ML20206E727

Submits Original & Four Complete Copies of Application for Renewal of Permit to Discharge,Deposit or Dispose of Wastes Into or Adjacent to Water in State. with Three Oversize Drawings

ML20206E727
Person / Time
Site:	Comanche Peak
Issue date:	04/29/1999
From:	Kelley J TEXAS UTILITIES ELECTRIC CO. (TU ELECTRIC)
To:	TEXAS, STATE OF
References
TXX-99108, NUDOCS 9905050215
Download: ML20206E727 (150)

Text

p -

];

4 g

1UELECTRIC .

i.

l- File No. 222 TXX 99108

l. JannenJ. Kenny,Jr.

Ykw President April 29,1999 Executive Director I- Texas Natural Resource Conservation Commission P.O. Box I3087 Austin, Texas 787113087 ,

I

' Attention: Water Quality Division

Wastewater Permits Section/ Applications Team (MC 148)

Comanche Peak Steam Electric Station USNRC Docket Nos. 50-445 and 50-446 i TNRCC-TPDES Permit No. 01854 )

Application for Pennit Renewal l 1

Dear Sir / Madam:

I

! As a result of the United States Environmental Protection Agency's (USEPA) delegation of the National Pollutant Discharge

j. Elimination System (NPDES) to Texas Natural Resource Conservation Comnussion (TNRCC) and in accordance with the rules and

! ~~ regulations of both agencies, Texas Utilities Electric Company (TU Electric) hereby submits one original and four complete copies

! of an " Application for Renewal of Permit to Discharge, Deposit or Dispose of Waste (s) Into or Adjacent to Water in the State",

consisting of the " Administrative Report for Permit Application (Revised 10/98) and the " Technical Report For Industrial Wastewater Discharge Permits"(Revised 12/98). A check for the required renewal fee of $2,015.00 has been mailed to the TNRCC Revenues Section (see Attachment 4). This submittal represents the Company's formal application for permit renewal.

l In wh with Appendix B of the Operating Licence for Comanche Peak S.E.S. Units I and 2, a copy of this application is being l provided to the Nuclear Regulatory Commission (NRC).

^ Although this application is necessary because of the pending expiration of the facility's EPA NPDES Permit No. TX0065854 on

/

'[ l l October 31,1999, all outfall designations and technica' information supplied in the enclosed application are based on the current TNRCC Wastewater Discharge Permit No. 01854.- 1 The Company's proposed changes to the existing permit are listed in Attachment i of the application.

( The Company believes this application is a complete and reasonable reflection of the current plans for operation of the facility. TU l Electric is confident of your carefbl consideration. If there are any questions, please contact Scott Wilde at 214/812-5221.

l Sincerely ours,  ;

lt James J. Kelley, Jr.

SKW -

Attachment -

..~gn\n l 9905050215 990429 PDR ADOCK 050004454 p PDR2

[# I k C( MANCHE PEAK STEAM ELECTRIC STATION P.O. Box 1002 - Gen Rose, Texas 76043-1002 L

e . 1

- bec: Randy Morrison (Retain this application for a period of 3 years from the date of the cover letter) l Bruce Turner (w/o Attachments)

Mr. D. H. Jaffe, NRR (w/o Attachments) -

U. S. Nuclear Regulatory Commission, Attn: Document Control Desk T. A. O'Shea (include Facility map, USGS map w/ site only, General Description, and Water Use Diagram)

Gary Spicer (include Facility map, USGS map w/ site only, General Description, and Water Use Diagram)

' Gail Jespersen (w/o Attachments)

File: Comanche Peak S.E.S., TNRCC-TPDES Permit - CORRESPONDENCE 1

• 4 a

L- j

\

' Texas Utilities Electric Company j Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854 April 29,1999

,;.. l t

I 1

l

+

EXECITTIVE DIRECTOR j

TEXAS NATURAL RESOURCE CONSERVATION FOR COMMISSION USE ONLY Admin Review Staff ATTN: Water Quality Division '

Wastewater Permits Section (MC 148) ^#P " " " I'* ****iE" " '

Applications Team Admin complete cate P.O. Box 13087 county Austin, Texas 78711-3087 Region (512) 239-4433 Segment (512) 239-4430 or 239-4888 FAX j Expiration Date Proposed / Current Permit APPLICATION FOR PERMIT TO DISCHARGE, DEPOSIT OR DISPOSE OF WASTE (S) INTO OR ADJACENT TO WATER IN THE STATE For a Texas Pollution Discharae Elimination Svstam (TPDES) Permitt The owner of the facility must apply for the permit. The operator is required to apply with owner when i the operator is the entity responsible for the overall operation of the facility.

(Please see the application instructions regarding Who Applies for a Permit".)  ;

1 For a Texas Land Aeolication Permit (TLAP) The owner of the facility must apply for the permit.  !

gor both, Texas Pollution ~ Discharoe Elimination System (TPDES) and Texas Land Aoulication Permit (TLAP): The owner of the land where the facility is to be or is j located may be required to be a co-permittee. if the facility is considered a fixture i of the land (see instructions for definition), the owner of the land is considered part owner of the facility, and would need to apply as co-permittee. Alternatively, the facility owner may obtain a deed recorded easement from the landowner which will l give sufficient property rights. j

1. Applicant General Informations

a. Facility Owner: Texas Utilities Electric Comoany

• corporation or Other Legal Entity

• • Individual

• Corporation or Other Legal Entity: If the application is submitted on behalf of a corporation, identify the charter number or certificate of authority registration number on file with the Texas Secretary of State.

Identify the Tax Identification Number as recorded with the State Comptroller of Texas.

622780 75-1837355 ,

Charter Number (on file with the Tax Identification Number (on file with the Texas Secretary of state) State comptroller) or Social Security Number If the application is submitted on behalf of an entity other than an i individual and is not registered or chartered with the Texas Secretary of State, include a copy of the agreement which forms the entity.

REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 1 1

j

i L ** Individuals Pursuant to the Texas water code 26.027(b), please Supply f the following information when the applicant is an individual l Applicant (s): Not Anolicable (Full Legal Name)

Business:

(Assumed Business or Professional name - Chapter 36, Business & Commerce Code)

Physical Address of Individual:

(Street Address of Place of residence) l City: State: Zip:

Sext State Identification No.: Date of Birth:

(Driver's License or Personal ID Certificate)

b. Facility Operator: Texas Utilities Electric ComDany (Required if applying for a TPDES Permit)

• Corporation or other Legal Entity

• • Individual

• Corporation or Other Legal Entity: If the application is submitted on behalf of a corporation, identify the charter number or certificate of authority registration number on file with the Texas Secretary of State.

Identify ~ the Tax Identification Number as recorded with the State Comptrolle.r of Texas.

I 622','90 75-1837355 I Charter Number (cu file with the Tax Identification Number (on file with the Texas Secretary of state) State Comptroller) or Social Security Number )

i If the application is submitted on behalf of an entity other than an

{

individual and is not registered or chartered with the Texas Secretary j of State, include a copy of the agreement which forms the entity. j

• • Individual: Pursuant to the Texas Water Code 26.027(b), please I supply the following information when the applicant is an individual: l l

Applicant (s) : Not Anelicable i (Full Legal Name)

Business: l (Assumed Business or Professional name - Chapter 36, Business & Commerce Code) j Physical Address of Individual: )

(Street Address of Place of residence) l i

City: State: Zip:

( Sex: State Identification No.: Date of Birth:

(Driver's License or Personal ID Certificate) )

i REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 2 I

i

3... .

s

c. Address to.be used on the permit and.for receiving correspondence from the TNRCC:

Texas' Utilities-Electric Company Address: c/o Timothy A. O'Shea. Environmental Services Rnarav Plaza. 1601 Brvan Street City: Dallas State: Taran Zips 75201-3411 i

.d.  : Identify the person (s) to be contacted for-administrative and technical '

questions; during processing of . the application. Include - ~ the name, address,, - f acsimile , number, phone number, -title, firm name, where l applicable. The ? person (s) . _ identified will be the contact (s) for the pemitting ' staff if additional.'information is needed during the process.

If the address is the same as item 1 of the application, please indicate s'ame as item 1".

N===t Timnthv'A.~ O ' Stham . ' Ph . D . ~Titler Water Permit Coordinator

-Addream! Samm as Item 1.c Fax Numherr (214) 812-5695 Phana Numherr (214) 812-8413 J

e. Identify the individual to be contacted to publish notice in a newspaper of general circulation in the county .where - the facility is -(to be)-

located. on1v'identifv an= normon to be contacted. This person'will be notified.Lby 'the office of ' Chief Clerk to, publish . notice of Application / Draft Permit.-Note: This will occur after the draft permit has been mailed to the contact person identified above, for. review and comment of the draft permit (after technical review is completed). If the address is the same as. item 1 of the application, please indicate "same as item 1".

s=== as item 1.d.

s

. REVISED 10/98' ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 3 L.

E

f. O,he annlicant(s) identified in item 1 is an entity other than an individual, please provide the name of two individuals of both, the I owner and operator, that can be contacted by the agency as needed throughout the term of the permit. Include their phone number and j address If different than the permanent address to be used for the i permit, in item 1 of the application. (i.e., President or Vice President of a Corporation, Utility District, an Elected Official of a City or County, a General Partner of a Partnership, etc.) If the address is the i same as item 1 of the application, please indicate same as item 1", )l Owner: Timothy A. O'Shea. Ph.D. Water Permit Coordinator, address & I chone same as Item 1.c.

J Gary L. Snicer. Water Quality Coordinator. (214)812-8699. address same as Item 1.c Sama as owner \

Operator: w

.g. List'each person employed by the State of Texas who renresented vour e-==v and was naid for services regarding this application. NOTE: Any violation of '382.0591 of the Health and Safety Code, *26.0283 of the Water Code, or

• 572.054 of the Government Code, relating to conflict of interest, may result in denial l of the application or filing of charges with the appropriate office, j Not Annlicable

2. 'Petrmit Information

a. State Permit Number.(if existing): 01854

~ Expiration-Date of Existing Permit: July 2, 2000

b. NPDES Per1 nit No.: TX0065854

~ NPDES' Permit Expiration Date: October 31. 1999

-REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION. PAGE 4 t- _ l

\

NOTE APPLICANT MUST HAVE BOTH NON-RYDIRED NPDES AND STATE PERMIT. OR l- TPDES PERMIT TO APPLY FOR A RENEWAL.

i i L c. Type of Permit for Which Application is Submitted (check one):

[] New TPDES Permit (Original, Unpermitted)

{] New Texas Land Application Permit (Original, Unpermitted)

[] Major Amendment (Renewing the permit term)

[] Major Amendment (without renewal)

(Retain current expiration date. Application requirements are limited to those items that relate to  ;

the proposed modification.) J (x) Renewal l

[] Minor Amendment 1

(Retain current expiration date. Application requirements are {

limited to those items that relate to the proposed modification. '

See application instructions to determine if proposed changes can be made through a minor amendment.)

d. Type of Technical Report (s) Attached to Administrative Report for Permit Application. (Please note that a Technical Report is considered part of the application for permit):

[] Domestic Wastewater Application Technical Report

[x] Industrial Wastewater Application Technical Report l

[] Sewage Sludge Technical Report 1

e. If the application is for a major or minor amendment, briefly list the l proposed changes requested in the amendment. A major amendment includes i but is not limited to any change that makes a monitoring requirement l less stringent, removal of a monitoring requirement, increase in a flow limit, relocating an outfall, increasing acreage or adding authorization i for effluent-irrigation site, increasing acreage or adding authorization l for sewage sludge beneficial use or sludge disposal site, changing disinfection method from chlorination to ultraviolet system, etc. Note:

Permits are site specific. If applying for a permit at a different site than currently permitted, an application for a new permit must be submitted.

See Attachment it Procosed chances To Permit No. 01854 REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICA'[ ION PAGE 5 L d

f. For any application involving an average daily discharge of ' five (5)million gallons or more, provide the name of each county or counties -

located within 100 statute miles downstream of the point (s) of 9 discharge. (30 TAC Subsection 305.93 (c))

Somervell. Johnson. Bosoue. McLennan. Falls and Hill Counties

3. Facility / Plant Site Information-

a. Plant Name, if applicable Comanche Peak Steam Electric Station

b. Physical Street Address of the facility / plant, if available:

Not Aeolicable

c. Facility Location Latitude: Deg. 32 Min. 17 Sec. 54 Longitude: Deg. 97 Min. 47 Sec. 06

d. Facility / Plant Location

Description:

(1) For an existing permitted facility:

i Is the location as described on page one of the existing permit correct? [x] Yes [ ] No If No, provide a more accurate description in item b., below.

if the location is a different site than currently permitted, an application for a new permit must be submitted. Permits are

. site specific.

(2) For a new permit:

Give a written location description (not directions) of the facility (plant) with respect to known or easily identifiable landmarks which can be found on a USGS Topographic map, indicating the miles or feet from major intersections. The description must be detailed enough for the facility to be located on the USGS topographic map submitted with the application.

. Not Aeolicable i

I t

- REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 6

r:

l

e. County (s) where Facility iL/is to be Located: Some rvell If the waste disposal activity is located in Bexar, Comal, Hays, Kinney,

'Medina, Travis, Uvalde or Williamson County, is the waste disposal .

activity subject to 30 TAC Chapter 213, entitled Edwards Aquifer Rules?

I

() Yes ()No Not Applicable If YES, the applicant may be required to submit additional information concerning methods of aquifer protection, i

f. Identify the name of the nearest city where the proposed / existing l facility is be located:

Glen Rose

g. For Domestic Facilities, identify type of service provided by this fucAlity: Not Applicable

?ublic Private Both Public and Private 1

h. Is Facility located on Indian Land? ()Yes [x] No

4. Effluent Disposal Site Location Description Give a written location description (not directions) of the effluent disposal i site, if significantly different from the facility site, with respect to known or easily identifiable landmarks which can be found on a USGS Topographic map, indicating the distance . from major intersections. If,the location is not significantly different.from the facility site, indicate "same as facility sit. isseription".

sama as facility alte location REVISED:10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 7

. . _ _ -l  ;

l

5. Facility / Plant Ownership Information (If the . following items are . not properly answered, the application may be returned or there may be a significant delay in processing.):

a. Ownership of treatment facility / plant

• Texas Utilities Electric Comnany (Individual, corporation or other Legal ntity)

Address, if different.from Question 1: 'Sama as Question 1

• The owner'of the treatment facility must be identified as the applicant in item 1,of the application. The owner of the treatment facility is required to hold the permit. (see application instructions.)

l

b. Ownership of land where treatment facility / plant is or will be I

)

located ** Texas Utilities Electric Comnany I (Individual, corporation or Other Legal Entity)

Address, if different from Question 1: 92== as Question 1 l

• • If the owner of the land where.the facility is located is different than the owner of the facility, and the facility is considered a fixture of the land - (i.e. . pond system, . evaporation pond, units. half-way in ground, holding' ponds) the applicant must provide a copy of executed deed recorded easements giving the. facility owner sufficient rights to

-the land or apply as a co- permittee. (see application instructions.)

If.the facility is not considered a fixture of the land, a long term lease for the life of the facility must be provided.

Application for new facilities: If the land is to be acquired by the facility owner, a copy of an executed option to purchase agreement must be provided. The agreement must include a statement that the facility-will- not be constructed until the owner of the facility obtains ownership of the land.

)

c. Ownership of effluent' disposal area for land application system: *** _ l Not Annlicable (Individual, Corporation or other Legal Entity)

. Address,.' if different from Question 1:

I I

• • • If-the owner of the effluent disposal site is not the same as the )

applicanti provide a copy of a long tem lease for the use of the land.

I

-If the lease agreement is less than a five year term, the permit may be given a ' tem equivalent to the tem of the lease.

-REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 8

U'

.6. Discharge information-

a. For a currently permitted discharge into a watercourse:

l Are the point of discharge and discharge route description the same as  !

described on page one of the current permit.  !

. [x} Yes [ ] No If.no, provide a more accurate description in item b., below. If the point of discharge has changed or a new outfall is proposed, an application for a major amendment must be submitted,

b. For a proposed discharge into a watercourse:

Provide a written descriptior. that traces the flow of effluent from the plant site to the nearest major watercourse. '(For example: "From the plant site through a six-inch pipe to a county drainage ditch, to an unnamed tributary to Doe Creek, to Doe Creek, then to the Bravos River.")

. Not Anolicable l

l I

c. Is treated wastewater to be discharged to a city, county, or state highway right-of-way, or flood control district drainage ditch?'

(]Yes [x] No If.YES, the applicant must inform the responsible entity of the proposed discharge plans and seek their approval for the discharge. The anolicant must orovide with this anolication oroof of contact and cooles of an acoroval letter from such entity.

7. Land Disposal Infomation (not discharged directly into surface water)

a. Provide a written description that traces the flow of effluent to final disposition including transportation and temporary storage (e.g., holding ponds). For example: "From the plant through a six-inch pipe to a holding pond then through a pipe to the irrigation site." ,

Not Anolicable REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 9

rs ,

b.  : Identify the nearest, identifiable watercourse to the disposal site to i; ,

which rainfall, runoff might flow if.not contained.

~

l Not Anolicable G

8. l site Maps

~

l

, -a'.

' Attach a COMPLETE ORIGINAL (colored) ..USGS TOPOGRAPHIC Quadrangle MAP (S)

..(7 % minute scale) (copies are not acceptable). You may obtain original USGS topographic maps by ' calling 1- (800) 435-7627 On the original map,.

clearly show and label;the following information, as it applies:

See Attachment 2 USGS Site Maps (1) Clearly. label and delineates (a) The applicant's property boundaries (b). The boundaries of the wastewater treatment, sewage sludge processing and/or composting facility (plant), within the applicant's p:operty boundaries.

(2) Show an area at least one (1) mile in all directions of the

facility and-all; disposal activities. Adjacent quadrangle maps must be provided, if necessary, to show a one mile radius of the -

facility and all disposal activities.

l (3)- .(a) Clearly label and identify the point (s) of discharge, by  ;

Outfall number, '

(b) Trace the discharge route with a- highlighter f rom' the

. point (s) of discharge for a distance of three (3) stream miles or. to the . point- that .theD effluent' reaches a classified segment'li'sted in-30 TAC, Chapter 307, Appendix A. (Note Do not mark;with dark ink over the. discharge route. A~new original uap will.be required if the discharge route is not visible.)

t H (4) Clearly label and delineate the boundaries of effluent

. surface / subsurface. land disposal' site (s),

' storage / holding / evaporation ponds, and/or'the irrigation disposal area, within the applicant's approximate property

-bcundaries.

= (5)E Clearly label and delineate the boundaries of the sewage sludge disposal and/or land application sites, identify the location

~ of the disposal / land application area,. showing the applicant's approximate property boundaries, buffer zones, and existing U ~ drainage patterns.

l. .

(6): . . Indicate the proximityf of the plant site, discharge point (s) .

L (1 and/or'. disposal site (s).to any new or future commercial developnents, housing developments,' industrial sites, parks,

' L schools .and recreational areas.

?  ; REVISED 10/98; ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 10

l. >

l A

k_ _

(7) Clearly label all springs, public water supply wells, surface water. supply . intakes, water treatment plants, potable water storage facilities and sewage treatment plants within one mile of i the treatment facility.

(8) If the discharge route (s) abuts or crosses property which is being utilized as a park, playground or school yard and is within one mile of the point of discharge, highlight the area on the original i USGS topographic map. List each park, playground or schoolyard within one mile of the discharge.

THE FOLLOWING ITEM 8.b.'IS ONLY REOUTawn FOR NEW PanuTT APPLICATIONS AND MAJOR twwunwouT PumMTT APPLICATIONS. (The item is not anolicable for Renewal or Minor Amendment pared t annlications.) Not Applicable

b. . Landowners Property Boundary Map and Information. Please refer to the j application instructions for examples. The application processing will l be significantly delayed if the information is not provided exactly as requested. l (1) Provide a map or drawing, with scale, which includes the following  ;

information:

(a) Applicant's property where the facility / plant is located:

(1) Clearly delineate and label the applicant's property ,

boundaries.

(2) Clearly show and label the location of the wastewater treatment facility / plant. within the applicant's property boundaries. '

)

(3)- Clearly delineate the approximate property boundaries

'of the landowners surrounding the applicant's property boundaries.

(4) For domestic wastewater treatment plants, the map must also show the distance of the buffer zone into adjacent property and the approximate property boundaries of the landowners affected by the buffer zone.

REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 11

rn I

l-L.

L (b). For discharge into a water body:

.(1)  : Clearly identify and label the location of the i

point (s) of discharge.

(2) Highlight and . trace the discharge . route (s) for one

! mile downstream from the point of discharge. 4 (3) Clearly delineate the property boundaries of the' landowner's adjacent to the discharge route for one

~ mile downstream-from the point of discharge. Or,'if

~the point of discharge is into a lake, bay estuary or area ef fected -' by tidal, . delineate the approximate property boundaries of the landowners 'A mile in all directions of the outfall(s), along the watercourse. j i

(c) For land disposal of effluent:

(1) Clearly delineate the boundaries of the irrigation j site within the applicant's property boundaries.

(2)' Clearly delineate the property boundaries of the landowners surrounding the applicant's property boundaries where the irrigation site is proposed.

.(3) Clearly ' label' the location of' holding / evaporation pond (s) within the applicant's property boundaries.

(d) For sewage sludge land application / disposal / incineration

- ( 1) .- Clearly' delineate the boundaries of the beneficial use= land application site, sludge . disposal site and/or incineration.' site 'within the applicant's property boundatlee.

(2) Clearly ' delineate . the property boundaries of the landowners surrounding the applicant's property boundaries-where the beneficial use land application site-and/or incineration site is located.

(3)- Clearly delineate the. property boundaries - of the landowners within'1/2 mile in all directions from the applicant's property boundaries where the sewage sludge disposal site is' located, o

c.u . . REVISED 10/98. ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 12 F ,

(2) Corresponding list of landowners identified on the above requested map showing adjacent landowners. .

(a) Provide a separate list of the adjacent and surrounding >

1andowners required to be shown on the landowners map

'above. The list must include the name and complete mailing

' address of each landowner; and, the list must correspond with the map in a numeric order beginning with number one (1) . A list corresponding by lot and/or tract numbers will not be accepted. Any map and list that is not easily cross referenced and the landowners are not easily identifiable, will be returned for the applicant to revise accordingly.

(b) Provide the._ adjacent landowner mailing list on computer disk. If more convenient, printed labels of the list may be provided in lieu of a computer disk. This means that before your permit application can be declared administratively complete, a complete list of the adjacent landowners identified in the application must be provided on a 3 1/2

~ inch diskette using software compatible with Wordperfect.

Or if the list is provided in the form of printed labels, four' sets of_ labels are required.

Please carefully read the following- instructions for providing the disk or labels as the application will not be declared administratively complete if the information is not provided exactly as requested.

Instructions for DISK and LABELS:

If the names are oubmitted on computer disk, please label the disk with the applicant's name and permit number. on the disk itself, type the permit number and applicant's name on the top line before typing the addresses. Names and addresses must be typed in the format indicated below. This format is-required by the U.S. Postal Service for machine readability. Each letter in the name and address must be capitalized, contain no punctuation, and the appropriate two-character abbreviation must be used for the state. Each entity listed must be blocked and spaced consecutively as shown below.

Example:

Permit No. XXXXX-XXX, Texas Chemical Plant l

l TERRY M JENKINS l RR 1 BOX 34 WACO TX 76724 _

MR AND MRS EDWARD PEABODY 1 1405 MONTAGUE LN WACO TX 76710-1234 REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 13 L l

k:

A list submitted on computer disk should be the only item on that disk. Please do not submit the list on a disk that l" includes maps or other materials submitted with your j application.

If you wish to provide the list on printed labels, please use sheets of labels that have 30 labels to a page. Please provide four complete sets of labels of the landowner list.

l Each name and corresponding address must appear only once f .on the mailing labels or disk even if.the entity owns more #

than one parcel of land identified on the landowners map.

Please eliminate duplicate names and addresses. Names'and addresses should appear in the same order as the list cross l

referencing the landowner with their property on the landowners map.

c. ' The names and mailing addresses of persons identified as potentially affected persons were obtained from:

(Source s city, County, School or Water District Records, Abstract Co.,etc.)

(3) If the adjacent property ownership list shows the State of Texas to be an adjacent landowner, your application may affect lands dedicated to the permanent school fund. Refer to Texas Water Code

• 5.115. To determine whether lands dedicated to the permanent school fund are affected, you may submit a request which includes

the property location to the General Land Office at the following address:

GENERAL LAND OFFICE DEPUTY COMMISSIONER OF ASSET ACQUISITION

- STEPHEN F AUSTIN BLDG 1700 N CONGRESS AUSTIN TX 78701 If it is determined - that your application may affect.. lands dedicated to. the permanent school- fund, your application must include the following information:-

(a) State the location of the permanent school fund land to be affected.

t (b) Describe any foreseeable impact or effect of the proposed permitted action on permanent school fund land.

n

l I

i

- REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE II

, _t t.

A formal action or ruling by the Commission on an application affecting permanent school fund land that is )

made without the notice required by the above-referenced l rule is voidable by the School Land Board as to any j permanent school fund lands affected by the action or l ruling. (Texas Water Code 5.115(g)] j THE FOLLOWING ITEM 8.d. IS ONLY REQUIRRT1 FOR NEW PERMIT APPLICATIONS AND MAJOR AMENDMENT PRWTT APPLICATIONS FOR DOMESTIC FACILITIES. (This item is ]

not anolicable for Domestic Renewal normit anolications or Industrial New.

Amendment. and Renewal normit anolications.) Not Applicable '

4

d. Facility Drawing: Show on a 8 1/2" by 11"' site map (to scale) the following:

(1) The applicant's property boundaries, j (2) Each treatment unit and specify the distance from each unit to the property line.

(3) The required buffer zone (set back) in accordance with 30 TAC Chapter 309.

(4) If the required buffer zone (set back) as shown in the facility drawing is not owned by the applicant, indicate the alternative to ownership which will be utilized based on 30 TAC Section 309.13 (e) (2) or (e) (3) or the request for a variance in accordance with 30 TAC Section 309.13(f):

i (5) Provide documentation to support the alternative or variance to l be utilized to comply with 30 TAC Section 309.13 (e) or (f).

)

i l

1 (6) Indicate if the facility meets the requirements of 30 TAC Section 309.13(a) through (d):

[] Yes ( ) No -

l i

REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 15 i i

?

THE FOLLOWING ITEM 8.d. IS ONLY REOUInun FOR. NEW PRauTT APPLICATIONS AND MAJOR AunnunT PanuTT APPLICATIONS. (This item is not anolicable if d recruestina a Ranawal Permit annlication) . Not Applicable j

d. New Facilities and physical expansions of facility: Submit a minimum of one original ground level photograph as instructed in items a. and b.,

below. Clearly describe the exact location of the photos on a plot plan or map. Indicate the direction (N, E, S or W) that the photographer is facing.

(1) Discharge Applications: Show the location of the wastewater treatment facility, the point of discharge to the receiving watercourse and as much area downstream as may be captured on film. If discharge is to a lake, show the area on either side of the point at which the discharge line is proposed to enter the lake.

(2) Land Disposal: Show the location of the wastewater treatment j facility and the general characteristics of the area of disposal.

9. Additional Permit Coverage for Site

a. List any other pemits, existing or pending, which pertain to pollution control activities conducted at this facility (site) and any other TNRCC permits or licenses.

Hazardous Waste Management Permit No.

Non-Attainment Permit-No.

National Emission Standards for Hazardous Pollutants Permit No.

Water Right/Use Permit No. CP-20. CP-20A. P-2871. P-2971A. P-2971B. P-2971C Water Right/ Secondary Use Pemit No.

TNRCC Certificate of Adjudication 12-4097 TNRCC Certificate of Convenience and Necessity On-Site Subsurface Facility Permit Industrial Solid Waste Registration No. -33306 Dredge and Fill Pemit No.

UIC program under SWDA Sewage Sludge Registration Sludge /Septage Transporter Registration Municipal Solid Waste Landfill No.

Other EPA NPDES Permit No. TX0065854 EPA NPDES Stormwate Permit No. TXR05G567 TNRCC RCRA-Part B No. HW-50356-000 Texas New Source Review Nos.19225, 34242, 38783 REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 16

rr 6

b. I For domestic wastowater ' treatment facilities: If any portion of the treated efflusnt is given or sold to another party for the purpose of

. irrigation, provide the following: Not Applicable l (1) Copies of approval letter (s) authorizing use of treated effluent

! under an approved plan in accordance with 30 TAC Chapter 210, Use of Reclaimed Water, and include the following information:

.(2) An-estimate of volume of treated effluent in gallons per month.

l

! l i

(3) The number of acres irrigated by each authorized user that is

l. given, sold or otherwise utilizes treated effluent.

l C. List any encity that acts as a customer or waste contributor, who i maintains a wastewater collection system for transport of their '

wastewater to the applicant's facility, separate from the applicant.

Not Anolicable i

1 i

l I

L l

REVISED.10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 17

t. = t.

7 .

I

10. Application and Postage Fats

a. Check the appropriate ' permit application processing and postage fee below. The ' application fee must be sent under separate cover to TNRCC, Revenues Section.(see instructions for mailing address). To assist in expediting the application, please include a copy of the check with the

. application. See Attachment 4: Copy of Submitted Application Fee Check 1

(1) Industrial permit application fees are based upon the EPA I Major / Minor . facility. designation and' the applicability of EPA  ;

. categorical' guidelines (Table 1) for the facility as-follows: .

Tyne of Annlication *Anolication Fees NEW/ AMEND RENEWAL

-() Minor amendment for a minor facility $150.00 N/A

() Minor amendment for a major facility $450.00 N/A-(]' New, major amendment and/or renewal $350.00 $315.00 for a minor facility not subject to categorical standards promulgated by EPA (40 CFR Part 400-471)

(] New, major amendment and/or renewal $1,250.00 $1,215.00 for a minor facility subject to

.. categorical standards promulgated by EPA (40 CFR Part 400-471)

(X) .New, major amendment and\or renewal $2,050.00 $2,015.00 for a major facility, ,

1 (2) Domestic wastewater application fees are dependent on the type of application and the' size of the facility. Not Applicable Tyne of Annlication *Annlication Feem ,

New/ Amend Renewal '

l Minor ameridment $150.00 N/A Fee for new, major amendment or renewal:

[]_ .'< .05 MGD: $350.00 $315.00

^

.()' > .05 but < .10 $550.00 $515.00

~

() > .10 but < .25- $850.00 $815.00.

() > .25 but < .50 $1,250.00 $1,215.00 l

[-] > .50 but < 1.0 $1,650.00 $1,615.00

() .> 1.0 $2,050.00 $2,015.00

'*(Postage fees of $50,00 for New and Amendments and $15.00 for Renewals

have been' included with the application fees (above) to cover the expenses

' REVISED;10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 18 b ,

i

( of the required notice.) (30 TAC, Section 305.53)

11. Attachments List and index all attachments crossed-referenced to the specific related item in this application. (Provide a separate attachment if necessary. )

Attachment '1: Pronosed Chances To Permit No. 01854 Attachment 2: USGS Site Maos )

Attachment 3r Facility Mao Attachment 4: Cooy of Submitted Aeolication' Fee Check Attachment 5; General Descriotion Attachment 6r Water Use Diaoram Attachment 7: Once-throuch Coolina Additives l

Attachment 8: Auxiliary Boiler Additives '

Attachment 9 Wastewater Ponds and Low Volume Waste Pond Liner Snecifications Rtachment 10: Soils Man

. REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 19 a_

l l

l l

INSTRUCTIONS FOR SIGNATURE PAGE Signature on Application

The person who signs the application form should be the applicant (s). If the operator is required to apply as co-permittee with the facility owner, both signature pages are required.

SIGNATORY REQUIREMENTS:

The application must'be signed by the official indicated below, according to the type _of entity e corporation - a principal executive officer of at least the level of vice president; e

partnership - general partner as identified in the partnership agreement

• sole proprietorship - the proprietor

• ' municipality - a ranking elected official I

• - independent school district - at least the level of assistant superintendent a

state, federal or other public facility, the application must be signed by a principal executive officer When another person signs on behalf of the applicant (s), his/her title or relationship to the applicant must be shown. In all cases, the person signing the form must be authorized to do so by the applicant. A Person sianina an annlication on behalf of an annlicant (s) =uat crovide croof of authorization. A cony of thg authorization letter from the executive officer must be included with the application.

The signature page must bear the seal of a notary public. The date signed by the applicant must be same date notarized. The signature page will not be acceptable if the dates are different.

l l-t l'

REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 20 t

y

• L. 1

l. SIGNATURE PAGE l

~

l- ONNER OF FACILITY:

i I

(I, . Jmmas J. Kellev Vice President. Nuclear Enaineerina and Sunnort

~ (Typed or Printed Name): .(Title) )

'1 certify under penalty.of law that this document and all attachments were prepared i

under my direction or supervision.in accordance.with a system designed to ans'ure that qualified personnel properly gathered and evaluated the information submitted. i

. Based on my inquiry of. the person or persons who manage the system, ~ or ~ those persons i directly responsible for gathering the information, the information submitted is, '

to the best of my knowledge and belief, true, accurate, and complete. I am aware there are significant penalties for' submitting false information, including the possibility of fine and imprisonment for known violations.

Signature: Dates NOTE: ALL APPLICATIONS MUST BEAR THE SIGNATURE AND SEAL OF NOTARY PUBLIC.

SUBSCRIBED AND SNORN to before me by the said on this day of ,

My commission expires on the

' day of ,

(Seal)'

Notary Public-County, Texas

~

. REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 21 4

i.

p .

1

l. l t

I .

, SIGNATURE PAGE

. FACILITY OPERATOR:

(THIS ONLY APPLIES IF THE OPERATOR IS REQUIRE TO APPLY AS CO-PERMITTEE)

I l

I

-[I, Not Anolicable (Typed or Printed Name) (Title)

. certify under penalty of law'that this document'and all attachments were prepared under my direction or supervision in accordance with a system designed to assure ,

that qualified personnel properly gathered and evaluated the information submitted. )

Based on my inquiry of the person or persons who manage the system, or those persons i directly responsible for gathering the information, the information submitted is,  !

to the best-of my knowledge and belief, true, accurate, and complete. I am aware there are significant penalties for submitting false information, including the possibility of fine and imprisonment for known violations.

Signature: Date: I I

NOTE: ALL APPLICATIONS MUST BEAR THE SIGNATURE AND SEAL OF NOTARY PUBLIC.

SUBSCRIBED AND SWORN to before me by the said on 1

this day of ,

I My comission expites on the

. day of , .

(Seal)

Notary Public County, Texas J

REVISED 10/98 ADMINISTRATIVE REPORT FOR-PERMIT APPLICATION PAGE 22 t

4 " gl

p .

! _All Applicants should. Complete the Following Items Permit Number - 01854 Address for receiving Self-Reporting /DMR forms:

Provide the address to be used for receiving self -reporting /DMR forms from the TNRCC. The address given in' item 1 of'the application will be used if a different-address is not provided in the space.

Texas Utilities Electric Comoany 1601 Bryan Street. Suite 09-130 )

Dallas. Taran 75201-3411 Attn! Phvilis Robinett l

Permit Number: 01854 Address for receiving Annual Billing Invoicecs Provide the address to be used for receiving invoices of Annual Water

. Quality Assessment and Wastewater Treatment fees assessed, September 1.

The address given in item 1 of the application will be used if a different address is not provided in the space.

Refer to Item 1.

{L REVISED 10/98 ADMINISTRATIVE REPORT FOR PERMIT APPLICATION PAGE 23

,- i TECHNICAL REPORT FOR INDUSTRIAL WASTEWATER DISCHARGE PERMITS (Revised December 1998)

The following information (Items 1-16) must be provided as a minimum to l

support an industrial wastewater permit application. All attachments  !

(Attachments A-J) need to be reviewed and completed as directed. Do not l refer 'to supplemental reports in lieu of filling out these minimum l requirements. . If an item does not apply to your f acility write N/A to l

! indicate that you have. considered it. Please do not include information l concerning storm water discharges which are authorized and regulated by an ,

EPA promulgated general permit. '

ITEM 1 IS ONLY nmOUImun FOR EXISTING PMDMTTTED FACILITIES SURMTTTING AMENDMENT APPLICATIONS.

1. Are you requesting an amendment of an existing permit? .

YES 'NO X If YES, discuce the scope of any permit changes being requested. Explain why j the permit amendment is needed and provide supplemental information or additional data that will support the request.

ITEM 2 IS ONLY BMoUYamn FOR EYTSTING Pa#MYTTED FACILITIES SUMMTTTING RENENAL APPLICATIONS.

2. Are you requesting any minor changes to the permit which include correcting typographical errors, changing the construction schedule for a new source discharger, and/or removing a point source outfall? (Please note that changes such as reductions- in monitoring frequencies, removal of effluent

. limitations, addition of wastestreams, etc., are not considered minor changes.)

YES X NO If YES, list-and discuss the requested changes.

See Attachment 1: Proposed Changes To Permit No. 01854 l

L REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 1

JTEMS- 3-16 ARE REOUIRED FOR AT 7. (NEW, AW WMENT, AND RENEWAL) PEP}IIT APPLICATIONS.

~3. FACILITY / SITE INFORMATION:

a. Describe the type of facility and industrial or commercial activity at the plant. ~ Provide a detailed description of the processes at the facility which generate wastewater. Your description should include information such as any modifications to your process water / storm water handling ~ facilities, the start-up or shutdown of any process or treatment units, any wastewater recycle projects, or any changes in production throughput. l The facility's process and/or wastewater treatment system is described in Attachment 5: General Description. The information contained therein is correlated with Technical Report, Item 3.f.

4

b. Describe the general nature of your business and list any Standard Industrial Classification codes that apply.

Generation of electricity SIC Code (s) 4911 , , , , ,

c. Provide a list of raw materials, major intermediates, and products handled at your facility. Provide corresponding Chemical Abstracts l Systems (CAS) numbers. Be specific and avoid trade names. For commercial (nonmanufacturing) facilities, provide a list of chemicals used on-site which could impact effluent quality. (Attach additional l pages if necessary.) j i

RAW MATERIALS INTERMEDIATES PRODUCTS l

l water steam electricity l

enriched uranium l

i REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 2 d

n

.d. Businnaa' operates 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> /dsy '7 days /wask 12 months / year. ,

I Will the discharge / disposal be seasonal? YES X NO. {

L

-If YES, please explain.

~

l L

I

e. . List'any physical, chemical, and/or biological treatment processes that

.youLuse for the treatment of wastewater at your facility. This list should be specific and include-each unit in the treatment process and

.;, dimensions (e.g. dissolved . air floatation, chemical precipitation, q

equalization,-pH control?. aeration, steam stripping, . clarification, 1 anaerobic ' lagoon) . Please specify the ' associated outfall for each

, treatment unit and which wastewaters. are chlorinated prior to Ldischarge.

Treatment Unitae Refer to Attachment 5: General Description 1

I

f. ' Attach a flow schematic showing each treatment unit (including any_

lagoons, ponds or impoundments) and all sources.of wastewater flow into the treatment plant.and to each outfall.--This schematic should include process wastewater, cooling water, domestic wastewater, and storm water. A water.. balance using average flows for each waste stream must

, be' included..(See Attachment J for example.)

See Attachment 6:' Water Use Diagram

~

g. .- Attach a facility map (drawn to scale). showingr

..See' Attachment 3: Facilitiy Map

(1). ~ Production areas, maintenance. areas, materials handling areas,

. and waste disposal areas.

'(2) - The .o location of each unit of the wastewater treatment plant including the location of sumps and impoundments.

'(3)s The accurate location of . water supply ' wells and ground water .

monitoring wells.

.(4): The location of-outfalls and the outline of the drainage area that flows to each outfall that contains storm water.

-aEvtsBo 12/se: IwousTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 3 i-  :

i:' , '

p

.4.

Plsesa provida tha following information concerning each outfall for discharga and sich finni point of efflusnt disposal for no-discharge operations: a) describe the location of each discharge outfall (e.g. Outfall

_001; at the outlet weir of the treatment plant prior to entering the river) aid the sampling location (if different); b) please complete the table to describe discharge or disposal . operations; and c) provide a list of the wastestreams (e.g. process wastewater, cooling tower blowdown, once through cooling. water, sanitary wastewater) to be discharged or disposed of via this permit.

LATITUDE LONGITUDE OUTFALL MMg ggg DESCRIPTION OF LOCATION from the Once-through Cooling 001 a. 32 17 46 97 46 51 Discharoe to Sauaw Creek Reservoir

b. Discharge -Daily' Daily Type of or Average Maximum Flow Disposal Flow Flow Flow I or P or Measurement Method

• hrs /dav MGD** Iggt*,* C***, G**** Device D 24 3168 3168 L P , record

c. CONTRIBUTING WASTESTREAMS

'See Attachment St General Descriotion i

LATITUDE- LONGITUDE OUTFALL MME MME DESCRIPTION OF LOCATION from the. Safe Shutdown Impoundment 002 a.. 1 12.,, E 2 2 1 2,. 1 to Sauaw Creek Reservoir l

1

b. Discharge Daily Daily Type of or Average Maximum Flow D20posal Flow Flow Flow I or P or Measurement

$4e t hod

• hrs / day MGD** MGD** C*** G**** Device i

D 24 1,L,2 18.7 I ,Q estimate ,

1 1

c. CONTRIBITTING WASTESTREAMS See Attachment S: Ganaral Descriotion

• Please indicate the method of wastewater discharge / disposal:

D = Discharge; I = Irrigation (Land Application);

E = Evaporation; S =' Subsurface Disposal (Septic Tank / Drain Fields)

• • Please state the' flow you are requesting to have authorized by this l

l permit application.

j' *** Please indicate whether the flow is (I) Intermittent or

• Continuous.

• • • • Pumped or gravity flow. If pumped, indicate pump capacity (gpm) .

REVISED 12/98, INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 4 u J

n.. .

If IATITUDE LONGITUDE OUTFALL DEG MIN SEC DEG MIN SEC QESCRIPT20N OF LOCATION from the Sewage Treatment Plant 003 a. 12,_ .12., E .22 E E to Sauaw Creek Reservoir

b. Discharge Daily Daily Type of or Average Maximum Flow Disposal Flow Flow Flow I or P or Measurement 1 Method

• hrs /dav MGD** MGD** C*** G**** Device '

I D 24 report renort C P estimate l

-c. CONTRIBUTING WASTESTREAMS See Attachment Sr General Descrintion LATITUDE LONGITUDE OITrFALL DEG MIN SEC DEG MIN SEC DESCRIPTION OF LOCATION from the waste. Management System to 004 a. 32,,,, E E 22 ,(2,,, 2,1., outfall 001 and/or Saumw Creek Reservoir l

b. Discharge Daily Daily Type of or Average Maximum Flow Disposal Flow Flow Flow I or P or Measurement Method

• hrs /dav MGD** 24GQ*_* C**,* G**** Device D 24 report report _,1 ,,, ,,S,_,,, estimate

c. CONTRIBUTING MASTE9TREAMS See Attachrnant 5 General Descrintion LATITUDE LONGITUDE-OUTFALL DEG MIN SEC DEG MIN SEC DESCRIPTION OF LOCATION I 005 .a. d .12' -

22,_ 22 12 . g from saumw creek Reservoir to Y.mira Granhury

'b. Discharge Daily '

Daily Type of or Average Maximum Flow

-Disposal Flow Flow Flow I or P or Measurement Method *- .

hrs / day MGD** Hgg *,*. C* * *, G**** Device

.,,,,R,,, 24' report renort I P estimate l

c. CONTRIBUTING MASTESTREAMS

'See Attmehment 5 Ganaral'Descrintion

' REVISED'12h98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL' REPORT PAGE 5 y

p,,,,,,, . . . . . . . . .. -

-l; LATITUDE LONGITUDE OUTFALL . DEG MIN SEC - DEG MIN SEC DESCR2PTTON OF LOCATZON from the Metal Cleaning Waste Basin 104' a . ' 32, 1.0,,,, : E - 22 E 2,1 to Outfall 004.-

b. Discharge Daily Daily Type of or~ Average Maximum Flow Disposal. Flow Flow Flow I or P or Measurement

' Method

• hrs /dav MGD** MGD** C*** G**** Device D 24 report report _,,I,,,,. P . estimate

. c. CONTRIBUTING MASTESTREAMS

See Attachment 5: rannaral ' Descrintion LATITUDE LONGITUDE OUTFALL DEG MIN SEC DEG MIN SEC DESCRIPTION OF LOCATION

-a. __,,,

+

-b. -Discharge: Daily Daily Type of or Average Maximum Flow Disposal Flow Flow Flow I or P or Measurement Method

• hrs / day MGD**-  !$H2* *, C*** G**** Device

c. CONTRIBUTING MASTESTREAMS LATITUDE LONGITUDE OUTFALL DEG MIN SEC DEG MIN SEC DESCRIPTION OF LOCATION a.

. b. . ; Discharge Daily ' . Daily Type of or Average Maximum Flow Disposal Flow . Flow Flow I or P or Measurement Method

• hrs / day tgE2*,* lgE2* *, C * * *. G**** Device

c. CONTRIBtFFING MASTESTREAMS Ravisso.12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 5 h j

(: -

l

.5. For each outfall. regulated in your existing parmit which requires you to

,_ monitor or report the flow, report the average and maximum values from the Monthly Ef fluent Reports for the previous 24. months regardless of the t

required monitoring frequency. Indicate the total number of excursions (NE) over the last 24 months.

Monitoring Start Date 2/97 Monitoring End Date 2/99 1.

---

FLOW .(MGD) ----

FLOW (MGD)

AVERAGE OF MAXIMUM OF MAXIMUM OF NUMBER l DAILY DAILY DAILY OF OUTFALL AVERAGE AVERAGE MAXIMUM SAMPI.ES VALUES VALUES NE VALUES NE 001 2827 3168 0 3168 L 24 002 No discharae over east 24 montha 003 '0.0201 0.0426- 1 0.3000 0- 24 004 0.7689 0.9152 0 1.3771 L 24 005- No discharae over east 24 monthe 104 No discharam over cast 24 monthm

6. For 'each outfall that discharges storm water runoff and is t.o be regulated by this~ individual permit, provide the following information-(please refer to Attachment K for' guidance):

a. Outfall Area of Impervious Surface Total Area Drained

~

Number (provide units) (provide units)

Discharaem of' storm water r - ff are authorized by the subiect

-normit for the followina outfall!

002 82 acres 355.65 acres l

REVISED,12/98 INDUSTRIAL WA8TEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 6

+

w 6 k i'.

7 .

~b.'D ucribe any trar.tmsnt:for storm water runoff for each outfall.

See Attachment 5: General Description

c. List'the' local area rainfall and your source of information.

Average rainfall for wettest' month. 4.S~ -in/ month

' 25-year 24-hour rainfall. 7.25 inches Source: Averaos rainf all for wettest mont h Tavan Denartment of Water.

Resources. Climatic Atlas of Tavam. LP-192. 1983 25-vear 24-Igggg rainfall;' National Weat her Service. Technical Paner 40.1961

7. .Is your treatment facility located above the 100-year frequency flood

~

-level?

X YES NO Source of information: Damian clana'for Sauaw Creek Reservoir orecared by Freese & Nirhnlm. Inc. 1974 If NO, then please provide the elevation of the 100-year flood plain, the elevation of the treatment facility, and a description of what protective measures are in use or planned ' to prevent flooding of. the treatment facility?

8. . INDUSTRIAL' SOLID WASTE MANAGEMENT:

-a. Are hazardous wastes treated, stored, or disposed of within the wastewater treatment system at this facility?

YES X - NO -

If YES, list the EPA hazardous . waste number (s) and the units within the wastewater treatrc2nt system used to . treat, store, or . dispose of hazardous wastes. Show the location of these units on the, site map.

b. -Locate all. active and inactive hazardous and non-hazardous solid waste storage, treatment and/or disposal sites on a facility map.

See Attachment 3; Facility Map.

c. Describe the management : of storm water runoff for the solid waste disposal site (s) . .

All facility landfills have been capped in accordance with approved

-TNRCC closure plans or in compliance with TNRCC approved guidelines which includes proper diversion of storm water runoff.

REVISED.12/$$ INDUSTRIAL' WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 7

g.

d. Is any latchtto collseted from tha solid wasta disposal site (s)?

t X YES NO If YES, describe the leachate collection, treatment and disposal method.

r.

Collection of.leachate is governed by the facility's Leachate Collection Plans which have been previously submitted to the TNRCC.

These plans are subject to change based on monitoring program results.

