ML20085F792
| ML20085F792 | |
| Person / Time | |
|---|---|
| Site: | Calvert Cliffs  |
| Issue date: | 10/15/1991 |
| From: | Creel G BALTIMORE GAS & ELECTRIC CO. |
| To: | NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM) |
| References | |
| NUDOCS 9110230048 | |
| Download: ML20085F792 (112) | |
Text
{{#Wiki_filter:- - _ _ _ _ _ _ _ _ _ _ B Al. TIM ORE GASAND IILECTRIC i CHARLES CENTER
- P.O. BOX 1475 e DAl]IMORE. MARYl.AND 21203 1475 i
GEORGL C CRf CL yx s vot wx4t an int r4r ('01) ?t@ 44% October 15, lWI U. S. Nuclear Regulatoly Conunission Washington, DC 205S5 ATiliNTION: Document Contipt Desk SUltiliCT: Calvert Clifl> Nuclear Power Plant Unit Nos.1 & 2; Docket Nos. 50-317 & $0 31R IkLWinlof NPQliS Permit Gentlemen: As required by our Environmental Protection Plan Technical Specifications, we are providing a copy of our application for renewal of the NPDl!S Permit for Calvert Cliffs. Should you have any further questions regarding this matter, we will be pleased to discuss thern with you. Very truly yours, ~ f )- / \\ k J J 1,. L GCC/ PSF /dtm linclosures ec: D.A.Ilru:i Esquire J. E. Silberg. Esquire R. A. Capra, NRC D. G. Mcdonald, Jr., NitC T. T. Martin, NiiC L E. Nicholson, NilC R.1. McLean, DN R 4 J.11. Walter, PSC !f}h w/ - o- ,,,eme -,,,e,e PDR ADOCK e5000317 p PDR gl i
D ALTIMORE GAS AND ELECTRIC 1000 BRANDON SHORES ROAD e DAL.TIMORE, MARYLAND 21226 (301) 787 5000 roSR CNQ1NrrNNQ $rRVICC3 DE P ARTut'it September 25,1991 Department of the Environment llazardous and Solid Waste hianagement Administration industrial Point Source Division 2500 Broening liighway Daltimore.hiaryland 21224 A*ITENTION: hir. E. Gertler, Chief
Dear hit. Gertler:
Enclosed ate the completed application forms for the renewal of the Calvert Cliffs Nuclear power plant NPDES permit (No. 84DP-0187). To a sist the permit writers, additional information is provided in this letter on issues and changes to operation since the last applicatloa was made: Data and discussion are provided on the use of Ammo,ia for pil control of our boiler water. We believe this should be resolved by permit conditions requiring monitoring without limits at hip 103A and MP 104A. Detailed information is attached to request permission to test *Clamtrol CT 1" for efficacy, and for a general provision to allow similar future tests with approval of MDE. rather than requiring a full permit modification. Since intake water is monitored without limits in the existing permit, the full Form 2 C Part V analytical work on intake water included for your information. Here is an Arrowhead Water Treatment System operation in service, which produces approximately 30 GPM of reject water from a reverse osmosis unit processing well water. This water discharges through a storm drain to Outfal1002. We can either sample for Form 2 C data as it discharges now, and/or sample the reject water stormwater mixture during a rainfall. Please advise which is appropriate. We operate a 'Precoat Sump" which dis harges precoat filter backwash water to Outfal1001 at approximately 1.5 GPM. There appa ently has been some discuuion and waiver to discharge in the past, but this can't be dsumented from o.' cords. Unless your files indicate some special considerations to tne contrary, wr i ~.1de the form 2 C data upon request. l
Finally, there are two tanks associated with operations in the Auxiliary Boiler Duilding, teth accumulating water at a rate in the order of 1/2 GPM, which dhcharge to Outfall(X)l. Plant procedures require a circalating pump rate such that a minimum 600,(XX) GPM of circulato'y water is flowing when these tanks are drained. Before sampling for Form 7-C work, we should discuss if the results would be meaningful considering the dominance of the circulating water volume. Although this application is for the most part a request to continue the discharges currently permitted, I've also uled to incorporate the other small discharges for an updated total flow accounting. If the permit writer assigned to this renewal will contact me with his position on which of these deserve outfall status, I'll be happy to provide the detailed information required.
