ML20113H921
| ML20113H921 | |
| Person / Time | |
|---|---|
| Site: | Waterford  |
| Issue date: | 07/31/1992 |
| From: | ENTERGY OPERATIONS, INC. |
| To: | |
| Shared Package | |
| ML20113H919 | List: |
| References | |
| NUDOCS 9208060157 | |
| Download: ML20113H921 (24) | |
Text
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T a
l REPORT A METilOD014GY AND RESULTS OF TIIE 1992 SURVEY OF T0XIC CilEMICALS STORED, PROCESSED OR TRANSPORTED IN TiiE VICINITY OF WATERFORD SES UNIT NO. 3 9208060157 920731 L
PDR ADOCK 050003G2 R
pon L
liETHODOLOGY AND RESULTS OF THE 1992 SURVEY OF TOXIC CHEMICALS STORED. PROCESSED OR TRANSPORTED IN THE VICINITY OF WATERFORD SES UNIT 3 (WATERFORD 3) l INTRODUCTION Technical Specification 6.9.1.9 for Watorford 3 requires Entorgy Operations Inc. to perform a survey and analysos of major industrios in the vicinity of Watorford 3, which could have significant inventorios of toxic chemicals on sito, to dotormine the impact cn safoty and submit the results to the iiRC at least ove ry four years. A report of the results of the last such survey and analysos was transmitted to the NRC by L P & L lotter W3P88-O ',10, dated May 12, 1988 (a more detailed description can be found in Section 2.2.3 of the Waterford 3 FSAR, Rev. 2). This-ruport providos the results of tho 1992 survey.
A companion report (Report D) discussos the survey and analynos of pipelinos and explosive hazards in the vicinity of Waterford 3.
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TOXIC CHEMICAL SURVEY Survey of_ Local Industries /Particientina Facilities The 1991-92 survey of toxic chemicals in the Waterford 3 vicinity identified 15 industrial facilities which stored or processed such materials within a 5-mile radius of the Waterford 3 Control Room. Rogulatory Guido (R.G.) 1.76 specifies that sources more than five miles away neod not be considorod, since they are not likely to pose a hazard to the nuclear plant.
One of those, E.I.
Du pont Do Nomours & Co., was omitted from the current survey sinco all structures on its property are outside the 5-milo radius.
To dotormino if there wore any other industrial facilities with significant sources of toxic chemicals in this area, the Emergon;y Preparednoss Contors (EPC's) of the Louisiana Parishes Of St. Charles and St. John The Baptist wore consulted. The area encompassed by the five-mile radius lies within the boundaries of s
these two parishes.
Sinco state law requires _that hazardous chemicals stored anywhere in the parishes are to be reported to the respectivo parish EPC, facilitios storing toxic chemicals have been assumed to have filed the roquired reports.
A map of the affected the area was prepared by assembling four U.S. Geological Survey -7.5 Minute Series (topographic) maps that covered the five-mile radius.
These were the quadrangles entitled Reserve, Laplace, Hahnville and Lac des Allemands.
By trimming the margins and joining the sheets together, a convenient reference was prepared for locating the sources of 1
toxic chemicals. Two concentric circles, contored on the Watorford 3 Control Room and having scaled radii of two and fivo 1
w
- m
t-
)
milaa. respectively, delineated the zones for the pipeline and cno toxic chemical surveys.
The list of industries for St. Charlos Parish, shown in Table A-1 of this report, was obtained from the St. Charlos Parish office of Emergency Preparodnoss.
Information on St. John the Baptist Parish industries was obtained from St. John The Baptist Emergency Planning Committee.
The only industry within the fivo-mile zone which did not recoivo a survey questionnaire was Big Thrca Industries. Telephone conversations with plant personnel established that the only hazardous materials wore non-toxic gases (nitrogen, oxygon, and argon) stored at cryogenic temperatures.. Thus, there was no need for this facility to respond to the written questionnaire.
Survey Ouestionnaires An initial stop of the survey was to tolophone the plant official or the contact person listed on the last survey reports to solicit their participation in the now survey and to determine the best person to whom to direct the survey questionnaire.
After being alerted by tolophone, each participant in the survey was furnished a questionnaire.
For the convenience of the vonpondents and to enable a direct comparison with earlier information, data from the previous survey was entered on tho questionnaire.
These questionnaires wero fashioned after Table 2.2-3b and Table 2.2-3c of the FSAR, Rev.2 with instructions for the responients to update as necessary. Data included the shipment frequencies, routes, direction (by rail, highway and water), storage and process temperatures, and locations, pressures and flow rates in pipelines entering and leaving the plant.
Facilities that provided information in 1987-88 were asked to provide updated information.
In addition, fLcilities were furnished copies of topographical maps including the areas of their site and were asked to indicate on the maps the actual location of each storage tank. Many respondents chose to oubmit a sito plan map of their facility showing the location of their storage sites.
Table A-2, lists the names of the individuals contacted.
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conduct of the Survey Two considorations governed the conduct of the survey. Data was nooded to conduct detailed analysos of those sources of toxic chemicals which can pose potential hazards to Waterford 3.
In addition, it was necessary to update the data already in the FSAR.
In some casos the respondents called to ask for guidance as to what information was actually noodod. In such casos, the caller was told that chemicals could be omitted with vapor pressures of loss than 10 torr (mm Hg) at 100 'P (this is in accordance with the guidance of R.G.
