAY-1999 S ,~. .

1.I . I . . ':~ I 219

Assncned to: ???7 -------

FnR INFnRMUTIA5npji y I..!

E !i~

Jjlww. wait, From : IJRL DIST. PHONE No. 4822e95306 Apr.25 1995 7:4mt P8ei i 4) s

• ILo.3(Q Po4trNoVI Ms A/24 V  ? I

-P j,- I.-f 3-.

29se .1 77 Co.

PZZuaipi mw I b-MuI rd0 727 South 13th Street 800-432-93D6 Omaha, Nebradk 68102 FAX 402-3414W354 MATERIAL SAFETY DATA SHErT.

• DZNTfY (A used on bbC and LM): . SKIN CONTAC'M No ignifeant adveno cdects

.11 SIZIWA AMMMEMCOOLANT arc expected i3de anaicpated conditioso of norsal U. R_=44d pmlonged expo may Cause SU&

PRODUCCr C0DE! SMOIAF6P a tom ad 8 OddkL n oWALAMON. No aignifleant adve effects awo expeted etd andeipao conitions of 1nal de 0 -Least Ifeffect do oorrefor toPIRST AID ecton Health: 0 Fric I I - Sllght 2 - Modeaat IN* ESTIM: NM signi3cn adverse afrefs m

.I Reativinty. 0 3 - llIsl etpeetd inder anticipated ondilor. at normal l m.

4 -e Execive bigestion may coaa curtral nevous .I zy~w efctt.

SIGNS AND SYNarTOMS OF OVERE0OSURE:

Sab Brands Cbrporalion asaixove 2849RiveN Road Coci ufBhfts 1A 51501 MEDICAL . CONDITIONS GENERAILY ZmerWny (402)341-9397

• AGGRAVATE BY POSUREX Matedl and/or Irdormation (S00) 432-9306 its Calna my aggravate preexitiz eye disease.

Chcmucr (800) 424-9300 Rcvisod 02-18-94 07HERJEALTH MINORMA7ON: n I.

].

EYE CONTACr: ImMdately riue with CIMn wacr Ar 20-30 nsimncs Retza cyelids ofln.

LMIST "LVAVAPOR CAS 70l.44 Obisin nedicl a3tnzion if pain, blinking Iears redness PM1t.

'r .I "Waui. eabt<ed seadm" SdPe .

9 9~w . -e

• 0 1M44 nme esaWdn Si coNTAc Proiuct iso ast xpcIed lo pruselt a sltnifcant skin 1a6-i tIneatipa

-I NIL=HAZJ.DOUWCRE2U~T >I -%

conditdam of normal use.

54 3S"S.G INHALAON: If overcome by I qrp

?fprk~ry addkiva 3 vk1ln. to fesh air inuicdiaftly. 'Give oxygen or utificil repiratn as mede& Obtain emerecwy.

(Does not contin lARC. NTP, OSHA and ACGIH nidcal attentdo. Ffrompt action is IaL 1Isc1d Carclngczazs &rcalrthan 0.I%)

INGESTION: If large quantity is smiowd, sie a :1 ps o _ukmrm tcr if victim is completely 11I r -

I con=ow and aert. If largo quaztics uam conwsed, linduwe youitns. Obmahain emeq ncy EYE CONTACT: May cause minor eye irrizatin edial attention.

1 S094-63b 220 I

.1

-'U

. I. 0I I -I . 17

'Assioned to! ???? .- - FORINFORMATIONONLY Fmnlraes O~n- I Assaned to ???? - POR INFORMATION ONLY Fwyr. fl,. I Frobm : WR2E -DIST. PHONE'No. 4022eSSM6 Apr.2 1995 7:41AM ~P02 CARClNO)GEN1CfY.- n/ under normal -candiiion's ofiiiiicipated Vsce with ad eq uslc ve ilation.

Fa7s"N 75nivaiammNimMa *VEOfILATION: Adcoyatc gacnel wultlation is required, lo~al oxhmitt is rcomnaiedid if possibl.

FlubhPoint dcg F): 211 Fnanmabic or Explosive Limits (Appioxhugae 1% by PR07BCTVB GLO4VES: not required I vuhnne n air) 1EL1 2.4M 1a7A4 EEPROTECTION: 'Chemical splah gassig oj EXTINEiUISHMN MWlA- catbon dioxide, dry ful faceg drsini berno wh4eri possibility eists

• facucwlact di= to, 100~mdz ire --rajng 110ud, cbcmacal lch typro E, Vatcripry, mwatrfog SPF.cIAL. GNNG PPDXXUREB: Wear 3FIR Oix w pw = IV EQU W ME? ] m PRO k EC shoul I podtive prmsume self contacne bmtldns appmm and ofhe protectiwo Apparatus at wmrante& Fghz firn ftom distance or prolecied location - beg smay bnfld up pscssum and supture dosetd contWnMs WORK PRACTMtES/NGINEEUNG 6- Liquid rmy form ulippy film. Use wate spray or *CONTROLS:. Keep container _dos when M in fog for c001132. solid 'srcam maty sprea fag as bwunh% liqlaid wvill float on water. Avoid

ftothinr/steam explos~ion. Noify autboritics If *PER~SONAL EYGIENE_ Ifp gmd andling resuts liquid enters scwers~mblc vraters in Ski C na.t w a4hhands and otbrr~rx ocd armas

- itth inuld soap an)d vsaler b o ceaftir drinking

-I

• n Wi z n ki l t fac l i t. e ' n npl r m v UNUSUAL FIRE AND BXP'LOSION HAZAR~DS:

Iliedtfir fiuu can generate flanmable vapo. When sm'led clothing and wasb haomngh before reuse.

2flixed with alr and exposed to igziditio source, vaport can bumn in open or explode If confined.

Vapors may be heaver than air and imel Song dlsa, -P along ground beeignhtig and flashin back. rim sprays and mists may be coaabmWta at SOLlin Ybint (deg r): 365 teperabucs below onoral Ma~sh Point. Specifc Gravity (1I20-1): 1.04

",;Vapor PressUre (suM Ng :-o i ~Mcting Point (degF): .76 Vapor Density (Air'-1): 2.6 STES .TO]M TAKEN IN CASE MATEIL46 IS Solnility Ill Water jomlete

.1.~ MXASED OR SPI1ID; Prevent now to iL and public water as it may contamiatc said vaLt=.

Restrict Ws= mC. to prmqt siPI -APIEARANCE AND' ODOXR.- dak g& slightly Soak up zmfl asUs wtuh ineut solids. Dike and Viscoue amod 6dalienshqud.

recover lage Land spiits. Notify appropriate auibories ifproduct eners any watcrnuy.

VI=.17 *STABILITY:, slawl

- ITI NS TO A VO ID:

- ON hea. spamr s. open MECUTONS TO BE TAKE IN HANDLING AND STORAG: Store in lightly. scd and Properly yente~ WI]Cr aWay YroM hezt. sprk, 'INCOMPATMI=lT (MATEMLiALS 70 AVOID).

open fame, and strong mddizing agents. slc l s su oing wd l i k a ents

• JAZA-DUS . DECOAMPSITION - OR B'.YPRODUCrS: airzbon inanoxide and other ooxic HAZARDOUS POLYNMEPZATION. not expecte RESPIRATORY PROTECTON. No special to0occ respiralosy procmlon equipmetw is r==o =cd 221

it Assigned to: ???? FOR INFORMATION ONLY Expires O, Fronm :tJZ DIST. PHONE No.: 4228953a6 mpr.25 1995 7:41 t(0-36 s25

.ODMMONS TO AVOID: PA 4-1 Sce Secdon IV

• . JIiI No0 tebeilealsIn this roix r suet~ to die

. *1 1*

I1

-WASTE DISPOSA MEhODm : Lm-%'lfl sUds at pcrmined skea utidg rcgistere trmnspores. Burn con1ean..d liquidr, - flammomt, and

,"IdinS .. I mode8 emissom comply vith ,pplkabe

• 4~ 4 . . ... . . . .~

j adom. Miolte a Io wste may bladegrade.

but avedd overloading plant bii~mazs and attoring' flu. th applicable sephtoDom

.I

.. . .complies ..

This pnoduc is not culated by TOr

.. 11 WITS clacationbfor pzoducL n/a This prodoa Is" been casairsed in accordance with thc hazard crlteria vC thc CMt azd tih MSDS ceutalusall the JInbmrnatin rquiud by this CFR ;_

ThI l saftty daw shca and the iunmaion it c ins is euol toyoi fn god ithba _ -.

We haw reviewed any inftacnalon contaired in tbi

-SI

.A dam sheet which weo mcecdfd from ou outgidc our cmpany and we bclicm that infomuMion to bc corm, but sanrol guaroe itis oacuis or c tnm Helth and saY precautions in ths data'shet may not bz adequmat for aU individuah as4or situatons. 1t Is tho usces oblisatwn to

• vlumte and c tWhs prodWct safely and to covply wth all applicallo la"8 azd. wplaio. No scznent made in this data sitct shafn bc contnred

.1 i, .

aa permislon or rcceinmudaflo for the us* of any product in a anne that nzljl lnfflngo existing patctas. No warranty is mldO, cithcr expressed cc Implied.

TI 3

222 ..-I1I

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- @ f

~ WESTERN CHEMICAL INTERNATIONAL, INC.- .- .~t1 r

-- - 29~39 N. 7TH PLACE. SCTTSDALE, AZ 05251 .!(602) 990.9407 ~ 4A Ito"?w s A I I IAwCTwy s

I DJ A.

101-I splow COMPUNDCAWUNG LIQIUID/COMBUS. 1IQ. N~A l270Do`0T.C~kSS4CATKM:

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• I _

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.r'ODUCTNAIM 1IMPA 2nfflfl IMrT-IfLn I FLERCENCYPHNOW fqA2l Qgfl-QLA~7 INIrCnrra M. Nichaels IDATE PAEPARED 81/21. .

N04t OF THE *4NJGM0PTS w4 HIS FOAUNATMNARE FO~P NAYiT*C A~lOS Cfl*=OrN2C0O ABANHED0HCEMICAL AGENTS O

-LMAIERLALS CENEPATED BY THEM. ADENCES I4VEIAIOAEO VICLIDE Ti EEPA.; FDA.. tAiooNA,.cANc~fn tlsTTUtE. idATD4AI. CWNErOLJVATO4.

O.S.I4A. (FEOE PAL AM~ CALIFOANLA). THE COWSAER FRODUCT SAFETY=6OSO*Sso. D.OT. ISAFrTY PNsrITUTE DAP6 tIAL Pr'OGRAMS.

ALYJIN ISRAT 04), ANDOTE KAT*#4AL T0XX;CQQVY PRQOM. THE FOWXa AT9Wh LS AIWWAflRCFUT AND COAPLIE WITH MA XVt~I- I b-1200.

SFCTINiONC.-TRAA SECRETS.- -s. .-

3 I4~ROI$ WREOI.t" I!PHM1CPLE-cCMPOINEN(S) (CEMrCA. NAI$) CASb rkv PEt

_ - . I.- I . ________

1.200

- I ALIPIIATIC UYDRoCARZo~s- CIO-C.1 64742!-47-8 200 PARAFFINIC UYDROCAUfOKS - -- *-.4-88** 200- .260 I>_7MOENE5989-27-5 INone oe--

"EPA 2000" formula t* a trade secret elid compliteS itb 29 CFR 1910.1200, Section (i) 2rade -Secrets. , :voc (Volatile _Organic .Compounds la wit'hIn Air Quility ftismijon 1 'Drinkins Standrard (Ciliforni&a-AllDiatricts). N~o-ingredleinite'lieed under C-a1l _S b Toxic: ChemiCa6l Wnforceiment Ac't (1986>. OSHA Hataid Claq tV O%-

HAZAR.DOUS L!QUID; RCRA'3lazardous Was'tteClasis 40,CFR 261.2; I-~UW rE; -

TcLp Waste Class 40 CFR 261.4 - NiON HAZARDUS WASTE INOV.39?

t _____________________________________REC..

. . ~I.-Pt4ThALIDATA . . SYS.

.r3!w~  %-320~-290"F *'S- PECFIOOGRAWIY (4soJ -

IVAPOR PRSSURE(pigqiMj"g. 6250 C 3. Pt, - - ID pAOCNIYA.I .. 3* E'V"PATVNRATE Butyl Acetateal , Goet medical attention promptly. Sf symptoms Indiests, *pply treatment as appro9riate for corioaive alkali substance.

225

Asiriiia t: u . Epi~ar On:

Ousl~yProduts Sktc 1875 mpvw Wombsf AiWks. An-WCAaM~riu I0wA. WlU Paj'#a4 K-w &*z-Q tCogm9U% aw 541/N y  ; tt cbWm.

~O ocxtiI'3101 tga w. fromi Cditfll. A*miIIFld4aw.

HAI.JJ: 291W I I STAD'LTI: Wtbb INI

% 3*

2 HA2Ag0UjpOT1ft`ZA~O~x illiotl Pe. hn2 -

SAVOGIIzS TOS "!UA i ITE ?-I SECTION LIALLL.L StAblo 7I ORLEAK PR DTA N

i NAIR AWUN EPULOSNrIATON AUP. z Vilt nOt SrmotPTi1Ittt Swetepruta to evor d tSolutions In water Toe highly alkySine *nd osy produce hydroen gas when In contact with oluuinum. V11l react with acids to form carbon dlexidu. ateriaI n tgyroeiopie *nd tends wase. to CoWDITIOWS to AYO!O: See 'IECTIoW * - UNUSUAL fREtE AMD.EXPLOSICK KAZARDS."

10 T5*t:I:NL M LTsm SruA tEAb il:O;::~::. *sci:  ;.~e clean PiltS: 3viep up materietal Srt tip roeidue.

dtns Reosining residue *ey hr washd away with water._l to eontrlners. Thoroughly awprroa to I.i JRE SPILIZ Some as for small spills.

DISPOSAL_9F WASTE: Small quantities may bv deposited In general trash end residue 4lushod down drain with water. Large spiLts - Deposit contoiners fn posted toxic substances land-fitt In accordance with tocoal $tate and federal regulations. trisodlum phosphate has a reportable quantity (tE) of 5000 tbs.

SECTION a SPECIAL PROTECTION IN 01"VAION i YFWT+/-LATlOL ' Use local exhaust to control dust formation

Veer NIOCIN/SEA approved dust respirator, if duot is formed 9J.lOYt Industriol quality Cotton lined neopreno olvel with close fitting r-Istlets.

gyr PROTICTION: Ciheoeol goggles or safety glass#s with sidt shield.

o27Et PROTEIC7VE EgUI#NE7T: No *pelol protective clothing needed; however, wear tong sleeved shirts with long pants to protect skin ageinst splashes and pitlls.

IECTYON 9 SPECIAL PRECAUTIONS gyPTI1E CORTAINWtts fEpty eontalners may be Incinerated oe discierdd with general trash. Large contulners *bould be completely emptied before disposar. Because empty

.eontolners soy contain residues which era hozardous, all precautions given on this sheet *-

shoutd be observed.

STOtlNO: Store PRECAUTIMS *0 3E TAKEf IV WAMOLlIC AWO caking. Keep sway from acids of olt types. Voter solutions can be corrosive to *lumfnvo and ganertca hydrogen, In dry ptecw. Moisture can ceuse i

NOTE. Judgement of potential hazards of this mixture Is based on Information available about individual components Listed under SECTION 2 - MAZARDOUS:

IN*IEDJIETS. Direct testing .1 mixture has not been one.

j Information given herhin Is betlivod to be sceurato and i* given In lood faith; however, -

no4warranty either expressed or implied is made. It io strongly mugstted that users confira in advance of need that the Inforratlon Is current end appilcobte to their situations.

-Note: The sele or use of cleaners containing Phosphates in prohibited in some stas end tocelitls.

11 226

I Assigned to: ?? FOR INFORMATION ONLY Expires On: V I .', * .'

i . _A eChem . '

- -- 11r r vAL Ltsz 1*

I MATERIAL SAFETY DATA SHEET .

S MSDS NUMBER  : -M389-MSDS DATE'*  : 04-0990-.'

PRODUCT NAME 50% CAUSTIC SODA SOLUTION

- 24 HOUR EMERGENCY PHONE: (7.15) 27B-70122

1. PRODUCT IDENTIFICATION ---

- ,,IS HAZARD RATINGS '

HEALTH HAZARD- 3 FIRE HAZARD 0 -"REACTIVITY 2 eased on the National Paint.&.Coattnos Association HMIS rattng system.

t .%irr....; t tf Y WY t  % M" ^- tF  ;^ X Immeodiat .(ACUTE)"Heal6th: YES . Reactive Hazeard: YES Delayed (Chronic) Health: NO Sudden Release of Pressure: NO Fire Hazard: NO

' MANUFACTURER'S:

NAME ADDRESS AND '  :

Occidsental -Chaitcal Corporat Customer- Service. Occidental Tower-P O Box 80905G. Dallas. Texas 75380 Ion

'(1-800-752 Tolophor noe

-5151)

' "sO/;MICAL NAME: SodsIsum Hydroxi de . . CAS NUMBER: 1310-73-2 SYNONYMS/COMMON NAMES: Sodium Hydroxide: NaHC CHEMICAL ,FORNULA: NaOH .

DT' PROPER SHIPPING NAME: Sodium Hydr-oxide. Liqtiid DCOT HAZARD CLASS: . Corrosive'Mater-ial

,OT I. D., NUMBER: UN 1B24 ,. .-

, DT. hsAZARDOUS SUBSTANCE: RIO 100'W. g

' I1.-'HEALTH HAZARD INFORMATION ' '

EMERGENCY AND FIRST AID PROCEDURES, EYES: ' , . .

OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY.:-THEN SEEK MEDICAL, ATTENTION. IMMEDIATELY.flush.eyes with-laroonamounts of water for at least 15 -minutes forcibly . holding ,l1ids apart to ensur-e flushing of entIre surface. Washing eyes within several seconds Is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY.

"VS hI 3Slk £hgttat L mi V..,4g . W Cu*~ a Al. et",410 t 41#994,1111 3"Faw atio

• ma i *v Ia Nota pp o

¶0.,o *9

• 16Ik th r..hast on .0 sW 1.. S uf S is,

• 411 :.O :t;PR we 010,10 3 a 9.. 10 0 0

• ply i a, m. e t t. to tn.l 1s 69 64W i .. a w eu .. i o i~

~

PI I P T IN L T .

Iaw U

a . .

=

1 6 W

. T al S I a. ,o r 01a I

• g a .. a e Isv mewl WA: 60 S P t~. 6 5 *

• sI tI

• F I M IJASJUT'r I . . . I1al CR9 ,185 t VP o w g S*

1 O

3 O

P J

• m L S 6=a W i - O S b S I A S E W

• s a tl Pat1id a 10W9t #I M A A 0 05 W 4a 114 910,11 l a :

t

• .. 3 o ut

~ se

.e . S.. . l. ..l .5 v

aa a to i e resp 0 4 1 0 5 ond to 41" atst sa po I.?d lfng safe 405 . . . . . .

hIN dl O 9 0 0 04 0 4 6 .

~ e B

• a

• d A~ o w *.

~

P I

• g f i 0 50 .

W 1

h l d l m h a0 . 9 5 , 5 5 ' " .1 544 , % d t l .. 0 . . 6f 9 I 9 l 9 5 1. 1 1 1 9 0 G I I 0 .@7 9 4 , 1 14 0 0

• 8 0 227

run-n uvrO7wliWDDUlN LY . Exp~ioii:

OCCIDENTAL CHEMICAL Pace 2 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION'

-.23.. f\V7151 ,'

11. HlEALTH HAZARD INFORMATION (Continued)

SKIN:

IMMEDIATELY wash with plenty of water for at least 15 minutes. .

Remove contaminated clothing and footwear. Wash clothing before rouse and discard footwear which cannot be decontaminated. SEEK MEDICAL ATTENTION IMMEDIATELY. t*

.IN}ALATION:

Remove to fresh air; if breathing is difficult have trained person administer oxygen. if'. respiration stops. give mouth-to-mouth resuscitation. GET MEDICAL ATTENTION.

INGESTION: m .

an . *i p NEVER give anything by mouth to on unconsoI0us porson. If swallowed. DO NOT. INDUCE. VOMITING. Give large quantities of water. If available. give several glasses of milk. If vomiting occurs spontaneously. keep airway clear. SEEK MEDICAL ATTENTION IMMEDIATELY.

o: . ~~ROUTES OF EXPOSURE ..- 1 NHALATI ON:

ALrborTno

, . . i I concontrat1ns of dust. mist. or spray of this product may cause damage to the upper respiratory tract and lung tissue proper which could produce chemical pneumonia, depoending upon severity of exposure.

SKIN:

This product is. destructive to-tissue contacted and-produces severe burns. A latent period may exist between exposure and sense of irritation; EYE CONTACT:

This product Is destructive to eye tIssues on contact. Will cause severe burns that result In damage to the eyes and even bl indenss.

INGESTION:

This product. if swallowed. can cause severe burns snd complete tissue perforation of mucous membranes of the mouth. throat.

esophagus, and stomach.

EFFECTS OF OVEREXPOSURE ACUTE:

Corrosive to all superficial dermatitis.

body tissues with which It comes In contact.

The effect of local 'dermal exposure may consist of multiple areas of destruction of Similarly.

tho' skin or of primary Irritant inhalation of dust, spray. or mist may I

result In- varying degrees of Irritation or damage to the respiratory tract tissues and an increased susceptibility to I respiratory illness. These effects occur only when the TLV is

• o~xcoodod.-_

CHRONIC:,.

No known chronic effects.

TOXICOLOGY DATA: '

Caustic soda is'a corrosive material.

Acute Oral LD50 - 140-340 mo/kg (rat)

Acute Dermal LDSO -'1350 mg/kg (rabbit)

P-ktn Dermal Exposure - -

Reogardless of concentrations. the severity of damage and extent of its irreversibility Increases with length of contact time.

Prolonged contact with even dilute sodium hydroxide solution can cause a high degree of tissue destruction. The latent period. I following skin contact durino'which no sensation of irritation -

occurs, varies from several hours for 6.4 - 4% solution to 3 minutes with 25 - 50% solution.

. .. 4

- S ~228 j

Assignedto: ?n7 FOR INFORMATION ONLY - gRires On: I I Assined o: 777 OR NFORATIN ONY citesOn_

I I

. OCCIDENTAL CHEMICAL . - , . - I . Pae 3 of 9

' .- MSDS NUMBER: M5389 - .- ' . 04-09-90 PROOUCT NAME: SOX CAUSTIC SODA SOLUTION I .

IL(f V4I Ill. IMPORTANT-COMPONENTS I, ., , .. CASIIWIBE / NAMIE "13 10732 "SodI um hydroxide, (Na(OH))

EXPOSUREILIMITS; PERCENTAGE PELw2 rho/m3..Celling.'- VOL ND TLV-2.nig/m3.-Cftlling *U* ..-WT 48.50-51 COMMON NAMES:

CAUSTIC.SODA  : i

• Listed On(List Legend I elow):-.

13 I8 21

- -- - - ' r- - - - - - -

c* r i, a . .,

7647145 Sodiumn chlorido (N&Cl)

EXPOSURE LIMITS PERCENTAGE

.. PEL"None established VOL' ND TLV-None established - 'WT -O80-I.30 COtMOtN NAMES:

SALT

.Listed OrdList Legend Rel10v): ---

23- - - - - - - - - -

.7732185 . Water EXPOSURE LIMITS PERCENTAGE PEL-Not Established VOL - ND TLV-Not Established WT . . 49-51.5O COMMON NAMES:

Listed On (List Legend Below):

19 23 See.SectIon II All components of 'this product that are required to:be on the TSCA Inventory are listed on the Inventory.

Not I sted as carcinogen - IARC. NTP. OSHA LIST LEGEND 13 PA ENVIROMENTAL HAZ SUBSTANCE 18' NY HAZARDOUS: SUBSTANCES 19 PA REOUIREMENT- 3X OR GREATER 21 NJ SPECIAL HEALTH HAZ.SUB 23 NJ REQUIREMENT-- % OR GREATER-

[V. FIRE AND EXPLOSION DATA " -

• '_ , . - , r -. *Is-, '? I - - , . , .'_.' . " . .-

FLASH POINT: NA AUTO IGNITION . TEMPERATURE: Nonflam1minable FLAMMABLE LIMITS IN AIR.  % BY VOLUME- UPPER: NA LOWER: NA EXTINGUISHING MEDIA:

This product IS not combustible. Water spray. foam, carbon dioxide or dry chemical may be used where this product is stored.

SPECIAL FIRE FIGHTING PROCEDURES:

Wear full protective clothing. Avoid direct contact of this product with water as this can cause a violent exothermic react0on.

UNUSUAL FIRE AND EXPLOSION HAZARD:

None. See Reactivity (Section Vtt).

I.;

229

Assigned to: ???? FOR INFORMATION ONLY Expires On:

OCCIDENTAL CHEMICAL Page 4 olf 9 MSDS NUMBER: M5389 . 4-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION 49

-T d F.AL Ia V. SPECIAL PROTECTION .

I VENTILATION REQUIREMENTS: -

Special ventilation is not required 'Lnder normal use. Use .I1 local exhaust ventilation' where dust, . mist. or spray may be oenerated. NOTE: - Where carbon monoxIda -or other reaction products may be generated. special ventilation may be required.

SPECIFIC PERSONAL PROTECTIVE EQUIPENT RESPIRATORY:

Respiratory protection is not required under normal use. Use NIOSH/MSHA approved respirators where dust. mist, or spray may be generated.

EYE: .I Wear chemical safety goggles plus full face shield to protect against splashing.

GLOVES;*

ChomicaE resistant gloves should be worn. Gloves may be decontaminated by washing with mild soap and water. Natural and butyl rubber have been suggested.

OTHER CLOTHING AM EQUIPHENT: .. I Imeorvious protective clothing and chemically resistant safety shoes should be clothino with soap worn to minimize contact.

and water and dry before rouse.

eyewash facilities should be accessible.

