ML20087G186
| ML20087G186 | |
| Person / Time | |
|---|---|
| Site: | Arkansas Nuclear  |
| Issue date: | 03/14/1983 |
| From: | James M. Levine ARKANSAS POWER & LIGHT CO. |
| To: | NRC |
| References | |
| 1617.098, NUDOCS 8403190356 | |
| Download: ML20087G186 (13) | |
Text
[8 %ddw'1 ARKANSAS POWER & LIGHT COMPANY g
Arkansas Nuclear One mLE: TRANSMITTAL FORM NO. 1013.02H REV. # 12 PC #
Arkansas Nuclear One Russellville, Arkansas Date 3-14-84 MEMORANDUM TO:
7 h - N [ (.
FROM:
ANO DOCUMENT CONTROL
SUBJECT:
ANO MASTER PLANT MANUAL UPDATE PROCEDURE NUMBER 1617.98 REV. # 0 PC #
TC #
PROCEDURE TITLE ORION MODEL 1610 BORON / pH ANALYZER SITE ACCEPTANCE TEST PROCEDURE NUMBER REV. #
PC #
TC #
PROCEDURE TITLE PROCEDURE NUMBER REV. #
PC #
TC #
PROCEDURE TITLE The following pages of the indicated procedure (s) contains items which involve personal privacy or proprietary material. PLEASE REMOVE THE INDICATED MATERIAL PRIOR TO DISTRIBUTION TO PUBLIC DOCUMENT ROOMS, PROCEDURE (S) pat;E (S) l l PROCEDURE (S) HAS BEEN PLtCED IN YOUR SET OF THE PLANT MANUAL.
l v4 PROCEDURE (S) SHOULD BE PLACED IN YOUR SET OF THE PLANT MANUAL.
NOTE: PLEASE PITURN SIGNED TRANSMITTAL TO DOCUMENT CONTROL - 4TH FLOOR:
SIGNATURE DATE UPDATED ff g[
d 8403190356 840314 PDR ADOCK 05000313 F
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s ru h ARKANSAS POWER & LIGHT COMPANY n
[
- RECORD OF CHANGES AND REVISIONS No. 1000.06A
@ ff WsGERM/GAIM SYSTEM REV. # 12 PC # /
l Safety Related YES ( NO O ORION MODEL 1610 BORON /pH ANALYZER SITE ACCEPTANCE TEST 1617,398 RE. O lhl f o n fr d ic o U MiU
- 7 6 PAGE REV PC#
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1 0
2 0
3 0
4 0
5 0
6 0
7 0
8 0
9 0
10 0
APPROVED BY:
APPROVAL DATE G
,/ider hma//k ut[y REQUIRED' EFFECTIVE DATE:
(General Manager)
b PLANT MANUAL SECTION:
PROCEDUREMNORK PLAN TITLE NC:
)RION MODEL 1610 BORON /pH i
GERM /GAIM SYSTEM ANALYZER SITE ACCEPTANCE TEST 1617.098 PAGE 1 of 10 (1
ARKANSAS NUCLEAR ONE aavision 0 oarE 02/14/83 CHANGE DATE 1.0 PURPOSE The purpose of this work plan is to test the capability and reliability of the Orion Model 1610 Boron /pH Analyzer.
- 2.0 SCOPE This work plan is applicable to both Unit one and Unit Two.
3.0 REFERENCES
3.1 References used in the development of this work plan.
3.1.1 Orion Model 1610 Boron /pH Analyzer Instruction Manual 3.1.2 NUREG 0737 3.2 References used in conjunction with this work plan.
3.2.1 1617.009 " Panel 2C357 Valve Alignment" l
3.2.2 1617.011 "Inline Monitoring of pH And Boron Concentration in
(' N.
'%,]
3.3 References used which interface with this work plan.
None l
4.0 DEFINITIONS l
None 5.0 PRECAUTIONS AND LIMITATIONS None l
6.0 PREREQUISITES 6.1 The analyzers shall have set unattended for at least seven days immediately prior to commencing PHASE I of the SAT.
