Text

Forwards NPDES Permit Renewal Application for Perry Nuclear Power Plant
	ML20094H873
Person / Time
Site:	Perry
Issue date:	11/07/1995
From:	Shelton D; CENTERIOR ENERGY
To:	Lee D; OHIO, STATE OF
References
	NUDOCS 9511140387
	Download: ML20094H873 (93)
	v • d • e

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N:-C NTERCOR ENERGY Donald C. Shelton PERRY NUCLEAR POWER PLANT Mail Address:

SENIOR VICE PRESIDENT P.O. BOX 97 10 CE*;TER ROAD PERRY, OHIO 44081 NUCLEAR PERRY, OHIO 44081 (216) 259 3737 November 7, 1995 PY-CEI/0 EPA-0234L Attention:

Mr. Dennis Lee, Group Leader Division of Vater Pollution Control Ohio Environmental Protection Agency Northeast District Office 2110 East Aurora Road Twinsburg, Ohio 44087-1969 Re: NPDES Permit No. 3IB00016 Ohio EPA No. OH006346 Perry Nuclear Power Plant; The Cleveland Electric Illuminating Co.

10 Center Road, Perry Village, Ohio 44081 Lake County Gentlemen:

Enclosed is the NPDES permit renewal application for the Perry Nuclear Power Plant. Included in this application are the following documents:

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(1) Application Form 1 - General Information (2) Application Form 2C - Vastevater Discharge Information (3) USGS Hap (Perry Quadrangle, Lake County) showing the location of the plant and associated outfalls.

(4) Line Drawing of Vater Flow at the plant site.

(5) Check for the $100.00 Permit Renewal Application Fee.

Please note that there are no forms provided for Outfall 002, Chemical Cleaning Lagoon, since it was not in service and there was no discharge during the permit application sampling period.

The Perry Plant also requests the following changes in the new permit:

1.

Asterisks (*) should be placed by all sampling frequencies except flov for outfall 002 denoting sampling required only on days when there is a discharge.

2.

Ph limits on all outfalls should be changed to 6.0-9.0. This change is justified by alkalinity studies conducted previously at other Centerior Power Plants on Lake Erie and furnished to OEPA.

3.

Outfall 001 should be redesignated as 601 to reflect its status as an entirely internal discharge which combines with the flov from outfall 004 upstream of the final discharge from the plant.

130103 Operonng Companies

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9511140387 951107 PDR ADOCK 05000440 P.

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PY-CEI/0 EPA-0234L November 7, 1995 Page 2 of 2 i

4.

If the agency decides to establish effluent loadings, the plant i

requests that the flows on which the limitations are based be a reasonable measure of actual production and be no more stringent i

than the following i

Outfall 001:

..0415 HGD Outfall 004:

144.8 MGD To place lower daily effluent loading limitations vould severely afft :t plant operations and capacity to generate electricity.

l It should be noted that the plant routinely adds small amounts of water treatment chemicals such as hydrazine to the feedvater for the plant auxiliary boilers. Chemical additives are provided on the Form 2C for each outfall. The plant requests the Agency's approval to use these l

additives in its water treatment programs.

i If you have questions or require additional infornation, please contact Donna Tizzano at (216) 280-5514.

Very truly yours, DGT:sc Enclosures cc:

USNRC Document Control Desk (Docket No. 50-440)

USNRC Region III t

NRC Resident Inspector Office NRC Project Manager

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i ATTACHMENTS:

(BLOCK FLOV DIAGRAM)'

(FORM 1)

(FROM 2C, PAGES 1-4) i (3 FORM 2C'S, PAGES V-1 THRU V-9)

(USGS MAP -- PERRY QUADRANGLE)

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i (ELECTR0 ANALYTICAL LAB DATA)

(QUANTERRA DATA) l

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i.lNUTRUCTl0NSMComplete Athroughito de'termine whether you need to submit any permit application forms to the EPA. lf you answer"yes"to any:

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Mll. t6ATURE OF. BUSINESS { provide a brief description Generation, transmission and distribution of electricity for sale.

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Xill. CE RTI FICATION (see Instructions) -

/ certify undeipenalty of law that I have personally examined bnd am familiar with tlk information submitted IN this a5lication aj

'attachmin'ts"and that,"babelf"on'my' inquiry' of thosepersons imniediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate and complete. I am aware that there are significant penalties for submi false information, including the possibility of fine andimprisonment.

1 C, D Al L SiG N L D u.51GNATUHE A. N A M L & OF F IC I A L T 11 L E grype or prin gj Donald C. Shelton a

Senior Vice President, Nuclear 1

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OH006346 Approval oxpire.s 5-3192 PieTse print of type en the unshided trets only.

FORM u.rs. E N Vt HON M EN T A L PHOT ECTtON MG ENCY g%

APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER 2p g EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS g

NPDES Consolidated Permits Program I ;~'l:p j i Q L f. l J f & & hy ;:l u:? 6*ptf g h f.,f-)..Q 7.}

I. OUTFALL LOCATION

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For sach outfall, list the latitude and longitude of its location to the nearest 15 seconds and the narne of the seceiving water.

A,Ou FALL B. L AT8TUDE C. LONGlTUDE I

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001 41 48 00 81 08 45,

P hnt Service Water Systems 002 41 48 15 81 08 30 Plant Circul. Water Systems 004 41 48 30 81 08 45 Lake Erie 800 41 48 15 81 08 30 (intake)

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- [6 i lN;l:'.<T' IL FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES }

A. Attach a line drawing showing the water flow through the facility. Ind'cate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the rnore detailed descriptions in item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatment unitt, und outfalls. If a water balance cannot be determined (e.g., for certain mining activities), provide a 1

' pictorial description of the nature and amount of any sources of water and any collection or treatment measures.

B. For each outfall, provide a description of: (1) All operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue i

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a. OPER ATtON(S) CONTRIBUTtNG FL.OW

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a. DESCRIPTION AB E C-

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p Regenerant 0.0189 MGD neutralization 2-K 1

neutralization 001 Chemical Cleaning none sedimentation 1-0 002 waste treatment hgoon (batch process) 1 l

Plant Discharoe SR ~7 Man Seainm gulfite Mchlordnat-iorM -E r

including cooling tower coagulation 2-D 004

( blowdown, sodium hypochlori :e filtration 1-P addition, radioactive waste Ion exchange 2-J discharge and lime & ferrou ;

sulfite addition for water :reatment )

Calgon H-130 Malluskicide treatment Betz DE-1519 cmlinn Wafwr-t rm%nt Plant water intake 99.36 MGD 800 OF F'4CI A&. USL ONLV (cf[jkent guidtjmes gut >-Caftgottes)

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3. Exept for storm runotf,leiks, or spills, tra any of the discharges described in itsms If.A or 8'in'termittent orM--q$1)l $$*fj M m,

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001 Regenerate Neutralization 1

12 0.0189 0.0419 isc M r[ 3

.98 MG 2.18 M 2-4 hrs.

004 Radwaste discharge 4

12 0.036 0.100 7.49 MG 20.4, Mc ischars 2 Ill. PRODUCTIO A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facihty?

D no (to to Section IV)

QvEs (complete item fil-B)

B. Are the limitations in the applicable effluent guideline expressed in terms of production (or other measure of operation)T D No (to to Section IV)

DYES,(complete item !!!-C)

C. If you answered "yes"to ltem ill-0. hst the quantity which represents an actual measurement of your levei of p used its the applicable effluent guideline, and indicate the affected outfalls.

1. AVERAGE DAILY PRODUCTION

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h ciudes,q pquiprnerit or (Jactices or any other environmentaj;[3rograms which'tneyraffec};th '.11isctiarges tieferiMin.this app g rderya grant s

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B. OPTION AL: You may attach additional sheets describing any additidn$1 water pollution contrbi program l

your (tischarges) you now have underway or which you plan. Indecate whether each program is now underway or plann

, planned schedules for construction-Omaan x-ir ocscaierson"or ^oo:Teoaa' coaino' enoonaas is avvacaco

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V. INTAKE AND EFFLUENT CHARACTERlSTICS A. B, & C: See instructions before proceeding - Complete one set of tables for each outfall - Annotate the outfall number in the space provided.

NOTE: Tables V-A, V-8, and V C are included on separate sheets numbered V 1 through V-9.

D. Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions, which you know or have reason to believe is discharged or may t>

discharged from any outf all. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical data in you possession.

1. POLLUTANT

2. SO U RC E

1. POLLUTANT

2. SO U RC E Asbestos Outfall 004 Unit I cooling tcrwer fill material, made up of cement boards contain..ng 10-15% nonfriable asbestos.

The estinated weight is 1,400,000 - 2,100,000 lbs. of asbestos in the cement boards.

Vt. POTENTIALDISCHARGES NOT COVERED BY ANALYSISM

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as any poginant testedin item %Q asubstance pr.a component of a substance which you currently.use or manufacture es an 6ntermediate or final product or Q oducit g>i$ yptd %.~e $ typp43 W M

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. EIOLOGICAL TOXICITY TESTING DATA M you teve any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on sn ecsiving water in relation to your discharge within the last 3 years?

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Q vEs (idenufy the testis) and describe their purposes below)

Acute toxicity testing: 48 hour5.555556e-4 days 0.0133 hours 7.936508e-5 weeks 1.8264e-5 months Static acute - Daphnia 96 hour0.00111 days 0.0267 hours 1.587302e-4 weeks 3.6528e-5 months static acute - fathead minnow for zebra mussel molluskicide applicatien compliance verification llCONTRACT ANALYSISINFORMATION Were any of the analyses esported in item V perforrned by a contract laboratory or consulting firm?

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YEs !!ist t e ame 5 ress,'and telephone number o and pollutants Os is analyzed by, each such laborutory or firm below A W Ed l D.N M TA 1

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Quanterra Incorporated 4101 Shuffle Drive, NN (216)

See attached North Canton, OH 44720 497-9396 Analyses Electro Analytical 7118 Industrial Park Blvd.

(216)~

See attached Mentor, OH 44060 951-3514 Analyses Laboratory.

b Icdrtifyhr$eVpena'Ithflawth'atthIslfocu' bn'tandallattachmentswere'preparedundermydirectionorsu0e'rvi sssurs that qualifiedpoisonriefprpperlygather andevatuste the information submitted. Basedon myinquiry of theperson orpe m

thosepersons directly'iesponsble forgotheling the information. the information submittedis. to the best of my knowled Icm'LweYe that tise are i,lgnificant' penalties for' submitting false information, including the possibil

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, c B. PHONE No. (area code 4 no.)

A. N AMC at OFFBCB As. TITE E (type or print)

Donald C. Shelton (216) 259-3737 Senior Vice President, Nuclear D. D ATE $4GNED C. SIG N ATU H E es a v': s* A n r A

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.;ag g EPA 4.D. NUM AER (CTpy from If4m J of Form JJ t

PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONt.Y. You may report some or all of this information on separate sheets lute the same format) instead of completing these pages.

OH006346 -

OU T F A LL NO.

see iNSTnucTIONS.

001 V. INTAKE AND EFF LUENT CHARACTERISTICS (continued from page 3 of Form 2-CJ il PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each

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(

e c = e d,'

a, e I'I""**

ce=esh..veen I'I " *

conceNImateo, (8) M ASS R Tl

< 3.0 x 2489 1

oxvoan Demand

<3.0

<l.0 i

mg/L PPD

a. Bacchemical IBOD)

PPD

< 20.

< 16593 1

I

b. Chemical c"Jff,"

"*"d 35.

12.

1 mg/L PPD 1.8 1493 1

cut >on (roci 9.1 3..I 1

mgfg

e. Tots oro.nic PPD 1.6 1327 1

d. Tot.: suwended soiidstrss>

125 44 37, 13.

72 ma/L mg/L ppd

.34 282 1

^" **"" "'

2.4 I

i VALUE VALUE

f. Flow 0.0189 NA MGD N/A 99.36 N/A VALUE VALUE VALUE 0.0419 VALUE VALUE

.72 N/A VALUE

o. Temperature NA f"'"'">

^

25 N/A A Tampwature NA tsummeri

,qgg.), Ap Men Mum M AxtMuM M4NtMuM M AxiMuu STAND ARD U.NITjS.

LpH 18

- Wrm =

6.8 8.8 f

ll t t Mark ~~X~~ in column 2-a for each potiutant you know or have reason to believe is present. Mark X"in column 2-b for each p which is limited either directly, or indirectly but expressly. in an effluent limitations guideline.you must provide the results of atlesss II'Sesthe instructions for additional details and requirements.

PART B -

column 2a, you must provide quantitative data or an explanation of their presence in youldischarge'.lCom. pl'et' one ta.bTe f.'.@-e s

o

.p 7 c.y - w (p

,,, pp-p u r -

,n

3. EFFLU ENT $g4jg;',h"j$f'CMJJ4< MDYi (CDP 4! UNITS *

5. INT AKE (cprional) 4.

ER O

I dhC

[ Fg h'h

^

1. M A R M ' x-M gggY V ALUE Ok hhN h

t. POLLUT.

O

b. M A x t (if cuallable)

IEU s J, j'),,,,,

(sp w as -

,,,,, p),,,,,,

{a) mass QQ}i@,$ @$#D Ystsi M N" e.,, C,3..,...

(8) "

88 YsEs i

e EcJ,ff;

e. M AxIMUM D AILY V ALUE CAS NO B. Bror9lde 1

m/T, PPn 40 33170 1

(24959-67-9)

X 40 13.988

<.01

< 8.292 1

Tote Residu.'

X

<0.0i

<0.003 1

mg/L PPD

b. Chlorine.

1 Pt-Co N/A 10 8292.5 1

c. co'o' X

300 N/A 1/100 1

$o7n X

43 N/A ml N/A 4 3 N/A 1

e. Fluoride 1

ma/L PPD 0.1 82.92 1

ne984 48 8>

X 0.6 0.21

f. Nitrate-1 ma/L PPD 0.5 414. A 1

Nhrite (as NJ X

3.7 1.294 CONTINUE ON REVERSE P AGE V-1

N

~

ITE41 V 9 C_ONTtNUED FROM FRONT

2. M A R M x'

3. EFFLU ENT k.).*M 3'Id. -ff

- W." T* Y (4. U NITS

5. INT AKE (oprinnefj 1.POLLUT.

a. M AXIMUM D AILY V ALUE D* M A A'%MMY vhLUE c.LO N G T g

., V A LU E d. NO.O r Ah AOE VA L17 E b NO.Os

[as^n o de*Ifed.js G. CO N C EN-

,,, J'),,,,,,

g,3....

,,,,, g),,,,,,,

g,3 " " * *,.

e enc e N/='nT e'n

'Is).sase YsE C e=c e W ee nt e ose

{a) wats v5 MANN (fr aveffabtei sea' se=<

g. Nitrogen,

[EE, '"

X 2

0.6994 1

tro/L PPD 4

1 4 829.25 1

h. Oil med G-X

<5 41.75 1

mg/L PPD 4

4 3522 1

1. Phosphcres tas l's'.14-03 X

< 0.1

<0.035 1.

mg/L

' PPD 0.4 331.70 1

Total (7723

^

l. Asdioactiviti

' fy)KD-f?y$ sys.h ?ry (1) Alpha, N='

X 4 40 NA 1

pCi/L NA 4 3 NA 1

(2) sota.

X 4 60 NA 1

pCi/L NA

< 5 NA 1

(3) Radium, X

4 2

NA 1

pCi/L NA 4

NA 1

(43 n.dium 0.1+/-

22s. m*'

X 0.1 NA 1

rCi/L NA 0.1 NA 1

k. sulf ate X

4m

< m.8 1

g/L M

M MM 1

j'8,l.',,,,

0

1. Tutfide ra' 8>

X 1.5 0.524 1

mg/L PPD

< 0.1 (82.92 1

m. Suffite O'4$s!4s.33 X

4 1

< 0.3497 1

mg/L PPD

<.1 (829.2 1

n. sun.ct.""

X

< 0.05

<.0.0175 1

trg/L PPD

<.05 441.4 1

o. Aluminum, Total (7429 90.s)

X 0.59 0.206 1

mg/L PPD

< 0.2 4166 1

p. O trium, Totti (7440-39 3>

X 4 0.2

< 0.07 1

mg/L PPD

< 0.2 4166 1

q. B#ron, Tot 14 (76CO'42-8)

X

< 0.2 40.07 1

mg/L PPD

< 0.2

<166 1

r. Cabelt.

Totti (7440-48-4)

X 4 0.04 40.014 1

mg/L PPD

(. 0.04 433.1 1

s. Iron, Total (7439-89 6)

X 10.1 3.532 1

mg/L

. PPD 0.22 182.44 1

t. Magnesium,

[72$9 95 43 X

51.4 17.97 1

mg/L PPD 7.9 6551.1 1

u. Molybdenum.

[74$9 98 7)

X 4 0.03 40.01 1

mg/L PPD 4 0.05

< 24.9 1

v. M ng.nes..

Totst (7439 96-5)

X 0.038 0.013 1

mg/L PPD

< 0.01 48.292 1

w. Tin. Total X

41 40.3497 1

mg/L PPD

.1 4829.2 1

m. 7 6tenium.

l

[72E32.s>

X 4 0.021 40.007 1.

mg/L PPD

< 0.5

( 414.6 1

rua Emm PAGE V-2 CONTINUE ON PAGE V -

mn.w <a.nns

EP A 1.D. NUM 5LER (Copy [ rom frtM i of Form JJ OUTFALL NUMWiR OH006346 001 ONT1'NUED FROM PAGE 3 OF FORM 2.C PART C - If you are a primary industry and this outf all contains process wastewater, refer to Table 2c-2 in the instructions to determine whic'h of the GC/MS fractions you must test for. Ma 2.s for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2 a (secondary industrict, rionprocess westewater out/a//s, andnonrequired GC/MS fractions /, mark "X" in column 2-b for each pollutant you know or have reason to believe is present. Mark "X? in column 2-c f or each pollutant you believe is absent. lf you mark column 28 for any pollutant, you must provide the results of at least one analysis for that pollutant. lf you merk column 2b for any pollutant, you must prov of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrstions of 10 ppb or greater. lf you fnark column 2b for acrotein, acrylon dinitrophenot. or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each ci these pollutants wh be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (a/T 7pages) for each outfall. See instructions for additional details and requirements.

8 4. UNITS -

5. INT AKE (optional)

. POLLUTANT

a. M ARK ax*

3. EFFLU ENT s

C.LON G T

.VALUE d, N O.0 F hg

-dE E,R& g ONG b NO F

N M M Y.VALUE D""*'

gc NUMBER a 7,eyty,gg,e e,

e M AxtMUM D AtLY V ALUE (if resilable) og. 7"U

, e J,,,,,,y,,,,,,

til man

,,,,,y,,,,,,

(a) unos

,,,, f,p, u,,,

g a ) =...

N M.707 N

"q*

N

N ETALS, CYANIDE, AND TOTAL PHENOLS M. Antimony, T 0.5

< 0.175 1

mg/L PPD

t. 0.5 4414 1

otai t7440 36 o)

X X

WL Arsinic, Total 1

mg/L PPD-L 0.003 4 2.49 1

744Sas-2)

X X

< 0.03 T 0.01 EM. 81ryllium, 1

mg/L PPD 4.0.005 4 4.14 1

otai, 7440-41 71 X

X

< 0.005

< 0.001

.M. Csdmium, 1

mg/L PPD

< 0.005 4 4.14 1

'otal (7440-43-9) y X < 0.005

< 0,001 M. Chromium, otsi (7440-47 3)

X X

% 0.01

< 0.003 1

mg/L PPD

<.0.01

< 8.29 1

M. Copper Total

'" S508)

X X

< 0.04

< 0.014 1

mg/L PPD 4 0.02 416.6 1

'M. Lead. Total 1

mg/L PPD 4 0.05 441.4 1

7439.s7-n X

X < 0.15

< 0.05 M. M rreury, Total 7439-97 6)

X X < 0.002

< 0.0007 1

mg/L PPD 4.0002 40.166 1

iM. Nicket, Total 744 - 2 0)

X X < 0.06

< 0.02 1

mg/L PPD 40.03

<24.9 1

oM. Silenium, otel (7782 49-2)

X X

< 0.04

% 0.014 1

mg/L PPD 4 0.004 4 3.31 1

1M. Silver, Total 744 4)

X X T0.01

< 0.003 1

mg/L PPD 4 0.01

<'8.29 1

2M. Thallium,

~ t*'87d*>28-o)

X X

< 0.3 5 0.1 1

mg/L PPD 40.3 4249 1

3M. Zinc, Total 7d4488 81 X

X < 0.06

< 0.02 1

mg/L PPD

(.0.02 416.6 1

4M. Cy.nio.,

'ota' (37 t2-5)

X X < 0.005

% 0.001 1

mg/L PPD 4 0.005 <4.14 1

'SM. Fhenols, t='

X X

C 0.005

< 0.001 1

mg/L PPD 40.005 < 4.14 1

, +..

