Text

Quarterly Aquatic Toxicity Monitoring Rept for Jul 1997 for Millstone Station
	ML20216F232
Person / Time
Site:	Millstone
Issue date:	07/31/1997
From:	Scace S; NORTHEAST NUCLEAR ENERGY CO.
To:	;
Shared Package
ML20216F102	List: ML20216F099; ML20216F232;
References
	NUDOCS 9709110192
	Download: ML20216F232 (26)
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STATE OF. CONNECTICUT

' DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER MANAGEMENT AQUATIC TOIICITY MONITORING REPORT Millstone / NU CTf0003263 001A FacilityNone ypDEse DSN e Waterford Niantic Bay 2000 Town Receimng K'aser Boein cade Sompte Collectedpom: _b '30 -97 09 3a Qp,,e To-

~7 - / - 9 ~J O 9/c gp D**

D*e Date isme Flowfor Sample Collection Period I,e?7Q ccous

y o a g p,

.z,,,,, o g,p Total uanmum y,,umu,,,

Scheduled Monitoring Retest Other W

M) VAd/4 TEST RESULTS: WHOLE EFFLUENT TOXICITY

~ 755/

~

Jfysidopsis bahia Definitive LCse

^ll/f A. NOEL A/lA h

I% Eftluent: Mean survival 90 %

Conttel Survival:

/dC %

7 2- %

32- %

Replicat 01 Raplscate 02 Replicate SS Cyprentdon w1riegatus Definidve LC,a Al A. NOEL

^lYb h@

Y _% Effluent: Mean autvival --

/dC %

Control Sussival:

/4 0 %

/d o %

/4c) %

Reph:st *1 Replicate 92 Replicose e3 1certfy under penalty oflaw skat this docu=wnu ed all anachmaus wre perpared under my dsrecnon or superwston en accordance w<tk a syssem destgesedto assure ik.st qual (sedpenannelproperlygather andewsluate the sforomotion submutted.

Based on my inquiry ofthe penon orpersons who manage the sytem. or those penons directly respor.siblefor gathers *ng the egormation the *<ornation submittedis. to the best ofmy knowled andbelief ture. a: curate andcomplete.1em aware that t

Ihere are stgnfaeantpenaltiesfor sub=mittigfalso sformanon. snelust the postshshty offne and snprisarunentfor knowing welatsoas, i

S.E.Scace Director-Nuclear Engineering Programs

/ ors.~ed qktV eaa, 96 9/97 Auth Tale Signtuur, '

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' Date e

9709110192 970829 PDR ADOCK 05000245 R

PDR

STATE OF CONNECTICUT

DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER MANAGEMENT AQUATIC TOXICITY MONITORING REPORT Millstone / NU CT#0003263 001A FacilityNome yppgs a DSM g Waterford Niantic Bay 2000 Town Receivent M'eser Basin Code Sample Collectedfrom: T/$'9 7 N00 &pn To-7~/b ~'I 7 O/;0<3 (D pu Dose nme Date Two flowfor Sample Collection Period R ZTo @Gdt.

/7 wo &M

/2,000 SPM Total Hammum Muumum Scheduled Monitoring Retest

/

Other --

$ //W/}4ll)

?"f"S7 TEST RESULTS: WHOLE EFFLUENT TOXICITY

~

Sfysidopsit bahla DeCaitive LCsa _ Ak b

I A. NOEL h

N % Efnuent: Mean survival 9O %

,p K 70 %

d 70 %

/40 %

Conttel Survival:

Raplicat *I Reptocato a2 Replicate 63 Qvrmadon uriegatus Dermitive l4 sN$

NlN A. NOEL PS @

4Y#

_% Efauent Mean survival - A//#

MM d/M

_ - 4//#

Control Susvival:

Replant 01 Replicate 92 Replicate s)

I certsfy aoder penalty oflaw that shts docume nt ad at! anachmenst wre prepared under my der:tton or supervnsnon sn occordance Mth a sysum duig wd to assure sket qualfelpersonnelproper& gather andawfuere the snformation submutted.