- Regaids, D %k.~
ill Warner, Senior lingineer Environmental Programs Section JDW:sg ec: E. I. Bauereis to T. O. Ringger P. Crinigan/J. fizymianviak File 4 2 l
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- 1. EP A l.D. NUMBE R j
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- 't GENERA' INFORMATION I
1 > 1 i i ?. 4 .. ew l Consolictesdl'ermtra Program F MD0002399A l l0; OENERAL Mead the "Geaeren lastrueffons" herwe startiae s ..i..ia Laos L mm
- 1. E A 1 D. NUM BE R \\\\g g\\ N co k N L M A 4. iN & T R U G T i ON S gg a\\g
\\ \\ \\ \\ \\ \\ If a proprinted label has tioon provided, of fia \\ 4 \\ N \\ it in the designated space. RevioW the inform. .\\ x\\ \\ g \\ etion careful'y; if any of it is incorrect, cross sJII. FACILIT[hAUC \\ \\ N N through it and enter the correct data in the N \\ x \\ \\ \\ NN\\ xx d. \\N\\\\ appropriate fill-in eres below. Also, if any of .\\ g x x xN\\ ih. proprmied date is.bseni trhe a,9, to e, y* FACILITY \\g M AI N ADOR S N _ \\ , \\ \\x X / eft of the label spre lists the informerion N .\\ \\ \\ Pl. EASE PLACE LABE IN THIS SPACE '**r should WPerl, please prov6de it in the s g s proper fill-n eteefsl below. If the label is y T \\ ' '\\N\\- \\ \\ ' compiete and correct, you need not complete \\ \\ Items I, lit, V, and VI leacept V/ # which must be completed regardtoes). Complete all i F ACILITY ltems if no label has been provided. Refer to ' 'LOCATIO \\ the Instructions for detailed item descrip-N NN N N tions and for the level authorisat6ons under g \\ \\ s which this date is coll *cted,
- 11. POLLUTANT CHAR A INSTlWCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. If yu answer "yss"to any questions, you must subrHt this form and the supplemental form listed in the parenthesis following the question. Mark "X"in the box in the third column if the supplemental form is attached, if you answer "no" to each question, you need not submit any of these forms. You may answer "no"if your activity is excluded from permit requirements; see Section C of the instructions. See also, Section D of the instructions for definitions of bold-f aced terms, g
J a fe K 'N' l-M A M R ' A' sPECip. ouEstiONs JU seccaric out eveOMs v.e . Jg,j A. Is this facility a pubincly owned treatment works D. Does or will this tacility (e/cher exist /ng or proposed / which results m a dtscharge to waters of the U.S.y include a cortcerttreted animal feeding operation o.' (FORM ?A) X equatic animPt production facility which results in a X discharge to waters of the U.SJ (FORM 20) C. Is this a tacdity which currently results in discharges D. la this a proposed faciaity (orher then those coacnbad to wete s of the U.S. other than those os:cribed in X in A or 8 aborel which will result in e discharus to E A or B ebove? Fr)RM 2C) waters of the U.S)(FORM 2D) n n u n n n. F Do you or will you in?ct et this facihty industrial or E. Does or wal this facility treet, ttore, or dispose of X municipal ef fluent below the lowermost stratum con-X hassedous westes t (FORM 3) tainmg. withm one quarter mile of the well bore, underground sources of drinking water? (FORM 4) n n G. M vou or w.il you insect et this f ac.iity any proved water or other fluds which are brought to tb4 surf ace X in enne eciton with conventional oil or natural 2as pro-g y duction, infect fluids used for enhanced recovery of process, solution msnmg of minerals in situ combu> oil or natural gat or inject fluids for storage of hqueo g 4 hs1rocarborC (FORM 4) IFORM 4) n i. 4. Is this recility a propo*ed stationary source which is a la this facihty a proposed stationary source wnich is one of the 28 incunrial categorms hsted in the in-NOT one of the 28 it.dustriat categories hited in the structions and which will potenttally emit 100 tons X instructions and which wii; potentially emit 250 tons X per year of any air pollutant regulated under the per year v.,f any air pollutant regitated under the Clean Clean Air Act and may affect or be located m an Air Act and may ef fect or be located in an attainment attainment a.eas IF ORM M even, (FORM 51 1 . i 4 g, i t " 'IC A L,V.E R.T CLIFFS............... NUCLEAR POWER PLANT n ...,,x 4 A. H A M E ai T I T 4.E der * ' *. d tiddJ B. PHON E farre code.e no.) 1 e i i i i i I i I E iiiI I i I" i i i i I I I ii i i g i i i i i 2 W A.R.R E R. . J E R R.Y. . S.E.N.I.0 R. E N_G I N_ E E_R_ 3.01 17.8.7 5.3.7.9 r.. A. S T R E E T O R P.0, BO X e i i i i i a i. I a i i 1 1 3 I I I I I i i i i iI 3 P O. B O X 1475 B. CITY OR TOWN C.ST A TE D. IIP COD E i i I i i i I i i i i i i i i i i e t i i g g g g A i. A. L. T I_ M 0 R E MD 21203 B 4 rerr A. ST R E ET. ROiJTE NO. O R O TH E R SPECIFIC IDENTf PlE R c i I . i i i i - i i i i s s i i i i i i,, i i 2 . i 5 M. D. . RTE .4 S. COOH f V N AME I 1 I i I I i 4 3 3 i I i i l i i i I i 1 i CALVERT u C. CIT Y OR T OwN E %f[QN D. STATE E.I4PCODE s i,, ,,,,,.,,, i,,,,,,,,,, 6 L'U. S o Y MD 20657 u EPA Form 3510-1 (Rev.10-80) CONTINUE ON REVE'ISF
