ML20090D403
| ML20090D403 | |
| Person / Time | |
|---|---|
| Site: | Three Mile Island  |
| Issue date: | 10/04/1991 |
| From: | GENERAL PUBLIC UTILITIES CORP. |
| To: | |
| Shared Package | |
| ML20090D391 | List: |
| References | |
| 1104-28I, NUDOCS 9203060187 | |
| Download: ML20090D403 (62) | |
Text
{{#Wiki_filter:- [EiE] Nuclear 0091,,DCO?Y -a , operatino Procedure 1104-28! Revis&on No. Title waste solidification Process control Program 16 Responsible office Applicability / scope Plant Ops. Dir. , TMI-1 Division This docuneent is within QA plan scope _K, Yes _ No Effective Dato Safety Reviews Required X Yes _ No ' _1 ,0/04/91 FLA*.T ENG List of Effective Pages UIslI 1 P*ge * *- 4 g g [tevi s ion, Page, Revision g Po'ision 1.0 16 26.0 15 ES-1 8 20 14 27.0 15 E8-2 9 3.0 14 El-1 15 E8-3 8 4.0 14 El-2 8 E9-1 16 5.0 14 El-3 15 E9-2 16 6.0 14 31-4 16 E9-3 16 7.0 14 E2-1 8 E10-1 8 8.0 14 E2-2 9 E10-2 9 9.0 14 E2-3 7 E10-3 8 10.0 15 E3-1 8 E11-1 16 11.0 15 33-2 8 E11-2 16 12.0 15 E3-3 15 E12-1 9 13.0 15 23-4 16 14.0 15 E4-1 8 15.0 15 14-2 9 16.0 15 24-3 7 17.0 15 25-1 16 18.0 15 E5-2 16 19.0 15 35-3 16 20.0 15 26-1 8 21.0 15 36-2 9 22.0 15 36-3 7 23.0 15 E7-1 16 24.0 15 27-2 16 25.0 15 27-3 16 II signature I concurrino organizational Element i DaU oriainatorll d d b l oriainator l 9 -7(o '4 t concurred ll V C l l ny l%. a b_e00. I Proe.dur. own., 19 16.n ll .. . .- I i ll <2hiv&h~ i - Iu A /9/ ll l l Il l I Approved ll_M l Approver I 9\ 'Sol % \
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sy ll l l 1.0 1372c 9203060187 920302 PDR ADOCK 050002G9 R PDR
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ENu3 fear' Ts1_1 operat ing Prectdure !!O4-28T Revision No. Title l i 14 Weste solidification Preseess Control Progr_am i Table of Contents , fage 5eetion 4.0 1.0 Discuss 1om 4.0 2.O RsFERENCE8 6.0 3.0 DEFINIT 10ms 6.0 4.0 REPORTING R3QUIREMENTS semi Annual Etfluent Report 6.0 4.1 7.0 4.2 Annual Report Waste solidification Hishaps 8.0 4.3 8.0 5.0 LIMITS AND FRSCAUT!0ms 10.0 6.0 TBST SOLIDIFICATION OF 4 TO 10 WTt DORIC ACID (CONCENTMATED Wh875) 10.0 6.1 Prerequisites 10.0 6.2 Procedure 13.0 7.0 TEST SOLIDIFICATION OF > 10 to 20 WTt DORIC ACID (CONCENTRATED WASTE) 13.0 7.1 Prerequisites 14.0 7.2 Procedure 16.0 8.0 TEST SOLIDIFICATION OF WASTE OIL 16.0 8.1 Prerequisites 17.0 8.2 Procedura 18.0 9.0 TRST SOLIDIFICATION OF USSD PRBOOAT 18.0 9.1 Prorsquisites 19.0 9.2 Procedures , 21.0 10.0 TEST SOLIDIFICATION OF BEAD RESIN 10.1 Prerequisites 21.0 22.0 10.2 Procedure 2.0 1372c
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I""""*r MUClear' 131 1 operating Procedure 1104-281 Revision No. Title 14 Waste solidification Preeces Control Program Table of Contente (Cont'd) Page seetion
- 21. 0 11.0 AL!sRMATE TEST sOLIDIP1 CATION PROGRAMS 25.0 11.1 Prerequisites 25.0 11.2 Procedure 26.0 12.0 ACCEPTANCE CRITERIA Class A Unstable and Stable, Class B and C Test El-1 ATTACHMENT 1 solidification Data Sheet for 4 to 10 vtt Boric Acid E2-1 ATTACHMENT 2 Solidification Calculation Sheet for 4 to 10 wtt Boric Acid Class A Unstable and stable, Class B and C Test EJ-1 ATTACHMENT 3 Solidification Data Sheet for > 10 to 20 wt t Boric Acid E4-1 ATTACHMENT 4 Solidification Calculation Sheet for > 10 to 20 wt n Boric Acid Class A Unstable and stable, Class 8 and C Test El-1 ATTACHMENT 5 Solidification Data Sheet for Waste Oil E6-1 ATTACHMENT 6 Solidification Calculation Sheet for Waste Oil Class A Stable, Class B and C Test Solidification E7-1 ATTACHMENT 7 Calculation Sheet for Used Procoat E8-1 ATTACHMENT 8 Solidification Calculation Sheet for Used Procoat Class A Stable, Class B and C Test solidification E9-1 ATTACHMENT 9 Data sheet for Read Rosin E10-1 ATTACHMENT 10 solidification Calculation Sheet for Bead Rosin Test Solidification using Westinghouse - Hittman E11-1 ATTACHMENT 11 Procedure Percent solids of pH Adjusted Waste vs. Water / E12-1 FIGURE 1 coment Ratio 3.0 1372c
Nustaar T,1 1 Operating Procedure 1104-281 __ Revision No. Title Waste solidificatie: Process control Program 14 1.0 Discurston the purpose of the Process Control Program (PCP) for incontainer solidification , is to provide a progr am which will assure a soliditied product with no f ree standing liquid prior to transportation for disposal and which meets the re-quirsaents of 10 CFR 61.56, Waste Characteristies. The PCP's for each vasto streaA included in this psocedure are based on labora-tory testing, the results of which are included in " Topical Report coment solidifiwd Waste to Meet the stability Requirements of 10 CFR 61" prepared by Westinghouse. These PCP's are valid for all liner types using electric or hydraulic mixing heads provided by SEO. The appropriate portions of this document shall be considered complete only when used with the operating procedures (OP 1104-28A for borated and oily wastes or OP 1104-28C for resin) for full scale solidification. This document describes the methodology for determining the acceptable ratto of waste, coment and additive that will result in an acceptable product for transportation and ultimately burial. The solidification Data / Calculation sheets convert these ratios into the recommended quantity of cement and additive that should be mixed with Class A unstable waste and the recommended quantity of coment and additive which must be mised with Class A stable and Class B or C wartes. NOTE: Until regulatory issues are resolved concerning Class B and C waste forms (refer to Reference 2.10), this procedure shall only be utilised to ;*rf orm verification testing of Class A unstable waste forms only.
2.0 REFERENCES
2.1 Westinghouse - Hittman F421-P-004, Process Control Program for Incontainer Solidification of 4 to 20 wtt Boric Acid 2.2 Westinghouse - Hittman STD-P-05-002, Process Control Program for Incon-tainer Solidification of oily Waste 2.3 Westinghouse - Mittman F421-P-006, Process Control Program for Incontainer solidification of Powdered Rosina 2.4 Westinghouse - Hittman F421-P-005, Process Control Program for Incontainer solidification of Class A Unstable or stable, Class B and C Resin at Maximum Packaging Iffictency 2.5 Westinghouse - Hittman STD-A-05-007, Topical Report Coment solidified Waste to Meet the stability Requirements of 10 CTR 61 2.6 Westinghouse - Hittman STD-R-05-011, Topical Report Mobile Incontainer Dewatering and solidification system (KDss) 2.7 NRC Letter from Charles E. Rossi, Assistant Director, Division of PWR Licensing-A to R.J. Leduc, Dir2ctor of Engineering Westinghouse Hittman - 4.0 1372c
MUClear 1H1 1 operating Procedure 1104-28! 88visic" No. Title 14 Waste Solidification ProcJss Control Program
'Ac.eptance of Peferencing of Liconsing Topical Poport STD-R-g5-011, Hitttf an Mobile Inctntattier Downtering and Solidification System (KOSSl",
Dated Oct. 31, 1986. 2.8 GPUN Operational Quality Assvrance Plan 2.9 GPUN Radiation Protection Plan 2.10 Waste Form Technical Position, Rev. 1, dated January 24, 1991 2.11 Generic Letter 91-02, Reporting Hishaps involving LLW Forms Prepared f or Disposal, dated December 28, 1990 3.0 DEFINITIONS 3.1 Process Control Program The PROCESS CONTROL PROGRAM (PCP): A document that. shall contain the current formulas, sampling, analyses, test, and determinations to be made to ensure that processing and packaging of solid radioactive wastes based on demonstrated processing of actual or sLmulated wet solid wastes will be accomplished in such a way as to assure compliance with 10 CPR Parts 20, 61, and 71, state regulations, burial ground requirements, and other requirements governing the dispoent of solid radioactive waste. 3.2 solidification SOLIDIFICATION shall be the conversion of radioactive wastes from liquid treatment systems to a uniformly distributed, monolithic immobilised solid wita definite volume and shape, bounded by a stable surf ace of distinct out *,ine on all sides (f ree-standing) , 3.3 Batch A BATCH is defined as that quantity of waste required to fill a disposal liner to the appropriate level on the waste level indicator. 3.4 operable The solid Radwaste system is operable when it is capable of performing its intended function within the required range of the Process Control Program. The system shall be considered to have the capability when the performance requirements have been met by system operation within the previous 92 days or a vendor is under contract to perform solidificatiou services in accordance with a Process Control Program, 3.5 solid Radwaste 5,y stem The solid Radwaste System comprises the equipment necessary tc solidify liquid or solid (i.e., resin) Radioactive Wastes in accordance with a Process control Program. As a minimum the system includes a disposal liner, mixer head, coment feed system and ventilation. These components are housed in a solidification building adjacent to the TMI 1 Auxiliary S.O 1372c
MUCltar T31 1 operating Procedure 1104-281 Povision No. Title 14 Waste Solidification Process Contro}, Pro,qram Building. Caparate solid Radwaste Systems may also be ured for specif!: purposes as long as they comply with a valid PCP. 4.0 F.EPORTING RB@l!REMEltTS 4.1 Semi Annual Effluent Report 4.1.1 Process Control Program A. Changes to a PCP shall be submitted to the NRC in the Semiannual Radioactive Effluent Release Report for the period in which the changes were made. This submittal shall contains
- 1. sufficiently detailed information to justify the changes without benefit of additional or supplemental information
- 2. a determination that the changes did not reduce the overall conformance of the solidified waste product to existing criteria for solid wastes, and
- 3. documentation that the changes have been reviewed and approved pursuant to T.s. 6.8.2.