Based on my inquiry ofthe person orpersons who manage the s><em. or those persont dirtedy respansiblefor gathering the odormonon, she s<armanon submissedis. co the best ofmy knowled and belief ture. occurate andcomplete. J em c'uere thet t

Ihere are engntfacantpenaltiesfor submimagfalte sgormanen, niuding the potssbasty ef);ne and inprisonmentfor knowing v.orat ons.

S.E.Scace Director-Nuclear Engineering Programs Authowasiop;csal Tide S

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r Mtc1s Sigstrure lhte

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g STATE OF. CONNECTICUT

' DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER MANAGEMENT AQUATIC T0XICITY MONITORING REPORT Millstone /NU

___ CT#0003263 001B Focility Name NPDES 0 DSN 0 Waterford Niantic Bay 2000 Town Receivsng Wour Betin Code Sample Collectedfrom: _7 ~/ 3

9 7 2 T OC_am & To _ 7~/9~97 O 13 O '& pm Deu nme Date Dme Flowfor Sample Collection Pernod E, / W GM GPm 2'lf 000 C/M 23.000 dPM Total Maxsmum Msnamum Sebeduled Monitoring /

Retest Othet _ --

TEST RESULTS: WHOLE EFFLUENT TOXICITY Afysidopsit behia Defattive lcm AIN A. NOEL dA (9F @

/do % Ef0 cent: Mean survival 92 %

Control Survival:

/00 % _-

/d o %

/o o %

Replicas el Repheate c)

Replicate *3 A lA Cyprmsdon variegatus Definidve LCa

$N A. NOEL

/

d?F @

/d O _% Efouent Mean surviva! _-

96 %

Control Susvwit:

/co%

/co %

/co */.

Repluot al Replicate c)

Replicate o)

Icertrfy umder penalty oflaw shat thu docuament and oH attachments wre prepared under my dsrecnon or supervesion en accordance with a system detigned to assure that qualgfledpersonnelproperly gather and evaluare the uformornon submrtted.

Based on my inquiry ofthe person orpersons who manage the tyur or those persont directly retpensible for gotkering the odormattoot the agarmatson tubmaud is. co the best ofmy knowledg and belief ture, accurose andcomplete Iam aware that Ihere are tsgntfa:antpenaltiesfor submitnntfalso uformanon. sneludsng the potssbshty offne and smprisonmentfar knowsng vio/otions.

S.E.Scace Director-Nuclear Engineering Programs authorced of. cia ntle

l'46d s,g. tar.

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i STATE OF. CONNECTICUT

' DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WATER MANAGEMENT AQUATIC TOIICITY MONITORING REPORT Hillstone / NU

_ _ _ CT80003263 001C Facihty Name NPDES 0 DSN i Waterford Niantic Bay 2000 Town heeimag Water Basin code Sompte Collectedpom: _ _]~ 9 ' 9 7

// 30 9 p.n To-

'7 4 - 4 7

/3M

,Q Date nme pa,,

p,,

Flowfor Sample Collection Pened _2x s~ia. m

/l> 7,0004PM

_/47c.vo 6PM Tota!

Maxnmum numum Scheduled Monitoring Retest Other TEST RESULTS: WHOLE EFFLUENT TOXICITY Mysidopsit bahla Detmntive LCa A. NOEL k

h/F @

/d O

% Ef0uent: Mean sunival 93 %

Contiol Survival:

9/ %

/d C %

/40 %

hphcasel Rephease n2 Replicate U s/h)

Qpranodon variegatus Definidve LCu A//A A yoyt 99%

h@

/dC _% Effluent: Mean sutviva! __

Control Survwal:

/#0 %

/'#O %

/00 %

Repluatel Replicate n2 Replicate 5)

Icor:fy under penalty ofLsw shat skt docment and aQ anachments wre propered under my dweenan or supernsnon a occordanet u4th a system desigudto anure that qualfedpersonnelproper& gather and evoluere the agermatson subwtted Based on my inquiry ofthe person orpersons who manage the sytem. or those persons directly respo.sible for gathering the nyorononon, the sgormatson submated is, to the best of nsy knowled and behef ture, occurote and complete Icm aware that t

there are ssgn{scantpenaltiesfor embmitangfalse sgormarson, sneluding the possnbshty offrae and insprisontnerafor bsowing wo/atw.

