ML20209F976

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Ack Receipt of Informing NRC of Steps Taken to Correct Violations Noted in Insp Rept 50-128/87-01.Requests Records Substantiating That Bromine Experiment Reviewed by Nuclear Science Ctr Before Bromine Irradiated in Reactor
ML20209F976
Person / Time
Site: 05000128
Issue date: 04/28/1987
From: Fisher W
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION IV)
To: Richardson H
TEXAS A&M UNIV., COLLEGE STATION, TX
References
NUDOCS 8704300438
Download: ML20209F976 (2)


See also: IR 05000128/1987001

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APR 281987

In Reply Refer To:

Docker: 50-128/87-01

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Texas A&M University

ATTN: Dr. Herbert H. Richardson, Director

Texas Engineering Experiment Station

College Station, Texas 77843

Gentlemen:

-Thank you for your letter of April 8,1987, in response to our letter and the

attached Notice of Violation dated March 11, 1987. Your response was also

discussed during a telephone conversation on April 10, 1987, between your

Dr. J. A. Reuscher and Mr. H. D. Chaney of this office. As a result of our

review, we find that additional information is needed. Specifically, we need

copies of your records that will substantiate your position that the bromine

experiment was reviewed by the Nuclear Science Center staff before the bromine

was irradiated in the reactor.

Please provide the information within 15 days of the date of this letter.

Sincerely,

MWB:

Y

WILLIAM L FISHER

William L. Fisher, Chief

Radiological and Safeguards Programs

Branch

cc:

F. E. Vandiver, President

Texas A&M University

College Station, Texas 77843

M. E. McLain

Radiation Safety Officer

Texas A&M University

College Station, Texas 77843

F. Jennings, Chairman

Reactor Safety Board

Texas A&M University

College Station, Texas 77843

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Texas State Department of Health

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Texas Bureau of Radiation Control

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Austin,-Texas 78756

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TEXAS ENGINEERING EXPERIM ENT STATION

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TEXAS A&M UNIVERSITY

COLLEGE STATION, TEXAS 77843-3575

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NUCLEAR SCIENCE CENTER

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Mr. Robert D. Martin

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Regional Administrator

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Region IV

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Dear Mr. Martin:

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Reference: Docket 50-128/87-01

The following is in response to the USNRC Region IV letter of 11 March 1987 re-

garding violations of NRC requirements identified by Mr. H. D. Chaney of your

office during an inspection of NSCR activities conducted on 12-14 January 1987.

1.

Failure to Evaluate Reactor Experiment

The management of the NSCR contends that the Bromo-Phenanthrene experiment of

18 December 1986 was properly reviewed and approved for irradiation under

Experiment Authorization E-1 "In-Pool Irradiations" (attached) with maximum

credit given to the design safety features of the long tube irradiation device

and the recognized relatively small total activity of 40 millicuries of e28r

gaseous activity (reference letter of 27 January 1987 from NSC Director to

USNRC Region IV).

In addition this experiment was reviewed in detail con-

cerning processing and packaging of the sample for delivery to the experi-

menter.

These detailed procedures are documented in NSCR Staff Meeting #374.

The development of procedures to prevent an accidental release during the

processing of the Bromo-Phenanthrene was of much greater concern than an

accidental gaseous release to the pool water during irradiation.

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RESEARCH AND DEVELOPMENT FOR MANKIND

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Contrary to the stated violation of Technical Specification 6.3.3(a), an

experiment of this type is evaluated against 3.6.3(b) which states:

"In calculations pursuant to 3.6.3(a), the following assumptions

shall be used":

(1)

If the effluent from an experimental facility exhausts through a

holdup tank which closes automatically on high radiation level, at

least 10% of the gaseous activity or aerosols produced will escape.

(2)

If the effluent from an experimental facility exhausts through a

filter installation designed for greater than 99% efficiency for

0.3-micron particles, at least 10% of these vapors can escape.

(3)

For materials whose boiling point is above 130 F and where vapors

formed by boiling this material can escape only through an un-

distributed column of water above the core, at least 10% of these

vapors can escape.