B. Changes shall become ef f ective upon review and approval BY GPUNC Hanagement. 4.1.2 Solid Waste Shipments A. The Radioactive Ef fluent Release Reporta shall include the following information for each type of solid waste shipped offsite during the report periode
- 1. Type of waste
- a. Spent resins, filter eludges, evap. bottoms, etc.
- b. Dry compressible waste, contaminated equipment, etc.
- c. Irradiated components, control rode, etc.
- d. Other
- 2. Total volume (cubic meters)
- 3. Total curie quantity
- 4. Principal radionuclides (specify whether determined by measurement or estimate),
6.0 1372c
l l MUClear m .1 _ 11C4;161 operating Procedure _ __ _______ RevAaton No. ; Title 14 ,__Waste Sc11dification Process _gentrol Program :
- 5. Dispesttion of Solid Waste Shipments (i.e., numbar of shipnents to barial, mode of t ransportation, destination)
Disposition of Irradiated fuel shipments (i.e., number , 6. of shipments, mode of transportation, destination) 4.2 Annual Report 4.2.1 Ha}or Changes to Radioactive Waste Treatment Systems A. GPU Nuclear Corporation initiated safety related changes to the solid radioactive waste systems
- 1. Shall be reported to the Commission in the Annual poport (T. S. 6.9.18) for the period in which the evaluation was reviewed. The discussion of each ,
change shall containt
- a. A summary of the evaluation that led to the determination that the change could be made in accordance with 10 CFR $0.59;
- b. sufficient detailed information to totally support the reason for the change without benefit of additional or supplemental informations
- c. A detailed description of the equipment, components and processes involved and the interfaces with other plant systems;
- d. An evaluation of the change which shows the predicted releases of radioactive materials in liquid and gaseous effluents and/or quantity of solid waste that differ from those previously predicted in the license application and amendments thereto;
- e. An evaluation of the change which shows the expected maatsum exposures to individuals in the unrestricted area and to the general population that differ from those previoaaly estimated in the license application and amendments thereto
- f. A comparison of the predicted releases of radioactive-materials, in liquid and gaseous affluente and in solid waste, to the actual releases for the period prior to when the changes are to be mados
- g. An estLaate of the exposure to plant operating personnel as a result of the change; and
- h. Documentation of the fact that the change was reviewed and Opproved.
7.0 1372c
YUClear' w. operat ino Procedure 1304-28!
,_, Fevtston No.
Title 14 daste solidification Process Control Progron _
- 3. shall become effective upon review and approval in accordance with T. s. 6.6.1.
4.3 Waste solidification Mishaps
- 1. THI-1 Licensing shall be notified within 10 working days of any mishaps regarding solidification of Class 8 or C waste forms as followet The production of a solidified class B or c waste forn. that has any of the following characteristics:
. Contains f ree liquid in quantities exceeding 0.5 percent of the volume of the waste.
+ contains waste with radionuelides in concentratione exceeding those considered during waste form qualification testing accepted by the regulatory agency, which could lead to errors in assessment of waste class.
e contains a significantly dif f erent waste loading than that used in qualification testing accepted by the regulatory agency.
- Contains chemical ingrediente not present in qualification testing accepted by the regulatory agency, and those quantities are sufficient to unacceptably degrade the waste product.
e shows instability evidenced by crumbling, cracking, spalling, volds, softening, disintegration, nonhomogeseity, or dimensional changes.
- Evidence of processing phenomena that exceed the limiting processing conditions identified in applicable topical reports on process control plans, e.g., foaming, temperature extremes, premature or slow hardening, and production of volatile material.
2, TMI-1 Licensing shall review each event for determination of voluntary reporting to the NRc's Director of the Division of Low Level waste Management and Decommissioning within 30 days of the incident. 5.0 LIMITS AND PR9CAUTICMS
- 5.1 The PCP shall be used to verify the solidification of at least one l representative test specimen from at least every tenth batch of each type l
of wet radioactive waste (e.g., evaporator bottone, oily waste, resin and l precoat sludge). l 8.0 1372c
MUClear Tm .1 operat ino Procedure 1104-78! < _ , , Revtston No. Title _14 Waste Solidification Process Control Program 5.2 If any test sF*cimen fails to solidify, solidification of the batch under ' test shall be suspended until such time as additional test specimens can to obtained, alternative solidification parameters can be determined in accordance with the Process control Program, and a subsequent test veri-fios solidification. Solidification of the hatch may then be resumed using the alternate solidification parameters determined. 6.3 2f the initial test specimen from a batch of waste f ails to verify solidi-fication then representative test specimens shall be collected from each consecutive batch of the same type of waste until the three (3) consecu-tive initial test specimens demonstrate solidification. The Process Control Program shall be modified as required to assure solidification of subsequent batches of waste. 5.4 Solid Radwaste System 5.4.1 The solid radwaste system shall be demonstrated operable qu arterly. As defined in section 3.4. 5.4.2 The solid radweste system shall be used in accordance with the Process Control Program (PCP) to process wet radioactive wastes to meet shipping and burial ground requirements.
- a. With the provision of the PCP not satisfied, suspend shipments of defectively processed or defectively packaged solid radioactive wastes from the site.
5.5 For high activity wastes, such as spent resin or used precoat, where handling of samples could result in personnel radiation exposures which are inconsistent with the ALARA principle, representative non-radioactive samples will be tested. These samples should be as close to the actual waste physical and chemical properties as possible. Typical expended mixed bed resin shall be used to simulate the spent bead redin and the appropriate mix of anion to cation powdered resin shall be used to simu-late used precoat. 5.6 All Chemicals used to condition or solidify waste or simulated waste in solidification teste shal1~be the actual chemicals used in full scale solidification. 5.7 A Test Solidification Data sheet will be maintained for each test sample solidified. Each Data Sheet will contain pertiner' information of the test test sample. sample and the liner numbers solidified based on t 5.8 samples should be drawn at least six hours prior to the planned full scale waste solidification to allow adequate time to complete the required l testing and verification of solidification for Class A unstable waste. 28 hours should be allowed, if practical, for Class A stable, class 5 and c wastes. 5.9 The tank containing the waste to be solidified should be mixed by recircu-lating the tank contents for at least three volume changes prior to sampling to assure a representative sample. 1 9.0 1372c
Nuclear m.1 Operet ing Pro;edure _ 1,104 78f , Revision No. Title 16 Weste Solidification Process Control ProQram 6.10 An RWP suet be obtained and used for performing test solidtfications of radioactive samples. 6.0 TEST SOLIDIPICATION OF 4 TO 10 WT4 BORIC ACID (ODIBCESITRATED WARTE) 6.1 Prerequisites This pCP Test solidification Procedure is applicable to NOTE: class A Unstable, class A stable, class a and C waste Forms. For the interim, however, refer to section 1.0. 611 A suf ficient oise sample of concentrated waste (appres.1 liter) has been drawn and the following parameters analysed for by Plant chemistrys c
- Soron r
- pH e Total solide e cassoa scan The total solide and ganuna scan are used for information NOTBs purposes only to track waste characteristics and are not to be used in the Process Control Program calculations.
6.1.2 The ops Quality Assurance Group has been contacted to inform them of the pending Test solidification to see if they care to witness the test. 00A Monitor contacted ,,
/ Date / Time Name t
6.1.3 The appropriate portions of Attachment 1 have been completed including waste classification, chemistry information, balance calibration data and the ooquential sample number.' The sample number shall include the year, unit and the next sequential number (i.e., 91.TN!1 01). 6.2 Procedure
.... ......... Tare .............. ..............................................
weights of waste, cement, additives, etc. should be NOT8: , obtained during performance of the following procedure. Round off to the nearest gram. 6.2.1 Calculate the weight percent of soric Acid on Attachment 1. 10.0 1372c . ~ . , . ,. , . .n- .,, , ,. , - - ,,,_,r,,e,- -
,.y.,,-,,.,,7 .m., ~ . , , ---,..,,,,,-,.,,,.,,.,wn-
e k UlNucleaf Txi.1 Orwrating Procedure 1104 28f Revision No. Title _1j Waste Solidification Process Control Program 6.2.2 MEASURE 500 gms of untreated concentrated waste into a container. 6.2.3 RECORD the weight and volume on Attachment 1. 6.2.4 ADD 50 wtt sodium hydroxide (NaOH) to raise the pH between 8 to 8.5 for Class A unstable, Class A stable, B and C solidifica- I tion. If pH is >B.5 then reduce to a range of 8 and 8.6 with ! sulfuric acid. 6.2.$ RECORD the weight of NaOH used and the adjusted pH on Attachment 1. 6.2.6 If large (i.e., foam causing) quantities of detergents are present, TREAT the sample with an anti-foaming agent until the foam disappears. 6.2.7 RECORD the weight of anti-foaming agent used on Attachment 1. 6.2.8 Determine if oil is present by looking for an oli film on the surface of the sample. If oil is present perform the followings el (oil) - mi (total sample) e 100 = n oil
- a. If oil is present in stable waste in a quantity greater than 16 by volume, reduce the quantity of oil to less than it by skimming.
- b. For unstable waste if oil is present and the volume is between 3 and 12% of the volume of waste, TREAT with an emulsifying agent such as Maysol 776 (20% of the volume of oil). 011 in concentrations > 1?) by volume may noc be solidified by this procedure. (Refer to Section 8.0 Test solidification of Waste 011).
NOTE: The density of Maysol 776 is 1.0 g/mli the volume in mi is equal to the weight in grams.
............... v............................................................
I 6.2.9 RB00RD_the % cil and the quantity of any emulsifying agent used l ' on Attachment 1. l 6.2.10 Record the volume and calculate the weight of the treated sampi.e on Attachment 1. l 6.2.11 Calculate the percent solide in the sample by completing items [ (9), (10), (11) and (12) in Section !! of Attachment 1. 6.2.12 For ?,he test solidification of the concentrated waste, seasure , into a mixing vessel 400 ml of pretreated wasta, l l l l 11.0 1372c l
Y ENuclear m! .1 operating Proc- ure 1104-tet Revision No. Title 15 Waste solidification Process Control Program - s
)
Test solidifications should be conducted using a 1.000 ml NOTE: disposable beaker or sLmilar site container.
............................................................................. 1 6.2.13 RECORD the volume AND weight of the treated sample on Attachment 1.