) TOXIN 3.7.8-Tetra-DEfCRIBE REsuLTS hlorodibenro-P.

y Dioxin (1764-016)

CONTINUE ON REVERSE pang v.3

na e..

mae,....

.=m

001 ONTINUED FROM THE FRONT

- T'"d*"

" ** 4. U NITS

5. I N T A K E (cptionalf

3. EFFt.U ENT

1. pot.LUT AN T

2. M A R M *x*

ghOdG (ER$

b NO F' '

NUMBER 8 7,82 *},

7,f,$ a. M AMIMUM D ABLY V ALUE

"^^'$ N,ifeS$[

- W " M Mg haf*VALUE

^

O g

3 g

g y p),,,,,,

(s)wass

,,,,, y),,,,,,

(a) = = ss

gggggg gyJ (m,..y M SEs* E.9"

%,*,*,%7 f el mass VSES (if sucilable) eJj. EU ss =r

!$WJNMMlleh6?""@ * *h -* @cM??"* -

' + *

3C/MS FRACTION -VOLATILE COMPOUNDS T 00 4 82.9 1

V. Acrtfeln 1

ug/L PPD 1

107-02 4)

X X

< 100 0.035

V. Acrytonitrile 1

uq/L PPD (100 482.9 1

107-13-1)

X X

<- 100 0.035 iv. swron.

1 uq/L PPD

<5 4 4.14 1

71432)

X X

< 5 0.002 IV. 8Is (CMoro-EY2TE.h'"*"

X NA NA 0

uq/L PPD N/A N/A 1

.V. Bromoform 1

uq/L PPD

<5 44.14 1

73-25-2)

X X

( 5 0.002

.V. Ctrusn

s3fy**

X X

% 5 0.002 1

uq/L PPD T5 4 4.14 l'

s V. Chlorobenzene 1

uq/L PPD T5

< 4.14 1

108-947)

X X

s 5 0.002

.V. Chlorodi-1 uq/L PPD

<5 44.14 1

i*s.LT.h"*"'

X X

< 5 0.002 V. Chloroethene 1

uq/L PPD

\\ 10

<8.29 1

7s-oS3)

X

-X

< 10 0.003 OV. 2-Chloro-iT7$Ii X

X

< 10 0.003 1

uq/L PPD - $10 (8.29 1

E *""

IV. Chlorof orm T 5 (4.14 1

sm-3)

X X

< 5 0.002 1

uq/L PPD 2V. Dichtoro-

$"2N'"*"*

X X < 5 0.002 1

uq/L PPD T 5 44.14 1

3V. Dichloro-litutremethane 0

uq/L PPD N/A N/A 1

is.71c X

NA NA 4V.1,1-Olchloro-thca' (75-34-3)

X X < 5 0.002 1

ug/L PPD f5

<4.14 1

SV.1.2-D! chloro-Y 5 4.14 1

thane (107-06-2)

X X < 5 0.002 1

ua/L PPD 4

SV.1,1 DichIoro-I 5

<4.14 1

1 ug/L PPD t*tytM (75-35-4)

X X < 5 0.002 i

7V.1,2-Dichloro-T 5 d _14

+

reprna (78 87 s' X

X

< 5 0.002 1

ug/L PPD 4

CV.1.3-Dichforo-5 5 d4.14 1

wonen42m X

X

< 5 0.002 1

ug/L PPD (5

(4.14 y

9V. Ethylbenzene i co-41-41 X

X

< c; 0.002 1

"9/n ppn oY"oN7Ys3 98 1

ua/L PPD T10 44.29 1

X X

<. 10 0.003 (10 1V. MMhyt 48.29 1

hiorm (7447 3)

X X ( 10 0.003 1

ua/L PPD CONTINUE ON PAGE V-!

a r e n 9t-te.om yAGEy.4

...............,.. u,

)NTINUED FROM PAGE V-4 C)M006'446

.I

. PO Lt.U TAN T

2. M A R M *st'

3. EFFLUENT g-

d. U NIT 3

5. INT AKE (optioncf/

o y; j.goM G TE R

.VALUE O

Y V A LU k c.LONG T Mg NUMBE

",'ff 'd,$,J,5 %'.,

s. M AxsMUM D AILY V ALUE D*"^* M.MaNJ gggg (t/ erstrable)

.{;-

US

..%,,;,, t,',i,,,,,j t.)....

,,,,,,I,*1,,,,,,,

t:3....

l,g,,t,*)gg,,,

C til mase J

.vses T?^3 BON t,

,e;c e, e.

g, g,,,,

yggg s

^

iC/MS FR ACTION - VOLATILE COMPOUNDS (continraed)

NC&tt it. '.iJA higrida (75-09-21 X

X

< 10 50.003 1

ug/L PPD

<5 5 4.14 1

2V. M nhytene

$a7s7'"'

X X

<5

< 0.002 1

ug/L ppd

<5

< 4.14 1

3V.1,1,2,2 Tatra-thyl@ns (127 18-4) X X

<5

$0.002 1

ug/L PPD

<5

% 4.14 4V. Tetrachloro-y x

X

<. 5 50.002 1

ug/L ppd

<5

% 4.14 sv. Toiueno so8-sa a>

SV.1,2.Trans-X X

A5

% 0.002 1

ug/L ppd

<5

< 4.14 1

/*NE"*"

Ns7sS*"*

x X

<5 50.002 1

ug/L ppd 5

< 4.14 1

7V.1,1,1 Trb A

BV.1,1,2 Trt.

}

4 5

% 4.14 79-00-5) x X

<5

< 0.002 1

ug/L PPD

,loroethene x

X

<5 50.002 1

ug/L PPD

%5

< 4.14 1

9V. Trichloro, thyiene (79-01 s)

DY. Trichloro.

1 0

ug/L ppd NA NA

,ugeg nene X

NA NA 1

iv. vin [7s oi.4)

X X

< 10

<0.003 1

ug/L ppn q 10 A 90 i

hrsrid

?'

C/MS FRACTION-ACID COMPOUNDS W**W ^T 12 M*N

?

ism 8>

X X

< 10

< 0.003 1

uq/L PPD

< 10 4 8_29 1

l A. 2,4 Dichloro-honoi (120-83-21 X

X

<.10

%0.003 1

uq/L PPD

< 10

< 8.29 1

l A. 2,4-Olmethy1 1

ug/L PPD 5 10

< 8.29 1

honot (10s-67 9)

X X

< 10

< 0.003 ruoi (s34-s2-1)

X X

% 50 50.02 1

ug/L PPD C 50

< 41.4 1

A. 4.6-Dinitro-O-hemi (s1-28 s>

X X

< 50

< 0.02 1

ua/L PPD 5 50

<41.4 1

A. 2.4-Dinitro.

18 7 s-5)

X X

( 10

<0.003 1

uq/L PPD 510 5.8.29 1

A. 2 Hitrophenol A. 4-Nitrophenot 100-02 7)

X X

< 50 90.02 1

uq/L PPD

' 50 5 41.4 1

A. P-Chloro-M.

rssei (59-s 0-7)

X X

< 10 (0.003 1

uq/L PPD

< 10 4 8.29 1

A. Psntechloro-q hsnot (87 86-s)

X X

< 50

<0.02 1

uq/L PPD 50

< 41_4 1

OA.Phsnot 4

ica-93 21 X

X 10

< 0.003 1

uq/L PPD 10

<8.29 1

1 A. 2,4.6 Trh S.29 1

on i X

X 5 10 50.003 1

uq/L PPD

$10 8

Eos?"n 2

ONTINUED FROM THE FRONT

001

3. EFFLUENT

'4. UNITS I

S. IN T A K E (opr#maff

1. POLLUT A NT

a. M ann x-c.LONG T y.VALUE MolOF [ #k*(hm JdONG TER h N O.O F

s. M AXIMUM D AILY V ALUE D* MAX 8% M.y M YVALUE 3

YsN NUMBER 87JJ*},*l-j,*,7, Ysh.NN M,*gae

a-t il....

(if evedoblef

. f,4-U.ti

,,, g),,,,,,,, l t,3....

,,,,,, p),, n,,

g.3....

, f,,,,,g,i,,,g q (,i... 9 Y-4, GC/MS FRACTION - BASE / NEUTRAL COMPOUNDS r

(83-32 93 X

X

< 10

<0.003 1

ug/L PPD g10 4

l o: Acen.phthen.

8.29 1

g (208-96-8)

X X

< 10

\\ 0.003 1

ug/L PPD 10

< 8.29 1

2B. Aese.ohtyion.

4 (12412-7)

X X

< 10

< 0.003 l

1 ug/L PPD 10

< 8.29 i

38. Anthrecone q

(9247-5)

X X

< 50

% 0.02 1

ug/L PPD 10

< 41.4

48. Brnriern.

1 5 B. Brnro (a)

"s'"7*i,a*

X X

% 10

%.0.003 1

ug/L PPD 10

< 8.29 i

i 5

( 10

< 8.29 1

6B. BInto (of 5.003 1

ug/L PPD Pyrene (50-3241 X

X

% 10 0

5 l

l' ug/L PPD 10

< 8.29 1

78. 3/rBenro-E285Y9-2)

X X

< 10 5 0.003 j

I 1

ug/L PPD 10

< 8.29 8 B. 82nzo (ghij 1

Ii9ff4-2, X

X

% 10

< 0.003 g

98. BSnro @)

ug/L PPD 10

<8.29 1

[2geggf"*

X X

% 10

\\ 0.003 1

108. G1s (2-Chloro-q I Wi l U"*"*

X X

< 10

<0.003 1

ug/L PPD 10

\\ 8.29 1

118. Ble (2 Chloro-IEi1D)*'

X X

4 10

\\ 0.003 1

ug/L PPD 10

<8.29 1

orcar'/ Edw(102W)

X X

25 0.0087 1

ug/L PPD q 10 8.29 1

128 Bis (2thforoire-13D. Bis (2-Ethyl-N 10 58.29 1

5.003 1

ug/L PPD I1NS1YY **

X X

< 10 0

148. 4 Brorno-Ether (101-55-3)

X X

< 10 50.003 1

ug/L PPD 10 fCS.29 1

phsnyt Phenyl 4, 10 5 8.29 1

158. Butyl Benzyl Phthilste (85-68-7)

X X

( 10 0.003 1

ua/L PPD 5.29 168. 2 Chloro.

M"S8jf"*

X X

( 10 0.003 1

ua/L PPD

< 10 8

1

\\

17 B. 4-Chlerc-EE"JI7OEY2-3> X X

< 10 (0.003 1

ug/L PPD 10 N

8.29 1

158. Chrysene (218-01-9)

X X

( 10 5 0.003 1

ua/L PPD 10

%8.29 1

19 8. Olbenzo (a.h/

4 g

Anthracene 1

ug/L PPD 10 8.29 1

G3 7S3)

X X

10 5 0.003 208.1.2 Olchloro-g y

y

(

(0.003 1

ua/L PPD 10 8.29 1

benz $ne (95-50-1) 4 10 k

aiB i 3 oichloro-8.29 1

bent:ne (54173.i: X x

5 10 g 0.003 i

ua/L PPD CONTINUE ON PAGE V-PAGE V-8

- + -

=r

- o m.

m.

a

EPA 1.D. NUMCER (copy from ifem I of form 1) OUTFALL NUMEZER I

OH006346 001

ONTINUED FROM PAGE V-6

4. UNITS

5. INT AK E (esptmetaff

3. EFFLUENT onG TcR g o y

gfg d'RAGtVA

. POLLUTANT

t. M A RM x'

pg.VALUE C.LON G T M

O F

gY V ALU E b.MAXA

s. M AXIMUM D AILY V ALUE T " "T ' * "

b i ff7,,"-

t el.' a ss vsEs NUMBER

" l"J ' '),

l*,f,M*,

,,,,u ;),,,,,,,l t 4 =...

,,,,, j,),,,,,,,,

t,1 = = * *

,,,,, l'),,,,,,,

Ed uase vsEs t

*f- 0M

.W,

( I setilabicJ e

IC/MS FRACTION - BASE / NEUTRAL COMPOUNDS (continued' 1,

ug/L PPD 4

C.29 1

8 10 223.1,4Dichloro-T 10

< 0.003

>enzzne 11os-48 7:

X X

238. 3,3* Dichloro<

1 ug/L PPD S 20

<16.6 1

I X

X t 20 50.007 9 i-9 248. Diethyt 1

ug/L PPD C 10

< 8.29 1

Is"f$$

X X

< 10 5 0.003 258. Dimethyl 1

ug/L PPD 5 10

< 8. 29 3

ti3i.ii 3 X

X 4 10

< 0.003 7hthtlete 26 8. 06-rd-Sutyt 1

ug/L PPD

< 10 48.29 3

5 0.003

84762:

X

.X

% 10 s hth&l?ts 1

ug/L PPD N 10

<8.29 3

27 B. 2,4 Dinitro-toluena 021-1+2)

X X

< 10 (0.003 1

ug/L PPD N 10 58.29 3

22 B. 2.,6-Olnitro-sos-20-2)

X X

% 10 4 0.003 toluen 1

ug/L PPD

$ 10

<8.29 1

29 B. Di-N-Octyl Ei$$EIn X

X

< 10 (0.003 1

ug/L PPD

< 10 (8.29 1

lo A 1.2-Diphenyl-5.003 J

f*

X X

% 10 0

' U'fn'";*t$72 e'6 7 :

(208-8601 x

X

< 10 4 0.003 ug/L PPD 5 10 18.29 3

1 313. Fluorenthene 1

ug/L PPD N 10

%8.29 3

328. F luorone 5.003 (8 " 3 73 X

X

< 10 0

1 1

ug/L PPD

\\ 10 A8.29 3

us.9e a m eno usm3 X

X

< 10 (0.003 343. H:xe-1 ug/L PPD

$ 10 (8.29 1

i$ sui"'*"*

X X t 10 (0.003 35 8..HIx echloro-1 ug/L PPD

< 10 48.29 1

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X X

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- - (57'7"

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37% Indono 1

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X 5 10

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k.29 1

1 uq/L PPD 10 38 B. Isophorone 5.003 (78a.n X

X N 10 0

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5 8

1 ug/L PPD 10 398. Naphthaleno (91-2 S3)

X X

$ 10

$0.003 4

5.003 1

ua/L PPD 10 8.29 1

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X X

$10 0

k k.29 1 '

i 1

uq/L PPD 10 419. N-N itro-(62759)

X X

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8 5.003 l

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X N10 0

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EPA i.D. NUMLER (copy front lesna 1 of Forns 1)

PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or sti of this information on separate sheets fuse the same format)instead of completing these pages, OH006346 sEE INSTRUCTIONS PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one tab

s.:.

4. INT AKE (oprfonal)

i'

.,. 3. UNITS sig.

,csi - 2. EFFLU ENT W i *. C'

Y- '

+

"A AG A

W 41NO OF

b. map.}yy,jg,gg,yVAwE mM y,y,p,y,f. 9W 8 -

d.NO.0F h"8 e..e, N),,,,,,

ta) man

1. Pot.LUT ANT

e. M AxtuuM cAILY vALuc "A

I'I"""

c onc e ht'e n vie =

I'3 "a n R AT M e en e.II-ano.

I'I " * "

coat.

.,*o=

2. sioceem.cei 1

mg/L PPD

( 3.0

< 2489 1

,fJ y," " *"d

( 3.0

( 2079 D. Chemical 1

mg/L PPD (20.

(16593 1

<c"Jy,"

"'"d

( 20.0

( 13861

.Toni orsenic 1

mg/L PPD 1.8 1493 1

carbon troc>

2.6 1665

d. Tot.i su.oend.d 1

ma/L PPD 1.6 1327 1

8*ud*F83>

2.5 1732 1

ma/L PPD

.34 282 1

9 Ammonie (as NJ

.90 624 VALUE VALUE VALUE 99.36 NA VALUE 58.7 NA MGD NA

f. Flow VALUE 146.3 VALUE VALUE

.72 NA VALUE g Temperature NA vaLuE T"'">

12.22 vALUE C

25 NA vALuE vALus Tesere NA tama">

28.33 f*. s..g j.ag. g 3

u,Niuum m Aximuu miNimuu u A Aimuu

,N *,

" **"M

"'I*c ' M W'

18

i. "

8.1 8.2 k l n 2a for anypo!!utant Merk "X" in column 2.s for each pollutant you lu mn or have reason to believe is present. Mark "X"..in column 2-b for each poIIutant yo f

whichislimitedeitherdirectfy,orindirectlybutexpressly.Inaneffluentlimitstiorisguideline,youmustprovide i

f dditional details and requirements.

PART B -

. 5. INTAKE (opric.1all e '?.4; U NITS.

'; M c <"../

t

3. EFFLUENTa

AVE AGE ALUE M O. O F

2. M A R K 'X *I d NO. OF e. CO((bE N.

Ik M As's '-

ANT AND e....

o,,,,

s. M AxlMuM DAILY V Al.uE W ft.ffahd, (VachaY,'V^

A N A L-

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is) man-

,,,,, k),,,,,,

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,,,,,1Q,,,,..,

ts)=au vsEs

C CAS NO.

(if et enable) 1 mg/L PPD 40 33170 1

s. Bremide (24959-67-9)

X 31 37851 1

mg/L PPD 4.01 48.292 1

b. Chlorine.

Total aniduo' X

4 0.01

( 12.21 1

Pt-Co NA 10 8292.5 1

X 10 12210 1

col /100nl NA 4 3 NA 1

d. Fecal conform X

43 NA 1

mg/L PPD 0.1 82.92 1

e. Fluoride (16984 a8 4)

X 0.1 122,1

f. Nitrate-1 mg/L PPD 0.5 414.63 1

Nitrite (as NJ X

0.7 854.7 CONTINUE ON REVERSE P AGE V-1 EPA Form 3510-2C (8-f J)

'u

004

5. INT AKC (ntrriornl/

l

' ITEM V B"CCNTINtlFD F ROM FRONT

~* M N

T. h *?,

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I X

2 2441.9 T ot e

9. g.ms 1

ra r,

1 mg/L PPD 4 4 43522

h. Oi - 7 X 44 4884

6. Phcspho'us 1

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' PPD 0.4 331.70 1__

W72ill'oT X

1.8 2198

..m E

1. R adioactivity 4 3 NA 1 __

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43 NA 4 5 NA 1

(2) tets.

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4 NA 1

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< < > R.d '"*

0.1 +/-

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0.1 NA 1

2 2 8 ' '*'

X o,1 NA

k. Sulf ate F

g/L M

M MM 1

p 8yg,,,,

X U

M9 1

mg/L PPD

<- 0.1 L82.92 1

1. Suffid.

'= 8e X

1.5 1831

m. sumt.

1 mg/L PPD C1 829.2 1

$c$ l! s.33 X 41 1220 441.4 1

1 mg/L PPD 4.05 X

L 0.05 60.1

"**"d'""

< ium.aum.

1 mg/L PPD L- 0.2 4166 1

IISk9o.s>

X 40.2 244

p. Defium, 1

mg/L PPD L 0.2 C166 1

I/S539 31 X

40.2 244 Q. BoTon, 1

mg/L PPD 4 0.2 4 166 1

[ISk42-si X

40.2 244

r. Cobeit.

1 mg/L PPD 4 0.04 433.1 1

I/Sk 8 4i X

4 0.04 48.8 1

mg/L PPD 0.22 182.44 1

s. Iron, Totat (7439 89 6)

X 0.12 146.5

s. u.en...um.

1 mg/L PPD 7.9 6551.1 1

7439 9s 4i X

10.9 13308.

Tetet

u. voivoo.num.

1 mg/L PPD

< 0.03 424.9 1

((5598a:

X 4 0.03 36.6

.. u.ne.n...

1 mg/L PPD

' O.01 48.292 1

I?Uk9e si X

4 0.01 12.2 d

.1 4829.2 1

w. Tin. To tet 1

mg/L PPD

""S

5' X

41 1221.0

.. T n.nium.

