ML20238A410

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Radiological Regional Environ Monitoring Program,Rept 11, Jan-Dec 1975
ML20238A410
Person / Time
Site: Peach Bottom  Constellation icon.png
Issue date: 12/31/1975
From:
RADIATION MANAGEMENT CORP. (RMC)
To:
References
10999, NUDOCS 8708310066
Download: ML20238A410 (283)


Text

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PEACH BOTTOM ATOMIC POWER stall 0N FULTON GENERATING STATION Radiological Regional Environmental -o Monitoring Program g

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4 , January 1; 1975 Through December 31,19759 kby %qo,s $ 'yc in P:epared For Philadelphia Electric Company .g By f-Pe,", RADIATION MANAGEMENT CORPORATION C,, p ,? t

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t PEACH BOTTOM ATOMIC POWER STATION FULTON GENERATING STATION Radiological Regional Environmental Monitoring Program , Report #11 January 1,1975 Through December 31,1975 1 r Prepared For i Philadelphia Electric Company By I RA0IATION MANAGEMENT CORPORATION University City Science Center 3508 Market Street Philadelphia, Pa.19104 July 1976 i i

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TABLE OF CONTENTS PAGE , i I. INTRODUCTION A.. Program Objectives 1 B. Program Implementation 2 { C.- Special Study 2 II. RMC PROGRAM DESCRIPTION A. Sample Collection & TLD Placement 3 I l Procedures ) l l B. Program Changes 5 J C. Atlalyses Performed 6 l l D. Exceptions to the Program 6 III. RESULTS AND DISCUSSION A. . Data Interpretation 6 Statistical 8 Analysis l B. Discussion of Results 9

1. Surface Water 9 f ]

l l 2. Discharge Water 11

3. Well Water 13
4. Precipitation 14
5. Milk 14
6. Fish 18
7. Plankton 19
6. Vegetation 19
9. Soil 19
10. Ambient Gamma Radiation 21 IV.

SUMMARY

AND CONCLUSIONS i J

V. TABLES VI. FIGURES VII. SPECIAL STUEY APPENDIX A - ANALYTICAL PFOCEDURES j APPENDIX B - STATISTICAL NETHODS l l l 1 l 11 l

LIST OF TABLES TABLES I. RMC Station Resignation and Sample Identification System II. RMC Sample Collection and Analysis Program III. Summary of Analysis Performed on Samples Collected l During 1975 j IV. Summary of Radioactivity Concentrations V. Summary of Gamma Spectrometry VI. Summary of Ambient Dosimetry Program VII. Concentrations of Aqueous Tritium in Surface Water (Total Sanple) VIII Concentrations of Alpha Emitters in Surface Water (Soluble Fraction) IX. Concentrations of Alpha Emitters in Surface Water (Insoluble Fraction) X. Concentrations of Beta Emitters in Surface Water (Soluble Fraction) XI. Concentrations of Beta Emitters in Surface Water (Insoluble Fraction) XII. Concentrations of Potassiur. -40 in Surface Water (Soluble Fraction) X11I. Concentrations of Gamma Emitters in Surface Water (Soluble Fraction) XIV. Gamma Spectrometry of Surface Water (Soluble Fraction)

             - Minimum Detectable levels of Nuclides Searched for but not Found XV.         Concentrations of Gamma Emitters in Surface Water (Insoluble Fraction)

XVI. Gamma Spectrometry of Surface Water (Insoluble Fraction) - Minimum Detectable Levels of Nuclides Searched for but not Found lit L__ _ _ .

LIST OF TABLES (Cont. ) TABLES XVII. Concentrations of Aqueous Tritium in Dircharge Water (Total Sample) XVIII. Concentrations of Beta Emitters in Discharge Water (Soluble Fraction) XIX. Concentrations of Beta Emitters in Discharge Water (Insoluble Fraction) XX. Concentrations of Fotassium-40 in Discharge Water (Soluble Fraccion) XXI. Concentrations of Gamma Emitters in Discharge Water (Soluble Fraction) ) XXII. Gamma Spectrometry of Discharge Water (Soluble Fraction) - Minimum Detectable Levels of Nuclides Searched for but not Found XXIII. Concentrations of Gamma Emitters in Discharge Water (Insoluble Fraction) XXIV. Gamma Spectrometry of Discharge Water (Insoluble Fraction) - Minimum Detectable Levels of Nuclides Searched for but not Found XXV. Concentrations of Aqueous Tritium in Well Water (Total Sample)

 'XXVI. Concentrations of Beta Emitters in Well Water (Soluble Fraction)

XXVII. Concentrations of Beta Emitters in Well Water (Insoluble Fraction) XXVIII. Concentrations of Gamma Emitters in Well Water (Total Sample) XXIX. Gamma Spectrometry of Well Water (Total Sample) - Minimum cetectable Levels of Nuclides Searched for but not Found XXX. Concentration and Surf ace Density of Aqueous Tritium in Precipitation (Total Sample) XXXI. Concentration and Surface Censity of Beta Emitters in Precipitation (Total Sample) iv

LIST OF TABLES (Cont.) TABLES XXXII. Concentrations of Aqueous Tritium in Milk XXXIII. Concentrations of Organic-bound Tritium in Milk XXXIV. Concentrations of Iodine-131 in Milk (Total sample) ' XXXV. Concentrations of Iodine-131 in May 5 Milk Sample at Farm D XXXVI. Concentrations of Aqueous Tritium in Fish (Edible Portion) XXXVII. Concentrations of Organic-bound Tritium in Fish (Edible Portion)  ; l XXXVIII. Concentrations of Beta Emitters in Plankton i XXXIX. Concentrations of Tritium in Vegetation > XL. A Comparison of Tritium Concentrations in Varicus Media XLI. Concentrations of Alpha Emitters in Soil XLII. Concentrations of Strontium-89 and Strontium-90 in Soil XLIII. Concentrations of Gamma Emitters in Soil ) l XLIV. Gamma Spectrometry of Soil - Minimum Detectable Levels I of Nuclides Searched for but not Found XLV. Monthly TLD Results 1

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XLVI. Quarterly TLC Results l XLVII. Semi-Annual TLD Fe sults XLVIII. Mean Monthly, Quarterly, and Semi-Annual TLD Results for the Site Boundary, Middle, and Outer Rings XLIX. Gamma Spectrometry of Special Samples Taken at Station 23 L. Special Study TLD Measurements l l l 1 V l l 1

LIST OF FIGURES FIGURE 1 Environmental Sampling Stations on or near Peach Bottom Site 2 Environmental Sampling Stations at Intermediate Distances from Peach Bottom Site 1 3 TLD Stations en Peach Bottom Site 1 4 TLD Stations at Intermediate Distances from Peach I Bottom Site 5 TLD Stations at Remote Distances from Peach Bottom Site 6 A Comparison of Aqueous Tritium Concentrations in Surface Water at Conowingo and Holtwood Dams (Total Sample-Grab) 7 A Comparison of Aqueous Tritium Concentrations in Surface Water at Conowingo and Holtwood Dams (Total Sample- Composite) 8 A Comparison of Aqueous Tritium Concentrations in Surface Water at Conowingo Dam with Depth (Total Sample-Grab) 9 A Comparison of Aqueous Tritium Concentrations in Surface Water at Chester Water Intake-Pond and Holtvood , Cam (Total Sample-Grab) 10 A Ccmparison of Gloss Alpha Concentrations in Surf ace Water at concwingo and Holtwood Dams (Soluble Fraction-Grab) 11 A Comparison of Gross Alpha Concentrations in Surface Water at Conowingo and Holtwood Dams (Insoluble i Fraction-Grat) l 12 A Comparison cf Gross Alpha Concentrations in Surface Water at Conowingo and Holtwood Dams (Soluble Fraction-Composite) 13 A Ccmparison of Gross Alpha Concentrations in Surface Water at Conowingo and Holtwood Dams (Insoluble Fraction- Composite) i l vi i

l I l LIST OF FIGURES (Cont. ) 1 FIGURE l 14 A Ccmparison of Gross Beta Concentrations in Surf ace Water at Conowingo and Holtwood Dams (Soluble Fraction-Gritb) i l 15 A Comparison of Gross Beta Concentrations in Surface i Water at Conowingo and Holtwood Dams (Insoluble Fraction-Grat) l 16 A Comparison cf Gross Beta Concentrations in Surface Water at Conowingo and Holtwood Dams (Soluble Fraction-Composite) 1 17 A Comparison of Gross Beta Concentrations in Surf ace l Water at Conowingo and Holtwood Dams (Ins oluble Fraction-Composite) l l 18 A Comparison cf Gross Beta Concentrations in Surface Water at Conowingo Dam with Depth (Soluble l Fractien-Grab) l 19 A Comparison of Gross Beta Concentrations in Surf ace Water at Conowingo Dam with Depth (Insoluble l Fraction-Grab) ' i 20 A Comparison cf Gross Beta Concentrations in Surface l Water at Chester Water Intake Fond and Holtwood Dam ' f (Soluble Fraction-Grab) 21 A Comparison of Gross Beta Concentration in Surface Water at ChEster Water . Intake Pond and Holtwood Dam j (Insoluble Fraction-Grab) 1 22 A Comparison of Potassium-40 and Gross Beta Concentrations in Surf ace Water at Holtwood Dam (Soluble Fraction-Grab) 23 A Comparison of Potassium-40 and Gross Beta Concentrations in Surf ace Water at Holtwood Cam (Soluble Fraction-Composite) 24 A Comparison of Potassium-40 and Gross Beta Concentrations in Surf ace Water at Conowingo Cam (Soluble Fraction-Grab) 25 A Ccmparison of Potassium-40 and Gross beta Concentrations in Surface Water at Conowingo Cam (Soluble Fraction-Composite) vii