1.78). If the person was a safety engineer, the person was askud to use judgemont in listing sources that, in caso of an accident, were capable of causing a toxic hazard off-sito (boyond the boundary of their facility). Since the safety and/or environmental specialist at major chemical plants are required to regularly perform such assessments to meet state and federal requirements, their experience would enable them to make such datorminations. As the previous survey concluded in the ca.se of shipment routos, the respondent was told the data provided could be limited to shipments to or from the facility in the direction of Watorford 3.
Survey Results All of the facilitics responded to the survey by providing i
sufficient information to enable a determination of the consequences in the event of a toxic chemical release acciuont.
The survey results indicated that the types a.1d quantities of sourcos of toxic chemicals have either remained the same or have been reduced or eliminated since the last survey. There were no new respondents to this survey.
Union Pacific Railroad The tracks of the Union Pacific Railroad pass approximately 0.45 miles SSE of the Waterford 3 site.
Thorofore, it was necessary to include toxic chemicals transported over these tracks-in the survey.
The Standard Transportation Commodity Code (STCC) Tariff, published by the various regional railroad associatjons, annigns a seven digit number called the STCC code to each commodity.
Hazardous cargo has an STCC code beginning with the number 49.
Table A-3 includes hazardous materials and their assigned STCC codes shipped on the Union Pacific Railroad track within five miles of Waterford 3.
For each commodity, the number of cars passing over this portion of the track in 1990 and the average loading of each car are listed (this data was taken from the 3
, -. =.. -, - -, -
r
^,
i railroad's hazardous material report, entitled " Total Car Loads &
Trailer Loads").
The total quantity of certain commodities, such as butane and liquified petroleum gas, has increased since 1988;
- however, their quantities are such that they continue to not pose a hazard.
Additional commodities, such as morpholine, hexamethylamine, butyl chloride and ethyl other, were identified in the 1992 survey.
These had not been identified in the 1988 report.
R.G.
1.78 states that " frequently" shipped hazardous chemicals should be considered in the evaluation of control room habitability, and goes on to define frequent as more than 30 shipments per year for rail traffic.
The number of shipments of each of the newly identified chemical is less than 30; only five had greater than ten shipments.
Additionally, since these chemicals had zero shipments in the 1908 survey, the average annual frequency would be even less.
Therefore, it is concluded that these chemicals do not pose a hazard to the Waterford 3 Control Room personnel.
The analysis of the 1992 survey results indicate that the overall hazard probability from,, toxic chemicals being transporteg by rail is approximately 9.0X10 per year, which is below the 10 per year criterion.
Truck. Ship and Baroe sources Data on shipments of toxic chemicals in the Waterford 3 vicinity by truck, ship and barge were obtained. There is only one highway near Waterford 3 where a truck load spill of toxic chemicals could pose a possible hazard to the control Room.
This is Louisiana Route 18, which is a local road 600 feet from the 2
Reactor Building and does not carry through truck traffic.
Therefore, it was assumed that only shipments to or from facilities in the immediate vicinity (i.e., the respondents to the survey) would travel on this road.
It was found that shipments on this road do not pose a hazard to Waterford 3 Control Room personnel.
Ship and barge shipments listed in Table A-3 were found not to pose additional hazards.
In many cases, the maximum quantity of the given chemical was within the limits specified by R.G.-l.78-for stationary sources at the nearest distanco of the highway or river channel to the Waterford 3 Control Room.
Baued on a hydrographic map of the Mississippi River, the river channel was assumed to be 1,500 feet from the Control Room air intake.
4 I
o Chlorino Sources The largest chlorino sourcos in the Waterford 3 vicinity are the 500 ton storage tanks at occidental Chemical in Taft. The Waterford 3 control Room had already been evaluated with respect to a hypothetical rupture of the nearest such tank. This ovaluation was included in the report transmittod to the NRC by LP&L letter W3P85-3154, dated January 24, 1986.
As stated in the previous report, there should be no nood to repeat this analysis in the future unless other sources of chlorine are reported or unless the charactoristics of the Control Room or the chlorino detectors should change.
Overall Results of Toxic Chemical Hazard Analyses over 130 sourcos of toxic chemicals (storage tanks, materials in process, or materials in transit), wore analyzed.
None of those sources were found to poso an undue hazard to Waterford 3 Control Room personnel.
The results reported in the Waterford 3 FSAR Tablo 2.2-4 continues to be the bounding evaluation rosv?ts for material transported, stored, or processed at the facilities within a five milo radius of Waterford 3.
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o Table A-1 Industrial Facilities Storing Significant Quantities of Toxic Chemicals within Five Miles of Waterford 3 i
Name Location Agrico Chemical Co.' (formerly Becker Industries)
Taft i
Henry Martin Oil Co.
Laplace GATX Terminals Corp.
Norco Louisiana Power and Light Co.
Little Gypsy SES Montz.
Waterford 1 & 2 G.P.1 K111ona t
occidental Chemical Corp Taft
]
(formerly Hooker Chemical) occidental Chemical Co.-Taft Ammo 1ta Plant 1 Taft (formerly occidental Agricultural-Products)
Shell Chemical Co.3 Taft She11' offshore Inc.-Crawfish Gas Plant Taft Shell oil Company-(Including Shell Chemical)
Horco Trans-American Refining Corp.
Horco Union Carbide-Ind Chemical Div.
Taft (formerly Ethylene Oxide / Glycol Plant)
Union carbide (Linde Div.)
