ML20212H782
| ML20212H782 | |
| Person / Time | |
|---|---|
| Site: | Crane  |
| Issue date: | 10/10/1986 |
| From: | Toole G GENERAL PUBLIC UTILITIES CORP. |
| To: | |
| Shared Package | |
| ML20212H717 | List: |
| References | |
| 1104-28I, NUDOCS 8703060219 | |
| Download: ML20212H782 (48) | |
Text
ENuclear Number 1,,_,
Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
Applicability / Scope Responsible Office TMI-I Division Plant Ops. Dir.
This document is within QA plan scope X
Yes No Effective Date Safety Reviews Required X
Yes No Important to Safety X
Yes No 10/10/86 Environmental Impact Related X
Yes No CONTROLLED COPY FOR List of Effective Pages USE IN UNIT 1 ONLY Page Revision Page Revision Page Revision Page Revision 1.0 7
E2-1 7
CONTROL ROOM 2;0 l
WORK 1yG COP.Y 22
,ft P, h k,
4.0 7
E3-1 7
.f 5.0 7
E3-2 7
!i a M g. 3 a
6.0 7
E3-3 7
',c N
d' %
7.0 7
E3-4 7
8.0 7
E4-1
- 7'
=
.a a:
l:2 1 ?
" ' NFc, o@
11.0 7
E5-1
", V 7 g '3o-D)
.l>. E5-22 12.0 7
7 13.0 7
E6-1 7
14.0 7
E6-2 7
15.0 7
E6-3 7
16.0 7
E7-1 7
17.0 7
E8-1 7
18.0 7
E8-2 7
19.0 7
E9-1 7
20.0 7
E9-2 7
El-1 7
E10-1 7
i E1-2 7
E10-2 7
El-3 7
E11-1 7
El-4 7
E12-1 7
l l
Signature Concurrino Organizational Element Date m
l Oricinator th Oriainator t o - a -PL Concurred L)
(
\\
By M.. N L_Ln--
Procedure Owner
> o f4 I tr.,
( 4fd4 s'ds /wt L-PRG tchc/H
/L Approved OVM Approver
/O -/O -B L B,y U
8703060219 870302 PDR ADOCK 05000289 R
PDR 1.0 1372c
(UClear
""*b
THI_i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
Table of Contents Section Page 1.0 DISCUSSION 4.0
2.0 REFERENCES
4.0 3.0 LIMITS AND PRECAUTIONS 4.0 4.0 TEST SOLIDIFICATION OF 4 TO 10 HT7. BORIC ACD 6.0 (CONCENTRATED WASTE) 4.1 Prerequisites 6.0 4.2 Procedure 7.0 5.0 TEST SOLIDIFICATION OF > 10 TO 20 HTY BORIC ACID 9.0 (CONCENTRATED WASTE) 5.1 Prerequisites -
c.
r 9.0 5.2 Proc d r
- a g '.g y t{!y J j y gj! O 10.0 6.0 TEST SOLIDIFICATION OF WASTE OIL 12.0 6.1 Prerequisites 12.0 6.2 Procedure 13.0 7.0 TEST SOLIDIFICATION OF USED PREC0AT 14.0 7.1 Prerequisites 14.0 7.2 Procedures 15.0 8.0 TEST SOLIDIFICATION OF BEAD RESIN 16.0 8.1 Prerequisites 16.0 8.2 Procedure 17.0 2.0 1372c
Number gg p
Operating Procedure 1104-28I
! tie Revision No.
Waste Solidification Process Control Program 7
Table of Contents (Cont'd)
- tion Page 0 ALTERNATE TEST SOLIDIFICATION PROGRAMS T
18.0 9.1 Prerequisites hk 18.0 9.2 Procedure rh 18.0 3.0 ACCEPTANCE CRITERIA
[
k 19.0 n '.3, t TACHMENT 1 Class A Unstable: and-St le, Class B and C Test El-1 Solidification Dith%heet for 4 to 10 wt% Boric yvyp '
'TACHMENT 2'(.
SoljdtfNtionCalculationSheetfor4to10wt%
E2-1 4'Bo'ricAcid b*
iTACHMENT 3 Class A Unstable and Stable, Class B and C Test E3-1 Solidification Data Sheet for > 10 to 20 wt %
Boric Acid 7TACHMENT 4 Solidification Calculation Sheet for > 10 to E4-1 20 wt 1 Boric Acid iTACHMENT 5 Class A Unstable and Stable, Class B and C Test E5-1 Solidification Data Sheet for Haste Oil
'TACHMENT 6 Solidification Calculation Sheet for Haste Oil E6-1
'ACHMENT 7 Class A Stable. Class B and C Test Solidification E7-1 Calculation Sheet for Used Precoat
~7ACHMENT 8 Solidification Calculation Sheet for Used Precoat E8-1 iACHMENT 9 Class A Stable, Class B and C Test Solidification E9-1 Data Sheet for Bead Resin TACHMENT 10 Solidification Calculation Sheet for Bead Resin E10-1
~7ACHMENT 11 Test Solidification using Hestinghouse - Hittman E11-1 Procedure
'.URE I Percent Solids of pH Adjusted Haste vs. Water /
E12-1 Cement Ratio 3.0 1372c
Nuclear 1H1_i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
1.0 DISCUSSION The purpose of the Process Control Program (PCP) for incontainer solidification is to provide a program which will assure a solidified product with no free standing liquid prior to transportation for disposal and which meets the re-quirements of 10 CFR 61.56, Hu te Characteristics.
l The PCP's for each waste stream included in this procedure are based on labora-tory testing, the results of which are included in " Topical Report Cement Solidified Waste to Meet the Stability Requirements of 10 CFR 61" prepared by Westinghouse - Hittman. These PCP's are valid for all liner types using elec-tric or hydraulic mixing heads provided by Hittman.
2.0 REFERENCES
2.1 Westinghouse - Hittman F421-P-004, Process Control Incontainer l
Solidification of 4 to 20 wt7. Boric A Westinghouse - Hittman STD-P-A54002{ Q 4RrocesshontelPro 2.2 tainer Solidification of. Otly haste r-s A t a
gg Solidification of Powdersdk[esinsb86,ProcessControlProgramforInco l
Westinghouse-4fftman"F421 2.3
%),
2.4 Westinghous Hittman F421-P-005, Process Control Program for Incontainer Solidifica'llon of Class A Unstable or Stable, Class B and C Resin at Maximum Packaging Efficiency 2.5 Westinghouse - Hittman STD-R-05-007, Topical Report Cement Solidified Waste to Meet the Stability Requirements of 10 CFR 61 2.6 Tech. Spec. Section 3.22.3, Solid Radioactive Waste 2.7 GPUN Radiation Protection Plan 3.0 LIMITS AND PRECAUTIONS 3.1 As required by the Radiological Effluent Technical Specifications for PWR's and BWR's, the PCP shall be used to verify the solidification of at least one representative test specimen from at least every tenth batch of each type of wet radioactive waste (e.g., evaporator bottoms, oily waste, resin and precoat sludge).
3.2 For the purpose of the PCP a batch is defined as that quantity of waste I
required to fill a disposable liner to the appropriate level on the waste I
level indicator.
4.0 1372c
ENuclear
- rur_,
Operatino Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
3.3 If any test specimen falls to solidify, solidification of the batch under test shall be suspended until such time as additional test specimens can be obtained, alternative solidification parameters can be determined in accordance with the Process Control Program, and a subsequent test veri-fles solidification. Solidification of the batch may then be resumed using the alternate solidification parameters determined.
3.4 If the initial test specimen from a batch of waste falls to verify solidt-fication then representative test specimens shall be collected from each consecutive batch of the same type of waste untti the three (3) consecu-tiveinitialtestspecimensdemonstratesolidl[p 1
on.
The Process Control Program shall be modiflad as requ re solidification of subsequent batches of waste.