l LIST OF FIGURES (Cont. ) FIGURE 26 Aqueous Tritium Concentrations in Discharge Water at l Feach Bottom Unit #1 Screen Well Discharge (Total Sample Composite) 27 A Comparison of Aqueous Tritium Concentrations in l Discharge Water at Discharge Canal 2200 ft. and Canal Discharge (Ictal Sample-Grab) , 28 A Comparison of Aqueous Tritium concentrations in Water I at Peach Bottom Units #2 and #3 Intake and Discharge (Total sample-Grab) 29 A Comparison of Aqueous Tritium Concentrations in Water at Peach Bottom Unit #1 Intake and Discharga (Total Sample-Grab) 30 A Comparison of Average Aqueous Tritium Concentrations in Surface Water and Discharge Water at all Grab Sample l Stations (Total Sample) 31 Gross Beta Concentrations in Discharge Water at Peach Bottom Unit #1 Screen Well Discharge (Soluble l Fraction-Composite) 32 Gross Beta Concentrations in Discharge Water at Peach Bottom Unit #1 Screen Well Discharge (Insoluble Fraction Composite) 33 A Comparison of Gross Beta Concentrations in Discharge Water at Discharge Canal 2200 ft, and Canal Discharge (Soluble fraction-Grab) 34 A Comparison of Gross Beta Concentrations in Discharge  ! Water at Discharge Canal 2200 ft. and Canal Discharge (Insoluble Fraction-Grab)  ; 35 A Comparison of Gross Beta Concentrations in Water at Peach Bottom Units #2 and #3 Intake and Discharge l (Soluble Fraction-Grab) j l 36 A Comparison of Gross Beta Concentrations in Water at Peach Bottom Units #2 and #3 Intake and Discharge (Insoluble Fraction-Grab) 37 A Comparison of Gross Beta Concentrations in Water at Peach Bqttom Unit #1 Intake and Discharge (Soluble Fraction-Grab) l l 1 l viii l l 1 ( 1 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ - - t

1 LIST OF FIGURES (Cont. )  ; i FIGURE  ! 38 A Comparison of Gross Beta Conc'ntrations e in Water at  ! Peach Bottom Unit #1 Intake and Discharge (Insoluble  : Fraction-Grab) l 39 A Comparison of Average Gross Beta Concentrations in Surface Water and Discharge Water at all Grab Sample . Stations (Soluble Fraction) 40 A Comparison of Average Gross Beta Concentrations in Surface Water and: Discharge Water :at 'all ' Grab Sample Stations (Insoluble Fraction) 41 A Comparison of Potassium-40 and Gross Beta Concentrations in Discharge Water at Peach Bottom Unit

        #1 Screen Well Discharge (Soluble Fraction-Composite) 42     A Comparison of Potassium-40 and Gross Beta Concentrations in Discharge Water at Discharge Canal 2200 ft.   (Soluble Fraction-Grab) 43     A Comparison of Potassium-40 and Gross Beta l

Concentrations in Discharge Water at Canal Discl.arge (Soluble Fraction-Grab) 44 A Comparison of Potassium-40 and Gross Beta l Concentrations in Discharge Water at Peach Bottom Unit

        #1 Discharge (Soluble Fraction-Grab) 45     A Ccmparison of Average Potassium-40 concentrations in                       i Surface Water and Discharge Water at all Grab Sample Stations (Scluble Fraction) 46     A Ccmparison of Average Aqueous Tritium Concentrations in Well Water at On-Site Wells, Site Area Wells, and Distant Wells (Total Sample-Grab) 47     A Ccmparison of Average Gross Beta Concentrations'in                         ,

Well Water at On-Site Wells, Site Area Wells, and l Distant Wells (Soluble Fraction-Grab) 48 A Comparison of Average Gross Beta Concentrations in l Well Water at On-Site Wells, Site Area Wells, and Distant Wells (Insoluble Fraction-Grab) 49 Aqueous Tritium Concentration in Precipitation at Peach Bottom Weather Station #1 (Total Sample-Composite) ix

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                 . LIST OF FIGURES (Cont.)                      ;
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FIGERE i 50 Aqueous Tritium Surface Density in Precipitation at l Peach Bottom Heather Station #1 (Total Sam 91e-Composite) 51 Gross Beta Concentrations in Precipitation at Peach Bottom Weather Station #1 (Total Sample-Composite) 52 Gross Beta Surface Density in Precipitation at Peach Bottom Weather Station #1 (Total Sample-Composite) 53 A Comparison of Average Aqueous Tritium concentrations in Milk at Near, Intermediate and Distant Farms 54 A comparison of Average Crganic-bound Tritium Concentrations in Milk at Near, Intermediate, and Distant Farms 55 A comparison of Averas 3 Crganic-bound Tritium Concentrations in Milk at Near, Intermediate, and Distant Farns  ! 56 A Comparison of Average Aqueous Tritium Concentrations in Milk at Near, Intermediate and Distant Farms 57 A Comparison of Average Organic-bound Tritium concentrations in Milk at Near, Intermediate, and Distant Farms 58 A Comparison of Average Tritium Concentrations in Milk at All Farms 59 A Comparison of Average Iodine-131 Concentrations in Milk at Near, Intermediate and Distant Farms (Total Sample)

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60 Iodine-131 Concentrations in Milk at Farm D 61 l A Ccmparison of Average Aqueous Tritium concentrations  ! in White Crappie Fish in conowingo and Holtwood Ponds 62 A Comparison of Average Organic-bound Tritium f Concentrations in White Crappie Fish at Conowingo and i Holtwood Ponds 63 A Comparison of Average Organic-bound Tritium I ConcentratiGus in White Crappie Fish at Conowingo and Holtwood Ponds j i X l k l l

LIST OF FIGURES (Cont. ) FIGURE 64 A Comparison of Average Aqueous Tritium Concentrations in Channel Catfish at Cenowingo and Holtwood Ponds l 65 A Ccmparison of Average Organic-bound Tritium J Concentrations in Channel Catfich at Conowingo and Holtwood Ponds 66 A Comparison of Average Organic-bound Tritium Concentrations in Channel Catfish at Conowingo and Holtwood Ponds 67 A Comparison of Aqueous Tritium Concentrations in White Sucker Fish at Peters Creek and Pequea Creek 1 68 A Ccmparison of Organic-bound Tritium Concentrations in l White Sucker Fish at Peters Creek and Pequea Creek 69 A Comparison cf Organic-bound Tritium Concentrations in l White Sucker Fish at Peters Creek and Pequea Creek 70 A Ccmparison of Tritium concentrations in Variouc Nedia 71 A Ccmparison of Grons Alpha Concentrations in Soil Top One Inch and Ecttom Cut at Peach Botton 1300 Sector Hill 72 A Comparison cf Gross Alpha Concentrations in Soil Top One Inch and Bottom Cut at Delta, Pa. Substation 73 A Comparison cf gross Alpha Concentrations in Soil Top One Inch and Bottom Cut at Wakefield, Pa. 74 A Comparison of Average Gross Alpha Concentrations in the Top One Inch at On-site Soil Locations and Distant Soil Locations 75 A Ccmparison of Average Gross Alpna Concentrations in the Botton cut at on-Site Soil locations and Cistant Soil Locaticns 76 A Comparison cf Strontium-90 Concentrations in Soil Top One Inch and Bottom Cut at Peach Bottom 1300 Sector Hill 77 A Ccmparison of Strontium-90 concentrations in Soil Top One Inch and Bottom Cut at Delta, I s. Substation xi

l LIST OF FIGURES (Cont. ) l FIGURE 78 A Comparison.of Strontium-90 Concentrations in Soil Top One Inch and Bottom Cut at Wakefield, Pa. 79 A Comparison of Average Strontium-90 concentrations in the Top One' Inch at On-Site Soil Locations and Distant ] ( Soil locations 80 A comparison-of Average Strontium-90 Concentrations in the Bottom Cut at on-Site soil Locations and Distant , I Soil Locaticas l 81 A Comparison of Strontium-89 Concentrations in Soil Top One Inch and Bottom Cut at Peach Bottom 1300 Sector-Hill I 82 A Ccmparison of Strontium-89 Concentrations in Soil Top One Inch and Bottom Cut at Celta, Pa. Substation 83 A Comparison of Strentium-89 Concentrations in Soil Top One Inch and Bottom Cut at Wakefield, Fa. 84 A Comparison of Average Strontium-89 Concentrations in-the Top One. Inch at On-Site Soil Locations and Distant Soil Locations 85 A Comparison of Ave.page Strontirm-89 Concentrations in-the Bottom Cut at On-Site Soil L :ations and Eistant Soil Locations 86 A Ccmparison of Cesium-137 Concentrations in soil Top One Inch and Bottom Cut at Peach Bottom-1300 Sector Hill 87 A Comparison cf Cesiur -137 Concentrations in Soil Top One Inch and Bottom Cut at Delta, Pa. Substation f 88 A Comparison of Cesium-137 Conceittrations in Soil Top One Inch and Bottom Cut at Wakefield, Va. 89 A Comparison cf Average Cesium-137 Concentrations in the Iop One Inch at On-Site Soil Locations and Distant Soil Locations 90 A Comparison of Average-Cesium-137 Concentrations in I the Bottom Cut at On-Site Soil Locations and Listant Soil Locations l xii )