Taft Union Carbide-Star Plant 2 Taft--
Union Pacific Railroad' Taft Witco Chem 3 cal Corp. Argus Division 1 Taft-t t
Returned' - map ' with storage location marked 2Returned plot plan with stor69e locations.
marsed 3Returned Geological survey sep - with plant outline
' Produced computer printout of hazardous material headquartered in Tulsa, OK
i.
Table A 2 Names, Addresses. And Phone Numbers Of Respondents to 1992 Industrial Survey Initial Contact Actual Respondents Mr.R.O. Olivier o
Mr. R. A. Johnson Plant Manager Environmental Supervisor Agrico Chemical Co.
Agrico Chemical Co.
Taft Taft 7760 River Road 7760 River Road Hahnville LA 70057 Hahnville La 70057 (504) 783 6872 (504) 783 6872 Mr. Fred Cerstner Mr. Mark Forman o
CATX Terminal Corp.
Environmental Manager.
P.O. Box 157 CATX Tetuinal Corp. P.O. Box 157 Norco LA 70079 Norco LA 70079 (504)443 2511 (504)764 3300 o
Robert O. Bourg
?
Supervisor Plant Chemistry Loululana Power 6 Light Co.
Little Gypsy SES Route 1 Box 1000 La Place LA 70068 (504)464 0101 Mr. Cus Von Bodungen o
Chemistry Supervisor Louisiana Power-1 Light Waterford SES Unit 1-6 2 P.O. Box 50 K111ona La 70066 (504)465 8107 Mr. Vayne Middlebrook o
Henry Martin 011 Co.
P.O. Box 187 La Place LA 70068 (504)652 9783 Mr. George Haas Mr. James A.- Anderson o
Occidental Chemical Environmental Supervisor P.O. Box 74 Taft Plant Hahnville LA 70057
.(504)783 6661 Occidental Chemical Corp.
P.O. Box 74-Hahnville La 70057 (504)783 6661
i.
t 4
Table A 2 5
4 Mr. Jesse Payne o
Occidental Chemical Corp.
Taft Ammonia Plant P,0. Box 74 Hahnville IA 70057 (504)783 6661 Mr. Paul Barletta o
Mr. A. C. Sullivan Environmeneal Eng.
Environmental Engineer Shei: Chemical Co.
Shell Chemical Co.
P.O. Box 160 P.O. Box 160 Hahnville LA 70057 Hahnville LA 70057 (504)465-5230 (504)465 5230 Mr. M.J. Bourg Mr. T.J. Madere shell offshore Co.
Shell Offshore Co.
No. Terrebonne Gas Plt Crawfish Gas Plt P.G. Box 1 P.O. Box 1 Cibson La 70356 Cibson La 70356 (504)575 3369 or 588-8412 or 588 7730 Mr. Jonathan Topper Mr. R.L. Jacoby o
Envir.conser. Dept.
Manager Environmental Conservation She,11 011 Co.
Shell Oil Co.
P.O. Box 10 P.O. Box 10 Norco, IA 70079 Norco IA 70079 (504)465 7401
...f-(504)465-6674 i
Mr.Cary Karr o
Plant Manager Trans American Refining Corp.
P.O. box Drawer 537 Good Hope LA 70079 (504)764-8611 Mr, Art James Mr. J.L. ioung o
Safety Eng.
Union carbide Corp.
Union Carbide Corp.
Indusc. Chem. Div.
Indus. Chem. Div.
Rive Road P.O. Box 50 Hahnville La 70057 Hahnville LA 70057 (504)468-4223 (504)468-4586 Mr. Stan Dufrene Union Carbide Chuelcal Corp.
Indus. Chem Div.
Bldg 631 River Road Hahnville IA 70057 i
_m_
2 e,
TJi a A 2 o
Ms. Ramona Owens Office Administrator 4
Linde Div.
Union Carbide Corp,
'j P.O. Box 5 l.
Hahnville 1A 70057 (504)468 7302 i
t j
o Mr. V J. Aaron Union Carbide Corp.
Star Plant a
P.O. Box 110 Hahnville 1A 70057 (504)468-7302
,i Mr. James Goletz Mr A. H. Rodgers-o
itco Chem. Corp.
Environmental Sup er:
e Argus Div.
Vitch Cheeltal Cc P.O. Box 310 P. O.
h.-
.10 Hahnville La 70058 Hahnville LA 70058 (504)783 6201 (504)783 6201-Mr. Leo Tierney Sandy Tovey o
Union Pacific RR Union Pacific Rai1 Road j
Room 1104-Information & Communication System
^
1416 Dodge Street 1416 Dodge Street-Omaha Nedraska 68179 Omaha Nebraska 68179
{
(402)271-4400 (402)271-3674-
}
District Engineer
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U S. - Army Engineer District New Orleans LA 70160 Actual Respondent o -
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r TABLE A-3 (Sheet 1 of 13)
Revision 3 (4/92)
HAZARDOUS CARGO CARRIED IN WSES-3 VICINITY IN'1990 gli THE UNION PACIFIC RAILROAD'-
)
Number Avg._Wt.
3 3
STCC No.
