ML20210S604

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Identifies Interim Solution for Millstone,Unit 3 Which Will Remove Chlorine from Strainer Backwash Discharge.Application for Emergency Discharge Authorization Forwarded
ML20210S604
Person / Time
Site: Millstone Dominion icon.png
Issue date: 08/11/1997
From: Scace S
NORTHEAST NUCLEAR ENERGY CO.
To: Grier J
CONNECTICUT, STATE OF
References
SES-97-GN-126, NUDOCS 9709110196
Download: ML20210S604 (27)
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R<,r* uny RddRouw 1%), T
adord, Cr 062 Northeast s j Nuclear Energy nit. ion. Noci , rower st. tion b Northeast Nuclear Energy conq>any P.o. Box 128

- August 11,1997 v.i,aora, er Ocm.Ons (860) 447 1791 SES 97-GN-126 "'* ("' ) * * ' "

D11362 nn Northeut Utihties system Mr. James Grier Supervising Sanitary Enginee Water Management Bureau Department of Envhonmental Protection 79 Elm Street Hartford, CT 06106-5127

Reference:

1) Letter D11148 from S. Scace to J. Grier dated May 27,1997
2) Letter D11192 from S. Scace to J. Grier dated June 20,1997
3) Letter D11188 from S. Scace to J. Grier dated June 30,1997 Millstone Station l Recuest for Emeraency Authorization By way of verbal notification on May 20, and May 22,1997, and by way of letter I (References 1-3), Northeast Nuclear Energy Company (NNECO) advised the Department of the discharge of service water system strainer backwash at Millstone Units 1,2 and 3. This matter was discussed further at a meeting with the Department on May 29,1997, during which NNECO agreed to provide additional information ,

4 regarding possible engineering solutions. Accordingly, this letter identifies an interim solution for Millstone Unit 3 which will remove chlorine from the strainer backwash discharge. As a result, NNECO, in accordance with Section 22a-430 3(i) of the Regulations of Connecticut State Agencies (RCSA) hereby notifies the Department of a planned facility modification to remove chlorine from the Unit 3 strainer backwash and seeks emergency authorization under Connecticut General Statutes 22a-6k for this planned activity and ongoing discharge.

Unit 3 - Request for Emergency Authorization By way of background, the service water systems at the Millstone plants serve to cool various components throughout the plants. These components are vital to safe Plant ,t f operation and are therefore classified as " nuclear safety related". Even when the plants are in a shut down condition, these components generate heat, so the service water systems at Millstone must be operated at all times so that these components may be -h0f cooled.

NNECO is permitted to inject sodium hypochlorite into the service water systems to prevent biofouling of system components. NNECO employs " targeted chlorination" such that the injection point is located near the suction of the running service water pumps.

9709110196 970811' 1 PDR ADOCK 05000423 P PDR esammae ((((}{ ((\((}((${ kl h\\,hhkk,kk

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e In the past, NNECO has h:d sev;ra probi:ms with syst;m biofouling at tha Millston) plants and, as the Department is aware, is under a commitment to the Nuclear

, Regulatory Commission (NRC) to continuously inject sodium hypochlorite into the service water system at the Millstone Units.

With respect to Unit 3, service water flows to DSN 001C-5 and subsequently to DSN 001C. At DSN 001C-5, NNECO is authorized to discharge free available chlorine up to .

0.25 ppm. Each of the service water systems at Millstone are equipped with strainers, located at the discharge to the pumps, which remove suspended solid matter.

Periodically, these strainers must be backwashed. The backwash water is supplied by the service water system. At Unit 3, the discharge of the strainer backwash, rather than flow to DSN 001C, flows to two pipes (approximately 3 inch diameter) located on the East and West faces of the intake structure.

NNECO has performed an engineering evaluation of several alternatives for Unit 3. As a result, NNECO is proposing to re-route each of the service water hypochlorite injection lines from the service water pump suction bells to a previously abandoned service water pipe connection directly downstream of the strainers. This would allow for continuous chlorination of the service water system as is currently permitted and would eliminate chlorine in the Unit 3 strainer backwash discharge.

Other options considered would maintain the hypochlorite injection point in the pump bell housing but provide for mechanicalisolation of hypochlorite injection based on a timer and a time delay for automatic strainer backwash activation. However, these options would result in hypochlorite discharge during automatic activation of backwash due to differential pressure and the loss of hypochlorite injection to the service water system during extended periods of continuous strainer backwash resulting from storm -

related high debris loadings. As the service water system is safety related, it is vital that fouling be continuously controlled in keeping with NRC Generic Letter 89-13. This letter is available on request.

Following implementation of the proposed design change, Unit 3 would return to its previous backwash schedule. This includes timer activated backwash every four hours in conformance with an NRC commitment and activations due to differential pressure across the strainer. The duration of each timer activated backwash is approximately three minutes for each of the four strainers. Backwash flow is approximately 650 gallons / minute. Generally only two service water pumps are operating at any one time and so only two strainers would normally discharge.

NNECO be'ieves that an emergency authorization under the above circumstances is appropriate. Its issuance would serve to prevent the discharge of chlorine into the Long Island Sound and Niantic Bay via the Unit 3 service water strainer backwash. Moreover, under an emergency authorization, the Commissioner has the authority to impose such additional conditions as are necessary to adequately protect human health and the environment.

2

4 Addition:lly, becaus2 tha b;ckw:sh disch rga configurations ct Unit 1 and 2 ara

, different than Unit 3, NNECO will also be seeking, under separate cover, a temporary

, authorization, pursuant to Section 22a-6k of the Connecticut General Statutes, to perform additional sampling of the Unit 1 and 2 strainer backwash discharges containing chlorinated service water, This information will aid in our assessment of alternatives for these Mo Units.