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LIST OF FIGURES (Cont. ) FIGURE 91 A Comparison of Average Monthly TLD Results at the Site  ! Boundary, Middle, and Outer Rings 92 A Comparison cf Average Quarterly TLD Results at the ~ Site Boundary, Middle, and Outer Rings 93 A Comparison of Average Semi-Annual TLD Results at the site Boundary, Middle, and Outer Rings 94 Monthly TLD Results at Plant Complex Stations l 95 Special Study TLD Stations Near Peach Bottom Plant Complex 96 Monthly TLD Results at Special Study 7LD Stations 1 97 Monthly . TID Results at Special Study TLD Stations xiii

9 k . t j 'i 1 I i I. INTRODUCTION 1 1

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I. INTRODUCTION l Radiation Management Corporation (RMC) began conducting a radiological environmental'.ronitoring program in' September'1970 for the Philadelphia Electric Company in connection with the, . Peach Bottom Atomic Power Station (PBAPS) located in Peach Bottom j Township, York County, Pennsylvania. This RMC program j supplements an existing program being conducted by others which l has been carried out since March 1960. PBAPS is located along 1 the Susquehanna River, between Holtvood and Conowingo Dams which -l are about 14 miles apart. The pond created by Conowingo Dam is' 1

 -called Conowingo.. Pond.                 .

The initial loading of fuel into Peach Bottom Unit # 1, a 40 MWe . (Net) high temperature gas-cooled reactor, was started on February 5, 1966, and initial criticality was achieved March 3, l 1966. Final shutdown of Peach Bottom Unit #1 was on October 31, 1974. Peach Bottom Units #2 and #3 are. boiling water reactors I each with a power output of 1050 MWe (Net) . The first fuel was loaded into Unit #2 on August 9, 1973, and criticality was first achieved on september 16, 1973. The first fuel was loaded into Unit #3 on July 5, 1974 and criticality was first achieved on August 7,1974. Peach Bottom Unit 2 first reached full power on June 16, 1974 Peach Bottom Unit 3 first reached full power on  ; December 21, 1974. Since the Philadelphia Electric Company's proposed Fulton j Generating Station, consisting of two 1100 MWe (Net) reactors, is located across Conowingo Pond from the Peach Bottom Atcmic Power Station, its preoperational radiological monitoring program has i been combined with the Feach Bottom program to form a joint Peach Bottom-Pulton Regional Radiological Environmental Monitoring ) Program. Results of the RMC portion of the overall regional radiological environmental monitoring program are reported in semi-annual and annual reports. This report contains data from samples collected from January 1, 1975, through. December 31, 1975. A special preoperational report 1 for Peach Bottom Units #2 and #3 I has been issued previously which summarizes results of all analyses performed by EMC on samples collected from the start of the RMC pertion of the overall program through August 8, 1973, the day before fuel was first loaded into Peach Bottom Unit 2. 1 A. PRCGRAM CBJECTIVES

1. Identify, measure, and evaluate existing l

radionuclides in the environs of the Peach Bottom-Fulton sites and any fluctuations in radioactivity , levels which may occur. ' 1

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2. Monitor and evaluate ambient radiation levels.

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3. Determine, within the , scope of the program, any measurable quantity of radioactivity introduced to j the environment by the operation of the Peach j Bottom Atomic Power Station. l
4. Supplement other existing radiological environinental monitoring programs at Peach Bottom Atomic Power Station.
5. Establish pre-operational . radiation levels in environmental media for Fulton Generating Station.

B. PROGRAN IMPLEMENTATION In order to achieve these objectives, Radiation Management Corporation performed the following analyses on samples collected during the period of this report. i

1. Measured and evaluated concentrations of tritium in surface water, discharge water, well water, i precipitation, milk, fish, and vegetation.
2. Measured and evaluated concentrations of alpha emitters in surface water and soil.
3. Measured and evaluated concentrations of beta emitters in surf ace water, discharge water, precipitation and plankton.
4. Measured and evaluated concentrations of t

potassium-40 in surface water and discharge water.

5. Identified, measured and evaluated gamma emitting ]

radionuclides in surface water, discharge water, j well water, and soil.  ! I

6. Measured and evaluated low level concentrations of 131I in nilk.
7. Measured and evaluated concentrations of e'Sr and {

90Sr in soi].

8. Measured ambient radiation levels in the environment and evaluated the variations with time and location with respect to the site.

C. SPECIAL STUDY A special study was undertaken to determine the source of the increased dose rates observed at TLD station 1K. The initial findings are discussed in section VII. 2 1

l l l l l II. RMC PROGRAM DESCRIPTION

II. RMC PROGRAM DESCitIPTION A. S AMPLE CCLLECTION AND TLD PLACEMENT PROCEDURES The program being conducted by RMC is described in tables I and II and ligures 1-5.

1. Sample Collection
a. Water (except precipitation)

All samples were collected by consultants to the Philadelphia Electric Company except samples frora Station 1S, which were collected by Philadelphia Electric Company personnel. All samples were collected in new two gallon polyethylene bottles. All persons involved in sample collection and handling were advised not tu wear tritium luminous dial watches in order to avoid possible cross contamination from that source. Sample containers were rinsed at least twice with the water to be sample 6 before collection. All water samples were grab samples oncept those collected at stations 1S, 6I and 4L. Weekly samples were taken from a tank which continually collects a sample at stations 4L and 6I. These 1 were composited into a monthly sample for analysis. Station is was sampled from a continuous sample tank prior to liquid radwaste discharge from PBAPS Unit #1 and these samples were composited into monthly sample. Collection methods are deseeribed in more detail in table II, Section V.

b. Precipitation I Precipitation was collected in an apparatus i
consisting of a new polyethylene bottle with a j plastic funnel 8 inches in diameter. The bottle t

was replaced monthly and the sample bottle was shipped to RMC for analysis. The amount of precipitation was recorded continuously by a separate rain gauge at the saac location.

c. Milk Milk samples were collected in new two gallon  !

polyethylene bottles from the bulk tank at each i farm and chipped immediately. No preservative was added. l l l 3 l 1 t l l f

d. Fish Fish samples were collected by Ichthyological Associates, sealed in plastic bags immediately after collection, frozen, and shipped to RMC. No preservative was added.
e. Plankton Plankton samples were collected using a plankton net, sealed in a polyethylene bottle and shipped to RMC.
f. Vegetaticn Samples of vegetation were collected, sealed in plastic bags, and shipped to RMC. No preservative was added.
g. Soil Soil samples consisting of seven cores, 2" in diameter and 6" deep were collected from a 50 x 50 ft. area. Top soil (upper 1 inch) and bottom soil (lower 5 inches) were separated, then sealed in separate nlastic bags, and shipped to RNC.
2. TLD Flacement A system using thermoluminescent dosimeters (TLDs) was used to measure the direct radiation levels in the PBAPS environment. The TLD stations were placed on and around the Peach Bottom site using the "three ring concept". Three on-site stations were not included in any of the three rings and were called plant-complex stations,
a. A site boundary ring near the site perimeter, representing fencepost doses, i.e., at locations where the doses are greater than maximum cff-site doses from plant releases; b ,. A middle ring extending to approximately 10 miles from the site, designed to measure possible ,

exposures to close-in population.

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c. An outer ring extending from approximately 10 to  !

about 60 miles f rom the site, and considered not to be affected by station releases; i

d. The specific location of each station was determined by the following criteria:

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(1) The presence of relatively densely populated areas; (2) Areas where estimated annual' dose from the station, if any, would be more significant, calculated from site meteorological data taking .I into account distance and elevation for each of  ! the 36 ten-degree sectors around the site; (3) On hills and (where practical) within aight of the j stack, and free from local obstructions; i 1 (4) Near the closest house'to the stack in the prevailing downwind direction. I l

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e. Bach TLD set (4 TLDs per set) was placed in a i

sealed polyethylene package to verify the l integrity of the dosimeters when collected. Three i l packages were kept in a locked formica " birdhouse" or polyethylene jar, about six feet above the ground or supporting surface at each location. At each station one package was exchanged for l measurement on a monthly schedule, one en a l quarterly schedule and one on a semi-annual schedule. B. PROGRAM CHANGES

1. Sampling )

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a. Surface Water - One station, designated as 6I, was '

added to the program January 5, 1975. This station is located at Holtwood Dam and is sampled l fro;n a tank which continuously collects a sample, I as described in table II, section v.

b. Milk - Samples were collected on a monthly basis until March 17, 1975, when weekly sampling was l reinstituted to coincide with the beginning of the j casture season.
c. Milk - Farm K was not sampled after July 21, 1975. I because the f armer went out of the dairy business. i Farm L was not sampled after July 14, 1975 because the farmer vacated the property and there was no dairy herd tc be sampled for the remainder of 1975. Farm E was added to the program October 16, i 1975 as c distant regional farm and sampled quarterly.

