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Advises That Util Enlisted Betz Industrial to Assist in Removal of Calcium Carbonate Scale from Emergency Svc Water HX Twice During Current Outage.Proposed Method Is to Add Betz DE-1579 to HX for Two 48 H Treatments
	ML20095A200
Person / Time
Site:	Perry
Issue date:	04/09/1992
From:	Lyster M; CENTERIOR ENERGY
To:	Jackson K; OHIO, STATE OF
References
	PY-CEI-OEPA-015, PY-CEI-OEPA-15, NUDOCS 9204160147
	Download: ML20095A200 (8)
	v • d • e

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. CENTERIOR ENERGY PERRY NUCLEAR POWER PLANT o ess Michael D. Lyster RCC; L ="=o aoa' wc"n= ~n (2:0 259 3m April 9, 1992 PY-CEI/0 EPA - 0151L Xim Jackson Ohio Envirenmental Protection Agency Division of Vater Pollution control Enforcement and Compliance Section 1800 'iatermark Drive, P.O. 3cx 1039 Columbus, Ohio 43266-0149 Ron Perry Nuclear Power Plant NPDES Permit No. 3IB001600 Cooling Vater Additive for Nonroutine Hest Exchangar Cleaning

Dear Ms. Jackson,

The Perry Nuclear Pover Plant has enlisteu Bett Industria to assist in the removal of calcium carbonate scale from an emergency service water heat exchanger twice during the current outage. The proposed method is to add Betz DE-1579 to the hea t exchanger for two 48 hot.r treat! rents. The discharge v'll be continuous during each treatment s it vill be comMned with untreated seiv'ce vater prior to entering state vatets.

i This product and procedure vill only bc used for cleaning and in not part of routine daily operation. This product wr.s approved for a similar application at the Perry Plant in June 1989 (see Attachment 1).

Attachments 2 - 5 contain the information required in accordance with O' lo EPA procederen. Our intention is to begin the first treatment during the va n of 4pril 13, 1902, pending yw r appraval;-ve would appreciate your notifying us of the results of your evaluation as soon as possible. Please contact Letise Barton at (216) 259-3737 ext. 5512 vith your results, or if you have questions or need further information.

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Hichael D. Lyster MDLalkbrss cer NRC 00cutaent Control Desk l NRC Project Managar l NRC Resident Inspector Office i l

URC Region III l B Hall. OEPA - Northeast Oistrict Office .

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cuta <d oth. EstwmntaA Pivtxtk i Aarmy gge P.O Box 149,'300 Watermark Dr. cm, Columbus.Onio t.3260 0149 4 '

.Tane 20, 1969 Re Cotins Water Additive 7,equest Perry Maalear Power Piant CEPA Vo. 3I300016*CD N? DES No. CH0063a61 Ray:nond M . P o s t . P .E .

Engineering Group Leader Betz Industriai 4636 Scr.orton Road

'Irevoso. PA 1904 7-w7 33 Ocar Mr. Post:

Your requesa, which was subnitted in accordance with Part II cf the above referenced NPDEC permit, to discharge Detz DE-1319, Betz GOP-109 and Bet:

GC?-127, cooling water additives, at concentrations of 250 e4/1, 20 26/1. 30 e4/1 respectively to I,ake Erie at the above ref erenced f acility la hereby app roved.

g Please note the approval is given subject to the understanding that theso additives are uned for cleaning on a temporary basis and are not a part of routine daily operation. We also understand ths.t pH of the final etfluent will be controlled within the petuit r,uidelines and that proposed cencent.rstions of the additives Betz DE-1579 and Betz GCP-109 would doctense to 100 mf,/1 and 0.8 mg/l eerpoetively within 24 hours2.777778e-4 days 0.00667 hours 3.968254e-5 weeks 9.132e-6 months of discharge.

a greater concentration or usa an If you wish to-discharse therw additives et:

alterr.ative Sdditivo, then a separate approval f ron Ohio KPA r.ast be ac:lutred prior to the change. 7,! you have any furthar questions, please contact Swaraj X. Chaktatarti of ny staf f at (614) 6&&-2001, 31ncarely.