Should you have any questions, please call Mr. Paul Jacobson, Environmental Services- Nuclear at (860) 447-1791 extension 2335.

Very truly yours, NORTHEAST NUCLEAR ENERGY COMPANY (acL

/

l S. Scace

! Director - Nuclear Engineering Programs cc: D. Gonyea, DEP -

NRC Document Control Desk NRC Resident inspectors 3

Application for an Emergency or Temporary Discharge Authorization I

Pursuant to Section 22a-6k C.G.S.

Picase complete this form and submit for review and processing to: .

Authorir.adon Coo.dinator DEP/ Bureau of Water Management . PERD 79 Elm Street

- . .. .. ._ , Hanford , CT 06106-5127 *- -- . ._

Note: The processing fees for Authorizations are typically; $500.00 for surface water dehge,5250.00 for sanitary sewer discharge, and 5750.00 for groundwater discharge. These fees may be modified higher or lower upon review by DEP. The fee for municipalhics shan be % of these fees, and the fee shall be walved for single family residences.

If an emergency exists on site, the application will be processed prior to submittal of fees. Fees shall then be due widdn 10 days ofissuance. If submined fees are deemed inadequate, addidonal fees shall also be due wi:hin 10 days of issuance.

The fee shall be non-refwdable and shall be paid by c.crtified check or money order payable to the Depanment of Environmemal Protection. The check shan state,

  • Water Management Fec'.

In addidon to the anached forms, the discharger shall submit:

l 1) A site diagram indi:ating the location of all structures, drainages, parkmg arcu, monitonut or recovery weUs, and all exisdng or proposed equip:cem, structures and discharge locadons associated with remediation etforts.

2) A copy of the USGS topographic map, or oter suitable map iMiming si:e location, adjacent roads, and ,

all adjacent wetlands or waterbodies.

3) Plans and specification for the proposed collection and treatment synem to be installed on site.
4) Analysis indicating pollutan.s in untrea:ed water in the L: waters to be discharged, Analysis to be submined shall be from samples collected within the past 12 months, and must include a complete a: counting of known or existing contaminants. Contact Donald Gouyca at (860) 424 3827 if questions crise. Resu!ts may be submined on the screening form supphed.
5) A repon detalling the nature of the work being conducted. If the discharge is to coniinae beyond 30 days. this report must detail the nature of the " imminent threat ta human health or the environment *
6) For all discharges to a POTW, a signed approval from the appropriate sewer authority.

NOTEt If the discharge is composed solely of groundwater remediation wastewater, and is discharged to a sanitary sewer, the discharger must file for coverage under the General Permit for the Discharge of Groundwater Remediation Wastewater to a Sanitary Sewer, issued August 13, 1996.

Bureau of Water Management 1 of 6 Res. o&!21/96 I

1.  : Fill in the name of the applicant / registrant / operator.

unr+w.m & wn e.1.a r vnerav company g VRegistranuOperator:

Mauidg ess: P.O. Box 128 City / Town: _

Waterford gut, CT Z p Code:

06385-0128 .

Busloess Phone; f860) 447-1791 extg 2335 pga. 4256 Contact Person: Paul M. Jacobson

Title:

Manager /Environmen ;al ausv6wwo-auvivas

2. List faculty or sita owner.

Name.

Northeast-Nuclear Energy Co.

Mailing Address: P.O. Box 128 City / Town: Waterford State: CT . Zip Code: 06385-0128 Business Phone: (860) 447-1791 ext. 2335 pax. 4256 Contact Person: Paul M. Jacobson Titic: Manacer/Envi ronment al Services-Nuclear

3. List site name and address.

Name: Millstone Nuclear Power Station Mailing Address: P.O. Box 128 City / Town: Waterford 3 3,,. CT Zip code:

06385-0128 Business Phone: (860)'447-1791 ,xg, 2335 p,x: 4256 Contact Person: Paul Jacobson Manager -

Tide.

4 List any engineer (s) or consultant (s) employed or retained to assist in prepanng the registration or in designing.

constructing or operadng the groundwater remediat:on wastewater activity.

Name:

Mailing Address:

City / Town: Sute: Zip Codet Business Phone: ext. Fax:

Contact Person:

Title:

Service Provided:

Bureau of Water Management 2 et a n.v. osts t tes N" ebe

,~ -19.1 @ 11:41 DEP WATER PE 060 420 4055 P.034E 1 1s the project site located in a town whhin a constal area as denned in sectan 22a-94(a) COS7 D&es D No (If unimown, contact Donald Gooyea at (460) 424-3827)

2. Is the project site located within an endangered, threatened or speela! concern species area as ide'atified on the

' State and Federal Listed Species and Namtal Communities Map'? -

(map available at DEP. 79 Elm St.. stors level)XE Yes a No Dass of yy. Attachment H IF UNKNOWN CHECK O Has a fictd survey been conducted to identify any presence or absence of endangered, threatened or special concern species? XZYes ~ O No If yes, provide:

Biologist's Name: Northeast Utilities Environmental Laboratory Company Name: Northeast Utilities Service Company and submit a copy of the 6 eld survey with your application.

4. is the she located within 1/4 mile of a well used for potable supply? O Yes XD No
1. Marimnm Daily Flow of the withdrawal and dinharge 1.R7>.non p l Number of hours per day of the withdrawal and discharge 24 (Max.)

Maximum Instantaneous Flow 1300 u,m f

l 1 Estimated duradon of the withdrawal and discharge activity. Provide an estimated begummg and ending date.

T - na4=+nly and until issuance of the Myr. Dermit renewal.