It is difficult to imagine that under the allowed conditions of 3.6.3(b) or

even a 100% release the resulting radiological consequences would be in excess

of the Design Basis Accident for the NSCR or for previously evaluated releases

of several curies of "3Ar.

It should also be noted that the W C values for

82Br are essentially the same as those for "3Ar as indicated in Appendix B of

10CFR20.

A recent evaluation of 82Br accidental releases indicate that a re-

lease to the reactor building of approximately 100 curies over a 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br /> period

would result in a 1 W C-Yr exposure to a radiation worker. For a release to

the site boundary from the exhaust stack, a 595 curie release over 1 hour1.157407e-5 days <br />2.777778e-4 hours <br />1.653439e-6 weeks <br />3.805e-7 months <br /> re-

sults in a 1 W C-Yr exposure. These values clearly demonstrate the orders of

magnitude difference in the 40 millicuries of a:Br gas when compared to

analyzed incidents.

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Immediate Corrective Action

Regarding the processing of Bromo-Phenanthrene in a toluene base and the con-

tamination incident of 12 December 1986, there is a suspension of this type of

experiment until new procedures are developed. Although the incident resulted

in contamination of personnel and the facility, the exposures were minimal

and releases did not approach reportable levels. USNRC Region IV and

the Texas State Department of Health were notified, however, and informed of

the events that followed the incident. A detailed report was issued to the

TAMU Radiological Safety Officer indicating a resulting whole body burden of

less than 1 mrem maximum among the four involved individuals.

The actions

taken by the NSC Senior Health Physicist with help from the TAMU Radiological

Safety Office were proper and highly comendable. The Chairman of the Reactor

Safety Board assigned Dr. Fred Sicilio of the TAMU Chemistry Department to

review the procedure for the handling of the toluene base Bromo-Phenanthrene

experiment. Several suggestions were made by Dr. Sicilio.

Future Corrective Action

New handling procedures will be developed for the processing of Bromo-

Phenanthrene incorporating Dr. Sicilio suggestions.

To improve the

review and approval of the irradiation samples that contain gaseous

activity, the NSC staff will consider an addition to SOP's which will

provide isotopic maximum curie content values of gaseous releases such

that when averaged over a year would not exceed the limits of Appendix

B of 10CFR20.

Compliance Date

The recent evaluation of a Br against Technical Specification 3.6.3 has been

performed and the results mentioned earlier in this report.

It was known in

advance that several curies of e2Br activity would be the resulting maximum

values.

Evaluations of experiments against 3.6.3 will continue to be made

using sample activity, encapsulation, and processing requirements as guide-

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lines to determine if detailed review is needed.

It is very important that

the policy of blanket approval of experiments be permitted not only for the

NSCR but for all research reactors.

It is not practical to provide detailed

evaluations for the thousands of samples irradiated in a single year of opera-

tion (face samples, rotisseries, pneumatic tube samples, etc.). This has

been the policy at the NSCR for over 25 years of safe operation with no re-

leases off-site of any consequence.

2.

Failure to Implement the Emergency Plan

Management agrees that the emergency support agreement letter with the St.

Joseph Hospital of Bryan, Texas had expired on 31 December 1986 and had not

been renewed at the time of inspection. Contrary to requirements of having

a signed agreement letter on file, the absence of such a document did not

result in the NSCR losing the support of St. Joseph Hospital which is really

of main concern.

The agreement letters and emergency training for support of

radiological events are obtained by the TAMU Radiological Safety Office and

the agreements cover University activities involving radioactive materials,

the AGN-201 reactor, the NSCR and the Cyclotron Institute.

Immediate Corrective Action

The Radiological Safety Office was notified of the expiration of the agree-

ment letter with St. Joseph Hospital and the RSO set out immediately to obtain

the agreement.

There was difficulty in getting a timely response from the

responsible St. Joseph administrator. This problem was explained in a memo-

randum from the RSO to the Director of the NSC.

The memorandum is attached.

Ironically while waiting on the hospital administrator to provide a signed

agreement, staff of the hospital were actively participating in the biennial

emergency exercise conducted on 4 March 1987.