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Manager. Pernits Section Division of ' dater Pollution Controi JJ3/.KC/mds t 0039F/29

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cc: Martin Hilovsky NEDO l Owsrsj X. Chakrabarti. CVPC

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. l ATTACliMENT 2 Co$ ling Vater Additive Taformation. ,

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. Name of the additive to be used and general produce, information. )

Additive Name - Bot: DE i,579

a. MSDS - Attachment 3 b, c s In e. Ingredient informattop Attachment 4 '

d. The additive vill be used to remove calcium carbontre scale from a !

plant heat exchanger. l

2. The concentration of the additive to be used pg/1). '

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a. The additive vill be applied tvice during the current refueling

, outage.

b. Each application vill last 48 hours5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months ,

c. The additive vill be fed by metering pump to ensure feed concent.rathn,

3. The expected concentration of the ad!.itive contained in the discharge f immediately prior to entering state surface vaters.

The expected discharge concentration in 30 mg/1, (Tae analytical ,

detection limit is 5 mg/1.)

4. The average flovrate (MGD) and the outfall number of each outfall containing the additive. ;

i The volume of blevdown entering the discharge stream vill be -

approximately 1.00 - 1.44 MGD. The total discharge flovrate vill be '

approximately-82.08 HGD. A line drawing is Attachment 5.

S. Name of the state surface vaters that receive the discharge, i t

, Lake Erie

6. Toxicity information for the additivc, r

Adjusted pH:

E 48-hour --Daphnia marna - 0% mortaliy at-10,000 mg/l 48-hour - Rainbov trout - 0% mortality at 2,500 mg/l ,

100% sortality at 5,000 mg/l

Unadjusted pH - '

48-hour;LC50 - Rainbow trout - 625 mg/l-I l' The above results are in accordance with EPA static bioassay l procedures. Conditions for the first set of data vere modified to L maintain the pH at 8.0. The unadjusted pH data reflects the fact that l Betz DE 1579 is acidic (pH 2.5). The pH of the final effluent at L Perry durthg the application vill be maintained within the NPDES l- permit guidelines of 6.5 - 9.0, which vill eliminate low pH induced mortality.

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791NTED:

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RCOUCT APPLICAi!CN CMENICAL CLEANING ~.CMFCUND.

5 E C T I CN 1 -------- --- H A.'.\ROCd5 I NG RED I EN T S ------ - ----- ---

!NFOR9AT:CN ON 84YSICAL HALAR05. HE R TH -A:AROS, DEL'S AND TLv's FOR $PEC:F'.C PRCf,'UCT INGRE0:ENT5 AS RECV!RE7 3Y THE CSFA ".AZ.ARD ::MMUNICATICNS 5TANDARD 15

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PEL: NUISANCE OUSI;*LI:NU!5ANCE OU$i. i RN 125432 - 5214P TRADE,:5ECRET lNGREDIENT(E'.95); EYE IRRIT ANT;PEL: NCNE;iLV:NCNE. ISRN 125 38

. : ... . .n N!TRI: AC:0"*C AS/7597-17-2:CX!0I:ER;C RRC3:VE;PULHCNARY DA.4 ACE; DENTAL ERC51CN;PEL/TLV: 5MG/M3(ICNGiV3-5TEL).

RECIlvE0 NOV 9 o.*c.c1 tE13WEM $a817D01,

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PH: AS IS (APPROX.) 1.4 GCCR: PUNGENT FL ?T.(DEG.F): 200?-4(CC) $P.GR.(70F)CR DENSITY: 1.070 VAPOR PRESSURE (mmHG): 36 VAPOR DENSITY (AIR =1): 1 VISC cr;70F: 9 f.SCLUBlLITY(WATER): 100 EVAP. RATE: 1 ETHER =1 APPEARANCE: CCLCRLESS TO GREEN PHV3! CAL STATE: LICUID FREEIE POINT (dig. ): 27

SEC T ~ CN 3 ---- ,------ R EAC ilY t iv D A T A----- ------ -- ------------- --

STABLE.9AY REACT WITH SYkONG OX101:ERS.00 NOT CCNT!HINATE.BE TI TANK CLEAN CUT CATEGCRY '3' THERMAL DECCMPOSITICH (DEsiRUCTIVE FIRES) Y1 ELDS ELEMENTAL OX1 DES.