Tvoe of Materia 1 of cars (tons) 4091105 AMMUNITION FOR CANNON WITH EXPLOSIVE 3
13.09 PROJECTILE 4902420 PROPELLANT EXPLOSIVE, SOLID 33 88.66 l
4903520 COMMON. *tEWORKS 72 18.00-l 4904120 CHLORINE 6034 88,70 5
4904210 ANHYDROUS AMMONIA 6819 76.85 4
4904271 HYDROGEN CHLORIDE, REFRIGERATED LIQUID-68 69.69 4904290 SULFUR DIOXIDE 14 77.78 4904501 AIR, COMPRESSED 1
18.00 4904503 ARGON, REFRIGERATED LIQUID 12 83.66 4904509 CARBON DIOXIDE, REFRIGERATED LIQUID 317 74.40 4904516 DICHLORODIFLUOROMETHANE-2 50.00 4904517 NON-FLAMMABLE GAS, N.O.S.
1 25.00 4904552 CHLORODIFLUROMETHANE 2
61.50 l
4904820 FIRE-EXTINGUISHER 2
17.50 4
4904879 AMMONIA, ANHYDROUS-20 76.85 4905510 DIMETHYLAMINE, _
29 67.60-ANHYDROUS 4905520 METHYL MERCAPTAN 336 74.20 4905530 METHYLAMINE, ANHYDROUS-28 58.47 4905540
' TRIMETHYLAMINE, AMHYDROUS 37 50.42 4905704 BUTADIENE, INHIBITED 1076 76.86 4905706 BUTANE 299 74.64 m.-
. ~
a.
h--
J TABLE A.3 (Sheet 2 of 13) Revision 3 (4/92)
HAZARDOUS CARCO CARRIED IN WSES-3 VICINITY IN 1990 ON THE UNION PACIFIC RAILROADI d.
Number Avg. Wt.
2 STCC No.
Type of Materia 13 of cars (tons) 4905707 LIQUIFIED PETROLEUM GAS (Butene gas, 167 70.51 liquified) 4905711 LIQUIFIED PETROLEUM CAS (Butylene, 2
71.00 impure) 4905715 COMPRESSED CAS, N.O.S.
1 18.00 4905726 CICARETTE LICIITER (flammable gas) 11 17.66 4905748 ISOBUTYLENE 89-71.35 4905750 IS0 BUTANE 1
70.00 4905752 LIQUIFIED PETROLEUM CAS 538 70.64 4905761 METHYL CHLORIDE 288 81.67 4905782 PROPYLENE 133 66.68 4905792 VINYL CllLORIDE 656 85.80 t,905795 VINYL METHYL ETHER 37 80.66 l
4906011 ALUMINUM ALKYL 17
-40,51 4906420 ACRYLONITRILE 53 74.12 l
4906610 ETHYLENE OXIDE 1309 78.85 4906620
--PROPYLEhE OXIDE 101 73.72 4907210 ACETALDEHYDE or EfHYL ALDEHYDE 342 92.90' l
4907215 ETHYL ACRYIATE, INHIBITED -
321 86.64 i
l 4907219 FIAMMABLE LIQUID, N.O.S.5 37 78.57 (Dicyclopentadiene)-
4907230 ISOPRENE.
1-74.00 4907245-METHYL t.CRYLATE, INHIBITED 1
11.00 4907250 METHYL METHACRYLATE MONOMER, 842 82.20
.m..--
..,,... ~
_ -. _. - - - - _ - _,. - _, - -.... - ~,
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- INHIBITED TABLE A-3 (Sheet 3 of 13)
Revision 3 (4/92) i HAZARDOUS CARGO CARRIED IN VSES-3 VICINITY IN 1990 ON THE UNION PACIFIC RAILROADI 4
Nataber.
Avg.'Vt.
l STCC2 No.
Type of Materials of cars (tonsL 4907265 STYRENE MONOMER, INHIBITED 1039 89.38 j
_4907270 VINYL ACETATE 672 89.89 j
4907280 VINYLIDENE CHLORIDE, INHIBITED-66 86.33 3
4907420 EPICHIAROHYDRIN 277 89.84 l
4907422 FIAMMABLE LIQUID, POISON 0US, N.O.S.
78 67.;2 1
4907625 METHYL DICHLOROSIIANE 3
87.00 4907815
. DIETHYIAMINE 1
74.60 4
4907820 DIMETHYIAMINE. AQUEOU 2
80.00 4907829 FLAMMABLE LIQUID, CORROSIVE, N.O.S.
6 81'.27 1
3 4907846
- MORPH 0LINE 3
82.36
{
4907872 HEXAMETHYLENE-D',AINE 15 86.25 4907877 TRIETHYIAMINE
' 7.
44.40 j
4908105-ACETONE 73 72.72 4908110 BENZENE 4
83.68' i-4908115-BUTYL CHLORIDE 4-4 76.82 4908119L
'BUTYRALDEHYDE.
-16 67.50-4908125
. CARBON BISULFIDE, CARBON DISULFIDE 34.
84.71 4908144 FIAMMABLE LIQUID, N.O.S.
3 64.66' i.
(Butylene oxide) i' 4908156
- ETHYL ETHER 9-45.24
)
--4908160
' PROPYL MERCAPTAN-1 84.32
{-
4908162 ETHYL CHLORIDE 4
62.00 t
4908176 CASOLINE 2
83.48 i
l 1
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TABLE A 3 (Sheet 4 of 13) Revision 3 (4/92)
Lil2ARDOUS CARGO CARRIED IN USES-3 VICINITY IN 1990 ON THE UNION PACIFIC RAI,lE0ADA Number Avg. Wt.