6.2.14 Calculate the water in the sample by completing items (15), (16) and (17) in section !!! of Attachment 1.
)
6.2.15 Using rigure 1 and the percent solids from the Test solidifica. tion Date Sheet, Item (12), DETERMINE the water /coment ratio then CALCVLATE and WEIGH out the required quantity of Portland Type I coment. 6.2.16 RECORD the weight of coment on Attachment 1. 6.2.17 CALCULATE and WEIGH out the required quantity of meteo beads, i.e., anhydrous modium amtssilicate (AEMA), into a separate vessel. 6.2.18 RECORD the weight of ASMS on Attachment 1. 6.2.19 slowly ADD the coment to the test sample while it is being mixed. Mixing should be accomplished by stirring with an electric NOTE: mixing motor with blade or manually with a rigid stirrer until a homogeneous mixture is obtained, approximately one minute. After all the coment is added, slowly ADD the ASM8 to the test 6.2.20 sample while it is being mixed. 6.2.21 After sufficient rtxing (2 minutes after all the ASMS is added) so that a homogeneous mixture is obtained, SEAL the sample and CURI at 120 + 5'r for 24 hours #or Class A stable, Class 5 or C or at room temperature for Class A unstable. NOTE: If at any time during the 24 hour cure, the sample meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be disqualified without at least 24 hours of cure. 6.2.22 Verify the Acceptance criteria (Section 12) has been met and sign and date Attachment 1. If the test solidification fails, refer to section 12.2. Three additional test solidifications must be successfully performed before proceeding. l 12.0 1372c 4 r
MUCl88r rul-1 operating Procedure 1104-287 Revision No. Title 15 Waste Solidification Process control Program 6.2.23 When the Acceptance Criteria has been met per Section 12, calculate the required quantities of cement and additives for the full scale solidification using a liner type applicable for this and waste type (as determined by Radwaste operations Engineering) the Solidification Calculation Sheet for 4 to 10 wtt Boric Acid (Attachment 2). The liner shall be solid $fied using OP 1104-28A, Radio NOTE: active Waste Solidification - SEG. 6.2.24 Complete Section VII of Attachment 2 upon completion of the solidification if coment remains in the hopper. 7.0 TEST SOLIDIFICATION OF > 10 'fC 20 wt% BORIC APID (OONCENTRATED WASTE} 7.1 Prerequis ites
.--...-..-.. -.-.This ......--------...----------.------------..----------.------
PCP Test Solidification Procedure is applicable to NOTE: Class A Unstable, Class A Stable, class B and C Waste Forms. For the interim, however, refer to Section 1.0. 7.1.1 A sufficient size sample of concentrated waste (approx. 1 liter) has been drawn and the following parameters analyzed for by Plant chemistry:
- Boron
- pH
- Total Solide
- Gamma Scan NOTBt *W t.ch rolids and gamma scan are used for information porw e++ only to track waste characteristics and are not to be used in the Process Control Program calculations.
----...---.--.........--...--..........--..--.......------...-.~..--..
7.1.2 The Ops Quality Astarance Group has been contacted to inform them ) of the pending Test Solidification to see if they care to witness the test. l _OQA Monitor Contacted / Date / Time Name l 13.0 1372c 1 1 l
(UClear Tx1 1 c44 rating Proceduro 1104-28! _,, Revision No. Title 15 Waste Solidification Process Control Program 7.1.3 The appropriate portions of Attachment 3 have been completed including waste classification, chemistry information, balance calibration data and the sequential sample number. The sample number shall inclvde the year, unit and the next sequent ial number (i.e., 91-7 mil-01). 7.2 Procedure Tare weights of waste, cement, additives, etc. should be NOTE: obtained during performance of the following procedure. Round off to the nearest gram. 7.2.1 Calculate the weight percent of Boric Acid on Attachment 3. 7.2.2 KEASURE 500 gms of untreated concentrated waste into a container. 7.2.3 RECORD the weight and volume on Attachment 3. 7.2.4 ADD 50 wtt sodium hydroxide (NaOH) to raise the pH between 12 and 12.5. If pH is > 12.5 then reduce to a range of 12 and 12.5 with sulfuric acid. 7.2.5 RECORD the weight of NaOH used and the adjusted pH on Attachment 3. 7.2.6 If large (i.e., foam causing) quantities of detergents are present, TREAT the sample with an anti-foaming agent. 7.2.7 RECORD the weight of anti-foaming agent used on Attachment 3. 7.2.8 Determine if oil is present by looking for an oil film on the surface of the sample. If oil is present perform the followings al (oil) - ml (total cample) x 100 = n oil
- a. If oil is present in stable waste in a quantity greater than 14 by volume, reduce the quantity of oil to less than 1% by skimming.
- b. For unstable waste if oil is present and the volume is between 3 and 12% of the volume of waste, TREAT with an emulsifying agent such as Maysol 776 (20% of the volume of oil). Oil in concentrations > 12% by volume may not be solidified by this procedure. (Refer to Section 8.0 Test solidification of Waste oil).
NOTE The density of Maysol 776 is 1.0 g/ mil the volume in m1 is equal to the weight in grams. 14.0 1372c
MUClear rMI-1 operating Procedure 1104-28I Revision No. Title 15 Wasta Solidification Process control Program 7.2.9 RECORD the % oil and the quantity of any emulsif ying agent used on Attachment 3. 7.2.10 Record the volume and calculate the weight of the treated sample on Attachment 3. 7.2.11 Calculate the percent solide in the sample by completing items (9), (10), (11) and (12) in SectAon II of Attachment 3. 7.2.12 For the test solidification of the concentrated waste, measure into a mixing vessel 400 ml of treated waste.
........._.-._.......____.._. .s.....---.......----...............-..
NOTE: Test solidifications should be conducted using a 1,000 ml disposable beaker or.....---...-------..--.._-.--.---........ simi.ar size container. 3. 7.2.13 RECORD the volume AND weight of the sample on Attachment 7.2.14 Calculate the water in the sample by completing items (15), (16) and (17) in Section III of Attachment 3. 7.2.15 Using Figure 1 and the percent solids from the Test Solidifica. tion Data Sheet, Item (12), DETERMINE the water /coment ratio then CALCULATE and WEIGH out the required quantity of Portland Type I coment. 7.2.16 RECORD the weight of coment on Attachment 3. 7.2.17 CALCULATE and WEIGH out the required quantity of anhydrous sodium metasilicate (ASMS) into a separate vessel. 7.2.18 RECORD the weight of ASMS on Attachment 3. 7.2.19 Slowly ADD the coment to the test sample while it is being mixed. NOTE: Mixing should be accomplished by stirring with an electric mixing motor with blade or manually with a rigid stirrer until a homogeneous mixture is obtained, approximately one minute. 7.2.20 After all the coment is added, slowly ADD the ASMS to the test sample while it is being mixed. 7.2.21 After sufficient mixing (2 minutes after all the ASNS is added) so that a homogeneous mixture is obtained, SEAL the sample and CURE at 120 + 5'r for 24 hours for Class A Stable, Class 8 or C or at room temperature for Class A Unstable. 1372c 15.0
e i l V UJNuclear Tm _1 Operating Procedure 1104-281 Revision No. Title 15 Waste Solidification Process Control Program NOTE: If at any time during the 24 hour cure, the sample meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be dis. qualified without at least 24 hours of cure. ___ ....__.......__...___.....__...--_......-~______.__..___.....__.......____ 7.2.22 Verify the Acceptance Criteria (Section 12) has been met and sign If the test solidification fails, refer and date Attactanent 3. to Section 12.2. Three additional test solidifications must be successfully performed before proceeding. 7.2.23 When the Actoptance Criteria han been met per Section 12 calculate the required quantities of cement and additives for the full scale solidification using a liner type applicable for this znd waste type (as determined by Radweste Operations Engineering) the Solidification Calculation Sheet for > 10 to 20 wtt Boric Acid (Attachment 4). NOTE: The liner shall be solidified using OP 1104-28A, Radioactive Waste solidification - SEG. 7.2.24 Complete Section VII of Attachment 4 upon completion of the solidification if coment remains in the hopper. 8.0 TRST SOLIDIFICATIOGI OF WASTE OIL (12 - 40% Oil) 8.1 Prerequisites NOTE: This PCP Test Solidification Procedure is applicable to class A Unstable, Class A Stable, Class B and C waste focus. For the interim, however, ref er to Section 1.0. 8.1.1 A sufficient size sample (approx. 500 mi.) each of pH adjusted concentrated waste and waste oil have been drawn. NOTE: The pH of the concentrated waste will be adjusted in the tank before the test solidification. 8.1.2 The Ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test. OQA Monitor Contacted Name / Date / Ti.me 16.0 1372c
- - - - - _ _ _ - _ - _ _ - _ _ _ _ _ _ _ _ - _ _ _ _ _ _ _ ~ - -- __
MUClear ' Tx1 1 Operating Procedure 1104-28I Revision No. Title 15 Waste Solidification Process Control Program 8.1.3 A sample number has been assigned to the test and included on Attachment 5. The sample number chall include the year, unit and the next sequential number (i.e. , 91-THIl-01) . 8.1.4 A determination has been made as to the waste class of the pending full scale solidification by Radwaste Ops. Engineering. 8.1.5 The balance calibration data has been included on Attachment 5. 8.2 Procedure Tare weights of waste, coment, additives, etc. should be NOTE: obtained during performance of the following procedure. Round off to the nearest gram. 8.2.1 Measure into a mixing vessel 210 m1 of concentrated waste and 140 ml oil. Test solidifications should be conducted using a 1000 ml NOTE: disposable beaker or similar size container. 8.2.2 Record the waste volumes added and calculate the percent oil by volume on Attachment 5. 8.2.3 MEASURE ouc 28.0 ml (28.0 gms) of Maysol 776. 8.2.4 RECORD the quantity of the emulsifier on Attachment 5. 8.2.5 ADD the Maysol 776 to the waste and mix until a homogeneous mixture is obtained, at least five (5) minutes. NOTE: Mixing should be accomplished by stirring with an electric mixer with blade or manually with a rigid stirrer. Any signs of pure oil may be an indication that the emulsion is breaking down. Should this occur, contact Radwaste ope. Engineering for further instructions. 8.2.6 If large (i.e., foam causing) quantities of detergents are present, treat, the sample with anti-foaming agent until the foam disappears. 8.2.7 Record the amount of anti-foaming agent used on Attachment 5. 8.2.8 MEASURE out 447.3 gas of Portland Type I cement and 51.8 gas of ! anhydrous sodium metasilicate (ASMS). i 8.2.9 RECORD the quantities of coment and ASMS on Attachment 5. l 17.0 1372c