3. Groundwater et="*= tion of the site
4. Name of Receiving Water. POTW or Watershed for groundwater discharge Lono Is, land Sound -Niantic Bay Bureau of Water Management 3 of 6 Rev. o8/21/96

. JU.-17-1997 lit 42 DEP WATER PLS 860 424 4055 C).04/06 ,.

l Local Approvals na registrant ad a responalble of$clal from the POTW receiving the discharge must sign this approval. %1wre a local sewer commission acts Leiy of the POTW (i.e. facilldes that receive sewage from more than one town), bothw

. local sewer r=nmienion and POTW authority must sign tbc approval.

De below reforcoced facility is seeking Authority from the Departznent of Environ-ral Protection to dacharge wastewaar to the sanitary sewer for a permd of (circle) NA <30 days >30 days to one year >1 year Discharge volume will not exceed gallons per day. -

Average daily flow is antiipated at gallons per day.

Maximum instantaneous flow will be gallons per minute.

The discharge shall consist of:

Discharge Site:

She Address:

Signature of Registrant Da:e l

Name of Receiving POTW

l l Address of POTW:

l .

Approved by:

Signamre -Title Date Local Sewer Commission:

(if different that receiving POT %)

Address:

Approved by:

Signature -Title Data Comments!

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J1.A.-17-1997 .118 42 DEP IJATER PLS 860 424 4055 P.05/06

. Emerg:ncy cr Tcmperary Authcrizati:n Screenivrg Form g;g, name. W\3 nt $UC CA t- a w L!~ *l *h

' Addreset 7 O' boy' 5 b -

ones,mston supphed W DEP)

\l/otteM_8 CT di f FI~-o /d 2 n ,,ssenen me.

"I certify that I have personally examined and am famillar with the Information subtr.itted in this document, and I certify that bened on recater LD.

reasonable investigation, including my inquiry of those individuals responsible for obtaining the Information, the information is true, occurate and complete to the best of my knowledge and belief. I understand that a f also statement made in this information may be punishable as a criminal offense, in accordance with Section 22a 6 of the General Statutes, pursuant to Section 53a-157 of the General Statutes, and in accordance with any other opplicable statute."

K/ Dnkchf a v 6 wK U

' Date F Signhture

  • Tiue O I Monitoring results shall be recorded below and on the following peges se required in Sections 4 and 6 of this general permit. Parameters not required shall be marked *NA'.

Date Sampled: 2, 7 Discharge of 3 f eu n'c c U/8TtC P'" - 4I W y 5- "L- lRyf f.

Deifv Row St. 9 c/ol l4k Su]mi e,(

VOCs se detected by EPA Method soi ud4-b FY r Oh r+1 T n:HCt.A.-al o o / i ce bd o, # 6//3/ 77 Total VOCs (EPA Method 601 & 602) a 011 & Grease . Hydrocarbon praction MTBE Total Leed Arsenic Berium Bervilium Boron Cadmium Chromium (totel)

Chromium (heravalent)

Cobett Cooper Maanesium Mercury Nickel Selenium Silver Thettlum h

avre u of wet.r Menesernem 6 of e Rev. 08/21/96

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Total' Cyanide Amenable Cyanide Phenols (EPA Method 626)

Phthalate Esters (EPA Method 606)

Polvnuclear Aromatic Hydrocarbons (PAHal (EPA Method) .

Does Neutral /Aoid Extractables (SNAs)

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Endr6n eldehyde HentacNor Hootechler epoxide MethonvcNor ,

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Mmit with Authoritetion Apoken'en g og g ev,08/21/96 gyggeu et Water Management TDTR P.06

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4

-e Attachment H Field Survey Information A search of the Connecticut Department of Environmental Protection's (CTDEP) Natural Diversity Data Base maps and Bles has revealed no " endangered" or " threatened" species within ,

the Millstone Nuclear Power Station (MNPS) project boundary. However, two local species were classi5ed as being of"special concern": seabeach sandwort (Honkenya peploides) and -

osprey (Pandion haliaetus).

Seabeach sandwort is a low, fleshy leafed herb occasionally found above the strandline, or high-water berm above sandy beaches. As the major MNPS discharges are near rocky shores, impact associated with station. operation on this plant is, and is expected to remain, minimal.

The osprey is a large, migratory, fish eating hawk-like raptor that " summers"in southern New England, including the MNPS area. The osprey population throughout its range suffered enormously in the 1950s and 1960s because of the heavy use of pesticides, including DDT and dieldrin. The accumulation of pesticides caused thinning of the birds' eggshells and reproductive l

failure. Millstone Point has historically been a nesting site for osprey, and during the construction of Millstone Unit 1 in 1967, a platform was erected to support osprey nesting. In 1971, a pair of osprey established their nest on this platfonn and successfully produced three young. Since that time, Northeast Utilities has worked cooperatively with staff from CTDEP and U.S. Fish and Wildlife to establish over 20 osprey platforms in southeastem Connecticut._ The seven platforms located at the Millstone site have produced approximately 8% of Connecticut's fledglings since the program was instituted. Since the ban on use of DDT in 1972 and the efforts to restore the population, ospreys have made a dramatic comeback and are expected to be removed from Connecticut's list of species of"special concern" later this year. Under the -

conditions of the NPDES permit for MNPS, no impacts on osprey are expected.

Another important natural community identified in the waters near MNPS includes subtidal saltwater aquatic vegetation. Since 1985, eelgrass (Zostera marina) beds in the vicinity of Millstone Point have been monitored extensively as part of a much larger ecological monitoring program designed to assess the impacts of MNPS operations on the local marine environment.

