ML20195J139
| ML20195J139 | |
| Person / Time | |
|---|---|
| Site: | North Anna  |
| Issue date: | 06/11/1999 |
| From: | Birckhead R VIRGINIA POWER (VIRGINIA ELECTRIC & POWER CO.) |
| To: | Pandey J VIRGINIA, COMMONWEALTH OF |
| References | |
| NUDOCS 9906180103 | |
| Download: ML20195J139 (17) | |
Text
4 innsbrook 1h hniud Center 5000 Dominion Houlevard Glen AHen. Mrginia 230<,n o
Certified Mail Retum Receipt Reauested June 11,1999 VirtGIN!A POWEtt Mr. Janardan R. Pandey, P. E.
DEO - Valley Regional Office 4411 Early Road P. O. Box 1129 Harrisonburg, VA 22801 RE: North Anna Power Station - Bearing Cooling Tower Blowdown - VPDES Permit Application Addendum
Dear Mr. Pandey:
As recently discussed per telephone, we are proposing to use three chemicals in the bearing cooling tower at North Anna Power Station that were not addressed in our last application for reissuance of the VPDES permit. This information is submitted as an addendum to the original application. We have recently submitted application addenda to the Tidewater Regional Office for new chemicals proposed for use at the Chesapeake Energy Center and Yorktown Power Station. Attached are examples of submittals made to the Tidewater Regional Office.
For years,'the bearing cooling tower has been chlorinated on a continuous basis, but has not been blown down. Due to the lack of blowdown, the calcium concentration has
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increased in the gstem, resulting in scale buildup. The bearing cooling tower needs to be blown down continuously to reduce this concentration. The estimated flowrato for the blowdown is 150 gpm to 200 gpm. This is an internal discharge that discharges into the circulating water tunnel where it mixes with as much as 2,000,000 gpm of lake water before being discharged into the discharge canal and cooling lagoons.
Calgon Corporation has recommended the use of a liquid oxidant system utilizing Calgon H-940 (40% sodium bromide) and sodium hypochlorite (15% active). The chemicals would be fed over a 30-minute period up to four times a day. The feed rates would be 3.5 gallons for Calgon H 940 and 11.3 gallons for sodium hypochlorite during each 30 minute period. Due to varying plant conditions, the recommended feed rate may change. However, at no time would we add these chemicals for more than 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> per day. This treatment method will provide adequate oxidant to control the system and still meet the limitations of our VPDES permit. Attached is the MSD sheet for Calgon H-940.
Calgon Corporation has also recommended the use of an amine salt of endothall(Calgon EVAC) to control mollusk infestations in the bearing cooling tower. EVAC would be added to the uni! 3 to 4 times a year at the rate of 100-150 pounds per treatment to produce a concentration of 1.5 ppm to 3.0 ppm. The treatment is effective in as little as 8 to 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br />.
However, the bearing cooling tower would not be blown down for at least 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br /> to provide timo for EVAC to naturally decompose. The half-life for this product is 19 to 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br />. Attached is the MSD sheet for Calgon EVAC.
Ok 9906180103 990611 PDR ADOCK 05000338 P
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pags 2 Mr. Pandey June 11,1999 We look forward to hearing from you on our proposal. If you have any questions, please contact me at (804) 273-2992.
Sincer ly, Ron Birckhead Staff Engineer l
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U. S. Nuclear Regulatory Commission Region 11 Atlanta Federal Center 61 Forsyth St., SW, Suite 23T85 -
- Atlanta, GA 30303 RE:
North Anna Units 1 and 2 Docket Nos. 50-338/50-339 License Nos. NPF-4/NPF-7 '
U. S. Nuclear Regulatory Commission Document Control Desk Washington, DC 20555 9E:
North Anna Units 1 and 2 eocket Nos. 50-338/50-339 i
- License Nos. NPF-4/NPF-7 Mr. M.J. Morgan NRC Senior Resident inspector North Anna Power Station 1
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February 11,1998 Mr. Mark H. Sauer l
DEQ-Tidewater Regional Office j
t 5636 Sopthern Boulevard Virginia Beach, Virginia 23462
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RE: Chesapeake Energy Center -VPDES Permit Application Addendum
Dear Mr. Sauer:
As we_ discussed earlier today, Energy Centn personnel commenced using two chemicals in 1997 that were not addressed in our last application for reissuance of the VPDES permit. We are submitting this information as an addendum to the original application.