3.5 For high activity m ter, su y en or used precoat, where handling of samples ceu.d fe.i ers el radiation exposures which are inconsistent with,t.Y 4 1ple, representative non-radioactive sempics will be t96t h Gh amales should be as close to the actual waste physic
$ndn: hem (c41roperties as possible. Typical expended mixed b Thp,t,e used to simulate the spent bead resin and the approar
('
o % ion to cation powdered resin shall be used to simu-
[
9(AIT C)emicals used to condition or solidify waste or simulated waste in 3.6
'sphdification tests shall be the actual chemicals used in full scale solidification.
3.7 A Test Solidification Data Sheet will be maintained for each test sample solidified.
Each Data Sheet will contain pertinent information of the test sample and the liner numbers solidified based on the test sample.
3.8 Samples should be drawn at least six hours prior to the planned full scale waste solidification to allow adequate time to complete the required testing and verification of solidification for Class A unstable waste. 28 hours3.240741e-4 days <br />0.00778 hours <br />4.62963e-5 weeks <br />1.0654e-5 months <br /> should be allowed, if practical, for Class A stable, Class B and C wastes.
3.9 The tank containing the waste to be solidified should be mixed by recircu-lating the tank contents for at least three volume changes prior to sampling to assure a representative sample.
3.10 If the contents of more than one tank are to be solidified in the same liner then representative samples of each tank should be drawn.
These samples should be of such size that when mixed together they form samples of standard size.
If the contents of a particular tank represents X percent of the total waste quantity to be solidified then the sample of that tank should be of such size to represent X percent of the composite samples.
5.0 1372c
[
THI-1 Operatino Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
3.11 An RHP must be obtained and used for performing test solidifications of radioactive samples.
4.0 TEST SOLIDIFICATION OF 4 TO 10 WT% BORIC ACIO (CONCENTRATED WASTE) 4.1 Prerequisites
-_----_-----------------------__--- -----==
NOTE:
This PCP Test Solidification Procedure is applicable to ClassAUnstable,ClassAStable,ClassBandQfasteForms.
.-s-y
/a k
4.1.1 A sufficient size sample of concentrated drox.1 liter) g has been drawn and the followin,g para lyzed for by Plant Chemistry:
-p g
[
b Boron p.. 1 e
,q
.i
%J e 5 ribTotalSolids gw Gamma Scan
-_- __=_ _ -------------_--------_---------- ___
NOTE:
The total solids and gamma scan are used for information purposes only to track waste characteristics and are not to be used in the Process Control Program calculations.
_ _ _ ___--_--- =_. -
=
=---------- -__-
NOTE:
The Concentrated waste sample shall be kept heated (> 100*F) unless previously neutralized. The acceptable pH range for concentrated waste is 7.4 to 9.2.
4.1.2 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
4.1.3 The appropriate portions of Attachment I have been completed including waste classification, chemistry information, balance calibration data and the sequential sample number.
6.0 1372c
Nuclear 1,1_i Operating Procedure 1104_28I Title Revision No.
Haste Solidification Process Control Program 7
4.2 Procedure 4.2.1 Calculate the weight percent of Boric Acid on Attachment 1.
4.2.2 MEASURE 500 gms of untreated concentrated waste into a container.
4.2.3 RECORD the weight and volume on Attac 1.
4.2.4 ADD 50 wt% sodium hydroxide (N F pH is between 8 to 8.5 for Class A unstable, las B and C solidifica-tion.
tu%dandtheadjustedpHonAttachment 4.2.5 RECORDthewp of a g
'() g
- 4.2.6
,If4Rg'f 1 Toam causing) quantities of detergents are e
- (present
T the sample with an anti-foaming agent until the.
appears.
p 4 /f 3,* RECORD the weight of anti-foaming agent used on Attachment 1.
4.2.8 If oll is present in stable waste in a quantity greater than 1%
by volume, reduce the quantity of oil to less than 1% by skimming.
For unstable waste if oil is present and the volume is between 3 and 12% of the volume of waste, TREAT with an emulsifying agent such as Maysol 776 (20% of the volume of 011). Oil in concentrations > 12% by volume may not be solidified by this procedure.
(Refer to Section 6.0 Test Solidification of Waste 011).
_==_==________
NOTE:
The density of Maysol 776 is 1.0 g/ml; the volume in ml is equal to the weight in grams.
4.2.9 RECORD the % oil and the quantity of any emulsifying agent used on Attachment 1.
4.2.10 Record the volume and weight of the pretreated Sample on Attach-ment 1.
4.2.11 Calculate the percent soilds in the sample by completing items (9), (10), (11) and (12) in Section II of Attachment 1.
7.0 1372c
\\
luClear THI-i Operating Procedure 1104-28I Title 3avision No.
Waste Solidification Process Control Program 7
4.2.12 For the test solidification of the concentrated waste, measure into a mixing vessel 400 ml of pretreated waste.
NOTE:
Test solidifications should be conducted using a 1,000 ml disposable beaker or similar size container.
==--==---------
4.2.13 RECORD the volume AND weight of the sample on Attachment 1.
4.2.14 Calculate the water in the sample by comp et items (15), (16) and (17) in Section III of Attach, ment '
4.2.15 UsingFigure1and..thep'erhetso.1h M Test Solidifica-bATER
- the water / cement ratio tionDataSheet, Item'(ly)kIherequiredquantityofPortland then CALCULATE: and!,WQ i
IC'{*hh f9
}
y n y h. RECORD ihe weight of cement on Attachment 1.
4.2.16 4'.d b 7 CALCULATE and WEIGH out the required quantity of metso beads, 2
i.e., anhydrous sodium metas111cate (ASMS), into a separate vessel.
4.2.18 RECORD the weight of ASMS on Attachment 1.
4.2.19 Slowly ADD the cement to the test sample while it is being mixed.
==
===== ----------------------------------------
NOTE:
Mixing should be accomplished by stirring with an electric mixing motor with blade or manually with a rigid stirrer untti a homogeneous mixture is obtained, approximately one minute.
4.2.20 After all the cement is added, slowly ADD the ASMS to the test sample while it is being mixed.
4.2.21 After sufficient mixing (2 minutes after all the ASMS is added) so that a homogeneous mixture is obtained, SEAL the sample and CURE at 120 1 5'F for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> for Class A Stable, Class B or C or at room temperature for Class A unstable.
NOTE:
If at any time during the 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> cure, the sample meets the acceptance criteria, the liner solidification may proceed.
However, no test solidification shall be disquallfled without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
8.0 1372c 1
- 400!OOI THI-l Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
4.2.22 When the Acceptance Criteria has been met per Section 10, calculate the required quantities of cement and additives for the full scale solidification using a liner type applicable for this waste type (as determined by Radwaste Operations Engineer-ing) and the Solidification Calculation Sheet for 4 to 10 wt%
Boric Acid (Attachment 2).
g---------
NOTE:
The liner shall be solidified using OP 1104-28A active Waste Solidification - Hittman.
{
_-----------------_------__ _====
eh2 4.2.23 CompleteSectionVIofAttasty(p c
ton of the solidification if ce e Vima hopper.
5.0 TEST SOLIDIFICATION OF > 101t00 wtVBORk AC (CONCENTRATED WASTE) f u W9 *
- 5.1 Prerequisi e' fe
_4-qM4-----_--_-----____----__-_-_-_---
=
NOTE:
'This PCP Test Solidification Procedure is appilcable to Class A Unstable, Class A Stable, Class B and C Waste Forms.
_------=---____ ------------------------====-- =-----------
5.1.1 A sufficient size sample of concentrated waste (approx. I liter) has been drawn and the following parameters analyzed for by Plant Chemistry:
l Boron pH Total Solids Gamma Scan l
____==..--------------_-------------
NOTE:
The total solids and gamma scan are used for information purposes only to track waste characteristics and are not to be used in the Process Control Program calculations.
l NOTE:
The Concentrated waste sample shall be kept heated O 130'F) unless previously neutralized.
The acceptable pH range for concentrated waste is 7.4 to 9.2.
9.0 1372c
\\
ENuclear er 1
1,1_i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
5.1.2 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
5.1.3 The appropriate portions of Attachment 3 have been completed including waste classification, chemistry informatica, balance calibration data and the sequential sample' number.
