ML20101F271

NPDES Noncompliance Notification:Cooling Water Additive & Trial for Circulating Water Sys Will Be Conducted for 3-month Period.Chemical Will Be Injected Twice/Day for 1 H Duration.Slimicide Will Be Considered for Permanent Use

ML20101F271
Person / Time
Site:	Perry
Issue date:	06/12/1992
From:	Lyster M CENTERIOR ENERGY
To:	Jackson K NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM), OHIO, STATE OF
References
NUDOCS 9206240356
Download: ML20101F271 (5)

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CENTERDOR i ENERGY 1

uasi Address' 1

i PERRY NUCLEAR POWER PLANT PO BOX 07 ggagg l 10 CENTER ROAD PERRY, OHIO 44081 VICE 'PF90ENT NUCLEAR PERRY, OHIO 44081 (216) 259-3737 June 12,1992 -

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PY-CEI/0 EPA-0155L i

l Hs. Kim Jackson '

i Ohio Environmental Protection Agency i Division of Vater Pollution Control j Enforcement and Compliance Section

. 1800 Vatermark Drive, P.O. Box 1049 Columbus, Ohio 43266-0149 l Res Perry Nuclear Power Plant

NPDES Permit No. 3IB0016DD

{ Cooling Vater Additive Trial for i Circulating Vater System i

Dear Ms. Jackson,

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The Perry Nuclear Power Plant has enlisted Betz Industrial to determine the j effectiveness of Slimicide C-78P (a solid bromine / chlorine donor) for slime and i algae control in the plant circulating water system. The trial period vill be

! three months. The chemical vill be injected tvice per day, for one hour j

duration. The discharge vill be dehalogenated using the existing sodium sulfite addition system and combined vith untreated service vater prior to entering state waters.

1 During this trial period, the circulating vater system chlorination system vill

, not be used unless the trial is discontinued; however, plant service water and

, emergency service vater vill continue to receive routine chlorine treatm"nts.

l Based on the success of the trial and your approval, the Slimicide vil_ oc

considered for permanent use.

l Attachments 1 and 2 contain the information required in accordance with Ohio ,

j EPA procedures. Our intention is to begin the trial upon receipt of your ,

i approval; we vould appreciate your notifying us of the results of your l evaluation as soon as possible. Please contact Louise Barton at (216) 259-3737 i ext. 5512 with your results, or if you have questions.

4 Sincerely, Michael D. Lyster

! MDL: 1kb:ss i I

cc: NRC Document Control Desk i

NRC Project Manager q, NRC Resident Inspector

() NRC Region III

CJ B. Hall - OEPA Northeast District Office fg Opeta'eg compomet C.eveioN f;ecmc Wwour g

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I tvece d s" 9206240356 920612 l

' PDR. ADOCK 05000440 - -l s PDR 1

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PY-CEI/0 EPA-0155 L l Attachment 1 Page 1 of 1 Cooling Vater Additive Information l

l 1. The name of the additive to be used and general product information.

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{ Additive Name - Betz Slimicide C-78P 2

a. MSDS - Attachsent 2 b,c. Bromo-dichloro-dimethylhydantoin (a solid bromine / chlorine donor) i d. Specified use - To control slime and algae in the plant circulating water system

e. EPA Registration No. 5787-65-3876

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2. The concentration of the additive to be used (mg/1).

l The average concentration of the additive to be used is 0.5 mg/L.

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} a. Frequency - The additive vill be applied tvice per day.

b. Duration - Each application vill last one hour.

l c. Method - The Slimicide vill be fed manually via a Betz Brominator System.

3. The expected conce'itration of the additive .outained in the discharge

immediately prior to entering state surface waters.

a. The expected discharge concentration is <0.05 mg/L TRO.

i b. Dehalogenation vill be accomplished using the existing plant sodium i sulfite addition system, i

! 4. The average flovrate (HCD) and the outfal! number of each outfall

containing the additive.

l The volume of blowdown entering the d_ischarge stream vill be approximately 14.4 HGD. The total discharge flovrate vill be j approximately 82.08 HGD. The outfall is No. 3IB00016004.

, 5. Name of the state surface waters that receive the discharge.

Lake Erie.

6. Toxicity information for the additive.

96-hour LC50 - Rainbow trout - 0.87 mg/L 96-hour LC50 - Fathead minnov - 2.25 mg/L 48-hour LC 50 - Daphnia magr.a - 0.46 mg/L j

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• OG/10/02 10:09 t. Q002 A rfm.unic.ar 2 BETZ IJLHORATORIES,INC.

