ML20128M502

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Certificate of Compliance 9094,Rev 8,for Model CNS 14-195-H. Approval Record for Combustible Gas Mixtures Encl
ML20128M502
Person / Time
Site: 07109094
Issue date: 05/22/1985
From: Macdonald C
NRC OFFICE OF NUCLEAR MATERIAL SAFETY & SAFEGUARDS (NMSS)
To:
Shared Package
ML20128M496 List:
References
NUDOCS 8505310675
Download: ML20128M502 (4)


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CERTIFICATE OF CEMPLlANCE FO~l RADCACTIVE MATERIALS PACKA'!ES lE 1 a CElflFICATE NUMBER ti Revision NUMBER c PACKAGE IDENTIFICATION NUMBER a PAGE NUMBER e TOTAL NUMBER PAGES I i

9094 8

USA /9094/A 1

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1 2 PREAMBLE

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a. inis ceriivicare is issued to certiry tnat in. packaging and cont.nts described ea st.m s b.io=. me.ts tn.appiscaei. sat.ty standards set fortn in titie to, Cod.

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of Federai Regulations, Part 7t, *Packagirig of Radioactive Materiais for Transport and Transportation of Radioactiv. Materiai Under C.rtain Conditions. '

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n. inis certificai. does not r.ii.v. in. consignor from compi anc..itn any requirem.nt of tn. reguistions of in. u.s. capartm.ni of Tran,portation or ein.r

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I applicabi. reguiatory agencies, inciuding tn. government of any country tnrougn or ento wnicn tn. packag. will be transport.d f

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rsis cERTiricATE is issuEO oN TsE sAsis or A sArETv ANAtysis REPORT or TwE PAcxAcE DEsicN oR APPucATioN j

I a PREPARED 8v (Nemo amt Addresst ts. TITLE ANO IDENTIF6 CATION OF REPORT oR APPLICATION-I Chem-Nuclear Systems, Inc.

Chem-Nuclear Systems, Inc. application ji l

220 Stoneridge Drive dated March 31, 1980.

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)j l.j inis certificat... conditionai upon ruirisiing the requir'ements of to CrA Part ri, as appiicani.. and in. conditions sp.civi.d e.io.

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Packaging

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$l (1) Model No.: 'CNS 14-195-!!

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Description

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f A steel encased lead shielded cask for low specific activity material.

j The cask is a right' circular rylinder 83-1/8-inch diameter by 89-7/8-g i

inch with a 77-inch diameter by'80-1/8-inch cavity.

Lead shielding is y

1 2-3/16-inch thick, and is encased-in an~ outer steel shell 3/4-inch I

1 thick ~ and inner ~ steel shell 1/8-inch th'ick.

Positive closure of the I

h silicone rubber-sealed lid is provided by twelve,1-1/4-inch diameter I

cap screws. ATsecondary lid with a Neoprene seal uses eighteen, 3/4"-

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10VNC bolts for' closure; The cask is welded to a 96-inch square based R

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3 plate, has two lifting trunnions, three lid lif t rings and one secondary lp 1

lid lifting ring.

Package gross weight is 56,500 pounds.

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(3)

Drawing 1

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The packaging is fabricated in accordance with Chem-Nuclear Systems, y

g Inc. Drawing No. 1-189-101, Sheet 1 of 1, Rev. A-F.

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1 (b) Contents

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(1) Type and form of material j

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Process solids, either dewatered, solid or solidified in secondary

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containers, meeting the requirements for low specific activity lli l

material; or 3) j Ji j'

(ii) Solid reactor components in secondary containers, as required j

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that meet the requirements for low specific activity naterial.

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(2) Maximum quantity of material per package

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1 Greater than Type A quantity of radioactive material with the weight i

j of the contents, secondary containers and shoring not exceeding 17,700 j

pounds, j

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  • CONDITIONS (contanu:d)

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I Page 2 - Certificate No. 9094 - Revision No. 8 - Docket No. 71-9094 h

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6.