!NCCRMAiiON UNLY

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A;MIE SKIN '.~ FCTS ?RIMARY ROUTE Cf EXFCIURE I SLIGHILY IRR!TATING 70 THE SK!N ryrr--e ...

troirS!V[R ry:5 iRRii15i IO IVC EYES ACUTE RESPIRATCRY EFFECTS *** ?RIMARY RCUTE OF IXPCSURE V APCRS,3ASES. MIS 75 AN0/CR AEROSCLS CAU5E 'RRIIATICN TO UPoc.R RESP!RATCRY TRACT ChRCN;C EFFECTS OF CVEREXPCSURE""

PRULCNGED OR RE?EATED EXPCSURE MAY CAUSE LUNG DAMAGE AND/CR MAY "AU..

PR! VARY ;RRITANI DERMAili!S.

MEDICAL CF,N0iT!CNS AGGRAV ATED ***

NCI KNCWN SYMPTCMS 0F EXPCEURE '"

INHALAT:CN VAf CAUSE IRR!!ATICN OF RESPGATCRY TRACI;5K:N ~CNTACT MAY CAUSE !TCHING AND/CR REONE55.

PRECAUT!CNARY STATEMENT BASED CN TEsiiNG REIULIS ***

uAY BE 70X!C IF CRALLY INGESTED CR lNHALED.

.... 3 g ,71 c y 3.... ..... .. .:! RST A !D I NSIRUCT ! CNS------- ---------- ----

SK*N CONIACT***

REMOVE CONTAMINATED CLOTHING. WASH EXPCSED AREA WITH A LARGE CUANIITY CF SCAP SCLUTICN CR WATER FCR 15 MINUTES EYE CONTACT ***

IMMEDIATELY FLUSH EYES WITH WAIER FCE 1E WINUTES.!KMEDIATELY CONTACT A PHYSICIAN FCR A00!TICNAL TREATMENI INHALATICN EXPOSURE "'

REMOVE VIC7IM FRCM CONTAMINATED AREA TO FRESH AIR. APPLY APPROPRIATE FIRST AID TREATMENT AS NE:ESSARY INGESTICN'**

CO NOT FEED ANYTHING 3Y MOUTH TO AN UNCONSCICUS CR CCNVULSIVE VICTIM 00 NOT IN00CE VCMITING.IMMED.:CNTACT ?HYSICIAN DIL'JfE CONTENTS CF STCMACH USING 3-4 GLASSES MILK CR WATER

< SECTION 5-----------IP ILL,0 !SPCSAL AND F IRE !NSTRUCTIONS---------

SP!LL INSTRUCTICNS

VENTILATE AREA,USE SPECIFIED PROTECTIVE ECUIPMENT.CCNTAIN AND ABSCRB CN ABSCREENT MATERIAL. PLACE lN WASTE DiSPCSAL CCNTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,CR ANY CONTANINAIED SOIL, SHOULD BE "ETERMINED IN ACCORDANCE WITH RCRA REGULATIONS.

FLUSH ARE/ 4ITH WATER. WET AREA MAY BE SLIPPERY. SFREA0 SAND / GRIT.

DISPOSAL INSTRUCTIONS "'

WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATHENT FACILITY,IN ACCCROANCE WIT!! ANY LOCAL AGREEMENT,A PERMITTED WASTE . TREATMENT FACILITY CR DISCHARGED UNDER A NPOES PERMIT PRODUCT (AS IS)-

INC!NERATE CR BURY IN APPROVED LANDFILL FIRE EXTINGUISM!NG INSTRUCTICNS"'

FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF iCNTAINED 3REATHING APDARATUS(FULL FACE-?!ECE TYPE). PROPER FIRE EXTINGUISHING MEDIA:

ORY CHEMICAL, CARSON DIOXIDE,FCAM CR WATER

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u;E ;ROTEcihE ECU!WENT S ACORDAA:E JITH ZE.FR SECT:C1 1910.132 '34. 'J E ESPIRAICRS WIThlN USE L!N!IAilCNS CR E )i. 'JSE SUPPLIED AIR RESP!RAICRS VENT *LATICH ?ROTECI!ON""

ADECUATE VENTILATI~N TO MAINTAIN AIR CCNTAHINANTS SZLCW LX?CSURr tp:t73 RECCMMENCEO RESP *RATCRY Ps0TECTILN"*

!? VENTILATICN IS INADEQUATE CR SIGN!i! CANT DRODUCI EXPCSURE IS LIKELY.