9. DOMESTIC. SEWAGE, SEWAGE SLUDGE, AND/OR SEPTAGE MANAGEMENT AND DISPOSAL:

Please check the appropriate method (s) of domestic sewage and domestic sewage sludge treatment / disposal and complete Attachment F if directed.

Domestic sewage is not generated on-site. PROCEED TO QUESTION NO.

10.

Facility is connected to a wastewater treatment plant permitted. to receive domestic sewage or domestic sewage is transported off-site to a permitted facility for treatment and/or disposal. PROVIDE THE NAME AND TNRCC, NPDES,.and/or TPDES PERMIT NO. OF THE PLANT WHICH RECEIVES THE DOMESTIC SEWAGE. IF HAULED BY MOTORIZED VEHICLE, PROVIDE THE NAME AND TNRCC REGISTRATION NO. OF THE HAULER.

X1"__ Industrial wastewater and domestic sewage are commingled prior to wastewater treatment.

Industrial wastewater and domestic sewage are treated separately.

Domestic treatment sludges and/or domestic septage are commingled with industrial wastewater treatment sludges prior to sludge use or disposal. COMPLETE ATTACHMENT F OF THIS APPLICATION.

_X Industrial wastewater and domestic sewage are treated separately.

Domestic treatment sludges and/or domestic septage are HQI_ commingled with industrial wastewater treatment sludges prior to sludge use or disposal. COMPLETE ATTACHMENT F OF THIS APPLICATION.

Domestic sewage is disposed of by on-site septic tank. COMPLETE ATTACHMErr F OF THIS APPLICATION.

Other (Please provide detailed description).

in A small amount of chemical laboratory waste is commingled with the domestic sewage but domestic sludges are HQI commingled with industrial wastewater treatment sludges prior to sludge use or disposal.

} -REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 8

10. Do you receiva wastes from off-cite courcas for a) trestmsnt in your fecility, b) disporal on-sita via lend eppliettion (irrigation, evaporation, etc. and/or c) discharge via a permitted outfall?

YES X NO If NO, go to Item 11. If YES, proceed as directed.

a. Do you receive wastes, for treatment at your facility, from off-site sources which are directly related to the on-site activities conducted at your facility?

YES NO

'If YES, provide a list of the waste (s) received (including volumes, characterization, and compatibility with on-site wastes), identify the source (s) of the waste (s) (name and address of the generator), and describe ' the relationship of the waste source (s) with your facility's activities.

b. Is wastewater from a TNRCC, NPDES, and/or TPDES permitted facility commingled with your wastewater af ter your final treatment and prior to discharge via your final outfall or disposal on-site via land application?

_ YES NO If Y3S, provide the name, address, and 'IWRCC, NPDES, and/or TPDES peInit num$ser of-the contributing facility and a copy of any agreements and/or contracts relating to this activity.

c. Is your facility a Publicly owned Treatment Works (POTW) that accepts process wastewater from any Significant Industrial User (SIU) and has or is required to have an approved pretreatment program under the NPDES /TPDES program?

i

. YES NO If YES, then complete Attachment G of this permit application as directed.

j =

l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL kB NkT PAGE 9 L_

6 .

.11. SIGNIFICANT LEAKS AND/OR SPZLLS

)' , Please provide existing informatidn regarding the history of significant I

! leaks or spills of toxic or hazardous pollutants at the facility within the  !

last three (3) . years. Include the approximate date and location of the

.. spill / leak,.and the type of material and amount of material released.

!- 13. November 1996: 100 gallons of H.PO.C. Polymer. and HEDP leaked ham a relief valve failure in the Southwest Chemical Feed Building.

I

! 12. COMPLIANCE HISTORY

]

l,  : Are you currently required to meet any implementation schedule for the construction, operation, or upgrading of your wastewater treatment equipment? This requirement includes . Federal, State, or local authority permit' conditions,~ administrative or enforcement orders, enforcement i compliance schecule letters, stipulations, court orders, or grant and loan conditions.

[

l IES X NO' 4

If YES, provide a brief summary of the requirements. I I

-13. -Radioactive materials shall ' not be - discharged in - excess of the amount

' regulated by 25 TAC Sections 289.11-289.126 (relating to Texas Regulations for Control of Radiation) and 30 TAC Chapter 336 (relating to Radiation Rules)...If you mine, use, store, or process any radioactive material (s),

-list the - radioactive materials and provide the results of at least one analysis of your effluent in ' picoeuries per liter ~ (pci/L) for all radioactive 1 paras.eters which may be present. (This requirement is not applicable to radioactive materials fixed- in a device or instrument.) If this application is ' for a new facility submit results from similar fccilities, treatability studies, or literature sources.

-Not Applicable,-discht/cge of radioactive material falls under the jurisdiction of _ the Nuclear Regulatory Commission (NRC) .

REVIsso 12/ps INDUSTRIAL WAETEWATER PERMIT APPLICATION TEClOtICAL REPORT PAGE 10

rT-i4. .Doas your facility use any cooling towsrs or boilers that discharge blowdown or other wastewater streams to the outfall(s) ? i Xm YES NO l J

If YES, the following information on all chemical additives including i biocides must be submitted for cooling towers and boilers. If aquatic toxicity information is not available, additional effluent biomonitoring may be required. If'the MSDS sheets do not contain the information specified

'below, it wi..1 be necessary to obtain the information frou. the manufacturer.

Provide a suumary of this information in addition to the submittal of the ]

l MSDS sheets. Please specify which cutfalls are affected. l

.a. Manufacturers-Product Identification Number.

bi Product Use. (e.g., biocide, fungicide, corrosion inhibitor, etc.) 'I

c. Chemical Composition including Chemical Abstracts System (CAS)unumber for each ingredient.

d. Product toxicity data ~ specific to fish and aquatic invertebrate organisms. Specify if data is for the whole product or for an active ingredient.

l e, classify product as non-persistent, persistent, or bioaccumulative,

f. Product cnr active ingredient half-life.

g. If data in Item d., above is for the whole product, indicate the concentration of the whole product in the blowdown stream.

If data in Item d., above is for the active ingredient, indicate the

! concentration of the active ingredient in the blowdown stream.

h. Frequency of product use (e.g., 2 hr/ day once every two weeks).

l I. The number of cooling towers on site is (e.g., 2,3,4, etc.)

[ and the total blowdown volume is:

Daily Averdge gallons / day l

l ' Daily Maximum _ gallons / day

j. The number'of boilers on site is 1 (e.g., 2,3,4, etc.) and the total blowdown volume is:

Daily Average. (11 gallons / day 3 Daily Maximum (1) gallons / day mine Auxiliary Boiler is an emergency back-up system that is only

[

activated'in the event of a ?.oss of steam generator use. The Auxiliary Boiler is run periodically for naintenance purposes.

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 11

.% i

l l

15.

~

Doas,your facility diccharga.once-through cooling water to tha outfall(o) ?

X YES NO If YES, the following information on all chemical additives including chlorine and bromine must be submitted. If aquatic toxicity information is not available, additional effluent biomonitoring may be required. If the s

MSDS sheets-do not contain-the information specified below, it' will be

~

necessary to obtain the information from the manufacturer. Provide a summary of this-information in addition to the submittal of..the MSDS sheets. Please specify which outfalls-are affected.

See Attachment 73.Once-through Cooling Additivies

a. . Manufacturers Product Identification Number.

b. Product Use. (e.g., biocide,1 fungicide, corrosion inhibitor, etc.)

c. Chemical Composition including Chemical Abstracts System (CAS) number for each ingredient.

d. . Product toxicity data specific to fish and aquatic invertebrate organisms. Specify if data is for the whole product or for an active ingredient.

e. Classify product as non-persistent, persistent, or bioaccumulative.

f. Product or active ingredient half-life.

.g.

~

If data in ?Mm d., above is for the whole product, indicate the

, concentrat'* if the whole product in the once-through cooling water stream, it :a in Item c. . , above is for the active ingredient, indicate t .. concentration of the active ingredient in the once-through cooling water stream.

h. Frequency of product use (e.g. , 2 hr/dsy once every two weeks) .

16. IMPOUNDMENTS:

.Do you use or plan to use any lagoons, ponds, or impoundments for treatment

-(T), disposal (D), containment (C), or evaporation (E) of your wastewater?

2 YES No If YES, complete items a-d for existing impoundments and items ' a-I for proposed new impoundments. If NO, skip items a-I:

See Attachment 9: Comanche Peak S.E.S. Wastewater Ponds and Low Volume

.. Waste Pond Liner Specifications for-items a, b, c, d, a and f.

a. WN c'are the dimensions of the impoundment (s)?

POND 1 POND 2 POND 3 POND 4 Designations (T) * (D) or (E) __

Length ft _ ft ft ft 9

Width ft ft ft ft p

Depth from water surface ft ft ft ft Depth below natural ground level- ft- ft ft ft For i v

• nts with irregular shapes, submit surface area (inutead of length and width), the average depth, and the maximum depth below ..atural gaccund level.

msvIsso 12/98 INDUSTRIAL MASTEWATER PERMIT APPLICATION TEOGIICAL REPORT PAGE 12 pr i s.. ,.,..-...g ,

m, .

v:

'b.  ; What is tha captcity 'of ths impoundmsnt (s) ?

POND 1 . POND-2 ' POND 3 POND 4

, e-

, , Gallons.

. Acre-Feet-

c. If a discharge occurs from the impoundments, designate the outfall associated with the impoundment.

POND 1 POND 2 POND 3. POND 4 Outfall No.

d. Arelthe.'mpoundment's. lined to comply with one of the following-specifications? Please describe the pond liner.

(1) ~ - weted - clav Linar: 1 The soil liner shall contain at least 3

' feet, . along - the ' sider and bottom, of clay-rich soil . material

. compacted in ilif ts - of no more. than ~ 9 inches, to 95% standard proctor ' density ' at the optimum moisture content to achieve -' a permeability equal to or less than 1 x 10 -7 cm/sec.

(2) In-situ clav Linarr The soil liner shall contain at least 3 feet, l,

along the sides and bottom, of clay-rich soil material having more than 30% passing a 200-mesh. sieve, liquid limit greater than or equal to 30%, and a plasticity index greater than or equal to 15,

. to achieve a permeability equal to or less than l1 x 10_ -7 cm/sec.

l (3) Plastic /nnhh-r idnart The liner. shall be either - a plastic or rubber membrane liner at least 30 mils in thickness which

~

completely covers the sides and the bottom of the pond and which is not subject to degradation due to reaction with wactewater with which it will come into contact. If ' this - lining material is vulnerable to ozone or ultraviolet deterioration it should be covered'with'a protective layer of soil of at least 6 inches.'A leak. detection system is also required.

M HQ Linar Descrintion Pond 1

, Pond 2' Pond 3.

I e.

d

):

]

i REVkSED12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECIOi! CAL REPORT PAD 13 I

l-

~ _-

1 i

T '

'o. submit eny availcble data on the following:

(1) ~ Liner - permeability, . liner ' thickness, test results on liner

, _ compatibility with appropriate wastes, test results from clay

, borrow source, test results from liner construction, etc.

. (2) J For.. impoundments constructed using in-situ soils as the liner:

submit available soils boring infomation, the depth of impermeable.. clay. ~ soils, test results on soil permeability, procedures for compaction of top. layer of in-situ soil, etc.

' (3) L Analytical data on wastewater stored in each impoundment.

(Additional testing is not being required, initially. However, information regarding levels of the contaminants Aat are listed in TABLES B-1 through B-9 may be useful in assessing the need for including pond lining requirements in the permit.)

Are there any leak detection systems or ground water monitoring

f.

i

. wells in place or planned?

'YES NO If YES, describe in a separate attachment, the leak detection system for each pond'and/or attach any available ground water monitoring well data. 'All ground water monitoring wells must be numbered and accurately, located on a map submitted with the application.

Existing ground water- monitoring data should be sununarized and evaluated to determine if there is a statistically significant trend

'in concentrations and/or - at statistically significant difference compared.with background. The. ground water monitoring summary should also include information on the metitoring wells such as the driller's logs, well completion data, ground. water elevations, sampling

~

procedures, etc. .

g. Is the botitom of the pond'above the seasonal high water table in the most shallow water bearing zone?

X .YES NO

.h. On a USGS quadrangle map, accurately locate and identify water supply wells within'a'l mile radius'of the' impoundments. Submit copies of State-Nater Well Reports.'(driller's' logs, completion' data), and' data

' on ': depths to - ground water . for water wpply: wells including a description of how the depths to ground water were'obtained.

See-Attachment 3: Facility Map

-- I . clude ' any ' other pertinent site-specific data that is available pertaining to the ground water,. soils, geology, etc. that has been or

can' be cused to assess the potential for migration of war

tes from the simpoundments and the' potential for: contamination of ground water or

, ' surface water.~ Additional data may include logs and location plats of 3 1 borings, soil' analyses, water quality data, etc.

See Attachment los Soils Map t

4

- REVISED'12/90i : INDUSTRIAL NASTEMATER PERMIT APPLICATICel TEOsTICAL REPORT PAGE 14

, 1, - ,

I ATTACHMENTS 1

TO THE INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT The following attachments may be required to be completed and submitted with the technical report. Please indicate, at the end of this section, if the attachment is completed and submitted with the technical report based on the following:

l ATTACHMENT As EPA EFFLUENT CATEGORICAL GUIDELINES Attachment A is required to b1 submitted for applications which seek l authorization to discharge wastewaters which are subject to USEPA l Effluent Limitation Guidelines - Title 40 of the : Code of Federal Regulations (40 CFR) , Parts 400 - 471.

l If your are requesting authorization to discharge a wastewater which is subject to an effluent limitation guideline then complete Attachment A as directed. If your business or industry is not subject to an effluent limitation guideline then skip Attachment A.

ATTACHMENT B: EFFLUENT CHARACTERIZATION AND ANALYTICAL TESTING Attachment B is required to be submitted for all applications.

ATTACHMENT C: LAND DISPOSAL OF EFFLUENT r

Attachment C is required to be submitted for applications which seek i authorization for the use of land disposal (irrigation, evaporation, etc.) as a method of effluent disp > sal.

l If this application seeks a new authorization or a renewal (with or r

without an amendment request) of an existing authorization to use land disposal for effluent disposal then complete Attachment C as directed.

l If this application does not request any authorization for land

! disposal of effluent then skip Attachment C.

I i

i REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 15 L -

. q l

l ATTACHMENT D TOXICITY TESTING Attachment - D is required to be submitted for applications which contain 1) process wastewater outfalls and/or any other continuous discharge outfalls from an industrial facility subject to EPA Categorical Standards (40 CFR 400-471), 2) process wastewater outfalls and/or any other continuous ' discharge outfalls f rom an industrial i facility classified as an EPA Major, or 3) treated domestic wastewater from outfalls at flows of 1 MGD or greater. External outfalls conducting routine toxicity testing as a requirement of the currently issued wastewater discharge permit do not need to be re-tested.

Internal outfalls also do not need to be tested.

If this application requires toxicity testing, under the conditions stated. above, then complete Attachment D as directed. If this application does not require toxicity testing, under the conditions stated above, then skip Attachment D.

ATTACHMENT Et RECEIVING WATERS Attachment E is required to be submitted for applications for a permit to discharge wastewater into waters in the state.

Attachment E is not required to be submitted for applications for a permit which seeks authorization for the use of land disposal (irrigation, evaporation, etc.) as the only method of effluent disposal with no discharge of wastewater into waters in the state.

ATTACHMENT F: SENAGE SLUDGE MANAGEK8NT AND DISPOSAL Attachment F is required to be submitted for some application 0 to obtain information concerning the disposal of domestic sewage altdze and/or domestic septage. Please refer to Item No. 15 on Page No.8 of the technical report to determine if Attachment F is r1 quired for ycur application.

ATTACHMENT G: INDUSTRIAL WASTE CONTRIBUTION l

Attachment G is required to be submitted for applications from those facilities which have or are required to have an approved pretreatment program under the TPDES program.

If this facility does have or is required to have an approved pretreatment program under the TPDES program, then complete Attachment G as directed. If this facility does not have and is not required to have an approved pretreatment program under the TPDES program, then skip Attachment G.

1~'

REVISED 12/98 INDUSTRIAL' WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE 16

7 ATTACHMENT H: HAZARDOUS SUBSTANCES I Attachment H is required to be submitted for all applications.

' ATTACHMENT 1: POLLUTION PREVFJfTION '

A*,tachment I is required.to be submitted for all applications.

ATTACHWENT J: SCHEMATIC OF WASTEWATER FLOWS EXAJPLE Attachment J.is an example of the type of wastewater flow schematic which is expected to be submitted in response to Item No. 3.f. on Page No. 3 of the technical report. The example provided in the application as Attachment J does not need to be submitted with the application. An actual schematic of your facility's wastewater flows must be submitted with application as Attachment J.

ATTACHMENT Ks STORM WATER PERMITTING Attachment K is intended to provide information concerning which conditions require individual TPDES permits for storm water discharges. Attachment' K does not need to be submitted with the application.

Please indicate which attachments are completed and submitted with the technical [

report based on the above information. Attachments that are not applicable do not need to be submitted with the technical report.

ATTACHMENT COMPLETED AND SUBMITTED WITH THE TECHNICAL REPORT:

A EPA EFFLUENT CATEGORICAL GUIDELINES YES X NO B: EFFLUENT CHARACTERIZATION AND ANALYTICAL TESTING YES .X NO C: LAND DISPOSAL OF EFFLUENT YES NO X D: mTOXICITY TESTING YES NO X E: RECEIVING WATERS YES X NO F: SEWAGE SLUDGE MANAGEMENT AND DISPOSAL YES X NC G: INDUSTRIAL WASTE CONTRIBUTION YES NO X l

H: HAZARDOUS' SUBSTANCES YES X NO I: POLLUTION. PREVENTION YES X NO l REVISED 12/98 . INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL RE=0RT PAGE 17

.t n

l ATTACHMENT A EPA EFFLUENT-CATEGORICAL GUIDELINES

.1. Table A-1 is a list of' effluent limitation guidelines as found in Title 40 Code of' Federal Regulations, Parts 400 - 471. Check the category (s) that applies to wastewater generated at your f acility.

l TABLE A-1 l INDUSTRY Ap CFR PART

[. Dairy. Products Processing 405 l Grain Mills- 406 j

. Canned and Preserved Fruits and Vegetables- 407 Canned and Preserved Seafood Processing 408 Sugar Processing 409 Textile Mills 410 Cement Manufacturing 411 j Feedlots - 412

__ Electroplating _ 413 Organic Chemicals, Plastics, and Synthetic Fibers 414' Inorganic Chemicals 415' Soap.and Detergent Manufacturing 417

{ Fertiliser Manufacturing 418 l Petroleum Refining 419

l. Iron and Steel Manufacturing 420 Nonferrous Metals Manufacturing 421 Phosphate Manufacturing 422

_X___ Steam Electric Power Generating 423 Ferrealloy Manufacturing 424 l Leather Tanning and Finishing 425 l

Glass ManufactuaLng 426 Asbestos Manufacturing 427 Rubber Manufacturing 428 Timber Products Processing 429 4 Pulp, Paper, and Paperboard 430 l Builders' Paper and Board Mills 431

' Meat Products 432 Metal Finishing 433 Coal Mining 434 l -.011 and Gas Extraction- 435 l Mir.eral Mining and ' Processing - 436 I I

_____ Pharmaceutical Manufacturing 439 l- Ore Mining and Dressing 440 l Paving and Roofing Materials 443 l ' Paint Formulating- 446 I Ink Formulating .

447 Gum and Wood Chemicals Manufacturing 454 Pesticide Chemicals 455 Explosives Manufacturing 457 Carbon Black Manufacturing '

458 Photographic 459 Hospital 460 Battery Manufacturing 461 u Plastics Molding and Forming 463

~

Metal Molding and Casting 464 Coil Coatingf 465

' Porcelain Enameling. 466 Aluminum Forming 467 Copper Forming. 468 Electrical and Electronic Components 469 Nonferrous Metals Forming and Metal' Powders 471 N/A iWIBE5 U7WYilDUBfhiAL ilAffRRkfki' Ptlibiit'KWLIckflJ TacierICAL REPORT PAGE A-1

c. -

2. Industrial wastswttar must be treated to levels that maat the requiremants of applictble USEPA Efflutnt Limitation Guidelins's - Title 40 of the Code of Federal Regulations (40 CFR), Parts 400 - 471. Therefore, the permit application must contain all information necessary to calculate permit limits based on these guidelines.

If limitations in the above referenced guidelines that apply to your facility are expressed in terms of production (e.g. lbs of pollutant /1000 lbs of production), provide a quantity representative of the actual level I of production over the last three years, if available, for each category or subcategory. For refineries (40 CFR Part 419) , please include the size of each process unit, the throughput of the refinery, and the throughput of each unit.

)

ACTUAL- DESIGN SUBCATEGORY QUANTITY / DAY QUANTITY / DAY UNITS Not Aeolicable i

i l

l I

For facilities subject to effluent limitation guidelines for organic chemicals, plastics and synthetic fibers manufacturing, provide the fraction of total plant production that falls into each subpart (for instance, 459.

commodity chemicals, 35% bulk chemicals, and 30% specf.alty chemicals.) Also identify processes in Appendices A.and B to 40 CFR Part 414 that are utilized and provide the flow of metal bearing waste streams and cyanide i bearing waste streams, if any. See 40 CFR 414.

% of' Total APPENDIX A AND B SUBCATEGORY Production Metal Process Not Aeolicable  !

l I

l l

s l

For refineries (40 CFR Part 419), please identify the specific subcategory (i.e., topping, cracking, petrochemical, lube, and/or integrated) your facility is' classified as and include a justification for the l classification.

1 1

l i

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAI, REPORT PAGE A Y l

L l

s l

3. Provida a braakdown of process wastewater flow (s) and non-process wasttw:ter flow (s) as dafined for the industry in the appropriate guideline category. This quantitative listing of all wastewater sources is required in addition to a schematic flow diagram.

i See Attachment 6: Water Use Diagram I

4. Please list all - the processes which are both subject to USEPA Effluent Limitation Guidelines and generate a wastewater which is discharged via this permit. Please provide all the requested '

information for each process listed.

EPA GUIDELINE DATE PROCESS PROCESS- (PART & SUBPART) BEGAN OPERATION (*1) low volume waste sources 40 CFR Part 423 Anril 2, 1979 j chemical metal cleaninct wastes 40 CFR Part 423 February 3. 1994 once-throuah coolina 40 CFR Part 423 Anril 2. 1979 i I

J I

l I

i l-l

(*1) May also-include the date construction for the process commenced.

r 1

'REV15 d 12/98 INDUSTRIAL WA3TIMATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-3 H

L.

E i-ATTACHMENT B I I

EFFLUENT CNARACTERIZATION AND ANALYTICAL TESTING J

( .1. GENERAL GUIDANCE FOR ATTACHMENT B- 'i

[ Attachment' B contains a series of analytical tables which may need to be completed in ]

order for. the .' application to be technically complete. Following is a listing of )

l conditions which determine when a particular table is required to be completed and )

when it is not required.-Please note that the term " complete table required" means I that all pollutants listed on that table are required to be tested if the table is I required and the term " partial table required" means that only certain pollutants from f the tablen(as determined.by the instructions) will be required to be tested if the 1 table is required.

TABLE B-1: Complete table required for . all external outfalls which do not j

discharge solely storm water.

Complete table required for all final effluent monitoring peints for 1 effluent disposed of via land application or evaporation. ]

l Not required for internal outfalls or storm water only discharges.  !

TABLE B-2: Complete table required for all external outfalls which discharge process wastewater.

Partial table (only those pollutants that are used at the facility as a feedstock,' intermediate, product,' byproduct, coproduct, maintenance chemical or that could in any way contribute to contamination in the wastewater streams) required for each continuously discharging nonprocess external outfall (including noncontact cooling water) . Please respond with a."N/A' for each individual pollutant which is Egy,_ analyzed under this condition.

Not required for internal outfalls or storm water only discharges.

TABLE B-3: Partial table (only those pollutants which are required by the conditions specified) required for each external outfall.

Not required for internal outfalls or storm water only discharges.

TABLE B-4: Complete table. required for all external outfalls which discharge process wastewater and other wastewaters, which may contain pesticides or herbicides, from a facility ~ which manufactures or formulates pesticides or herbicides.

Not required for internal outfalls or storm water only discharges.

TABLE B-5: Complete table required for all external outfalls.

Not required for internal outfalls or storm water only discharges.  %

TABLE B-7: Partial table (only those fractinna as specified in Table B-6) required for all process. wastewater outfalls.

TABLE B-8 Complete table required for each external outfall under the conditions specified.

.Not required for internal outfalls or storm water only discharges.

TABLE B-9 Partial table (only those pollutants which are required by the conditions specified) required for each external outfall.

Not required for internal outfalls or storm water only discharges.

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B+1

Table B-10: Complete tabla requirzd for cl1 cxtsrnal outfalls which discharga solely ctorm witsr runoff Snociatid with "indu; trial activity" cnd are not regulated by an NPDES /TPDES multi-sector or construction general storm 4 water permit. Please refer to Attachment K for specific guidance.

TABLE d-11: Partial table (only those pollutants which are required by the conditions j specified) required for all external outfalls which discharge solely storm I water runof5 associated with " industrial. activity" and are not regulated by an NPDES /TPDES multi-sector or construction general storm water pemit, Please refea to Attachment K for specific guidance.

s

2. GENERAL REQUIREMENTS FOR ATTACHMENT B: 0 l

1 All information submitted with this attachment shall comply with the following: '

a. For pollutants currently regulated in your permit, report the average and maximum  ;

values from the Monthly Ef fluent Reports for the previous 24 months for all pollutants in the existing pemit regardless of the required monitoring frequency.

(For pH, report the minimum and maxir.um values. )

I

b. Tables B-1, B-2, and B-3: For pollutants not currently regulated in your permit, average and maximum concentrations must be calculated from at least four (4) )

separate analytical results obtained from four (4) grab or composite samples a collected at a frequency of 1/ week for a period of 4 weeks from the wastewater l stream unless otherwise specified in the application or approved by the TNRCC, Prior approval to submit less than four (4) samples should be obtained from the TNRCC prior to application submittal.

Tables B-4, B-5, B-7, B-8, B-9, B-10, and B-ll For pollutants not currently regulated in your pemit, average and maximum ccncentrations may be calculated from at least one (1) analytical result obtained from a grab or composite sample.

The quantitative data may be data collected over the past 365 days.

c. If this application is for a new discharge, results from similar facilities, treatability studies, design information, or literature sources may be submitted when real effluent analytical data ir, not available. Tbc basis of the "results" submitted should be explained.

d. For facilities which have an intermittent discharge from final retention impoundment (a) when the impoundments reach holding capacity and a discharge is not foreseen in the near future; samples of the effluent currently stored in the impoundment may be used to satisfy the analytical requirements.

e. Test Methods utilized should be sensitive enough to detect the constituents at the Minimum Analytical Level (MAL) specified. For analytical results that are non-detect, please report the analytical values as less than the detection level (example: a result that is non-detect with a detection level of 50 ug/l should be reported as "< 50 pg/1").

f. Grab samples must be used for pH, temperature, cyanide, total phenols, residual chlorine, oil and grease, fecal coliform, and enterococci. 24-hour composite samples must be used for all other pollutants,

g. If any of the analysis reported in this application are performed by a contract laboratory or a consulting fim, please povide the name, address, and telephone number for each laboratory and/or fim. Also specify which pollutants were analyzed by which laboratory / firm.

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT AFPLICATION TECHNICAL REPORT PAGE B-2 L,.

( .

h 3.

i fi Outfclla thit contcin any wintewrter othsr thin storm witer (e.g. , procaza f wastewater, utility wastewater, domestic wastewater, groundwater, etc.) must

[ complete TABLE B-1. Facilities that utilize land application or evaporation for wastewater treatment / disposal must also provide these analytical results.

TABLE B-1 OUTFALL 001 Sample Type GRAB X COMPOSITE INFLUENT EFFLUENT CONCENTRATION NUMBER CONCENTRATION NUMBER (mg/1) OF (mg/l)

OF POLLtTrANT & MS SAMPLES &EL tM L SAMPLES BOD (5-day) L21 4 4 CBOD (5-day) H/,A. & N/A Chemical Oxygen Demand 19. 3 8 2JLa 4 Total Organic Carbon . 6 . 92 L 11 4 Ammonia Nitrogen 0.064 0.10e 4 Total-Suspended Solids 4 5 4 q

Nitrate Nitrogen 0. 013 L.9.1 4

-Total Organic Nitrogen 0. 818 L.1 4 Total Phosphorus L2h2 9d2 4 Oil and Grease L.lli L.Q._ 4 Total Residual Chlorine 0.003 9 df 108 Total Dissolved Solids 1111 1910 4 l Sulfate 343.8 394.0 4  !

-Chloride iBL 221 '4 Fluoride 0.360 0.399 4 Fecal Coliform HL H/JL N/A Temperature ('F) 2.L.11 113. 00 730 pH (Standard Units; min / max) L.ii L.11 4 EFFLUENT CONCENTRATION NUMBER (ug/1) OF MAL POLLITTANT h M&L, SAMPLES g;[/1 Total Aluminum 13 J 12.J. 4 30 Total Antimony 0 0 4 30 Total Arsenic o 0 4 10 Total Barium 12.1J4 If1J. 4 10 Total Beryllium- 1JJ.1 R 4 5 Total Cadmium iJli 14.6 4 1 Total Chromium 0 0 4 10 Trivalent Chromium lHL lHL NA --

Hexavalent Chromium H& H&,. NA 10 Total Copper 0 0 4 10 Cyanide, . (Total, J.inenable to Chlorination or weak-Acid Dissociable 0 0 4 20 Tott.1 Lead 0 0 4 5 Total Mercury 0.127 0.206 4 0.2 Total' Nickel 0 0 4 10 Total Phenols' Edli L.9,11 4 20 l

i Total Selenium 0 0 4 10 Total Silver 0 0 4 2 Total Thallium 0 0 4 10 Total Zinc L,121 12.B0 4 5 1:

REVISED 12/98 INDUSTRIAL NASTENATER PERMIT APPLICATION TECHNICAL REPORT FAGE B 3 L_

ri s i

4 '.

ITABLE B-2 (contains a ' list ' of orgtnic compounds included in the Texas Surfaca Water Quality Standards at.30 TAC 307.6. TABLE B-2 must be completed with the results of an analysis of.all pollutants for each outfall that

contains process wastewater. In addition, an analysis for each continuously l discharging nonprocess 'outfall- (including noncontact cooling water) must be provided for nonly _ those. pollutants in TABLE B-2 that are used at the f acility "as 'a feedstock, intermediate, product, byproduct, coproduct,

~ maintenance chemical or that could.in any way contribute to contamination in the wastewater streams.

i TABLE b 2 OUTFALL 001W ,_ 4 CONC. ug/l (*I) NUMBER OF MAL 'l POLLUTANT E H&L. SAMPLES fau/l) .l l

Benzene sl.Q 1 10 Benzidine 50 q Benzo (a) anthracene 10 Benzo (a)' pyrene .

10 Bis (chloromethyl) ether ,_ (*2)

Carbon Tetrachloride si.Q 1 10 Chlorobenzene 510 i 10

. Chloroform s1Q '1 10 .

!' 'Chrysene 10

.Cresols. (*3) j Dibromochloromethane s19._ 1 10 ]

1'2-Dibromoethane

, 2 1,4-Dichlorobenzene 10 f 1,2-Dichloroethane s19_. 1 10 l l 1,1-Dichloroethylene 10 i Fluoride- 0.360 9,122 4 500 I

Hexachlorobenzene 10 Hexachlorobutadiene 10 Hexachloroethane 20 l . Methyl Ethyl Ketone 50

j. Nitrobenzene- 10 n-Nitrosodiethylamine 20 n-Nitroso-di-n-Butylamine 20

-PCB's,, Total (*4) 1 Pentachlorobenzene .

20

-Pentachlorophenol~- 50

!  : Phenanthrene 10 Pyridine' _ .

20

.1,2,4~5-Tetrachlorobenzene

, '20 Tetrachloroethylene 10 Trichloroethylene 10 1,1,1-Trichloroethane s19 1 10 2,4,S-Trichlorophenol: 50 TTHM (Total Trihalomethanes) 10 vinyl Chloride- s1Q 1 10 1 1

(*1)- Indicate units if different from ug/l l

(*2) Hydrolyses in water. will not require applicant to analyse at this time. J L(*3) MAL's 'for Cresolo sp-Chloro-a-crosol 10 ug/1 4,6 Dinitro-o Cresol SO ug/1;p Cresol 10 yg/l

.(*4) ' Total of PC5-1242, PCB-1254, PCB-1221; PCS 1232, PCB 1240, PCB 1260, PCB-1016.

(a)- Available data is provided. The company has no specific knowledge of the

. ' presence of these constituents in this effluent or of their use as a feed stock, intermediate product, by-product, co-product, maintenance chemical or potential contaisinant. The requirement to provide this data is, therefore, not applicable.

AEVISED 12/98 INDUSTRIAL WASTEMkTER PERMIT APPLICATION TECHNICAL REPORT PAGE B-4

E *

.5. TABLE B-3 contains tssting r$quirtmints for tha compounJ ."Tributyltin" and for' ths indicator ~ bact$ria "anterococci." Not.cll applicants are required to test for tributyltin or enterococci. Testing is required only under the following conditionst A .' TRIBUTYLTIN' Testing. will be required ~ for " 1) ' industrial / commercial facilities which directly' dispose of wastewater,from the types of operations listed below OR 2) ]

domestic facilities, which , receive wastewater from the types of j industrial / commercial operations listed below..Please check all that apply.

1). M eufacturers and formulators of tributyltin or related compounds, ie.luding, but not limited to SIC code 2879.-Testing required.

2). Painting of ships, boats and marine structures, including, but not limited to SIC code 1721. Testing required. .

3)- Ship and boat building and repairing, including, but not limited to SIC codes 3731, 3732 and 3441. Testing required, l

4) Ship and boat cleaning, salvage, wrecking and scaling, including, {

but not limited to SIC codes 4499 and 7699. Testing required. l l

5) Operation and maintenance of marine cargo handling facilities and I marinas,' including, but not limited to SIC codes 4491 and 4493.

Testing required.

6) . Facilities engaged in wood preserving, including, but not limited to, SIC code 2491. Testing required.

7) Any other industrial / commercial facility for which tributyltin is known to be present, or for which there is.any reason to believe that tributyltin may be present in the effluent. Testing required.

X 8) None of the above. No testing required.  !

B. ENTEROCOCCI Testing will be required for all dischargers directly into the Houston Ship j Channel (classified stream segment nos. 1006 or 1007). Please check all that j apply: .i i

1) Discharge is directly to the Houston Ship Channel (classified stream segment number 1006 or 1007). Testing required.

l '2) Discharge is not directly to the Houston Ship Channel (classified .

stream segment number 1006 or 1007). No testing required.

TABLE 5-3 OffrFALL  !

Concentration NUMBER OF MAL POLLUTANT &ML, H&L, Unita SAMPLES (ua/l)  !

)

Tributyltin 0.010 J Enterococci .

N/A I

L REVISED 12/98- INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORf PAGE B-5

o .

6. - TABLE B-4 containz a list of particida compounds includsd in the Texas Surfcca Watsr Quality Sttndards at 30 TAC 307.6. TABLE 13-4 must be completed

-f the f acility manuf actures or for.t.ulates pesticides or herbicides. Complete TABLE B-4 with the results of an analyses for each outfall that contains process wastewater or may contain pesticides or herbicides. Report an average and maximum value if more than one analytical result is available.

X N/A: This facility does not manufacture or formulate pesticides or herbicides.

TABLE B-4 OUTFALL CONCENTRATION NUMBER (ug/l)

• OF MAL POLLUTANT AVG. MAX. SAMPLES fua/11 Aldrin 0.05 Alpha-hexachlorocyclohexane 0.05 Beta-hexachlorocyclohexane . 0.05 Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D 10 Danitol ...

4,4--DDD 0.1 4,4'-DDE 0.1 4,4'-DDT' O1 Demeton 0.2 Diazinon 0.5 Dicofol 20

' Dieldrin 0.1 Diuron ...

Endosulfan I (alpha) 0.1 Endosulfan II (beta) 0.1 Endosulfan Sulfate _ _ . , 0.1 Endrin 0.1 Gamma - Hexachlorocyclohexane 0.05 (Lindane)

Guthion _._ 0.10 Heptachlor 0.05 Heptachlor Epoxide- 1.0 Hexachlorophene 10 Malathion 0.10 methoxychlor 2 Mirex 0

' Parathion 0 Texaphene 5 2,4,5-TP (Silvex) 2 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-6 L

l q

J

'I . Rsvisw th2 following TABLE B-5 and mark tha appropriate column with an "X" <

if you believe a specific constituent to be present or absent in your '

discharge. Rase your determination on your knowledge of raw materials, (

. maintenance chemicals, intermediates, and products handled at your facility )

and/or previous analyses of your wastewater. You must provide the results of l at least one analysis ' for each constituent believed present. Report an I average and maximum value if more than one analytical result is available.

TABLE B-5 OUTFALL 001 CONCENTRATION BELIEVED BELIEVED (mg/1)* NUMBER OF POLLUTANT PRESENT ABSENT &E M&K SAMPLES Bromide X D ag 1 l

Color (PCU) X g_d 1 Nitrate-Nitrite (as N) X 1 Sulfide (as S) X 1 Sulfite (as SO,) X 1 Surfactants X 1 Total Antimony X 4 Total Beryllium X 0.001 0.003 4 Total Boron X 1 Total Cobalt X 1 Total Iron X 0.042 1 Total Magnesium X M i Total Molybdenum X i Total Manganese X 0.014 1 Total Thallium X 4 Total Tin X 1 Total Titanium X 1

• Indicate units if different from ag/1.

I t

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-7

8- Trble 3-6 is a list 'of primary indu2 trial categories with a breakdown of Gas Chromatography / Mass Spactromatry (GC/MS) testing requiramants for Priority Pollutants. Categories ' are defined ir. 40 CFR Parts 400 - 471. Check any category (s) that apply to your facility and provide the indicated analysis ,

for Priority Pollutants listed in Table B-6.

TABLE B-6

, N/A GC/MS Testincr Reauired -

Volatile W Base / Neutral Pesticides 'l Adhesives and Sealants Yes Yes Yes No Aluminum Foming Yes Yes Yes No Auto and Other Laundries Yes Yes Yes Yes Battery Manufacturing Yes No Yes No Coal Mining No No No No Coil Coating Yes Yes Yes No 1 Copper Forming Yes Yes Yes No

-Electric and Electronic Yes Yes Yes Yes Components Electroplating Yes Yes Yes No Explosives Manufacturing No Yes Yes No Foundries Yes Yes Yes No Gum and Nood Chemicals l

Subparts A,B,C,E Yes Yes No No

_ _ Subparts D,F Yes Yes Yes No Inorganic Chemicals- Yes Yes Yes No Iron and Steel Mfg. Yes Yes Yes No Leather Tanning / Finishing Yes Yes Yes No l

Mechanical-Products Mfg. Yes Yes Yes No Nonferrous Metals Mfg. Yes Yes Yes Yes Ore Mining (Subpart B) No Yes- No No Organic Chemicals, Yes Yes Yes Yes l Plastics and Synthetic Fibers I Paint and Ink Formulation Yes Yes Yes No Pesticides Yes Yes Yes Yes l Petroleum Refining Yes Yes Yes No Pharmaceutical Preparations. Yes Yes Yes No Photographic Equipment and Yes Yes Yes No Supplies Plastic Processing Yes No No No Porcelain = Enameling 'No No No No Printing and Publishing Yes Yes Yes Yes Pulp and Paperboard Mills

. Subparts A,B,C,D,R-

• Yes

• Yes Subparts F,G,H,I, Yes Yes

• Yes K,L,M,N,O,P,-

Subparts;E,Q,S,T Yes ~ Yes

• Yes Subparts J,U Yes Yes Yes

• Rubber Processing Yes Yes Yes- No Soap and Detergent Mfg. Yes Yes Yes No

_X ' Steam Electric Power Plants Yes Yes No No Textile Mills(Not Subpart C) Yes Yes Yes No Timber Products. Processing Yes Yes Yes Yes Test if

• believed presenta AEVISED 12/98 INDUSTRIAL NASTEWATER PRRMIT APPLICATI0lt TECistICAL REPORT PAGE B-8

I 9.

Table B-7 contains a list of priority pollutt.nts. If you are a primary industry as shown in Tcblo B-6 and process wastewster is dischargsd, you must analyze for those GC/MS fractions as shown in Table 3-7 If you are not a 3 j

primary industry and if you believe that a specific constituent '(except for:  !

1 acrolein, acrylonitrile, 2,4'_ dinitrophenol, or 2-methyl-4,6 dinitrophenol) is present in an amount greater than 10 ppb you must provide the results of l at.least one analysis. 'If you believe that acrolein, acrylonitrile, 2,4  !

dinitrophenol, or 2-methyl-4,6 dinitrophenol is present in an amount greater j than 100 ppb you must provide results for these chemicals. Base your j

. determination on your ' knowledge of raw materials, maintenance chemicals, j intermediates, and products handled at your facility or analysis of your wastewater. Report an average and a maxinnm value if more than one analytical result is available.

l l

TABLE B-7 I

'OUTFALL 001 CONCENTRATION (4g/l)

• NUMBER OF MAL POLLUTANT AYQ,. E SAMPLES (ua/1) l VOLATILE COMPOUNDS Acrolein 510_. 1 50 ,

Acrylonitrile < 5 0_ . . 1 50 l Benzene <10 1 10 l Bromoform <10 1 10 Carbon Tetrachloride <10 1 10 Chlorodibromomethane <10 1 10  ;

Chloroethane <10 1 10 2-Chloroethylvinyl Ether 1 1 50 Chloroform <10 1 10 Dichlorobromomethane <10 1 10 1,1-Dichloroethane < 10_ 1 10 1,2-Dichloroethane <10. 1 10 i ~1,1-Dichloroethylene <10 1 10 1,2-Dichloropropane <10 1 10 l 1,3-Dichloropropylene <10 1 10 Ethylbenzene <10 1 10 Methyl Bromide <20 1 20 Methyl Chloride <20 1 20 Methyleno Chloride <20 1 20 1,1,2,2-Tetrachloroethane <10 1 10 Tetrachloroethylene, <10 1 10 Toluene <10 1 10 1,2-Trans-Dichloroethylene <10 1 10 1,1,1-Trichloroethane <10 1 10 1,1,2-Trichloroethane <10 1 10 Trichloroethylene <10 1 10 Vinyl Chloride <10. 1 10

+ Indicate units if different from yg/l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-9 i

E -

1 9

TABLE S-7 (cen't)

OUTFALL 001 CONCENTRATION (ug/1)* NUMBER OFMAL POLLUTANT h & SAMPLES fua/1)

ACID COMPOUNDS 2-Chlorophenol

<10 1 10 2,4-Dichlorophenol <10 1 10 2,4-Dimethylphenol <10 1 10 4,6-Dinitro-o-Cresol 2,4-Dinitrophenol sig__ 1 50 l' sig__ 1 50 Nitrophenol <20 1 20 4-Nitrophenol <50 1 50 P-Chloro-m-Cresol <10 1 10 Pentachlorophenol <50 1 50 Phenol slo 1 10 2,4,6-Trichlorophenol <10 1 10 BASE / NEUTRAL COMPOUNDS l

'Acenaphthene 10

-Acenaphthylene 10 Anthracene 10 l Benzidine 50 Benzo (a) Anthracene 10 Benzo (a) Pyrene 10 3,4-Benzofluoranthene 10 l Benzo (ghi)' Perylene 20

- Benzo (k) Fluoranthene 10 Bis (2-Chloroethoxy) Methane 10 Bis (2-Chloroethyl). Ether 10 Bis (2-Chloroisopropyl). Ether 10

. Bis (2-Ethylhexyl) Phthalate- 10 4-Bromophenyl Phenyl Ether 10 Butylbenzyl Phthalate 10 2-Chloronaphthalene 10 4-Chlorophenyl Phenyl Ether 10 Chrysene 10

- Dibenzo (a,h) Anthracene 20

-1,2-Dichlorobenzene 10 1,3-Dichlorobenzene 10 1,4-Dichlorobenzene 10 3,3-Dichlorobenzidine 50 Diethyl Phthalate 10 Dimethyl Phthalate 10 Di~n-Butyl

- Phthalate 10 2,4-Dinitrotoluene 10 2,6-Dinitrotoluene 10 Di-n-Octyl Phthalate. 10 1,2-Diphenyl Hydrazine -

(as Azobenzene)" 20

• - Indicate-units-if different from pg/l REVISED 12/98 IlfDUSTRIAL NASTENATER PRRMIT APPLICATION TEClOf1 CAL REPORT FAGE B-10

p .

TABLE B-7 (ctn't)

OUTFALL 001 CONCENTRATION (49/l)

• NUMBER OF MAL POLLUTANT h MAX. SAMPLES (aa/1) I i

BASE / NEUTRAL COMPOUNDS (con't)- i 1

l Fluoranthene 10

' Fluorene 10 Hexachlorobenzene 10 Hexachlorobutadiene 10 l

Hexachlorocyclopentadiene 10 Hexachloroethane 20 Indeno(1,2,3-cd) pyrene 20 Isophorone 10 Naphthalene 10 Nitrobenzene~ 10 N-Nitrosodimethylamine 20 N-Nitrosodi-n-Propylamine 20 N Nitrosodiphenylamine 20 Phenanthrene 10 Pyrene 10 1,2,4-Trichlorobenzene 10 j PESTICIDES Aldrin 0.05 alpha-BHC 0.05 beta-BHC 0.05 gamma-BHC 0.05 delta-BHC 0.05 Chlordane 0.15 4,4-DDT 0.1 4,4-DDE 0.1 4,4-DDD 0.1 Dieldrin 0.1 l

alpha-Endosulfan. 0.1 beta-Endosulfan 0.1 Endosulfan Sulfate 0.1

! Endrin _

0.1 l Endrin Aldehyde 'O.1

Heptachlor 0.05 Heptachlor Epoxide 1.0 i PCB-1242 1.0 PCB-1254 _ 1.0 PCB-1221 1.0 PCB-17r.3 2 1.0.

PCB-1248 1.0 PCB-1260 1.0 PCB-1016 1.0 Toxaphene 5.0

• Indicate units if different from pg/l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-11 f

e

3. Outfalla thtt contr.in any.wtatswitar othar thin stom wtter (e.g. , process wastewater, utility wastewater, domestic wastewater, groundwater, etc.) must complete TABLE B-1, Facilities that utilize land application or evaporation for wastewater treatment / disposal must also provide these analytical results. .

TABLE Bal OITIFALL 002- Sample Type GRAB X COMPOSITE INFLUENT EFFLUENT CONCENTRATION NUMBER. CONCENTRATION NUMBER (mg/l) OF (mg/1)

OF POLLUTANT & & MAX. SAMPLES && tWL, SatiPJES BOD (5-day) L,21 4 4 CDOD (5-day) H/A_ H/&_ N/A Chemical Oxygen Demand 2,L1 12_, 4 Total Organic Carbon Lg21 M 4 Ammonia Nitrogen 0 0 ,,,,,,i,__,,

Total Suspended Solids gggg Discharae _

Nitrate Nitrogen 0 0 4 Total Organic Nitrogen 0. 823 L.A 4 Tota 1' Phosphorus 0.399 0.497 4

, Oil and Grease ggIg Discharae

. Total Residual "hlorine ZAI2 Disch^rce Total Dissolvsa solids 1A12_ 191D 4

' Sulfate lia._, 253 4

~ Chloride 706.5 25,i.,, 4 Fluoride A.J.li 0.442 4 Fecal Colifonn Ef&_, M/,A_ N/A

-Temperature ('F) 2L,1 78 4 l pH (Standard Units; min / max) R 5.1 L.52 4 EFFLUENT l l

CONCENTRATION NUMBER (ug/1) OF MAL

' POLLIfrANT && H&L, SAMPLES Ag/1 Total Aluminum 54.95 BL2 4 30 Total Antimony 0 0 4 30 Total Arsenic 0 0 4 10

' Total Barium 15L,1 12,'L,2 4 10

. Total Beryllium LD.1 _L.1 4 5 Total Cadmium 0 0 4 1 Total Chromium 0 0 4 10 Trivalent Chromium H& H&_ NA --

Hexavalent Chromium ell, Ed_ NA 10 Total Copper _ _ .