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d. ' Fish - One station, 6J, was established as: an alternste station in'Holtwood Pond because fish wel e not availab10 at station 6H. The first samples were collected at station 6J on July 1, 1375.
e. Plankton - One station, designated as 4G,.was .i added to the program September 30,.1975. This I sample is collected monthly (unless ice conditions j exiet) from Conowingo Pond, just upstream of )

Conowingo Dam. l I

2. AlmLYSES Beginning with samples collected in.1976, the minimum detectable level for gross beta analyses was lowered because of a procedure change (see Appendix A). This affects composite sampics collected in 1976, but representing 1975 and:

included in this report. C. ANALYSES PEREORMED The schedule of ' analyses performed by RMC is i listed by sample type in table II. This schedule l was followed except where notedL below. Table III-  ! lists the type and number of analyses performed  ; during this period by. sample type and station , location. Methods used in performing these I analyses can be found in Appendix A. D. EXCEPTIONS TO THE PROGRAM i

1. . Discharge water samples from 1S were not taken from November 21, 1974, until February 5, 1975.
2. Fish sanples could not be obtained from Holtwood ]

Pond (Station 6H) and Pequea Creek (Station 25A, J B, C or C) during the first quarter because of a scarcity of fish resulting from high velocities during that time period. Samples could not be obtained from Pequea creek during the third quarter, again because of a scarcity of fish.

3. Two additional milk samples were taken from farms L, M and N on May 12, 1975 and May 19, 1975 to .

provide additional information af ter the detection 1 of 131I in milk at one sampling _ location. 6 I l ___ _ _ - _ - _ - _ _ - _ - _ _ _ _ _ - _ - _ _ _ _ _ .\

4. Monthly TLDs from Station 23 were stolen after installation on January 5, 1975, therefore, no results are available for that month.
5. Monthly and quarterly TLDs were destroyed at station 22 by vandals after they were installed on April 6, 1974, therefore no results are available for April and the second quarter.
6. Semi-annual TLDs were missing from station 23 after installation July 13, 1975, therefore, no results are available for the second semi-annual period.
7. Monthly TLDs were missing from station 19 after installation on September 7, 1975 and November 2, 1975, therefore, no results are available for  ;

these months.  !

8. The TLD shelter at station 22 was destroyed by gunfire following the November 2, 1975 TLD installation. The semi-annual TLCs were missing.

The monthly TLDs at the same station were stolen l after the December 7, 1975 installation. Since no l shelter was available on December 7, 1975, the l TLDs were taped to the pole until a new shelter l l was installed a short time later. No results are  ; available for November or December and for the second semi-annual period.

9. Special vegetation and soil samples were taken at station 23, on August 16, 1975, in connection with anomalous TLD readings.

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III. RESULTS AND DISCUSSION i l l

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III. RESULTS AND DISCUSSION A. DATA INTERPRETATION AND STATISTICAL ANALYSIS Several factors are important in the interpretation of the data. In order to avoid undue repetition in the discussion which follows, these factors are described below.

1. Grab Sampling Grab sampling is a useful and acceptable procedure for taking environmental samples of a medium in which the concentration of radionuclides is i expected to vary slowly with time or where l intermittent sampling is deemed sufficient to l establish the radiological characteristics of the l medium. This method, however, is only representative of the sampled medium for that I specific location and instant of time. As a  !

I result, variation in the radionuclides concentrations of the samples will normally occur. l Since these variations will tend to counterbalance i one another, the extraction of averages based upon l repetitive grab samples is valid. l

2. Minimum Detectable Levels (MDL) l It is characteristic of environmental monitoring i data that many results occur at or belcw the  !

specified detection level. Formal statistical i error analysis of groups of such data is { difficult. Pragmatic approaches to the problem I include counting the detection level entries as zero, a's half the detection level value, or as . full detection level value. For' reporting and l calculation of averages, any result occuring at or below the minimum detectable level is considered to be at that level. Averages obtained using this , method are therefore biased high. Detectable l levels are defined in Appendix A by analysis type. j

3. Standard Deviation of Analytical Results Within the data tables an approximate 95% (2 ,

sigma) confidence interval is supplied for those i data points at and above the mininum detectable level. These intervals represent the range of values into which 95% of repeated analyses of the sample would fall. 8 i _. _ ___ D

1

4. Table Means'and Standard Deviations i

Results for each type of sample were grouped . according to the analysis performed. Means and standard deviations of these results were  ; calculated. These standard deviations represent I the variability of measured results for different samples rather than single analysis uncertainty. For these calculations, all results below the MDL were considered to be at the MDL. As a result, l the means are biased high, and the standard j deviations are biased low.

                                                                                                   ]

B. DISCUSSION OF RESULTS Results are summarized in brief form in tables IV, V, and VI (section V). Tables of results for individual sample types and analyses performed can be found in Section V. Graphical presentations of i results can be found in Section VI. 1

1. Surface Weter Samples were taken from eight stations on a monthly schedule. Of these eight stations, six (1P, 10, 4F, 4G, 41, 13A) could be affected by releases from Peach Bottom Atomic Power Station.

The remaining stations (6A and 6I) were above Holtwood Dam and therefore could not be affected by plant discharges. (Refer to figures 1 and 2, i Section VI, for station locations). Intake

surface water samples are discussed below with discharge water samples, i Total samples from all eight stations were analyzed for concentrations of aqueous tritium.

l Results of this analysis in surface water samples { n can be found in table VII. section V and figures  ! 6-9, section VI. The concentrations detected were  ; well within the range found during the Peach i Bottom Units #2 and #3 pre-operational period.1 i Graphical comparisons of the unaffected stations  ! (6A and 6I) above Holtwood Dam, with potentially j l affected stations (4F and 4L) at Concwingo Dam, ' showed no difference in concentrations, indicating  ; no detectable addition of tritium to conowingo a Pond by FBAPS (figures 6 and 7, section VI) . A  ! graphical comparisen of Station 4F with station 4G i l at Conowingo Dam showed no difference in tritium ) l concentration with depth, indicating uniform j mixing (see figure 8, section VI) . A graphical  : comparison of station 13A, at the Chester Water i 9 I 1 (

~_-_ -_--

Intake, with unaffected station 6A, above Holtwood Dam, showed no difference in tritium concentration I indicating no eff ect on a potential public drinking water supply by the operation of PBAPS (figure 9, section VI). Samplos from four stations (4F, 4L, 6I and 6A) were analyzed for gross alpha concentration in the soluble and insoluble fractions. Results of gross alpha analysis in surface water samples can be found in tables VIII-IX, section V and figures 10-13, section VI. Graphical comparisons of the unaffected stations (6A and 6I) above Holtwood Dam, with the potentially affected stations (4F 3 and 4L) at Conowingo Dam showed no significant difference in concentration with a few exceptions (figures 10 and 11, section VI) . The concentrations detected in the April, September and Decenter samples taken at Conowingo Dam (station 4F) are probably due to the presence of unusually high sediment content (approximately 1 5-10 times greater than samples from the other stations) in these samples. Sediment, being a reservoir for radionuclides, would be expected to  ! ! contain fallout radionuclides and natural alpha l emitters. l l ' } Samples from all eight stations were analyzed for I concentrations of gross beta in the soluble and I insoluble fractions. Results of gross beta ( analysis in surface water samples can be found in tables X-XI, section V, and figures 14-21, section VI. The concentrations detected were well within I the range observed during the pre-operational l period for Units #2 and #3.1 Graphical comparisons of the unaf fected stations (6A and 6I) above , Holtwood Dam, with potentially affected stations I (4F and 4L) at Conowingo Dam, showed no significant difference in gross beta concentration, with a few exceptions. (figures 14-17, section VI). Concentrations detected in l the insoluble fraction of the April, June, November and December samples at station 4F were higher than in samples collected at station 6A. A graphical comparison of station 4F with 4G at Conowingo Dam showed no dif ference in gross beta concentration with depth in the soluble fraction and differences noted in the insolucle fraction can be attributed to higher sediment content in the samples taken at greater depth (figures 18-19, section VI) . A graphical comparison of station 13A, at the Chester Water Intake, with unaffected 10

q 1 i I station 6A, above Holtwood Dam, showed no difference in gross beta concentration, indicating l no effect on a potential public drinking water ' supply by the operation of PBAPS (figure 20-21, section VI. ) . Samples from all eight stations were analyzed for 40K concentrations in the soluble fraction by 1 atomic absorption. Besults of *0K analysis in surface water samples can be found in table XII, section V. Graphical comparisons of *0K and gross ' beta concentrations, in the soluble fraction, indicate that generally at least one-third of the gross beta concentration was due to naturally-occurring *0K, a beta emitter (figures 22-25, section VI) . Samples from all eight stations were analyzed for gamma emitting nuclides by spectrometry of the soluble and insoluble fractions. Results of gamma spectrometry on surface water samples can be found in tables XIII-XVI, section V. The detection of

     *0K in one sample (station 6I) was attributed to statistical variation not being accounted for in the calculation of background.                        !
2. Discharge Water Samples were taken frcm four stations on a monthly schedule. All four stations (1M, 1R, 1T and 1S) were exposed to PBApS liquid radwaste discharge, (for station location see figure 1, section VI) .

