ML20154C719
| ML20154C719 | |
| Person / Time | |
|---|---|
| Site: | Three Mile Island  |
| Issue date: | 06/03/1988 |
| From: | GENERAL PUBLIC UTILITIES CORP. |
| To: | |
| Shared Package | |
| ML20153G141 | List: |
| References | |
| 1104-28I, NUDOCS 8809140468 | |
| Download: ML20154C719 (55) | |
Text
_ - _ - - - -
FORMA"0N 0LY :
' Nuclear y,_,
"umu r Oqeratina Procedure 1104-281
- Title .
Revision No. ,
r Haste Solidification Process Control Program 10 Applicability / Scope Respc~idie Office THI-1 Division Plant Ops. Dir.
This document is within QA plan scope X Yes No Effective Date
) 1 Safety Reviews Required Importar.t to Safety X
X Yes Yes No No 06/08/88 7
Environmental Impact Related X Yes No List of Effectiva Pages Page Revision Page Revision Page Revision Page Revision
) 1.0 10 El-1 8 E9-1 8 R
R 2.0 8 El-2 8 E9-2 9 3.0 8 El-3 8 E10-1 8 4.0 8 El-4 9 E10-2 9 5.0 8 E2-1 8 EIO-3 8 6.0 8 E2-2 9 E11-1 7 7.0 9 E2-3 7 E12-1 9 8.0 9 E3-1 8 9.0 10 E3-2 8 10.0 9 E3-3 8 11.0 9 E3-4 9 12.0 3 E4-1 8 13.0 10 E -2 9
- 14.0 9 E4-3 7 15.0 9 ES-1 9 16.0 9 E5-2 9 17.0 9 E6-) 8 18.0 9 E6-2 9 19.0 9 E6-3 7 20.0 9 E7-1 8 21.0 9 E7-2 9 .
22.0 9 E8-1 8 23.0 9 E8-2 9 24.0 9 E8-3 8 Il Signature I Concurring Organizational Element I Date Oriainatorl' \db l Oriainator I lo 1. - Bt>
Concurred ll k ) l l By ll u G MI,._k l Procedure Owner l (o.2 p d ll , , s. l l ll y/%/gld/imv I PRc lz,/z,/m ,
ll l 1 ti i i , .
Approvea l __ _ //pau I Approver IGhhP 8809140460 000029
[ UNDY 1.0 1372c
E NUCIOBr Tui.1
- Operatino Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 8 l Table of Contents l
l Section : Pace 1
1.0 DISCUSSION 4.0
2.0 REFERENCES
4.0 3.0 LIMITS AND PRECAUTIONS 5.0 4.0 TEST SOLIDIFICATION OF 4 TO 10 HT1 BORIC ACID 6.0 (CONCENTRATED WASTE) 4.1 Prerequisites 6.0 4.2 Procedure 7.0 S.0 TFST SOLIDIFltATION OF > 10 TO 20 HT1 BORIC ACID 10.0 (CONCENTRATED WASTE) 5.1 Prerequisites 10.0 5.2 Procedure 11.0 6.0 TEST SOLIO!FICAi!ON OF WASTF OIL 13.0 6.1 Prerequisites 13.0 6.2 Procedure 14.0 7.0 TE*T SOLIDIFICATION OF USED PREC0AT 15.0 7.1 Prerequ sites 15.0 7.2 Procedures 16.0 8.0 TEST SOLIDIFICATION OF BEAD RESIN 18.0 E.1 Prerequisites 18.0 8.2 Procedure 19.0 9.0 ALTERNATE TEST SOLIDIFICATION PROGRAMS 21.0 9.1 Prerequisites 21.0 9.2 Procedure 22.0 2.0 1372c
a Nuclear Tsi-i Operating Procc.*ure 1104-28!
Title Revision No.
Weste Solidification Process Control Program 8 Table of Contents (Cont'd)
}ection Paje 10.0 ACCEPTANCE CRIT 23IA 22.0 ATTACHMENT 1 Class A Unstable and Stable Class B and C Test El-1 Solidification Data Sheet for 4 to 10 wt% Boric Acid ATTACHHENT 2 Solidification Calculation Sheet for 4 to 10 wt% E2-1 Boric Acid AT1/SHENT 3 Class A Unstable and Stable, Class 6 and C Test E3-1 Solidification Data Sheet for > 10 to 20 wt %
Boric Acid ATTACHHENT 4 Solidification Calculation Sheet for > 10 to E4-1 20 wt % Boric Acid ATTACHHENT 5 Class A Unstable and Stable, Class B and : Test ES-1 So11dification Data Sheet for Waste Oil ATTACHHENT 6 Solidification Calculation Sheet for Waste Oil E6-1 ATTACHHENT 7 Class A Stable, Class B and C Test Solidification E7-1 Calculation Sheet for Used Precoat ATTACHMENT 8 Solidification Calculation Sheet for Used Precoat E8-1 ATTACHMENT 9 Class A Stable. Class B and C Test Solidification E9-1 Data Sheet for Bead Tesin ATTACHMENT 10 Solidification Calculation Sheet for Bead Resin E1C 1 ,
[
ATTACHMENT 11 Test Solidification using Pestinghouse - Hittman E11-1 Procedure FIGURE 1 Percent Solids of pH Adjusted Haste vs. Water / E12-1 Cement Ratio 3.0 ll72c
Nuclear
' m _i Operatina Procedure 1104-2_{ f Title Revision No.
"Waste Solidification Process Control Program 8 1.0 DISCUSSION ThepurkseoftheProcessControlProgram(PCP)forincontainersolidification is to provide a prograr. which will assure a solidified product with no free standing 11guld prior to transportation for disposal and which meets the re-quirements of 10 CFR 61.56. Haste Characteristics.
The PCP's for each waste stream included in this procedure are based on labora-tory testing, the results of which are included in "Topical Report Cement Solidtfied Waste to Meet the Stability Requirements of 10 CFR 61" prepared by Westinghouse - Hittman. These PCP's are valid for all liner types using elec-tric or hydraulic mixing heads provided by Hittman.
The appropriate portions of this document shall be considered complete only when used with the operating procedures (OP 1104-28A for borated and oily wastes or OP 1104-28C for resin) for full scale solidification. This document describes the methodology for determining the acceptable ratio of waste, cement and additive that will result in an acceptable product for transportation and ultimately burial. The Solidification Data / Calculation Sheets convert these ratios into the recommended quantity of cement and additive that should be mixed with Class A unstable waste and the recommended quantity of cement and additive which must be mixed with Class A Stable and Class B or C wastes.
2.0 REFERENCES
2.1 Westinghouse - Hittman F421-P-004, Process Control Program for Incontainer '.
Soltritf tcation of 4 to 20 wtT, Boric Acid I: 2.2 Westinghouse - Hittman ST0-P-05-002, Process Control Program for Incon- !
tainer Solidification of Otly haste 2.3 Westinghouse - Hittman F421-P-006. Process Control Program for Incontainer -
Solidification of Powdered Resins 2.4 Westinghouse - 'ttman F421-P-005, Process Control Program for Incontainer {
Solidification o. Class A Unstable or Stable, Class B and C Resin at '
Maximum Packaging E(ftclency 2.5 Westinghouse - Hittran STD-R-05-007. Topical Report Cement Sol 1dified l Waste to Meet the Stability Requirements of 10 CFR 61 l 2.6 West.nghouse - Hittman ST0-R-05-011, Topical Report Hobile Incontainer i Dewatering and Solidification System (MDSS) 2.7 NRC Letter from Ctaries E. Rossi, Assistant Director, Division of PWR licensing-A to R.J. Leduc, Director of Engineering Westingh"use Hittman -
i "Acceptance of Referencing of Licensing Topical Report STD-R-05-011, Hittman Mobile Incontainer Dewaterir.g and Solidification System (MDSS)".
Dated Oct. 31, 1986.
4.0 1372c
. Number 1
Nuclear Tsi-i Optratino Procedure 1104-28!
Title Revision No.
Witte Solidification Process Control Program 8 2.8 Tech. Spec. Section 3.22.3, Solid Radioactive Waste 2.9 GPUN Radiation Protection Plan 3.0 LIMITS AND PRECAUTIONS 3.1 As required by Te:h Spec 4.22.3.1.2, the PCP shall be used to verify the l solidification of at least one representative test speelnier from at least l every tenth batch of each type of wet radioactive waste (e.g., evaporator l bottoms, oily waste, resin and precoat sludge).
l l 3.2 For the purpose of the PCP a batch is defined as that quantity of waste I
required to fill a disposable liner to the appropriate level on the waste level indicator.
3.3 If any test specimen falls to solldtfy, solidification of the batch under test shall be suspended until such time as additional test specimens can be obtained, alternative solidification parameters can be determined in accordance with the Process Control Program, and a subsequent test veri-fles solidification. Solidification of the batch may then be resumed using the alternate solidification parameters determined.
3.4 If the initial test specimen from a batch of waste fails to verify solidi-fication then representative test specimens shall be collected from each consecutive batch of the same type of waste until the three (3) consecu-tive inittai test specimens demonstrate solidification. The Process Control Program thall be modified as required to assure solidification of subsequent batches of waste.