Penetone PL 998, a liquid phosphoric acid cleaner, is used to clean the air preheater baskets. Approximately 240 gallons of this product are used per year. Wastewater from cleaning the air preheaters is treated in the metals cleaning waste pond.
ProChemTech 7950, a liquid potassium hydroxide cleaner, is used to restore the activated carbon associated with the reverse osmosis system and to clean other portions of the reverse osmosis unit. A maximum of 110 gallons is used per year. Depending upon which part of the system is being cleaned, the wastewater is discharged to either the ash pon the condenser cooling water discharge canal.
Attached are the MSD sheets for these two chemicals, a copy of the procedure for cleaning the air preheaters, and a list of the bulk chemicals used at the Energy Center.
If you have any questions, please call me at (804) 273-2992.
Sincerely, Ron Birckhead StaffEngineer l
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September 30,1998 -
Mr. Mark H. Sauer-DEQ-Tidewater Regional Office 5636 Southem Boulevard l
-Virginia Beach, Virginia 23462 L
RE: Chesapeake Energy Center - VPDES Permit application Addendum
Dear Mr. Sauer:
This is to notify you of the proposed use of a new chemical at the Chesapeake Energy Center on a trial basis, in the past, Energy Center personnel used hydrochloric acid to control scaling on the membranes of the reverse osmosis system. Currently, the water is pre-treated with a wat'e'r
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softener. Energy Center personnel are planning on using Hypersperse AF 200 UL, a polymer from Argo Scientific, on a trial basis to control scaling of the membranes. The test period would be for a maximum of two months and the product will be used at the rate of approximately 500 pounds per month. This will allow Energy Center personnel to evaluate the product prior to a planned replacement of the membranes. The discharge would continue to be directed to the condenser cooling water discharge canal. Attached for your information is a copy of the MSD sheet.
We understand that the City of Chesapeake uses this product at its water treatment plant with great success.
If you have any questions or desire additional information, please call me at (804) 273-2992.
Sincerely, Ron Birckhead Staff Engineer i
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JtJN-10-1999 11:23 N$rLCKgfMONiCM e
sisua e az ca n.exe ausste Hpril 13, 1333 j
l H-940 P.O. Box 1346 Pittsburgh, PA 15230-1346 Phone-(412)494-8000
...v MATERIAL SAFETY DATA SHEET Section 1. PRODUCT IDENTIFICATION PRODUCT NAME:
H-940 CHEMICALDESCRIPTION:
Aqueous solution of alkall rnetal halido PRODUCT CLASS-Blacide MSDS CODE: OA4811-04-93 Section 2. INFORMATION ON INGREDIENTS CAS
% by Chemk:alName Number Weicht OSHA PEL ACGlH TLV Sodium bromide 7647-15-6 40 None established None estab!!shed Section 3. HAZARDS IDENTIFICATION i
EMERGENCY OVERVIEW
- ==*** **********
WARNING!
May cause eye and skin irritation.
PRIMARY ROUTES OF ENTRY: Eye and skin contact, inhalation of mlst TARGET ORGANS: Eye, skin MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre existing skin disorders.
POTENTIAL HEALTH EFFECTS:
EYE CONTACT: This product may produce irrttalion upon contact with the eye.
SKIN CONTACT: This solution was found to be non Irritating to the skin in animal tests it is not expected to be absorbed in harmful arnounts. Prolonged or repeded skin exposure rnay result in skin Irrttation and dermatitis. Failure to decontaminate could resuk in superficial bums.