0 0 4 10 Cyanide, (Total, Amenable to Chlorination or weak-Acid Dissociable 0 0 4 20 Total Lead 0 0 4 5 Total Mercury 0 0 4 0.2 Total Nickel 0 0 4 10 Total Phenols L.Qii 0.073 4 20 Total Selenium 0 Q,._ 4 10 Total Silver 0 0 4 2 Total Thallium 0 0 4 10 Total Zinc 6.525 L12_ 4 5 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-3

U+

y 4. TABLE B-2 contains a 'lict of organic compounds included in the Texas Surfica Wttsr. Quality Stcndnrd) at 30 TAC 307.6. TABLE B-2 must be completed with the results of an analysia of all pollutants for each outf all that contains process wastewater. In addition, an analysis for each continuously  ;

discharging nonprocess outfall (including noncontact cooling water) must be provided for only those pollutants in TABLE B-2 that are used at the f acility. as' a feedstock, intermediate, product, byproduct, coproduct, maintenance chemical or that could in any way contribute to contamination in the wastewater streams.

TABLE B-2 OUTFALL 0028*)

CONC. g/l (*I) NUMBER OF MAL POLLUTANT &ZL. M&L, SAMPLES (uo/1)

Benzene s10 1 10 Benzidine 50 Benzo (a) anthracene 10 Benzo (a) pyrene 10 Bis (chloromethyl) ether (*2)

Carbon Tetrachloride si.Q 1 10 Chlorobenzene 11D_. 1 10 Chloroform 11.Q_ 1 10 Chrysene 10 Cresols (*3)

Dibromochloromethane s10 1 10 1,2-Dibromoethane 2 1,4-Dichlorobenzene 10 1,2-Dichloroethane s19 1 10 1,1-Dichloroethylene , ,, 10 .

Fluoride 0.336 0.442 4 500 I Hexachlorobenzene 10 Hexachlorobutadiene 10 Hexachloroethane- .20

' Methyl Ethyl Ketone 50 Nitrobenzene 10 n-Nitrosodiethylamine 20 n-Nitroso-di-n-Butylamine 20 1 PCB's, Total (*4) 1 Pentachlorobenzer:a 20 Pentachlorophenol 50 Phenanthrene 10 Pyridine 20 1,2,4,5-Tetrachlorobenzene 20 Tetrachloroethylene 10 Trichloroethylene 10 1,1,1-Trichloroethane s1D._ 1 10 2,4,F-Trichlorophenol 50

- TTHM (Total Trihalomethanes) 10 vinyl Chloride 11.0 1 10

-(*1) Indicate units if different from ug/l

(*2) Hydrolyses in water will not require applicant to analyze at this time.

(*3) MAL's for Cresolo sp-chloro-m-Cresol 10 ug/l:4,6-Dinitro-o-cresol so ug/ lip-Cresol 10 ug/l

(*4) Total of PCB-1242, PCB-1254, PCB-1221, PCB 1232, PCD-1248, PCB-1260, PCB-1016.

(a). See note on_Outfall 001, Page B-4 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-4

5. TABLE B-3 contcinS tS0 ting rSquirtmente for the compound "Tributyltin" and for the indicator b ctr.ric "cntsrococci . " Not . all applicanto era rsquirsd to test for tributyltin or enterococci. Testing is required only under the following conditions:

A. TRIBtfrYLTIN Testing will be required for 1) industrial / commercial facilities which directly dispose of wastewater from the types of operations listed below OR 2) domestic facilities which' receive wastewater from the types of industrial / commercial operations listed below. Please check all that apply.

1) ' Manufacturers and formulators of tributyltin or related compounds, including, but not limited to SIC code 2879. Testing required.

2) Painting of ships, boats and marine structures, including, but not ,

limited to SIC code 1721. Testing required.

l

3) Ship and boat building and repairing, including, but not limited to SIC codes 3731, 3732 and 3441. Testing required.

4) Ship and boat cleaning, esivage, wrecking and scaling, including, but not limited to SIC codes 4499_and 7699. Testing required.

5) Operation and maintenance of marine cargo hand:ing facilities and marinas, including, but not limited to SIC coden 4491 and 4493.

Testing required.

6) Facilities engaged in wood preserving, including, but not limited to, SIC code 2491. Testing required.

7) Any other industrial / commercial facility for which tributyltin is known to be present, or for.which there is any reason to believe that tributyltin may be present in the effluent. Testing required.

1 8) None of the above. No testing required.

B. ENTEROCOCCI Testing will be required for all dischargers directly into the Houston Ship Channel (classified stream segment nos. 1006 or 1007). Please check all that apply-1). Discharge is directly to the Houston Ship Channel (classified  !

stream segment number 1006 or 1007). Testing required.  !

l JL, 2) Discharge is not directly to the Houston Ship Channel (classified stream segment number 1006 or 1007). No testing required.  !

TABLE B-3  !

OUTFALL Concentration NUMBER OF MAL POLLITIANT E tgL, 11g115 SAMPLES (ua/1) {

'Tributyltin 0.010

? Enterococci N/A i

= REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-5

, s

]

w .__

6.

TABLE B-4 contains a liot of pasticida compounds includsd in tha Texas Surfeca Witar Quality Sts.ndards at 30 TAC 307.6. TABLE 13-4 must be completed

-f the facility manufactures or fomulates pesticides or herbicides. Complete TABLE B-4 with the results of an' analyses'for each outfall that contains process wastewater or may contain pesticides or herbicides. Report an average and maximum value if more than one analytical. result is available.

X N/As-This facility does not manufacture or formulate pesticides or herbicides.

TABLE B-4

.OUTFALL CONCENTRATION NUMBER (99/1)* OF MAL POLLifrAN.T &E. M&L. SAMPLES ,,(uq / l)

Aldrin 0.05 Alpha-hexachlorocyclohexane -

. . , _ . _ 0.05 Beta-hexachlorocyclohexane 0.05 Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D _

10

-Danitol ...

4,4--DDD 0.1 4,4'-DDR 0.1 4,4'-DDT 0.1 Demeton 0.2 Diazinon 0.5 Dicofol' 20 Dieldrin 0.1 Diuron ...

Endosulfan I (alpha) 0.1 Endosulfan II.(beta) 0.1 Endosulfan Sulfate 0.1 Endrin 0.1 Gamma - Hexachlorocyclohexane 0.05 (Lindane)

Guthion 0.10 Heptachlor 0.05 Heptachlor Epoxide 10

-Hexachlorophene . 10 Malathion' O.10 1

methoxychlor 2 Mirex __ 0 Parathion 0 Toxaphene 5 2,4,5-TP (Silvex) 2 l

ARVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT FAGE B.6 i

l i

r;

]

l 4

'l

1. Ravicw tha following TABLE B-5 and mark tha approprista column with an "X" if you believe a specific constituent to be present or absent in your discharge. Rase your determination on your knowledge of raw materials, maintenance chemicals, intermediates, and products handled at your facility and/or previous analyses of your wastewater. You must provide the results of at least one analysis for each constituent believed present. Report an 4 average and maximum value if more than one analytical result is available.

TABLE B-5 OUTFALL 002 CONCENTRATION BELIEVED BELIEVED (mg/1)* NUMBER OF POLLUTANT PRESENT M R M&K SAMPLES Bromide X Liq 1 Color (PCU) X 5.d., 1 Nitrate-Nitrite- (as N) X 1 Sulfide (as S) X 1 Sulfite (as SO,) X 1 Surfactants X 1 _

Total Antimony X 4 Total Beryllium .

X 0.002 0.004 4 Total Boron X L,51 1 Total Cobalt X 1 Total Iron X 0.044 1 Total Magnesium X iLi 1 Total Molybdenum _ X 1 Total Manganese X 0.013 i Total Thallium X 4 Total Tin X 1 Total Titanium X 1

• Indicate units if different frosa ag/1.

1 i

REVISED 12/fr8 INDUSTRIAI, WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-7 L

y ,

8-Table 3-6 is n'lict of primary industrial cattgories with a breakdown of Gas.

l

_ Chromatogrcphy/Mt03 Sp1ctrometry (GC/MS) testing rsquiramants'for Priority Pollutants. Categories are defined in 40 CFR Parts 400 - 471. Check any j

- category (s) that apply to' your, facility and provide the indicated analysis j for Priority Pollutants listed in~ Table B-6. 1

, TABLE B-6 '

N/A. GC/MS Testina Reauired Volatile &cid Base / Neutral Pesticides Adhesives and Sealants Yes Yes Yes No Aluminum Forming Yes Yes Yes No

Auto and Other Laundries Yes Yes Yes Yes Battery Manufacturing Yes No Yes No

' Coal Mining No No No No Coil Coating Yes Yes- Yes No l Copper Forming Yes Yes Yes ' No Electric and Electronic Yes Yes Yes Yes Components l Electroplating Yes des Yes No I

Explosives Manufacturing No Yes Yes- No Foundries Yes Yes Yes No Gum and Wood Chemicals l _ Subparts A,B,C,E Yes Yes ' No No Subparts D,F Yes Yes Yes No Inorganic Chemicals Yes Yes Yes No Iron and Steel Mfg. Yes Yes Yes No l Leather Tanning / Finishing Yes Yes -Yes No Mechanical. Products Mfg. Yes ' Yes Yes No Nonferrous Metals Mfg. Yes Yes Yes Yes Ore Mining (Subpart.B) NoYes No No Organic Chemicals, . Yes Yes Yes Yes Plastics and Synthetic Fibers Paint and Ink Formulation Yes Yes Yes No Pesticides Yes . Yes Yes Yes Petroleum Refining Yes Yes Yes No Pharmaceutical Preparations Yes Yes Yes No Photographic Equipment _and Yes Yes Yes No Supplies Plastic Processing Yes No No No Porcelain Enameling No No No No Printing and Publishing Yes Yes Yes Yes Pulp and Paperboard Mills Subparts A,B,C,D,R

• Yes

• Yes Subparts F,G,N,I, -Yes Yes

• Yes K,L,M,N,0,P, Subparts E,Q,S,T Yes Yes

• Yes l i Subparts J,U Yes Yes Yes

• l Rubber; Processing. -Yes Yes Yes No

-Soap and Detergent Mfg. Yes Yes Yes No L Steam Electric Power Plants Yer Yes No No Textile Mills (Not Subpart C) Yes -Yes Yes No Timber Products Processing Yes Yes Yes Yes Test'if " believed present"

^RavIsso 12/se. zwoosTRIAL uAsTEWATER PERMIT APPLICATION TEClOf1 CAL REPORT PAGE B-8 L

9. Tcble B-7 contains a list of ' priority pollutants. If you are a primary indu try cs rhown in Tcble B-6 cnd procus wastawitor is discharged, you must analyze for those GC/MS fractions as shown in Table 3-7. If you are not a primary industry and if you believe that a specific constituent (except for acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol) i is present in an amount greater than 10 ppb you must provide the results of at least one analysis. If you believe that acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol is present in an amount greater than 100 ppb you - must provide results for these chemicals. Base your determination on your knowledge of raw materials, maintenance chemicals, intermediates, and products handled at your facility or analysis of your wastewater. Report an average and a maximum value if more than one analytical result is available.

TABLE B-7 OUTFALL 002 CONCENTRATION (ug/l)

• NUMBER OF MAL POLLUTANT E M&L. SAMPLES 0;o/1) I VOLATILE COMPOUNDS l I

Acrolein <50 1 50 Acrylonitrile sji L , 1 50

]

Benzene <10 1 10 )

Bromoform <10 1 10 Carbon Tetrachloride <10 1 10 Chlorobenzene <10 1 10 Chlorodibromomethane <10 1 10 Chloroethane <10 1 .10 2-Chloroethylvinyl Ether <50 1 50 Chloroforn <10 1 10  !

Dichlorobromomethane <10 1 10 1,1-Dichloroethane <10 1 10 1,2-Dichloroethane <10 1 10 l,1-Dichloroethylene <10 1 10 1,2-Dichloropropane <10 1 10 1,3-Dichloropropylene- <10 1 10 Ethylbenzene <10 1 10 Methyl Bromide <20 1 20 Methyl Chloride s2dL 1 20 Methylene Chloride s2L 1 20 1,1,2,2-Tetrachloroethane 4 1 10 j Tetrachloroethylene, _djjL i 10 Toluene s1L i 10 1,2-Trans-Dichloroethylene s1L i 10 1,1,1-Trachloroethane s1Q_ 1 10 1,1,2-Trichloroethane 510 1 10 Trichloroethylene s1L _ 1 10 vinyl Chloride s1L i 10

• Indicate units if different from g/l REVISED 12/98 INDUSTRIA!,NASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-9 i

L _

i

TABLE B-7 (con't)

(

OUTFALL 002 CONCENTRATION

( g/1)* NUMBER OFMAL POLLUTANT h IBL, SAMPLES (ua/1) .

ACID' COMPOUNDS '

2-Chlorophenol <10 1 10 2,4-Dichlorophenol <10 1 10 2,4-Dimethylphenol <10 1 10 4,6-Dinitro-o-Cresol SEQ __ 1 50 2,4-Dinitrophenol <50 . 1 50 2-Nitrophenol <20 1 20 4-Nitrophenol s1Q.__ 1 50 .

P-Chloro-m-Cresol <10 1 10 /

Pentachlorophenol <50 1 50 Phenol <10 1 10 2,4,6-Trichlorophenol <10 1 10 .

}

BASE / NEUTRAL COMPOUNDS A"enaphthene 10 Acenaphthylene 10 Anthracene 10 Benzidine 50 Benzo (a) Anthracene 10 Benzo (a) Pyrene 10 3,4-Benzofluoranthene 10 Benzo (ghi) Perylene 20 Benzo (k) Fluoranthene 10 Bis (2-Chloroethoxy) Methane 10 Bis (2-Chloroethyl) Ether 10 Bis (2-Chloroisopropyl) Ether 10 Bis (2-Ethylhexyl) Phthalate 10 4-Bromophenyl Phenyl Ether 10 Butylbenzyl Phthalate 10 2-Chloronaphthalene 10 4-Chlorophenyl Phenyl Ether 10 Chrysene 10 Dibenzo (a,h) Anthracene 20 1,2-Dichlorobenzene 10 1,3-Dichlorobenzene 10 1,4-Dichlorobenzene 10 3,3-Dichlorobenzidine 50 Diethyl Phthalate 10 Dimethyl Phthalate 10 Di-n-Butyl Phthalate' 10 i 2,4-Dinitrotoluene 10 2,6-Dinitrotoluene 10 Di-n-Octyl Phthalate 10 1,2-Diphenyl Hydrazine (as Azobenzene) 20

• Indicate units if different from ug/l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-10

/

m .

l

, TABLE B-7 (con't)

OUTFALL 002 CONCENTRATION (pg/1)

• NUMBER OF- MAL POLLUTANT AYL. MAX. SAMPLES fua/1)

BASE / NEUTRAL COMPOUNDS (con't)

Fluoranthene 10 i Fluorene- 10 Hexachlorobenzene 10 Hexachlorobutadiene 10 l Hexachlorocyclopentadiene' 10 I Hexachloroethane 20 Indeno(1,2,3-cd) pyrene 20 Isophorone .

10 Naphthalene 10 Nitrobenzene 10 N-Nitrosodimethylamine 20 N-Nitrosodi-n-Propylamine 20 N-Nitrosodiphenylamine 20 Phenanthrene 10 Pyrene 10 l 1,2,4-Trichlorobenzene 10 l PESTICIDES ,

l Aldrin 0.05 l alpha-BHC 0.05 beta-BHC 0.05 1 gamma-BHC 0.05  ;

delta-BHC 0.05 j Chlordane 0.15 4,4-DDT 0.1 4,4-DDE 0.1 3 4,4-DDD 0.1

• Dieldrin 0.1 alpha-Endosulfan 0.1 beta-Endoculfan 0.1 Endosulfan Sulfate 0.1 j Endrin' O.1 I Endrin Aldehyde 0.1 l

Heptachlor 0.05 l Heptachlor Spoxide 1.0 l

.PCB-1242 1.0 i PCB-1254 1.0 l PCB-1221 1.0 .'

~PCB-1232 1.0 PCB-1248 1.0 I

.PCB-1260 1.0-  !

I PCB-1016l 1.O l

!- Toxaphene 5.0

• -' ' Indicate units if different from yg/l i

i-  !

'kEVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECleIICAL REPORT PAGE B-11 l

f l'

~

fI 3. Outfalls that contein any wantswater other thtn storm water (e.g., process l wastewater,. utility wastewater, domestic' wastewater, groundwater, etc.) must V . complete TABLE B-1. Facilities that utilize land application or evaporation for I  : wastewater treatment / disposal must also provide these analytical results.

i 1 l TABLE B.1 OUTFALL 003 Sample Type: ' GRAB X COMPOSITE INFLUENT iFFLUENT g CONCENTRATION NUMBER CONCENTRATION NUMBER (mg/1) OF (mg/1)

OF POLLtNANT && H&L, SAMPLES && H&L. SAMPLES BOD (5-day) .R 1,(L _ 16 CBOD '(5-day) N/&,_- HZ&,,, N/A Chemical Oxygen Demand 1 25 340 4 Total' Organic Carbon 2.J8._ 7.7 4 Ammonia Nitrogen L.125 0.218 4 Tota 1' Suspended Solids Li_,_ 22_,,, 16 Nitrate Nitrogen 2Li RL.Q 4 Total Organic Nitrogen 1.825 L.2 4 Total Phosphorus 1L.2 1L2 4 Oil and Grease L.121 1LQ 4 Total Residual Chlorine *H/.&

. H/,,& N/A Total Dissolved Solids 311 _ Ag2 4 Sulfate 69.35 2L.i._ 4 Chloride 1 & 28 102.0 4

,. Fluoride 0.164 0.279 4 Fecal Coliform' 12 0 2.2 4 L

Temperature ('F).

L 71 4 pH (Standard Units; min / max) 2.d2 2.jil 16 EFFLUENT CONCENTRATION NUMBER (ug/1) OF ' MAL P0f7f1 TANT &E H&L. SAMPLES ggil Total Aluminum 44.03 EL1 4 30 Total Antimony 0 0 4 30 Total Arsenic 0 0 4 10 Total Barium AL2 15.d._ 4 10 l

Total Beryllium 0 0 4 5 Total Cadmium 0 0 4 1 Total Chromium 0 0 4 10 Trivalent Chromium H&._ H& NA --

Hexavalent Chromium NL H&._ NA 10 Total Copper' 2L.9.2 22.Ji 4 10 Cyanide, (Total, Amenable to Chlorination or weak-Acid Dissociable 0 0 4 20 Total Lead 0 0 4 5 Total Mercury L.122 0.206 4 0.2 Total Nickel. 0 0 4 10 Total-Phenols 0.019 0.061 4 20

' Total Selenium 0 0 4 10

' Total Silver 0 0 4 2 L Total Thallium 0 0 4 10

! Total' Zinc ~ 197.25 221.0 4 5

/ *0utfall 003 utilizes Ultra violet disinfection (See Attachment 1, item 1 for details.)

fical conh pr no ml. (C FWs),

i , REVISED 12/98 . INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-3

/

r

4. TABLE B-2 contains a 'ligt of organic compounds includsd in the Texas Surface Water Quality Standards at 30 TAC 307.6. TABLE B-2 must be completed with the results of an analysis of all pollutants for each outfall that contains process wastewater. In addition, an analysis for each continuously  ;

discharging nonprocess outfall (including noncontact cooling water) must be provided for only those pollutants in TABLE B-2 that are used at the facility as a feedstock, intermediate, product, byproduct, coproduct, j

maintenance chemical or that could in any way contribute to contamination in the wastewater streams.

TABLE B-2 OUTFALL 003W CONC. ug/l (*I) NUMBER OF MAL j

POLLUTANT h [21, SAMPLES (uq/l) l Benzene s.l.Q_ 1 10 l Benzidine 50 Benzo (a) anthracene 10 Benzo (a) pyrene 10 j Bis (chloromethyl) ether (*2)  :

Carbon Tetrachloride $10._ 1 10 l Chlorobenzene s.EL. 1 10 Chloroform 110_ 1 10 Chrysene 10 Cresols (*3)  ;

Dibromochloromethane 510_ 1 10 j 1,2-Dibromoethane 2 1,4-Dichlorobenzene 10 1,2-Dichloroethane 510_ i 10 1,1-Dichloroethylene 10 Fluoride 0.164 0.279 4 500 j Hexachlorobenzene 10 l Hexachlorobutadiene 10 j Hexachloroethane 20 l Methyl Ethyl Ketone 50 j Nitrobenzene 10 i n-Nitrosodiethylamine 20 l n-Nitroso-di-n-Butylamine 20 j PCB's, Total (*4) 1 l

Pentachlorobenzene 20 l Pentachlorophenol 50 i Phenanthrene 10 l Pyridine 20 l 1,2,4,5-Tetrachlorobenzene 20  !

Tetrachloroethylene 10 l Trichloroethylene 10 l

1,1,1-Trichloroethane s10_ 1 10 j 2,4,S-Trichlorophenol 50 j TTHM (Total Trihalomethanes) 10 ,

Vinyl Chloride s1Q_ 1 10 l

(*1) Indicate units if different from ug/l

(*2) Hydrolyzes in water, will not require applicant to analyze at this time.

(*3) MAL's for Cresolssp-Chloro-m-Cresol 10 pg/ise,6-Dinitro-o-Cresol SO ug/1;p-Cresol 10 ug/l

(+4) Total of PCB-1242, PCB-1254, PCB-1221, PCB-1232, PCB-1248, PCB-1260, PCB-1016. l I

(a) See note on Outfall 001, Page B-4 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-4 <

i I L l

i .

?

'S. TABLE B-3 contains testing rsquircments for tha compound "Tributyltin" and for the indicator brctaria *antarococci " Not all applicants are requir&d to test for tributyltin or enterococci. Testing is required only under the following conditions A. TRIBUTYLTIN Testing will be required for 1) industrial / commercial facilities which directly dispose of wastewater from the types of operations listed below OR 2) domestic facilitier which receive wastewater from the types of industrial / commercial' operations listed below. Please check all that apply.

1) Manufacturers and formulators of tributyltin or related compounds, including, but not limited to SIC code 2879. Testing required.

2) Painting of ships, boats and marine structures, including, but not limited to SIC code 1721. Testing required.

3) Ship and boat building and repairing, including, but not. limited to SIC codes 3731, 3732 and 3441. Testing required.

4) Ship and boat' cleaning, salvage, wrecking and scaling, including, but not limited to SIC codes 4499 and 7699. Testing required.

5) Operation and maintenance of marine cargo handling facilities and marinas, including, but not limited to SIC codes 4491 and 4493.

Testing required.

6) Facilities engaged in wood preserving, including, but not limited to, SIC code 2491. Testing required.

7) Any other industrial / commercial facility for which tributyltin is known to be present, or for which there is any reason to believe that tributyltin may be present in the effluent. Testing required.

X 8) None of the above. No testing required.

.B. ENTEROCOCCI Testing will be required for all dischargers directly into the Houston Ship Channel (classified stream segment nos.'1006 or 1007). Please check all that apply

1) Discharge is directly to the Houston Ship Channel (classified stream segment number 1006 or 1007) . Testing required.

X 2)- Discharge is not directly to the Houston Ship Channel (classified stream segment number 1006 or 1007). No testing required.

TABLE B-3 OUTFALL l Concentration NUMBER OF MAL POLLUTANT &yl, lE Unita SAMPLES (ua/1)

Tributyltin 0.010

. Enterococci N/A

' REVISED 12/90 INDUSTRIAL WASTEMATER PERMIT APPLICATION TECIDEICAL REPORT PAGE B-5 t

l t

lT1 . . . . . . . . . . . . .....: .

p

6. TABLE B-4 ' contains a list of pasticida compounds includsd, in the Texas surfaca WLter Quality Standards' at 30 TAC 307.6. TABLE 13-4 must be completed

-f the facility manufactures or-formulates pesticides or herbicides. Complete TABLE B-4 with the results of-an analyses for each outfall that contains process wastewater or may contain pesticides or herbicides. Report an average and maximum value if more than one analytical result is available. I 1

X N/A: This facility does not manufacture or formulate pesticides or herbicides.

TABLE B-4 OUTFALL CONCENTRATION NUMBER

( g/1)* OF MAL POLLUTANT AVG. MAL. SAMPLES fao/11 Aldrin 0.05 Alpha-hexachlorocyclohexane 0.05 Beta-hexachlorocyclohexane 0.05 l Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D 10 Danitol ---

4,4--DDD 0.1 ,

4,4'-DDE 0.1 4,4'-DDT _. 0.1 Demeton 0.2 Diazinon 0.5 Dicofol 20 i Dieldrin 0.1 Diuron ---

Endosulfan I (alpha) 0.1

~ Endosulfan II (beta) 0.1

'vidosulfan Sulfate 0.1 Endrin 0.1 Gamma - Hexachlorocyclohexane 0.05 (Lindane)

Guthion' O.10 Heptachlor .

0.05 Heptachlor Epoxide 1.0 Hexachlorophene 10 Malathion 0.10 methoxychlor 2 Mirex 0 Parathion 0 Texaphene 5 2,4,5-TP (Silvex) 2 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-6 L.

]

r-a . . .

L7. :Ravisw-tha.following TABLE B-51and mark the appropriate column.with an "X" if; you believe a specific constituent to be present or ' absent in your  ;

discharge. Rase "your , determination on your knowledge of raw ' materials, maintenance chemicals, intermediates, and products. handled at your facility 1 and/or previous analyses of your' wastewater. You must provide the results of )

.at. -least one analysis for each ! constituent believed present. Report an

~

l L

average and maximum value'if more than one analytical result is available. 'l TABLE B-5 OUTFALL 003 CONCENTRATION-

' BELIEVED BELIEVED (mg/l)* NUMBER OF POLLUTANT PRESENT ABSENT h M&X SAMPLES Bromide X 0.01 1 Color (PCU): X 3.1._ 1 Nitrate-Nitrite (as N) X fM 1 l

Sulfide . (as S) X 1 '

Sulfite (as.SO,) X- 1 j Surfactants. X 1 Total Antimony- X 4 Total. Beryllium X 4 Total Boron X M i Total Cobalt X 1 Total' Iron X 0.095 1 Total Magnesium X 14.40 1 Total Molybdenum X 1

> Total Mar ganese . X 9 008 1 Total Thallium X 4 Total-Tin X '1 Totial - Titanium . X 1

• Indicate units if different from ag/1.

l t

l

- REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT AFPLICATION TECIGIICAL REPORT FAGE B-7 b

'8 Table 3-6 is a list of primary industrial categories with a breakdown of Gas Chromatography / Mass Spectrometry (GC/MS) testing requirements for Priority Pollutants. Categories 'are defined in 40 CFR Parts 400 - 471. Check any category (s) that apply to your facility and provide the indicated analysis for Priority Pollutants listed in Table B-6.

TABLE B-6 N/A GC/MS Testino Reauired l'

Volatile Ag.id Base / Neutral Pesticidgg Adhesives and Sealants Yes Yes Yes No Aluminum Forming Yes Yes Yes No Auto and Other Laundries Yes Yes Yes Yes Battery Manufacturing Yes No Yes No Coal _ Mining No No No No Coil Coating Yes Yes Yes No Copper Forming Yes Yes Yes No Electric and Electronic Yes Yes Yes Yes Components-Electroplating Yes Yes Yes No

. Explosives Manufacturing No Yes Yes No Foundries Yes Yes Yes No Gum and Wood Chemicals Subparts'A,B,C,E Yes Yes No No ,

Subparts D,F Yes Yes Yes No

-Inorganic Chemicals Yes Yes Yes No Iron and Steel Mfg. Yes Yes Yes No Leather Tanning / Finishing Yes Yes Yes No Mechanical Products Mfg. Yes Yes Yes No Nonferrous Metals Mfg. Yes Yes Yes Yes Ore Mining (Subpart B) No Yes No No Organic Chemicals, Yes Yes Yes Yes Plastics and Synthetic Fibers Paint and Ink Formulation Yes Yes Yes No Pesticides Yes Yes Yes Yes Petroleum Refining Yes Yes Yes No Pharmaceutical Preparations Yes Yes Yes No Photographic Equipment and Yes Yes Yes No Supplieu Plastic Processing Yes No No No Porcelain Enameling No No No No Printing and Publishing Yes Yes Yes Yes Pulp and Paperboard Mills Subparts A,B,C,D,R

• Yes

• Yes Yes Yes

• Yes Subparts F,G,H,I, K,L,M,N,O,P, Subparts E,Q,S,T Yes Yes

• Yes Subparts J,U Yes Yes Yes

• Rubber Processing Yes Yes Yes No Soap and Detergent Mfg. Yes Yes Yes No X Steam Electric Power Plants Yes Yes No No Textile Mills (Not Subpart C) Yes Yes Yes No Timber Products Processing Yes Yes Yes Yes Test if " believed present" REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-8

.s_.

j

9. Table B-7 contains a list of priority pollutants. If you are a primary industry as shown in Table B-6 and process wastewater is discharged, you must analyze for those GC/MS fractions as shown in Table 3-7. If you are not a q

primary industry and if you believe that a specific constituent (except for: j acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol) )

-is present in an amount greater than 10 ppb you must provide the results of j at least one analysis. If you believe that acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol is present in an amount greater I than 100 ppb you must provide results for these chemicals. Base your i determination on your knowledge of raw materials, maintenance chemicals, intennediates , and products handled at your facility or analysis of your  !

wastewater. Report an average and a maximum value if more than one analytical result is available.

TABLE B-7 OUTFALL 003 CONCENTRATION (ug/1)

• NUMBER OF MAL POLLUTANT AVG. 1G1. SAMPLES fua/1)

VOLATILE COMPOUNDS Acrolein <50 1 50 Acrylonitrile 110._ 1 50 Benzene <10 1 10 Bromoform <10 1 10 Carbon Tetrachloride <10 1 10  !

Chlorobenzene <10 1 10 Chlorodibromomethane <10 1 10 Chloroethane <10 1 10 2-Chloroethylvinyl Ether s10 _. 1 50 Chloroform <10 1 10 '

Dichlorobromomethane < 10 ... . 1 10 1,1-Dichloroethane <10 1 10 1,2-Dichloroethane <10 1 10 1,1-Dichloroethylene <10 1 10 1,2-Dichloropropane <10 1 10 1,3-Dichloropropylene <10 . 1 10 Ethylbenzene <10 1 10 Methyl Bromide <20 1 20 Methyl Chloride s2J1 1 20 Methylene chloride s2.Q 1 20 1,1,2 2-Tetrachloroethane s_1.Q 1 10 Tetrachloroethylene, s1.D._. 1 10 Toluene s10 1 10 1,2-Trans-Dichloroethylene s1Q 1 10 1,1,'l-Trichloroethane s1D_. 1 10 1,1,2-Trichloroethane 51Q_. 1 10 i

Trichloroethylene s10._ 1 10 Vinyl Chloride s1D_. 1 10

• Indicate units if different from g/l i

REVISED 12/90 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-9

[

u

m s

l ,

TABLE B-7,(con't) i OUTFALL 002 l

CONCENTRATION l (49/l)* NUMBER OFMAL POLLUTANT &YG. M&K. SAMPLES fau/1) p.

ACID COMPOUNDS 2-Chlorophenol <10 1 10 2,4-Dichlorophenol <10 1 10 2,4-Dimethylphenol <10 1 10 4,6-Dinitro-o-Cresol <50 1 50

.2,4-Dinitrophenol 1 <50 1 50 2-Nitrophenol <20 1 20

.4-Nitrophenol. <50 1 50 P-Chloro-m-Cresol' <10 1 10 Pentachlorophenol. <50 1 50 Phenol. .

<10 1 10 2,4,6-Trichlorophenol <10 1 10 BASE / NEUTRAL COMPOUNDS Acenaphthene 10 Acenaphthylene 10 Anthracene 10 Benzidine 50

. Benzo (a) Anthracene 10 Benzo-(a) Pyrene 10 3,4-Benzofluoranthene 10

Benzo (ghi) Perylene . 20 Benzo (k) Fluoranthene __ 10 Bis.(2-Chloroethoxy) Methane _ _ _ _ _ 10 Bis . (2-Chloroethyl) Erder . 10 Bis (2-Chloroison-spyl) Ether 10 Bis - (2-Ethylhexyl) Phthalate. 10 4-Bromophenyl Phenyl Ether 10 Butylbenzyl Phthalate 10 2-Chloronaphthalene' 10 4-Chlorophenyl Phenyl Ether 10 Chrysene. _ 10 Dibenzo (a'h) Anthracene

, 20 1,2-Dichlorobenzene 10 1,3-Dichlorobenzene 10 1,4-Dichlorobenzene 10 3,3-Dichlorobensidine 50 Diethyl Phthalate 10 Dimethyl-Phthalate 10 Di-n-Butyl Phthalate. 10

-2,4-Dinitrotoluene 10 2,6-Dinitrotoluene -

10 Di-n-Octyl Phthalate' 10 1,2-Diphenyl.Hydrazine g (as Azobenzene) 20 l-

l. ~*I Indicate units if different from pg/l i

PAGE B-10 E REVISED 12/98. . INDUSTRIAL NAma =ATER PERMIT APPLICATION TECHNICAL REPORT

, 1 ka.

F l , TABLE B-7 (con't)

OUTFALL 003 CONCENTRATION (ug/1)

• NUMBER O? MAL POLLUTANT E & SAMPLES (no/1) i BASE / NEUTRAL COMPOUNDS (con't)

Fluoranthene 10 i Fluorene "0 Hexachlorobenzene 10 i Hexachlorobutadiene 10  !

Hexachlorocyclopentadiene 10 Hexachloroethane 20 Indeno(1,2,3-cd) pyrene 20

-Isophorone 10 Naphthalene 10 Nitrobenzene 10 l N-Nitrosodimethylamine 20 l N-Nitrosodi-n-Propylamine 20 N-Nitrosodiphenylamine 20 Phenanthrene 10 Pyrene 10 1,2,4-Trichlorobenzene 10 PESTICIDES Aldrin 0.05 alpha-BHC 0.05 beta-BHC 0.05 gamma-BHC 0.05 delta-BHC 0.05 Chlordane 0.15 4,4-DDT 0.1 4,4-DDE 0.1 4,4-DDD 0.1 Dieldrin 0.1 alpha-Endosulfan 0.1 beta-Endosulfan _ 0.1 Endosulfan Sulfate 0.1 Endrin 0.1 Endrin Aldehyde 0.1 Heptachlor 0.05 Hepachlor Epoxide 1.0 PCB-1242 1.0 PCB-1254 , 1.0 PCB-1221 1.0 PCB-1232 1.0 PCB-1248 1.0 PCB-1260 1.0 l

PCB-1016 1.0 Texaphene 5.0

'

• Indicate ur.its if different from yg/l l

l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-11 L-

3. Outfalls that contain any wastawster othar than storm water St.g., process wastewater, utility wastewater, domestic wastewater, groundwater, etc.) must '

complete TABLE B-1.: Facilities that utilize land application or evaporation for wastewater treatment / disposal must also provide these analytical results, {

1 l

TABLE B-1 OUTFALL 004 Sample Type: GRAB X COMPOSITE INFLUENT EFFLUENT CONCENTRATION NUMBER CONCENTRATION NUMBER l (mg/1) OF (mg/1)  ;

OF j PouMANT &EL HE SAMPLES &EL M&L. SAMPLES BOD (5-day). 2_,__, 3 4 CBOD (5-day) N/,A_ N/JL N/A Chemical Oxygen Demand 21.13 2L1 4 Total Organic Carbon f.d2_ L.11 4 Anunonia Nitrogen - 9 dil LL, 4-

. Total Suspended Solids Lai,_ 2L,2.,_ 112 Nitrate Nitrogen 0.068 Om.12 4 l

Total Organic Nitrogen 0.87 1.J 4 i Total Phosphorus' Lail 0.081 4 Oil and Grease. id _ 1L,,_ 112

, Total Residual Chlorine HZA,_ , H/.A N/A Total Dissolved Solids 12.1[L 2212 4 Sulfate 393.25 438.0 4 Chloride 122 , 2,2,[L 4 Fluoride - 9.d22 0.384 4 Fecal Coliform H/ L H/jL N/A Temperature ('F) iLi 70 4 pH (Standard Units; min / max) 2,dt L2,Q 112 EFFLUENT CONCENTRATION NUMBER (ug/1) OF MAL POf.f.f FTANT &yL, HE SAMPLES gg/_1 Total Aluminum 0 0 4 30 Total Antimony 0 0 4 30 Total Arsenic 0 0 4 10

' Total Barium M lib,2 4 10 Total Beryllium L2_,,, L1 4 5 Total Cadmium 1.d__ 21d 4 1

' Total Chromium 0 0 4 10 Trivalent Chromium H&_ H& NA --

Hexavalent Chromium HL. H&_ NA 10 Total Copper . 0 0 4 10 1

Cyanide,.(Total, Amenable to Chlorina' tion or weak-Acid Dissociable 0 0 4 20

.. Total Lead' O O 4 5 Total Mercury 0 0 4 0.2 Total Nickel 0 0 4 10 j Total Phenols 0.018 0.058 4 20

Total Selenium 0 0 4 10 1

Total Silver 0 0 4 2 j . Total Thallium 2,.d R 4 10 l' Total Zine 1.11 lid a 5 I

I. REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE.B-3 l '.:

r. ~ . 1 1

+1

4. [ TABLE B-2 contains 's ' list ' of organic compounds includsd in the Texas Surface Water Quality Standards at 30 TAC 307.6. TABLE.B-2 must be completed with thel results of' an analysis of all pollutants for each outfall that-contains process wastewater. In addition, an analysis'for each continuously

' discharging nonprocess outfall (including noncontact cooling water) must be provided . for only those ' pollutants .in TABLE B-2 that are used at the facility as' a feedstock,- intermediate, product, byproduct, coproduct, maintenance chemicalcor that could in any way contribute to contamination in the wastewater streams.

TABLE B-2

'OUTFALL 001W CONC. yg/l (*I) NUMBER OF MAL POLLUTANT h t&lk SAMPLES (ac/1)

Benzene 51D._ 1 10 Benzidine. 50 g

' Benzo (a). anthracene 10  ;

Benzo (a) pyrene . 10 - i' Bis (chloromethyl) ether (*2).

Carbon Tetrachloride sig_ 1 10-Chlorobenzene s.l.Q._ 1 10

' Chloroform 11D 1 10 Chrysene 10 i

-Cresols (*3)

Dibromochloromethane s19 1 10 1,2-Dibromoethane- 2 1,4-Dichlorobenzene 10 l 1,2-Dichloroethane s12 1 10

<1,1-Dichloroethylene 10 j Fluoride- 9.,d11 0.384 4 500 Hexachlorobenzene- 10 Hexachlorobutadiene ~

10 Hexachloroethane 20-Methyl Ethyl Ketone 50 Nitrobenzene, 10

n-Nitrosodiethylamine 20 n-Nitroso-di-n-Butylamine 20 PCB's, Total (*4) 1 Pentachlorobenzene 20

Pentachlorophenol 50 Phenanthrene 10 Pyridine 20 1,2,4,5-Tetrachlorobenzene 20 Tetrachloroethylene 10 Trichloroethylene 10 "1,1,1-Trichloroethane <10_ 1 10 2,4,S-Trichlorophenol 50 TTHM (Total Trihalomethanes) 10 Vinyl Chloride s12 1 10

(*1) Indicate units if different from pg/l

(*2) Hydrolyses in water, will not require applicant to analyse at this time.

(+3) MAL's for Cresola sp-Chloro-m-Cresol 10 ug/l:4,6-Dinitro-o-Cresol so ug/1;p-Cresol 10 ug/l

(*4) Total of PCS-1242, PCB-1254 PCB 1221, PCB-1232, PC5-1248, PCB-1260, PCB-1016.

(a) See note on Outfall 001, Page B-4 REVISED 12/98 . INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-4

p .

1

5. TABLE B-3 contains testing rsquiramInts for the compound "Tributyltin" and for the indicttor bacteria "cnterococci." Not all applicants are required to test for tributyltin or enterococci. Testing is required only under the following conditions:

A. TRIBUTYLTIN j Testing will be required for 1) industrial / commercial facilities which directly dispose of wastewater from the types of operations listed below OR 2) domestic facilities which receive wastewater from the types of industrial / commercial operations listed below. Please check all that apply.

1) Manufacturers and formulators of tributyltin or related compounds, l including, but not limited to SIC code 2879. Testing required.

2) Painting of ships, boats and marine structures, including, but not limited to SIC code 1721. Testing required.

3) Ship and boat building and repairing, including, but not limited to SIC codes 3731, 3732 and 3441. Testing required. .

l

4) Ship and boat cleaning, salvage, wrecking and scaling, including, i but not limited to' SIC codes 4499 and 7699. Testing required.

5) Operation and maintenance of marine cargo handling facilities and marinas, including, but not limited to SIC codes 4491 and 4493. .

Testing required. l

6) Facilities engaged in wood preserving, including, but not limited to, SIC code 2491. Testing required.

7) Any other industrial /conunercial facility for which tributyltin is 1 known to be present, or for which there is any reason to believe I that tributyltin may be present in the effluent. Testing required.

X 8) None of the above. No testing required.

B. ENTEROCOCCI Testing will be required for all dischargers d'.:ectly into the Houston Ship Channel (classified stream segment nos. 1006 or 1007). Please check all that apply

1) Discharge is directly to the Houston Ship Channel (classified stream segment number 1006 or 1007). Testing required.

X 2) Discharge is not directly to the Houston Ship Channel (classified stream segment number 1006 or 1007). No testing required.

TABLE B-3 OUTFALL Concentration NUMBER OF MAL POLLtTrANT AVG MAX. Unigg SAMPLES fua/11 Tributyltin 0.010 Enterococci N/A

' REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATIoM TECHNICAL REPORT PAGE B-5 L,

c.

Q. TABLE B-4 contains a list of pasticida compounds includtd in the Texas Surface Water Quality Standards at 30 TAC 307.6. TABLE 13-4 must be completed

-f the facility manufactures or formulates pesticides or herbicides. Complete TABLE B-4 with the results of an analyses for each outfall that contains process wastewater or may contain pesticides or herbicides. Report an average and maximum value if more than one analytical result is available.

X N/A: This facility does not manufacture or formulate pesticides or herbicideo.

TABLE B-4 OUTFALL l CONCENTRATION NUMBER

( g/l)* OF MAL POLLUTANT R MAX. SAMPLES (aa/1)

Aldrin 0.05 Alpha-hexachlorocyclohexane 0.05 Beta-hexachlorocyclohexane 0.05 Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D 10 Danitol ...

4,4--DDD 0.1 4,4'-DDE 0.1 4,4'-DDT 0.1 Demeton 0.2 Diazinon 0.5 Dicofol 20 Dieldrin 0.1 Diuron ...

Endosulfan I (alpha) 0.1 Endosulfan II (beta) 0.1 Endosulfan Sulfate 0.1 Endrin 0.1 Gamma - Hexachlorocyclohexane 0.05 (Lindane)

Guthion 0.10 Heptachlor 0.05 Heptachlor Epoxide 1.0 Hexachlorophene 10 Malathion 0.10 methoxychlor 2 Mirex 0 Parathion 0 Toxaphene 5 2,4,5-TP (Silvex) 2 1 J

I l

)

\

l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-6 i

L o

h. Review the.'following TABLE B-5 and mark the appropriate column with an "X" if you .: believe a specific constituent to be present or absent in your

~ discharge. ~ Rase your. determination on your._ knowledge of raw . materials, _

maintenance chemicals,-intermediates, and products. handled at your' facility-and/or previous analyses ~ of your wastewater. You must provide the results of

~

]

at least one analysis for each constituent believed present. , Report an I average and maximum value-if more than one analytical result is available.

TABLE B-5 OUTFALL 004 CONCENTRATION BELIEVED BELIEVED (mg/1)* NUMBER OF-POLLUTANT PRESENT ABSENT &YL. M&K SAMPLES i

Bromide X 9df 1 Color (PCU) ..

X L.D 1  ;

Nitrate-Nitrite (as N)- X 0.172 1 l Sulfide (as S) X 1 Sulfite (as SO,) X 1 Surfactants X 1' ]

-Total Antimony. ~X '4  ;

Total Beryllium X L.QD2 0.004 4 l Total Boron X L12 1 Total Cobalt- X 1

' Total Iron X O.006 '1 Total Magnesium- 'X 15.20 1

-Total Molybdenum X 1 Total Manganese- X i

. Total Thallium X 0.003 0.006 4 Total Tin X .,_,._

1 Total Titanium X i  ;

• Indicate units if different from ag/1. 4 l

l l

l5 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TRODfICAL REPORT PAGE B-7 t- . . _ _ _

i S Tchle 3-6 is a list of primary industrial catsgorica with a breakdown of Gas Chromatography / Mass Spectrometry (GC/MS) testing requirements for Priority Pollutants. Categories are defined in 40 CFR Parts 400 - 471. Check any category (s) that apply to your facility and provide the indicated analysis- s for Priority Pollutants listed in Table B-6, l l

TABLE B-6 N/A GC/MS Testino Reauired Volatile Acid Base / Neutral Pesticides Adhesives and Sealants Yes Yes Yes No Aluminum Forming Yes Yes Yes No Auto and Other Laundries Yes Yes Yes Yes Battery Manufacturing Yes No Yes No Coal Mining No No No No Coil Coating Yes Yes Yes No i Copper Forming Yes Yes Yes No Electric and Electronic Yes Yes Yes Yes Components I Electroplating Yes Yes Yes No Explosives Manufacturing No Yes Yes No l Foundries Yes Yes Yes No l Gum and Wood Chemicals Subparts A,B,C,E Yes Yes No No Subparts D,F Yes Yes Yes No Inorganic Chemicals Yes Yes Yes No Iron and Steel Mfg. Yes Yes Yes No L Leather Tanning / Finishing Yes Yes Yes No Mechanical Products Mfg. Yes ' Yes Yes No Nonferrous. Metals Mfg. Yes Yes Yes Yes Ore Mining (Subpart B) No Yes No No Organic Chemicals, Yes Yes Yes Yes Plastics and Synthetic Fibers Paint and Ink Formulation Yes Yes Yes No Pesticides Yes Yes Yes Yes Petroleum Refining Yes Yes Yes No l

Pharuaceutical Preparations Yes Yes Yes No Photographic Equipment and Yes Yes Yes No Supplies Plastic Processing Yes No No No Porcelain Enameling No No No No Printing and Publishing Yes Yes Yes Yes Pulp and Paperboard Mills l Subparts A,B,C,D,R

• Yes

• Yes Subparts F,G,H,I, Yes Yes

• Yes K,L,M,N,0,P, Subparts E,Q,S,T Yes Yes

• Yes l Subparts J,U Yes Yes Yes

• i Rubber Processing Yes Yes Yes No Soap and Detergent Mfg. Yes Yes Yes No JL Steam Electric Power Plants Yes Yes No No Textile Mills (Not Subpart C) Yes Yes Yes No Timber Products Processing Yes Yes Yes Yes Test if " believed present" l

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-8

(

l_

h.

9. Tcble B-7 contains a list of priority pollutants. If you are a primary industry as shown in Table B-6 and process wastewater is discharged, you must

analyze for those GC/MS fractions as shown in Table 3-7. If you are not a primary industry and if you believe that a specific constituent (except for i acrolein;' acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol) l' is present.in an amount greater than 10 ppb you must provide the results of at least one analysis. If you believe that acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol is present in an amount greater than 100 ppb you must provide results for these chemicals. Base your determination on your knowledge of raw materials, maintenance chemicals, intermediates, and products handled at your facility or analysis of your wastewater. Report an average and a maximum value if more than one analytical result is available.