A (spectfy) LL. i i I (spectfy) 7 4.9.1.1 Electric Power Generation [] ra a C. T MIR D l D.PouRTH l \\ ' I !specify] i I tspeCify/ k 1 0 A. - 4 % i. Lt. $ the nerne i4g100 in( nem v m-4.i.o th.( . i i i i i i i i i e i i i i i i i r4 i i i i, i iiii4 i i i i i i owner P 8 B A L,T I M 0 R E AS AND ELt TRIC C0MPANY E] Y ES [] NO o
- c. sf ATus or oPa n Atom (Enfer the appropriate Jarrer into the entwet i osi t/ Other", sperffy./
D, PHont (area code a n<k) F = FEDERAL M = PUDLIC forher then frJeraJ or state) (spers/D~ .1 3 3 3 I 3 3 s - ST ATE O = OTHER (specify) P A 301 260 4101 P = PRIVATE ^ n- .I ^
- s. sta tsT on P.o. no n a i i I
I I i i I i i i I i i i I i i I I I i i i i l i i P. 0..B_0 X. 1475 F. CITY OR TOWN G.sT A T E M. IIP COOK l i i 4 . i i i i i i i i i i i i i i a i i i i i i i I i i is the faceuty located on Indian ianot? 8 B A.L T.I.M,0,P 2 MD 2 1,2 0 3 gYES ICNO A. NFons (Di.scharges to Sistface Water)
- n. reu3 (Air Emn.nons from Proposed SourcesI t
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- n. OTHn n twecify]
e, i i i i i i i 1 3 i i i c I i i i i i 1 3 I I I i c e (gpyggfyj 9 R 9 XI. M AP' Attach to this application a topographic map of the area extending to at least one mile beyond property bounderies. The map must show i the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment. storage, or disposal facilities, and each well where it injects fluids underground, include all sprin95, rivers and other surface water bedies in the map area. See instructions for precise requirements. lit. NATURE OF BUSINESS forovsve a brief oiescrersons i Electric Power Generation by pressurized water reactors. i X111. CE R TIFICATION (see instruerions) e I certity under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment. [ j'l A. N A h.et & O F F IC i A L T 6 T LE (type or prgarj
- s. SIGN A F. E j '
C.DATIIIONED C. C. Creel / Vice President j - y / S 9/ v ,C l I i.. ni EPA Form 3510-1 iRev.10-801 Rever.e
e a Lu N um u.acue,,,uan uv, > in tur,n s, - - ~ ~ MD 000 2399A ova no mo ou,s > %,,,,. o..n,, n, ys Pese pont m type in the unshao arens oniv u m aNvonoNutniat pHueLL'tsom e.uopu.v F,. RM 4% APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER 2gg Q EXISTING MANUF ACTURING, COMMERCI AL, MINING AND SILVICULTURAL OPE R ATIONS b NPDES Consolidated Permits Pngram ,c jh,(- } 'J
- 1. OUTF ALL LOCATION
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,.g ? s. For cach outf all, hst the latitude and longitut.fe of its locatinn to the nearest 15 seconos and tne name of the ecceivinti noter. b B. L A TIT UDL C LONui1UDL NWM W% N D H E C l' IV t 94 G W A T E N rPf Jefe,', vim i.... I, -,- l l 40 Chesapeake Bay 001 38 25 50 76 26 l 002 101A l" l 103A jn l o n n n n n gg r l" l l" 106A II. FLOWS. S0URCES OP POLLUTION, AND TR EATME NT TE CHNOLOGIE S 16"' QJk n,uG4Hi4LM'MTC[ ~ A. Attx5 a line dra.ving showin g the water Now thrauch Se f acihty. Indicate tr'uf ces of e' tab e water, Operations contributing westewater to the tatttuet" and treatment n ts 1.eduteo to corremnd to the enore detaned descr pt6ana in hem B. C:snuruct a water baiance on tha iinn drawing by showinti o ver y fions between nitakes, operotmns, :reatmant unsts, ano outtvis. If a wot r batance canr,et ce determinea te g, ror curta n m,nmg.sctmtiesj, proude pictorial aesenption of the nature and arnount of any sources of water and any coni ction or trentment measuret 8, F nt each puttail, providet a tiescnption Of: (1) All operDtions contributing W44ttwater to the ef fluent. socluding prOcts4 wastew0ter, &anstary wastewat+ cochng water, and storm water runof f; (2) The average flow contn: uted by eun operation, anJ (31 The treatment received by the wastewatrn. Contm;. on L Jitior al sheets if necessary. 2 o rt a a o"'$ 2 co N T "'au r >~ u Low 3 rurArurNT i.our s, a OPE R ATION thar! ,f 4 D r.$ C N t P f 10 N ABLEU l 5 F _NRncrat g d poline Water _LA00..D00_f2D_ Xhlschutian l 001 l l 1 Plant Sumps 313 MGD Discharne to Surface Water 4 A l 002 j l I I Sewage Treatment Plant 26538 CPD Dechlorination 2 E_ Aerated Lagoons 3 B 101A Denitrification 3 D Auxiliary Boiler Dump 2410 GPD Discharge to Surface Water 4 A 103A ^ Demineralizer Waste 77421 GPD Neutralization 2 K 104A Condensate Dumps 20 000 CPD Discharce to Surface Water 4 A 106A o o ic u L use.oNLv oem ant,ma,ance.uoent,,un m EPA Form 3510 2C (Rev. 2 85) P AGE 1 OF 4 CONilNUL UN HLVL -
rnNT1NOT D FR AM THF F AONT i C. E Atept IOr ?%vC 'unott,100kt, Or spillt, are any of the d4 charges described m iterr% ll A or D Wetmittent or menonal? f}t K % framptelc the foUvu veg intrit) [, % O sto m 3< c Won lfl; l".
- 3. F'R.' ? U E NC Y 4 FLOW I
l-a D Avs b MONTHS a r Low n o rt i n r o v a t v,o L u u t 1.OUTFALL
- 2. OPCR ATIONh /
,, y,,m, l ng,c,f.y,, 3 u n,,n e ou, g ^ NUMBER CCNTRIBUTING FLOW PEM WL W PE R Y F AM gppy (hst} ihat) w "r w n"aw'.