~

Di ector-Nuclear Engineering Programs e,A scace Ast ce social Tale k9 o eit<_P,

~

Signttun Djte

VATER CCHFLIANCE UNIT / AQUATIC TOEICITY AQUATIC TOIICITY MONITORING REPORT (1 DOL)

P17T.1 NPDES 10 ctoo03263 Facility Wase:

W wittsfoFf f 0061 Salinity: 2s.32 - ppt Receiving Vaters winnele Bav 2000

.Essin Code 2006 vaterbody ID __

fros // 00 AX/JJf to

// 00 AHg 4 !/f !9'4 - (date)

Sasple Collected ons-e//6 /9 I. CALCVLATION OF INSTREAM TASTE CONCENTRATION (ITC)

A11ocated 2ene of Influence Tiov Rate = (

)=

(A)J47000enithe 1

(3) /Rdco e mi /hr

=

Paraitted Average Daily Flov Kate (c) 302'2,8 en t /_hr Mean Flow for Previous 30 operating Days

/@T as1/hr (D)

Nighest Daily Fiov for Previous 30 Operating Days =

I f

ITC.

ITC = (3 er C) / [(1 or C) t A) X 100

If D/C is greater than 1.25, you sust use 3. otherwise you say use either.

II. DETreWTui! ION OF C00LIANCE CettFLIANCE STATt/S lTIST SPICTES tc 50_

NOAft MatMUM D Af tY 70TICITY ll f P AS $ / TAILS

_l acute. 15 's No Kau.

ll Mu

_l lNysdepsis 7g g

ehrente -10o % Ab A u.

ll_

rA rt _ __ l 1bakin meute =

ll

_l 1

__ehrente =

__ { l

[

1 ttitrwrw? or Acxxortmmmet this document and all attachments were I certify under penalty of law that prepared under my direction er supervision in accordance with a systen designed' to assure that stualified personnel, properly gather a9 evaluate the taformation submitted. Based on my inquiry of the person or persons who sanage the systsa, or these perseas directly responsible for gathering the information, the information submitted is, to the best of my knowledge and beltet, true, accurate and cosplete. I an avars that there are significant penalties for i

submitting false information, including the possibility of fine and imprisonment for knowing violations.

Director-Nuclear 6*E.Scace g

p Authorised Official _

26 ?7 e-Date s.

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AquaticToxicity Monitoring Report

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Millstone Nuclear Power Station DSN 001 A,001B,001C and 006 :-

i-1 July 1997 -

7 NPDES Permit No. CIT)003263 Millstone Station.

.. Northeast Nuclear Energy Company..

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l AOUATICTOXTCITY hDJTTOR!NG FEIMT : PART 2 1

Fac hty Name NORT1 FEAST UflUTIES MNE STATat [9 on6 NPDOSID.CTttm263 SalmutyApra Test L..v. h X+7 DdatumWaeerS-twid s

Savn#r.wdanGwe-Fdiemn SampleCuHectalOrt 7/15/97-7/1 A/97 f11m110Ci (Jane) Sunple Renmm10rt 7/16/07(Jane)TestSpecesA*wim!=TasSource N1JELS 31 Age 4 DanTesaforatsorry hours av.,1510 (PM)On 7/16/9' (Jane) Er=1 1425 fat} Orr 7/18/97 (J ee)

LTFLUENT _

Number Orgarusms Dusolved Temperatwe pH DtufTION Wg O ggen

(%)

(mg/t) hour 00 24 48 72 96 00 24 45 72 00 24 48 72 00 24 48 72 1

100L1 10 9

9 8.4 6.8 63 2D 4 21 1

, 20 6 86 85 83 1

100L2 to 10 to 84 6.8 47 20 4 212 21 0 86 85 83 75L1 10 9

9 7.9 68 64 20 4 21 2 20 6 85 84 54 75 L2 10 to 10 7.9 6.8 46 20 4 21 2 20.9 85 8.4 83 63L1 10 10 10 78 7.1 72 20 4 21 2 205 85 84 83 63 L2 10 10 10 7.8 7.1 47 2n4 21 2 20 8 85 8.4 80 SGL1 10 10 13 7.9 67 62 20 4 213 205 84 83 8,2 50%-2 10 7

5 7.9 67 4.1 20.4 21 3 2a7 84 83 8.1 25 %-1 10 9

9 80 7.1 63 203 21 3 205 8.2 82 8.1 y

2SL2 to 10 7

80 7.1 37 203 21 3 m8 82 82 77 CONTROL '

to 10 9

81 73 7.0 20 6 21.4 2a7 7.9 7.8 7.9 (0%)-1 CONTROL 10 10 10 81 73 45 20 6 21.4 207 7.9 7.8 80 (9%)-2 I

~

LC.