TABLE B-7 OUTFALL 004 l I

CONCENTRATION l (ug/l)

• NUMPER OF MAL l POLLUTANT && M&L. SAMPLES fua/1)

VOLATILE COMPOUNDS Acrolein <50 1 50 Acrylonitrile <50 1 50 j Benzene ~ <10 . 1 10  ;

Bromoform' <10 1 10 Carbon Tetrachloride <10 1 10 Chlorobenzene <10 1 10 Chlorodibromomethane <10.. 1 10 Chloroethane s.lD.__ 1 10 2-Chloroethylvinyl Ether <50 1 50 l Chloroform <10 1 10 I

'Dichlorobromomethane <10 1 10 lil-Dichloroethane <10 1 10 4 1,2-Dichloroethane <10 1 10 1,1-Dichloroethylene <10 . 1 10 1,2-Dichloropropane <10 1 10 ,

-)

1,3-Dichloropropylene <10 1 10 Ethylbenzene <10 1 10 Methyl Bromide- <20 1 20  ;

Methyl Chloride s2D_ 1 20 Methylene Chloride .

s2D_., 1 20 1,1,2,2-Tetrachloroethane sig_ 1 10 Tetrachloroethylene, sig_ 1 10 Toluene _ s1D_ 1 10 l',2-Trans-Dichloroethylene sig_ 1 10 1,l',1-Trichloroethane s 10_ i 10 1,1,2-Trichloroethane sig_ 1 10 Trichloroethylene s1L i 10 Vinyl Chloride- s1.Q_ 1 10

• Indicate units if different from yg/l i

f REVISED 12/98 INDUSTRIAL NASTENATER PERMIT APPLICATION TECHNICAL REPORT FAGE B-9

F -

]

j

l. _ TABLE B-7 ; (can' t)

. OUTFALL- 004

[] CONCENTRATION l ( g/l)* -NUMBER OFMAL' l

POLLUTANT AVG. lHL. SAMPLES fua/1) 1 ACID COMPOUNDS I

.2-Chlorophenol <10 1 10 2,4-Dichlorophenol <10 1 10

^2,4-Dimethylphenol. <10 1 10 g 4,6-Dinitro-o-Cresol- <50 1 50 1 2,4-Dinitrophenol: <50 1 50 2-Nitrophenol <20 1 20 Nitrophenol s52__ 1 50

_P-Chloro-m-Cresol: <10 1 10 Pentachlorophenol- <50 1 50 Phenol ,

s.la__ 1 10 2,4,6-Trichlorophenol- <10 1 10 l

BASE / NEUTRAL COMPOUNDS i

Acenaphthene 10 Acenaphthylene- 10 l Anthracene. 10

' Benzidine 50 Benzo (a) Anthracene 10 '

Benzo . (a) ' Pyrene 10 l 3,4-Benzofluoranthene 10 Benzo (ghi) Perylene =20  ;

l . Benzo'. (k) Fluoranthene 10 '

Bis (2-Chloroethoxy). Methane. l10 ]

l_ Bis (2-Chloroethyl) Ether 10 )

L _ Bis (2-Chloroisopropyl) Ether 10

! Bis (2-Ethylhexyl) Phthalate 10 4-Bromophenyl Phenyl Ether; 10 l' Buty1 benzyl.Phthalate~ 10 l .: 2-Chloronaphthalene 10 4-Chlorophenyl Phenyl Ether 10 Chrysene. .

10 Dibenzo,(a,h) . Anthracene 20 1,2-Dichlorobenzene 10 1,3-Dichlorobenzene 10 1,4-Dichlorobenzene 10 3,3-Dichlorobenzidine 50

' Diethyl'Phthalate. 10 Dimethyl Phthalate 10 Di-n-Butyl Phthalate 10 2,4-Dinitrotoluene 10 2,6-Dinitrotoluene 10 Di-n-Octyl Phthalate 10

-1;2-Diphenyl Hydrazine (as Azobenzene)~ 20

• Indicate units if different from pg/l REVISED 12/98 INDUSTRIAL MASTEWATER PERMIT APPLICATION TBCHNICAL REPORT PAGE B-10

n --

TABLE B-7 (con't)

OUTFALL 004 CONCENTRATION (4g/l)

• NUMBER OF MAL .

POLLUTANT AEL. MAX. SAMPLES (aa/1) I BASE / NEUTRAL COMPOUNDS (con't).

Fluoranthene 10 Fluorene 10 Hexachlorobenzene 10 Hexachlorobutadiene 10 Herachlorocyclopentadiene 10 Hexachloroethane 20 Indeno(1,2,3-cd) pyrene 20 Isophorone 10 Naphthalene 10 Nitrobenzene 10 g N-Nitrosodimethylamine 20 l N-Nitrosodi-n-Propylamine 20 N-Nitrosodiphenylamine 20 Phenanthrene 10 Pyrene 10 1,2,4-Trichlorobenzene 10 PESTICIDES Aldrin 0.05 alpha-BHC 0.05 beta-BHC 0.05 gamma-BHC 0.05

)

4 delta-BHC 0.05 l Chlordane 4,4-DDT 0.15 0.1

)

4,4-DDE 0.1 4,4-DDD- 0.1 Dieldrin 0.1-alpha-Endosulfan 0.1 bet Endosulfan 0.1 Endosulfan Sulfate 0.1 Endrin 0.1 Endrin Aldehyde 0.1 Heptachlor 0.05 j Heptachlor Epoxide 1.0 PCB-1242 1.0 j PCB-1254 1.0 j PCB-1221 1.O j PCB-1232 1.0 i PCB-1248 _

1.O  !

PCB-1260 1.0  !

1.O  !

PCB-1016 , _ , , _ _ . , , ,

Toxaphene 5.0

>* Indicate units if different from yg/l i l

l . REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B 11 I

m

3 .' Outfalle th*.t contain sny wn::tswitsr othtr thin stom witer (e.g., procasa wastewater, utility wastewater, domestic wastewater, groundwater, etc.) must complete TABLE B-1. Facilities that utilize land application or evaporation for wastewater treatment / disposal must also provide these analytical results.

TABLE a-1 OUTFALL 005 Sample Type: GRAB X COMPOSITE INFLUENT EFFLUENT CONCENTRATION NUMBER . CONCENTRATION NUMBER j (mg/1)~ OF (mg/1)  !

OF POLLMANT l

&& M&L. SAMPLES AVG. M&L. SAMPLES j BOD (5-day)' , _ , ,

B L 4 CBOD.(5-day) gf.A_ Hut. N/A i Chemical Oxygen Demand 21 _ 22_ 4 Total. Organic Carbon LJL5._ 2.42 4 Ammonia Nitrc3en 0 0 4 Total Suspended Solide 4.25 5.0 .. 4 Nitrate Nitrogen o o 4 Total Organic Nitrogen 0.88 1.10 4 Total Phosphorus 0.358 0.368 4 011 and Grease LJ_ 1L1 -4

. Total Residual Chlorine N/A . HlA N/A Total Dissolved Solids 1830 1112 4 Sulfate 1 221 4 Chloride 726.5 2R 4 Fluoride DJ38 0.371 4 Fecal Coliform HUL._ N/A. N/A Temperature '('F) 22 ,lll__. 4 pH (Standard Units; min / max) Ljii. JL18 4 EFFLUENT CONCENTRATION NUMBER (ug/1) OF MAL POLLMANT AVG,. M&L. SAMPLES y.gf.1 Total Aluminum 124.21 fjk2 4 30 Total Antimony o o 4 30 Total Arsenic o 0 4 10 11 E 4 10

. Total Total Beryllium Barium L.1 L.2 4 5 Total cadmium o o 4 1 Total Chromium o o 4 10 I Trivalent Chromium E H&_ NA -- I Hexavalent Chromium E H& NA 10 Total Copper 'o o 4 10 Cyanide, (Total, Amenable to Chlorination or weak-Acid Dissociable o o 4 20 Total Lead o o 4 5 Total Mercury o o 4 0.2 [

Total Nickel o o 4 10 Total Phenols 0.014 0.025 4 20

. Total Selenium o o 4 10 Total Silver o o

• 2 Total Thallium o o 4 10

t. Total Zinc 34.9 JL1 _ 4 5 ,

l l l

i l

l l- arvtsso 12/ss INousTarAL wasTswArsa eranIT APPLzcArzou recHNIcAL aspoar PAos s-3 I

! l E l

=

7:

4. TABLE B-2 'contains a ' list of organic compounds includsd in the Texas ,

Surface Water Quality Standards at 30 TAC 307.6. TABLE B-2 must be completed 1 l with the~results'of an analysis of all pollutants for each outfall that contains process wastewater. In addition, an analysis for each continuously J

' discharging nonprocess outfall_ (including noncontact cooling water) must be provided . for only those pollutants in TABLE B-2 that are used at the

! sfacility as . a feedstock, intermediate, product, byproduct, coproduct, maintenance chemical or that could in any way coutribute to contamination in the wastewater streams.

l-TABLE B-2 OUTFALL 005W CONC pg/l (*I) NUMBER OF MAL POLLUTANT &yl, M&L, SAMPLES fua/l)

Benzene s1Q 1 10 Benzidine 50 Benzo'(a) anthracene- 10 Benzo (a) pyrene. 10 Bis (chloromethyl) ether (*2)

Carbon Tetrachloride 512 1 10 Chlorobenzene <10. 1 10 i

" Chloroform 119._ 1 10 l i Chrysene 10 l Cresols , _ (*3) )

Dibromochloromethane' s12., i 10 )

1,2-Dibromoethane 2

1,4-Dichlorobenzene 10 1,2-Dichloroethane 512 1 10 t 1,1-Dichloroethylene _ 10 Fluoride 0.338 0.371 4 500 Hexachlorobenzene 10 Hexachlorobutadiene 10 Hexachloroethane 20 Methyl' Ethyl ~ Ketone 50 Nitrobenzene 10 n-Nitrosodiethylamine 20 f

.n-Nitroso-di-n-Butylamine _

20 PCB's, Total (*4) 1- t Pentachlorobenzene 20  !

Pentachlorophenol 50 Phenanthrone 10 Pyridine 20 L 1,2,4,5-Tetrachlorobenzene 20 I Tetrachloroethylene 10 Trichloroethylene . 10 l l 1,1,1-Trichloroethane 119_. 1 10

, 2,4,8-Trichlorophenol 50 L TTHM (Total Trihalometharhes) . 10 vinyl. Chloride s1Q 1 10  !

,(*1) ' Indicate units if different from ug/l

(*2) Hydrolyses in water. will not require applicant to analyze at this time.

(*3)- MAL's for Cresolssp-Chloro-m-Cresol 10 ug/1;4,6-Dinitro-o Cresol 80 ug/1;p-Cresol 10 g/l

.(*4). Total of PCB-1242, PCB-1254, PCB-1221, PCB-1232, PCB-1248, PCB-1260, PCB-1016. j

.(a).See note on Outfall 001, Page B-4 l

l REVISED 12/98_ IR:DUSTRIAL WASTEWATER PERMIT APPLICATION TECl0tICAL REPORT PAGE B-4 L1 __

?

5. TABLE B-3 contains tstting riquirim2nts for tha compound "Tributyltin" and for the indicitor bictsria " enterococci." Not all applicants are required to test for tributyltin or enterococci. Testing is required only under the following conditions:

A. TRIBUITLTIN

. Testing will be required for 1) industrial / commercial facilities which directly dispose of wastewater f rom the types of operations listed below OR 2) domestic facilities which receive wastewater from the types of industrial / commercial operatinas listed below. Please check all that apply.

1) Manufacturers and formulators of tributyltin or related compounds, including, but not limited to SIC code 2879. Testing required.

2) Painting of ships, boats and marine structures, including, but not limited to SIC code 1721. Testing required.

3) Ship and boat bttilding and repairing, including, but not limited to SIC codes 3731, 3732 and 3441. Testing required.

4) Ship and boat cleaning, salvage, wrecking and scaling, including, but not limited to SIC codes 4499 and "1699. Testing required.

5) Operation and maintenance of marine cargo handling facilities and marinas, including, but not limited to SIC codes 4491 and 4493.

Testing required.

6) Facilities engaged in wood preserving, including, but not limited to, SIC code 2491. Testing required.

7) Any other industrial / commercial facility for which tributyltin is known to be present, or for which there is any reason to believe that tributyltin may be present in the effluent. Testing required.

L., 9) None of the above. No testing required.

B. ENTEROCOCCI Testing will be required for all dischargers directly into the Houston Ship Channel (classified stream segment nos 1006 or 1007). Please check all that apply

1) Discharge is directly to the Houston Ship Channel (classified stream segment number 2006 or 1007). Testing required.

l 2) Discharge is not directly to the Houston Ship Channel (classified stream segment number 1006 or 1007). No testing required.

TABLE B-3 OUTFALL Concentration NUMBER OF MAL POLLUTANT Ay1. HAL, Units SAMPLES fue/1)

Tributyltin 0.010 Enterococci _ N/A RdVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-5 b ..

r. ,

6. TABLE B-4 contcins a lict of p2sticida compounds includsd in the Texas Surface Water Quality Standards at 30 TAC 307.6. TABLE 13-4 must be com, eted if the facility manufactures or fonnulates pesticides or herbicides. Cu.plete TABLE B-4 with the results of an analyses for edch outfall that contains process wastewater or may,contain pesticides or herbicides. Report an average and maximum value if more than one analytical result is available.

X N/A: This facility does not manufacture or formulate pesticides or herbicides.

TABLE B-4 OUTFALL CONCENTRATION NUMBER (ug/l)* OF MAL POLLITTANT AY.Q M&L. SAMPLES fua/1)

Aldrin 0.05 Alpha-hexachlorocyclohexane 0.05 Beta-hexachlorocyclohexane 0.05 Carbaryl 5 Chlordane 0.15 Chlorpyrifos 0.05 2,4-D . 10 Danitol ---

4,4--DDD 0.1 4,4'-DDE 0.1 4,4'-DDT 0.1 Demeton 0.2 Diazinon 0.5 Dicofol 20 Dieldrin _

0.1 Diuron ---

Endosulfan I (alpha) 0.1 Endosulfan II (beta) 0.1 Endosulfan Sulfate 0.1 Endrin 0.1 Gamma - Hexachlorocyclohexane 0.05 (Lindane)

Guthion 0.10 Heptachlor 0.05 Heptachlor Epoxide 1.O Hexachlorophene 10 Malathion 0.10 methoxychlor 2 Mirex 0 Parathion 0 Toxaphene 5 2,4,5-TP (Silvex)- 2 REVISED.12/98 INDUSTRIAL WASTEWATER PERMAT APPLICATION TECHNICAL REPORT PA 5 D-6 l

E .l

l

h. Review the following TABLE B-5 and mark the appropriate column with an "X"  ;

if you believe a specific constituent to be present or absent in your I discharge. Rase your determination on your knowledge of raw materials, maintenance chemicals, intermediates, and products handled at your facility and/or previous analyses of your wastewater. You must provide the results of at least one analysis for each constituent believed present. Report an average and maximum value if more than one analytical result is available.

TABLE B-5 l

OUTFALL 005 i CONCENTRATION I BELIEVED BELIEVED (mg/1)* NUMBER OF POLLUTANT PRESENT MSENI E MM SAMPLES k 1

I Bromide X M i 1 Color (PCU) X 8 1 Nitrate-Nitrite (as N) X 1 Sulfide (as S) X 1 Sulfite (as SO,) X 1 Surfactants X 1 Total Antimony X 4 Total Beryllium X 0,001 0.004 4 Total Boron X 0.51 1 Total Cobalt X 1 Total Iron X 0.035 1 Total Magnesium X 49.60 1 Total Molybdenum X 1 Total Manganese X 1 Total Thallium X 0.012 4 ,j Total Tin X 1 l Total Titanium X 1 I l

• Indicate units if different from ag/1, i

~

S i

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-7 f

L

'8 Table 3-6 is'a list of primary industrial categories with a breakdown of Gas Chromatography / Mass Spectrometry (GC/MS) testing requirements for Priority Pollutants. Categories are defined in 40 CFR Parts 400 - 471. Check any category (s) that apply to your facility and provide the indicated analysis

,for Priority Pollutants listed in Table B-6.

TABLE B-6 N/A- GC/MS Testina Reauired Volatile W Base / Neutral Pesticides Adhesives and Sealants Yes Yes Yes No Aluminum Forming- Yes Yes Yes No Auto and Other Laundries Yes Yes Yes Yes Battery Manufacturing .Yes No' Yes No Coal Mining No No No No Coil Coating Yes Yes Yes No Copper Forming Yes Yes Yes No Electric and Electronic Yes . Yes Yes Yes

' Components Electroplating Yes Yes Yes No Explosives Manufacturing No Yes -Yes No

' Foundries .

Yes Yes Yes No l Gum and Wood Chemicals Subparts A,B,C,E Yes Yes No No Subparts D,F. Yes Yes Yes No i Inorganic Chemicals- Yes Yes Yes ' No Iron and Steel Mfg. Yes Yes Yes No Leather Tanning / Finishing' Yes Yes Yes No Mechanical Products Mfg. Yes Yes ~ .Yes_ No Nonferrous Metals Mfg. Yes Yes Yes Yes Ore Mining (Subpart B) = No Yes- No No Organic Chemicals, Yes _ Yes Yes Yes Plastics and' Synthetic Fibers Paint and Ink Formulation Yes Yes Yes No Pesticides. Yes Yes Yes Yes Petroleum' Refining Yes Yes Yes. No Pharmaceutical Preparations Yes - Yes Yes No Yes

~

Photographic Equipment and Yes Yes No-Supplies Plastic. Processing = Yes No No No Porcelain Enameling No No No No Printing and Publishing Yes Yes Yes Yes Pulp and Paperboard Mills '

Subparts A,B,C,D,R * -

Yes

• Yes Subparts F,G,H,I, Yes Yes

• Yes K,L,M,N,0,P, Subparts B,Q,S,T Yes Yes

• Yes Subparts J,U _Yes Yes Yes

• Rubber Processing . Yes Yes Yes No

. Soap and Detergent Mfg. -Yes Yes Yes No X, Steam Electric Power Plants Yes Yes No No Textile Mills (Not-Subpart C) Yes Yes Yes No Timber Products Processing. Yes Yes Yes Yes Test if " believed present" REVISED 12/98 . INDUSTRIAL ltASTDfATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-8 L' i

p .

I 9.

' Ttble B-7 contains a list of priority pollutents. If you are a primary industry as'shown in Tcble B-6 and process wastewater is discharged, you must analyze for those GC/MS fractions as shown in Table 3-7 If you are not a primary industry and if you believe that a specific constituent (except for: I l

acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol) l is present in an amount greater than 10 ppb you must provide the results of at least one analysis. If you believe that acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol is present in an amount greater than 100 ppb ' you must provide results for these chemicals. Base your determination on your ' kncwledge of. raw materials, maintenance chemicals,  ;

intermediates, and products handled at your facility or analysis of your '

I wastewater. Report an average and a maximum value if more than one analytical result is available.

TABLE B-7 OUTFALL 005 CONCENTRATION (ug/l)

• NUMBER OF MAL POLLUTANT & M&L. SAMPLES (ua/1)

VOLATILE COMPOUNDS Actolein <50 1 50 Acrylonitrile siD___. 1 50 Benzene <10 1 10 Bromoform s1D___ 1 10 Carbon Tetrachloride <10 1 10 Chlorobenzene <10 1 10 Chlorobenzene <10 1 10

-Chlorodibromomethane <10 1 10  !

-Chloroethane <10 1 10 2-Chloroethylvinyl Ether siD_ _ 1 50  ;

Chloroform <10 1 10 Dichlorobromomethane s1D___ 1 10 1,1-Dichloroethane <10 1 10 1,2-Dichloroethane <10 1 10 1,1-Dichloroethylene <10 1 10 1,2-Dichloropropane <10 1 10 1,3-Dichloropropylene <10 1 10 Ethylbenzene < 10 . .. 1 10 Methyl Bromide <20 1 20 Methyl Chloride s2.Q_. 1 20 Methylene Chloride 52D_. 1 20

'1,1,2,2-Tetrachloroethane s1D_. 1 10 Tetrachloroethylene, s1D_. 1 10 Toluene s10_. 1 10 1,2-Trans-Dichloroethylene s19._ _, i 10 1,1,1-Trichloroethane s1D._ 1 10 1,1,2-Trichloroethane s10_. 1 10 Trichloroethylene sla._ 1 10 Vinyl Chloride <10._ 1 10 l- '

• Indicate units if different from pg/l REVISED 12/98 INDUSTRIAL NASTEdATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-9 kn

- ~ ~

re- ,

, TABLE B-7 (can't) l

l. OUTFALL 005 CONCENTRATION (4g/1)* NUMBER OFMAL POLLUTANT E' E SAMPLES (ua/1)

ACID COMPOUNDS

2-Chlorophenol <10 1 10

1. 2,4-Dichlorophenol <10 1 10  ;

2,4-Dimethylphenol <10 1 10  ;

4,6-Dinitro-o-Cresol <50 1 50 l 2,4-Dinitrophenol <50 1 50 2-Nitrophenol <20 l' 20 4-Nitrophenol <50 1 50 P-Chloro-m-Cresol <10 1 10

.Pentachlorophenol __ sea __ 1 50  !

! Phenol <10 . 1 10 2,4,6-Trichlorophenol <10 1 10 BASE / NEUTRAL COMPOUNDS I

Acenaphthene 10 l Acenaphthylene 10 Anthracene 10 Benzidine 50 Benzo (a) Anthracene 10 Benzo (a) Pyrene 10 3,4-Benzofluoranthene 10 Benzo (ghi) Perylene- 20 Benzo (k) Fluoranthene 10 Bis (2 *Chloroethoxy) Methane 10 Bis (2-Chloroethyl) Ether 10 Bis (2-Chloroisopropyl) Ether 10 Bis (2-Ethylhexyl) Phthalate 10 4-Bromophenyl Phenyl Ether 10 Butylbenzyl Phthalate 10 2-Chloronaphthalene 10 4-Chlorophenyl Phenyl Ether 10 Chrysene 10 Dibenzo (a,h) Anthracene 20 1,2-Dichlorobenzene 10 1,3-Dichlorobenzene 10  !

1,4-Dichlorobenzene. 10 23,3-Dichlorobenzidine 50 Diethyl Phthalate. 10 Dimethyl Phthalate 10 Di-n-Butyl Phthalate 10 j 2,4-Dinitrotoluene 10 2,6-Dinitrotoluene 10 Di-n-Octyl Phthalate 10 1,2-Diphenyl Hydrazine (as Azobenzene) 20

• -Indicate units if different from yg/l REVISED 12/98 INDUSTRIAL WhSTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-10

a. . .o

t- ,

1 t

- TABLE B-7 (cen't) i 1

i OUTFALL -005 i CONCENTRATION (pg/1)

• NUMBER OF MAL POLLUTANT & l'&L, SAMPLES (uc/l)

I BASE / NEUTRAL COMPOUNDS (con't)

Fluoranthene 10 Fluorene 10 Hexachlorobenzene , 10 Hexachlorobutadiene _ 10 )

Hexachlorocyclopentadiene 10 j Hexachloroethane __ 20 Indeno(1,2,3-cd) pyrene 20 Isophorone 10 Naphthalene 10 Nitrobenzene 10 N-Nitrosodimethylamine 20 N-Nitrosodi-n-Propylamine 20 N-Nitrosodiphenylamine 20 Phenanthrene 10 Pyrene 10 1,2,4-Trichlorobenzene 10 PESTICIDES Aldrin 0.05 alpha-BHC 0.05 beta-BHC 0.05 l gamma-BHC 0.05 delta-BHC 0.05 Chlordane 0.15 4,4-DDT 0.1 j 4,4-DDE 0.1 4,4-DDD 0.1 Dieldrin 0.1 alpha-Endosulfan 0.1 l beta-Endosulfan 0.1 Endosulfan Sulfate 0.1 Endrin 0.1 Endrin Aldehyde 0.1 Heptachlor 0.05 Heptachlor Epoxide 1.0 PCB-1242 10 PCB-1254 1.O PCB '221 1.0 PCB-1232 1.O i PCB-1248 1.0-l PCB-1260 1.0 l PCB-1016 1.0 Toxaphene 5.0

• Indicate units if different from g/l l

i' REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-11 t

j I

3. Outf alls that contain any wistewater other than storm water (e.g. , process wastewater, utility wastewater, domestic wastewater, groundwater, etc.) must l complete TABLE B-1. Facilities.that' utilize' land application or evaporation for wastewater treatment / disposal must also provide these analytical results.

TABLE B-1 1

1 OUTFALL 104* ~ Sample Type GP1.B X COMPOSITE 1 I

INFLUENT EFFLUENT <

CONCENTRATION NUMBER CONCENTRATION NUMBER i

-(mg/1) OF_ (mg/1) j OF POLLUTANT h M&L. SAMPLES & M&L, SAMPLES BOD (5-day)

CBOD (5-day).

Chemical Oxygen Demand

. Total Organic carbon

- Ammonia Nitrogen

' Total Suspended Solids Nitrate Nitrogen Total Organic Nitrogen

. Total Phosphorus

-Oil and Orease Total Residual Chlorine _

Total Dissolved Solids Sulfate -

Chloride l l

Fluoride i Fecal Coliform Temperature ('F) . )

pH (Standard Units; min / max) l l

EFFLUENT  !

CONCENTRATION NUMBER (ug/1) OF MAL j pornerAbrr M h SAMPLES ggf.1 -

Total. Aluminum 30

~ Total' Antimony 30 1 Total: Arsenic' 10 Total Barium.' 10

t. fTotal Beryllium 5

!' Total Cadmium 1 oTotal Chromium 10-Trivalent Chromium --

I

. Hexavalent Chromium 10 j

Total Copper. 1C

' Cyanide, (Total, Amenable to Chlorination  ;

or weak-Acid Dissociable 20 Total Lead 5

.-Total Mercury - _ 0.2 i

-Total Nickel - . . 10

. Total Phenols 20 Total Selenium 10

Total Silver 2 Total Thallium 10 Total = zinc: 5L

• Results pending; to be submitted as soon as possibl'e  !

REVISED 12/98 INDUSTRIAL NASTENATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-3

4. TABLE B-2 contains a 'lict of org::.nic compounds includ::d in tha Taxes Surftca Witsr Qu211ty Standards at 30 TAC 307.6. TABLE B-2 must be completed with the results of an analysis of all pollutants for each'outfall that contains process wastewater. In addition, an analysis for each continuously discharging nonprocess outfall (including noncontact cooling water) must be provided for only those pollutants in TABLE B-2 that are used at the facility as a feedstock, intermediate, product, byproduct, coproduct, maintenance chemical or that could in any way contribute to contamination in the wastewater streams.

TABLE B-2 OUTFALL 104N CONC. g/l (*I) NUMBER OF MAL POLLUTANT M E SAMPLES fuc/11 Benzene 10 Benzidine 50 Benzo (a) anthracene 10 Benzo (a) pyrene 10 Bis (chloromethyl) ether (*2)

Carbon Tetrachloride 10 Chlorobenzene 10 Chloroform 10 Chrysene 10 Cresols (*3)

Dibromochloromethane 10 1,2-Dibromoethane , 2 1,4-Dichlorobenzene 10 1,2-Dichloroethane 10 1,1-Dichloroethylene 10 Fluoride 500 Hexachlorobenzene 10 Hexachlorobutadiene 10

~

Hexachloroethane 20 Methyl Ethyl Ketone 50 Nitrobenzene 10 n-Nitrosodiethylamine 20 n-Nitroso-di-n-Butylamine ___ 20 PCB 's , Total (

• 4 ) 1 Pentachlorobenzene 20 ,

-Pentachlorophenol 50 Phenanthrene 10 Pyridine 20 i

'.').4,5-Tetrachlorobenzene 20

< ' t r e- 'oroethylene 10 Trichlo.sethylene 10 1,1,1-Trichloroethane 10 2,4,S-Trichlorophenol 50

' 'ITHM (Total Trihalomethanes) 10

! Vinyl Chloride. 10

(*1) Indicate units if different from ug/l

(*2) Hydrolyzes in water. will not require applicant to analyze at this time.

(*3) MAL's for Cresolarp-Chloro-m-Cresol 10 ug/1:4.6-Dinitro-o-cresol SO ug/1;p-Cresol 10 ug/l

(*4) Total of PCB-1242, PCB-1254, PCB-1221, PCB 1232, PCB-1348, PCB-1260, PCB-1016.

(a) See note on Outfall 001, Page B-4 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-4 L

p i

5 TABLE B-3 contains tseting r&quiremente for tha compound "Tributyltin" and for the indicator bacteria " enterococci." Not all applicants are required to test for tributyltin or enterococci. Testing is required only under the following conditions:

A. TRIBUTYLTIN Testing will be required for 1) industrial / commercial facilities which directly dispose of wastewater from the types of operations listed below OR 2) domestic facilities which receive wastewater from the types of industrial / commercial operations listed below. Please check all that apply.

1) Manufacturers and formulators of tributyltin or related compounds, including, but not limited to SIC code 2879. Testing required.

2) Painting of ships, boats and marine structures, including, but not limited to SIC code 1721. Testing required.

3) Ship and boat building and repairing, including, but not limited to SIC codes 3731, 3732 and 3441. Testing required.

4) Ship and boat cleaning, salvage, wrecking and scaling, including, but not limited to SIC codes 4499 and 7699. Testing required.

5) Operation and maintenance of marine cargo handling facilities and marinas, including, but not limited to SIC codes 4491 and 4493.

Testing required.

6) Facilities engaged in wood preserving, including, but not limited to, SIC code 2491. Testing required.

7) Any other industrial / commercial facility for which tributyltin is known to be present, or for which there is any reason to believe that tributyltin may be present in the effluent. Testing required.

_2 , 8 ) None of the above. No testing required.

B. ENTEROCOCCI Testing will be required for all dischargers directly into the Houston Ship j Channel (classified stream segment nos. 1006 or 1007). Please check all that 'l apply

1) Discharge is 'directly to the Houston Ship Channel (classified

. stream segment number 1006 or 1007). Testing required.

_2 2) . Discharge is not directly to the Houston Ship Channel (classified stream segment number 1006 or 1007). No testing required.

TABLE B-3 OUTFALL Concentration NUMBER OF MAL POLLUTANT h lE Unij;,3 SAMPLES (ua/1)

Tributyltin 0.010 Enterococci- N/A Il

' REVISED 12/98. INDUSTRIAL NASTENATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-5 o c

6. TABLE B-4 contains a list of pasticida compounds includzd in the Texas Surface Water Quality Standards at 30 TAC 307.6. TABLE 13-4 must be completed if the facility manufactures or formulates pesticides or herbicides. Complete TABLE'B-4 with the results of an analyses for each outfall that contains process wastewater or may contain pesticides or herbicides. Report an average and maximum value if.nore than one analytical result is available.

x N/A This facility does not manufacture or formulate pesticides or herbicides.

TABLE B-4 l OUTFALL

! 1 CONCENTRATION NUMBER (ug/1)* OF MAL POLLUTANT E M&L. SAMPLES (ua/1) i l

Aldrin 0.05 Alpha-hexachlorocyclohexane 0.05-l Beta-hexachlorocyclohexane 0.05 Carbaryl 5 Chlordane 0.15

. Chlorpyrifos 0.05 2,4-D 10 Danitol ---

4,4--DDD 0.1 4,4'-DDE 0.1 4,4'-DDT 0.1 Demeton 0.2 i Diazinon 0.5 l- Dicofol 20 Dieldrin , , , , _ , _ _ 0.1 Diuron- ---

. Endosulfan I (alpha) 0.1 Endosulfan II (beta) 0.1 Endosulfan Sulfate 0.1 l

i. Endrin- 0.1 j i

l' Gamma Hexachlorocyclohexane 0.05 l

(Lindane)

Guthion 0.10 Heptachlor 0.05 Heptachlor Epoxide 1.0 Hexachlorophene 10 Malathion 0.10 methoxychlor 2 l Mirex 0 Parathion 0  ;

Toxaphene- E l 2,4;5-TP (Silvex) 2 l

l l

REVISED 12/98 INDUSTRIAL WASTEWATR4 PERMIT APPLICATION TEClOIICAL REPORT PAGE B-6 i L l

• f . Rsvicw tha following TABLE B-5 and mark the appropriate column with an "X" if you believe a specific constituent to be present or absent in your I discharge. Rase your determination on your knowledge of raw materials, l I maintenance chemicals, intermediates, and products handled at your facility I and/or previous analyses of your wastewater. You must provide the results of at least one analysis for each constituent believed present. Report an average and maximum value if more than one analytical result is available.

l TABLE B-5 OUTFALL 104'M l

CONCENTRATION BELIEVED BELIEVED (mg/l)* NUMBER OF l POLLUTANT PRESENT ABSENT E M&K SAMPLES l Bromide Color (PCU)

Nitrate-Nitrite (as N)

Sulfide (as S)

Sulfite (as SO,)

Surfactants

. Total Antimony Total Beryllium Total Baron ,

Total ~ Cobalt '

Total Iron _____

Total Magnesium Total Molybdenum Total Manganese Total Thallium Total Tin Total Titanium

• Indicate units if different from ag/1.

(" Results pending; to be submitted as soon as possible.

I l.

\

l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-7 t

J 8 T:ble.3-6 10 a liet of primary industrial cctsgories with a breakdown of Gas l Chromatography / Mass Spectrometry (GC/MS) testing requirements for Priority )

Pollutants. Categories are defined in 40 CFR Parts 400 -

471. Check any j category (s) that apply to your facility and provide the indicated analysis I for Priority Pollutants listed in Table B-6.

TABLE B-6 "

N/A GC/MS Testina Reauired Volatile Acid Base / Neutral Pesticides Adhesives and Sealants Yes Yes Yes No Aluminum Forming Yes Yes Yes No Auto and Other Laundries Yes Yes Yes Yes Battery Manufacturing Yes No Yes No Coal Mining No No No No Coil Coating Yes Yes Yes No Copper Forming Yes 'e s Yes No Electric and Electronic Yes Yes Yes Yes Components Electroplating Yes Yes Yes No.

Explosives Manufacturing No Yes Yes No Foundries Yes Yes Yes No Gum and Wood Chemicals Subparts A,B,C,E Yes Yes No No Subparts D,F Yes Yes Yes No Inorganic Chemicals Yes Yes Yes No Iron and Steel Mfg. Yes Yes Yes No Leather Tanning / Finishing Yes Yes Yes No Mechanical Products Mfg. Yes Yes Yes No Nonferrous Metals Mfg. Yes Yes Yes Yes Ore Mining (Subpart B) No Yes No No i Organic Chemicals, Yes Yes Yes Yes

' Plastics and Synthetic Fibers Paint and Ink Formulation Yes Yes Yes No Pesticides Yes Yes Yes Yes l Petroleum Refining Yes Yes Yes No Pharmaceutical Preparations Yes Yes- Yes No ]

Photographic Equipment and Yes Yes Yes No  ;

Supplies Plastic Processing Yes No No No Porcelain Enameling No No No No Printing and Publishing Yes Yes Yes Yes Pulp and Paperboard Mills Subparts A,B,C,D,R

• Yes

• Yes Subparts F,G,H,I, Yes - Yes

• Yes K,L,M,N,0,P, Subparts E,Q,S,T Yes Yes

• Yes Subparts J,U Yes Yes Yes

• Rubber Processing Yes Yes Yes No Soap and Detergent Mfg. Yes Yes Yes No X Steam Electric Power Plants Yes Yes No No Textile Mills (Not Subpart C) Yes Yes Yes No Timber Products Processing Yes Yes Yes Yes Test if " believed present" REVISED 12/98 INDUSTRIAL NASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-8 IL

x .

p 9. = Tcble ' B-7 contains a list of priority pollutcnts. If . you are a primary J 4

' industry as shown in Table B-6 and process wastewater is discharged, you must )

analyze for those GC/MS fractions as shown in Table 3-7. If you are not a I {

. primary industry and if you believe that.a specific constituent.(except for: J

-acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4,6 dinitrophenol) q

j. is present in an amount greater than 10 ppb you must provide the results of l' at least one . analysis . If you believe that acrolein, acrylonitrile, 2,4

' dinitrophenol, or 2-methyl-4,6 dinitrophenol is present in an amount greater.

than 100 ppb you must provide results for these chemicals. ' Base your l determination on .your . knowledge of raw materials, maintenance chemicals,

. intermedie.tes , and products handled at your facility or analysis of your wastewater. Report an average and a maximum value if more than one analytical result is available.

TABLE B-7

.OUTFALL 104 m CONCENTRATION (ug/l)

• NUMBER OF MAL POLLITTANT & M&L. SAMPLES (ua/1)

VOLATILE COMPOUNDS I

Acrolein 50 i Acrylonitrile 50 Benzer.e 10 Bromofom 10  ;

Carbon Tetrachloride 10 Chlorobenzene 10 Chlorodibromomethane 10 Chloroethane 10 2-Chloroethylvinyl Ether 50 Chlorofom -10 Dichlorobronomethane. 10 1 1,1-Dichloroethane 10 1,2-Dichloroethane 10 1,1-Dichloroethylene 10 1,2-Dichloropropane 10 1,3-Dichloropropylene 10.

Ethylbenzene 10 >

Methyl Bromide. 20 l Methyl Chloride 20 l

= Methylene chloride .

20 1,l'2,2-Tetrachloroethane-

, 10 Tetrachloroethylene, 10 Toluene. 10

'1,2-Trans-Dichloroethylene 10-1,1,1-Trichloroethane 10 1,1,2-Trichloroethane 10

.Trichloroethylene 10 vinyl Chloride 10

- *' Indicate units if difforent from yg/l in Results pending; to be submitted as soon as possible.

REVISED 12/98, INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-9

7 -- .

, TABLE B-7 (con't)

OUTFALL 104">

CONCENTRATION -

(4g/l)* NUMBER OFMAL POLLUTANT & E SAMPLES fua/1)

ACID COMPOUNDS 2-Chlorophenol 10 2,4-Dichlorophenol. 10 2,4-Dimethylphenol 10 4,6-Dinitro-o-Cresol 50 2,4-Dinitrophenol 50 2-Nitrophenol 20 4-Nitrophenol 50 P-Chloro-m-Cresol 10 Pentachlorophenol 50 Phenol 10 2,4,6-Trichlorophenol 10 BASE / NEUTRAL COMPOUNDS

. 'Acenaphthene '10 Acenaphthylene 10 Anthracene 10 Benzidine 50 Benzo (a) Anthracene 10 Benzo (a) Pyrene 10 3,4-Benzofluoranthene 10 Benzo (ghi) Perylene 20 Benzo (k) Fluoranthene 10 Bis (2-Chloroethoxy) Methane 10 Bis (2-Chloroethyl) Ether 10 Bis (2-Chloroisopropyl) Ether 10 Bis (2-Ethylhexyl) Phthalate 10 4-Bromophenyl Phenyl Ether 10 Butylbenzyl Phthalate 10 2-Chloronaphthalene 10 4-Chlorophenyl Phenyl Ether 10 Chrysene 10 Dibenzo (a,h) Anthracene 20 1,2-Dichlorobenzene 10 1,3-Dichlorobenzene 10 1,4-Dichlorobenzene 10 3,3-Dichlorobenzidine 50 Diethyl Phthalate 10 Dimethyl Phthalate 10 Di-n-Butyl Phthalate 10 2,4-Dinitrotoluene 10 2,6-Dinitrotoluene 10 l Di-n-Octyl Phthalate 10 1,2-Diphenyl Hydrazine (as Azobenzene) 20

• Indicate units if different from pg/l u> Results pending; to be submitted as soon as possible.

l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-10 t

4

, TABLE B-7 (ctn't)

OUTFALL 104'O CONCENTRATION (ug/l)

• NUMBER OF MAL POLLUTANT E MAX. SAMPLES fuo/1) i BASE / NEUTRAL COMPOUNDS (con't)

Fluoranthene 10 Fluorene -

10 Hexachlorobenzene 10 Hexachlorobutadiene 10 Hexachlorocyclopentadiene 10 Hexachloroethane 20 Indeno(1,2,3-cd) pyrene 20 Isophorone 10 Naphthalene 10 Nitrobenzene 10 N-Nitrosodimethylamine 20 N-Nitrosodi-n-Propylamine 20 N-Nitrosodiphenylamine 20 Phenanthrsne 10

. Pyrene 10 1,2,4-Trichlorobenzene. 10 PESTICIDES Aldrin 0.05 alpha-BHC 0.05 beta-BHC 0.05 gamma-BHC. 0.05 delta-BHC 0.05 Chlordane 0.15 4,4-DDT 0.1 4,4-DDE 0.1 4,4-DDD 0.1 Dieldrin 0.1 alpha-Endosulfan 0.1 beta-Endosulfan 0.1 Endosulfan Sulfate 0.1 Endrin . . 0.1 Endrin Aldehyde 0.1 Heptachlor 0.05 Heptachlor Epoxide 1.0

PCB-1242 1.0 PCB-1254 1.0 PCB-1221 1.0 PCB-1232 1.0 PCB-1248 1.0 PCB-1260 1.0 PCB-1016 1.0 Toxaphene 5.0

• Indicate units if different from yg/l

'" Results pending; to be submitted as soon as possible.

s REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TEC10ilCAL REPORT PAGE B-11 g .-

10. Undar csrtain conditions, tha cpplic.nt may b2 rs;;;ponsible for providing cnnly;sc of tha offluent from its process wastewater outfalls for i Dioxin /Furan compounds. Please review the conditions below and proceed as '

instructed. The applicant is required to' report that 2,3,7,8 Tetrachlorodibenzo-P-Dioxin (TCDD) may be discharged if the applicant 1) knows or has reason to believe that TCDD or any congeners of TCDD will or may f be present in the effluent or 2) uses or manufactures one of the following compounds:

a. Please review the following compounds. Check those compounds which are manufactured and/or used in a. process at the facility. Also provide a brief description of the conditions of its/their presence at the facility and then proceed to Item No. 10b. If none, then check N/A and proceed to Item No. 10b.

X N/A 2,4,5-trichlorophenoxy acetic acid (2,4,5-T) CAS #93-76-5 2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex, 2,4,5-TP) CAS #93-72-1 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon) CILS #136-25-4

. 0,0-dimethyl o-(2,4,5-trichlorophenyl) phosphorothioate (Ronnel) CAS #299-84-3 2,4,5-trichlorophenol (TOP) CAS #95-95-4 Hexach?orophene tHCP) CAS #70-30-4

[

b. If .you know or have any reason to believe that 2,3,7,8 TetrachaorodibenzoP-Dioxin (TCDD) or any congeners of TCDD may be present in your effluent then give a brief description of the condit/ons for its presence below and then proceed to Item No. 10c below. If you do not have any reason to believe that TCDD may be present in your effluent then check N/A and proceed to Item No. 10c below.

X N/A

c. If you checked N/A in both Item Nos. 10a and 10b above, then proceed to Item No. 11. Otherwise you must complete one analysis of a composite sample of each process wastewater outfall for Dioxin /Furan compounds. An additional sample of sludge from the wastewater treatment system must also be analyzed. The samplen shall be analyzed and reported for congeners of chlorinated dibenzo -p- dioxins and dibenzofurans and also reported as toxicity equivalents (TEQ) based on the relative toxic equivalence factors provided in interim Procedures for Estimatina Riska Associated with Ernosures to Mixtures of

! chlorinated Dibenro-o-Dioxins and Dibenzofurans (CDD's and CDF's) and 1989 Undate. EPA /625/3- 89/016, March 1989. TABLE 7 is provided to f

report the - results of the congeners listed below in parts per quadrillion (ppq) for wastewater and parts per trillion (ppt) in j sludges. The analyses should be made using EPA method 1613 or an equivalent method if approved by the TNRCC.

REVISED 13/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-12 L

TABLE B-8 Outfall Wastewater Sludge Compound Concen- Equiva- Concen- Equiva Equivalent tration lents tration lents MAL ~

Factors (ppq) (ppq) (ppt) (ppt) (ppq) 1 2,3,7,8-TCDD 1 10.0 1,2,3,7,8-PeCDD 0.5 50.0 2,3,7,8-HxCDDs 0.1 50.0 2,3,7,8-TCDP 0.1- 10.0 1,2,3,7,8-PeCDP 0.05 50.0 2,3,4,7,8-PeCDF 0.5 50.0 2,3,7,8-HxCDFs 0.1 50.0 Total EXAMPLE:

Compound Concen- Equiva Equivalent tration lents Factors (ppq) (ppq) 2,3,7,8-TCDD \

1 13 11_.  ;

1,2,3,7,8-PeCDD 0.5 22 L 2,3,7,8-HxCDDs 0.1 17 M 2,3,7,8-TCDF 0.1- 20 2 _,

1,2,3,7,8-PeCDP 0.05 100 5 2,3,4,7,8-PeCDF 0.5 120 fd_ j 2,3,7,8-HxCDFs 0.1 100 19._

{

l Total TEQ 102.7 Test methods utilized must be sensitive enough to quantify the constituents at the Minimum Analytical Level (MAL) speca C4.ed.

l 1

i i

i

(

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECIDlICAL REPORT PAGE B-13

rp -

11. c. Plot 5s En:wsr tha following qus2tions and procu d as directed.

l Are there pollutants listed in Attachment H of this application which I are believed present in the discharge? .

l YES NO X

[ Are there pollutants listed in' Item No. 3.c. on Page No. 2 of the l Industrial 7 Wastewater Permit Application Technical Report which are I l= believed present in the discharge and have not been analytically quantified elsewhere in this application?

YES NO X If NO to both questions then go to Item No. 12 of this attachment.

If YES to either question then proceed as directed below. I l

b. Table B-9 must be completed for pollutants listed in ATTACHMENT H and for ' pollutants related to materials handled on-site (raw materials, intermediate products, products, etc., as listed in Item No.

5 on Page No. 2 of . the : Industrial Wastewater Permit Application Technical Report), which are believed to be present in a wastewater

, discharge.

For. analytical results that are non-det'ect, please report the analytical values as less than the detection level (example: a result that is non-detect with a detection level of 50 ug/l should be reported as "< 50 g/l")

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-14

m TABLE D-9 -

Outfall ,

Number i

-Avg Max of Analytical Pollutant'& CAB Numher- M M Samples Method .

t f

l

)

1

==

l t

o REVISED 12/90 INDUSTRIAL NASTEWATER PERMIT APPLICATION TEQOIICAL REPORT PAGE B-15 1.

(.

l

i2. Tchle B-10 mu::t be complated for all outfalls which discharges only storm water runoff associated with " industrial activity" and are not regulated by a multi-sector general stom water permit (please refer to Attachment K for specific guidance) . The_. discharge must be sampled and analyzed for the

.following pollutants at least Once by grab sample during the first 30 minutes or once by a flow weighted composite sample if equipment is available for i compositing by flows-l TABLE B-10 l J

MAXIMUM VALUES (ma/l) AVERAGE VALUES (ma /1)

Outfall N/A Grab Sample Grab Sample Number Taken Flow Taken Flow of During weighted During weighted Stom First 30 Composite First 30 Composite Events Pollutant Einates Samnle Minutes Sample Samnle Oil and Grease l Biochemical oxygen )

Demand (BOD 5) l Chemical oxygen .l Demand Total Organic Carbon Total Suspended Solids i

Total Dissolved I

' Solids Total Kjeldahl Nitrogen-Nitrate plus Nitrite Nitrogen Ammonia Nitrogen Total Phosphorus pH (Standard Units)

Min Max Min Max MAXIMUM VALUES fua/l) AVERAGE VALUES f ua /l.), M8L pg/l

~ Total Aluminum 30.O Total Arsenic 10.0 p Total Barium _10.0 l ~ Total Cadmium' 1.0

' Total Chromium 10.O

j. Trivalent Chromium N/A l Hexavalent Chromium- 10.0 Total Copper 10.0.

Total. Lead 5.O Total Mercury 0.2 Total Nickel 10.0 Total Selenium- 10.0 Total' Silver 2.0 Total Zine 5.0 REVISED 12/90 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-16 t'

o

13. Table B-11 must be completed for every outfall which discharges only storm  !

water runoff associated with " industrial activity" and is not regulated by a multi-sector general storm water pemit (please refer to Attachment K for specific guidance) . Each discharge must be sampled and analyzed for the following pollutants at least once by grab sample during the first 30 minutes or once by a flow weighted composite sample if equipment is available for composting by flow. Do not include those pollutants listed previously in TABLE B-10

a. Include each pollutant that is limited in a USFPA Effluent Guideline to l which the facility is subject (40 CFR Dart 400 - 471) except those for which the monitoring frequency is less than once per month.

b. Include each pollutant that is limited in an existing TNRCC, NPDES, and/or TPDES permit for process water for the facility except those for which the monitoring frequency is less than once per month.

c. Include each pollutant from TABLES B-2, B-3, and B-4 that ir used at the facility as a feedstock, intermediate, product, coproduct, j byproduct, maintenance chemical or that could in any way contribute to contamination of storm water runoff.

d. Include each pollutant from TABLES B-5, B-7, B-8, and B-9, and ATTACHMENT H that you know or have reason to believe is present in outf alls- containing only stom water runof f. I (1) For pollutants listed from TABLE B-5, either report quantitative data from the analysis of a grab sample or a flow weighted j composite sample or briefly describe the reasons the pollutant is i expected to be discharged. I (2) For pollutants listed from TABLE B-7 (except for: acrolein, acrylonitrile, 2,4 dinitrophenol, and 2-methyl-4,6 dinitrophenol)  !

that are expected to be discharged in concentrations of 10-ppb or greater, you must submit quantitative data from the analysis of

! at_least one grab sample or one flow weighted composite sample.