5.2 Procedure 5.2.1 Calculate the weight percent of Boric n
t chment 3.
5.2.2 HEASURE 500 gms of untreated (oncent e into a container.
RECORDtheweightjgd:vkt 5.2.3 4Att hment 3.
ADD 50 wt1 sodiblt,hhr (NaOH) until the pH is between 12 5.2.4 and 12,5. O Q
m i\\,0.
5.2.5 cRECORD th'e t of NaOH usEd and the adjusted pH on Attachment 3{
'yD g 1
,s s
5.2.6 p large (i.e., foam causing) quantitles of detergents are 3e present, TREAT the sample with an anti-foaming agent.
5.2.7 RECORD the weight of anti-foa:ning agent used on Att?.chment 3.
5.2.8 If oil is present in stable waste in a quantity greater than 1%
by volume, reduce the quantity of oil to less than 1% by skimming.
For unstable waste if oil is present and the valume is between 3 and 12% of thz volume of waste, TREAT with an emulsifying agent such as Haysol 776 (20% of the volume of y
oil). 011 in concentrations > 12% by volume may not be solidified by this procedure.
NOTE:
The density of Haysol 776 is 1.0 g/ml; the volume in ml is equal to the weight in grams.
5.2.9 RECORD the % oil and the quantity of any emulsifying agent used on Attachment 3.
5.2.10 Record the volume and weight of the pretreated sample on Attach-ment 3.
5.2.11 Calculate the percent solids in the sample by completing items (9), (10), (11) and (12) in Section II of Attachment 3.
10.0 1372c
ENuclear" 1,1-i Operating Procedure 1104-28I iltle Revision No.
,l Waste Solidification Process' Control Program 7
[
,a v
5.2.12 For the test solidification of the concentrated waste, measure into a mixing vessel 400'ml of pretreated waste.
=
NOTE:
Tes't solidifications should be conducted using a 1,000 ml disposable beaker or similar size container.
-==
- - - - - - - - - = = _ _ _ - - - - - -
5.2.13 RECORD the volume Ahc weight of the sample on Attachment 3.
5.2.14 Calculate the water in the sample by completing itemse(I, (16) and (17) in Section III of Attachment 3.
q.
5.2.15 Using Figure 1 and the percent solid,s drfmth(Ts)Sbidifica-tion Data Sheet, Item (12), OETERMJN yh i ateMement ratio then CALCULATE and W2IGH out e 76qu ep antity of Portland Type I corrent.
y '4 y
m RECORD the we}ght'of> % ;
a c
t-5.2.16 o Attachment 3.
eq
,7t M
5.2.17
~CALCULATEQd out the.equired quantity of anhydrous
,sodt'.behli te (ASMS) into,a separate vessel.
5/2^.18 RECOPD the weight of ASMS on Attachment 3.
5.2.19 Slowly ADD the c? ment to the test sample while it is being mixed.
e
__==__
.___= -
NOTE:
Mixing should be accomplished by stirring with an electric mixing motor with blade or manually with a rigid stirrer until a homogeneous mixture is obtained, approximately one minute.
---=.. - - - - - - - - - - - - - - - - - - - - -... - - - - - - - - - - - - - - - - - = = - - - _ = = = = = = = - - - - -_ _ =--
5.2.20 After all the cement is added, slowly ADD the ASMS to the test surple while it is being mixed.
5.2.21 After sufficient mixing (2 minutes after all the ASMS is added) so that a homogeneous mixture is obtained, SEAL the sample and CURE at 120 2 5'F for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> for Class A Stable, Class B or C or at room temperature for Class A Unstable.
[
NOTE:
If at any time during the 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> cure, the sample meets the acceptance criteria, the liner solidificaticn may proceed.
However, no test solidification shall be dis-cuallfled without at least 24 nours of cure.
I 11.0 1372c
Nuclear 1st-i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Procram 7
5.2.22 When the Acceptance Criteria has been met per Section 10, calculate the required quantities of cement and additives for the full scale solidification using a liner type applicable for this waste type (as determined by Radwaste Operations Engineer-ing) and the Solidification Calculation Sheet for > 10 to 20 wt%
Boric Acid (Attachment 4).
NOTE:
The liner shall be solidified using OP 1104-28A, Radioactive Waste Solidification - Hittman.
5.2.23 Complete Section VI of Attachment 4 upon completion of h I
solidification if cement remains in the hopper. p *g 6.0 TEST SOLIDIFICATION OF WASTE OIL (12 - 40% 011) 6.1 Prerequisites
--_---_--_--__-----_--,_ p y-Thig FCP4TestkSo Clah)j UgabW'lididdtlon Procedure is applicable to NOTE:
, tlass A Stable, Class B and C waste forms.
g.7- -_
.- = - - -. = - - - -__
__ _______=
6.1.1 A sufficient size sample (approx. 500 ml.) each of pH adjusted concentrated waste and waste oil have been drawn. The concen-trated waste shall be within a pH range of 7.4 to 9.2.
l
--____---__-----= -=- --- -----------____----_-_____---________
===_------
NOTE:
The pH of the concentrated waste will be adjusted in the tank before the test solidification.
6.1.2 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
6.1.3 A sequential sample number has been assigned to the test and included on Attachment 5.
6.1.4 A determination has been made as to the waste class of the pending full scale solidification by Radwaste Ops. Engineering.
6.1.5 The balance calibration data has been included on Attachment 5.
s 12.0 1372c I
a n
.~
Nuclear 1H1_i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
6.2 Procedure 6.2.1 Measure into a mixing vessel 210 ml of concentrated waste and 140 ml oil.
- _ = - - -_==
__=--_
NOTE:
Test solidifications should be conducted using a 1000 mi l
disposable beaker or similar size container.
)
--=
___-------=-
6.2.2 Recordthewastevolumesaddedandthepercentoilb'ko
>on t.
6.2.3 MEASURE out 28.0 ml (28.0 gms) of M 6.
l 6.2.4 RECORD the quantity of t ij ng?tachment5.
6.2.5 ADD the Maysolf hfg n mix until a homogeneous mixture feBta
$a five (5) minutes.
% b.df
.N1dbeaccompikkhedbystirhingwithanelectric N0hE:
M1 kg
. mixer with blade or manually with a rigid stirrer. Any
". signs of pure oil may be an indication that the emulsion is breaking down. Should this occur, contact Radwaste Ops. Engineering for further instructions.
==- _ _.
_ ------===
=
6.2.6 If large (i.e., foe.1 :ausing) quantities of detergents are present, treat, the sample with anti-foaming agent until the foam disappears.
6.2.7 Record the amount of anti-foaming agent used on Attachment 5.
6.2.8 MEASURE out 447.3 gms of Portland Type I cement and 51.8 gms of I
anhydrous sodium metasilicate (ASMS).
6.2.9 RECORD the quantities of cement and ASMS on Attachment 5.
l 6.2.10 Slowly ADD the cement to the test sample while it is being mixed I
and mix until a homogeneous mixture is obtained but in no case less than one (1) minute.
6.2.11 After all the cement is added, slowly ADD the ASMS to the test I
sample while it is being mixed.
6.2.12 MIX for two (2) minutes after all the ASMS is added and homo-l geneous mixture is obtained.
13.0 1372c
MUClear mi-i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
6.2.13 Seal the sample and cure at 120 + 5'F for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> for Class A Stable, Class B or C or at room temperature for Class A Unstable.
=_.
_==_ -- =
NOTE:
If at anytime during the 24-hour cure time, the sample meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be disquallfled without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
_ _ =.==
6.2.14 When the Acceptance Criteria has been met per Section 10, l
calculate the required quantitles of cement and additives W
the full scale solidification using a liner type a b
ifor this waste type (as determined by Radwaste Ope n[r-ing) and the Solidification Calculation et (Attachment 6).
, Th,--- d.,
- - - - - - = _ - -
=- ------- __
==
-n-NOTE:
The liner sha blf I%iYdP1104-28A, Radioactive
- '==
=
WasteSp1;ldi(l ff$
1
~:
y
==== =--
7.0 TESTSOLIDIFICATIONOF?U$EDakECOAT
- w. -
7.1 Prerequisites
_=------==
_=_=----------
NOTE:
This PCP Test Solidification Procedure is applicable to Class A Stable, Class B and C Haste Forms.