The objectives of the eelgrass monitoring program are to identify temporal patterns of eelgrass distribution, abundance and reproduction, and to determine the extent to which changes in these panerns are the result of natural variability or MNPS operation. Results of this long tenn monitoring indicate that sampling sites nearest to MNPS (Jordan Cove and White Point) have supported stable populations since 1985.

After further consultation with staff from the Natural Diversity Data Base and review of the processes in the renewed NPDES permit for Millstone Station, no impacts to any of these species or communities are expected.

Also, as part of this submittal, attached hereto is the 1996 Annual Report: Monitoring the Marine Emironment of Long Island Sound at Millstone Nuclear Power Station, Waterford, Connecticut as prepared by the staff of Northeast Utilities Service Company, Environmental, Health & Safety

(- Services and the NU Environmental Laboratory.

l 1

J

STATE OF CONNECTICdT

, , DEPARTMENT OF ENVIRONMENTAL PROTECTION )

i I FRANKLIN WILDLIFE MANAGEMENT AREA 391 ROUTE 32 '

NORTH FRANKLIN, CT 06254 TELEPHONE:(860) 642 7239 .

January 24, 1997 Mr. Paul Jacobson l

Northeast Utilities Service Company P.O. Box 270 Hartford, CT 06141-0270 Re: Renewal of Existing Permit for Millstone Nuclear Power Station (Waterford, CT)

Dear Mr. Jacobson:

Your request for information has been forwarded to me by Dawn McKay of the Department of Environmental Protection's (DEP)

Natural Diversity Data Base. According to our rrNords, Ospreys (Pandion haliaetus) a state species of special concern, have been known to nest on the Millstone property.

L The Wildlife Division has not made an on-site inspection of the project area nor seen details of the work to be done.

Consultation with the Wildlife Division should not be substituted for on-site surveys required for environmental assessments.

If you have any questions or need additional information please contact me. Thank you for the opportunity to comment.

Sincerely, ,

y, --

Julie Victoria Wildlife Biologist cc: D. McKay - 7999

'w An Equal Opportunity Employer  ;

c 'I STATE OF CONNECTICUT' '

q[Ts E DEPARTMENT OF ENVIRONMENTAL PROTECTION Og I' "

>  % NATURAL RESOURCES CENTER

' ' T .-

79 Elm Street, Store Level l Hartford, CT 06106

~

) Natural Diversity Data Base Januuy 6,1997 Paul Jacobson Northeast Utilities Service Company P.O. Box 270 Hartford, CT cc,:,141- 0 2.'lC re: Renewal of Existing Permit for Millstone Nuclear Power Station (Waterford, CT)

Dear Mr.Jacobson:

I have reviewed Natural Diversity Data Base maps and files reguding the area delineated on the map you provided for the Millstone Nuclear Power Station in Waterford, Connecticut. I have attached a list of species and natural communities (with their state and federal status)that fall within your shaded boundaries. For more information regarding the wildlife species you should contact Julic Victoria (DEP Wildlife; 860 642 7239). For information on the fish you should contact Peter Aarrestad (DEP Marine Fisheries; 860-434-6043). For more information on plants or communities, please contact Nancy Murray (DEP Natural Resources Center; 860-424 3589).

Natural Diversity Data Base infonnation includes all information regarding critical biological resources available to us at the time of the request. This information is a compilation of data collected over the years by the Natural Resources Center's Geological and Natural History Surve: and cooperating units of DEP, private conservation groups and the scientific community. This information is not necessarily the result of comprehensive or site specific field -

investigations. Consultations with the Data Base should not be substitutes for on-site surveys required for environmental assessments. Current research projects and new contributors continue to identify additional populations of species and locations of habitats of concem, as well as, enhance existing data. Such new information is incorporated into the Data Base as it becomes available.

Please contact me if you have further questions at 424-3592. Thank you for consulting the Natural Diversity Data Base. Also be advised that this is a preliminary review and not a final determination. A more detailed review may be conducted as part of any subsequent environmental permit applications submitted to DEP for the proposed site.

Sincerely, h @ . N C. k L -

Dawn M. McKay Biologist / Environmental Analyst CC: Peter Aarrestad Julie Victoria Nancy Murray

( Printed on Recycled Paper )

79 Elm Street

  • Hartford, CT 06t06 5127 An Equal Opportumty Employer

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Part A:- G:nsral Dischargs Informati n (cantinu:d)

! Discharge Serial Number 001 C-5 Effluent Limitations and Conditions (continued) lib.- Are any of the effluent limitations applicable to the diacharge expressed in terms of production?

O Yes E No If yes, complete the following table. For existing discharge, list en actual measurement of your .

average or maximum level of daily production. For new discharges, list an average or maximum projected daily production. (Indicate in the table whether the production figures given are average or maximum level.) Express the production in the terms and units used in the applicable discharge limitation. Attach additional sheets if necessary.

Name of Category and Subpart Name and Quantity of Description of Process No. of Product per Day with Cycles Units of Measure throe:h Process Example:

Stalnless steel strips'are Iron and Steel Man'ufacturing; 27,000 lbs of. Stainless passed through solder flux .

  • 22 Hydrochloric Acid Pickling' steel' strips (average) baths'in~ #1 Tinner b

(. . . '

Bureau of Water Management DEP PERD APP.107 5 of 21 Rev. 03/CS/95

. Attachment 0: Discharge Inf:rrnati:n (c:ntinu:di Part B': Discharge Analysis All applicants must complete Part B, Tables 1 through 4 for each discharge. De sure to review the instruct /ons; specifically, ' Testing Requirements for All Discharge Categories *, Schedule A in the

('

instructions under Attachment O before completing this part. In add;t on, please note that for existing discharges previously licensed by DEP, Identify the substances that were monitored in the existing permit by placir.g 'PP" in the

  • Dally Composite or Grab Sample Results' column by the substance. For such substances, you need not repeat the analytical results in Tables 1 through 4, as long as such results are ,

provided in Aitachment E of the application.

