ML20209J021
| ML20209J021 | |
| Person / Time | |
|---|---|
| Site: | Peach Bottom  |
| Issue date: | 09/05/1986 |
| From: | Willsey W PECO ENERGY CO., (FORMERLY PHILADELPHIA ELECTRIC |
| To: | Corriveau E HARRISBURG, PA |
| References | |
| NUDOCS 8609160113 | |
| Download: ML20209J021 (9) | |
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PHILADELPHIA ELECTRIC COMPANY
, 2301 MARKET STREET f P.O BOX 8699 PHILADELPHI A. PA.19101 (215)841-4000 September 5, 1986 Mr. Edward Corriveau Chief, Permits and Grants ~Section Bureau of Water Quality Management Department of Environmental Resources One Ararate Boulevard Harrisburg, PA 17110 RE: Peach Bottom Generating Station NPDES Permit PA 0009733
Dear Mr. Corriveau:
In accordance with Chapter 92.7 " Reporting of New or Increased Discharges", of the Departments' Rules and Regulations, we hereby request permission to use Nalco 1360 (polymaric zinc, 5% by weight zinc, 15% by weight polyacrylate).
This Nalco product will be evaluated as a means to control corrosion in the Emergency Service Water System (ESWS) at Peach Bottom Generating Station. The flow through the ESWS is approximately 60 gpm noncontact cooling water during normal plant operations. Use of the Nalco 1360 is not expected to violate effluent limitations specified in the subject NPDES permit. ,
We intend to maintain a concentration 60 ppm as product in the ESWS. This results in a concentration of 3 ppm zinc and 9 ppm polyacrylate in the ESWS. Since the ESWS flow is a very small part of the total discharge point 001 flow, there should be very little, i f any, increase in concentrations of zine from discharge point 001.
The existing treatment program which uses polysilica (Nalco 2513) and polyacrylate (Nalco 1370) will be terminated upon approval and implementation of this new treatment program.
60 c,D- M 1 8609160113 860905 PDR ADOCK 05000277 8 110 P PDR i g
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- i j I Attached is a product bulletin and Material Safety Data
! Sheet for the Nalco product. Confidential information such as the chemical formula for this chemical product, has been sent to you directly from the Nalco Chemical Company.
If there are any questions or concerns, please call David W. Mobraaten at (215) 841-5679. i i'
s Sincerely yours, -
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b .W !
i W. B. Willsey Director Environmental Affairs i
! Attachment DWM:nas j cc: NRC Director, ONRR w/ att.
Washington, DC l NRC Administrator, OIE I King of Prussia, PA w/ att.
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i i Utility Product Chemicals Bulletin 9
SUPER ZINC ~ c g
mu.co 1360 CORROSION INHIBITOR 8
Product Benefits e Extends the lifetime of system o Minimizes acid usage; pH above components 8.0 is optimum e Minimizes maintenance of corroded components Principal USeS SUPER ZINC 1360 is designed to utility recirculating cooling water minimize corrosion of mild steel systems.
and copper components in electric General Description SUPER ZINC 13 0 is a liquid Form Clear, colorless liquid polymer zinc corrosion inhibitor. Odor Slight sulfurous Specific Gravity 1.20 pH (Neat) 3.7 Freeze Point 22 F Application SUPER ZINC 1360 should be led of your system, the water chemistry, directly from the drum or bulk and the severity of pioblems storage tank to a location in the encountered. Your Nalco Utility system where it will be uniformly Account Manager will recommend mixed and thoroughly distributed. Il the optimum dosage necessary to should be fed continuously to ensure maximum program cer-maintain optimum product activity. formance for your system.
The specific dosage of SUPER For specific feeding and material ZINC 1360 will vary depending compatibility instructions, consult upon the operating characteristics your Natco Utility Account Manager.
Handling and Storage SUPER ZINC 1360 is an acidic 15 minutes; for eyes, also get medi-solution and should be handled cal attention. Do not take internally, with caution to prevent contact with Keep out of reach of children.
skin, eyes, or clothing. In case of Recommended in-plant storage contact, immediately flush with ,
large amounts of water for at least Shipping SUPER ZlNC 1360 is available in The product is shipped from bulk or in 55-gallon, nonreturnable Chicago, lilinois.
lined steel drums. The net drum weight is approximately 550 pounds.
