Text

Rev 0 to EMF-1946, Modular Extraction/Recovery Facility (Merf):Hazard Analysis
	ML20141C070
Person / Time
Site:	Framatome ANP Richland
Issue date:	04/29/1997
From:	Koegler S, Salisbury H, Ward G; SIEMENS POWER CORP. (FORMERLY SIEMENS NUCLEAR POWER
To:	;
Shared Package
ML20141C068	List: ML20141C064; ML20141C070;
References
	EMF-1946, EMF-1946-R, EMF-1946-R00, NUDOCS 9705160131
	Download: ML20141C070 (39)
	v • d • e

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SIEMENS EMF-1946 i

Revision O Modular Extraction / Recovery Facility (MERF):

Hazard Analysis April 1997 K

257

(.j) c eon Siemens Power Corporation kj Nuclear Division

Siemens Power Corporation - Nuclear Division EMF-1946 Revision O Issue Date 4/30/97 l

Modular Extraction / Recovery Facility (MERF): Hazards Analysis 4!N/h7 Prepared:

A d Mh/

Hazard Analysis Review Tearryfor MERF Da(e

/

M. B. Salisbury, Team LeaderV Waste Management Engineering W&b 4M'f7 Concurred:

S. 5. Koegler, Ma@er Date i

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Waste Management Engineering Approved: d N

77 G. pard, fianageF Date Mahufacturing Engineering l

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l EMF 1946 i

R::visi:n 0

- Modular Extraction / Recovery Facility (MERF): Hazards Analysis Pagei l

l Contents l

1..

Introduction......................................................................................................1 i

2.

Proc e s s D e s cripti o n.......................................................................................... 1 2.1 S orti ng /Shre ddi ng................................................................................... 1

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2.1.1 Pr efilte r M e d ia............................................................................ 1 2.1.2-Drummed H EPA M ed la................................................................ 2 l

2.1.3 Wh ole H EPA Fil t e r s..................................................................... 2 2.1.4 We t W a st e s............................................................................... 2 2.1.5 Alcohol-Cont a min ated Rag s......................................................... 2 -

l

2.2-Le a c hi n g /Ex tra et io n................................................................................. 2 2.3 Pr eci p it a ti on/Filtr atio n.............................................................................. 3 2.4 Li q u i d W a s t e.......................................................................................... 3 2.5 Solid Wa s te D i s po s a1............................................................................... 4 2.6 A s s a y Ope r a t io n s.................................................................................... 4 2.7 Of f g a s Tr e a t m e nt.................................................................................... 5 2.8 Pr o d u c t S t o r a g e...................................................................................... 5 2.9 C he mi c al S t o r a g e.................................................................................... 5 2.10 N it ric A cid S u pply S y st em....................................................................... 6 2.11 C au stic Supply System............................................................................ 6 i

2.12 H ydrog e n Per oxide Supply Syst em............................................................ 7 2.13 Propa ne Fired Ste am Boiler....................................................................... 7 i

3.

C hemic al H andling And Pre c autio n s........................................ :........................... 7 i

3.1 Nit ri c A cid ( 6 8 % ).................................................................................... 7 3.2 Sodiu m H yd ro xid e ( 5 0 % )........................................................................., 8 3.3 H yd rog e n Pe r o x id e ( 3 0 % )........................................................................ 8 4.

S a f ety Pre c a ut i o n s............................................................................................ 8 1

5.

R ad i ati o n Pr ot e ct i o n.......................................................................................... 9 t

6.

Pers onal Prot ectiv e Equipment............................................................................ 9 i

t 7.

Hazards Analysis: A Wh at-I f A p pr o a c h............................................................. 10 1

Attachment A Hazards Analysis For Modular Extraction /h.,scry Faci!ity.....................11

' Attachment E Material Safety Data Sheet 68% Nitric Acid.........................................14 Attachment C Material Safety Data Sheet 50% Sodium Hydroxide..............................18 Attachment D Material Safety Data Sheet 30% Hydrogen Peroxide.............................. 26 i

Attachment E Saf ety Equipment General Arrangement............................................... 34 l

1 Siemens Power Corporation Nuclear Division t

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' EMF-1946 R:visi:n O v

Modular Extraction / Recovery Facility (MERF): Hazards Analysis Pageii l

i Distribution Controlled Distribution Richland B. F. -Bentley,'_45.

W.D. Black, J. E. Edgar,16

' E.; L ' Foster,11 l

.G. L.' Fring,14 I

' J. W. Helton,14 S. S. Koegler,19 l

S. R.. Lockhaven,16 l

L. J. Maas,16 o

t

.A.' J. Mix, 45 D. L. Pedersen, 28 i

'J. H. Phillips,45 j

t T. C. Probasco,11 I

L G. Stephens, 45 i

~ M. S. Stricker,19 R. E. Vaughan,11 i

.G. N. Ward, 27 I

1 File.

r Seemens Power Corporation. Nuclear Division f

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1 EMF-1946 R2visisn 0 -

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Modular Extraction / Recovery Facility (MERF):' Hazards' Analysis Pege lii -

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i Hazards Analysis Review Team Members:

E. '. L. Foster '

Radiological Safety:

G., L~ Fring -

Plant Engineering -

i S. R. Lockhaven -

Industrial Hygienist Lead Technician A;' J. Mix

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4 Plant Maintenance Engineering '

D. L. - Pedersen' J.' H. Phillips Operations Supervisor i

T. ' C. Probasco -

Safety Manager Waste Management Engineering _

M. S. Stricker L. D. Weaver Waste Management Engineenng l

Recodyne l

W. D. Black i

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f Siemens Power Corporation - Nuclear Division

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EMF-1946 R2 vision O Modular Extraction / Recovery Facility (MERF): ' Hazards Analysis Page 1

1. Introduction This analysis discusses hazards of the Modular Extraction / Recovery Facility (MERF) to be located north of the Lagoon Uranium Recovery / Solids Processing Facility (LUR/SPF). Each cr:a of the piocess is described and includes measures that have been taken to protect the worker and the environment. The hazards of the chemicals that are used in this process cra described and Material Safety Data Sheets (MSDSs) attached for reference. A "What-If Analysis" will be used to examine the major aspects of the facility's design and operation (o.g., material handling, operating procedures, work practices, waste disposal, etc.).

2. Process Description A temporary, modular, processing facility will be constructed offsite and transported for installation at Siemens Power Corporation (SPC) to recover uranium from SPC's backlog of w:ste (wet wastes, prefilters alcohol-contaminated rags and HEPA filters). The uranium r: covered in this process will be processed through solvent extraction. The solid waste will be incinerated at the Solid Waste Uranium Recovery (SWUR) facility or shipped to Adva iced Technology Group (ATG) for supercompaction and final waste packaging for disposal at US Ecology. Liquid wastes will be discharged to Lagoon 3. At the conclusion cf this campaign, the facility will be transported to other sites to process waste. It will r: turn to SPC to process accumulated waste as needed. This facility will be located on the southeast corner of the waste pad (adjacent to LUR/SPF).

The following activities will be conducted in the MERF: sorting / shredding, j

1::ching/ extraction, precipitation / filtration, liquid and solid waste management, product and chemical storage, assay operations and offgas treatment. This discussion also includes a d:scription of the nitric acid supply system, the caustic supply system, the hydrogen

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p;roxide supply system and the propane fired steam boiler.

2.1 Sorting / Shredding This process utilizes a sorting operation to separate waste materials for uranium recovery, direct disposal or incineration.

2.1.1Prefilter Media The prefilter drums contain an average of 12 filters per drum. The POG prefilters, characterized by a heavy loading of white ammonium fluoride solids and low uranium content, will be sorted out and shipped directly to Envirocare for disposal. Only the non-POG prefilters will be processed for uranium recovery. The prefilter drums are brought into the sorting glove box and their contents are removed. The prefilters are then sorted into the following waste streams:

poly bags non-POG pre-filters, POG prefilters, and miscellaneous.

Siemens Power Corporation Nuclear Division

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EMF-1946 f

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Rivision 0 -

Modsler Extraction / Recovery Facility iMERF): Hazards Analysis '

Page 2 2.1.2 Drummed HEPA Media l

- HEPA filters that have already been punched from their frames will be repackaged into j

- shredder bins for shredding.1 The shredded media will then be processed through the j

washer / extractor for uranium recovery processing.

l 2.1.3Whole HEPA Filters-Whole HEPA filters _ will be brought into the HEPA punch glove box where the media will be removed from the plywood frame. The HEPA filter generates the following waste streams: wire 1

cupport screens, plywood frames, the media, the poly liner, and in some cases a cardboard i

box. The HEPA media will be shredded and processed through the washer / extractor for j

uranium recovery processing. The washed media will then be shipped to ATG for 1

i supercompaction and final waste packaging for burial at US Ecology. The plywood frames and cardboard boxes will be shredded and incinerated at SWUR.. The poly liners will be incinerated.

1

,The wire support screens will be packaged for shipment to ATG/US Ecology.

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.2.1.4 Wet Wastes 1

The wet waste drums will likely contain free liquid due to the disposal of rags and mopheads -

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- soaked with nitric acid. In addition, liquid organic wastes such as lubricating oils, gresses, tri-butyl phosphate and dodecane are expected to be present in some of the drums.