1 mg/L PPD

4. 0.5 4414.6 1

1

[ISk32.si X

4 0.010 12.2 CONTINUE ON PAGE V 3 1

PAGE V-2

)

EPA Form 3510 2C (8-90) i

EPA 1.D. NUM1ER (Copy from Jf.m J of Form JJ OUTf ALL NUM2ER--

OH006346 004

ONTINUED FROM PAGE 3 OF FORM 2-C i

PART C. If you are a primary industry and this outf all contains process wastewater, refer to Table 2c-2 in the instructions to det

^

2.s for all such GC/MS fractions that apply to your industry and for ALL toxic metsis, cyanides, and total phenots. lf you are not required to mark column 2-a Mark "X"in column 2-c for each pollutant you wastewater our/a/ls, and nonrequired GC/MS fractions /, mark "X** In column 2-b for each pollutant you know or have reason to believe is present.

believe is absent. If you mark column 2a for any pollutant,you must provide the resuits of at lesst one analysis for that pollutant.lf you markcolumn 2b of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. lf you m dinitrophenot, or 2-methyl-4,6 dinitrophenol, you must provide the results of at least one analysis for each of these po!!utants which you know o concentretions of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at idast one analysis or briefly d be drscharged Note that thers are 7 pages to this part; pfesse review each carefully. Complete one table (aft,7pages) for each outfall. See instruct

3. EFFLUENT Y T,D M M.d Q Sf;Edi s y.'

- 46 CUNITSMM Mb5.;IN T4 KE1oprional/

. POLLUTANT z M ARK *x' G ER D NO F

gh

-ho NUMBE 8 7.'..3%J 5%',, s. M AxsMUM D AILY VALUE D " ^^'$MMY, V ALU E cgg.TgM pgg4LKE4 O F of. aorn op. Im

.v.s,,,,,, v,1,,,,,,

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,,,,,, !,y,,,,,,,,

r.: e... gengi,;g Ngen..: s.vsEsc m' ^9" c mnem Mt.v,y %m vses M*?FIF WW '

Ib!TWMN#

E MW'O *-

1ETALS, CYANIDE, AND TOTAL PHENOLS M. Antimony, 1

mg/L PPD S 0.5

<414 1

X X < 0.5 4 6.09 otal (7440-36-o)

M. Arsonic. Totsi 1

mg/L PPD-

< 0.003 5 2.49 1

re38 25 X

X 4 0.003 4 3.66 M. Biryt: lum.

1 mg/L PPD

< 0.005 % 4.14 1

'"' 744041 75 X

X 4mm 4 LM M. Cedmium.

1 mg/L PPD

< 0.005 5 4.14 1

L 6.09

'"'(

od3Si X

X 4 0.005 4 0.01 4 12.21 1

mg/L PPD

< 0.01

< 8.29 1

M. Chromium.

a' (7'*o-47 3)

X X

5 0.02

( 16.6 1

u. co.r. imi Z. 24.41 1

mg/L PPD C 0.02

'owal X

X 4

4 60.98 1

mg/L PPD 5 0.05

% 41. 4-1 48 Leaa, Total

38-82 11 X

X 0.05 5.0002 <0.166 1

M. u.,cury Tot.i 0

. '439 97-81 X

X 4

4.244 1

mg/L PPD 0.0002 4 36.63 1

mg/L PPD 5 0.03 524.9 1

M. Nick el, Total.

'

02-01 ~

X X

4 0.03 ot i cn8249 2)

X y

(

4.88 1

mg/L PPD 0.004 5 3.31 1

au. sa.nium, d

n_nnd w 224)

X X

< 0.01

< 12.21 1

mg/L PPD 5 0.01 5 8.29 1

IM. Silver, Total 2M. ThMilum.

1 mg/L PPD 50.3 5249 1

3t.u744o-28-o1 X

X

< 0. 3 4 366.3 4

1 mg/L PPD T 0.02

<16.6 1

l 3M. Zinc, Total "S*

X X

< 0.02 24.41 I

mg/L PPD

< 0.005 54.14 1

SM. Cyrnid..

4 st:l (57-t 2-5)

X X

< 0.005 6.09 5 0.005 54.14 1

3M. Phenols, ot? :

X X

C 0.005 L

1 mg/L PPD 6.no 10xxN ~

W.6,6RutsnMhny;r.p.wew-MJawayagemnepamgp,++gy.;mggwlwgp:.p:-

3.7,8-Tetre-DESCRISE RESULTS Jorod!bento-P.

'o4o(176441-6)

X CONTINUE ON REVERSE PAGEv.3 PA Farm 3510-2C (8 90)

CONTINUED FROM THE FRONT

004

t. rou.uTAN

M*ru.4p6tq2iLit:Milenameswggye^ gggggnsrJgitriitty6ima

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ii- '

ma acus FRACTION :,v0t4Tmsr.c..c.,. C rW Mw+

m~ mm awwe

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+'

(ic73a)?.(y{g:

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X

< 100 122.1 1

ug/L PPD T100 4 82.9 1

24.1Mo'niinfD7 (tahi.3;.inggif X

X

<.100 122.1 1

ug/L PPD C100 4 82.9 1

3Eun' uni'@AM (7.14g2) f f*

t X

X 55 6.09 1

uq/L PPD

<5 4 4.14 1

4V. sie (Chloro-H Q*$?%.'39h$.

X NA NA 0

ua/L PPD N/A N/A 1

av':bi'&&b+oW'.

(7s-2?;2)ceb7!:

X X <5 6.09 1

uq/L PPD

<5 44.14 1

av. certion...

X X \\ 5 6.09 1

uq/L PPD f5 44.14 1

[sE*3jy??%

h 7V. Chlorobenton.

1 uq/L PPD T5

< 4.14 1

(108-90-7)'

X y

(5 6.09 ave chieredi..

Ii2 G N 7"I 5.

X X

N 1

uq/L PPD T5 44.14 1

5 6.09 oV. Cht' ro'eth' n.'-

o a

12.21 1

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<10 4 8.29 1

(7540-3h X

X 5 1n 10V. 2<,htoro.

@EE"d/>'jff}

X X

5 12.21 1

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in iividierMErrs" 3

T 5 (4.14 1

(87-66-3)w.gt X

X 4.3 5.25 1

uo/L PPD 12V. Dichio 4

Isiisii$$' {}

g 1

ua/L PPD T 5 44.14 1

X X

2.1 2.55 13VE:Dit:hloroWg

$My*h X

NA 0

ug/L PPD N/A N/A 1

NA 09.tfydiniW N 5 1

ug/L PPD f5

< 4.14 1

- gf.54ft$i X

X 6.09 18%tT' nth 11M Y 5 I4.14 1

(fa'.J10t9K X

X <5 6.09 1

ua/L PPD r

~ VSii'6Gi'or^o ie T 5

< 4.14 1

othy'*a* (75-351)

X X 55 6.09 1

ug/L PPn 17V.1,2-OE5ior$

Y 5 d.14 1

< 5 6.09 1

ug/L PPD 4

propan* (7847-51' X

X isv.t.s w.

Y 5 (4.14 1

WW 7541 X

X

<5 G.09 1

ug/L PPD 5 ov. Ethyin.nr.n.

7 5 5 6.09 1

ng/L PPD 5

d4.14 1

(toS*1-41 X

X 20V, Methyt

\\ 10 12.21 1

ua/L PPD T10 4 8.29 1

sromid. (7443-ol X

X s t v. u.thyi' T10 8.29 1

Chlorld.(7447 3)

X y k }0 12.21 1

ua/L PPD 4

CONTINUE ON PAGE V-!

PAGE V 4 EPA Form 3510 2C (8-M)

J= Estimated value; detected, but below quantitation litnit.

ONTINUE_D F'OM PAGF V 4 OH006346 004 l

3.' EFFLUENT '

'5Inf4NI.

ich4: LjNITS t-

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I

t. POLLUTANT

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'r7@'Shid%Qt.t.f X

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ug/L PPD

<5

< 4.14 1

r2v. u.thve.n.

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1 4 5 4 4.14 x

X 45 4 6.09 1

ug/L ppd ghighvi*a*

17V.1,1,1-Tri-C 1

4 5

< 6.09 1

ug/L PPD 5

44.14 7,'j$"

x X

1.V.1.1,2-Tri-1 4

4 5 4 4.14 x

X 5

4 6.09 1

ug/L ppo 7M" tev. Trichiere 4

y x

X 5

6.09 1

ug/L ppd 4 5 4 4.14 gyi.n. t78-01-6)

~.Trichloro-1 X

NA NA 0

ug/L ppd tm NA s-oi-41 X

X 4 10 412.21 1

ug/L ppn 4 to 4 n ?o 1

IC/MS FRACTION - ACID COMPOUNDS ' WYr ' ? @ CM9"PP.W M QMM14/ J 4$'if 5f*M '.*QW.,df{Tig$5%D$ C4 C@%hD sd&d '.EWQ74;."

Ph 7E3 X

k 4

4 12.21 1

ug/L PPD 4 10 L 8_29 1

10

.i. 2.e.-oicheoro-

.oot (i204s 21 X

k 4 10 4 12.21 1

uq/L PPD 10

< 8.29 1

4 IA.;no,4-Olm.thyk X

X 4 10 12.21 1

ug/L PPD 410 4-8.29 1

i 2

+ s tics-s7-o)

L 460.9 1

uq/L PPD 4 50 4 41.4 1

j IA'C e-otnitro-o.

r oi <ss4-s2 ti X

X 4 50 i4.no.4-oiniero-2

'h i tsi-28-s)

X X

L 50 60.9 1

ua/L PPD 450 4 41_4 1

L

'sI U s'E '*" '

X X

410 12.21 1

uq/L PPD 4 10 4 8.29 1

E

'A.#Aditroph.nol toCho2-7)

X X

L 50 4-60.9 1

uq/L PPD 4 50

< 41_4 1

'. M $s"I>Ti X

X 4

4 1

ug/L PPD 4 10 Ca.29 1_

10 12.21

A. P.nt. chloro-4

.h.nol (874s-s)

X X

A 60.9 1

uq/L PPD 50

< 41_4 1

50 A sE' X

X 2 10 12.21 1

uq/L PPD 410 48.29 1

1 A. 2.4.5 Tel-4 12.21 1

uq/L PPD 10 4

4.29 1

hieroph.not X

X 4 10 8

seos-23 CONTINUE ON REVERSE PAGEV.5 EPA Form 3510-2C (8-90)

CONTINUED FROM THE FRONT

.#004 i POLLUTANT a Mann x'

'3. EFFLUENT

4. UNIT 2

5. INT AME (oprinnell

e. M AXIMUM D All.Y VALUE D MAXI %$hi,%;Y V ALUE Mg c.LO N G T

.VALUE g

y ONG ERM g

y

2. NUMBER

", ', '. ' ' 'd. * !".

MAMN

.n'.fi/ evedeble)

. !,a 40

^1,,,,,, 8 *),,,,,, l. g et...

,,,e,.),,,,,,,

,g,,.....

,,, e, f.,3,,,,,,

g,,....

vses H eo.

g,9,,,,

ygg, e,

to.

GC/MS FRACTION - BASE /NEU' RAL COMPOUNDS 1 fD Acenophthene s pea si X

X 4 10 412.21 1

ug/L PPD 4 10 4 8.29 1

2'?Acone'phtvlene (208-864)

X X

4 10 412.21 1

ug/L PPD 4 10

( 8.29 1

38. Anthrocene (120w12-7)

X x

L 10 4 12.21 1

ug/L PPD 4 10 48.29 1

48. eenridine-

4 50

( 60.9 1

ug/L PPD 4 10 441.4 1

teac741 X

X E.8'senzo (a).

^"y7g,"? J X

X A 10 412.21 1

ug/L PPD 4 10 48.29 1

e$senio'Ve> '

X 4 10 4 12.21 1

ug/L PPD 4 10 48.29 1

ryrene tso 324:

X 7;L 3.4-Benzo.

X L 10 412.21 1

ug/L PPD 4 10

<8.29 1

E2SIYI2 X

sis: sean rehl>

X 10 412.21 1

ug/L PPD 4 10 4 8.29 1

[i9'.g,,

X 4

c s. s.nro (m)

I2EffEf"*

X I

.X 10 412.21 1

ug/L PPD 4 10 48.29 1

103. f. le (2-CMom X

4 10 412.21 1

ug/L PPD 4 10 4 8.29 1

{s $7[y,"h*"*

X

%18n te (2 Chloro-77,', 17,

X X

C 10 4.12.21 1

ug/L PPD 4 10 4 8.29 1

12k secven==

W E8=rt102:eoti X

4 10 412.21 1

ug/L PPD 4 10 4 8.29 1

X 13a t. Is (:-Ethyl-i UUSI.7/*'".*

4 10 4 8.29 1

X 4 10 412.21 1

ug/L PPD x

tu.ceromo EO!IEi sY2>

X L

L12.21 1

ug/L PPD 4 10 48.29 1

x 10 1s'd. Futyi eenryt rneheiste res-se-71 X

X L

4 12.21 1

vo/L PPD 4 10 48.29 10 1

168. 24hloro-5"siff"*

X X

4 L12.21 1

ua/L PPD 4 10 4.29 1

8 10 17A 4-Chloro-l 1

ua/L PPD

' 10 4.29 IDl FEY 2-s>

X X Lo 412.21 8

1 181 Chrysene 4.29 4 12.21 1

uo/L PPD 4 10 atxtel X

X 4 10 8

1 la oit=nzo (e.h>

s"[7U3 X

X 1

4 12.21 1

ua/L PPD 4 10 8.29 1

in 08.1.2-Dichloro.

4 4

E.29 1

X X

in 12.21 1

uo/L PPD 10 8

( 10 4

4

121.3-oichiaro-an'att541-73-1:

X X

4.29 1

12.21 1

ua/L PPD 10 8

PAGEV.4 CONTINUE ON PAGE V-7,,

PA Fore 3510-2C (B-90)

{ EPA I& MUMJ.iR (copy from litm J ef Form JJ GUTFALL NUM32R OH006346 004 CONTINUED FROM PAGE V/4 1

4. U NIT 3;

5. INT AKE (optional)

3. EFFLUENT ' s I; POLLUTANT

2. Mas 3et T YY%LUE c.LONG T

.VALUE dNOOF U

NUMBER

'. '.. ' ' 'I.%deM'.

s, MAXIMUM' DAILY VALUE4 NMahp A

A E

ANI -

e.CONCEN-

{ 'g g g'g*

TR ATION

{t e, -

. g,g,,,

yggy g

$,fi/ soeNeble)

. " * *. M *i e*s%,,,,, j'),,,,,,, l gege.nes

,,,,, p,B,,,,,,

.tsl=ses-

, t.L,,

g,3 vsts 24w: i

-Ati, 4 1 -

L'-

v-GC/ME FRACTION - BASE /NEtJTRAL COMPOUNDS teentinued' %

229' 1.LDichloro-1.

ug/L PPD 4 10

<8.29 1

b* eat (106-48 71 X

X

< 10 4' 12.21 238. 3,7 Dichloro.

UE'$.$

X X

t, 20 4 24.42 1

ug/L PPD L 20 516.6 1

248. Diethyl 1

ug/L PPD

( 10

< 8.29 1

[EE X

X 4 10 4 12.21 26 A Dirnethyt 26 8. OkN-Sury." _

X X

L 10 4 12.21 1

ug/L PPD

l. 10

<8.29 3

Phthelete ~

(i33.i s-3i,

.(85742)

X X

L 10 4 12.21 1

ug/L PPD

/.10 58.29 1

Phthelete 1

ug/L PPD

4. 10

<8.29 i

27 3. 2,4-Dinitro-Lto'uae 021-1+2)

X X

L 10 4 12.21 i.to'veae teos-20-2)

X X

L 10 4

1 ug/L PPD L 10

<8.29 7

282. 2.6-Olnttro-12.21

$2e ObN-Octyi 1

ug/L PPD L 10 8.29 1

$,7N X

X 4 10 4 1771 S.1,2-Olpheny 8 eenseE* t$2T[7:

X

.X L-10 4

ug/L PPD L 10

<8.29 1

1 17_91 S' Fluorenthene 4 12.21 1

ug/L PPD L 10 4 8.29 1

mi X

X 4 10 b1 Fluorene te6 73-7)

X X

4 10 4 12.21 1

ug/L PPD L10 t8.29 1

, PD L10 (8.29 3

33a.iemocNoneamens P

n t&7* 1F X

X 4 10 4 12.21 1

ug/L 348. Hexe-Is7D)***"*

X X

L 10

< 12.21 ug/L PPD 5 10

<. 8. 29 3

1 365. Hexechloro-is.4T/**'"*

X X

' 10 l 12.21 1

ug/L PPD T 10

( 8.29 3

othene (67-72-1) y y

4 4 12.21 1

ug/L PPD

< 10 58.29 l-'

368. Hexechloro; 0

37.t.Indono

{iiYl[*'*"*

X X

10 12.21 1

uq/L PPD

< 10

<8.29 1

A E

4 4 12.21 1

uq/L PPD 5 10

<8.29 1

38 L loophorone X

X 10 as 2n X

X 10 l-12.21 1

uq/L PPD T 10

<8.29 1

39L Neohthetene E

aos.Naroh.nr.n.

4 l-12.21 1

ua/L PPD

< 10

<8.29 1

(es-es-3 X

X 10 413. N-Nltro-I 10

<8.29 1

4 1

uq/L PPD 75D'*""*

X X

10 12.21 4

d

< 12.21 1

uq/L PPD

< 10 8.29 1

42% N-Nitrosodi.

"ei,"If,7"'

X X

10 CONTINUE ON REVERSE PAGE V-7 IPA Forin 3510-2C (s-90)

004 CONTINUE'*4 FROM THE FRONT

f. POLLUTANT a.MAnot?xt6..efi&+%

.W@ c. v

'*..;...v..

3,EFFt.t/ENT s w:

4##,Ib

.e -

4. UNITS

5. INT AKE fortionself

.VALUE

~

o.LOMG T g NUMBE

" '. '., * *).T.d,$k'- al MXittMue( OAlt.Y' val.UE 'l A " AAI$f"Mf,@ VALUE ddo O

G En O F

== a w

a.64,r

.yj. ::n. AL asw.ty,al.em.... c.),,,,,,W

.<. (.r...:w,,,,,, p) g,,_

m.....

y.E..

t,, ::-

m....

nE.

x M

y-. - cv' c:

OC/MS FR ACTION - BASE / NEUTRAL COIWOUNDS teontinuedJ s

n'$,*4f"!@"' $

438. N-Nltro-X X

< 10

<12.21 1

ug/L PPD

< 10

<8.29 1

44ece6.nentar.n.

(as-oty;Y-@

X X

< 10 (12.21 1

ug/L PPD 4 10

<8.29 1

4se.Pyr.n

..a.

4 10

<12.21 1

ug/L PPD q 10

<B.29 1

(12ewo) b.D X

X 4es.1,2.4.qre

$2%)%$y;3 x

X C 10

( 12.21 1

ug/L PPD

< 10 (8.29 1

GC/MS FRACTION a PESTICIDECpalGT.,"iRCZ.5 MVF '

C. !>

R *-

'11*.O

^-

1P.iAGrid (30ecoo.-2.)w.-

4 X

t.

2Pjd-bl4C' M

(31s44-e,)

X e w,w

/

3b dii 1'467 X'

(3.%=wt)d h

tygn

~

i x

eNEN5r'deM '*< -

get.@-di x

w 9,-3.1. m, 3 e

2 7

X

. s v.. !

6R4,W.bOE I d7 (72.m.85-9).'.s f..

X 9."$.WO O D'..?

(72444.)

^ S,h X

w 10P!dieldries (80:57;1)oQ'jd X

11P.6Endosulfen (115 29 7) 4 X

12P.8 Endoeulfen (113-29-7)

X 13P. Endosuffen Sutfate y

(1031 074) 14P. Endrin (72204)

X 15P. Endrin Aldehyde y

(7421 93-4)

ISP. Heptochlor (78-4 4)

X PAu M CON N O W N EPA Form 3510-2C (8-90) m

E, A t.49. MUMsEn (copy from item J of Form J) m UTFALL NUMBEA OH006346 004 CONTINUED FROM PAGE V 8

5. SNT AME (optioneff

3. EFFLUENT

h*

' 4.. U N ITS

5. POLLUTANT

2. M A W M *A*

N.-WM k'A d,N O.

e. CONCEN-A A

s. M AXIMUM DAILY V ALUE

"" hMN)

Ab I P

A N,d,-

NUMLER

", '. ',, "d,'!;d,'.*',;

TRATson th _M ass -

gygy, e,m g,,,,,,

y g e*.*

,,,,, [*),,,,,,

til =ase

,,,,, ['),,,,,,

tel mas,

,,,,,,f,',1,,,,,,,

talmne.

vsEs (4/ arsi8e ble)

." 7,4-Un

'GC#4S FRA CTION - PESTICIDES (continued).