6.2 The analyzers shall have successfully completed PHASE I of the SAT prior to commencing PHASE II of the SAT.
7.0 SETPOINTS None
[]/
8.0 INSTRUCTIONS
~.
8.1 PHASE I - Phase I of the SAT shall not be conducted unless the pre-
PLANT MANUAL SECTION:
P g g gRggNgig NO:
GERM /GAIM SYSTEM ANALYZER SITE ACCEPTANCE TEST 1617.098 o
PAGE 2 of 10 LI ARKANSAS NUCLEAR ONE aevisioN o o.1E 02/14/83 CHANGE DATE requisite in step 6.1 nas been satisfied. PHASE I will take approxi-mately two weeks to complete and shall be performed on Honday through Friday of weeks one and two.
Both analyzers shall be tested concur-rently. See Attachment 2 for the listing of the random order the standards will be analyzed in.
The results of the analyses shall be recorded on Form 1617.098A. When PHASE I is completed the results shall be tabulated on Form 1617.098B and compared to the acceptance criteria in section 9.0 if acceptable initiate PHASE II of the SAT, otherwise the SAT shall be terminated at the end of PHASE I with the results recorded as unsatisfactory. The analyzer printouts should be maintained as a part of the SAT data.
NOTE:
Upon commencement of this test inclusive of step 6.1 no ad-justments to the Sensing Panel or Reagent Panel components or solutions may be made with the exception of removing the temporary sampie pumps upon the completion of PHASE I and the reconnection of the analyzers into the PASS system start the start of PHASE II of this test.
8.1.1 Each days testing should be initiated by placing the sample pump suction lines into the first standard solutions to be analyzed for the day (see Attachment 2) then place the ana-(]
lyzers into the INTERMI'ITENT mode of operation on a 45 minute U
time cycle using procedure 1617.011.
8.1.2 As each standard solution completes its analysis cycle record the information on Form 1617.098A, then place the sample pump suction line into the next standard solution for analysis (see Attachment 2).
l 8.1.3 Repeat step 8.1.2 until the last standard solutions for the day have been analyzed then terminate the analyzer'c INTER-l MITTENT mode of operation using procedure 1617.011.
8.1.4 When all the analyses for PHASE I have been completed tabulate the results on Form 1617.098B and compare them with the accep-l tam u iteria in section 9.0.
The Radiochemistry Supervisor l
or his designee should mark the appropriate box on Form
~
1617.098B and tnen sign the form.
8.1.5 If PHASE I was signed off as Satisfactory proceLi to PHASE II of the SAT otherwise the SAT is complete at this point with the results being Unsatisfactory.
8.2 PHASE II - PHASE II of the SAT shall consist of a test of the analyzer's operation under normal in-line conditions (ie Reactor in Mode I with RCS total gas > 20cc/kg). PHASE II will be conducted over an approxi-mate two week period on Honday, Wednesday, and Friday of each week. At
,,()
least five analyses on each analyzer should be performed on each of the l
above mentioned days. Prior to initially starting PHASE II remove the
~
l temporary sample pumps and reinstate the analyzers into the in-line system (see Procedure 1617.011).
~~
PLANT MANUAL SECTION:
PROCEDUREANORK PLUJ TITLE NO:
ORION MODEL 1610 BORON /pH GERM /GAIM SYSTEM ANAT.V7FR STTF ArrFPTAMPF TF9T 1617 gor PAGE q nf 10 7mU ARKANSAS NUCLEAR ONE aEvisioN n oATE n2/, ara, CHANGE DATE 8.2.1 Prior to comraeacing each days testing contact the Operations Departmant to determine if any evolutions that could change the chemistry status in the RCS are planned during the days testing period.
If no evolutions are scheduled then the Radiochemistry department shall sample the RCS to determine the Boron and pH values in the system. When tais is com-pleted the in-line analyzer testing may be commanced by lining the system up to sample the RCS using Procedure 1617.009 and then placing the analyzers in the INTERMITTENT mode of operation on a 45 minute time cycle using procedure 1617.011.
8.2.2 When at least five sets of analyses have been completed for the day then tcrminate the in-line analyses using Procedure 1617.011 and secure sample flow using Procedure 1617.009.