All four stations are exposed to Unit #1 liquid radwaste discharge and only station 1M is exposed i to Units #2 and #3 liquid radwaste discharge. Total samples from all four stations were analyzed for concentrations of aqueous tritium. Results of tritium analysis in discharge wat er samples can be found in table XVII, section V, and figures 26-30, section VI. The concentrations detected were well within the range found during the Peach Bottom Units #2 and #3 pre-operational period with one exception.1 One sample from station 1S, a composite of Unit #1 discharges, collected during December showed a higher concentration of tritium. This concentration was attributed to Unit # 1 which was being decommissioned during this time period. Graphical comparison of aqueous I tritium concentrations at station 1T (about 60 I feet upflow of the Units #2 and #3 liquid radwaste j discharge) and station 1M (at the exit of the 11 I l

discharge canal) showed no significant differences (figure 27, section VI) . Graphical comparisons of the intake and discharge from Peach Bottom Units

  1. 1, #2 and #3 showed no significant difference in l concentrations of aqueous tritium in surf ace and  ;

discharge water (figures 28 and 29, section VI) . A graphical comparison of average results for surf ace water and discharge water samples showed no significant difference in concentrations of aqueous tritium, indicating no measurable addition of tritium to conowingo Pond by PEAPS (figure 30, section VI). The concentration of tritium in discharge and surf ace water samples continued a  ; downward trend as seen in previous years (figure 30, section VI). 1 Samples from all four stations were analyzed for l gross beta concentrations in the soluble and insolutle fractions. Results of these analyses in discharge water samples can be found in tables XVIII and XIX, section V, and figures 31-40, section VI. The concentrations detected were well within the range fouad during the Peach Bottom Units #2 and #3 pre-operational period 1 Graphical comparisons of gross beta concentrations i at Staticn 1T (about 60 feet upflow of the Units i

  1. 2 and #3 liquid radwaste discharge) and station ,

1M (at the exit of the discharge canal) showed no significant difference (figures 33-34, section VI) . A graphical comparison of Units #1, #2 and

  1. 3 intake and discharge showed no difference in concentrations of gross beta in the soluble and insoluble f ractions of surf ace water and discharge water (see figures 35-38, section VI). Graphical comparisons of average results for six surface water stations and four discharge water stations showed no significant difference in concentrations of gross beta in the soluble and insoluble fractions indicating no measurable addition of Deta emitters to Conowingo Pond by PBAPS (figures 39 and 40, section VI).

Samples from all four stations were analyzed for

  • 0K concentrations in the soluble fraction by atomic absorption. Results of *0K analysis in discharge weter samples can be f ound in table XX, section V. Graphical comparison of 40K and gross beta concentrations in the soluble fraction indicated that generally at least one-third of the gross beta concentration in discharge water was due to the natural radioactive nuclide, *0K (figures 41-45, section VI) .

12

1 l i i i Samples from all four stations were analyzed for { gamma emitting nuclides by gamma spectrometry of the soluble and insoluble fractions. Results of gamma spectrometric analysis of samples from all stations are given in tables XXI -XXIV, section V. 3 The detection 40K in one sample (station 1S) was 1 attributed to statistical variation not being accounted for in the calculation of background. t

3. Well Water Samples were taken from two stations on a monthly schedule and from three stations on a quarterly schedule. The two stations (10 and 1V) sampled monthly were located within the site area (for station location see figure 1, section VI) . The stations sampled quarterly were located about one mile (station 28) and about 10 miler (stations 7 ,

and 8) from the plant. The station locations are shown in figures 1 and 2, section VI. Total samples from all five stations were analyzed for aqueous tritium concentrations. Results of tritium analysis of well water samples can be found in table XXV, section V, and figure 46, section V1. Results of all samples were well within the range found during the Peach Bottom Units #2 and #3 pre-operational period.1 Graphical comparisons of the distant, site area, and on-site wells showed no differences in concentration, indicating no detectable addition of tritium to the ground water by PBAPS (see figure 46, section VI). Samples from all five stations were analyzed for i gross beta concentration in the soluble and l insoluble fractions. Results of gross beta analysis on well water samples can be found in tables XXVI-XXVII, section V, and figures 47-48, section VI. In both the soluble and insoluble l fractions all results were near or below the I minimum detectable level which is consistent with Peach Bottom Units #2 and #3 pre-operational data.1 Graphical comparisons of the on-site, site-area, and distant wells showed no significant difference in concentration, indica, ting no detectable addition of beta emitting nuclides to the ground water by PBAPS (figures 47-48, section VI). All samples were analyzed for gamma emitting nuclides by spectrometry of the total sample. 13 i

Results of gamma spectrometric analysis of samples q from all stations are given in tables XXVIII-XXIX, j section V. The detection of *0K in one sample j (staticn 1V) was attributed to statistical 1 variation not being accounted for in the ] calculation of' background.

4. Precipitation f i

Precipitation was collected from one station (1A), j located on-site at Peach Bottom Weather. Station #1 (for station location see figure 1, section VI) . Monthly samples were analyzed for concentrations of aqueous tritium in the-total sample. Results of this analysis of precipitation samples can be found in table.XXX, section V, and figures 49-50, section VI. Conc'entrations detected were well within the range'found during Peach ~ Bottom Units

     #2 and #3 pre-operational period.1 A comparison of concentration measurements with the surface density measurements indicate that tritium is present in the atmosphere as water, although this is not apparent for beta activity.

Monthly samples were analyzed for gross beta concentrations in the total sample. Results of gross beta analysis in precipitation samples can be found in table XXXI, section V and figures.51- 4 52, section.VI. Concentrations detected were well within the range found during the Peach Bottom Units #2 and #3 pre-operational period 2, indicating no detectable addition of beta emitting nuclides by PBAPS.

5. Milk l

Milk was sampled at twelve farms: three (G, H, J) were designated as "near farms" (within 2 miles of - PBAPS) ; five (D, K , L , M , N) were designated as 1

    " intermediate farms" (3-5 miles from PBAPS) ; and four (A,B,C and E) were designated as " distant farms" (>5 miles from PBAPS) . Farm D was                                                         j transferred from the: distant farm group to the                                                  )

intermediate farm group on January 1, 1975 since the simultaneous occurrence of infrequent plant  ; operating conditions and rare meteorological  ! conditions demonstrated the possibility of plant releases af fecting this location as described below. 14 i _ . - _. . _ - _ ._...--------_n------- --

Milk from all twelve farms was sampled and . 1 analyzed for tritium concentrations in the aq2eous and organic fractions on a quarterly basis. Results of tritium determination in milk samples can be found in tables XXXII-XXXIII, section V, and figures 53-58 section VI. Concentrations detected were wel] within the range found during the Peach Bottom Units #2 and #3 pre-operational 1 period.1 The lower concentrations in most October ) samples corresponds to precipitation data for the j same period. Tritium concentrations in milk were j similar to those four.d in other media (see table XL, section V) . Graphical comparisons of the near, intermediate, and distant farms showed no significant differences in tritium concentration,  ; indicating that PBAPS has not added tritium to the milk (figures 53-57, section VI) . Graphical i comparisen of the average concentrations in the aqueous and organic fractions, (expressed per ml. of water) at all f arme showed no significant differences (figure 58, section VI) . The concentration of tritium relative to total hydrogen in both the aqueous and organic fractions of milk from all farms continues to be very similar. A comparison of the three farm groups over a longer period of time shows no difference in organic bound tritium in milk (figure 55, Sec.  ! VI). These comparisons show that no measurable j tritium from PBAPS is present in milk, Milk from eight Peach Bottom farms was sampled and analyzed for concentrations of 181I monthly while  ! cows were not grazing and weekly during the period l March 17, 1975 to December 1, 1975 while the cows were orazing on pasture. In addition, milk from four f arms was sampled and analyzed for concentrations of 131I quarterly. Results of 1311 analysis can be found in table XXXIV, section V, and figure 59, section VI. Concentrations detected were below the minimum detectable level of about 0.06 pCi/l at all farms with two exceptions. 131I was detected at one distant farm (f arm A) in a single sample collected January 20, 1975 at a concentration of 0.5 pci/1. Examination of PBAPS 131I release data and corresponding meteorology measured at Peach Bottom indicates that this concentration is probably not due to PBAPS operation. No unusually high releases were observed during December and January and no transport mechanism could be seen in wind patterns 15

