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Forwards NPDES Rept for Sept 1987 & Addl Required Data.Plant Maintained Power Generation Through Month Until Unscheduled Shutdown on 870928
	ML20235Y878
Person / Time
Site:	Trojan File:Portland General Electric icon.png
Issue date:	10/14/1987
From:	Hess R; PACIFIC GAS & ELECTRIC CO., PORTLAND GENERAL ELECTRIC CO.
To:	; OREGON, STATE OF
References
	ES-911-87L, NUDOCS 8710200516
	Download: ML20235Y878 (12)
	v • d • e

_ _ _ _ - _ - _

j Portland GeneralElectricCompany USHRC-0S

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6810C120 A (5 51 October 14, 1987 EG-911-87L Trojan GOV REL 9C Oregon Department of Enviro,nmental Quality Northwest Region Executive Building 811 SW Sixth Ave Portland OR 97204 Gentlemen:

Enclosed is the NPDES report for the Trojan Nuclear Plant for October 1987.

Also enclosed are data required to be submitted in addition to that on standard NPDES forms.

The plant maintained power generation through the month until an unscheduled shutdown on September 28, 1987.

The plant remained shutdown for the remainder of the month.

All discharges with the exception of the neutralizing tank and the Sewage Plant Effluent were within specification.

The Sewage Plant Effluent BOD concentration and pounds released, limits were exceeded on September 9.

A concentration of 81.6 ppm BOD was reported, the limit is 30 ppm.

There was no visual indication of any problem at the Sewage Plant on this day, and the suspended solids was reported well within the 30 ppm limit at 8.2 ppm.

Review of the BOD calculations and techniques used for the analysis did not reveal any errors.

This high BOD value raised the monthly average concentration to 28.6 ppm, with the limit at 20 ppm.

Although no obvious error in the analysis was found, the BOD concentration reported is highly suspicious, based on the visual observation of this plant and the low suspended solids concentration.

8710200516 871024 PDR ADOCK 05000344 R

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1 ES-911-87L October 14, 1987 Page 2 l

There were several events related to neutralizing tank problems i

that occurred during the month.

On September 4, approximately l

4,000 gallons of 50%' sodium hydroxide and 10 ft3 of anion resin l

were inadvertently discharged to the neutralizing tank.

This 0

event generated considerable heat in the tank (>140 F) which prevented any immediate attempts at neutralization.

To protect I

the tank lining neutralization was delayed until the tank cooled 0

to less than 140 F.

Attempts to neutralize the tank or to use the settling basin to dilute the high caustic concentration were unsuccessful.

A temporary storage truck was brought on site to allow room in the tank for further neutralization but the pH was still too high.

On September 5 a decision was made to transport some of the i

neutralizing tank contents to the Beavet Plant neutralizing pit.

This decision was based on the inability to neutralize the tank, which was now close to 100% tank level, and the possibility that the tank may have been damaged by the excessive caustic and heat generated.

Approximately 7,000 gallons were shipped by truck to Beaver on September 7.

The remaining contents of the tank were neutralized and discharged on September 10.

During this discharge the main outfall pH increased to a maximum of 9.5 (limit 6.0 -

[

9.0) from 1300 to 1305.

The discharge was stopped immediately and it was determined that the pH of the liquid in the tank had increased from pH 7.7 at 83% level to a pH of 13.0 at 21% tank level.

The tank contents had been recirculated and air sparged prior to the initial sample.

An investigation into the cause of the increased pH indicated a layer of high pH anion resin and sludge in the bottom of the tank.

Attempts to neutralize this resin / sludge mixture were only partially successful.

Neutralizing tank discharges during the remainder of the month were performed within NPDES limits, but continued to indicate an increasing pH as the tank level decreased.

Visual inspection of the tank indicated damage to the tank lining.

A temporary water treatment plant will be brought on site in October and the tank i

will be cleaned out and relined.

The settling basin was over filled on September 7.

Approximately 100 gallons of pH 10.2 water overflowed the basin and drained into the Columbia River.

The discharged valves from the settling basin pumps to the main outfall had been throttled back due to the high pH in the settling basin from attempts to dilute a portion of the neutralizing tank contents on September 5.

The water retreatment plant filters automatically backwashed on September 7 at approximately 0400 and overflowed the basin because of the throttled discharge valves.

.s.

LES-911-87L 1

October. 14,.1987

-Page'3-The transportation of caustic materials and use of the Beaver

. neutralizing tank were reported.to the DEQ, specifically George Davis and Dennis Adamczyk on September 10, 1987.

If you have i

questions,.please. contact Stan Katkansky at 226-8409.

Sincerely, M

R.

J. Hess, Manager Environmental Sciences RJH/SCK: sic es.1014 Enclosures c:

Jim Durham

-David Kish, DOE Art Olmstead Bill Peregoy Tom Walt Paul-Yundt R..C.

Barr, USNRC Trojan j

John Martin, USNRC l

USNRC Document Control Desk j

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