8.2.3 The Radiochemistry department should then sample the RCS and analyze the samples for Boron and pH.
All results for the day should then be recorded on Form 1617. 0.98C.
8.2.4 When the minimum of six days of analyses have been completed the results should be tabulated on Form 1617.098D and then
(;
compared to the acceptance criteria in section 9.0.
The Radiochemistry Supervisor or his designee should mark the appropriate box on Form 1617.098D and then sign the form.
9.0 ACCEPTANCE CRITERIA 9.1 Range - Boron:
100 - 6000 ppm; pH:
2 - 12 9.2 Accuracy - Bcron: (>1000 - 6000 ppm) REL. STD. DEV. of % ERRORS $ 5 Boron: (100 - 1000 ppm) REL. STD. DEV. of % ERRORS 5 10 pH:
(2 - 12) REL. STD. DEV. 5 0.3 The relative standard deviation shall be calculated in the following manner.
R"+R %
t 2 +... + RN
~
REL. STD. DEV. =
N Where:
R = result of the analyzer from the true concentration expressed as a percent for Beron or pH units for pH.
N = number of analyses being evaluated.
NOTE:
During PHASE I of the Acceptance Test the intended concentration will be assumed "true" unless both analyzers have a relative standard deviation of the % ERRORS > 10 if the standard's con-
,3
(_)
centration is 5 1000 ppm or REL. STD. DEV. >5 if the standard's I
concentration is > 1000 ppm and the errors are in the same
~
PLANT MANUAL SECTION:
PROCEDUREN.'ORK PLAN TITLE:
NO:
ORION MODEL 1610 BORON /pH
_ GERM /GATM SYSTEM ANAT V7FR STTF APPFPTAMPP TFST 1617 09A PAGE 4 nf 10
(^')
ARKANSAS NUCLEAR ONE aswsmN n oaTE n2/iaen,
'~'
CHANGE DATE direction.
If this condition occurs the on-site lab will analyze the standard in question and if the results show the analyzed concentration to be > 15% from the intended concentration the results for that standard will be voided, a fresh sample pre-pared and the test for that standard repeated. During PHASE II of the Acceptance Test if the initial concentration step 8.2.1 is >5% from the final concentration step 8.2.3, the plant condition wasn't stable enough to conduct the test. The results for that day will be voided and the test extended for an additional testing day per step 8.2.
10.0 ATTACHMENTS AND FORMS 10.1 Attachment 1 - PHASE I CHEMICAL STANDARD SHEET: Orion Boron /pH Analyzer 10.2 Attachment 2 - PHASE I Listing of Random Sequence for Standard Analysis: Orion Boron /pH 10.3 Form 1617.098A - PHASE I DATA SHEET: Orion Boron /pH Analyzer 10.4 Form 1617.098B - PHASE I DATA
SUMMARY
SHEET: Orion Boron /pH Analyzer
((_-
10.5 Form 1617.098C - PHASE II DATA SHEET: Orion Boron /pH Analyzer 10.6 Form 1617.098D - PHASE II DATA
SUMMARY
SHEET: Orion Boron /pH Analyzer q\\._)
PLANT MANUAL SECTION:
PROCEDURElWORK PLAN TITLE:
NO:
ORION MODEL 1610 BORON /pH GERM /GAIM SYSTEM ANALY7FR STTT* ArrFPTAMrF TFST 1617.098 PAGE S of 10 f ~s LJ ARKANSAS NUCLEAR ONE aEvisioN n o*TE 02/14/R, CHANGE DATE ATTACHMENT 1 PHASE I CHEMICAL STANDARD SHEET: Orion Boron /pH Analyzer l
STD.