(3) For acrolein, acrylonitrile, 2,4 dinitrophenol, and 2-methyl-4,6 dinitrophenol, you must submit quantitative data if any of these l four pollutants is expected to be discharged in concentrations of l

100 ppb or greater, J (4) For every pollutant listed from TABLE B-7 expected to be discharged in concentrations greater than 10 ppb (or 100 ppb for the four pollutants listed above) you must either submit quantitative data or briefly describe the reasons the pollutant l is expected to be discharged.

(5) For pollutants listed from ATTACHMENT H, explain why the pollutant is believed to be present and report any analytical data that you have. No additional' analysis is required.

f REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-17

7--; 1 i

l . TABLE B-11

j. MAXIMUM VALUES (ma/1) AVERAGE VALUES (ma/1)

Outfall N/A Grab Sample Grab Sample Number Taken Flow Taken Flow of During Weighted During Weighted Storm First 30 Composite First 30 Composite Events Pollutant Minutes Samnle Minutes Samnle Samoled l

l I

4 l .

REVISED 12/98 INDUSTRIAL NASTENATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-18

p -

14. Please provide the following data for the storm event (s) which resulted in the maximum values for the flow weighted composite sample: Not Applicable

.a. Date of storm event:

b. Duration of storm event.(in minutes):

c. Total rainfall during storm event (in inches):

d. Number of hours between beginning of storm measured and end of previous measurable rain event:

e. Maximum flow rate during rain event (gallons / minute) :

I l

f. Total storm water flow from rain event (in gallons) :  ;

g. Provide a description of the method of flow measurement or estimate:

I 1

l I'

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-19

p. ,

MINIMUM ANALYTICAL LEVELS FOR APPLICATION SCREENING POLLUTANT CASRN* MAL y/1 Suggested Method Aldrin .309-00-2 0.05 608 Alphahexachlorocyclohexane- 319-84-6 0.05 608 Aluminum 7429-90-5 30 202.2 Arsenic' 7440-38-2 10 206.2 Barium 7440-39-3 10 208.2 ,

I Benzene 71-43-2 10 624 Benzidine 92-87-5 50 625 Benzo (a) anthracene 56-55-3 10 625 l

Benzo [a] pyrene 50-32-8 10 625 l

- Betahexachlorocyclohexane 319-85-7 C.05 608 Bis (chloromethyl) ether 542-88-1 ** **

Cadmium 7440-43-9 1 213.2 Carbon Tetrachloride 56-23-5 10 624 Carbaryl 63-25-2 5 632 Chlordane 57-74-9 0.15 608 Chlorobenzene 108-90-7 10 624 Chloroform 67-66-3 10 624 Chloropyrifos 2921-88-2 0.05 1657 Chromium 7440-47-3 10 218.2 l

Hexavalent Chromium 7440-47-3 10 218.4 l l

Trivalent Chromium 7440-47-3 *** ***

p-Chloro-m-cresol 59-50-7 10 625 4,6-Dinitro-o-Cresol 534-52-1 50 625

.p-Cresol 106-44-5 10 625 Copper 7440-50-8 10 220.2 Chrysene 218-01-9 10 625 1

Total cyanide 57-12-5 20 335.2 REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-20 s

POLLUTANT CASRN* MAL ug/l Suggested Method Cyanide, Amenable to Chlorination 57-12-5 20 335.1 l Cyanide,_ Weak Acid Dissociable 57-12-5 20 4500-CN I.

4,4'-DDD 72-54-8 0.1 600 4,4'-DDE 72-55-9 0.1 608 4,4'-DDT 50-29-3 0.1 608 2,4-D 94-75-7 10 615 Danitol 39515-41-8 **** *****

Demeton 8065-48-3 0.20 1657 Diazinon 333-41-5 0.5 1657 Dibromochloromethane 124-48-1 10 624' 1,2-Dibromoethane 106-93-4 2 618 Dieldrin 60-57-1 0.1 608 1 1,4-Dichlorobenzen 106-46-7 10 625 l 1,2-Dichloroethane 107-06-2 10 624 1,1-Dichloroethylene 75-35-4 10 624 Dicofol 115-32-2 20 617 J Dioxins/Furans (TCDD Equivalents) 2,3,7,8-TCDD 1,2,3,7,8-PeCDD 1746-01-6 10-Sor ppq 1613 ,

2,3,7,8-HxCDDs 40321-76-4 50 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 39227-28-6 50 1,2,3,7,8,9-HxCDD 57653-85-7 50 2,3,7,8-TCDF 19408-74-3 50 1,2,3,7,8-PeCDP 51207-31-9 10 1 2,3,4,7,8-PeCDP. 57117-41-6 50 2,3,7,8-HxCDFs -57117-31-4 50 1,2,3,4,7,8-HxCDP

'1,2,3,6,7,8-HxCDF 70648-26-9 50

-1,2,3,7,8,9-HxCDP 57117-44-9 50  ;

2,3,4,6,7,8-HxCDP 72918-21-9 50 60851-34-5 50 1

4 Endosulfan I_(Alpha) 115-29-7 0.1 608 j Endosulfan 11 (Beta) 115-29-7 0.1 608 Endosulfan sulfate 1031-07-8 0.1 608 I

Endrin 72-20-8 0.1 608 Fluoride 16984488 500 340.3 Gammahexachlorocyclohexane 58-89-9 0.05 608 (Lindane)

REVISED 12/90 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-21 l

POLLUTANT CASRNO MAL ug/l Suggested Method

(:

Guthion 86-50-0 0.1 1657 Heptachlor 76-44-8 0.05 608 Heptachlor Epoxide 1024-57-3 1.0 608 Hexachlorobenzene 118-74-1 10 625 f .Hexachlorobutadiene 87-68-3 10 625 l-1

, Hexachloroethane 67-72-1 20 625 Hexachlorophene~ 70-30-4 10 604.1 l Lead 7439-92-1 5.0 239.2 l Malathion 121-75-5 0.1 1657 l i Mercury- 7439-97-6 0.2 245.1 Methoxychlor 72-43-5 2.0 617 Methyl Ethyl Ketone 78-93-3 50 624 i

Mirex 2385-85-5 0.2 617 Nitrate-Nitrogen 14797-55-8 1000 352.1 l

Nickel 7440-02-0 10 249.2 Nitrobenzene 98-95-3 10 625 N-Nitrosodiethylamine 55-18-5' 20 625 N-Nitroso-di-n-Butylamine 924-16-3 20 625 Parathion 56-38-2 0.1 1657 Pentachlorobenzene 608-93-5 20 625 Pentachlorophenol 85-01-8 50 625 Phenanthrone 87-86-5 10 625 Polychlorinated Biphenyls (PCBs)

PCB-1232

.PCB-1242 1336-36-3 1.0 608 PCB-1254 1336-36-3 1.0 PCB-1221 1336-36-3 1.0 PCB-1248 1336-36-3 1.0 PCB-1260 1336-36-3 1.0 PCB-1016

~

1336-36-3 1.0 1336-36-3 1.0 Pyridine. 110-86-1 20 625 Selenium- 7782-49-2 10.0 270.2 Siver 7440-22-4 2.0 272.2 1,2,4,5-Tetrachlorobenzene 95-94-3 20 625 Tetrachloroethylene 127-18-4 10 624 REVISED 12/98 INDUSTRIAI. WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE B-22

r- .

l POLLUTANT CASRN* MAL ug/l Suggasted Method Toxaphene 8001-35-2 5.0 608

- 2,4,5-TP .(Silvex) 93-72-1 2.0 615 i-Tributyltin 688-73-3 0.010 TNRCC 1001 2,4,5-Trichlorophenol 95-95-4 50 625 l l

Trichloroethylene 79-01-6 10 624 1,1,1-Trichloroethane 71-55-6 10 624 TTHM-(Total)

Chloroform 67-66-3 10 624 Bromoform 75-25-2 10 Dichlorobromomethane 75-27-4 10 Chlorodibromomethane 124-48-1 10 vinyl chloride 75-01-4 10 624 Zinc 7440-66-6 5.0 289.2

• Chemical Abstracts Service Registry Number Hydrolyzes in water. Will not require applicant to analyze at this time.

• • • Trivalent Chromium (Cr) deterTnined by subtracting Hexavalent Cr from Total Cr.

• • • • ' EPA procedure not approved. Will not require applicant to analyze at this time.

' REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPt.1 CATION TECHNICAL REPORT PAGE B-23

1 i

. ATTACEMENT E RECEIVING WATERS All applicants must submit USGS quadrangle maps showing the location of the facility as and the discharge point (s) and/or the land treatment / land application area, as appropriate. If this is an application for a discharoe permit, USGS quadrangle maps must be submitted that depict the discharge route for three (3) miles from the point of discharge (or until a classified segment as defined in 30 TAC Chapter 307, Appendix C, Texas Surface Water Quality Standards is reached).

The permittee should retain a copy of the infomation sube.itted with this Attachment for reference in subsequent applications.

APPLICATIONS FOR A PERMIT.TO DISPOSE OF ALL WASTEWATER BY LAND DISPOSAL ARE NOT REQUIRED TO COMPLETE ATTACHMENT E, SECTION 1 OR 2.

SECTION 1 DESCRIPTION OF RECEIVING WATERS If all outfalls do not enter the same reed ring water, SECTION 1 must be completed for each receiving water. The outfalls that flow into each receiving water should be listed.

OUTFALL NUMBER (S) 001. 002. 003. 004

1. Is tl.ere a surface water intake for domestic drinking water supply located within 5 (five) miles downstream from the point / proposed point of discharge?

YES X NO.

If YES, identify owner of the drinking water supply and accurately locate it on the USGS 7.5-minute topographic map.

2. For discharges into tidally affected waters, Not Applicable a) What is the width of the receiving water at the outfall?

feet b) Are there oyster reefs in the vicinity of the discharge?

s If YES, give approximate distance from outfall(s). feet

3. Is the discharge directly into (or within 300 feet of) a classified segment as defined in Appendix C or a partially classified water body as defined in Appendix D of the Texas Surface Water Quality Standards (30 TAC 307.10)?

YES If YES, stop here. SECTION 1 is complete. It is not necessary to complete SECTION 2.

X NO Check NO if the discharge goes into a watercourse such as a creek or tributary prior to flowing into a classified segment and then complete Items 4 and S. (Complete SECTION 2 only if appropriate.)

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE E-1

7 -

,0UTFALL NUMBER (S) 001. 002. 003. 004 The following questions refer to the Immediate receiving water (e.g., a drainage ditch, a stream, a lake, a bay, etc.). Check the box which best describes the first receiving water -into which the discharge will flow after it leaves the outfall and answer any associated questions.

4. The receiving water can best be described as:

a. ( ) Open Bay: Name

b. ( )' ' Tidal Stream, Bayou, or Marsh: Name

.c. (X) Lake or Pond: Name Souaw Creek Reservoir (1) Surface area 3.300 acri.s (2) Average depth of the entire water body 46 feet (3) Approximate average depth of water body within a 500 foot radius of the discharge point 25 feet

d. () Stream QR / ) Man-made Channel or Ditch:

Name/ Number (1) Stream or Channel Type: Characterize the area upstream of the discharge by checking one of the boxes below. (For a new discharge, characterize downstream area.)

(a) () Intermittent (dry for at least one week during most years)

(b) []

, Intermittent with Persistent tools (enduring pools

containing sufficient habitat to maintain significant aquatic life uses)

(c) () Perennial (normally flowing)

(2) Characterize the stream channel modifications (check as appropriate):

() channelized [-] dammed [] banks rip-rapped

(] leveed -[ ] concrete lined [] others, specify:

1 (3) - List 'the name' (s) of any perennial streams which join the receiving water within three miles downstream of t% discharge point:

1

,tEVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE E-2

p -

(4) Do the rscalving wster chtrcctorietica changa within three miles downstream of the discharge? (e.g., natural or man-made dams, ponds, reservoirs, etc.)

4 YES NO If YES, state hows i

1 (5) Basis of ficw assessment (for answer to item d(1)) : [] USGS flow records, '[ ] personal observation, [] historical observation of adjacent landowner (s), [] other, specify (6) General observa3Jons of water body during normal dry weather conditions:

-Date and time of observation:

Was water body influenced by storm water runoff during

-observations?

i 1

e. [' ] Freshwater Swamp or Marsh: Name )

f. [ ] Other, Specify J

5. General Characteristics of Water' Body:

a. Is the receiving water upstream of the discharge or proposed I

' discharge site influenced by (check as appropriate):

-[] oil field activities [ ] urban runof f

[X] agricultural. runoff [] septic tanks

[] upstream discharges [] others, specify:

b. Uses of water body (observed or evidences of) (Check as appropriate):

[X] livestock watering [X] contact recreation  ;

[X] _non contact recreation [X] fishing

[ -] domestic water supply [X] industrial water supply

.[] irrigation withdrawal [] navigation

[X] picnic or park activities

[ ] others, specify:

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE E-3 S -

. c. Salset ona of tha following to baat dascriba tha testhatics of the receiving water and the surrounding area (check one):

() Wilderness: outstanding natural beauty; usually wooded or unpastured area; water clarity exceptional (X) Natural Area ' trees and/or native vegetation common; some development evident (from fields, pastures, dwellings); water clarity discolored.

() common settina: not offensive, developed but uncluttered; water may be colored or; turbid

( ) Offannives stream does not enhance aesthetics; cluttered; highly developed; dumping areas; water discolored i

l i

l l

IEilSED 12/98 INDUSTRIAL WASTEWATER SERMIT APPLICATION TECHNICAL REPORT PAGE E-4 3-

ATTACHMENT E i

RECEIVING WATERS I All applicants must submit USGS quadrangle maps showing the location of the facility as and the discharge point (s) and/or the land treatment / land application area, as appropriate. If this is an application for a discharoe permit, USGS quadrangle maps must be submitted that depict the discharge route for three (3) miles from the point of discharge (or until a classified segment as defined in 30 TAC Chapter 307, Appendix C, Texas Surface Water Quality Standards is reached).

The permittee should retain a copy of the information submitted with this Attachment for reference in subsequent applications.

APPLICATIONS FOR A PERMIT TO DISPOSE 00' ALL WASTEWATER BY LAND DISPOSAL ARE NOT REQUIRED TO COMPLETE ATTACHMENT E, SECTION 1 OR 2.

SECTION 1 DESCRIPTION OF RECEIVING WATERS If all outfalls do not enter the same receiving water, SECTION 1 must be completed for each receiving water. The outfalls that flow into each receiving water should be listed.

OUTFALL NUMBER (S) 005 i

1. Is there a surface water intake for domestic drinking water supply located within 5 (five) miles downstream from the point / proposed point of discharge? l YES X NO. I l

If YES, identify owner of the drinking water supply and accurately locate it I on the USGS 7.5-minute topographic map.  !

2. For discharges into tidally affected waters, Not Applicable a) What is the width of the receiving water at the outfall?

feet ,

b) Are there oyster reefs in the vicinity of the discharge?

If YES, give approximate distance from outfall(s). feet

3. Is the discharge directly into (or within 300 feet of) a classified segment as defined in Appendix C or a partially classified water body as defined in Appendix D of the Texas Surface Water Quality Standards (30 TAC 307.10)?

X YES If YES, stop here. SECTION 1 is complete. It is not necessary to complete SECTION 2.

NO Check NO if the discharge goes into a watercourse such as a creek or tributary prior to flowing into a classified segment and then complete Items 4 and S. (Complete SECTION 2 only if appropriate.)

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE E-1

7 l

,0UTFA11 NUMBER (S)'

The following questions refer to the Immediate receiving water (e.g.,

~

a drainage ditch, a stream, a lake, a bay, etc.).. Check the box which best describes the first . receiving water into which the discharge will flow after it leaves the outfall and answer any associated. questions.

4. The rece'iving water can best be described as:

I

a. ( ) Open Bay: Name j

.i

b. ( ) Tidal Stream, Bayou, or Marsh: Name '!

c. ( ) Lake or Pond: Name (1) Surface area acres (2) Average depth of the entire water body feet

~(3) Approximate average depth of. water body within a 500 foot radius of the discharge point feet i 4

d. ( ) Stream QR ( ) Man-made Channel or Ditch:

Name/ Number (1) . Stream or Channel Type: Characterize the area upstream of the discharge by checking one of the boxes below. (For a new discharge, I characterise downstream area.)

(a) [] Intermittent (dry for at least one week during most years)- J l

(b) []

Intermittent with. Persistent Pools (enduring pools containing sufficient .

l habitat to maintain significant aquatic life uses) l (c) [] Perennial (normally flowing)

(2) Characterize the stream channel modifications (check as j appropriate):

]

[ l' channelized- [' ] dammed [] banks rip-rapped

[] leveed _ [] concrete lined [] others, specify: )

1 (3) List the name (s) of'any perennial streams which join the receiving l water within three miles downstream of the discharge point:

REvIsso 12/pe INDUSTRIAL WASTRWATER PERMIT APPLICATION TECHNICAL REPORT - PAGE E-2

f ,

l f _ .

(' (4) .Do the racsiving' water characterictics changa.within three miles

} downstream of the discharge? (e.g., natural or man-made dams, ponds, , reservoirs, etc. ) -

l YES NO- _ If YES, state how:

(.

l-(5) Basis of flow assessment (for answer to item d(1)): () USGS flow records,-( ) personal observation, [-] historical observation of adjacent landowner (s), [] other, specify.

i (6) General observations of water body during normal dry weather conditions:

Date and time of observation:

Was water body influenced by storm water runoff during I

observations? j

)

e. () Freshwater Swamp or Marsh: Name

f. [ ] Other, Specify l

S. General Characteristics of Water Body

a. Is the receiving water upstream of the discharge or proposed .

discharge site influenced by (check as appropriate):

() oil field activities [ ] urban runoff 1 (X) agricultural runoff () septic tanks

[ ] upstream discharges [] others, specify:

b. Uses 'of water body (observed or evidences of) (Check as appropriate):

( l' livestock watering

( ) contact recreation

[] non contact recreation [] fishing l' .( ) domestic water supply () industrial water supply

.() irrigation withdrawal [] navigation

(-1 picnic or. park activities

(] others, specify:

i

- REVISED 12/98 _ INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT FAGE E-3 L m_

(

l .

, .c. Salset ons of tha following to bast'dascribe tha sesthstics of the' receiving water and the surrounding area (check one):

l

[] Wilderness outstanding natural beauty; usually wooded or unpastured area; water clarity exceptional

[X] Natural Areas trees and/or native vegetation common; some development evident (from fields, pastures, dwellings); water j clarity discolored.

[] common settina: not offensive, developed but uncluttered; water may be colored or turbid

() Off=naiver stream does not enhance aesthetics; cluttered; highly developed; dumping areas; water discolored 4

1 l

l 1

l j

i i

I i

l i

l-l t

t l

l l

REVISED 12/98 . INDUSTRIAL NASTEWATER PEltMIT APPLICATION TECHNICAL REPORT PAGE E-4 w.

l

, ATTACHMENT F i

SEWAGE SLUDGE MANAGEMENT AND DISPOSAL I

This attachment.is for the management and final disposal of sewage sludge from your facility. Please answer all ' questions and provide all the information r required.

I Under some circumstances (as directed in this attachment), you may be required to submit the SEWAGE SLUDGE TECHNICAL REPORT as a supplement to this application.

Please refer to the APPLICATION INSTRUCTIONS FOR WASTEWATER / SLUDGE. PERMIT for methods of obtaining the SEWAGE SLUDGE TECHNICAL REPORT.

l Is this a new permit application or an amendment permit application?

YES NO X If YES, complete item 1.

Is this an application (new, amendment or renewal) for a facility discharging into the Lake Houston Watershed?

YES NO X.__ If YES, complete item 1.

Note that Lll permit applications for facilities that discharge to Segment Nos.

.1002,,1003, 1004, 1008, 1009, 1010, 1011, and 1015 are required to complete item

1. The Lake Houston Watershed is defined in 30 TAC Section 311.31 as the entire drainage area of Lake Houston, with the exception of that portion of the drainage basin of the' West Fork of the San Jacinto River which lies upstream of the Lake Conroe Dam.

1. SLUDGE MANAGEMENT AND DISPOSAL Provide a solids management plan that includes:

a. The dimensions and capacities of all sewage sludge handling and treatment units and processes.

b. Calculations showing the amount of solids generated-at design flow and at 75 percent, 50 percent and 25 percent of design flow.

c. ~ Operating range for mixed liquor suspended solids in the treatment process based on the projected actual and design flow expected at the facility.

d. A description of the procedure and method of solids removal from both the wastewater and sludge treatment processes,

e. Quantity of solids to be removed from the process and schedule for removal of solids that is designed to maintain an appropriate solids inventory, l

l f. Identification and ownership of the ultimate disposal site and a j system of documenting the amount of solida disposed of in dry weight form,

g. If the treatment system utilizes facultative lagoons, provide calculations describing the design life of the sludge holding volume of the ponds. Provide the location and depth of any monitoring wells located in the area of and adjacent to the facultative lagoons.

l Describe how the sludge will ultimately be disposed of upon reaching this design life.

Rzvtsso 12/sa- zwousTRIAL wAsTswATER PERMIT APPLICATION TECHNICAL REPORT PAGE F-1 L

F I L

'. ~

.. IThe 2 THRU 9 An REQUIRED FOR AT T. (NEW, ANNNnT , AND RENEWAL) PERMIT l' APPLICATIONS.

H t

2. Is sewage sludge dispoced of at a TNRCC Permitted co-disposal landfill?

I' YES NO X If YES, complete the following:

L

a. Site'name and TNRCC permit number:

b. Owner / operator:

c. Location (include county) :

d. Transported by (truck, train, pipe, other) :

e. If hauled by motorized vehicle, name and TNRCC registration number of hauler:

l  !

f. Method of sludge dewatering (drying beds, etc.) for landfilling and i average percent solids of landfilled sludge:

1 I

I

3. Is sewage sludge transported'to another plant for further treatment and i disposal? I YES NO X If.YES, complete the following l

a. Plant to receive sludge, name and TNRCC Permit No:

i i

b. Transported by struck, pipe, etc.) :

If hauled'by motorized vehicle, provide Transporter's TNRCC Registration l number:

c. Attach a written statement or a copy of contractual agreements confirming ll that-the plant identified above will accept and be responsible for the sludge from the plant for the life of.the permit (at least five years).

l 4. . Are you requesting to continue the current authorization in your existing lL permit to. beneficially land apply sewage sludge at this site or a site under L your direct control?

YES NO_L l

l REVISED 12/90. INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE F-2 6- "

• Are you rsquasting a nsw cuthorization to bsnaficially land apply sawags sludga at this cito or e sits under your direct control?

YES NO X j

If YES to either question, provide the information required in the SEWAGE SLUDGE TECHNICAL REPORT.

If NO to both questions and your sewage sludge is beneficially land applied, provide the following information: Not Applicable

a. Reclamation; Soil Conditioning;

b. Transported by:

Transporter's TNRCC Registration Numbers

c. Transported in: liquid semi-liquid semi-solid solid state

d. Location of disposal site (include county) and name of owner:

e. Site name end TNRCC Registration Number

5. a. Are yc.,0 currently authorized in your existing permit to utilize composting of sewage sludge at this site or for a site under your control? l YES NO_X___,If YES, provide the fc.1.owing:

(1) Date operation commenced:

(2) Location of operations (3) Type of bulking agent:

(4) Approximate amount of sludge compostedt (5) A brief description of composting processi (6) Identify any significant changes in composting process since the last permit issuance REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE F-3

b. Ara.you rsqussting authorization to compost sawxge sludge?

[ '

YES. -NO_X ,,If'YES, provida the information required in the LSEWAGE SLUDGE TECHNICAL REPORT.

6. a. Are.you currently authorized"in your existing permit to utilize

~

l marketing;and' distribution.of sewage sludge at t!is site or for a site under your control? YES N O _ Z, ,_

i

-If YES'and you received authorization prior to August 19, 1993, provide the information required in the SEWAGE SLUDGE TECHNICAL REPORT.

If YES and;you received. authorization after August 19, 1993, or your 1 sewage. sludge is marketed and distributed by someone else provide-the. .{

following infortaation: 1 i

(1) TNRCC permit number:

('2 ) Site used for distribution storage center: 3 i

~(3) Type of storage:

J

, .(4) Type of. treatment:

. (5) . ' Type of record keeping

b. -Are you requesting authorization to market and distribute sewage sludge at this facility'or a facility under your direct control?

YES. NO,X If YES, provide the information required in the SEWAGE' SLUDGE TECHNICAL REPORT. i

, 7 .- a .' Are you currently authorized in your' existing permit to utilize

- surface disposal of sewage sludge at this site or a site under your direct control?

YES NO X If YES and you received authorization prior to August 19, 1993 provide the'information required in the SEWAGE SLUDGE TECHNICAL REPORT.

If YES and you received authorization after August 19, 1993, provide the-following information:

'(1) Site name and TNRCC permit numbert 1(2) Owner / operators (3) Locations (4) Transported by (truck, train, pipe, other) :

(5) .If hauled by motorized vehicle, name and TNRCC Registration

' Number of tranporter:

REVISED 12/98. INDUSTRIAL WASTEWATER PERMIT APPLICATION TECIGIICAL REPORT PAGS F-4 r

n

]

(6) Mathod of ciudga dtwztering (drying bads, etc.) for landfilling and avsrcg3 parcznt rolida of landfilled sludge:

.(7) Describe the type of landfill (e.g., trench, aerial) i d.

Are you. requesting authorization to surface dispose sewage sludge at this site or site under your direct control?

YES NO 'If YES, orovide the information required in the SEWAGE SLUDGE TECHNICAL REPORT.

8. Are you currently authorized in your existing permit or are you seeking authorization to utilize sludge lagoons on property owned and/or under your direct control?

YES NO X If YES, ptovide the following information,

a. Number of lagoons: , j l

b. Surface area of each lagc_.a: _,_,y, Average depth of each lagoon:

. c. Locations i

l

d. Pond lining or plans for lining:

e. Depth to shallowest groundwater:

Provide a profile of soil types encountered down to the groundwater table.

f. Describe method to control extraneous surface water from entering site:

g. Provide a closure plan for the site,

h. If the site includes monitoring wells, provide information including

-location, depth of wells and monitoring results,

i. Ultimate method for sludge disposal:

.j. Provide a schedule for removal of solids. If storage time exceeds 2 years, justification for on-site storage will need to be provided. If storage time' exceeds 5 years, complete the SEWAGE SLUDGE TECHNICAL REPORT.

REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE F-5

l ATTACHMENT H g

i- HAZARDOUS SUBSTANCES REQUIRED TO BE IDENTIFIED IF EXPECTED TO BE PRESENT l

Attachment H is a list of hazardous substances which are required to be identified d by the applicant if expected to be present in any wastewater discharged or '

disposed of via this permit. Please check all substances listed below which are expected to be present in the effluent. if none of the substances listed below are expected to be present then please check the following statement to verify that l all of the hazardous substances listed in Attachment H have been reviewed.

l X All of the hazardous substances and toxic pollutants listed in Attachment j H have been reviewed for possible presence in the effluent discharged / disposed of j via the proposed pemit.

l 1

l ToxicPollutant Asbestos Hazardous Substances Acetaldehyde Kepone Allyl alcohol Mercaptodimethur Allyl chloride Methyl mercaptan Amyl acetate Methyl methacrylate Anilin Mevinphos

. Benzonitrile Mexacarbate Benzyl chloride Monoethylamine Butyl acetate Monomethylamine Butylamine Naled Carbofuran Naphthenic acid Carbon disulfide Nitrotoluene Coumaphos Phenolsulfonate Cresol Phosgene Crotonaldehyde Propargite Cyclohexane Propylene oxide Dicamba Pyrethrins Dichlobenil Quinoline Dichlone Resorcinol 2,2-Dichloropropionic acid Strontium Dichlorvos Strychnine Diethylamine styrene Dimethylamine 2,4,5-T Dinitrobenzene (2,4,5 Trichlorophenoxyacetic acid)

Diquat TDE Disulfoton (Tetrachlorodiphenylethane)

Diuron Trichlorofan Epichlorchydrin Triethylamine Ethion Trimethylamine Ethylene diamine Uranium Formaldehyde Vanadium Furfural Vinyl acetate l Isoprene Xylene Isopropanolamine Xylenol Zirconium l

REVISED 12/98 INDUSTRIAL WASTEWATER PEMIT APPLICATION TECHNICAL REPORT PAGE H-1

i l

l 1

ATTACHMENT I POLLUTION PREVENTION This attachment is intended to gather information on your facility's efforts for pollution prevention. Please answer all questions of this attachment and provide all the infonnation required with your application.

1. Have you instituted or continued programs directed toward pollution prevention (P2), especially to incorporate water conservation, source reduction, waste minimization, and/or recycling?

YES X NO If YES, provide a brief summary of the program (s) that incorporate water conservation, source reduction, waste minimization, recycling, and/or any other elements that are similar to the suggestions above. PLEASE DO NOT SUBMIT DETAILED PLANS OR REPORTS WITH THIS APPLICATION.

Camanehe Peak S.E.S. carticinated in the TNRCC's " Clean Industries 2000" and ham ca==4tted to reducina hazardous waste ceneration in the year 2000 by at least 50% from 1987 annaration rates (19 tons). In adAltion. Ca=anche Peak S.E.9. further ca-4tted to a more accreasive Small Ouantity Source Reduction / Waste Min 4mization to reduce hazardous waste ceneration 25% by vaar 2003 as comoared to 1997 annatities, resultina in an annual aeneration not to exceed 8 tons.

2. HAve you collected and compiled reliable data to record trends of actual reductions of pollutants in either pounds per day or percent reductions?

YES X NO If YES, provide a brief sunnary of the actual or percent reductions. PLEASE DO NOT SUBMIT DETAILED PLANS OR REPORTS WITH THIS APPLICATION.

Hazardous waste canarated durina 1998 totaled accror4matelv 9.9 tons.

This cuantity reflects a 74% reduction from 1987 ceneration rates.

l REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL FEPORT PAGE I-1 L

3. Th3 TNRCC scourigap facilities to davalopa c.nd implf; mint nrw pollution prevantion l programs or modify axisting pollution prevantion progrEm2 for ycur facility.

Following are some components that may.be considered when developing a pollution prevention program. PLEASE DO NOT SUBMIT ANY RESPONSE FOR THIS ITEM, THIS IS PROVIDED IN THE APPLICATION FOR INFORMATIONAL PURPOSES ONLY.

a. Develop a Pollution Prevention Mission Statement, incorporating ecoromic

-growth and ensuring environmental protection of your watershed, b .' Develop Your Industry's Policy Statements on Pollution Prevention.

(1) Promote Water Conservation, Source Reduction, Waste Minimization and Recycling.

J (2) Apply policy statements-to any and all departments and processes of your )

industry.

l

c. Incorporate P2 plans and best management practices as part of industrial process and wastewater plant designs.

d. Learn about Pollution Prevention Opportunities for Your Specific Industry, (1) Research potential areas where P2 may be incorporated into your industry's processes and operations through a P2 self-assessment.

(2) Provide P2 information, contact persons and telephone numbers to your management and other similar industries.

(3) Use the internet as a resource. I

e. Serve as a. Role model.

(1) Coordinate recycling efforts with the city government and between industries.

(2) Arrange an. industrial user mentor program.

(3) Provide meeting facilities for other industries in your watershed and other industry groups.

f. Use the Media and Local Resources.

(1) Request local universities provide technical expertise.

(2) Send public service announcements to newspapers, radio, and local television stations to communicate your industry's purpose in P2 activities, meeting times and locations.

(3) . Ensure the success of your programs by involving your community, including other industry organizations and asking for feedback.

g. Educate Your Industry and Community.

(1) Train staff (including management) and introduce P2 principles and

, activities during the process operations and wastewater treatment plant.

l l

(2) Request that . indust.ry leaders influence and support P2 curriculum and terminology taught at all levels in community schools and universities, l

l h. Establish Reliable Data (1) Collect and compile reliable data to record trends of actual reductions of pollutants in either pounds per day or percent reductions.

(2) Develop, implement, and track the success of your organization's P2 plan as an example for other industries.

REVISED 12/98 INDUSTRIAL NASTEWATER PERMIT APPLICATION TECHNICAL REPORT PAGE I-2

fk

'i. 'Evalu".ts Why Pollution Prsysntion is Important to Your Industry. l (1) Knowing that water is a limited resource, establish rationale for your industry to save water, j (2) Prepare for Total Maximum Daily Loads (TMDLs) that may.be developed in l your watershed'- TMDLs define the. limits to what a watershed can receive.

1

'(3)' Assist other industrias in your watershed to encourage them to reduce ]

L pollutant contributions.

]

i

j. Optimize the efficiency and extending the useful life of the wastewater '

plant. The following items should be considered: 'j

. (1) The influent' loadings, flow and design capacity.

(2) The effluent quality and wastewater plant performance.

(3)' .The age and expected life of the wastewater plant's equipment.

(4) ' Bypasses and overflows of the wastewater plant.

(5) . New developments at the facility.

' '( 6 ) Training plans and status.

l (7) The financial status of the facility. I (8) Preventative maintenance programs and equipment condition.

(9) An overall evaluation of conditions at the facility.

I REVISED 12/98 INDUSTRIAL WASTEWATER PERMIT APPLICATION TECHNICAL REPORT. PAGE I-3 Lm-

l l

1 l

l l

l 1

Attachment 1 Administrative Report; Item 2.e.

Technical Report; item 1 Proposed Changes To Permit No. 01854 -

Texas Utilities Electric Company Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854 f

Attachment 1 Proposed Changes to Permit No. 01854 (Response to item 2.e. of the Administrative Report)

Texas Utilities Electric Company (TU Electric) offers the following comments as the Company's changes to the previously mentioned permit:

1. Outfall 003. Sanitarv Sewage Effluent: In a letter dated 1 August 1996, TU Electric notified the Commission of its intent to replace the existing sewage  ;

treatment plant associated with Outfall 003 with the new treatment facility. This i modification was complete as of January 1997 and the monitoring requirements have been conducted since then in accordance with the Commission's guidance (as described in the referenced notification letter). The replacement facility provides disinfection by ultraviolet (UV) radiation as a substitute for the previous chlorination system. The location for the discharge of the treated sewage effluent via Outfall 003 did not change. Based on the Commission's guidance, the Company proposed that chlorine limits be replaced with the following fecal coliform monitoring and reporting limitations and requirements:

Daily Average Limit = 200 cfu/100 mi, reported as the geometric mean of the values for the effluent sampleu collected during the calender month,

. Daily Maximum Limit = 400 cfu/100 ml,

. Sample Type = grab, and

- Monitoring Frequency = 1/ week.

2. Outfall 003. Altemate Disinfection: In the event that the Ultra Violet disinfection system is taken out of service, TU Electric proposes to include alternate chlorine disinfection and monitoring limits on the permit. Based on the chlorine limits contained in the EPA-NPDES Permit, the Company proposes these limits to be as follows: The effluent shall contain chlorine residual of at least 1.0 mg/l and a maximum chlorino residual of 4.0 mg/l after a detention time of at least 20 minutes (based on peak flow), and shall be monitored five times per week, by grab sample.

3. Outfall 003. Flow Monitoring Freauency: The flow ~of the sanitar,< oewage effluent is monitored and recorded daily from a flow totalizer or an installed weir. With a flow totalizer in place, the Company requests authori2.ation to average the flows for weekends and holidays. This average would be calculated from the totalizer flow reading taken the day after the weekend or holiday.

l

4. Outfall 005.' Waters Contained in Sauaw Creek Reservoir (Discharge To Lake Granburv): The referenced outfallis a component of the existing TNRCC

- Wastewater Discharge Permit but is absent on the EPA-NPDES Permit; however, in a letter dated 5 December 1994; TU Electric requested its inclusion in the facility's NP" DES Permit. To avoid any confusion, the Company wishes to restate its position that this outfall is essential to the successful operation of this facility and should be included in the forthcoming TPDES Permit.

5. Other Reauirements. Provision 5: Regulations at 40 CFR 423.13(b)(2) allows simultaneous multi-unit chlorination, and the requirements of this Provision under-

" Total Residual Chlorine" correctly reflects this regulation. Nevertheless, the second paragraph under " Free Available Chlorine Analysis" prohibits such a practice. TU Electric Believes this inconsistency can be eliminated if the second I paragraph under " Free Available Chlorine Analysis"is amended to read "Neither  !

. free available chlorine nor total residual chlorine may be discharged from any unit l for more than two hours in any one day". No changes would be required under  !

" Total Residual Chlorine".

6. Part II, Section M of the existing EPA-NPDES Permit, entitled " Raw Water i

Intake", requires a study of impingement and entrainment of organisms at the l circulating water intake structure in Squaw Creek Reservoir pursuant to Section 326 (b) of the Clean Water Act. This program was successfully completed on 29 -

September 1995, and the USEPA issued an approval letter on 13 December i 1995; therefore, the Company proposed that the statement requiring the study be deleted.

J.hm-

If J l

l l l.-

l l

l l

I l

.{

i I

i Attachment 2 l

Administrative Report; Item 8. a.

Technical Report; items 3. g. (4) and 16. h.

Attachment E, Page 1 USGS Site Map Texas Utilities Electric Company 1 Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854 l

l l

I-1 l

f

{

l l

i l

l l

Attachment 3 Technical Report; Item 3. g.

Facility Map Texas Utilities Electric Company Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854:

[;

I I

1 Attachment 4 Administrative Report; Item 10. a.

Copy of Submitted Application Fee Check Texas Utilities Electric Company Comanche Peak Steam Electric Station '

TNRCC-TPDES Permit No. 01854 q 1

L

!"!!7USERVlCES 3 :

-de-- SAN ANGELO NAflONN, ASSOC. 1001001353 DALLA $, TEXAS CHECK NO. 1001001353

. o EXACTLY TWO THOUSAND FIFTEEN AND N0/**********************************

A Y

1 TO THE ORDER OF l DATE CHECK AMOUNT TEXAS NATURAL RESOURCE 04/07/99 *******2,015.00 l CONSERVATION CONNISSION voto AFTER 90 DAYS P O BOX 13087 l AUSTIN TX 78711-3087 TEXAS UTILITIES SERVICES INC.

B000956653 AI l ii' 40010013 5 3ti' s:1 L L 300880s: li'O E 3000 L L 7 E En*

"!7USERVlCES DALLAS, TEXAS TUEi 006393558 04/07/99 1001001353 Daft afvolcM:lunir am Descen0N Gfl008 DISCOUl# NET l1 33hlh9 WP033199 2015hD dOO 201500 ll i I

..**..* l I

l I

li li l l

I I I i I I I I

\ 79 IC ICn GneN6 0 t'rV{' N0. ,

l (lWh i i i I I l I i i ' '

i i

1 i l

l ll ' '

l!

l i l

l

' ' l l ll li '

I I

' ' l l

' ' i i I I I I

I I 1 l l I I  :

l 1 I I I I

I I i 1 I I I I

I I i i 4 I I I I I I i 1 ll l '

l i

l i

l' l'. l l i i I I i 1 I 3 l l ll 3 I l l I

I I I l l I I I I Lll I t l l 201500 000 201500 l THE ATTAesEocHEcK is iN eavuswr TOTAL > j l FORITEMS DESCRISED A80VE. ,

L

r3 e

i Attachment 5 Technical Report; Item 3. a. and 3. e.

General Description

, Texas Utilities Electric Company Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854

< l

C ,

1 l

a TEXAS UTILITIES ELECTRIC COMPANY COMANCHE PEAK STEAM ELECTRIC STATION GENERAL DESCRIPTION The Comanche Peak Steam Electric Station (Comanche Peak S.E.S.) is a two-unit nuclear-powered steam electric generating facility owned and operated by Texas Utilities Electric Company (TU Electric).

The facility is located on the west side of Squaw Creek Reservoir along HWY 56 approximately four and a half (4.5) miles northwest of the city of Glen Rose, Somervell County, Texas. Wastewaters are discharged to Squaw Creek Reservoir; thence to Squaw Creek; thence to the Paluxy River in Segment ]

j No.1229 of the Brazos River Basin; or, to Squaw Creek Reservoir; thence to Lake Granbury in Segment i No.1205 of the Brazos River Basin. Squaw Creek Reservoir is the source of all water used for cooling l and industrial use. When needed, make-up water is provided to the reservoir via a pipeline from nearby i Lake Granbury. Potable water is obtained from groundwater and is delivered by Company-owned on-site wells. i The generating capacity and date of initial commercial operation for each generating unit are as follows:

Mail Caoacity (Mw) Qalg 1 1150 1990 2 1150 1993 Wastewaters produced at the plant site are collected, treated and discharged via six (6) permitted outfalls. TU Electric's operating procedures and wastewater handling practices are designed both to comply with all applicable environmental regulations and to provide operational flexibility wherever practical.

The Company is aware of an increased potential for macro invertebrate invasion of any plant water system. In the event of such occurrence, the Company is prepared to treat its water on a static or flow through basis with either of the following non-oxidizing biocides: BetzDearborn Spectrus CT 1300 [N-alkyl- dimethyllbenzylammonium chloride (Quat) and ethanoll or Buckman Bulab 6002 Poly [oxyethylene(dimethylimino) ethylene (dimethylimino)-ethylene dichloride.

The six (6) permitted outfalls are listed below and a description of the wastewater system pertinent to each outfall follows:

Outfall Tvoe of Wastewater 001 once-through and auxiliary cooling water /previously monitored effluents 002 Safe Shutdown impoundment containing cooling water, low volume wastes (service water), and stormwater runoff 003 sanitary sewage effluent 004 low volume wastewater /previously monitored effluents 005 reservoir discharge i 104 metal cleaning wastes I TPDES Outfall 001 (Once-throuah and Auxiliary Coolinal Water from Squaw Creek Reservoir is withdrawn at the intake structure, treated chemically and then passed through the main condensers or auxiliary heat exchange equipment to condense steam or cool system components. The intake water is treated with sodium hypochlorite to prevent biofouling and sodium bromide as a chlorine enhancer to improve chlorine conversion and thereby reduce chlorine feed L

f +

I Comanche Peak Steam Electric Station General Description Page 2 - 1

-g ,

~

rates. Application of these substances is intermittent and does not exceed the regulatory maximum frequency of two hours / unit / day. A mixture of hydroxyethylidine diphosphoric acid (HEDP)/ polymer and a mixture of phosphorous acid /HEDP is also added as a corrosion / scale inhibitor. This "once through" cooling water, elevated in temperature by the cooling process, is then discharged via Outfall 001 back

. to the reservoir through a submerged discharge structure. A small slipstream, approximately 18.7 MGD, can be diverted through an opened valve for discharge to the Safe Shutdown impoundment (SSI) to provide'make-up'and flow to this structure (see Outfall 002).

TPDES Outfall 002 (Safe Shutdown imooundment)

The Safe Shutdown Impoundment (SSI) is a safety component of the facility required by the Nuclear l Regulatory Commission (NRC) to provide a source of emergency cooling water for safe reactor i

shutdown in the unlikely event of a failure of the Squaw Creek Reservoir dem. This 367 acre-foot impoundment was created by constructing an earthen dam across an arm of the reservoir. The SSI and reservoir are connected by an equalization channel and underwater weir (top elevation 769.5 ft MSL)

located immediately southwest of the SSI dam. Outfall 002 is located in this channel; discharge occurs whenever there is a not flow of water into the SSI. This not flow will normally be achieved by diverting approximately 18.7 MGD of condenser cooling water as makeup to the SSl, if necessary. Storm water runoff from portions of the plant area and surrounding undeveloped area also contribute water to this j impoundment; however, this does not constitute a discharge of the Outfall because a similar quantity '

of runoff enters the reservoir.on the other side of the equalization channel. Therefore, a storm event does not create a not flow out of the SSI. ,

4The Service Water System provides once-through cooling to plant components designated as safety-related reactor support systems by the NRC. To assure the availability of this cooling water under emergency conditions, the water must be extracted from the SSl; it is then circulated through reactor support components and is discharged back to the SSI. NRC regulations require treatment of this safety-related auxiliary cooling system at the Service Water System intake structure to assure its

. reliability. Treatment consists of Betz ClamTrol CT 2 [N alkyldimethylbenzylammonium chloride (Quat); '

dodecylguanidine hydrochloride (DGH); ethylene glycol; isopropanol; othanoll or Buckman Bulab 6002

{ Poly [oxyethylene(dimethyliminio) ethylene (dimethyliminio) ethylene dichloride]} as a non-oxidizing

. biocide; sodium hypochlorite as a blocide; sodium bromide as chlorine enhancer to improve chlorine conversion and thereby reduce chlorine feed rates; and a coordinated system of hydroxyethylidine diphosphoric acid HEDP/orthophosphate/ polyacrylate or polyacrylate co-polymer as a corrosion and deposition inhibitor.

TPDES Outfall 003 (Sanitary Sewaae Effluent)

This effluent is received from Plant potable water systems and is discharged from a normal 0.090 MGD capacity treatment facility that employs the extended aeration, activated sludge retum process for treatment of domestic sanitary sewage. The facility is designed as a single, integral, above ground installation consisting of a surge basin, grinder pumps, aeration basin, circular clarifier, aerobic digester and a sludge holding basin. Treated effluent is routed through an ultraviolet disinfection unit to a 3500 gallon contact chamber then through a V-notch weir to the final discharge. Sludge from the sludge

- holding basin is transferred to a sludge dewatering facility for volume reduction. Dewatering is achieved by gravity flow through porous bags that retain solids while allowing filtrate to be returned to the domestic waste treatment process. All dowatered sludge is retained on-site in containment bins.

1

Comanche Peak Steam Electric Station General Description Page 3 TPDES Outfall 004 (Low Volume Wastes)

Certain low volume wastes may become contaminated with low level radioactive material. These wastes must comply with both TNRCC TPDES effluent limitations, as well as the limitations imposed by the NRC. As a result, two separate low volume waste treatment systems are employed; as described below, one system is dedicated to the treatment of these potentially radioactive wastes and the other treats wastes generated from non-radioactive low volume sources.

The potentially low level radioactive low volume wastes are principally composed of wastewater from floor, equipment, laboratory and sample drains, as well as the periodic drainage of various system components. These wastes are collected in holdup tanks and are then processed as necessary to meet limitations imposed by the NRC Off-Site Doss Calculation Manual (ODCM) and TPDES, respectively.

Treated effluent is collected in a monitoring tank where it is sampled and analyzed for compliance with both TPDES effluent limitations and the NRC ODCM for radioactive parameters. The monitored wastes are then batch discharged via Outfall 004 into the condenser cooling water. The discharge of these potentially low-level radioactive low volume wastes into the condenser cooling water is a practice approved by the NRC.

The non-radioactive low volume wastes from secondary support systems include equipment, floor, laboratory, and sample drains; water treatment wastes from demineralizer regeneration, reverse osmosis (R.O.) systems operation, condensate polisher system and other miscellaneous water treatment blowdown and backwash operations; periodic drainage and flushing of various system components; and intermittent boiler blowdown from the plant's auxiliary boiler. With the exception of one of the two R.O. system wastes which are segregated and treated separately, these low volume wastes and the previously monitored wastes discharge from Outfall 104 are routed to a low volume Waste Management System (WMS). The WMS consists of the following components: surge basin, API oil / water separator, clarifier blowdown and condensate polisher decant basin, and three separate but interconnected low volume waste retention basins with double synthetic liners and leacnate collection systems. The WMS provides for oil and grease removal, suspended solids reduction and pH control. Provisions for in-situ chemical treatment of suspended solids and pH are incorporated through the addition of polymer and acid or caustic. Recirculation / mixing of the wastewater is achieved by either of two recirculation pumps. Interconnecting piping and valves allow wastewater transfer between the three (3) basins to add treatment flexibility. The R.O. system waste stream which is not treated by the method described above is treated in a lined concrete equalization basin and a limestone neutralization basin for pH control and solids reduction. These R.O. system wastes are then commingled with the other treated low volume wastes prior to discharge.

The treated non-radioactive low volume wastes are normally commingled with the wastes which are potentially radioactive and are discharged via Outfall 004 to the condenser cooling water; the commingled waste stream is sampled prior to mixing with the cooling water for compliance with the appropriate effluent limitations. An alternative practice is to discharge the treated non-radioactive wastes via Outfall 004 directly to Squaw Creek Reservoir; this approach produces two separately discharging waste streams. Appropriate physical or mathematical flow-weight compositing is then employed for determining and reporting compliance with Outfall 004 limitations.

TPDES Outfall 005 (Reservoir Discharae)

This outfall is designed to discharge water from Squaw Creek Reservoir via a pipeline to Lake Granbury on an "as needed' basis in response to the varying chemistry of the cooling reservoir. The need for l

Comanche Peak Steam Electric Station General Description Page 4 treatment prior to discharge in not anticipated. The discharge frequency is intermittent and at present is expected to be very infrequent. Present estimates predict an average flow of 24 MGD or less during l discharge events.