3.5 For high activity wastes, such as spent resin er used precoat, where handling of samples could result in personnel radiation exposures which are inconsistent with the ALARA principle, representative non-radioactive samples will be tested. These samples should be as close to the actual waste physical and chemical properties as possible. Typical expended mixed bed resin shall be used to simulate the spent bead resin and the appropriate mix of anion to cation powdered resin shall be used to simu-late used precoat.
3.6 All Chemicals used to condition or solidify waste or simulated waste ir, solidification tests shall be the actual chemicals used in full scale solidification.
3.7 A lest Sol' '1 cation Data Sheet will be maintained for each test sample solidiftet ach Data Sheet will contain pertinent information of the test sample and the liner numbers solidified based on the test sample.
5.0 1372c
~
Number i Nuclear Operating Procedure m .i 1104 281
-Title Revision No.
Waste Solidtftcation Process Control Program 8 3.8 Samples should be drawn at least six hours prior to the planned full scale waste solidification to allow adetuate tire to complete the required testing and verification of solidification for Class A unstable waste. 28 hours3.240741e-4 days <br />0.00778 hours <br />4.62963e-5 weeks <br />1.0654e-5 months <br /> should be allowed, if practical, for Class A stable, Class B and C
, wastes.
l l 3.9 The tank contalning the waste to be solidified should be mixed by recircu-l lating the tank contents for at least three volume changes prior to sampling to assure a representative sample.
3.10 If the contents of more than one tank are to be solidified in the same Ihier then representative samples of each tank should ba drawn. These samples should be of such size that when mlzed together they form samples of standard size. If the contents of a particular tank represtats X per:ent of the total waste quantity to be solidified then the sample of that tank should be of such size to represent X percent of the composite samples.
3.11 An RWP must be obtained and used for performing test solidifications of radioactive samples.
4.0 TEST SOLIO!FICATION OF 4 TO 10 WT1 BORIC ACID (CONCENTRATED WASTE) 4.1 Prerequisites NOTE: This PCP Test Solidification Procedure is applicable to Class A Unstable. Class A Stable, Class B and C Waste Forms.
4.1.1 A sufficient size sample of concentrated waste (approv. 1 liter) has been drawn and the following parameters analyzed for by Plant Chemistry:
- Boron e pH
- Total Solids
- Gamma Scan NOTE: The total solids and gamma scan are used for information ,
purposes only to track waste characteristics and are not I to be used in the Process Control Program calculations.
6.0 1372c
MUClear Tm.i
""*b" Operatino Procedure 1104 281 Title Revision No.
Haste Solidification Process Control Program 9 NOTC: The Concentrated waste sample shall be kept heated (> 100'F) unless previously neutralized. The acceptable pH range for concentrated waste is 7.4 to 9.2.
4.1.2 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
00A Monitor contacted Name / Date / Time 4.1.3 The appropriate portions of Attachment I have been coTpleted including waste classification, chemistry information, balance calibration data and the sequential sample number.
4.2 Procedure NOTE: Tare weights of waste, cement, additives, etc. should be obtained during performance of the following procedure.
. Round off to the nearest gram.
4.2.1 Calculate the weight percent of Boric Acid on Attachner.t 1, 4.2.2 MEASURE 500 g s of untreated concentrated waste into a contaire .
4.2.3 RECORD the weight and volume on Attachment 1.
4.2.4 ADD 50 wtt sodium hydroxide (ha04) until the pH is betmee, 8 to 8.5 for Class A unstable, Class A stable, B and C solidifica.
tion.
4.2.5 RECORD the weight of NaOH used and the adjusted pH on Attachment 1.
4.2.6 If large (i.e., foam causing) quantities of detercents are present, TREAT the sample with an anti.foaning agent until th(
foam disappears.
4.2.7 RECORD the weight of anti-foaming agent used on Attachment 1.
4.2.8 If oil is present in statle waste in a cuantity greater tha, I?.
by volute, reduce the Quantity of oil to less than 1% by skimning. For unstable waste if oil is present and the volu t is betmern 3 and 12% of the volume of waste, TREAT with an 7.0 1372c
ENuclear
""= b "
1H1_i OpeJatina Procedure 1104-281 Title Revision No.
Waste Solidification Process Control Program 9 emulsifying agent such as Haysol 776 (20% of the volume of
, oil). Oil in concentrations > 12% by volume may not be solidified b/ this procedura. (Refer to Section 6.0 Test Solidification of Haste 011).
N0YF: The density of Haysol 776 is 1.0 g/ml; the volume in ml is equal to the weight in grams.
4.2.9 RECORD the % oil and the quantity of any emulsifying agent used on Attachment 1.
4.2.I0 Re:ord the volume and calculate the weight of the treated Sample on Attachment 1.
4.2.11 Calculate the percent solids in the imple by completing items (9), (10), (11) anc (I2) in Section .I of Attachment 1.
4.2.12 for the test solidification of the concentrated waste, measure into a mixing vessel 400 ml of pretreated waste.
...._____..._____.....___.....................__.......__..........~.__......
NOTE: Test solidifications should be conducted using a 1.030 ml disposable beaker or similar size container.
4.2.13 RECORD the volume AND weight of the treated sample on Attachment 1, 4.2.14 Calculate the water in the sample by coipleting itemi (15). (16) and (17) in Section !!! of Attachtent 1.
4.2.15 Using Figure 1 and the percent solids from th? Test Solidifice-tion Data Shett, Item (12), DETERMINE the water /cc. ment ratio then CALCULATE and WEIGH out the required quantity of Portland Type ! cement.
4.2.lc RECORD the weight of cement on Attachment 1.
4.2.17 CALCULATE and WEIGH out the required quantity of metso beads, i.e., anhydrous sodium iretasilicate (ASMS), into a separate vessel.
4.2.13 RECORD the weight of ASM5 on Attach 7ent I.
6.0 1372:
AUClear
- THI.i Operatina Procedure 1104-281 Title ,
Revision No.
Haste Solidification Process Control Program 10 4.159 Slowly ADD the cement to the test sample while it is being mixed.
NOTE Hixing should be accomplished by stirring with an electric mixing motor with blade er manually with a rigid stirrer until a homogeneous mixture is obtained, approximately one minute.
4.2.20 After all the cement is added, slowly ADD the ASHS to the test sample while it is being mixed.
4.2.21 After sufficient mixing (2 minutes after all the ASMS is added) so that a homogeneous mixture is obtained, SEAL the sample and CURE at 120 2 5'F for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> for Class A Stable, Class B or C or at room temperature for Class A unstable.
NOTE: If at any time during the 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> cure, the sample meets the acceptance criteria, the liner solidification may proceed. Howev*r, no test solidification shall be disquallfted without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
4.2.22 Verify the Acceptance Criteria (Section 10) has been met and sign and date Attachment 1.
4.2.23 When the Acceptance Criteria has been met per Section 10, calculate the required quantitles of cement and additives for the full scale solidification using a liner type applicable for this waste type (as determined by Radwaste Operations Engineer _
ing) and the Solidification Calculation Sheet for 4 to 10 wt%
Boric Acid (Attachment 2).
NOTE: The liner shall be solidified using OP 1104-28A, Radio act!ve Waste Solidtfication - Hittman.
4.2.24 Complete Section VII of Attachment 2 upon completion of the l solidification if cement remains in the hopper.
90 1372c f
I YUClear Tm _ i
""*b" Oparatino Procedure 1104-28!
iltle Revision No.
Waste Solidification Process Control Program 9 5.0 TEST SOLIDIFICATION OF > 10 TO 20 wt% BORIC ACIO (CONCENTRA'E0 WASTE) 5.1 Pre' requisites NOTE: This PCP Test Solidification Procedure is applicable to Class A Unstable, Class A Stable, Class B and C Waste Forms.
5.1.1 A sufficient size sample of concentrated waste (approx. ! liter) has been drawn and the following parameters analyzed for by Plant Chemistry:
e Boron e pH e Total Solids e Gamma Scan NOTE: The total solids and gatra scan are used for informatter purposes only to track weste characteristics and are not to be used in the Process Control Prcgram calculations.
NOTE: The Concentrated waste sample shall be kept heated 130'F) unless prsiviously neutralized. The acceptable pH ran, for concentrated waste is 7.4 to 9.2.
5.1.2 The Ors Quality Assurance Group has teen contacted to inform them of the pending Test Solidification to see if they care to wi', ness the test.
OQA Monitor Contacted hace / Date / Timt 5.1.3 The anpropriate portions of Att6thment 3 have been complet?d int bading waste classification, chemistry infornation, balance calibration data and the sequential sample number.
10.0 1372c
o .
Nuclear Number
- im.i Operatina Procedure . 1104 281 11tle Revision No.
Waste Solidification Process Control Program g 9
5.2 Procedure NOTE: Tare weights of waste, cement, additives, etc. should be obtained during performance of the following procedure.
Round off to the nearest gram.
5.2.1 Calculate the weight percent of Borte Acid on Attachment 3.
5.2.2 MEASURE 500 gms of untreated concentrated waste into a container.
5.2.3 RECORD the weight and volume on Attachment 3 p 5.2.4 ADD 50 wt% sodium hydroxide (NaOH) until the pH is between 12 and 12.5.