._=
=-- ____==_=_=_=-----___
7.1.1 A sufficient size sample of used precoat (approx. 500 ml) has been drawn and the following parameters analyzed for by Plant Chemistry:
pH (of sluice water) e Gamma Scan
==-
=_=----------------------------------
NOTE:
The gamma scan is to be used for information purposes only to track waste characteristics and is not to be used in the PCP calculations.
7.1.2 The sample has set to verify 1 1% oil by volume.
14.0 1372c l
ENuclear "u*r m.i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
7.1.3 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
7.1.4 The appropriate portions of Attachment 7 have been completed including the balance calibration data and the sequential sample number.
7.2 Procedure 7.2.1 MEASURE out 380.1 gms of dewatered powdered resin and 151.5 gms of water and place into a mixing vessel.
=__=__==_ -.
-- =.........==--- =----
Test solidification Nih0ml#--.
.=
disposablegakerford;houldfb[co
'u ted ksim[la[\\ 1{e{c'ogtain?.
NOTE:
- B Se,.h ','d,4,(
b g y u-
====-
=-----
liREC0_RD[thtg(ojyme5cf he sample (resin and water) on Atta c
7.2.2
'gPJa 7.2.3 MEASURE out 444 grams of Portland Type I cement and approximate-ly 10 grams of Calcium Hydroxide, Ca(OH)2 also known as hydrated lime.
7.2.4 Slowly ADD the calcium hydroxide to the powdered resin slurry, two (2) grams at a time. HIX for three (3) minutes between additions until the pH is at least 11. ADD an additional three (3) grams of calcium hydroxide. This final addition may or may not alter the pH of the slurry.
= - - - - - - -
==
-_=_=
NOTE:
Mixing should be accomplished by stirring with an electric mixing motor with blade or manually with a rigid stirrer until a homogeneous mixture is obtained approximately one (1) minute.
= - - - - - _ - -. _ ___=- =.
__===-------
=-
7.2.5 RECORD the quantity of calcium hydroxide added to the slurry on.
7.2.6 Slowly ADD the cement to-the test sample while it is being mixed.
7.2.7 MIX for one (1) minute after all the cement is added to obtain a homogeneous mixture.
15.0 1372c
(UCISar THI-i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
7.2.8 Seal and allow the sample to CURE for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> at 120 2 5'F.
=_
NOTE:
If at anytime during the 24-hour cure time, the sample meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be dis-qualified without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
_=
7.2.9 When the Acceptance Criteria has been met per Section 10, calculate the required quantitles of cement and additives using a liner type applicable for this waste type (as determi by Radwaste Operations Engineering) and the Solidif cat o icula-tion Sheet for Used Precoat (Attachment 8).
+
_--------- ------------------_---------_-_--- Jr N ---
1-_--
NOTE:
Thelinershallbesolidifffd sink 104 C, Primary
= -.
=
ResinandPrecgtgP,rgesynd Qtm f'( W $ 9
- q. ------------
__=-_-------_--
8.0 TESTSOLIDIFICATIONOF-BEADRESIN[k w
gu Prerequisites ($
8.1
_= _------_-_
NOTE:
This PCP Test Solidification Procedure is applicable to Class A Stable, Class B and C Haste Forms.
_..------- __=_ --------.
==_
_=__ -
__==------_
8.1.1 A sufficient size sample of bead resin (approx. 500 ml) has been drawn and the following parameters analyzed for by Plant Chemis-try:
pH (of sluice water) a Gamma Scan
_--- _ _ ----_--------- _----_...-------- -_= =--- _
NOTE:
The gamma scan is to be used for information purposes only to track waste characteristics and is not to be used in the PCP calculations.
8.1.2 The sample has set to verify 1 17. oil by volume.
8.1.3 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
16.0 1372c
ENuclear
=-
1,1-i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
8.1.4 The appropriate portions of Attachment 9 have been completed including the sequential sample number.
8.2 Procedure 8.2.1 MEASURE into a mixing vessel 320 gm of dewatered resin and 235.3 gm of water.
== --------
NOTE:
Test solidification should be conducted using a 1,000 ml disposable beaker or similar size container.
=_-__
8.2.2 RECORD the total volume of the sample (resi q
r1 l.
I
.,<-5*Q 8.2.3 MEASUREout,653,6gm6fPbrtdand
'eme a
pproximately 18 grams'of Calci.bs Hy'dr' iids 'C; so known as hydrated '
o 6 h t { { \\j "2 5 *
- i,ime..b g(y0 0
SloblhADthecalciumhydroxidetothebeadresinslurry,two 8.2.4 (2) grams at a time. MIX for three (3) minutes between addi-tions until the pH is at least 11.5.
ADD an additional three (3) grams of calcium hydroxide. This final addition may or may not alter the pH of the slurry.
8.2.5 RECORD the quantity of calcium hydroxide added to the slurry on.
8.2.6 Verify final pH is > 11.5.
8.2.7 Slowly ADD the cement to the test sample while it is being mixed.
8.2.8 MIX for one (1) minute after all the cement is added to obtain a homogeneous mix.
8.2.9 RECORD the quantity of cement added to the slurry on Attach-ment 9.
8.2.10 SEAL the sample and allow the sample to CURE for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> at 120 2 5'F.
NOTE:
If at anytime during the 24-hour cure time, the sample meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be dis-qualified without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
17.0 1372c
)
i
ENuclear 1,1-3 Operatina Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
8.2.11 When the Acceptance Criteria has been met per Section 10.0, CALCULATE the required quantities of cement and additives using a liner type applicable for this waste type (as determined by Radwaste Operations Engineering) and the Solidification Calcula-tion Sheet for Bead Resin (Attachment 10).
=-_
__=_
NOTE:
The liner shall be solidified using OP 1104-28C, Primary Resin and Precoat Processing - Hittman.
9.0 ALTERNATE TEST SOLIDIFICATION PROGRAMS
=D*
__==_==
ngthpro dkr$'
NOTE:
The PCP Test Solidification presented he-shouldcoverthemajorityofthe%steproces ng ments of THI-1.
In,theeye~n
$1ffsge
%s stream g
procedure-butE.s~(gor *awases requires proce sin mit red by this hai$g
'sppr late waste form or no liner typ'e',;gPCP s 90 ification can be performed Hittman.4 * (pl p usingajcuri' edure provided by Westinghouse -
==
__====_=_- --
__= -
._ =__
9.1 Prerequisites 9.1.1 A procedure is available for the particular waste stream to be processed.
9.1.2 This procedure has been verified current by the Radwaste Ops.
Manager or his designee and will be reviewed by the Radwaste Engineer prior to its use.
9.1.3 The sample required by this procedure has been obtained and i
applicable chemistry parameters analyzed for by Plant Chemistry.
9.1.4 The Ops Quality Assurance Grogp has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
9.1.5 Balance calibration data has been included on Attachment 11.
9.1.6 1 has been completed.
9.2 Procedure 9.2.1 Performed the applicable portions of the Westinghouse - Hittman procedure.
1 18.0 1372c
Nuclear 1H1_i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
10.0 ACCEPTANCE CRITERIA 10.1 Solidification Acceptability 10.1.1 The sample solidification is considered acceptable if there is not visual or drainable free water.
10.1.2 The sample solidification is considered acceptable if it resists penetration.
V, n
- gY9 %
h0TES Eventhohhthesamplesu,rfacea'qpeh and dry this may be just a surface crustQIn otAr to avoid this situation the solidif tcatibri$all be considered acceptable ifaflatsurfacemeta1pjoire(approx.1/8inchindiameter) 4 cannot break.thes sti ftce*and penetrate to the sample core.
t Normalade.ntingoffthe surface is acceptable.
p9 -
~~~---
Solidifikattori(Up ceptability 10.2 10.2.l%Ng g.
f the waste fails any of the criteria set forth in Section 10.1 g
the solidification will be termed uni.cceptable and a new set of solidification parameters will need to be established under the procedures in Section 10.3.