USE A RESP!RATCR WITH OUST /MI's F LIERS.

RECCMMENCEO SKIN PROTECTICN'"

NECPRENE GLOVES WASH CFF AFTER EACH USE.RE? LACE AS NU. ESSA'tY RECCMMENDED EYE PRGTECTICN"'

S?'. ASH PRCCF CHEMICAL GCJGLES

SE:T!CN 3----------5ICRAGE AND HANDLING ?;iCAUT CNS----------

5 /CRAGE INSTRUCTICNS"'

TEEP DRUNS L P AIL.S CLOSFD WHEN NOT !N J3E.

DROTEC' FRCM FREE!!NG.XEE? ORY HANDL:NG INSTRUCTIONS"'

CNTAINS As CXICIZER. AVOID L CONTACI a'!iH REDUCING AGENTS.

CILS, GREASES, CEGANICS AND ACIDS.

TT W T T T T TT TTT T T T YT T TTTTT*# T YFTTTTTT T T FT TT t-TTT1 T T FTTTT TT TT1*TTTT ' 3*TTTTT W T TFFTT THIS MSDS WAS 4RITTEN TO CCMPLY WITH THE CSHA HAZARD CCMMUNICATICN STANDARD R S T T TTTT T T TT T TT T*lf T TT TTTTTTTT TTT T M TTTT F TTTT T TT'*'TT F W FTTTTTT S T TTTT TTTTTW TTT AP ENUIX: RiGULATORY INFCPNATION THE CCNTENT OF THIS APPEN0!X REPRE;ENTS INFORNATICN KNOWN TO 3ETC CN THE EFFECTIVE DATE CF THIS MS0'. THIS INFCRMATION 15 SELIEVE0 70 3E ACCURATE.

ANY CHANGES IN RECULATICNS WILL RESULI IN UPDATED VER51CNS Cf THIS DOCUMENT.

...TSCA: ALL CCMPCNENTS CF THIS PRC00CT APE LISTED CN THE i!CA INVENICH

...RE?CRTAELE CUANTITY(RO) FOR UNDILUTED PR000CT:

E,51'. GALLUNS DUE TO NITRIC AC'0:11,212 GALLONS 00E 70 (IZ2)

... RCRA: IF THIS PRCDUC~ IS DISCARDED AS A WASTF,IHE RCRA MA2.AP.00US WAS1E ICENTIFICATICN NUMBEi! IS: 0002iCCRRCSIVE(PH, STEEL)

.. 00T MAZAR0/UN#/ER GUIDEi IS: CCRRCSIVE TO STEEL UN1750/#60

...CALIFCRNIA SAFE ORINK!;4G WATER ACT (PROPOSli1CN $5) MATERIALS: NCNE

. .. SARA SECTICN 302 CHEMICALS: NITRIC ACID (7597-37-2) ;

... SARA SECTICN 313 CHEMICALS: HITRIC AC?0(7697-U-2', , 2.0-5.0". ;

... SARA SECTICH 312 HAIARD CLASS: IHMEDIATE(ACUTE),0ELAYED(CHRCHIC) AND F1.'!E

... MICHIGAN CRITICAL MATERIALS: NCNE NFPA/HMIS : HEALTH - 2 ; .cIRE - 1 ; REACTIVITY - 0 ; SPECIAL - CCRR ; PE - B N ORMATica

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AT7ACht:ENT 4 sunt warna

. ,4 4134th mastum in:20 su.3 Apnl7,1992 Ma. LouisT Banen CEl Perry Nuclear Power Plant 10 Canter Road Forry, OH 4081

Dear Ms. Berton:

detz DE 1579, a calcium carbonato scale remcVer, is a preptforary aqueous blond o' weak organic adds.

Because tnis procuct la not a regulated antfinicrobial biocido ?t doec not reculto nor does it possest a FIFRA registration nurnt or. OnN EPA rugtstered antimicreblal biocides requim this registration, if you have any Iuither questbns, please fee! free to can me.

Very truly yours, DETZ INDUSTRIA(

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(JrWitaon Area Manager Lake Land Power Distnct (210) 277-8800 FAX 216 250-5915 (Attn, Jorf Wilson)

Mail no TA oxt. 6636

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ML20095A200

Text

Dear Ms. Jackson,

Dear Ms. Berton:

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