The bulk of the wet waste will be repackaged directly into laundry bay ior uranium recovery 4

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. processing. Filter cartridges ( i.e., UNH and grinder filters) will be processed through a thredder in the glovebox to facilitate' uranium recovery.

2.1.5 Alcohol-Contaminated Raas l

Alcohol rags contain up to 50%' isopropyl alcohol and are packaged in 30-gallon drums. This 4

w:ste stream will be repackaged directly into laundry bags for uranium recovery processing.

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' 2.2LeecMngMxtracatan 1

- Uranium leaching / extraction and solid waste rinsing and dewatering will take place in a 450-Ib.

l-capacity centrifugal washer / extractor. Further dewatering will occur in an 85,000 pound -

compactor. The actual number of bags washed during each cycle will depend upon the weight cf each bag.

Dudng the wash cycle, the uranium in the v'aste will be leached using 3M HNO at 60-80*C for 3

cpproximately 30 minutes. The leach cycle will be followed by a UNH extraction (spin) cycle to

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- remove free liquids. The UNH solution is discharged from the washer into a strainer _

i screen / overflow box that is designed to contain the ' entire liquid contents of the washer in the cvent of a dump valve failure. The screen in the overflow box restricts the down stream flow of solids that may escape from the washer in the unlikely event of a laundry bag failure.-

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4 Siemens Power Corporation - Nuclear Division i

1 (N BUTYL ACETATE =1)

Solubility In Waters COMPLETE Percent Volatiles By Volumes 100 pH

<1 Corrosion Rate (IPY): IBGGIONN 2.............................

Fire and Explosion Matard Data Flash Points NONE Extinguishing Media WATER SPRAY, DRY CEEMICAL.

Special Fire Fighting Procs NEAR FIRE FIMTING PROTECTIVE EQtTIPMENT AND A PULL FACED SCRA. FI MT FIRE AS FAR A DISTANCE AS POSSISLE. COOL FIRE EKPOSED CONTAINERS WITN MATER SPRAY.

tkausual Fire And Exp1 Easrds: NITRIC ACID MAY YIELD OEYGEN NEEN REATED, WRICE WILL INCREASE TEE RATE OF BURNING OF COMBUSTIBLE MATERIAL & MAY RESULT IN IGNITICII, VIOLENT COSUSTION OR EXPLBN Reactivity Data

..e Stability: MS Cood To Avoid (Stability): EETRBIE REAT.

Materials To Avoid: COMBUSTIRLE MkTERIALS, BASES, METALLIC PONDERS, i

EYDROGEN SULFIDE, CARRIDES, atr e ra, REACTS WITN WATER TO PRODUCE REAT.

Essardous Decoup Products: NITROGEN DEIDES.

Essardous Poly Occurs No Conditions To Avoid (Poly): NtFF APPLICABLE Realth Masard Data

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ID50-LC50 Mixtures TLV IS 2 PPM TNkg4 PPM STEL Route Of Entry - Inhalation: YES Route of Entry - Skin YES Route of Entry - Impostion: YES Nealth Ras Acute And Chronic: **EIM LY CORROSIVE ** EYES:MAY ChUSE DAMAGE OR BLINDIntSS. SKIN MkY CADSE MENIckL BURNS. INGEST:MkY CAUSE GI TRACT MkY CADBE TEETR TO DISC 014Nt.

Carcinogenicity - NTP: ND

-Carciaopenicity - IARC: NO j

Carciaopenicity - OSEk: NO Explanation Carcinogenicity: TERRE ARE NO INGREDIENTS ABOVE 0.1% NEICN ARE j

' IDEIrrIFIED AS CARCINOCRENS SY NTP,IARC OR OSRA.

Signs / Symptoms Of Ovessays SKIN YELI4di DISC 01ARATIC38 WI191 BURIES, POSSIBLE DEEP ULCERAT%CIIS.INEALa >200 PPM MkY CADBE SEVERE LIEIG DAMAGE, POSSIBLY

'l DEATE.

Med Coed Aggravated By Exp INDIVIDGhLS WITE A IISTOItY OF EYE, SKIN AMD l

RESPIRATORY DISCADERS MkY BE AT INCREASED RISK FROM EEPOSURE.

j EmerWency/First Aid Procs ETES:PLUBE Wits PLENTY OF MATER FOR AT LEAST 15 i

MINUTES.IF IRRITATICII PERSISTS.SEE DOCTOR. SKIN MASII WITE MILD SOAP AIID MkTER WIIILE RBIOVING OCBETAMINkTED CLOTEZIIU AIID SEDES. INEkIATION:RBIOVE VICTIM TO FRESM AIR.GIVE QEYGml/CPR IF NEEDED.SEE DOCTUR. INGESTION D0 NOT IIIDUCE VOMIT.SEE DOCTUR IISIEDIATELY.IF CGIISCIOUS,GIVE 1-3 GLASSES OF WATER OR MILE.

Precautions for Safe Bandling and Use Steps If Matl Released / Spills RBIOVE PERSCIEEEL. ELIMIMk1E IntITIcel SOURCES. VENTIL&11 AREA. WEAR PROTECTIVE CLONING AIID BQUIPMEllT. HEUTRALIEE VERY ChDTIOUBLY. SQhK UP WI11t A NCEE-COISUBTIRLE, INERT ABSCRSAllTgPLhCE IN AN APPROPRIATE DISPOSAL CONTAINER AND COVER.

Neutralising Agent SLAEED LIIS, 80DIt36 BICARBOIIATE OR CRUBEED LINES 1tHE.

Maste Disposal Methods CONTACT YOUR LOCAL ElfVIRGIBMrrAL OFFICER. DISPOSE OF III ACCOItDhpCE WITil ALL FEDERAL, STATE AIID 14 CAL REGULATICIIS. EPA M *NW" MkBTE IRBSER D002.

Precautions.ya.dting/ Storing: STORE IN COOL, DRY, WELL VENTILkTED AREA.

PROT 9CT PROM PEYS!ckL DhMh5B, EEkT, IstITION SCENtCES AND INCOMPATIBLE MkTmmut2 REEP Ct3rTAIIIERS CLOSED.

Other Precauticas: AVOID EEPOSING PRODUCT TO DIRECT StBILIMT AVOID ETE AID SKIN COIFFACT. DO JEDT BREk15E VAPOIts.

Beamens Power Corporation - Nuclear Di

EMF-1946

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Rzvision O L odulir Extraction / Recovery Facility (MERF): Hazards Analysis Page 16 M

Att:chment B Material Safety Data Sheet 68% Nitric Acid (Continued)

Control Measures Respiratory Protection: WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR A NOISH/

MSHA APPROVED RESPIRATOR FOR ACID GAS, DEPENDING ON THE AIRBORN CONCENTRATION.

Ventilation: 14 CAL EKHAUST VENTILATION TO KEEP E7POSURE LEVELS BELOW PEL.

Protective Gloves: NATURAL RUBBER, NEOPRENE OR PVC GLOVES.

Eye Protection SPLASH-PROOF GOGGLES AND FACE SHIELD.

-Other Protective Equipment PROTECTIVE CLOWIF.L AS REQUIRED TO MINIMIZE EXPOSURE FROM PROIANGED OR REPEATED CONTACT. EYE BATH AND SAFETY SHOWER.

Work Hygienic Practices: NASH THOROUGHLY AFTER HANDLING AND BEFORE EATING.

LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.

Suppl. Safety & Health Data: NONE.

Transportation Data Trans Data Review Date:

94009 DOT PSN Coder KFD DOT Proper Shipping Names NITRIC ACID DOT Class 6 8 DOT ID Number: UN2031 t

DOT Pack Group: II

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DOT Label CORROSIVE

.IMO PSN Code: KPF IMO Proper Shipping Names NITRIC ACID IMO Regulations Page Number: 8195 IMO UN Numbers 2031 IMO IBI Class: 8 IMO subsidiary Risk Label:

IATA PSN Code NER IATA UN ID Number: 1760 IATA Proper Shipping Naine: CORROSIVE LIQUID, N.O.S.