10.2.2 If the test solidification is unacceptable then the same test procedure must be followed on each subsequent batch of the same type of waste until three consecutive test samples are solidi-fled.
10.3 Alternate Solidification Parameters 10.3.1 If a test sample for Class A unstable waste falls to provide acceptable solidification of waste the following procedures should be followed.
a.
Mix 454.5 gms of cement and 45.5 gms of ASMS with 400 mis of water to ensure that the problem is not a bad batch of cement.
b.
Add additional 50 wf.7. NaOH to raise the pH above 8 but less than 9.2 for borated wastes.
19.0 1372c
Nuclear mi Operating Procedure 1104-281 Title Revision No.
Haste Solidification Process Control Program 7
c.
If the waste (other than waste oil) is only partially solidified, use lower waste to cement and Hetso ratios.
Using the recommended quantittas of cement and Hetso Beads, reduce the waste sample to 375 ml and continue reducing the sample volume by 25 ml. until the acceptability criteria of Section 10.1 are met.
d.
If the waste oil mixture is only partially solidified try using lower waste to cement ratics. Reduce the quantity of waste by 25 ml. and the emulsifier by 1 ml., (This will result in a slightly higher concentration of emulsifier in the waste) and proceed with the test solidification.
Continue with similar reductions until a satisfactory product is achieved.
10.3.2 For Class A stable, Class B and C waste test samples that fall to solidify, Contact Radwaste Operations Engineering for resolu-tion.
/&
j 20.0 1372c
Nuclear 1HI_i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 1 Page 1 of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR 4 TO 10 WT% BORIC ACID Chemistry Parameters Balance Cal. Info.
Liner No.:
Sample Date CMTE No.
Sample No.:
Boron ppm Serial No.
Date:
Total Solids ppm Cal. Due Date Waste Class e g pH Total Act.
FC1/cc 9
l I.
PRECONDITIONING:
gB
\\ hgb g
. ;k 4 o.v
.5 Weight Percent of Boric. Aci'd(in]declya.ld form):
, r-L, _
1 g4 s
Boron (ppm)
$ \\' (
'-8 1748 x.01 xj 748 x.01 (1)
Weight of Untreated Sample:
gms (2)
Volume of Untreated Sample:
mis (3)
Weight of 50% Na0H Added to Adjust pH gms (4) within range per Section 4.2.4.
pH of treated sample:
Weight of Anti-foam Added:
gms (5) 1
% 011 :
Weight of Emulsifier Added:
gms (6)
Volume of treated sample:
mis (7)
Weight of treated sample:
I (2) + (4) + (5) + (6) - ( )+( ) +( )+( )-
gms (8)
El-1 1372c
ENuclear 1MI_i Operatino Procedure 1104-281 Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT I (Cont'd)
Page 2 of 4 II. DETERMINATION OF PERCENT SOLIDS OF SAMPLE:
Height of Boric Acid Untreated Sample:
(2) x (1)
-(
) x (
)
gms (9)
Height of 50% NaOH:
- N
{O\\
- Agar ( 11 )
(4) x 0.5
(
) x 0.5 -
Height of Solids in Treated Sample:
n T h h.
c, S t ',. A y '6 h n (5) + (6) + (9) + (10)
,;m
,,,c
~
yu hgy d, 3
(
)+(
)+(
) e.C ')
gms (11) t PercentSolidsinTreategSaNhle:
- 9 100 x (11) + [(8)] -
100 x (
) + [( )) -
1 (12)
III. DETERMINATION OF HATER IN SAMPLE FOR SOLIDIFICATION:
Volume of Treated Sample to be Solidified:
ml (13)
Height of Treated Sample to be Solidified:
gms (14)
Height of Water in Sample Contributed by Haste:
(2) x (14) x'
[1 - (1)] -
, 8)
(
"( ) x(
)
x
[1 - ( })
gms (15) l
( )
Height of Water in Sample Contributed By 50% NaOH:
(4)
[ (8) x (14)] x 0.5
(
)
gms (16) l
[(
) x (
)]
x 0.5 Total Height of Water in Sample:
(15) + (16) - ( )+( )-
gms (17)
El-2 1372c
Nuclear 1M1_i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT I (Cont'd)
Page 3 of 4 IV. DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENT AND METSO BEADS TO USE FOR SAMPLE SOLIDIFICATION:
Using Figure I, find the % solids in sample (12), and DETERMINE the Water / Cement Ratto:
(18)
Weight of Cement to Use:
(17)
(
)
1h'
=
=
(18)
(
)
M 19k Weight of Metso Beads to use:
Oh3 h (19) x 0.15 - (
) x 0.15 -
~~
,,o, 6 _ m 9 gms (20)
Test Solidtflcation P,erfor'med.By:',.(9 \\%) O F k3 g
t t
t
>a 3g %d
^
Name u"
Date Time Additional batches solidified based on this sample solidification:
Liner Haste Liner Haste Liner Haste No.
Vol.
Date No.
Vol.
Date No.
Vol.
Date 2.
5.
8.
3.
6.
9.
4.
7.
10.
V.
SAMPLE INSPECTION Sample cured for:
Hours Cured Temp. Cured Verified By Date Sample contains "No Free Liquid":
El-3 1372c
Nuclear
""*b'r 1st_i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 1 (Cont'd)
Page 4 of 4 Verified By Date Sample " Resists Penetration":
Vertfled By Date FOOTNOTES:
1.
Maximum allowable oil content for stable waste is 1% by volume.
9 a#gh
- e%$& oh u.
k x
,.- t,R \\'
)
~
, y g \\{tg 'i
.. Q e
- W,1 gh El-4 1372c
Nuclear 1sI_i Operattnq Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 2 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR 4 TO 10 HT7. BORIC ACID Liner Type to be used II. Volume of Untreated Haste to Add to Linerl:
(3)
Max. Treated Haste Vol.
(7) x from Solidification Data Tables
.h
(
)
1 l
ft3
- 4
(
)
x gi)
Q eq* %
II. Volume of Additives to Add to Liner:
pi e
NaOH:
(4) x 4.86 4.(21}3 2. ( ) x4.1864d(
)=
gals (22)
(3,) r 'l
, 9
- O r Anti-foam
(5) x 7.48.)J(2Ii3 - ( ) x 7.48 x(
)-
gals (23) l (3) L
( )
Emulsifier:
(6) x 7.48 x (21)3 - ( ) x 7.40 x(
)-
gals (24)
(3)
( )
i III. Volume of Treated Haste to be Solidified :
(22) + (23) + (24)
(
) +(
) +(
)
i ft3 (25)
I (21) +
7.48
(
)+
7.48 IV. Cement Quantity for Full Scale Solidification:
lbs (26)
I (19) x 62.4 x (25) - (
) x 62.4 x (
)
(13)
(
)
(26) + 94 - (
) + 94 -
bags 2 l
V.
ASMS Quantity for Full Scale Solidification:
(26) x.15 - (
) x.15 -
Ibs (27)
(27) + 100 - (
) + 100 -
bags 2 E2-1 1372c
i Nuclear 1M1-i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 2 Page 2 of 3 FOOTNOTES I
The volume of treated waste to be solidified in a single liner cannot exceed the maximum treated waste volume listed on the attached Solidification Data Tables.
2 Round off up to the nearest whole bag.
3 If waste volume added to liner is less than the value obtained in equation 21, use the actual volume added to the liner.
VI. DETERMINATION OF THE QUANTITY OF CEMENT ADDED TO HASTE:
Quantity of Cement Added to Hopper:
,gQ db (28)
Q{T {
Quantity of Cement Left in Hopper:~
t i lbs (29)
^
Quantity of Cement Added pe ft.3Ha(te,.: e
) -;(d N N J 8 (28) - (29) - (
Ibi cement /
(25)
(- )
ftJ waste NOTE:
Minimum Quantity of Cement Allowable for 4 to 10 Ht. %
Boric Acid Class A Unstable Haste is 62 lbs./ft.3, For Stable waste solidifications all the cement must be added to the liner.