5.2.5 RECORD the weight of NaOH used and the adjusted pH on Attachment 3.
5.2.6 If large (i.e., foam causing) quantitles of detergents are present, TREAT the sample with an anti. foaming agent.
5.2.7 RECORD the weight of antl. foaming agent used on Attachment 3, 5.2.8 If oil is present in stable waste in a quantity greater than 1%
by volume, reduce the quantity of oil to less than 1% by skimming. For unstable waste if oil is present and the volurt is between 3 and 12% of the volute of waste, TREAT with an etulsifying agent such as Maysol 776 (20% of the volute of oil). Oil in concentrations > 12V, by volute may not be solidified by this procedure. (Refer to Section 6.0 Test Solidification of Weste 011).
NOTE: The density of Maysol 776 is 1.0 g/ml; the volui.9e in ml is equal to the weight in grams.
5.2.9 RECORD the % oil and the quantity of any emulsifying agent used on Attachment 3.
5.2.10 Record the volur,e and calculate the weight of the treated sae;1e on Attachment 3.
5.2.11 Calculate the percent solids in the $4Tple by coe.pleting ite.ti (9), (10), (11) and (12) in Section II of Attach. tent 3.
11.0 1372c
MUCl68r THI.i Operating Procedure 1104-28I Title Revision No.
6'aste Solidification Process Control f rcoram 8 5.2.12 For the test solidification of the concentrated waste, measure
- into a mixing vessel 400 ml of treated waste.
NOTE: Test solidifications should be conducted using a 1,000 ml disposable beaker or similar size container.
5.2.13 RECORD the volume AND weight of the sample on Attachment 3.
5.2.14 Calculate the water in the sample by completing items (15), (16) and (17) in Section III of Attachment 3.
5.2.15 Using Figure I and the percent solids from the Test Solid 1'ica-tion Data Sheet, Item (12), DETERMINE the water / cement ratio then CALCULATE and WEIGH out the required quantity of Portland Type I cement.
5.2.16 RECORD the weight of cement on Attachment 3.
5.2.17 CALCULATE and WEIGH out the required quantity of anhydrous sodium metas111cate (ASMS) into a separate vessel.
5.2.18 RL'.URD the weight of ASMS on Attachment 3.
5.2.19 Slowly ADD the cement to the test sample while it is being mined.
NOTE: Mlaing should be accomplished by stirring with an ele:tric mining motor with blade or manually with a rigid stirrer untti a homogeneous mixture is obtained, approximately one minute.
5.2.20 After all the cement is added, slowly ADD the ASMS to the test sample while it is being mixed.
5.2.21 After suffletent mixing (2 minutes after all the ASMS is added) 50 that a homogeneous mixture is obtained, SEAL the sample and CURE at 120 2 5'r for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> for Class A Stable, Class B or C or at room temperature for Class A Unstable.
NOTE: If at any time during the 24 hour2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> cure, the sample meets the acctptance criteria, the liner solidification may proceed. However, no test solidification shall be dit.
Qualified without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of :ure.
12.0 1372:
7__
lkllJhCI!IBdlII' THI-I Operattna P_rocedure 1104 28!
Title ,
Revision No.
Waste Solidification Process Control Program 10 5.2.52 Verify the Acceptance Criteria (Section 10.0) has been met and ,
sign and date Attachment 3.
5.2.23 When the Acceptance Criteria has been met per Section 10, calculate the required quantitles of cement and additives for i the full scale solidification using a liner type applicable for this waste type (as determined by Radwaste Operations Engineer-ing) and the Solidification Calculation Sheet for > 10 to 20 ut%
Boric Acid (Attachment 4).
NOTE: The liner shall be solidified using OP 1104-2dA, Radioactive Waste Solidification - Hittman.
5.2.24 Complete Section VII of Attachment 4 upon completion of the l solidification if cement remains in the hopper, ,
6.0 TEST SOL 10!FICAT!0N OF WASTE O!L (12 - 40% 011) 6.1 Prerequisites
____ __.....____....__........___....__.......___........_~............___.... ,
NOTE:
~~~~
This PCP Test Solidification Procedure is applicable to I Class A Unstable Class A Stable. Class B and C waste forms, l 6.1.1 A sufficient $1re sample (approx. 500 ml.) ench of pH ad,iusted concentrated waste and waste oil have been drawn. The concen.. i trated waste shall be within a pH range of 7.4 to 9.2.
NOTE: The pH of the concentrated waste will be adjusted in the tank before the test solidification.
6.1.2 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
OQA Honitor Contacted _.
[
Name / Date / Time .
6.1.3 A sequential sample number has been assigned to the test and -
included on Attachment 5.
6.1.4 A determination has been made as to the waste class of the pending full scale solidification by Radwaste Ops. Engineering.
13.0 1372c t
. EgMr s 7st.i l Nurber Operating Procedure 1104.j81 T]il_e Revision No.
Weite Solidification Pr_ocess Control Program g 6.1.5 The balance calibration data has been included on Attachment 5.
6.2 Prbcedure 1
NOTE: Tare weights of wasto, cement, additives, etc. should be obtained during performance of the following procedure.
Round off to the nearest gram.
6.2.1 Heascre into a mixing vessel 210 ml of concentrated waste and 140 mi oil.
NQ*E: Test solidifications should be conducted using a 1000 ml "
disposable beaker or similar size container.
l .............................................................................
6.2.2 Record the vaste volumes added and Calculate the percene oil by volume on Attachment 5.
L 6.2.3 MEASURE out 28.0 ml (28.0 gms) of Maysol 776.
6.2.4 RECORD the quantity of the emulsifier on Attachment 5.
6.2.5 AD3 the Maysol 776 to the waste and mix until a homogeneous mliture is obtained, at least five (5) minutes.
NOTE: Hising should be accomplished by stirring with an electric miner with blade or manually with a rigid stirrer. Any signs of pure oil may be an inalcation that the er.Islon is bretting do.n. Should th!s occur, contact Rad.'aste Ops. Engine (ring for further instructions.
6.2.6 If large (i.e., foam causing) quantitles of detergents are present, treat, the sample with anti-foaming agent until the foam disappears.
6.2.7 Record the amount of anti. foaming agent used on Attachment 5.
6.2.8 NEASURE out 447.3 gms of Portland Type I cement and 51.8 gms of enhydrous sodium metasilicate (ASMS).
6.2.9 RECOR3 the quantitles of cement and ASMS on Attachmer.t 5.
14.0 137?c
1MCl48F "'"
m!.1 Operatino Procedure 1104 28!
Title Revision No.
Wasta Solidification Process Control Program 9 6.2.10 Slowly ADD the cement to the test sample while it is being mixed and mix until a homogeneous mixture is obtained but in no case less than one (1) minute.
6.2.11 Af ter all the cement is added, slowly ADD the ASMS to the test sample while it is being mixed.
6.2.12 HIX for two (2) minutes after all the ASMS is added and homo-geneous mixture is obtained.
6.2.13 Seal the sample and cure at 120 1 5'F for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> for Class A Stable, Class B or C or at room temperature for Class A Unstable.
If at anytime during the 24-Four cure time, the sample NOTE:
meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be disqualified without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
6.2.14 Verify the Acceptance Criteria (Section 10.0) has been eet and sign and date Attachment 5.
6.2.15 When the Acceptance Criteria has been met per Section 10, calculate the required quantities of cement and additives for the full scale solidification using a liner type applicable fcr this waste tyce (as determined by Radwaste Operations Engtreer-ing) and the Solidificat'on Calculation Sheet for Waste Oil (Attachmer.t 6).
l l NOTE: The liner snall be solidirled ustni OP 1104-26A, Radica:tive l Waste Solidification Hittman.
7.0 -TEST SOLIDIFICATION OF USED PREC0AT 7.1 Prerequisites NOTE: This PCP Test Solidification Procedure is applicable to Class A Stable, Class B and C Waste Forms.
7.1.1 A sufflctent size sample of used precoat (appron. 500 ml) has been drawn and the following parameters analyzed for by Plant Cnemistry:
e pH (of sluice water)
I S . C- 13T2c
UOlOOI
' THI-l Operatino Procedure 1104 ?8!
Title Revision 50.
Haste Solidification Process Control Program 1
- Gamna Scan NOTE: Where high activity waste could pose personnel radiation exposure pecble"s when performing the test solidification, e>pendeo powder with an appropriate anton/ cation ratio shall be substituted. The ratio shall be determined by Radwaste Operations Engineering. A small sample of use precoat
(= 20 mis) shall be taken for isotopic analysis.
NOTE: The gamma scan is to be used for information purposes only to track waste characteristics and is not to be used in tne PCP calculations.
7.1.2 The sample has set to verify 1 It o.1 by volume.
7.1.3 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
OQA Monitor Contacted Name / Date / Tire 7.1.4 The appropriate portions of Attachmeit 7 hase been c0Tpleted including the balance calitration data and the secuential sa ple nurter.
7.2 Procedure N3it: Tate weights of waste, cement, additives, etc. should be cttained during performance of the following procedure.
Round off to tne nearest gram.
7.2.1 PEASURI out 381.1 gms of dewatered powdered resin and 151.5 gt1 of water and place into separate contair.trs.
NOTE: Test solidification should be corducted using a 1,000 ml disposable beaker or similar stre container.
7.2.2 RECORD the volume and weight of the po=ered resin on Attacheint 7.
16.0 137 :
-(UClear Tsi-i Operatino Procedure 1104 28!
Title Revision No.
