ML22143A842

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27 - Zorita Ril
ML22143A842
Person / Time
Issue date: 05/25/2022
From: Matthew Hiser, Pat Purtscher, Robert Tregoning
NRC/RES/DE
To:
Kalikian R, 301-415-5590
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Download: ML22143A842 (14)


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RIL 2022-05: NRC Technical Assessment of Zorita Materials Testing Results Matthew Hiser, Patrick Purtscher, Robert Tregoning NRC Office of Nuclear Regulatory Research May 25-26, 2022 Annual NRC-Industry Materials Exchange Meeting

Summary

  • EPRI led a cooperative effort to harvest reactor internals from a decommissioning plant in Spain known as the Zorita reactor

- Effort included NRC and other international participants

  • Materials harvested from Zorita included:

- Baffle plate materials with fluences up to ~50 displacements per atom (dpa)

- Core barrel weld and heat-affected zone (HAZ) materials with fluences up to ~2 dpa

  • NRC technical assessment of Zorita materials testing results was recently published: RIL 2022-05 2

Zorita Background and Context

  • Zorita reactor internals characteristics:

- 160 MWe Westinghouse-designed single loop PWR

- Operated for 26.4 effective full-power years

- Internals fabricated with Type 304 austenitic stainless steel (SS)

- Operated at a fairly low temperature for a PWR (<330°C max compared to

>360°C at many PWRs)

  • Fabrication records for the internals could not be found

- Compositional and microstructural analysis of weld and plate show expected results for 304 SS plate and 308 SS weld metal

  • Highly representative of the SS internals in operating U.S. plants

- Based on design, aging conditions, and known fabrication information

Overview of Zorita Research Programs Key Takeaways from Zorita Testing

  • Baffle plate materials

- Very low amount of observed void swelling

- Repeated observations of high crack growth rate (CGR) during irradiation-assisted stress corrosion cracking (IASCC) CGR testing

- Tensile, crack initiation, and fracture toughness (FT) data as expected based on literature data

  • Core barrel weld materials

- Very low FT values observed in multiple tests

- Tensile and CGR data as expected based on literature data

Void Swelling Results Void Swelling Takeaways

  • Swelling results correlate more strongly with temperature than fluence, consistent with literature data
  • Results are an encouraging sign that void swelling may not progress rapidly in LWRs

- Due to lower temperature (<330°C), Zorita results do not conclusively eliminate the potential for significant void swelling, particularly at higher temperatures

  • Additional LWR-irradiated materials at higher temperatures should be studied to more confidently assess void swelling for extended plant operation

High Fluence IASCC CGR Results High Fluence IASCC CGR Takeaways

  • NRC staff have carefully analyzed the Zorita plate CGR results

- Conditions leading to high CGRs are K > 15 MPam and fluence >25 dpa

- High CGR data are representative of the IASCC susceptibility at elevated fluence

  • Other factors to consider:

- Zorita data likely from one heat of material - heat-to-heat variability

- Low operating stresses and irradiation-induced stress relaxation

  • Additional data from SMILE should help improve understanding

SS Weld Fracture Toughness Results SS Weld Fracture Toughness Takeaways

  • BWRVIP-100, Rev. 1-A criteria for irradiated SS FT are not bounding of the Zorita weld data or data from ANL on a cancelled BWR core shroud

- Zorita HAZ data are approximately bounded by the BWRVIP-100 criteria

  • Regulatory Activities

- In March 2021, EPRI notified the NRC of a Part 21 notification about the potential nonconservatism in BWRVIP-100, Revision 1-A (ML21084A164)

- In November 2021, NRC released a LIC-504 assessment of the BWRVIP-100 non-conservatism issue (ML21312A543) finding no immediate safety issue

SS Weld Fracture Toughness Takeaways

  • SS Weld Materials

- SS weld materials (including Zorita) show strong resistance to IASCC crack growth

- Low weld FT most relevant to pre-existing fabrication flaws or slowly growing SCC flaws

- Zorita data remain approximately bounded by BWRVIP-100, Rev. 1-A criteria

- Operating experience shows flaws are more likely to form in this region

  • Additional data from SMILE and other potential harvesting should help improve understanding

Future Work

  • Seeking additional data on harvested irradiated SS materials in key areas:

- Low dose (<2 dpa) SS weld to validate Zorita FT results

- Higher dose (2-20 dpa) SS weld to assess FT and IASCC performance at higher fluences

- High dose (>20 dpa) and high temperature (~360°C) SS plate to assess CGR and void swelling behavior

  • SMILE project will help to address each of these interests:

- SS weld material above and below 2 dpa

- SS plate material up to ~50 dpa at a higher temperature than Zorita

Acronym List

  • ANL Argonne National Laboratory
  • MWe Megawatt-electric
  • ASME American Society of Mechanical
  • NEA Nuclear Energy Agency Engineers
  • NWC Normal water chemistry
  • BWR Boiling water reactor
  • OECD Organization for Economic Co-operation
  • BWRVIP Boiling Water Reactor Vessel and and Development Internals Project
  • PWR Pressurized water reactor
  • CGR Crack growth rate
  • EPRI Electric Power Research Institute
  • FT Fracture toughness
  • HAZ Heat-affected zone
  • SEM Scanning electron microscopy
  • SMILE Studsvik Materials Integrity for Life Extension
  • IASCC Irradiation-assisted stress corrosion
  • SS Stainless steel cracking
  • TEM Transmission electron microscopy
  • WCAP Westinghouse Commercial Atomic Power
  • K Applied stress intensity factor
  • ZIRP Zorita Internals Research Project
  • MRP Materials Reliability Program