2 STCC No.
Type of Materia 1 3 of cars (tons) l 4908178 CAS01 INE 6
82.86 1
4908183 HEXANE 6
80.17 1
4908185 FLAMHiBLE LIQUID, N.O.S.5 62 91.09 (Isobutyraldehyde) 4908192 ISOf3TANE 32 38.60 l
j 4908194 ISOPROPYIRiINE 64 49.47 4908195 DIIS0 PROPYL ETHER 11 82.64 4908234 FIhiMAELE LIQUID N.O.S.
21 91.09 i
4908255 PENTANE 21 17.50 4908290 TETRAHYDROFURAN 3
80.17 j
4909103 ALCOHOL, N.O.S.
1 90.14 l
3 4909105 A'E0HOL, N.O.S.
54 90.14 4909109 ALCOHOL, N.O. S.
2 90.14 4909117 BUTYL ALCol!0L (1-butanol) 33 91.54 4909128 BUTYL ACETATE 30 95.41
- 4909129 BUTYL ALCOHOL (2-butanol) 12 90.41 4909131 BUTYL ALCOHOL (Isobutyl alcohol).
18
-93.59 4909139 CY"'4HEXYERIINE 1
66.00 4
4909141 DENATURED ALCOHOL 243 81.12 4909146 ETHYL ALC0HOL 14 80.06 1
4909155 DIOXANE 1
42.00 4909160 ETHYL ACETATE 18' 88.06 4909163 ETHYL BENZENE 4
41.10 i
.. ~ _. _ _ _ _. _ _. _. _....,..
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TABLE A-3':
' (Sh'eet 5_ of 13). Rovision 3 (4/92) i
.i llAZARDOUS CARCO CARRIED IN USES-3 VICINITY IN 1990 ON THE UNION PACIFIC RAILROADA i
l Number Avg, WC.
2 STCC No.
Type of MateriaI3 of cars (tons) t i
4909183 FIAMMABLE LIQUID, N.O. S.
2 91.09 4
i 4909195 AMY1 AMINE 1
32.00 f.
l 4909205 ISOPROPANOL or ISOPROPYL.*.LCOHOL 167 86.73 4909207 ISOBUTYL ACETATE 17 94.35 1
4909208 FIAMMABLE LIQUID, N. O. S. 5 7
30.50 l
(isobutyronitrile) i 4909210 ISOPROPYL ACETATE 40 91.46 i-
,1 4909215 FUEL, AVIATION, TURBINE-19 91.46 i
j 4909219 FLAMMABLE LIQUID, N.O.S.
106 84,96 j
(diethyl carbamate) i 1
4909220 MERCAPTAN MIXTURE 1
45.00-
{
4909225 METHYL BUTENE 2
56.42
{
4909230 METHYL ALCOHOL of METHANOL 691 94.41
~
j
[
4909233 ALCOHOL, N.O.S.
2 90.14-4909237 METHYL A'.COHOL or MOTHANGL (contaminated) 1 92.00
{
4909239 FIRIMABLE LIQUID,' N.O.S. (waste organic 1
45.00
,I chlorides) 4909243 METHYL ETHYL KETONE 21 86.45
+
4909266 PINENE 1
82.00 i
l.
4909267 PROPYL ALCCHOL (1-propanol)
.160 75.15.
1, 4909268-PROPYL ACETATE 26 95.50 s
4909269 PROPYLENE DICHLORIDE 1
74.32 4909305 TOLUENE 223
-84.35 I
4909328 FLAMMABLE LIQUID, N.O.S.
49
-32'.34 1
i
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TABLE A - (Sheet 6 of 13) hevision 3 (N91) i HAZARDOUS CARCO CARRIED IN VSES-3 VICINITY IN 1990 ON Tile UNION PACIFIC RAILROADI I
1 Nwnber Avg. Vt.
2 STCC No.
Type of Materia 13 of cars (tons)
{
4909349 XYLENE 4
64.35 6
l 4909350 XYLENE 8
.83.93 i
j 4909351 XYLENE (paraxylene) l' 85.57
)
4909356 TOLUENE 3
84.35 l
4909365 FIJiABLE LIQUID N.0.S.
7 91.0?
I 4
4910103 ALCOHOLIC BEVERACE 3
85.00 4910107 FLAMMABLE LIQUID N.O.S.
8.
84.36 i
i 4910109 ADHESIVE 14 15.00 i
j
-4910142 COATING SOLUTION 3
10.00 j
4910147 COMPOUND, CLEANING, LIQUID (flammable) 1
-78.00 l
4910153 PAINT RE1ATED MATERIAL (flammable) 3 33.00 l
{-
4910154 PAINT RELATED MATERIAL 3
34,36 4910165 CRUDE OIL, PETROLEUM 3
- 82.00.
[
4910168 FLAMMABLE LIQUID, N. O. S.
2 75.95 4910171 FIAMMABLE LIQUID, N.O.S.
1 84.00 4910176 PAINT 1
-35.00 i
4910185 FIA%2LE ' LIQUID, N.O. S.
L150 175.951 4910197 INSECTICIDE, LIQUID N,0.S.
5
- 70. 72 L; i
4910220 ASPFALT, CUTBACK 1
25.00 4910243 PETROLEUM, OIL 3
73.46 l'
4910245 OIL, N.O.S.,-or PETROLEUM OIL, N.O.S.
-614 91.42 4910251 PAINT 2
33.36'-
4910256 PETROLEUM DISTILIATE 1
72.00 4
i e
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+ 1
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4 l _ 4;.