INGESTION: This product would be regarded as pracbcally non-toxic il swallowed. Excessive ingestion of sodium bromide may produce rashes, depression, smaciation and, in severe casas, psychosis and mortal deterioration.
MSDS Coder QA4811-04-93 Page 1 lasue Date: OW12/96 Continued on Page 2
JUN-10-1999 11:23 MA1HTEraX@ gif4Chr menstrase vm Ens res*Da D:netd 5ptsa April 13, 1333 H-940 INHALATION: This peduct would not be = parted to be an Inhalation hazard unless the produd is misted or sprayed. Bromide rashes may occur when bromide inhalation is prolonged. The systemic effeds of bromide non are diistly mentat drowsiness, irraabilty, vertigo, cordusion, hallucinations.
SU8 CHRONIC, CHRONIC:.
A three generation reproduction study in rats fed 4800 mg/kg of solid sodium bromide showed a decrease in ferttity. Other animal tests wth sodium bromido produced adverse reproductive effects.
The physiologiosi effects of sodium bromide are attributable to the bmmide lon. Metak**My, bromide has a biologic half-life of about 12 days, is not No.pvi.ied into lat or blood proteins, and none is extractable from plasma or hemolyzed blood cells by other. Nor does the brornide ion interfere wth thyroid adivay even at large daily doses for extended portods of time.
CARCINOGENICITY:
NTP:
- No Ingredients listed in this sectiorf IARC:
'No ingredients listed in this section*
OSHA:
- No ingredients hated in this sectiorf Section 4. FIRST AfD MEASURES EYE CONTACT: In case of contact,immediately flush eyes wth plenty of water for at least 15 minutes. Seek medical aid.
j SKIN CONTACT: In case d contact, flush sidn with plenty of water. Remove contaminated dothing.&ek medeal aid ll Irritation persists. Wash clothing before reuse.
I STION: Not an expected route of overexposure. If swallowed, do nd induce vomiting. calla physician This product would be expeded to be pradkally non toxic by iniption.
IN TION: Not an expeded route of overexposure. However,11 exposure by Innalation is suspeded, ramme to fresh air. And in breathing W necessary and seek medicud and # symptoms occur.
i Section 5. FIRE-FIGHTING MEASURES FLASH POINT:
None LOWER FLAMMABLE UMIT:
Not apphcable UPPER FLAMMABLE UMIT:
Not appikable AUTO-lGNITION TEMPERATURE:
Not appliamble EXTINGUISHING MEDIA-This matertal does not bum. If exposed to fire from another source, use suitable fire extinguishing agent for that fire.
FIRE. FIGHTING INSTRUCTIONS:
Exerdse caution when fighting any chemical fire. A sof contained breathing apparatus and protodive clotNng are essential FIRE & EXPLOSION HAZARDS: Produd emas toxic gases under fire condtions.
HSDS Code OA481104 93 Page 2 issue Dste: 0W12/96 Continued on Page 3
JUN-10-1999 11:24 f1AINTENANCE SUPPORT SMlesE7dm m
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erpeii n. un H-940 DECOMPOSmON PRODUCTS: In fires f ueled by other meerial. hydrogen bromide or bromine may be released.
NFPA RATINGS:
Health = 2 Flammabilty = 0 Reactivity = 0 Spedal Harard - None Hawd ralng sosis:0-Minimal 1 -singht 2-Moderste 3-Sedous 4-severe Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Wearing appropriate personal protodive equipment, contain spill, coiled onto inert absorbent and place into suitable container.
l Section 7. HANDLING AND STORAGE 1
l l
HANDUNG:
h is a violation of Federal law to use this produd in a mani.a inconsistent with its labeling.
Avoid contact with eyes. skin and dothing.
Avoid breathing mist.
Use with adequate ventilation.
(
Wash thoroughly after handling. Keep container closed when not in use.
STORAGE:
Store in a cool. dry, we5. ventilated location.
The recommended minimum storage temperature is O'F (-17.8'C).