IATA IBf Class: 8 IATA Label CORROSIVE AFI PSN Codes RWF AFI Syunbols: 0 AFI Prop. Shipping Names NITRIC ACID AFI Class: 8 AFI ID Number UN2031 AFI Pack Groups II AFI Label: CORROSIVE AFI Basic Pac Ref: 12-14 I
pe4AC codes NR N.O.S. Shipping Name: NITRIC ACID 55-684 Additional Trans Data: RQ IS 1000 LBS OR 85 GALIANS.
Disposal Data Label Data tabel Required: YES Technical Review Date: 09JAN95 MFR Label Number IntENOWN Label Status: F Couenon Names NITRIC ACID,55-68%
Signal Word DANGERI Acute Mealth Masard-Severe X Contact Hasard Severe X Fire Mascard-Slight: K Reactivity Masard-Slights X Special Essard Precautions: **HIGELY CORROSIVE" EYES MAY CAUSE DAMAGE OR RLINDNESS. SKIN MAY CAUSE CRIMICAL BURNS. INGEST MAY CAUSE GI TRACT j'
MAY CAUSE TEEN TO DISCOLOR. FIRST AID: EYES FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.IF IRRITATION PERSISTS.SEE DOCTOR. SKIN: WASH WITH MILD DO NOT INDUCE VOMIT.SEE DOCTOR IpetEDIATELY.IF CONSCIOUS,GIVE 1-3 GLASSES OF WATER cot MILK.
Protect Eye: Y l
Biomens Power Corporation Nuclear Division -
EMF-1946 Rovisisn O Modular Extraction / Recovery Facility (MERF): Hazards Analysis Page 17 Material Safety Data Sheet 68% Nitric Acid (Continued)
. Protect Skin: Y Label Names CHEMICAL INTERCHANGE Label Street: 2932 SOtml BRENTWOOD,
Label city: ST. LOUIS Label state: MO.
Label Zip Code: 63144
~ Label Country: US Label Emergency Number: 000-424-93 00 (CHEMTREC)
URL for this mods http://siri.org. If you wish to change, add to, or delete information in this archive please sent updates to danesiri.org.
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Seemens Power Corporation - Nuclear Division
EMF 1946 R3 vision 0 (Modul:t Extraction / Recovery Facility (MERF): Hazards Analysis Page 18 Attachment C Material Safety Data Sheet 50% Sodium Hydroxide OMS /MDL Record Numter : OMS 21300 MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MDL informehon Systems inc.
FOR EMERGENCY SOURCE INFORMATION 14600 Celehne Street CONTACT:1415 386-2000 in USA San Leandro CA 94577 1400436 0064 (Toll Free)or 14104051313 CAS Regelry Number: 1310 73 2 RTECS Number
WS4000000 i
UN Number
UN 1823 SUSSTANCE: SOOlUM HYDROXIDE TRADE NAME/ SYNONYM (S) CAUSTIC f.ODA; SODA LYE; LYE; WHITE CAUSTIC; CAUSTIC SODA, SEAD; CAUSTIC SODA DRY: CAUSTIC SODA FLAKE; CAUSTIC SODA.
GRANULAR: CAUSTIC SODA. SOLID; SODluM HYDRATE; SODIUM HYDROXfDE (NA(OH)t i
SODIUM HYDROXIDE. FLAKE; SODIUM HYDROXIDE. DRY: SODIUM HYDROXIDE. SOLID, ASCARfTE; SOOlUM HYDROXIOE DRY SOLID. FLAKE. SEAD OR GRANULAR; FOTOFOIL-ETCHANT (nGLLER DIAL); UN 1823; STCC 4936235; NoOH 1
CHEMICAL FAMILY: Inorganic bees SunNARY SHEET AVARASLE:Y CREATION DATE:19841217 REMSED:19000123 CHEM CHANGE DATE: 19000123 j
SECTION 2. COMPOSITION INFORMATIONONINGREDIENTS
)
1) Component Substonos' SOOlUM HYDROXIDE Camponent Percent 100 %
CAS Registry Number: 1310 73 2 CONTAMINANTS: NOlE l
SECTION 3 - HAZARDS IDENTIFICATION NFPA Rehngs (sosio 0 4): Heath =3 Fim=0 ReactMiy=1 EMERGENCY OVERVIEW DESCRIPTION Odortees, whits or oN wNes hygroecopic sold.
STATEMENT OF HAZARDS Hermhst ll soebowed Causes respiratory tract, eWn and eye bums and severe bums to mucous membranos PRECAUTIONARY STATEMENTS:
Do not bresmo dust. Do not get in eyes, on skin, or on delNng. Do not abow water to get in container.
Keep container behey atooed. Weeh thoroughly stor handbng. Use only wAh odequate wenWeton Hende wah cauton.
POTENTIAL HEALTH EFFECTS INHALATION:
SHORT TERM EFFECTS: May cause irmamon, poseedy severe Ademonel e9ects may include dNhouky breelhing, lung congeston and shock.
LONG TERM EFFECTS: May cause edleets es in short term esposure Addluonal eHects may include eenhoe and lung ogmats.
SIGN CONTACT:
SHORT TERM EFFECTS: May cause bums.
LONG TERM EFFECTS: Some essets se short term esposure 1
1 Seemone Power Corporation. Nuclear Division
EMF-1946
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R: vision 0 ~
Modul:r Extraction / Recovery Facility (MERF): Hazards Analysis Page 19 betrchment C Material Safety Data Sheet 50% Sodium Hydroxide (Continued)
EYE CONTACT:
SHORT TERM EFFECTS: May cause bums. Additional eflects may include blindness.
LONG TERM EFFECTS: Same aflects as short term exposure.
INGESTION:
SHORT TERM EFFECTS: May be harmfulif swallowed. May cause bums. Additional effects may include derrhee, stomach pain, bloody vomit. Nood in the stool, shock, come and heart failure.
LONG TERM EF FECTS: Same effects as short term exposure CARCINOGEN STATUS:
OSHA: N NTP: N.
IARC: N Date: 19801020 SECTION 4. FIRST AlD MEASURES l
INHALATION:
FIRST AID Remove from exposure area to fresh airimmedetely Perform artificiel respiration if necessary. Mesntom airway, blood pressure and reepwebon. Keep warm and at rest. Treat symptomencelly and supportively. Get medmet egentenimmodately QueRAed medicalpersonnelshould consider adminstenna oxygen SKIN CONTACT:
FIRST AID. Remove conismmated clothing and shoes immediately. Weeh with soap or mHd detergent and large amounts of ester unel no evidence of chemical remems (at least 15-20 nunutes). If bums occur, proceed with the fotowing: Cover allected eres securely with sterne, dry,looedtung dressing. Treet symptomsecolly and m-;-:-t;d,. Get medeel suonbon immediately.
EYE CONTACT:
FIRST AfD.Weeh eyes immediately wNh large amounts of water, oocesionouy lifting upper and lower
[
lids, untN no evidence of chemical remems (at least 15 20 minutes). Conenue irrtgeeng with ncwmel sonne until the pH has retumed to normel(30 60 minutes). Cover with sterile bandages. Get medical aseneon tr.nnedstely.
INGESTION:
q FIRST AfD. Do not use geeste lovege or emesis. DEute the abeN by giving Water or mHk to drink immediately and allowing vomlbne to occur. As soon as poselble, have queNAed medical personnel do esophagoscopy and intgote injured areas wth 1% ocate acid undt the eteN is completely neutraltred (Dreisbach. Handbook of Poisonmg.11th Edibon). Get medmel seendon immodately.
NOTE TO PHYSICIAN ANTIDOTE.
i No speelRc entidote. Treet symptome6ceny and ;; -2;Q.
l SECTION 5 FIRE FIGHTING MEASURES i
FIRE AND EXPLOSION HAZARD.
Neghgible fire hetard when exposed to heet or Game.
EXTINGUISHING MEDIA:
Dry chemmel, carbon dioxide, water oprey or regular toom (1993 Emergency Response hwn=8ww*
r RSPA P 8400.6).
For larger tres, use water oprey, tog or regular foam (1993 Emergency Response heta*ww* RSPA P r
5000.6).
FIREFIGHTING:
Move container trem tre eres if you con do it wuhout rtek. Apply coolmg water to eldes of containers that are esposed to temos unen was oRor tre is out Stoy away from ends of tanks (1993 Emergency Response theenaww*, RSPA P 5000.6, Guide Peps 80).
use agent numeNe for type of are. use waterin nooding guenenes as sog.
Apply water tem os ter a distence as poselbie HAZARDOUS COhSUSTION PRODUCTS-Thermal decongmenion may release tonic fumes of sodium oxide.
Beemens Power Corporation Nuclear Division
EMF-1946 '
Rsvision D f Modular Extraction / Recovery Facility (MERF): Hazards Analysis Page 20 Attachment C Material Safety Data Sheet 50% Sodiurn Hydroxide (Continued)
SECTION 6 '- ACCIDENTAL RELEASE MEASURES OCCUPATIONAL SPILL:
Do not touch spilled meterlet Stop leak if you can do it without risk. For small spins, take up with sand or other absorbent meterial and place into contakers for later disposal For ernal! dry spes, with cioen shovel place malenalinto clean, dry contamer and cover, Move containers from spin area. For larger spes, dike for sheed of spill for later deposal. Keep unnecessary people away. Isolate hazard area and deny entry.
Reportable Ouanety (RO): 1000 pounds The Superfund Amendments and Resuthortzabon Act (SARA)Seccon 304 requires that a reisese equal to or greater than the reportable quantity for this substance be L.. ' _ i reported to the local omorgency planning commises and the state emergency response commission (40 CFR 355.40). If the rolesse of this substance is reportable under CERCLA Secton 103, the National Response Center must be noelled immediately at (800) 424 8802 or (202) 426-2675 in the metropohten Washngton, D.C. area (40 CFR 302.6).