MUClear TMr-1 operatino Procedure 1104-28I Revision No. Title 15 Waste solidifiestion Process control Program 8.2.10 Slowly ADD the cement to the test sample while it is being mixed and mix until a homogeneous mixture is obtained but in no case less than one (1) mis.ute. 0.2.11 After all the cement is added, slowly ADD the ASMS to the test sample while it is being mixed. 8.2.12 MIX for two (2) minutes after all the ASMS is added and homo-geneous mixture is obtained. 8.2.13 seal the sample and cure at 120 + 5'T for 24 hours for Class A Stable, class B or C or at room temperature for class A Unstable. If at anytime during the 24-hour cura time, the sample NOTE: meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be disqualified without at least 24 hours of cure. 8.2.14 Verify the Acceptance criteria (Section 12.0) has been met and If the tear colidification fails, sign and date Attachment 5. refer to Section 12.2. Three additional test solidificatione must be successfully performed before proceeding. 8.2.15 When the Acceptancs. Criteria has been met per Section 12, calculate the required quantities of coment and additives for the full scale solidification using a liner type applicable for this and waste type (as determined by Radwaste Operations Engineering) the Solidification calculation Sheet for Waste oil (Attachment 6). The liner shall be solidified using CP 1104-28A, _ Radioactive NOTE: Waste solidification - SEG. 9.0 TEST SOLIDIFICATICE OF USED P m T 9.1 Prerequisites [ NOTE: Thie PCP Test Solidification Procedure is applicable to class A Stable, Class 5 and C Waste Forme. For the interim, however, refer to section 1.0. l 1372c 18.0
MUCl68r TH1 1 operating Procedure 1104 28I Revision No. Title 15 Waste Solidifiestion Process control Program 9.1.1 A sufficient site sample of used precoat (approx. 500 ml) has been drawn and the following parameters analysed for by Plant Chemistrys e pH (of sluice water)
+ camma scan NOTE Where high activity waste could pose personnel radiation solidification, exposure problems when performing the test expended powdex with an appropriate anion / cation ratio shall be substituted. The ratio shall be determined by Radwaste operations Engineering. A small sample of use precoat
(- 20 mis) shall be taken for isotopic analysis. NOTE: The gamma scan is to be used for information purposes only to track waste characteristics and is not to be used in the PCP calculations. 9.1.2 The sample has set to verify < It oil by volume. 9,1.3 The Ops Quality Assurance Group has been contacted to inform them of the pending Test solidification to see if they care to witness the test. OQA Monitor contacted Name / Date / Time 9.1.4 The appropriate portions of Attachment 7 have been completed including the balance calibration data and the sample number. The sample number shall include the year, unit and.the next sequential number (i.e., 91.THIl-01). 9.2 Procedure NOTE: Tare weights of waste, cement, additives, etc. should be obtained during performance of the following procedure. Round off to the nearest gram. 9.2.1 MEASURE out 381.1 gas of dowatered powdered resin and 151.5 gma of water and place into separate containers. NOTE: Test solidification should be conducted using a 1,000 ml disposable beaker or similar size container. 19.0 1372c
_ - _ . _ . . _ . .__ m_.- . _ _ - . _ . . _ _ . . . __ _ . . _ __ _ l
""*"" )
ENuclear THl.1 operating Procedure 1104-28I Paviston No. Title 15 Waste solidification Process Control Program 9.2.2 RECORD the volume and weight of the powered resin on Attachment 7. 9.2.3 ADD the water to the powered resin and RECORD the weight of water added and the total volume of waste slurry (water plus resin) on Attachment 7. 9.2.4 If any foam is present, TREAT the sample with an anti-foaming agent. 9.2.5 RECORD the quantity of anti-foaming agent used on Attachment 7. 9.2.6 Determine if oil is present by looking for an oil film on the surface of the sample. If oil is present perform the followings ml (total sample) x 100 = % 0.1 el (011) -
- a. If oil is present and the volume is between 3 and 12% of the volume of waste, TREAT with an emulsifying agent such as Haysol 776 (20% of the volume of oil). Oil in concentrations > 12% by volume may not be rolidified by this procedure. Contact Radwaste Operations Engineering for guidance.
The density of Haysol 776 is 1.0 gm/ml; the volume in NOTE: ml is equal to the weight in gas. 9.2.7 RECORD the quantity of oil present and the amount of Haysol added to the sample on Attachment 7. 9.2.8 RECORD the initial pH of the sample on Attachment 7. 9.2.9 HEASURI out approximately 10 grams of calcium hydroxide Ca(OH) , also known as hydrated lime. 9.2.10 Slowly ADD the calcium hydroxide to the powdered resin elurry, two (2) grams at a time. MIE for three (3) minutes between additions until the pH is at least 11.5. ADD an additional three (3) grams of calcium hydroxide. This final addition may or may not alter the pH of the slurry. h0TE: Mixing should be accomplished by stirring with an electric mixing motor with blade or manually with a rigid stirrer until a homogeneous mixture is obtained approximately one (1) minute. ...................._ .._.......... 9.2.11 RECORD the quantity of calcium hydroxide added to the slurry and the final pH.on Attachment 7. 20.0 1372c
Nuclear Tx1 1 operating Procedure 1104-28I Revision No. Title 15 Waste Solidification Process control Program 9.2.12 KEASURE out 444 gma of Portland Type 1 cement. 9.2.13 RECORD the amount of cement on Attachment 7. 9.2.14 Slowly ADD the cement to the test sample while it is being mixed. 9.2.15 MIX for two (2) minutes after all the cement is added to obtain a homogeneous mixture. 9.2.16 RECORD the final sample volume on Attachment 7. 9.2.17 Seal and allow the sample to CURE for 24 hours at 120 + 5'F. NOTE: If at anytime during the 24-hour cure time, the sample ments the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be dis-qualified without at least 24 hours of cure. 9.2.10 Verify the acceptance criteria (Section 12.0) has been met, sign and date Attachment 7. If the test solidification fails, refer to Section 12.2. Three additional test solidifications must be successfully performed before proceeding. 9.2.19 When the Acceptance Critaria has been met per Section 12, calculate the required quantities of coment and additives using a liner type applicable for this waste type (as determined by Radwaste Operations Engineering) and the Solidification Calcula-tion Sheet for Used Precoat (Attachment 8). NOTE: The liner shall be solidified using CP 1104-28C, Primary Rosin and Precoat Processing - SEC. 10.0 TssT SOLIDIFIC&TIcel OF BEAD RESIN 10.1 Prerequisites NOTE This PCP Test Solidification Procedure is applicable to Class A Stable, Class a and C waste Forms. For the interim, however, refer to section 1.0. 10.1.1 A sufficient site sample of bead resin (approx. 500 mi) has been drawn and the following parameters analyzed for by Plant Chemis-try:
- pH (of sluice water)
- Camma Scan 21.0 1372c
MUClear Tur.1 Operating Procedure 1104-261 Revision No. Title 15 Waste Solidification Process Control Program Where high activity waste could pose personnel radiation NOTE: solidification, exposure problems when performing the test expended non-radicactive resin shall be substituted. The source of this resin shall be determined by Radwaste Operattens Engineering. A small vample of spent resin (= 20 mis) shall be taken for isotopic analysis.
..........c,.......c..__.._....... ..._..........._..........................
NOTE: The gamma scan is to be used for information purposes only to track waste characteristics and is not to be used in the PCP calculations. 10.1.2 The sample has set to verify $ It oil by volume. 10.1.3 The Ops Quality Assurance Group has been contacted to inform them if the pending Test Solidification to see if they care to witness the test. 00A Monitor Contacted / Date / Time Name 10.1.4 The appropriate portions of Attachment 9 have been completed including the balance calibration data and the sample number. The sample number shall include the year, unit and the next sequential number (i.e., 91-Tx!1-01). 10.2 Procedure Tare weights of waste, coment, additives, etc. should be NOTE: obtained during performance of the following procedure. Round off to the-nearest gram. 10.2 1 MEASURE into a mixing vessel 240 gm of dewatered resin. DOTE: Test solide.fication should be conducted using a 1,000 ml disposable beaker or similar size container. NOTE: Tap the beaker gently to consolidate the resin prior to l measuring the volume. 22.0 1372c
ENuclear' Tsi 1 Operating Procedure 1104-281 Revision No. Title 15 Waste solidification Process Control Program RECORD the weight d volume of the sample (resin and water) on 10.2.2 Attachment 9. 10.2.3 WEIGH out 2.1 gma of EC-3 into a separate vessel. 10.2.4 RECORD the weight of EC-3 on Attachment 9. 10.2.5 WEIGH out 84.3 gas of water and record the weight on Attachment 9. 10.2.6 ADD the water to the vessel containing the EC-3 and mix thoroughly. 10.2.7 ADD the water /EC-3 mixture to the bead resin and mix thoroughly. 10.2.8 If any foam is present, TREAT the sample with an anti-foaming agent. 10.2.9 RECORD the quantity of anti-foaming agent used on Attachment 9. 10.2.10 Determine if oil is present by looking for an oil film on the surf ace of the sample. If oil is present perform the followings al (oil) - ml (total sample) x 100 = t oil
- a. If oil is present and the volume is between 3 and 12% of the volume of waste, TREAT with an emulsifying agent such as Maysol 776 (20* of the volume of oil). Oil in concentrations > 124 by volume may not be solidified by this procedure. Contact Radwaste Operations Engineering for guidance.
NOTE: The density of Maysol 776 is 1.0 gm/ml; the volume in mi is equal to the weight in gas. 10.2.11 REOORD the quantity of oil and the volume of emulsifier used on Attachment 9. 10.2.12 REOORD the initial sample pH on Attachment 9. 10.2.13 NEASURE out approximately 11.5 gas of Calcium Hydroxide Ca(OH) , also known as hydrated lime. 23.0 1372c
I (UClear THI-l Operating Procedure 1104-28I Revision No.
~ Title 15 Weste Solidification Process Control Program a
10.2.14 Slowly ADD the Ca(OH), to the resin sample two (2) grams at t ime . Mix for three (3) minutes ADD between additions until the pH three (3) additional gma of of the slurry is at least 11.5. Ca(OH)2 This final additional may or may not alter the pH of the slurry. 10.2.15 RECORD the quantity of calcium hydroxide added to the slurry and the final pH on Attachment 9. 10.2.16 MEASURE out 178.2 gms of Portland Type I cement into a separate vessel. 10.2.17 RECORD the weight of the cement on Attachment 9. 10.2.18 Slowly ADD the cement to the test sample while it is being mixed. 10.2.19 MIX for two (2) minutes after all the coment is added to obtain a homogeneous mix. 10.2.20 RECORD the final sample volume on Attachment 9. 10.2.21 SEAL the sample and allow the sample to CURE for 24 hours a* 120
+ 5'F.