Quantity of Cement Added Meets Minimum Requirements:
Verified By Date The recommended minimum treated waste volume and minimum solidified waste volume meet the requirements of the Solidification Data Tables for STABLE waste forms.
Verified By Date E2-2 1372c
gggy Number Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
ATTACHMENT 2 (Cont'd)
Page 3 of 3 SOLIDIFICATION DATA TABLES FOR 4 TO 10 WT% BORIC ACID HN-100 HN-100 LVM Series 3 Series 3I Usable Liner Vol. (cu. ft.)
141.1 157.5 Max. Treated Waste Vol. (cu. ft.)
104.4 116.6 h
157,5 d p h 4 g.
% '~
Max. Solidified Waste 141.1 a
Vol. (cu. ft.)
m
'l
- g s % '% td4i J
e c
Recommended Min.
Treated Waste Vol.
98.1 103.8 (cu. ft)2 g
Min. Solidified Haste Vol. (cu. ft)2 132.6 140.2 Max. Rad. Level 12 12 R/hr Contact 1.
For less than A2 quantities of LSA waste.
For greater than A2 quantitles of LSA waste, the maximum treated waste volume is 112.4 cu. ft. due to weight Ilmitations.
2.
These minimums are required when shipping to Barnwell, to comply with the 15%
maximum vold space criteria for liners containing solidified stable waste forms.
E2-3 1372c
Nuclear THI-i Operatino Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 3 Page 1 of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET > 10 TO 20 WT% BORIC ACID Chemistry Parameters Balance Cal. Info.
Liner No.:
Sample Date CMTE No.
Sample No.:
Boron ppm Serial No.
Date:
Total Solids ppm Cal. Due Date Haste Class pH Total Act, pC1/cc fS
,., ec h pg
(
o 3
I.
PRECONDITIONING n i,1, 9, e
Height Percent of Boric, Acid (in decimal.{fpi'm.g c.
. s ;p a
a f
\\ )tM g s
\\,
Boron (ppm)
,(
t 1748 x.01 - g 1748 x.01 (1)
Height of Untreated Sample:
gms (2)
Volume of Untreated Sample:
mis (3)
Height of 50% NaOH Added to Adjust pH per Section 5.2.4:
gms (4) pH of treated sample:
l Height of Anti-foam Added:
gms (5) 1
% 011 :
Weight of Emulsifier Added:
gms (6)
Volume of treated sample:
mis (7)
Height of treated sample.
gms (8)
(2) + (4) + (5) + (6) - (
)+(
)+(
)+(
)-
E3-1 1372c
Nuclear Ts!-i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 3 (Cont'd)
Page 2 of 4 II. DETERMINATION OF PERCENT SOLIDS OF SAMPLE Height of Boric Acid Untreated Sample (2) x (1)
-(
) x (
)
gms (9)
Neight of 50% NaOH:
(4) x 0.5
(
)
x 0.5 -
gms (10)
Height of Solids in Treated Sample:
(5) + (6) + (9) + (10) -
(
)+(
)+(
)+(
)-
gms (11) i Percent Solids in Treated Sample:
if 100 x (11) + [(8)) =
100 x (
) + [(
)) -
" '., c, c' ?
i j
+
s..
('2)
.a1M III. DETERMINATION OF WATER IN SAMPLE FOR SOLIDIFICATI N:
y;d**'
Volume of Treated Sampleator be Solidified:
ml (13)
Weight of Treated Sample to be Solidified:
gms (14)
Height of Water in Sample Contributed by Haste:
'(2) x(14i x [1 - (1)) -
, 8)
(
'( ) x(
i x [1 - (
}) -
gms (15)
( )
Weight of Water in Sample Contributed by 50% NaOH:
(4)
(
)
[(8) x (14)) x 0.5
[(
) x (
)) x 0.5 gms (16)
Total Height of Water in Sample:
(15) + (16) = (
)+(
)-
gms (17)
E3-2 1372c
Nuclear THI-i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
l l
I ATTACHMENT 3 (Cont'd)
Page 3 of 4 IV. DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENT AND METSO BEADS TO USE FOR SAMPLE SOLIDIFICATION:
Using Figure I, find the 7. solids in sample (12), and DETERMINE the Water / Cement Ratio:
(18) l Height of Cement t( Use:
(17)
(
)
\\
(18)
(
)
(19)
Weight of Hetso Beads to use:
(19) x 0.15 - (
) x 0.15 -
f, gms (20) l Test Solidification Performed By:
p x
.h Name
_;,g4' Date Time Additional batches solidified $., s
- ased on this sample solidification:
sa Liner Haste
, S
Liner Haste Liner Haste No.
Vol.
Date No.
Vol.
Date No.
Vol.
Date 2.
5.
8.
3.
6.
9.
4.
7.
10.
V.
SAMPLE INSPECTION Sample cured for:
Hours Cured Temp. Cured E3-3 1372c
Nuclear m _i Operatino Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 3 (Cont'd)
Page 4 of 4 Verified By Date Sample contains "No Free Liquid":
Verified By Date Sample " Resists Penetration":
Verified By Date FOOTNOTES:
1.
Maximum allowable oil content for Stable Haste i 1
k g$ b4 M4 r
a
,,T r~) ' s ;d c,3.ug m
!'('M
.$ y, g 4 E3-4 1372c
Nuclear TsI_i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
ATTACHMENT 4 Paga 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR > 10 TO 20 WT7. BORIC ACI,0 Liner type to be used I.
Volume of Untreated Waste to Add to Linerl:
(3)
Max. Treated Waste Vol.
(7) x from Solidification Data Tables - c,g
(
)
j%
i
.s
(
)
x m
MM t
(21)
I c.; 'p '4 '
s a i
II. Volua,e of Additives to Addgtg ner:
.,f NA0H:
(4) x' 4186k x (21)3 - (
) x 4.86 x(
)-
gals (22)
(3)~
(
)
Anti-foam:
(5) x 7.48 x (21)3 - (
) x 7.48 x(
)-
- gals (23) l (3)
(
)
Emulsifier: (6) x 7.48 x (21)3 - (
) x 7.48 x(
)-
gals (24)
(3)
(
)
l III. Volune of Treated Waste to be Solidified :
(22) + (23) + (24)
(
)+(
)+(
)
(21) +
7.48 ft3 (25)
(
)+
7.48 IV. Cement Quantity for Full Scale Solldtfication:
(19) x 6.24 x (25) = (
) x 6.24 x (
)-
Ibs (26)
(13)
(
)
(26) + 94 - (
)
94 -
bags 2 g
V.
ASMS Quantity for Full Scale Solidification:
(26) x.15 - (
) x.15 -
Ibs (27)
(27) + 100 - (
)
100 -
bags 2 E4-1 1372c
Nuclear TsI_i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
ATTACHMENT 4 Page 2 of 3 SOLIDIFICATION CALCULATION SHEET FOR > 10 TO 20 HT% BORIC ACID FOOTNOTES I
The volume of treated waste to be solidified in a single liner cannot exte d the maximum treated waste volume listed on the attached Solidification Data les.
2 Round off up to the nearest whole bag.
/
3 If the waste volume added to the liner is less than the e
n d in equation 21, use the actual volume added to the liner.'
DETERMINATIONOFTHEQUANTITYOFCEMENTADDEDT0gd VI.
. ch e 91 {%g Quantity of Cement Added to Hopper:
,s-lbs (28)
Quantity of Cement Left in Hopper 4
lbs (29)
Quantity of Cement Added per ft 3 Waste:
y 3
(28)
(29) = (
) - (h 3 -
Ibg cement /
(25)
(
)
ftJ waste NOTE:
Minimum Quantity of Cement Allowable for >10 to 20 Ht.
% Boric Acid Class A Unstable Haste is 60 lbs./ft.3, For STABLE waste solidifications all the cement must be added to the liner.
Quantity of Cement Added Heets the Minimum Requirements:
Verifted By Date The recommended minimum treated waste volume and minimum solidified waste volume meet the requirements of the Solidification Data Tables for STABLE waste forms.