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To circumvent the problem of obtaining signatures to agreements, it was

decided to negotiate an open renewal agreement to remain in force unless

terminated by either party to the agreement.

A request to change the NSCR

emergency plan to accommodate such agreements was denied by the USNRC

Standardization and Special Projects Directorate. However, two year

agreements are permitted and this change to the approved emergency plan will

be made and reported under 10CFR50.54(q).

Future Corrective Action

As stated in the RSO memorandum, future plans are to enter into agreement with

the new Humana Hospital in College Station, Texas as soon as possible. Future

agreement letters with the City of College Station for fire and emergency

medical support will be reviewed and renewed on a two year basis to coinside

with biennial emergency exercises.

Date of Compliance

An agreement letter with St. Joseph Hospital has been obtained which will

satisfy emergency hospital support requirements until an agreement is reached

with the new Humana hospital in College Station, Texas.

3.

Open Item: Potential Uncontrolled Drain Path From Radioactive Effluent Tank

The auxiliary liquid waste tank in question is normally empty and not on line

to the liquid radioactive waste sump pumps in the demineralizer room. There

is a small misunderstanding in Mr. Chaney's description for use of the tank.

Domestic water is sometimes stored in the tank to provide a supply for cooling

tower makeup or other uses rather than the stated use of reactor grade water.

The auxiliary tank is sometimes used to store reactor pool water if the stall

portion of the pool is drained.

The pool water is later returned to the pool

by way of the mixed bed demineralizer. Pool water is never used for cooling

tower makeup water.

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In reference to the installation of a drain valve to handle domestic water

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stored in the tank, its accidental failure would produce the same result as

failure of the tank sampling valve.

Both valves are located at the bottom

level of the tank. Thus installation of the special drain valve does not

present a hazard not previously reviewed in the SAR or SOP's.

The sample valves for the liquid waste tanks are not described in the SAR

but are in SDP VII, Figure VII-C-6.

Installation of the valve has been

reported under 10CFR50.59 in the 1986 NSC Annual Report issued March 1987.

Changes to S0P VII involving the drain valve on the auxiliary tank will be

made at the next Reactor Safety Board Meeting. Since the valve presents

no additional potential hazard, it will remain on the tank but its output

will be plugged to prevent an accidental draining of the tank if it is in

use.

4.

Open Item:

Radioactive Material Control

In reference to the control of radioactive materials within the reactor

building and the facility site boundary, a meeting of NSC and RS0

adninistrators was held shortly following the USNRC Region IV inspection.

The meeting was called to discuss licensing options that could be considered.

The chairman of the Reactor Safety Board was informed of the options and in

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turn suggested to the Licensee that the matter receive additional study.

At

present the NSC is waiting to receive requested licensing information from the

Texas State Department of Health. Hopefully this matter can be resolved with-

out undue burden on reactor operations or the Health Physics program at the

NSCR.

Respectively submitted,

Donald E. Feltz

Director

DEF/ym

Enclosure

cc:

H. H. Richardson, Director, Texas Eng. Experiment Station

F. Jennings, Chairman, Reactor Safety Board

M. E. McLain, Radiological Safety Office

K. L. Peddicord, Head, Nuclear Engineering Dept.

J. A. Reuscher, Director, Nuclear Research Reactor Programs

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TEXAS

A&M

UNIVERSITY

COLLEGE STATION, TEXAS 77843

officr of

March 25, 1987

RADIOLOGICAL SAFEn

(409)S45-1361

MEM0 RAN D UM

TO:

Mr. Don Feltz

Nuclear Science Center

Texas A&M University

THRU:

Dr. Milton

E.

McLain

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Director, Radiological Safety Office

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Texas A&M University

FROM:

Mr. John

E.

Simek

Radiological Safety Office

Texas A& M Universi ty

Request for signed letters of agreement from the

Associate Administration of St. Joseph Hospital, Bryan, Texas

have been submit ted-in a tim ely m anner each year.

The return of

such documents in a timely manner has not been an annual * event.

