ML20097H126
| ML20097H126 | |
| Person / Time | |
|---|---|
| Site: | Calvert Cliffs  |
| Issue date: | 06/30/1984 |
| From: | Lundvall A BALTIMORE GAS & ELECTRIC CO. |
| To: | Murley T NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I) |
| References | |
| NUDOCS 8409200180 | |
| Download: ML20097H126 (83) | |
Text
{{#Wiki_filter:l SEMI-ANNUAL EFFLUENT RELEASE REPORT FOR CALVERT CLIFFS NUCLEAR POWER PLANT FIRST HALF - 1984 LIST OF ENCLOSURES TITLE PAGE Regulatory Limits 1 Maximum Perinissible Concentration 2 Measurements and Approximation of Total Radioactivity 3 Batch Releases 7 Abnormal Releases 8 Gascous Ef fluents - Summation of Releases 9 Gaseous Effluents - Isotopic Breakdown 10 Liquid Effluents - Summation of Releases 12 Liquid Effluents - Isotope Breakdown 13 Solid Waste Shipments 16 g b 8409200100 840630 DR ADOCK 05000 ,j i l
i CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL SEMI-ANNUAL REPORT 1/ SUPPLEMENTAL INFORMATION Facility - Calvert Clifis Nuclear Power Plant Licensee - Baltimore Gas & Electric Company I. REGULATORY LIMITS A. Fission and Activation Gases:
- 1. The instantaneous release rate of gross activity, except for I-131 and particulates with half-lives longer than eight days shall not exceed Qi g 5
(3.85 x 10 ) (MPC)i where Qi is the release rate in C1/sec for isotope i and MPCI is the maximum permissible concentration of isotope i as defined in Appendix B, Table II, Column I,10 CFR 20.
- 2. The release rates of gross gaseous activity shall not exceed 16 percent of the values specified in I.A.I. above when averaged over any calendar quarter. See Table I A, A3.
- 3. The release rates of gross gaseous activity shall not exceed 8 percent of the values specified in I.A.I. above when averaged over 12 consecutive months. See Table I A, A4.
_lf. Submitted in accordance with Section 5.6.1.b of Appendix B of the Environmental Technical Specifications
B. Iodines and Particulates, Half-Lives >8 Days:
- 1. The release rate from the main vents of I-131 and particulates with half-lives greater than eight days released to the environment as part of airborne effluents shall not exceed 2.0 uCi/sec.
- 2. The release rates of I-131 and particulates shall not exceed 8 percent of the value specified in I.B.1. above when averaged over any calendar quarter. See Table I A, B3.
- 3. It should be noted that " iodines" as used here includes only iodine-131 since the Technical Specifications only refer to it specifically. Such other lodines, i.e., lodine-133, lodine-135, etc., are treated as gross activity and are .'i.cluded in I.A.l. and I.A.2.
- 4. The release rates of I-131 and particulates shall not exceed 4 percent of the values specified in I.B.1 above when averaged over any 12 consecutive months. See Table I A, B4 C. Liquid Effluents:
- 1. The release rate of radioactive liquid effluents, excluding tritium and noble gases, shall not exceed 10 curies per unit during any calendar 4
quarter.
- 2. The radioactivity release concentrations in liquid effluents from the plant shall not exceed the values specified in 10 CFR, Part 20, Appendix B, for unrestricted areas.
II. MAXIMUM PERMISSIBLE CONCENTRATION 5 The MPC's used for radioative materials released in liquid and gaseous effluents are in accordance with Technical Specifications and/or are derived from the use of notes to Appendix B,10 CFR, Part 20. In all cases, the most restrictive (lowest) I MPC found for each isotope is used regardless of solubility. {
' The following limits were used to calculate the percent of applicable limit in Table 2A:
A .' Fission an'd Activation Products - Limit used I x 10-7 uCi/ml. This limit was used as given in the notes to Appendix B, Table II, Column 2 of 10 CFR 20. B. Tritium - Limit used 3 x 10-3 uCi/ml. This limit was used as given in Appendix B, Table D, Column 2 of 10 CFR 20. C. Dissolved and Entrained Gases - Limit used 3 x 10-6 uCi/ml. This limit was used as given in Appendix B, Table II, Column 2 of 10 CFR 20. Ill. AVERAGE ENERGY - not applicable IV. MEASUREMENTS AND APPROXIMATIONS OF TOTAL RADIOACTIVITY A. Fission and Activation Gases:
- 1. Batch Releases Prior to each batch release of gas from a pressurized gas decay tank, a sample is collected and analyzed for each significant isotope using a Ge(LI) detector. The total activity released is based on the pressure / volume relationship (gas laws) of the tank prior to and af ter the release.