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Im W "D i! Y un U -. ~ ~~.n i i t ALL Variations in electricity
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Unk. Unk. i Unk. Unk. Unk. ! Unk. demand will affect flows plantvide. Also, plant is l subject to outages by regulatory decision. I I o li e l i l i l i I I I i l l ,jMKM n' $ '&e,,ftNE*IE,Qd, MrMM.y,)d@ rom)g=~gr2 dUM3fgQM *MM; -#Mf#-%1:oQ, ,. - - yw -.. -_ Tw - et w-y p,- -.m m-w L1. PR C C UCTiO N O .L Dws an etts at uce ne hm ute oeusatt t t v t rea gqm sy,wn ;oa j i.w c un u n act,; y ,,,i,i { g y es u omp w f rem til In _ No u m ' n !n
- 3. Are the iimitations in the5pnma'e etNent guene noressed m Mrrm ef ;)toductan vr ovw "e nure Of WrJfMIDI
[v ts.< w N rc ' t ut, x1 m i amchr4 &nts an ace.m -eaw-vo ct your v af.mrtue e m n r 'm' i er m W -- ^ 't <ou ar%wer e
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r i l l, t. r 4 1 {' lit. IMPROVEMENTS MMMMibVMM31 VJ) ff45Ni A 3[65M[h%k e M$$yGUEW12k A Are you now recereu cy 2nv Feamai. State or wa: autro e ta meet any waivmentar.on ecr.cou.e vor me ucutsc: on, upgrad.ng m aoeration of nas> water treatment eq#pment or pracoco or an, other envuonn, ental programs w*ucn may af fect the cinchames uesentwd in tna appucati an? Tnis invuces but n not tenited to, permu cor;d trons, adm>nstratwv or i.ntercement orders, en'orceme it compuance $cn'dde latteet st*pu,at:ons, court orders, an<i ya't or loan condttions r-y g s %mp:c t, the fatn via tarve) f No iso to item Ital
- s. sozNTirsc ATioN OF CONDITION.
- 2. AF rECTED QUTF ALLS l 4 F I N A [,, C O M M
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- 2. millL F DESC RIPTION OF PR OJE CT AnnraurNT, sTc, txso, ace.....co u.e,j
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may n i I i, I t i I f i 9 i L OPTION AL: You niav attach add,tional sheets riescribmg any additeona! waM : poOution rr.ntro' prog ams (or oterer t nv4ronments/ projects whrch may affet?t your (fischarges) you now ha<a underway of whicn you plan ind cate wheth ar earn pmgr.im is now uncierway or piarmed. md indicatst your actual or pianned st.nedules for construction- [M A Rn "x" er otscNIPTioN O F ADDITION AL CONTROL PHocaH AMS IS ATT ACHED EPA Forrn 3510 2C (Rev. 2485) PAGE2or4 CONTINUE ON PAGE
n vv~ ~ ~ ~. - N 000 2399A y AcNo*W ewaes #2 31 as P! naso onnt or tvoe in the unshadad areas nn v. '# * " N V ' " O N " N ' ' ' " " O ' " ' ' ' N """N FORM APPLICATlON FOR PERMIT TO DISCH AHGE WAS1EWATER A EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVit;ULTUR AL OPER ATIONS 2p g Conschdated Permits Proaram h %pOEs ~. ': [ L OUTF ALL LOCATION. '. ' For each outf a't, bst the latitude unst tongitude of its location to the neaerest 15 t,etonds and the name of the receivinn water. A. O U T r' A L L p L Af tT UDE C. LONulT UDL l Q N E C EIV lNQ W & T E N lindnff) 96 V M U E H (141f J e.cas, j
- a. as e se.
. sac. ,. p e u I .m i i q. l 26 MPF Sump 38 l 25 50 76 40 Chesapeake Bay 1 I I I i i I l J } 11. FLOWS, SOURCES OF POLLUTION, AND TRE ATMENT TE CHNOLOGIES.N@jAfd131dM-MR.Vj,%72MQVf-%EQ j A. Attaen a bne drawmg showiry toe water flow tveue 'ne - c mv.. nacre wu ces of mtab c water, averations contrest ng wasteweter to the et r and treatwnt units isoemd to correspond tu ine we am.. ae.cnamm n itet B. Construct 1 water emn:e on the nne urowmg by thowing avm : a Water ba'ance cannot de detP*ttri+d le 7, fr>r cettsan m,nmq xtivitzes), pf evidir ' FLOWS bditWeen intaket auttrations, frectrnent Jm's..inr t veter and anS cui ectzor cr trerarment me wn. pictorist uescr>puon of the nature and ornount er any wu (1) A:n operatsns. ' ioutmg wastenam to :no ettluent, oc,uomy omc ss watewater, sai,etary westewat r + tl. For each outta.t. proviae a oesenption of: nt <eceived by the wastewater. Conum. coobng water and storm water runctf; C) Tre m rage How uintnuatea ta un oce ation; anu C) Tne. eatme on additione sneets if necessary. 2 rJ P f. N 4 T S O N r $ 6 C O N T 8t l D i j T I N.', rLaw } 3 Twg4yugNT l" r d$U N "i 1 OUT. " "' "
- M'.[ '
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- s. ort n arion d.u i Stormwater Runoff
_ _ _ 55 GPD DisCLAIEe lo_ Surf ate _Wattr_ _ l 4 4_ MPF 1 Sump { j l l __p.__.__.._,___. 4 I i i I i 4 j i j i I i l l l l 1 i 4 .I l } i 1 1 I i l l o n sca ns un O N u e ternuent suutennes nu r>-categorwn 1 l CON I 6NUL UN HL V c. EPA Form 351C Gev. 2 85) PAGE1OFa
E P A t.D. N UM hK HlCUpy from item J Uf f onn 2 6 ~ fer9s espprown (*8 ** ""'.j f.35 MD 000 2399A 4curovat eaunes 72 CONTINUED FROM PAGF 7 A.B. & C: See instructions before proceeding - Complete one set of tables for each outf all - Annotate the outf 6tl number in the space provided. NOTE; Tables V A, V.0, and V C are included on separate sheets numbered V 1 through V 9. D, Use the space below to list any of the pollutants listed in Table 2c.3 of the instructions, which you know or have rehton to beheve is discharged of may discharged from any outfall, For every pollutant you hst, brie'ly describe the reasons you beheve it to be present and report any analytical data in v. possession,