95% CONFIDENCEINTERVAL NOAEL COMPUTATTONALMET1tOD

>100%

25 %

Persons conductmg test DPC IV l

1 l

I l

RefermteTouscant Resetts SA Date Lkm

.x Tonicant Sewere 1_C.

Mysufersrs 6alew 6/30/97 Sairam DodecyISulfate Fisha Saeemfic 1261 Fpm 00615 0)

M29 ppm (118-216) 7/7/97 14 Of ppm 00.7-19 4) 7/14/97 1125 ppm PD 9-13 8) 7/17/97 Cypnesodow rarrystas 6/30/97 Smiram Dmisyl Suhte Fahn Soenedic S 1 ppm (45-S 4)

S8ppei(5245) 7/7/97 f 75 ppm (6941) 7/14/97 m

Mdistone Unst One (001 A) test cors! cted on 7/I/97 had one control replicate wrth k-ss than W% surmal, tht=gh et'luent survival was 90L Tbc ent was repeated or 7/16/97, harmg two control repLcates with less than 90% survrval agam with gt=st effluent surmal rates (90%) T1=s test wd1 be repeated mL p.kr. fee myu.Is only. W Trao k<t DEP was informed of tids on August 28,1997.

l l

Statementof Acknowledgement I cerfdy that the data repor*ed on this document were pr9amt under my directun or supervision an accordance with the testmg prosociA descrd=4 m ETA 600/4-4S/013 and Sections 22a-4%3 and 22a-430-4 of the Regulatwns of Connecticut State Agmoes except as reted nieve_1he mformation submitted a to the best of my L== ledge and bcM, true, accurate, arsi complete.

Antimwized Ofhcial Mdan Keser Title Manager - Northeast Utahties E...

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?AX 11 (137304764

?. 3 Aquatic Toxicity Monitoring Report: Part 3 Facility Name: Millstone DSN:

001A NPDES: CT0003263 Work Order:

97 0789 Sample Collected On: 07/01/97 Sample Received on:

07/03/97 Chemical Analysis Data The semple collected for use in tonicity tests run to determine compilance with NPDES permN limits or conditions must be analyzed for the parameters listed below. Enter the results of these analyses in the space provided and attached this fortn to the ATMR and transmit to DEP using the malling labels provided.

Report Date: August 13,1991 Concentration Date Parameter Code Effluent inIake Analyzed

.Totat Copper 01042 028

<20 ug/l

<20 ugli 08/11/97 Total Lead 01061 028

< 5 u g/l

<5 ug/l 08/12/97 Total Nickel 01067 028

<10 ug/l

<10 ug/l 08/11/97 Total Zinc 010927 028

<10 ug/l 16 ug/l 08/11/97 NH3 00610-019

<0.02 mg/l

< 0.02 mg/l 07/28/97 Total Suspended Solids 00530 019 20.6 mg/l 17.8 mg/l 07/03/97 j

Surfactants 38260 019 0.02 mg/l 0.01 mg/l 07/03/97 Total Oil & Grease 70030 019

<0.5 mg/l

< 0. 5 mg/l 07/07/97 -

i Total Residue Chlorine" C0030 028 40 ug/l 20 ug/l 07/01/97 Free Available Chlorine" 50060 028 30 ug/l

<20 ug/l 07/01/97 pH" 8.1 S.U.

7.9 S.U.

07/01/97

.w

Anatysed at sue

" Analysed t y N.u.t'.L Method:The samples were analyted following procedures outlined in EPA Pub!! cation 600/4 79420 as followst Total Suspended Solids: Method 160.2. oil & Grease: Method 413. Metals: Method 200 7. Surfactant: Method A28,1 Ammonia: Method 350.3. TRO: Method 330.5.