TABLE A-3 (Sheet 7 of 13) Revision 3 (4/92) j; HAZARDOUS CARCO CARRIED IN USES-3 VICINITY IN 1990 j;
ON THE UNION PACIFIC RAILROADA i
i Number Avg. Wt.
2 STCC No.
Type of Materia 13 of cars (tonsL i
j-4910259 PETROLEUM NAPHTA (f: amable) 73 79.96 i
4910269 PETROLEUM NAPHTA 1
70.73
{
4910280 RESIN SOLUTION 1
97,00 l
491u282 RESIN SOLUTION (plastics, resins or 2
92.00 i
gums, nec', liquid)
{'
4910295 PAINT 2
33.25 4910308 ALCOHOLIC BEVERACE 1
90.00 i
4910309 ALCOHOLIC BEVERACE 1
88.00-J j
4910313 TURPENTINE 20 81.43
)
4910320 FLAMMABLE LIQUID, N.0,S.5 (pulp mill 71-50.46
}
liquid) i
[
4910361 PETROLEUM OIL 1-13.00 4
~
4910411 ADHESIVE 14 15,46 1
4910426 FLAMMABLE LIQUID, N.O.S.
1-32.00
{
4910430 FLAMMABLE LIQUID, N.O.S.
1 35.00 4910456 FIAMMABLE ' LIQUID 1
84.00 4910489 FIAMMABLE LIQUID, N.O.S. (resinous 90 88.48 j,_
petroleum residue) 4910504 ADHESIVE, N.u.S. (flammable)-
1-15;00 i
4910525 FLAMMABLE LIQUID, N.O.S; 1
82.00 i
4910535-FIAMMABLE LIQUID, N. O. S.
'l_
_76.00 3 -.
l_
4910555 FIAMMABLE LIQUID,. N.O.S.
l' 88.00 t
j 4912215 COMBUSTIBLE LIQUID, N.O.S.
508 87.83
-(butyl acrylate) 1-t k
I
-a m.
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TABLE A-3 (Sheet 8 of'13)- Revision 3 (4/92) l 4
4 IIAZARDOUS CARCO CARRIED IN USES-3 VICINITY,,).d 1,9_,92 l
l ON THE UNION PACIFIC RAILROAD' Number Avg. Wt.
l STCC No.
Type of Materia 13 2
of cars (tons) 4912220 COMBUSTIBLE LIQUID, N.O.S. (ethyl hexyl 61 85.16 i
acrylate) l l
4913103 ALCOHOL, N. O. S. (combustible liquid) 57 83.28 4913106 ALCOHOL, N.O. S 1
82.00 4913111 BENZALDEHYDE 18 82.38 4913116 ETHYLENE GLYCOL MON 0 ETHYL ETHER 4
D7.00 4913117 ETHYLENE CLYCOL MON 0 ETHYL ETIIER ACETATE 5
88.00 4313144 FORMALDEHYDE SOLUTION, FORMALIN 11 88.63 49131t.7 COMBUSTIBLE LIQUID, N.O.S.
1 67.52 4913155 COMBUSTIBLE LIQUID, N.O.S.
27 64.36 4913158 ALCOHOL, - N. O. S. (octyl alcohol, not-82 77.62 perfumery grade) 4913162 ETHYLENE CLYCOL MONOMETHYL ETHER
'90 88.15-4913168 FORMALDEHYDE SOLUTION or FORMALIN 168-87,30 4913169 FORMALDEHYDC SOLUTION 2
86.25-4913175 COMBUSTIBLE LIQUID, N.O.S.
8 77,52 4913178 CottB'.1STIBLE LIQUID 2
84.36 4913179' COMBUSTIBLE LIQUID, N.O.S.
-197 88.20 (cyclohexanone) 4913194 COMBUSTIBLE LIQUID, N.O.S.
18 69.00 (glycol ethers) 4915147 COMPOUlO, CLEANING, LIQUID (combustible) 3 _-
4.00-4915165_
CRUDE OIL PETROLEUM (combustible) 2 13.00-4915170-PINE OIL 1
67.00 s
l TABLE A-3 (Sheet 9-of 13) _ Revision 3 (4/92)
HAZARDOUS CARGO CARRIED IN USES-3 VICIJLITY IN 1990 ON THE UNION PACIFIC RAILROADI Number Avg. Wt.
2 STCC No.
Tvoe of Materia 13 of cars (tona.)_
4915185 COMBUSTIBLE LIQUID, N.O.S.
59 84.09 4915'45
- OIL, N.O.S., or.'ETROLEUM OIL, N.O.S.
160 77.44 i
4915251 PAINT 1
18.00 4915259 PETROLEUM NAPMTHA 178 81.94-4915287 PETROLEUM DISTILLATES (petroleum 75 93.14 naptha, naptha) 4915320 ASPHALT, CUT-BACK or ROAD ASPHALT 6
70.33 (combustible) (asphalt petroleum liquid and tall oil pitch, mixed) 4915325 DIACETONE ALCOHOL 1
46.00 4915401 ALCOHOL, N,0.S. (alcohol distillates) 1 90.32 4915518 CYCLOHEXANOL 51 84.61 4915535 COMBUSTIBLE -LIQUID, N.O.S.3 (additives, 2
29.50
<50% petroleum) i 4915560 COMBUSTIBLE LIQUID, N.O.S. (chemical.