Please inc1cate whether the discharge analysis was based on (check one):

O Projection G5 Actual wastewater O Wastewater from other similar discharge All applit ants must provide analysis results in column 1 for all the substances listed in Table 1 and other information needed to complete columns 2 end 3, for each discharge except the following: For discharges of non contact cooling water, heat pump wastewaters and blowdewn from heating and cooling equipment, provide analysis results for substances numbered in Table 1 as 3,5,6, and 11 through 16 only.

Table 1 Date Sampled M/7 m 7 Discharge Serial Number 001c.5_._ _

1 2 3 Daily Composite Number EPA

GENERAL or Grtib Sample' of Method Results Analyses

1. Biochemical Oxvoen Demand 15 Day) < 2.0 mg/L 1 405.1
2. Chemical Oxygen Demand 250.9 mg/L 1 410. 2 ,, _
3. Oil and Grease. Total' O.4 mg/L 6 413.1
4. Oil and Grease. Hydrocarbon Freetion'
5. Total Suspended Solids 11.1 mg/L 1 160.2
6. Ammor;a las Nitrogen) < 0.02 mg/L 1 350.1 l 7. Phosch,3rus (Total) 0.02 mg/L 1 365.4
8. Nitrate 0.08 mg/L 1 352.1
9. Nitrite < 0.01 mg/L 1 353.2
10. Total Kieldahl Nitrooen 0.15 mg/L 1 351.2
11. Total Residual Chlorine' O.tt to 0.17 mg/t. 6 l 12. Temper.iture (Winter and Summor)' 48 'F
13. pH (minimum and maximum)' 7.86 7.96 s.u.
14. Cooper, Total < 20 ug/L 1 200.7
15. Lead. Tstal < 5.0 vg/L 1 200.7
16. Zine. Total < 10 ug/L 1 200.7 ,,

' Check the instruct:0ns under this part *or the required method of sample Collection.

For surf ace w ster discharges only, check the instructions under this part for required EPA methods of analyses.

! Bureau of water Managemeht CEP.P[8tD. APP t07 6 of 2t Rev. 03/09/95 i

I .

Part B: Disch:rge Analysis (c:ntinu:d)

All applicants must complete Table 2 for each discharge by placing an *X* in either column 1,2, or 3. If column 1 or 2 is marked for any substance, you must provide analysis results in column 4 for that l/ '

tubstance and other information needed to complete columns 5 and 6 for that substance.

Table 2 K17 /07 Discharge Serial Numb _er. . oot c4 l Drte Sampled 1 2 3 4 5 6 Analysts Known or Believed Daily Number . EPA **

TOXIC METALS, flequired Suspected Absent Composite of Method CYANIDES, PHENOLS by Schedule Present or Grab Analyses A .see Sample Instructions Results' 4 l Antimony, Total X < 5.0 vo/L 1 200.7 l 1.

4

2. - Arsenic, Total X < 5.0 vo/L 1 200.7 Beryllium, Total X < 5.0 ug/L 1 200.7 l
3. i Cadmium, Total X < 3.0 vg/L 1 200.7
4.
  • Chromium. Total X 11 pg/L 1 200.7 5.
6. Chromium, Hexavalent' X Mercury, Total X < 0.5 vg/L 1 200.7 7.

X < 5.0 pg/L 1 200.7  ;

8. Nickel. Total Selenium, Total X < 5.0 pg/L 1 200.7 9.

X < 5.0 vo/L 1 200.7 .

JO, Silver, Total

11. Thallium, Total X 8.1 ug/L 1 200.7
12. Cyanide. Total' X
13. Cyanide, Aniendable' X
14. Phenols. Total
  • X F

N

  • Check the instructions under this part for the required method of sarN's collection.

For surf ace water dischstges only, check the instructions under this part for reau/ rect EPA rriethods of snalyses.

Bureau of Water Management Rev. 03/c8/95 DEP PERD APP 107 7 of 21

. . , , . - - . . . . . ~ . . , -~

P a'rt B: Discharge An: lysis (ctntinu:d)

Table 2 (continued)

Date Sampled -_ EI7/97 ._

Discharge Serial Number- 0010 5 {.-

1 2 3 4 5 6 -

Analysis Known or Believed Dolly Number EPA' Required Suspected Absent Composite of Method VOLATILESe by Schedule Present or Grab Analyses -

A .see Sample l Instructions Results'

1. Acrotein X < 25 vo/L 5 624 l 2. Acrylonitrife X < 10 vg/L 5 624

- 3. Benrene X < 2.0,gg/L 5 624

4. - Bromoform -

X 4.98 vo/L 5 624

5. Carbon Tetrachloride X < 2.0 vo/L 5 624-
6. Chlorobenzene - X < 2.0 vo/L 5 624
7. Chlorodibromomethane X < 2.0 ug/L 5 624
8. Chloroethane X < 5.0 vg/L 5 624 9, 2.Chloroethylvinyl Ether X < 10 ug/L 5 624
10. Chloroform X < 2.0 vg/L 5 624
11. Dichlorobromomethane X < 2.0 vg/L 5 624 i
12. 1,1.Dichloroethane X < 2.0 vg/L 5 624 13.1. 2 Dichloroethane X < 2.0 vg/L *5 624