- l. POLLUTANT 2 SOURCC
- 1. POLLUTANT 3,SUUNtt i
i I i i 1 l VI. POTENTI AL DISCHAHGE S NOT COVERED BY ANALYSIS. "N QMi;Fdf[()FQMSlyy5 ;.k. J ]+))J_25/(1,d],%[M is any potiutant hated in item V C a suostance or a component of a sucttance wnsen you currently use or manutacture as an intermeoiate or tinal procuct or bypeoduct? {: s ss that au ncn po%ran ts vu,,n, X uO,a > rs trem VI in I 1 P AGE 3 OF 4 CONTINUE ON RE'. EPA Forrn 3510 2C (Rev. 2-85)
CONTINUtD FROM THF F RONT j ? l Vil. DIOLOGICAl.10XICIT f Do you have any knowwp or reason to twheve that any bioiogical test for acute or chronic tonicity has L+en mace on any of your mucharges or on e } receiving water m relation to ytiur discharge wittutt the last 3 years? 1 s u ten to secute,n s'lts; Q v ts IMenusf> the tenun and acunte three purpe,are henu o e i h 9 V.MU lim @%I, W $4-V7 if,, M 4.8 - - NillCONTn ACT ANAL.YSIS INFORMATION ( hhMN 1,Q l., k) ' JMY c 7. h Were any of the analyses reportm)m lierr V peeenrmed by a contract beboratory or connuitig tom / $ Y t.8 that the neitfif. addryst and tstep'gone mguet hvP of, ustd,)oihald itJ , }. Se u idu to her fioes IX) ans4 > sed by, aut h sucn labnNitory or fir,g beh>w n N'" l vs,ACOHElb A N AME i n.o m r-n 4 o I i I I E.A.-Engineering. Science ; Hunt Valley /Loveton Center 301-771-4950 jPart A, a through e and Technoltsgy, Inc.
- 15 Loveton Circic Part C, IM 15M 3
} Aparks, Maryland 21152 IV 3V ~ 5V 31V l lA llA j } IB 46B t } t l 1 1 b IX. CE R TIFICATION ~ leertify underpenehy cflaw that this document andallattachments were prepared urWer my direction or superv : ton in accordance wrth a Systam designed to assure that qualsfiedpersonnetpropertygather andevo'uate the enformatitan subme*ted Basedon my mquiry of theperson stpersons who menage the system or thosspersons dwectly vesponsible for gatherins.he informstron, the snformation subantteo is, to the best of my knowledge andbelief. true. acer rate. and complete 1cm aware that there are signsficant penalties for submitting false information, mctuding the posssbdoty of fme and impresunment for kr mmg violations. A. H A M E tb OF FICI A L TI T LE t rype 47' Prunf 3 tt. PH ON E. N o f aren rode & tio # G. C. Creel, Vice P sidpt 301-260-4455 cr i U C.UGNATUM O DATEteONLU lo D '3l EPA Form 3510 2C (Rev. 2 85) PAGE4OF4
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424959 67 9) X 4 ts_ Chtoeine. Total Residust X-
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uunts. cnNtDE. AND TOTAL PHENOLS j__ iu e ms.,onW jLess Less total 17440 36 C). X- . h an 34'3 Than'445A I ug/l _T/ day 2M. Arsenet, Total 044o 3s 2: X 2.0 26.2' r 3u Deeyimtm. k Y otat. 7440 41.7) I I
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i l STATE OF MARYLAND - DEPARTMENT OF THE ENVIRONMENT REMOVED SUBSTANCES REPORTING FORM INSTRUCTIONS: Use this form to report the disposal of substances resulting from (1) treatment of' wastewaters and (2) related marufacturing processes as required by the State of Maryland " Water Quality and Water Pollution Control Regulations", COMAR 26.08.01. Use a separate form for each waste which is disposed of in a different manner, if several wastes are mixed before disposal, each waste must be separately described regardless of the quantity. NOTE: Submission of this form does not replace annual reporting of hazardous wastes as required by State of Maryland Regulation " Disposal of Controlled Hazardous Substances", COMAR 26.13.01. 1. DISCHARGE PERMIT NUMBER 86-DP-0187 (MD 0002399) 2. NAME OF FACILITY calvert Cliffs Nuclear Power Plant 3. FACILITY MAILING ADDRESS Baltimore cas and Electric Company, P. O. Box 1475, Baltimore, Maryland (Zjp) 21203 4. LOCATION OF FACILITY (If different from item 3) Rt. 4, near Lusby, Mar / land (Zip) 20657 5. FACILITY CONTACT (Name and Phone) Jerry Warner 301-_787-5379 6. DESCRIBE the nature of the removed substance (waste oil, sludge, etc,). Treated sanitary waste sludge 7. DESCRIBE the treatment process or the manufacturing process that generated the Removed Substance (precipitation, settling, etc.). Dechlorination, aerated lagoons, denitrification 8. DESCRIBE the physical character of the Removed Substance (liquid, solid, sludge, etc.). Yet no?4dn If sludge, what per cent solids? Is a chemical analysis attached? Yes X No l PENV 122 i
9. QUANTIrf of Removed Substance Measured 518.75 Estimated Liquids: Average gallons / week Maximum gallons / week Solids or Sludges: Average tonsAseex tons / year Maximum tons / week
- 10. MEANS OF DISPOSAL:
On Site (at facility location) X Off Site 11. WASTE HAULER (Name) Brothers Johnson ( Address) 1925 Laveille Road, Pot;t Republic, Maryland 20676 (301-586-2800) 12. DISPOSAL SITE (If not facility location) solomons 'Jaste Water Treatment Plant
- 13. OTHER.