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION l
PERSONAL PROTECTIVE EQUIPMENT:
EYE / FACE PROTECTION: Chemical splash goggles l
SKIN PROTECTION: Chemical resistant gloves l
RESPIRATORY PROTECTION: When misting may occur in the work area, use a NIOSH approved respirator in accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
ENGINEERING CONTROLS. Use local exhaust ventilation where mist or spray may be generated.
WORK PRACTICES: An eye wash station should be accessible in the knmediate area of use.
i Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOluNG POINT: 217 219'F (103-104*C)
SOLUBILITY IN WATER: Complete i
VAPOR PRESSURE: Similar to water SPECIFIC GRAVITY: 1.43 8 25'C VAPOR DENSITY (air =1): Similar ta water pH: 5.5 - g.0 8 25'C
% VOLATILE BYWEIGHT:
80 (water)
FREEZING POINT: -10*F (-23.3*C) l MSDS Cadet 0A48-1104-EKI Page 3 Continued on Page 4 lasue Date: Oly12/96
JLN-10-1999 11:24 f1AINTEMECE @DMoWY h
A H-940 APPEARANCE AND ODOR:
Clear, colorless to pale yellow liquki with no odor.
Section 10. STABILITY AND REACTIVITY CHEMICALSTABILRY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID:
Overhoding.
INCOMPAT1BluTY:
Product is incompatible with strong oxidizers and acids and is mildfy corrosive to aluminum.
Sodium bromide is rapidly attacked by brornine trifluoride. -
DECOMPOSITION PRODUCTS: In fires fueled by other material, hydrogen bromide or bromine may be released Section 11. TOXICOLOGICAL INFORMATION j
ON PRODUCT:
Product Oral LDoo(rat): > 5000 mg/kg Product Dermal LDeo (rnbbit): > 2000 mg/kg i
Section 12. ECOLOGICAL INFORMATION ON PRODUCT:
Aquatic toxicity data:
The produd is an aqueous sodium bromide solution. This data is not on the product as is, but rather on the activated produd which is hypobromous acid. Values presemed are for hypobromous add expressed as bromine.
l 48 hr LCso (Daphnia magna): 0.71 ppm g6 hr LCso (bluegill sunfish): 0.52 ppm g6 hr LCso (rainbow trout): 0.23 ppm Environmental data:
Do not disdurge affluent containing this product into takes, streams, pords, estuaries, oceans or other waters unless in somedance with the requirements of a Nelonel Pollutant Discharge Elimination System (NPDES) permt l
and the permRting authorty has been notified in wrting prior to discharge. Do not discharge effluent coramining this produd to sewer systems wthout previously notifying the local sewage trestrnent piart authority. For guidana l
contact your State Water Board or Regional Office of the EPA.
Section 13. DISPOSAL CONSIDERATIONS I
1 RCRA STATUS: Discarded product, as sold, would not be considered a RCRA Hazardous Waste.
DISPOSAL: Diapose of in accordance wth lomi, state and federal regulations Scotton 14. TRANSPORT INFORMATION DOTCl.ASSIFICATION:
ClasafDtvislan: Not restrided ProperShipping Name Not applicable MSDS Cadet 044511-04-93 Page 4 Continued on Page 5 lseue Date: OlW12fg6
JUN-10-1999 21:25 11AINTENANCE SUPPORT h
l H-940 Labet None Padcing Group-Not apphcable ID Number: Not applicable Section 15. REGULATORY INFORMATION L
OSHA Hazard Communicdion Status:
Hazardous TSCA: Poetiddes are exempted by TSCA (the Toxc Substanoss Control Ad), under Sedion 3(2)(a)ll, from the provisions of the Ad.
CERCLA reportable quantity of EPA hazardous substances in product:
l
. ChemicalNarne BD.
No ingredients of this product have CERCLA reportable quantities.
Product RQ:
Not applicable (Notify EPA of product spills exceeding this amount.)
SARATITLE lil:
l Section 302 Extremely Hazardous Substances:
Chemical Name.
G6,1.1.
