ML20086F316

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Environ RO 77-18:on 770624,pH for Settling Basin Effluent Exceeded ETS Limit.Caused by Leakage of Two Valves Located Between Neutralizing Tanks & Demineralizer Regeneration Waste Sump.Settling Basin Neutralized
ML20086F316
Person / Time
Site: Peach Bottom  Constellation icon.png
Issue date: 07/05/1977
From: Cooney M
PECO ENERGY CO., (FORMERLY PHILADELPHIA ELECTRIC
To: Stello V
Office of Nuclear Reactor Regulation
References
RO-77-18, NUDOCS 8312210073
Download: ML20086F316 (2)


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PHILADELPHIA ELECTRIC COMPANY 2301 M ARKET STREET 4

PHILADELPHI A. PA.19101 1215) 841-4ooo

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July 5,1977 s

N Mr. Victor Stello, Jr.

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Director

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Office of Nuclear Reactor Regulations 1 '.

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U.S. Nuclear Regulatory Coninission Washington, DC 20555

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SUBJECT:

ENVIRONMENTAL DEVIATION I

Dear Mr. Stello:

The following deviation was reported to Mr. Caphton, Office of Inspection and Enforcement, Region 1, United States Nuclear Regulatory Commission on June 24, 1977.

Reference:

License Number DPR 44/56 Environmental Technical Specifications:

2.2.2 Report No.:

50-277/278-77-18 Report Date:

July 5,1977 Deviation Date:

June 24,1977 Facility:

Peach Bottom Atomic Power Station Units 2 and 3 R.D. 1, Del ta, PA 17314 Identification of Deviation:

The pH for the settling basin effluent exceeded the Environmental Technical Specification limit.

Conditions Prior to Deviation:

Settling basin operating with long paths. Raw water sump in automatic mode of operation.

Description of Deviation:

The daily grab sample from the settling basin effluent on June l

24, 1977 measured a pH of 9.6.

The verification s le also measured 9.6.

l COPY SENT REGION l

i JUL 151977 I

B312210073 770705 771930463 PDR ADOCK 05000277 S

PDR j

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Mr. Victor Stello, Jr.

50-277/278-77-18 July 5,1977 Page 2

The problem occurred again the next day when the effluent from the set-Cling basin had a pH of 9.5 The Technical Specification limit is that pH shall be within the range of 6.0 to 9.0.

Designation of Apparent Cause of Deviation:

These deviations in pH resulted from through leakage of two valves which are located between the neutralizing tanks and the de-mineralizer regeneration waste sump (one valve per neutralizing tank).

Each valve is closed before the associated tank is neutralized and discharged. However, because the valves leaked, un-neutralized waste could be released to the settling basin when the waste sump pumps operated during a release from a neutralizing tank. The leakage from the valves occurred downstream of the pH meter; therefore, the pH meter could not detect or prevent the release of the un-neutralized waste.

Analysis of Deviation:

1 The duration of each deviation was less than one hour.

Because the settling basin effluent is diluted by a factor of 10,000 with circulat-ing water flow, the pH of the circulating water leaving the discharge canal was not affected, and therefore, the environmental impact was minimal.

1 Corrective Action:

Each time the settling basin was isolated and neutralized.

Af ter the pH was checked, the system was returned to normal operation.

The two leaking valves were repaired.

Failure Data:

Several previous instances of pH beyond Technical Specification limits have occurred; however, the causes were not the same as the above occurrences.

Very truly yours, h

M.

Cooney Su rintendent Generation Division - Nuclear-cc:

Mr. J. P. O'Reilly NRC, Reg. Office i

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