Haste"Solidification Piocess Control Piogram 9 7.2.3 ADD the water to the powered resin and RECORD the weight of
- water added and the total volume of waste slurry (water plus resin) on Attachment 7.
7.2.4 If any foam is present, TREAT the sample with an anti-foaming agent.
7.2.5 REC 0AD the quantity of anti.fcaming agent used on Attachment 7.
7.2.6 If oil is present and ti,e volume is between 3 and 12% of the volume of waste, TREAl with an emulsifying agent such as Haysol 776 (20% of the volume of oll). Oil in concentrations > 12% cy tolume may not be solidified by this procedure. Contact Aad aste Operations Engineering for guidance.
NOTE: The dersity cf Maysol 776 is 1.0 gr./ml; the volume in ml is equal to the weight in gms.
7.2.7 RECORD the quantity of oil present and the amount of Maysel added to the sample on Attachment 7.
7.2.8 RECORD the initial pH of the sample on Attachment 7.
7.2.9 MEASURE out approximately 10 grams of calcium hydroside Ca(08)2, also knomn as hydrated lime.
7.2.10 Slo ly ADD the calcium hydronide to the powdered resin slurry, two (2) grams at a time. Mlf for three (3) minutes tetaten additions until the pH is at least 11.5. ADD an aediti:nal three (3) grats of calcium hycroiide. This final additier ma,.
or may not alter the pH of the slurry.
ND1E: Mlaing should be a:complished by stirring with an electric mining motor with blade or manually with a rigid stirrer until a homogent:r>us mixture is obtaired approximately one (1) m.inute. l 7.2.11 RECORD the quantity of calcium hydroeide added to the slurry and the final pH on Attachment 7.
7.2.12 MEASURE out 444 gms of Portland Type I cement.
7.2.13 RECOR] the amount of cement en Attachment 7.
17.0 1372:
b
. ldICI!lINIII' TNI.1 Operatino Procedure 1104-281 1 Title Revision ho.
Waste Solidification Process Control Program 9 7.2.14 Slowly ADD the cement to the test sample while it is being mixed.
7.2.15 MIX for two (2) minutes after all the cement is added to obtain a homogeneous mixture.
7.2.16 RECORD the final sample volume on Attachment 7.
7.2.17 Seal and allow the sample to CURE for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> at 120 1 5'F.
[ NOTE: If at anytime during the 24. hour cure time, the sample meets the acceptance criteria, the liner solidification may 4
proceed. However, no test solidification shall be dis-
, qualified without at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
i i
7.2.18 verify the acceptance criteria (Section 10.0) has been met, siga
- and date Attachment 7.
- 7.2.19 When the Acceptance Criteria has been met per Section 10, calculate the required quantitles cf cement and additives using a liner type applicable for this waste type (as determined by Radwaste Operations Engineering) and the Solidification Calcula.
tion Sheet for Used Precoat (Attachment 8).
N3TE: The liner shall be solidified using OP 1104 280, Primarj Resin and Precoat Processing . Hittman.
1 8.0 Test SOLIDIFICATION Or BEAD RES!N 8.1 Prerequisites NOTE: This PCP Test So'idification Procedure is applicable to Class A Stable, Class B and C Waste forms.
8.1.1 A sufficient size sample of bead resin (approx. 500 ml) has beer.
drawn and the following parameters analyzed for by Plant Chemis.
try:
l i
e pH (of sluice water) 1
- e Cat.ma Scan 1
18.0 1372c
.i
MUCI 6ar' ""
' isi i Operatino Procedure 1104 281 Title Revision No.
Haste Solidification Pro (9.55 Control Program g I
ROTE: Where high activity waste could pose personnel radiation exposure problems when performing the test solidification, expended non. radioactive resin shall be substituted. The source of this resin shall be determined by Radwaste Operations Engineering. A small sample of spent resin
(= 20 mis) shall be taken for ltotopic analysis.
NOTE: The gamma scan is to be used for information purposes only to track waste characteristics and is not to be used in the PCP calculations.
8.1.2 The sample has set to verify i li 011 by volume.
8.1.3 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care t:
witness the test.
OQA Monitor Cor.tacted Name / Date / Tiri -
8.1.4 The appropriate portions of Attachnent 9 have been com;leted including the balance calibration data and sequential sarste number.
8.2 Frocedure h0iE: Tare weights of weste, cement, aeditives, etc. should te obtained during performance of the following procedure.
Round off to the nearest gram.
8.2.1 NEASURE into a mixing vessel 240 gm of dewatered resin.
NOTE: Test solidification should be conducted using a 1,000 ml disposable beaker or similar size container.
NOTE: Tap *he teater gently to consolicatt the resin prior to reasuring the volume.
19.0 1372c
Nuclear 1,1.i
- ' r Ooeratino Procedure 1104-28!
Title Revision No.
t Waste Solidification Process Control Program 9 l
L 8.2.2 RECORD the weight and volume of the sample (resin and water) on
. Attachment 9. L
{ 8.2.3 HEIGH out 2.1 gms of EC-3 into a separate vessel. '
8.2.4 RECORD the weight of EC.3 on Attachment 9.
- 8.2.5 PEIGH out 84.3 gms of water and record the weight on Attachment 9.
1 8.2.6 ADD the water to the vessel containing the EC.3 and mix thoroughly.
i 8.2.7 ADD the water /EC-3 mixture to the bead resin and mix thorougly.
8.2.5 If any foam is present, TREAT the sample with an anti-foaming 4
agent.
8.2.9 RECORD the quantity of anti-foaming agent used on Attachmert 9. f
- 8.2.10 If oli is present and the volume is between 3 and 12% of the volume of waste, TREAT with an emulsifying agent such as Maysol
)i
' 776 (20% of the volume of oil). Oil in concentrations > 12% by volume may not be solidified by this procedure. Contact l Radwaste Operations Engineering for guidance.
NOTE: The density of Maysol 776 15 1.0 gm/ml; the volume in ml is equal to the weight in gms.
t 8.2,11 I RECORD the quantity of oli and the volume of emuistfier used on !
I Attachment 9. '
8.2.12 RECORD the initial sample pH on Attachment 9.
8.2.13 l
HEASURE out approximately 11.5 gms of Calcium Hydromide t
- Ca(04)2, also known as hydrated lime. ;
8.2.14 Slowly ADD the Ca(OH)2 to the resin sample two (2) grams at a
! time. Mix for three (3) minutes between additions until the pH i of the slurry is at least 11.5. ADD three (3) additional gms of !
Ca(OH)2 This final additional may or may not alter the pH of the slurry, i 5 8.2.15 R(CORD the quantity of calcium hydroxide added to the slurry an: ['
the final pH on Attachment 9.
1 i
1 20.0 1372c
Nuclear 18t i
,,,,,,,,,;,,c,,u,e Number Title , ,go4- , j, y haste Solidification Process Co,ntrol Program 9 8.2.16 MEASURE out 178.2 gms of Portland Type I cement into a separate
. vessel.
8.2.17 RECORD the weight of the cement on Attachment 9.
8.2.18 Slowly ADD the cement to the test sample while it is being mixed.
B.2.19 HIX for two (2) minutes after all the cement is added to obtain a homogeneous mix.
8.2.20 RECORD the final sample volume on Attachment 9.
9.2.21 SEAL the sample and allow the sample to CURE for 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> at 120
. S*F.
NOTE: If at anytime during the 24-hour cure time, the sample reets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be dis.
Qualified witnout at least 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> of cure.
8.2.22 VERIFY the acceptance criteria (Section 10.0) has been eet, sigt and date Attachment 9.
8.2.23 When the Acceptance Criteria has been ret per Section 10.0, CALCULATE the required quantitles of cecent and additives ustr; a liner type applicable for this waste type (as determined ty Radwaste Operations Engineering) and tre Solidification Calcula-tion Sheet for Bead Resin (Attachment 10).
NOTE: The liner shall be solidified using CP 1104 280, Primary Resin and Precott Processing . Hittman.
9.0 ALTERNATE TEST SOLIDir! CATION PROGRAMS NOTE: The PCP Test Solidification presented in this procedure should cover the majority of the waste processing require.
ments of THI.l. In the event a different waste stream requires processing or a waste stream covered by this procedure but not having the appropriate waste form or liner type, a P P Test So!!dification can te perforce:
using a current procedure provided by Westinghouse .
Hittaan.
21.0 137'c
MUCl68r Tm.i Number Operating Procedure 1104-281 Title Revision No.
Haste Solidification Process Control Program 9 9.1 Prerequisites 9.i.1 A procedure l's available for the particular waste strean to be processed.
9.l.2 This procedure has been verified curreht by the Radwaste Ops.
Manager or his designee and will be reviewed by the Radwaste Engineer prior to its use.
9.1.3 The sample reautred by this procedure has been obtained and applicable chemistry parameters analyzed for by Plant Chemistry.
9.1.4 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test.
OQA Monitor Contacted Nace / Date / Tire 9.1.5 Balance calibration data has been included on Attachment 11, 9.1.6 Attachrent 11 has been corpleted.
9.2 Procedure 9.2.1 Performed the applicable portions of the Westir.; house - Hittes" procedure.
10.0 ACCEPTANCE CRITERIA 10.i Solidification Acceptability 10.1.1 The sample soildification is considered acceptatie if there is not visual or craineble free water.