4636 t?MERTON ROAD, TREVOSE, PA. 19053 UElt, MATERIAL SAFETY DATA S!!EET EMERGENC*l TELEPHONE (11EAurit/ ACCIDENT) 800-877-1940 (PAGE 1 OF 3)

PRODUCT SLIMICIDE C-75P EFFECTIVE DATE 05-31-91 PRINTEDI 31-May~1991 REVISIOND TO DECTIONS: 2; EDIT! APPENDIX /9 PitoDUCT APPLICATION 1 SOLID MICROBIAL CONTROL AGENT.

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S ECTION 1------~~~~-HAZ ARDOUS INGRE01 ENTS ---~~----------

INFORMATIOW ON Pl!YSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED DY THE OS!!A HAZARD COMMUtf1 CATIONS STANDARD IS LIOTED. REFER TO SECTICN 4 (PAGE 2) FOR OUR ASSESSM11NT O." THE POTENTIAL ACUTE AND C11RONIC HAZARDS OF THIS FORMULATION.

1-HROMO-3 -CllLORO- 5, 5-DIMETHYLHYDANTOIN # * *CAS f 160 79 2 ; OXIDIZER ; EYE AND SKIN IRRITANT J PEI/TLVt NONE ; NOTE-MAINFACTUREll'S RECOM6 ENDED LIMITI 0. 2MG/M3

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SECTION !.----- -----TYPICAL PHYSICAL DATA---------------- --------

PHI 54 DISP. (APPROX.) 4.7 ODOR HALOGEN FL. PT. (DEG. P) : >200 P-M(CC) SP.GR. (7 0F)OR DENSITY: 65 LBS/CU.FT.

VAPOR PRESSURl;(unaHC) : NA VAPOR DENSITY (AIR =1): NA VISC cps 70F: NA %DOLUBILITY(WATER)I 1 EVAP. RATE NA WATER =1 APPEARANCEI W11ITE PHYSICAL STATF.: GRANUI.ES FREEZE POINT (DEG.F): NA

-- ---s E CTION 3 -----------REACTIVITY DATA------------------------

STABLE. OXIDIZER. SLOWLY RELEASES ItAIDGEN GASES hfREN CONTAMINATED WITH MOISTURE. MAY *tEACT WITH ALKALIES, LCIDS, ORGANICS OR REDUCING AGENTS. DO NOT CONTAMINATE. DETZ TANK CLEAN-OUT CATEGORY 'D'.

THERMAL DECOMPOSITION (DESTRUCTIVE FIRYS) YIELDS ELEMENTAL OXIDES.

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00/1042 10:03 Iy @ 003 Bli.'TZ MATERIAL SAFETY DATA SHEET (PACE 2 OF 3)

PRODUCT! SLIMICIDE C-78P

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S ECTION 4 -----------if3ALTH HA T. ARD E FFMCTS -------~~ ~ ~ ~~ ~---------

ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE i

MODERATELY IRRITATING.MAY DE CORROSIVE DI CCNTACT WITH NOIST SKIN.

ACUTE BYE EFFECTS ***

SEVERE IRRITANT TO THE EYES ACUTE RESPIRATORY EFFECTS ***

DUSTS CAUSE IRRITATION TO UPPER RESPXRATORY TRACT CIDtONIC EFFECTS OF OVEREXPOSURE ***

• NO EVIDENCE OF POTENTIAL CHRONIC EFFEC"TS.

MEDICAL CONDITIONS AGGRAVATED ***

NOT IOiOWN SYMPTOMS OF EXPOSUR3 4 ** '

MAY CAUGE REDNESS OR ITCHING OF SKIN.

PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS ***

MAY BE TOXIC 1F ORALLY INGESTED.

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SECTION 5---~~~------FIRST AID INSTRUCTIONS-~~~~-----------------

SKIN CONTACT ***

l REMOVE CLOT!!ING. WASH AREA WITil MEGE AMOUNTS OF SOAP fiOLUTION OR WATER FOR l

15 MIN.IMMEDIATELY CONTACT #11YSICIAN EYE CONTACT ***

IMMEDIATELY FLUSH EYES WITif WATER FOR 15 MINUTES.IMMEDIATELY CCHTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE ***

r REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIKST AID TREATMENT.IMMEDIATOLY CONTACT A PllYSICIAN.

DIGESTION * * *

, DO NOT FEED ANYTHING DY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM l DO NOT INDU::E VCMITING.IMMEDIATELY CONTACT PHYSICIAN. DILUTE CONTENTS Or STOMACH USINC 3-4 CLASSES MILK OR WATEtt

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SECTION 0 -----------SPILL, DISPOSAL AND F:;RE INSTRUCTIONS---~~----

SPILL INSTRUCTIONS ***

VENTILATE A2EA,USE SPECIFIED FROT4CTIVE EQUIPMENT. SPILLED MATERIAL WilIC11 CAN TOT DE RECOVERED FOR RE-USE,SMOULD BE PLACED IN A WASTE DISPOSAL CCMTAINER AND DISPOSED OF IN AN APPROVED PESTICIDD IANDFILL.SL1 PRODUCT IABEL STORAGE AND DISPOSAL INSTRUCTIONU.