Wash contaminated Showers and 'A{

MONITORING EXPOSURE BIOLOGICAL:

NA PERSONAL/ARA:

Use NIOSH Analytical Method No. 7401.

Vl. PHYSICAL DATA BOILING POINT a 760 mm Ho: 1436C (289*F)

FREEZING POINT: 12.t1-0 (54F)

VAPOR PRESSURE: 13 mm Hg

• 6eeC SPECIFIC GRAVITY-(H20-1): 1.54 0 25.6'C SOLUBILITY IN H2Q % BY WT: Completely soluble VAPOR DENSITY (Air-2): NA APPEARANCE AND ODOR: Clear liquid with no distinct odor.

pH: 7;5% solution has pH DENSITY: 12.8 lb/gal 14.e :_11 I

... I1

_A 11 1i

. 11

- ;230 ..4

Assgned to: 777? -. FORINFORMATION ONLY - Expires On:1 OCCIDENTAL CHEMICAL Page of 9 MSDS NUMBER: M5389 ,4-G9-9

• PRODUCT NAME: 5e% CAUSTIC SODA SOLUTION Vii. REACTIVITY DATA, ,' -:

CONDITIONS CONTRIBUTINGGTO INSTABILITY:

-Under normal conditions. 'thls'product is stable.

INCOHPATIBILITY: "-.

.' Se Handlin and Storage '(Section VIII)'. -Avaid direct contact with water. ThIs product :may 'be added'slowly to water or acids

.-with dilution and .,agtation to avoid a 'violent exothermic reaction'. ' When .'harbdlino- this -product,- avold contact with I' aluminum. tin. zinc¢.' '-and alloys contaning -these metals. Do not mix with-strono acids §'without dilution and agitation to prevent lviolent-or explosive reaction.- Avold contact with leather. wool.

acids, -organic halobon compounds and organic..nitro compounds.

NAZARDOUS: DECOIPOSITION.PRODUCTS::

Nono known. "

CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION:

- - -Material Is not known'to polymerize. -

Vill. HANDLING AND STORAGE HANDLING AM STORAGE PRECAUTIONS:'

Do not.set Into eyes. on sk1n. on clothing.

Avoid breathing cust. mists,-'or spray..

Do.not take internally.

Use'with adequatft-:'ventilation -and' employ respIratory protection

'lh.'-' '.. -'hn dust. mist or spray is possible.u I @:.When hiandling. -wea0 chemical. splash. ooooglos; face.shio1d. rubber-gloves and protective clothin*g. ' -

Wash thoroughly after handling or contact' -' exposure can cause L - . burns vih1ch are not 'nmmodately painful.or visible.

Keep 'container closed." ' .:r . -

Product-.can'react. violntly'wIth water,. acids. Ondcother substances

' .- read Special Mix1ng and Handl~ino Instructions below carefully

!- before using.

Product Is corrosive to-.tin. aluminum. zinc and alloys containino thseo metals, 'and will' react. violently -with' these metals In 1' ' powder form. .

Hazardous carbon monoxido gas

-a -or . o c w ran .form 4upom contact wlth food o

and beverage products in enclosed spaces and'can cause death. Follow

^approprate 'tank entry procedures (ANSI Z117.2-3977).

SPECIAL MIXING AND HANDLING INSTRUCTIONS Product can- react - violently with water.- Considerable heat Is

- -.- ganerated'when product' is. mixod 'with' water. ,Therefore. whon making solutions always'carefully-follow theso steps:

. ALWAYS wear ALL protective clothing described-above. NEVER add

'water -to product. ALWAYS -add product - with constant stirring -

slowly 'to surface of lukewarm (80-10@1F) water. to assure product Is being completely'dissolved as it is-added.

-- If product is added otoo: rapidly, or without stirring, and becomes concentrated at bottom of mixing vessel, excessive heat may be generated, resulting in DANGEROUS boliIng and spattering.

and a possible IMMEDIATE AND VIOLENT ERUPTION of highly caustic solution.

231

-Exp O is Assioned to: ???? FOR INFORMATION ONLY Asafoned to: 77?? FOR INFORMATION ONLY

-1 OCCIDENTAL CHEMICAL Page 6 of 9 MSDS NUMBER: M5389 - 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION VilI. HANDLING AND STORAGE (Continued).

-T( FA4ar7 T SPECIAL MIXING AND HANDLING INSTRUCTIONS (Coatinued)

NOTE: Never add more product than can be absorbed by solution while maintaining ,temperaturoe below 2000F, (a sea level) to prevent boiling and spatterino.-, -

Ir Product can containing react. EXPLOSIVELY with acids,, aldohydes. and many other-oroanic, chemicals such chemicals,

-- whon, mixing product with solutions Instructions, and add ,product, vary constantly.

follow all gradually.

of above mixing while stirring A

ALWAYS empty and clean containers of all res1duos before adding product, to avoid possible EXPLOSIVE reaction between product and unknown residue.

Returnable conwtainers should bo shipped In accordance with supplier's recommendations. Return shipments should comply with IA all federal. state, and .'DOT regulatIons. All residual caustic soda should be removed from containers prior to disposal.

IX ENVIRONMENTAL PROCEDURES .

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:. .-I Leaks should be stopped.

cleaned up VOCULX.n truck.

immediately.

Neutralize dilute inorganic acid Spills should be- contained. and Spills should be removed by using a remaining traces of. material with any such *as hydrochloric. sulfuric. nitric.

U' phosphoric, and acetIc ncId. The 5pill area -should then be flushed, with . water bicarbonate. .All in approved containers, followed. by, lIberal covering of clean-up material should be removed and placed labeled and. stored await proper treatment. or disposal..- Spills on.areas other than sodium in a safe place to ..A pavement. e,.g. dirt or sand. may be, handled by removing the affected soils and placing in approved containers. Persons performing clean-up work should wear adequate personal protective equipment and. clothing. Spills or releases should be reported.

If required. to the appropriate local, state and federal regulatory agencies. -

CAUTION: Caustic acids and WASTE DISPOSAL METHOD:

soda . may water.

react violently with

I The materials resulting from clean-up operations may be hazardous wastes and. therefore. subject, to specific regulations.

Package. store. transport. and dispose.of all clean-up materials and any- contaminated-equipment In accordance with all applicable federal. state, and local health and env1ronmental regulations.

I Shipments of waste materials may be. subject to manifesting requIrements per applIcable regulatIons. - ApproprIate dIsposal will depend on the nature of each waste material and should be Performed by competent and properly permitted contractors. -

Ensure that all responsible federal. state, and local agencies receive proper notification of spill and disposal methods.

• .I1

-I 232 KB Ii

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-1. -I. A..-.Atn-7777 tn* 7777 -- ....- -- .. FORINFORMATIONONLY FOR INFORMATION ONLY -- ---

-. . Expires Expires On: I I *. ' - Page 7of 9 OCCIDENTAL CHEMICAL I MSDS NUMBER: M5389 * . . 04-09 PRODUCT NAME: 50% CAUSTIC SODA'SOLUTION i

MprL

-- C1 X. ADDITIONAL INFORMATION  ; - : ..

OSHA Standard 29CFR 191. 1200 requires- -that. InformatIon be provided to employees regarding the hazards of chemicals by means

.of a hazard communication pr-ogram.Including labeling. material safety data sheets. training and'access to written' records. We

• oequest that you.. and. itais. your legal .duty to. make all information In this-Materialnsafety Data -Sheet-avalable to your emp l1oy e es .@'*';t*!,',,',,

To a1d our customers In complying with regulatory requirements.

SARA Title III hazard categories -for this product are Indicated i in Section I. If the. word "YES - appears next.-to-any category, thi

• product may be;reportable by'youurider -the requirements of

.1 49 CFR Part 370. Please consult thoso regulations for details.

I Xi. -PREPARATION INFORMATION, I

I

-i I *1 . . '

For additional Non-Emergency health. safety, or environmental information telephone (716) 286-3G81. or.write 'to;:

- Occidental Chemical Corporation

• . *- .Product 'Stowardshlp Department

~~~Su'Ite 4@00' '

I 350jtRalnbow Boulevard South I :o'Niagara-Falls'-NY

- *~ .-;143@2- -

TI  :.For Emergencies: 24 HOUR EMERGENCY PHONE:, (716) 278-7021 This MSDS replaces MSDS Number M5389 dated 07-14-89.

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a-Assiged to: 71?? FOR INFORMATION ONLY bwire On:'

• OCCIDENTAL CHEMICAL Pake 8 of 9 MSDS NUMBER: M5389 04-09-90 PRODUCT NAME: 50% CAUSTIC SODA SOLUTION WARNING LABEL INFORMATION' SIGNAL WORD: -DANGER1 .  !

STATEMENT OF HAZARDS:

CAUSES SEVERE BURNS TO SKIN. EYES AND MUCOUS MEMBRANES.

CONTACT WITH EYES CAN CAUSE PERMANENT EYE DAMAGE.

INHALATION OF DUST. MIST. OR SPRAY CAN CAUSE SEVERE LUNG DAMAGE.

CAN REACT VIOLENTLY WITH WATER. ACIDS. AND OTHER SUBSTANCES.

PRECAUTIONARY STATEMENTS.

Do not.get Into eyes..on skin. onelothtng.

Avoid broathino.'dust'. mist.

Do not take Internally.

Use or spray.'_..

with adequate vent11ation and employ respiratory protection i

when exposure to dust, mist, or spray Is possible.

When handllrig. wear-choemcal.splash goggles. face shield. rubber g loves and protectIve clothing. 'j Wash thoroughly after handling or contact -' exposure can cause burns which are not immedlatoly painful, or visible.

Keep container closed..

Product can react vi-lently with water. acids, and other substances

- read Handling and Storage.instructions carefully before using.

Product is corrosive to tin, aluminum. zinc, and alloys containing _11 these metals, and will react violently with these metals In powder. form.

Hazardous ca'rbbn monokide gas can form upon contact with food and beverage products in enclosed spaces and can cause death. Follow appropriate tank entry procedures (ANSI Z117.1-1977). l FIRST AID:

IN CASE OF CONTACT:...

FOR EYES:

OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL . l ATTENTION. IMMEDIATELY flush eyes with large amounts of water for at least 15 minutes forcibly holding lids apart to ensure flushing of entire surface. Washing eyes within several seconds Is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY.

FOR SKIN:

IMMEDIATELY wash with plenty of water for at least 15 minutes.

Remove contaminated clothing and footwear.- Wash clothing before rouse and discard footwear which cannot be decontaminated. SEEK MEDICAL ATTENTION IMMEDIATELY.

IF INHALED:

Remove to fresh air. If breathino Is difficult. have trained person administer oxygen. If respiration ctops. give mouth-to-mouth resuscitation. GET MEDICAL ATTENTION.

IF SWALLOWED:

NEVER give anything by A

mouth to an unconscious person. If swallowed. DO NOT INDUCE VOMITING Give large quantities of water. If available, give several glasses of milk. If vomiting occurs spontaneously, keep airway clear. SEEK MEDICAL ATTENTION IMMEDIATELY.

IN CASE OF:

SPILL OR LEAK:

Leaks should be stopped. Spills. after containment. should be shoveled up or removed by vacuum truck (if liquid) to chemical waste area. Neutralize residue with dilute acid, flush spill area with water followed by liberal covering of sodium bicarbonate. Dispose of wash water and spill by-products according to federal, state. and local regulations.

wJJ.

11' 234 4.

i Assigned to: 7??? - FOR INFORMATION ONLY.

Expires On:I I

Y OCCIDENTAL CHEMICAL fl)Ji -,- -

Page 9 of 9 ..

MSDS NUMBER: M5389 04-09-90 *

..,PRODUCT NAME: 50%SCAUSTIC SODA.SOLUTION Z4 LL-1al

-WARNING LABEL INFORMATION (Continued)-

1.

XHADLING MD STORAGE:

Considerable heat-~-Is. enerated when product :-is- mixed with water. Therefore.' 'when making solutions'always carefully follow i those steps:

ALWAYS wear ALL proscribed protective clothing. NEVER add water to product. ALWAYS add product - with constant stirring - '

slowly to surface of lukewarm (80-1iO'F) water. to assure product 1 Isbeing completely dissolved as It is added.

If product Is added too rapidly, or without tstirring,. and, becomes concentrated at bottom of miKing vessel, excessive heat, may be generated. resultino In DANGEROUS boiling and spattering.

and a possible IMMEDIATE AND VIOLENT ERUPTION of highly caustic' I solution. *.. -

NOTE: Never add more'. product than can be absorbed 'by.solut I on while maintaining temperature below 200-F (0 soa level) to prevent boiling and spattering.

-l Product can react. :EXPLOSIVELY with acids. aldehydes. and many other organic' chemicals.- when mixing product with-solutions

-.containing such chemicals, follow- all -. of -above mixing instructions. and add product very gradually, while stirring 1 constantly.-. . . . .

ALWAYS empty and clean containers of all resIdues before addin*

product, to avoid possible EXPLOSIVE reaction between product and -

unknown residue..

• 1L Returnable containers should be shipped in- accordance with supplier's recommendations. Return shipments should comply with all federal, state, and DOT regulations. All residual caustic

_l soda should be removed from containers prior to disposal.

DISPOSAL: - . '. .

K The materialsi resultIng from .clean-up hazardous wastes.and. therefore. subject to specific regulat ions..-

• .Package. store. transport. and dispose of operaitIons all 'clean-up materials may be I and any contaminated equipment In accordance with all federal, Shipments requirements state. and , local -health of waste ::materials. may be -subject per applicable regulations.

environmental applicable regulations.

to manifesting Appropriate disposal L will depend on the nature of each waste material- and should be performed by competent and. properly permitted -contractors.

Ensure that all responsibleofederal. state., and, local -agencies "

receive proper notification of disposal... -

1 INFORMATION REQUIRED BY FEDERAL, This product contains:

STATE OR LOCAL REGULATIONS:

• 1 . -

CAS# NAME IU .1310732 Sodium hydroxide (Na(OH))

7647145. Sodium.chloride-C(NaCl) 7732185 Water .. -

HMIS RATING SYSTEH: HEALB 3: FLAMhB ILI TY 0 REACTIVITY 2 r-FOR INDUSTRIAL USE ONLY ' LABE- L40X5369 I

235

FEB-08-05 TUE 03:08 PM HUC SA3 FAX HO. 5705423461 P. 02 Material Safety Data Sheet Sodium Nitrite ACC# 21410 Section 1 - Chemical Product and Company Identification MSDS Name: Sodium Nitrite Catalog Numbers; S80187, NC9757363, S338-3, S347-10, 5347-250, S347-3, S347-500, WESS347500 Synonyms: Nitrous acid, sodium-salt.

Company Identification:

Fisher Scientific 1 Reagent Lane -

Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887

. Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EiNECS/ELINCS 7632-00-0 Sodium nitrite >97 231-555-9 Hazard Symbols: T 0 N Risk Phrases: 25 8 50 I I Section 3- Hazards Identification EMERGENCY OVERVIEW Appearance: white to light yellow crystals. May cause methemoglobinemia. Danger! May be fatal if inhaled.

Strong oxidizer. Contact with other material may cause a fire. Hygroscopic. Harmful if swallowed. Causes eye and skin irritation. This substance has caused adverse reproductive and fetal effects In animals. Air sensitive.

Causes respiratory tract irritation.

Target Organs: Blood, cardiovascular system, smooth muscle.

Potential Health Effects Eye: Causes eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.

Skin: Causes skin irritation. May be absorbed through the skin.

Ingestion: Harmful If swallowed. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions,-and death. Causes digestive tract irritation. Ingestion may cause weakness, muscular incoordination, fine tremors, loss of reflexes, convulsions and possible death from circulatory collapse. Ingestion may cause a decrease in blood pressure, rapid pulse and visual disturbances.

Inhalation: May be fatal if inhaled. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea (labored breathing), and death. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.

Chronic: May cause reproductive and fetal effects. Laboratory experiments have resulted In mutagenic effects.

Animal studies have reported the development of tumors. Sodium nitrate may react with secondary or tertiary amines to form nitrosamines (certain nitrosamines are cancer suspect agents).

• 'I htlps://f'scirnagc.fishersci.coni/mcds,/2 141I 0.hitin 1/320 10/13/2003

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FEB-08-05~~~~

FEB-08-05 TUE 03:08 PH NUO SA3 FAX NO. 5705423461 P. 03 Section 4 - First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Ingestion: Call a poison control center. If swallow'ed,do not Induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.

Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using 'oxygen and a suitable mechanical device such as a bag and a mask. SPEED IS ESSENTIAL, OBTAIN MEDICAL AID IMMEDIATELY.

Notes to Physician: Absorption of this product into the body may cause cy'anosis (bluish discoloration of skin due to deficient oxygenation of the blood). Moderate degrees of cyanosis need to be treated only by supportive measures: bed rest and oxygen inhalation. If cyanosis is severe, Intravenous injection of Methylene blue, lmd/kg of body weight may be of value.

I Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in'pressure-demand, MSHA/N1OSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. Use water with caution and in flooding amounts. May explode from heat or contamination. May accelerate burning if involved in a fire.

Extinguishing Media: Use water only! Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. For large fires, flood fire area with water from a distance.

Do NOT use dry chemicals, C02, Halon or roams.

Flash Point: Not applicable.

Autoignition Temperature: Not available.

Explosion Limits, Lower:Not available.

Upper: Not available.

NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 1; Special Hazard; OX I Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.

Provide ventilation.

,. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize l dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.

Avoid contact with clothing' and other combustible materials. Do not ingest or inhale. Handle under an Inert atmosphere. Store protected from air. Use only in a chemical fume hood.

Storage: Do not store near combustible materials. Store in a tightly closed container. Store In a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.

II1 https://rscimnic.filslersci.com/nisds/2141O.htm 10/13122003

FEB-08-05 TUE 03:08 PM NUC SA3 FAX 110. 5705423461 P. 04 Section 8 - Exposure Controls, Personal Protection - 11 Engineering Controls: Facilities storing or utilizing'this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.

Exposure Limits Chemical Name l ACGIH NIOSHI OSHA - Final PELs -..

Sodium nitrite . none listed - none listed none listed OSHA Vacated PELs: Sodium nitrite: No OSHA Vacated PELs are listed for this chemical.'

Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin: Wear appropriate protective gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134'and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties Physical State: Crystals Appearance: white to light yellow -

Odor: odorless pH: - 9 Vapor Pressure: Not available.

Vapor Density: Not available.

Evaporation Rate:Not available.

Viscosity: Not available.

Boiling Point: 320 deg C Freezing/Melting Point:271 deg C Decomposition Temperature:320 deg C Solubility: Soluble.

Specific Gravity/Density:2.168 Molecular Formula:NaNO2 Molecular Weight:69.00

- . Section 10 - Stability and Reactivity.

Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Unstable if heated, may explode at temperatures greater than'5330C.

Conditions to Avoid: Unstable if heated, may explode at temperatures greater than5330 C., incompatible materials, ignition sources, dust generation, exposure to air, combustible materials, reducing agents, exposure to moist air or water, temperatures above 320 0 C.-

Incompatibilities with Other Materials: Reducing agents, acids, amines, chlorates, permanganates, cyanides (e.g. potassium cyanide, sodium cyanide), metals as powders (e.g. hafnium, raney nickel),

hypophosphites, sulfites, tannic acid, organic matter, antipyrine, ammonium salts, acetanilide, iodides, mercury salts, moisture, air, activated carbon, vegetable astringents.

Hazardous Decomposition Products. Oxides of nitrogen, Irritating and toxic fumes-and gases.

Hazardous Polymerization: Will not occur.

11 ii https://fsciniagc.fishcrsci.comlmsds/2 141 0.hitm 10/13/2003

FX NO. 5705423481 P.05 FEB-08-05 TUE 03:08 P 03:08 PH NUC S3 NUC SA3 FAX NO. 5705423461 P. 05 Section 11 - Toxicological Information RTECS#:

CAS# 7632-00-0: RA1225000 LD50/LC50:

CAS# 7632-00-O!

Draize test, rabbit, eye; 500 mg/24H Mild; Inhalation, rat: LC50 - 5500 ug/m3/4H; Oral, mouse: LDS0 = 175 mg/kg; Oral, rabbit: LD50 186 mg/kg; Oral, rat: LD50 = 180 mg/kg; Carcinogenicity:

CAS# 7632-00-0: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.

Epidemiology: Oral, rat: TDLo = 2190 gm/kg/2Y-C (Tumorigenic - Carcinogeni c by RTECS criteria -

Gastrointestinal - tumors).; Ora I, rat: TD = 91 gm/kg/2Y-C (Tumorigenic - equivocal tumo rigenic agent by RTECS criteria - Skin and Appendage s - tumors and Reproductive - Tumorigenic effects - testicular tumors).;

Oral, rat: TD = 40 gm/kg/56W- C - (Tumorigenic - neoplastic by RTECS criteria - Liver - tumors).

Teratogenicity: Oral, rat: TDLo = 660 mg/kg (female 1-22 day(s) after conception) Effects on Embryo or Fetus - fetal death and Effects on Newborn - growth statistics (e.g.%, reduced weight gain).; Oral, rat; TDLo =

10280 mg/kg (female 1-22 day(s) after conception and lactating female 20 day(s) post-birth) Effects on Newborn - weaning or lactation index (e.g., # alive at weaning per # alive at day 4).; Oral,mouse: TDLo = 280 mg/kg (female 1-14 day(s) after conception) Specific Developmental Abnormalities - blood and lymphatic systems (including spleen and marrow).

Reproductive Effects: Oral, mouse. TOLo = 1200 mg/kg (female 6-15 day(s) after conception) Fertility - pre-Implantation mortality (e.g. reduction In number of Implants per female; total number of Implants per corpora lutea).; Oral, mouse: TDLo = 1680 mg/kg (male 14 day(s) pre-mating) Fertility - male fertility index (e.g. #

males impregnating females per # males exposed to fertile nonpregnant females).; Oral, mouse: TDLo 840 mg/kg (male 14 day(s) pre-mating) Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count).

Neurotoxicity: No information available.

Mutagenicity: Unscheduled DNA Synthesis; Human, HeLa cell = 6 mmol/L.; DNA Inhibition; Human, Fibroblast

= 2000 ppm.; DNA Inhibition; Human Cells - not otherwise specified = 725 umol/L.

Other Studies: Standard Draize Test: Administration into the eye (rabbit) = 500 mg/24H (Mild).

Section 12 - Ecological Information l Ecotoxicity: Fish; Rainbow trout: LC50 = 0.19-0.39 mg/L; 96 Hr; Flow-through bioassay Mosquito Fish: TLm

=8.1 ppm; 24 Hr; Highly turbid water Creek chub: Critical range = 400-2000 ppm; 24 Hr; Detroit River No data available.

Environmental: In water sodium nitrite dissociates completely and under aerobic conditions the nitrite ions are oxidized to nitrates.

Physical: No information available.

Other: Harmful to aquatic life in very low concentrations.

Il Section 13 -. Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed In 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Serles: None listed.

.1 1lUps://fscimage.fishersci.cornfmsdsl/2141 W.iwtm 10/13/2003

FEB-08-05 TUE 03:09 PM NUC SA3 FAX 110. 5705423461 P. 06 ll Section 14 - Transport Information .

US DOT ATA U

ATS DO I RID/ADR I I MOT Canada DG Shipping Name; SODIUM NITRITE SODIUTR Hazard Class, 5.1 S.1(6.1)

UN Number: UN1500 UN1500 Packing Group; III III Section 15 - Regulatory Information US FEDERAL TSCA CAS# 7632-00-0 is listed on the TSCA inventory.

Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules None of the chermicals in this product are under a Chemical Test Rule.

Section 12b -'

CAS# 7632-00-0; 5a2/12b TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA.

SARA CERCLA Hazardous Substances and corresponding' RQs CAS# 7632-00-0: 100 lb final RQ; 45.4 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ.

SARA Codes CAS # 7632-00-0: acute, chronic, flammable.

Section 313 This material contains Sodium nitrite (CAS# 7632-00-0, 97%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40'CFR Part 373.

Clean Air Act:

This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

CAS# 7632-00-0 is listed as a Hazardous Substance under the' CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE CAS# 7632-00-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.

California No Significant Risk Level: None of the chmicalsin thisaproduct are listed, European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols:

TO N Risk Phrases:

R 25 Toxic if swallowed.

R 8 Contact with combustible material may cause _ I) L.

https://Tscimra c.ishcrsci.com/msds/2 141 O.ht/n 10/13/2003

FEB-08-05 TUE 03:09 PM NUC SA3 FAX NO. 5705423461 P. 07 fire.

R 50 Very toxic to aquatic organisms.

Safety Phrases:

S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S 61 Avoid release to the environment. Refer to special Instructions/Safety data sheets.

WGK (Water Danger/Protection) -

CAS# 7632-00-0: 2 Canada - DSL/NDSL CAS# 7632-00-0 is listed on Canada's DSL List.

Canada - WHMIS This product has a WHMIS classification of C, D1B, D2B.

Canadian Ingredient Disclosure List CAS# 7632-00-0 is listed on the Canadian Ingredient bisclosure List.

Exposure Limits CAS# 7632-00-0: OEL-CZECHOSLOVAKIA:TWA 1 mg/m3;STEL 5 mg/m3 OEL-HUN GARY:STEL 1 mg/m3;Skin l Section 16 - Additional Information MSDS Creation Date: 7/02/1999 Revision #S Date: 12/03/2002 The information above Is believed to be accurate and represents the best Information currently available to us. However, we make no warranty of merchantablllty or any other warranty, express or implied, with respect to such information, and we assume no liabliy resulrlng from Its use. Users should make their cwn Investigations to deterinne tho suitability of the Information for their pafticuilar purposes. In no event shall FIsher be llable fcarany claims, losses, or damages of any third partyodrorlost profits orany specil3, Indircct, lnddenm3l, consequential or exemplary damages, howsoever arising, even If risher has been advised of the possibility of such damages.

7L4\

https://CIscimage.rlslhersci.com/msds/2 141 O.ltin1 10/13/2003

aL-zr -a -7 Enformation only IPAG EOZ 1V88/98 1Biwi3s rAx ID: 08MG881-H414844D-B838242 (SOMWE: one )I -O-U RISIDS Number. N366 -.- Effective t0630/9S 24 Hour E£mrgency Telephone: 908-839-2151 CHEtTREC: 14004244300 AISDS Material Safety Data Sheet_

Ntlonal Response In Canead CANUTEC: 61 39"5466 Outsid U.S. and Canada Chamirec: 202a83-7616 it rrom: Mallinckrodt Baker, Inc.

ERODT NOTE: CHEMTREC, CANUTEC and National I

_J.T.Bke 222 Red School Lane Response Center emergency nrumbers to be II Phillipsburg, NJ 08885 I_

used only in the avert of chemical emergencies fwnvoig a spil, leak fire, *xpostr. or accidert ivolvig dwemkslx AlI non-emergency questions should be directed to Customer Service (1-800-582-2537) for assistance. I NITRIC ACID, 50-70%

1" MSDS Number: N.3660 - Effective Date: 06/30/98 11

1. Product Identification .1 Synonyms: Aqua Foitis; Azotic Acid; Nitric Acid 50%; Nitric Acid 65%; nitrc acid 69-70%

CAS No.: 7697-37-2 Molecular Welght: 63.00 Chemical Formula: HNO3 Product Codes:

J.T. Baker 5371, 5555, 5801, 5876, 9597, 9598, 9600, 960I, 9602, 9604, 9606, 9607, 9616 Mallinckrodt 1409, 2703, 2704, 6623, V069; V077, V336, V561

2. Composition/Information on Ingredients I Ingredient - - CAS No Percent Hazardous I Nitric Acid .__ - ._ _7697-37-2 50 - 70% Yes I Water 7732-18-5 30 - 50% No A

3. Hazards IdentiEcation A

Emergency Overview Ii End ofPage: 1 -Continued on ned page 1.998.12-08 at 10.18 242 I Ii

Information Only . .Jry A v 1PACE B63 1vJEl98 1B:11:?7 -AX ID: E8863801-14148440-BB02842 (SEDD1Cf:CHEHm X )

WSDS Number. N3660 Effective Date: 06/30198 . . .. ...... .:

POISON1 DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE CORROSIVE LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BOD TISSUE MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE. '. - .

L J.T. Baker SAF-T-DATA (tm) Ratings (Provided heire for your convenience)

Health Rating 3 - Severe (Poison)

L Flammability Rating 0 - None Reactivity Rati 3 - Severe (Oxidizer)

Contact Rating: 4 - Extreme (Corrosive) -....

Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code: Yellow (Reactive)

L  :. < .  : ~

Potential Health Effects . - .  ::

Nitric acid is extremely hazardous; it is corrosive, reactive, an oxidizer, and a poison."

Inhalation: - .i.. -

Corrosive! Inhalation of vapors can cause breathing difficulties and lead to pneumonia and pulmonazy edema, which may be fatal.- Other symptoms may include coughing, choking, and irritation or the nose, throat, and respiratory tracL Ingestion:

Corrosive! Swallowing nitric acid can cause imediate pai and ;burns of the mouth, throat, esophagus and gastrointestinal tract. m. --

L ~~~Skin Contact : ..... ...;m.........-.....

Corrosive! Can cause redness, pain, and severe skin burns. Concentrated solutions cause deep ulcers and stain skin a yellow or yellow-brown color.

Eye

Contact:

Corrosive' Vapors are Irritating and may Ziausiedamnage to the eyes. Contact may cause severe burns and permanent eye damage.

Cbronic Exposure:

Long-term exposure to concentrated vapors may cause erosion of teeth and lung damage.

Long-term exposures seldom occur due to the corrosive properties ofr the, acid.

Aggravation of Pre-existing.Conditiolls: .. .

Persons with pre-exisftg skin disorders, eyedisea-, or caidiopubnonaiy diseases may be more susceptible to the effects of this substance ... . .. . . . .. .. .

4. First Aid Measures - :.

-immediate first aid treatment reduces the health effects of this substance.

Inhalation:

Remove to resh air. If not breathing, give arficial respiration. If breathing is difficult, give oxygen. Call a physician.

EndofPagc 2-Cointnuedonneatpa;ge i998-12-08cf 10:18

._____ ___ .... 243

Infornation Onlye rZj Juv IL..

PARB 884 VISOB 10:12:26 FAX ID: 88MG311-8414811D71B 42 (SOURCEc: COAX )

.MSDSlsumberN366O ..- Effecive Date: 06.130/98 * .,

Ingestion: ,

DO NOT INDUCE VOMITING! Give lirge quantities of water or milk if available. Never give anything by mouth to an unconscious person. Get medical attention immediately.

Skin Contact.,

In case of contact, immediately flush skin with plenty of water for at least_5 minutes 1 while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.

Eye

Contact:

Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures - X Fire:.J Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause Ignition. Can react with metals to release flammable hydrogen gas.

Explosion:

Reacts explosively with combustible organic or readily oxidizable materials such as:

alcohols, turpentine, charcoal, organic refuse, metal powder, hydrogen sulfide, etc. Reacts with most metals to release. hydrogen gas which can forn explosive mixtures with air. 1l Fire Extingulshing Media:

Water spray may be used to keep fire exposed containers cooL Do not get water inside container.

Special Information:

Increases the flammability of combustible, organic and readily oxidizable materials. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure 11 mode.

1

6. Accidental Release Measures Ventilate area of leak or spilL Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e. g., vermiculite, dry sand, eaith), and-place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewerl US Regulations (CERCIA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard 1

National Response Center is (800) 424-82

- T. Baker NEUITRASORB(tn) or TEAM(tm) 'Low Na+' acid neutralizers are recommended J for spills of this product End ofPqe: 3- Continuefon nect pae 1998.12-08 at 10:18 1 244

Information Only 't 7)o.

SE0B 1O1Z/BR9 i62:S' FAX ID: a88a6301-B41484408- 28442 (SDURC:,.CEHiMF )

MSDS Numbcr. N3660 - Effective Dalc:06130/9f

7. Handling and Storage Store In a cool, dry, ventilated storage area with acid resistant floors and good drainage.

Protect from physical damage. Keep out of direct sunlight and away from Fiat, water, and incompatible materials. Do not wash out container and use it for other purposes. When L diluting, the acid should always be added slowly to water and in small amounts. Never use hot water and never add water to the acid. Water added to acid can cause uncontrolled boiling and splashing. Containers of this material may be hazardous when empty since they retain product residues (vapors, Equid); observe all warnings and precautions listed for the product.

L 8. Exposure Controls/Personal Protection Arborne Exposure Limits:

-OSHA Permlissible Exposure Limit (PEL):

L 2 ppm (IWA), 4 ppm (STEL)

-ACGIH Threshold Limit Value (llV):

2 ppm (TWA); 4 ppm (STEL)

L Ventilatlon System:

A system of local and/or generl exhaust is recommended to keep employee exposures below the Abborne Exposure Linits.:Loal exhaust ventilation is generally preferred because L itcan control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Venttionl , A- -

Manual of Recommended Practices , most recent edition, for details. -

Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. Nitric acid is an oxidizer and should not come in contact with caitridges and -canisters that contain oxidizable materials, such as activated charcoaL Canister-type respirators using'sorbents are ineffective.

Skin Protection:

Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

Eye Protection:

Use chemical safety goggles and/or a full face shield where splashg i possible. Maitain eye wash fountain and quick-drench faciitie 3n 'woork area.

9. Physical and Chemical Properies  ;. -

L Oppeardnc Colorless to yellowish liquid.

g ~~Odor. - - - - - . -

Suffocating, ZcS - .. .. ,

End ofPage 4-Continuedonnezdpage " ` :- . 99812-.O at 1eLi8 1"~ - 245 .

Information Only a y 5 aT PA M 12M/91 18:13:28 rAX ID: OB63fi1-Bj41144D-BBB8M42 (SamRC: IIEHFAX 4 -

MSDS Nmnber. N3660 -- Effectic Date: 06130I9 .

Solubility.,1 Infinitely soluble.

Specific Gravity.,

1.41 1.0 (0.lM solution)

% Volatltes by volume @21C (70F):n 100 (as water and acid) - 1 Boiling Point.

122C (252F) -

Melting PointS 42C (44 :)

Vapor Density (Air=1):

Vapor Pressure (mm Hg):

48 @ 20C'(68F) 1 Evaporation Rate (BuAc=l):

No infozmation found.

. ll

10. Stability and Reactivity 1I Stablirn Stable under ordinary conditions of use and storage. Containers may burst when heated.

Hazardous Decomposition Products: .l When heated to decomposition, emits toxic nitrogen oxides fumes and hydrogen nitrate. Will react with water or steam to produce heat and toxic and corrosive fumes.

Hazardous Polymerization:

Will not occur. .

Incompatibilifes:.

A dangerously powerful oxidizing agent, concentrated nitric acid is incompatible with most substances, especially strong bases, metallic powders, carbides, bydrogen sulfide, turpentine, and combustible organics.

Conditions to Avoid:

Light and heat.

11. Toxicological Information.

Nitric acidL Inhalation rat LC50: 244 ppm (N02)/30M; Investigated as a mutagen, reproductive effector. Oral (human) LDLo: 430 mg/kg.

- --- Cancer Listsk---------------- -- - - -- - i

--- NTP Carcinogen-- -

EndofPge: - Continuedon nwt pane 1998-12-08at410:18 J 246

Information Only ._ . , .

flfu/J fj * - .7 .! . . -S 1 -.

I PGE 8? 12/8/98 D ., .

1:13:t

.ff t FA ID: B8B8G3B1-E1l44B44D-88B8M4Z' tS==: CEtx

. . . . .09

~~/~;bo6. "-