If at anytime during the 24-hour cure time, the sample NOTE: meets the acceptance criteria, the liner solidification may proceed. However, no test solidification shall be dis-qualified without at least 24 hours of cure. 10.2.22 VERIFY the acceptance criteria (Section 12) has been met, sign and date Attachment 9. If the test solidification fails, refer to 12.2. Three additional test solidifications must be successfully performed before proceeding. 10.2.23 when the Acceptance Criteria has been met per Section 12.0, CALCULATE the required quantities of cement and additives using a liner type applicable for this waste type (as determined by Radweste Operar'ons Engineering) and the Solidification Calcula-tion Sheet for Eead Resin (Attachment 10). The liner shall be solidified using OP 1104-28C, Primary NOTE: Rosin and Precoat Processing - SEG. 24.0 1372c
7
""*'*" l MUClear THz.1 Operatino Procedure 1104 28I Revision No.
Title 15 Waste solidification Process control Program 11.0 ALTERNATE Test soLIDIFICATIcer PROGRAM 8 The PCP Test solidification presented in this procedure NOTE: should cover the majority of the waste processing require-ments of THI-1. In the event a different waste stream requires processing or a waste stream covered by this procedure but not having the appropriate waste form or liner type, a PCP Test solidification can be performed using a current procedure provided by Westinghouse . SEG. For the interim, any alternate procedures utilized shall be for unstable' waste forms only. l 11.1 Prerequisites 11.1.1 A procedure is available for the particular waste stream to be processed. 11.1.2 This procedure has been verified current by the Radwaste Ops. Manager or his designee and will be reviewed by the Radweste Engineer prior to its use. 11.1.3 The sample required by this procedure has been obtained and applicable chemistry parameters analyzed for by Plant chemistry. Applicable sample results have been included on Attachment 11. 11.1.4 The ops Quality Assurance Group has been contacted to inform them of the pending Test Solidification to see if they care to witness the test. OQA Monitor contacted Name / Date / Time 11.1.5 Balance calibration data has been included on Attachment 11. 11.1.6- Attachment 11 has been completed. N_0_TE,3 The sample number shall include the year, unit and the next oequential number (i.e., 91-TMIl.01). 11.2 Procedure 11.2.1 Performed the applicable portions of the Westinghouse - SEG procedure. 11.2.2 Verify acceptability of the test solidification per section 12.0. If the test solidification fails consult the guidance
.given in the governing procedure. Three additional test solidifications must be successfully performad before proceeding.
25.0 1372c
MUClear Tx1 1 Operating Procedure 1104-281 Revision No. Title 15 Waste solidification Process Control Program 11.2.3 GPUN management shall verify all calculations and document such on Attachment 11. 12.0 AOC'EPTANCE CRITERIA 12.1 Solidt Tication Acceptability 12.1.1 The sample solidification is considered acceptable if there is not visual or drainable free water. 12.1.2 The sample solidification is considered acceptable if it resists penetration. Physical examination shall be for resistance to a ten (10) NOTE: pound load applied to the surface of the solidified product using a 1/2 inch diameter metal rod. The solidification shall be considered acceptable if the metal probe cannot break the surface and penetrate to the sample core. Normal denting of the surf ace is acceptable. The rod tolerances are as follows:
+1 lb Weight 10 lbs -O lb
+O in Diameter 1/2 inch -1/4 1:
........ .....................................m~............................
12.2 solidification Unacceptubility 12.2.1 If the waste fails any of the criteria set f orth in Section 12.1 the solidification will be termed unacceptable and a new set of solidification parameters will need to be established under the procedures in Section 12.3. 12.2.2 If the test solidification is unacceptable then a modified test procedure (per 12.3) must be followed on a batch of the same type-of waste until three consecutive test samples are solidified. The next sequential sample number shall be assigned with the addition of an alpha designator (i.e., 91-TMIl-OLA,3 and C) to identify the three independent test solidifications. 12.3 Alternate Solidification Parameters 12.3.1 If a test sample for clase A unstable waste fails to provide acceptable solidification of waste the following procedures should be followed.
- a. Mix 454.5 gas of coment and 45.5 gms of ASMS with 400 mis of water to ensure that the problem is not a bad batch of coment.
I t 26.0 1372c
. -1 EDNuclear Tx1-1 Operating Procedu n 1104-28!
Revision No. Title 15 Waste solidification Process control Program
- b. Add additional 50 wt.t NaOH to raise the pH above 8 but less than 9.2 for borated wastes.
- c. If the waste (other than waste oil bead and precoat resin) is only partially solidified, use lower waste to cement and Metso ratios. Using the recommended quantities of coment and Metso Beads, reduce the waste sample to 375 mi and continue reducing the sample volume by 25 ml. until the acceptability criteria of Section 12.1 are met.
- d. If the waste oil mixture is only partially solidified try using lower waste to coment ratios. Aeduce the quantity of waste by 25 ml. and the emulsifier by 1 mi., (This will result in a slightly higher concentration of emulsifier in the waste) and proceed with the test solidification.
Continue with similar reductions until a satisfactory product is achieved. 12.3.2 For test solidifications performed under section 11.0, consult the guidance contained within the governing procedure for alternate solidification parameters. 12.3.3 For class A stable, class a and c want s test samples that fail to solidify, Contact Radwaste operations Engineering for resolu-tion. 27.0 1372c
Nuclear m .1 Operating Procedure 1104-28! Revision No. Title 15 Waste Solidification Process control Program ATTACfD(ENT 1 Page 1 of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET FOR 4 TO 10 WTl BORIC ACID Chemistry Parameters Balance Cal. Info. Liner No.: Sample Date CMTE No. Sample No.: ppm Serial No. Dates Boron Cal. Due Date Waste Class Total Solida ppm pH Total Act. _ mci /cc I. PRECONDITIONING: Weight Percent of Boric Acid (in decimal form): Boron (ppm) x .01 ( ) x .01 1748 = 1748 = (1) gas (2) Weight of Untreated Samples Volume of Untreated Samples mis (3) Weight of 50% NaOH Added to Adjust pH gms (4) within range per Section 4.2.4. pH of treated sample: gas (5) Weight of Anti-fc.na Added
% 0111 :
Weight of amuleifLer Added: gas (6) Volume of treated samples mis (7) Weight of treated samples (2) + (4) + (5) + (6) = { }+( )+( )+( )= gas (8) L l El-1 1372C I i
Nuclear TWi-t Operating Procedure 1104-281 Title- Revision No. Waste Solidification Process Control Program B ATTACHMENT 1 (Cont'd) Page 2 of 4
!!. OETERMINAT!0N OF PERCENT SOLIDS OF SAMPLE:
Weight of Boric Acid in Untreated Sample: l (2) x -(1) .(- ) x( ) . gms (9) Weight of 50% NaOH: (4) x 0.5 . ( ) x 0.5 a gms (10) Weight of Solids-in Treated Sample: (5) + (6) + (9) + (10) . . ( ) + (. - ) +'( )+( )- gms (11) Percent Solids in Treated Sample: , 100 x (11) + ((8)) - 100 x ( ) +- (( )) . % '(12) 111. DETERMINATION OF WATER IN SAMPLE FOR SOLIO!FICATION: Volume of Treated Sample to be Solidified ml (13)- , Weight of-Treated Sample to be Solidified: gms (14) Weight of Water.in Sample Contributed by Waste:
^
I2) x (14) x (1 - (1)) .
,( 8) ' .
L_). x ( = ) x (1 - ( )) - gms (15) J) . Weight of Water in Sample Contributed By 50% NaOH: (4) x (14) x 0. 5 = . (8) . ( ) x- ( ) x 0.5 - gms .(16)' ( -)- ,
-Total Weight of Water in Sample:
(15) + (16) -( )+(). gms .(17) El-2 1372c
Nutrbor ; a (UClear rxI.1 Operating Procedure 1104-28I Revision No. Title 15 Waste Solidification Process Control Procram
\
(Cont'd) Page 3 of 4 ATTACHKENT 1 IV. DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENT AND METSO BE SAMPLE SOLIDIFICATION: and DETERMINE Using Figure I, find the % solids in sample (12), (18) the Water / Cement Ratio Weigh' of Coment to Uses
=
(17) = { } gms (19) (la) ( ) Weight of Metso Beads to uses gms (20) (19) x 0.15 = ( ) x 0.15 = Test solidification Performed By: Date Time flem V. SAMPLE INSPECTION Sample cured for Hours Cured Temp. Cured ___ Sample contains "No Free Liquid":
~
Date Verified By Sample " Resists Penetration": Verified By Date The test-sample'has met the acceptance criteria of Section 12.1: Yes No (Circle one) Name Date Time NOTE: If the test solidification falla refer to Section 12.2 for guidance. El-3 1372C
l 1 4UCI8ar yx1 1 operating Procedure 1104-281 Title Revision No. waste solidification Process control Program 16 i ATTACHMENT 1 (Cont'd) Page 4 of 4 consnents associated with any Test solidification Failures If the previous Test solidification failed, have three (3) consecutive tests been successfully completed? Yes No (Circle one) Additional batches solidified based on this sample solidifications Liner Waste Liner Waste Liner wasta No. Vol. Date No. Vol. Date No. Vol. Date
- 2. 5. 8.
- 3. 6. 9.
4, 7. 10. FOOTNOTES:
- 1. Maximum allowable oil content for stable waste is 14 by volume.