TPDES Outfall 104 (Metal Cleanina Wastes)

A retention basin has been dedicated for the storage and treatment of metal cleaning wastes. Metal cleaning wastes are generated by the chemical cleaning of plant equipment and are evaluated for treatability prior to their collection and 9tention in the basin. Unsuitable wastes are treated and/or disposed by alternative methods; e.g., off site contract disposal.

Wastewater in the basin as well as treatable metal cleaning wastes whl;h might be collected in temporary facilities (frac tanks), is treated for metals and pH adjustment prior to discharge via Outfall 104 to the Low Volume Waste Basins associated with Outfall 004. The treat 3d wastes so discharged will be commingled as a previously monitored effluent with the non-radioactive low volume wastes prior to' discharge via Outfall 004.

GENDESC EM 06 98 0

M N

4 Attachment 6 Technical Report; item 3. f.

Water Use Diagram Texas Utilities Electric Company Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854

[l a

G e .

f _

I -

T _

R I A _

O 4 i EOERC

• EG8 .

n )W I 3 t

sD 0

. D HT P TAO J

eL m(SL 3 e 0 0 t t 7 L f e eS I 8 EYA N A

EMC C sS " EAM U VBPE EG B vTE. d I 0(

_ EA N N NNT I

N DETDSI I

R YM ESA S

SK t

)

1 yIpe A S W

L E

TE EDIVCEATRW TG ETDAEO lI I

eAECI ET L A

t

( ADI A I F

T.

OMt F

E l H ECNI t TS EDeTLG 0ATW

/ .

GT NI IDuR9A POI NOA V 3 t 8 -C g F A t 0

1 g F R 0 E ) ) ) ) )

y + 30 V

)

, AEi 1 234 5 t g At ( ( ( (

S Y t g B E

T O

P - 9 2

d e

2 I

8 8

1 K -

1 3 En Y -

EI L p

3 t g f

SL '42 R Cy EA5 EU 5g n OF0 } K IB PT0 AI 4g LA R r

3 8

RE I

TW G S

Y _

NN --

AIO 4 0

i. 4

) 0 PTA 4 li 0

MTS 3 A

(

O lT 4 CIC 0 -

R 1 M0 i T

d L

TM 5 CCA I

ER 1

0 3

g g

M.

0 6 S

E OR P a RLG 4 8 3 3 TEA I99 s

t I 0 t

I g Tg g

)

5 SL L

L TW _

I N ( EA 4 A e P Ng T CMD 9 )

- NI 0 t T a l1 T E 0 2 A l

2 E

S T Eg Tp l .F

.TA 1 E  ;

EA 1 (

MI L e

sZ t I

(

R A

K i

t R

(

6 4

L TS EE H T N I TA EBMI I

TI IL Z 3 _

E SU C TAI AITA 0 R M Rt T AtsW WLNR I /T KR A A T rI LA e LTMU T SAE EET M M T

I VE FE0 l

IEEE DS I

PA '

eo0 eeee .

T W I

E . -

L CH I

' 0 1

1 3

C S a T TN 5 I

' 6 1 6 M 8 E _

' 5 GW" UAM 1

' 3 0 1 A 0 WA S 0 EE S

O aI N 8 ) R SC L 8 3 4 T A N0 s0 2

1

)

T X- uC .

+ t C

2 0

nY 1 T E

3 6

e t ut f t 2 t

P I a

T A . 1 0 I A 4 i

- I l S A I N T EL p 0 E I cL nI OK M

",Ts

• ,A t

I MS T A

l i

G E

E 4 0 8 4

A t

L EW 0

. p 0 .

_' .E AG 3; DE

( 0 M 0 O E I

LR

= E D

t 3 BE _

S 0 AT A TA W 0 OW P _

2 1

mI RO R

3 T

0 8

CV 17 3 4 R 7 D 0 eE mS 3

=_y g g 1 f

ER TE 0 oE = g a 1 AT A

S 7

E3 T

3 GR f

uE oT R A OW l

r .

)

l 1

I I

J Attachment 7 Technical Report, item 15 Once-through Cooling Additives Texas Utilities Electric Company Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854 i

l l

l i

l

Texas Utilities Electric Company Comanche Peak Steam Electric Station l Wastewater Discharge Permit No. 01854 l

Once-through Cooling 1 Chemical Additives

a. Manufacturers Product identification Number: Sodium Nypochlorite

6. Product Use: Blocide(oxidizing)

c. Chemical Composition: NaOCl

d. Product toxicity data: See attached data sheets

e. Classification (non-persistent, persistent or bloaccumulative): NotAvailable

~

f. Product or active ingredient half-life: NotAvailable l

g. Concentration in once-through cooling water: NotAval/able i

h. Frequency of product use: Intermittent use not exceeding 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> / day / unit

r .

SETZ LABORATORIES, INC.

4636 SCMERTON ROAD. TREVCSE, PA 19053 PRODUCT: SLIMICIDE C-70 AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bicassay LC50: 1.9 mg/L No Effect Level: 1.38 Daphnia magna 48 Hour Stat 1c Acute Bioassay LC50: 1.6 mg/L No Effect Level: 0.51 Bluegill Sunfish 96 Hour Static Acute Bioassay LC50: 5.3 mg/L No Effect Level: 2.8 l

BIODEGRADATION 1

NO DATA AVAILABLE MAMMALIAN TOXICOLOGY Oral LD50 RAT: 6,200 MG/KG Dermal LD50 RABBIT: 3,000 MG/KG l'

Skin Irritation Score RABBIT: 8-Eye Irritation Score RABBIT: 53 m

1

MATERIAL SAFETY DATA SHEET NUMBER 15506 FA3E 1 PRODUCT: SLIMICIDE C-70 MANUFACTURER: BETZ LABORATORIES, INC.

.NFPA RATINGS HEALTH: ~3 FIRE: 0 REACTIVITY: 0 OTHER:

SARA RATINGS FIRE: N REACTIVITYs N PRESSURE: N ACUTE: Y CHRONIC: Y DATE PREPARED: '04/19/91 TSN: 000000 THIS-COMPUTERIZED MSDS-CONTAINS THE INFORMATION FROM THE MANUFACTURER'S

. ORIGINAL MSDS SUPPLIED TO TU ELECTRIC IN ACCORDANCE WITH 29 CFR 1910.1200.

.A COPY OF THE ORIGINAL-MSDS IS AVAILABLE THROUGH SAFETY AND INDUSTRIAL HEALTH: 954-5243.

• • • GENERAL PRODUCT.INFORMATION ***

SECTION 1 Trtde Product.Name- :SLIMICIDE C-70 Synonyms :NOT LISTED Mnnufacturer Name :BETZ Manufacturer!s Address :NOT LISTED

' City :TREVOSE State' :PA ZIP :19053-6783 Emargency. Phone Number :800-877-1940 Talsphone :215-355-3300

~ Additional.Information  :

Product application  : WATER-BASED MICROBIAL CONTROL AGENT

• • • INGREDIENTS INFORMATION ***

SECTION 2

• • EXPOSURE LIMIT **

. OSHA ACGIH INGREDIENT'NAME PEL TLV SODIUM HYPOCHLORITE NONE NONE SODIUM CHLORIDE- 'NONE NONE SODIUM HYDROXIDE (CAUSTIC SODA) 2.0 MG/M3 '2.0 MG/M3

~

• • PERCENTAGES **

INGREDIENT NAME HIGH % LOW %

SODIUM HYPOCHLORITE NOT LISTED ON MSDS SODIUM CHLORIDE NOT LISTED ON MSDS SODIUM HYDROXIDE . (CAUSTIC SODA)

- NOT LISTED ON MSDS o

I *

• C.M NUMBERS *

• f INGREDIENT NAME CAS NUMBER i

~ SODIUM HYPOCHLORITE-. '

7681-52-9 SODIUM CHLORIDE -

7647-14-5 SODIUM HYDROXIDE (CAUSTIC-SODA) 1310-73-2 f.

L . I

l l

MATERIAL SAFETY DATA SHEET NUMBER 15506 .: AGE 2 l PHYSICAL / CHEMICAL CHARACTERISTICS ***

SECTION 3 Boiling Point :NOT LISTED ~ l Malting Point :NOT. LISTED l

Spscific. Gravity- :1.217 Vapor. Pressure :22 '

Parcent Volatiles :NOT LISTED Vapor Density (air =1) :ND Evcporation~ Rate  :<1 Compared to  : ETHER = 1  ;

Water Solubility.. :100 l

-Appsarance'and Odor  : YELLOW TO GREEN LIQUID W/ CHLORINE ODOR 1

Additional Information:

PH : AS IS .  :(APPROX.) 12.5 )

VISC CPS 70F :13.2 FREEZE POINT (DEG F)  :-14

-*** FIRE AND EXPLOSION HAZARD DATA ***

SECTION.4 Flach Point  :>200F Flcsh Point MethodL :SETA (CC)

Uppsr Explosive Limit :NOT LISTED Low 0r Explosive Limit :NOT LISTED

Autoignition Temperature :NOT LISTED Extinguisher Media  : DRY CHEMICAL, CARBON DIOXIDE, FCAM OR WATER.

'Spscial Fire Fighting Procedures :

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED-

' BREATHING APPARATUS (FULL FACE-PIECE TYPE).

'Unucual Fire-& Explosion Hazards :

Additional'Information:

• • • ~ REACTIVITY DATA ***

-SECTION 5-

-Io'this chemical stable under-normal conditions of handling and storage? :YES Conditions to' Avoid :DO NOT CONTAMINATE

Incompatibility (materials to avoid)  : ACIDS H:12Ordous decomposition' products  : ELEMENTAL OXIDES Io hazardous polymarization possible :NOT LISTED kl

MATERIAL SAFETY' DATA SHEET NUMBER 15506 FAGE 3 I

Conditions.to avoid'regarding i I

polymerization' . :NOT LISTED Additional Information: l BETZ. TANK CLEAN-OUT CATEGORY 'C' l

• • • HEALTH HAZARD DATA ***

SECTION 6 Routes of entry:

SKIN Symptoms of exposure:

CAUSES SEVERE IRRITATION, BURNS OR TISSUE ULCERATION WITH SUBSE-QUENT SCARRING. i l

Acute effects of overexposure l Skin contact : CORROSIVE TO SKIN

' Eye : CORROSIVE TO EYES Rocpiratory.: VAPORS, GASES, MISTS AND/OR AEROSOLS CAUSE

' IRRITATION TO UPPER RESPIRATORY TRACT.

. Chronic effects of overexposure:

PROLONGED OR REPEATED CONTACT MAY CAUSE TISSUE NECROSIS. j

.Madical conditions aggravated by exposure:

NOT KNOWN l Io chemical' listed as a carcinogen or potential carcinogen? ,

National Toxicology Program IARC Monographs OSHA NOT LISTED NOT LISTED NOT LISTED 4

• • • FIRST AID PROCEDURES ***

Emargency phone.num r: 800-877-1940 Skin:. contact:

' REMOVE CLOTHING. WASH AREA WITH LARGE AMOUNTS'OF SOAP SOLLUTION

'OR WATER FOR 15 MIN. IMMEDIATELY: CONTACT PHYSICIAN.

Eya-contact: . ..

IMMEDIATELY FLUSH EYES.WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A' PHYSICIAN FOR ADDITIONAL TREATMENT.

'Inhnlation:

REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT. IMMEDIATELY' CONTACT A PHYSICIAN.

n .

MATERIAL SAFETY DATA SHEET NUMBER 15506  ; A ,g 4

'Ingsstion:

DO-NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM. DO NOT INDUCE VOMITING. IMMEDIATELY CONTACT PHYSICIAN.

DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR. WATER.

• • • PRECAUTIONS FOR SAFE HANDLING AND USE ***

SECTION 7 Procautions to be taken in handling and storage:

KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN DRY AREA.

' KEEP AWAY FROM DIRECT SUNLIGHT AND HEAT. STORE AWAY FROM COMBUSTIBLES AND OXIDIZABLES. CONTAINS AN OXIDIZER. AVOID ALL CONTACT WITH' REDUCING AGENTS, OILS, GREASES, ORGANICS AND-ACIDS.

DO NOT ALLOW TO DRY.

JStcps to be taken in case material-is released or spilled:

VENTILATE AREA, USE SPECIFIC PROTECTIVE EQUIPMENT. CONTAIN AND ABSORB-ON ABSORBENT MATERIAL. PLACE IN WASTE DISPOSAL CONTAINER. I THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL, OR ANY '

CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA )

REGULATIONS.- FLUSH' AREA WITH WATER. WET AREA MAY BE SLIPPERY.

SPREAD SAND / GRIT.

Wrote disposal methods:

' WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY, IN ACCORDANCE WITH ANY LOCAL AGREEMENT, A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)-

! PRODUCT OR RINSATES THAT CANNOT BE'USED SHOULD BE DILUTED WITH WATER BEFORE DISPOSAL IN A SANITARY SEWER.

~

• • • CONTROL MEASURES ***

SECTION 8- .

Rstpiratory protection: .

USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE' SUPPLIED AIR

~ RESPIRATORS.. IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE-RESPIRATOR WITH ACID GASSES CARTRIDGES

'AND. DUST / MIST PREFILTERS.

~Vantilation:

ADEQUATE VENTILATION.

' Skin protection:

. GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON. WASH OFF

-AFTER'EACH US. REPLACE AS NECESSARY.

Eyo protection:

(

MATERIAL SAFETY DATA SHEET NUMBER 15506 pAGE 5 SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD.

l j

~

• • • DOCUMENTARY ***

.SECTION 9 1 This MSDS pre' pared'by :NOT LISTED Effcctive date for this-MSDS :04/19/91 Ravisions to sections :1, APPENDIX /9

• • • ADDITIONAL INFORMATION ***

SECTION 10 1 THIS MSDS WAS WRITTEN TO COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD'.

APPENDIX: REGULATORY INFORMATION:

THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF-THIS MSDS. THIS INFORMATION IS BELIEVED'TO BE ACCURATE. ANY. CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT.

i

...TSCA: ALL COMPONENTS OF THIS. PRODUCT ARE LISTED ON THE TSCA INVENTORY

. . . FIFRA (40 CFR) : EPA REG. NO. 3876-200001

... REPORTABLE QUANTITY (RQ)'FOR UNDILUTED PRODUCT.

79 GALLONS DUE TO SODIUM HYPOCHLORITE; 4,933 GALLONS DUE TO SODIUM HYDROXIDE

... RCRA: IF THIS PRODUCT'IS DISCARDED AS A-WASTE,-THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: D002= CORROSIVE (SKIN,PH) u ... DOT HAZARD /UN#/ER? GUIDE # IS: CORROSIVE TO SKIN UN1791/#60 ,

l

... CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) MATERIALS: ]

NONE-

... SARA SECTION 302 CHEMICALS

NONE i

... SARA SECTION 313 CHEMICALS: NONE

... SARA SECTION 312 HAZARD CLASS: IMMEDIATE (ACUTE) AND DELAYED (CHRONIC).-

j ... MICHIGAN CRITICAL MATERIALS: SODIUM HYPOCHLORITE (7681-52-9);

L' NFPA/HMIS:

3 HEALTH 0-FIRE-0LREACTIVITY CORR- SPECIAL PE D-l l

l

Texas Utilities Electric Company Comanche Peak Steam Electric Station Wastewater Discharge Permit No. 01854 Once-through Cooling Chemical Additives

a. Manufacturers Product identification Number: Sodlum Bromide

b. Product Use: Blocide enhancement

c. Chemical Composition: See attached data sheets

d. Product toxicity data: See aftsched data sheets

e. Classification (non-persistent, persistent or bioaccumulative): NotAvailable

f. Product or active ingredient half-life: NotAvailable

g. Concentration in once-through cooling water: NotAvailable

h. Frequency of product use: Intermittent use not exceeding 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> /daylunit

, . av swJ 377 5263 PAGE 2 *

>V hm 'R00113 01 ,

i kIHEET llM i m e!" M .='

1) CNBBCAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : SLEWCIDE C-84 PP.ODUCT APPUCATION AREA: WATER-8ASED MICROBIAL CONTROL AGENT. I CpMPANY AD -

NkNation numser 1 )-

1 131 MAERGENCY TENHOSE (HEALTH /ACCIDWIT): (800) 877-1940 (USA)

2) COMPOSITION / BIPORMATION ON INGREDIBfTS MNtY$XftbHNEbYioN Refer to addHlonel asceans of this MSDS for our asenesment of the poteneet hauents of this fannulation. i HAIAMM)US BIGREDWITS:

cw canscaL mes 7047-15-4 SODIUM BRoteDE  !

irritant at = _

PAGE 1 CONTINUSD t

- e as 2. ,

PRODUCT NAME : $UMICIDE C 94 EFNCTIVE DA78: 21 JUN 1998 i

3) HAZAftDS IDW6TIFICAT10N eo se s s e .. . . . .e. e.e .e . e.e .se. . . e..e. . e es se s se..se .e .. ... .e.. ... . .... . .e .. .... . .

EMERGENCY OVPalVIEW CAUTION Non-hazardous to sidn. May coues moderate irritation to the eyes. t hEstaleerosole may cause irettatier. to upper respiratory tract.

DOT herord le not appuestdo Emergency Response Guhle le not Odor: Sligt* Appearance: Colorless, i Rre Sghters should weer pochive preneurs self contained treathing 8 apparatue(full face piece . Proper fire extinguishing media:

foam or weenr l oosese .ohemic.a.l, oorben d eese seeeesseeeee,eeeeeeeeeeeeeeeeeeeeeeesseeeeeeeeeeeeee.eeeeessese.e FOT58TIAL HEALTH EFFECTS .'

I Act#TE SICDI EFFECTS:

Primary roues et espesure: Non4mserdous to oldn. ,

l ACUTE EVE WFECTS: j May cause snoderate irritation to the eyes.

MSPEATORY ENECTS:

seroeses may neues witteson to upper respiratory treet. I I

BIWSTION W95C75:

May cause geelreintestinel irritetton.  ; j TAR W ORGANS:

No evidence of potentlei ehronic effects.

N CCNIDfflONS ASSHAVATED:

Not known. >

SYRWTOMS OF EXFORNIE: ,

May cause redness or iteNng of sidn. '

e 1

l PAGE 2 CONTINUED I

L .. _ . ,

i e

r ue ,

b PRODUCT NAME : SLASCOE C 84 EFFECTWE DATE: 2161998 C) RRST AfD MEASURES SIGN CONTACT No treatment re EVE CONTACT: quired..

Immediately Hush eyes with water for 15 minutes. Immedietely contact a physician for additional treatment.

WOHALATION:

Remove victim from contaminated eroe to fresh air. Apply

,,ggge nret eid treatment es .

Do not feed by mouth to en 'unconsolous or convulelve vietim. Do not . Immedletely contact physician.

Deutecontentsof stomach 3 4 glaseos milit or water. 3 l

sipas riewrwe mea 8unes -

PIM PleNTWie INSTIEftm0NS: j Fire Sehtere should weer poetthe pressure self contained M.:. g .

. m chenu s.te.,=ear.en g g- '.va*-

d e. ,.am - weier 9000 RIP 00m0N PRODUCTS:

doosmpesnion (destructive fires) yleide elemental oxides.

PLASH P0utT:

> 200P P-M(CC4 St ACCmWITAL RB. EASE MEASURES PROTEEm0N AfD GPRL CONTA51tNNT:

ventsees arms use speeNied protnothe equipment. Conteki and ahearts on shoorbent matortel. Pleos in weets deposei container.

Contaminated eres be woohed down with water.

DWp0 SAL Water contaminated with thee product be sent to e sanitary sewer trootnent f ,an accordance with any agreement,e permitted womes tree feeNety~or under a permit. Product as is - D6spose of in approved e faciety or seoonting to labelinstruellene.

7)HANDE.We AND STORAeE MANDLSGS:

Normel chemiset hentBing.

sTonAes:

Kase containere elese(when not in use. D not temas, if 'rosen, thew and mhr oornplagsfy preer to use.

PAGE 3 CONTINUED

e- .

.- c .  ; ma, , , _ , , ; . ,

~

PRODUCT NAME : SUMICIDE C-94 EPMCTIVE DATE: 214UN-1SSS

8) EXPOSURE CONTROL $/ PERSONAL PROTECTION EXPOSURE UMITS SOOlUM BROMIDE PEL (OSHA): NOT DETUIMINED I TLV (ACGlH): NOT DETERMINED ,

WHNMMRIRIG CONTROLS:

adequate ventsaSon '

PWWONAL PIIDTECTWE EQUIPINNT:

Use tactive socordance with 29CFR 1910 Subpert ! ,

A RESPIRATOlW PROTECTION PROGRAM THAT MEETS OSHA'S 29 CPR  !

1910.134 AW ANSI 298.2 REQUIMMENTS MUST M FOLLOWED WHENEVER '

WORKPLACE CONDITIONS WAMANT A IWSPIRATOR'S USE. l USE AIR PURIPYING IIESPIRATORS WITHIN USE LANTATIONS ASSOCIATED WITH THE EQUIPIMNT OR 5.SE USE SUPPUED ANHWSPIRATORS.

MRI PROTECT 10Rl:

rubber glowee- Wash off efter each use, Repiece as EVE PM:  !

--P S-

.,- - - - i REEEC4 J N > L .1 2 '

3 P-M(CC) lvaporScori ste'kEthor=1) < 1.00

.A . - E ..- - ,

c i

I I

PAGE 4 CONTINUED i l

.N

. eu udJ si/ 5263 p Ac;E 6*

e 4-PRODUCT NAME : EURECWE C-M BFFECTIVE DATE: 21 JUN.1980  !

101 STABE.lTY A380 REACTIVITY STAagny: .

wi . UsPOL b

• NMt g g ser s.

l

.m. ." ash.inkh*e*d#4llr"" ***-

- I

11) TOXICOLOGICAL WIP0fuRAT1001 6

O en e

PAGE S CONTINUS

~- -

. ..wa -,,, ussa pace ,,

9 PRODUCT NAME : SuhWCtDE C 84 EFFECTIVE DATE: 21 JUN-1996

12) ECOLOGICAL INPCNWWATION AGJATIC T0XICOLOGY

. Rainbow Trout 90 Hour Static Acute Blessesy Textetty or hypotremous acid expressed as bromine. '

LC50: .29 mg/L Daphnie magne 48 Hour Static Acute Blosassy Toxicity of hypobromous acid expueesed as fromine.

LC50: .71 mg/L .

I No Effect Level: .41 mea.

j A Sunfloh 96 Hour Stette Aoute Mueglicity Tox of hypobromous asid expre%

ssed as bromine. I LC50: .52 mea. l No Effect Level: .3rng/L '

Mysid Shrime 96 Hour Flow-Thru Tedetty ofhypotremous moed as bromine.

I LC50: .17 mg/L l

9mepehead Mnnow 96 Hour Row Thru Mosesey Tomisity of hypoteemous said expressed as bromine.

i LCsO: . teres /L No Effect Lovel: .11 m04.

Deshnie meane 40 Hour Stado Asute Blessesy Tomioity of product as le.

i LCaO: 27s00 rne/L

• EIOCEGAADATION .

No Oste Availshie. {.

I

13) DISPOSAL CONSBERATIONS t if this undluted goodnet le decenled as a waste, the US RCRA '

hemordous weste identiflossion number le :

Not applioshie.

Please be advised; hoivever, that stees and local requiremame for  ;

weste esposal may to more remoteeve or otherwise efferent from -

fhforal Opneuit state and loosi teguistione reserding the proper or ele materief. i i

! I PAGE 8 CONTWAJE  ;

, 1

E Texas Utilities Electric Company Comanche Peak Steam Electric Station Wastewater Discharge Permit No. 01854 Once-through Cooling Chemical Additives

a. Manufacturers Product Identification Number: BetrDearborn Depositrol BL5301

b. Product Use: Scale inhibitor and dispersant

c. Chemical Composition: See attached data sheets

d. Product toxicity data: See attached dets sheets

o. Classification (non-persistent, persistent or bioaccumulative): Not Available

f. Product or active Ingredient half-life: Not Avallable

g. Concentration in once-through cooling water: Not Available j

h. Frequency of product use: Continuous low concentration feed 1

Df RN ERIAL gggggggygoyn EFFECTIVE DATE: 29-JAN-1997 .

PRINTED DATE: 20-MAR-1998 l

1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION  !

. PRODUCT NAME : DEPOSITROL BL5301  ;

PRODUCT APPLICATION AREA: WATER-BASED DEPOSIT CONTROL AGENT.

' COMPANY ADDRESS:

BetzDearbom Inc.

4636 Somerton Road, Trevose, )Pa.19053Information phone number: (215 - 35 ,

EMERGENCY TELEPHONE (HEALTH / ACCIDENT): (800)-877-1940 (USA)

2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.

HAZARDOUS INGREDIENTS:

CAS# CHEMICAL NAME 2809-21-4 PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE) BIS- (HEDP) i Corrosive (eyes) l No component is censidered to be a carcinogen by the National Toxicology Program the Intemational Aaency for Research on Cancer or the

. Occupati,,onal Safety and Heilth Administration at OSHA th,esholds r for carcinogens.

em 4

PAGE 1 CONTINUED

WCT NUDEPOSITROL BL5301 EFFECTIVE DATE: 29-JAN 199'I

3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION -

May cause moderate irritation to the skin. May cause moderate irritation to the eyes. Mists / aerosols may cause irritation to upper respiratory tract.

DOT hazard: Corrosive to steel Emergency Response Guide #153 Odor: Mild; Appearance: Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing cpparatus(full face-piece type). Proper fire-extinguishing media:

dry chemical, carbun dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

. Primary route of exposure; May cause moderate irritation to the skin.

ACUTE EYE EFFECTS:

M:y cause moderate irritation to the eyes. -

ACUTE RESPIRATORY EFFECTS:

Mists / aerosols may cause irritation to upper respiratory tract.

INGESTION EFFECTS:

M:y cause gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea.

TARGET ORGANS:

No evidence of potential chronic effects.

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF EXPOSU'RE:

M y cause redness or itching of skin, irritation, and/or tearing of cyls (direct contact).

i PAGE 2 CONTINUED l

1 PRODUCT NAME : DEPOSITROL BL5301 EFFECTIVE DATE: 29 JAN 1997 i L4) FIRST AlD MEASURES SKIN CONTACT: .

~

- Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes.

EYE CONTACT:

' immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.  ;

INHALATION:- -

Remove victim from contaminated area to fresh air. Apply -

rppropriate first aid treatment as necessary.

INGESTION:

Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician.

Dilute contents of stomach using 3-4 glasses milk or water. .

- 5) FIRE FIGHTING MEASURES -

FIRE FIGHTING INSTRUCTIONS:

^ Fire fighters should _ wear positive pressure self-contained breathing -

apparatus (full f loce type).

EXTINGUISHING ME  :

dry chemical, carbon dioxide, foam or water -  !

HAZARDOUS DECOMPOSITION PRODUCTS- i Thermal decomposition (destructive fires) yields elemental oxides.

FLASH POINT:'

> 200F P-M(CC)

MISCELLANEOUS: l Corrosive to steel UN3265; Emergency Response Guide #153 l

6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and cbsorb on absorbent material. Place in waste disposal container.

Flush area with water. Wet area may be slippery. Spread sand / grit.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitary sewer tristment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product cs is - Incinerate or land dispose in an approved landfill.

7) HANDLING AND STORAGE HANDLING: L -.

Acidic. Do not mix with alkaline material.

STORAGE:

Keep containers closed when not in use. Use ap xoved containers

- only. Store in cool, well-vented area. Contact wit 1 metals may release flammable hydrogen gas.

- PAGE 3 CONTINUED u

F PRODUCT N'AME : DEPOSITROL BL5301 EFFECTIVE DATE: 29 JAN 1997

8) EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS 1 CHEMICAL NAME J

!~

PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE) BIS-(HEDP) l PEL (OSHA): NOT DETERMINED i TLV (ACGlH): NOT DETERMINED l

' l

. ENGINEERING CONTROLS:

adequate ventilation l PERSONAL PROTECTNE EQUIPMENT:

Use protective equipment in accordance with 29CFR '910 Subpart i RESPIRATORY PROTECTION:

- A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHEFEVER i

' WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. i USE AIR PURlFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.

If air-purifying respirator use is appropriate, use a respirator with dust / mist filters.

SKIN PROTECTION: .

rubber gloves- Wash off after each use. Replace as EY bCTION:

splash proof chemical goggles

9) PHYSICAL AND CHEMICAL PROPERTIES l Specific Grav. (70F) 1.406 Vapor Pressure (mmHG) ~

18.0 Freeze Point (F) Vapor Density (air =1) < 1.00 Viscosity (cps 70F) - < -30.00 80  % Solubility (water) 100.0

' Odor - Mild l Appearance -Yellow

l. Physical-State Liquid Flash Point (F) . > 200 P-M (CC )

pH As Is (approx.)- < 1.0

' Evaporation. Rate (Ether =1) < 1.00

~

' NA o not applicable - NO = not determined PAGE 4- CONTINUED i~

L PRODUCT NAME : DEPOSITROL BL5301 EFFECTIVE DATE: 29-JAN-1997

'10) STABILITY AND REACTIVITY STABILITY:

Stable under normal stor e conditions.

HAZARDOUS POLYMER TlON:

Will not occur, INCOMPATIBILITIES:.

M:y react with strong oxidizers.

DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

CETZ INTERNAL PUMPOUT/ CLEANOUT CATEGORIES:

"B"

'11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: >4,000 mg/kg

~ NOTE - Estimated value Dormal LD50 RABBIT: >4,000 mg/kg NOTE - Estimated value Eya Irritation Score RABBIT: 9.3 NOTE - Maximum score at 48 hr; completely reversible by day 14

12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY

= Fathead Minnow 48 Hour Static Screen

- Toxicity estimated from product with similar formulation at a pH of 6-9.

0% Mortality: 500 mg/L

. D;phnia magna.48 Hour Static Screen Toxicity estimated from product with similar formulation at a 'pH of 6-9, 0% Mortality: 500 mg/L BIODEGRADATION COD  : 329 Calculated TOC (  : 89 Calculated j BOD-  : 3 Calculated i B00-28 mg/gm): 7 Calculated 1

PAGE 5 CONTINUED j l

4

" LPRODUCT NAME : DEPOSITROL BL5301 EFFECTIVE DATE: 294AN-1997 -

13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA

- hazardous waste identification number is :

' D002= Corrosive (pH, steel).

, Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.

~

14) TRANSPORT INFORMATION DOT HAZARD:. Corrosive to steel 1 UN / NA NUMBER: UN3265 DOT EMERGENCY RESPONSE GUIDE #: 153

15) REGULATORY INFORMATION

- TSCA:

All components of this :roduct are listed in the TSCA inventory.

CERCLA ANDOR SARA ItEPORTABLE QUANTITY (RQ):

No regulated constituent present at OSHA thresholds SARA SECTION 312 HAZARD CLASS:

Immediate(acute)

SARA SECTION 302 CHEMICALS:

No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: L No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC

. ENFORCEMENT ACT (PROPOSITION 66) CHEMICALS PRESENT:

No regulated constituent present at OSHA thresholds -

MICHIGAN REGULATORYINFORMATION No regulated constituent present at OSHA thresholds PAGE 6 ~ CONTINUED

PRODUCT NAME : DEPOSITROL BL5301 EFFECTIVE DATE: 29 JAN-1997 i

16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 2 Moderate Hazard Fire 1 Slight Hazard Reactivity 0 Minimal Hazard Special .

CORR DOT corrosive (1) Protective Equipment B Goggles, Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.  !

CHANGE LOG j EFFECTIVE a DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 29-JAN-1997 ** NEW **

PAGE 7

~

Texas Utilities Electric Company Comanche Peak Steam Electric Station Wastewater Discharge Permit No. 01854 Once-through Cooling Chemical Additives

a. Manufacturers Product identification Number: Betr Clam Trol CT-2 l

b. Product Use: Blocide (non-oxidizing) 1

c. Chemical Composition: See attached data sheets i l

d. Product toxicity data: See attached data sheets

o. Classification (non-persistent, persistent or bioaccumulative): Not Available

f. Product or active ingredient half-life: Not Available

g. Concentration in once-through cooling water: Not Available

h. Frequency of product use: One of two products available forIntermittent use as needed; either Bett CT-2 or Buckman Bulab 6002 will be used.

BETZ MATERIAL

• SAFETY DATA' SHEET _

EFFECTIVE DATE: 29-AUG-1995 4

' PRINTED DATE: 14-SEP-1995

1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : CLAM-TROL CT-2 PRODUCT APPLICATION AREA: WATER-BASED MICROBIAL CONTROL AGENT.

COMPANY ADDRESS:

Betz Water Management Group, Division Betz Laboratories,Inc.

200 Witmer Road Horsham , PA 19044 Information phone number (215) 773-6269 EMERGENCY TELEPHONE (HEALTH / ACCIDENT): (800)-877-1940 (USA)

2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the OSHA HAZARD COMMUNICATIONS STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.

HAZARDOUS INGREDIENTS:

'CAS# CHEMICAL NAME 68424-85-1 (C12-16) ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE Corrosive (eyes and skin) ..

64-17-5 ETHYL ALCOHOL (ETHANOL)

Flammable liquid; irritant (eyes); potential liver and kidney toxin; may cause CNS depression No component is considered to be a carcinogen by the National Toxicology Program, the intomational Agency for Research on Cancer, or the Occupational Safety and Health Administration at OSHA thresholds for carcinogens.

r

. . . ., .. . . . . . . ..v... , ..s, . ~ , .

-n9ss0MWe6 51FEF WFpgyTMggME: 29 AUG-1995 1

-3) HAZARDS IDENTIFICATION

= = = - = = = ____-___________====_=;_._...

EMERGENCY OVERVIEW <

DANGER Severe irritant to the skin. Potential skin sensitizer. Corrosive to the eyes. Vapors, gases, mists and/or aerosols may cause irritation to upper respiratory tract.

DOT hazard: Combustible liquid Emergency Response Guide #27 Odor: Mild; Appearance: Colorless To Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). Proper fire-extinguishing media:

Dry chemical, carbon dioxide, foam er water.

POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS:

Primary route of exposure; Severe irritant to the skin. Potential skin sensitizer.

ACUTE EYE EFFECTS:

Corrosive to the eyes.

ACUTE RESPIRATORY EFFECTS:

Vapors, gases, mists and/or aerosols may cause irritation to upper .

rcspiratory tract.

INGESTION EFFECTS:

Toxic; May cause severe irritation or buming of rnouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses.

TARGET ORGANS:

Prolonged or repeated exposures may cause CNS depression, skin

. sensitization, and/or toxaty c. the liver and kidney.

MEDICAL CONDITIONS AGGRAVATED:

Not known.

SYMPTOMS OF EXPOSURE:

Inhalation of vapors / mists / aerosols may cause eye, nose, throat and n lung imtation. Skin contact may cause severe imtation or bums.

r rwuubi NAME : CLAM-IROL CT-2 EFPECTIVE DATE: 29-AUGU995

4) FIRST AID MEASURES ~

SKIN CONTACT:

Rrmove clothing. Wash area with large amounts of soap solution or w:ter for 15 min. Immediately contact physician.

EYE CONTACT:

Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment.

-INHALATION:

Rrmove victim from contaminated area. Apply necessary first aid tre tment. Immediately contact a physician.

IN2ESTION: -

Da not feed anything by mouth to an unconscious or convulsive

. victim. Dilute contents of stomach. Induce vomiting by one of the standard methods. Immediately contact a physician. '

5) FIRE FIGHTING MEASURES FIRE FIGHTING lidSTRUCTIONS: 1 Fire fighters should wear positive pressure self-contained breathing -

cppartus (full face-piece type).

EXTINGUISHING MEDIA:

Dry chemical, carbon dioxide, foam or water.

HAZARDOUS DECOMPOSITION PRODUCTS:

Th:rmal decomposition (destructive fires) yields elemental oxides.

FLASH POINT:

130F P-M(CC)

MISCELLANEOUS:

Combustible liquid NA1993; Emergency Response Guide #27

6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT:

. Ventilate area. Use specified protective equipment. Contain and

. cbsorb on absorbent material. Place in waste disposal container. -

Remove ignition sources. Flush' area with water. Spread sand / grit.

DISPOSAL INSTRUCTIONS:

Water contaminated with this product may be sent to a sanitasy sewer

- treatmentfacility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Dispose of in approved pesticide facility or according to labelinstructions.

. ,. . . n . .~. .. .. . ..-,...... . . . . . . . . . . . . , , . .... : .... . . ...... _. - ..

-~-

m m. m. anu

7) HANDLING AND STORAGE '

HANDLING:

Combustible. Do not use around sparks or flames. Bond containers

'during filling or discharge when performed at temperaturas at or

. above the product flash point. l STORAGE: -

Keep containers closed when not in use. Keep away from flames or sparks. Bond containers during filling or discharge when performed

at temperatures at or above the product flash point.

8) EXPOSURE CONTROLS / PERSONAL PROTECTION CHEMICAL NAME - l

'(C12-16) ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE PEL(OSHA): NOT DETERMINED TLV (ACGlH): NOT DETERMINED i ETHYL ALCOHOL (ETHANOL)

PEL (OSHA): 1,000 PPM -

TLV (ACGlH): 1,000 PPM ENGINEERING CONTROLS:

Adequate ventilation to maintain air contaminants below exposure I limits.

PERSONAL PROTECTIVE EQUIPMENT:

Use protective equipment in accordance with 29CFR 1910 Subpart I ,

RESPIRATORY PROTECTION: i A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 nequirements must be followed whenever workplace conditions warrant a respirator's use. Use air-purifying respirators within use limitations associated with the equipment or else use supplied air-respirators. If air-purifying respirator use is appropriate, use a respirator

. with organic vapor cartridge & dust / mist profilter.

SKIN PROTECTION:

Rubber gloves. Wash off after each use. Replace as necessary.

- EYE PROTECTION:

Splash proof chemical goggles.

. :. .. ; . . .. . . .. .. ... :n .; . .. . . .-

a

a 6 .-c$eJ-CQUU*tUCQ

9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (70F) 0.965 Vapor Pressure (mmHG) 44.0 Frasze. Point (F) -7.00 Vapor Censity (air =1) < 1.00 Viccosity (cps 70F) 73.  % Solubility (water) 100.0 Oder Mild Appearance Colorless To Yellow Physical State Liquid Flcsh Point (F) 130 P-M(CC) pH As Is (approx.) 8.9 Evaporation Rate (Ether =1) > 1.00 NA = not applicable - ND = not determined

10) STABILITY AND REACTIVITY STABILITY:

Stable HAZARDOUS POLYMERIZATION:

' Will not occur.

INCOMPATIBILITIES: 4 May react with strong oxidizers.

DECOMPOSITION PRODUCTS:

Thermal decomposition (destructive fires) yields elemental oxides.

BETZ INTERNAL PUMPOUT/ CLEANOUT CATEGORIES:

"B" l

1 4

11) TOXICOLOGICAL INFORMATION Oral LD50 RAT: , 445 mg/kg D3rmal'LD50 RABBIT: >1,800 mg/kg

- e u w o eaenez ms. 4s muu-i =wo

'12) ECOLOGICAL INFORMATION

~ AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.

LC50: .72 mg/L

' No Effect Level: .41 mg/L D phnia magna 48 Hour Flow-Thru Bioassay .

. Test concentrations were analytically verified.

LC50: .04 mg/L No Effect Level: .026 mg/L Riinbow Trout 96 Hour Flow-Thru Bioassay

- Test concentrations were analytically venfied.

LC50: 2 mg/L No Effect Level: 1.2 mg/L Mysid Shrimp 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.

LC50: .16 mg/L No Effect Level: .03 mg/L Sheepshead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified.

LC50: 1.76 mg/L No Effect Level: 1 mg/L Menidia beryllina'(Silversides) 96 Hour Flow-Thru Bioassay Test concentrations were analytically venfled.

LC50: .62 mg/L No Effect Level: .35 mg/L SIODEGRADATION COD (mg/gm): 1513 -

TOC (mg/gm): 427 BOD-5 (mg/gm): 39 B00-28 (mg/gm): 39

i

13) DISPbSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA

. hrzardous waste identification number is :

D001=lgnitable.

Pirase be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding tha proper disposal of this material.

14) TRANSPORT INFORMATION .

DOT HAZARD: Combustible liquid UN / NA NUMBER: NA1993 DOT EMERGENCY RESPONSE GUIDE #: 27

15) REGULATORY INFORMATION TSCA:

This is an EPA registered blocide and is exempt from TSCA inventory requirements.

CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):

No regulated constituent present at OSHA thresholds FIFRA REGISTRATION NUMBER:

-3876-149 SARA SECTION 312 HAZARD CLASS:

Immediate(acute); Delayed (Chronic); Fire SARA SECTION 302 CHEMICALS: .

No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS:

No regulated constituent present at OSHA tt.resholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINIONG WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION SS) CHEMICALS PRESENT:

No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds

snst9mnrensem a s. s-wau.T 335 d

16) OTHER INFORMATION NFPA/HMIS CODE TRANSLATION Health 3 Serious Hazard Fire 2 Moderate Hazard Reactivity 0 Minimal Hazard Special NONE No special Hazard (1) Protective Equipment B Goggles, Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations.

CHANGE LOG EFFECTIVE DATE REVISIONS TO SECTION: SUPERCEDES MSDS status: 22-AUG-95 REVISED FORMAT I

4 I

f l

. . . . . . . . . . . .. . . ." : Tr . <

Texas Utilities Electric Company Comanche Peak Steam Electric Station Wastewater Discharge Permit No. 01854 Once-through Cooling ,

Chemical Additives

)

I

a. Manufacturers Product identification Number: Buckman Bulab 6002

. b. Product Use: Blocide (non-oxidizing)

c. Chemical Composition: See attached data sheets

d. Product toxicity data: See attached data sheets

c. Classification (non-persistent, persistent or bloaccumulative): NotAvailable

f. Product or active ingredient half-life: NotAvailable i

g. Concentration in once-through cooling water: NotAvailable

h. Frequency of product use: One of two products available IbrIntermittent use as needed; either Betz CT-2 or Buckman Bulab 6002 will be used.

(.c

cf21pz BUCKMAN LABORATORIES, INC. g/ o Sos

' l MATERIAL SAFETY DATA SHEET BULAB 6002 Revision Date: 3/08/96 Phone 1800-BUCKMAN l

Buckman Laboratories, Inc. 1 24 Hour Emergency Phone 1256 North McLean Boulevard (901) 767-2722 Memphis, TN 38108 N8ll*tSt'~n % '

l OSHA HAZARD CLASSIFICATIONS l SECTION 1 ne n v g q Irritating to eyes. C$$ gg HAZARDOUS COMPONENTS l SECTION 2 r%=ir.1 Nam. CAS Number  % by Wei.ht M

Poly (oryethylenc(dimethyliminio) ethylene 31075 24-8 60 % N/A (dimethyliminio) thylene dichloride)

Totallisted: 60 %

The remainder of the components comprise proprietary information.

SECTION 3 PRECAUTIONARY LABELINFORMATION AS PRESCRIBED BY THE U.S. EPA CAUTION: Harmful if swallowed. Avoid breathing vapors. Avoid contact with skin, eyes, or clothing.

STATEMENT OF PRACTICALTREATMENT(FIRST AID):If swallowed:DO NOT INDUCE VOMITING. Rinse h

with copious amounts of water first. Irris*** th' **0P agus and dilute the stomach content by slowlY siving one (1) to two (2) 51asses of water. Avcid giving alcohol or alcohol related products In cass where the individualis semi. comatose, comatose or convulsing DO NOT GIVE FLUIDS BY MOUTH. In case of internal ingestion of the product seek medical assistance imma&arely; take individual to nearest medical facility. If in Eyes: Rinse eyes for at least 15 minutes with copious anounts of water. Seek medical attention. If on skin: Rinse with large anounts of water. If irritation occurs mk medical attention. If inhaled move person to a well ventilated place and apply artificial respiration if required.

Call a physician.

ENVIRONMENTAL HAZARD $s This pesticide is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into takes, streams, ponds estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewag,e treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA.

BULAB 6002 Page 1 of 6

SECTION 4 FIRST AID INFORMATION Eye exposure: Flush immediately with copious amounts of tap water or normal saline (minimum of 15 minutes). Take exposed individual to a health care professional, preferably an ophthalmologist, for further evaluation.

Skin exposure: Wash exposed area with plenty of soap and water. Repeat washing. Remove contaminated clothing and wuh thoroughly before reuse. If irritation persists consult a health care professional.

Inl alation: If exposure by inhalation is suspected, immediately move exposed individual to fresh air. If individual experiences nausea, headache, dininess, has difficulty in breathing or is cyanotic, seek a health care professional immediately.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with copious amounts of water or milk, first. Irrigate the esophagus and dilute stomach contents by slowly giving one (1) to two (2) glasses of water or milk. Avoid giving alcohol or alcohol related products. In cases where the individual is semi-comatose, comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In case of k mtional ingestion of the product seek medical assistance immediately; take individual to the nearest medical fr.nhty.

NOTE TO PHYSICIAN: No spuife ecodxr b known. Treat Symptoms. Medical consultation is available 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> a day. Call the B sckman Center 4r Pn6.: .nformation at (901) 767 2722.

I PRIMARY ROUTES OF EXPOSURE l SECTION S

1. Effects from Acute Exposure:

Eye exposure: Mild irritant. Effects may range from none to mild depending on the length of exposure, solution concentration and first aid measures, Skin exposure: Non. irritating to the skin.

Inhalatian: May cause irritation or corrosion of mucous membranes and the lungs. Exposed individuals should be monitored for respiratory distress, bronchitis or pneumonia.

Ingestion: Ingestion is not expected to be a primary route of exposure.

2. Effects imm Chronic Exposure:

The effects from chronic exposure to this product have not been fully evaluated.

TOXICOIDGICAL INFORMATION l SECTION 6 l

Acute effects: Oral LD50: Male: 1951 mg/kg, Female: 2587 m6/kg Acute Dermal LD50: > 2,000.0 mg/kg Acute Inhalation LC50: 2.9 mg/L Irritant effects: Mild transient irritation.

I Sensstization effects No evidence of sensitiation.

Carcinogenic possatist: A two year rat':arcinogenicity study showed a slight increase in c cell adenomas in female rats.  !

Studies with male rats and male and female mice did not show any evidence of carcinogenic response. This product is j not considered a carcinogen.Not listed in the OSHA Standard, Section 1910.1200 as a carcinogen. l Target Organ E5ecess Eyes (irriistion) are expected to be the primary target organ of this product. i Other hesith effects: Mutagenicity studies were negative.

ENVIRONMENTAL TOXICOIDGICAL INFORMATION l SECTION 7 BULAB 6002 Page 2 of 6 1

)

A 'te Animatie LC50's l

i 4f Hr. Daphnia Masna: ' O.37 ml/L-

' % Hr. Fathead minnow: 0.43 mg/L 96 Hr. Bluegill sunfish: 0.34 mg/L 96 Hr. Rainbow trout: 0.47 mg/L '

Acute n4=eine i F4n's 96 Hr. Sheepshead minnow: > 600.0 ms/L 96 Hr. Mysid Shrimp: 13.0 mg/L

' Avian Acute Oral LD50's Mallard ducks: 305.0 mg/kg Bobwhite quail: 1,100.0 mg/kg Avian D:= v LC50's -

Mallard ducks: > 5,620.0 ppm Bobwhite quail: > 20,000.0 ppm l SECTION 8 PHYSICAL AND CHEMICAL PROPERTIES

. Appearance . . . . . . . . . . . . . . . . . . . . . . . . . . clear, pale yellow liquid Odor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . mild Density 8 25'C . . . . . . . . . . . . . . . . . . . . . . 1.155/mL Flash Point . . . . . . . . . . . . . . . . . . . . . . . . . . . none Freezing Point ........................ < 0*C Boiling Point . . . . . . . . . . . . . . . . . . . . . . . . . > 100 *C ( > 212 *F)

Solubility . . . . . . . . . . . . . . . . . . . . . . . . . . . Completely miscil'e with water, insoluble in most organic solvents.

pH....................... ........ 6 8

- pH (100 ppm in water) . . . . . . . . . . . . . . . . . 6 7 -

Vapor Pressure . . . . . . . . . . . . . . . . . . . . . . N/T o/w Partition Coefficient . . . . . . . . . . . . . . . . . N/T

- Oxidizing / Reducing Properties . . . . . . . . . . . . . Not tested.

NOTE: N/A - Not Applicable, N/T - Not Tested FIRE AND EXPI.OSION INFORMATION l SEC110N 9 Fl=====ht- liniits: Not determined.

5 :' . ' '-'- media: Dry chemical, water foam or carbon dioxide. Water should be used to cool surrounding containers.