- .I MSDS Nuamber. N366D ... Effective Date. 06130198 - ----- -- I -- .- .- - . .  ::

,; ~ 1,- . j- -, --. - - . - . : .; ,

Ingredient ;Known 'Anticipated IARC Category.

.. _9 Nitric Acid (7697-37-2) No No None:

Water (7732-18-6) No No None

12. Ecological Information Environmental Fate:

No infonnation found.

Enironimental Toidcht .  ;.

No ionnation found. * *

13. Disposal Considerations -

Whatever cannot be saved [or recovery or recycling should be managed in an appropriate.

and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to .

determine specific disposal requirements. Processin& use or contamination of this product may -change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information -- ..-.

Domestic (Land, D.O.T.)

Proper Shipping Name: NITRIC ACID (WITH NOT MORE THAN 70% NITRIC `ACID)  ;

Hazard Claw. 8 UNINAM UN2031 Packing Group: 11 Information reported for product/slze: 150LB  ;  : -

International (Water, I.M.O.)

Proper Shipping Name: NITRIC ACID (WiTH NOT MORE THAN 70% NITRIC ACID)

Hazard Class: 8 UNINA UN2031 Packing Group: 11 Information reported for product/size: 150LB International (Air, L.C.AO.)

.: . . -. , /I .

1. ...

. . ;,. , -1 .-9,

-1  :

End ofPagc 6 -Conlnued on nz page 1998-12-08 af 10:18 247

Information Only - OY PfEE 88 12/88/98 18:14:11 FYAX D: 80886381-0414044D-86088828 I1 (SOMn: CHENX )

SISDS Nxiber. NS6 --- EffadeMM D 0te:06/3/9 . i Proper Shipping Name: NITRIC ACID (WITH NOT MORE THAN 70% NITRIC ACID)

Hazard Class: 8 I UN/NA UN2S31 Packing Group: I Information reported for product/size: 15OLB v Il I1

15. Regulatory Information I1 Part i\ --- -__-____-___

-\Chemical Ingredient Inventory Status TSCA EC Japan Australia I.

Nitric Acid (7697-37-2) Yea Yes Yes Yes Water (7732-18-5) Yes Yes. Yes Yes I

.Al

---

\Chemical Inventory Status - Part 2\----------------- -----------

Ingredient Korea

-- Canada -

DSL NDSL Phil. A Nitric Acid (7697-37-2)

Water (7732-18-5)

Yes Yes Yes Yes.

No No Yes Yes Il

---

\Federal,-State & International Regulations - Part 1\---------------

Ingredient -

-SARA 302-RO TPQ

---

SARA 313-----

List Chemical Catg A Nitric Acid (7697-37-2)

Water (7732-18-6) 1000 No 1000 No Yes No No No 11

---

\Federal, State & International Regulations - Part 2k --------------

Ingredient

. a CERCLA

-RCRA-261.33

-TSCA-8(d) I Nitric Acid (7697-37-2)

Water (7732-18-5) 1000 No No No No No I Chemical Weapons Convention: No SARA 311/312: Acute: Yes TSCA 12(b): No Chronic: Yes Fire: Yes Pressure: No CDTA: No I Reactivity: No (Mixture 1 Liquid) jI Australian Hazchem Code: 2PE Poison Schedule: S6 I1 WHMIS:

This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the infornation required by the CPR Ii EndofPae: -Coninuedon nex pay 998-12-08 at 10:18 248 Ii Ii

Information only - __T ' h - f-F P'e"C4,a-iPAGIE 889 12/189/98 -- 1B11432 FAX ID: 2888&381-R4.14844D-BBBB2W4 1S!JDE-1ciw Hhax )

SSNumber.N366O...Effctive Date:06130/9S

16. Other Information NFPA Ratings: Health. 3 Flammability: 0 Reactivity: 0 Other Oxidizer Label Hazard Warning:

POISON! DANGER' STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE.

LUNG AND TOOTH DAMAGE.

LUbe Precautionsr Do not get in eyes, on skin, or on clothing.

Do not breathe vapor or mist.

Use only with adequate ventilation. --

Wash thoroughly after'handling. , -

Keep from contact with clothing and other combustible materials.

Do not store near combustible materials'.;

Store in a tightly closed container.

Remove and wash contaminated clothing promptly. , ,

label First Ad:

In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing'before' reuse. if swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not .

benthing give artificia respirtono If breathing is difficult, give oxygen. In all cases get medical attention,immediatel.-

Product Use.

Laboratory' Reagent.

Revision Information:

MSDS Section(s) changed since last revision of document include: 1, 2. '- . ,'

Disdaimer.,

Mallnckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by 'a properly trained person using this product Individuals recelving.the Information mmt exercise their independent judgment in determining Its appropriateness for a particular purpose. M4ALUNCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILIUY,-FITIESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET'FORTH HEREIN OR THE PRODUCIT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR REULANCE UPON THIS INFORMATION. '

Prepared by: Strategic Services Diiin' Phone Nwnber. (314) 539-1600 .(U.S.A) _'- '

Ead ofPaq 8- Endof docujmejzt 1998-12-08 at I0 18 249

• Information only a-m MATERIAL SAFETY DATA SHEET Meeting OSHA Standard 29CFR §1910.1200 (9)

CAL OSHA StandardTltle 26 §5194 (9)

Q D RAXEFFECTIVE DATE: August 31, SHE0 ILJ PRODUCT TRADE NAME: Borax TSCA NO.: 1303-96-4 CHEMICAL NAME AND SYNONYMS:

Sodium tetraborate decahydrate' CAS NO.: 1303-96-4 Ii CHEMICAL FAMILY: Borate ' FORMULAe N oilO 0 PHYSICAL HAZARD RATING: National Fire Protection 2 4 Il Association Health Flammability 0

0 Ii Reactivity 0 0

• a *

• Il MATERIAL OR COMPONENT %:

Sodium tetraborate decahydrate >99% CAS No. 1303-96-4 I

Appears on CAL OSHA Directors' List of Hazardous'Substances:

Does not appear on any EPA List of Hazardous Substances. Il WARNING: This product contains trace amounts of arsenic, a chemical known to the State of California to cause cancer.:

I I1 I Ua 3. I APPEARANCE:

SPECIFICGRAVITY: 1.73 White, odorless, crystalline solid II MELTING POINT: 620C VAPOR PRESSURE: Negligible SOLUBILITY IN WATER: 20C 100oc-5.8%

65.6%

Ii HEAT OFSOLUTION: - 222 BTU/lb.

FORMULA WEIGHT: 381.37 A

pH3%SOLUTION:9.25 Q 20*C, -  : I CONTACT: P.L. Strong; Manager, PrQduct Safety II The Informatlon and recomrnendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or I"pled Is made with respect to the Information contained herehi.

RAt0t1n nX u H

a UNTEDSTATES ORA & CHEMIC ORPORATI WIlHIRE BLVD.,LOIANELES,1I PJg91e 256401911 250 Ij Ii

-4CtrnTr-. 1' -.

Information Only

.t 6I-x, 0~A9WM~gft98 I IUUTU ** £II

• L EFFECTS OF ACUTE 1EXFPSURE INGESTION: '-V.

7;" "

L ACUTEORALLD5 o :4.5-5.0 gram/kg of body weight (Sprague-Dawley rats).

HUMANACCIDENTALEXPOSURE. Anticipated symptons: nausea, vomiting, diarrhea. Pfter 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />, erythema' macular" skin'rash, 'and dizziness may occur. . C, L EYE: Irritant (rabbits - per 16 CFR 51500.42). Probable human eye irritant. - -.

L DERMAL:

ACUTE DERMAL WD5 Greater than 10 gram/kg of body weight - ,

L (rabbits - per 16 CFR S1500.40).

K PRIMARYSKINIRRITATIONINDEXo - no effect (rabbits - per 16 CFR 51500.41)

SKIN:No known adverse effects to'humans with intact skin. May be absorbed through L damaged skin.

OORROSIVE:5his product is non-corrosive.

INHALATION:May cause sneezing and coughing if exposed to high concentrations ' '- '

(>IC mg/m3-).

L EFFECTSOFCHRONICOVEREXPOSURE - - -. .

INGESTION: Animal testing for carcinogenicity of boric acid has been negative. '

Animal studies show that'ingestion of large amounts of borates over prolonged-periods of time causes a decreise ')n sperm production and testicle 'size in male laboratory animals and developmental effects in fetuses of pregnant female laboratory animals. No-evidencelof such effects in humans. ' .

LEYE: Possible irritant to human eye.

LDERMAL:No evidence of effect from exposure on intact human skin.

L:

INHALATION:As with any nuisance dusts, may aggravate chronic respiratory ailments such L as asthma, bronchitis, etc.

!J UNITEDSlATES BORAX CHEMICALCORPORATKN 3075WILSHRE BLVD., LOS ANGELES.CA90010 I¶ Dnln X.v Page 2 Borax 251

• ..nfn-rMat~nn' O~nlvN'. ' -- .A AC0r,. FW T3 O¶c f-'

. 1.

• 0 0 . I I3

..-..'11 RECULATORY INFORMATION OSHA PERMISSIBLE EXPOSURE LIMIT (PEL)

10 mg/rn 3 ACGIH RECOMMENDED THRESHOLD LIMIT VALUE: 5 mg/mR 3 29CFR§1910 SUBPART Z A

CAL OSHA PERMISSIBLE EXPOSURE LIMIT (PEL): 5 mg/M 3 NOT LISTED INTHE NATIONAL TOXICOLOGY PROGRAM ANNUAL REPORT ON CARCINOGENS (1989)

NOT LISTED INTHE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) MONOGRAPH NOT.USTED ON THE OSHA CARCINOGENS UST EMERGENCY AND FIRST AID PROCEDURES: l I EYES: Flush with tepid water for 15 minutes., Consult a physician.

I SKIN: Rinse with water. A INHALATION: Remove to fresh air.

A INGESTION: Drink large amounts of water or milk. Consult a physician.

NOTE TO PtIYSICIAN: A IA Gastric lavage with 5t sodium bicarbonate is suggested.This should be followed by saline catharsis. Assure adequate hydration. Borax is not considered an acute poi-son. After ingestion or absorption into the bloodstream of large amounts (15 grams I or more), symptoms may.appear after 24-72 hours. Borates are readily dissipated through the urine Q?0% in the first 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />). Complimentary blood analysis is available for physicians and emergency rooms. Medical consultation is also avail-able. Call (714) 774-2673. 11 1

lU6EDSTAT BORAX CHE ACALORPORATION 9

• 7 W LIRE BLVDO LOSAANGELES CA9001012 n D Page 3 . Borax 252 II

Information Only - . . - IV .,-6IC 5 -,

0 *

• 9*04Le 0 IJo £ffta **3 Dii A lFLASH POINT (METHOD USED): N/A ,FLAMMABLE LIMITS:N/A LL. EXTINGUISHINGMEDIA:None required. Product is an inherent fire retardant.

SPECIAL FIREFIGHTING PROCEDURES: None are required. No potential for fire or explosion hazard. Product is an inherent fire retardant.

UNUSUAL FIRE AND EXPLOSION HAZARDS: None

, f:. to] . - ,I . , . .I .  :

__ g LSTABILITY Borax is a stable product.

INCOMPATIBILITY (MATERIALS TO AVOID): Elemental zirconium (hot)

LL4AZARDOUS DECOMPOSITION PRODUCTS: None HAZARDOUS POLYMERIZATION: will not occur CONDITIONSTOAVOID:Contact with elemental zirconium (mixture explodes when heated).

tiS g £ *** 3W1-11 STEPS TO BE TAKEN INCASE MATERIAL IS RELEASED OR SPILLED: Sweep or vacuum followed by water rinse.

KVASTE DISPOSAL METHOD:Refer to local disposal requirements and regulations for waste disposal methods. Not regulated under 5313 of SARA Title III or RCRA (40 CFR 261.33)

! .Y I UM7EOSTATES BORAX SCHEMJCALCORPORATION-*3075 WILSHIRE BLVD..LOS ANGELES,CA900IO.1294 fffff Page 4 . Borx 253

- - I - -  : -- - - - -.

• In formation OJnly .5 _-

0 . S*

RESPIRATON PROTECTION (SPECIFYTYPE):Recommend use of light duty dust mask (such as 3M model 5800) in areas of airborne concentrations greater than 1mgm/r 3.

VENTILATION:Local exhaust is sufficient. I PROTECTIVE GLOVES: None needed unless skin is abraded. Leather, cloth or rubber gloves.

Ii EYE PROTECTION: Avoid eye contact. To avoid eye contact, dust goggles are recomrrmended in areas of high airborne concentrations.

OTHER PROTECTIVE EOUIPMENT: None I

NM SI 01 *1 MMUI

• PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Dry indoor storage.

OTHER PRECAUTIONS:Retain package integrity.

I A

DATE:.ejLC f SIGNATURE:

P.L. Srong. Manag, Pmduct Safety UNITEDSTATES BORAXCHEMICALCORPORATION-3075 WLSHIREBLVD.LOSANGELESCA9010-0n1294 nnVI

.1 Pag 5 -- Borax Al 254 I

Ii

Information Only

--w -73 0 I  ! . .s- ,*

MATERIAL SAFETY DATA SHEET / -

Meeting OSHA Standard 29CFR § 1910.1200 (9)

L': O A CAL OSHA Standard Tite26 § 8-5194 (g)

EFFECTIVE DATE: August 31, 1990 0 3 1 £90f-111j l PRODUCT TRADE NAME: Boric Acid .. ., - . , .. , - 77 - . '  ;

TSCA NO.: i0043-35-3 CHEMICAL NAME AND SYNONYMS: I . .. - - -- r --,

• CAS NO.: 10043-35-3 T Boric acid, Orthoboric acid I CHEMICAL FAMILY: Borate .  : FFORMULA: H3 T

I PHYSICAL HAZARD RATING: National Fire Protection AAssociation Health 0 Flammability , 0 Ow- .;. '

'Reactivity IO . ".  :-.,,

04"I[*?IM a aV'GI1*0imIt13 IIII I

I MATERIAL OR COMPONENT%::

T Boric Acid >99% CAS No . 10043-35-3 WARNING: This product contains trace amounts of arsenic, a chemical known . I I -. 6.

to the State of Calif6lrni to caiuse cancer.;

I 36 I  :. '. .. , .. '

APPEARANCE: White, odorless, cryatalline solid SPECIFIC GRAV!TY: . 1.5128. . . . ..

MELTING POINT: . 1 0.9 C (3400F) . ..

SOLUBILITYINWATER. ,. 20'C 4, 7; r ,

,.100!*C -.. 27.5.

HEATOFSOWUTION: 157 BTU/lb. S 18° C-FORMULA WEIGHT: 61.84 pH at 20 C: 0.1% solution 6.1 1.0% solution 5.1 4.7% solution 3.7

.4 0i;ush I

CONTACT:

az P.L. Strong: Manager --

11k" .;KI w Product safet"y..

- .tl

Bif 0 jI B as 1 Informatlon and recommndatlons contalned herein are basd upon data believed to b corct Hw r, no guanne or wifnanty ot any kind expressed or kTimled Ismade wlth respect to the Information contained hereon.

INI7EDSTATES BORAX &CHEMICALCORPORATION

• 3075 WILSHRE BLVD., LOS ANGELES. CA900IO-1294 (DSBO RAX -

Page 1 2540-1907 255

information only .-

4011O 1A 2 AO 4 I 0 I

EFFECTS OF ACUTE EXPOSURE INGESTION: -A ACUTEORALLD50 :3.5-4.1 gram/kg of body weight (Sprague-Dawley rats).

Ii HUMANACCIDENTALEXPOSURE:Anticipated symptons: nausea, vomiting, diarrhea. After 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />, erythemas macular skin rash, and dizziness may occur.

I EYE: Is a mild eye irritant (rabbits - per 16 CFR S1500.42)

A DERMAL: A ACUTEDERMALLDs4 Greater than 2.0 gram/kg of body weight PRIMARYSKINIRRITATK>N (rabbits - per 16 CFR $1500.40)

INDEX:O (rabbits - per 16 CFR 51500.41)

A SKIN:No known adverse effects to humans with intact skin. May be absorbed through damaged skin.

A CORROSIVE:This product is non-corrosive. A INHALATION:Hay cause sneezing and coughing -if exposed to high concentrations

(>10 mg/m 3 ).

EFECTS OF CHRONIC OVEREXPOSURE w Ii INGESTION: Animal te3ting for carcinogenicity of boric acid has been negative.

iA Animal studies show that ingestion of large amounts of borates over prolonged periods of time causes a decrease in sperm production and testicle size in male laboratory animals and developmental effects in fetuses of pregnant A

female laboratory animals. No evidence of such effects in humans.

A EYE: may cause slight reversible conjunctivitis I

DERMAL:No evidence of effect from exposure on intact human skin.

INHALATION:As with any nuisance dusts, may aggravate chronic respiratory ailments suc..

as asthma, bronchitis, etc.

UNITED STATES BORAX& CHEWCALCORPORTION

• 3075 WILSHIRE BLVD., LOS ANGELES.CAOOt.12940 D -1 M BODR AX I . 1. i

. . . 1.

1-Boric Acid _ I 256 Ii

0 0 - ) .. _. . I .

'V - . t . -. ,

F11311111111fj mitt] I -A olatLWA .

I ! .-. .

REOULATORY INFORMTION OSHA PERMISSIBLE EXPOSURE LIMIT (PEL): Not listed 29CFR§1910 SUBPARTZ L ACGIH RECOMMENDED THRESHOLD LMIT VALUE: Not listed NOT LISTED INTHE NATIONAL TOXICOLOGY PROGRAM ANNUAL REPORT ON CARCINOGENS (1989)

NOT LISTED INTHE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) MONOGRAPH_

NOT LISTED ON THE OSHA CARCINOGENS LIST L IEMERGENCY AND FIRST AID PROCEDURES: l L EYES: Flush with tepid water for 15 minutes. Consult a physician.

L SKIN: Rinse with water.

INHALATION: Remove to fresh air.

L INGESTION: Drink large amounts of water or milk. Consult a physician.

NOTE TO PHYSICIN: - , .

Gastric lavage with 5% sodium bicarbonate-is-suggested. this should be followed by saline catharsis. Assure adequate hydration. Boric acid is not considered'an acute L poison. After ingestion or absorption into the bloodstream of large amounts (15 grams or more), symptoms may appear after 24-72 hours. Borates are readily dissi-pated through the urine (700 in the first .24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />). Complimentary blood analysis is available for physicians and emergency rooms. Medical consultation is also available. Call (714) 774-2673.

L LIuNTEDS1ATESs CHELR POR *Z SOLSHXRE BLD., LOSANELES, A9010 -n n*

L Page 3 3Q<*->Hs<i^v§li- ocAd--^; Bori- Ad -

257

r.41 - v -.

r-- - 1 .lWi Lrtrs - - ^s..

061IL1 y M * ,I *A 0 e000

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FASH POINT (METH,. 'JSED): N/A FLAMMABLE LIMITS: NjA Ii EXTINGUISHING MEDIA:None required. Product is an inherent fire retardant.

Ii SPECIAL FIREFIGHTING PROCEDURES: None are required. No potential for fire or explosion hazard. Product is an inherent fire retardant.

Ii UNUSUAL FIRE AND EXPLOSION HAZARDS: None I'

lit3*'.

I' STABILIlY: Boric acid is a stable product.

INCOMPATIBILITY(MATERIALSTOAVOID):Acetic anhydride; elemental potassium A

HAZARDOUS DECOMPOSMON PRODUCTS: None.. A1 HAZARDOUSPOLYMERIZATION: will not occur.

CONDITIONSTOAVOID:Contact with acetic anhydride or elemental potassium may result in

-1 explosion.

Ii 0 *

• I-Ii STEPS TO BE TAKEN INCASE MATERIAL IS RELEASED OR SPILLED: Sweep or vacuum followed by water rinse.

A WASTE DISPOSAL METHOD: Refer to local disposal requirements and regulations for wasteo disposal methods. Not regulated under 5313 of SARA Title III or A

RCRA (40 CFR 261.33)

A1 CHEMCALORPORATION 3075 WLSHIRE BLVD.. LOS ANGELES. CA 010-124 B 0 Pan& A UNITE STATES Boric Acid

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258 I'

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• z lF' aA .. o 1 5 I I 5 S1 RESPIRATON PROTECTION (SPECIFY TYPE): Recommend use of light duty dust mask (such as 3M model 5800) in areas ofhign airborne concentra

_ tlons.

_ VENTILATION: Local exhaust is sufficient.

PROTECTIVE GLOVES: Leather, cloth or rubber gloves EYE PROTECTION: To avoid eye contact, dust goggles are recommended in areas of high airborne concentrations.

OTHER PROTECTIVE EOUIPMENT: None 11111k I a[elI PRECAUTIONS TO BE TAKEN INHANDLING AND STORING: Dry indoor storage.

OTHER PRECAUT#ONS:Retainr package integrity.

DATE: SIGNATURE: ____

P.L Slong. MMagr. ProddfSaI.?y lUNITEDSTATES ORAXCHEM1CLMOL TI N> 075VVLSHIRESLVD., LOSANELES, >1AOI-t294nn nnnA P LSI B0RAX I Pago 5 Boric Acid

L 3800-PM-WSW1 iooosa -ir2m LModule 2 Applicant Name: PPL SusquehannaLLC ffi COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT WASTEWATER TREATMENT TECHNOLOGIES MODULE 2 PPL Susquehanna, LLC -

Method for Handling and Disposal of Solid or Liquid F Number Outfall' -Treatment Unit Description (list in sequence)

- - - Residue Resulting from Treatment (list In sequence) 070 Sedimentation (setting) . }. Cleanfill 7 Discharge to Surface Water N/A F_071 Sedimentation Landfill, or soil amendment Disinfection (chlorination) i .; N/A Dechlorination N/A Discharge to Surface Water N/A 171 Filtration Radioactive Waste Landfill Ion Exchange Radioactive Waste Landfill Neutralization N/A 371 Neutralization N/A 571 Requesting to be eliminated (see attached additional support information for Module 3, Outfall 571) 072 Oil & Grease Removal . Recycled Discharge to Surface Water . N/A

- 073 Oil & Grease Removal Recycled Discharge to Surface Water N/A 074 Oil & Grease Removal Recycled Discharge to Surface Water N/A 075 Sedimentation (Settling) Cleanfill Discharge to Surface Water N/A 260

11-3800-PM-WSWMO0O8e Module 2 1/2004 Applicant Name PPL Susquehanna, LLC i..

079 Grinding NA

. Screening Landfill Equalization Activated Sludge NA Aerobic Digestion / Landfill <II Neutralization N/A Disinfection (Chlorine),

Dechlorination N/A N/A Il Discharge to Surface Water N/A 080 Sedimentation (Settling) Cleanfill Discharge to Surface Water N/A Ii A

Ii A

Il ii 261 Ii

L =80-M-WSWMOO8f Module 3 11004 Applicant Name: PPLSusquehanna',LLC Outtall: 070 L. . COMMONWEALTH OFPENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT SOURCES OF WASTEWATER

- MODULE 3 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

L IPPL Susquehanna, LLC 070 S-2 Pond

1. Process Wastewater - N/A - - -- -- -

a. Describe process and type of wastewater.

b. Production Rate.

Referring to the instructions in Appendix 1 for this question, provide the production data as an attachment for each L - process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

• c. Discharge Occurs. hrs/day; days/wk; - days/yr - months/yr.

During which months?

Rep.ort the discharge rate as:

The maximum daily discharge rate. MGD The monthly average discharge rate. MGD T

7 -For The lona-termaveraae discharge rate.

batch discharges report:

Number of decant cycles.

MGD Cycles/day Length of each decant cycle. MIN.

Average decant discharge rate. GPM

2. All Other Wastewater Contributing to this Ouffall NWA

a. Describe the wastewater.

F b. Source(s).

c. Discharge Occurs. . hrs/day; days/wk; days/yr; months/yr.

During which months? -

Report the discharge rate as:

The maximum daily discharge rate. 'MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:

Number of decant cycles. Cycles/day Length of each decant cycle. MIN.

Average decant discharge rate. GPM

-1 -

262

3800-PM-WSWM0008I . 112004 Module 3 Applicant Name: PPL Susquehanna, LLC, Outfall: 070 IL

3. Total Process, Miscellaneous Noncontact Cooling, and SanItary Wastewater

a. Source(s). Stormwateronly Ii

b. Discharge Occurs. hrslday; dayslwk; days/yr, months/yr.

Report the discharge rate as:

During which months? II The maximum daily discharge rate. MGD.

The monthly average discharge rate. MGD The long-term average discharge rate. MGD

4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution.

I1 Ii Ii Ii

.1 I1

. . . - - - . . Z - .. - . . . . . .. . .

.II 263 I

L 3800PM-WSWM0008f Module 3 112004 Applicant Name: PPL Susquehanna, LLC Outfall: 071

.. COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT.

SOURCES OFWASTEWATER  :

L  ;:-' MODULE3 Before completing this form, read the step-by-step Instructions'provided In Appendix 1.

PPL Susquehanna, LLC M 071 Cooling Tower Blowdown

1. Process Wastewater

a. Describe process and type of wastewater.- - -- - - -

Cooling Water Blowdown from Circulating Water and Emergency Service Water (ESW) System operation.

.Includes ESW Pond overflow to blowdown. 4 -

b. Production Rate. Continuous Operation Referring to the Instructions in Appendix 1 for this question, provide the production data as an attachment for each process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

I . Discharge Occurs. 24 hrs/day; 7 dayslwk; 365 days/yr; 12 months/yr.

During which months? All Report the discharge rate as:

The maximum daily discharge rate. (Based on last 3 years) 18.31* MGD l The monthly average discharge rate. (Based on last 3 years) 12.09* MGD The long-term average discharge rate. (Based on last 3 years) 12.09* MGD For batch discharges report:

Number of decant cycles. Cycles/day T Length of each decant cycle. MIN.

Average decant discharge rate. GPM

12. All Other Wastewater Contributing to this Outfall

a. Describe the wastewater.

t Outfall 171 - Liquid Radwaste Discharge to CT Blowdown, 371 Neutralization Basin Internal discharge to Circ Water and 571 Circ Water Pumphouse sump return to Circ Water (Outfall 571 Is requested to be eliminated. See additional Module 3 Information, Outfall 571 description).

- b. Source(s). Volume of Uquid Radwaste discharge 171 to Cooling Tower Blowdown.

c. Discharge Occurs. 0-6 hrs/day; 1-7 days/wk; 60 days/yr, 12 months/yr.

FDuring which months? All Report the discharge rate as:

r The maximum daily discharge rate.

The monthly average discharge rate.

The long-term average discharge rate.

(Based on last 3 years)

(Based on last 3 years)

(Based on last 3 years) 0.049 MGD 0.011 0.011 MGD MGD For batch discharges report:

Number of decant cycles. Cycles/day 264

3800-PM-WSWM0008f 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 071 l Length of each decant cycle. MIN.

Average decant discharge rate. GPM

3. Total Process, Miscellaneous Noncontact Cooling, and SanitaryWastewater 'll

a. Source(s). Cooling Tower Blowdown, ESW Spray Pond over flow and Liquid Radwaste Discharge

b. Discharge Occurs. 24 hrs/day; 7 days/wk; 365 days/yr, 12 months/yr.

During which months? All Report the discharge rate as:

The maximum daily discharge rate. 18.36 MGD -

The monthly averade discharge rate. 12.10 MGD The long-term average discharge rate. 12.10 MGD

4. Stormnwater Complete Module 12 or Module 14 for the stormwater contribution.

• Includes 3% Emergency Spray Pond overflow. See Module 3 additional Outfall 071 description for details. I.

11 21

• .1

- 265 11=111111

L 3800-PM-WSWM0008f 1/2004 Applicant Name: PPL Susquehanna, LLC * --

Module 3 Ouffall: 072 I .. . . .- COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF. ENVIRONMENTAL PROTECTION -

BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT

-SOURCES OF-WASTEWATER

- -- ; MfDlflifl- .

Before completing this form, read the step-by-step Instructions provided In Appendix 1. .

i PPL Susquehanna, LLC 072 S&A Sump

1. ProcessWastewater NWA

a. )Describeprocess and type of wastewater. -

b. Production Rate.' -- - -

Referring to the instructions In Appendix 1for this question, provide the production data as an attachment for each process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

c. Discharge Occurs. hrs/day; days/wk; - days/yr, months/yr.

During which months?

Report the discharge rate as:

The maximum daily discharge rate. MGD r The monthly average discharge rate. MGD I The long-term average discharge rate. MGD F For batch discharges report:

Number of decant cycles. Cycles/day Length of each decant cycle. MIN.

Average decant discharge rate. GPM

2. All Other Wastewater Contributing to this Outfall

a. Describe the wastewater.

Miscellaneous stormwater collected around Emergency Transformers, Diesel Generator oil unloading area and equipment and S&A oil storage area berm downstream of O&G separator.

b. Source(s). Containments around oil containing equipment.

c. Discharge Occurs. 1 hrs/day; dayslwk; 33days/yr; 12 months/yr.

During which months? All

- Report the discharge rate as:

The maximum daily discharge rate. (Based on last 3 years) 0.020 MGD l The monthly average discharge rate. (Based on last 3 years) 0.011 MGD The long-term average discharge rate. (Based on last 3 years) 0.011 MGD For batch discharges report:

Number of decant cycles. Cycles/day Length of each decant cycle. - MIN.

266

II 3800-PM-WSWM008f 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 072 Average decant discharge rate. GPM

3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater -l .

a. Source(s). S&A Sump

b. Discharge Occurs. 1 hrs/day; dayshwk; 33 dayslyr; 12 months/yr. 11 During which months? All Report the discharge rate as: I The maximum dailv discharge rate. 0.020 MGD The monthIv average discharge rate. 0.011 MGD The long-term average discharge rate. 0.011 MGD

4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution. IL

,i A

• ' .Al

.2i -267 A

.1 A

267.1

3800-PM-WSWMD008f 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 - I Outtall: 073 I

COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT SOURCES OF WASTEWATER --

- i...

MODULE 3 .

,A I Before completing this form, read the step-by-step instructions provided In Appendix 1.

-PPL Susquehanna, LLC Ll_ 073 U-1 Transformer Sump

1. Process Wastewater N/A

a. Describe process and type of wastewater.

X. b. Production Rate. - ,, - . , . ',

Referring to the Instructions in Appendix I for this question, provide the production data as an attachment for each process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

C. Discharge Occurs. hrslday; days/wk; days/yr; months/yr.

During which months?

Report the discharge rate as:

The maximum dailv discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. . MGD L For batch discharges report Number of decant cycles. , Cycles/day Length of each decant cycle. MIN.

Average decant discharge rate. GPM l 2. Ail Other Wastewater Contributing to this Outfall

a. Describe the wastewater.

Miscellaneous stormwater collected around U-I Transformer(s), Lube oil storage tank berm, and oil filled circuit breakers downsteam of O&G separator.

b. Source(s). Containments around oil containing equipment.

L c. Discharge Occurs. 1 hrs/day; dayshvk; 18 days/yr; 12 months/yr.