VI. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT Test sample Meets Acceptance Criteria (Section 12) Name / Date / Time Test solidification Data Sheets (Calculations) Reviewed Name / Date / Time El-4 1372C
Nuclear 1Mi-i Operattnq Procedure 1104-281 Title Revision No. Waste Solidification Process Control Program 8 ATTACHMENT 2 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR 4 TO 10 Wit BORIC ACID Liner Type to be used I. Volume of Untreated Haste to Add to Linerl.3: (3) Max. Treated Haste Vol. ITI x from Solidification Data Tables - ( ) ( ) x - ft3 (21) II. Volume of Additives to Add to Liner: Na0H: (4) x 4.86 x (21) - ( ) x 4.86 x( ) - gals (22) (3) () Anti-foam: (5) x 7.48 x (21) =( ) x 7.48 m( ) - gals (23) (3) () Emulsifier: (6) x 7.48 x (21) - ( ) s 7.48 x( )- :1 5 (24) (3) () III. Volume of Treated Waste to be Solidifiedi : (22) + (23) + (24) ()+( )+( ) (21) + 7.48 - ( )+ 7.48 - ft3 (25) IV. Cement Quantity for full Scale Solidtftcation: (19) x 62.4 x (25) -( ) x 62.4 x ( ) - Ibs (26) (13) ( ) (26) + 94 - ( ) + 94 - bags 2 V. ASHS Quantity for full Scale Solidification: (26) x .15 - ( ) x .15 - lbs (27) (27) + 100 - ( ) + 100 - bags 2 E2-1 1372c
- }
i MUClear TMt.i : Operating. Procedure It04 25! l' , Title Revision No. Waste Solidification Process Control Program 9 : ATTACHMENT 2 Page 2 of 3 VI. INDEPENDENT _ VERIFICATION BY GPUN MANAGEMENT ; SOLIDIFICATION. CALCULATION SHEETS REVIEHED . Name / Date / Time , i FOOTNOTES- : i I The volume of-treated waste to be solidified In a single liner cannot exceed the ! maximum treated waste volume listed on the attached Solidification Data Tables. ! 2 Round offfup to the near9tt whole bag. 3 Use the actual waste volume added to the liner in Steps / Equations 22, 23 and 24 , if the waste volume added-to the liner is less than the value obtained in Step / Equation 21. - VII.-DETERMINATION Of_THE QUANTITY OF CEMENT A00E0 TO WASTE: Quantity of_ Cement Added to Hopper: Ibs (28)
. Quantity of Cement Left in Hopper: lbs -(29) ,
. Quantity of Cement Added per ft.3 Waste:
(28) .-(29) - (- ) --( ) - lbi cement /
-(25) ( ) ft3 waste
- NOTE: ~ Minimum Quantity of Cement Allowable for 4 to 10 Ht.- %
Boric Acid Class A Unstable Waste is 62 lbs./ft.3 For Stable waste solidifications all the cement must be added to the liner. Quantity of-Cement Added Meets Minimum Requirements for unstable waste forms: Vertfled_8y-- Date The recommended minimum treated waste-volume and minimum solidtfled waste volume meet the requirements of the Solidification Data Tables for STABLE waste forms. L Verified By- Date l l E2-2 1372c l l l
0 MUClear Tsi-i Operating Procedure 1104-28! Title Revision No. Haste Solidification Process Control Program 7 ATTACHMENT 2 (Cont'd) Page 3 of 3 SOLIO!FICATION DATA TABLES FOR 4 TO 10 WT% BORIC ACIO HN-100 HN 100 LVH Series 3 Series 31 Usable Liner Vol. (cu. ft.) 141.1 157.5 Max. Treated Waste Vol. (cu. ft.) 104.4 116.6 Max. Solidified Waste 141.1 157.5 Vol. (cu. ft.) Recommended Min. Treated Waste Vol. 98.1 103.8 (cu ft)2 Min. Solidifigd Waste Vol (cu. ft)' 132.6 140.2 Max. Rad. Level 12 12 R/hr Contact 1, For less than A2 quantities of LSA waste. For greater than A2 quantitles of LSA waste, the maximum treated waste volume is 112.4 cu. ft. due to neight limitations.
- 2. These minimums are required when shipping to Barnwell, to comply with the 15%
maximum void space criteria for liners containing solidified stable waste forms. E2-3 1372c
Nuclear Tsi i ODerating Procedure 1104_28! _ Title Revision No. q I Waste Solidification Process Control Program 8 ATTACHMENT 3 Page I of 4 CLASS A UNSTABLE AND STABLE, CLASS B AND C TEST SOLIDIFICATION DATA SHEET > 10 TO 20 HT1 BORIC ACID Chemistry Parameters Balance Cal, Info. Liner No.: Sample Date CMTE No. Sample No.: Boron ppm Serial No. Date: Total Solids ppm Cal. Due Date Haste Class pH Total Act. pC1/cc
!. PRECONDITIONING Weight Percent of Boric Acid (in decimal form):
Boron (ppm) x .01 ( ) x .01 - (1) 1748- = 1748 Weight of Untreated Sample: gms (2) Volume of Untreated Sample: mis (3) Weight of 50% NaOH Added-to Adjust pH per Section 5.2,4: gms (4) pH of_ treated sample:- Weight of Anti-foam Added: gms (5)
- % 0111: %
Weight of. Emulsifier Added:- gms (6) Volume of treated sample: mis (7) Weight of treated sample: (2)'+ (4) + (5) + (6) - ( )+( )+( )+( ). gms (8)- l , E3-1 1372c
- --- -v-.--- , e- ,,..w% ,,wo ,%..,.,,p.,,_,_w,,,L ,,,,.,_,.y__.,.,,,,p.,,,,.7,,,m.,m,,,7 _ g,- _,.n, ,y,,,,,%, , , , , ,,_,g
1 Number D- UlNuclear THi-i Operating Procedure 1104-281 Title Revision No. Waste Solidification Process Control Program 8 ATTACHMENT 3 (Cont'd) Page 2 of 4 !!. DETERMINATION OF PERCENT SOLIOS OF SAMPLE Height of Boric Acid in Untreated Sample (2) x (1) .( ) x ( ) . gms (9) Weight of 50% NaOH: (4) x 0.5 - ( ) x 0.5 gms (10) Height of Solids in Treated Sample: (5) + (6) + (9) + (10) - ( )+( )+( )+( ) . gms (11) Percent Solids in Treated Sample: 100 x (11) + ((8)] = 100 m ( )+(( )) - T. (12) III. DETERMINATION OF WATER IN SAMPLE FOR SOLIDIFICATION: Volume of Trented Sample to be Solidified: ml (13) Height of Treated Sample to be Solidified: gms (14) Height of Hater in Sample Contributed by Haste:
~
12_) x (14)' x (1 - (1)) -
,( 8) ,
~
1_). x( ) x (1 - ( )) - gms (15) () Height of Hater in Sample Contributed by 501 NaOH:
'i4l x (14) x 0.5 - '( ) x ( )' x 0.5 - gms (16)
( ( ) _ 8) , , , Total Height of Hater in Sample: (15) + (16) - ( ) +( )- gms (17) E3-2 1372c
~. .. . ~ . . . . - . . . . - = . , - - - - - . - . - - . .- ..- - --. . _ .
NI THI-1 Operating Procedure 1104-2BI Revision No. Title 15 Waste Solidification Proessa Control Program Page 3 of 4 ATTACHMENT 3 (Cont'd) IV. DETERMINATION OF QUANTITY OF PORTLAND TYPE I CEMENT AND METSO BEADS T SAMPLE SOLIDIFICATION Using Figure I, find the % solide in earnple (12), and DETERMINE (18) the Water /Coment Ratio Weight of Coment to Uses (17) ( ) gma (19)
= ) =
(18) ( Weight of Metso Beads to uses gms (20) (19) x 0.15 = ( ) x 0.15 = Test solidification Performed By: Date Time Name V. ~ SAMPLE INSPECTION Sample cured for Hours-Cured Temp. Cured Sample contains "No Free Liquid": Verified By Date Sample " Resists Penetration": Verified By Date The test sample has met the acceptance criteria of Section 12.1: Yee No (Circle one) Name Date Time NOTE: If the test solidification fails refer to Section 12.2 for guidancs, E3-3 1372c
Nu21 ear ,, _1 Operating Procedure 1104-281-Title Revision No. Waste solidification Process control Program 16 ATTAC} DENT 3 (Cont'd) Page 4 of 4 Coments associated with any Test solidification Tailures If the previous Test solidification failed, have three (3) consecutive tests been successfully coa:pleted? Yes No (Circle one) Additional batches solidified based on this saeple solidification Liner Waste Liner Waste Liner Wasta No. Vol. Date No. Vol. Date No. Vol. Date
- 2. 5. 8.
- 3. 6. 9.
- 4. 7. 10.
TOOTNOTES:
- 1. Nazimum allowable oil content for Stable Waste is 1% by volume.
IV. INDEPENDENT VRiUFICATION BY GPUN MANAGEMENT Test Sample Meets Acceptance criteria (Section 12) -Name / Date / Time Test solidification Data sheets (Calculations) Reviewed Name / Date / Time l l l l I E3-4 1372c l
Number [r ti lNuclear Tst-i Operating Procedure 1104-2BI _ _ _ , Title Revision No. Waste Solidification Process Control Program 8 ATTACHMENT 4 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR > 10 TO 20 Wit BORIC AC10 Liner type to be used I. Volume of Untreated Haste to Add to Liner1 ,3: (3) Max. Treated Waste Vol. [7I x from Solidification Data Tables - ( ) ( ) * ,
- ft3 (21)
II. Volume of Additives to Add to Liner: NaOH: (4) x 4.86 x (21) - ( ) x 4.86 x( ) - gals (22) (3) ( ) Anti-foam: (5) x 7.48 x (21) -( ) r 7.48 x( ) - gals (23) (3) ( ) Emulsifier: (6) x 7.48 x (21) - ( ) x 7.48 x( ) - gals (24) (3) ( ) l III. Volume of Treated Waste to be Solidifiedi : (22) + (23) + (24) ( ) +( ) + ( ) (21) + 7.48 - ( )+ 7.48 - ft3 (25) IV. Cement Quantity for full Scale Solidification: (19) x 62.4 x (25) = ( ) x 62.4 x ( ) - lbs (26) (13) ( ) l (26) + 94 - ( ) 94 - bags 2 V. ASHS Quantity for Full Scale Solidification: (26) x .15 - ( ) x .15 - lbs (27) i (27) + 100 - ( ) 100 - bags 2 l l E4-1 1372c
ENuclear Tp].; Cperating Pr0Cedure
%mber 11C4 23I Title Re"isl0n No, Waste Solidification Process Control Program 9 ATTACHMENT 4 Page 2 Of 3 SOLIDIFICATICN CALCULATION SHEET FOR > 10 TO 20 WT% SCRIC ACID VI. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIDIFICATION CALCULATION SHEETS REVIEWED Name / Date / Time FOOTNOTES I The volume of treated waste to be solidified in a single liher cannot exceed the mailmum treated waste volume listed on the attached Solidification Data Tables.
2 Round off up to the nearest whole bag. 3 Use the actual waste volume added to the liner in steps / equations 22, 23 and 24 If the waste volume added to the liner is less than the value obtained in Step / Equation 21. VII. DETERMINATION OF THE QUANTITY OF CEMENT ADDED TO WASTE: Quantity of Cement Added to Hogger: lbs (28) Quantity of Cement left in Hopper: lbs (29) Quantity of Cement Added per ft.3 Waste: (28) . (29) . ( )-( ) = lbs cement / (25) ( ) ft3 waste NOTE: Minimum Quantity of Cement Allowable for >10 to 20 Wt,
- 7. Boric Acid Class A Unstable Waste is 60 lbs./ft.3, For STABLE waste solidifications all 9.e cement must be added to the liner.