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As there is now under construction a new hospital in

College Station which will be closer and will also have a nuclear

medicine department , it is the intent of the Radiological Safety

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Office to request that the Reactor Safety Board petition Texas

A&H University to enter into an agreement of support with the new

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Humana Hospital, the opening date of which is scheduled for the

middle of April this year.

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All requirements of coordination and training would be

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as required under the existing agreement.

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The results of this proj ec ted change in support to an

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emergency shall be forwarded to Region IV upon completion of the

decision making process.

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All efforts short of bodily harm shall be continued to

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secure a copy of a signed letter of agreement from St. Joseph

Hospital.

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NSC

Form 111

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Rev 1/85

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EXPERIMENT AUTHORIZATION

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E.A. No.

IN-P0OL 1RRADIATIONS

TITLE:

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1.

STAFF REVIEW

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Date

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2.

REACTOR SAFETY BOARD REVIEW -- The hazards associated with this experiment

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have been reviewed by the Reactor Safety Board.

It is determined that this

experiment does not increase the probability of occurrence of an accident

previously analyzed in the Safety Analysis Report, and does not increase

the possibility that an accident or malfunction of a different type than

any evaluated previously will be created.

Approved:

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Chairman,RSB(/

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Date

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EXPERIMENT AUTHORIZATION

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Director, NSC

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Approval sheet format revised 1/85 - Original authorization was OcIob& 2N,1980

and approval sheets are on file.

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SATETY EVALUATION OF IN-POOL IRRADIATIONS

1.

Scope of Authorization

This authorization covers the irradiation of materials positioned

in .the NSCR pool within or near the reactor core for the production of

radioisotopes or exposure to radiation.

The production of any radioiso-

tope in the periodic table is authorized.

2.

Description

Typical experiments covered by this authorization involving the

irradiation of materials in the reactor pool using the NSCR as the radi-

ation source are as follows: face samples, rotated samples (rotisseries),

dry tubes, samples positioned in core reflector vacancies, samples

positioned in fuel vacancies, samples positioned in water spaces between

fuel elements, and samples positioned at selected distances from the

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reactor core to establish gamma and neutron radiation exposures. Most

samples require encapsulation in water tight containers.

Loading of

the experiment into the reactor is through the pool surface or in dry

tubes at the reactor bridge.

3.

Safety Discussion

Past experience has shown that samples may be safely irradiated in

many different types of encapsulating devices. The devices most commonly

used are metal tubes with Swagelok fittings, heat sealed polyethylene s

tubes, aluminum rotisserie containers with rubber o-ring seals, welded

containers, and aluminum cans. These have provided adequate sample

encapsulation to prevent contamination of the pool or work areas when

used in accordance with the conditions listed in section 4.

Other

sample containers have also been safely used, which again are in accor-

dance with the conditions listed in section 4.

The pressure produced

inside the encapsulation device is censidered in the design of all

containers.

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4.

Conditions, Limitations and Restrictions

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Samples will be encapsulated as necessary to prevent contamination

of the NSCR pool. Approved encapsulation devices include, but are not

limited to, those listed in section 3.

Any encapsulation device must

be reviewed and approved by the staff of the NSC.

Samples which will

not cause pool contamination may be irradiated without encapsulation,

an example of which would be non-corroding flux wire.

Samples will

be prepared and handled in accordance with S0P IV-A, IV-B, and IV-G.

The following technical specifications apply to this authorization:

1.9, 1.10, 3.6, 4.3.lb, 4.3.5, 6.la, 6.2d, 6.5, 6.6.

Sample loading

and unloading into the NSCR will be coordinated by operations personnel

to minimize any unexpected reactivity changes.

5.

Conclusions

The hazands associated with the production of radioisotopes and

radiation exposure experiments conducted in the NSCR pool have been

reviewed by the staff of the NSC and it was concluded that t,his

authorization does not constitute a change in the Technical Specifi-

cations, is not an unreviewed safety question, and will not increase

the probability of an accident previously analyzed in the Safety

7AnalysisReport.

It will not increase the possibility that .an accident

or malfunction of a different type than any evaluated previously will be

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created, and it will not reduce the margin of safety as defined in the

bases for any Technical Specification.

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