J SOIL SPILL:
Dig holdmg ares such as lagoon, pond or pit for containment.
Use protochve cover such as a plante sheet to prevent meterial from desolving in fire extmguishing water or rain.
WATER SPILL:
Add suitable agent to neutraltre spined motorial to pH-7.
SECTION 7 - HANDLING AND STORAGE Observe all federal, state and local regulomons when stonng or deposing of this substance Store in a cool, dry, wes venmeted locomon Separate from acus, water, metais..... ' _ ;remme and property thopose of any speed motonal (NFPA 49. Hezerdous Chemicais Dets,1991)
Store away from incompedble substances SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS:
SODIUM HYDROXIDE:
i 2 mphn3 OSHA TWA 2 mphn3 OSHA ceihn0 (vacated by 58 FR 36338 June 30,1993) 2 m0hn3 ACGlH coding 2 mg/m3 NIOSH recommended colknD.
2 mphn3 DFG MAK TWA (total dust);
4 mphn3 DFG MAK 5 minute peak, momentary vetus,8 mmes/ shift i
Measurement method Paraculate Ilher; hydroditoric acid; titrabon;
)
(NIOSH Vol. lil # 7401, Alkahne Dusts).
1000 pounds CERCLA Sedian 103 Reportsbie Quentity VENTILATION:
Provide local exhaust ventRetion system to meet putdished exposure limits.
EYE PROTECTION:
Employee must weer, 34 or dust-vosistent esisty goggles and a faceshield to prevent contact wah this outetence Emergency weehlocabos Where there is any possibety that an employee's eyes and/or skin may be
==pa==d to this subelence, Wie employer should provide an eye wash fountam and quick crench shower witiin Wie immediate work ares for emergency use.
CLOTHING:
Employee must weer appropriate protochve (impervious) clothing and equipment to prevent any poenibuty of skin contact wah this sutemmco GLOVES:
Siemens Power Corporation - Nuclear Diviolon
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EMF-1946 Rsvision O Modul*r Extraction / Recovery Facility (MERF): Hazards Analysis Page 21 Att:chment C Materiel Safety Data Sheet 50% Sodium Hydroxide (Continued)
Employee must wear appropnete protectwo gioves to prevent contact with this substance.
RESPIRATOR:
The following respirators and mexwnum use concentrations are recommendsbons by the U.S.
Department of Hea!!b and Human Serwces, NIOSH Pocket Guide to Chermcel Hazards: NIOSH cntena documents or by the U.S. Department of Labor,29 CFR 1910 Subpart Z. The specine resprotor selected must be based on contommebon levels found in the work place, must not exceed the worldng lwnits of the resprotor and be jointly approved by the NationalInstnute for twaaah~ml Safety and Health and the Mine Safety and Health Admrustration (NiOSH-MSHA).
SODIUM HYDROXIDE:
10 mg/m3-Any supphed-er respirator operated in a conimuous flow mode. Any air-purifyng ful fv respirator with a high ofRciency perbculate filter. Any powered, air-purtfying respirato with a dust and mist filter, Any self<ontained breathmg apparatus with a full fecepiece. Any supphed air resprotor with a full facopiece Escape Any air-purifying, fun facepece respirator with a high ofRcency perbculate filter. Any appropriate escape type, self-contamed breathmg appe stus.
FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS:
Any self contained breathing apparatus thct has a full eral aea and is operated in a pressure demand or d
j_
other posihve pressure mode. Any supphed-air respirator that has a full focopiece and is operated in a pressure demand or other ;-- "~;; A z n mode in combineition with an auxibery self contamed t
breathing apparatus operated in pressunHiemand or other i- "';; F_ :7 mode.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES DESCRIPTION: Odorless, white or off white hygroscope solid.
MOLECULAR WEIGHT: 40.00 MOLECULAR FORMULA: NA-O H PHYSICAL STATE (8,L.G): S BOILING POINT: 2534 F (13g0 C)
MELTING POINT: 604 F (318 C)
SPECIFIC GRAVITY: 2.130 pH: 14 8 5% solukon
/APOR PRESSURE: 100 mmHg @ 1111 C WATER SOLUBILITY:solubio SOLVENT SOLUSILITY: Soluble in alcohol, glycerot; insoluble in acetone, other.
SECTION 10 - STABILITY AND REACTIVITY REACTIVITY:
Reacts exothermicety with water.
CONDITIONS TO AVOID:
May bum but does not ignite readily. Flammable, poisornus gases may accumulate in tanks and ' topper cars. May ignite combustibles (wood, paper, oil, etc.).
INCOMPATIBILITIES:
SODIUM HYDROXIDE:
j ACETALDEHYDE: May result in vinient polymertzebon.
i ACETIC ACID: M6 ming in domed containerincrosses temperature and pressure l
ACETIC ANHYDRIDE: Mixing in 9 cdosed container increases temperature and pressure ACIDS: May react violently, l
ACROLEIN: May result in an extremely wolent polymertzabon ACRYLONITRILE: May cause vlomnt g,.nT--r..
ALLYL ALCOHOL + BENZENE SULFONYL CHLORIDE: Possible awplaawm hazard ALLYL CHLORIDE: Hydrolytes ALUMINUM: Vigorous reachon.
ALUMINUM, ARSENICTRIOXIDE. SODIUM ARSENATE:Maygenerate flammable hydrogen gas.
AMMONIA + SILVER NITRATE: Precipitehon of explosive silver nitt:le may occur.
AMMONIUM SALTS: May react violently evoMng ammonie gas.
BENZEPE 1,4 DIOL: Exothemuc reachon Siemens Power Corporation. Nuclear Division
p EMF-1946 Rsvision 0 Mrdul r Extraction / Recovery Facility (MERF): Hazards Analysis Page 22
' Attachment C Material Safety Data Shost 50% Sodium Hydroxide (Continued)
N,N*-BIS (TRINITROETHYL) UREA: Formabon of explosNe compound.
BROIANE: Possible explosion if not stirred conbnously.
CHLORINE TRIFLUORIDE: May cause violent reachon.
CHLOROFORM + METHYL ALCOHOL: Exotherne reachon.
CHLOROHYDRIN: Mixing in a closed contamer causes an increase in temperature and pressure 4-CHLORO 2-METHYLPHENOL: Possible ignition.
CHLORONITROTOLUENES: Possible ="r'"M CHl.OROPICRIN: May cause violent reachen.
CHLOROSULFONIC ACID: Mixing in a cioned contemer causes an increase in temperature and pressure.
CINNAMALDEHYDE: Exothermic reaction.
COATINGS: May be acacked COPPER: Solucons may slowly cortade CYANOGEN AZlDE: May form todnam 5-ezidototrozolide, which is explosive if isolated 2,2-DICHLORO 3,3 D18ETHYLBUTANE: Hazardous reaction 1,2 DICHLOROETHYLENE: May form si.; :: -'y flammable monochloroecetylene D180RANE AND OCTANAL OXIME: Exothemuc reaction ETHYLENE CYANOHYDRik Madng in a closed container causes an increase in temperature and preneurs
- FLAMMABLE LIOUIDS: Fire and==f*=% hazard
- GLYCOLS: May cause exothermic decompositon with evoluton of hydrogen gas.
GLYOXAL: Madng in a closed container incesses temperature and pressure HALOGENATED HYDROCARSONS: Violent reaction.
HYDROCHLORIC ACID: Mhdne in a cioned container causes an increcee in temperature and pressure HYDROFLUORIC ACID: Mudng in a closed container causes an increase m temperature and pressure HYDROQUINONE: Rapid decomposition of hydroquinone with evolution of heat.
IRON: Solutons may slowly cortade LEAD: May be anar* art; temmable hydrogen gas may be Eberated LEATHER:
iey be sueched n
MALEIC ANHYDRIDE: Explosive decompoolbon METALS: Corrodes motels, reacting to form ilemmetne hydrogen gas.
4-METHYL 2 NITROPHENOL: Exothermic reachon, NITRIC ACID: nexing in closed containerincreases temperatu.'s and pressure.
NITROBENZENE: Possibly explosive reaction upon homen0 in presence of water.
NITROETHANE: Forms an explosive sen..
NITROMETHANE: Forms an explosive salt.
NITROPARAFFINS: The nitroperellins, in the pmeance of water, form dry sets with organic bases. The dry mans em expion.ve.
NITROPROPANE: Forms en explosive sell 0 NiTROTOLUENE: Possible explosion.
OLEUM: Mbdne in a closed container causes an increses in temne:sture and pressure ORGANIC PEROXIDES:Incompouble PENTOL (3 METHYL-2 PENTENE 4 YN 1 OL): Possible expr.asion.
PHOSPHORUS: May form snimod phosphines which may 1.dte spontaneously in air, j
7 PHOSPHORUS PENTOX1DE: May react violenty w*mn heated PLASTICS:May be seeded B-PROPIOLACTONE: Mbdne in a cioned conselw causes an increcee in temperature end pressure i
PROPYLENE OXIDE: Ignition or==r*=% may ecur.
j RUSSER: May be anschad i