During which months? All Report the discharge rate as:

The maximum daily discharge rate. (Based on last 3 years) 0.032 MGD The monthlv average discharge rate. (Based on last 3 years) 0.008 MGD The lona-term average discharge rate. (Based on last 3 years) 0.008 MGD For batch discharges report:

Number of decant cycles. Cyclestday Length of each decant cycle. MIN.

268

3800-PM-WSWM0008f 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 073 Average decant discharge rate. GPM J

3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater

a. Source(s). U-1 Transformer Sump

b. Discharge Occurs. 1 hrs/day; - dayslwk; 18 days/yr; 12 months/yr. I During which months? All Report the discharge rate as:

The maximum daily discharge rate. 0.032 MGD The monthly average discharge rate. 0.008 MGD The long-term averagqe discharge rate. 0.008 MGD

4. Storrnwater Complete Module 12 or Module 14 for the stormwater contribution.

A

.2' 269 A

11 269

L 3800-PM-WSWMooof Module 3 112004  ; Applicant Name: PPL Susquehanna, LLC Outfall: 074 COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION

- - BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT SOURCES OF WASTEWATER

-MODULE 3 Before completing this form, read the step-by-step'luistructlons provided In Appendix 1.

PPL Susquehanna, LLC B 074 U-2 Transformer Sump

1. Process Wastewater WA

a. Describe process and type of wastewater.

L. b. Production Rate-.'

Referring to the instructions InAppendix 1for this question, provide the production data as an attachment for each process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

c. Discharge Occurs. hrs/day; days/wk; _ days/yr - months/yr.

During which months?

Report the discharge rate as:

The maximum dailv discharge rate. MGD L The monthly averaae discharge rate. MGD The long-term average discharge rate.  ; MGD For batch discharges report:

Number of decant cycles. Cycles/day Length of each decant cycle. MIN.

L Average decant discharge rate. -GPM

2. All Other Wastewater Contributing to this Outfall

a. Describe the'wastewater.

Miscellaneous stormwater collected around U-2 Transformer(s), and lube oil storage tank berm downsteam of O&G separator.

b. Source(s). Containments around cil containing equipment.

c. Discharge Occurs.' 1 hrs/day; days/wk; 22 days/yr, 12 months/yr.

During which months? All Report the discharge rate as:

The maximum dally discharge rate. (Based on last 3 years) 0.016 MGD The monthly average discharge rate. (Based on last 3 years) 0.007 MGD

- The long-term average discharge rate. (Based on last 3 years) 0.007 MGD For batch discharges report:

_ Number of decant cycles. Cycles/day Length of each decant cycle. MIN.

270

aL-3800-PM-WSWM000Sf 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 074 I, I II, Average decant discharge rate. GPM J iiL

3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater

a. Source(s). U-2 Transformer Sump - -

.I

b. Discharge Occurs. 1 hrs/day days/wk; 22 days/yr; 12 months/yr.

A During which months?. All Report the discharge rate as:

The maximum daily discharge rate.

The monthly average discharge rate.

0.016. MGD 0.007 MGD ii The long-term average discharge rate.

4. Stormnwater 0.007 MGD Il Complete Module 12 or Module 14 for the stormwater contribution.

':i A

Il Il Ii Il Ii I

I I1

.1 Ii 271 ]1

L 3800-PM-WSWMOOO8I 112004 Applicant Name: PPL Susquehanna, LLC LModule 3 Outfall: 075 L~e --

CMM O NWE'ALTH O"F,PENNSYLVANIA 6.

DEPARTMENT OF ENVIRONMENTAL PROTECTION UREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT SOURCES OF-WASTEWATER MODULE 3 IBefore completing this form, read the step-by-step Instructions provided In Appendix I.

I ~ PPL Susquehanna LLC JU AI B075 Peach Stand Pond I 1. Process Wastewater N/A a.. Describe process and type of wastewater.

~~b. Production Rate.

Referring to the instructions InAppendix 1 for this question, provide the production data as an attachment for each process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

c. Discharge Occurs. hrs/day; - days/wk;........ days/yr; months/yr.

During which months?

Report the discharge rate as:

The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:

Number of decant cycles. Cycles/day ILength of each decant cycle.

K2.

MIN.

Average decant discharge rate. GPM All Other Wastewater Contributing to this Outfall N/A

a. Describe the wastewater.

Lfb. Source(s).

C. Discharge Occurs. hrs/day;~ dayslwk;- days/yr;- months/yr..

During which months?

Report the discharge rate as:

The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD Frbatch discharges report:

Number of decant cycles. - Cycles/day TLength of each decant cycle. MIN.

LAverage decant discharge rate. GPM 272

3800-PM-WSWMW08f 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 075 'A

3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater

a. Source(s). Stormwateronly

b. Discharge Occurs. hrs/day; days/wk; days/yr; months/yr.

During which months?

Report the discharge rate as:

The maximum daily discharge rate.

The monthly average discharge rate.

MGD MGD A

4.

The long-term average discharge rate.

Stormwater MGD

.i Complete Module 12 or Module 14 for the stormwater contribution.

IL II I

I i]

I Ii Ii Ii Ii 273 II I

3800-PM-WSWM0008 1/2004 Applicant Name: PPL Susquehanna, LLC Module S Outfall: 079 COMMONWEALTH OF PENNSYLVANIA .

DEPARTMENT OF ENVIRONMENTAL PROTECTION ---

BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT SOURCES'OF WASTEWATER -

i..;:MODULE 3

Before completing this form, read the step-by-step Instructions provided In Appendix 1.

+1 j PPL Susquehanna, LLC

. -. 079 Sewage Treatment Plant

1. Process Wastewater N/A ,, . .'

L a. Describe process and type of wastewater.

L b.Production Rate.

Referring to the instructions in Appendix 1 for this question, provide the production data as an attachment for each process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

L c. Discharge Occurs. hrs/day; days/wk; dayslyr; months/yr.

During which months?

L Report the discharge rate as:

The maximum daily discharge rate. .; MGD The monthly averane discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:

L Number of decant cycles. Cycles/day.

Length of each decant cycle. MIN.

L Average decant discharge rate. GPM

2. All Other Wastewater Contributing to this Outfall L a. Describe the wastewater.

Sanitary wastewater effluent from extended aeration sewage treatment plant L b. Source(s). Gravity Collection System and Grinder Pump Stations

c. Discharge Occurs. 24 hrs/day;, 27 days/wk; 365 days/yr; 12 months/yr.

During which months? All Report the discharge rate as:

The maximum daily discharge rate. (Based on last 3 years) 0.069 MGD The monthly average discharge rate. (Based on last 3 years) 0.025 MGD The long-term average discharge rate. (Based on last 3 years) 0.025 MGD L For batch discharges report:

Number of decant cycles. Cycles/day Length of each decant cycle. MIN.

Average decant discharge rate. GPM 2 274

3800-PM.WSWM0008f 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 079

'IIaIL

3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater

a. Source(s). Sewage Treatment Plant Effluent.

b. Discharge Occurs. 24 hrs/day; 7 days/wk; 365 days/yr; 12 months/yr.

Report the discharge rate as:

During which months? All if The maximum daily discharge rate. 0.069 MGD The monthly average discharge rate.

The long-term average discharge rate.

0.025 MGD 0.025 MGD if1

4. Stormwater Complete Module 12 or Module 14 for the stormwater contribution.

ill It 1

.4

.1 It II II

-I 275 Ii Ii

3800-PM-WSWM0008f .12004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 080 COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTlON BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT SOURCES OF WASTEWATER Z'..MODULE 3 Before completing this form, read the step-by-step Instructions provided In Appendix 1.:

PPL Susquehanna, ULC 080 0-1 Pond

1. Process Wastewater -- N/A

a. Describe process and type of wastewater.

b. Production Rate.

Referring to the Instructions in Appendix 1 for this question, provide the production data as an attachment for each L process contributing wastewater to this outfall. The most recent 5 years of production data must be provided.

c. Discharge Occurs. hrs/day; days/wk; days/yr - months/yr.

During which months?

Report the discharge rate as:

The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The lona-term average discharge rate. MGD For batch discharges report:

Number of decant cycles. Cycles/day Length of each decant cycle. MIN.

_ Average decant discharge rate. GPM

2. All Other Wastewater Contributing to this Outfall N/A

a. Describe the wastewater.

i b. Source(s).

c. Discharge Occurs. hrs/day; days/wk; days/yr; months/yr.

During which months?

Report the discharge rate as:

The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The long-term average discharge rate. MGD For batch discharges report:

Number of decant cycles. Cycles/day

_ Length of each decant cycle. MIN.

Average decant discharge rate. GPM 276

3800-PM-WSWM0008f 1/2004 Applicant Name: PPL Susquehanna, LLC Module 3 Outfall: 080

3. Total Process, Miscellaneous Noncontact Cooling, and Sanitary Wastewater

a. Source(s). Stormwater only

b. Discharge Occurs. hrs/day; days/wk; days/yr;- months/yr.

During which months?

Report the discharge rate as: -I The maximum daily discharge rate. MGD The monthly average discharge rate. MGD The Tong-term average discharge rate. MGD

4. Stormnwater Complete Module 12 or Module 14 for the stormwater contribution.

If If

. I II

.I

.1 11

. -I I1

.11 277 I A

ADDITIONAL INFORMATION FOR MODULE 3 ADDITIONAL OUTFALL DESCRIPTIONS 070 - The S-2 Pond, located on the South side of the Susquehanna SES site, is a storm water runoff outfall (SWRO). This SWRO outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may also contain small amounts of chlorine, which will dissipate upon mixing with storm water in the pond, before'the discharge reaches Lake Took-a-while. Due to the similarity of this outfall and Outfalls 075 and 080, only Outfall 075 was sampled for this NPDES permit application.

071 - Cooling Tower Blowdown includes input from the Unit 1 and Unit 2 Cooling Towers, internal discharges, and Emergency Spray Pond (Spray Pond) overflow, and other miscellaneous water. The Cooling Towers and Spray Pond contain river water used for cooling station main condensers and heat exchangers. Spray Pond discharge is based on pond level, and is dependent on make-up to the pond and rainfall.

Assuming an estimated Spray Pond discharge of 250 gpm (0.36 MGD) and an average two-unit Cooling Tower discharge of 8,333 gpm (12-MGD), then the pond discharge adds only an additional 3.0% to the station blowdown. This amount however, is not captured in the blowdown flow recorders located upstream of the Spray Pond.

Therefore, it may be more accurate to revise the permit to require an Estimated Flow and not Recording Instrumentation for Outfall 071. We will continue to provide recorded readings from blowdown excluding the additional 250 gpm from the Spray Pond.

Turbulence and river debris in the blowdown line downstream of the Spray Pond discharge have made flow recorders inoperable.

Evaporative losses in the Cooling Towers generally result in the cooling water being cycled 3 to 5 times the concentration of river water. Cooling Tower Basins each contain approximately 7 million gallons of water and the Spray Pond 25 million gallons.

In order to reduce fouling and corrosion in the Service Water and Circulating Water Systems, PPL utilizes a chemical treatment program. Chemicals included'in present.

and proposed treatment are listed in Module 1 / Item #7 / Section a., "Information and Analysis of Effluent Quality," in this permit renewal application.

By definition closed cooling systems are not routinely discharged to the environment.

When maintenance is performed on these systems, batch discharges can be directed to the Cooling Tower blowdown (Outfall 071), Sewage Treatment Plant (Outfall 079), or other storm water outfall as described in this permit application. The following Table 1, lists Station Closed Cooling Systems and volumes.

278

TABLE1 CLOSED COOLING SYSTEMS SYSTEM SYSTEMS NO. OF SYSTEMS VOLUME (gal)

Units 1 & 2 Reactor Building Closed Cooling Water 2 4,750 ii Units 1 & 2 Turbine Building - 2 1,130 Closed Cooling Water Units 1 & 2 Common Gaseous 3 3,080 Radwaste Recombiner Closed Cooling Water Units 1 & 2 Reactor Building 2 4,750 Chilled Water Units 1 & 2 Turbine Building 2 6,200 Chilled Water.

Temporary Drywell Chiller 550 Learning Center Closed Cooling 1 650 Water Loop Control Structure Chilled Water 1 1,200 Radwaste Building 1 860 Chilled Water A-D Emergency Diesel 4 710 Generator Jacket Cooling Water E Emergency Diesel Generator 1 1,500 Jacket Cooling Water 27 279 ii

To date, no Zebra mussels or Asiatic clams have been found in the river near the Susquehanna SES. Zebra mussel young were'observed during years past in the Johnson City, New York area,'about 150' miles upriver. Asiatic clam adults have been observed in the river near'Bloom'sburg, Pennsylvania, approximately 18 miles downriver from Susquehanna SES. In2001, a single Asiatic clam was'collected from a heat' exchanger within'the-plant,' however since"that tirie no additional Asiatic clams have.

been found. '

If such species do eventually impact'th' plant, PPL plans'to utilize a non-oxidizing biocide listed in Module 1, Item #7, to periodically eliminate these mollusks from the plant intake piping as well as the Cooling Tower and Spray Pond. This material will be added over a 12-24 hr. period at a frequency of 2-4 times or as needed annually. This biocide will be detoxified with bentonite clay, which will be continuously added to the Cooling Tower Blowdown Line during treatment.' The bentonite clay absorbs the' biocide,'deactivating the biocide. Ext isiv6'studies'of the biocide and its detoxified by- A-products have been conducted by the vendor and MSDSs for these products are,,,,

attached as additional information to Module 1.- -

During refueling outages Cooling Tower basin' sediment is removed and dewatered by xX '

belt filter press. A flocculant is used to enhance the dewatering process. The filtrate from the dewatering process is discharged to the Cooling'tower blowdown' line. The dewatered sediment is currently transported offsite'for disposal.

PPL Susquehanna, LLC has received PaDEP approval to dry Cooling and Spray Pond sediment onsite as a coproduct. This coproduct can be used to control site erosion -

and/or support warm season grasses on PPL lands in the vicinity of the Susquehanna SES. Runoff from the sediment may enter the SWROs, however, this additional runoff would be negligible compared to present site runoff volume. To date we have not utilized this option to dry cooling tower' and spray pond sediment.

Included in the Cooling Tower Blowdown is miscellaneous wastewater such as tanker discharges of rainwater from the Condensate Storage Tank b'ermed areas, water from:

clean system drains in the Radiological Controlled Area (RCA) and peripheral facilities associated with the station and also mop water collections near the RCA exits'100 - 300 gal/week. ' ' '

During periodical maintenance (or malfunctions) at the River Intake Structure screen wash water may be retumed temporarily to the river from the Debris Handling Pit. This occurs infrequency and is recorded in station `op6rating logs, work orders and tracking records as appropriate. Previous occurrences have been evaluated as non-impacting, (i.e. no detrimental chemicals are added at the Intake Structure) and were reported to the PaDEP in DMR cover letters for information only. For consistency these occurrences will be noted in our operating records and the PaDEP notified only if deleterious affects on the environment are suspected in accordance with appropriate sections of the NPDES Permit.

280

During operation of the Clarified Water System, which uses river water makeup, (typically used. only during outages to augment well water use) there is a minimum flow .

of clarified water (approximately 150 gpm) back to the circulating water system to maintain consistent clarifier operation., This clarified water has no impact of circ water I

as min flow or as pumped out of the clarified during shut down. It is clean water typically <2.0 NTUs. Solids removed as underflow during'clarifier operation are collected and removed for offsite disposal. Filter backwash water is retumed/recycled A

to the clarifier inlet for treatment. Following clarifier shutdown low volume waste is pumped to the neutralization basin (Outfall 371) for processing prior, to discharge.

INTERNAL OUTFALLS A 171 - Liquid Radwaste discharge includes leakage and wastewater from the radiologically controlled area and the in plant chem lab. Prior to combining with Outfall at 071, this wastewater is passed through various treatment processes to reduce the concentration of radioactive materials. Approximately 90% of liquid radwaste are, treated by one of two processes: filtration followed by ion-exchange demineralization, or ion-exchange demineralization followed by microstraining.

Approximately 10% of liquid radwaste is processed through the laundry drain system, which receives wastewater from equipment washdown stations and personnel decontamination facilities in the radiologically controlled area. PPL-supplied clothing is sent to an outside contractor for cleaning. Miscellaneous wastes discharged through this system also include service water leakage, mop water from cleaning,'and leakage from various pumps and valves. This water passes through microstraining filters 'prior to sampling for discharge.

A 271 - Waste Filter Bypass was previously eliminated from this NPDES permit since it is no longer in operation.

371 - Neutralization Basin internal discharge includes inputs from the demineralizer rinse water, chemical waste inputs from Circulating Water Pumphouse Building equipment and floor drains and clarifier sludge holdup sump decant water. There are two neutralization basins each with a capacity of approximately 18,000'gallons. The '

basins are used alternately and the contents are air sparged, recirculated, and sampled prior to being directed to the suction side of the circulating water pumps. l 471 - Waste Filter was previously eliminated from this NPDES permit since it is no longer in operation. '

281 Al

571 - Request elimination of the Circ'ulating Water Pumphouse Building sump outfall from the NPDES permit sinceIIt receives only circulating water and seal water (well water) from circ water/service water pump operation and Is not impacted by station operation'. This sunmp autromatically pumps to the circulating water system suction and is correctly hicld'd 'Within the limits' of the cooling tower system operation.' Historic monitoring has only'documented elevated solids during river water makeup turbidity excursions'during periods'of high river solids (reference attached August 2003 DMR Letter PLE-0023359 dated September 16, 2003). It does not meet the definition of Low Volume Waste; it is miscellaneous cooling water that should not require monitoring. ' i -

072 The Service and Administration (S&A)' Sump receives stormwater from the emergency start-up transformer ben'hed'areas', the'diesel -generator oil unloading areas and equipment, and S&A Oil Storage bermed area. The sump contains two cells, each with approximately 10,000-gallon capacity. 'An oil and grease separator is provided upstream of the sump to remove any fuel or transformer oil leakage.: Request reduction In the monitoring frequency of this outfall to be consistent (currently quarterly) with outfalls 073 and 074 below. Adequate controls, treatment, and visual confirmation are in place. Historical monitoring at increased frequency for a long period of time has consistently shown minimal oil & grease and total suspended solids and has not indicated any challenges to the monitored parameters.

073 - Unit 1 Transformer Water Sump collects stormwater from the transformers, turbine lube oil, and oil circuit breaker bermed areas. This sump has two cells of approximately 8,100 gallons each. The storm water collected in this sump passes through an oil and grease separator prior to entering the sump and is visibly inspected prior to discharge.

074 - Unit 2 Transformer Water sump is similar to Outfall 073. It collects stormwater from the Unit 2 transformers and lube oil storage tank berm. Due to the similarity between these outfalls only Outfall 073 was sampled to represent this discharge for the NPDES permit renewal application.

075 - The Peach Stand Pond is a SWRO that collects and conveys runoff from North drainage area including site sumps and buildings. This outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may contain small amounts of chlorine, which will dissipate upon mixing with storm water before entering Lake Took-a-while.

Discharge from this outfall goes into Lake Took-a-while located east of US Route 11.

Because this outfall and Outfalls 070 and 080 are similar, only this outfall was sampled for this NPDES permit renewal application.

282

079 - The Sewage Treatment Plant (STP) is designed to treat 80,000 gallons per day of sanitary wastes from the gravity collection system onsite and from grinder pump stations at the Learning Center, Riverlands Recreation Area, Environmental Lab, West Building, and Vehicle Maintenance Garage.-, In certain circumstances discharges from various sumps and drains may be routed.to the Sewage Treatment Plant to meet NPDES permit limits.. Sanitary wastes may contain small amounts of miscellaneous waste water, cleaning agents, and other chemicals. Material Safety Data Sheets for i

these chemicals recommend treatment at STPs prior to discharge (Susquehanna River).

080 - The C-1 Pond is a SWRO outfall located in the Central Drainage Area just East of the station's protected area. This outfall may contain occasional discharges of clarified water, demineralized water, well water, fire protection water, and other miscellaneous water. These discharges may contain small amounts of chlorine, which will dissipate upon mixing with storm water before entering Lake Took-a-while. Due to the similarity of this outfall and ouffalls 070 and 075, only Outfall 075 was sampled for this permit application. A

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283 A

September 16, 2003 ppI .#zy A L

Ms. Kate Crowley Water Quality Regional Manager L_ Bureau of Water Quality Management Pennsylvania Department of Environmental Protection Two Public Square Wilkes-Barre, PA 18711-0790 SUSQUEHANNA STEAM ELECTRIC STATION DISCHARGE MONITORING REPORT -AUGUST 2003 ,

NPDES PERMIT NO. PA 0047325 PLE - 0023359

Dear Ms. Crowley:

Pursuant to Part A,3.b.(I) of NPDES Permit No. PA 00477325, enclosed is the Susquehanna Steam Electric Station (SES) Discharge Monitoring Report (DMR) for August. Also enclosed is the Monthly Facility Report Form (01-1 12).

On August 13, 2003 a total suspended solids excursion (191.1 mg/L) occurred at the circulating water pumphduse sump (internal outfall 571) due to elevated Susquehanna River turbidity from significant rainfall events. Although there are no solids limits on circulating water (cooling water) a given amount of circulating water typically passes through the circulating water pump seals contributing to sump solids levels whenever river solids are elevated. Additional sump samples collected by the end of the month resulted in the monthly average permit limit for this internal outfall being met.

- If you have any questions, please call Curt Saxton (570) 542-1879 or Jerrold McCormick at (570) 542-3014.

- Respectfully yours, David J. Moan/

Sr. Staff Engineer/Scientis CHS/raa Enclosure I - August 2003 DMR (8 pages)

Enclosure 2 - Monthly Facility Report Form (1 page)

_ Copy to:

Ms. N. Green, EPA Region III 284

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1 3800- SW9 I. -j 117F-- I- F-- I -- F7 f7- I[ F- F-- Ar i- Name PPL S--

Applicant Name: PPL Susquehanna, LLC LL Module 4 COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 MDL 4lhiFA Before completing this form, read the step-by-step Instructions provided In Appendix 1.

___ PPL Susquehanna, LLC - -

o Outfall Number (Show location of sampling point on Line Drawing) 0intake Sampling Results - Optional (Specify Source: Susauehanna River) -

OD Background Sampling ResuIts Optional (Specify Location of Sample: -,...- J l Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing)

- New Discharge (Basis for Information: .

- Bypass or Sewer System Overflow (Describe: )

1. LEVEL PRESENT -- - - - 2. UNITS 3.

- Coefficient POLLUTANT GROUP 1 of Effluent

- a. Maximum Daily Value - b. Average of Analysis . . a. Vrbit

_.'x,_______________ .... '(1) Concentration - (2) Mass (1) Concentration (2)Mass Analysis Concentration - .- b. Mass- - - (CV)

Biochemical Oxygen Demand, BOD ... 33 - . .

• 26 . 3 - ma3.

Chemical Oxygen Demand, COD--- - 15.3 3 .mg/l n_.. .

Hardness (CaCO 3 ) - - 107 89.43 mg/l . - .

Total Suspended Solids, TSS - - 45

• 22.3 3 man Total Dissolved Solids, TDS - 208- -- 173 3 mg/i Ammonia as N. - - --. 1____0 .-- _g_-

_3 Nitrate-Nitrite (as N) .67 7- 3 mg/i .

Total Kjeldahl Nitrogen (TKN) ND ND 3 mg/i Phosphorus(asP), Total ND N.- - ---- 3 mg/I Temperatire wiAnter Value or 23 Value Numerous (C)

Temperature summer 28.9° Value 23 Value Numerous (6c) , _

pH . _ Mi . - 7.39 Max. 8.32 3 Standard units Standard units 1.a.- Maximum Daily Value - Report the hlahest daily value or daily average value from the last year of data. Repor both mass and concentrailon.  ;

1.b. Average of Analysis- The average of all values within the last year and report both the mass and concentration. -

I.c. A minimum of 3 Sampling Events riquired for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and background. - -

- . '  : -' -'1-

3800-PM-WSWM0008g 1/2004 Module 4 Applicant Name: PPL Susquehanna, LLC

3. Level Present _

POLLUTANT GROUP 1 1.MDL 2. EPA S. CoefficWent a.Max Daily Value b. Averageof Anoalysis Believed Used Method c. 4. Uni s of Effluent Absent (ug/L) Number Used Concentration Number of Variability Mass Concentration Mass Color Analysis ConcentratIon Mass O 5 SM18-2120B 40 (CV)

Fecal Coliform 35 3 CU O -

Fluoride O 100 300.0 .12 0.07 3 mg/i Oil and Grease El 2200 1664 ND ND Bromide 3 mg/O O 300 300 ND ND 3 Chlorine, Total Residual [l 50 330.1 ND ND mg/I __ ____

SulfateI 5 1000 300.0. - 37.2 22.4 3 mg/I Sulfide 3 mg/l El 1000 376.1 ND ' No Suifite. 5 3 mg/I 2000 377.1 2.0 .67 3 mg/I Surfactants [ 25 SM18-5540C .057 .019 3 mg/I Aluminum, Total 50 so 200.7 .65 .31 3 mg/I Barium, Total 10 200.7 .033 .030 3 mg/I Boron, Total O 50 200.7 .19 .06 3 mg/l Cobalt, Total ' 3 200.7 ND ND 3 mg/I Iron, Total O 30 200.7 1.23 .78 3 mg/i Iron, Dissolved 5 60 200.7 .13 .06 3 mg/I Manganese, Total O 3 200.7 .092 .087 3 Radioactivity GR-A 5 1.55 900 ND ND mg/I Total Organic Carbon, TOC 3 pCI/I 5 1000 SM185310B 3.6 2.5 Radioactivity GR-B 3 mg/I O 2.36 900 4.90 1.63 33 pCI/I Magnesium O 50 200.7 7.83 _ 6.16 3 Molybdenum 5 10 200.7 ND ND mg/I Tl, Total 3 mg/I 10 200.7 ND .N 3 mg/l Titanium, Total 5 10 200.7 .01 .003 3 mg/I

3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 3.a. Maximum Daily Value - Report the highest daily value 5.

or daily average value from the last year of data. Report 3.b. Average of Analysis - Determine the average of all samples both mass and concentration.