3 68,00 plant vaste) i '
4916141 PHOSPHORUS; WHITE or YELLOW, IN WATER:
1 97.63 1
4917332 FIAMMABLE SOLID, N.O. S.
3-14.54-l
=
4918310 AMM0NIUM NITRATE FERTILIZER (<.2% carbon)_
4 I
i l
i e
4
-4 p-g 4-y g
=m-y yi y-r m-+s-
'n<-
+F,is-1
i 4.-
)
TABLE A-3 (Sheet 10 of 13)
Revision 3 (4/92)
HAZARDOUS CARGO CARRIED IN VSES-3 VICINITY IN 1990 i
ON THE UNION PACIFIC RAIIROADA Number Avg. Wt.
2 STCC No.
Type of Mater'a13 of cars (tons) i l
4918765 OXIDIZING MATERIAL, N.O.S.
(Sodium 353 87.30 j
chlorate and sodium chloride, in water i
solution) 4918775 INDROCEN PEROXIDE SOLUTION (8%-40%)
3 39.00 i
{
4918776 HYDROCEN PEROXIDE SOLUTION (40%-52%)
69 93.49 i
4920125 HYDROCYANIC ACID, LIQUIFIED 23 15.00 l
j 4921210 CARBOLIC ACID, LIQUID or PHENOL, 2
86.25 LIQUID SOLUTION 1
4921220 CARBOLIC ACID, PHENOL 639 86.90 4
4921410 ANILINE OIL, LIQUID 27 84.64 l
4921445 MOTOR FUEL ANTIKNOCK COMPOUND or 1
52.61 i
ANTIKNOCK COMPOUND j
4921475 POISONOUS LIQUID, N 0,S.,
POISON B, 13 52.66 LIQUID, N.O.S.
3 4921479 POISONOUS LIQUID, N.O.S.,
(Poison B, 6-20.00 weed killing acids) 4921575 TOLUENE DIISOCYANATE 216 78.92 i
4921674 ORGANOPHOSPHORUS PESTICIDE,-LIQUID-2 13.33 4923115 ARSENIC TRIOXIDE, SOLID or ARSENIC, 16 19.64 WHITE, SOLID 4930024 INDROCEN FLOURIDE or HYDROFLUORIC 1
75.00 ACID, ANHYDROUS 4930026 HYDROFLU0SIL70If 41 90.00 4930030 OLEUM-(fuming sulfuric acid)-
3 89.63 4930040.
SULFURIC ACID-656-97.47 4930228 HYDROCHLORIC ACID' 72 89.92
~ - -
o l
4 0,
i
\\
TABLE A-3 (Sheet 11 of 13) Revision 3 (4/92)
HAZARDOUS CARGO CARRIED IN VSES-3 VICINITY IN 1990 1
ON-THE UNIpN PACIFIC RAILROAD i
Number Avg. Wt.
2 STCC No.
Type of Material 3 of cars (tons) 4930247 PHOSPHORIC ACID (fertilizer solution, 1216 95.85
<77% phosphoric anhydride by vt) l 4530248 PHOSPHORIC ACID 41 27.40 i
4931303 ACETIC AC1D, CLACIAL 26 89.23 4931304 ACETIC ANHYDRIDE 60
-81.93 4931404 ACID, LIQUID, N.O.S.5 (organic) 43
-84.00 I
4931405 ACRYLIC ACID 364 90.05 4931417 CRESOL 1
66.00 4931448 PROPIONIC-ACID 3
93.92-4932359 PHOSPHORUS TRICHLORIDE or PHCSPHORUs 422 c5.31 CHLORIDE 4932380 SULFUR CHLORIDE or CHLORIDE OF SULFUR 115 92.36 4
(sulfur monochloride) 4935030 HYDRAZINE, AQUEOUS SOLUTION 2
17.00 4935220 ALKALINE LIQUID, N.O.S. (corrosive) 21 83.11 4935225 POSASSIUM HYDROXIDE, DRY, SOLID, FLAKE, 1
18.00 BEAD or CRANULAR or CAUSTIC POTASH 4935230 POTASSIUM HYDROXIDE, LIQUID SOLUTION or.
93 93.19 CAUSTIC POTASH, LIQUID 4935235 SODIUM HYDROXIDE, DRY, SOLID, FLAKE, 18 80.61 BEAD, or.CRANULAR cr CAUSTIC POTASH 4~35240 SODIUM HYDROXIDE, LIQUID SOLUTION or 308 92.32 CAUSTIC SODA, LIQUID SOLUTION 4935243 SODIUM HYDROXIDE, LIQUID SOLUTION or 10193 96.13 CAUSTIC SODA, LIQUID SOLUTION
(>48% water)
~.. -.. _... _..
i
.l'..
I'
- 1. -
p TABLE A-3 (Sheet 12 of 13) Revision 3 (4/92) i HAZARDOUS CARCO CARRIED IN WSES-3 VICINITY IN 1990 ON THE UNION PACIFIC RA!IROAD1 l
Number Avg. Vt.
l STCC2 No.
Tvoc of Materia 13 of cars (tons) 4 4935248 CORROSIVE LIQUID, N.O.S.5 (sodium 10193 96.13 i
solution waste) j 4935262 SODIUM HYDROXIDE 3
73.00 4935268 SODIUM HYDR 0 SULFATE 3
84.23
{
4935278 COPROSIVE LIQUID, N.O.S.-(de-inking 4
18.00 compounds) 4935628 ETHYLENEDIAMINE.