Quantity of Cement Added Meets the Minimum Requirements for unstable waste forms: Verifled By Date The recommended minimum treated waste volume and minimum solidified waste volume meet the requirements of the Solidification Data Tables for " TABLE waste forms. Verified By Date E4 2 1372c i
Nuclear 1si-i Operatino procedure 1104-78i
~
Title Revision No. 7 Waste Solidificat_ ion Procegs Control Program ATTACHMENT 4 (Cont'd) Page 3 of 3 SOLIDlFICAi!ON DATA TABLES
'0R > 10 TO 20 Wi% BORIC AC10 HN-100 HN-100 LVM Ser_tes 3 Seriesjl j Usable Liner Vol. (cu. ft.) 141.1 157.5 Man. Treated AU te Vol. (cu. ft.)- 101.3 113.1 Mas. Solidified Waste 141.1 157.5 ,
Vol. (cu. ft.) [ Recommended Hin.= Treated Waste Vol. 95.2 100.7 , (cu. ft)2 1 Min. Solidifttd Waste Vol. (cu. ft)4 132.6 140.2 : Max. Rad. Level 12 12 : R/hr Contact l' . For less than A2 quantitles of'LSA waste, for greater than A2 quantitles of LSA waste, the M ximum treated waste volume is 106 cu. ft. due to weight ! _llmitations._ 2* These minimums are required when shipping to Barnwell, to comply with the 15% > maximum vold space criteria for liners containing solidified stable '<aste forms.. t 5 E".3 1372c 1 1
. a w --m m . r w n.. m m e ., .e
.m.,,,_omm,,., , , , , _ . , , ,, _
(UCl88r ,, , 1 Operating Procedure 1104-281 Title Revision No. Maste Solidification Process cont _rol Program _ 16 ATTACHMENT $ Page 1 of 1 l CLA38 A 1N87ASLI AND STABLE, CLASS 8 AND C TEST SOLIDIFICATION DATA SHEET FOR WA8TE OIL i Chem. Paraabeters (Cono. Waste) Balan,ee Cal. Info Liner No.: Sample Date CMTR No.: Sample No.: Boron ppe Serial No.: Dates Total Solide ,, . _ppe Cal. Due Dates Waste Classe PM Total Act, uCi/cc
!. SAMPLE PREPARATION Volume of oil to be Soliditiede mis (1)
Volume of concentrated Weste added to the oils mis (2) Total Volume of Samples mis
% Oil by Volumes (1) x 100 = ( ) x 100 = n (3)
(1) + (2) ( )+( ) Weight of 50 wtt NaOli added to sample to raise pH > 5 giae (4) Quantity of moutsifier to Add to Samples mis (5) Quantity of Anti Foam Added to Samples _ mie (6) Quantity of Portland Type 1 Camer.t Added to Samples ges (7) Quantity of Anhydrous Sodium Metasilicate Added to Samples gas (8) Test Solidification Performed By: Name Date Time 1 35-1 1372c
Nuslear Tx1 1 operating Procedure 1104-28! Revision No. Title waste solidification Prteese control Prtgram 16 Page 2 of 3 I ATTACHMENT 5 (cont'd) II. SAMPLE IN5PECTION Sample cured fort Hours Cured Temp. cured sample contains "No Free Liquid" verified By Date Sample " Resists Penetration": Verified By Date The test sample has set the acceptance criteria of section 12.18 Yes No (circle one) Name Date Time NOTE : If the test solidification fails refer to Section 12.2 for guidance. comments associated with any Test solidification railure If the previous Test solidification f ailed, have three (3) consecutive tests been successfully completed? Yes No (Circle one) Additional batches solidified based on this sample solidification Liner Waste Liner Waste Liner Waste No. Vol. Date No. Vol. Date No. Vol. Date
- 2. 5. 8.
- 3. 6. 9.
- 4. 7. 10.
15-2 1372c
$UCl88F Txr-1 Oserating Procedure 1104-281
--;gg , Revision No.
Weste solidification Procese Oootrol Program 16 j f ATTACHMEN7 5 (Cont'd) Page 3 of 3 : 822.INDEPENDENTVERIFICATIONBYOPUNMANAGEMEl[T Test 8ssple Meets Acceptance criteria (section 12) Name / Date / Time Test solidification Data sheets (calculations) Reviewed Name / Date / T1 Jam 55-3 1372c _ . .---.. . .._ - - ~ . _ . . . - _ - -
1 I [e U 1 Nuclear 1si_i 1104 ?R! Operatini Procedure i title Revision No. Waste Solidification Process Control Program 8 _ ATTACHMENT 6 Page 1 of 3 SOLIDIFICATION CALCULAi!ON SHEET FOR WASTE 0!L Liner type to be used I !. PARAMETERS FOR rVLL SCAL _E_50L10!rtCATICJ Emultifier: ($) 7.48 + (1) .( ) x 7.48 + ( ) . ,, ga{/ (9) ft Anti-foam 1 1 (6) x 7.48 s (1) + (2) .( ) x 7.48 m ( )+( ) gall (10) ft3 Cement: 1 1 l (7) x 62.43 m (1) + (2) .( ) 62.43 x ( )+( ) Ibg/ (11) i fte ASMS: 1 1 (8) x 62.43 m (1) + (2) = ( ) x 62.43 m ( ) +( ) Ibl/ (12) ftJ !!. QUANTITIES TO BE A00E0 FOR Full SCALE SOLIDIFICATION Volume of untreated waste to add to liner (Max Treated Waste Vol from iM idificatlon Data Tables):3 (13) Concentrated Haste to be added: 60% x (13) x 7.48 - 0.60 x ( ) x 7.48 gals (14) Waste 011 to be added: 40% x (13) 0.40 x ( )= ft3 (15) 40% x (13) x 7.48 - 0.40 m ( ) x 7.48 gals E6-1 1372c
AUClear , ,,, s n e' Qgeating PrM edure _;,{ gjj
'Ti_t l e . _Revlil-? \!
Wa$te_ Solidification Process Control Pr gr3,1 _
)
ATTACHM[Ni 6 (C:nt'j) Page 2 Of 3 Emulsifier to be ad:ed: (15) (9) .( ) i ( ) . gals Anti-foam to be Added: (13) (10) =( )x( ) - gal 5 ASMS to be added: (13) : (12) = ( ) ( ) - Ib5 (16) (16) + 100 ( ) + 100 _ Jags l Volume of cement to add to liner: (13) x (11) . ( ) x( ) . Ib5 (17) (17) + 94 . ( ) + 94 _ bags l FOOTNOTES: I Round off up to the nearest whole bag. 2 Reduce the quantity of total waste in the 1:ler by I ft3 for every 10 gallons of anti-foam added to the liner. No adjustment is nece55ary for the first 10 gallons. 3 Use actual waste volume adoed to the liner in step / equations used in Section 11 If waste volume added to the liner is less than the value obtained in Step / Equation 13.
!!!. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIDIFICATION CALCULATION SHEETS REV!fHED Name / Date / lime E6-2 1372c
Nuclear 1si-i Operating Precedure 110_4-28! Revigicn No. fitle 7 Hast LSolidiflCatton Process Centrol Program ATTACHW(NI 6 (Cont'd) Page 3 of 3 SOLIDIFICAi!ON DATA TABLts FCR WASTL O!L HN-LOO HN-100 Series 3 , LVH Usable Liner Volume, (ft 3) 141.1 157.5 Man. Watte Volume (oil and cont. watte), ft3 93.7 104.6 Max Solidified Volume, ft3 141.1 157.5 Mhulmum Rad Level R/hr Contact 12 12 E6-3 1372c
MUClear ynx.1 Operating Procedure 1104-28! Title Revision No. Weste solidification Prncose_ control Program 16 i ATTACHMFFT 7 Page 1 of 3 l C1.A88 A STABLE, class e AND C TEST 80L!DIF1 CATION DATA SHEET FOR USED PRECOAT Balance cal. Infe. Cheelstry Parameters Liner No. Of75 No. pH Sample No. serial No. Gamma scan uci/m1 Dates cal. Due Date, 4 011 4 Waste class
- 1. SANFL2 PREPARATION Weight of Dewatered Powered Roein gas (1)
Volume of Dewatered Powered Resin al (2) Weight of Water Added to Powdered Rosins gas (3) Total of Volume cf Powered Rosin slurry _ _ _ ml (4) Quantity of Anti-foam Agent Added to samples gne (5) Quantity of oil in sample _% ( 6,5 Quantity of Emulsifying Agent Added to samples gne (7) Initial pH of samples (s) II. 50LIDIFICATIOli Quantity of ca(Ost), necessary to raise pH > 11.5: gas (9) Final pH of samples (10) Quantity of Portland cement Added to sample gne (11) Final sample Volumes sie (12) Test solidification Perfozued Bys Name Date Time E7-1 1372o
(UClS8r Tx!.1 operating Procedure 1104-2s! Title Revision No. Waste solidification Procese_ control Progree 16 ATTACKKENT 7 (cont'd) Page 2 of 3 class A STABLE, CLASS 3 AND C TEST SOLIDITICATION DATA SHEET FOR USED PRECOAT
!!!. s AMPLE INSPECTION sample cured fors Hours cured Temp. Cured ,,,
sample contains "No Free Liquid":
~~
verified my Date sample "Resiste Penetration" Verified By Date The test enspie has met the acceptance criteria of section 12.1: Yes No (Circle one) Name Date Time NOTE: If the test solidification fails refer to section 12.2 for guidance. Pa== ante associated with any Test solidification Failures If the previous Test solidification f ailed, have three (3) coneocutive teste been successfully completed? Yes No (circle one) l l l-E7-2 1372c l L _.
Muclear Tx1 1 operatino Procedure 1104-28! ~ Title Revision No. Waste solidification Process control Pmeros 16 ATTACHNINT 7 (Cont'd) Page 3 of 3 Additional batches solidified based on this sample solidifications Liner Waste Liner Waste Liner Waste No. Vol. Date No. Y,o l . Date No. Vol. Date
- 2. S. 8.
- 3. 6. 9.
- 4. 7. 10.
IV. INDEPENDENT VERIFICATION SY GPUN MANAGEMENT Test sample Meets Acceptance criteria (section 12) Name / Date / Time Test solidification Data sheets (calculations) Reviewed Name / Date / Time E7-3 1372c
o i Nuclear tar-i Operating Procedure 1104-281 _ litle Revision No. Waste Solidtftcation Procett Control Program 8 - ATTACHMENT 8 Page 1 of 3 SOLIDIFICAliON CALCULATION SHEET FOR USED PREC0Af Liner Type to be used
- 1. PARAMETERS FOR FVIL SCALE SOLIO!FICAt!ON:
Quantity of Water: (3) x7.4(.( 7.48 , gaj/ ; ft of (13)
)
(2) ( ) waste ' Quantity of Anti-Foam Agent: ! (5) 7.48 . ( ) 7.48 gaj/ (14) l (2) ( ) ft of waste : Quantity of Emulsifier: (7) x 7.48 . ( ) x 7.48 gaj/ (15) . (2) ( ) ft of waste Quantity of Ca(OH)2: (9) 62.43 . ( ) x 62.43 Ib f2) ( ) ftg/ of(16) waste Quantity of Portland Type 1 Cement: (11) x 62.43 . ( ) 62.43 Ibl/ (17) (2) ( ) ftJ of waste , f
!!, ggANTITIES TO 8E ADDED FOR FUI.L SCALE SOLIO!FICATION Volume of Dewatered Powdered Resin to be Solidified: ft3 (18)
Quantity of Water: (18) x (13) - ( )x( ). gal (19)
-r Quantity of Anti-Foam Agent:
(18) x (14) . ( )x( ). gal (20)- - Quantity of Emulsifier: (18) x (15) -( )x( ). gal- (21). 4 r EB-1 1372c 1.