I SODIUM TETRAHYDROSORATE: Dry mbdures with sodium hydroxide contalrung 15 40% of tetrahydroborate Rtorate hydrogen explosively at 230-270 C.
SULFURIC ACID: Mhdng in a closed container causes en increses in temperaure and preneure 1,2,4,5 TETRACHLOROBENZENE: Vloient reacton TETRACHLOROSENZENE + METHYL ALCOHOL
Possible explosion TETMACHLOROETHYLENE: Possibio explosion TETRAHYDROFURAN Serkus explosions can occur.
TIN: Evolumon of hydrogen gas which may form an explosive mbouse 1.1.1-TRICHLOROETHANOL:Fut*=% may occur.
- TRICHLOROETHYLENE: Formation of explosive mbouros of decidoroecetylene.
TRICHLORONITROhETHANE + hETHANOL: May cause violent reaction WOOL: May be sendied l
Seemens Power Corporation - Nuclear Division
EMF-1946 Rsvision 0 bodulu Extraction / Recovery Facility (MERF): Hazards Analysis Page 23 btt:chment C Material Safety Data Sheet 50% Sodium Hydroxide (Continued)
ZINC (DUST): Fire ar4 :=olosen hazard
(
ZlRCONIUM: May c=
r. plosive reacion upon heating.
HAZARDOUS DECOW OSITION:
Thermal decomposeson eney release toxic fumes of sodium oxide.
POLYMERIZATION:
Hazardous i;O,._ = _
, has not been reported to occur under normal temperatures and pressures SECTION 11 TOXICOLOGICAL INFORMATION SODIUM HYDROXIDE:
IRRfTATION DATA: 500 mel24 hours eiun<ebbit severe; 1% eye <ebbit
sowem, 50 ug/24 hours eyo<ebbit severe; 1 mg/24 hours eyo<ebbit severe; 400 ug eye <obbit mild: 1 mgl30 seconds nneed r,:.
eevers;1%I24 hours eyHmmley severe TOXICITY DATA: 1360 melkg oldn<ebbit LD60 (Van Waters & Rogers Inc.
MSDS);
800 melks orel rebt* LDLo; 104-340 m0/k0 orel ret LD50 (Van Waters &
. Regare Inc. MSDS); 40 mg/kg intreportioneel<nouse LD60; mutagenic date (RTECS).
CARCINOGEN STATUS: None.
LOCAL EFFECTS: Conceive inhaishon, sidn, eye, ingestion ACUTE TOXICITY LEVEL: Toxic by ingeston; moderstely toxic by dormal absorption TAROET EFFECTS: No dets oveliebin AT INCREASED RISK FROM EXPOSURE: Persons with pre exiebng sidn and eye condibons HEALTH EFFECTS INHALATION:
SODIUM HYDROXIDE:
CORROSIVE.10 rnelm3 Irnmediately Dangerous to Life or HesNh.
ACUTE EXPOSURE Effects due to inheloton of duels or mist may very from mild irrtesion of the noes at 2 trigfm3 to severe pneumonius depending on me sese'lly of exposure. Low concentranons may cause mucous membrane irritation wlm sore tweet, coughirg, and dyspnes. Intense evoceures may neult in destruction of mucous membranes and deisyed pulmonary ademo orpneumonitis Shock may occur.
CHRONIC EXPOSURE Prolonged exposures to high concentrekons of ducts er mists eney cause discomfort and ulceration of the nasal passages Repeated emoosures of 5000 moi. were hermises to rats, but 10,000 mg/L led to nervousness, sore eyes, thstrhos and retarded growth. Rats W 30 l
renutosidey to unmeasured concentrebens of sodium hydroxide aerosols sullered pulmonary damage eher 2-3 months. Doeth occuned in 2 of 10 rats exposed to en semeal of 40% equeous soditwn hydromide for 30 nunutes, teice a week for 3 weeks. Hugopellelogical examinston showed mosey normed lung theaue wlm foci of enterged elveolar septoe, emphyswns, tronchiel ulceremon, and eniergec8 lymph adenoidal useues. An epidemiologic study of 2g1 workst chmrucety exposed to causte duets for 30 years or more found no signillcent inomene in mortetty in.vasori to duramon or intensity of such exposures SKIN CONTACT:
SODIUM HYDROXIDE:
CORROSfVE.
ACUTE EXPOSURE-Upon contact with the sidn, damage includmg redness, cutaneous bums, sidn Gesums and while eschers may occur wthout immodels pain. Exposure to solutions as week as 0.03 N (0.12%)for 1 hour1.157407e-5 days 2.777778e-4 hours 1.653439e-6 weeks 3.805e-7 months has caused injury to heathy sidn. With solutions of 0.4 4%, irrteten does not occur unel eher several hours. Solutions of 26-60 % deused no eeneshon of irritomon wthin 3 minutes in human subjects Shin tdopoles imm human subjects having 1 N sodium hydromide opphed to meir arms for 15 to 180 minutes showed progresseve changes bogening wem dissolution of the cens in the homylayer and progrecoing through edoms to total destrueban of to epidermis in 60 rninutes A 5%
equeous soluton eeused severe necrosis to me stdn of rabbts when oppted for 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months . Abelles penetrate me sidn slowly,The entent of injury tiepends on te ciurellon of contact if sodsam hydroside l
is not removed hem me oldn, severe bums wlm theep ulceraton may occur. Exposure to me duet or mist may causeinuelpie emot bums and temporary loss of heir, Pathologic Andings due to alkalies mayinclude gelegnous, necreec artes etme site of contact Seemens Power Corporation - Nuclear Diviolon
i EMF-1946 l
Revision 0 Moduier Extraction / Recovery Facility (MERF): Hazards Analysis Page 24 Att: chm:nt C Material Safety Data Sheet 50% Sodium Hydroxide (Continued)
CHRONIC EXPOSURE-Effects are dependent upon concentration and duration of exposure.
Dermatibs or effects similar to those for acute exposure may occur.
EYE CONTACT:
SODIUM HYDROXIDE:
CORROSrVE.
ACLTTE EXPOSURE-Contact may cause draintegration and sloughing of conjunctival and comeal epithe6um, comaal opacificatKm, rnarked edema and ulceration. After 7 to 13 days either gradual recovery begins or there is progression of ulcershon and comeal opacification. Complications of severe eye bums are symblepharon with overgrowth of the comes by a vasculanzed membrane, progresssve or recurrent comeal ulceration and pomunent comaal @whW Blindness may occur.
CHRONIC EXPOSURE Effects are depender:t upon concentrabon and durstbn of exposure.
Conjunctivitis or effects similar to those for acute exposure may occur.
INGESTION:
=
SODIUM HYDROX1DE:
CORROS!VE/ TOXIC.
ACUTE EXPOCURE-The reported lethal dose in rats is 140 340 mg/kg. Ingestion may cause a bummg sensabon in the rnouth, corrosion :f the lips, mouth, tongue and phsrynx, and severe esophageal and sodommel pam, vomibng of blood and large pieces of mucosa, and tWoody diarrhea.
Aspnyxas con occur from sweling of the throat. Mediastmitis, aikatemia, pallor, weak, slow pulse, cardsovascular collapse, shock, come and death may occur. Perfornbon of the alimentary tract and constricbve scarring may result. Esophageal stricture may occur weeks, months, or even years later to l
make swallowing difficult.The estimated fatal dose in men is 5 grarns. Cases of squamous cell coronome of the esophagus have occumed with lalent penods of 12 to 42 years after ingestion.
These cancers were believed to be sequela of besus destruebon and possitWy scar formabon rather than the result of direct ce G +,4 schon of sodium hydroxide.
CHRONIC EXPOSURE Dependmg on the concentration. repeated ingestion pf alkalme substances may result in inflammatory and ulcerabve effects on the oral mucous membranes and other effects as with acute ingestion.
SECTION 12 - ECOLOGICAL INFORMATION I
Ecologscal information is not yet available for this record l
SECTION 13 DISPOSAL CONSIDERATIONS Observe all federal, state and local reguisbons when storing or deposing of this substance.
l Disposal must be in accordance with standards applicable to generators of hazardous waste,40 CFR 262. EPA Hazardous Waste Number D002.100 pound CERCLA Seebon 103 Reportable Ouentity.
4 SECTION 14 TRANSPORTINFORMATION S. DEPARTMENT OF TRANSPORTATION SHIPPING NAME-ID NUMBER,49 CFR 172.101:
1 Sodann hydroxide, solad-UN 1823 U.S. DEPARTMEffT OF TRANSPORTATION HAZARD CLASS OR DMSION,49 CFR 172.101:
8 Corrosive material U.S. DEPARTMENT OF TRANSPORTATION PACKING GROUP,49 CFR 172.101:
PG 11 U.S. DEPARTMENT OF TRANSPORTATION LABELING REOUIREMENTS,49 CFR 172.101 AND SUBPART E:
Corrosive U.S. DEPARTMENT OF TRANSPORTATION PACKAGING AUTHORIZATIONS:
EXCEPTIONS:49 CFR 173.154 Si mons Power Corporation Nuclear Division Iu_
f EMF-1946 Rxvisi:n O I Modul:r Extraction / Recovery Facility (MERF): Hazards Arnalysis Page 25
Att:chment C Material Safety Data Sheet 50% Sodium Hydroxide (Continued)
NON-8ULK PACKAGING:49 CFR 173.212 BULK PACKAGING:49 CFR 173.240 U.S. DEPARTMENT OF TRANSPORTATION OUANTITY LIMITATIONS 49 CFR 172.101:
PASSENGER AIRCRAFT OR RAILCAFL 15 k9 CARGO AIRCRAFT ONLY: 50 kg SECTION 15. REGULATOf;ViisORW.llON TSCA Status
Y SARA Sachon 302 (40 CFR 365.30) : N TPO SARA Secton 304 (40 CFR 365.40) : N RO SARA Secton 313 (40 CFR 372.65) : N CaWomie Prop 65 Status
N SARA ACUTE Hazard
Y SARA CHRONIC Hazard
N SARA FIRE Hazard
N SARA REACTMTY Hazard
Y SARA SUDDEN RELEASE Hazard
N SECTION 16. OTHER INFORMATION No other informston is cummey owedeble br this record l
t l
l l
[
Seemens Power Corporation - Nuclear Division
EMF-1946 Revision O G2odular Extraction / Recovery Facility (MERF): Hazards Analysis Page 26 attachm:nt D Material Safety Data Sheet 30% Hydrogen Peroxide OHS /MDL Record Number: OHSIA348 MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I
MDL Mformeton Systems, Inc.
FOR EMERGENCY SOURCE INFORMATION 14600 Celehne seest CONTACT: 1415 386 2000 in USA SanLeendro CA 94577 1400436 0064 (To8 Free)or 1-510 805 1313 SUSSTANCE. HYDROGEN PEROXIDE TMADE NAAE/ SYNONYM (Sk DlHYDROGEN DIOXIDE (SOLUTION)
CHEMICAi FAMILY: Madure
SUMMARY
86 AVAA.AALE: Y CREATION DATE: 19031124 REMSED: 10000619 CHEM CTJdGs DATE: 19060109 SECTION 2 COMPOSITION INFORMATION ONINGREDIENTS l
1) Component Substenos HYDROGEN PEROXIDE. SOLUTIONS Component Percent: Range 25 35 %
CAS RegeWy Number
7722441 Component SARA 302 TPQ: 1000 Component SARA 304 RQ 000000001
2) Component Subetence WATER Component Percent Range e6 75 %
SECTION 3 - HAZARDSIDENTIFICATION NFPA Reunes (scale 0 4) Needm=2 Flrs=0 ReactMay=0 EAERGENCY OVERVIEW-i OESCRIPTION Clear,colosteesligdt.
STATEAENT 08: HAZARDS Heruful N hholed or swetomed. Causes sien bums and severe bums to mucous membransa Causes sospeetary tract and eye hvasson, poseedy severs.
PRECAUTIONARY STATEnENTS Do not breathe vapor or nest. Do not get in eyes, en ohm, or en GotNng Keep from conasct wth cheerig and other combusubis matkiels. Store eney tem combusetde metenels. Keep contener eghgy closed. Weeh Woroughly stor handhng. Use only wel odeguese venglehen. Handle wNh osumon.
POTENTIAL HEALTH EFFECT3 INHALA110N:
SHORT TERM EFFECTS: May be hermM Ifinhaiad. May amuse smieten, possibly severe. Addamonel eescas mry halude wrNenG. sherrhee, chest poln, shormees of tream, wheetmg, headache, thEnness, numbness, tauche10. Bung congeston, aorwussions and shock.
LONG TERM EFFECTS:May cause eneets os in short term expoews Addeonel eGects may hetude seanng 880N CONTACT:
SHORT TERM EFFECTS: May cause irrenton, poestdy severe. Addannel erecto may mctude unghne senesson LONG TERM EFFECTS: May cause oNects es soported in lon0 term exposure. Some e5ects os short term esposure EYE COMrACT:
Damsna Power Corporation Nuclear Division
EMF-1946 Revision O Modulir Extraction / Recovery Facility (MERF): Hazards Analysis Page 27 Att:chment D Material Safety Data Sheet 30% Hydrogen Peroxide (Continued)
SHORT TERM EFFECTS: May cause irrtission, po@ eevere. Addeonel esects may include tearing and bhneness LONG TERM EFFECTS: Same eGects as short term exposure INGESTION:
SHORT TERM EFFECTS: May be hermM N swallowed. May cause bums. Addmonal eneas may include tower, nauses, womleing, derrhea, emmach pain and chest pain.
LONG TERM EFFECTS: May cause seects as in short term espesure Addmonal esects may include idoney damage. May also cause tumors CARCINOGEN STATUS:
OSHA: N NTP: N lARC:N l
)
SECTION 4 FIRST AfD hEASURES INHALATION:
FIRST AfD. If person esponences nauses, heedecne or derziness, person should stop work knmedsetely and move to tesh air ungl tiene symptoms dieeppeer. N teenshing is dellicult, administer seypen, keep the person warm and at rest. Ces e phymiaan. In the event that an indwidual inhaies enough product to lose consciousness, person should be moved to tesh air immodately,if teosth6mg has esopped, arWAcial respiremon should be given immediately. In ad cases, ensure adequets wonalisbon and provide respiratory soutesman behoe Die pomon resume to work.
900N CONTACT:
FIRST AD. Remove contamineled clothing and shoes immediately. Wash witi soap or mud detergent and large amounts of meter unul no evidence of chratical remains (at least 1520 minutes). If hums occur, proceed unh sie tonoming:CoveraGected ama securelywitistores, dry, loose 4mng dresemg. Trust sympmmemoney and supportwely. Get medlemi ausnuon immedetely EYE CONTACT:
FIRST AC-Weeh eyes "
'- ;wth inspo amounb of weser, occasionogy INung upper and lower tds, unal no evidenes of chemical remaine (et least 1520 nonutes). Congnue irrigseng wuh normel schne l
ungl the pH has resumed to normal (30 00 minutes). Coverwth starte bandeges. Get medioet amonton i
knmediesesy INGESTION:
FIRST AID If the person is consolous and not convulsing, give 2 4 glasses of water e duuta the l
chemical. Use geseb tubs to rollows the preneum caused by evolved cuygen (Dreistuch. Handbook of l
Poisoning,1291 Ed.). Treat symptomatoesy and supporthrely, inkbeton should be performed by queBAed medical personnel. Get medical asenmon immediately l
SECTION 5 - F;RE FIG 6CING MEASURES FIRE AND EXPLOSION HAZARD Noghgede Are hazand when exposed m heet or tems.
Quedesc Quedleers decompose, especiesy when hered, to yield cuygen or seier gases which wel incrosse sie huming rete of combusubio menor.
Connect wert asety oxidualde, organic, or other combungtde instensis may result in ionman, wtaient someuemon or espionion.
EXTINGUISHING MEDIA.
Water Do not uso dry chemloel, certion diosdde or helen.
(1883 Emergency Response Guidebook, RSPA P 5000.8).
For larger tres, Anod ams wlBi meter tesi a distonos (1983 Ilmergency Response Guidateok, RSPA P 5000A).
FIREFIGHTING, Move conseiner tem tre eres if you een do N wipiout reek. Apply cootng water to sir)es of contuners that are esposed to temse uns was ener em is out. abey emuy tem ande of tanks. For messive tre h cargo eres, use unmanned hoes holder or montor nosales; if esis is impoestde, wahdrew tom ares and let Are bum (1983 Emergency Response Guidebook, RSPA P 8800.6. Guide Page 45). Flood wariwater.
(
Siemens Power Corporation - Nuclear Division
EMF-1946 '
Rrvision 0 l M:dul:r Extraction / Recovery Facility (MERF):' Hazards Analysis Page 28
, Att:chment D Materiel Safety Data Sheet 30% Hydrogen Peroxide (Continued)
Cool contemers with floodmg amounts of water from as for a detence as possible. Avoid brestlwng corrosive vapors or dusts. If fire is uncontrollable, evacuate for a radius of 2500 feet.
FLASH POINT: Not appleable HAZARDOUS COMBUSTION PRODUCTS:
Thermal decompoeillon products may include oxygen.
SECTION 6 - ACCIDENTAL RELEASE MEASURES OCCUPATIONAL SPILL:
Keep combusubies (wood, paper, oil, etc.) Awey from speed motorial. Do not touch speed motorial Stop leek if you con do it wahout rtek. Use water uprey to reduce vapors. Do not get waterinside contemer. For emeu dry spas, seh cteen shovel piece meterial into cimen, dry container and cover.
Move containers from sp;il eres. Fur./.aH liquul spas, flush area with Gooding amounts of wotor. For larger spas, dike for sheed of sput for inter dispceal. Keep unnecessary people away leoiste hazard aree and deny entry.
Reportable Quentity (RO): The Superfund Amendments and Resulhortration Act (SARA) Section 304 nquires that a reisese equel to or greater then the reportable quenoty estatsshed for that substance to immedelely reponed to the local emergency pionning commisse and the state emergency response commesion (40 CFR 356.40), if the reisese of this subetence is reportable under CERCLA Secton 103, the Notensi Response Center must be notNied immodately at (800)424 8002 or (202) 426-2675 in the metropohten Washington, D.C. ares (40 CFR 302.6).
HYDROGEN PEROXfDE (ONn Corporellon has reported the fotowmg): Remove all ignibon sources. Do not piece speed meterleis back in their original containers SECTION 7 - HANDLING AND STORAGE I
Observe all federal, state and local reguisbone when storing or disposing of this substance.
)