Methu Shah. Laboratory Supervisor Masa certification. MA 071 Conn Cerincation.PH4520 v,-t

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AUMH? fiU 12:43 til TIS: il!!EFl(LD P. A.L FAX K 4137304764

!. 1 Aquatic Toxicity Monitoring Report: Part 3 i

Facility Name: Millslone DSN:

001A NPDES: CT0003263 Discharge Work Order:

97 0824 Sample Collected On:_ 07/16/97 Sample Received On:

07/17/97 Chemical Analysis Data The sample collected for use in toxicity tests run to determine compliance with NPDES permit limits or conditions must be analyted for the parameters listed below. Enter the results of these analyses in the space provided and attached this form io the ATMR and transmit to DEP using the malling labels provided.

Report Date: August 13.1997 Concentration Date Parameter Code Effluent intake Analyzed Total Copper 01042 028 (20 ug/l

<20 ug/l 08/11/97 Total Lead 01061 028

<5 ug/l

<5 ug/l 08/12/97

+

Total Nickel 01067 028

<10 ug/l

<10 ugIl 08/11/97 Total Zlnc 010927 028 11 ug/l 13 ug/l 08/11/97 NH3 00610 019

<0.02 mg/l

<0.02 mg/l 07/28/97 Total Suspended Sollds 00530 019 11.2 mg/l 12.4 mg/l 07/18/97 Surfactants 38260 019

<0.01 mg/l 0.01 mg/l 07/17/97 Total Oil & Grease 70030 019

<0.5 mg/l

<0.5 mg/l 07/22/97 Total Residue Chlorine *'-

C0030 028 30 ug/l

<20 ug/l 07/16/97 Free Available Chlorine" 50060 028 (20 ug/l

<20 ug/l 07/16/97 pH" 7.7 S.U.

7.9 S.U.

07/16/97 L

4

Analysed at site

" Analyzed by N.u.E.L.

Method: The a amples were anatyred following procedures outlined in EPA Publication 600/4 79420 as follows:

Total suspanded Soleds: Method 160.2, oil & Grease: Method 413, Metals: Method 200 7. Surfactant: Method 426.1 Ammonia: Method 350.3. TRo: Method 330.5.

e Madhu $ hah, Laboratory SupetW16I Mass Certification MA411 Conn Cetification. PH 4520 4

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FAX Ec.

U 3 730 C H

?. 1 Aquatic Toxicity Monitoring Report: Part 3 Facility Name: Millstone DSN:

0010 NPDES:, CT0003263,

Work Order:

97 0847 Sample Collected On:_ 07/20/97 Sample Received On:

07/21/97 Chemical Analysis Data The sample collected f or use in toxicity tests run to determine compliance with NPOES permit limits or conditions rnust be analyzed for the parameters listed below. Enter the results of these analyses in the space provided and attached this form to the /4TMR and transmit to DEP using the malling labels provided.

Report Date: Augsst 13,1997 Concentration -

Date Parameter Code Effluent intake Analyzed Total Copper 01042 028

<20 ug/l

<20 ug/l 08/11/97 Total Lead 01051 028

<5 ug/l

<5 ug/l 08/12/97 Total Nickel 01067 028

<10 ug/l

<10 ug/l 08/11/97 Total Zinc 01092 028

<10 ug/l 35 ug/l 08/11/97 NH3 00610 019

<0 02 mg/l

<0.02 mg/l 07/28/97 Total Sospended Solids 00530 019 13.2 mg/l 13.6 mg/l 07/25/97 Surfactants"*

38260 019

<0.01 mg/l

<0.01 mg/l 07/21/97 Total Oil 8 Glease 70030 019 0.6 m 1/1 0.6 mg/l 07/23/97 Free Available Chlorino" C0030 028 20 ug/l 40 ug/l 07/20/97 Total Residual Chlorino" 50060 028 80 ugli 70 ug/l 07/20/97 Free Available Chlorine' C0030 028 80 ug/l ug/l 07/20/97 pH" 8.0 S. U.