Nuslear fur-i
~m e, OpprAting Procedure _
I T N.2 a l Title keviliCn %]. Wtste 'olidification Protes) C_ont,rol Pr: gram 9 ,_ ATTACFPENT 8 (Cont'd) Page 2 of 3 SOLID!rICAi!ON CALCULATION 5HEET FOR USED PREC0AT Quantity of Ca(OH)2: (18) (16) . ( ) ( )= lbt (22) (22) + (100) . ( )+( ) = tagst Quantity of Portland Type Cement: (18) r (17) = ( ) x( ) . Ib5 (23) (23) + (94) . ( )+( ) . bag 52 I The volume of waste, to be solidified in a liner cannot exceed the maximum settled and treated waste volume listed on the Class B Hatte Solidificatton Data Table for used pretoat. 2 Round up to the nearest whole bag. 11!. INDEPENDENT VERIFICATION BY GPUN MANAGEMENT SOLIO!FICATION CALCULATION SHECTS REVIEHED Name / Date / Time EB-2 1372:
[r kJ ] Nuclear tMi-i Operating Pro?fdure 110a 1R1 title Revisten No. Waste Solidification Process Control Progr6m 8 ATTACHMENT 8 (Cont'd) Page 3 cf 3 SOLIDIFICATION DATA TABLE FOR USED PRCCoat HN-600 MJ} HN-22Q MV usable Liner Volume, ft3 59 3 59.4 Man. Solidified Haste Vol. ft3 59.3 59.4 Man. Dewatered Waste Vol., ft3 33.3 33.3 Min. Waste Vol. ft3 32.9 32.0 Min. Solidified Waste Vol, ft3 58.6 57.0 Man. Radiation Level R/hr Contact of Liner 100 800 E8-3 1372c l 1
MUClS8r m -1 operating Procedure 1104-281 Title E*'A0" N0' waste solidification Procese control Program 16 ATTAC10GNT 9 Page 1 of 3 l CLAS5 A STABLE, CLASS B AND C TEST SOLID!TICATION DATA 8KEET FOR BEAD RES!N Balance Cal. Info._ chemistry Parameters Liner No.: CMTE No. pH Saeple No.: Serial No. Cassaa scan pC1/mi Dates Cal. Due Date % 011 % Waste Classt
- 1. SAMPLE PREPARATION sample Weights gas (1) 8 ample Volume: ml (2)
Weight of EC-3: gne (3) Weight of waters gne (4) Weight of Anti-foaming agent added to samples gne (5) Quantity of oil in samples % (6) Weight of Emulsifier added to saeples gas (7) Initial pH of samples (8) 3I. sANFL3 s0LIDIFICATION Weight of Ca(ou), added to sample to raise the pH g 11.5: gne (9) Final pH of samples (1D) Weight of Portland Type 1 coment added to samples gne (11) Final sample Volumes al (12) Test solidification Perfotised Sys i Name Date Time l l l 29-1 1372c l
MUClear rar 1 operating Procedure 1104-231 Title Revision No. Weste solidification Process control Program 16 ATTACHMENT 9 (Cont'd) page 2 of 3 class A STABLE, CLAS8 8 AND C TEST SOLIDIFICATION DATA SHEET i FOR BIAD RESIN
!!!. SAMPLE INSPECTION j sample cured fore Hours cured Temp. Cured sample contains "No Free Liquid"s i
verified sy Date sample "Resiste renetration": verified my Date The test sample has met the acceptance criteria of Section 12.18 Yes No (Circle one) Name Date Time
.. = . .... . ...... . . -.... . - ... ...... ....
NOTES If the test solidification fails refer to section 12.2 for guidance. Casumente associated with any Test Soliditication Failures If the previous Test solidification failed, have three (3) consecutive teste been successfully completed? Yes No (Circle one) E9-2 1372c
- _ - . _ - . _ , _ _ _ , . _ _ _ _ . ~ - ~ , , _ . . . _ . . .
MUClear wr.1 l Operating Procedure 1104-281 Title Reviston No. Waste solidification Process control Program 16 (Cont'd) Page 3 of 3 ATTACHMENT 9 l Additional batches solidified based on this sample solidification Liner Waste Liner Waste Liner Waste No. Vol. Date No. Vol. Date No. Vol. Date
- 2. S. 8*
i
- 3. 6. 9. I
- 4. 7. 10.
l
$V. INDIPINDENT VERIFICATION SY GPUN MANAGEMENT Test sample Meets f4cceptance criteria (section 12) Name / Date / Time Test solidification Data sheets (calculations) Reviewed _
Name / Date / Time i Y E9-3 1372c
k ki lNuclear tui i Operatis Procedure. 1104 0R1 Iltle Revisten No. WA$te Solidtfication process Control Program 8 ATTACHMEN! 10 Page 1 of 3 SOLIDIFICATION CALCULATION SHEET FOR BEAD RE5!N Liner Type to be used:
!!. PARAMETERS FOR FULL SCALE SOLIDIFICATION Quantity of EC-3:
(3) r 6. ) . ( ) u 6.3 , gaj/ (13) (2) ( ) ft of waste Quantity of Water: (4) r 7.4J . ( ) x 7.48 , ga / (14) (2) ( ) ft of waste Quantity of Anti-Foam Agent: i (5) x 7.48 . ( ) x 7.48 gaj/ (15) (2) ( ) ft of waste Quantity of Emulsifier: (7) x 7.46 = ( ) x 7.48 , __ gag /(16) ft of waste (2) ( ) Quaatity of Calcium Hydroxide Ce(OH)2: g) x 62.43 . ( ) x 62.43 , ibl/ (17) (2) ( ) ftJ of waste Quantity of Portland Type 1 Cement: (11) x 62.43 . ( ) x 62,43 , ibl/ (18) (2) ( ) ftJ of waste II, OUANTITIES TO BE ADDED FOR FULL SCALE 50L10lFICAT10N Waste Volume of to be Solldtfledl 3: ft3 (19) Quantity of EC-3: (19) x (13) . ( ) x( ). gal (20) E10-1 1372t l
& Nuclear rug.;
N.mter Oferiting precedure 1104. a: Title Revision 'c. Waste Solidificati0n Proce,Js Control Pregram a ATTACWlN? 10 (Cent'd) Page 2 :r 3 SOLIO!FICATICN CALCULAT!CN SHEET FOR BEAD RES!N Ovantity of Water: (19) i (14) - ( ) ( ) . gal (21) Quantity of Anti-Foam Agent: (19) x (15) = ( ) ( ) - gal (22) Quantity of Emulsifier: (19) x (16) = ( ) x( ) = gal (23) Quantity of Calclum Hydroxide Ca(OH)2 (19) x (17) . ( ) x( ) . Ibs (24) (24) + (100) = ( ) + 100 - bags 2 Quantity of Portland Type Cement: (19) x (18) = ( ) x( ) - Ibs (25) (25) + (94) - ( ) + 94 = bags 2 1 The volume of dewatered bead resin to be solidified cannot exceed the manimum treated waste volume listed on the Class A Stable, Class B and C Test Solidification Data Sheet for Bead Resin, 2 Round up to the nearest whole bag, 3 Reduce the quantity of waste in liner by 1 ft3 for every 10 gallons of anti-foam agent plus emulsifier added to liner. !!!, INDEPENDENT VERIFICATION Bf GPUN MANAGEMENT SOLIDIF1 CAT 10N CALCULATION SHEETS REVIEWED Naine / Date / fime f 4 (10-2 1372c
O Nuclear 1Hi-i Operatina Procedure 1104-20! ittle levision No. 9 _ Wa$te Spildification Process Control ProJLeam ATTACHMENT 10 (Cont'd) Page 3 of 3 SOLIDIFICAi!0N 0ATA TABLES rog stAo RtstN HN-100 HN-600 HN-600 LVMV HN-2QQ MU LVMVG5 Usable Liner 148.8 59.4 64.0 61.7 Volume (cu. ft.) Man Dewatered 120.0 47.9 51.6 49.8 Hasu Volume (cu. ft.) Man. "$11dified 148.8 59.4 64.1 61.7 Haste Volume (cu. f t.) Max. Rad. Level 12 800 100 100 R/hr Contact Hin.Recommenged(l) 46.0 47.3 Haste Vol (ft ) 106.9 - Min Solidified (l) 132.6 57.0 - 58.6 (I) Grout will have to be added to the HN600 HJ to increase the solidified waste volume to meet the 157, mastmum void space criteria for shipment to Barnwell. , E10-3 1372c
< c MUCl88F TMr 1 Operatino Frocedure 1104-281 Title Revision No. waste solidification Process control Program 1,6 ATTACHMENT 11 Page 1 of 2 TEST 80LIDIr! CAT!oM USING WESTINGHOUSE - HITTMAN PROCEDURE Waste to be Processed Westinghouse - Hittm3 Procedure No. Procedure - Title Current Revision Justification to use this alternate test procedures Eng. Review By Liner Men Alternate Test Procedure Approved for Use Sample Nos Name /Date Liner Type Waste Clase Salance Cal Info. Chemistry Parameters CMTE No. Sample Date Serial No. Boron ppe Cal. Due Date Total Solide ppe PN Total Activity uct/cc Independent verification by GPUN Management The Test Sample Has Het The Acceptance Criteria of Section 12.1: Yes No (Circle one) Name /Date / Time 311-1 13720 _ _ . _ . . . , _ ~ _ - . - . - _ - - - _ _ . . _ _ . . _ _ _ . _ _ . _ . . _ . - _ _ -
Ir kl ] Nuclear m -1 1104-281 operating Procedure Revision No. Title Waste solidtficat ton Procor9_ control,figram 16 ATTACKKENT 11 Page 2 of 2 Comments associated with any Test solidification railures !! the previous Test Solidification failed, have three (3) consecutive tests been cuccessfully completed? Yes No (Circle one) i 1 Tcat Solidification Data Sheets (Calcu1ations) Paviewed Name / Date / Tf*7 E11-2 1372c
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