taken within the past year. Report both mass and concentration.

3.c. - A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling background. Event for all other discharges, treatment facility Influent, Intake water and IIt is In the applicants Interest to achieve the lowest level number of effluent limits and/or monitoring requirements of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential In the final NPDES permit. for establishing a large

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Module 5 A;pplicant Name: PPL Susquehanna, LLC COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTiON BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 2 Before completing this form, read the step-by-step Instructions MODULE 5 provided In Appendix 1.

PPL Susquehanna, LLC El Outfall Number_ (Show location of sampling point on Line Drawing) 21 Intake Sampling Results - Optional (Specify Source: Susauehanna River) o Background Sampling Results - Optional (Specify Location: )

o Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing) o New Discharge (Basis for Information: )

0 Bypass or Sewer System Overflow (Describe: )

POLLUTANT GROUP 2 3.Level Present 1; MDL S.Coeficient a.Max Dal Value b. Average of Analysis c.

Metals Used* 2. EPA Method 4. Units of Effluent 0.a) Number Used Concentration Number of Variability Mass Concentration Mass Analysis Concentration IM Antimony, Total 10 200.7 Mass (CV)

ND ND 3 2M Arsenic, Total mg/I 4 200.7 ND ND 3 mg/I 3M Beryllium, Total 3 200.7 ND. ND 3 mg/I 4M Cadmium, Total 1 200.7 ND ND 3 5M Chromium IlI mgoI 1 200.7 ND ND 3 mg/I .

SM Chromium VI 10 SM18-a500-CrD ND ND 3 6M mgi Copper, Total 10 200.7 .016 .015 3 7M mg/I Lead, Total . . 3 200.7 ND ND 3 8M mg/I Mercury, Total . .2 245.1 ND ND 3 mg/I 9M Nickel, Total . 10 200.7 ND ND 3 mg/I 10M Selenium, Total - 200.7 ND ND. 3 mg/I liM SilverTotal - -- 2 --200.7  :, D N N D 3 mg/I .

3. If other data Isavailable (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determnine the average of all samples taken within the past year. Report both mass and concentration.

3.0. Aminimum of 3 Sampling Events required for process wastewater discharges, and amlinimum of 1 Sampling Event for all other discharges, treatment It is In the applicants Interest to achieve the lowest level of detectlon facility Influent, Intake water and background.

number of effluent limits and/or monitoring requirements Inthe final NPDES possible. This will minimize uncertainty and therefore the need for additional analysis permit. or potential for establishing a large

i-;1-.

3800-PM-WSWM0008h 1/2004 Applicant Name: PPL Susquehanna, LLC Module 5

3. Level Present POLLUTANT GROUP 2 5. Coefficient

1. MDL 2. EPA a. Max Dali Value b. Average of Analysis c. 4. Units of Effluent Metals Used* Method Number of Variability

• Number Used Concentraton Mass Concentration Mass Analysis Concentration Mass (CV) 12M Thallium, Total 10 200.7 ND ND 3 mg/I 13M Zinc, Total 5 200.7 .028 .026 3 mg/i 14M Cyanide, Total 5 335.3 ND ND 3 mg/i 14M Cyanide, Free - _5 SM4500CNI ND ND 3 mg/I 15M Phenols, Total. 5 420.4 ND ND 3 mg/ _ _

3. - If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a! 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and background.

• It Is In the applicant s Interest to achieve the lowest level of detection possible. This will minimize Uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit.

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3800-PM-WSWM00681 F - [-

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Applicant Name: PPL Susquehanna, LLC Module 6 COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 3 MODULE 6 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

~ PPLSusquehanna, LLC a Outfall Number (Show location of sampling point on Line Drawing)

IIntake Sampling Results - Optional (Specify Source: Susauehanna River)

O Background Sampling Results - Optional (Specify Location: J O Treatment Facility Influent Sampling Results (Show location of sampling point on LUne Drawing)

. New Discharge (Basis for Information: ,.- -

O Bypass or Sewer System Overflow (Describe: )

POLLUTANT GROUP 3 -- 2.EA3. Level Present .. - 5 Coefficient

- . 1. MDL Method a. Max Dall Value b. Average of Anal'sis C. 4. Units of Effluent Volitales - Used' Number _ . Number at .o..f . -.

_ Varlabillty -

- - .&-.*.. - -- - Used ' Concentration Mass ConcentratIon Mass Analysts Concentration Mass (CV).

IV Acrolein ..... 20._.. 624 -- N D ----- ND' 3 ug-2V Acryloitnile _4 .24 ---- NDO-. - NO 3 ugh ____

3V Benzene 1_ ,... 624:..- - ND,

-ND 3 ugf: .

5V Brorrnoform . 1 624 ND ND 3 ug/i-6V Carbon Tetrachloride 1 - 624 ND ND 3 ug/I 7V Chlorobenzene -1 624 ND ND 3 ug.

8V Chlorodibromomnethane - 1 624 '.'ND ND 3 ug _

0 9v Chloroethane. - 1 624 'ND', ND 3 ug/ _ _

10V 2-Chloroethylvinyl Ether-- 2 624, N ND- 3 ug/ _

3.' It other data Isavailable (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maxmurn Daily Value -. Report the fl!gftj'daiiy~value or daiiy average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass'and conce6ntration.

3.c. - A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and background. .

• it Is In the applicanrs Interest to achieve the lowest level of detectilon'possible' 'This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits andlor monitoring requirements In the final NPDES permit. '

3800-PM-WSWM0008I 1/2004 Module 6 Applicant Name: PPL Susquehanna, LLC POLLUTANT GROUP 3 2. EPA

3. Level Present

1. MDL Method a. Max Dal Value 5. Coefficient

b. Average of Analysis c. 4. Units Volitales Used' Number of Effluent

. .(gL) Used Concentration Number of Variability Mass Concentration Mass Analysis Concentration 11V Chloroform 1 Mass . (CV) 624 ND ND 3 ug/l_.

12V Dichlorobromomethane 1 624 ND ND 3 ugA 14V 1,1-Dichloroethane 1 624 ND ND 3 ug/l 15V 1,2-Dichloroothane 1 624 ND ND' 3 ug/l 16V 1,1-Dichloroethylene 1 624 ND! ND 3 ughI _

17V 1,2 Dichloropropane 1 624 ND ND 3 ug/l 18V 1, 3-Dichloropropylene 2 624 ND ND 3 ug/l 19V Ethylebenzene 1 624 ND ND 3 ug/l 20V Methyl Bromide. - - 624 ND ND 3 u/gh 21V Methyl Chloride .1 624 . ND ND 3 ug/l 22V Methylene Chloride 2 624 ND ND 3 ug/l 23V 1,1,2,2-Tetrachloroethane 1 624 ND ND 3 ug/l 24V Tetrachloroethylene 1 624 - ND ND 3 ughl . -

25V Toluene 1 624 ND ND 3 ug/!

26V 1,2-Trans-dichloroethylene 624 ND ND 3 ugh 27V 1,1,1-T -'-norocthana 1 624 ND ND 3 ug __

28V .1,1,2-Trichloroethane 1 624 ND ND 3 ug/l 29V Trichloroethylene 1 624 ND ND 3 ug/!

31V Vinyl Chloride 1 624 ND ND 3 ug/l

3. 11other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the hiahest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment background. facility Influent, intake water and It is in the applicants Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional number of effluent limits and/or monitoring requirements in the final NPDES analysis or potential for establishing a large permit.

N 0

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7 [ [7 I1. I r 38O0f1 SWl iIU- [7 F- 17 X- [77 FT [7 it7 F-- plilcant Name: PPL Susquehanna, LLC Module 7.

COMMONWEALTh OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 4 MODULE 7 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

J PPL Susquehanna, LLC El Outfall Number (Show location of sampling point on Une Drawing) -

- ' ' Intake Sampling Results - Optional (Specify Source: Susavehanna River)

El Upstream Background Sampling Results - Optlonal (Specify Locatl6n: . . - - -- :

a Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing)

E New Discharge (Basis for Information: )

o Bypass or Sewver System Overflow (Describe: - -)

- 3'. Level Present POLLUTANT GROUP 4 ... EPA 5. Coefficient

1. MOL Method - a. Max Dali Value b. Average of Analysis C.' 4. Units of Effluent

-Acid Compounds Used' Number . Number of . . Variability -

- Wseiocnrtion Mass.- Concentration , .Mass- - Analysis Concentration Mass *j ) =

1 A?2--Chlorophenol - - 10:1 1 625 ND ----.- - - D ~ rI 3. ug h' 2A- 2,4-Dchlorophenol ' 10'_ -625- - D- ND.. _ u - -- -u - -

3A' 2,4 Dimethylphenol - -- - 10. ' 625 - ND ND: .- - . 3 - - ugh  : ____

4A 4,6-Dlnitro-o-cresol ' 19 625 ND - ND 3 ugI_

5A- 2,4-Dinitrophenol - 24 625 ND ND 3 ug__

6A 2-Nitrophenol

• 10 625 - ND - ND 3 ug 7A 4-Nitrophenol 11 625 ND- ND 3 ugA_

8A P-chloro-m-cresol - -- 10 625 ND ND 3 ugA_

9A Pentachlorophenol 24 625 ND ND 3 ugA 10A Phenol , 10 625 ND. ND 3 ug_

11A 2,4,6-Trichlorophenol 10 625 'ND ND 3 ugh

3. If other data Isavailable (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daffy Value - Report the highest daily value or dafly average value from the last year of data. Report both mass and concentratlon.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatrmeuit facility Influent, Intake water and background.

It Is In the applicanrs Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits andlor monitoring requirements In the final NPDES permit.

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Module 8 Applicant Name: PPL Susquehanna, LLC COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 5 MODULE 8 Before completing this form, read the step-by-step Instructions provided InAppendix 1.

KE gW PPL Susquehanna, LLC EJ Outfall Number - (Show location of sampling point on Une Drawing)

El Water Supply Sampling Results - Optional (Specify Source: Susauehanna River)

O0 Background Sampling Results - Optional (Specify Location:

)

ol Treatment Facility Influent Sanmpling Results (Show location of sampling point on Line Drawing) o New Discharge (Basis for Information: )

- 0 Bypass or Sewer System Overflow (Describe: )

POLLUTANT GROUP 5 2. EPA

____ ____ ___ 3. Level Present _ _ _ _ _ _

b.Annual Average of

1. MDL Method 5. Coefficient

a. Max Daly Value Anal sis

- Base Compounds. Used, Number

c. 4. Units of Effluent (0/1) Used Number of Variability Concentration Mass Concentration Mass 1B Acenaphthene Analysis Concentration Mass (CV) 3 625 ND ND 2B Acenaphthylene 3 Pg/L 3 625 ND ND 38 Anthracene 3 Pg/9 2 625 ND ND 4B _13 u1g.L _

Benzidine 19 625 ND ND 5B Benzo(a)anthracene 2 3 Pg/ _

625 ND ND 6B Benzo(a)pyrene 3 _9_

2 625 ND ND 7B 3,4-Benzofluoranthono - 3 I_

2 625 ND ND 8B Benzo(ghlperylene 2 3 pg-625 ND ND 9B Benzo(k)fluoranthene 3 jg/I-2 625 ND ND 10B Bls(2-Chloro-ethoxyrmethane 3 jg/I 3 625 ND ND 11B Bis(2-Chloroethyl)ether - 3 pig/L 3 625 ND ND 128 Bis(2-Chloro-isopropyl)ether 3 1I 2 625 ND ND 13B BIs(2-Ethy/haxynphthalate 3 PigL N0 2 625 ND ND 14B 4-Bromophenyl Phenyl Ether 3 Pg N 3 625 ND ND 3 15B Butylbenzyl Phthalate pg/-L 5 625 ND ND 16B 3 PAlL 2-Chloronaphthalene 5 625 ND ND 17B 4-Chlorophenyl Phenyl Ether 3 Pg/IL 5 625 ND ND 3 - __

3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and 3.b. Average of Analysis - Determine the average of all samples taken concentration.

within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of I Sampling Event for all other discharges, treatment facility Influent, Intake water and background.

• It Is In the applicanrs interest to achieve the lowest level of detection possible.

This will minimize uncertainty and therefore the need for additional analysis number of effluent limits and/or monitoring requirements In the final NPDES or the potential for establishing a large permit.

I I IiI 'i.I'

7 Modd.......T--- I- Fr r- f~ V7 fl I- r- 4-antrf---PPL[--eha[-IC I I-POLLUTANT GROUP 5 3. Level Present 2 .Ana vrg EPA a aleo b.MxAnna AveragentsSCefiin

1. MDL Method a.MC.iiytAalss4 Base Compounds Used* Number Uis5 ofEffiuent Number of Variability

• 1aj Used Concentration Mass Concentration Mass Analysis 18B Chrysene Concentration Mass (Cy).....

2 625 ND ND 198 Dibenzo(a,h)anthracene 3 AMIL __________

. 2 625 ND ND 20B 1,2-Dichlorobenzene

______ 3 .Pg/ _____

5 625 ND ND 218

______ 3 PgIL 1,3-Dichiorobenzene 5 625 ND Pg/ 1 22B

-ND

. 3 1,4- Dichiorobenzene 5 625 ND

_____ ND 3 . rg/L 23B 3,3-Dichlorobenzldine 10 625 ND . ___ ND~ 3 Pg/

248 Diethyl Phthalate 10 625 ND ND 3 258 Dimethyi Phthaiate

. .jgAip _____

10 625 ND ND 268 Di-n-butyl Phthalate. -

3 . ji/i ___

5 625 ND' ND 278 2,4-Dinitrotoluene

.3 PA/i ____

- 2 .. 625 . ND ND 288 2,S-Dinitrotoiuene

_____ -3 Vg/L _____ _______

2 625 . ND ND 29BDi-n-octyl Phthalate

. -*.3 --pg/i.

5 625 ND ND 30B (as Azobenzena)

.-. 3 - us/i-

-1¶.2-Diphenyihydrazine 5 625 ND ND 31B Fluorantheno..2 3 . pg/i _____

625 ND ND 3 32B Fruorene .

. pg/ ____

-.- 3--625 - ND- __ ND 33B Hexachlorobenzene .3 pgAi __ ___

.- 2.. .625-- ND ND- 3 348 Hexechiorobutadiene i jigi ____

5 S. 625~ .ND -- -- - D----3--~

35B Heanchlorocyciopentadiene 10 625 ND D3, g/i.

36B Hexachloroethane -. 5 625 ND _'

1 ND - 3..

37B ind~eno(1,2,3-c*Wpyene 2 625

.~.P9/i.- -

ND ____ ND _____ 3 Yg/.

38B8Isophorone -3 -- 625, ND. _ _ ND. __ 3 g/L 398 Naphthalene 625

.3 ND ND 408 Nitrobenzene

_____ -3 pg9/i.1- __ _______

3 625 ND ND 41B N-Nltrosodimnethylamnine

______ 3 Pg/.

. ~3 625 ND 42NNitrosodl-n-propyiamine 65ND

-ND ______ 3 pg/i. ____ _______

.3.

- D _____ 3 pgAiL ____

43B N-Nitrosodiphenylamine -3 625 ND _____ NDO ____ 3 prgAiL 448 Phenanthrene 3~. 625 ND ND 3 48Pyrene Ji/i ____

-2 625 ND.,. 3 468 1,2,4-Trichlorobenzene

.*ND _____ Pg/i.

5 625 ND ND

_____ ______ 3 pg/. _____ _______

3.a. Maximum lDaly'Value - Report the hhstdaiiy value or daily average value from the last year of data. Report both mass and 3.b. Average of Analysis - Determine the avorage of ali samples taken within the past year. Report concentration.

minimum of both mass and concentration.

3.c. A 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for ail other discharges, treatment facility Influent, intake water and background.

It IsInthe applicant's Interest to achieve the lowest level of detiction possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements Inthe final NPDES permit.

II 3800-PM-WSWM0008I 1/2004 Applicant Name: PPL Susquehanna, LLC Module 9 COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 6 MODULE 9 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

'WM N PPL Susquehanna, LLC o Outfall Number (Show location of sampling point on Une Drawing) 0 Intake Sampling Results -.Optional (Specify Source: Susauehanna River)

O Upstream Background Sampling Results - Optional (Specify Location: J o Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing) o New Discharge (Basis for Information: J 0 Bypass or Sewer System Overflow (Describe: J

3. Level Present _____

POLLUTANT GROUP 6 .DL 2. EPA 3. 5. CoefficIent

1. MDL Method a. Max Dali Value b. Average of Analysis c. 4. Units of Effluent Pesticides Used' Number Number of Variability WkL) Used Concentration Mass Concentratlon Mass Analysis Concentration Mass (CV) 1P Aldrin 2P Alpha-BHC 3P Beta-BHC . .

4P Gamma-BHC 6P Deita-BHC 6P Chlordane 7P 4,4-DDT  :-

8P. 4.4-DDE -

9P. 4;4-DDD 10P Dleldrin 11P Alpha-endosulfan -

3. If other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, Intake water and background.

It Is in the applicants Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit.

- - - , ~~-

I - - - -

- 3800{ 'SWN 1IU 1I-'

Module 9 F1- 1-I - 1V V'- cantkme: PPLIusqueIlamLLF- I-POLLUTANT GROUP 6 3. Level Present _____

2.EPA

1. MDL Method a. Max Dali Value 5. CoefficIent

b. Average of Analysis c. 4. Units Pesticides Used Number of Effluent 0 fgL)

Used Concentration Number of VarIabilIty Mass Concentration Mass Analysis ConcentratIon 12P Beta-endosulfan Mass (Cy) 13P Enidosulfan Sulfate 14P Endn*_

15P EndrinAldehydo _ _-_-_-.

16P Heptachlor 17P Heptachlor Epoxide . ..

18P PCB-1242 -.96 6-08 ND ND 3 Pg/L 19P PCB-1254 _ .98 608 ND ND 3 'pgIL .-

20P PCB-1221 .' .96- 608 ND ND 3 pg/L 21P PCB-1232 .96 808 ND ND 3 Pg/L_

22P PCB-1248 .96

- 808- ND ND 3 pg/L 23P PO1260 - 1 . -. 96 608 ND - ND- 3 Jpg/L- __

24P PCB-1016 - - -

808 ND' ND- . ;Pg/L3 25P Toxaph-ne_ ._. -ie. . - - . .. .

26P DIOXIN: 2,3,7, 8*Tetrachlorodibenzo-P- .

Dioxin (TCDD) - -

eciERsls - .

3. If other data Is available (i.e., DMR data, etc.). the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest dally value or daily average value from the last year of data. Repor both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1. Sampling Event for all other background. discharges, treatment facility Influent, Intake water and It Is In the applicant's Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for number of effluent limits and/or monitoring requirements In the final additional analysis or potential for establishing a large NPDES permit.

N

'0 0'

3800-PM-WSWM0008g 112004 Module 4 Applicant Name: PPL Susquehanna, LLC COMMONWEALTH OF PENNSYLVANIA Ekep DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 MODULE 4 Before completing this form, read the step-by-step instructions provided In Appendix 1.

PPL Susquehanna, LLC 0 Outfall Number 071 (Show location of sampling point on Une Drawing)

Flows = 6/3, 12.63 MGD, 6/17, 14.58 MGD, & 7/1, 15.38 MGD El Intake Sampling Results - Optional (Specify Source: )

El Background Sampling Results - Optional (Specify Location of Sample:

)

El Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing)

El New Discharge (Basis for Information: )

El Bypass or Sewer System Overflow (Describe: )

1. LEVEL PRESENT

2. UNITS 3.

POLLUTANT GROUP 1 a. Maximum Daily Value CoefficIent b.Average of Analysis

. of Effluent (1)Concentration (2)Mass (1)Concentration (2)Mass

c. No. of a. Variability Analysis Concentration b. Mass (CV)

Biochemical Oxygen Demand, BOD 5.4 573 2.7 338 3 mg/I Chemical Oxygen Demand, COD Ibday 49.0 5960 43.6 5160 3 mg/I lb/day Hardness (CaCO 3) 377 48700 324.0 38400 3 mg/I Total Susps.end Wklds, TSS Ib/day 42 4460 21.3 2520 3 mg/I IbIday Total Dissolved Solids, TDS 696 89300 608.7 72100 3 mg/I lb/day Ammonia as N 1.23 150 .47 55.7 3 mg/I lb/day Nitrate-Nitrite (as N) 2.38 251 1.93 241 3 mg/I lb/day Total Kqeldahl Nitrogen (TKN) 2.20 N - 282 1.63 193 a0 3 mg/I lb/day Phosphorus (as P), Total . 1.01 106 .93 110 3 mg/I Ib/day Temperature winter 13 Value 13 Value Numerous (C)NA Temperature summer 32 Value 29 Value Numerous (C) NA pH Min. 8.58 Max. 8.64 3 Standard units Standard units l.a. Maximum Daily Value - Report the highes daily value or daily average value from the last year of data. Report both mass and concentration.

1.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.

1.c. A minimum of 3 Sampling Events required for process wastewater discharges, background. and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and I _J800J ......SWd_..W'_j ii7 F--. I-- I----- 7 [F 7 F - ApplFc--t Name: PPL Susquehanna, LLC Module 4

3. Level Present

5. CoeffIcIent POLLUTANT GROUP I 1.MDL 2.EPA a.Max Dail Value *b. Average of Analysis C. of4. Units of Effluent BelIeved .Used* Method Number ofVariability

_________________ AsnQ Number Used Concentration Mass Concentration Mass Analysts Concentration Mass Color Q .5 SM18-2120b- 150 70 3 CU _ _

F ocal Colifoarm [E l_ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Fluoride 100 300 .25 30.4 .25 29.6 3 mg/l lb/day Oil and Grease Q 2100 1664 NO NO NDO NO 3 g/ b/day_____

Bromide .Q30 300 1.8 219 1.3 .154. 3 mg/I lb/day ______

Chlorine, Total Residual so5 330.1 ND ND. NDO ND 3 mg/I lb/day_______

Sulfate - E 5000 300 121 15500 96.6' 11400 3 mg/I lb/day ______

Sulfide . 51 1000 376.1 ND ND ND ND 3 mg/I lb/day-Sulfite E]. 2000 377.1 ND ND ND ND 3 mg/I lb/day Surfactants 525- sm18-5540c .145 18.6 .072 8.53 3 -mg/I lb/day

• Aluminum,Total 550 200.7 - 2.93 309 1.26' 149 3 mg/I lb/day______

Barium, Total -i5 0 200.7 -.128 16.4 '.117 13.9 3 mg/I. lb/day______

Boron, Total 550 -200.7 - . .08 - -10.3 -- .07 - 8.29 - 3 -Mg/IC lb/day _____

Cobalt,,Totali1' (  : 5 3 .200.7: .. N---tO ND-, - -ND rNDO 3 rng/I> . lb/daf libn.,Total '.:. 530 200.7' 3.49. 368. ~ 2.17 -3 - mg/I lblday _____

Iron; Dlssblved 5 60 200.7 - .28 - .'29.5 .. 20 . 23.7. 3 mg/I lb/day, -

Manganese. otal - 5 3 200.7 .263 27.7 .198 23.4 -3 mgI lb/day -

Radioactivity GR-A 52.36 900 . ND ND ND ND 3 pCI/I N/A Total Organic Carbon, TOCO 1000 sml8-5310b 10.6 1116 9.2 1090 3 mg/I lb/day ______

Radioactivity GR-B 2.56 900 12.4 W/A 10.7' N/A 3 pCI!

Magnesium - 5. 50. 200.7 27.1 . 3476 21.7 2570 3 mg/ lb/day ______

Molybenum .,. 5 10-. 200.7 ND ND ND ND 3 mg/I lb/day _____

Tin, Total - 510. 200.7 NDO ND .NO ND 3 mg/i lb/day ____

Titanium, total ] I0 200.7 -.03 .*316 -011.18 3 mg/I lb/day ______

.3. If other data Isavailable (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3,.a. Maximum Daily Value - Report the highest daily value or daily average value from the lait year of data. Report both mass and concentration.

3,*b. Average of Analysis - Determine th6 average of all samples taken within'the p'ast ye'ar. Report both mass and concentration.- - -

I.c. A,minimum of 3 Samp~ling Events required for process wastewater discharges, and a minimum of I Sampling Event for all other discharges, treatment facility Influent, Intake water and background.., -

It is In the applicant's lnterest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits andfor monitoring requirements In the final NPDES permit. .

3800-PM-WSWM0008h 1/2004 Module 5 Applicant Name: PPL Susquehanna, LLC COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP.2

- - .MODULE 5 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

" PPL Susquehanna, LLC 0D Outfall Number 071 (Show location of sampling point on Uno Drawing) o Intake Sampling Results - Optional (Specify Source

)

o Background Sampling Results - Optional (Specify Locatlon:

)

o Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing)

El New Discharge (Basis for Information: )

El Bypass or Sewer System Overflow (Descnbe:

)

POLLUTANT GROUP 2 3. Level Present 1.MDL a. Max Daly Value 5. Coefficient Metals b. Average of Analysis c. 4. UnIts Used' 2. EPA Method of Effluent (ug/L) Number Used Concentration Number of Variability IM Antmony, Total Mass Concentration Mass Analysis 10 Concentration Mass (CV) 200.7 ND ND ND ND 3 mg/L lb/day 2M Arsenic, Total 4 200.7 ND ND ND ND 3 mg/L lb/day 3M Beryllium, Total 3 200.7 ND ND ND ND 3 mg/L lb/day 4M Cadmium, Total I 200.7 ND ND ND ND 3 m/L - lb/day 5M Chromium IIl 3 200.7 .003 .32 .001 3 .11 3 mg/L lb/day 5M Chromium VI 10 smlB-3500-Cr-D ND ND ND ND 3 mg/L lb/day 6M Copper, Total 10 200.7 .012 1.25 .008 .947 3 mg/L Ib/day 7M Lead, Total 3 200.7 .005 .-645 .0017 .201 3 mg/L lb/day 8M Mercury, Total .2 200.7 ND ND ND ND 3 mg/L lb/day-OM Nickel, Total 10 200.7 ND ND ND ND 3 mg/L lb/day M Seenium, Total 10 200.7 ND ND ND ND 3 mg/L lb/day l1 M Siver, Total 2 200.7 ND ND ND ND 3 mg/L lb/day

3. If other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a.- Maximum Daily Value - Report the ghest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, intake water and background.

it is In the applicanrs Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore number of effluent limits and/or monitoring requirements in the the need for additional analysis or potential for establishing a final NPDES permit large

_ l - . I I I i E I I -_ L_

I ii-7 11804mv,.vaWMIuo-i r--I-F77

-- F-- F'r- F -i-r r7Applicant - rx7- v --

Name: PPL Susquehanna, LLC I- --

Module 5 POLLUTANT GROUP 2 3. Level Present____

1.MDL 2. EPA a.Max Dali, Value b. Average of Analysis c. 4. UnitsofElun Metals Used* Method Number of Variability UjfL Number Used Concentration Mass Concentration Mass Analysis Concentration Mass (Cy 12M Thalliumn, Total 10 200.7 NO ND ND ND 3 mg/L lb/day 13M Zinc, Total 5 200.7 .027 3.47 .019 2.25 3 mg/L. lb/day 14M Cyanide, Total .5 335.4 ND ND ND, ND 3 mg/L lb/day 14M Cyanide, Free. 5 S400CMI NDON ND ND 3 m/ lb/day 15M Phenols, Total ,* 5 420.4 ND ND ND ND 3 mgIL. lb/day ______

3., .- It other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maxim~um Daily Valuea- Report the hiahest daily value ordailyavelage value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c.. A minimum of 3 Samnpl~ Evnts required for process wastewater discharges, and a mlnirium of I Sampllng Event for all other discharges, treatment facility Influent, Intake water and -

background. - --

• It IsInthe applicants Interest to achieve the lowest level of detection possilble. This will minimize uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permit. -.--

'a

%JD 3800-PM-WSWM0008I 1/2004 Module 6 Applicant Name: PPL Susquehanna, LLC COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 3 MODULE 6 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

= . it 0~ MU- PPL Susquehanna, LLC 03Outfall Number 071 (Show location of sampling point on Une Drawing)

E Intake Sampling Results - Optional (Specify Source: )

E Background Sampling Results - Optional (Specify Location:

o Treatment Facility Influent Sampling Results (Show location of sampling point on Una Drawing)

El New Discharge (Basis for Information: )

E Bypass or Sewer System Overflow (Describe: J POLLUTANT GROUP 3 2. EPA

3. Level Present______

1. MDL Method a. Max Dail Value

s. Coefficient Volitales b. Averageof Analysis c. 4. Un ts Used' Number of Effluent tug/L) Used Number of Variability Concentration Mass Concentration Mass Analysis 1V Acrolein 20 Concentration Mass (CV) 624 ND ND ND ND 3 ug/h lb/day 2V Acrylonitrile 4 624 ND ND ND ND 3 ug/l lb/day 3V Benzene 1 624 ND ND ND ND 3 ug/lIb/day 5V Bromoform 1 624 ND ND ND ND 3 ugh lb/day 6V Carbon Tetrachloride 1 624 ND ND ND ND 3 ug/I lb/day 7V Chlorobenzene 1 624 ND ND ND ND 3 ug/i IbIday 8V Chlorodibromomethane 1 624 ND ND ND ND 3 ug/ lb/day 9V Choroethane 1 624 ND ND ND ND 3 ug lIb/day 1OV 2-Chloroethylvinyl Ether 2 624 ND ND ND ND 3 ug/ lb/day

3. If other data is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment background. facility Influent, intake water and It Is In the applicants Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for number of effluent limits and/or monitoring requirements In the final NPDES additional analysis or potential for establishing a large permit.

1-a-I -

- I I

\L L I i l I L I

[I7738ooJ2I-SWr&L2 .. UU7 177 ~T V . F U7 U~177 Applicant Name: PPL Susquehanna, LLC I--: F -

Module 6 POOPL33. L T A N G R Level Present G RMaxPDali MDLLMethod ValueS.

1. MDLMthod___Ma Dail b. Average of Analysis Coefficient Volltales Used, Number

__Value C. 4. Units of Effluent Ui/L Used Number of VarIability Concentration Mass Concentration Mass Analysis Concentration lIV Chloroform Mass.- -(y

.- 1 624-N NO ND. ND, 3 ughI lb/day 12V Dichiorobromomethane 1 24 ND

. ND ND NO 3 ughI lb/day 14V 1,1-Dichloroethane 624 ND

-1

.ND, ND' ND 3 ug/h lb/day 15V 1.2-Dichloroethane I 624 ND ND ND ND 3 ug/h lb/day 16V j,1,-DIchloroethylene-.-- -1 624 ND ND ND ~ D3ug/Ilbda 17V 1,2 Dichloropropane.. .64ND ND ND - ND3 ug b/da'y. _ _ _ _ _ _

18V 1, 3-Dichloropmopyiene I 624 ND ND NDO ND 3 (ughI lb/day 1SV Ethyeben'zene -. 1 . . 6 4* DNNDD3 uh *, lb/day 20V Methyt Bromide 1 624 ND NNDD 3 ughlb/day.

21V Methy! Chl6rlde 1 624 ND

-. NDON ND .. -3ug/h lb/day 22V Methylene Chloride 2 624 NDON ND- NE.) . 3 ug/l - lb/day

.23V 1,1,2,2-TetrachI6roethane . 624 N D_

_ _ _ _ND-: -. NDO... N 3 ... ugh -* lb/day -

24V Tetrachioroethylene . 624 ND D-.

NN

_ _ -ND~... ND~ . 3 ugA - lb/day,

,.25V Toluene~ .1 624 ND- .N D_ N D.- ND . 3UgA lb/day.- -

26V 1,2-Trans-dichioroethylene 1I 624 .N ND ND ND-.- N3O ug/h lb/day _ __ _ __ _

27V 1.1,1-Trichloroethane I1 624 ND ND ND NO 3' ug/ lb/day _______

28V 1,1,2-Trlchloroethane 11 624 ND ND ND ND 3 ug/h lb/day ______

29V Trichloroethylene I 624 ND ND ND ND. 3 .. ugh . lb/day ______

31V Vinyl Chloride 1624 I-.. ND ND) ND ND 3 ug/h lb/day _ _ _ _ _ _