Special firefighting procedures: None l

REACTIVITY INFORMATION l SECTION 10 Stability: Stable under ordinary conditions of use and storage.

'- , T: . Anionic polymers Hasardoens r- ,

Products: Unknown, but carbon monoxide may be released on burning.

HANDIJNG PRECAUTIONS l SECTION 11 BULAB 6002 Page 3 of 6

Eye. wash fountains in the work area are recommended.

Rdbber gloves, indirect ventilation goggles, body protective clothing, and rubber safety shoes are required.

SECTION 12 SATISFACTORY MATERIALS OF CONSTRUCTION Tested SatM* tory Materials Polypropylene Plexiglas .

Teflon l PVC rigid l Buna N rubber Viton l EPDM rubber l PVC flexible I Neoprene Fiber 51 ss Polyethylene . low density Tyson Tyril 880 Gum rubber Silicone rubber Hypalon Aluminum 5052 H34 Stainless steels 304 and 316 NOTE:With respes to all odwr masenals not listed abon, user should be aware that use of such mecenals wnh BULAB 6002 may be hasardous and l result in damaps to such materials and other property and personal injuries. No data concermns such matenals nec listed abon should be unpled by the user.

i l

SPIIJ., LEAK. AND DISPOSAL PROCEDURES l SECTION 13 SPILL AND LEAK RESPONSE GUIDELINES Importantt Before responding to a spill or leak of this product, review each section of this MSDS. Follow the recommendations given in the Handling Precautions sections. Check the Fire and Explosion Data section to determine if the use of non-sparking tools is merited. Insure that spilled or leaked product does not come into contact with materials listed as incompatible.] irritating fumes are present, consider evacuation of enclosed areas.

Emergency Response Ah Emergency technical assistance is available at any time from Buckman Laboratories, Inc., by calling (901) 767 2722.

Initially mim== area affected by thc spill or leak. Block any potential routes to water systems (e.g., sewers, streams, lakes, etc.). Based on the product's toxicological and chemical properties, and on the size and location of the spill or leak, assess the impact on contaminated environments (e.g. water systems, ground, air equipment, etc.). There are no methods available to completely eliminate any toxicity this product snay have on aquatic environments. Minimize adverse effects on these enytronments. Buchman Laboratories, Inc. can be contacted for technical assistance Determine if federal, state, and/or local release notification is required (see Regulatory Classifications section of this MSDS). Recover na much of the pure product as possible into appropriate containers. Later, determine if this recovered product can be used for its intended purpose. Address clean-up of contaminated environments. Spill or leak residuals may have to be collected and BULAB 6002 Page 4 of 6 l

D

disposed ef. Clay, soil, or commercially available absorbents may be used to recover any material that can not readily b(recovered a pure product. Flushing residual material to an industrial sewrr, if present at the site of a spill or leak incident. may be acceptable if authorized approval is obtained. If product and/or spill / leak residuals are flushed to an industrial sewer, insure that they do not come into contact with incompatible materials. Contact the person (s) responsible for the operation of your facility's industrial sewer system prior to intentionally flushing or pumping spills or leaks of this product to the industrial sewer.

DISPOSAL GUIDEUNES Note: Follow federal, state, and local regulations Soverning the disposal of waste materials.

Neat Product: Contact your Buckman representative or Buckman Laboratories, Inc., at (901) 278 0330.

Contaminated Materials: Determine if waste containing this product can be handled by available industrial effluent l system or other on. site waste management unit. If off-site management is required, contact a company experienced in industrial waste management. This product is not specifically listed in 40 CFR 261 as a Resource Conservation and Recovery Act (RCRA) hazardous waste. However. spill or leak residuals 2g meet the criteria of a characteristic l hazardous waste under this Act. Check the characteristics of the material to be disposed of and/or the physical and reactivity data given in this MSDS for the neat product.

Container Dispo:al: Empty containers, as defined by appropriate sections of the RCRA, are not RCRA hazardous wastes.

However, insure proper management of any residuals remaining in container.

l SECTION 14 TRANSPORTATION AND SHIPPING INFORMATION l

DOT Shipping Name: NOT REGULATED j REGULATORY INFORMATION l SECTION 15 l The following Regulations are known to apply to the use and disposal of this product. Additional Federal, State and Local regulations may also be applicable.

SARA (Superfund Amendments and Renuthortzation Act):

SARA 302 Ed. dy Hazardous Substances Lisa No components of this product are listed.

SARA 312 Hazard Categoryt Immediate (Acute) Health Hazard SARA 313 Toxic Chernicals List: No Section 313 listed substances are present above de minimus levels.

CERCLA (Comprehensive Environmental Response, C==p "- and Liability Act:No components of this product are listed.

RCRA (Resource Conservation and Recovery Act) Usted Hazardous Wastes: No components of this product are listed.

CWA (Clean Yater Act)IJeted Substances: No components of this product are listed.

FDA (Food and Drug phainimeration): This product not approved for food contact uses.

TSCA (Toxic Sah=enar== Control Act) Applicability: Registered pesticides are exempt from the requirements of TSCA.

All components are listed on TSCA Inventory.

FIFRA (Federal inn. Fungicide, and Rodenticide Act): This product is a registered pesticide.

EPA Reg. No. 1448-42 BULAB 6002 Page 5 of 6 s

)

r-, - -

e ,

HMIS/NPCA Ratings: Health 1; Flammability 1; Reactivity 1 NFPA Ratings: Health 1; Flammability 1; Reactivity 1 STATE REGULATIONS California Proposition 65: This product has been reviewet. .or Prop 65 components, and the following warning applies:

WARNING: This product may contain substance (s) which are known to the State of California to cause cancer or reproductive harm.

(Contains May contain trace levels of (<10 ppm) of Dichloroethyl ether, 1,4-Dioxane, and (<20 ppb)

N nitrosodimethylamine.)

(Trace Contaminant from Poly (oxyethylene(dimethyliminio) ethylene (dimethyliminio) ethylene dichloride])

Various State Right to Know Acts: Non-proprietary hazardous chemicals are listed in Section 2 of this MSDS. Should you require funher information on specific proprietary chemicals or inerts please contact Buckman Laboratories

• Regulatory Affairs Department.

1 N andermanise se this htmanal seley Does shem renesse the Isasa -l_ sad desa chas we have en haasres propertass and han&ag af the preest under the resemmended t h- ei eso. Amy was el abas product er usebed of appinance ehesh is esa demreed e ibs Prahast Due Shese es 6s . *-y elihn mer. Thas Masenal Safey Dara Shem was propered is semp4 7 omb es osha Hansed d' .

Seckasa ' ' _ Ims. omtreass abas the preasse annieres se as shamasal Asssripees and as sensenably be is she pwpees seierred to in the ernsteens der ens whee unsd is amerdanee onk the deresmans ender sonnat . Sayer assems es neli si say use essurary se ensk eresames l sesse ashes memberwarriesy er - siany hans emprem er . .ebe pruden,inshmans NO IREftatD T Aa:ANTY Of MIBCHANrAARTrY OR rtTNLtB OF 11E GOODA POR ANY OTMBA PARTICIAAR PURf0ER. No sush warresma shal be imphed by Irw sed me a$sse si seiler a enhanced to sher mis womary a say eny j susys a wnesg wit a sperde sdurense to this outramry. <

l N sachmarse ransdy agssam asBer absa le a slaan for damages oss as sessed es purefase prue af she pressa, emhem ragssd se whnbar sush s'slaam a based spus breech ed warraary l l

er tark Aay semmoverer er slama anast aus of er rehung is abs saamass, er brush shersel, shot ha uuded by arharnese a assesdnase web ths ___ menernese reiss af the Amances Ashuramas

• _. sed bsdymuses eyes the swerd rundmed by ihe ArhareserW may he sammed e any seers hanes - enremi.

BULAB 6002 Page 6 of 6

p- ,

f l

Attachment 8 1

Technical Report, item 14 Auxiliary Boller Additives Texas Utilities Electric Company ,

Comanche Peak Steam Electric Station i TNRCC-TPDES Permit No. 01854 l

l I

l u- ______ _

l 1

Texas Utilities Electric Company Comanche Peak Steam Electric Station Wastewater Discharge Permit No. 01854 Auxiliary Boller l Chemical Additives

a. Manufacturers Product identification Number: Hydrazine l

b. Product Use: Oxygen Scavenger l

c. Chemical Composition: See Attached Data Sheets l

l

d. Product toxicity data: See Attached Data Sheets

e. Classification (non-persistent, persistent or bioaccumulative): NotAvailable

f. Product 'or active ingredient half-life: Not Available ,

g. Concentration in auxiliary boiler water: NotAvailable

h. Frequency of product use: Once or twice peryear.

1 l

l l

l

Environmental Data Summary Hydrawine l

CAS #: 30212 Toxicity Data:

Oronnium Duration LC 50 Value D.magna- 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 0.810 mg/l P. promelas 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> 8.98 mg/l ,

P. promelas  % hours 5.98 mg/l  !

Reference:

EPA database:"Aquire" 1

l l

l l

h'

' MATERIAL' SAFETY DATA SHEET NUMBER 4697 FAGE .

[ .s 1

' PRODUCT: HYDRAZINE MANUFACTURER: VAN WATERS.& ROGERS NFPA RATINGS HEALTH: 3 FIRE: 1 REACTIVITY: 1 OTHER: I l ' SARA RATINGS FIRE: N REACTIVITY: N PRESSURE: N ACUTE: Y CHRONIC: Y I DATE' PREPARED: 12/28/89 TSN: 282066 l l

l

. THIS COMPUTERIZED MSDS CONTAINS THE INFORMATION FROM THE MANUFACTURER'S ORIGINAL. MSDS SUPPLIED TO TU ELECTRIC IN ACCORDANCE WITH 29 CFR 1910.1200, A COPY.0F.THE ORIGINAL MSDS IS AVAILABLE THROUGH SAFETY AND INDUSTRIAL HEALTH: 954-5243. l

• • • GENERAL PRODUCT INFORMATION ***

f Trcdn Produet'Name' :HYDRAZINE SOLUTION i . Synonyms :HYDRAZINE'

~ DIAMIDE HYDRATE, SCAV-OX-(R) l

Manufacturer.Name  : VAN WATERS & ROGERS INCORPORATED SUBSIDIARY OF UNIVAR l Manhfacturer's Address :1600 NORTON BLDG.

! City  : SEATTLE l StatG  : WASHINGTON

' ' ZIP- :98104-1564 ,

Em3rgency Phone Number  :(800) 424-9300 l Talsphone  :(408) 435-8700 l Additional'Information:

,"VWER CODE :P1105001-l ' Formula-  : MIXTURE Ordar-No. :130505379-l Product No. :04047630

'*** INGREDIENTS INFORMATION ***

l

! ** EXPOSURE LIMITS **

l - INGREDIENT NAME . PEL TLV

. HYDRAZINE-1 (SKIN) 0.1 (SKIN) l WATER NONE NONE i i

• • PERCENTAGES **

l HIGH % LOW %

l!HYDRAZINE 35 l~ WATER: .. BALANCE

~** CAS NUMBERS **

CAS ON MSDS

.-HYDRAZINE- 305-02-1 WATER- 7732-18-5

• • HAZARDOUS INGREDIENTS **

t L--

ERIAL SAFETY ;gTA Sh p~' WMBER 4697 FAGE 2

.=

HYDRAZINE HAZARD:

CARCINOGEN, COMBUSTIBLE

• • • PHYSICAL / CHEMICAL CHARACTERISTICS ***

Boiling Point DEG F :229' Molting Point DEG F  :-87 Spscific Gravity (WATER =1) :1.02 Vapor Pressure--  :<1 (MM HG/20 DEG C Parcant Volatiles :NOT STATED Vapor Density (air =1) :1-Evaporation Rate j

N/A Compared to  : BUTYL ACETATE =1 Water Solubility :100 .

1 Appserance and Odor-

COLOR-LESS TO PALE YELLOW LIQUID WEAK AMMONIACAL ODOR

• • • -FIRE AND' EXPLOSION HAZARD DATA ***

Flach Point' :NONE Fldch Point-Method :PMCC Upp;r Explosive Limit :83.4 Lower-Explosive Limit :9.3 Autoignition Temperature :NOT STATED Extinguisher Media :USE WATER SPRAY Sp1cial Fire Fighting Procedures :

FIRE' FIGHTERS'SHOULD WEAR SELF-CONTAINED APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL. NEARBY CONTAINERS AND STRUCTURES EXPOSED TO. FIRE.

Unusual Fire & Explosion Hazards : EXTINGUISH ALL NEARBY SOURCES OF

. IGNITION SINCE LIQUID HYDRAZINE MAY LIBERATE GASEOUS HYDRAZINE WHOSE EXPLOSIVE LIMITS ARE 4.7-100%. VAPORS ARE HEAVIER THAN. AIR AND MAY

' TRAVEL TO DISTANT IGNITION SOURCES AND FLASH BACK.

• • • REACTIVITY DATA ***

Is this chemical stable under normal ~

conditions'of handling and storage?  : STABLE Conditions to Avoid :CONCENTPATION OF PRODUCT BY EVAPORATION.

Incompatibility (materials to avoid)

=

0XIDIZERS, CATALYTIC METALS

, .. SUCH AS LEAD, COPPER, AND l ZINC, AND THEIR ALLOYS, Hnzerdous decomposition products :MAY LIBERATE HYDROGEN, AMMONIA, HYDRAZINE GAS, AND OXIDES OF NITROGEN.

Io hazardous; polymerization possible :WILL NOT OCCUR

y. - .

MATERIAL SAFETY DATA SHEET NUMBER 4697 pAgg 3 Conditions-to avoid regarding polymerization :NONE STATED

• • • HEALTH HAZARD DATA ***

Primary Routes of Exposure:

SKIN OR EYE CONTACT, INHALATION.

Signs and' Symptoms of Exposure:

INHALATION--VAPORS WILL IRRITATE THE NOSE AND UPPER RESPIRATORY TRACT.

MAY ALSO CAUSE DIZZINESS, NAUSEA, AND CENTRAL NERVOUS SYSTEM STIMULA-TION. RODENTS EXPOSED BY INHALATION TO HYDRAZINE DEVELOPED TUMORS AND HEPATOTOXIC EFFECTS. -

Eya Contact--LIQUID AND VAPORS WILL IRRITATE THE EYES AND MAY CAUSE PERMANENT EYE DAMAGE.

Skin ~ Contact--IRRITATES THE SKIN. HYDRAZINE IS ABSORBED THROUGH THE  !

' SKIN AND CAUSES SYSTEMIC INJURY IF EXPOSURE IS EXTENSIVE, PROLONGED, OR REPEATED. HYDRAZINE MAY CAUSE DERMATITIS IN SOME INDIVIDUALS.

Swallowed--CAUSES DIZZINESS AND NAUSEA. RODENTS EXPOSED ORALLY TO HY-DRAZINE DEVELOPED TUMORS AND HEPATOTOXIC EFFECTS.

Chronic Effects of Exposure:

CARCINOGENIC ~TO LABORATORY ANIMALS. DAMAGES LIVER, LUNGS, KIDNEYS, BLOOD AND BLOOD FORMING ORGANS,.AND CAUSES DERMATITIS AND ALLERGIC

. SENSITIZATION TO THE SKIN. MAY CAUSE FATAL MALFORMATIONS.

Madical Conditions Generally Aggravated By Exposure:

NONE' REPORTED.

Ic~ chemical-listed as a carcinogen or potential carcinogen ? NO National Toxicology Program IARC Monographs OSHA NOT STATED NOT STATED NOT STATED

• • • FIRST AID PROCEDURES ***

Emergency Telephone Number: _( 800) 424-9300 1

Inhalation:  !

REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF.NOT BREATHING. GET

.IMMEDIATE MEDICAL ATTENTION.

'Eya:

r- .

MATERIAL SAFETY DATA SHEET NUMBER- 4697 PAGE 4 L -IMMEDIATELY-FLUSH EYES WITH LOTS OF RUNNING WATER FOR 15 MINUTES, l' LIFTING THE UPPER'AND LOWER EYELIDS' OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION.

Skin:

IMMEDIATELY FLUSH' SKIN WITH LOTS OF RUNNING WATER FOR 15 MINUTES. RE-

' MOVE CONTAMINATED CLOTHING AND SHOES WASH BEFORE' REUSE. GET IMMEDIATE MEDICAL ATTENTION. DESTROY CONTAMINATED LEATHER ARTICLES Ingsstion:

IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING BY GIVING 2 GLASSES OF WATER

.AND STICKING A FINGER DOWN THE THROAT. GET IMMEDIATE MEDICAL ATTEN-TION. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING-PERSON.

---

TOXICITY DATA-----------------------------

-Orcl:

LRAT,LD50=60 MG/KG Darmal:

RABBIT LD50= 420 MG/KG

' Inhalation:

RAT LC50 = 570 PPM /4 HR.

Carcinogenicity:

THE NATIONAL TOXICOLOGY PROGRAM CONCLUDES HYDRAZINE.MAY REASONABLY BE ANTICIPATED TO BE A CARCINOGEN. MOBAY CHEMICAL CORPORATION REPORTS EPIDEMIOLOGICAL STUDIES PERFORMED TO'DATE ON HYDRAZINE PRODUCTION WORKERS HAVE NOT IDENTIFIED ANY ASSOCIATION BETWEEN HYDRAZINE EXPOSURE AND AN INCREASED RISK OF CANCER.

• • • PRECAUTIONS FOR SAFE HANDLING AND USE ***

Precautions'To Be Taken In Handling and Storing:

' STORE IN A COOL, DRY, WELL-VENTILATED PLACE. STORE AWAY FROM ALL OTHER CHEMICALS AND POTENTIAL SOURCES OF USE PRESSURE TO. EMPTY CONTAINER. ,

WASH THOROUGHLY AFTER HANDLING. DO NOT GET'IN EYESj ON SKIN, OR ON l

. CLOTHING..

Othsr Precautions: l CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE AND VAPQRS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL.

Spill or' Leak Procedures:

WEAR PROTECTIVE EQUIPMENT INCLUDING VINYR OR BUTYL RUBBER BOOTS, VINYL ,

OR~ BUTYL RUBBER GLOVES, VINYL OR BUTYL RUBBER APRON, AND A SELF-CON- )

.TAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE OR A

' SUPPLIED-AIR _ RESPIRATOR. FOR SMALL SPILLS OR DRIPS, MOP OR WIPE UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FOR LARGE SPILLS, CONTAIN

m  !

MATERIAL SAI'ETY D,TrA SHEET NUMBER 4697 =

. A ., .-.

BY DIKING WITH SOIL OR OTHER NON-COMBUSTIBLE SORBENT MATERIAL AND PLACE RESIDUE IN DOT-APPROVED WASTE CONTAINERS. KEEP OUT OF SEWERS, STORM DRAINS, SURFACE WATERS, AND SOIL.

COMPLY"WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL RE-

-PORTING, AND HANDLING AND DISPOSAL OF WASTE.

Waste Disposal Method:

DISPOSE OF CONTAMINATED PRODUCT.AND MATERIALS USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPRO-PRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER i DISPOSAL PROCEDURES.- l l'

Additional'Information:

Rspair and Maintenance-Precautions--DO NOT CUT, GRIND, WELD, OR DRILL ON OR NEAR THIS CONTAINER.

Note: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES, AND MISTS AND ARE SUBJECT TO PROPER DISPOSAL, AS ABOVE.

• • • CONTROL MEASURES ***

Racpiratory Protection:

WEAR A NIOSH-APPROVED EELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, OR A SUPPLIED-AIR RESPIRATOR IF USE CONDITIONS GENERATE VAPORS OR MISTS AT CONCENTRATIONS ABOVE THE PEL.

Eya Protection:

CHEMICAL GOGGLES UNLESS'A FULL FACEPIECE RESPIRATOR IS ALSO WORN. IT IS GENERALLY RECOGNIZED THAT CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTELTO THE

' SEVERITY'OF AN EYE INJURY.

OthSr Protective Clothing:

-LONG-SLEEVED-SHIRT, TROUSERS, VINYL OR BUTYL RUBBER BOOTS, VINYL OR I BUTYL RUBBER GLOVES, AND VINYL OR BUTYL RUBBER APRON. I Ventilation:

LOCAL MECHANICAL' EXHAUST VENTILATION CAPABLE OR MAINTAINING EMISSIONS

.AT THE POINT OF USE BELOW THE PEL.

• • • DOCUMENTARY ***

'Thic MSDS prepargd by :NOT STATED Dato of preparation for this. MSDS :12/28/89 q

..:.....___.....__..__.---------REVISION-------------------------------

1 11/86: CORRECTED NFPA REFERENCE. ADDED COMPONENT CAS NUMBERS AND PER-SONNEL' EXPOSURE-LIMITS AND HAZARD.-EXPANDED FIRST AID FOR SKIN CONTACT AND CORRECTED ~FIRST AID FOR SWALLOWING. EXPANDED INHALATION HAZARDS. ,

i C

r; -

MATERIAL SAFETY DXTA SHEET NUMBER 4697 _A3g g. j i

REVISED PERSONAL PROTECTION, FIRE FIGHTING INFORMATION. MATERIALS TO l

-AVOID, SPILL-AND LEAK PROCEDURES,-AND HANDLING ADVICE.

12/88: ADDED:OTHER REGULATORY INFORMATION.

08/89: ' CHANGED HEADING AND. CONTACT INFORMATION. .

• • • ADDITIONAL INFORMATION ***

l

---

OTHER REGULATORY INFORMATION---------------------

THIS PRODUCT IS A' TOXIC CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORI-ZATION ACT OF 1986 ADN 40CFR PART 372.

THIS PRODUCT IS CONSIDERED BY THE STATE OF CALIFORNIA'S SAFE DRINKING j WATER'AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65) AS CAUSING l CANCER OR REPRODUCTIVE TOXICITY AND FOR WHICH WARNINGS ARE NOW RE- i

-QUIRED..

---

OTHER REGULATORY INFORMATION---------------------

.THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL (S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40CFR PART 372:

Names- Cas No. %WT HYDRAZINE 302-01-2 35%

THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS (S) CONSIDERED BY THE

' STATE OF CALIFORNIA'S SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986-(PROPOSITION 65) AS CAUSING CANCER OR REPRODUCTIVE TOXICITY AND FOR WHICH WARNINGS ARE NOW REQUIRED:

CHEMICAL: CAS NO.

HYDRAZINE 302-01-2

---

NOTICE--------------------------------

• • VAN WATERS E ROGERS INC. ("VW&R") EXPRESSLY DISCLAIMS ALL EXPRESS OR IMPLIED WARRENTIES OF MERCHANTABILITY AND. FITNESS FOR A PARTICULAR

' PURPOSE, WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN.**

~

~ALL INFORMATION 4PPEARING'HEREIN IS BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES. WHILE THE INFOR-

=MATION IS BELIEVED TO BE ACCURATE,.VW&R MAKES NO REPRESENTATIONS AS TO ITS ACCURACY OR SUFFICIENCY. CONDITIONS OF USE ARE BEYOND VW&R'S CONTROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER

.THEIR OWN-OPERATING CONDITIONS TO DETERMINE WHETHER THE PRODUCT IS

. SUITABLE FOR THEIR:PARTICULAR PURPOSES AND THEY ASSUME ALL RISKS OF THEIR USE, HANDLING, AND DISPOSAL OF~THE PRODUCT, OR FROM THE PUBLI-CATION OR USE OF, OR RELIANCE UPON, INFORMATION CONTAINED HEREIN. THIS

MATERIAL' SAFETY DYlA SHEET NUMBER 4697 FA3I. 7 i

i INFORMATION RELATES ONLY TO THE PRODUCT DESIGNATED HEREIN, AND DOES NOT RELATE OTHER =TO ITS PROCESS. USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY 1

.{

~ Hazard Rating'(NFPA 704 CRITERIA)

HEALTH: 3 FIRE: 1- .

. REACTIVITY: 1 SPECIAL: NONE '

Hnzard Rating Scale:

0= MINIMAL' 1= SLIGHT 2= MODERATE 3= SERIOUS 4= SEVERE.

i d

Texas Utilities Electric Company Comanche Peak Steam Electric Station l Wastewater Discharge Permit No. 01854 Auxiliary Boller Chemical Additives

a. Manufacturers Product identification Number: Morpholine

b. Product Use: pH adjuster

c. Chemical Composition: See Attached Data Sheets

d. Product toxicity data: See Attached Data Sheets

o. Classification (non-persistent, persistent or bioaccumulative): NotAvailable

. f. Product 'or active ingredient half-life: Not Available l

g. Concentration in once-through cooling water: NotAvailable

h. Frequency of product use: Intermittent use not exceeding 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> /daylunit 1

7__

MATERIAL SAFETY DAT5 SHEET NUMBER 6339  ; AC,E .

PRODUCT: MORPHOLINE MANUFACTURER: DOW CHEMICAL U.S.A.

NFPA RATINGS HEALTH: 2 FIRE: 3 REACTIVITY: 0 OTHER:

SARA RATINGS FIRE: Y REACTIVITY: N PRESSURE: N ACUTE: Y CHRONIC: Y DATE~ PREPARED: 12/15/78 TSN: 171504 THIS COMPUTERIZED MSDS CONTAINS THE INFORMATION FROM THE MANUFACTURER'S ORIGINAL MSDS SUPPLIED TO TU ELECTRIC IN ACCORDANCE WITH 29 CFR 1910.1200.

A COPY OF THE ORIGINAL MSDS IS AVAILABLE THROUGH SAFETY AND INDUSTRIAL HEALTH: 954-5243.

• • • GENERAL PRODUCT INFORMATION ***

Trcde Product Name  : MORPHOLINE M:nufacturer Name :DOW CHEMICAL M:nufacturer's Address  : NUMERICAL ADDRESS NOT STATED ON MSDS City  : MIDLAND Stcte  : MICHIGAN ZIB :48640 Emergency Phone Number :517/636-4400 Additional Information:

PRODUCT CODE 255937

. *** INGREDIENTS.INFORMATION ***

• • EXPOSURE LIMITS **

INGREDIENT NAME PEL TLV MORPHOLINE NOT STATED NOT STATED

• • PERCENTAGES **

HIGH % LOW %

MORPHOLINE 100% NOT STATED

• • CAS NDMBERS **

CAS ON MSDS MORPHOLINE NOT STATED

• • • PHYSICAL / CHEMICAL CHARACTERISTICS ***

Colling'. Point. :262F (APPROXIMATELY)

Specific Gravity :1.0 25/25C VCpor Pressure :8.0 MMHG e 20C PCrcent Volatiles :100 V por Density (air =1) :3.0 W;ttr Solubility  : COMPLETELY MISCIBLE App arance and Odor  : COLORLESS, AMMONIACAL LIQUID.

L - ...

MATERIAL SAFETY CATA SHEET NUMBER' 6339 FAGE :

i i

• • • FIRE AND EXPLOSION HAZARD DATA *** 1 1

Flech Point' :98F Fitch Point Method  : TAG CLOSED CUP Uppsr Explosive Limit :NOT DETERMINED Lowsr Explosive Limit :1.4%

Extinguisher Media  : WATER FOG, ALCOHOL FOAM, CO2, DRY  ;

CHEMICAL. J Spscial Fire Fighting Procedures:

WEAR FULL PROTECTIVE CLOTHING WITH SELF-CONTAINED BREATHING APPARATUS.

Unusual Fire & Explosion Hazard:

NOT STATED ON THE ORIGINAL MSDS

• • • REACTIVITY DATA ***

Io this chemical stable under normal conditions of handling and storage? :WILL IGNITE IN AIR AT 555F, DECOMPOSES e 489F (254C)

' Conditions to Avoid :NONE STATED Incompatibility (materials to avoid)  : ACID, OXIDIZING MATERIAL.

Htz rdous decomposition products :POSSIBLY AMINATED DIETHYLENE GLYCOL, ACETALDEHYDE, FORMALDEHYDE, & NITROGEN DIOXIDE.

Io hazardous polymerization possible :WILL NOT OCCUR Conditions to avoid regarding polymerization :NOT STATED

• • • HEALTH HAZARD DATA ***

. EYES--CAUSES SEVERE BURNS.

SKIN--CAUSES' SEVERE BURN. LD50 FOR RABBITS ABOUT 500 MG/KG.

MODERATE TOXICITY.

INHALATION--OSHA GUIDE is ACGIH TLV IS 20 PPM INGESTION--LOW SINGLE DOSE ORAL TOXICITY LD50 (GUINEA PIGS) 900 L

MATERIAL SAFETY. DATA SHEET NUMBER 6339 ;Agr 3 j MG/KG, (RAT) 1050 MG/KG. VERY IRRITATING TO MUCOUS MEMBRANE.

Systemic & Other Effects:

IRRITATION OF TISSUE AND TISSUE INJURY.

Is chemical listed as a carcinogen or potential carcinogen ? NO National Toxicology Program IARC Monographs OSHA NOT STATED NOT STATED NOT STATED

• • • EMERGENCY AND FIRST AID PROCEDURES ***

k Emergency Telephone Number: (517) 636-4400 Eyes:

IMMEDIATE AND CONTINUOUS IRRIGATION WITH FLOWING WATER FOR AT LEAST THIRTY MINUTES IS IMPERATIVE. PROMPT MEDICAL CONSULTATION ESSENTIAL.

Skin:

=

SKIN BURN LIKELY. IMMEDIATE CONTINUOUS AND THOROUGH WASHING IN FLOWING WATER FOR THIRTY MINUTES IS IMPERATIVE. REMOVE CLOTHING IMMEDIATELY.

WASH CLOTHING BEFORE REUSE. DESTROY CONTAMINATED SHOES.

Ingestion:

IF SWALLOWED, INDUCE VOMITING IMMEDIATELY BY GIVING TWO GLASSES OF WATER AND STICKING FINGER DOWN THROAT. CALL A PHYSICIAN.

Inhalation:

REMOVE TO FRESH AIR IF EFFECTS OCCUR. CALL PHYSICIAN AND/OR TRANSPORT TO MEDICAL FACILITY.

F_ Note To Physician:

,. Eyes: MAY CAUSE SEVERE CORNEAL INJURY OR BURN. IF CORNEA IS

,,/ BURNED, INSTILL ANTIBIOTIC STEROID PREPARATION

j FREQUENTLY CONSULT OPTHALMOLOGIST.

Skin: MAY CAUSE SEVERE BURN.

Oral: MAY CAUSE SEVERE IRRITATION Systemic: MAY CAUSE KIDNEY DAMAGE. MAY CAUSE LIVER DAMAGE. HUMAN EFFECTS NOT ESTABLISHED. (SOME DIFFERENCE IN THE LITERATURE AS TO THE SEVERITY OF SKIN RESPONSE TO-DIRECT EXPOSURE) . BASED ON MINIMAL DATA. VERY ALKALINE.

TREATMENT BASED ON THE SOUND JUDGMENT OF THE PHYSICIAN AND THE INDIVIDUAL. REACTIONS OF THE PATIENT.

T~ s I

MATER'AL SAFETY DATX SHEET NUMBER 6339 l m ,

i

• • • PRECAUTIONS FOR SAFE HANDLING AND USE ***

l Proccutions To Be Taken In Handling And Storage: ,

i l HANDLE WITH GREAT CARE, AVOID EYE AND SKIN CONTACT AND BREATHING OF l VAPORS.

l Spill Or Leak Procedures:

USE ABSORBENT OR SAND.

! ATION. LARGE SPILLS MAY BE RECLAIMED FOR REDISTILL- l Wccto Disposal Method:

BURN IN INCINERATOR OR BURY AWAY FROM WATER SUPPLIES.

1

• • ADDITIONAL INFORMATION ** l DO NOT USE SODIUM NITRITE OR OTHER NITROSATING AGENTS IN FORMULATIONS CONTAINING THIS PRODUCT. SUSPECTED CANCER-CAUSING NITROSAMINES COULD l BE FORMED.

• • • CONTROL MEASURES ***

Rocpiratory Protection:

NIOSH APPROVED RESPIRATORY PROTECTION REQUIRED IN ABSENCE OF PROPER ENVIRONMENT CONTROL. FOR EMERGENCIES, A SELF-CONTAINED BREATHING APPARATUS OR A FULL-FACE RESPIRATOR AS APPROVED BY NIOSH IS RECOMMENDED.

Protsctive Clothing:

CLEAN, BODY-COVERING CLOTHING. IN ADDITION, IMPERVIOUS GLOVES, BOOTS APRON DEPENDING UPON TIC EXTENT AND THE SEVERITY OF EXPOSURE LIKELY.

Eya Trotection:

CHEMICAL WORKERE GOGGLES.

Oth0r Protective Equipmentr EYE FOUNTAIN AND SAFETY SHOWER IN WORK AREA.

V4ntilation Requirements:

RECOMMENDED CONTROL OF VAPORS TO SUGGESTED GUIDE.

1

• • • DOCUMENT 711Y ***

MATERIAL SAFETY DATK SHEET NUMBER 6339 PAGE 5 1

L This MSDS prepared by :NOT STATED ON THIS MSDS i

I Dnts of. preparation for this MSDS  : DECEMBER 15, 1978

• • • ADDITIONAL INFORMATION ***

l THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EZPRESSED OR IMPLIED, IS MADE. CONSULT THE DOW CHEMICAL COMPANY FOR FURTHER INFORMAITON.

f l

ADDITIONAL INFORMATION: DO NOT USE SODIUM NITRITE OR OTHER NITROSATING f AGENTS.IN FORMULATIONS CONTAINING THIS PRODUCT. SUSPECTED CANCER- 1 CAUSING NITROSAMINES COULD BE FORMED.

)

1 i

~

l l

s.

i L

l L..- -

CA5 # Species Latin Name Effect Endpoint Exposure Duration Conc. & fype 110918 Anaeystis eerusino2e PGR/' 8 0 ys 1700 F 110918 Brachydente rerio MOR LC50 96 Hours > 1000 F

.110918 CheLon engeL1 LC50*

110918 ChiLomenes paremoclue MOR 96 Nours 100000 F M>L dd' PGR/ 44 Nours 18000 F 110918 Cyprinus corple NOR/ 46 Nours 131 MG/KG F 110918 Daphnfo meena EC50 24 Nours 101me/L F 110918 Daphnte acene ECO 24 Nours 68mg/L F 110918 Cephnle meena EC100 24 Nours 260me/L F 110918 Daphnle seenn Ilet EC50* 24 Hours 119000 F 110918 Daphnfo magne NOR LC50 24 Hours 100000 F 110918 Entosiphon sulcatus - PGR/ 72 Hours 12000 F 110918 Ged uale offinis MOR LC50* M Noure 320000 F 110918 K elle sendvicensis BEN / 0.03 Nours 20000/ F 110918 Lepeals macrochirus MOR LC50 96 Neurs .350000 F 110918 Monidle beryLLine NOR LC50 M Neurs 400000 F 110918 Oncorhynchus sykise NOR LC50 M Neurs 380000 F 110918 meerhynchus mykise NOR LC50 M Neurs 380000 F 110918 scenodessus quadricaude PeR/ Net Reported 4100 F l

110918 Scenedeemus g edricaude PGR/ 7 Days 4100 F 110918 Scenodessus p adricaude PGR/ 8 Days 4100 F l 110918 Selenastrias capricornutus GRO EC50 M Neurs 20000 F 110914 Selenastrue copeIcernutus POR/ 3 Days 80000 F 110918 Selenostrum.capricornutus PGR/ 3 Days 100000 F 110918 Titopte op MOR LC50* M Neurs >1000000 F tringmann,4. and R.Ke n

• Testing of a d stences for Their Teufsity Thresholds i Nedet Orgenless Nferacystle (DIptesystle) seruginese and Scenedessus quadricaudem Mitt. Int. Ver. Theer. Angew. Llamot. 21:275 2M (Auther Commmicetten used) 1978B (R:ference Number: 15134)

Wellene,N. "Cooperfeen of the Senettivity of Brachydente terie and Leuciscus fdus by Testing the Flah Toxicity of Cheefcets and Westeueters" 2.

Weeser Abusseer Forsch. 15(2):49 52 (GER) (ENS ASS) 1982 (Rsference Mu ser 11037)

Mcce(n,J.C. and J.N. Peck,Jr. "The Teufcity of Selected Cheefcets used in Peuer Generating Stations to Neuellen Flahesa Ses 8 rent Tech. Report UNINI Seagrant TR 77 01, Mattenet Oseenic & Ateespheric Aedn., tecintille, 2:17 p. (U.S.' NTIS Pg 262437) 1976

-(R:forence Number: 603B)

Bringmann,4., R. Ken, and A. Winter 9eterminetfen of BlelegIcel Damage Free Water Pallutants to Protease. III. Sepresels Flagottstes* 2.

Wesser Abuesser Foresh. 13(5):170173 (GEs) (Eus Ass) 1900 (R:forence Musher 5719) 1.oeb,N.A. and W.N.Ketty "Aoute Gret Tamicity of 1,496 Chemicals Force Fed to Carpa U.S. Flah. Wildt. Serv., Sp. Sci. Rep. Flah. No. 471, Weehlneten, D.C.:124 p. 1963 (R forence thsher: 15898)

Bringmann,4. and R. Kenm Results of Temic Aetten of Water Pettutents en Daphnle mesme Strom Tested by en leproved Standardlaed Procesare" 2.

Weseer Abusseer Forsch.15(1):16 (est) (ens Ass) 1982

-(R:ference Number: 707)

C;teneri,0., R.D.Seese, 8.8elsesi, A.Provint, and N.Vight "Slodegradation and Tonicity of Selected Amines on Apotic orgentessa chemosphere 9(12):753 762

1980 (R:ftrenceMuEnr 5089)

• Bringmann.G. and R.Kuhn u tesults of the Damastry Ef fect of Water Pottutents on Daphnis magne" 2. Weseer Abuseser Forsch. 10(5):161 164 (GRR) (ENG ASS) 19713 (R:f:rence numer 5718)

Brinpenn,0. and R.Ke n "Comperleen of the Toulcity Thresholde of Water PIllutants to Bacterle, Algae, and Proteses in the cett leuttlplication

' Inhibition Test

• Water Res. 14(3):231241 (Auther communication used) 19004 (R:forence skaters $303) 4 Histt,R.W., J.J.Neughton, erd D.C.Nettheus "Ef fects of Chemicate en a schooting Flah, K4 Lle sendvicenale" Slot. Butt. 104:28 44 1953 (R:forence Nutor 10010)

Deusen,0.W., A.L.Jerminee, D.Dravhbl, and E. Rider *The Acute Tealcity of 4F Insastrict themicate to Freak and Satttester Flaheen J. Nesord. Noter. '

1(4):303 314 1977 (R:forence thsters SG)

I I

.. I j

j q

. system ouers-vleu Ree:rdo Reporte Estp

~de Chemical Informatten 6666666666644444444444444444444 ~ " " " " " "' " " ~

' CAS Naher 110918 **

' 9CI Name NORPN0LINE **

l j

sss,, ~ ~ w , , , , , , , . . . . w , a m ,, w w , w w - w -,,,,,,,,,,w9

~04 specien Infernetien '''"'''""'" ~ " ' * '''''^~

' Naher 5 Minor Code CLAD **

"' casumen Name Water fles Major Code CR *~

j

'-. Latin Name Daphnfo menne **

' j Life 24 N **

~ ~ w w w w ,, w n, l 2,,,,, w n w w ns n,1,,,,,,,,,,,,,,,,,,

w ,,, w ,,, . .., w w ,, w ,,.

"'Effest NOR En$sint LCSO Concentratten 100000 Type F "

' Test Method unmeneured Tissue NR "

Unit us/L' Lesation Lab

' Teet Duretien 24.0000 Neure Nedta Fresh **

'.Centril Code Indetereinste Emposure Type S "

~' Firtt Auther Bringmann,8. Reference umher 5718 "

~* P 4. fr. 1977 **

Revleu Come 2 a4444444444444444444444444444444444444444444444444444444444444444444 a 444444443" "e First ><teet- >< OCF/Canc ><T, N, A, 00, pu, 8, QC, D>< Save >< Close >

~

< Prov >< Nest > <; teference > <temerke > < search > < Tebte >

Record 10 of 24 Neve to nest record of apJery reeutte j

. System Query View Records Reports Help

% Chemical Informetion H M M'A'4AAA44M H M H M M M H M M M M M M M M *~ H H M*~

~'CAS Number 110918 *~

~' 9CI Name MORPH 0LINE ..

am

• • L& u2&&ALLAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAgggggg

~

~56 species Inf ormation " A""'""""'"'""'"'"""'"u'""uun '~

~' Minor Code CLAo Number 5 *~

Major Code CR

~' Comunen Name Water fles *~

~' Latin Name Daphnia magna

• ~

~' Life NR

- m ,u u u uL u u A u u u u u u u Au k u u u u u u u u u u uA3-n A uu u uu uuuu uuuuuu u u u An Anu Auu u A uu u u u u u Au uu ug-Type F *~

~'Effact En@ointEC100 concentration 260ms/l

• ~

~* Test Method unmesoured Tissue unit as/L Location Lab

• ~

Media Fresh

~* Test Duration 24.0000 Hours *~

Exposure Type S

~' control Code Indeterminate '~

~' First Author Bringmann,G. Reference Number 707

• ~

~' Revieu Code 2 Pub. Yr. 1982' g u u u u u u u A u u u A u u u u u u u u u u ku v u u u u u u u u u u u u u uA}-

>< SCF/ Conc ><T, N, A, 00, pH, 8, QC, D>< SaVe >< Close >

~< First ><Last > < Table >

~

>< Reference > < Remarks > < search

< Prev ><Next Record 7 of 24 Nove to next record of gaery results

+

System Query View Records Reports Help

~56 Chemical Information 'A'#'44'4'#AA/4A'A*' ' m 'm 'mw'-

l

~*CAS Number 110918 *-

~* l 9CI Name NORPHOLINE *-

_ .. - g _ - - - - - - - _ _ . ~ _ _ . _ , _ , _ ,, _ ,-

54 Species Information ' " ^^ w m m m 'd m ' m m 'e m ' m m -

~*- Number 5 *~

, Minor Code CLAD

• • Common Name Water fles Mejor Code CR *-

~* Latin Name Daphnia magne *-

~*

Life NR *~

a4A44444A44444444A444444A44AmaA4444444Aaaa444444A4&aa44444444A4444,444,444,4,s-

"Ha&&&AAA&&AAAAAAAAAAAA&&&&AA&&&4AA&&AAAA&&AAA&&&&a&&AA&&&&AAA4AAAAAAAAA&&&&&&s-

• • Effact En@ointEC50 concentration 101ms/L Type F *-

~* *~

Test Method Unmeasured Tissue Unit as/L Location Lab

~* Test Duration 24.0000 Neurs *~

Media Fresh

~* Control Code Indeterminate *~

Exposure Type S

~* First Author Bringmann,0. Reference W h 707 *~

~* *~

Pub. Yr. 1982 Review Code 2 "AdadadadddddAAAAdddddadadadadadadadadaddadadddddaddaddd&ddadadddaadad&dddddd&%-

~< First ><Lest >< BCF/ Conc ><T, N, A, D0, pN, S, QC, D>< SaVe >< Close >

~< Prev >< West >< Refarence > < Remarks > < Search > < Table >

Record 8 of 24 Nove to next record of query results v

Se e

6

l I

I l

l System Query View Records Reports Netp

.~66 Chemical information ^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^*~ i

• ~

~'CAS Iksber 110918

~' *~

9CI Name NORPNOLI M

. .- i

~&&d&&AAAAAAA&&&&AAAAAAA&&AAAAAAAAA&&dA&&&&&AAAAAAAAAA&&&&AAAAAAAAAAAA&&AAAAAA%~

'"66 $pec i ee I nf ormet i on ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ *~

• • *~

iksber 5 Minor Code CLAD Major Code CR *~

"* Common Name Weter f Lee

~' Latin Name Daphnia magne *~

' *~

Life m "A A A A AA A A AAAAAam AAllia A&& AAAAA A AA A A&&& A A&& AA AA AA A&& A AA A A AA&&& A A A A A A A A A AA A A A AAA%*

~KAAAAAA&&&AAAAAAAAAAAAAAAAAA&&AAAAAAAA&&AAAAA&&&&&&&&&&AAAAAAAAAAAAA&&&&&AAAAs"

• ~

"*Effect IM En@oint EC50* Concentration 119000 Type F

• ~

~* Test Method Measured Yissue M Unit us/L Location Lab

'~

~' Test Duration 24.0000 Nours Media Fresh Exposure Type M **'

" Control Code Indeterminate

• ~

" First Author Calamert,0., Reference thaber 5089

• ~

~' Pth. Yr. 1980 Review code 2 A A A A&&& A A A A A&& A A A&&A AA AAA AA A AA A&&& A A A AA A A A A A A A&& A A A A A A A A Ad& A A A A A A A A A A&&& A A A A As-

< First ><tast >< BCF/ Conc ><T, N, A, 00, pH, S, QC, D>< SeVe >< Close >

~

< Prev ><Next >< Reference > < Remarks > < Search > < Table >

Record 9 of 24 Move to next record of query results

i -

-System Quer$ Vleu Rectrde Reporte N3lp

' % Cheet cal informat i on M AMMa'MaM am^^ ^ ^ ^ ^'n"'"a n n;-

• • CAS Number 110914 **

~*

9CI Name NORPMOLINE *-

~s u u n n u n , , , , , , , , , , , , , , , , , u , u , u n u , , , , , , u n u u n n , u n u , , , , , u , , ,3 54 Spac l es Informat t en "" " "" " " '""""'"""'"""'"'""'"" "" *

' Muuher 5 Nic.or Cees CLA0 **

• • Ceauen Name Water flee Mejor Code CR '~

~*

Latin Ness Daphnte magne . *~

'~*

Life 24 N **

.nk u n n n u ,u u u u u u u u u u u u u u u u u ,,u gggggggggggggggggggggas,.

n>>,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,

\

'~5Effect NOR. En @ int LC50 Concentratten 100000 - Type F ** l

~*

Test Method IMmeneured fleeue NR Unit us/L Lesetlen Lab - '"

' "' Test Duretten 24.0000 Neurs Nedle Fresh ** ,

l

~* Centrol Code Indeterminate Emposure Type S **

• • First Auther Bringueres,s. Reference thaber 5714 " '

~* P e . Yr. 1977 **

Revleu Code 1

~M \~

~4 Fir"t ><Lest >< BCF/Cene ><T, N, A, 00, PN, S, OC, D>< SeWe >< Close >  !

~4 Prov >< Meat > t', Reference > <temerke > < Search > < Table >

Record 10 of 24.

Neve t3 nest record of gaery results a

te

4 .

l System- Query Vleu Records Reports Help

~56 Chemi cal Informet len """"""""'"'""'""'""""""""'""*"

• ~

"'CAS Number 110918

~* **

9CI Name NORPHOLINE e e-

~

)~

~56 Spec t ee Information """""""""'"'""'"""u"u'"u"'"'""=

~*' *"'

thaber 5 Minor Code CLAD Nejor Code CR '~

~* Common Name Unter fles l

' ' ' Latin Name Daphnia magne '~

~' *~

Life 24 N l A u Ausuusuuuuuuuuuuuu&uu u uu uu u uauuu uuauuuu a n~

"Ma&adaduadadadadaAAAdudadadaddua A Audadda Addadudadadda AA A Audaddaadadud Am~ -

• ~

Effect MOR EinheintLC50 concentration 100000 Type F

• ~

~' Test Method Unsensured Tissue NR Unit ug/L Location Lab

• ~

~* Test Duratten 24.0000 Neurs Media Fresh-

• ~'

' ~' control Code Indeterminate Exposure Type S

"* First Auther Bringuarm,0. Reference Number 5718  ;

~* *~  !

' P4. Yr.1977 Revleu Code 2 "L& AA AAA AA&&AAM AMAAAA AMA&&A AA AA A A A A&&& Aua A&& A A A A A A A A AA A A A A A AA A A A A A A A&&&uM~

~< First ><Last ; >< BCF/ Cons ><T, N, A, 00, PN, S, QC, 0>< SaVe >< Close > l

~< Prev ><Next >< Reference > < Remarks > < Search > < Tebte > l 1

Record 10 of 24  ;

Nove to next record of query results i i

l i

.I

Attachment 9 Technical Report, item 16.