Consult NFPA fu% 43A Storage of Uguid and SoNd Oxidizing Materials, for Storage Reguments
_l Store in a cool, dry, weg venested aree.-
1 l
Do not store near heat or flame.
l Protect from light.
j Shelf ufe is 12 nonths.
I Store below 100 F.
Store away from incompouble subetences SECTION 8. EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS:
14YDROGEN PEROXIDE:
1 ppm (1.4 mghn3) OSHA TWA l
1 ppm (1.4 mphn3) ACGtH TWA ACGlH A3 Animal Carcinogen (Proposed Addeon 1995 06) 1 ppm (1.4 mg/m3) NIOSH recommended 10 hour1.157407e-4 days 0.00278 hours 1.653439e-5 weeks 3.805e-6 months TWA 1 ppm (1.4 mpfm3) DFG MAK TWA; 2 ppm (2.8 meen3) DFG MAK 5 minute peak, momentary value,8 times / shift HYDROGEN PEROXIDE (GREATER THAN 82%)-
1000 pounds SARA Seceon 302 Threshold Plannmg Quently
- 1 pound SARA Sechon 304 Reportable Quenety Semens Power Corporation - Nuclear Dwision
EMF-1946 Revision O
' Modular Extraction / Recovery Facility (MERF): Hazards Analysis Page 29 i Attachment D Material Safety Data Sheet 30% Hydrogen Peroxide (Continued) 7S00 pounds OSHA Process Safety Management Threshold Quantity VENTILATION:
Provide local exhaust venti!ation system to meet published exposure I m ts.
EYE PROTECTION:
Employee must wear splash-proof or dust-resistant safety goggles with or without a faceshield to prevent contact with this substance. Emergency eye wash:Where there is any possibility that an employee's eyes may be exposed to this substance, the employer should provide an eye wash fountain withm the immediate work area for emergency use. CLOTHING: En-G,u must wear.w,up-Ote protactive (impervious) clothing and equipment to prevent repeated or Hv;G6 god skin contact with this substance. GLOVES: Employee must wear appropriate protecbve gloves to prevent contact with this substance.
RECOMMENDED MATERIAL TYPES:
Natural rubber RESPIRATOR:
The followng respirators and maximum use concentrations are recommendations by the U.S.
Department of Health and Human Serv 6ces, NIOSH Pocket Guide to Chemical Harards: NIOSH cntena documents or by the U.S. Department of Labor,29 CFP 1910 Subpart Z. The specific respirator selected must be based on contamination levels found in the work place, must not exceed the working limits of the respirator and be jointly approved by the NationalInstitute for Ch*ml Safety and Health and the Mme Safety and Health Admirustration (NIOSH-MSHA).
HYDROGEN PEROXIDE:
10 ppm-Any supplied-air respirator.
25 ppm Any supplied-air resperator operated in a continuous-flow rnode.
50 ppm Any self-contained breathing apparatus with a full facopesce Any supplied-air respirator with a full facepeece 75 ppm-Any supphed-air respirator that has a full facopeece and is operated in a pressure demand or other positive-pressure mode.
Escape. Any air-purifying, full-facopiece respirator (ges mask) with a chin-style, front-or back mounted caruster providing gei. coon against this compound Any appropriate escape-type, self-contained breathing apparatus.
FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH l
CONDITIONS:
l Any self-contained breathing apparatus that has a full facepeace and 5 operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator that has a full facepiece and is operated in a pressure demand or other positive-pressure mode in combmation with an auxiliary self-contained breathing apparatus operated in pressure <lemand or other positive-pressure mode.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES DESCRIPTION: Clear, colorless liquid.
PHYSICAL STATE (S.L,G): L BOILING POINT: 223 F (106 C)(30% solution)
MELTING POINT:-15 F (-26 C)
SPECIFIC GRAVITY: 1,113 (30% solution) pH: 3.3 (30% solution)
VAPOR PRESSURE:25 mmHg @ 30 C VOLATILITY: 100%
WATER SOLUBILITY: Complete SECTION 10 - STABILITY AND REACTIVITY
. REACTIVITY:
Stab 6e under normal temperatures and pressures.
CONDITIONS TO AVOID:
I Siemens Power Corporation Nuclear Division
EMF-1946 R: vision 0 Modul r Extraction / Recovery Facility (MERF): Hazards Analysis Page 30 Att:chment D Material Safety Data Sheet 30% Hydrogen Peroxide (Continued)
May ignies other combustible malensis (wood, paper, oil, etc.). Reaction with fuels may be violent.
Flammable poisonous gases may occumulate in tonks and hopper cars. Runoff to sewer may create fire or explosion horard.
INCOMPATIBILITIES:
HYDROGEN PEROXIDE (Olin Corporanon has reported tne followmg):
BACOC: May generate oxygen gas and high pressure COMBUSTISLE MATERIALS: Incompenbie METALS: May generate oxygen gas and high pressure ORGANIC MATERIALS:Incompenble OXIDl2ABLE MATERIALS: Incompedble.
METAL SALTS: May generate oxygen gas and high pressure SOLVENTS: May generate oxygen ges and high pressure HYDROGEN PEROXIDE:
ACETALDEHYDE: Forme explosive compound ACETIC ACID: Forms exploshe compound.
ACETONE: Fe ALCOHOLS: May form explosive compounds BENZENESULFONIC ANHYDRIDE: Explosive decomposition CARBOXYLIC ACIDS: Form explosive peroxyacids.
. CHLOROSULFONIC ACID: May form exploone compound CHLORINE + POTASSIUM HYDROXfDE: Reacts with red lummencence COWUSTIBLE MATERIALS: May acosierate the bummg rate, or cause igndion or explosion on contact.
DIETHYL ETHER: Explosive mhdure DlWTHYLPHENYLPHOSPHINE: Vloient reaction on rapid mbdng DIPHENYL DISELENIDE: May form explosive compound.
ETHANOL: F=riaam GADOLINIUM HYDROXIDE: Forms explosive compound l
HYDROGEN SELENIDE: Rapid interschon KETENE: Forms exploshe compound j
KETONES + NITRIC ACID: May form explosive compounds LITHlUM TETRAHYDROALUMINATE: Explosive minuture METALS (+ ALLOYS): May catalyze violent, exothemuc J _
i" i.
ETAL OXIDES: Vigorous or violent reacdon METAL SALTS: May catalyze violent, exothermic decomposition NITRIC ACID + THIOUREA: Formsbon of explashe compound NITRIC ACID: Unstable mbeure when more then 50% acid is present l
NITROGENOUS BASES: Explosion hozord l
ORGANIC COMPOUNDS: Under certain circumstances, may ignite or form detonsbie i
mhdures. The presence of a catalyst may incrosse the risk of a reaction l
OXYGENATED COMPOUNDS + WATER: May form detonable mixtures l
PHENYLSELENOKETONES: Strong. exothermic reecnon.
PHOSPHOROUS: Veient reecean if heated.
PHOSPHOROUS (V) OXIDE: Extremely vicient reecemn.
POTASSIUM: Vloient reecean POTASSIUM PERMANGANATE: Violent reaction _
REDUCING AGENTS: Fire end =rplaam hazard j
SODIUM: Violent reaction TETRAHYDROTHIOPENE: May form explosive correpointd.
SULFURIC ACID:Feriaam horard if heated to dryness TIN (II) CHLORIDE: Exothermic reacten WOOD. Possible ignibon l
HAZARDOUS DECOMPOSmON:
Thermal decompoellen products may include oxygen POLYMERIZATION:
Haterdous pe,.
--- has not been reported to occur under normel temperatures and pressures
.Seemens P wer Corporation Nuclear Division
EMF-1946
- Rsvision O Modui:r Extraction / Recovery Facility (MERF): Hazards Analysis Page 31 Att:chment Dysterial Safety Data Sheet 30% Hydrogen Peroxide (Continued)
SECTION 11 - TOXICOLOGICALINFORMATION HYrROGEN PEROXIDE (Ohn Corporebon has reported the foHowmg*):
CARCINOGEN STATUS: None.'
ACUTE TOXICITY LEVEL: No dote evaliable.
TARGET EFFECTS: Pomoning may aNect the eyes, mucous membranes, resprotory tract, tissues, and lungs?
AT INCREASED RISK FROM EXPOSURE: Persons with methms and other resprotory dessees, sidn or
. eye disoniers *
- ADDITIONAL DATA: Hamdullfinhaled, swallowed, and exposed to oldn or eyes.*
HYDROGEN PEROXIDE:
TOXICITY DATA:
90%: 2 gmhW4 hours inhelstorwat LC60; 227 ppm inhalation-mouse LCLo; S00 mg40 skirwebtWt LDLo; 4000 mg40 eldrwet LD60; 2 gmte sidn pig LDLo; 2 gm40 oro6eouse LD60; 15 gmtg intrevenous-robbit LD50;
>2000 ppm 4 hours4.62963e-5 days 0.00111 hours 6.613757e-6 weeks 1.522e-6 months inhaistiorwet LC50 (Van Waters & Rogers MSDS);
mutagenic dets (RTECS): tumortgenic data (RTECS).
76%: 75 mg4g oro6 rat LD60 (Van Waters & Rogers MSDS).
70%: 9200 mg4g oldn robtWt LD50 (Van Waters & Rogers MSDS).
30%: 2000 mgMW4 hours ineelegorwat LC50 (CE MSDS).
30%: 1429 m04g cro6een LDLo; 2626 uB40 oro6eomen LDLo; 1200 mg40 cro6momen TDLo; >60 gm40 intrevenous mouse LD50; mutagenic data (RTECS); tumorigenic date (RTECS). -