4 54.31
)
4935631 CORROSIVE LIQUID, N.O.S. - (diethylene 41 73.58 triamino)-
i 4935645 HEXAMETHYLENE DIAMINE SOLUTION 1967
'87.38 4935665 MON 0ETHAN0LAMINE or ETHAN0LAMINE 3
72.00 l'
4935674 CORROSIVE. LIQUID, N.O.S.
26 88.75
]
(aminoethylethanolamine) 4936018 CORROSIVE LIQUID 618 81.50 4936110 BROMINE 1
21.00 4936370 1,2,3,6-TETRAHYDROBENZALDEHYDE.
3 87.00 4936540 CORROSIVE LIQUID, N.O.S'.
39 79.97-4936545 CORROSIVE SOLID, N.O.S.
2 73.80 4936556 BATTERY, WET,-FILLED WITH ACID 2
72.08 4936595 CORROSIVE LIQUID, N.O.S.-(waste-1 8.00 etchant solution) 4940310 CHLOROFORM (not technical grade)-
'269
'92.67 4941132 DICH1DROMETHANE' 42 90.25
'4941161 MALEIC ANHYDRIDE-108 87.03 4941170
. SODIUM DICHROMATE 1-90.00
.. -.. _... -. - ~.. _ _ _ _.. -.... _
.m J
l
)
i -.. - b TABLE A-3
-(Sheet 13 of 13) Revision 3_(4/92) l HA7.ARDOUS CARGO CARRIED IN USES 3 VICINITY IN 1990 j.
ON THE UNION PACIFIC RAILROADA i
Nunbar Avg. Wt.
2 1-STCC No.
Type of Material 3 of cars (tons) 4941171 TRICHLOROETHYLE!!E 8
95.38 i
v 1
4941176 1,1,1 TRICHLOR0 ETHANE (ethyl chloroform) 132 91.82-4 4950110 ACIDS, CHEMICALS & OTHER ARTICLES, FIXED 24 72.70
}
IDADS 1]
4950130 FREIGHT FORWARDER TRAFFIC 51 16.33 4950150 ALL FREIGHT RATE SHIPMENTS, NEC', or 398 10.89 TRAT J.R-ON-FLAT-CAR SHIPMENTS
)
4960132 HAZARDOUS SUBSTANCE, LIQUID or SOLID, 807 84.92 N 0.S.
4966110 ADIPIC ACID 1823 92.'67' i
i 4966756 AMMONIUM THIOSULFATE (solution) 6 99.25 TOTAL NUMBER OF CARS 58174
(
1 j
NOTES:
1.
Data furnished by Union Pacific Railroad--includes all hazardous materials. passing j
through Edgard Station,- LA. Dufresne. LA or any points in between
~
4 2.
Numerical. designation from SJandard Transportation Commodity Code Tariff ~STCC
{
6049-T,-. issued by J. R. Rogers, TPO, Western Railroad Traffic Association.
3.
Description of material conforms to 49 CFR 172.101, additional description (lower cass type) from STCC Tariff (see note 2.)
4.
NEC - not elsewhere classified 5.
N.O.S. - not otherwise specified s'
6.
N/A - not gvailable I
i 1
e h
... 4
.- t v - + - -~
--.w -
~
D TIBLE A-4 HAZARDOUS FREIGHT TRAFFIC ON T]LF.
S B]SSISSIPPI RIVER. SHIPPED PAST RIVER MILE 129 IN 1989 Total Quantity Commodity (Short Tons)
Crude Petroleum 32,190,308 Ordinance and Accessories 3
l Sodium Hydroxide 1.116,163 Crude Tar, Oil, Cas Products 635,979 Alcohols 428,408 Benzene and Toluene 52,390 4
Sulphuric Acid 68,445 Basic Chemicals and Products, NEC*
1,445,275 Plastic Materials 2,753.
Synthetic Rubber 2,769 Drugs 140 Soap 2,616
- Paints 478 Asphalt and Pitches (Building.Mati 247,538 Coke, including Petroleum Coke 1,041,514 Rubber and Misc. Plastic Products 560 Gum and Wood Chemicals 3,372 Nitrogenous Chemical Fertilizers 1,590,476 Potassic Chemical Fertilizers 457,926 Phosphatic-Chemical Fertilizer 122,344 Insecticides, Disinfectants 63
- Fortilizer and Materials, NEC*
2,295,587 Gasoline 3,417,769 Jet Fuel 674,318 Kerosene 101,921-Distillate Fuel 011 1,639,585-Residual Fuel 011-6,478,502' Lubricating oils anc Creases 2,538,569 Naphtha, Petroleum Solvents 1,928,f*8 Liquified Cases 355,803 Petroleum and Coal Products, NEC*
44,506' Dept. of Defense-& Science ***
0 Miscellaneous 18,945
]
NEC Not Elsewhere Classified Military cargo moved in Department of Defense Vessels is omitted from i
these statistics R
" Export shipments under various foreign aid programs. on Department : of Defense operated vessels which affect national security are not published -
in teras of the individual commodities shipped.
- Instead' a lump sum tonnage figurc is compf id and appears'as commodity coded Department of Defense,-d Science."'
i Source:
Hasett, Susan, _ Corps of Engineers, National Waterways and Harbors
- Office, Dept.
of the Army, Corps _ of Engineers, Personal Communication, 0ctober 25, 1991, Waterborne Commerce of the United -
States, 1989 Department of the Army Corps of Engineers -
i
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