BQ.
EQ.
There are no SARA 302 Extrernely Hazardous Substances in this produd.
Section 311 and 312 Health and Phys 6 cal Hazards:
Immedide Delayed Fire Pressure Reactivry l
[yes]
[yes)
(no]
(no]
(no]
1 Section 313 Toxic Chemicals:
ChemicalName CAS #
% by Weiaht These use no soportable SARA 313 Toxic Chemiemis in this produd.
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5ection 18. OTHER INFORMATION l
HMlS RATINGS:
Health = 2*
Flammabety = 0 Readivity= 0 Personal Protocuve Equipment = X (to be spedfied by user depending on use conditions)
- These are potential chronic health effeds to consider.
Haanni rehg sosle: 0=Winwnal1-6 fight 2=Moderase 3-Serious 4= Severe MSDS REVISION
SUMMARY
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j PREPARED BY:.
- P.J. Maloney i
MSDS Code OM811-04 93 Fage 5 last Pape Issue Dele:0 Elf 17/98 TOTAL P.06 f
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PRODUCT BULLETIN Bulletin No. T-001 Rev. 2/98 CALGON EVAC MOLLUSK CONTROL TREATMENT DESCRIPTION.
Calgon EVAC molluscicide is FIFRA registered for use in once through and recirculating co systems. Calgon EVAC is an amine salt of endothall.that effectively controls rnollusk infe plant distribution systems when used at recommended levels. Calgon EVAC is sold a key application service coo.rdinated by Calgon technical representatives.
ADVANTAGES:
Treatment effectiveness in as little as 8 to 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> per application which provides flexibilit approach to any situation.
No need for deactivation with clay or any other compound.
No concern over additional suspended solids in the discharge or associated equipment and expense.
Excellent environmental fate characteristics Calgon EVAC has a half life of 19 to 72 hours8.333333e-4 days <br />0.02 hours <br />1.190476e-4 weeks <br />2.7396e-5 months <br /> versus 28 days for'.other products.
Calgon EVAC is more environmentally acceptable helping to minimize and conc degradation in receiving waters.
ANALYTICAL TEST METHODS A test method of measuring both the endothall salt and the amine portion of th low and high ranges. The high range tests are used to confirm product levels in being treated. The low range test is for accurate measurement in discharge waters.
Consult your Calgon field engineer for the specific procedure applicable to your need.
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EVAC P.O. Box 1346 Pittsburgh, PA 15230-1346 gh (QQ Phone-(412)494-8000 v4Ya o n o a a v
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CHEMTREC8 1-800-424-9300 MATERIAL SAFETY DATA SHEET l
Section 1. PRODUCT IDENTIFICATION PRODUCT NAME:
EVAC CHEMICAL DESCRIPTION:
Dicarboxylic acid, mor > amine salt l
. PRODUCT CLASS:
Blocide MSDS CODE: OK41 Section 2.t INFORMATION ON INGREDIENTS CAS
% by Number Weight OSHA PEL ACGtH TLV Chemical Name _
Endothall, mono (N,N-dimethylcocoamine) salt 66330-88-9 53 None established None establishec '
Section 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW 1
Yellowish brown liquid with very faint odor.
DANGERI May cause severe eye damage.
May cause severe skin irritation.
May cause severe digestive tract burns if swallowed.
May be harmful if inhaled or if absorbed through skin.
I-PRIMARY ROUTES OF ENTRY:
Eye and skin contact, skin absorption, inhalation, ingestion TARGET ORGANS:
Eye, skin, mucous membranes MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: No data available.
POTENTIAL HEALTH EFFECTS:
EYE CONTACT:This product may cause severe irritation and damage upon contact with the Page 1 MSDS Code:OK41 Continued on Page 2 issue Date: 02/25/98 l
L
EVAC I
SKIN CONTACT:This product is expect' ell to produce severe irritation upon contact with the sliin. This product rr be harmful if absorbed through the skin.