17P. Hepteshlor Epoxide (102457-3)

X ISP. PC8-1242 (53469-21-9) y 19P. PC8-1254 (11097-69 1) y 20P. PC81221 (11104-28-2) y 21P. PCB-1232 (111C1 16-5) y 22P. PC8-1248 (12672-29-6) y 23P. PC 8-1260 (11096,82-5) y 24P. PCB-1016 (1267?+11-2) y 26P.Truephone 18o01 as 2)

X u.

pat.. V.9 i

-na r.-

usa 9e fit.tni

e

,"EP A 1.D. N UM k E R (ca,,, grom it4m j of Form j PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or a;ll of i

this information on separate sheets (use the same formarl instead of completing these pages.

SEE ffdSTRUCTIONS.

OuYFALLPeo f:)

V. INTAKE AND E FFLUENT CHARACTERISTICS (cont /rrued from page 3 of Form 2lC) 800 PART A - You must provide the results of at least one analysis for eveiy pollutaittWihiff36fe?AdiTpiste%6(ditableifo'r3shfFolitfallFSRGstTuctfo'riffoCa~dditional details.

-d.M ef?W I '* 2'J EFFLU ENT 95.M.Y$2M@dMMMIN.Y'*W ?% $I3MUNIT5:!*tfMTP

%"d?b?*4.'t' T AKE foprionall

'N C.LO N G.T gg VALUE5..

~'I'###b II bi8" D* "#9:Nyj8aN)Y V ALU E q,

, o g yg M

f. POLLUTANT

e. m A xsMUM D Ast.Y V ALUE

[,,' jk f,(,

, (e)wass c a c e br'= a r.o I8I "*

c o=c e ke',. e.o=

I'I " * "

c oi.e e he'= avve= ' ld Mass ' '

A RAT

.. e.ocnemicei

,,JE"

- - "d

<3.0

/ 2489 1

mg/L PPD

b. Chemicet Oxygin Demenc 4.20.0 PPD tcovi (16593 1

mg/L

c. Totti Organic c.roon troc>

1.8 1493 1

mg/L PPD

d. Totil Suspended souds(rssi 1.6 1327 1

mo/L PPD

"^*'"*"i"(*'"#

.34 282 1

m9/L PPD VALuE VALUE VALUE VALuk E

99.36 99.36 MGn N/A VALuc VALut vALUE VALuE T W W ure wM rer) y vALUE VALUE VALUE VALUE summers 25.0 NA mimuum

. Axmum umiuum maximum

ART B. Mark **X"in column 2-a for eac,h ' olfutant Mygprj ajf'

$s,yp

~ ffpg;r,kyoluiTt6.2a for any pollutant p

whichislimitedeitherdirectlylor,ind[r,ectJ/tiutoJpf,ogly, rygejfl e,su tsp

[orghgpo!!utants forwhich ycu mark column 2a you must provide quantitagi,ve date orien e,xp,,ngo,

,r prgsyce ge4e,ogetabigfg_ eg,gugy, ns4 ns fot,adgign,al,d_etai_Is and requirements.

a W.. W.j. 43.:,EFFLU ENTMM*MtWNTY.$@MpMhW@ 'Udit C7tYfi43U NITS *We MIL cO 5f t NT A KE (oprionalf l. PO LLU T.

2. u A u r f'fQh i"'M*AUNG hLdM

'

It syf;

e. M AxtuuM DAILY V ALug b. M.Ax,t4gggY,V A,LU Eg LOJ g

VALUE O

F O

F ace g

AS N 6*a (f/ eveffable)

IEU s'e = t,,,,,, iG,,,,,,,

. (si mass-J

, g,,,, [G,,,,, g;,

i s taJ uass,.,",;;t1')fg,g

's tal = ass vsEs

,,,,, D),,,,,,

Id==ss vsEs TRAvton

. Bromids X

40 33170 1

mn/L PPn

. Chlorine, y

(Q,Ql

( 8.292 1

mg/L PPD 0101 Fts:siduel C*

X 1

Pt-Co N/A 10 8292.5

-I7oi X

<3 N/A 1

Gl/100 o

ml N/A Fluorida isesS48

X 0.1 82.92 1

ma/L PPD N t'&

' trip (*' N>

X 0.5 414.63 l

1 m2/L PPD PAGE V-1 EPA Form 3510 2C (8 90)

CONTINUE ON REVERSE

ITEM V B CONTINUED FROM FRONT

800

'k'n-4. U NIT 3-

5. I N T A K E (n,"rremalj s '*

~'*~~~

Ak.".:!q, :,Wpv.w"W4?443.1ErrsinstnTV~ w'"HG Tg/tM,ffigt7. V ALQ

x. u n u N :*c 1*:s.:

Oi (Mue(,hthy.viduQ,$ M.AxagM gg,4vgus eggg-v..,,

g.wame gog siron t.uTr-c.

. c"'nr. Ash."o T

...J, f..cc

^

D eS PE ';. A.g.a.4.,,;,,

..s,,7 m.,,.7,,a9;,,;,

,,, y,,

,,,, a.x,,,,,,

Ay,g.

t.:-...

vses e...........

e.

ee

g. Nitrogen,..

Titel Orgenic 1

mg/L PPD re. ur.,

X

<1 4 829.25 rat one.. -

1 mg/L PPD CTc.N '

X

< 4 c3322 (se I'J, Totel. -

1 mg/L

' PPD

4. Phosphorus (7723 14-01.,..

X 0.4 331.70

?@lWt'.M @.WhMif

- w

'~

v ceelosen, tty.

?~

':cc-w

~ :s'.4-(ifrAb rie 'ms

.TSylM.,8i X

43 fa' 1

pCi/L NA (2IJi ete". - 4

?*f!,41k"!k'E 1

pCi/L ta X

4 5 NA 7.*$pIRedlu"mT'-

(3 'i'i$$

1 pCi/L NA X

4 4 NA s

i 24spam,7%

22,goig X

40.1 NA 1

rCi/L NA k; S 4 ifett 1

mg/L PPD f7Md#.l9-sM X 18 14926

s. suma. M5?.

1 mg/L PPD

(**EA*MF 4 0.1 c82.92 m, S. ifite i r 3 Tes*SO )-!W' 1

mg/L PPD 3

X

< 1 (829.2 ticassas.33 1

mg/L PPD

n. krfectente X

4 0.05 441,4 ew Aluminum, (7029945)-

d g,7 (166.

1 mg/L PPD TAtil

p. Serium,.- -

Tgy;g *.-e.. V 1

mg/L PPD (74dlG39-3 v.y X

(. 0.2 (166

= Swon.

1 mg/L PPD T5 t'.I -

p44o.424 X

4, 0.2 d gg

r. Cobalt, Tit? tW3;g4g, 1

mg/L PPD m4o.4s-4) ^

X 4 0.04

(,, i e tron, Total 1

mg/L PPD (74anto X

0.22~

182.44

t. ueen ium.

TA t?!

1 mg/L PPD (7'.39-95 X 7.9 6551.1

.. unydo.num.

1 mg/L PPD I/Nol.h X

4 0.03 4 24.9

v. ueneen '.

1 mg/L PPD T4tt ' 453 '

d 0.01 f-8.292 r

(7439-96

w. T1n. Totet 1

mg/L PPD X

4 1 482g_7 Titenium.

l 1

mg/L-PPD Ii4Asm-si X

4. 0.5 4 414.6 CONTINUE ON PAGE V 3 PAGE V-2 EPA Form 3510-2C (8-90)

EP#4 0.0. NUMLER Icopy from item j ef Farm JJ auTFALL NUM AE R Y

STiNUED FROM PAGE 3 OF FORM 2-C 01006346 800 A

%RT C - If yo nts a primary industry and this outf all contains process wastewater, refer to Table 2c-2 it' the in'structions to determine WhiEh of 1

4 a

~.%...

,m 2-a for all such GC/MS fractions tt'at oppfy to your industry and for ALL toxic metals, cyanidtsiand total phenols. lf you are not required topnerk column 2-a (secondary indus wastewater out/at/s. endnonrequired GC/MS A tions), mark "X"in column 2-b for each pulutant you know or have resson to believe is present. Mark "X"in column 2-c for eac believe is absent. lf you mark column 2a for any poffutant,you mustprovide the results of atleast one analysis for that pollutant.lf you mark column 2b for any pollutant,you c,f at least one analysis for that pollutant if you know or hsve reason to believe it will be disctierced in concentrations of 10 ppb or greater. If you mark column 2b fo dinitrophenot, or 2-methyl-4,6 dinitrophenot, you must provide the results of at least one analysia for eacti of these pollutants which you know or have'reasor) to beli concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b.you must either submit at least one analysis or briefly describe the reasons be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7pages/ for each outfall. See instructions for additional deta

4. UNITS $T-.. 25.. INT AKE (opnonst/

3. EFFLUENT %%, Q-hdC./E u.i

'O t.t.U T A N T

z. M a n n x' g

O G ER o

y

a. M AXtMUM'O AIt.Y.V At UE hMdk".,#.d.[goN,%[4,)IY Y,E *b,?."f

['aMa% '.VALUE c

7.'.". J,M' J.*g-

.g 30

(,*,;,

,,g, g),,,

fg. W. N Nld v;'e=

~ l'T"N'N eMe~4MdM,.

'II'I'****

. vsEs ' WN " -

N

M,*,*,7 *,,","*

- tel = a **

vsrs NUM E (tf eveffold:) w co=e 2

WiR

's-

ma r. m

+54 -4

'- r :#4-A k-WoWr:

a TALS, CYANIDE, AND TOTAL PHENOLS s

Xn'ttr'rlony','

1 mg/L PPD et (7440-36-0).

( Q,3 4 a1a x

y 1

fhikT,otal 1

mg/L PPD-

t38;..F X

X

< 0.003 4 2.49 2

e.Nmum.

1 mg/L PPD n 7'* W t X

X

< 0.005 4 4_14 2:.8' iumyn m

[0.005

< 4.14 1

mg/L PPD

'W44t'.3?)

X X

'ChrMGm7 '

F. ** -*' ')

X X

d o_01

< 8.29 1

mg/L PPD s;;%.ie

%b y X

X

<nno 416.6 1

mg/L PPD

%,rsi (0.05

< 41.4 1

mg/L PPD T1 E X

x

@IrEUfy';'Totn't

!,8JMMi. t.

X X

< 0.0002 (0_166 1

mg/L PPD Nie=Wot.ij toff $.!&If X

X

< 0.03 4 24.9 1

mg/L PPD WG'GbWie

$3?!Mh2K X X

< 0.004 43.31 1

mg/L PPD 1

mg/L PPD X

X

<0.01 4 8.29 KnZistr32 Id7Ji98-oM X

X

<n1 4 24g 1

mg/L PPD F8pS.i&B yst.r:

1 mg/L PPD th'-.

X X

4 n n?

4.1 A g C% gen?

'ypy2 Sib X

X 4nn 44.14 1

mg/L PPD if rn4=i,

M; h X

X

< 0.005 4 4.14 1

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X CONTINUE ON REVERSE PAGE V.3 k Firm 3510-2C (8-90)

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$ 10 8.29 CONTINUE ON REVERSE PAGE V-5