~

14. 1.1.Dichloroethylene X < 2.0 vo/L 5 624 15.1. 2 Dichloropropane X < 2.0 ugg 5 624 16.1. 3 Dichloropropylene X < 2.0 g/L 5 624
17. Ethylbentene X < 2.0 vg/L 5 624
18. Methylbromide X < 5.0 vo/L 5 624
19. Methylchloride X < 5.0 vo/L 5 624
20. Methylene Chloride X 2.5 vg/L 5 624
21. 1.1. 2, 2.. Tetrachloroethane X < 2.0 vo/L 5 624
22. Tetrachloroethylene X < 2.0 ug/L 5 624
13. Toluene X < 2.0 vg/L 5 624 24.1. 2.Trans Dichloroethylene X < 2.0 ug/L 5 624 as
  • Check the ins; ructions under this part for the required rnethod of sample collection.
  • r r surf ace water discharges only, check the mstructions under this part for required [PA rnethods of analyses.

Bureau of Water Management DE P. PERO. APP.t 07 8 of 21 Rev. 03/08/5 5

. = = - -

Y%

P ort 5 : Disch:rge An: lysis (c:ntinued)

Table 2 (continued)

[*' Date Sampled E/7/97 Discharge Serial Number 001c.s 1 2 3 4 5 6 -

Analysis Known or Believed Dolly Number EPA

Required Suspected Absent Composite of Method VOLATILES

  • by Schedule Present or Grab Analyses -

A .see Sample Instructions Results' 25,1,1,1 Trichlotoothane X < 2.0 vg/L 5 624

26. 1,1, 2 Trichloroethane X < 2.0 vg/L 5 624 I 27. Trlehtoroethylene X < 2.0 /to/L 5 624
28. Vinyl Chloride . X < 5.0 vo/L 5 624 l OC/MS FRACTION ACID COMPOUNDS
1. 2 Chlorophenol X i

2, 2. 4 Dichlorophenot X

3. 2, 4.Dimethylphenol X
4. 4,6 Dinitro O.Cresol X
5. 2. 4. Dinitrophenol X
6. 2.Nitroohenot X
7. 4. Nitrophenol X ,
8. P.Choro.M.Cresol X

_9. Pentachlorophenot X

10. Phenol X
11. 2. 4, 6.Trichlorophenot X BASE NEUTRAL COMPOUNDS
1. Acenaphthene X _
2. Acenophthylene X
3. Anthracene X
4. Benridine X
5. Benrefalanthracene X
6. Ben?.ofaloyrene X
7. 3. 4. Benzo.fluoranthene X

. ~

  • Check the instrucbons under this part for the reavired method of sample conection.

For surf ace water discharges only, check the instructions under this part for reguked EPA methods of analyses.

Bureau of Water Management DEP-PERO. APP 107 9of21 Rev. 03/0s/95

' P rt 51 Dischargo Analysts (ctntinued)

R/7 /87 Table 2 (continued)

Discharge Serial Number 001Cf

(\ '-

Date Sampled 1 2 3 4 5 6 .

BASE NEUTRAL COMPOUNDS Analysts Known or Belleved Daily Number EPA

Required Suspected Absent Composite of Method by Schedule Present of Grab Analyses ,

A .see Sample instructions Results*

8. Bentofghl)perytene X
9. Benro(kifluoranthene X
10. Bis (2 Chloroethoxy) Methane X
11. Bis (2 Chloroethyll Ether X
12. Bis (2 Chloroisoproovl) Ether X
13. Bis (2. Ethylhexyl) Phthalate X
14. 4.Bromophenylphenyl Ether X
15. Butylbenzyl Phthalate X

- 16. - 2.Chloronsphthalene X 17, 4.Cholorophenylphenyl Ether X

18. Chrysene X
19. Dibenrola. H) anthracene X
20. 1. 2.Dichlorobenzene X 21.1. 3 Dichlorobenrene X 21.1. 4 Dichlorobenzene X
23. 3. 3 Dichlorobenridine X
24. Diethyl phthalate X
25. Dimethyl phthalate X
26. Ol n butyl phthalate X 27, 2. 4 Dinitrotoluene X
28. 2. 6 Dinitrotoluene X
29. Di n octyl phthalate X 30.1,2 Diphenythydrazine (as Arobenzenel X
31. Flucranthene X

' Check the instructions under this part for the reavited method of sample collection.

" For surface water discharges only, check the instructions under this part for required EPA methods of analyses.

Bureau of Water Management DEP. PERO APP 107 10 of 21 Rev 03/08/95 J

P;rt B: Dis:h rg] Analysis (c:ntinued) .

4 4

4 Date Sampled - R17/87 Table 2 (continued) )

Discharge Serial Number 001c t

  • 4 1 2 BASE NEUTRAL COMPOUNDS 3 4 Analysts 5 6 Known or Selleyed Dolly Mequired Number EPA * *'

Suspected Absent Composite of by Schedule Present Method A .see of Grab Analyses Sample Instructions Results *

32. Fluorene X
33. Hexachlorobenrene X
34. Hexachlorobutadiene X
35. . Hexachlorocyclopentadiene -

X

-36. Hexachloroethane X

37. Indenoli,2,3.edl Pyrene X
38. Isophotone l X
39. Naphthalene X
40. Nitrobenrene X
41. N.nitroso dimethylamine X

_42. N Nitrosodi n. Propylamine X

43. N Nitrosodiche tylamine X
44. Phenanthrene X

_45. Pyrene .

X

46. 1. 24.Trichlort benzene X

PESTICIDES

1. Aldrin X
2. Aloha BHC X
3. Beta BHC '

X

4. Gamma BHC X
5. Delta BHC X
6. Chlordane X
7. 4. 4 DDT X
8. 4.4 DDE X

' For surface water discharQes chly. check the instrygtions under this part tot e r eutred EPA methods of analyses.