(a)

For any package containing water and/or organic substances which could N

I radiolytically generate combustible gases, detemination must be made by i

I tests and measurements or by analysis of a representative package such that

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the following criteria are met over a period of time that is twice the E

l expected shipment time:

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{u (i) The hydrogen generated must be limited to a molar quantity that would ln i l be no more than 5% by volume (or equivalent limits for other inflam-p 1

W mable gases) of the secondary contaiger gas void if present at STP l

(i.e., no more than 0.063 g-moles /f t at 14.7 psia and 70*F); or g -

l (ii) The secondary container aiid c7sk cay,d(to 5% by volume in those f

T ity must be inerted with a diluent to assure that oxyg'enimust' bd li5ite l

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!I of the package-which'could have hydrogen' greater than 5%.

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I For any package' delivered to a carrier for transport,ithe secondary container

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l must be prepareddfor shipment in the same manner in'which determination for il q

gas generation'is-made.

Shipment period begins,when the package is prepared the, expected shipment time.

!g (sealed) andiniust'bejampleted within twice,jif g

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(b)

For any package shipped kthin 10; days of' preparation, or within 10 days I.

after venting of drums-or other secondary containers, the' determination in E

(a) above seed not be inade; fand the,' time 're'striction in (g) above doe l

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Shoring must be, laced, tween ~secondaryicontainers f(or. activated components) i Lp i

I and the cask cavity to'p'rEvent mov'einent dur,in'g' normal conditions of transport.

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I The lid lifting lugs rustTnot'bIuse}di forlyTiftin'g' the cask and shall be coveredj

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g in transit.

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Prior to each shipmerit'the lid gaskets'j \\ W s/.

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i must be inspected.; These gaskets must be N

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I replaced if inspection ' shops any defects or every twelve (12) months, whichever I

occurs first.

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Packagings fabricated after March 31, 1980, must be constructed of A-516, Grade g

s 70 carbon steel instead of A-36 carbon steel.

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The package authorized by this certificate nust be transported on a motor W

I vehicle, railroad car, aircraft, inland water craft, or hold or deck of a seagoing l

l vessel assigned for sole use of the licensee.

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The package authorized by this certificate is hereby approved for use under the p

i ll general license provisions of 10 CFR 971.12.

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Expiration date:

May 31,1985.

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Page 3 - Certificate No. 9094 - Revision No. 8 - Docket No. 71-9094 g

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I REFERENCE N

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g Chem-Nuclear Systems, Inc. application dated March 31, 1980.

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FOR THE U.S. NUCLEAR REGULATORY C0f1 MISSION N

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Charles E. MacDonald, Chief g

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I F 'rDiv.fsiifn(of fuel Cycle and R

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I MaterialSafety,jNMSS I

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UNITED STATES

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NUCLEAR REGULATORY COMMISSION E

WASHINGTON, D. C. 20555

.....,o Transportation Certification Branch Approval Record Combustible Gas Mixtures Conditions were imposed on packages containing water and/or organic substances to limit the accumulation of radiolytically generated gases

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over the shipping period to preclude the possibility of significantly reducing the packaging effectiveness due to explosion.

Part of the conditions included

"...it must be detemined by tests and measurecents of a representative package whether or not...."

There is no reason to believe that calculational methods could not be used as means of determining gas generation. So as not to preclude a valid analysis, part of the condition to limit the accumulation of radiolytically generated gases is revised to read "...it must te detemined by tests.and measurements or by analysis of a representative package whether or not...."

The analytic approach involves detennining the hydrogen generated in the waste by radiolysis based on the absorbed dose of the waste over a given period of time. To satisfy the condition to preclude a combustible mixture, the period since closure ~.and twice the shipping time must be considered. The calculation requires that the properties of the waste are known.

These properties may be determined from test and measurement of representative waste foms or from data that is applicable to the waste fann. The determination should be documented and retained as part of the records for the shipment.

Charles E. MacDonald, Chief Transportation Certification Branch Division of Fuel Cycle and Material Safety, NMSS 22M Date:

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