I 1 following periods of slightly elevated 131I releases. In addition, the cows were not grazing on pasture at this time, therefore, this i concentration of 131I was not attributed to PBAPS operation. 131I was also detected in milk from one intermediate farm (f arm D) of the eight locations sampled sampled on May 5, 1975 at a concentration of 1011 pCi/1. This was reported to the NRC in accordance with technical specifications. The 131I concentrations from all milk samples taken at i this location in 1975 through July 30 are plotted j in figure 60, Section VI. The 1311 found at this .l location is most probably of Peach Bottom origin and resulted from a combination of very rare , events. The first of these was a Unit 2 scram at l 6:38 p.m. on April 28, 1975, resulting in a l l temporary increase of 131I released f rom the Unit i 2 vent / stack. The meteorological conditions at this time indicate that the " puff" of radioactivity was carried by the wind toward one of the sampling locations. At this time, it began to rain, probably depositing the airborne radioactivity on the ground, where it could be ingested by the cows while grazing. If the rain had already started when the " puff" were released, or if it started at some later time after dispersion had time to occur, the 131I would probably not have been deposited in measurable quantities anywhere. Since unit scrams and the beginning of rain only occasionally occur, the simultaneous occurrence of these events is quite rare. It is, therefore, i expected that such 131I deposition, by this mechanism, will only rarely, if ever occur in the future. The milk sample taken from this location on May 5 was recounted at approximately three-day intervals until the activity was below the detection limit. The results of these recounts are listed in table XXXV, section V as " Uncorrected Result." Listed also in table XXXV, section V and plotted in l figure 60, section VI are these values corrected for radioactive decay from times of sampling to the time of first analysis. This permits a direct comparisen of the recount values with the criginal l measured concentration. Analysis of the change of activity in this sample with time yields a l radioactive half-life of 8.210.2 days at the 95 l 16

percent confidence level which agrees with the accepted value of 8.05 days for na1I. This confirms that the activity measured in this sample was 131I and demonstrates the sensitivity of the present method of measuring 131I radioactivity. The 1811 found in outsequent milk samples f rom this location decreased in concentration with time until it was below detectable levels by mid-June. The half life of this decrease was 5.010.6 days as compared with the radioactive half life of 131I of about eight days. This indicates removal from the pasture by mechanisms other than radioactive , decay. The data also indicates that no further j depositicn occurred following the initial i deposition. l This evetit in April, 1975 is the only time prior to the end of 1975, that as1I known to be of Peach l Bottom origin has been detected in the , environment. The sum of the calculated daily amounts of s a:I in one liter of milk from May 5 through June 12, (when the calculated daily concentration fell below 0.05 pCi/1) based on a 5.0+0.6 day half life, was 78.7 pCi, which is equivalent to an annual average concentration of 0.22 pCi/1. Using the accepted conversion factor of an annual average concentration of masI in milk of 2.4 pC1/1 producing 15 mrem / year to an inf ant's thyroid drinking one liter of milk per day, the total hypothetical dose to an infant's thyroid from the incident would be 1.3 mrem which is very low and not of significance. Using the dose model in  ! Regulatory Guide 1.109, this concentration would  ! result in a slightly lower dose of 1.03 mrem. Calculated on the basis described above, this is , approximately equivalent to the total dose which j resulted at the single most affected sampling i station in the Teach Bottom network from the atmospheric nuclear detonation in June, 1974 in the Peoples Eepublic of China. l' If it is assumed that 131I first appeared in the milk on April 30, 2 days after the release, at its maximum concentration and decreased to the May 5 measured concentration with a half life of 5.010.6 days, the maximum hypothetical dose to the thyroid of an infant prior to May 5 would be an additional 1.3 mrem using the above assumptions. l 4 17' l l l I

1 I

6. Fish l Fish were sampled from locations 1W (an isolated pond), 1X (a cooling tower pond) , 1EE (in the PBAPS discharge canal) , 4I and 4J (in Conowingo Pond), 6H and 6J (above Holtwood Dam) , 4H (below Conowingo Dam) , 30A (in Peters Creek) , and 25C (in Pequea Creek) . For sampling locations see figures I 1-2, section VI. I The species sampled were white crappie (Pomoxis annularis) from stations 1W, 1X, 1EE, 4 I, 4J and R 6J, and channel catfish (Ictalurus punctatus) from l sta tions 1W, 1X, 1EE, 4I, 4J, 6J, and 6H. '

American shad (Alosa sapidissimus) was sampled from station 4H. The species sampled in Peters Creek (30A) and Pequea Creek (25C) was white sucker (Catostomus commersani). I The edible portions of all fish samples were analyzed for tritium concentrations in the aqueous

                                                                                                                                             ]

j and organic fractions and results were found to be I consistent with PBAPS Units #2 and #3 pre- ' operational findings.* Besults of tritium analyses in fish samples can be found in table XXXVI-XXXVII, sectior V, and figures 61-69, section VI. Lower tritium concentration in American Shad (station 4H) reflects the lower concentration of t tritium in all species and in other media at the I time of the year when shad are rampled. 1 Concentrations of aqueous tritium did not vary by J species sampled and levels found were the same as for other media sampled (table XL, sect u m V) . Results in the organic fraction were somewhat I higher in samples analyzed during the second quarter and may have been caused by carry over in j the combustion of the organic fraction. Following I refinement of the analytical technique (See Appendix A) third and four quarter results were lower. Graphical comparisons of thite crappie and channel l catfish from the unaffected stations (6J and 6H) , ' discharged water station 1EE, and potentially affected stations (4I and 4J) ebowed similar concentrations, indicating that the operation of FBAPS has not increased tritium levels in fish in conowingo Pond (figures 61-66, section VI) . Graphical comparisons of white sucker in Pequea Creek and Peters Creek showed no difference in tritium concentration, indicating that PBAPS has 18 I

not increased tritium levels in fish in the tributary creek (Peters Creek) (figures 67-69, section VI) .

7. Plankton Samples of plankton were collected monthly from Conowingo Pond by net beginning September 30, 1975. All samples were analyzed for concentrations of beta emitters. Results of gross i beta measurements can be found in table XXXVIII, '

Section V. The results are within the range of those obtained previously under another portion of the program.

8. Vegetation Two stations, one in the site area (station 1) ,

an6 one about 5 miles away (station 5) , were l sampled (for station location see figure 2, I section VI) . Vegetation sampled was grass, lettuce, string beans, beets, cucumbers, turnips, cabbage, and onions. All samples were analy ed for tritium  ! concentrations in the aqueous and organic fractions and results found in the aqueous , fraction were consistent with PBAPS Uni ts #2 and )

   #3 pre-operational data.1 Results of tritium          l concentrations in vegetation samples can be found in table XXXIX, section V. Tritium concentration      l did not vary by sample type and levels found in        l the aqueous fraction were the same as for other media sampled (see table XL, section V and figure 70, section Vl} . Results in the organic fraction were unusually high in camples collected in June and may have been caused by carry over in the combustien of the organic fraction     ( ee Appendix A). Samples collected from the same locations in November had lower concentrations in the organic traction following refinement of the analytical method. The actual presence of high concentrations of organic-bound but not aqueous tritium in vegetation samples taken at locations five miles apart is highly unlikely, and therefore, these high concentrations are not considered real.
9. Soil Samples were taken at three locations, one (station 2) on site (for station location see figure 1, section VI) and two (stations 3A and 5) 19

about four miles away from PBAPS (for station  ! locations see figure 2, Fection VI) . The area at j station 2, is heavily wooded with rock 1 outcroppings. The soil at this location would be expected to contain substantial humus'from the accumulation of natural vegetative debris. Station 3A is covered only with grass. Station 5 is a combination of grass and cultivated land, samples from all stations were analyzed for gross alpha concentration in the top one inch and bottom five inches separately. Results of gross alpha l analysis in soil samples can be found in table XLI, section V, and figures 71-75, section VI. Graphical compariuona of the top cue inch of soil with the bottom cut showed no difference in gross alpha concentration indicating no recent deposition (figure 71-73, section VI) . Graphical comparisons of samples from the on-site location (2) with samples from distant locations (3A and 5) showed similar concentrations (figures 74-75, section VI) . Samples from all stations were analyzed for e*Sr and 'osr concentrations in the top one inch and bottom five inches separately. Results of $0Sr and e'Sr analysis in soil samples can be found in I table XLII, section V, and figures 76-85, section l VI. Concentrations of '0Sr detected were sell within the range found during PBAPS Units #2 and ,

 #3 pre-operational period 1     seSr mc:Curements were not made prior to operation of PBAPS Units #2    l and #3. Graphical comparisons of the top one inch of soil with the bottom cut showed no detectable dif ference in concentrations of 90Sr except at ctation 2, where the terrain is such that heavy accumulation of vegetative debris could contribute
 'oSr during the process of biological decay (figures 76-78, section VI) . Since e*Sr was not detected at this location there is no evidence to indicate any relationship to PBAPS operation.

Samples from all stations were analyzed for gamma j emitting nuclides by Ge(Li) spectrometry (tables XLIII-XLIV, section V). Nuclides identified were the same as those found during the PBAPS Units #2 and #3 pre-operational period with most at the same or lower concentrations.1 Some naturally occurring nuclidet .ere found (40E, 232Th, 2 2 6Ra) . Others found have been attributed to fallout, because other plant associated radionuclides were not found and concentrations were evenly 1 20 l l

7

                                                               .I distributed on-site.and.off-site.. .The greater         l value for ta7Cs, at station;2 compared to:the more distant stations may be. attributed to this location having a different terrain than the other locations as' discussed above. The absence of 13*Cs,.a' reactor' generated radionuclides not fcund     ,

in~homb fallout,.further indicates that this i concentration of~137Cs'io not due to PBAPS operation. Similar differences between the top and bottom. cuts at. station,2. appeared before PBAPS z Units f2.and #3 were operational,so it can be l concluded that the 537Cs. fallout came from other sources fsee Figures !86-88, section VI) . . j 10. Ambient gamma Radiation Ambient garama L radiation levels were measured with calcium sulfate: Thn thermoluminescent dosimeters. Eleven stations (1B, 1C, 1D, 1E, 1F,'1G, 1H, 1J, 1L,. tM and 2) were' located around the site boundary and designated as tue site boundary ring for comparison purposes (see figure 3 for station locations, section VI) . Fifteen stations (3A, 4K, 5,6E, 14, 15, 17, 22, 23, 26, 27, 31, 32, 33A, and

38) were located within. a 10-mils radius.of the site and designated as the middle; ring (for station locations see figure 4, section , vI) .