Wastewater Ponds Table and Low Volume Waste Pond Liner Specifications Texas Utilities Electric Company Comanche Peak Steam Electric Station TNRCC-TPDES Permit No. 01854

G N

RI LS OL o o o o o o w Ta E N N N N N N rW O

lo f

M a h

a m g m N m u o

mh m O m r m

m KT AC I

m' s

'se 8

"s

's

's o t m

m E E L T m

m e m Y Y Y e

Y e e N g n

m E m Y is m

u D u s s m u a p

r N e OI f t

a _

T P 3 4 m 3 *e

• I d d e d d R t te n .

a l t C a a t

a t

a a o _

S E m m n r m m m p _

D e t e t e e t e e e R

! l lt t w

E M A A A A l

A l

t c

N I

e p _

L .

s e

e r

m ) 04 01 01 04 s m t 06 0 it m E4 0 09 09 06 0 0 N m m

Mer Uc 4, 0 0, 4 0, 4 0, 9 0, 4 0, t o

O t r m L a, 0

3 0

0 0

0 01 0

0 0

0 n _

o i

I m Ola 0 6 k T p m u

Vg 1 6, 4, 5, 2, c A ( 1 1 6 1 1 a

T e s m b S R e m ; e m t n

d e

l m tEE L e p C a miGGWAE mTAAO RDm m

• 55 5'. 5

5. 5 55 5 m m I c PRRL TRu UA m 0 0". 55 t

a u RSn TDh i

mEEEE mDVVB AA N AG usm 5 5 1 1 55 1 1 1 1 11 1 1 1 1 1

1 t

e r is p

u e CNc m m u

T

=

g a

E L POe T S N

u m

u ' '4 '4 6

0 i,

s k

a E e OEA u6 1 1 6 0 6* u u le Rh SR m7 m *x 1 1 x

3 1

'x 4

• x o is M Et NA Er m6

• x 0 0'

• x 0 0 0 u h ATo a r

f 1 T G o EA T 6 D

m 7 m

u m

1 4

1 4

1 4

1 4 2 u q

e e g

SW1 E D lo w k a

a .

K Tm E L f T L AA le ASe t I

C TF 4

0 4

0 4

0 4

0 4

0 4

0 F

= l la EAi OU 0 0 0 0 1 0 n

s -

PWt E

o e

S SO A it a

o t

le c

H e r lo s o c C

N n

o p

m m

m m

E P

Y e e e e t

e s

ae e a

p v

e h

ic h

A s m m

T R

t s

e t

s a

t s

a t

a s wt ga s

t s

a

= w r -

M e m E w w w w nw w E e n

O R m m

T A e e e e e

ne e )

e i

l C m m

W E

m u

m u

m u

m u

amu e m u

g r

t s

r _

m T l l l

cl a i o

l m S o o lo l o lo h f

e m A v v v v av v s

c h m

m W w o

w w w t

ewo w d i t u

m l lo lo lo ml lo ( w o e -

a l

e l

s eg m 9 p

o ba -

pk m E m S T. T. T. sr a m O i

dein me -

m m

P E. E. E. E. =l ul sf R o m U D. D. D. T. dE at -

m m

P mF m

C C C C C ,P yn _

)Orbu n e o A B C g n

oHndm t

i. l l i e r a N n mi i r r i l emiomi e O i s in n n ns n t t I

D AT a s is a

is ea d a

a e0 r

(66ot nh B a a eB r NN e B B B l

Ce a tniac 3mdro O

PaG g t la S S S a as ees t n a t .

hE l a =

S r E u M M M t p

r L B meiho ir c

=

=

'D S MeW F nnwt .

W W W A uv c o et T tset r te er O oArde _

R T ct ckliz DE Nm S = ooet un aao =

Oh E CDCLt PU T N 1 2 3 4 5 S O N WmmW

=.

=

Low Volume Waste Pond Liner Specifications (Response to item 16.e. of the Technical Report)

1. Low volume waste ponds are lined with High Density Polyethylene Liners (HDPL) and were constructed in accordance with the requirements set forth in this attachment entitled: DESIGN DATA FOR SINGLE OR DOUBLE LINER SYSTEM. ,

2. Liner construction leak testing was performed in accordance with the portion of  !

this attachment entitled CONTRACT FOR SERVICES BY AND BETWEEN Leak Location Services, Inc. AND Texas Utilities Electric Company DATED August 5, 1992 NO. 6K9-00655. Records of leak testing results are unavailable. l l

l l

l l

f

i

~

-TU Electric - Generating Division Revision: 0 Specification No.: 719 2000.C8001 4/22/92 ATTACHMENT A DESIGN DATA FOR SINGLE OR DOUBLE LINER SYSTEM 1 1

1.- Minimum service life of the components of the synthetic liner system shall be l 20 years.

2. The comporeat of the liner system shall be desiWd to withstand the following:

2.1 - The fluid to be pumped into the facility will have the following estimated chemical analysis:

2 Constituent Concentration (* PPM as Ions) ph 14 max. 8. avg. 1 min.

' Ca

• _.25.Q m ax. 2M avg. _110_ min.

Mg* _.121. max. - _121. avg. 10_ min.

Na* 21QQQmax. 10(Lavg.' .22Lmin.

SO4* 21QQQmax. .121QQavg. .19000 min.

Cl

• _.2210 max. _.fiGQavg. 4Smin.

300nmar- at spike conditions In addition, the fluid will have the following chemicals:

Acetic Acid -

5%

Aluminum Salts - < 1%

Ammonia - < 1%

Ammonium Hydroxide - < 1%

Ammonium Salts ' - < 1%

PAGE - A-1

c- .

i

'111 Electric - Generating Division Revision: 0

_ .. Specification No.: 719 2000-C8001 j

4/22/92 l ATTACHMENT A 4

Citric Acid -

5-10 %  ;

Formic Acid -

3%

Hydrogen Peroxide -

3 % (ppm)

Phosphoric Acid -

1-5 % ,

Sodium Hydroxide -

1-5 %

Sulfuric Acid -

1-5 %

Trichloroethylene - < 1%

Morpholine - < 1%  ;

Hydrazine -

5-50 ppm Ferric Sulphate -

10 % ppm Ferric Hydroxide - < 1%

Boric Acid /Borotes -

107000 ppm Sodium Phosphate -

50 ppm Dimethyl Amid (DMAD) - < 1%

Sodium Nitrite _ -

500 ppm Cationic Polymer < -

2 ppm Under abnormal operations, the concentration (PPM as Ions) can increase  ;

maximum values as much as .20_ percent. i TDS, PPM fiQQQQmax. _1300 avg. 121Qmin.

Conductivity, > _1QQQQmax. _1QQQavg. .2000 min.

hos Temperature Range . Jig._deg. F. to ._120 deg. F.

Max. localized temp. _.100_deg. F.

2.2 'The solids in a slurry form to be pumped into the facility will have the following properties:

Slurry SpeciSc Gravity LQQQmin. _LQ22 max.

Solids % by Weight 17% min.E max.

Solids Density 451bs. per cubic foot.

PAGE A-2

TU Electric - Generating Division Revision: 0 Specification No.: 719 2000-C8001 4/22/92 A'ITACHMENT A Solids Constituent Percent By Weight i

I CaSO4 .310 max. L1. avg. O min.

CaSO3 .912 max. R avg. .J12 min.

Inerts _64Jmax. 14)_ avg. 4.3 min.

1 2.3 Ambient Air Conditions:

1 1

Temperature .1.deg. F. to .J11deg. F.

__46_deg. F. to ._81deg. F. avg.

Wind .6.9_ miles per hour max.

.J2 miles per hour avg.

2.4 Description of the Facility:

Maximum operating water level elevation 857. ft.; subgrade 95%

compacted clayey sand; and HDPE double liners with leachate collection system.

2.5 Drainage Net Design _ Criteria:

W Mini =n= thickness 0.25 inch. j; O 01 S *

• Minimum hydraulic transmissivity shall be 3x10. msq/sec at a compressive stress of 4000 lbs./sqft.(.200kPa) with boundary conditions consisting of 60 mils HDPE Gexible membranes, as specified in Division 3 of Specification C8001, using water at 20 dess. C under a gradient (i) of 0J, reference test

- ASTM D 4716-87, Constant Head Hydraulic Transmissivity (In Plane Flow) of Geotextiles and Geotextile Related Products.

PAGE - A-3

TU ELECTRIC GENERATING DIVISION-400 N. Olive Street, LB 81 Dallas, Texas 75201 STANDARD SPErWICATION FOR IMPERVIOUS LINER (SYNTHETIC)

SPErTFICATION NO.: C3432 4

REVISION NO.: jL DATE: Ja==w 3.1992 w spadamshe caea, ase,e

m . .

EJ Elecmc Generating Division Revision: 0 Standard Specificati::n No.: C3432 January 3,1992 STANDARD SPECIFICARON FOR ,

IMPERVIOUS LINER (SYNTHETIC) l TABY F OF CONTENTS ARECLE fAQE 1.0 GENERAL 1 1.1 Description of Work To Be Performed i 1.2 Dm4Gon of Systems 1 2.0 CODES AND STANDARDS 1 2.1 Codes and Standards 1 3.0 DOCUMElfrARON 2 3.1 Submittals with Bids 2 3.2 Submittals after Award of Contract 2 33 Submittals during Installation 2 4.0 MATERIAL 3 4.1 General 3 4.2 Uner Material 3 43 Welding Material 5 4.4 Drainags Net Material 5 4.5 Geotestile Fabric Material 6 i

layerness user (spaksite) -

sammened spesamstem CNRL asy.e

TU Electric Generating Divisi:n Revision: 0

' Standard Specificatien No.: C3432 January 3,1992 i

STANDARD SPECIFICATION FOR l IMPERVIOUS LINER (SYNTHERC) l TABIF OF CONTENTS ARTICLE g 5.0 INSTALLATION 7 5.1 General 7 5.2 Geotexule Fabric Strips Installation 7 53 IJner Installarian 8 5.4 Field Seaming of Liner (Welding) 9 5.5 Drainage Net Installation 10 5.6 Anchor Trench 11 .

, 5.7 Repairing and Patma of Liner 11 l 5.8 Air-Gas Vents 12 5.9 Ilner to Concrete Strucmres and ?enetrations 12 6.0 OUAr rrY CONTROL - INSPECTION & in1u4G 12 6.1 General 12 6.2 Field Quality Control 13 63 Trial Field Seam Testing 14' 7.0 WAKRANUES 14 imeerdams user (sm w spessRamese CSSR. Asr.G

l TU Elterne - Generating Divisien Revision: 0 Standard Specificatien No: C3432 Page: 1 1/3/92 STANDARD SPECIFICATION FOR IMPERVIOUS LINER (SYNTHETIC) i 1.0. GENERAL 1.1 Description of Work To Be Performed This Specification covers the materials, delivery, installation, quality control (inspections and testing), and warrannes for a single impervious liner system or a ,

double impervious liners system to be used for lining basms for solid or liquid i au.a-1.2 DescriRgan of Svntems 1.2.1 For a single liner system, the liner shall be the primary liner. The liner shall be applied over prepared subgrade or other suitable surface and anchored at the top of the facility.

1.2.2 For a double liners system, the bottom liner shall be the secondary liner and the top liner shall be the primary liner. Between the two liners there shall be drainage net leading to a leachase collection sump. The liners and drainage net will be applied over prepared subgrade or other suitable surface and anchored at the top of the facility.

1.2.3 For each liner system, there shall be an air-gas venting system as speci5ed herein.

2.0 CODES AND STANDARDS

- 2.1 I4 test edition of the following dammante in effect on the date of issue of this Mada= for bid, together with the da==ana they reference, shall form a part of this Wdan 2.1.1 American Standards of Testing Materials (ASTM).

2.1.2 EPA /530SW86031 - Technical Guidance Domment- " Construction Quality Assurance for Hazardous Waste Land Disposal FaciHties".

Imperesas user (symemme seamend seemssensa cses, asr.e

TU Electric - Generating Division Revision: 0 Standard Specification N@: C3432 Page: 2 1/3/92 2.1.3 EPA /SW-870. "Uning of Waste Impoundment and Disposal Facilities".

2.1.4 NSF (National Sanitation Foundation) - Standard Number 54 for Flexible Membrane Liners.

2.2 All work practices shall conform to accepted good work practices for lining solid or liquid imaaimdmants and the latest requirements of OSHA and all federal, state, and local requirements.

3.0 DOCUMENTATION 3.1 Subnuttals with Bids The Contractor shall submit with the Bid the following Items:

a. Specification sheets and samples of liner, drainage net, and geotextile fabric to be supplied.

b. Written instructions for storage, h=adlia= ins *=11=+iaa seaming, and repairing of the materials.

I

c. M==id m'ing quality control procedures and field quality control procedures.

d. Material and installation warrannes.

3.2 Submittals after Award of Contract Upon award of the Contract, the Contractor shall submit the followmg Items:

a. Shop drawings of liner panel layout, air-gas vent design, liner to concrete details and other - . " / , details to the Owner for review prior to fabrication.

b. Quality control cerheiaa of compliance on mannfactured rolled liner panels i prior to field installation of the panels.

3.3 Submittals during Installation  :

The Contractor shall maintain and submit daily records of testing, liner damages and repairs to the Owner.

Impmens IJear (synshsM senene spesmannes cMai, ass,e

TU Electric - Generating Division Revision: 0 i Standard Specification No: C3432 Page: 3 1/3/92 ,

4.0. MATERIALS 4.1 General 4.1.1 The materials supplied under these specificanons shall be new first quality products designed and manufactured specifically for installing a liner system for the purpose ofliquid and/or solid containment in the facility as shown on the drawmss and which have been sausfactorily demonstrated by prior use to be suitable and durable for such use.

1 Ilner Material 4.2 l

4.2.1 The liner material shall be ==aafaealeed from high quality high density polyethylene copolymer resin and specifically coa for use in the facdity. Reprocessed i materials shall not be used. l 4.2.2 The lining material shall be a single ply extrusion construction ptepared by low-pressure polymerization of ethylene as the principle monomer.

4.23 The liner shall have a nominal 60 mils thielma==

4.2.4 The liner shall be so praAH as to be free of holes, blisters, nadi ==arsed raw materials, or any signs of eaataminatian by foreign matter. Any such defect shall be repaired using the extrusion fusion welding thai;2e in accordance with their written instructions and as specified herein. The defacead area locations and date of repairs shall be recorded and information submitted to the Owner.

4.2.5 The liner shall have the following / ==mifmemred physical properties:

Prnparty Test Method Requirements

a. Thicimess ASTM D1593 54 mils, (min.)

b. Dennisy ASTM D1505 0.94/gm/cc

c. Matt Flow Inden ASTM D1238 Condition E 3, g/10 minutes randivian P .5, g/10 minutes imperveses IJmer (W w spostamales cses, asr.e

l

. TU Elecmc - Generating Divisicn

Standard Specificati n No: C3432 Revision: 0 Page: 4  !

1/3/92

d. Minimum Tensile Propenies:  ;

(Each Direction)  ;

dl. Tensile Strength at Yield ASTM D638 140 lbs./in. width I l

d2. Tensile Strength at Break ASTM D638 240 lbs./in. width I d3. Elongation at Break ASTM D638 700 %

d4. Elongation at Yield ASTM D638 13 %

d5. Modulus of Elasticity ASTM D638 80,000 psi

e. Tsar and Impact Propenies:

el. Tear Resistance ASTM D1004 45 lbs. (min.)

e2. Puncture Resistance FTMS 101 90 lbs.

Method 2065

f. Seam and Adhesion Properties:

fl. Seams Peel Adhesion ASTM D413 Fdm Tear Bond pounds /in.

min. -

g. Environm,nemi Resistance Properties

gl. Low Temperature ASTM D746 70 deg. C g2. Dimennianal Stability ASTM D1204 11%

(each direction) 212 deg. F,15 min.

33. Volatile Imes ASTM D1203 0.1 g4.. Resistance to Soil Burial ASTM D3083 (max. % change in original vaine)

a. Tensde Strength at Yield and Break i 10

b. . Elongation at Yield and Break i 10 i

ImperWees IJear (Spushneld scenense spesiassess cses, ase.e l

. TU Electric - Generating Division Revision: 0

' Standard Specificati::n No: C3432 Page: 5

-1/3/92 l

c. Modulus of Elasticity . 10 g5. Ozone Resistance ASTM D1149,7 days, No Cracks 100 pphm.104 deg. F g6. Environmental Stress Crack ASTM D1693 1500 +

(minimn= hours) Condition C (50deg.C) g7. Water Absorption ASTM D570 0.1%

(max. percent weight change) g8. Hydrostatic Resistance ASTM D751 Method A 490 psi Procedure 1 g9. Coef5cient of linear ASTM D696 0.00012 normalwe (in/in/ des. C [-30 des +30 des]

g10. Moisture Vapor Tran<mia<ian ASTM E96 0.03 (g/sq. m day) 1 4.2.5 All rolled liner panels shall be sized to ../ ./ I the amount of field seaming; or by weight and the ability of a crew to place it in the field.

4.2.6 Each rolled liner panel shall be labeled with thih length, width, and fabrication mark munber to facilitate installati^n 4.3 Weldint Matarial 4.3.1 Estrusiast weld material shall be mamif=renrod froin the same material used in Producing the lining membrans.

i 4.3.2 All welding meterial shall be delivered in ths. original sealed containers each with an indelible label bearing the brand name, mannine'urefs mark munber, and complete directions as to proper storage.

4.4 Drainaga Net Material 4.4.1 The drainage not shall be an integrally formed pd i ec/s net strucmre specifically designed and fabricated to be used as drainage medium It shall have umform tapervesse user (syuhmis) seamend speslassess csas, mer.e

. TU Electric Grnerating Divisi::n Revision: 0 Standard Specification No: C3432 Page: 6 1/3/92 channels, open area and thickness to assure uniform flow throughout the structure.

It shall have high tensile strength and tear strength to resist installation damage leadi- on steep slopes. It shall also have a low compressibility under high loadmg {

to maintain a high tranmissivity under a range of loading conditions. The dramage  !

not shan be resistant to the materials being sared in the facility and shau also be l resistant to ultraviolet degradation.

l 4.4.2 The drainage net shall have a minimum thicima<s of 0.25.t. 0.025 inch.

4.5 Geotaxule Fabric Matenal l

,4.5.1 'Ihe geotestile shall be 100% polyester nonwoven fabric.

4.5.2 The geotezule fabric shall have the following physical properties:

a. Fabric Weight (ASTM D-3776) 7.4 oz/sq yd

b. Thickness (ASTM D 1777) 100 mils

c. Grab Strength (ASTM D 4632) 270/225 lb, MD/CD*

d. Grab Elongation (ASTM D 4632) 75/85 %,MD/CD

e. Trapesoid Tear Strength (ASTM D 4533) 105/95 lb, MD/CD

f. Puncere Sse 3 -5/16" Hemispherical Tip (ASTM D-3787) 115 lbs.

g. Muuan Burst Strength (ASTM D 3786) 390 psi

h. Vertical Water Flow (ASTM D 4491) 120 gal / min /sqft

i. AOS (U.S.Std. Sieve) (CW 02215 mod. to 10 min.) 70 120

• MD = Machine Direction, CD = Cross Machine Directions 4.5.3 The gooteutus fabric rous shan have the following minimim average physical properties (weakest pi dpel direction):

a. Fabric Weight (ASTM D 3776) 7.1 oz/sqyd

b. 'Ibicimess (ASTM D l'n7) 100 mils

c. Grab Strength (ASTM D 4623)- 200 lb.

d. Grab Elongadon (ASTM D-4632) 60 %

e. Trapesoid Tear Strength (ASTM D 4533) 75 lbs.

s. Puncare Strength -5/16" Hemispherical 11p (ASTM D 3787) 95 lbs.

h. Mauen Burst Strength (ASTM D 3786) 360 psi L AOS (U.S.Std. Sieve)(CW-02215 mod. to 10 min) 70 120 iso w e u mme<sym e n w w spensamen esen,asy.e

, TU Eltetric . Gen: rating Division Revision: 0

' Standard Specificati:n No: C3432 Page: 7 1/3/92 5.0 INSTALI.ATION 5.1 General 5.1.1 De Contractor shall provide crews experienced in the installation of all components of the synthetic liner system.

l 5.1.2 The rolled liner shall remain in the =hiapia: containers and shall be covered and protected from weather until ready for installatian. i 1

5.1.3 ne campan==*n of the liner system shall not be placed during rain or on surfaces I that are excessively wet or muddy as determmed by the Owner.

5.1.4 Vehicle type equipment (cars, trucks, forldifts, frontend loaders, etc.) shall not be

. perantted to travel on the liner system at any time.

5.1.5_ If any portion of the liner is damaged by any cause, the Owner shall be nonfied im=artistely. All damages shall be repaired by the Contractor. Records of liner ,

damages and repairs will be maintainant by the Contractor and provided to Owner.

5.1.6 De installation ofliner must be coordinated very closely with the preparation of the subgrade. De intent is that an area of subgrade be propered to finished grade and I smooth without any irregularities just pnor to installarian of the liner. He 1 Contractor shall direct that certam areas of the subgrade be prepared to support the  !

- installation of the liner. After acceptance by the Contractor, the Contractor shall be responsible for its maintenance-5.1.7 The Contractor shall not begin the top liner installation until the completion of electrical leak detection test of the bottom liner, the completion of bottom liner's repairs, and installmeian of the drainage net.

5.1.8 De Contractor shall furnish, f!!! and place sandbags to hold down the drainage net and top liner during the electrical leak detection and location test. The sandbags when flDod shall have a =ini=== weight of 25 pounds. De sandbags shall be depicyed on a 25 feet center to center grid on the bottom of the facility. The san 6egs required on the slope at the 25 feet center to center grid shall be placed at the toe of the slope. The sandbags shall be left in place.

5.2 Geotentila Fabric Strips Installation 5.2.1 The gootestile fabric shall be instaued in conhection with the deployment of bottom taperness unsr (symhnist seemesse symunesten Q4 3, Ber.e

'RJ Electric - Generating Divisi:n

- Revision: 0 Standard Specificatica No: C3432 Page: 8 1/3/92 liner. Fabric that has been installed shall be covered as soon as possible and shall not be left exposed overnight unless authorized by the Owner.

5.2.2 Imtalled fabric shall not be *Md to precipitation. Any fabric that has beconne saturated shall be removed and replaced with dry fabric before being covered by the bottom liner.

5.23 Installed fabric shall be temporanly held down with sandbags until covered by the bottom liner.

5.2.4 Fabric ends shall be tied together using electrical tie wraps (plastic) or with nylon

[q cord (100 lbs. strength).

5.2.5 Geotextile fabric strips for air gas ventilation shall be installed between the bouom

, liner and the subgrade. '

a. A .. ' . ' ..' .. of l'-(T' wide strips of geotextile fabric shall be installed along the inside slopes having the same spacings as air-gas vents. The fabric shall tie into and vent thru the air-gas vent. The strips shall be anchored at the top of the slope, installed down the slope and overlap the geoemmia fabric strip at the toe of slope,

b. A ..'"'." .. of 3' 0" wide strips of geotextile fabric shall be installed along the toe of inside slopes and across the bottom of the facility.

5.2.6 Geotaxule fabric shall bo installed as a cushion between the liner and concrete surfaces. The geotexule fabric shall extend a > ' . '- ~ l'-0" beyond the edge of the concrete.

53 Iinar Installatina 53.1 The !iner shan be oriented in such a mannar a to minimi= stress on factory seams l and field seems. Liner shall be placed with factory seams and long 6 eld seams oriented longitudinauy with the slopes.

53.2 The liner shau extend up the slopes, into, and across the bottom of the anchor trench or anchor strip.  ;

533 The Contractor shall pay particular attention to the prevailing wind conditions so that the pl==aam of the liner overlaps do not oppose the prevailing wmd.

i=, n*= user <sposem senadese sommamesse cses,mer.e

. TU Electric Generating Divisi:n Revision: 0

' Standard Specification No: C3432 Page: 9 1/3/92 53.4 The liner shall be tetnporanly anchored and held in place with sandbags or other approved methods until completion of installation.

5.3.5 ' The Contractor shall ensure that the liner are positioned in a slackened condition so that they will conform to basin irregularities without being tant and placmg undue ,

stress on the liner when covered with a protective cover. I 53.6 The Contractor shall position the liner in such a way as to minimin excessive l wnnkles at the overlaps where field seaming will be completed and when a protective cover is placed.

53.7 Installation of the liner and lappmg of the seams shall be accomplished in a manner so as to prevent water from runnmg under the liner.

. 5.4 Field Seaming of Linar (Welding) 5.4.1 All seaming processes as prescribed shall provide a " film tearing bond". A " film l

taanns bond" is considered to be a bond 9 8+at y strong that failure of the seam will not occur at the bonded surfaces.

5.4.2 The following field sesming methods are approved:

a. Double fusion welded seam with air gap.

b. camhiantian extrusion fusion welding and Leister X-10 fusion welder. (This method shall be used only if double fusion welded seam with air gap is not fesable).

5.43 Individual panels of liner material shall be rolled out and overlapped by a minimum of 4 inches prior to the seaming process.

5.4.4 All semaing surfaces shall be clean and dry.

5.4.5 when necommy, sootanile shall be placed under the seam area to facilitate welding.

5.4.6 Tbs welding equipment used shall be capable of continuously monitoring and controlling the temperamres in the zone of contact where the machine is actually fusing the lining material Changes in enviranma=*=1 conditions shall not affect the integrity of the weld.

5.4.7 For the double fusion welded seam with air gap system, the two panel overlap shall lanser*e IJmer (Spahads) senadsed synedhmales C5433 Asr.e :

l TU Electric . Generating Division Revisien: 0

- Standard Specificati::n No: C3432 Page: 10 1/3/92 be pulled tightly to keep the seamed edges smooth and wrmklefree.

5.4.3 For the combination extrusion fusion welding and Leister X-10 fusion welder, the Leister X-10 shall be used to temporarily hold the two panels overlap together in order to extrusion weld the liner panels together.

5.4.9 Wher eg.ausion fusion welding is performed the followmg shall be complied with:

a. De seaming areas shall be ground to remove surface contamination and surface tension.

b. Welding material shall be free from dirt, dust, moisture and tangles at all times.

l

c. The welding machine shall be purged prior to actual extradite welding in '

accordance with the equipment ==aidarairer's written insuuctions.

d. Bottosa portion of welding die shall stay in intimata contact and conform to various seam angles and -:--- '"P.tions.

e. The welder die shall be kept "on center" at all times, resulting in an equal amount of extradite bead at the edge of the two (2) overlapped sheets, resulting in a weld 9d seam. '

f. The welder shall keep a consistent forward welding speed. De results shall be a smooth and uniform extradite bead.

5.5 Drainage Net Installation 5.5.1 The Contractor shall begin installation of the drainage not after completion of the , i bottom liner. Completion of the bottom liner inehutan.

a. Completion of the electricalleak detection test.

b. unar leak repaired.

c. IJnar surface cissa of trash, ned, dirt, and gravel 5.5.2 fame =Ilmeian of the drainage not shall be :- a i"*:i such that no damage to the liner is incurred.

5.5.3 The Contractor shau not entrap dirt or small stones or other foreign material in the Impu*es IJeur madmar) sessene sesmassess osa, mer.e o

TU Electric - Generating Division Revision: 0 Stanciard Specification No: C3432  ;

Page: 11 1/3/92 drainage net channels when installing the drainage net.

l 5.5.4 Dunng all installation steps, care shall be taken to keep the drainage net clean. All '

trash, nmd, temporary sandbag anchors, and other foreign objects etc. shall be removed from under and on top of the drainage net prior to the installation of the top liner.

5.5.5 The drainage net shall overlap on a slope such that the upslope net lies atop the downslope net. Minirmim overlap shall be 4".

5.5.6 The drainage not shall be stretched to - /.. " wrmkle formations.

5.5.7 The drainage net shall be butted and tied together with nylon cord (100 lbs. strength) or 1/4" wide electrical tie wraps (plastic). Metal tie rmss or metal cords shall not

, be used. Mannmm spacmss of ties along the butted sides shall be 4 feet. Mammum spacings of tie at the overlap ends and butted ends shall be 2 feet. The nylon cord or electrical tie wraps shall be white to facilitate inspection.

5.5.8 The drainage net roll shall be tomy-wily anchored and held in place with sandbags or other approved methods until the installarian of the top (primary) liner.

5.6 Anchor Trench 5.6.1 The Contractor shall excavate and backfill the anchor trench for the drainage net and the liner as follows:

a. The E=R5 operation shall be accomplished without damagmg the liner, drainage net e'.c. Any damage to the liner shall be repaired before installing and tucidag the drainage not and top liner into the anchor trench.

b. Secdons of anchor trench shall be excavated just prior to installarian and tucking the drainage net and liner into the anchor trench.

c. Soil fkaan the trench may be used for hacMill. Backfill material will be campacted to 90% of .. i- - dry density as per ASTM D-1557 or ASTM D-698.

. 5.7 W

-5.7.1 The Contractor shall repair any leaks detected and located by the electrical leak detecdon test, air pressure test or any other means of testing *W by the Owner inosroesus IJour(symente senadsma spadassess cses, ase.e

TU El ctric - Generating Divisi n Revisien: 0 l Stantinrd Specificati:n Nc: C3432 Page: 12 1/3/92 '

l or the Contractor.

5.7.2 Any liner area damaged or showmg injury due to excessive scuffing, puncture, or distress from any cause shall be replaced or repaired with an additional piece of liner material (patch).

5.7.3 When the integrity of the liner is questionable by the Owner in any way, the Contractor shall repair the area in question as directed by the Owner.

5.7.4 All punctures, cuts, slices, etc., shall be filled with extrusion fusion welded materials and patched.

5.7.5 All cutouts shall have rounded corners.

5.7.6 All patches shall have a 1" radius on corners and a 3" minimum overlap of the damaged area.

5.8 Air-Gas Vents 5.8.1 The air-gas vents shall be installed to allow air or gas to escape from beneath the ilner for a single liner system; and from beneath the bottom liner and the top liner for a double liner system.

5.9 Yinar to ca=, ete Strnemres ==d Penetrariaan 5.9.1 All marhanical seals, metal h="*a= straps and anchor bolts shall be stainless steel.

l 5.9.2 Liner to concrets adhesive shall be used per Mamif=rmrer's instructions.

5.9.3 The Contractor shall prepare surfaces per Maanf=rmeer's racamnwn.dations on all concrets surfaces to be lined.

6.0 OtJAIRY CON 1ROL - INSPECHON & TESTING 6.1 Gansmi 6.1.1' 'Ibe Owner reserves the right of access for the inspection and i=d-a-ada=* testing of all phases of tbs m===farencing and in===Herian of all ca panana of the liner system including electrical leak detection tests for the conformance with the Sparme=rians  ;

and the Drawings. .

i u-r<sanam w spammesa cset, ass.e

o .

HJ Electric Generating Divisica

Revision: 0 Standard Specification No: C3432 Page: 13 1/3/92 6.1.2 . The Contractor shall repair any leaks detected and located by the electricalleak detection tests in accordance with the Speci5 cation.

6.2 Field On=lity Caneral 6.2.1 ne Contractor shall furnish all equipment and quali5ed personnel for quality control on the installation of the Amer for the conditions of their warranties and in cornpliance with these Speci5 cations..

l 6.2.2 Test wells shall be performed prior to Seld seaming each day. I l

6.2.3 Quality control tesung shall involve nondestructive testing of welded seams. The l nondestructive testing is primarily centered on "watertightness".

l 6.2.4: Nondestructive tesung shall consist of visual ===inneian vacuum test method, and air pressure testing of the air gap between the double fusion welded seam.

6.2.4a Visual Fmmminarian . A quality-control mehnician shallinspect the entire lining area and examine each seam. Any area or seam suspected of showing a defect shall be marked and repaired.

6.2.4b Vacuum Testing - 100% of all extrusion welded seams and fusion welded seams except as noted in Section 6.2.3c, patched areas seams, and ==&ad defected areas shall be vacuum tested for possible pinhole leaks. I

1. Vacuum testing is achieved by utilizing a glass-faced suction box. typically 3 feet long and wide enough to cover the weld, a pressure gauge on the inside, and a vacumn hose menactian i

2. De boa is placed over the seam section which has been thoroughly samrated

, with a sospy water sahitian (1 oz. soap to 1 gal water). De rubber gasket on the bottom perimeter of the boa must St snugly against the sosped seam section of the liner. As 3 5 inches of water vacuum is drawn, the box will auto..+ny seat itself to the liner.

3. When proper vacumn is achieved, ( ' ' ; porosity or non bonded areas can be easdy detected, as soap bubbles will appear in these areas. Dwell time shall be 1015 seconds per test.

4. If leak is detected, it shall be property marked and repaired.

um u-r(simanu .

seemdsse spadessansa csm, ase.e

,TU Eltetric Gsnerating Divisi:n Revision: 0

• Standard Specificati:n No: C3432 Page: 14 1/3/92 l

6.2.4c All double fusion welded seams with air gap shall be tested usmg the Owner approved Contractor's Quality Control Manual. The Owner reserves the right at any time to require the Contractor to perform the vacuum test on the double wedge fusion welded seams in conjunction with the air pressure test.

63 Trial Field Seam Testing 6.3.1 Trial field seam tests shall be performed when any weld mnehina first starts up at any time of day or is being restarted for reuse that day or when deemed necessary by the '

Owner.

6.3.2 The trial Seld seam test shall consist of test weld strips.

63.3 : Test weld strip shall be a l l ten (10) feet long for a double fusion welded seem machine, and three (3) feet long for an extrusion welder machine; and tested under the sans Meia== as exist for the liner -4 The test weld strip shall be marked with date, ambient temperamre, and welding machins amnber and operator.

Allow test weld strip to cool namrally to ambient temperamre. Samples of the weld shall be cut from the test weld and tested in shear and peel in accordance with ASTM D3033 and ASTM D413 respectively. A success 6al bonded saamis indicated by yielding of the patent material before the seam faGurs. If sample weld failure occurs prior to yield, repeat the entire weld procedure, using adjusted welding temperamre and speed. No welder shall start production work until sample welds have been approved.

63.4 All tests shall pass both shear and peel Tacihrima using a field tensionometer Prior to any actual facility liner welding.

6.3.5 These g, mJ test weld strips shall be used for field and laboratory testing to detenmins ==pHamme with the Tacihriana Umally aweld strip willbe required at appandmately 500 linear feet of welding. This weld strip will be taken at the end of a weld or at other location to mHeninnes p+Ad==

7.0 WARRANIES 7.1 Tbs Contractor shall submit a ===fnemnving 20 year warranty for the High Density Polyethylens materials to be free frosa defects, and =minenin its strucare under the exposure to the fluid and solids to be stored in the facGity.

(End of Tacine=riaa C3432) s q, * . u -r<s,m mn w w sommannes cses,asy.e

Pummm

=r =e

_= _

1UBECTRC CONTRACT FOR SERVICES BY AND BETWEEN Leak Location Services, Inc.

AND Texas Utilities Electric Company DATED August .,1992 h .. ex-t E

1 I

I l

l L -

s I

4 Contents -

CONTRACT FOR SERVICES . . . . . . . . . . . . 1 DEFINITIONS . .. ... .... . . . . 1 SCOPE OF WORK ... . .. . . . , . . . . . . . 1 SCHEDULE ........ .. ......... . . . . . . . . . . . . . . . 1 WORK SITE ................. . . . . . . . . . . . . . 2 COMPENSATION .. .. . ...... . . . . . . . . . . . . . . . . . . 2 INVOICES AN0 PAYMENT . . . . . . . . . . . . . . . . . . . . . . . . . . 2 INSURANCE . .......... . . . . . . . . . . . . . . . . . . . . . . . . 2 TERMS AND CONDITIONS .... ............ . . . . . . . , . . . . . . . . 2 NOTICES ................ . . . . . . . . . . . . . . . . . . . . . . . . . . 3 SALES /USE TAX ........ ................................. . . 3 ATTACHMENTS ........................................... . . 3 ENTIT<ETY OF AGREEMENT ,... ...................... . . . . . . . . . . . 3 ATTA CHMENT NO.1 .................... . . . . . . . . . . . . . . . . . . 5

%'AP.RANTY ..................................... . . . . . . . . 5 l

l t

u

No. 6K9-00655 CONTRACT FOR SERVICES This Agreement is made, entered and effective as of the 5th day of August,1992, by and between Texas Utilities Electric Company, a Texas Corporation, with its pnncipal omce in Dallas, Texas and Leak Location Services, Inc., a Texas Corporation with its principal office in San Antonio, Texas.

DEFINITIONS

• COMPANY" shall mean Texas Utilities Electric Company, its successors and/or assigns.

' COMPANY's Authorized Representative" shall mean the agent (s), representative (s), or appointee (s) who is authorized by COMPANY to perform the functions provided for in this Agreement, COMPANY may appoint at any time, and in its sole discretion, more than one such agent, representative, or appointee.

" CONTRACTOR

• shall mean Leak Location Services, Inc., the party entering into this Agreement to

- perform the Work, as defined herein, its successors and/or assigns.

• Work" shall mean all labor, materials, equipment, transportation, facilities or services necessary to perform the scope of work described in this Agreement.

• Work Site" shall mean the COMPANY installation or facility or any other location at which Work shall be performed.

" CONTRACTOR Group" shall mean CONTRACTOR, all subcontractors of any tier employed by CONTRACTOR, and all amliate or related firms and entitles, officers, directors, partners, limited partners, shareholders, associates, employees, servants, and agents of each,

" COMPANY Group

• shall mean COMPANY, its parent corporation Texas utilities Company, and all subsidiaries of Texas Utilities Company, and all officers, directors, shareholders, associates, affinated or related firms and entitles, employees, servants, and agents of each.

SCOPE OF WORK CONTRACTOR shall be responsible for the supply of any and all materials, equipment, supervision and labor required for the full and complete performance of the following scope of woric Conduct an elearicalleak detecten survey on each of the five (5) ponds after the HOPE liners (top and bottom) have been installed. This work is associated w6th the modification to the Wastewater Management System.

SCHEDULE The Work to be performed shall commence by August 5,1992 and shall be completed by September 25, 1992. The Work will be scheduled as required through the drection of COMPANY's Authonzed Representative listed below.

Joe Austin (817) 897 0046 f

f l

1 I

aR

__-_-----7----

?

w No. 6K9-00655 m

1 8

WORK SITE M The Work authorized by this Agreement shall be performed at the following COMPANY location:

A TU Electric

]w Comanche Peak Steam Electric Station Off FM 56,5 miles NW of

- Glen Rose, Texas M

COMPENSATION As full and complete compensation for all Work to be performed hereunder, including the payment of any federal taxes, fees, charges or levies of any nature that m .v or hereafter be imposed.

COMPANY shall pay CONTRACTOR a ceiling price of ~

satisfactory completion and acceptance of Work by COMPANY's Authorized Representative.

INVOICES AND PAYMENT CONTRACTOR shall submit one invoice not 20 days after mobilization for 914,50lLOG and all succeeding E invoices to be not 20 days payment cycle, for the full and complete performance of the Work.

CONTRACTOR's invoices shall be identified by this Agreement number nereof and shall be marked

" FINAL INVOICE". However, if a discrepancy or conniet arises, the disputed portion of the invoice shall not be paid until the parties hereto resolve such discrepancy or conflict to their mutual satisfaction.

~ All invoices shall be sent to:

s 1

TU Electric W P.O. IBo;: 1002 Glen Rose Texas 70043-1002 L., INSURANCE 1

4 ~ CONTRACTOR shall at its sole expense purchase and maintain in full force and effect during the performance of this Agreement, insurance policies with substantial and sound insurers, havmg coverage of the types and in the arnounts specined in the Certificate of insurance submitted by CONTRACTOR to COMPANY prior to the execution of this Agreement A sample certificate of insurance setting forth the minimum requirements is attached.

J TERMS AND CONDITIONS The performance of the parties to this Agreement shall be in empliance with the terms and conditions of this Agreement and the attachment hereto entitled " Standard Terms and Conditions ST03 082498*.

2 T

-a.

.. _______ s .

e~q

-J q No. 6K9-00655 J

-q l

-a NOTICES All notices from one party to the other shall be deemed to have been duly delivered if hand delivered E or sent by United States certified mail, return receipt requested, postage prepaid, as follows:

]

)

If to CONTRACTOR:

Leak Location Services, Inc.

if to COMPANY:

Texas Utilities Electric Company 7028 Bandera, Suite 228 400 N. Olive, L.B. 81 San Antonio, Texas 78238 Dallas, Texas 75201 ATTENTION: Daren Laine ATTENTION: Contracts Manager n

A SALES /USE TAX 9

__j The materials / services furnished pursuant to this Agreement are exempt from sales or use tax. Do not include such tax on invoices.

m Fj ATTACHMENTS

"' CONTRACTOR and COMPANY agree that the following attachments constitute part of this Agreement and are incorporated herein in their entirety:

~ 1. Standard Terms and Conditions ST03 082498 Note: The WARRANTY clause to be amended as outlined in the Attachment #1. This clause

~l shall supersede any reference in COMPANY's Terms and Conditions.

A ENTIRETY OF AGREEMENT This Agreement,' together with any and all attachments identified and made a part hereof, shall constitute the entire agreement between the parties hereto, and all prior negotiations, undertakings, understandings and agreements between the parties relating to the Work to be performed hereunder are merged herein.

rm

-~

mW my E -

El 3

4

.. . . .~

~

. l No. 6K9@655 IN WITNESS WHEREOF, the parties have affixed their signatures hereto in acknowledgement of and agreement to the foregoing as of the effective date of this Agreement.

CONTRACTOR COMPA'NY By: By: s< ----

s.eaan s.eaan '

f Name: Name: Darryl Spencer

Title:

Title: Senior Engineer, Contract Services E '? ' Date: Date: [8//9#

/'

/

6R924162 E 6K900655 DES E

E E

l E I E

E 4

5

l No. 6K9-00655 ATTACHMENT NO.1 WARRANTY CONTRACTOR will perform the work under this agreement and the proposal in a good and workmanlike manner with the degree of high professional skill and sound practices and judgement which is normally exercised by recognized professional firms with respect to services of a similar nature. However, CONTRACTOR:

Does not warrant that it will deteM, or identify, or mark .A_LL leaks in the Geomembrane that are present at the time the inspection is performed; Does not assume any liability for direct, foreseeable or consequential loss, cost or damage resulting from death, personal injuries, loss or damage to property, or impairment, or any damage to any right, including but not by any way of limitation, the right to be paid for the loss of time, loss of services, fines, penalties, or Attorney's Fees and other expenses incurred, aristr}g out of or as a consequence of the use or misuse of any survey results, data or o8her information resulting from performing services under this Agreement; Does not make any warranty, express or implied, with respect to the accuracy, completeness, usefulness or reliability of survey results, data or information furnished to COMPANY under this E Agreement; Does not warrant that it will detect, identify or mark any leak equal to or less than 0.032 inches E diameter; Does not warrant that other leaks will not occur and/or be detected if the head pressure is increased; and Does not warrant, by implication or otheiwise the condition of the Geomemb'rane(s) tested and makes no representations with respect thereto and further is not responsible for any activity by COMPANY including COMPANY'S monitoring r4 the areas.

E a

C 5

--_- - / '-- '--

CONTRACT FOR SERVICES STANDARD TERMS AND CONDITIONS CONSEQUENTIAL CAMAGES Contents <NDEuNIFtCATtON .

3 2

INCEPENCENT CONTRACTOR RELATIONSNIP T "$ '

1 fgANG RR

}

MATERIALS. EQUIPMENT AND LABOR ... 1 CONTRACTOR'S RESPONStBluTY FOR WORK 1 SUSPENSION OF WORK' 4 CONotitONS AFFECTING WORK ,

... 1 TERMLNATION 4

STANDAROS AND CODES ....... t CONFUCT OF INTEREST' 4 ASStGNMENT AND SU8 CONTRACTING ,. .. 1 CLEANING UP ' 4 RECORDS AND RIGHTS TO AUOtf ........ 1 INTELLECTUAL PdO'PkRT A AUTHORI2ED REPRESENTATIVES ANOINSPECTORS 1 PROPRIETARY INFORMATION' ' S WARRANTY . . . ..... .2 RIGHTS TO CATA 5 BACXCHARGE ................ 2 PROTECTION AGAINST UENS'A'NO ENCUMBR'ANCES ' 5 FINAL INSPECTION AND ACCEPTANCE ... 2 TITLE AND RIGHT 5 WORK SITE. PERMITS ANO UCENSES .... .2 GOVERNING LAW ' 5 ACCESS ............., .... 2 NON WAfVER OF RibNT' S' .. 5 WORK SITE SAFETY ANO SECURITY ..... 2 SURVIVAL ' '

5 REMOVAL OF PERSONNEL ........... .2 SEVERAaluf ' 5 PROTECTION OF PROPERTY AND PERSONS . . 2 PUBUCITY 5 PROTECTION OF HtGNWAYS AND RAtutOADS .,2 BIN 0tNG ON SU'CbdSSdR'S 'ANh SSIG' NS 5 COMPuANCE WITH LAWS .. ... .... 3 SMALL SUSINESS CONCERNS 5 TAXES ..... . .. .... . .. 3 EOUAL EMPLOYMENT OPPORTUNI[Y' 6 FORCE MAJEURE . .. ... 3 iMMGRATION ** ***** 6 o

a

\

\

n

\

\\

M

,N 6 S,. - -

c .

'i I

Attachment 10 Technical Report, item 16 i.

Soils Map i

Texas Utilities Electric Company l Comanche Peak Steam Electric Station' i TNRCC-TPDES Permit No. 01854 l

i l

3 j

i L .. -

z .

~

, , . , ,. .-. ,,5.[\"1 Y f j N

'Q Y hg.

u.#n...94j-7 e4

" [..

,,4g,,

h, g-f **.' '

. . .w i 7

. v..

I. . s ..,. ,,

, j. ,

\., x

), l,

..Q,p  ;

< <o '-

.8", 'e 8 g,

ik 8 ,+h. , 4.,

?.*% .' is ;[ "..< C.T ,

g- 7

-. :: .. . {

nt; f, Jf.

?..'s

' 3, W~ u *,,,. g 4 ,-

P,pk. y ..

? .

,' - ., \ ^

6 4 y. n-

~ <

s',&

. i

'QM.

.1 , :- "a a u p

to ' .

@. . av n . .,  % ,

.M. .*y ,g . ,-

. s. '.',e ,"'a,' a S'

./ IY .,e Y x.. s. ~

. -> QE8 '-

.u... m.

.z is k,y* I,'" . ,  ; ,

t ..eg,w eGn.m. .

.. ,m S

, fy 9.g)*' . -

g sEs l -

u g, e:

F# - ':- a.c.4." p(

G 9 g -

N es F

w 4;e... .

.. - ..: i u

j. .;~ .. . a . -

.. ~ .  ?.Wf. ' ,.,

~

r >

q: :6,

- - f

. d'P;$ . ,_

~;

4. . . . .br-} ,.'$ i, , '

Q.1

(

.,, J -

M.. ..bg .

-&. . .'f . ;;

m ..y . . -

- . .. r. '

• n-n*a r.

t.

+*

'ng .' .,, %

A.

3 '.,. /.

,. . - f** - J..

n ,, . g ,,

H a ;

"*. ' ;; ^ , ,

.~ .

. i

• ; .y ., . a

. g" '

a

/

N. .

e I -

p'

, e- . . . . i

'g.

,, n '

a ...

a a

'l _" i ' l . u~

p ..y.

j ,,

n

' f.

/ '

n. .

. u .:,Y u % %,tr. ~ .y. Q. ._%

kV .

u

t. s. )

e~ ,

, & J .;R' : +"

y . n-Q :. ,. , %e  ; .

p;J.

n -

r**. . .

s m.

y

D ,

- . s. .

. e}

\ -

- ^

R /

i -

n.,

a n

" .e u n. >

i .

.* ~~ r .: .

..1v. .

.y...4.

a o

• 36 .

e a n

.u .-

. ,, ,,, i ua '

u.

( ,, , , (-  %. . S3 Q% , ,.

soits cara TU ELECTRIC COMANCHE PEAK SymtHW

%Pa** lwd wei4 STEAM ELECTRC STATION Nome No. 200 Sieve Limit Indes

"""'3**

N 49 Torrent 45 - 96 $6-76 38 - 4 9 S0lLS MAP

o. .

,ug,C;ga'g,,,t;Ti..%, y,,y..at HOOD and PQ h hum 1Elt W E gAncH1994 ggNylCES.INC.

c. -

a u * * ^*

OVERSIZE .

-s

~.

DOCUMENT

PAGE(S) PULLED [.l .

mmmmmmmmmmmmmmmmmmmmmmmmmmm - '

r' --

SEE APERTURE CARD-FILES '

APERTURE CARD / PAPER COPY AVAILABLE THROUGH NRC FILE C

. . 1 NUMBER OF OVERSIZE PAGES FILM

. ED ......

b ON........................

APERTURE CAR 0(S)

ACCESSION NUMBERS OF DVERSIZE.PAGES:

99050GOnl5 -Ol- Oh ';

' e

?

O OO O O