Explain substances. If wastes are stored on site, describe method of storage, type of container, storage area, pretreatment, etc.).
- 14. MAP.
Attach a copy of a U. S. G. S. 71 minute quadrangle map (or equivalent) showing the disposal or storage site. The map must show all water courses within 1/2 mile of the site. 15. CERTIFICATION. I hereby certify that the information on this form and the attachments is true and accurate to the best of my knowledge and belief. b ' YQ" /ok/$/
- SfgnatureofPermitteeorAgent Date SEND TO:
Department of the Environment, Hazardous and Solid Waste Management Administration, 2500 Broening Highway, Baltimore, Maryland 21224
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L l L OUTFALLC01 j CHESAPEAKE BAY l NONCONTACT COOLING l-> CHESAPEAKE BAY 2,400,088 GPM MP101A MP103A MP104A MP106A I i l SANITARY. BOILER DEMIN. CONDENSATE TREATMENT BLOWDOWN WASTE DUMPS A A A A WELL WATER CHESAPEAKE BAY CHESAPEAKE BAY CHESAPEAKE BAY 18GPM 2 GPM 54GPM 14 GPM OUTFALL 002 CHESAPEAKE BAY PLANT SUMPS CHESAPEAKE BAY 217,361 GPM 217,361 GPM CHESAPEAKE BAY l MFP SUMP DRUM STORAGE CHESAPEAKE BAY m j 55 GPD 55 GPD j SCHEMATIC OF WATER FLOW BG&E CALVERT CLIFFS NUCLEAR POtNER PLANT LUSBY, MARYLAND JDW 9/12/91
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Cahert Cliffs Nuclear Power Plant, Su te Discharge Permli No. 86 DP-0187: Regarding Use of Bloeldes Currently Calvert Cliffs is permitted to use chlorine continuously in the saltwawr system of the plant. There are many new products the ny piovide an effective means of foullng control and that cre environmentally acceptable. le . a allow li more timely process for testing o ae of some of these nroducts ws are requestir me following to be incorporated into the new Ca urt Cliffs permit: A provision to allow the use of other blocides with approval trom hide. e Specifically, Calvert Cliffs is interestod in testir.g a produtt called Clamtrol/CT-1 (Betz e 1.aboratories). If testing is successful we would like to use the product on a more permanent basis. Information regarding this pioduct and the proposal for testing C.lamtrol/CT-1 in the saltwater system were discussed with MDE representatives previously. The following is a description elthe proposed use of this product at Calvert Cilffs: T1.v procedure at CCNPP to target microfouling will be to treat one saltwater subsystem (4 all together,2 per Unit) at a time. Each subsyst m would be treated once a week for one hour (4 hours total for the entire plant). The concentration will te between 30-60 ppm in the system. Clatn.n'/CT 1 naturally adsorbs and detoxifies on suspended substances in the water (i.e. the water exerts a " demand" for the active product). Therefore, with dilution from the untreatni subsystem and the circulating water system plus the natural demand of the water, levels of Clamtrol/CT-1 at the NPDES 001 outfall 2re expected to be well below the detection limit of 0.2 ppm. If it is decided to use the product on a permanent basis the treatment may be modified to include a procedure to target macrofouling. Treatments in this situai on are less frequent, at lower concentrations and for sllghtly longer exposure t periods. Again discharge levels would be expected to be well below detection. The test period will last for approximately 2 months. Clamtrol/CT-i under certain circumstances has a tendency to foam. Because of the very low concentrations and the submerged discharge, it is believed that foaming will not occur in the Calvert Cliffs discharge. However, because there is a possibility of foam we request some allowance for this during the testing period. This will be a pert of the evaluation
- process, Some product information is attached including the MSDS. Additional information is f
available in the package provided to MDE previously (M. Knott and E. Gertler) or by contacting BG&E.,
AQUATIC m LABORATORIES, INC. DO T0i Y _ fl (- GCMEATON ACAC.TAEvCSE.PA iDO47.U S A. / TEL.;D S.355 33Co. TELEX 17314G.A Ax # 355 2009 ? ENVIRONMENTAL INFORMATION ON CLAM-TROL CT-1 FOR MACROFOULING CONTROL \\ Clam-Trol CT-1 is a patented nonoxidizing molluscicide providing state-of-the-art control for macrofouling caused by Asiatic clams, t Zebra mussels and marine fouling organisms. ~ Clam-Trol CT-1 is a j federelly registered molluscicide for use in once-through a'nd recirculating cooling systems. The EPA registration number for CT-1 i 8 is 387(-145. Clam-Trol CT-1 has been used since 1986 for Asiatic clam macrofouling control to power plants, steci mills, chemical refineries and other manufacturing facilities. Appendix I presents some case histories for' Asiatic clam control. The efficacy of CT-1 towards zebra mussels has been demonstrated in laboratory studies and it has also been utilized for the extermination' 4..,_ J of zebza musselt at power plants and industrial facilities 7 The- "0-laboratory