3. If other data Is available (iLe., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3o, and 5.

3.a. Maximum Daily Value - Report the highe daily value or daily average value from the last year of data.

Report both mass and concentration.

3.b. Average of Analysis - Determnine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimium of 3 Sampling Events required for process wastewater discharges, and a minimum of 1-Sampling background.-. -

Event for all other discharges, treatment facility influent, Intake water end

. ' ~

itisinthe appllcanis interest achieve the lowest level of detection possible. This will minimize uncertainty and therefore number of effluent limits and/orto monitoring requirements In the final NPDES permit.- the need for additional analysis or potential for establishinga large 0

3800-PM-WSWM0008j 112004 Applicant Name: PPL Susquehanna, LLC Module 7 COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION Pep BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 4 MODULE 7 r Before completing this form, read the step-by-step Instructions provided In Appendix 1.

a ' PPL SusquehannaLLC 23 Outfall Number 071 (Show location of sampling point on Une Drawing)

El Intake Sampling Results - Optional (Specify Source: )

' l Upstream Background Sampling Results - Optional (Specify Location: J a Treatment Facility Influent Sampling Results (Show location of sampling point on Una Drawing)

El New Discharge (Basis for Information: J o Bypass or Sewer System Overflow (Describe: . -'

3. Level Present POLLUTANT GROUP 4 2. EPA 5. Coefficient

1. MDL Method a. Max Datl Value b. Average of Analysis C. 4. Units of Effluent Acid Compounds Used Number Number of Variability A C u/L) Used Concentration Mass Concentration Mass Analysis Concentration Mass (CV) 1A 2-Chlorophenol 10 625 ND ND ND ND 3 ugh lb/day 2A 2,4-Dichlorophenol 10 625 ND ND ND' ND 3 ugh lb/day 3A 2,4-Dimethylphenol 10 625 ND ND ND ND 3 ug - lb/day 4A 4,6-Dinitro-o-cresol 20 625 ND ND ND ND 3 ughl lbday 5A 2,4-Dinitrophenol 25 625 ND ND ND ND 3 ugA lb/day 6A 2-Nitrophenol 10 625. ND ND ND ND - 3 - ugh lb/day-7A 4-Nitrophenol 12 - 625 ND ND ND ND 3 ug/l Ib/day' 8A P-chloro-nmcresol 10 625 ND ND ND ND 3 ug/l Ib/day _

9A Pentachlorophenol 25 625 ND .. ND ND ND 3 ug/ lb/day.

10A Phenol.' - 10 625 ND ND ND ND 3 ug/I lb/day 11A 2,4,6-Trichlorophenol 10 625 ND ND ND ND 3 ugA lb/day

3. If other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year.. Report both mass and concentratIon.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and background.

It Is in the applicants interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements In the final NPDES permit.

. ~~~ . .

.- .~ 6. .. . .. . . 1

- ' l~

I ~ 01~ ,yvm ' - II [F- [77 f7 [77 1'-~ I--'- I-- - NA4 -nt NJ "'-' PPLf '___eharV'-ThC [-7 .F COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 5 MODULE 8 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

Outfall Number -071 (Show location ofsampling point on Une Drawing)

El Water Supply sampling Results - Optional (Specify Source: .......

o ackgroud Sampling Resuits:- Optional (Specify Location:- ..

OjT'rbatm6nt Facility Influent Sampling Results (Show location of sampling point on Line Drawing)

'lNew Dischargd (Basis for Information: ......

ElBypass or Sewer System Overflow (Describe: ). ..-

POLLUTANT GROUP 5 ~EA..b ______

______ _____ 3. Level P resent

2. EA b.Annul nulAeaeo Avrageof5.

- -1. M DL Method , a. Max Dall Value Aall Is CoefficIent Base Compounds . Used* Number C.4 UtsosEfu

. ~ ~Used *...Number Concentration Mass' Concentration ofVariability 18 -Acenaphthene 2.Mass .- Analysis concentration -Mass"-:CV

. 3 . 625 ': ND. ND ND,---.

2B :Acenaphthylene .

- ND.' _..-3-2'-__ '- 'ugA lb/day: .

,3 625: ND- ND ND-: 'ND;. .. 3-ugA-.-'-

383 Anth raene > :'2 l/a 62 :N D-ND ND 48 Benzldine.......

- .- 3-- - tg/4 -lb/day----f-.

.*20 625 ND, ND ND ~ ND_ .~ -. 3 ug/- lb/day ..

58 Benzo(a)anthracene~ 625

'2 ND ND ND ND ~

68 Benzo(a)pyrene:< .3_. ugA lb/day ______

2 . 625, ND ND ND .ND 3 UgA. lb/day 7B 3,4-Benzofluoranthene 2 625 ND NDN D3ugh lb/day 88 Benzo(ghoperyiene 2 625 -

' ND .ND ' ND ND 3 983 Benzo(AWfuoranthene ugh lb/day _______

-~*- .5 .625 ND ND ND ND 3.

108 Bis(2-Chloro-ethoxy)methane'-- utghl .lb/day 3 625 ND ND ND ND 118 B1s(2-Chloroethy4)ether -3 ugh lb/day 2 625 ND-, ND ND ND 128 B~ls(2-Chloro-Isopropyl) ether 3 Ug11 lb/day 2 625 ND ND ND. ND 13B Bls(2-Ethythexy~phthalate 3 ugh lb/day:

- .2 625 ND ND 14B .4-Bromophenyl Phenyl Ether

-ND . ND 3 ugA, lb/day 3 625 ND ND ND'. ND 158 Butylbenzyl Phthalate 3-3. ug/I lb/day

.5 '625 ND ND ND 168 2-Chloronaphthalene

.ND 3 ug/h lb/day' -

5 . 625 ND ND. ND ND 178 4-Chlorophenyt Phenyl Ether

. 3 '-ugA lb/day

'5 ' 625 ND, -ND ND -ND -. 3 Ug/l Iblday _______

3.a. Maximum Daffy Value - Report the hi-ghest daily value or dafly average 3.b. Average of Analysis - Determine the average of all samples taken withinvalue from the last year of data. Report both mrass and concentration'.

the past year. Report both mass and concentration. --

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of I Sampling Event for all other discharges, treatment facility Influent, Intake water and background.

It Is Inthe applicants Interest to achieve the lowest level of detection possible:- This number of effluent limits and/or monitoring requirements In the final NPDES will minimize uncertainty and therefore the need for additional anarysis or the potential fdr estabiishing a large permit.

3800-PM-WSWM0009k 1/2004 Module 8 Applicant Name: PPL Susquehanna, LLC POLLUTANT GROUP 5b. 3. Level Present EPA Annual Average

1. MDL Method a. Max Daly Value b.AnulAerg.

Base Compounds of Ana Iysis Coefficient Used* Number 4. Units toEffluent (CL)

_ Number of Variability Used Concentration Maas Concentration 18B Chrysene Mass Analysis Concentration Mass 2 625 ND ND ND (CV) 19B Dibnzo(ah)anthracene ND 3 ugA lb/day

.2 625 ND ND ND 20B 1,2-Dichlorobenzene ND 3 ugh lb/day 5 625 ND ND ND 21B 1,3- Dichlorobenzene ND 3 ug/ lb/day 5 625 ND ND ND 22B 1.4- Dichlorobenzene ND 3 ugA lb/day 5 625 ND ND ND 23B 3.3-Dichlorobenzidine ND 3 ugA lb/day 10 625 ND ND ND 24B Diethyl Phthalate - ND 3 - ugA lb/day 10 625 ND ND 'ND 25B Dimethyl Phthalate . ND 3 ug/ lb/day 10 625 ND ND ND 26B DI-n-butyl Phthalate' ND 3 - ugA lb/day 5 625 ND ND ND 27B 2,4-Dinitrotoluene - ND 3 -ugA lb/day 2 625 ND '-ND ND 28B 2,6-Dinitrotoluene ND 3 ug - llb/day 2 625 *7ND ND ND 29B Di-n-octyl Phthalate ND 3 ugh lb/day

- ' 5 625 ND ND ND ND 30B 1,2-Diphenylhydrazine (as Azobenzene) 3 ugA lb/day 5 625 ND ND ND 31B Fluoranthene ND 3 ugA Ib/day .

2 625 ND ND ND 32B ND 3 ugA lb/day Fluorene 3 625 ND ND ND ND 3 33B Hexachlorobenzene 2 ugA lb/day' 625 ND ND ND - ' ND 34B Hexechlorobutadiene 3 ugA lb/day 5 625 ND ND ND 35B Hexachlorocyclopentadiene ND 3 ugA lb/day -

10 625 ND ND ND 36B ND 3 ug/I lb/day-Hexachloroethane 5 625 ND ND ND ND 3 37B Indeno(1,23-cd)pyrene ug/I lb/day' 2 625' ND ND ND 38B Isophorone ND 3 ug/ lb/day -

3 625 ND ND ND 39B Naphthalene ND _ 3 u9/i ibiday 3 625 ND ND ND S 40B Nitrobenzene ND 3 ugA lb/day 3 625 ND ND ND 41B N-Nitrosodimethylamine ND 3 ugA lb/day 3 625 ND ND ND 42B N-Nitrosodi-n-propylamine ND 3 ugA lb/day 3 625 ND ND

• ND 43B N-Nitrosodiphenylamine ND 3 . ugA Ib/day' 3 625 ND ND ND 44B Phenanthrene ND 3 ugA lb/day 3 625 ND ND ND 45B Pyrene ND 3 ugA lb/day 2 625 ND ND ND 46B 1,2,4-TrIchlorobenzene ND 3 ugA lb/day 5 625' ND ND ND ND 3 ugl lb/day 3.a. Maximum Daily Value - Report the WOIWLes daily value or daily average value from the last year of data. Report 3.b. Average of Analysis - Determine the average of all samples taken within both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater the past year. Report both mass and concentration.

discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and background.

ItIs in the applicanrs Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis number of effluent limits and/or monitoring requirements In the final or the potential for establishing a large NPDES permit.

L=IIILL-' i I I [ - I . Ii

1 17 1---

3800-PM-WSWM00081 1/2004 F--- F-- 17 7---r-- -- F- Fe F-- I- I . r-Applicant Name: PPL Susquehanna, LLC F---- -- -

Module 9 COMMONWEALTh OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 6 MODULE 9 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

N PPL Susquehanna, LLC 0 Outfall Number 071 (Show location of sampling point on Une Drawing) a Intake Sampling Results - Optional (Specify Source: )

0 Upstream Background Sampling Results - Optional (Specify Location: )

E Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing)

O New Discharge (Basis for Information: ) -

O Bypass or Sewer System Overflow (Describe: )

'3. Level Present _____

POLLUTANT GROUP 6 2.EPA 5. Coefficient

1. MDL Method a. Max Daily Value b. Average of Analysis - 4. Units of Effluent Pesticides Used' - Number > Number of Variability

- ' - , - s 'Used Conce'ntratlon Mass Concentration Mass Analysis Concentration Mass (Cy) 2P AlphaBH. . ._ . . _ _ . __._

3P Beta-BHC .  ; .- .

4P Gamma-BHO _ _ . __

5P Delta-BHC -.

6P Chlordane 7P- 4,4.-DDT ..- - - - .

8P 4,4-DDE ' .

9P 4,4-DDD . _ . . _

10P Dleldrin - , .

11P Alpha-endosulfan . *t_.,,,. _.,. _, _.,. _= __. ___ _

3. If other data is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the hiahest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and background.

• It Is In the applicant s Interest to achieve the lowest level of detection possible. This will minimize uncertainty and therefore the need for additional analysis or the potential for establishing a large number of effluent limits and/or monitoring requirements Inthe final NPDES permit.

-1 --

38W0-PM-WSWMOOOBI 112004 Module 9 Applicant Name: PPL Susquehanna, LLC POLLUTANT GROUP 6 3. Level Present.

2. EPA

5. Coefficient

1. MDL Method a. Max Dally Value b. Average of Analysis c.

Pesticides 4. Units of Effluent Used Number Number of (LL).. Used Concentration Mass Variability Concentration Mass Analysis Concentration Mass (CV) 12P Beta-endosulfan 13P Endosulfan Sulfate 14P Endrin 15P Endrin Aidehyde

.116P Heptachlor 17P Heptachlor Epoxide 18P PCB-1242 .95 608 ND ND' ND ND 3 pjg/L lb/day 19P PCB-1254 .95 608 ND ND ND ND 3 -ig/L 1bday 20P *PCB-1221 .95 608 ND

• ND ND ND 3 pg/I lb/day __-

21P PCB-1232 .95 608 ND ND ND ND 3 jg/IL 1b/day 22P PCB-1248 .95 608 ND ND ND ND 3 p/IL 1b/day 23P PCB-1260 .95 608 ND ND ND ND 3 pg/lL lb/day 24P PCB-1016 .95 608 ND ND ND ND 3 pig/L lb/day 25P Toxaphene _

26P DIOXIN: 2.3,7, 8-Tetrachlorodibenzo-P- 0 Describe Results:

_ Dioxin (TCDD) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

3. If other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a. 3b, 3c, and S.

Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3, Sampling Events required for process wastewater discharges, and a minimum background. of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and

• It Is in the applicants Interest to achieve the lowest level of detection possible. This will minimIze uncertainty and therefore the need for additional analysis or potential for establishing a large number of effluent limits and/or monitoring requirements in the final NPDES permiL w

ON 0s' I I

I --- I--- I1 - 1'-- 'II -- F__ - F 1F- V- F- Fr-V- I--- I-7-7[ F--- I -- F____

3800-PM-WSWM0008g 112004 Applicant Name: PPL Susquehanna, LLC Module 4 ep COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 MODULE 4 Before completing this form, read the step-by-step Instructions provided in Appendix 1.

APPLICANT. NAME PPL Susquehanna, LLC i Ouffall Number 072 (Show location of sampling point on Line Drawing) Flow= 7/13, 0.0098 MGD El Intake Sampling Results - Optional (Specify Source: -___ ) - -

' Background Sampling Results - Optional (Specify Location of Sample: )-

o Treatment Facility Influent Sampling Results (Show location of sampling point on Llne Drawing) a New Discharge (Basis for Information: . ) - -]

E Bypass or Sewer System Overflow (Describe: ' '

. . 1. LEVEL PRESENT -

--- 2. UNITS 3.

- .. Coefficient POLLUTANT GROUP I - a. Maximum DallyValue b. Average of Analysis  : of Effluent

. - - e. . No. of - Variability

. (1)Concentration: (2)Mass (1) Concentration (2) Mass Analysis Concentration . b. Mass . . (CV)

Biochemical Oxygerf Dednrid, BOD  ; ND I ND ND ND I ing.L . . Iblday . . .. . .

Chemical Oxygen Demand, Cob ND ND ND ND 1 mglL Iblday Hardness (CaCO 3) . i-Total Suspended Solids, TSS 7 0.57 7 0.57 . 1 mgIL Iblday Total Dissolved Solids, TDS . . ._._.

Ammonia as N Nitrate-Nitrite (as N) 0.44 0.036 0.44 0.036 1 mgIL- Iblday -

Total Kjeldahl Nitrogen (TKN) ND ND . ND ND 1- mgIl Iblday Phosphorus (as P), Total ND - - ND - ND NDO I mgIL Ib/day Temperature winter - Value -' Value Temperature summer Value Value pH - Min. 7.45.- Max.- 7.45 I _ Standard units Standard units 1.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. -Report both mass and concentration.

1.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration. - -

I .C. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and background.

, ,. - -1,,

3800-PM-WSWM0008g 112004 Module 4 Applicant Name: PPL Susquehanna, LLC

3. Level Present POLLUTANT GROUP 1 Z.EPA 1.MDL Method a.Max Dali Value b. Average of Analysis 5. CoefficIent Believed Used* Number c. 4. Units of Effluent Absent (us&) Numbter of Variability Used Concentration Mass Concentration Mass Color Analysis Concentration Mass (Cy)

. .0 .. .

Focal Coliform ] _ _ _ _ __ _ _ _ _

Fluoride 5 _

O4 and Grease 5 2100 1664 ND ND ND Bromide i ND 1 mg/L Ibfday Chlorine, Total Residual [ I Sulfate C] -

Sulfide l _

Sulfite - a Surfactants 5 Aluminum, Total Barium, Total _

Boron, Total _

Cobalt, Total O _

Iron, Total _

Iron, Dissolved _

Manganese, Total Total Organic Carbon, TOC O _

Radioactivity v=

0 MagnesiumE Molybdenum Cl Tin, Total E Titanium, Total E

3. If other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, and a minimum of I Sampling Event for all other discharges, treatment background. facility Influent, Intake water and

• It Is In the applicanrs Interest to achieve the lowest level of detection possible.

This will minimize uncertainty and therefore the need for additional analysis number of effluent limits and/or monitoring requirements in the final NPDES permit. or potential for establishing a large I = 'e e i i LF I- I is iL ili- T

1-800-r h WMf- 1/1- --- F F-- , -- I--. A'~Visufln~dami8 PPL uaqt Ieha~i.,L,.LC Module 4 D e~w COMMONWEALTh OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTi1 ION BUREAU OF WATER SUPPLY AND WASTEWATER MAN IAGEMENT ANALYSIS RESULTS TABLE POLLUTANT GROUP 1 MODULE 4 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

8. X l PPL Susquehanna, LLC

• 0 - Outfall Number 073 (Show location of sampling point on Une Drawing) Flow = 7/12, 0.0081 MGD Hi Intake Sampling Results - Optional (Specify Source: )-J a Background Sampling Results - Optional (Specify Location of Sample: )

El Treatment Facility Influent Sampling Results (Show location of sampling point on Une Drawing)

E Niew Discharge (Basis for information: )

a Bypass or Sewer System Overflow (Describe: . -_--

1. LEVEL PRESENT -- 2. UNITS- 3.

Coefficient POLLUTANT GROUP 1 . a.Maximum Daily Value b. Average of Analysis . - of Effluent

- Variability

- - _ (1) Concentration (2)Mass (1)Concentration (2)Mass Analysis Concentration b. Mass (CV)

Biochemiical Oxygen Demand, BOD - - NO - --ND - N D NDD,'mb1 m lb/day Chemical Oxygen Demand, COD--- 19- . 1.28 19 1.28 9g/L 1 lb/day Hardness (CaCO3) -- -.

Total Suspended Solids, TSS - - 7 0.47 7 0.47 1 mg/L lb/day Total Dissolved Solids, TDS .

Ammonia as N -~ -~

Nitrate-Nitrite (as N) 0.4 0.027 0.4. 0.027 1 . mgA. IbIday Total Kleldahl Nitrogen (TKN) 1.4 0.095 - -1.4 .

• 0.095 -1 I-- -_ mg/L lb/day Phosphorus (as P), Total ND . ND - ND - ND - 1 mg. lb/day _

Temperature winter - Value Value - Numerous Temperature summer Value value Numerous pH Min. 7.88 i Max. 7.88 . 1 Standard units Standardunits l.a. Maximum Daily Value - Report the highest daily value or daily average value from the last year of data: Report both mass and concentration.

1.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.

1.c. A minimum of 3 Sampling Events required for pr6cess wastewater discharges, and a minimum of 1 Sampling Event for all other discharges, treatment facility influent, intake water and background. . -. -- .

I b , ,  ?.

i . j -..' ,

3800-PM-WSWM0008g 1/2004 Module 4 Applicant Name: PPL Susquehanna, LLC

3. Level Present POLLUTANT GROUP 1 2. EPA 1.MDL Method a. Max Dal' Value b. Average of Analysis S. Coefficient Believed Used c. 4. Units of Effluent Number Number of Absent L Used Concentration Mass Variability Concentration Mass Analysis Concentration Mass (CV)

Color [. _ _ _ _

Fecal Coliform El Fluoride f1 O0and Grease [] 2100 1664 ND ND NO ND 1 mg/L lb/day Bromide E]

Chlorine, Total Residual E-- -

Sulfate - a Sulfide.. . . . .

Sulfite °E _

Surfactants E Aluminum, Total Q Barium, Total 5 Boron, Total O Cobalt, Total E]

Iron, Total E Iron, Dissolved E Manganese, Total E Radioactivity E Total Organic Carbon, TOC _

I.

Radioactivity E Magnesium E Molybdenum E mn,Total. D Titanium, Total

3. If other data Is available (i.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest daily value or dally average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum ,of 3 Sampling Events required for process wastewater discharges, and a minimum of I Sampling Event for all other discharges, treatment facility Influent, intake water background. and

• It is in the applicants interest to achieve the lowest level of detection possible. This will number of effluent limits and/or monitoring requirements In the final NPDES permiL. minimize uncertainty and therefore the need for additional analysis or potential for establishing

. a large

~ I = = - 7- 6I I I== i =

_== _-

i~ i:~ I-~

=

-Ud).PtwWML 1/2L, A1ppllcant Nanme: PPL usquehannaLLCF

' Module 4 5ep COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT

- ANALYSIS RESULTS TABLE POLLUTANT GROU JP1 MODULE 4 Before completing this form, read the step-by-step Instructions provided In Appendix 1.

MPPL Susquehanna, LLC 21 Outfall Number 079 (Show~ocation of sampling point on Uine Drawing) Fiow = 5/27, 0.02482 MGD Ei Intake Sampling Results - Otional (Specify Source: ) .- -

- Background Sampling Results - Optlonal (Specify Location of Sample: ..) - -

- E Treatment Facility Influent Sampling Results (Show locatlon of sampling point on Une Drawing)

El New Discharge (Basis for Information:.).--.--

El Bypass or Sewer System Oyefliow (Describe: --. )

. 1.LEVEL PRESENT . - 2. UNITS 3..

T N G RU....

.OL .. _ _ _ _ _- _ _ _ _ _ c N. a -- -Coefficient

a. Maximum Daily Value b. Average of Analysis o Effluent

- .. .~ .

.c.

No. of .

• V a.,;Vrablt ariabIlity

. ._ - -. (1)Concentration (2) Mass (1)ConcentratIon* (2) Mass Analysis Concentration . b. Mass (CV)

Biochemical Oxiygen Demand; BOD - - 4.2 --- .869 . 4.2 , .869  :.1 .mg/l Iblday 7"';

Chemnical Oxygen Demand, COD -- ------ 517-.

• 25 j. 5.17 '1mgllb/day _____

Hardness (CaCO 3 )-- --  : 82.4 . -17.1 82.4: 17.1 1 mg/I lb/day . ..

Total Suspended Solids, TSS . ND ND ND ND 1 mg/I Ib/day Total Dissolved Solids, TDS' 648 134 648 - 134 1 mg/i Ib/day Ammonia as N . i _ 1.36 .282 1.282 282 1 mg/l Ib/day-. _.

Nitrate-Nitrito (as N) 31.3 6.48 31.3 6.48 . 1 mg/I Ib/day .

Total Kleldahl Nitrogen (TKN) j 2.1 .435 2.1 .435 1 I* mg/I lb/day -

Phosphorus (as P), Total - . 6.46 . 1.34 6.4 1.34 1 mg/- Ib/day _.

Temperature winter , 3 Value - , Numerous C N/A Temperaturesummer - - - - 23 Value . 21 Value Numerous C N/A pH Min. 7.34 I Max. 7.34 1 Standard units Standard units 1.a. Maximum Daily Value - Report the Aches daily value or daily average value from the last year of data. Report both mass and concentration.

1.b. Average of Analysis - The average of all values within the last year and report both the mass and concentration.

1.c.. A minimum of 3 Sampling Events r quIred for process wastewater discharges, and a minimum of I Sampling Event for all other discharges, treatment facility Influent, Intake water and background-.

. 38001PM-WSWM0008g 1/2004 Module 4 Applicant Name: PPL Susquehanna, LLC

3. Level Present 5._________

POLLUTANT GROUP 1 1.MDL 2. EPA a. Max Dall Value 5. Coefficient

b. Average of Anal Is Believed Usedt Method C. 4. Units of Effluent Absent Ug&) Number Used Number of VarIabilIty Concentration Mass ConcentratIon Mass Analysis Color Concentration Mass (CV)

. 5 - sm18-2120b 45 45 1 cU Fecal Coliform n 922d 32 32 1 co m_100_l Fluoride O 200 300 ND ND ND ND Oil and Grease 5 2100 1 mg/I lb/day 1664 ND ND ND ND Bromide I mg/I lb/day 300 300 ND ND ND ND 1 mg/I lb/day Chlorine Total Residual O 50 330.1 NDO ND - ND ND Sulfate 1 mg/I lb/day 2000 300 79 16.3 79 16.3 1 mg/I lb/day Sulfide - 1000 376.1 ND ND ND ND -

Sulfite mg/I- Ib/day 2000 377.1 4 .827 4 .827 1 mg/I lb/day Surfactants a 25 smlS-5540c .044 .0091 .044 .0091 1 Aluminum, Total mg/I Ib/day 50o 200.7 ND :ND ND ND 1 mg/I lb/day Barium, Total I] 10 200.7 ND ND ND ND I mg/I lb/day Boron, Total 5 50 200.7 . ND ND ND ND 1 mg/I lb/day Cobalt, Total 3 200.7 ND ND ND ND 1 mg/I lb/day Iron, Total [ 30 200.7 .06 .012 .06 .012 1 mg/I lb/day Iron, Dissolved [ 60 200.7 ND ND ND ND 1 mg/I lb/day Manganese, Total 5 - 3 200.7 .018 .0037 .018 .0037 1 a mg/I lb/day Radioactivity GR-A El 1.45 900 ND ND ND ND 1 Total Organi Carbon. TOC pCI/ N/A a 1000 sm18-5310b 8.9 1.84 8.9 1.84 1 mg/I lb/day Radioactivity GR-B 5 2.66 900 22.6 N/A 22.6 N/A 1 pCI/I N/A Magnesium 5 50 200.7 5.7 1.17 5.7 1.17 1 mg/I lb/day Molybdenum - 10 200.7 ND ND ND ND 1 mg/I lb/day Tin,Total El 10 200.7 .ND ND ND ND I mg/I lb/day Titaniumi, Total 5 10 200.7 ND ND ND ND 1 mg/I lb/day

3. If other data Is available (I.e., DMR data, etc.), the past year of data may be used to determine 3a, 3b, 3c, and 5.

3.a. Maximum Daily Value - Report the highest dally value or daily average value from the last year of data. Report both mass and concentration.

3.b. Average of Analysis - Determine the average of all samples taken within the past year. Report both mass and concentration.

3.c. A minimum of 3 Sampling Events required for process wastewater discharges, background. and a minimum of 1 Sampling Event for all other discharges, treatment facility Influent, Intake water and

• It Is In the applicants Interest to achieve the lowest level of detection possible.

number of effluent limits and/or monitoring requirements In the final NPDES This will minimize uncertainty and therefore the need for additional analysis permit or potential for establishing a large I I S

1/2004 Applicant Name: PPL Susquehanna, LLC I 3800-PM-WSWM0008m Module 10 COMMONWEALTH OF. PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION

_w BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT

,, ..Fi I,.

. 4 . -, .; . . , I .

HAZARDOUS SUBSTANCE TABLE

-MODULE 10-iBefore completing this form, read the step-by-step Instructions provided In Appendix 1.

PPLSusquehanna, LLC

- 3. Amount Per Outfall - 5. Treatment Provided

1. Name of ____

Table 3 . I Quantity - - 4..

lb/24 hrs Frequency' Duration Origin and Source ' a b c r Substance 2. Outfall Sodium: 07 00 ~ a oling Tow'er E Hypochlorite 07 5 2 2 Chlorination . _i ____ °

_ _ _ _ _El El El,

-El El El.

. .El El-l r: ;_. _._.

,E 0 -E . l

. '.E. -. El El1 El El El -El El El E1 r =-..

r__

. ElEl.. El E

,OEl

-El

_El_ .E El:-El

__0 E E0 El

.. E

__ITE El El

. . .. . +.~.... ..El. El-0 O.

!.....El.. ... a El0 . El

___ . ... .. ... . ........ . -E __ O

. , .l. El C El

.1I. 313

UL-3800-PM-WSWM0008n Module 11 112004 Applicant Name:

Outfall: All COMMONWEALTH OF PENNSYLVANIA PPL Susquehanna, LLC It 01im DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT OTHER TOXIC CHEMICALS IL MODULE 11 Before completing this form, read the step-by-step Instructions provided In Appendix 1. it1

, IcaaPPL Susquehanna, LLC .

All (N/A) II

1. GC/MS "Five Peaks" pollutants (see Appendix 1)

Group . .

Average Effluent Maximum Effluent No. Samples Positive it Number Chemical Substance or MDL Concentration Concentration /

(3-6) 'Compound Name WIl) (ug/L) _ bgl1-) No. analyzed It

2. Other Chemicals I Average Indicate if Concentration Presence is Substance Reason for Presence in Discharge WM Known (K) or Suspected (S)

'i 11

..I Ii -1. Ii 0If additional peaks were not available for one or more groups with the method used check here and attach an explanation of why the method was selected.

Provide additional sheets as necessary. i 314 1

L3800PM-WSWMO008o 112004 Applicant Name: PPL Susquehanna, LLC

'LModule 12 COMMONWEALTH OF PENNSYLVANIA -

DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT STORMWATER lMODULE-12 -

Before completing this form, read the step-by-step Instructions provided In Appendix 1.

I' UC PPL Susquehanna, LLC

1. Site Plan and Stormwater Runoff.' Attach a copy of your facility's site plan.. (See instructions)

DEP strongly recommends the separation of stormwat6r and other wastewaters.

2. Description of Potential Pollutant Sources and Controls

a. For each stormwatpr outfall, provide, an estimate of the area (include units) drained to the outfall, and a list of potential pollutant(s) and sources for the outfall '

Total Area Drained '

Outfall Number (provide units) - Potential Pollutant(s) and Sources 070 133 Acres Oil Storage In south drainage, water storage tanks, water treatment bldgs.

075 167 Acres Oil Storage in north drainage, firing range, site runoff 080 51 Acres Oil and waste storage in central drainage, water storage tanks, well treatment bldg.

b. Describe Best Managemebnt Practices and nonstructbial controls used to prevent potential pollutantsn stormwater.  ; - - '

Inspections, container condition maintained, PPC Plan Implemented, training provided, assessments, audits,,

F walkdowns, limit storage volume(s), utilize less' hazardous approved materials whenever possible. I

-. I

c. For each stormwater outfall, provide the location and description of existing structural control measures to reduce pollutants in stormwater'runoff; and a description bf the treatment the stormwater receives, including the schedule F and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. i ___-i'__'_i;:_,_____,_,-_ -

Outfall Number  ; Control Measures -.

070 Rention p'ond, spill containment/ berms,' level alarms 075 - Spill berms, Oil spill collar on renterition pond stan~dpipe, leak detection alarms F 080 Rentention pond, s ill containments, levelcontrols/alarms

3. Non-stormwater Discharges -

a. All non-stormwater discharges from thes'e outfall(i) are identified in the Industrial Wastewater section of this application for the outfall. ' '

', 'YES E NO

b. Provide a description of the method used, the 'date of any testing, and the on-site drainage points that were directly observed during a test.,

N/A

4. Significant Leaks or Spills ' - --

Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the

_ facility in the last 3 years, including the approximate date and location of the spill or leak, and the type and amount of material released.

Lube Oil Cleanup in North Storm Drainage from Main Turbine Lube Oil Mist Elim Roof Vent Discharge Completed 09/23/04.

• ;.7 315

PPC PLAN NORTH FENCING REISP49 PROTECT'E'DAREA BOUNDARY aa SUSODUEA"4NA NGU -JUPdL LLLWELLSLL LAKEL Lm S1 - NRYP.10 ON AlADY LL LsrsI BL .LLL.

J.Lt ONTROL NG LLLI TER UGH ISTEAENELETRIC 1OICE STAIIL IL TY MAAR -AEAeAN-FOL RE'EISC 9/1LLO

~~__