Sureau of Water Management DEP PERD. APP 107 11 of 21 Rev. 03/08/96

. Port BI Disch:rge Analysis (centinued)

~

i All applicants must complete Table 3 for each discharge by placing an *X* In either column 1 or 2. If column 1 is marked for any substance, you must provide analysis results for that substance in column 3 and other information needed to complete columns 4 and 6 for that substance.

Table 3 Date Sampled _ Kt1181 Discharge Serial Number 001c.s ,

1 2 3 4 5 Known or - Belleved Daily Number EPA **

l OTHER SUBSTANCES Suspected Absent Composite of Method Pressnt or Grab Analyses Sample Results'

i. Bromide X
2. Color X < 6.0 1 110.2
3. Feest Collform' X- _ _ _
4. Fluoride X
6. Nitrogen, Total Organic X 0.13 mg/L 1 351.2 6.' Radioactivity X
a. Alpha, Total X t
b. Beta. Tota' X
c. Radium. Total X ,
d. Radium. 226 Total X
7. Sulfate X 39.82 mg/L _1 375.2
8. Sulfide
  • X < 0.01 mg/L 6 376.2
9. Sulfite X
10. Surfactants X O.01 mg/L 1 425.1
11. Aluminum. Total X 118 pg/L 1 200.7
12. Barium. Total X 84 pg/L 1 200.7
13. Boron. Total X 2230 pg/L 1 200.7
14. Cobalt. Total X < 10 pg/L 1 200.7
15. Iron.- Total X < 25 pg/L 1 200.7
16. Magnesium. Total X 032 mg/L 1 200.7

('v -

  • - Check the instru;tions under this part for the reavited method of semple collection.

. For surface water discharges only, check the instructions under this part for required EPA methods of analyses.

Buren s 91 Water Management DEPJHD APP.107 13 of 21 pov. 03/08/95

. . . + , - . . . . . . .....-.:.'.-...:.-

Pirt B: Disch rgo Analysis (c:ntinu:d)

Table 3 (continued)

Date Sampled _ 'U7/97 Discharge _ Serial Number _,QQ1Q.( {~*

1 2 3 4 5 .

Known or Believed Dally Number EPA" OTHER SUBSTANCES Suspected Absent Composite of Method Present or Grab Analyses .

Sample Results' _

17. Molybdenum. Total X < 25 vg/L 1 200.7
18. Manganese. Total X < 5 vg/L 1 200.7
19. Tin, Total X < 10 vg/L 1 200.7 1
20. Titanium, Total X < 10 gg/L 1 200.7 OTHER TOXIC AND l HAZARDOUS SUBSTANCES
1. Asbestos X
2. Acetaldehyde X
3. Allvi alcohol X
4. Ally! chloride X
5. Amyl acetate X
6. Aniline X
7. Benzonitrile X .
8. Benzyl chloride X
9. Butyl acetate X
10. Butylamine X
11. Caetan X
12. Carbarvi X
13. Carbofuran X
14. Carbon disulfide X
15. Chlorovrifos X
16. Coumachos X
17. Cret ol X
18. Crotonaldehyde X
19. Cyclohexane X __
  • Check the instructions under this part for the reovired method of sample co!!ection.

" For surface water discharges only, check the instructions under this part for required EPA methods of analyses.

1

( Bureau of Water Management DEP.PERD. APP.107 14 of 21 Rev. 03r08/95

Part 5: Disch:rge An: lysis (c:ntinued) t .. .

-l Table 3 (continued)

Date' Sampled R17187 Discharge Serial Number 001c.s ____

1 2 3 4 5 OTHER TOXIC AND Known or Believed Dally Number EPA

HAZARDOUS Suspected Absent Composite of Method SUBSTANCES Present or Grob Analyses -

Sample Results* _

20. 2,4.Dichlorophenoxy (seetic acid) X
21. Diarinon X
22. Dicamba X
23. Dichlobenil X
24. Dichtone X-25, 2,2 Dichloro, propionic acid X
26. Dichlorvos X
27. Diethyl amine X
28. Dimethyl amine X f
29. Dinitrobenzene X
30. Diount X ,
31. Olsulfoton X
32. Diuron - X
33. Epichlorohydrin X < 100 vo/L 5 624
34. Ethanolamine X __

< 10 mg/L 1,

35. Ethlon X- ,
36. Ethylene diamine ,

X

37. Ethylene dibromide X

' 30. Formaldehyde X

39. Furfural X
40. Guthlon X
41. Isoprene X=

\ .

  • Check the instructions undet this part for the required method of sample collection.
  • For surf ace watet discharges only, check the instructions undet this part for required EPA methods of analyses.

Sureau of Water Management DEP PERO. APP 107 t 5 of 21 Rev. 03/C8!95

- I

.. . .. .._... -- . ~ =

l P:rt BI Disch:rge An: lysis (c:ntinued) .

Table 3 (continued) ($

- Date Sampled arria r Discharee Serial Number 001c.5 (

1 2 3 4 5 .

OTHER TOXIC AND Known or Believed Dolly Number EPA

HAZARDDUS Suspected Absent Composite of Method SUBSTANCES Present or Grab Analyses .