evaluatiorc (See Appendix 2) demonstrated Lthe-efficacy of ~ ~ CT-1 for exposure periods of 6 to'24 hours at' water tempera'tu'res of 50, 100, 150 and 20 C. 0 It has been demonstrated ^that mortality" ' "*f responses are dependent upon CT-1 dosage, exposure per~1od', an'd temperature. Appendix 3 presents a case history on the'firsT 9T-1 applications for eradication of zebra mussels at two power plant's' located along Lake Erie in 1989, [tWa tumucM em<M re M.G,1; d ^t f %e,nALr..c w A(wd mud Tpd:; dea] v Marine macrofouling can be caused My a variety of. organisms, such air-l - blue mussels, oysters, barnacles, hydrozoans, bryozoans. tbnid5tesi J and others. A review on CT-1 control' methods for blue' mussel foulingi (See Appendix 4) provides a reference for" implementing confrol.' -M f programs to cooling systems. Another paper demo'nstrates the efficac?2 7 of month 1v CT-1 treatment programs during a 90: day sidestream WW ~ evaluat..on (See Appendix 5) for macrofouling conitr buted"by 'oystersTO I ribbed mussels, barnacles and othar biofouling growth. '~' Information on Clam-Trol CT-1 to aid in addreesing NPDES, permit P requir<.sents is being presented, as follows: ~-- 1. Name of the additive Clam-Trol CT-1 contains 13% active in'gredients (two cationic' f'- surfactants) and 87% inert materials. The two cationl'c "" (' surfactants are N-alkyl dimethylbenzyl ammonium chlorida (QuaiQ and dodecylguanidine hydrochloride (DCH). The inert l1natoria;1'sJof-
( l, i J this formulations ethylene glycol, isopropyl alcohol and water are relatively nontoxic to aquatic organisms. 2. Concentration (mg/L) of the additive to be used: Clam-Trol CT-1 is usually fed at concentrations ranging from 10 to 25 mg/L. The concentration to be fed will primarily depend upon the domand of the cooling system, resulting in passive neutralization of the CT-1 actives. The length of the exposure period will vary from 6 to 24 hours depending upon the water temperature and the CT-1 dosage. Either seasonal or bimonthly treatment programs ranging from 1 to 4 times / year is required for macrofouling control of either zebra mussels or Asiatic clams. Treatment programs for the control of marine macrofouling will range from 4 to >6 times / year depending upon the kinds of marine organisms and the length of the growning season. It must be noted that the objective of these seasonal or bimonthly applications is to provide a preventative treatment program by exterminating the juvenile stages to prevent their growth to adult fouling size and to reduce the overall accumulation of juvenile stages setting within cooling systems. Each cooling system will have a specific treatment program to moet the macrofouling control requirements for that facility. The frequency of the applications, ranging from 1 to >6 times / year, will depend upon the degree of larvae and juvenile infestatiens and the kind of macrofouling control no the operations of the power plant or industrial facility are not inipeded. 3. Expected concentration of the additive contained in tho discharge or blowdown immediately prior to entering state surface waters: All seasonal or bimenthly CT-1 treatment programs are designed so that the concentration of Clam-Trol CT-1 is always less than 1 mg/L in the discharge. The reduction of CT-1 from the point-of-feed to less than 1 mg/L at the outfall is achieved by one or more of the following approaches: 1) Both the intake river water and the cooling nystem have many kinds of naturally occurring materials - silts, clays, suspended solids, humic acids, and the microfouled surfaces of cooling pipes - that will exert a demand unan the CT-1 actives. Both actives (Quat and DGH) will readily adsorb to those materials, once adsorbed they no longer exhibit toxicity. Thus the passive neutralization of the CT-1 actives as they pass through the cooling system will significantly reduce the concentration prior ,k, to discharge.
n nn....- ~. -. -.. ~., ~. ~, .... ~ i I i y' l 2) Many Clam-Trol CT-1 treatment programs focus upon segmented applications where only a portion of the total cooling water is being treated at any one time. This segmented treatment approach allows for the dilution and passive neutralization of the treated water with the remaining untreated cooling water. This segmented treatment approach can often achieve CT-1 concentrations of less tl.an 1 mg/L. 3) If neceesary, clam-Trol CT-1 appitcations can be actively detoxified by feeding a blend of clays prior to discharge. Clays are fed at a ratio of 1 mg/l of clay for each 1 mg/L of CT-1 to be detoxified to achieve dischargo concentrations of insa than 1 mg/L. 4) An analytical photometric method is available for monitoring the concentration of CT-1. This field method has a sensitivity of 0.2 mg/L. (Appendix 17) 4. Toxicity information regarding additive only minimal amounts of Clam-Trol CT-1 are