Prior to and after the release of gas as a result of purging containment, samples are collected and analyzed for each significant isotope using a Ge(LI) detector. The total activity released is based on containment volume and purge rate with activity buildup while purging is being considered.
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- 2. Continuous releases During the release of gas from the main vents, samples are collected and analyzed at least weekly for each significant isotope using a Ge(Li) detector. The total activity released for the week is based on the total sample activity decay corrected to the midpoint of the sample period
- and multiplied by the main vent flow for the week.
B. lodine and Particulates: ! 1. Batch releases l Total activity released from a pressurized gas decay tank as lodines and particulates is measured by the same methods as fission and activation gases. l Prior to and after the release of gas as a result of purging containment, ! lodines are sampled using a charcoal filter and particulates are sampled using a particulate filter. These filters are analyzed for each significant isotope using a Ge(LI) detector. The total activity released is based on containment volume and purge rate with activity buildup while purging is being considered.
- 2. Continuous releases During the release of gas from the main vents, samples of lodines and particulates are collected using a charcoal and particulate filter l respectively. The filters are removed weekly and are analyzed for each l
significant isotope using a Ge(LI) detector. The total activity released j for the week is based on the activity found on the filters multiplied by the main vent flow for the week. The activity on the filters is corrected for decay and buildup during the sample period. These weekly f particulate filters are then composited to form monthly and quarterly composites at which time gross alpha and strontium 89 and 90 are analyzed.
C. Liquid Effluents:
- 1. Batch releases Prior to the release of liquid from a monitor tank, a sample is collected and analyzed for the concentration of each significant gamma energy peak to demonstrate compliance with Section I.C.1 above using the water flow rate in each discharge conduit into which the effluent is discharged at the time of discharge. The total activity released in each batch is determined by multiplying the volume released times the concentration of each isotope. The actual volume released is based on the difference in tank levels prior to and af ter the release. A proportional composite sample is also withdrawn for each week's releases, and this is used in turn to prepare monthly and quarterly composites for use in analyses of gross alpha and strontium 89 and 90.
- 2. Continuous releases Steam generator blowdown is sampled daily and these samples are used in turn to prepare a weekly blowdown composite based on each day's blowdown. The weekly composite is analyzed for each significant isotope using a Ge(LI) detector and these results are multiplied by the actual quantity of blowdown to determine the total activity released. The weekly composite is also used to prepare monthly and quarterly composites for use in analyses of tritium, gross alpha, and strontium 89 and 90.
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- d. Error in gas decay tank pressure.
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V. BATCH RELEASES 1984 ist 2nd Quarter Quarter A. Liquid:
- 1. Number of batch releases 6.60E+01 4.10E+01
- 2. Total time period for batch 3.59E+02 3.29E+02 release (hours)
- 3. Maximum time period for a 1.15E+03 1.19E+03 batch release (min) 4 Average time period for batch 3.27 E+02 4.81E+02 releases (min)
- 5. Minimum time period for a 2.00E+01 2.10E+01 batch release (min)
- 6. Average stream flow during periods 4.64E+06 4.64 E+06 of effluent into a flowing stream (liters / min of dilution water)
B. Gaseous
- 1. Number of batch releases 3.70E+01 4.10E+01
- 2. Total time period for batch 6.86E+03 8.40E+04 releases (min)
- 3. Maximum time period for a batch 3.15E+02 1.12E+04 release (min)
- 4. Average time period for batch 1.85E+02 2.05E+03 release (min)
- 5. Minimum time period for a batch 5.00E+00 2.00E+01 release (min) l 1
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- 1. - Number of re!aases e
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- 2. Total activity released (Curies) 2/1, s,. ,
B. Gaseous:
- 1. Number of releases
- 2. Total activity releases (Curles) .