~~~__ I-~~~ I= = = = I ~ = 6 = I--__ = ~ 6~_ ~ = 6 __ = =

3800-PM-WSWM0008o 1/2004 -. '- I I: Applicant Name: PPL Susquehanna, LLC

-Module 12

5. PREPAREDNESS, PREVENTION, AND CONTINGENCY (PPC) PLANNING.

Does the facility have a PPC plan? 0i YES E NO Does the facility have any other related plans, such as'a Pollution Incident Prevention (PIP)

Plan, Spill Prevention Control and Counter Measure (SPCC) Plan or Stormwater BMP Plan? ED YES E NO If EYES, identify and indicate date(s) implemented. >---..

Type of Plan' I1-. Date Implemented DD(n Dlan KNnta- MAPn 1198 PCnnicL nrezxnetnel wAtnnUinntinn I - - I Infnte4 II /I CaA Ir rIo IlII IJe.v I VIu ItC/ JJJ puIuVIen . w/uuIv YVIIjJvIIueuJ . - .l ,*;u I~ul~

SPPC Plan Note: Two (2) Copies provided w/Application Updated 11/19/04 DEP may require the plan(s) be submitted with this application

I V.

ar4 A oW- Qfnr rv.A'UuLI',F1ICU luI rtnmn,',4 I IIVQLVU Im-nrrnfInnI I1 icIUI II I"IIU aileo inn

%JuLI II IouIQQ I I

a. Could all sampling be performed as required? ., i El YES ONO C

(Explain below):

b. Complete a Stormwater Sampling Data Table (Module'13) for each outfall containing stornmwater.

Indicate the total number of tables submitted. Outfall 075 was sampled representative of- 070 & 080 a, I . , .;: ;: , '-. Y II-317

3800-PM-WSWM0008p 1/2004 - Applicant Name: PPL Susquehanna, LLC Module 13 Outfall: 075 COMMONWEALTH OF PENNSYLVANIA --

DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER SUPPLY AND WASTEWATER MANAGEMENT I STORMWATER SAMPLING DATA TABLE

-, .1 - IMODULE 13:

Before completing this form, read the step-by-step Instructions provided In Appendix 1.

Ii LI PPL Susquehanna, LLC 075 . I

1. Provide the results of at least one analysis for every pollutant in this table.' See Appendix 1.

CAS Number Maxdmum Values (include units)

Average Values (include units) Number

-I Grab Sample of Storm Pollutant Oil and Grease (if available)

Grab Sample Taken During First 30 Minutes ND Taken During First 30 Minutes ND Events Sampled 1

Sources of Pollutants I'

Biological Oxygen ND 1 Demand (BODS)

Chemical Oxygen ND ND 1 Il Dem and (COD) _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Total Suspended Solids (T SS) __ __ __ __ _ __

9 mg/.

__ __ _9 9 mg/L 1 A

Total Kjeldahl ND ND 1 Nitro g en Nitrate plus Nitrite N itro gen_

1.78 mg/L 1.78 mg/L 1

11 Total Phosphorus pH (min./Max.)

ND 7.55 SU 7.55 ND SU 1

1 Il List each pollutant that is limited by an ELG which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the facility is operating under an existing NPDES permit). See the instructions for additional details and requirements.

Maxdmum Values Average Values Il CAS (include units) (include units) Number Number Grab Sample Taken Grab Sample of Storm (if During Taken During Events Pollutant Chlorine total available) First 30 Minutes

<0.05 mg/L First 30 Minutes

<0.5 mgL Samped 1

Sources of Pollutants Infrequent, Incidental Tank A

Residual __0_05_______0_05 ______ Drain ace IS II

____ I___ __

.1 It a

318 It 1t

3800-PM-WSWMOOO8p 1/2004 Applicant Name: PPL Susquehanna, LLC

-Module 13 Outfall: 075

3. List each pollutant shown in Table 3 and Pollutant Groups 1-6 that is known or believed to be present. (See ADDendix 1.)

Maximum Values Average Values CAS (include units) (include units) Number Number Grab Sample Taken Grab Sample of Storm (if During Taken During Events

[i ttan available) First 30 Minutes First 30 Minutes Sampled Sources of Pollutants Firing Range - bullet backstop Lead ND ND 1 material previously screened to l_ remove fragments

4. Provide data for th storm event s) which resulted inthe maximum values for the flow weighted compost sample.

1. 2. 3. 4. 5.6. 7. 8.

Total flow Duration Total rainfall Number of hours between Maximum flow rate from rain Form of Date of of Storm during storm beginning of stormn during rain event event (gallons Season Precipitation Storm (in event measured and end of (gallons per minute or specify Sample (rainfall.

Event minutes) (inInches) previous measurable event or specify units) units Was taken snowmelt) 07OA4 8 min 0.1 72 Hours 166.35 gpm 28,435 gal Summer Rainfall L 5. Provide a description of the method of flow measurement or estimate.

Volumetric measurement at discharge pipe into containerof known quantity.

L 319

Appendix A EPA 316(b) Phase 11 Documentation PPL Susquehanna, LLC Operation is in compliance with Phase 11 per Compliance Alternative (1)(i)

NPDES RENEWAL APPLICATION PERMIT NO. PA 0047325 January 6, 2005

EPA 316(b) Rule (Phase 1.)

Cooling Water Intake Structure PPL Susquehanna, LLC is choosing'to comply with the requirements of the Phase II 316(b) Rule by selecting Compliance Alternativ'(1)(i). The following data shows that this facility is equipped with 'a closed-cycle 'recirculating'syst6m. According to the rule, having made this demonstration,'this facility will be deemed 'to have nmet'the applicable performance standards 'and will not be required to'demr6nstrate further'that thislfacility meets the impingement mortality and entrainment'performance'itandards in 40 CFR-125.94(b) of the rule. We are-sibmittng'thefollowing data "as"required by 40 CFR 122.2(r)(2),(3) and (5).

1. Source water physical data

.. ., . , ,. 1,- .. .. I 1.1 The Susquehanna',River is the principal water source for the Susquehanna SES (SSES). The Susquehanria'River Drainage Basin, shown on'Figure 1lies in the

• northeastern portion of the United States generally between latitudes N 390 30' to' N 430 00' and longitudes W 740 30' to W 790 00'. The basin is the largest on the' Atlantic seaboard of the United States. The length of the Susquehanna Basin is about 250 miles. The total drainage area is 27,510 square miles of which 6,270 are in south central New York, 20,950 in central Pennsylvania, and 290 'in' northeastern Maryland. The total drainage area upstream of the site is about 10,240 square miles.

Figure 2, Susquehanna River Profile, 'shows 'the' stream profile of the Upper Susquehanna River within a 50-mile radius' of the SSES. Between its confluence with the Lackawanna River, about 31 miles upstream of the SSES to its confluence with the West Branch of the'Susquehanna' about 41 miles downstream, the river undergoes a drop of about 115 feet for ari average drop of 1.6 feet per mile. Within L this reach there is only a small change'is streambed gradient. Upstream of the station the average gradient is 1.8 feet per mile. Downstream of SSES, the average gradient is 1.5 feet per mile.

The river channel is about 800 feet wide in'the vicinity of the SSES. Bathymetric; features of the river in'the'vicinity of.jthe 'make' up .water intake and blowdown discharge structures are provided on Figu're3, Susquehanna River Bathymetry.

Moderate to steep' slopes directed toward the river 'along'both its' banks characterize the topography in 'the genera -area of the site. The station is located approximately 4,000 feet west of the intake str~ucture at an elevation of about' 670 feet above mean sea level (msl) or 'aboiut 190 feet above the river bed.; The average slope toward the river is about 8%.

The elevation of the Susquehanna River at the SSES site ranges from 485.9 ft to 518.2 ft above msl. Flow range is from about 800 to 345,000 cfs. The maximum elevation and flow were from Tropical Storm Agnes in June 1972.

316(b)

Phase II Page1 of 15

A policy decision of the Susquehanna River Basin Commission regarding consumptive withdrawals during low flow periods provides that future water users will not diminish natural flow during droughts. The source of low flow augmentation for SSES is the Cowanesque Reservoir. Cowanesque is a storage release reservoir that was completed in 1990 and is owned and operated by the U. S. Army Corps of Engineers. Cowanesque is located in Pennsylvania along the New York border about 170 miles upstream from the Susquehanna SES. -A water release from Cowanesque is triggered by a river flow at the' USGS Wilkes-Barre, Pennsylvania gaging, station, equal to. the 7-day, .10-year, low' flow plus the consumptive use of the Susquehanna SES. The 1-day and 5-day rates of river flow decline and the 5-day travel time to Wilkes-Barre are other factors considered to make a water release. The normal trigger value is 868 cfs.

The Susquehanna River at SSES shows a predictable annual pattern of temperatures, with lowest temperatures in winter and highest temperatures in late summer. High water temperatures in August and September are moderated by lower air temperatures, and higher river flows in October. In 2002, daily mean water temperatures ranged from. 00 C (January 1 through January' 9) to. 28.90 C (August 4), while average monthly daily mean temperatures ranged from 0.80 C in January to 26.00 C in August.

2. Cooling Water Intake Structure Data 2.1 The Phase I 316(b) report for the SSES intake structure was filed with the PA' DER on 11 August 1982 and approved on 6 October 1982 after review by the United States Environmental Protection Agency, United States Department of Interior Fish and Wildlife Service, Pennsylvania DER Wilkes-Barre Office, and the Pennsylvania Fish Commission. The SSES intake, structure was constructed to outperform '

acceptable intake flow-design parameters listed in "Development Document for Best Technology Available for Location, Construction and Capacity of Cooling Water Intake Structures for Minimizing Adverse Environmental Impact%, USEPA, l April 1976.

2.2 Susquehanna SES is a base-loaded plant and is in operation 24/7/365 unless offline for an outage. The river intake structure consists of an embayment and A

pumphouse. It is located on the west bank of the Susquehanna River at a latitude of N 410 05.300' and longitude of W 760 07.910' (Figure 4). An earth embankment extends 20 ft above the floodplain to elevation 526.0 ft above msl,' which is 1.0 ft above the maximum water elevation for the postulated Standard Project Flood.

The floor level of. the intake' superstructure is located at the top of the graded embankment. The elevated embankment and the riverbank at the intake entrance are covered with a' blanket of heavy ri -rap for erosion protection during high riverflow conditions.

316(b)

Phase II Page 2 of 15

The intake structure consists of a steel superstructure above the operating floor and a reinforced concrete substructure extending'into the rock below the level of the river bottom. "The superstructure houses the rnakeup' water pumps and associated equipment, including' switchgear,"'automatic 'operating'equipment for trash-handling screehs, motor control centers',screen wash strainers, and a debris-handling facility. '

The substructure contains two water entrance chambers that house the traveling screens and two pump chambers; The 'floor'arnd sides of theentrance chambers (Figure 5) form the intake openings. The top of the intake openings is forned by' an inverted weir extending 1.0 ft below the minimum river water level (elevation 484.0 ft) to intercept floatin' oil 'and debris. The front of the intake is at the riverbank with flared wing walls extending down the niatural slope of the bank to

provide for an 'even and gradual water-approach velocity.'

The dimensions of the'wnrig walls are shown in Figure 6.! The applicant has computed the area of the embayment createdIby the'wing walls as approximately 5,400 sq ft (horizontal projection). During periods of low flow, the embayment will contain approximately 37,800 cu ft of water (based on an elevation of 482 ft above msl). At normal flow (based on m6an flow"'derived from June'1973 to May 1978)'

the calculated volume of the embayment will be 59,400 cu ft; at high flow (top of wing walls at an. elevation of 505 ft above msl) or maximum volume of the embayment, the volume 'will be 86,500 cufty'-'

Riprap protecting the east slope of the intake structure facing the river extends approximately 161-ft south and 89 ft-north from 'the resp6ctive edges' of 'the structure. The riprap was placed by "end dumping" on aAtwo-horizontal-to-one-vertical slope to an approximate elevation of 482 ft above msl. The riprap on the north and south side of the embankment covers approximately 2,500 sq'ft and 6,200 sq ft, respectively. The total surface area of riprap behind the wing' walls from elevation 505 ft (top of wing walls) to elevation 482 ft above msl is about 8,700 sq ft.

The intake-flow velocity is perpendicular to and less than the river velocity. Figure 5 shows the average horizontal velocity of the water flowing from the river to the intake pumps.' .

Four nominal one-third capacity intakea' pump with a capacity of 30 cfs 'each are installed in the intake structure. -Three pumps can support station load operation (100%) of both units with an 87 cfs intake flow under the least favorable (1%)

meteorological conditions. Four-pump operation is utilized from time to time to support certain operating conditions (i.e. to maintain makeup' water system' pressure) and may see increased use in the future as power uprates at the station are implemented.' Makeup flows-cann increase up'to' 20% under these conditions' but are acceptable within design criteria of the makeup system.'

,x' , . J,. ,

316(b)

Phase II Page 3 of 15

I Each of the tw6. ater entrance chambers is equipped with two automatically operated trash removal screens in series. A bar screen behind each'of the inverted weir intake openings prevents large debris from impeding operation of the' automatic traveling screen. The bar screen, trash racks, andtraveling screens are operated automatically either by differential pressure sensors or by a timer for periodic cleaning. Water-spray systems wash debris from the screens into a pit for i

disposal whenever the trash rack or traveling screens operate. The bar screens consist of vertical 1.25-in bars with' a 1.0-in opening between bars. The traveling screens have 0.37-in mesh wire openings.

i Stop-log slots are provided in front of and behind the screens so that the provided stop-logs may be lowered arid the chamber dewatered for repair of the screens.

Another set of stop-logs may be used to close the slot in the center wall for the purpose of dewatering one of the pump chambers. The insertion of these barriers requires the effort of heavy portable equipment and a maintenance crew.. Such an effort will normally be scheduled during a period of reduced station load when less water is required and design-intake velocities are not being exceeded. I With three pumps in operation (the flow being 87 cfs), the velocity of water through both intake-structure passages is:

a. 0.37 ft/s through the entrance openings (i.e., under inverted weir); this value is independent of river level.

b. 0.58 ft/s through the clean bar screen openings at the minimum river level of 484 ft above msl.

c. 0.64 ft/s through the clean traveling screen openings at the minimum X river level of 484 ft above msl.

Since there is the capability to block off one or more of the passages, there is a potential for increased velocities. During four-pump operation, these flow velocities may increase by up to 20%.

Under the worst case anticipated, with three pumps operating at a flow of 87 cfs and with only one passage open, the inlet velocity would be 0.75 ft/s. Four-pump operation under these conditions could increase this velocity up to 20%. The A insertion of stop-logs is regulated by strict administrative procedures.

3. Cooling Water System Data Each circulating water system consists of a main condenser, circulating water pumps, piping and valves, a natural draft cooling tower and a basin below the tower that acts as a reservoir for the cooled circulating water.

316(b)

Phase II Page 4 of 15 1

1

3.1 Main Condensers '

Each condenser is single pass, triple shell, triple pressure and is designed to remove 8.07 billion Btu/hr. At design conditions the circulating water flow through each condenser is 484,000 gpm, and at design meteorological conditions (730 F wet bulb and 65% relative humidity) the inlet temperature is 870 F and the outlet temperature is 121.80 F. The parts of.the condenser that contact the circulating water are tubes made of stainless steel and tube sheets' and water boxes made of carbon steel. The travel time' of the circulating' water through the condenser, is about 15 seconds.

3.2 Circulating Water Pumps and Piping ,; .

The circulating water system for each unit has four-25% capacity circulating water pumps, which are of the horizontal split case centrifugal type.. Each pump is designed to deliver 121,000 gpm at 103.5-ft total differential head.

The circulating water piping is lined with coal tar epoxy to minimize corrosion.

3.3 Cooling Towers .  ;, .

The towers are of the hyperbolic natural draft counter flow type, 540 ft high by.420 ft base diameter and are located approximately 750 ft apart, (center-to-center).

Cold air enters the bottom of the tower, mixes with the circulating water in the tower fill (water dispersal material), and removes heat from the water and the warm air-water vapor mixture rises to leave the tower at the top. The towers are suitable for year-round operation. Circulating water outlets from the tower basins are protected from ingress -of debris:by screens that are cleaned manually.

Duplicate screens are provided to permit removal of either one for cleaning.

The cooling tower blowdown is discharged through a diffuser directly into the river.

Monitoring instrumentation in the circulating water circuit and the blowdown lines warns if blowdown criteria are being approached.'

The tower blowdown rate is set from the central control room to control the concentration of chemical and dissolved solids in the circulating water. Water lost from the circulating system by tower evaporation,. drift and blowdown is made up by river water supplied from the intake structure..:

Circulating water carrying the heat rejected from the station is brought into direct contact with atmospheric air drawn into thetower by the difference in air densities inside and outside the tower. As the heated water falls through the tower, the incoming air-cools it. The cooler air passing over the warmer water vaporizes a small percentage of the. water, thereby. cooling the remaining water. The air is heated as it flows through the tower. 'The heat exchange between the air and water through direct contact-is derived fromrtwo types of heat transfer: a) the evaporative cooling of the water and b) the sensible heating of the air due to the difference intemperature of water and air.

316(b)

Phase II Page 5 of 15

I I Table 1, Cooling Tower Performance, shows the maximum and minimum water evaporation rates required for the 8 billion Btu/hr waste heat rejection for one unit at full power. This data is based upon the range of meteorology recorded at Avoca, Pennsylvania.

Drift Drift is the water that is entrained in the air discharging from the cooling tower. For the Susquehanna SES towers the manufacturer's guaranteed drift loss is 0.02% of the design circulating water flow. The drift is expected to be approximately 0.002%

of the design circulating water flow.

Drift is minimized by the installation in the tower of "Drift Eliminators." These function by forcing the discharge air carrying the entrained water to make sudden changes in direction; the resulting centrifugal force effectively'separates the drops of water from the air, depositing them .on the surface of the eliminator. The accumulated water droplets coalesce and then flow down to the tower basin.

Fo 11 A visible plume results when the warm moist air discharging from the tower mixes with cooler ambient air that lacks the capacity to absorb all of the moisture. The excess moisture condenses as fog. There is no practical means of preventing the formation of a visible plume in this type-cooling tower.

I Tower Performance The towers are designed to cool 478,000 gpm of circulating water to a temperature of 870 F at an ambient wet bulb temperature of 730 F and a relative humidity of 65%.

The average monthly tower performance for a flow of 478,000 gpm at the average monthly temperatures and humidities is presented in Table 1, Cooling Tower Performance. Also shown for comparison is the cooling tower performance design condition (Case 1) and the maximum (Case 2) and minimum (Case 3) evaporation in Figure 7, Cooling Tower Performance.

In general the flow of the circulating water remains constant through the cooling towers under normal variations in heat rejection loads. During periods of extended L reduced heat rejection loads, it may be desirable to reduce the circulating water flow by shutting off one (or-two in extreme cases) of the circulating water pumps.

In all such cases the evaporation and drift losses are less than the normal 11 operating conditions.

For reasons of power generation efficiency, pumps would not be stopped unless circulating water temperatures could be kept below normal with the reduced flow.

The temperature of the blowdown would be affected by a negligible amount with a reduced number of pumps in operation.

316(b)

Phase II L Page 6 of 15 L

l

The cooling tower has provisions that are used to isolate the center section of the tower during extremely cold weather operation. This is done to direct more warm water toward the periphery of the. cooling tower to prevent freezing in the outside fill sheets.

3.4 Cooling Tower Basin Each tower is located over a circulating water basin-reservoir. The basin inside diameter is 410.5 ft and at normal water level of seven feet contains about seven million gallons. The cooled water from the tower fill rains down uniformly upon the basin surface. The mean time for the 508,000-gpm design rate of cooled water to travel through the seven million-gallon basin is about 15 minutes.

The actual travel time of an increment of water flowing horizontally across the basin' varies from a few seconds to over five hours; depending upon the distance from the point where the water falls to the basin surface to the'circulating water outlet. The increment of circulating water, which is ultimately blown down makes approximately 100 passes across the basin' before it is discharged. The longest of the paths taken by the blowdown water, by which suspended solids are ultimately discharged, determines the suspended 'solids concentration of -the entire circulating water flow.  :,

The settling opportunity provided by the longest flow paths ensures that much of the suspended solids entering with the makeup water will settle in the basin and not appear in the blowdown.

. ~..

The cooling tower basin has high and low level switches that are tied into a flow-modulating valve in the makeup piping." The valve is opened or closed automatically to provide makeup water as necessary for the circulating water system during all meteorological and station operating conditions.

The basin is equipped with ramps to permit earth-moving equipment to enter the' tower basin and remove the accumulation of deposited silt during scheduled shutdowns. ,,.

316(b)

Phase 11 Page 7 of 15

Table 1 COOLING TOiER PEIFORHANCE (Based on One Unit at Full Load) wet  % Evaporation Cold Exit Exit Air Exit Air Sp. Vol Density Bulb Bel. acre Ft Water Air iillion Velocity Ft3/lb lb/Fts nontb"') or Hum. qpn Per 1o. of OF cfa fps Dry hir mixture Jan 22.3 24 9,560 1,307 59.2 77.6 58.7 825 13.99 .0729 Feb 18.5 0 9,480 1,170 57.9 75.2 60.2 846 13.89 .0733 Mar 27.1 15 10,490 1,434 62.0 80.7 56.9 799 14.12 .0724 Apr 35.4 28 11,020 1,458 66.7 86.0 53.5 752 14.35 .0715 fay 48.4 53 11,730 1,603 73.1 92.1 51.7 727 14.65 .0705 June 58.6 67 12,170 1,600 78.4 97.8 49.31 693 14.96 .0695 July 62.4 69 12,340 1,687 80.3 98.7 50.71 713 15.01 .0b94 Auq 63.3 76 12,250 1,674 80.7 99.3 50.4 70d 15.04 .0693 Sept 53.8 72 11,640 1,540 75.3 94.2 52.1 732 - 14.76 .0701 Oct 45.5 63 11,180 1,528 71.1 89.6 54.1 761 14.53 .0709 Nov 35.4 45 10,700 1,415 66.2 85.4 54.4 765 14.33 .0716 Dec 25.5 33 9,870 1,349 61.0 79.8 57.3 805 14.08 .0724

_ _ . ~~~~~ ~~~~ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ -- _ -_ _ - _-- _- _- _ -- _ -_ - _ _- _-__ -__

Desiqn (2) 73 65 13,170 87 104.8 46.4 653 15.37 .0683 Maxisua(31 75 37 14,210 90 108.4 41.5 583 15.61 .0676 fininum(3) 0 100 6,550 46 41.1 70.2 987 13.73 .0740 (1) 'lonthly Performance based upon on site neteorological observations during 1973 to 1975 (2) Selection of dusiqn condition based upon on site aeteoroloqical observations during 1973-1975 (33 Maximum summer evaporation (not the highest vet bulb) and minimum evaporation condition based upon on site m4.teorulu~;y observations durinq 1973 to 1975.

0)

CD -u 00 Sr c, OX

_- CD _

L1. =

6I=

L-

U-A LEVEL o 0 a LACKAWANNA RIVER CONFLUENCE l

WILKE5 BARRE i

.YMOUTH ifICOKE .

ES

.-s11 g Io a

Figure 2 Susquehanna River Profile -

31 6(b)

Phase II Page 10of 15 A l

, , I' Figure 3

! ,, / ..-- Susquehanna River Bathymetry

t';i ' J. /.. - '  ;.- I '!"

316(b)

Phase 11

. , . i.:. .Pagel 1 of 15

316(b)

Phase II Page 12 of 15 A= = I = L I 1 1 I I I W I I I

SECTION A-A (  ;, ,  !

AVERAGE HORIZ.

VELOCITY FPS'

, I * , ~ RIVER VELOCITY tPERPENDICULAR 2.00; TO INTAKE FLOW1 1.30 MAXIMUM 120 1.10 1.00. AVE RAGE

.90 lo0

.70 .

.60

.30

% "e_ ICHANNELIOPEN . _ -

.40

.30 - -_ MINIMUM 20 2CHANNELSOPEN . -- - ---

10 O

-WWATER TRAVEL RELEVANT VELOCITIES SHOWN IN SOLID LINES

'AT MINIMUM WATER LEVEL-39.I00GPM TOTAL FLOW Figure 5 River Intake Structure and Velocity Profile 316(b)

Phase II Page 13 of 15

U-L INTAKE STRUCTURE I SY-.AST.

I PLAN I - a-

.3yz[~

, I,.

-EL.472-G

-EL 4 64' 5' 10 ELEVATION A-A Figure 6 River Intake Structure Wing Walls 316(b)

Phase II Page 14of 15

NATURAL DRAFT COOLING TOWER PERFORMANCE CURVES-COLD WATER TEMPERATURE COLD WATER IN FUNCTION OF WET BULB AIR TEMPERATURE TEMPERATURE 0F AND RELATIVE HUMIDITY 100 A 90 80 70 60 50 10 20 30 40 50 60 70 80 WET BULB AIR TEMP OF TOTAL WATERFLOW: 478,000 GPM Figure 7 Cooling Tower Performance 316(b)

Phase II Page 15 of 15

Appendix B Preparedness Prevention and Contingency (PPC) Plan (Includes SPCC Plan)

NPDES RENEWAL APPLICATION PERMIT NO. PA 0047325 January 6, 2005 PPL Susquehanna, LLC (2 Copies provided to PaDEP with Original Application)

(PPL distribution, see Nuclear Department Waste and Chemical web site for copy of PPC Plan)