27-52%: 100 ppm inholettorwet LCLo (GE MSDS).
620%: 1518 mg4g oral ret LD60; repmductve eNects date (RTECS).
3%: 2000 melrrW4 hours inhaletorwat LC60; 2 g4g oral ret LD60 (Caledon MSDS).
CARCINOGEN STATUS: Animal Limbed Evidence (IARC Group 3). Oral adminis9ellon in mice resumed in edenomes and ceremomes of the duodenum.
Other studes indcolod that hydrogen peroxide has no tumor promoen0 aceMiy.
LOCAL EFFECTS: Cormsive Inhaletion, sidn, eyes, ingestion.
ACUTE TOXICITY LEVEL: Toxic by inholabon and ingeadon; shghty toxic by dermal absorpeon.
TARGET EFFECTS:No date avaliable AT INCREASED RISK FROM EXPOSURE: Persons with impelred pulmonary funcbon or sadn or eye doorders, i
HEALTH EFFECTS INHALATION:
HYDROGEN PEROXIDE (Olin Corporellon has reported the following):
ACUTE EXPOSURE-Vapors and mist may cause inteston and inRommenon of the nose, mouth, throat and respiratory tract. Pulmonary edoms may develop and may cause shortness of breath, wheating. choldn0. chest pain and impeirment of lung functon. ENects may be deisyed for several hours.
CHRONIC EXPOSURE. May cause bleachmg of the heir and impexment of lung funcdon HYDROGEN PEROXIDE:
CORRoslVE/ TOXIC.
75 ppm immediately Dengerous to Life or HesNh.
ACUTE EXPOSURE Vapor or mist may cause severe irrttellon of the respiratory tract 10% may cause sore throat, couGNng, and shortness of breath; atMwe 30% brestung may become labored Severe systeme pomonmg may result in headache, dizzmeos, vomieng, diarrhea, tremors, irritabluty, insomnia, hyper-reneste, numbness, convulsions, unconodouaneos, shock, and death.
.j Siemens Power Corporation - Nuclear Division 1
l EMF-1946 Ravision 0 Modul1r Extraction / Recovery Facility (MERF): Hazards Analysis Page 32 Att chment D Meteriel Safety Data Sheet 30% Hydrogen Peroxide (Continued)
Respiratory damage may range from mild broncNbs to pulmonary edome and effects may be deleyed for severes hours.
CHRONIC EXPOSURE Dogs exposed to 7 ppm of 90% soluton for 6 hours6.944444e-5 days 0.00167 hours 9.920635e-6 weeks 2.283e-6 months a day 5 days a week for 6 months showed no eGects fbr the first 23 weeks Ator week 23 they exhibited roughmg, lacrimston, and bleached heir. Autopsy showed INckening of the skin wHh no heir folhcie destruchon, and imtenon of the lungs. Rabbbs exposed to 22 ppm for 3 months exhibited bissched heir and imtelion around the nose.
SKIN CONTACT:
HYDROGEN PEROXIDE (ONn Corporeton has reported the fonowing)-
ACUTE EXPOSURE May cause severe inttellon and/or bums chorectortzed by a tinghng seneeton, redness, swelung, and whitoning of the oldn. Prolonged exposure may cause destruchon of the dorms wah uioeremon.
CHRONIC EXPOSURE-EHects from chronic exposure would be simmer to those from single exposure escept for eGects secondary to tesue destruction.
HYDROGEN PEROXfDE:
CORROSlVE.
ACUTE EXPOSURE-Vapor or mist may be irritehng to the eidn. A 0% aolution is a week inttent.
Contact with low concentregons of the liquid may cause tingung and whitaning of the skin. If not removed, erytheme or vesicle formellon may occur. High concentrollons may cause severe bums wnh ulceraton. There are inconciusive or unverthed reports of human sermahan.
CHRONIC EXPOSURE Eflects depend on me concentremon and duration of exposure Repeated cm prolonged contact wHh corrosive substances may cause dermedes or eGects similar to acute exposure.
EYE CONTACT:
HYDROGEN PEROXIDE (Oun Corporation has reported the fotowing): May cause severe irritation and/or bums. Direct contact may cause impairment of vision and comeel demoge.
HYDROGEN PEROXIDE:
CORROSIVE.
ACUTE EXPOSURE-Vapors may cause redness, eenging, toering and blurred vision. The liquid may cause severe comeelor conjuncovel ulceraton, possibly resumng in hundness. ENects may be deisyed.
In rebtit eyes 0.5% caused deturbances in the comeel eptheEum which retumed to normalin 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months ; 5% caused severe comeel edome, flere in me aqueous, intense congeston of the irts and I
vesculertzemon of the comes weh only permet ;,.m. n,: stor 4-6 months; 5 30% caused comeel clouding which was persistent et concentheons >10%.
CHRONIC EXPOSURE-Eflects depend on the concentaton and duremon of exposure PWor prolonged exposure to corrosive substances may cause conjunctivills or eGects sanitor to acute exposure Rabtits exposed to 7 ppm ter 10 weeks exhibited no comeel demoge INGESTION l
HYDROGEN PEROXIDE (ONn Corporeton has reported me fo6 lowing)-
1 ACUTE EXPOSURE-May cause irrtismon arewar burns to the entre gestrointesenal tract, including the I
stomach and intestines, chorectertred by nouses, womWng, disnhem, abdomines pain, t:leeding, and/or unsue ulceration. May cause severe damage to the gestointeounal tract wah the potenbal to cause pertornoon.
CHRONIC EXPOSURE E9ects would be simmer to those from a single exposure.
HYDROGEN PEROXIDE:
CORROSlVE/ TOXIC / LIMITED ANIMAL CARCINOGEN.
ACUTE EXPOSURE May cause severe irrliston and injury to the mouth and thmet, detenbon of the esophagus and stomach, and intemel bleeding 5 humans who ingested 60 ml of a 36% solution expertenced stomach and chest pains, retention of tweeth, foeming at the mouth, and loss of conoceueness. They later developed motor and sensory disorders, inver,, M z-i--.=.and moderate leucocytosis: 1 developed pneumonie AN recovered in 2 3 weeks. The lethei does reported in rats was 75 modkg of a 75% solution.
CHRONIC EXPOSURE Growth retardation,induchon of dental ceries, and pathological changes in the periodontium were otrarved in young male.rets secolvmg 1.5% hydmgen peroxide as their ennlung fluid for 8 weeks. Treatment of mico for 35 weeks wHh 0.15% hydrogen peroxide resuird in hydropic degenerston of hopeec and renal tubular epimellel teoues, necrosis, innemmebon, inegularlbes of tissue structure of me atomach wel and hypertrophy of me lymphetc issue of the smenintoshne weH;
$6emens Power Corporation - Nuclear Division c
_____d
EMF-1946 RIvision O
( M:dul:r Extraction / Recovery Facility (MERF): Hazards Analysis Page 33 f Attachment D Material Safety Data Sheet 30% Hydrogen Peroxide (Continued) concentrations in excess of1% ret ulted in a pronounced loss of body weight and death within 2 weeks.
Repeated adrrenistration to rnice and rats produced adenomas and carcinomas of the duodenum.
SECTION 12 - ECOLOGICAL INFORMATION Ecological informston is not yet availabie for this record SECTION 13 DISPOSAL CONSIDERATIONS Observe all federal, stats and local regulabons when storing or deposin9 of this substance Disposal must be in accordance with standards appienhl= to generators of hazardous weste,40 CFR 262. EPA Hazardous Wasts Number D001. 100 pound CERCLA Secbon 103 Reportable Quantity.
SECTION14 TRANSPORTINFORMATION U.S. DEPARTMENT OF TRANSPORTATION SHIPPING NAME-ID NUh8ER,49 CFR 172.101:
Hydrogen peroxide, ary-solubons-UN 2014 U.S. DEPARTMENT OF TRANSPORTATION HAZARD CLASS OR DIVISION,49 CFR 172.101:
5.1 - Oxidizer U.S. DEPARTMENT OF TRANSPORTATION PACKING GROUP,49 CFR 172.101:
PG 11 U.S. DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS,49 CFR 172.101 ANO SUBPART E:
Oxidizer, conoseve U.S. DEPARTMENT OF TRANSPORTATION PACKAGING A!JTHORIZATIONS:
EXCEPTIONS: None NON4ULK PACKAGING:49 CFR 173.202 BULK PACKAGING:49 CFR 173.243 U.S. DEPARTMENT OF TRANSPORTATION OUANTTTY LIMITATIONS 49 CFR 172.101:
PASSENGER AIRCRAFT OR RAILCAR: Fortmiden CARGO AIRCRAFT ONLY: Forbidden l
(
SECTION 15 - REGULATORY INFORMATION l
TSCA Status
Y SARA Section 302 (40 CSR 355.30) : Y TPQ SARA Seebon 304 (40 CFR 355.40) : Y RQ SARA Secton 313 (40 CFR 372.65) : N Cailfomia Prop 65 Status
N SARA ACUTE Hazard
Y SARA CHRONIC Hazard
Y SARA FIRE Hazard
Y 1
SARA REACTIVITY Hazard
N I
SARA SUDDEN RELEASE Hazard
N l
SECTION16 OTHERINFORMATION I
i No other informehon is cumently available for this record
=
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