7.9 S. U.

07/20/97

Analyted at site

" Analysed by N.ULL Method! The samples were analyzed following procedures outlined in EPA Publication 600/4 79 020 as follows:

TotalSuspended Solids: Method 160 2. oil & Grease: Method 413. Metals: Method 200 7. Surfactant: Method 426,1 Ammonla: Method 350,3. TRo: Method 330.8, bk Madhu fhah, Laboratory bupervisor Mass Cestification. MA 071 Conn Cetifcation. PH4520 1

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Aquatic Toxicity Monitoring Report: Part 3 l

i Facility Name: Millstone DSN:

001C NPDES: CT0003263 L

Work Order:

97 0809 I

i Sample Collected On: 07/09/97 Sample Received On:

07/11/97 Chemical Analysis Data The sample collected for use in toEleity tests run to determine compliance with NPDES permit limits or conditions must be analysed for the parameters listed below. Enter the results of these analyses in the space provided and attached this form to the ATMR and transmit to DEP i

using the malling labels provided.

Report Date. August 13,1907 Concentration Date Parameter Code Effluent intake Analyzed l

Total Copper 01042 028

<20 ug/l

<20 ugli 08/11/97 Total Lead 01051 028

<5 ug/l

<6 ugli 08/12/97 Total Nickel 01067 028

<10 ug/l

<10 ugli 08/11/97 1

Total Zinc 010927 028

<10 ug/l

<10 ug/l 08/11/97 NH3 00610 019

<0.02 mg/l

< 0.02 mg/l 07/28/97 i

Total Suspended Solids 00530 019 10.6 mg/l 5.8 mg/l 07/11/97 Surfactants-38260 019 0.01 mg/l 0.01 mg/l 07/11/97 Total Oil & Grease 70030 019

<0,5 mg/l

< 0. 5 mg/l 07/17/97 Free Available Chlorine

C0030 028 60 ug/l ugli 07/09/97 Free Available Chlorine" 50060 028

<20 ug/l

<20 ugIl 07/09/97 I

Total Residual Chlorine" C0030 028

_30 u0ll

<20 ug/l 07/09/97 pH" 8.1 S.U.

8.8 S.U.

07/09/97 1

Analysed at site

Anahted by N.u.E.t -

Method: The samples were analysed following procedures cuttined in EPA Publication 600/4 79 020 as follows:

Total suspended solids: Method 160.2. oil & Grease: Method 413. Metals: Method 200 7. Surfactant: Method 425.1 Ammonla: Method 360.3. TRO: Method 330.5.

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1 Aquatic Toxidity Monitoring Report: Part 3 Facility Namei Mllistone DSN:

006 NPDES:

CT0003263 Work Order:

97 0824 Discharge,,, -

S:mple Collected On:

07,/,16/97_ _

Sample Received On:

07/17/97 i

Chemical Analysis Data The sample collected for use in toxicity tests run to determine compliance with NPDES permit limits or conditions mur.t be analyzed for the parameters listed below Enter the results of these analyses in the space provided and attached this form to the ATMR and transmit to OEP using the mailing labels provided.

Report Cate: August 13,1997 Parameter Code Concentration Date Analyzed

. Total Suspended Solids 019 1.2 mg/l 07/18/97 Total Oil & Grease 019

<0.5 mg/l 07/22/97 pH" 012 7.7 SU 07/16/97 Total Copper 001

<0.02 mg/l 08/11/97 Total Load 001

<0.05 mg/l 08/12/97 Total Nickel 001

<0,05 mg/l 08/11/97, Total Zinc 019 0.12 mg/l 08/11/97 Total Residual Chlt.rIne' 019 0.04 mg/l 07/16/97 Total Residual Chlorine" 019 0.04 mg/l 07/16/97 Ammonia as N 019 0.05 mg/l 07/28/97 MBAS 606 0.01 mg/l 07/17/97 F

Flow 609 gpd

Analyzed at site

- Analyzed Ly N.U.E.t Method: The samples were arialyze'd following procedures outlined in EPA Publication 600/4 79 020 as follows:

Total h spended Solids: Method 160.2, Oil & Grease: Method 413. Metals: Method 200 7, Surfactant: Method 425.1 Ammonia: Method 350.3, TRo: Method 330.5, Madhu Safah, Laboratoff7]Pervisor'

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