10.1.2 The sarple solidification is considered 4:ceptatie if it resists genetraticr.
22.0 '372c
o o (UClear Tur.1 Operatino Procedure 1104-281 Title Revision No.
Haste Solidification Process Control Program 9 NOTE:
Physical examination shall be for resistance to a ten (10) pound load applied to the surface of the solidified product using a 1/2 inch diameter metal rod. The solidification shall be considered acceptable if the metal probe cannot break the surface and penetrate to the sample core. Normal denting of the surface is acceptable.
The rod toleranct;5 are as follows:
+1 lb Weight 10 lbs 0 lb
+0 in Diameter 1/2 inch 1/4 in 10.2 Solidification Unacceptability 10.2.1 If the waste fails any of the criteria set forth in Section 10.1 the solidification will be termed unacceptable and a new set of solidification parameters will need to be established urder the procedures in Section 10.3.
10.2.2 If the test solidification is unacceptable then the sare test procedure must te followed on each subsequent batch of the sa e type of waste until three consecutive test samples are solici.
fled.
10.3 Alternate Solidification Parameters 10.3.1 If a test sample for Class A unstable waste falls to prcside acceptatie solidification of waste the follo.ing procedures should te followed.
- a. Min 454.5 gms of cement and 45.5 gms of ASMS with 400 mis of water to ensure that the problem is not a bad tatch of ceeent.
- b. Add e.daitional 50 wt.% NaOH to raise the pH above 8 but less than 9.2 for borated wastes.
- c. If the waste (other than waste oil) is only partially solidified. use lower waste to cement and Metso ratios.
Using the recon ended quantitles of cement and Hetso Beads, reduce the maste sample to 375 ml and continue reduci ; the sample volute t'y 25 ml. until the accettability criteria of Section 10.; arc ret.
s 23.0 1372c
, , ENuclear m -i Nuzber Operating Procedure ,,0,.,,,
Title Revision No.
Waste Solidifica' ion Process Control Program 9
- d. If the waste oli mixture is only partially solidified try using lower waste to cement ratios. Reduce the quantity of waste by 25 ml. and the emulsifier by 1 ml., (This will result in a slightly higher concentration of emulsifier in the waste) and proceed with the test solidification.
Coatinue witn similar reductions until a satisfactory product is achieved.
10.3.2 For Class A stable. Class B and C waste test samples that fail to solicify, Contact Radwaste Operations Engineering for resolu-tion, g ,9 1372c
Nuclear' ""
. 1sI_i Operatina Procedure 1104-281 Title Revision No.
Waste Solidification Process Control Program 8 ATTACHMENT 1 Page 1 of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR 4 TO 10 WT% BORIC ACID Chemistry Parameters Balance Cal. Info. Liner No.:
Sample Date, CMTE No. Sample No.:
Boron ppm Serial No. Date:
Total Sollds ppm Cal. Due Date Waste Class pH Total Act. mci /cc
!. PRECONDITIONING:
Weight Percent of Boric Acid (in decimal form):
Boron (opm) x .01 ( ) x .01 1748 - 1748 . (1)
Weignt of Untreated Sample: gms (2)
Volume of Untreated Sample: mis (3)
Weight of 50% NaOH Added to Adjust pH gms (4) within range per Section 4.2.4.
pH of treated sample:
Weight of Anti-foam Added: gms (5)
% 0111 : 1 Weight of Emuistfier Added: gms (6)
Volume of treated sample: mis (7)
Weight of treated sample:
(2) + (4) + (5) + (6) . ( )+ < > +( ) + ( ). gms (8)
El-1 1372c
Nuclear ""**"
- 1s!-i Operating Procedure 1104-281 Title Revision No.
Haste Solidification Process Control Program 8 ATTACHMENT 1 (Cont'd) Page 2 of 4 l
II. DETERMINATION OF PERCENT SOLIDS OF SAMPLE:
Weight of Boric Acid in Untreated Sample: l (2) x (1) -( ) x ( ) - gms (9)
Weight of 501 NaOH:
(4) x 0.5 - ( ) x 0.5 - gms (10)
Weight of Solids in Treated Sampire:
(5) + (6) + (9) + (10) -
( )+ ( )+( ) + ( )- gms (11)
Percent Solids in Treated Sample:
100 x (11) + ((8)) -
100 x ( )+(( })- _ _% (12)
III. DETERMINATION OF WATER IN SAMPLE FOR SCLIDIFICATION:
Volute of Treated Sample to be Solidified: ml (13)
Weight of Treated Sample to be Solidified: gms (14)
Weight of Water in Sample Contributed by Waste:
'g ) x (14) x (1 - (1)) -
_( 8) .
Ox ( ) x (1 - ( )) - gms (15)
. () .
Weight of Water in Sample Contributed By 50% NaOH:
(4) x (14) x 0.5 - '
(8) .
( ) x ( ) x 0.5 -
( ) , gms (16)
Total Height of Water in Sample:
(15) + (16) - ( ) +( ) - gms (17)
El-2 1372c
Nuclear THI-i Operatina Procedure Number 1104-281 Title Revision No.
Waste Solidification Process Control Program 8 ATTACHMENT I (Cont'd) Page 3 of 4 IV. DETERMIN5TIONOFQUANTITYOFPORTLANDTYPEICEMENTANDHETSOBEADSTOUSEFOR SAMPLE SOLIDIFICATION:
Using Figure I, find the % solids in sample (12), and DETERMINE the Water / Cement Ratto: (18)
Weight of Cement to Use:
(17) . ( ) =
(18) ( ) gms (19)
Weight of Hetso Beads to use:
(19) x 0.15 - ( ) x 0.15 - gms (20)
Test Solidification Performed By:
Name Date Time V. SAMPLE INSPECTION Sample cured for:
Hours Cured Temp. Cured Verifted By Date Sample contains "No Free Liquid":
Verified By Date Sample "Resists Penetration":
Verifted By Date El-3 1372c
Nuclear' 1si i Operatina Procedure 1104-281 Title Revision No.
Haste Solidification Process Control Prograe 9 ATTACHMENT I (Cont'd) Page 4 of 4 Additional batches solidified based on this sample =>.,'idification:
Liner Haste Liner Waste Liner Haste No. Vol. Date No. Vol. Date No. Vol. Date
- 2. 5. 8.
- 3. 6. 9.
4 7. 10.
FOOTNOTES:
- 1. Maximum allowable oil content for stable waste is 1% by volume.
VI. INDEPEh0ENT VERIFICATION BY GPUN MANAGEMENT Test Sample Meets Acceptance Criteria (Section 10) Name / Date / Time Test Solidification Data Sheets (Calculations) Reviewed NaTe / Date / Time El-4 1372t
Nuclear in! i
""*b" Occratina Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 8
- ATTACHMENT 2 Page 1 of 3 SOLIDIFICATION CALCULATION liHEET FOR 4 TO 10 Wil BORIC ACID Liner Type to be used I. Volume of Untreated Waste to Add to Linerl.3:
(3) Max. Treated Waste Vol.
(7) x from Solidification Data Tables -
( )
( ) x -
___f t3 (21)
!!. Volume of Additives to Add to Liner:
NaOH: (4) x 4.86 x (21) - ( ) x 4.86 x( )- gals (22)
(3) ()
Anti-foam: (5) x 7.48 x (21) = ( ) x 7.48 x( )- gals (23)
(3) ()
Emulsifier: (6) x 7.48 x (21) - ( ) x 7.48 x( )- gals (24)
(3) ()
III. Volume of Treated Waste to be SolidifiedI *
(22) + (23) + (24) ( )+( )+( )
(21) + 7.48 - ( )+ 7.48 - ft3 (25)
IV. Cement Quantity for Full Scale Solidification:
(19) x 62.4 x (25) -( ) x 62.4 x ( ) - Ibs (26)
(13) ( )
(26) + 94 - ( ) + 94 - bags 2 V. ASMS Quantity for Full Scale Solidification:
(26) x .15 - ( ) x .15 - Ibs (27)
(27) + 100 - ( ) + 100 - bags 2 E2-1 1372c
Nuclear THI_i ODeratina Procedure 1104 28!
Title Revision No.
Waste Solidification Process Control Program 9
. ATTACHMENT 2 Page 2 of 3 VI. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIDIFICATION CALCULATION SHEETS REVIEHED Name / Date / Time FOOTNOTES I The volume of treated waste to be solidified in a single liner cannot exceed the maximum treated waste volume listed on the attached Solidifle.ation Data Tables.
2 Round off up to the nearest whole bag.
l 3 Use the actual waste volume added to the liner in Stept/ Equations 22, 23 and 24 L if the waste volume added to the liner is less than the value obtained in l Step / Equation 21. ;
l VII. DETERMINATION OF THE QUANTITY OF CEMENT ADDED TO WASTE:
Quantity of Cement Added to Hopper: lbs (28) ,
Quantity of Cement Left in Hopper: __
lbs (29)
Quintity of Cement Added per ft.3 Waste:
_28)
( - (29) = ( )-( )= lbi cement /
(25) ( ) ftJ waste ,
NOTE: Minimum Quantity of Cement Allowable for 4 to 10 Wt. % I Boric Acid Class A Unstable Waste is 62 lbs 'ft.3, For Stable waste solidifications all the ce .nt must be -
added to the liner.