NALCO CHEMICAL COMPANY UTILITY CHEMICALS 1G01 WEST OtEHL AOAO O NAPE AVILLE. ILLINOts 6056G SUR9tDtAn'f S IN AnG(NTtN A AUSTA' A. BAAllL CH'* f COLOMBIA (CUADOA. FINLANO.
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- AFFILIATES IN AUSTRAttA CANADA ME utCO.StNGAPOHE EDUTH Af fitC A T AlWAN UNITE D RING 00M AND THE UNITE 0 ST ATES Registe'ed irademath5 of Nafco Chemmal Company Of 985 NalcoChem<alCompany
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. ! I MATERIAL SAFETY DATA SHEET PRODUCT SUPER-ZINC 1360 INHIBITOR N ALC O Emergency Telephone Number Medical (312) 920-1510 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: SUPER-ZINC 1360 INHIBITOR -
DESCRIPTION: An aqueous solution of zinc chloride and an acrylic polymer NFPA'704M RATING 2 HEAI.TH 1 FLAMMABII.ITY 0 REACTIVITY 0 OTHER 0= Insignificant l= Slight 2= Moderate 3=High 4= Extreme SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient (s) as hazardous under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard (s).
INGREDIENT (S) CAS # APPROX.%
Zinc chloride 7646-85-7 10-20 SECTION 3 PRECAUTIONARY LABEL INFORMATION a
Warning: Causes eye injury and skin irritation. Do not get in eyes.
Avoid contact with skin and clothing. Wear goggles or face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally.
Empty containers may contain residual product. Do not reuse container unless properly reconditioned.
SECTION 4 FIRST AID.INFORMATION EYES: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once.
SKIN: Immediately flush with water for at least 15 minutes.
For a large splash, flood body under a shower. Call a physician at once.
INGESTION: Do not induce vomiting. Give water. Call a physician.
NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be l used to control symptoms and clinical condition.
CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water.
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use PAGE 1 OF 6 l
NALCO CHEMICAL COMPANY ONE NALCO. CENTER e NAPERVILLE. ILLINQlS GO5GG-1024
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[' ,. . MATERIAL SAFETY DATA SHEET PRODUCT SUPER-ZINC 1360 INHIBITGR N ALC O Emergency Telephone Number Medical (312) 920-1510 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
SECTION 4 FIRST AID INFORMATION ( CONTINUED )
of gastric lavage. Measures against circulatory shock, respiratory '
depression and convulsions may be needed.
SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE (S) OF EXPOSURE: Eye, Skin EYE CONTACT: Can cause moderate irritation. Can cause acidic, type burns.
SKIN CONTACT: Can cause moderate irritation. Can cause acidic, type burns.
SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure.
AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions.
SECTION 6 TOXICOLOGY INFORMATION
(
ACUTE TOXICITY STUDIES: N:) toxicity studies have been conducted on this product.
SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear colorless FORM: Liquid ODOR: Slight DENSITY: 10 lbs/ gal.
SOLUBILITY IN WATER: Completely SPECIFIC GRAVITY: 1.24 0 60 Degrees F ASTM D-1298 pH (NEAT) = 3.5 ASTM E-70 FREEZE POINT: 22 Degrees F ASTM D-1177 BOILING POINT: Greater than 212 Degrees F 0 760 mm Hg ASTM D-86 FLASH POINT: None (PMCC) ASTM D-93 NOTE: These physical properties are typical values for this product.
SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Not applicable UNUSUAL FIRE AND EXPLOSION HAZARD: Treat like an acid fire.
PAGE 2 OF 6 NALCO CHEMICAL COMPANY ONE NALCO CENTEA e NAPERVILLE, ILLINOl9 605GG-1024
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.j MATERIAL SAFETY DATA SHEET PRODUCT SUPER-ZINC 1360 INHIBITOR N ALC O Emergency Telephone Number Medical (312) 9201510 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
SECTION 9 REACTIVITY INFORMATION -
INCOMPATIBILITY: Avoid alkaline materials (eg. ammonia and its -
solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanides, sulfides, hypochlorites, chlorites) which can generate heat with splattering or boiling and the release of toxic fumes.
THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, CO ,
NOx, sox, hcl may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment.
SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATQRY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements and selection).
For large spills, entry into large tanks, vessels or enclosed small g spaces'with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended.
VENTILATION: General ventilation is recommended.
. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is recommended if gross exposure is possible.
The availability of an eye wash fountain and safety shower is recommended.
l If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Discard contaminated shoes and leather items.