Verifted By Date E4 2 1372c
Nuclear 1s!-i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 4 (Cont'd)
Page 3 of 3 SOLIDIFICATION DATA TABLES FOR > 10 TO 20 HT% BORIC ACID HN-100 HN-100 LVM Series 3 Series 31 1
Usable Liner
'hk Vol. (cu. ft.)
141.1 157.5 sh Max. Treated Waste Vol. (cu. ft.)
101.3 g f g1 g gv I
,x%
g;4,5g54 Max. Solidified Haste 141.1
--1 Vol. (cu. ft.)
9-f
'T. 'y Q
'y 4 Recommended Min.
of '
Treated Waste Vol.
95.2.b -
100.7 (cu. ft)2 o
9 Min. Solidifl Vol.(cu.ft)gdHaste 132.6 140.2 Max. Rad. Level 12 12 R/hr Contact I-For less than A2 quantitles of LSA waste. For greater than A2 quantitles of LSA waste, the maximum treated waste volume is 106 cu. ft. due to weight limitations.
2-These minimums are required when shipping to Barnwell, to comply with the 15%
maximum vold space criteria for liners containing solidified stable waste forms.
E4-3 1372c
Nuclear 1,1_i Operatino Frocedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 5 Page 1 of 2 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DA.
HEET FOR HASTE OIL e
Balance Cal. Info Liner No.:
6 CNTE No.:
Sample No.:
1 o % }(* 4
.,w Serial No.:
Date:
HasteCIahg-Cal. Due Date:
4(k)
I.
SAMPLE PREPARATION a o#
Volumeof011tobeSolidified$
mis (1)
Volume of Concentrated (Ha te added to the oll:
mis (2)
% 011 by Volume Total Volume of Sample:
(3)
Quantity of Emulsifier to Add to Sample:
mis (4)
Quantity of Anti Foam Added to Sample:
mis (5)
Quantity of Portland Type 1 Cement Added to Sample:
gms (6)
Quantity of Anhydrous Sodlum Metasilicate Added to Sample:
gms (7)
Test Solidification Performed by:
~
Name Date Time Additional batches solidified based on this sample solidification:
Liner Haste Liner Haste Liner Haste No.
Vol.
Date No.
Vol.
Date No.
Vol.
Date 2.
5.
8.
3.
6.
9.
4.
7.
10.
1 ES-1 1372c
gg p
Number Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 5 (Cont'd)
Page 2 of 2 II. SAMPLE INSPECTION Sample cured for:
Hours Cured Temp. Cured Vertfled By Date Sample Contains "No Free Liquid":
Vertfled By Date Sample Resists " Penetration":
3 Vertfled By di'g oeek S ES-2 1372c
ENuclear number ry,_,
Operating Procedure 1104-281 Title Revision No.
Waste Solldtfication Process Control Program 7
ATTACHMENT 6 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR WASTE OIL I.
PARAMETERS FOR FULL SCALE SOLIDIFICATION Emulsifier:
(4) x 7.48 + (1) -
x 7.48 +
/
(8)
,yh Anti-foam 4
(5) x 7.48 + (3) =
x 7.48 +
gall (9) s 1,3.p
- ft3
- A 's
- ('b
/
Cement:
N.i mg%'
(6) x 62.43 + (3) ='
'e 3 x 62.43 +
Ib /
(10) ft ga ASMS:
I (7) x 62.41 + (3) =
x 62.43 +
ftg/
(11)
Ib II. Liner type to be used III. Volume of untreated waste to add to liner:
Max Treated Waste Vol. from Solidification Data Tables:
(12) l Concentrated Waste to be added:
60% x (12) x 7.48 - 0.60 x (
) x 7.48 -
gals (13)
Waste 011 to be added:
40% x (12) = 0.40 x (
).
ft3 (14) 40% x (12) x 7.48 - 0.40 x (
) x 7.48 gals l
Anti-foam to be Added:
(12)3 x (9) - (
) x(
).
gals E6-1 1372c
ENuclear number 1,1_,
Operatino Procedure 1104-28I Title Revision No.
Haste Solidtftcation Process Control Program 7
ATTACHMENT 6 (Cont'd)
Page 2 of 3 IV. Volume of Additives to add to liner:
i 1
Emulsifier to be added:
(14) x (8) = (
)x(
)-
_ als
.g Anti-foam to be Added:
(12)3 x (9) - (
)x(
)-
')
gals l
0" % p o, \\,
v ASMS to be added:
.s
\\
6' d T
) x,L ) k ;[3;g (12)3 x (11) - (
g Ibs (15) l (15) + 100 - (
') + 100 - 1'9 bagsl l
d v. ' 3 t
Volumeof'cementtgadd'toliner:
(12)3 x (10)i #(>
l
)x(
)-
Ibs (16)
(16) + 94 - (
) + 94 -
_bigsl l
FOOTNOTES:
1 Round off up to the nearest whole bag.
(
2 Reduce the quantity of total waste in the liner oy 1 ft3 for every 10 gallons of anti-foam added to the liner. No adjustment is necessary for the first 10 l
gallons.
l 3
If waste volume added to liner is less than the value obtained in equation 12, use the actual volume added to the liner.
t E6-2 1372c
I P L Nuclear 1MI i Title Operating Procedure 1104-28I Revision No.
Nasto_Solidtfication Process Control Prcoram 7
ATTACHMENT 6 (Cont'd)
Fage 3 of 3 SOLIDIFICATION DATA TABLES FOR WASTE OIL HN-100 HN-100 Series 3 LVH 3
Usable Liner Volun.e, (ft )
141.1 157.5 Max. Haste Volume (oll and conc. waste), ft3 93.7 104.6 Max. Solidified Volume, ft3 141.1 157.5 Maximum Rad Level R/hr Contact 12 12
'{k
(,8g {N
%) o
- pd D (
w-
,.s u,.3,a I
s E6-3 1372c
Nuclear TsI_i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
ATTACHMENT 7 Page 1 of I CLASS A STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR USED PREC0AT Balance Cal. Info.
Chemistry Parameters Liner No.:
CMTE No.
pH Sample No.:
Serial No.
Gamma Scan PC1/mi Date:
Cal. Due Date
% 011 Waste Clas u 4 g
I.
SAMPLE PREPARATION Sample Volume:
kN ml (1)
Grams Ca(OH)2 to raise pH to 1 11.
gm (2)
Final Sample pH:
(
A34 gm (3)
Grams Portland Type I Ce ht 'addd' gm 3.e -
Test Solidification Performed By:
Name Date Time II. SAMPLE INSPECTION Sample cured for:
Hours Cured Temp. Ccred Ver1 fled By Date Sample Contains "No Free Liquid":
Vertfled By Date Sample " Resists Penetration":
Verifted By Date E7-1 1372c
ENuclear THI_i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 8 Page 1 of 2 SOLIDIFICATION CALCULATION SHEET FOR USED PREC0AT I.
PARAMETERS FOR FULL SCALE SOLIDIFICATION:
Quantity of (Ca OH)2:
(2) x 0.172 - (
) x 0.172 -
Ib (4)
Ca(OH)2/
FT3 Resin
-Y Quantity of Cement:
k
.lb (3) x 0.172 - (
) x 0.172 -
Cement /FT Q )$
3 gsf%%
i Waste Volume to be Solidified :
(6).
Liner Type:
i
( 'h II. OUANTITIES TO BE ADDED FOR FULt SCALE SOLIDIFICATION
%'p'4%
s Nater:
(6) x 3.12
( ) 3.12 -
gals (7)
Calcium Hydroxide:
(6) x (4)
(
) x (
)-
lbs.
(8)
=
(8) + 100 - (
) + 100 -
bags 2 Cement:
l (6) x (S)
(
) x (
)
lbs (9)
(
) + 94 -
bags 2 (9) +
94 1
The volume of waste, to be solidified in a liner cannot exceed the maximum settled and treated waste volume listed on the Class B Haste Solidification Data Table for used precoat.