L Quantity of Cement Addtd Meets Minimum Requirements for unstable waste forms: l Vertfled By Date The recommended minimum treated waste volume and minimum solidified waste volume I meet the requirements of the Solidification Data Tables for STABLE waste forms. ,
Vertfled By Date I
E2-2 1372c
"" *6 "
Nuclear Tn!.i Operatina Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 7
. ATTACHMENT 2 (Cont'd) Page 3 of 3 SOLIDIFICATION DATA TABLES FOR 4 TO 10 WT% BORIC ACID HN-100 HN-100 LVH Series 3 Series 31 Usable Liner Vol. (cu. ft,) 141.1 157.5 Max. Treated Waste Vol. (cu. ft.) 104.4 116.6 Max. Solidified Waste 141.1 157.5 Vol. (cu. ft.)
Recommended Hin.
Treated Waste Vol. 98.1 103.8 (cu. ft)2 Min. Solidiflad Weste Vol. (cu. ft)2 132.6 140.2 Max. Rad. Level 12 12 R/hr Contact
- 1. For less than A2 quantitles of LSA waste. For greater than A2 quantit.es of LSA waste, the maximum treated waste volume is 112.4 cu. ft, due to weight Ilmitations.
- 2. These minimums are required when shipping to Barnwell, to comply with the 15%
maximum vold space criteria for liners containing solidified stable waste forms.
E2-3 1372c
ENuclear
""* b "
Tm_i Operatina Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Procram 8
, ATTACHMENT 3 Page 1 of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET > 10 TO 20 WT1 BORIC ACID Chemistry Parameters Balance Cal. Info. Liner No.:
Sample Date CMTE No. Sample No.:
Boron ppm Serial No. Date:
Total Solids ppm Cal. Due Date Waste Class pH Total Act. pCi/cc I. PRECONDITIORING Weight Percent of Boric Acid (in decimal form):
Boron (opm) x .01 ( ) x .01 = (1) 1748 = 1748 Weight of Untreated Sample: gms (2)
Volume of Untreated Sample: mis (3)
Weight of 50% NaOH Added to Adjust pH per Section 5.2.4: gms ..o pH of treated sample:
Weight of Anti-foam Added: gms (5)
% 0111 : %
Weight of Emulsifier Added: gms (6)
Volume of treated sample: mis (7)
Weight of treated sample:
(2) + (4) + (5) + (6) - ( )+( )+ ( )+( )- gms (8) l E3-1 1372:
Nuclear Number
. Ts!-i
.' Operatino Procedure 1104-281 Title Revision No.
Waste Solidification Process Control Program 8 ATTACNMENT 3 (Cont'd) Page ?. of 4 II. DETERMINATION OF PERCENT SOLIDS OF SAMPLE Weight of Boric Acid in Untreated Sample (2) x (1) -( ) x ( ) - gms (9)
Weight of 50% NaOH:
(4) x 0.5 - ( ) x 0.5 - gms (10)
Welght of Solids in Treated Sample:
(5) + (6) + (9, + (10) -
( )+( )+( )+( )- gm; (11)
Percent Solids in Treated Sample:
100 x (11) + [(8)) -
100 x ( )+[( )) - % (12)
III. DETERMINATION OF WATER IN SAMPLE FOR SOLIDIFICATION:
Volume of Treated Sample to be Solidified: ml (13)
Weight of Treated Sample to be Solidified: gms (14)
Weight of Water in Sample Contributed by Waste:
~ '
- 12) x (14) x [1 - (1)) -
,( 8) ,
!_2 x ( ) x [1 - ( })- gms (15)
() .
Weight of Water in Sample Contributed by 50% NaOH:
'idl x (14)' x 0.5 - '( ) x ( )' x 0.5 = .gms (16) I
,( 8) , ,
( )
Total Height of Water in Sample:
(15) + (16) - ( )+( )- 9ms (17)
E3-2 1372c
Number Nuclear THI-i Operatina Procedure 1104-28I Title Revision No.
Hast! Solidification Process Control Program 8 ATTACHHENT 3 (Cont'd) Page 3 of 4 IV. DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENI AND HETSO BEADS TO USE FOR SAMPLE SOLIDIFICATION:
Using figure I, find the % solids in sample (12), and DETERMINE the Water / Cement Ratto: (18)
Height of Cement to Use:
(17) ( )
(18) , ( ) . gms (19)
Height of Metso Beads to use:
(19) x 0.15 ( ) x 0.15 gms (20)
Test Solidification Perfoimed By:
Name Date Time V. SAMPLE INSPECTION Sample cured for:
Hours Cured Temp. Cured Verified By Date Sample contains "No Free Liquid":
Verified By Date Sample "Resists Penetra+'an":
Verified By Date E3-3 1372:
Nuclear 1m_i Operatino Procedure 1104-281 Title Revision No.
Waste Solidification Process Control Procram 9 ATTACHMENT 3 (Cont'd) Page 4 of 4 Addition'i a batches solidified based on this sample solidification:
Liner Haste Liner Waste Liner Haste No. Vol. Date No. Vol. Date No. Vol. Cate
- 2. 5. 8.
- 3. 6. 9.
4, 7. 10.
FOOTNOTES:
- 1. Maximum allowable oil centent for Stable Waste is 17. by volume.
IV. INDEPENDENT VERIFICATION SY GPUN MANAGEMENT Test Sample Meets Acceptante Criteria (Se: tion 10) hane / Date / Tire Test Solidification Data Sheets (Calculations) Reviewed hame / Date / Tiri_
E3-4 137 c
Nuclear
""*6 "
mI_i Operatino Procedure 1104-28I Title Revision No.
Waste Solidification Process Control Program 8 ATTACHHF.NT 4 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR > 10 TO 20 HTT. BORIC ACID Liner type to be used I. Volume of Untreated Haste to Add to Linerl.3:
(3) Max. Treated Waste Vol.
(7) x from Solidification Data Tables -
( )
( ) x _
- ft3 (21)
II. Volume of Additives to Add to Liner:
NaOH: (4) x 4.86 x (21) - ( ) x 4.86 x( )= _
gals (1./
(3) ( )
Anti-foam: (5) x 7.48 x (21) - ( ) x 7.48 x( )- gals (23)
(3) ( )
Emuistfier: (6) r 7.48 x (21) - ( ) x 7.48 x( ) - gals (24) ,
(3) ( ) i III. Volume of Treated Waste to be SolidifiedI :
(22) + (23) + '24) ( ) +( )+( )
(21) + 7.48 - ( )+ 7.48 - ft3 (25)
IV. Cement Quantity for Full Scale Solidification:
(19) x 62.4 x (25) -( ) x 62.4 x ( )- Ibs (26)
(13) ( ) !
(26) + 94 - ( ) 94 - bags 2 V. ASMS Quantity for Full Scale Solidification:
(26) x .15 - ( ) x .15 - Ibs (27)
(27) + 100 - ( ) 100 - bags 2 E4-1 1372c
Nuclear THI-l Nueer Operating Procedure 1104 28!
Title Revision No.
Haste Solidification Process Control Program 9 ATTACHMENT 4 Page 2 of 3 50LIDIFICATIONCALCULATIONSHEETFOR>10TO20HT%BORICACIO V!. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIDIFICATION CALCULATION SHEETS REVIEHED Name / Date / Time FOOTNOTES I
The volume of treated waste to be solidified in a single liner cannot exceed the maximum treatec waste volume listed on the attached Solidification Data Tables.
2 Round off up to the nearest whole bag.
3 Use the actual waste volume added to the liner in steps / equations 22, 23 and 24 if the waste volume added to the liner is less than the value obtained in Step / Equation 21.
VII. DE'ERMINATION OF THE QUANTITY OF CEMENT ADDED TO WASTE:
Quantity of Cement Added to Hcpper: (28)
_ lbs QJantity of Cecent Left in Hopper: lbs (29)
Quantity of Cement Added per ft.3 Waste:
(26) . (29) . ( ) . ( ) =
lb (25) '. ) ftgcement/
waste NDTE: Minimum Quantity of Cement Allowable for >10 to 20 Ht.
% Boi'ic Acid Clas: A Unstable Waste is 60 lbs./ft.3 For STABLE waste solidifications all the cement must be added to the liner.
Quantity of Cement Added Heets the Minimum Requirements for unstable waste form.t:
Verified By Date The recovended mir.imum treated waste volume and minimJm solidified waste volum meet the requirenents of the Solidification Data Tables for STAELE waste forms.
Verified By Date E4 2 1372c
Nuclear rx!-i Operatino Procedure Humber l 1104-281
_ Title Revision No.
Haste Solidification Process Control Program 7 ATTACHMENT 4 (Cont'd) Page 3 of 3 SOLIDIFICATION DATA TABLES FOR > 10 TO 20 WT1 BORIC ACID HN-100 HN-100 LVH Series 3 Series 31 Usable Liner Vol. (cu. ft.) 141.1 157.5 Max. Treated Waste Vol. (cu. ft.) 101.3 113.1 Max. Solidified Waste 141.1 157.5 Vol. (cu. ft.)
Recommended Hin.
Treated Waste Vol. 95.2 100.7 (cu. ft)2 Min. Solidifi Vol.(cu.ft)gdWeste 132.6 140.2 Max. Rad. Level 12 12 R/hr Contact I- For less than A,9 quantitles of LSA waste. For greater than A2 quantities of LSA waste, the maximum treated waste volume is 106 cu. ft. due to weight limitations.