l l
l l
l l NUMBER BORON (ppm) l PH CHLORIDE (ppm)
IODINE (ppm) l l
l l
l 1
100
.1 l
l l
l 2
200
.2 l
l I
l 3
300
.3 l
1 l
l 4
400
.4 l
l l
l 5
500 l
.5 l
l l
l l
6 l
600 l
.6 l
l l
l l
1 l
l 7
700
.7 l
l l
^T l
8 800
.8 l
(V l
l l
9 900
.9 l
l l
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l 10 1000 1.0 l
l l
l 11 1250 7.0**
2.0 5
l l
l l
12 1500 7.0**
4.0 5
l l
l l
13 1750 7.0**
6.0 5
l l
I l
14 2000 7.0**
8.0 5
l I
l 15 2250 7.0**
10.0 l
5 l
l l
l l
16 25r.G 12.0 10 l
l l
l l
17 2750 14.0 10 l
l l
l 18 3000 16.0 10 l
l l
l 19 3500 18.0 10 l
1 1
l 20 l
4000 l
l 20.0 l
10 l
- to be determined at time of sample preparation g)
- NaOH added to solution to yield a pH of 7.0
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GERH/GAIM SYSTEM ANALYZER SITE ACCEPTANCE TEST 1617.098
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U ARKANSAS NUCLEAR ONE aEvisiON u oaTE ve/2*'o3 CHANGE DATE
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ARKANSAS POWER & LIGHT COMPANY Arkansas Nuclear One TITLE; PHASE I DATA SHEET l FORM NO.1617.098A REV. # 0 PC #
PHASE I DATii SHEET: Orion Boron /pa Analyzer Unit b.te l STANDARD I ORION l
- 7. DIFF. I SIANCARD I ORION l DIFF.
I
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l BORON ppm i BORON ppm i FROM STD. I pH I
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r' PLANT MANUAL SECTION:
PROCEDURElWORK PLAN TITLE:
NO:
ORION MODEL 1610 BORON /pH CFDM/CATM RVATFM A M A T.v'7pp RTTr arrrpT_n_nce Tret 1_ g 1_ ? nGA PAGE q nr 3 n O
ARKANSAS NUCLEAR ONE aavisiON
-oaTE n>,m in, n
CHANGE
- DATE
~ ' ~ ~~
ARKANSAS POWER & L!GHT COMPANY Arkansas Nuclear One TITLE: PHASE I DATA SL?c1ARY SHEET l FORM NO.1617.098B REV. # 0 PC #
PHASE I DATA SL?c1ARY SHEET: Orion Boron /pH Analyzer i STANDARD 1 STANDARD DEVIATION OF '4 ERROR I STANDARD l STANDARD DEVIATION OF QI I BORON rpal Unit 1 I Unit 2 l
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- t 0 Unsatisfactory Radiochemistry Supervisor p,
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5.3
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PLANT MANUALSECTION:
OggggOgffgbhH NO:
GER!!/GAIM SYSTEM ANALYZER SITE ACCEPTANCE TEST 1617.098 PAGE V ul lu O
ARKANSAS NUCLEAR ONE aavision u oats ve/ 2*/ o > ""
CHANGE DATE ARKANSAS POWER & LIGHT COMPANY Arkansas Nuclear One TITLE: PHASE II DATA SlfEET l FORM NO.1617.098C REV. f 0 PC #
PHASE II DATA SHEET: Orion Boron /pH Analyzer Unit Date I GRAB SAMPLE I ORION l % DIFF. I GRAB SAMPLE j ORION 1 DIFF.
t l
l BORON ppm l BORON ppm l FROM GS l pH I
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PLANT MANUAL SECTION:
PROCEDURElWORK PLAN TITLE:
NO:
ORION MODEL 1610 BORON /pH nme /ca Tit evcTrn anniv7to cTTE nccgpTyyr g Trem 197 non PAGE in nr 1n O'-
ARKANSAS NUCLEAR ONE aevisiON DATE ne,11,s3 n
CHANGE
' DATE
~ ~ '
ARKANSAS POWER & LIGHT COMPANY Arkansas Nuclear One title: PHASE II DATA SUMMRY SHEET l roRM PdO. 1617.098D REV. # 0 PC d PHASE II DATA SL? DIARY SHEET: Orion Boron /pH Analyzer l STANDARD DEVIATION OF BORON 7. ERROR l l
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UNIT 1 l UNIT 2 OVERALL l 1
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