2] Excluding tritium and dissolved gases
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TABLE l A - REG GUIDE 1.21 CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL SEMI-ANNUAL REPORT FIRST HALF - 1984 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES lst 2nd Est. Total A. Fission and activation gases Units Quarter Quarter Error, %
- 1. Total Release Cl 1.57 E+03 8.44E+02 2.15E+01
- 2. Average release rate for period uCi/sec 2.00E+02 1.07 E+02
- 3. Percent of tech. spec. limit (1) % 1.17E+00 6.57E-01
- 4. Percent of tech. spec. limit (2) % 2.53E+00 2.46E+00 B. Iodines
- 1. Total iodine - 131 Cl 1.47E-02 2.26E-02 1.84 E+01
- 2. Average release rate for period uCl/sec 1.87E-03 2.87 E-03
- 3. Percent of tech. spec. limit (3) % 1.17 E+00 1.80E+00
- 4. Percent of tech. spec. limit (4) % 4.21 E+00 4.07 E+00 C. Particulates
- l. Particulates with half lives greater than 8 days Ci 6.64E-06 4.21 E-05* 1.84E+01
- 2. Average release rate for period uCi/sec 8.45E-07 5.35E-06
- 3. Percent of tech. spec. limit (3) % 5.28E-04 3.35E-03
- 4. Percent of tech. spec. limit (4) % 2.88E-01 7.57E-03
- 5. Gross alpha radioactivity C1 4 2.74E-06 41.22E-05 D. Tritium
- 1. Total Release Ci 1.05E-01 6.18E-02 2.18E+01
- 2. Average release rate for period uCl/sec 1.34E-02 7.86E-03
- 3. Percer.t of tech. spec. limit (1) % 1.08E-04 6.38E-05 (1) Percent of I.A.2 for each quarter (2) Percent of I.A.3 for previous 12 months (3) Percent of I.B.2 for each quarter (4) Percent of I.B.3 for previous 12 months
- Does not include strontium 89,90 values
TABLE IC REG GUIDE 1.21 CALVERT CLIFFS NUCLEAR POWER PLANT FIRST HALF - 1984 GASEOUS EFFLUENTS - GROUND LEVEL RELEASES Continuous Mode Batch Mode 1st 2nd 1st 2nd
- 1. Fission and activation gases Units Quarter Quarter Quarter Quarter krypton - 85m Cl 1.llE-03 5.31 E-03 krypton - 88 Cl 1.92E-02 1.31 E-02 xenon - 131m Ci 4.95E+00 5.79E+00 xenon - 133 Cl 6.54E+02 5.08E+02 8.16E+02 2.74E+02 xenon - 133m C1 3.80E-01 6.49E-01 2.22E+00 3.06E+00 xenon - 135 Cl 8.64 E+01 4.77E+01 2.38E+00 3.74E+00 argon - 41 Ci 5.74E-02 2.17E-02 krypton - 85 C1 3.12E+00 1.20E+00 krypton - 87 Ci 1.65E-03 1.64E-03 Total For Period Ci 7.41 E+02 5.56E+02 8.29E+02 2.88E+02 2 Halogens lodine - 131 Cl 1.47 E-02 2.14E-02 2.48E-05 1.21E-03 lodine - 132 Ci 9.90E-05 1.07E-05 1.75E-05 lodine - 133 Cl 1.26E-02 8.44 E-03 5.17E-05 3.llE-05 lodine - 135 C1 4.38E-04 1.89E-03 1.26E-05 9.05E-07 bromine - 82 Ci 2.92E-05 2.32E-05 Total For Period Ci 2.77E-02 3.18E-02 1.29E-04 1.28E-03
TABLE IC REG GUIDE 1.21 (CONT'D) CALVERT CLIFFS NUCLEAR POWER PLANT FIRST HALF - 1984 GASEOUS EFFLUENTS - GROUND LEVEL RELEASES - Continuous Mode - Batch Mode
.lst 2nd 1st 2nd
- 3. . Particulates Units Quarter Quarter Quarter - Quarter strontium - 89 Ci < l.10E-06 **
strontium - 90 Ci 6.76E-07 ** rubidium - 88* Ci 1.29E-02 1.20E-02 cobalt - 58 Ci 8.94E-06 1.12E-05
. cesium - 138* Cl 9.94E-05 -3.29E-05
, cesium - 134 Cl ' 4.04E-07 4.64E-06 cesium - 137' C1 4.46E-06 1.74E-05 Total For Period Cl 1.78E-06 8.94E-06 . 1.30E-02 1.21E-02 i i
- Particulates with half lives less than eight days.