2- These minimums are r(quired when shipping to Barnwell, to comply with the 15*.
maximum void space criteria for liners containing solidified stable waste forms.
E4-3 1372c
l Nuclear
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1m i Operatino procedure 1104-281 Title Revision No.
Haste Solidification Process Control Program 9 ATTACHMENT 5 Page 1 of 2 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR HASTE OIL Chem. Parameters (Conc. Haste) Balance Cal. Info Liner No.:
Sample Date CMTE No.: Sample No.:
Boron opm Serial No.: Date:
Total Solids ppm Cal. Due Date: Haste Class:
pH Total Act. pC1/cc I. SAM 2LE PREDARATION Volume of 011 to be Solidified: els (1)
Volume of Concentrated Waste added to the oil: mis (2)
Total Volume of Sample: mis
% 011 by Volume:
(1) i 100i ( ) i 100 - % (3)
(1) + (2) ( )+( )
Height of 50 wt% NaOH added to sample to raise pH > 5 ges (4)
Quantity of Emulsifier to Add to Sample: mis (5)
Quantity of Anti Foam Added to Sample: mis (6)
Quantity of Portland Type 1 Cement Added to Sample: gms (7)
Quantity of Anhydrous Sodium Metaslittate Added to Sample: gms (8)
Test Solidification Performed By:
Name Date Tirre E5-1 137 :
Nuclear ""*"
Ts!.i Operatino Procedure 1104-281 ~
litle Revision No.
Waste Solidification Process Control Program 9 ATTACHMENT 5 (Cont'd) Page 2 of 2 II. SAMPLE !RSPECTION Sample cured for:
Hours Cured Temp. Cured Veriftec By Date Sample contains "No Free Liquid";
Verifte: 6) Date Saeple "Resists Penetration":
Vertfled By Date Additional tatches 5011dified cased on this sat;le solidificatter.:
Liner Haste Liner Waste Lintr Wast (
ho. Vol. Date No. Vol. Date No. Vol. Date
- 2. 5. 8.
- 3. 6. 9.
4 7. 10.
III. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT Test Sample Meets Acceptance Criteria (Section 10) Nare / Date / Time Test Solidification Data Sheets (Calculations) Revie ed Nare / Date / Itre E5-2 1372:
R Nuclear """
m .i
. Operatina Procedure 1104 281 Title Revision No.
Waste Solidification Process Control Program 8 ATTACHMENT 6 Page 1 of 3 l
- SOLIDIFICATION CALCULATION SHEET FOR WASTE OIL l
Liner type to be used ;
!. PARAMETERS FOR FULL SCALE SOLIDIFICATION l
i Emulsifier:
(5) x 7.48 + (1) = ( ) x 7.48 + ( )= gall (9) ft3 Anti-foam l (6) x 7,48 x (1) + (2) .( ) x 7.48 x ( )+ ( ) gal / (10) ft3 Cement:
1 1 1 (7) x 62.43 x (1) + (2) = ( ) x 62.43 x ( )+ ( ) -- lbt/ (11) i ft3 !
ASMS:
1 1 (8) x 62.43 x (1) + (2) =( ) x 62.43 m ( ) +1 ) Ibl/ (12) ftJ ;
!!. QLaNTITIES TO BE ADDED FOR FULL SCALE SOLIDIFICATION ,
Volume of untreated waste to add to liner (Man Treated Waste Vol from Solidification ['
Data Tables):3 (13) l Concentrated Waste to be added:
60% x (13) 7.48 0.60 x ( ) 7.48 _ gals (14) l Waste 011 to be added:
40% x (13) = 0.40 x ( )- ft3 (15) i 407. x (13) m 7.48 0.40 x ( ) x 7.48 = g al'c [
f E6-1 1372c
Nuclear THI-1 uumber
_ Operatino Procedure 1104-281 fitle Revision No.
Waste Solidification Process Control Program 9 ATTACHMENT 6 (Cont'd) Page 2 of 3 Emulsifier to be added:
(15) x (9) = ( )*( )= gals Anti-foam to be Added:
(13) x (10) = ( ) x( )= gals ASi% to be added:
(13) x (12) = ( ) x( ) = lbs (16)
(16) + 100 = ( )+ 100 = bags l Volume of cetaent to add to liner:
(13) x (11) =( )x( ) =
lbs (17)
(17) + 94 = ( ) + 94 = bags l FO?Th0TES:
1 Round off up to the nearest whole bag.
2 Reduce the cuantity of total waste in the liner by I ft3 for every 10 galloas of anti-fcam added to the liner. No adjusteent is necessary for the first 10 gallons.
3 Use actual waste volume Uded to the liner in step / equations used in Section I:
if maste volute added to the liner is less than the value obtained in Step / Equation 13.
!!!. INDEPEND[hi V[RIFICATION BY GPUN HANAGEM[NT SOLIDIFICATION CALCULATION SH((t$ R(Vl[h!D h a tte / Date / T itre
[6-2 1372c
ENuclear 1,1.,
Operatina Procedure au e.r 1104-281 Title Revision No.
Waste Solidification Process Control Procram 7 l l
ATTACHMENT 6 (Cont'd) Page 3 of 3 [
SOLIDIFICATION DATA TABLES FOR NASTE O!L i
) HN-100 HN-100 i
Series 3 LVM Usable Liner Volume (ft3 ) 141.1 157.5 i
Max. Waste Volume (oil and cone, waste), ft3 93.7 104.6 i
- Mar. Solidified ;
Volume, ft3 141.1 157.5 o
Maximum Rad Level i
- R/hr Contact la 12 j '
t t
I i l t
' I
(
F I
t I
t l
I E6-3 1372c l i
Nuclear Number s . rar-i ,
. Oceratino Procedure 1104-281 Title Revision No.
Waste Solidification Process Control Procram 8 ATTACHMENT 7 Page 1 of 2
- CL'SS A STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR USED PREC0AT Balance Cal. Info.
Chemistry Parameters Liner No.:
CMTE No, pH Sample No.:
Serial No. Gamma Scan mC1/ml Date:
Cal. Due Date % 011 % Waste Class I. SAMPLE PREPARATION '
Weight of Dewatered Powered Resin gms (1) l Volume of Dewatered Powered Resin ml (2) '
Weight of Water Added to Powdered Resin: (3)
] gms Total of Volume of Powered Resin Slurry: ml (4)
]
i Quantity of Anti-foam t. gent Added to Sarole: gms (S) i Quantity of oil in Sample % (6) !
Quantity of Emuistfying Agent AcJed to Saeple: gms (7)
Inttial pH of Sample: (8) l
!!. SOLID!FICaTION i Quantity of Ca(OH)2 necessary to raise pH > 11.5: gms (9) )
I l Final pH of Sample: (10) i j Quantity of Portland Cerent Added to Sample .,
gms (11)
Final Sample Volume: mis (12)
Test Solldtftcation Performed By: r f
~ ~
have Date ilme l
I l E7-1 1372:
i I
Nuclear "a6" 1,!.i
/
- Title Oceratina Procedure 1104-28! i Revision No. !
Waste Solidification Process Control Procram 9 ATTACHMENT 7 (Cont'd) Page 2 of 2 QLASS A STABLE, CLASS 8 AND C TEST SOLIDIFICATION DATA SHEET i FOR USED PREC0AT t
!!!.jiMPLEINSPECTION !
l Sample cured for: !
t Hours Cured
(
Terp. Cured l
~
Veriftec By Oate Sarple contains "No Free Liquid"' i i
i verifiec Ey Date Sarple "Resists Penetration":
I Verifles By Date i
Additional batches solidified based on this sarple solidification:
Liner Waste Liner Waste Liner Waste .
No. Vol. Date No. Vol. Date No. E Date i T
- 2. 5. 8. i
{
- 3. e. s.
4, 7, 10. j IV. INDEPEhDENT VERIFICATION SY GPUN MANa3EMINT Test Sarple Meets Acceptance i Criteria (Section 10) hame / Date / Time l
[
Test Solidification Data Sneets (Calculattens) Reviewed hane / Date / Time l
E7-2 1372:
i
Nuclear Number
, . TN!-i i
. Oceratina Procedute 1104-28!
Title Revision No.
Waste Solidtfication Process Control Proar,Lm 8 ATTACHMENT f Page 1 of 3 l i : 50s.!DIFICATION CALCULATION SHEET FOR USED PREC0AT Liner Type to be used I. PARAMETERS FOR FULL SCALE SOLIDIFICATION:
Quantity of Water:
Q) 7.48 = ( ) 7.48 ga!/ (13)
(2) ( ) ft3 of waste Quantity of Anti-Foam Agent: I (5) r 7.48 . ( ) 7.48 gall (14)
(2) ( ) ft3 of waste Quantity of Emulsifier:
(7) i 7.48 . ( ) 7.48 gall (15) r (2) ( ) ft3 of waste :
Quantity of Ca(OH)2; !
l (9) 62.43 . ( ) r 62.43 Ibl / (16) ' !