2 Round up to the nearest whole bas.
E8-1 1372c
Nuclear TsI-i Operatino Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 8 (Cont'd)
Page 2 of 2 SOLIDIFICATION DATA TABLE FOR USED PREC0AT HN-6001 HN-200 Usable Liner Volume, ft3 65 60 Max. Solidified Waste Vol. ft3 65 60 33.7, $1 Max. Settled Waste Vol., ft3 36.52 Water Added at Max.
Haste Volume: gallons h
's f
ef 4
'I05 Ca(OH)2 Added fi
$tnote(5)
Footnote (5) g Max. Radiation Level O'
) %
4q %
shcs R/hr Contact of Liner
,, ', i pig'4 100 800
%O
- s. 'sh
.3>
FOOTNOTES:
I Values shown for plain and grappable liner. Multiply all values by 0.922 for stackable or 0.893 for the stackable/grappable lir.ers. See Footnote 4.
2 Based on 15 inches of settled powdered resin in the liner, 14 inches for stackable and stackable/grappable.
3 Based on 28 1/2 inches of settled powdered resin in the liner.
4 For dewatered powdered resin use 114 gallons of additional water for all sizes of HN-600 liners.
5 To be calculated for each solidification.
E8-2 1372c
Nuclear 1sI i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 9 Page 1 of 2 CLASS A STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR BEAD F.ZSIN Balance Cal. Info.
Chemistry Parameters Liner No.:
CMTE No.
pH Sample No.:
9 Serial No.
Gamma Scan FC1/ml Date:
Cal. Due Date
% Oil Nast[Clss:
I.
SAMPLE PREPARATION Sample Volume:
3
{'s mis (1)
Grams of Ca (OH)2 to raise @pH. To >il ',5jV*
gms (2)
.].gw
,. M Final pH:
% h Weight of Portland Type I Cement:
gms (3)
Test Solidification Performed By:
Name Date Time Additional batches solidified based on this sample solidification:
Liner Waste Liner Haste Liner Haste No.
Vol.
Date No.
Vol.
Date No.
Vol.
Date 2.
S.
8.
3.
6.
9.
4.
7.
10.
II. SAMPLE INSPECTION Sample cured for:
Hours Cured Temp. Cured Verified By Date E9-1 1372c
(UCl68r TsI_i Operating Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 9 (Cont'd)
Page 2 of 2 CLASS A STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR BEAD RESIN Sample contains "No Free Liquid":
Verified By Date Sample " Resists Penetration":
Verified By Date
%i
- g
,j $ k --
g 0, % %
d
\\6
, <* g% ' n, s,1 l '-:, Q'O' -
p'.
n e
,7-
,e gs
' $3 q'
o E9-2 1372c
Nuclear TsI_i Operating Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
ATTACHMENT 10 Page 1 of 2 SOLIDIFICATION CALCULATION SHEET FOR BEAD RESIN II. PARAMETERS FOR FULL SCALE SOLIDIFICATION Liner Type:
%,' kk Quantity of Calcium Hydroxide:
(2) x 0.156 - (
) x 0.156 -
lbo%
%t OH )'l C
2 tFT _Res'in Quantity of Cement:
(3) x 0.156 - (
) x 0.156 -
g (. - - {'t lb (5)
, g(5 cement /FT3
,,# gy p resin VolumeDewateredResint6heSolid1'ft ft3 (6) 14 w II. OUANTITIESTOBEADDEDFORIFULLSCALESOLIDIFICATION Quantity of Water:
(6) x 4.4 gal /ft3-(
) x 4.4 -
gals (7)
Quantity of Calcium Hydroxide:
(6) x (4) - ( )x(
)-
Ibs (8)
(8) 100 - ( )
100 -
bags 2 Quantity of Portland Type I Cement:
(6) x (5) - ( )x(
)-
Ibs (9)
(9) 94 - (
)
94 -
bags 2 I
The volume of dewatered bead resin to be solidified cannot exceed the maximum treated waste volume listed on the Class A Stable, Class B and C Test Solidification Data Sheet for Bead Resin.
2 Round up to the nearest whole bag.
E10-1 1372c
1104-28I Revision 7 ATTACHMENT 10 (Cont'd)
Page 2 of 2 SOLIDIFICATION DATA TABLES FOR BEAD RESIN HN-100 HN-100 HN-600(1)
Series 3 LVMU HN-200 S
G S+G R
Usable Liner 143.0 153 59.5 59.6 64.6 57.7 64.6 Volume (cu. ft.)
Max. Dewatered 77.9 78.3 47.6 32.5 35.2 31.4 35.2 Waste Volume (cu. ft.)
Max. Solidified 143 143.7 59.5 59.6 64.6 4.7 64.6 Waste Volume (cu. ft.)
fg
{
Ca(OH)2 added at g
Max. Waste Volume (2)
O
"?
Weight (1bs.)
218 219.1 143.3 c191 88 99 Volume (bags) 4.4 4.4 2, 9 T'A %I "2.8 1.8 2.0 S
- h Lit 4 %
Portland Type I
, M' Y%f k s 0 i f% 'hk Cement Added a2 Max. Haste Vol.(2) n q 's A gg4 Weight (1bs.)
7945.8, s 7986.6 4 1766.0 3315 3590.4 3202.8 3590.4 84.53
- 4 4 Volume (bags) 85.0 18.8 35.3 38.2 34.1 38.2 Water Added to 343 345 100.0 143 155 138 155 Max. Haste Vol. (Gallons)
Max. Rad. Level 12 12 800 100 100 100 100 R/hr Contact I
(1) S - HN-600 Stackable G - HN-600 Grappable S+G - HN-600 Stackable - Grappable R - HN-600 Regular i
E10-2
.=.
r ENuclear Tsi-i Operatino Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 7
ATTACHMENT 11 Page 1 of 1 TEST SOLIDIF'ICATION USING WESTINGHOUSE - HITTHAN PROCEDURE Waste to be Processed:
Westinghouse - Hittman Procedure No.
Procedure - Tit 1e g'%
Current Revision n
(.*
n*s' _ 9lh l
c 4 $ . k p?
Justification to use this iT alternate test procedure:
1
,,, f'D 9, $ $ ("%g: \\
e a h%
s
,, q "{,j; j g 't ' '
,;fh Liner Type Waste Class Balance Cal Info.
CMTE No.
Serial No.
Cal. Due Date Approved By Eng. Review By NOTE:
Form should be attached to valid Westinghouse - Hittman Procedure used for the Test Solidification
~
E11-1 1372c
F421-P-004 1104-28I Prgo 31 of 34 R* vision 7
____q
,1
~
t
\\..
..RCENI_SD
\\
_FI...
. UGURE 2.
.J LIDS MjpH AnUiSIED. HASTE i
(
I
\\
wt 9
\\
,, n
.R
--1 0.9
\\
5.
4 -- - -
X
,3n i
i e
wv a
v.
t1 'b
~
i y
\\
i
.s w
~~' ' ' ' '
- ~ ~ ~ ~
O
\\
N
\\
te
.i
,j
\\g
- w 41
'\\
4 t
~
a.
-+\\
b
~
<6 t
- .4 e '-\\
p
.i
>.i
's w.
i!
\\
e,
. 3.i p 3 is.
3
\\
l l
4 i
e
\\
s :,.
x i
\\
E POINT C. -
_T PQINT B k.
.....3
'T gg i
I
\\
(
4 i
EYA@l_E
\\
3
\\
2 SOLIDS 15.
X ENTER AT POIET A. __ -.
F5fRT.B
\\
\\
DR AIJ A 1 TMF T"I AM PnTMf' A Tn t'ffRvv 0.85 3.LINE FLOM POINI B_TO.1 AYTA.
POINT C
\\
j POINT C= WATU / CEMENT. RATIO,, n RAA
\\
o
\\
\\
- l
\\
a h
i 1_0 e
g ol
\\.
....._.i 1
"s
\\
2:
i i
x "B
A
~ - - -, __j t
3 l
\\
w l
_..q i
x
.a
.q l
(
r
(
l
\\
1 0.8 l
(
t i i i
i l
i i t ii.
i ;
i
~
PDINT A
~
O S
10 E12-1 15 20 25
% SOLIDS OF DH ADJUSTED WASTE