Seven stations"(12B, 16, 18,.19, 20, 21B, and 24) were located from 10 to 60 miles from the site and designated as the1 cuter ring. (f or station , locations see figure 5, .section VI) . . Three ) stations (1A, 11, 1K)' . located within the plant complex constitute a fourth grcup called plant-complex. stations since; they could. be more directly

                                                  ~

affected by plant activities.and do not-re,present doses to the.public (for station location see figure 3, section VI) . Results of.TLD measurements . can be found in tables XLV-XLVII, section V. The annual' average;of n.onthly, quarterly, and semi-annual radiation levels were well within the range found during'the Peach Bottom Units #2 and 63 pre-operational period.1 Graphical comparisons

                             ~

l 1 of the site boundary, middle .and . outer , rings on 1 monthly, quarterly and semi-annual readings showed no differences ~ iri ambient' radiation levels with distance from PBAPS,' indicating'no measurable 6tation contribution .(table. XLVIII, Section V, figures 91-93,sectiori. VI) . Station .1K, located about 100 ft from the turbine building, in a 21 l

( l controlled area, indicated dose levels generally rising with power levels. Stations 1A and 1I, in the predominant downwind direction, did not show any increased levels so it is improbable that this was an effluent effect. The increased dose levels measured at 1K are attributed to direct and scattered radiation frcm Peach Bottom Units #2 and

   #3. A special study has been. undertaken to determine the source and location of other possible areas exhibiting measurable radiation                              i levels above a natural background. The initial                               ;

findings of this study are in section VII. A l graphical comparison of TLD measurements at these three stations can te found in figure 94, section VI. Unusual readings were taken from the TLDs at station 23 which were installed July 13, 1975 and removed August 11, 1975. The four readings were 58.90, 43.78, 41. 31 and 64.7 2 (mrad) with an l average and 2 standard deviations of 56.65119.73  : (mrad) corrected to a standard month of 30.4 days. l No other TLCs showed high readings during the same  ! time period. Two other TLD packets (quarterly and semi-annual) had been installed at the same time, July 13, 1975. Following removal and reading of l the monthly TLD packet an attempt to remove the semi-annual packet for verification was made on August 14, 1975 but this packet had been stolen i from the shelter. Of the remaining quarterly TLD l packet cne dosimeter was removed on August 29, ! 1975. The two readings were 8.37 mrad and 8.01 mrad indicating that the high readings on the monthly TLDs did not result from ambient gamma radiation at this station. This was reconfirmed when the other quarterly TLD was removed on October 4, 1975. This read 13. 92 naad and 15.39 mrad, which was the normal value. Samples of vegetation (tree leaves and grass) and I soil were taken in the area of the TLD shelter at station 23. All samples were analyzed by gamma spectrometry and the results showed no indication tnat plant related nuclides were present (table XLIX, section V) . The concentrations of gamma emitters detected in the soil sampled at station 23 agree with results of routinely analyzed loca tion s (station 2, 3A, 5) where TLCs are also present and consistently show low readings (See Table XLV, section V) . In addition, the soil ' samples were analyzed for concentrations of e'Sr,

  '0Sr and alpha emitting nuclides. The 1

22

l 4 ( concent' ration of 'osr in.the top.one inch was' I 0.28t0.05 pci/g (dry) and inLthe b6ttcml cut was " 0.23 t0. 04 pC1/g (dry) . 'The concentration of~**Sr in the top one inch was less (than 0.06 pCi/g(dry)-. and in the bottom cut was. less than 0.05 pCi/g (dry) . These c, concentrations are notf higher R than would.be expected and: agree with those found at. other locatione routinely sampled ,(table XLII, . ' section V). . CorteentrationsLof gross alpha in the. ) top.one inch of the soxl aampled wasi50120 ,) pCi/g (dry) and in the bottom cut was.60t30 , q pci/g (dry) . These conctntratic ne also agree,iilth

                                        ~                             1 samples fron locations routinely analyzed for alpha emitting nuclidss (table XL1, section. V) .                    ]   .

These special samples indicated that nu measur&hle deposition of radioactivity ' occurred at this location attributille to PEAES) operation. 6mec rs' ' were taken of the TLD shelter 'and analyged for i alpha and beta emitters. All results were less than the-MDL of,10 picoCuries. Plant releases during this ' time period were 'not high enough to. produce.a dose of this magnitude.

        ~

TLD scations closer to the' plant and in the same-direction flom the exhibited norm 61 readings (lower by a factor of 10) (table' XLV, L so ction v) . The readings of the two dosimeters from station :23 in July exhibited ratios of 1.34 and,l'.57 totween opposite ends of the dosimeter. Peadings generally do no dif fer by a ratic of more' than 1.1. Normally, TLD packets containingltwo dosimeters are hung from clips inside the shelter. This particular package was f collected frcm the floor of the shelter and it is not'known how'long the packet was in that position. It is known that 1 the higher ends of each dosimeter were adjacent to I each other in~the sealed packet. l Based on exposure studies of TLDs.in special geometries it is concluded that the exposure w&u from a snall source located at one end of.the TLD package and ilot from a large diffuse source as i would be present in nature.  ;

                                             ~

It is concluded that the higher dcae rates l' measured at station 23 during July '1, 1975 could not have beEn the Iesult of ' radiation f roth PBApS. l j i 23 i 1 1 i _ - _ _ = _ =__2

m. ,

L- t j[ < r (! }: c I l l l I I l l i

                                             )l s

I

IV.

SUMMARY

AND CONCLUSIONS i I J I l l I l 1 I l

                                             '1 l

l l I j l k _ . _ . .. .

IV.

SUMMARY

AND CONCLUSIONS This report on the supplemental radiological environmental 1 monitoring program conducted at the Peach Bottom Atomic Power l Station for Philadelphia Electric Company by Radiation Nanagement Corporation covers the period January 1, 1975, to December 31, 1975. During this period 4121 analyses were performed on 3061 samples. Surface water and discharge water samples were analyzed for concentrations of tritium, gr0ss beta, +0E and gamma emitting nuclides. Surf ace water was also analyzed for concentrations of l gross alpha. Comparisons of unaffected stations with potentially affected stations, in conowingo Pond, showed no significant difference in concentrations of the radionuclides studied. It l was shown that no significant differences existed between the i pre-operational and operational periods, therefore it can be l concluded that the levels of radioactivity in conowingo Pond have not been measurably influenced by the operation of Peach Bottum l 1 Atomic Power Station. i Other selected media in human food chains (milk, fish, and vegetation) were analyzed for concentrations of tritium in the aqueous and organic fractions. Levels measured agree with results seen in other media studied and with pre-operational data for the same media. High sensitivity 131I analyses were performed on weekly milk samples while cows were on pasture, and monthly samples while cows were not grazing. A small concentration of 13 51 was detected in one f arm in January but was probably not due to PEAFS operation. Concentrations of 131I were measured at decreasing levels in several sequential samples at one farm beginnir,g in May. This is most probably of PBAPS origin and resulted from a ccabination of rare plant operating and meteorological events. No 1311 was detected in any otner samples during this period. Soil samples were analyzed for concentrations of gross alpha, 00Sr-**SJ, and gamn;a e;nitting nuclides. Differences in concentration found at potentially affected locations and unaffected locations were attributed to differences in terrain. Environmental gamma radiation measurements were made using therdeluminescent dosimeters. Results from the site boundary, middle, and outer rings, were found to be not significantly different, so it can be concluded that the operation of Peach Bottom Atomic Power Staticn did not produce measurable levels of ambient gamma radiation at any offsite location. In assessing all the data gathered for this report and comparing the results witn preoperational data, it seems evident that the operation of the Peach Bottom Atomic Fower Station added no significant amount of radioactivity from a dose standpoint to the 24

environment. In all cases where fission and activation products were found except the 131I at Farm D, they occurred at both potentially affected and unaffected stations within the range of noraal variability.  ; 3 1 EEFERENCES (1) Radiation Management Corporation Publication, i Peach Bottom Atomic Fower Station Pre-operational ! Radiological Monitoring Report for Units 32 and ) B , January 1974, Philadelphia, Pa. t l , l l I i l l l 1 i l l l l l 2s l  ; l l l

V. TABLES l l

9 1 i TABLE I RMC STATION DESIGNATION AND SAMPLE IDENTIFICATION _ SYSTEM y-WW-XXYZ General code for identification of samples, where: y - Power Plant identification code PB - Peach Bottom Atomic Power Station 1 F - Fulton Generating Station I WWW - Type of Sample  ! AQF - Aquatic, Fish 4 AQP - Aquatic, Plankton j FPA - Food Products, Apple j l FPV - Food Products, Various ID - Immersion Dose I M - Milk l DW - Discharge Water RW - Rain Water SW - Surface Water