(2) ( ) ftJ of waste I '
I' i Quantity of Portland Type 1 Cement: l t
(11) 62.43 - ( ) x 62.43 Ib (17)
(2) ( ) ftg/ of waste ,
!!. QUANTITIES 70 BE ADDED FOR FULL SCALE SOLID!FICat!ON l Volume of Dewatered Powdered Resin to be So11difte0: ft3 (18) l l 1
j Quantity of Water. '
l (18) m (13) . ( ) ( ). gal (19) l1 l Quantity of Anti-Foam Agent:
, (18) (14) . ( ) ( ). gal (20) ,
I Quantity of Emulsifier: !
(18) > (15) . ( ) s >. gal (21) i j
j EB-1 1372; f
e Nuolear au er l TMI-I ;
Operattna Procedure 1104-281 '
Title Revision No.
Waste Solidification Process Control Program 9 ATTACHMENT 4 (Cont'd; Page 2 of 3 SOLIDIFICATION CALCULATION SHEET FOR USED PREC0AT l t
Quantity of Ca(OH)2:
i (IG) x (16) . ( )x( ). Ibs (22) + (100) . ( )+( ). bags 2 (22) '
Quantity of Portland Type Cement: ,
! (18) : (17) . ( ) ( ). Ibs (23) + (94) . ( )+( ). bags 2 (23) t I The volume of waste, to be solidified in a liner cannot exceed the manimun (
settledfor Table and treated used waste volume Itsted on the Class B Waste Solidification Data precoat.
2 Round up to the nearest whole bag. i i
!!!. INDEPENDENT VERIFICA' ION BY GPUN MANAGEMENT l l
I SOLID!r! CATION CALCULATION SHEETS REVliWED l l
Name / Date / f*e l l
l l
i EB-2 1372:
L_
'O
. Nuclear TMI-i Operatina Procedure Number 1104-28!
litle Revision No.
Waste Solidification Process Control Procram 8 i
ATTACHMENT 8 (Cont'd) Page 3 of 3
- SOLIDIFICATION DATA TA8LE FOR USED PREC0AT .
NN-600 ?)] HN-200 MU Usable Liner Volume, ft3 59.3 59.4 Max. Solidified Waste Vol. ft3 59.3 19.4 Max. Dewatered haste Vol., ft3 33.3 33.3 Min. Haste Vol. ft3 32.9 32.0 Min. Solidified Waste Vol, ft3 58.6 57.0 Max Radiation Level R/hr Contact of t,iner 100 800 EB.3 1372c
. Nuclear Tai-i Operatina Procedure -
1104-28! '
Title Revision No.
lig117 5clidif,j.ggtion Proces5 Control Procram 8 ATTAChrtNT 9 Page 1 of 2
- CLASS A STABLE, CLASS 8 AND C TEST SOLIDIFICATION DATA SHEET FOR SEAD RES!N Salance Cal. Info. Chemistry Part, meters 1.iner No.:
f.MTE No, p H, Sample No.: ,,,,,
Serial No. Gamma Scan mCl/ml Date:
Cal. Due Date % 011 % Waste Class:
- 1. SAMPLE PREPARATION Sarple Weight: gms (1) l Sample Volure: ml (2)
Weight of EC-3: gms (3) l Weight of water: gms (4)
- Weight of Anti-foaming agent added to sample
- ,
is (5) -
! i Quantity of oll in sample: (6) '
i
- Weight of Emuistfler added to sample
- gms (7; i
Initial pH of sample: (6)
, t I
)
j !!. SaWPLE SOLIDIFICATION i l
! Weight of Ca(OH)2 added to sample to raise { [
- the pH 2 11.5: gms (9) t J i Final pH of sample: (10) l 1
l Weight of Portland Type 1 cement added to sarple: 9ms (11) lk; Final Sample Volune: el (12) l Test Solidification Performed By:
^ '
j Naee Date time 1 1 '
)
E9-1 1372c I
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8 Nuolear T I.i "u*"
.: Ocerattna Procedure 1104-28!
Title Revision No.
Weste solldtficatten Process Control Program 9 ATTACHMENT 9 (Cont'd) Page 2 of 2 CLASS A STt.BLE, CLASS B AND C TEST SOLIO!FICATION DATA SHEET FOR BEAD RESIN
!!!.}AMPLEINSPECTION Sample cured for:
Nours Cured Tirp. Cured verified 6y Date Sarple contains No f ree Liquid":
Verified By Da.e Sample "Resists Penetration":
~
Verifted By Date Additional tatches solidified based on this satple solidification:
t.ine r Waste Liner Waste Liner Haste No. Vol. Date No. Vol. Date No. Vol. Date
- 2. 5. 8,
- 3. 6. 9.
- 4. 7. 10.
_ IV, IND(PEN 0(NT VERIFICATION Bf GPUN MANAGEM(Nt Test Sample Meets Acceptance Criteria (Section 10) have / Date / li r.e Test Solidification Data Sheets (Calculations) Revle.ed hate / Date / Time E9-2 1372c
r ..
7 Nuclear Tu!-i Ooeratino Procedure 1104-281 litle Revision No.
Waste Solidification Process Control Program 8
ATTACNMENT 10 Page i of 3 SOLIDIFICATION CALCULATION SNEET FOR SEAD RES!N Liner Type to be used: '
!!. PAReETERS FOR FULL SCALE SOLIDIFICATION ,
Quantity of EC-3:
(3) 6.3 . ( ) x 6.) . ga!/ (13)
(2) ( ) ft3 of waste Quantity of Water: ,
(4) 7.48 . ( ) h 7.48 ~ '~ g 1/ (14)
(2f ( ) f 3 of waste Quantity of Anti-Foam Agent:
(5) 7.48 . ( ) 7.48 gall (15)
(2) ( ) ft3 of waste i Quantity of Emuistfier:
l (7) 7.48 . ( ) 7.48 gall (16)
(2) ( ) ft3 of waste Quantity of Calcium Hydroxide Ca(OH)2:
(9) 62.43 . ( ) 62.43 Ibs/ (17)
(2) ( ) ft3 of waste l Quantity of Portland Type 1 Cement:
(11) 62.43 . ( ): 62.43 Ibl/ (18) o (2) ( ) ftJ of waste l !!. QUANT!T!ES TO BE ADDED FOR FULL SCALE SOLIDIFICATION 1
- Waste Volume of to be So'idifiedI 3
1 ft3 (19) l Quantity of EC-3:
(19) x (13) = ( ) ( ). gal (20) ;
r i
E10 1 1372:
t I
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MNuclear THI-1 1
Operatino Procedure 1104-281 Title Revision No.
Haste Solidification Process Control Program 9 ATTACHMENT 10 (Cont'd) Page 2 of 3 SOLIDIFICATION CALCULATION SHEET FOR BEAD RESIN Quantity of Water:
(19) x (14) - ( )x( )= gal (21)
Qdutity of Anti-Foam Agent:
(19) x (13) - ( )x( ) - gal (22)
Quantity of Emulsifier:
(19) x (16) - ( ) x( ) - gal (23)
Quantity of Calcium Hydroxide Ca(OH)2:
(19) x (17) - ( ) x( )- lbs (24)
(24) + (100) - ( )+ 100 - bags 2 Quantity of Portland iype Cement:
(19) x (18) -( ) x( ) - Ibs (25)
(25) + (94) - ( ) + 94 - bags 2 I
The volume of dewatered Dead resin to be solidified cannot exceed the maximum treated waste volume listed on the Class A Stable, Class B and C Test Solidification Data Sheet for Bead Resin.
2 Round up to the nearest whole bag.
3 Reduce the quantity of waste in liner by 1 ft3 for every 10 gallons of anti-foam agent plus emulsifier added to liner.
!!!. INDEPENDENT VERIFICATION Bf GPUN MANAGEMENT SOLIDIFICATION CALCULATION SHEETS REVIEHED Name / Date / Time E10-2 1372c
. Eb I THI-1
. Operatino Procedure 1104-28I Title Revision No.
Haste Solidification Process Control Program 8 ATTACHMENT 10 (Cont'd) Page 3 of 3 SOLIDIFICATION DATA TABLES FOR BEAD RESIN HN-100 HN-600 HN-600 LVMU HN-200 HU LVMVGS Usable Liner 148.8 59.4 64.0 61.7 Volume (cu. ft.)
Max. Dewatered 120.0 47.9 51.6 49.8 Waste Volume (cu. ft.)
Max. Solidified 148.8 59.4 64.1 61.7 Waste Volume (cu. ft.)
Max. Rad. Level 12 800 100 100 R/hr Contact M,1. Recommended (l)
Haste Vol (ft3) 106.9 46.0 -
47.3 Hin Solidified (l) 132.6 57.0 -
58.6 (1) Grout will have to be added to the HN600 HU to increase the solidified waste volume to meet the 157. maximum void space criteria for shipment to Barnwell.
E10-3 1372c
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Nuclear TxI-i Operating Procedure s, 1104-281 Title Revision No.
Haste 'olidification Process Control Program 7 ATTACHMENT 11 Page 1 of 1
- TEST SOLIDIFICATION USING HESTINGHOUSE - HITTHAN PROCEDURE Waste to be Processed:
Westinghouse - Hittman Procedure No.__
Procedure - Title Current Revision Justification to use this alternate test procedure:
Liner Type __
Haste Class Balance Cal Info.
CMTE No.
Serial No.
Cal. Due Date Approved By Eng. Review By NOTE: Form should be attached to valid Hestinghouse - Hittman Procedure used for the Test Solidification E11-1 1372c
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