1 INGESTION: This product is toxic by OSHA definition. Ingestion of this product may cause severe irritation or burns of the mucous membranes of the mouth, throat, esophagus and stomach.
INHALATION: Lung congestion and hemorrhage upon heavy overexposure.
SUBCHRONIC, CHRONIC:
See Section 11 for additional information.
CARCINOGENICITY:
NTP:
"No ingredients listed in this section*
IARC:
l
- No ingredients listed in this section*
OSHA:
"No ingredients listed in this section*
Section 4..FIRST AlD MEASURES EYE CONTACT: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical a immediately.
SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Seek medical aid immediately. Wash clothing before reuse.
INGESTION: If swallowed, do NOT induce vomiting. Give one or two glasses of water. Seek medical aid immediatel Never give anything by mouth to an unconscious person.
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures agair circulatory shock, respiratory depression and convulsions may be needed.
INHALATION:If inhaled, remove to fresh air. If not breathing, give an clat res'piration. If breathing is difficult, give l oxygen. Seek medical aid.
Section 5. FIRE-FIGHTING MEASURES FLASH POINT:
230*F (TCC)
This product is not by definition a
- flammable liquid" or a
- combustible liquid".
LOWER FLAMMABLE LIMIT:
Not available UPPER FLAMMABLE LIMIT:
Not available AUTO-lGNITION TEMPERATURE:
Not available EXTINGUISHING MEDIA:
Water, CO2, dry chemical, foam, earth or sand.
FIRE-FIGHTING INSTRUCTIONS:
Exercise caution when fighting any chemical fire. A self<ontained breathing apparatus and protective clothing are essential.
Use water to keep fire-exposed containers cool.
_i MSDS Code:OK41 Page 2 Continued on Page 3 issue Date: 02/25/98
EVAC FIRE & EXPLOSlON HAZARDS: Product emits toxic gases under fire cond.itions.
DECOMPOSITION PRODUCTS: Elevated temperatures convert endothall to anhydride, a strong vesicant, causing blistering of eyes, mucous membranes, and skin.
l NFPA RATINGS:
Health - 3 Flammability - 1 Reactivity - 0 Special Hazard - None Hazard rating scale: 0-Minimal 1 -51ight 2 -Moderate 3 -serious 4-Severe Section 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF MATERIAL 15 RELEASED OR SPILLED: Wearing appropriate personal protective equipment, contain spill, collect onto inert absorbent and place into suitable container.
Section 7. HANDLING AND STORAGE 5-HANDLING:
It is a violation of Federal law to use this product in a manncr inconsistent with its labeling.
l Do not get in eyes, on skin or clothing.
Do not breathe vapor or mist.
Use with adequate ventilation.
Remove contaminated clothing and wash before reuse.
Wash thoroughly after handling. Keep container closed when not in use.
STORAGE:
Do not contaminate water, food, or feed by storage.
Store in original container.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION i
PERSONAL PROTECTIVE EQUIPMENT:
EYE / FACE PROTECTION:
Chemical splash goggfes and face shield SKIN PROTECTION: Chemical resistant gloves and protective clothing I
Neoprene, butyl rubber, natural rubber, and polyethylene type gloves are acceptable.
l RESPIRATORY PROTECTION: If airborne concentrations become irritating, use a NIOSH approved resp accordance with OSHA respiratory protection requirements (29 CFR 1910.134).
1 ENGINEERING CONTROLS:
Local exhaust ventilation may be required in addition to general room ventilation tc maintain airborne concentrations below irritation levels.
WORK PRACTICES: Eye wash station and safety shower should be accessible in the immediate l
equipment should be cleaned thoroughly after each use.