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"y NUMBER y
I cswremon C636490 d
ENERGY INDEPENDENCE, OHIO THE PARENT COMPANY OF THE CLEVELAND ELECTRIC 3
ILLUMINATING COMPANY AND THE TOL.EDO EDISON COMPANY AMOUNT
~~ri 0951006000218 DATE OCT 09,1995~~
~~* * * * * * * * * *~~
~~100 DOLLARS 00 100.00 PAY I~~
TREASURER STATE OF OHIO CENTERIOR SERVICE COMPANY TO THE OHIO EPA NE DISTRICT OFFICE F
ORDER OF 2110 E AURORA ROAD TWINSBURG OH 44087-1969 FIRST NATIONAL BANK AN F LfA E OF Treasurer Or Assis@ Treasurer NATIONAL CITY BANK CLEVELAND, OHIO I
F u= S 3 5 t,90 iia i:Ot. L 20 389 5:* 008 2 L L t. iia.
2-2 m
~~__w~~
--+-
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. =- -:
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=-
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CENTERIOR SERVICE COMPANY THE ATTACHED 04CK l$ TEND [ RED N FUM $ETTLEMENT OF trEm$ DETAKED BELOW, W HCOneECT Pt1ASE RfTURN STATNG EXCErflONS YOUR PURCHASE ORDER OUR GROSS YOUR DATE NUMBER REFERENCE AMOUNT DEDUCTIONS REFERENCE 41 Aa #
i s0.00RZUCKER/PEgv RENEW 10/04/95 95-135715 s100.00 100.00 s0.00 s100.00 CHECK ID 0951006000218 ;
i C636490
~~42s(NSI REV 6 92~~
a RFA 3.0. pueber OR0041468 WATER FLOW DIAGRAM
~
TIIE CLEVELAND ELECTRIC ILLUMINATING COMPANY
,t,,,
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t,',',,,',',
rLAnf v4Ttt PERRY NUCLEAR POWER PLANT
"C' "C'
PERRY. OHIO JL Jh h
SootuM 4 s0Drun -->
h 500tvM SutFitt oft 0 Cat 0Rtit
~~ntPOCat0RITt~~
~~EMERCtpCT SERVICE Jg m~~
~~UAftt HEAT ERCRANGERS CREMICAL CLEAN!pC LAC 005 (001)~~
~~7 FIRE PROTECTION 50010M 4 svLr1ft if~~
~
N DEMtptpALtttRS. ETAFORATORS 0.036 MCD
~~PLANT STRAM CTCLE~~
~4 JL FILTERS. DEMIRERAttttRS DantuttAttttR RECENERAft SEUTRALIEATION UAftR TatATMtaf (001) 0.0T MCO JL II SERTICE VAftR Jh
/
N REAT EICRANCESS O
ETAF00ATION M+
M 9.3 MCD
't Jh SAptTART WASTt tagg COUNTT M
LAtt COUNTT POTARLE v4 Ten 0.036 MCD SACON ROAD PLANT R 0 0 m e
C00Ltpc Toutt WATER MAlm 0.08 MCD g
f, ROOF DRAIMS SODtUM IMPOUNDMERT STREAMS.
f.MOCRLORITE
~~STORM DRAINAct - 30.000 m~~
TO LArt ERIE W+
CPM 9A IN/RR RAIN H
U O
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~~FL0utAtt INTERMITTENT ORLT -~~
Set SECTION II.C 0F t A FORM 2C o.
a m
l r8 Electro-Analytical 42E Laboratories 7118 Industrial Park Blvd.
Mentor, OH 44060 Attn: Client Services Department Phone: (216) 951-3514 [ FAX 951-3774]
j Perry Nuclear Power Plant Order #: 95-09-435 10 Center Rd. E. 240 Date: 10/03/95 10:14 Perry, Ohio 44081 Work ID: NPDES Permit Renewal Date Received: 09/27/95 Attn: Donna G. Tizzano Date. Completed: 10/02/95 SAMPLE IDENTIFICATION Sample Sample Sample Sample Number Descriotion Number Descriotion 01 Plant Outfall 02 Service Water 03 Basin "A" All samples were analyzed as received. Samples are retained for 30 days prior to disposal or return. Reproduction of this report is prohibited except in its entirety. Contact Client Services with questions regarding this report.
f Certified 4 y '
Electro-Analytical Laboratories Tony Solitro, Lab Manager 4
i@2 LabOratoriesElectro-Analytical Page 2 Order # 95-09-435 10/03/95 10:14 Work Id: HPDES Permit Ren'ewal REGULAR TEST RESULTS BY TEST Ammonia; Nitrogen: EPA 350.2 Minimum:
0.20 Maximum:
Method: DIST_TITRIM Samnle Samole Description Result Units Extracted Analyzed h s 01D Plant Outfall 0.90 mg/ liter as 'N 09/27/95 KAM A 2D Service Water 0.34 mg/ liter as 'N 09/28/95 09/28/95 CO
.e 030 Basin "A" 2.4 mg/ liter as 'N 09/27/95 KAM Bioche 02 Demand-EPA 405.1 Minimum:
~~3.0 Maximum~~
Method: SDAY_20_DEGC Samole Samnle Descriotion Result Units Extracted Analyzed h v 01A Plant Outfall
<3.0 mg/ liter 09/27/95 10/02/95 C0
/ 02A Service Water
<3.0 mg/ liter 09/27/95 10/02/95 C0
/ 03A Basin "A"
<3.0 mg/ liter 09/27/95 10/02/95 C0 Chen Oxy. Demand: EPA 410.4 Minimum:
20 Maximum:
Method: Colorimetric Samole Samole Descriotion Result Units Extracted Analyzed h
/ 01B Plant Outfall
<20 mg/ liter 09/27/95 KAM
/02B Service Water
<20 mg/ liter 09/27/95 KAM 03B Basin "A" 35 mg/ liter 09/27/95 KAM Non-Filt.Res(TSS): EPA 160.2 Minimum:
~~1.0 Maximum~~
Method: GRAV_ DRYING Samole Samole Descriotion Result Units Extracted Analyzed h
/ 01C Plant Outfall 2.5 mg/ liter 09/28/95 09/29/95 C0 02C Service Water 1.6 mg/ liter 09/28/95 09/29/95 CO y 03C Basin "A" 16 mg/ liter 09/28/95 09/29/95 C0
Qhsanterra t,,,w services Quanterra Incorgerated 4101 ShugelDnve, NW Nonh Canton, Ohio 44720 l
216 497 9396 Telephone L1 216 497-0772 Fax i
ANALYTICAL REPORT r3 h1 u
~~
P
~~
aa l
~
\\
Donna Tizzano ILLUMINATING COMPANY
)
r1 L
QUANTERRA INCORPORATED l
r-
~
Duane Nielsen Project Manager
!)0 August 21, 1995 m
Q%anterra SAMPLE
~~SUMMARY~~
cow-ra Serriws The analytical results of the samples listed below are presented
'd on the following pages.
WO #
LABORATORY ID SAMPLE IDENTIFICATION DATE/ TIME SAMPLED COE22 A5G270132-001 OUTFALL 7/27/95 COE24 A5G270132-002 SW FOREBAY 7/27/95 COE25 A5G270132-003 NEUTRALIZATION BASIN 7/27/95 u
1-6.4 e
?
e.
V' L.
[..
i.
tl t
L
Qbhsanterra Environinental ILLUMINATING COMPANY Services OUTFALL WO # COE2210R DATE SAMPLED:
7/27/95 l
LAB #: A5G270132-001 TIME SAMPLED:
iI MATRII: WATER DATI RECEIVED:
7/27/95 DILUTION FACTOR:
1.00 I?
- - - - - - - - - - - - - - - - - - GC/MS volatiles - - - - - - - - - - - - - - - - - - -
j 1 0F 2
RESULT REPORTING EXTRACTION-QC PARAMETER (uct/L)
LIMIT METHOD ANALYSIS DATE BATCH L
Acrolein ND 100 CFR136A 624 08/08/95 5222044 Acrylonitrile ND 100 CFR136A 624 08/08/95 5222044
['
Benzene ND 5.0 CFR136A 624 08/08/95 5222044
{.
Bromoform ND 5.0 CFR136A 624 08/08/95 5222044 Bromomethane ND 10 CFR136A 624 08/08/95 5222044 1
.].
Carbon tetrachloride ND 5.0 CFR136A 624 08/08/95 5222044 J
Chlorobenzene ND 5.0 CFR136A 624 08/08/95 5222044 7
Chlorodibromomethane ND 5.0 CFR136A 624 08/08/95 5222044 Chloroethane ND 10 CFR136A 624 08/08/95 5222044 Chloroform 4.3 J 5.0 CFR136A 624 08/08/95 5222044 I.
Chloromethane ND 10 CFR136A 624 08/08/95 5222044 k
Dichlorobromomethane 2.1 J 5.0 CFR136A 624 08/08/95 5222044
[*
1,1-Dichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 ;
[
1,2-Dichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 l 1,1-Dichloroethene ND 5.0 CFR136A 624 08/08/95 5222044 h
1,2-Dichloroethene (total)
ND 5.0 CFR136A 624 08/08/95 5222044 1,2-Dichloropropane ND 5.0 CFR136A 624 08/08/95 5222044 cis-1,3-Dichloropropene ND 5.0 CFR136A 624 08/08/95 5222044
.('
trans-1,3-Dichloropropene ND 5.0 CFR136A 624 08/08/95 5222044 Ethylbenzene 10 5.0 CFR136A 624 08/08/95 5222044 Methylene chloride ND 10 CFR136A 624 08/08/95 5222044
[-
1,1,2,2-Tetrachloroethane ND 5.0 CFR136A 624 08/08/95 522204 Tetrachloroethene ND 5.0 CFR136A 624 08/08/95 522204 I?
{
SURROGATE RECOVERY l
ACCEPTABLE LIMITS 1,2-Dichloroethane-d4 106
( 76 - 114) l Toluene-d8 98
( 88 - 110) 5-Bromofluorobenzene 98
( 86 - 115) 7 NOTE: AS RECEIVED ND NOT DET1.CTED AT TIIE STATED REPORTING LIMIT J ESTIMATED VALUE. (DETECTED). BUT BELOW QU ANTITATION LIMIT.
t.-
E Ensinmmental ILLUKINATING COMPANY OUTFALL 1
WO # COE2210R DATE SAMPLED:
7/27/95 I
LAB #: A5G270132-001 TIME SAMPLED:
MATRIX: WATER DATE RECEIVED:
7/27/95 DILUTION FACTOR:
1.00 1
- GC/MS Volatiles - - - - - - - - - - - - - - - - - - - !
2 OF 2
RESULT REPORTING EXTRACTION-QC PARAMETER (ue/L)
LIMIT METHOD ANALYSIS DATE BATCH l
l Toluene ND 5.0 CFR136A 624 08/08/95 5222044 ;
1,1,1-Trichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 {
?"
~~1,1,2-Trichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 !~~
1 1
L~
Trichloroethene ND 5.0 CFR136A 624 08/08/95 5222044 Vinyl chloride ND 10 CFR136A 624 08/08/95 5222044 W
7 e=
t 7
h; r
f1 1-L.
SURROGATE RECOVEig 3.
ACCEPTABLE LIMITS
.~~
1,2-Dichloroethane-d4 106
( 76 - 114) 4 Toluene-d8 98
( 88 - 110) l Bromofluorobenzene 98
( 86 - 115) i.
i~
J NOTE: AS RECEIVED e
ND NOT DETECTED AT THE STATED REPORTING UMIT s
has I
Q%anterra Environmental Semices ILLUMINATING COMPANY OUTFALL WO #: COE2210T DATE SAMPLED:
7/27/95 LAB #: A5G270132-001 DATE RECEIVED:
7/27/95 1
MATRIX: WATER l
[
DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
1 OF 3
RESULT REPORTING EXTRACTION-QC I
PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH Acenaphthene ND 10 CFR136A 625 07/28-08/03/95 520905:
Acenaphthylene ND 10 CFR136A 625 07/28-08/03/95 520905; Anthracene ND 10 CFR136A 625 07/28-08/03/95 520905:
j Benzidine ND 100 CFR136A 625 07/28-08/03/95 520905:
Benzo (a) anthracene ND 10 CFR136A 625 07/28-08/03/95 520905:
Benzo (a) pyrene ND 10 CFR136A 625 07/28-08/03/95 520905:
}
Benzo (b) fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905:
1 Benzo (ghi) perylene ND 10 CFR136A 625 07/28-08/03/95 520905:
Benzo (k) fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905:
4-Bromophenyl phenyl ether ND 10 CFR136A 625 07/28-08/03/95 520905:
Butyl benzyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905:
I'"
bis (2-Chloroethoxy) methane ND 10 CFR136A 625 07/28-08/03/95 520905:
5 bis (2-Chloroethyl) ether ND 10 CFR136A 625 07/28-08/03/95 520905:
bis (2-Chloroisopropyl) ether ND 10 CFR136A 625 07/28-08/03/95 520905:
l p-Chloro-m-cresol ND 10 CFR136A 625 07/28-08/03/95 520905:
2-Chloronaphthalene ND 10 CFR136A 625 07/28-08/03/95 520905:
2-Chlorophenol ND 10 CFR136A 625 07/28-08/03/95 520905.
{
4-Chlorophenyl phenyl ether ND 10 CFR136A 625 07/28-08/03/95 520905.
Chrysene ND 10 CFR136A 625 07/28-08/03/95 520905.
f, Dibenz(a,h). anthracene ND 10 CFR136A 625 07/28-08/03/95 520905.
L-Di-n-butyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905.
l 1,2-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905 1,3-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905:
SURROGATE RECOVERY i
ACCEPTABLE LIMITS i
2-Fluorophenol 62
( 17 - 106)
Phenol-d5 61
( 15 - 126)
]
2,4,6-Tribromophenol 58
( 13 - 145)
Nitrobenzene-d5 69
( 36 - 148) 2-Fluorobiphenyl 65
( 38 - 106)
Terphenyl-d14 47
( 10 - 169)
NOTE:
AS RECEIVED ND NOT DETECTED AT THE STATED REPORTING UMIT
?j
M Eummament:1 Servxes ILLUMINATING COMPANY 7
OUTFALL WO #: COE2210T DATE SAMPLED:
7/27/95 LAB #: A5G270132-001 DATE RECEIVED:
7/27/95 MATRIX: WATER I
DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
2 OF 3
r I
RESULT REPORTING EXTRACTION-QC PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH 1,4-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 5209051 3,3'-Dichlorobenzidine ND 10 CFR136A 625 07/28-08/03/95 5209051
'2,4-Dichlorophenol ND-10 CFR136A 625 07/28-08/03/95 5209051 Diethyl phthalate,
ND 10 CFR136A 625 07/28-08/03/95 5209051
>d 2,4-Dimethylphenol ND 10 CFR136A 625 07/28-08/03/95 5209051 Dimethyl phthalate ND 10 CFR136A 625 07/28-08/03/95 5209051 I
4,6-Dinitro-o-cresol ND 50 CFR136A 625 07/28-08/03/95 5209052 2,4-Dinitrophenol ND 50 CFR136A 625 07/28-08/03/95 5209052 n
2,4-Dinitrotoluene ND 10 CFR136A 625 07/28-08/03/95 5209052 1
I 2,6-Dinitrotoluene ND 10 CFR136A 625 07/28-08/03/95 5209052 7
Di-n-octyl phthalate ND 10 CFR136A 625 07/28-08/03/95 5209052 F
1,2-Diphenylhydrazine ND 10 CFR136A 625 07/28-08/03/95 5209052 b4 bis (2-Ethylhexyl) phthalate ND 10 CFR136A 625 07/28-08/03/95 5209052 Fluoranthene ND 10 CFR136A 625 07/28-08/03/95 5209052 r-Fluorene ND 10 CFR136A 625 07/28-08/03/95 5209052 Hexachlorobenzene ND 10 CFR136A 625 07/28-08/03/95 5209053 i-Hexachlorobutadiene ND 10 CFR136A 625 07/28-08/03/95 5209053
[;
Hexachlorocyclopentadiene ND 10 CFR136A 625 07/28-08/03/95 5209053 Hexachloroethane ND 10 CFR136A 625 07/28-08/03/95 5209053 p
r-Indeno(1,2,-3-cd) pyrene ND 10 CFR136A 625 07/28-08/03/95 5209053 b
Isophorone ND 10 CFR136A 625 07/28-08/03/95 520905]
l l1 Naphthalene ND 10 CFR136A 625 07/28-08/03/95 5209053 3
Nitrobenzene ND 10 CFR136A 625 07/28-08/03/95 5209053
]
SURROGATE RECOVERY l
ACCEPTABLE LIMITS 9.,
5-2-Fluorophenol 62
( 17 - 106)
Phenol-d5 61
( 15 - 126) 1 0
2,4,6-Tribromophenol 58
( 13 - 145)
)
O Nitrobenzene-d5 69
( 36 - 148) 2-Fluorobiphenyl 65
( 38 - 106)
Terphenyl-d14 47
( 10 - 169)
NOTE:
AS RECEIVED ND NOT DETECTED AT THE STATED REPORTING LIMIT U
t*
b.
Q%anterra Environment)
Servkrs ILLUMINATING COMPANY OUTFALL c
WO #: COE2210T DATE SAMPLED:.
7/27/95 LAB #2 A5G270132-001 DATE RECEIVED:
7/27/95 j
MATRII: WATER DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - -
)
3 OF 3
RESULT REPORTING EXTRACTION-QC i
PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH l
2-Nitrophenol ND 10 CFR136A 625 07/28-08/03/95 5209051 i
j 4-Nitrophenol ND 50 CFR136A 625 07/28-08/03/95 5209051 I N-Nitrosodimethylamine ND 10 CFR136A 625 07/28-08/03/95 5209051 I
N-Nitrosodiphenylamine ND 10 CFR136A 625 07/28-08/03/95 5209051 i
,J N-Nitrosodi-n-propylamine ND 10 CFR136A 625 07/28-08/03/95 5209051 l Pentachlorophenol ND 50 CFR136A 625 07/28-08/03/95 S209051 I Phenanthrene ND 10 CFR136A 625 07/28-08/03/95 5209051 Phenol ND 10 CFR136A 625 07/28-08/03/95 5209051' Pyrene ND 10 CFR136A 625 07/28-08/03/95 5209051 I
i 1,2,4-Trichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 5209051 l 2,4,6-Trichlorophenol ND 10 CFR136A 625 07/28-08/03/95 5209051 )
f I.
I n
I I'
L..
SURROGATE RECOVERY l
ACCEPTABLE LIMITS 1
I 2-Fluorophenol 62
( 17 - 106)
Phenol-d5 61
( 15 - 126)
}
2,4,6-Tribromophenol 58
( 13 - 145)
{,
Nitrobenzene-d5 69
( 36 - 148) 2-Fluorobiphenyl 65
( 38 - 106)
Terphenyl-d14 47
( 10 - 169)
NOTE:
AS RECEWED ND NOT DETECTED AT THE STATED REPORTING UMIT Wu-
ME Envimamental Services ILLUMINATING COMPANY OUTFALL 3
WO #: COE22 DATE SAMPLED:
7/27/95 LAB # A5G270132-001 DATE RECEIVED:
7/27/95 I
MATRIZ: WATER 3
. REQUESTED METALS - - ----------------
REPORTING PREPARATION -
QC L--
PARAMETER RESULT LIMIT UNIT METHOD ANALYSIS DATE BATCH r'
Aluminum ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 5214008 i
Barium ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 5214008 Boron ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 5214008 l
Cobalt ND 0.050 mg/L MCAWW 200.7 8/02-8/03/95 5214008 J
Iron 0.12 0.10 mg/L MCAWK 200.7 8/02-8/03/95 5214008 Magnesium 10.9 5.0 mg/L MCAWK 200.7 8/02-8/03/95 5214000 f
Manganese ND 0.015 mg/L MCAWW 200.7 8/02-8/03/95 521400E Molybdenum ND 0.10 mg/L MCAWW 200.7 8/02-8/03/95 5214000 Tin ND 1.0 mg/L MCAWW 200.7 8/02-8/09/95 5214006 i
Titanium ND 0.010 mg/L MCAWW 200.7 8/02-8/03/95 521400E F
I E..
i' l.
t i
k..
L.
i..-
i t.
1
}
NOTli AS Rirt2VE2) g, ND NOT DET. irT12) AT TIIE STAT 12) RETORTLNG ID11T i.
5 m.
khanterra Envirutnental Services ILLUMINATING COMPANY OUTFALL DATE SAMPLED:
7/27/95 J
WO #: COE22 DATE RECEIVED:
7/27/95 LAB #: A5G270132-001 MATRIX: WATER
- - - INORGANIC ANALYTICAL REPORT -
i REPORTING PREPARATION -
QC RESULT LIMIT M
METHOD ANALYSIS DATE BATCH
{
PARAMETER L
Color (Colorimetric, 10 5
C.U.
MCAW 110.2 7/27/95 5209024
(
Platinum-Cobalt)
{
Broanida (Titrimetric) 31 20 mg/L MCAW 320.1 8/10/95 5222080 Total residual chlorine ND 0.2 mg/L MCAWW 330.5 7/27/95 5209023 (Spectrophotometric, DPD)
LJ Fluoride (Colorimetric, 0.1 0.1 mg/L MCAW 340.2 8/07/95 5219030 Ion Selective Electrode)
Nitrate-Nitrite 0.7 0.1 mg/L MCA W 353.2 8/03-8/04/95 5216012 Total phosphorus 1.8 0.1 mg/L MCAW 365.2 8/01-8/02/95 5213094 (Colorimetric) l Sulfide 1.5 0.50 mg/L MCAW 376.1 8/02/95 521410*J f
Sulfite ND 2
mg/L MCAWW 377.1 7/27/95 521603E Surfactants (MBAS)
ND 0.1 mg/L MCAWW 425.1 7/27/95 5209025 r
i Oil and Grease, ND 5.0 mg/L MCAWW 413.1 8/09-8/10/95 522104; i
Gravimetric Coliforms, Fecal ND 10.0
/100mL SM18 9222D 7/27-7/28/95 520902(
I' Total Organic Nitrogen 2
1 mg/L MCAW 351.3/3 8/11/95 5223081 1
Sulfate 27 5
mg/L MCAWN 375.4 8/11/95 522308( i j
8 L
p NOTES AS RECEIVED ND NOT DETECTED AT THE STATED REPORTING LIh0T ru ie a
6 l
(
e om L
MhSU Environmental ILLUMINATING COMPANY Servies SW FOREBAY q
WO #: COE2410R DATE SAMPLED:
7/27/95
,i LAB #: A5G270132-002 TIME SAMPLED:
i MATRIX: WATER DATE RECEIVED:
7/27/95 E3 DILUTION FACTOR:
1.00
- - - - - GC/MS Volatiles - - - - - - - - - - - - - - - - - - -
1 OF 2
RESULT REPORTING EXTRACTION-QC PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH
+-
Acrolein ND 100 CFR136A 624 08/08/95 5222044 Acrylonitrilo ND 100 CFR136A 624 08/08/95 5222044 Benzene ND 5.0 CFR136A 624 08/08/95 5222044 Bromoform ND 5.0 CFR136A 624 08/08/95 5222044 Bromomethane ND 10 CFR136A 624 08/08/95 5222044 Carbon tetrachloride ND 5.0 CFR136A 624 08/08/95 5222044 Chlorobenzene ND 5.0 CFR136A 624 08/08/95 522.2044 Chlorodibromomethane ND 5.0 CFR136A 624 08/08/95 5222044 b