Sample Results*

42. Isopropanolamine X
43. Keithano X l
44. Kepone X
45. Malathlon X
46. Mercaptodimethur X
47. - Methoxychle r -X-
48. Methyl merceptan X
49. Methyl methacrylate X
50. Methyl parathlon X
51. Mevinphos X
52. Mexacarbete X
53. Moneethyl amine X
54. Monomethyl amine X
55. Naled X
56. Naothenic acid X
57. Nitrotoluene X
58. Parathlon X _
59. Phenolsulfanate X
60. Phoscene X
61. Procarcite X
62. Propylene oxide X
63. Pyrethrins X 64 Quinoline : X
65. Resorcinot X

)

  • Check the instructions under this part for the required method of sarnple collection.
  • For surf ace water discharges only, check the instructions under this part for feevired EPA rnethods of analyses.

sureau of Water Management DEP PERO. APP.107 16 of 21. Rev. 03/08/95 J

l P5rt 8: Dischargo Analysis (continued) l l .

Table 3 (continued) 1- Date Sampled #11187 Discharge Serial Number 001 c.s

.1 2 3 4 5 OTHER TOXIC AND Known or Believed Dolly Number EPA

HAZADOUS Suspected - Absent Composite of Method SUBSTANCES Present or Grab Analyses .

Sample Results *

66. - Strontium X
67. Strychnine X
68. Styrene X < 2.0 vo/L 5 624-
69. 2, 4, 5 T (2, 4, 5 Trichlorophenoxy X acetic acid)
70. TDE (Tetrachloro-diphenviethane) X 71, 2, 4, 5 TPl2-(2, 4,5-Trichlorophenoxy) X propanoic acid)
72. Trichlorofan X
73. Triethylamine X
74. Trimethylamine X
75. Uranium X
76. Vanadium X
77. Vinyl acetate X
78. Xylene X < 2.0 vg/L 5 624
79. Xylenot X
80. Zirconium X
  • Check the instructions under this part for the reavited method of sample cettection.

For surf ace water discharges only, check the instructions under this part for required EPA methods of analyses.

Bureau of Water Management DEP PERD APP.107 17 of 2t Rev. 03/08/95

  • ==g, - e =44e

- Part B: Discharge An: lysis (c:ntinu:d)

All applicants must complete Table 4 for each discharge, by placing an *X* in either column 1 or 2 for the substances numbered 16. If column 1 is marked for any substance, you must provide analysis results for (' ,

that substance and any other information needed to complete columns 3 through 5 for that cubstance, Table 4 Date Sampled N7197 Discharge Serial Number 001C 5 1 2 3 4 5 Known or Delieved Dolly Composite Daily Number EPA

SUBSTANCES Suspected Absent or Grab Sample of Method Present Results' Analysis 1, 2,4,5 trichlorophenoxy acetic acid (2,4, S, T) X 2, 2 (2,4,5 trichlorophenoxy) propanoic acid (Silvex,2,4, X 5,.T P) 3, 2-(2, 4 .5 trichlorophenoxy) ethyl, 2, 2 X dichloropropionate (Erbon)

4. O,0 dimethyl O-(2,4, 5 trichlorophenyl) X phosphorothioate (Ronnell
5. 2,4, 5 trichlorophenol (TCP) X
6. hexachlorophene (HCP) X In addition, //:
1) your f acility uses or manufactures one of the substances listed above as items 16 or knows or has reason to believe or can reasonably ascertain that one of those substances may be present in the discharge; or
2) your facility has a discharge resulting from a process regulated under 40 CFR Part 430 Pulp, Paper, and Paperboard Point Source Category; or
3) you know or have reason to believe or can reasonably ascertain that 2,3,7,8 Tetrachlorodibento p-dioxin (TCDD) may be present in the discharge; you must also provide the analysis results for the dioxin and furan substances numbered 7 through 27, on ,

the following page, using " EPA Method 1613: Tetra through Octa. Chlorinated Dioxins and Furans by Isotope Dilution HRGC/HRMS".

' Check the instructions under this part for the required rnethod of sample collection.

G

For surf ace watet discharges only, check the anstructions under this part for required EPA methods of analyses.

Sureau of Water Management Rev, o3to8 /95 DEP PERO. APP 107 18 of 21 me e e e- 4 ee G m A

P$rt5: Disch:rge An: lysis (c:ntinued)

Table 4 (continued)

Date Sampled E/7/97 Discharge Serial Number 001c.s 1 2 3 l

Dally Composite Sample Number EPA

Results' SUBSTANCES of Method Analyses .

7. 2.3,7,8.TCDD (Tetrachlorodibento.p dioxin)
8. Total . TCDD
9. 2,3,7,8.TCDF (Tetrachlorodibentofurani
10. Total . TCDF 11,1,2,3,7,8.PeCDD (Pentschlorodibento p.

dioxin)

12. Total . PeCDD 13.1,2,3,7,8 PeCDF (Pentschlorodibentofuran)
14. 2,3,4,7.8 PeCDF
15. Total . PeCDF 16,1,2,3,4,7,8 HxCDD (Hexachlorodibento p-dioxin)
17. 1,2,3,6.7.8.H x C D D
18. 1.2.3,7.8,9.H xCDD
19. Total . HxCDD 20.1.2.3,6.7,8 HxCDF (Hexachlorodibentofurani

._2 h ._1.2.3.7,8.9 H x CDF _,

22. Total . HxCDF
23. 1,2,3,4,6,7,8.H pC D F (Heptachlorodibentofuran)
24. 1,2,3.4.7. 8,9.H oC D F
25. Total HoCDF
26. OCDD (Optachlorodibenro o-dioxin)
27. OCDF (Hexachlorodibenrofuran) ,

t e(* '

Check the instructions under this part for the reavired method of sample cottection.

  • For surface water discharges only, check the instructions under this part for requitect EPA methods of analyses.

Bureau of Water Management DEP PERD APP lo? 19 of 21 Rev. 03/o8/95 J

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