__\\
Section 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT: > 212'F SOLUBILITY IN WATER: Soluble Page 3 MSDS Code:0K41 Continued on Page 4 issue Date:02/25/98 L
r EVAC VAPOR PRESSURE: Not available SPECIFIC GRAVITY: 1.044 @ 25*C '
/
l VAPOR DENSITY (air-1): Not available pH: Not available
% VOLATILE BY WElGHT:
~ 47 FREEZING POINT: < 5'F j
j APPEARANCE AND ODOR:
Yellowish brown liquid with very faint odv.
f Section 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID:
Avoid high temperatures.
i INCOMPATIBILITY:
Water reactive compounds DECOMPOSITION PRODUCTS: Elevated temperatures convert endothall to anhydride, a strong vesicant, causing blistering of eyes, mucous membranes, and skin.
Section 11. TOXICOLOGICAL INFORMATION ON PRODUCT:
Product Oral LD e(rat): 233.4 mg/kg 3
Product Dermal LD a (rabbit): 480.9 mg/kg 3
Product inhalation I.Cso (rat): 0.70 mgM4H Skin sensitization: The product was found to be non-sensitizing in guinea pigs.
Toxicological data on chronic effects: Based on a one year feeding study of disodium endothall to dogs, the NOE considered to be 150 ppm. Mice were dosed with disodium endothall in an 18-month oncogenicity study. The NC for this study is considered to be 100 ppm. There was no indication of carcinogenic effects.
Section 12. ECOLOGICAL INFORMATION ON PRODUCT:
Environmental data:
This product is toxic to fish and aquatic organisms. Do not discharge effluent containing this product in ponds, estuaries, oceans, or other waters unless in accordance with the requirements of a Nati Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to d discharge effluent containing this product to sewer systems without previously notifying the local sewag authority. For guidance contact your State Water Board or Regional Office of the EPA.
Section 13. DISPOSAL CONSIDERATIONS l
RCRA STATUS: The EPA Hazardous Waste Number'for Endothall is P088.
~,
Page 4 MSDS Code:0K41 Continued on Page 5 Issue Date:02/25/98
EVAC DISPOSAL: Pesticide wastes are acutely hazardous, improper disposal of excess pesticide, spray mixture, or rinsate is a violation of federal law. If these wastes cannot be disposed of by'use according to label instructions, contact you State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.
"Section 14. TRANSPORT INFORMATION DOT CLASSIFICATION:
I Class / Division: 6.1 Proper Shipping Name: Pesticides, liquid, toxic, n.o.s. (endothall)
Label:
Keep away from food (ground)
{
Toxic (air)
Packing Group: 111 ID Number: UN 2902 Section 15. REGULATORY INFORMATION OSHA Hazard'Commu'nication Status:
Hazardous TSCA: Pesticides are exempted by TSCA (the Toxic Substances Controf Act), under Section 3(2)(alli, from the provistor of the Act.
CERCLA reportable quantity of EPA hazardous substances in product:
Chemical Name fLQ Endothall 1000 lb Product RQ:
4280 lb (Notify EPA of product spills exceeding this amount.)
SARA TITLE 111:
Section 302 Extremely Hazardous Substances:
Chemical Name-CAS #
RO-TPR.
There are no SARA 302 Extremely Hazardous Substances in this product.
Section 311 and 312 Health and Physical Hazards:
Immediate Delayed Fire Pressure Reactivi-
[yes)
(no)
(no]
[no)
[no]
Section 313 Toxic Chemicals:
CAS #
% by Weight Chemical Name _
There are no reportable SARA 313 Toxic Chemicals in this product.
PageS MSDS Code:OK41 Continued on Page 6 issue Date:02/25/98 i
EVAC
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Section 16. OTHER INFORMATION
'HM15 RATINGS:
Health - 3 Flammability - 1 Reactivity - 0 Personal Protective Equipment - X (to be specified by user depending on use conditions)
Hazard rating scale: 0 -Mintrnat t -Stight 2-Moderate 3 -Serious 4 -Severe MSDS REVISION
SUMMARY
- Not app!! cable White this Information and recoarnendations set forth herein are believed to be accurate as of the date hereof, CALoon CORPORATION MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FR PREPARED BY:
P.J. Maloney i
f 1
Page 6
- MSDS Code:OK41 Last Page lssue Date:02/25/98
-