Chloroethane ND 10 CFR136A 624 08/08/95 5222044 !
Chloroform ND 5.0 CFR136A 624 08/08/95 5222044 Chloromethane ND 10 CFR136A 624 08/08/95 5222044 i
Dichlorobromomethane ND 5.0 CFR136A 624 08/08/95 5222044 F
1,1-Dichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 i,
1,2-Dichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 1,1-Dichloroethene ND 5.0 CFR136A 624 08/08/95 5222044 1,2-Dichloroethene (total)
ND 5.0 CFR136A 624 08/08/95 5222044 l 1,2-Dichloropropane ND 5.0 CFR136A 624 08/08/95 5222044 cis-1,3-Dichloropropene ND 5.0 CFR136A 624 08/08/95 5222044 j i
[;
trans-1,3-Dichloropropene ND 5.0 CFR136A 624 08/08/95 5222044 Ethylbenzene ND 5.0 CFR136A 624 08/08/95 5222044 i Methylene chloride ND 10 CFR136A 624 08/08/95 5222044 f,t 1,1,2,2-Tetrachloroethane ND 5.0 CFR136A 624 08/08/95 5222044
~~d Tetrachloroethene ND 5.0 CFR136A 624 08/08/95 5222044 U~~
SURROGATE RECOVERY ACCEPTABLE LIMITS 1,2-Dichloroethane-d4 105
( 76 - 114)
Toluene-d8 98
( 88 - 110) k-Bromofluorobenzene 97
( 86 - 115) f*
I NOTE: AS RECEIVED ND NOT DETECTED AT THE STATED REPORTING UMIT 2 e
Qhanterra Eonronmental Sernas ILLUMINATING COMPANY SW FOREBAY WO #: COE2410R DATE SAMPLED:
7/27/95 e,
ldl LAB #: A5G270132-002 TIME SAMPLED:
MATRIX: WATER DATE RECEIVED:
7/27/95 DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - - GC/MS Volatiles - - - - - - - - - - s 2 OF 2
RESULT REPORTING EXTRACTION-QC p-PARAMETER (uo/L)
LIMIT METHOD ANALYSIS DATE ]!ATQI Toluene ND 5.0 CFR136A 624 08/08/95 5222044 1,1,1-Trichloroethane ND 5.0 CFR136A 624 08/08/95 5222044
[
1,1,2-Trichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 i
Trichloroethene ND 5.0 CFR136A 624 08/08/95 5222044 Vinyl chloride ND 10 CFR136A 624 08/08/95 5222044
!J I
l:
I' i.
I I
i
!~
SURROGATE RECOVERY 1
ACCEPTABLE LIMITS 1,2-Dichloroethane-d4 105
( 76 - 114)
Toluene-dB 98
( 88 - 110)
Bromofluorobenzene 97
( 86 - 115) 4 2
]
NOTE: AS RECEIVED ND NOT DETECTED AT THE STATED REPOR11NG LIMIT 9'
tb
M&M Enuzwau M Serrkes ILLUMINATING COMPANY SW FOREBAY WO #: COE2410T DATE SAMPLED:
7/27/95 LAB #s A5G270132-002 DATE RECEIVED:
7/27/95 MATRIX: WATER f^
DILUTION FACTOR:
1.00 l
- - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
1 OF 3
c-i RESULT REPORTING EXTRACTION-QC PARAMETER (ucr/L)
LIMIT METHOD ANALYSIS DATE BATCH
[
Acenaphthene ND 10 CFR136A 625 07/28-08/03/95 520905:
Acenaphthylene ND 10 CFR136A 625 07/28-08/03/95 520905:
Anthracene ND 10 CFR136A 625 07/28-08/03/95 520905: i s
I Benzidine ND 100 CFR136A 625 07/28-08/03/95 520905:
L Benzo (a) anthracene' ND 10 CFR136A 625 07/28-08/03/95 5209053 Benzo (a) pyrene ND 10 CFR136A 625 07/28-08/03/95 520905 p,
b Benzo (b)fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905:
Benzo (ghi) perylene ND 10 CFR136A 625 07/28-08/03/95 520905:
l Benzo (k)fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905:
r.
I 4-Bromophenyl phenyl ether ND 10 CFR136A 625 07/28-08/03/95 5209053 Butyl benzyl phthalate ND 10 CFR136A 625 07/28-08/03/95 5209052 4
bis (2-Chloroethoxy) methane ND 10 CFR136A 625 07/28-08/03/95 5209053 bis (2-Chloroethyl) ether ND 10 CFR136A 625 07/28-08/03/95 520905]
bis (2-Chloroisopropyl) ether ND 10 CFR136A 625 07/28-08/03/95 5209053 r,
I p-Chloro-m-cresol ND 10 CFR136A 625 07/28-08/03/95 5209053 i.
2-Chloronaphthalene ND 10 CFR136A 625 07/28-08/03/95 520905:
[.
2-Chlorophenol ND 10 CFR136A 625 07/28-08/03/95 520905:
[,
4-Chlorophenyl phenyl ether ND 10 CFR136A 625 07/28-08/03/95 520905; 1
Chrysene ND 10 CFR136A 625 07/28-08/03/95 5209052 Dibenz(a,h) anthracene ND 10 CFR136A 625 07/28-08/03/95 520905:
G Di-n-butyl phthalate ND 10 CFR136A G25 07/28-08/03/95 520905:
f*
1,2-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 5209053
[
1,3-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905:
SURROGATE RECOVERY 3.
ACCEPTABLE LIMITS 2-Fluorophenol 54
( 17 - 106)
Phenol-d5 58
( 15 - 126) 2,4,6-Tribromophenol 58
( 13 - 145) 1]
Nitrobenzene-d5 68
( 36 - 148) 2-Fluorobiphenyl 61
( 38 - 106)
Terphenyl-d14 36
( 10 - 169) l I
1 NOTE:
AS RECOVED ND NOT DETECTED AT Tile STATED REPORTING UMIT
{
Qhassierra Envirramentd Services ILLUMINATING COMPANY SW FOREBAY 3
I NO #: COE2410T DATE SAMPLED:
7/27/95 LAB #: A5G270132-002 DATE RECEIVED:
7/27/95 MATRIKs WATER DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/Ms semi-volatiles - - - - - - - - - - - - - - - - -
2 OF 3
i RESULT REPORTING EXTRACTION-QC PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH l
I' 1,4-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905; 3,3'-Dichlorobenzidine ND 10 CFR136A 625 07/28-08/03/95 520905:
2,4-Dichlorophenol ND 10 CFR136A 625 07/28-08/03/95 520905:
Diethyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905:
2,4-Dimethylphenol' ND 10 CFR136A 625 07/28-08/03/95 520905:
Dimethyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905:
f
4,6-Dinitro-o-cresol ND 50 CFR136A 625 07/28-08/03/95 520905:
2,4-Dinitrophenol ND 50 CFR136A 625 07/28-08/03/95 520905:
2,4-Dinitrotoluene ND 10 CFR136A 625 07/28-08/03/95 520905:
I 2,6-Dinitrotoluene ND 10 CFR136A 625 07/28-08/03/95 520905:
Di-n-octyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905: ;
f"~
1,2-Diphenylhydrazine ND 10 CFR136A 625 07/28-08/03/95 520905:
~
bis (2-Ethylhexyl) phthalate ND 10 CFR136A 625 07/28-08/03/95 520905:
Fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905:
Fluorene ND 10 CFR136A 625 07/28-08/03/95 520900 Hexachlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905 l
Hexachlorobutadiene ND 10 CFR136A 625 07/28-08/03/95 520905 j
Hexachlorocyclopentadiene ND 10 CFR136A 625 07/28-08/03/95 520905 Hexachloroethane ND 10 CFR136A 625 07/28-08/03/95 520905 f,
Indeno (1,2,.3-cd) pyrene ND 10 CFR136A 625 07/28-08/03/95 520905 L
Isophorone ND 10 CFR136A 625 07/28-08/03/95 520905 r
Naphthalene ND 10 CFR136A 625 07/28-08/03/95 520905 Nitrobenzene ND 10 CFR136A 625 07/28-08/03/95 520905 SURROGATE RECOVERY 1
ACCEPTABLE LIMITS j
i 2-Fluorophenol 54
( 17 - 106)
Phenol-d5 58
( 15 - 126)
J 2,4,6-Tribromophenol 58
( 13 - 145) 1 i ;
Nitrobenzene-d5 68
( 36 - 14B) 2-Fluorobiphenyl 61
( 38 - 106)
Terphenyl-d14 36
( 10 - 169)
NOTL AS RIIEIVFD ND NOT DETTICTED AT THE STATED REPORTING LIMIT mis
E Ermronmental Services ILLUMINATING COMPANY SW FOREBAY DATE SAMPLED:
7/27/95 WO #: COE2410T DATE RECEIVED -
7/27/95
~~I LAB #: A5G270132-002 MATRIX: WATER I'~~
DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
3 OF 3
RESULT REPORTING EXTRACTION-QC (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH j
ii PARAMETER ND 10 CFR136A 625 07/28-08/03/95 5209053.
ND 50 CFR136A 625 07/28-08/03/95 5209053 f I
2-Nitrophenol j
4-Nitrophenol CFR136A 625 07/28-08/03/95 5209053 '
N-Nitrosodimethylamine ND 10 l
}
N-Nitrosodiphenylamine ND 10 CFR136A 625 07/28-08/03/95 5209052 3
N-Nitrosodi-n-propylamine ND 10 CFR136A 625 07/28-08/03/95 5209053 Pentachlorophenol ND 50 CFR136A 625 07/28-08/03/95 5209053 ND 10 CFR136A 625 07/28-08/03/95 520905:
Phenanthrene ND 10 CFR136A 625 07/28-08/03/95 520905:
~
Phenol ND 10 CFR136A 625 07/28-08/03/95 520905:
Pyrene ND 10 CPR136A 625 07/28-08/03/95 520905 I
1,2,4-Trichlorobenzene CFR136A 625 07/28-08/03/95 520905 i
2,4,6-Trichlorophenol ND 10 k
i
?
!6.
I, '
i.
I j:
s SURROGATE RECOVERY l
ACCEPTABLE LIMITS 54
( 17 - 106) i 2-Fluorophenol 58
( 15 - 126)
Phenol-d5 2,4,6-Tribromophenol 58
( 13 - 145) j l-148) j l
Nitrobenzene-d5 68
( 36 2-Fluorobiphenyl 61
( 38 - 106) 36
( 10 - 169)
Terphenyl-d14 NOTE:
AS RECEIVED ND NOT DETECTED AT THE STATED REPORTING UMIT k
.f.
$50 EwimnmentJ Services ILLUMINATING COMPANY SW FOREBAY d
WO #: COE24 DATE SAMPLED:
7/27/95 LAB # A5G270132-002 DATE RECEIVED:
7/27/95 MATRII: WATER REQUESTED METALS -
f' REPORTING PREPARATION -
QC i
PARAMETER RESULT LIMIT UNIT METHOD ANALYSIS DATE BATCH Aluminum ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 5214008 f
Barium ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 5214008 Boron ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 5214006 l
Cobalt ND 0.050 mg/L MCAWW 200.7 8/02-8/03/95 5214008 J
Iron 0.22 0.10 mg/L MCAWK 200.7 8/02-8/03/95 5214000 Magnesium 7.9 5.0 mg/L MCAWK 200.7 8/02-8/03/95 5214006
,i Manganese ND 0.015 mg/L MCAWW 200.7 8/02-8/03/95 5214006 Molybdenum ND 0.10 mg/L MCAWW 200.7 8/02-8/03/95 521400E Tin ND 1.0 mg/L MCAWW 200.7 8/02-8/09/95 521400E Titanium ND 0.010 mg/L MCAWW 200.7 8/02-8/03/95 521400E l
1 Fn i
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ND NOT D1TIIT12) AT TIIE STAT 12) RIM)RTING ID1IT i-F ew
Quanterra Enviwamental Servias ILLUMINATING COMPANY SW FOREBAY 1
L-WO #: COE24 DATE SAMPLED:
7/27/95 LAB #: A5G270132-002 DATE RECEIVED:
7/27/95 MATRIZ: WATER
- - - - - - - - - - - - - - - - INORGANIC ANALYTICAL REPORT -
l REPORTING PREPARATION -
QC PARAMETER RESULT LIMIT UNIT METHOD ANALYSIS DATE BATCH i.
1 Color (Colorimetric, 10 5
C.U.
MCAWW 110.2 7/27/95 5209024 Platinum-Cobalt)
Bromide (Titrimetric) 40 20 mg/L MCAWW 320.1 8/10/95 5222080 j Total residual chlorine ND 0.2 mg/L MCAWW 330.5 7/27/95 5209023 (Spectrophotometric, DPD)
Pluoride (Colorimetric, 0.1 0.1 ag/L MCAWW 340.2 8/07/95 5219030 Ion Selective Electrode)
Nitrate-Nitrit,e 0.5 0.1 mg/L MCANW 353.2 8/03-8/04/95 5216012 r'
Total phosphorus 0.4 0.1 mg/L MCAWW 365.2 8/01-8/02/95 5213094 (Colorimetric)
I Sulfide ND 0.50 mg/L MCAWW 376.1 8/02/95 5214107 Sulfite ND 2
mg/L MCAWW 377.1 7/27/95 5216038 Surfactants (MBAS)
ND 0.1 mg/L MCAWW 425.1 7/27/95 5209029 1 t"*
Oil and Grease, ND 5.0 mg/L MCAWW 413.1 8/09-8/10/95 5221047 !
Gravimetric j
Coliforms, Fecal ND 10.0
/100mL SM18 9222D 7/27-7/28/95 5209026 Total Organic Nitrogen ND 1
mg/L MCAWW 351.3/3 8/11/95 5223088
]
Sulfate 18 5
mg/L MCAWW 375.4 8/11/95 522308C I
fl I
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NOlb AS RECDVED ND NOT DETECTED AT1HE STATED REPOR11NG UhCT
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WU Environmental ILLUMINATING COMPANY Services 4
NEUTRALIZATION BASIN DATE SAMPLED:
7/27/95 NO #: COE2510R r]
TIME SAMPLED:
fI LAB #: A5G270132-003 DATE RECEIVED:
7/27/95 MATRIX: WATER DILUTION FACTOR:
1.00 I~
- - - - - - - - GC/MS Volatiles - - -
~- -
1 0F 2
RESULT REPORTING EXTRACTION-QC (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH PARAMETER t
Acrolein ND 100 CFR136A 624 08/08/95 5222044 ND 100 CFR136A 624 08/08/95 5222044 Acrylonitrile ND 5.0 CFR136A 624 08/08/95 5222044 f
Benzene Bromoform ND 5.0 CFR136A 624 08/08/95 5222044 i
Bromomethane ND 10 CFR136A 624 08/08/95 5222044 ;
l Carbon te'trachloride ND 5.0 CFR136A 624 08/08/95 5222044 a
Chlorobenzene ND 5.0 CFR136A 624 08/08/95 5222044 Chlorodibromomethane ND 5.0 CFR136A 624 08/08/95 5222044
~~j Chloroethane ND 10 CFR136A 624 08/08/95 5222044 '~~
Chloroform ND 5.0 CFR136A 624 08/08/95 5222044
[
Chloromethane ND 10 CFR136A 624 08/08/95 5222044 8
Dichlorobromomethane ND 5.0 CFR136A 624 08/08/95 5222044 I
1,1-Dichloroethane ND 5.0 CFR136A 624 08/08/95 5222044
{,
1,2-Dichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 i 1,1-Dichloroethene ND 5.0 CFR136A 624 08/08/95 5222044 f
1,2-Dichloroethene (total)
ND 5.0 CFR136A 624 08/08/95 5222044 I-1,2-Dichloropropane ND 5.O CFR136A 624 08/08/95 522204e cis-1,3-Dichloropropene ND 5.0 CFR136A 624 08/08/95 5222044
!{j trans-1,3-Dichloropropene ND 5.0 CFR136A 624 08/08/95 522204 Ethylbenzene ND 5.0 CFR136A 624 08/08/95 522204-Methylene chloride ND 10 CFR136A 624 08/08/95 522204 L
1,1,2,2-Tetrachloroethane ND 5.0 CFR136A 624 08/08/95 522204 Tetrachloroethene ND 5.0 CFR136A 624 08/08/95 522204 f'
j SURROGATE RECOVERY i
ACCEPTABLE LIMITS 1,2-Dichloroethane-d4 106
( 76 - 114)
Toluene-d8 98
( 88 - 110) l Bromofluorobenzene 98
( 86 - 115)
I![j NCTTE: AS RECEIVED ND NOT DETECTED AT Tile STATT.D REPOR11NG UMIT
?
1
E E,w - ua w :al ILLUMINATING COMPANY Services l
NEUTRALIZATION BASIN DATE SAMPLED:
7/27/95
<m WO #2 COE2510R TIME SAMPLED:
f LAB #: A5G270132-003 DATE RECEIVED:
7/27/95 i
MATRIX: WATER DILUTION FACTOR:
1.00
- - - - - GC/MS Volatiles -
{f 2 OF 2
RESULT REPORTING EXTRACTION-QC PARAMETER (ua /L)
LIMIT METHOD LWALYSIS DATE BATCH m-I Toluene ND 5.0 CFR136A 624 08/08/95 5222044 1,1,1-Trichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 I~
1,1,2-Trichloroethane ND 5.0 CFR136A 624 08/08/95 5222044 i
[
Trichloroethene ND 5.0 CFR136A 624 08/08/95 5222044 Vinyl chloride ND 10 CFR136A 624 08/08/95 5222044 ia u,,
I' 1
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f I
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SURROGATE RECOVERY 1
ACCEPTABLE LIMITS L
1,2-Dichloroethane-d4 106
( 76 - 114)
Toluene-d8 98
( 88 - 110) y.
I Bromofluorobenzene 98
( 86 - 115)
E.
Il j
NOTE: AS RECEIVED ND NOT DETECTED AT THE STATED REPORTING LIMIT 5
L-i F
Quanterra Envirvament:I Services ILLUMINATING COMPANY
)
NEUTRALIZATION BASIN
. }m!
WO #r COE2510T DATE SAMPLED:
7/27/95 DATE RECEIVED:
7/27/95 b
LAB #: A5G270132-003 MATRIX: WATER I
DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
1 0F 3
7 RESULT REPORTING EXTRACTION-QC 1
l PARAMETER (ucr/L)
LIMIT METHOD ANALYSIS DATE BATCH f
Acenaphthene ND 10 CFR136A 625 07/28-08/03/95 520905;
}
Acenaphthylene ND 10 CFR136A 625 07/28-08/03/95 520905:
Anthracene ND 10 CFR136A 625 07/28-08/03/95 520905:
Benzidine ND 100 CFR136A 625 07/28-08/03/95 520905.
J Benzo (a) anthracene' ND 10 CFR136A 625 07/28-08/03/95 520905; Benzo (a) pyrene ND 10 CFR136A 625 07/28-08/03/95 520905' Benzo (b)fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905 ;
Benzo (ghi) perylene ND 10 CFR136A 625 07/28-08/03/95 520905 Benzo (k) fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905 '
4-Bromophenyl phenyl ether ND 10 CFR136A 625 07/28-08/03/95 520905 Butyl benzyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905 I
bis (2-Chloroethoxy) methane FD 10 CFR136A 625 07/28-08/03/95 520905 be bis (2-Chloroethyl) ether ND 10 CFR136A 625 07/28-08/03/95 520905 bis (2-Chloroisopropyl) ether ND 10 CFR136A 625 07/28-08/03/95 520905 i'
p-Chloro-m-cresol ND 10 CFR136A 625 07/28-08/03/95 520905 g
3 2-Chloronaphthalene ND 10 CFR136A 625 07/28-08/03/95 520905 2-Chlorophenol ND 10 CFR136A 625 07/28-08/03/95 520905
(,,
4-Chlorophenyl phenyl ether ND 10 CFR136A 625 07/28-08/03/95 520905 Chrysene ND 10 CFR136A 625 07/28-08/03/95 520905 l.,f Dibenz(a,h) anthracene ND 10 CFR136A 625 07/28-08/03/95 520905 ie Di-n-butyl phthalate ND 10 CFR136A 625 07/28-06/03/95 520905 !
{7 1,2-Dichlorebenzene ND 10 CFR136A 625 07/28-08/03/95 520905 l
}
1,3-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905 f i
SURROGATE RECOVERY 3,
ACCEPTABLE LIMITS I
I 2-Fluorophenol 58
( 17 - 106)
Phenol-d5 62
( 15 - 126) 2,4,6-Tribromophenol 79
( 13 - 145) i!
Nitrobenzene-d5 70
( 36 - 148) 2-Fluorobiphenyl 71
( 38 - 106)
Terphenyl-d14 103
( 10 - 169)
NOTIR AS RECEIVED ND NOT DETECTED AT DIE STATED REPORTING LIMIT e.
E E
Environmental Serriws ILLUMINATING COMPANY NEUTRALIZATION BASIN m
DATE SAMPLED:
7/27/95 l
WO #: COE2510T DATE RECEIVED:
7/07/95 LAB #: A5G270132-003 MATRIZ: WATER DILUTION FACTOR:
1.00
- - - - GC/MS Semi-volatiles - - - - - - - - - - - - - - - - -
2 OF 3
RESULT REPORTING EXTRACTION-QC PARAMETER (ua/L)
LIMIT METHOD ANALYSIS DATE BATCH 1,4-Dichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905:
3,3'-Dichlorobenzidins ND 10 CFR136A 625 07/28-08/03/95 520905: l 2,4-Dichlorophenol ND 10 CFR136A 625 07/28-08/03/95 520905:
l Diethyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905: !
2,4-Dimethylphenol' ND 10 CFR136A 625 07/28-08/03/95 520905:
Dimethyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905:
[
4,6-Dinitro-o-cresol ND 50 CFR136A 625 07/28-08/03/95 520905' 2,4-Dinitrophenol ND 50 CFR136A 625 07/28-08/03/95 520905 2,4-Dinitrotoluene ND 10 CFR136A 625 07/28-08/03/95 520905 2,6-Dinitrotoluene ND 10 CFR136A 625 07/28-08/03/95 520905 Di-n-octyl phthalate ND 10 CFR136A 625 07/28-08/03/95 520905 l F
1,2-Diphenylhydrazine ND 10 CFR136A 625 07/28-08/03/95 520905 i 1
i bis (2-Ethylhexyl) phthalate 25 10 CFR136A 625 07/28-08/03/95 520905 Fluoranthene ND 10 CFR136A 625 07/28-08/03/95 520905 Fluorene ND 10 CFR136A 625 07/28-08/03/95 520905 Hexachlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905 Hexachlorobutadiene ND 10 CFR136A 625 07/28-08/03/95 520905 Hexachlorocyclopentadiene ND 10 CFR136A 625 07/28-08/03/95 520905 Hexachloroethane ND 10 CFR136A 625 07/28-08/03/95 520905 Indeno (1,2,3 -cd) pyrene ND 10 CFR136A 625 07/28-08/03/95 520905