PkODUCT RELEASES CHLORINE WHEN WET. SPILL RESIDUE MAY BE NEUTRALIZED WIT!! 3% HYDROGEN PEROXIDE SOIIJTION.

DISPOSAL INSTF JCTICNS ***

l WATER CONTFIINATED WIT!! THIS PRODUCT MAY BE SENT TO A SANITARY CEWER TM MTNENT FACILITY,IN ACCORDANCE WITH ANY IE AL AGREEMENT,A PEP:FD FMITE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PPn"rp IS)-

MANP O2 IN APPRCVED PESTICIDE FACILITY OR ACCORDING TO LASEL T UI'.TIONS FIRE E WiMMIIr; TING INSTRUCTIONS ***

FIREFIGt!TEPd SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (FULL PACE-PIECE TYPE) . PROPER FIRE EXTINGUISHING MEDIA FLOOD WIT!! WATEfL USE OF CO2 OR FOAM MAY NOT BE EFFECTIVE.

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00<10r02 10:10 C @ 004 1

i i DETZ MATERIAL SAFETY DATA SilEET (PAGE 3 OF 3)

! PRODUCT! SLIMICIDE C-78P

- ~ ~--S ECTION 7 --------- ~~S PECI AL PROTE CTIVE EQU I PMENT--------------- ~ ~

i USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE l RESPIRATCRS WITHIN USE LIMITATIONS OR EIME USE SUPPLIED AIR RESPIRATORS.

i VENTIIATION PROTECTION ***

l ADEQUATE VENTILATION IC MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS  !

l RECOMMENDED RESPIRATORY PROTECTION ***

IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIRELY, l USE RESPIRATOR WITl! ACID GASSES CARTRIDGES AND DUST / MIST PREFILTERS i RECOMMENDED SKIN FRCTECTION***

l GAUNTLET-TYPE RUDDER GLOVES,CI!EMICAL RESISTANT APRON i WASif OFF APTER EACli USE.REPIACE AS NECESSARY i RECOMMENDED EYE PROTECTION ***

} AIRTIGHT C11EMICAL GOCCLES

, -----SEC*rION 0 -----------STORAGE AND IIANDt.ING PRECAUVIONS -------------

i STORAGE INSTRUCTIONS ***

l KEEP DRUMS & PAILS CLOSED Wi!EN NOT IN USE.

KEEP DRY. DO NOT STORE AT HIGli TEMPERATURE OR NEAR OXIDIZADLES OR CCMBUSTIDLES

< HANDLING INSTRUCTIONS ***

i OXIDIZER. AVOID ALL CONTACT WITH REDUCING AGENTS, OI LS , GREASES, 1 OR l * * * * .GANICS ********.4.AMD A.CI.D.S .

.*n.**.***.........*..1e...**...........e......*..*.

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. ...M.SDG .......~....WAS ',mITTE.N TO COMP.LY

........ ........ WIT!! T.itE.OS}IA.ITAZARD COMMUNICATION STANDARD APPENDIX: REGULATORY INF0FMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO HETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE.

ANY CIIANCES Ill REGULATIONS WILL RESULT IN UPDATED VERSIONS OF T1 TIS DOCUMENT.

...TSCAs T!!IS IS AN EPA SICISTERED DIOCIDE AND IS EXEMPT FROM TSCA II;VENTORY REQUIREMENTS

. . . FIFRA (4 OCFP) : EPA REC . )M. 5785-65-3876

. . . REPORTABLE QUANTITY (RC) FOR UNDILUTED PRODUCT 1 l NOT APPLICADTI

... RCRA IF T11'S PRODUCT IS DISCARDED AS A WASTE,TRE RCRA HAZ ARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE i . . . DOT HAZARD / JN#/ER CUIDEf IS OXIDIZER UN1479/#35 i . . . CALIFORNIA SAYE DRINKING WATER ACT (PROPOSITION 65) MATERIALS: NONE

... SARA SECTIC.T 302 CIIEMICALS: NONT, l ... SARA SECTICt 313 CllEMICALS: tiONE

... SARA SECTIC;( 312 !!AZARD CLASS: IMMEDIATE(ACUTE), FIRE AND REACTIVE

...MIC11IGAN ClETICAL MATERIALS: NONE NFFA/HMIS HEALTil - 2 ; FIRE - 1 ; REACTIVITY - 1 ; SPECIAL - OXY  ; PE - C i

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