** Strontium results will be included in an updated report.
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TABLE 2A - REG GUIDE 1.21 CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL SEMI-ANNUAL REPORT FIRST HALF - 1984 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES ist 2nd Est. Total A. Fission and activation products Units Quarter Quarter Error, %
- 1. Total Release (not including tritium, gases, alpha) Ci 2.75E-01 7.34E-01 2.16E+01
- 2. Average diluted concentration during period uCi/ml 4.79E-10 1.67E-09
- 3. Percent of applicable limit % 4.79E-01 1.67E+00 B. Tritium
- 1. Total Release Ci 1.99E+02 1.32E+02 1.81E+01
- 2. Average diluted concentration during period uCi/ml 3.47E-07 3.00E-07
- 3. Percent of applicable limit % 1.16E-02 1.00E-02 C. Dissolved and entrained gases
- 1. Total Release Ci 2.21E-01 7.24E-01 2.00E+01
- 2. Average diluted concentration during period uCi/ml 3.84E-10 1.65E-09
- 3. Percent of applicable limit % 1.28E-02 5.50E-02 D. Gross alpha radioactivity
- 1. Total Release Ci e 1.29E-04 4 5.81 E-04 3.00E+00 i
E. Volume of Waste Releases I (prior to dilution) liters 8.03E+06 7.54E+06 3.00E+00 l F. Volume of dilution water used during period liters 5.74E+11 4.39E+11 1.40E+01
f I TABLE 2B REG GUIDE 1.21 CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL SEMI-ANNUAL REPORT FIRST HALF - 1984 LIQUID EFFLUENTS Continuous Mode (1) Batch Mode 1st 2nd 1st 2nd Nuclides Released Units Quarter Quarter Quarter Quarter strontium - 89 Cl 5.46E-03
- strontium - 90 Ci 7.40E-04
- cesium - 134 Ci 5.51 E-02 4.18E-02 cesium - 137 Ci 1.28E-01 8.60E-02 lodine - 131 Ci 2.97E-02 3.28E-02 cobalt - 58 Ci 2.79E-02 2.47E-01 cobalt - 60 Cl 1.36E-02 4.67E-02 iodine - 132 Ci 7.85E-04 manganese - 54 Ci 1.29E-03 9.77E-03 chromium - 51 Ci 8.62 E-02 zirconium - 95 Ci 8.55E-04 2.10E-02 niobium - 95 Ci 1.96E-03 3.48E-02 molybdenum - 99 Ci 6.36E-06 1.08E-03 barium - 140 Ci 2.89E-05 antimony - 124 Ci 2.07E-03 iodine - 133 Ci 4.64E-03 2.51E-02 antimony - 125 Ci 6.67E-03 2.48E-02 cobalt - 57 Ci 6.51E-05 3.66E-05 silver - Il0m Ci 4.05E-03 3.89E-02 lanthanum - 140 Ci 2.10E-04 tin - 113 Ci 3.16E-05 1.39E-03 ruthenium - 103 Ci 4.30E-03 niobium - 97 Ci 1.35E-03 1.95E-02 fron - 59 Ci 7.09E-04
TABLE 2B REG GUIDE 1.21 (CONT'D) CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL SEMI-ANNUAL REPORT FIRST HALF - 1984 LIQUID EFFLUENTS Continuous Mode (1) Batch Mode 1st 2nd 1st 2nd Nuclides Released Units Quarter Quarter Quarter Quarter zirconium - 97 Ci 1.05E-03 t211urium - 132 Ci 4.26E-04 ctrium - 141 Cl 1.35E-03 czrium - 144 Ci 6.28E-03 unidentified Ci < 4.02E-03 < 3.77E-03 Total For Period Ci 2.85E-01 8.61E-02
- Strontium results will be included in an updated report.