~~g. 3 L~~
Isophorone ND 10 CFR136A 625 07/28-08/03/95 520905 Naphthalene ND 10 CFR136A 625 07/28-08/03/95 520905 Nitrobenzene ND 10 CFR136A 625 07/28-08/03/95 520905 CURROGATE RECOVERY
)_
ACCEPTABLE LIMITS 2-Fluorophenol 58
( 17 - 106)
Phenol-d5 62
( 15 - 126)
L,
2,4,6-Tribromophenol 79
( 13 - 145) j Nitrobenzene-d5 70
( 36 - 148) 2-Fluorobiphenyl 71
( 3B - 106)
Terphenyl-d14 103
( 10 - 169)
NOTE:
l AS RECE!VLD ND NOT DETECTED AT1HE STATED REPORTING UMIT I
l
~
1
Qhwanterra Ers;honmental Servias ILLUMINATING COMPANY NEUTRALIZATION BASIN p
DATE SAMPLED:
7/27/95
{l WO #: COE2510T DATE RECEIVED:
7/27/95 L
LAB #: A5G270132-003 MATRIX: WATER DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
3 OF 3
RESULT REPORTING EXTRACTION-QC PARAMETER (uct/L)
LIMIT METHOD ANALYSIS DATE BATCH 2-Nitrophenol ND 10 CFR136A 625 07/28-08/03/95 5209052 4-Nitrophenol ND 50 CFR136A 625 07/28-08/03/95 5209052 N-Nitrosodimethylamine ND 10 CFR136A 625 07/28-08/03/95 5209052 i
N-Nitrosodiphenylamine ND 10 CFR136A 625 07/28-08/03/95 5209053 J
N-Nitrosodi-n-propylamine ND 10 CFR136A 625 07/28-08/03/95 5209052 Pentachlorophenol ND 50 CFR136A 625 07/28-08/03/95 5209052 Phenanthrene ND 10 CFR136A 625 07/28-08/03/95 520905; Phenol ND 10 CFR136A 625 07/28-08/03/95 520905: l Pyrene ND 10 CFR136A 625 07/28-08/03/95 520905:
I 1,2,4-Trichlorobenzene ND 10 CFR136A 625 07/28-08/03/95 520905:
2,4,6-Trichlorophenol ND 10 CFR136A 625 07/28-0B/03/95 520905;
.I i
1 1
I-i L..
SURROGATE RECOVERY 1
ACCEPTABLE LIMITS k
2-Fluorophenol 58
( 17 - 106)
Phenol-d5 62
( 15 - 126) 2,4,6-Tribromophenol 79
( 13 - 145)
{j 148)
Nitrobenzene-d5 70
( 36 g
2-Fluorobiphenyl 71
( 38 - 106)
Terphenyl-d14 103
( 10 - 169)
NOTE:
AS RECEIVED ND NOT DETECI'ED AT DIE STATED REPORTING UMIT e
Quanterra Envimamentd Ser&rs ILLUMINATING COMPANY NEUTRALIZATION BASIN g
'hi-WO #: COE25 DATE SAMPLED:
7/27/95
)
LAB #: A5G270132-003 DATE RECEIVED:
7/27/95 MATRII: WATER
. REQUESTED METALS -
REPORTING PREPARATION -
QC p]QLAMETER RESULT LIMIT UNIT METHOD ANALYSIS DATE BATCH Aluminum 0.59 0.20 mg/L MCAW 200.7 8/02-8/03/95 521400E Barium ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 521400E Boron ND 0.20 mg/L MCAWW 200.7 8/02-8/03/95 521400E Cobalt ND 0.050 mg/L MCAWW 200.7 8/02-8/03/95 521400E
.11 Iron 10.1 0.10 mg/L MCA W 200.7 8/02-8/03/95 521400E Magnesium 51.4 5.0 mg/L MCA N 200.7 8/02-8/03/95 521400E I
. 0.038 0.015 mg/L MCAW 200.7 8/02-8/03/95 521400E
{'
Manganese Molybdenum ND 0.10 mg/L MCAWW 200.7 8/02-8/03/95 521400E Tin ND 1.0 mg/L MCAWW 200.7 8/02-8/09/95 521400E Titanium 0.021 0.010 mg/L MCAW 200.7 8/02-8/03/95 521400E F
L.
6
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NOlb AS RIrF2V12)
ND NOT IWTirT12) AT 111E STAT 12) Rt2aORTING IJh!!T 9
Q%anterra Enviwntoenri Services ILLUMINATING COMPANY NEUTRALIZATION BASIN 2,
i DATE SAMPLED:
7/27/95 J
WO # COE25 DATE RECEIVED:
7/27/95 LAB #: A5G270132-003 MATRIX: WATER INORGANIC ANALYTICAL REPORT - - - - -- -- - --- - --
REPORTING PREPARATION -
QC PARAMETER RESULT LIMIT UNIT METHOD ANALYSIS DATE BATCH Color (Colorimetric, 300 25 C.U.
MCAW 110.2 7/27/95 5209024 f'
Platinum-Cobalt)
Bromide (Titrimetric) 40 20 mg/L MCAW 320.1 8/10/95 522208(
f Total residual chlorine ND 0.2 mg/L MCAW 330.5 7/27/95 5209022 (Spectrophotometric, DPD)
,I J
Fluoride (Colorimetric, 0.6 0.1 ag/L MCAW 340.2 8/07/95 521903(
Ion Selective Electrode)
Nitrate-Nitrite 3.7 0.2 mg/L MCAW 353.2 8/11/95 522307!
Total phosphorus ND 0.1 mg/L MCAW 365.2 8/01-8/02/95 521309=
(Colorimetric) l f
Sulfide 1.5 0.50 mg/L MCAW 376.1 8/02/95 521410' i
Sulfite ND 2
mg/L MCAW 377.1 7/27/95 521603 Surfactants (MBAS)
ND 0.1 mg/L MCAW 425.1 7/27/95 520902:
Oil and Grease, ND 5.0 mg/L MCAW 413.1 8/09-8/10/95 522104' P
Gravimetric Coliforms, Fecal ND 10.0
/100mL SM18 9222D 7/27-7/28/95 520902 1
Total Organic Nitrogen 2
1 mg/L MCAW 351.3/3 8/11/95 522308 I
Sulfate ND 500 mg/L MCAW 375.4 8/11/95 522308
't i.
p b.
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4 NOTL AS RECEIVED ND NOT DETECTED AT T1tE STATED REPORTING UMIT i
4,.-...w an.g.xq.A.-e w e-e 44-.
m - as e me mw.'
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24 ma-w.ama 4. An.ag
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=m-&--M.Jh4.LJ^-4A-.
Sam.444,6.h maA -
A.,w4-.
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QUALITY CONTROL SECTION r
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khanterra Ewinmmental servim QUALIFY CONTROL NARRATIVE i}
The results included in this report have been reviewed for compliance with the laboratory QA/QC plan. All data have been found to be compliant with the exception of those items noted.
The matrix spike and matrix spike duplicates (MS/MSD) contamed in this quality control report were generated as part of the laboratory QA/QC program requirements.
These requirements include the analysis of a MS/MSD on a one in twenty basis. Therefore, the associated batch number indicated on the MS/MSD reports may not reflect the same batch numbers as those of the samples contained in the analytical report.
Recoveries for Chloroethane and Chloroemethane associated with batch 5215097 and 3,3'-
Dichlorobenzidine associated with batch 5109160 exceed quality control acceptance limits in the matrix spike. 'According to EPA 600 series method requirements, analytical data for these analytes have been verified by the check sample recoveries meeting quality control criteria.
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UBntOFFB Envinmmental QUALITY ASSURANCE / QUALITY CONTROL PROGRAM ELEMENTS Quanterra, Inc. conducts a quality assurance / quality control (QA/QC) program designed to provide scientifically valid and legally defensible data.
Quality control samples provide a mechanism for assessing the overall quality of the analytical 4
process and can be used to indicate the usability of the analytical data. These QC samples include check samples, method blanks, matrix spikes and surrogate spikes.
The CHECK SAMPLE is used to demonstrate that all laboratory analytical processes were functioning properly when the associated sample batch was prepared and analyzed. The check sample is a simulated sample spiked with representative analytes. It is prepared and analyzed
}.
with a batch of samples. Spike recovery values from this check sample must meet laboratory established acceptance criteria.
l i
The METHOD BLANK is used to measure the level of background contamination in the laboratory's analytical system. The method blank is carried through the same process as samples, including the preparation, and consists of all the reagents specific to the method.
All analytes of interest in the method blank for organic analyses must be below the method i
detection limits except for the following common laboratory contaminants.
l Volatiles Semivolatiles 2
Methylene chloride Dimethyl phthalate 2-Butanone Diethyl phthalate Acetone Di-n-butyl phthalate Butyl benzyl phthalate Bis (2-ethylhexyl) phthalate Di-n-octyl phthalate These commonly-detected laboratory contaminants may be present in the method blank at up to five times the method reporting limit.
1 For metals analyses, if any analyte concentration in the method blank is above the method reporting limit, then the lowest concentration of that analyte in the associated samples must be at least ten times the blank concentration. All samples associated with the blank which are less
{
than ten times the blank concentration are redigested and reanalyzed.
The laboratory performs MATRIX SPIKES (MS) and MATRIX SPIKE DUPLICATES (MSD) to indicate any matrix effects within a given sample. They also allow the laboratory to gather precision and bias data for a specific method and matrix.
Y RtOffB l
wm,,,,,e,,d Services Since matrix effects may bias percent recovery, the laboratory performs corrective action if the precision (RPD) criteria of the MS/MSD is not met.
)
SURROGATE SPIKES are used by the laboratory to indicate method bias introduced by the sample matrix during the preparation and analysis of a specific method.
Surrogates are normally organic compounds similar to those being analyzed for the GC or GC/MS. If surrogate recoveries fail to meet laboratory acceptance criteria it does not necessarily indicate i
poor laboratory control but may in fact be attributed to a sample matrix effect. In the event that surrogates fail criteria, a repreparation and reanalysis is performed to determine the presence of a matrix effect.
The laboratory uses the following surrogate recovery criteria for all organic analyses.
For the GC/MS Base / Neutral fraction the surrogate criteria requires that two of the three gy surrogates must meet recovery limits. The third surrogate must have a recovery of ten percent or greater.
p
[j For the GC/MS Acid fraction the surrogate criteria requires that two of the three surrogates must meet recovery limits. The third surrogate must have a recovery of ten percent or greater.
r 1
For GC/ ECD Pesticides, the surrogate criteria requires that one of the two surrogates must i
meet recovery limits.
F L
For Volatiles, PCBs and Herbicides all surrogates utilized must meet surrogate recovery limits.
b i
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O SM EnvironmmeJ Sernws CHECK SANPLE REPORT f
QC BATCH:
5222044 PREPARATION DATE:
8/08/95 LAB #: A5H100000-044 C DILUTION FACTOR:
1.00 DATE ANALYZED:
8/08/95
- - - - - - - - - - GC/MS Volatiles - - - - - - - - - - - - - - - - - -
SPIKE I
PERCENT Q/C RECOVERY LIMITS COMPOUND I
102 (79-125)
[
Benzene Bromodichloromethane 107 (65-144) 100 (46-151)
Bromoform
.{
Bromomethane 113 (47-160)
Carbon tetrachloride 113 (63-141) 100 (81-121)
Chlorobenzene 106 (38-170)
I Chloroethane.
108 (27-166) b 2-Chloroethyl vinyl ether Chloroform 106 (70-141)
Chloromethane 104 (36-158) c.
l Dibromochloromethane 105 (58-140) 107 (18-190) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 110 (59-156) 105 (19-190)
I 1,4-Dichlorobenzene
{,
1,1-Dichloroethane 100 (64-145) 1,2-Dichloroethane 103 (66-150) 1,1-Dichloroethene 104 (70-143) r-J-
trans-1,2-Dichloroethene 101 (58-140) 100 (71-142)
I 1,2-Dichloropropane cis-1,3-Dichloropropene 103 (59-140)
{
trans-1,3-Dichloropropene 104 (53 148) 101 (70-140)
L Ethylbenzene Methylene chloride 97 (72-144) 1,1,2,2-Tetrachloroethane 104 (52-153) 7,'
103 (67-136) l Tetrachloroethene 106 (79-122)
E-Toluene 1,1,1-Trichloroethane 105 (67-137) 101 (70-140)
{~
1,1,2-Trichloroethane Trichloroethene 104 (76-121)
Trichlorofluoromethane 122 (17-181) 109 (47-156)
Vinyl chloride i
s l
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QEuanterra Environmental Servias CHECK SAMPLE REPORT Il QC BATCE:
5209051 L'
LAB #: A5G280000-051 C PREPARATION DATE:
7/28/95 DILUTION FACTOR:
1.00 DATE ANALYZED:
8/02/95
- - - - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
SPIKE PERCENT Q/C l
COMPOUND RECOVERY LIMITS P
Acenaphthene 93 (48-113)
Acenaphthylene 90 (47-111)
Anthracene 89 (53-107)
Benzo (a) anthracene 85 (53-110)
Benzo (b)fluoranthene 96 (43-110)
Benzo (k)fluoranthene 104 (36-136)
"~
Benzo (a) pyrene 84 (28-114)
Benzo (ghi) perylene 84 (17-120)
Benzyl butyl phthalate 91 (35-110) bis (2-Chloroethyl) ether 83 (44-95) j bis (2-Chloroethoxy) methane 84 (50-106) bis (2-Chloroisopropyl) ether 71 (21-122) bis (2-Ethylhexyl) phthalate 90 (30-123) 4-Bromophenyl phenyl ether 82 (52-114)
[2 2-Chloronaphthalene 86 (43-111) 4-Chlorophenyl phenyl ether 81 (48-124)
Chrysene 92 (54-120) j Dibenzo(a,h) anthracene 82 (23-112)
L-Di-n-butyl phthalate 96 (44-115) 1,2-Dichlorobenzene 62 (43-95) 1,3-Dichlorobenzene 56 (41-92) 1,4-Dichlorobenzene 59 (37-92) 3,3'-Dichlorobenzidine 52 (19-137) f.,'
Diethyl phthalate 62 (16-129) 4 Dimethyl phthalate 35 (10-115) 5-2,4-Dinitrotoluene 85 (37-131) 2,6-Dinitrotoluene 92 (40-121)
Di-n-octyl phthalate 93 (25-123)
Flucranthene 83 (35-131)
Fluorene 88 (45-124)
Hexachlorobenzene 79 (53-110)
Hexachlorobutadiene 63 (45-96)
Hexachloroethane 58 (30-90)
Indeno(1,2,3-cd) pyrene 89 (28-112)
],
Isophorone 84 (44-105) j Naphthalene 77 (44-99)
Nitrobenzene 82 (44-102)
N-Nitrosodi-n-propylamine 77 (31-113)
Phenanthrene 95 (50-109)
Pyrene 93 (39-159) 1,2,4-Trichlorobenzene 69 (39-136)
L
E Fai,vamental Servins CHECK SAMPLE REPORT QC BATCH: 5209051
. PREPARATION DATE:
7/28/95
~
LAB #: A5G280000-051 C DATE ANALYZED:
8/02/95 DILUTION FACTOR:
1.00
- - - - - - GC/MS Semi-volatiles - - - - - - - - - - - - - - - - -
r' SPIKE I
PERCENT Q/C RECOVERY LIMITS COMPOUND 85 (30-117) 4-Chloro-3-methylphenol 79 (35-111) 2-Chlorophenol 80 (33-93) 2,4-Dichlorophenol 27 (23-74) 2,4-Dimethylphenol J
2,4-Dinitrophenol ~
81 (10-96) 87 (10-115) 4,6-Dinitro-2-methylphenol
{j 75 (10-99)
[.
2-Nitrophenol 110 (10-128) 4-Nitrophenol 82 (10-113)
Pentachlorophenol 7-80 (12-116) l Phenol 82 (22-102) 2,4,6-Trichlorophenol I.
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Emuunmernd Services CHECK SAMPLE REPORT i
i
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LAB #: A5G270132 1
t'
................... METALS - - - -- ---
SPIKE PERCENT Q/C PREPARATION -
COMPOUND RECOVERY LIMITS ANALYSIS DATE i
BATCH:5214008 Aluminum 102 (80-120) 8/02-8/03/95 Barium 106 (80-120) 8/02-8/03/95 102 (80-120) 8/02-8/03/95 d
Boron 2
Cobalt 107 (80-120) 8/02-8/03/95 106 (80-120) 8/02-8/03/95 Iron j
Magnesium 104 (80-120) 8/02-8/03/95 108 (80-120) 8/02-8/03/95 j
Manganese 106 (80-120) 8/02-8/03/95 Molybdenum 105 (80-120) 8/02-8/09/95 Tin l
Titanium 108 (80-120) 8/02-8/03/95 j
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Q%anterra Enviroroental Semces CHECK SAMPLE REPORT c
ii L1 LAB #: A5G270132
- - - - - - - - - INORGANIC ANALYTICAL REPORT SPIKE PERCENT PREPARATION -
Q/C COMPOUND RECOVERY LIMITS ANALYSIS DATE BATCH
('
Bromide (Titrimetric) 104 (68-129) 8/10/95 5222080
(
Fluoride (Colorimetric, 102 (87-113) 8/07/95 5219030 Ion Selective Electrode)
Nitrate-Nitrite 99 (88-110) 8/03-8/04/95 5216012 i
_i Nitrate-Nitrite 99 (88-110) 8/11/95 5223079 Total phosphorus 109 (81-119) 8/01-8/02/95 5213094 Sulfide 98 (55-121) 8/02/95 5214107 Sulfite 100 (57-116) 7/27/95 5216038 I
Surfactants (MBAS) 109 (82-116) 7/27/95 5209029
(
Oil & Grease 106 (70-134) 8/09-8/10/95 5221047 (Gravimetric)
Sulfate 97 (84-114) 8/11/95 5223080 L
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E hvironmenci METHOD ELANK REPORT Servias l
LAB #: A5H100000-044 f
DILUTION FACTOR:
1.00
)
- - - GC/MS Volatiles - - - - - - - - - - - - - - - - - - -
RESULT REPORTING PREPARATION -
QC n-(ua/L)
LIMIT ANALYSIS DATE BATCH
{
PARAMETER ND 100 8/08/95 5222044 Acrolein ND 100 8/08/95 5222044 I
Acrylonitrile ND 5.0 8/08/95 5222044 Benzene ND 5.0 8/08/95 5222044 Dichlorobromomethane ND 5.0 8/08/95 5222044 t
i Bromoform ND 10 8/08/95 5222044 Bromomethane I ~'
Carbon tetrachloride ND 5.0 8/08/95 5222044 ND 5.0 8/09/95 5222044 ;
f; Chlorobenzene Chlorodibromomethane ND 5.0 8/08/95 5222044 t'
ND 10 8/08/95 5222044 ;
ND 5.0 8/08/95 5222044 '
Chloroethane Chloroform ND 10 8/08/95 5222044 Chloromethane ND 5.0 8/08/95 5222044 j,
1,1-Dichloroethane ND 5.0 8/08/95 5222044 1,2-Dichloroethane ND 5.0 8/08/95 5222044 1,1-Dichloroethene 1-1,2-Dichloroethene (total)
ND 5.0 8/08/95 5222044 l
ND 5.0 8/08/95 5222044 1,2-Dichloropropane ND 5.0 8/08/95 5222044 l
cis-1,3-Dichloropropene trans-1,3-Dichloropropene ND 5.0 8/08/95 5222044 1-ND 5.0 8/08/95 5222044 Ethylbenzene
,3 ND 10 8/08/95 5222044 i'
Methylene chloride 4
ND 5.0 8/08/95 522204 1,1,2,2-Tetrachloroethane Tetrachloroethene ND 5.0 8/08/95 522204 ND 5.0 8/08/95 522204 Toluene 8/08/95 522204-ND 5.0 1,1,1-Trichloroethane i
SURROGATE RECOVERY 3.
ACCEPTABLE LIMITS 98
( 88 - 110)
-i Toluene-d8 Bromofluorobenzene 96
( 86 - 115) 1,2-Dichloroethane-d4 103
( 76 - 114) e L)
N oTE:
ND (NONE DETECTED)
L
Eu.;,- ;-a;.tal Serms METHOD BLANK REPORT
~~f..~~
~
LAB #: A5H100000-044 DILUTION FACTOR:
1.00 l'
- - - - - - - - - - - - - - - - - - GC/MS Volatiles - - - - - - - - - - - - - - - - - - -