                          ~

l WW - Well Water E - Soil l XX - Angular Sector of Sampling Location compass is divided into 36 sectors of 10 degrees each with centei at Peach Bottom off-gas stack. Sector 36 is centered l due North, and others are numbered in a clockwise direction. Sector 00 is used to designate an unidentified direction. l Y - Radial Zone of Sampling Location (In this report, the radial distance from the Peach Bottom off-gas stack for all regional stations) . S: on-site location D: 3-4 miles off-site A: 0-1 mile off-site E: 4-5 miles off-site B: 1-2 miles off-site F: 5-10 miles off-site C: 2-3 miles off-site G: 10-20 miles off-site H: 20-100 miles off-site 3 - Station's Numerical Designation within sector and zone, using 1,2,3... in each sector and zone. l

D ac 0t e 0te 0tpe ac ahc 0t e ac 0tpe ahc - . SE 4 ep 4 ep 4 el p 4 ep 4 el p T4 SR YO K

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                     , sm K

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                                           ,ssm K

Bs sa

                                                                            ,sm K

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ra - rra NE - ra ra - rra AP RGG HGG HGGG HGG HGGG - - LQ LE OR M M M M M CF e s h t e d e r sce ea m h i c n

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           #O        ssa          ssa                             sa             sa                sa   -

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           *E S

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                    ,sm 3om                     3om
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                                                       .                           n e

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        .NO                                                  I A

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Tt.BLE XXXIV (Cont *d) CONCERTRATIONR OP IODIIC-131 IN KILK (TOTAL 8 AMPLE) Pesults in Units of pC1/1 e 2 eigma DISTA E PARMS AVFRAGE OF ENV. BTr. TION NO. A B C ga DiBTANT AVERAGE OF PMC DE91GRATION PB-M*24P1 PS*M-1901 PD- N- 31 F1 PB 1-36F1 FARMS ALL STATIONS * - BTAT100 1-20-19'* 0.5060.07 (C.06 <0.06 -

                                                                                                  .21s.51      .104.27 2-17-?O*                     <0.05          <0.06             (0.06              -        <0.06      (0.06               3 3+17-79**                    (G.06          (0.06             <0.e6              -         *0.06      (0.04 3-?a-75                     (0.06          (0.06             <0.05              -        (0 06      <0.06 1-38-79                     <0.dt         <0.07              (0.18-             -
                                                                                                     <0.08       <0.08 l

4-*?-79 (0.05 <0.a8 <0.07 - <0.07 (0.07 - 4 '4-79 (0.06 <0.05 <0.05 - <0.05 <*.06 l a- 21-15 (0.06 (0.05 <e.05 -

                                                                                                     <0.05      (0.06 4-28-15                      (0.07         <0.07.            (0.07              -         <0.07      (0."7 l           *-e4-19                      (0.06         (0.06             (0.08              -         <0.e7     1.3187 .02          l l

1 j 5-12-75 <0.06 <0.66 <0.04 -

                                                                                                     <0.05      22t1.05 5-19-75                       <0.06         (0.07             <0.08              -         <0.07    . iSt. 75 5-26-79                       (0.05         <0.07             (0.06              -         <0.06    .12t.20 6-02-15                       (0.05         (0.06             (0.06              -         <0.06    .084.93 6-e9-75                       <0.05          <0.05             (0.01              -         <n.05    .061.02 -

6-16-79 <0.05 <0.05 <0.05 - <0.05 < 0.0 5 7-23-75 (0.05 <0.05 <0.07 -

                                                                                                    <0.06       (0.06 6-3n-75                       (0.08          (0.08            <0.00               -
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                                                                                                   <0.06        <0.0 6 7-15-75                       <0.07          <0.06             (0.07              -
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                                                                                                   <0.08        (0.08 7-28-75                       <0.07          (0.08             (0.06             -
                                                                                                   <0.08        <0.07 8-04-75                        <0.06          <0.07            <0.07              -
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8-11 75 (0.07 <0.57 (0.06 -

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                                                                                                  <0.06        (0.06 1

9-14-74 (0.07 (0.06 <0.08 -

                                                                                                  <04 07       (0.07                 J 9-22-75                         <0.05         <0.06             <0.06              -
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                                                                                                               <0.06                  l 10-13-15e                          (0.08           <0.07             (0.07          <0.1        <0.08        <0.07                  l ta-21-75                           (0.06           (0.01             <0.06             -
                                                                                                 <C.06         (0.v7 10-27-15                           (0.07           <0.06            <0.08              -
                                                                                                  <0.07        (0.06 11-03-75                           <0.05            (0.07            (0.06                      40.06 (0.06 11-10-75                          (0.07            <0.06            <0.05                      <0.06
                                                                                                               <0.06                  l 11-17 75                           (0.06            <0.06            <0.07                      <0.06
                                                                                                              <0.06                   )

11-24-75 (0.06 <0.05 <0.04 -

                                                                                                 <0.05         (0.05 I

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                                                                                                              <0.05                   I 12-16 75                           <0.05            <0.05            (0.05              -
                                                                                                 <0.05        <0.05 AVERAQee                           <0.07            <0.06            <0.06            <0.1     .076.00        1161.13 eror calcula.,lon of averages a lose than value is taken to equal that value. therefore the mean and deviatione are approximations. If all values are less than the e.iLimam detectable level. then the average le less than the minimum detectable level.

esmonthly sampling while cows are not graeing IJanuary 20 1975 sample f rom Farm A was reco4nted to confirm the presence of s aat and the result of the reconnt was .486.08 pC1/1 eThe (4 ret compte f rom Form E was 10-16-75. l l

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                 .M

_ O VI . NTO EAN A B C D E _ T 1 1 1 1 1 - N

ATE 3 1 1 4 0 TRV SAA 7 0 2 7 4 - U 1 3 7 3 9 - Q 2 1 1 1 1 DQ* o 7 9 6 4 _ REE n 7 9 6 0 _ A G . - DYA o 0 0 0 1 - NLR t t t t t AME TTV UNA 4 2 4 3 4 7 8 5 7 4 - O 7 4 5 4 E M 7 6 8 6 3 7 0 4 7 8 -__ 5 2 3 6 4 - 5 6 1 1 1 4 8 4 1 7 7 9 2 2 1 4 1. 1 0 0. 1 7 3. 2 -

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O D D D D D I I I I I I T - - - - - A B B B B B N P P P P P G I S E _ D N

                  .O vI          .

NTO EAM F G H l J _ T 1 1 1 i T S

NER t t i t i ATE 9 8  ! 4 2 TRV 6  % 8 8 0 .- SAA 4 U 1 1 9 5 U 1 5 1 1

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  • P i 1 8 9 4 9 L E 9 4 0 0 7 B T s 2 2 9 4 0 _

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                    .NO VI         .

NTO EAN K L M A T 1 1 1 2 3 S -

Q* E* D

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                         -       3          17               6            75              8 4 o3       0  4.1        7     1       0  5.1          0     1      3  8.1 2        8    7        3 05                 4       7 19          7 0t0
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                                                                                               -4 E

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O D D D D D I I I I I I T - - - - - . A B B B B B _ N P P P P P G - I _ S E D T

                      .O VI          .

NTO EAN 5 6 7 8 9 _ T 1 1 1 1 1 S

ALG 3 1 DRA 1 1 5 t 1 NER 1 t 1 5 4 1 ATE 4 2 8 4 5 TRV 3 7 SAA . . 8 3 U 0 0 7 1 1 Q 2 2 1

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7 1 9 5 9 4 1 0 5 SNA 6 4 O 6 6 5 M _ 7 8 5 6 9 _ 8 3 1 3 3 5 5 1 . 3 . 9 5 6 1 72 29 1 34 7 7 5 9. 2 9 2 4 1 2 2. 2 9 .1 59 80 0 4 4 o3 6 0

9. 2 4 1 9 2 7 0. 2 6 7.1 4 2 48 9 0 2 4
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                 -        -    9               . 2                  9               . 8                2              .

1 4 1 6 2 7 1 6 1 5 1 a 1 1 1 1 G G 1 B G 0 5 C 5 1 2 3 3 1 1 N - - - - - O D D D D D I I I I I I T - - - - - A B B B B B N P P P P P G I S E D N

                   .O VI          .

NTO B EAF 0 1 2 3 4

NER 2 t 1 t t ATE 6 6 6 0 7 TRV 4 6 9 7 5 SAA U 9 7 7 8 3 -_ Q 1 1 1 1 1 DO* 4 3 4 2 8 REE 9 2 0 8 7 - A G DYA 0 t t 0 c - NLR t 9 t 9 t 3 t 2 t Al E 9 T "l V I 4 8 9 2 5 . SNA O 6 5 5 6 4 M 4 5 8 5 7 5 8 9 9 1 4 3 3 0 1 . 5 6 0 1 0 8 20 15 7 7 4 6. 2 1 2 2 5.1 4 2 5 1 50 9 40 4

5. 02 5.1 4 o3 5 2 5 4 9 2 3 1. 1 0t0 80 0 9 9 58 1 0 9 55 3
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I I I I D D T - - - I I A B B B - - N P P P P F G I S E U N

                .O VI NTO.

EAN 6 7 1 2 A T 2 2 3 3 3 S 3

1I Q* E* D

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FYE 7 6 . ALG e 5 s u DPA 2 8 h 7 NER t 1 t l e - ATE 4 7 n a u 9 TRV 4 8 o v l 2 a SAA U Q 8 1 7 1

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r h y h ta _ a t l g u _ d n h u od n o t o de a m n r ace eas t o h s n m t rloe phh

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      - s  E I  t  P M  l                                                                                                       _

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