TABLE 2B REG GUIDE 1.21 (CONT'D) CALVERT CLIFFS NUCLEAR POWER PLANT EFFLUENT AND WASTE DISPOSAL SC.ii. ANNUAL REPORT FIRST HALF - 1984 LIQUID EFFLUENTS Continuous Mode (1) Batch Mode 1st 2nd 1st 2nd Nuclides Released Units Quarter Quarter Quarter Quarter Xtnon - 133 Ci 2.15E-01 1.16E-03 Xrnon - 135 C1 2.38E-03 8.65E-05 Xenon - 133m Ci 2.14 E-03 (1) Continuous mode releases, i.e., nuclides released, are less than " unidentified" unless otherwise noted.
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TABLE 3A EFFLUENT AND WASTE DISPOSAL SEMI-ANNUAL REPORT FIRST HALF - 1984 SOLID WASTE AND IRRADIATED FUEL SHIPMI'NTS A. SOLID WASTE SHIPPED OFFSITE FOR BURIAL OR DISPOSAL (NOT IRRADIATED FUEL) 6-Month Est. Total
- 1. Type of Waste Units Period Error %-
3
- a. Spent resin, filter sludge m 1.34E+01 evaporator bottoms, etc. Cj 2.34E+02 2.00E+01
- b. Dry compressible waste, m 3.96E+02 contaminated equipment, etc. Cj 1.87E+01 5.00E+01
- c. Irradiated components, m
- control rods, etc. Cj --
- d. Other (describe) m Ci _
- 2. Estimate of major nuclides (by type of waste)*
- a. Cobalt - 58 8.73E+00%
Cesium - 137 3.92E+01% Cesium - 134 2.04 E+01% Manganese - 54 3.87E+00% Cobalt - 60 9.15E+00% Antimony - 125 1.85E+00% Strontium - 90 2.05E-01% Iodine - 131 1.25E+01% Cobalt - 57 4.10E-01% Nickel - 63 3.67E+00%
- b. Cobalt - 60 3.97E+01%
Cobalt - 58 2.98E+00% Cesium - 137 1.13E+019; Cesium - 134 3.00E+00% Manganese - 54 2.66E+00% Nickel - 63 3.67E+01%
- 3. Solid Waste Disposition Number of Shipments Mode of Transportation Destination 13 Motor surface transit Barnwell, S. C.
12 Motor surface transit Richland, Wash.
*Only nuclides greater than 1% were reported.
CALVERT CLIFFS NUCLEAR POWER PLANT METEOROLOGICAL DATA JANUARY 1, 1984 TO MARCH 31, 1984 l I
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% CTCUERT CLITFS NUCLEAR SITE 1 f4 WIf4D REDLEED FROM 125 FOOT LEVEL TO 33 FOOT LEUfL STABILITY CLASS ALL (30-200 FOOT)
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UALTIMORE GAS AND ELECTRIC , CHARLES CENTER P.O DOX 1475 DALilMORE, MARYLAND 21203 AntHure E. LunovALL,JM. VK a Pna ttutNi
*)ureo August 31, 198'4 Dr. Thomas E. Murley llegional Administrator U. S. Nuclear Itegulatory Commission Region 1 631 Park Avenue King of Prussia, PA 19t #06 SUIDECT: Calvert Clif fs Nuclear Power Plant Docket Nos. 50-317 and 50-318 Semi-Annual Ef fluent Release Report
Dear Dr. Murley:
The purpose of this letter is to forward to you the attached Semi-Annual Ef fluent Release Report and meteorological summary for the first half of 198's in compliance with Paragraph 5.6.1.b of the Unit I and Unit 2 Environmental Technical Specifications. The report does not include the cornplete analytical results and an updated report shall be submitted as soon as these results are completed.
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Very truly yours,
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h [ T ~vu Mov,- At tachment cc: Director, Of fice of Management Information and Program Control
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