SECTION 11 SPILL AND DISPOSAL INFORMATION l
IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (312-920-1510)
SPILL CONTROL AND RECOVERY:
Small liquid spills: Contain with absorbent material, such as saw dust, clay, soil or any commercially available absorbent. Shovel PAGE 3 OF 6 NALCO CHEMICAL COMPANY ONE NALCO CENTEA e NAPERVILLE. ILLINOIS 60566-1024 A AE A 31 e.er31 -9500
,' , MATERIAL SAFETY DATA SHEET ,
PRODUCT SUPER.-ZINC 1360 INHIBITOR
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N ALC O Emergency Telephone Number Medical (312) 920-1510 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) ]
reclaimed liquid and absorbcnt into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. . I Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA )
in Section 14.
For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective I
equipment specified in Section 10.
DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D.
As a non-hazardous liquid waste, it should be solidified before disposal to a sanitary landfill. Can be deep-well injected in (.
accordance with local, state and federal regulations.
SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC DATA:
96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> static acute LC., to Rainbow Trout = 61 ppm 48 hcur static acute LC., to Rainbow Trout = 110 ppm 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> static acute LC , to Rainbow Trout = 230 ppm 95% Confidence Limit of 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> LC, = 43 - 79 ppm COMMENTS: Above study conducted with well-water at pH 8-8.5 hardess (as CACO 3 ) of 225-275 ppm and alkalinity (CACO3 ) of 325-375 ppm.
OTHER STUDIES: When conducted in reconstituted soft water pH 7-7.5, hardness (as Caco ) of 40-45 ppm and Caco, alkanlinity of 30-35 ppm the 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> LC,, for Rainbow trout was 5.2 ppm (3.9 - 7.0 95% L.C.)
24 and 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> LC,. were 32 and 25 ppm respectively.
If released into the environment, see CERCLA in Section 14.
SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/ HAZARD CODE - HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
ORM-E NA 9188 '
CONTAINS - ZINC CHLORIDE l PAGE 4 OF 6 NALCO CHEMICAL COMPANY ONE NALCO CENTER e NAPERVILLE. ILLINOlG 60568-102e3
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MATERIAL SAFETY DATA SHEET PRODUCT SUPER-ZINC 1360 INHIBITOR N ALC O Emergency Telephone Nu,nber Medical (312) 920-1510 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
SECTION 14 REGULATORY INFORMATION The following regulations apply to this product.
FEDERAL REGULATIONS:
OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below.
Zinc chlorido - Severe irritant Zinc chloride fume = TWA 1 mg/m8, STEL 2 mg/m2 ACGIH TLV CERCLA /SUPERFUND, 40 CFR 117, 302:
This product contains zinc chloride, a Reportable Quantity (RO) substance and if 50,000 pounds of product are released, it requires notification to the NATIONAL RES?ONSE CENTER, WASHINGTON, D. C.
(1-800-424-8802).
i TOXIC SUBSTANCES CONTROL ACT (TSCA):
. The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710).
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D:
If this product becomes a waste, it does not meet the criteria of a
- hazardous waste.
l FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311):
This product contains the following ingredient (s) covered by the Clean Water Act:
Zinc chloride - Section 307, 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112:
This product does not contain 2c.gredients covered by the Clean Air Act.
STATE REGULATIONS:
MICHIGAN CRITICAL MATERIALS:
This product contains the following substance identified on the Michigan Critical Materials Register:
Zine chloride PAGE 5 OF 6 NALCO CHEMICAL. COMPANY ONE NALCO CENTER e NAPERVILLE. ILLINOIS GO5GG-1024 AAEA 312-0 G 1 -9 500
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. .- MATERIAL SAFETY DATA SHEET ,
PRODUCT SUPER-ZINC 1360 INHIBITOR N ALC O - (,
Emergency Telephone Number Medical (312) 920-1510 (24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />)
SECTION 14 REGULATORY INFORMATION ( CONTINUED )
STATE RIGHT TO KNOW LAWS:
Regulated in those states using the TLV for zinc chloride as a criteria for listing.
SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information.
SECTION 17 BIBLIOGRAPHY SEE NALCO'S MSDS SECTION DESCRIPTION PREPARED BY: John J. Kasper, MSc., Toxicologist l DATE ISSUED: 11/19/85 l
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PAGE 6 OF 6 1 NALCO CHEMICAL COMPANY ONE NALCO CENTER
- NAPEAVfLLE. ILLINOIS 60566-1024 l t - I