RESULT REPORTING PREPARATION -
QC PARAMETER (ua/L)
LIMIT ANALYSIS DATE BATCH 1,1,2-Trichloroethane ND 5.0 8/08/95 5222044 f'
Trichloroethene ND 5.0 8/08/95 5222044
}
Vinyl chloride ND 10 8/08/95 5222044
-]
LJ 1;
I i
P f
$i r
I.
I l
I._l f
L.
SURROGATE RECOVERY 1
ACCEPTABLE LIMITS f
Toluene-dB 98
( 88 - 110) 5-Bromofluorobenzene 96
( 86 - 115) 1,2-Dichloroethane-d4 103
( 76 - 114)
Li d
NOTE:
e ND (NONE DETECTED) t I'
Qhassterra Etrrironmentd METHOD ELANK REPORT Services a!
. LAB #: A5G280000-051 DILUTION FACTOR:
1.00
- - - - - - - - - GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - - -
RESULT REPORTING PREPARATION -
QC (ua/L)
LIMIT ANALYSIS DATE EATCH i
PARAMETER
~,
ND 10 7/28-8/03/95 5209051 Acenaphthene t
Acenaphthylene ND 10 7/28-8/03/95 5209051 Anthracene ND 10 7/28-8/03/95 5209051 f
Benzidine ND 100 7/28-8/03/95 5209051 i
Benzo (a) anthracene ND 10 7/28-8/03/95 5209051 J
Benzo (b)fluoranthene ND 10 7/28-8/03/95 5209051 f' '
Benzo (k)fluoranthene ND 10 7/28-8/03/95 5209051
[
Benzo (ghi) perylene ND 10 7/28-8/03/95 5209051 Benzo (a) pyrene ND 10 7/28-8/03/95 5209051 bis (2-Chloroethoxy) methane ND 10 7/28-8/03/95 5209051 bis (2-Chloroethyl) ether ND 10 7/28-8/03/95 5209051 bis (2-Chloroisopropyl) ether ND 10 7/28-8/03/95 5209051 IL bis (2-Ethylhexyl) phthalate ND 10 7/28-8/03/95 5209051 4-Bromophenyl phenyl ether ND 10 7/28-8/03/95 5209051 Butyl benzyl phthalate ND 10 7/28-8/03/95 5209051 l
r,
\\L-p-Chloro-m-cresol ND 10 7/28-8/03/95 5209051 2-Chloronaphthalene ND 10 7/28-8/03/95 5209051 1
2-Chlorophenol ND 10 7/28-8/03/95 5209051 I"
4-Chlorophenyl phenyl ether ND 10 7/28-8/03/95 5209051 Chrysene ND 10 7/28-8/03/95 5209051 f,'
Dibenz(a,h) anthracene ND 10 7/28-8/03/95 5209051 L.
Di-n-butyl phthalate ND 10 7/28-8/03/95 5209051 l'
1,2-Dichlorobenzene ND 10 7/28-8/03/95 5209051 1,3-Dichlorobenzene ND 10 7/28-8/03/95 5209051 {
i 1,4-Dichlorobenzene ND 10 7/28-8/03/95 5209051 5
SURROGATE RECOVERY l
ACCEPTABLE LIMITS 2-Fluorophenol 61
( 17 - 106)
Phenol-d5 62
( 15 - 126)
!a 2,4,6-Tribromophenol 61
( 13 - 145)
Nitrobenzene-d5 76
( 36 - 148) 2-Fluorobiphenyl 66
( 38 - 106)
Terphenyl-d14 110
( 10 - 169)
I NOTE:
ND (NONE DETECTED)
+
M EnshamentJ METHOD ELANK REPORT
,h,
-s l'
LAB #: A5G280000-051 DILUTION FACTOR:
1.00
- GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -.
RESULT REPORTING PREPARATION -
QC (ua /L)
LIMIT ANALYSIS DATE BATCH i
P.AEAMETER 3,3'-Dichlorobenzidine ND 10 7/28-8/03/95 5209051 f
2,4-Dichlorophenol ND 10 7/28-8/03/95 5209051 Diethyl phthalate ND 10 7/28-8/03/95 5209051 2,4-Dimethylphenol ND 10 7/28-8/03/95 5209051 i
Dimethyl phthalate ND 10 7/28-8/03/95 5209051 Di-n-octyl phthalate ND 10 7/28-8/03/95 5209051' 4
4,6-Dinitro-o,-cresol ND 50 7/28-8/03/95 5209051 l
2,4-Dinitrophenol ND 50 7/28-8/03/95 5209051 i
2,4-Dinitrotoluene ND 10 7/28-8/03/95 5209051 2,6-Dinitrotoluene ND 10 7/28-8/03/95 5209051 t
i 1,2-Diphenylhydrazine ND 10 7/28-8/03/95 5209051 Fluoranthene ND 10 7/28-8/03/95 5209051 F
}
Fluorene ND 10 7/28-8/03/95 5209051 Hexachlorobenzene ND 10 7/28-8/03/95 5209051 Hexachlorobutadiene ND 10 7/28-8/03/95 5209051 h
Hexachlorocyclopentadiene ND 10 7/28-8/03/95 5209051 Hexachloroethane ND 10 7/28-8/03/95 5209051 f
Indeno (1,2,3-cd) pyrene ND 10 7/28-8/03/95 5209053 l
h ND 10 7/28-8/03/95 5209053 180P orone Naphthalene go 10 7/28-8/03/95 5209053
[}
Nitrobenzene ND 10 7/28-8/03/95 5209053 a.
2-Nitrophenol ND 10 7/28-8/03/95 5209053
['
4-Nitrophenol ND 50 7/28-8/03/95 5209053 4
N-Nitrosodimethylamine ND 10 7/28-8/03/95 5209053 N-Nitrosodi-n-propylamine ND 10 7/28-8/03/95 520905; i
SURROGATE RECOVERY 1
ACCEPTABLE LIMITS g
i 2-Fluorophenol 61
( 17 - 106)
Phenol-d5 62
( 15 - 126) 2,4,6-Tribromophenol 61
( 13 - 145) j Nitrobenzene-d5 76
( 36 - 148) 2-Fluorobiphenyl 66
( 38 - 106)
Terphenyl-d14 110
( 10 - 169)
I Non:
ND (NONE DDTfED)
Qkanterra E.; -,wx1 METHOD LLANK REPORT Smies r1kI l
LAB #: A5G280000-051 DILUTION FACTOR:
1.00
- - - - - - - - - - - - - - - - - GC/MS Senti-volatiles - - - - - - - - - - - - - - - - - -
RESULT REPORTING PREPARATION -
QC fuct/L)
LIMIT ANALYSIS DATE BATCH r4 PARAMETER N-Nitrosodiphenylamine ND 10 7/28-8/03/95 5209051 I'
Pentachlorophenol ND 50 7/28-8/03/95 5209051 I
Phenanthrene ND 10 7/28-8/03/95 5209051 Phenol ND 10 7/28-8/03/95 5209051 ND 10 7/28-8/03/95 5209051 Pyrene 1,2,4-Trichloroberizene ND 10 7/28-8/03/95 5209051
'4 I~'
2,4,6-Trichlorophenol ND 10 7/28-8/03/95 5209051 a~
i I
i I
5
[1 Ib..
i SURROGATE RECOVERY 1
ACCEPTABLE LIMITS 2-Fluorophenol 61
( 17 - 106) i Phenol-d5 62
( 15 - 126) 2,4,6-Tribromophenol 61
( 13 - 145) j Nitrobenzene-d5 76
( 36 - 148) gj 2-Fluorobiphenyl 66
( 38 - 106) 110
~,
( 10 - 169)
Terphenyl-d14 NOTE:
ND (NONE DETECITI))
t
&M Environmental Senices MxTHOD BLANK REPORT
i.
J LAB # A5G270132 e
i l
METALS I
REPORTING PREPARATION -
PARAMETER RESULT LIMIT UNIT METHOD ANALYSIS DATE 1
BATCH:5214008
{
Aluminum ND 0.20 mg/L MCAWW 200.7 8/02-S/03/95 Barium ND 0.20 mg/L MCAWW 200.7 8/02-is/C3/95 Boron ND 0.20 mg/L.
MCAWW 200.7 8/02-8/03/55 d
Cobalt ND 0.050 mg/L MCAWW 200.7 8/02-8/03/95 i
Iron ND 0.10 mg/L MCAWW 200.7 8/02-8/03/95 Magnesium ND 5.0 mg/L MCAWW 200.7 8/02-8/03/95
't 4
Manganese ND 0.015 mg/L MCAWW 200.7 8/02-8/03/95 6
Molybdenum ND 0.10 mg/L MCAWW 200.7 8/02-8/03/95 Tin ND 1.0 mg/L MCAWW 200.7 8/02-8/09/95 iLJ Titanium ND 0.010 mg/L MCAWW 200.7 8/02-8/03/95 I~
L.
f
-d n
i L.
{'
I nom ND NOT DETECTED AT 1HE STATED REPORTING UMIT l
I i 1 u
e d*
6 i
E Ensimamernal METHOD CLANK REPORT Senirs t
.3 l
'I LAB #: A5G270132
- - - - - - - - - - INORGANIC ANALYTICAL REPORT REPORTING PREPARATION -
QC l
PARAMETER RESULT LIMIT ___,
UNIT ANALYSIS DATE BATCH 7
Color (Colorimetric, ND 5
C.U.
7/27/95 5.709024
{
Platinum-Cobalt) i Bromide (Titrimetric)
ND 2
mg/L 8/10/95 5222080 Total residual chlorine ND-0.2 mg/L 7/27/95 5209023 (Spectrophotometric, DPD)
J Fluoride (Colorimetric, ND 0.1 mg/L 8/07/95 5219030 Ion Selective Electrode)
Nitrate-Nitrite ND 0.1 mg/L 8/03-8/04/95 5216012 Nitrate-Nitrite ND 0.1 mg/L 8/11/95 5223079 Total phosphorus ND 0.1 mg/L 8/01-8/02/95 5213094 (Colorimetric)
Sulfide ND 0.50 mg/L 8/02/95 5214107 Sulfite ND 2
mg/L 7/27/95 5216038
['
Surfactants (MBAS)
ND 0.1 mg/L 7/27/95 5209029 Oil and Grease, ND 5.0 mg/L 8/09-8/10/95 5221047 Gravimetric
}
Coliforms, Fecal ND 10.0
/100mL 7/27-7/28/95 5209026 i
Total Organic Nitrogen ND 1
mg/L 8/11/95 5223088 Sulfate ND 5
mg/L 8/11/95 5223080 t
I' i.
4 I
L J
No' n ND NOT DETECrFD AT DIE STATED REPORTING UbCT
E E
Environsnental Servkrs MATRIX SPIKE REPORT WO # :
COAND QC BATCH:
5215097 PREPARATION DATEt 7/28/95 LAB #: A5G220104-001 S DATE ANALYZED:
7/28/95 MATRIX: WATER DILUTION FACTOR:
1,00 t
- - - - - - GC/MS volatiles - - - - - - - - - - - - - - - - - -
SPIKE PERCENT Q/C i
RECOVERY LIMITS COMPOUND 99 (83-123)
Benzene 104 (57-153) e Bromodichloromethane (47-165) 96 Bromoform (76-150) 115 Bromomethane (73-135) 111 Carbon tetrachloride (85-120) f ' C(,j 95 i
l Chlorobenzene (71-154) 0 I
Chloroethane (10-153) 54 2-Chloroethyl vinyl ether (10-204) 93 I
Chloroform (44-151) i 0
Chloromethane (60-146) 99 Dibromochloromethane (18-190)
)
103
['
1,2-Dichlorobenzene (5F-156) 105
{;
1,3-Dichlorobenzene (18-190) 102 1,4-Dichlorobenzene (53-148) 93 1,1-Dichloroethane (52-167) 98 l
1,2-Dichloroethane (55-142) 97 s-1,1-Dichloroethene (55-139) 94 trans-1,2-Dichloroethene (64-146) 95 i
1,2-Dichloropropane (52-135) 100 cis-1,3-Dichloropropene (50-144) 102 trans-1,3-Dichloropropene (72-140) 95 Ethylbenzene (62-152) g 94 i
Methylene chloride (53-149) 96 b
1,1,2,2-Tetrachloroethane (67-141) 98 Tetrachloroethene (82-122) 104
{
Toluene (33-171) 105
[
1,1,1-Trichloroethane (73-138) 94 1,1,2-Trichloroethane (77-124) 100 Trichloroethene (17-181) 117 i
Trichlorofluoromethane 93 (48-161) k*
Vinyl chloride Ii 1
L}
i t
Calcutauons are performed before roumimg as avow rourd4ff errors in calculated resuhs t.
1
&M Environmental Senkes MATRIX SPIKE REPORT QC BATCH: 5109160 WO #:
A436G 3
LAB #: A5D190060-001 S PREPARATION DATE:
4/19/95 MATRIX: WATER DATE ANALYZED:
5/01/95 t
f
- - - - - - - - - - - - - - - - - GC/MS Semi-volatiles - - - - - - - - - - - - - - - - -
i SPIKE PERCENT Q/C l
COMPOUND RECOVERY LIMITS Acenaphthene 79 (45-112)
Acenaphthylene 84 (30-122)
J Anthracene 77 (18-133)
Benzo (a) anthracene 74 (17-130)
~
Benzo (b)fluoranthene 63 (29-108)
Benzo (k)fluoranthene 62 (23-127)
Benzo (a) pyrene 58 (13-126)
Benzo (g,h,1) perylene 34 (10-128) i Benzyl butyl phthalate 71 (10-152) bis (2-Chloroethyl) ether 99 (29-103) bis (2-Chloroethoxy) methane 84 (29-130)
{
bis (2-Chloroisopropyl) ether 79 (19-150)
{3 bis (2-Ethylhexyl)phthalate 83 (12-145) 4-Bromophenyl phenyl ether 79 (32-128) 2-Chloronaphthalene
'9 (27-125)
{
4-Chlorophenyl phenyl ether 3?.
(33-131)
L Chrysene 75 (20-138)
Dibenzo(a,h) anthracene 39 (18-116)
Di-n-butyl phthalate 68 (24-126)
{
1,2-Dichlorobenzene 81 (28-103) 1,3-Dichlorobenzene 80 (31-97) 1,4-Dichlorobenzene 80 (33-90) h 3,3'-Dichlorobenzidine 0
(10-139)
LI Diethyl phthalate 55 (27-110)
Dimethyl phthalate 68 (10-101)
?'
2,4-Dinitrotoluene 68 (37-124) 2,6-Dinitrotoluene 68 (23-130)
~
Di-n-octyl phthalate 72 (31-110)
Fluoranthene 77 (26-123)
Fluorene 84 (32-122)
Hexachlorobenzene 88 (34-129)
Hexachlorobutadiene 77 (31-109) 11 Hexachloroethane 78 (32-95)
{*l Indeno(1,2,3-cd) pyrene 41, (13-127)
Isophorone B'3 (19-133)
Naphthalene 84 (32-111)
Nitrobenzene 84 (34-114)
N-Nitrosodi-n-propylamine 90 (10-230)
Phenanthrene 82 (30-120)
L.
US$hM Ennnmermst:1 Scr-bes MATRIX SPIKE REPORT f*;*
WO #2 A436G 8
QC BATCH: 5109160 LAB #: A5D190060-001 S
. PREPARATION DATE:
4/19/95 DATE ANALYZED:
5/01/95-MATRIX: WATER
- GC/MS Semi-Volatiles - - - - - - - - - - - - - - - - -
n SPIKE
['
PERCENT Q/C COMPOUND RECOVERY LIMITS 52 (15-185)
Pyrene i
1,2,4-Trichlorobenzene 79 (40-133) d 4-Chloro-3-methylphenol 90 (71-120) 2-Chlorophenol 88 (10-134) 2,4-Dichlorophenol 90 (34-100) 2,4-Dimethylphenol 70 (11-78) 2,4-Dinitrophenol 55 (10-114) 66 (10-181) 4,6-Dinitro-i 2-methylphenol 2-Nitrophenol 73 (19-107) 4-Nitrophenol 55 (10-144)
I Pentachlorophenol 74 (10-122) b Phenol 90 (10-107) 2,4,6-Trichlorophenol 106 (18-118) r?('
La t~
p iM L
1-k.
I}ij Calcutanons are performed before roundmg to avoid round-uff errors in calculated results 4
y a
M
R$ ORT 8
---a Servkrc
.a METALS SPIKE REPORT WATER - ICP j
............. METALS- - - - - - - - - -------
~
SPIKE SPIKE / DUP PERCENT PERCENT
.Q/C RPD PREPARATION-
['
COMPOUND RECOVERY RECOVERY LIMITS RPD LIMITS ANALYSIS DATE W/0#
s Silver 101 96 (61-126) 5 (0-20) 6/02-6/07 95 A4P8 Aluminum 84 86 (56-147) 2 (0-20) 5/22-5/24 95 A4L9 l
Arsenic 95 94 (51-146) 1 (0-20) 5/26-6/01 95 A4LE l J
Boron 90 90 (73-110) 0 (0-20) 3/20-3/24/95 A3EM 7
Barium 100 95 (79-116) 5 (0-20) 6/02-6/07/95 A4P8 Beryllium
'105 100 (76-117) 5 (0-20) 6/02-6/07/95 A4PE Calcium 99 87 (40-146) 13 (0-20) 6/02-6/07/95 A4PE,
Cadmium 106 101 (70-109) 5 (0-30) 6/02-6/07/95 A4PE !
Cobalt 103 98 (75-110) 5 (0-20) 6/02-6/07/95 A498I Chromium 105 101 (74-117) 4 (0-20) 6/02-6/07/95 A4PE '
I Copper 101 97 (77-112) 4 (0-20) 6/02-6/07/95 A4PE L
Iron 98 86 (45-146) 13 (0-20) 6/02-6/07/95 A4PE Potassium 91 85 (67-123) 7 (0-20) 6/02-6/07/95 A4PE e-i Magnesium 99 93 (71-112) 6 (0-20) 6/02-6/07/95 A4PE Manganese 104 97 (57-131) 7 (0-20) 6/02-6/07/95 A4PE Molybdenum 96 96 (90-114) 0 (0-20) 3/20-3/21/95 A3EE i
Sodium 93 95 (40-144) 2 (0-20) 6/02-6/07/95 A4PE Nickel 104 99 (73-109) 5 (0-20) 6/02-6/07/95 A4PE Lead 103 96 (72-114) 7 (0-20) 6/02-6/07/95 A4PEl
[1 Antimony 105 100 (73-112) 5 (0-20) 6/02-6/07/95 AiPE !
n Selenium 97 97 (30-175) 0 (0-20) 5/26-6/01/95 A4Lb Tin 113 104 (73-123) 8 (0-20) 5/22-5/25/95 A4MC L
Strontium 95 90 (83-112) 5 (0-20) 6/05-6/08/95 A 4 0 ', i Titanium 93 94 (80-111) 1 (0-20) 3/20-3/24/95 A3EE l Thallium 95 90 (57-121) 5 (0-20) 6/02-6/07/95 A4PE j Tungsten 90 97 (72-112) 7 (0-20) 3/03-3/06/95 A312 Vanadium 104 98 (79-112) 6 (0-20) 6/02-6/07/95 A4PE 1
d Zinc 100 109 (67-118) 9 (0-20) 6/02-6/07/95 A4PE Osmium 92 98 (80'120) 6 (0-20) 3/16-3/29/95 A395 Lithium 96 96 (80-120) 0 (0-20) 3/22-3/29/95 A3DI J r-
&M Enviromental Servkrs MATRIZ SPIKE REPORT r--> -
I QC BATCH: 5222080 WO #
C08M9 LAB # A5G180127-001 S PREPARATION DATE:
8/10/95 MATRIZ: WATER DATE ANALYZED:
8/10/95
........... Bromide (Titrimetric)
SPIKE SPIKE / DUP PERCENT PERCENT Q/C RPD COMPOUND RECOVERY RECOVERY LIMITS RPD LIMIT Bromide (Titrimetric) 66 69 (68-129) 4.6 (0-20) f.;f
.t2 i..
c.
F l
LS e
Conculauono are performed tiefore roundmg to avoid round-off errors in calculated resuhs a
has
Qhsansterra Driirumnent:1 Servxes MATRIZ SPIKE REPORT WO #
CODXO I.
QC BATCH: 5219030 PREPARATION DATE:
8/07/95 LAB #1 A5G270125-003 S DATE ANALYZED:
8/07/95 MATRIX: WATER f
- - - - - - - - - - Fluoride (Colorimetric, Ion Selective Electrode) i SPIKE SPIKE / DUP PERCENT PERCENT Q/C RPD l
COMPOUND RECOVERY RECOVERY LIMITS RPD LIMIT Fluoride (Colorimetric, 102 101 (61-133) 0.98 (0-33)
.l Ion Selective Electrode) 1 d
I~
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i I
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T~
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.~.
~ - _..
_ -.. _ -.. _ _ -. - -., ~..
hM Dmeranmutal MATRIZ SPIKE REPORT Serras QC BATCH:
5214135 MO # :
C0658 LAB #2 A5G120104-004 S PREPARATION DATE:
8/02/95 MATRIX: WATER DATE ANALYZED:
8/02/95 t
- - - Nitrate-Nitrite - - - -- - -****--****-
SPIKE SPIKE / DUP i
PERCENT PERCENT Q/C RPD 1
COMPOUND RECOVERY RECOVERY LIMITS RPD LIMIT f
Nitrate Nitrite 144 144 (73-121) 0.27 (0-15) i I
T" f
f I
F L..
t..
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i.
t t
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?.
i il, IJ Cakuneuona are performed before roundmg to avond round+ff errors in calcunsted results Y*
'i
$VM
, Envircamental Services HATRIX SPIKE REPORT WO #
COE25 QC BATCH: 5213094 LI LAB #2 A5G270132-003 S PREPARATION DATE:
8/01/95 DATE ANALYZED:
8/02/95 C-MATRIZ: WATER
- - Phosphorus, All Forms (Colorimetric)
SPIKE SPIKE / DUP PERCENT PERCENT Q/C RPD RECOVERY RECOVERY LIMITS RPD LIMIT COMPOUND Total phosphorus 120 122 (22-156) 1.1 (0-63) 1 (Colorimetric)
.F La I
l l
I i
i
( *.1 t*
[,
1 i
'ii.J Cab:ulatmns are performed before roundmg to avoul round-off errors a enleulmied iceds 1
j i
Esmranumtal Sesske2 MATRIZ SPIKE REPORT QC BATCH: 5214107 WO #:
COE22 LAB # A5G270132-001 S PREPARATION DATE:
8/02/95 MATRIX: WATER DATE ANALYZED:
8/02/95 y 4 s
I"
........ - Sulfide -
t SPIKE SPIKE / DUP f
PERCENT PERCENT Q/C RPD j
COMPOUND RECOVERY RECOVERY LIMITS RPD LIMIT Sulfide 72 80 (26-197) 11 (0-11)
I i-s i
(
L_
t' 1
I 5
I I
I.
b-e l
r-Le I,
I!
I' S4 i
d j
'f J
Cckulmuuna are performed before roundag to avoid rowst ol' errors in cak:ulated reauha o-.
kV me
Qhanterra Eminnmental Savias MATRIZ SPIKE REPORT fl QC BATCH:
5216038 WO #
COE25 li LAB #: A5G270132-003 S PREPARATION DATE:
7/27/95 MATRIX: WATER DATE ANALYZED:
7/27/95
- - Sulfite -
SPIKE SPIKE / DUP PERCENT PERCENT Q/C RPD COMPOUND RECOVERY RECOVERY LIMITS RPD LIMIT Sulfite 95 100 (51-121) 5.1 (0-18)
LJ
'?
i 1
1 t'
F L
5 V' f l'
7
?,
.a 1
Cajculauous are performed tefore rounding to avoid roustw>ff errors in calculated results 4
y.,
m
E w_,,ea Sermes MATRIX SPIKE REPORT WO #:
COD 4H QC BATCH: 5209029 PREPARATION DATE:
7/27/95 i
3 LAB #: A5G260109-006 S I
DATE ANALYZED:
7/27/95 MATRIX: WATER 1'
I
- Surfactants (MBAS)
SPIKE SPIKE / DUP PERCENT PERCENT Q/C RPD COMPOUND RECOVERY RECOVERY LIMITS RPD LIMIT Surfactants (MBAS) 105 115 (49-141) 9.2 (0-44) i.]
7..
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r' l
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i L
t i
f II w
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SS Envimannmtal l
Serrues MATRIX SPIKE REPORT i
i MO #:
A53MS l:I QC BATCH: 5194055 1
PREPARATION DATE:
7/13/95 II LAB #: A5F170021-005 S DATE ANALYZED:
7/13/95 MATRIX: WATER t'
~~7..~~
.............. Sulfate -
SPIKE SPIKE / DUP PERCENT PERCENT Q/C RPD
?
RECOVERY RECOVERY LIMITS RPD LIMIT COMPOUND 89 86 (71-119) 3.7 (0-13)
Sulfate
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ML20094H873

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ML20094H873

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