required for short treatment periods (6 to 24 hrs) to provide macrofouling control. () The discharge of CT-1 concentrations of less than 1 mg/L would ( not result in an environmental impact to the receiving stream or lake. In fact, even the most sensitive aquatic organisms would not be affected in either an acute or chronic sense beyond the mixing zone of the discharge stream. In addition, detoxified CT-1 remains neutralized so that it wou3d not impact benthic organisms. _ Neutralized CT-1 actives would be further sub ect to j blodegradation that would prevent any accumulation of these actives in the environment. The following toxicity information is available Appendix 6: Clam-Trol CT-1/ Environmental Package Appendix 7: LC50 values of Clam-Trni CT-1 (Neat Formulation): Freshwater Species Appendix 8: A 7-day Fathead Minnow Chronic Toxicity Test with Clam-Trol CT-1; Acute: Chronic Ratio Appendix 9: A 7-day Fathead Minnow Chronic Toxicity Test of Detoxified Clam-Trol with clays Appendix 10: A 7-day Ceriedachnia Chronic Toxicity Test with Clam-Trol CT-1
i .I Appandix 11: Detoxification Potential of Clam-7rol CT-1 with Clays and other Materials to Fathead Minnows and Danhnia maana Appendix 12: Midge larvas (Chironomus ricarits) Ten Day Survival and Growth Study of Datoxified Clam-Trol CT-1 with Clays Appendix 13: A Long Term Study With Fathead Minnows and Daehnia EREDA on the effect of Datoxified clam-Trol CT-1 Appendix 14: A Comparison on the Acute Toxicity (LC50's) of Clam-Trol CT-1 at Different Water Hardness Appendix 15: Abiotic Effects (pH and temperature) on Detoxified Clam-Trol CT-1 with Clays Appendix 16: The Effect-of Ammonia Levels on Detoxified Clam-Trol CT-1 Appendix 17: Analytical Method for Clam-Trol CT-1 Appendix 18: MSDS s. Appendix 19: LC5 Values of Clam-Trol CT-1 (Neat Formulation): MarkneSpecies Appendix 20 A 7-day Sheepshead Minnow Chronic Toxicity Test with Clam-Trol CT-1 Appendix 21: A 7-day Mysid Shrimp Chronic Toxicity Test with Clam-Trol CT-1 Prepared by: Larry A. Lyons Aquatic Toxicologist Laboratory Manager LAL cn )
BETO LABORATORIES,INC. 4636 SOMERTON ROAD, TREVOSE, PA. 19047 BET: MATERIAL SAFETY DATA SHEET (f 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) 215/355-3300 (PALE 1 OF 3) PRODUCT
- CLAM-TROL CT-1 EFFECTIVE DATE 01-18-81 PRINTED:
3-Sep-1989 REV SEC.3 PRODUCT APPLICATIOli : WATER-BASED MICROBIAL CONTROL AGENT.
SECTION 1-----------HAZARDOUS INGREDIENTS---------------
INFORMATION 011 PHYSICAL HAZARDS, HEALTH HA"ARDS, PEL'S AND TLV'S FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIOliS STANDARD IS LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATIOll. ETHYLENE GLYCOL ***CAS#107-21-1; LIVER, KIDNEY AND BLOOD TOXIH;C!IS DEPRESSANT; ANIMAL TERATOGEN (HIGH ORAL DOSES) ;PEL/TLV: 50 PPM-C. ALKYL DIMETHYL BEtt2YL AMMONIUM CHLORIDE ***CAS#66424-85-1; CORROSIVE (EYES); PELINONE;TLVNONE. ISOPROPYL ALCOHOL * * * (IPA) ;CAS # 67-63-0 ; FLAMMABLE LIQUID;CHRollIC OVEREXPOSURE MAY CAUSE LIVER AND KID! LEY TOXICITY; PEL/TLV: 4 00 PPM ( 500 PPM-STEL). DODECYLGUANIDINE HYDROCHLORIDE ***(DGH);CAS#13590-97-1; CORROSIVE;PEL:NONE; TLV: NONE. q ETHYL ALCOH 0L* * * (ETHANOL) ;CAS # 64-17-5 ; FLAMMABLE ;MAY CAUSE DEFATTING DERMATITIS, DIZZINESS AND HEADACHE;PEL:1000 PPM;TLV:1000 PPM.
SECTION 2------~~---TYPICAL PHYSICAL DATA-------------------------
P!;: AS IS ( APPROX. ) 5.3 ODOR: MILD FL.PT.(DEG.F): 116 SETA(CC) SP.GR. (70F)OR DENSITY: 1.022 VAPOR PRESSURE (mmHG): 23 VAPOR DENSITY (AIR =1): >l VISC cps 70F: 23 % SOLUBILITY (WATER) : 100 EVAP. RATE: <1 ETHER =1 APPEARANCE: COLORLESS PHYSICAL STATE: LIQUID FREEZE POINT (DEG.F): <-30
SECTION 3-----------REACTIVITY DATA------------------------------
STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK ' LEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITIott (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. l l
BET: MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: CLAM-TROL CT-1 EFFECTJ/Y vE 05-18-0' ~~~--S ECTI ON 4 -----------HEALT!{ HAZ ARD E FFECTS --------------- ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE gqs CORROSIVE TO SKIN. POTENTIAL SKIN SENSITIZER V. CUTE EYE EFFECTS *** CORROSIVE TO THE EYES ACUTE RESPIRATORY EFFECTS *** PRIMARY ROUTE OF EXPOSURE VAPORS, GASES, MISTS AND/OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CHRONIC EFFECTS OF OVEREXPOSURE *** PROLONGED OR REPEATED OVEREXPOSURES MAY CAUSE: TISSUE NECROSIStBLOOD CELL DAMAGE OR IMPAIR BLOOD CELL FUNCTION; REPRODUCTIVE SYSTEM TOXICITY; SKIN SENSITIZATION. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** IN!!ALATION OF VAPORS / MISTS / AEROSOLS MAY CAUSE EYE, NOSE, THROAT AND LUNG IRRITATIONtSKIN CONTACT MAY CAUSE SEVERE IRRITATION OR BURNS. PRECAUTIONARY STATEMENT BASED ON TESTING RESULTS *** MAY BE TOXIC IF CRALLY INGESTED.
SECTION 5------------FIRST AID INSTRUCTIONS----------------------
SKIN CONTACT *** REMOVE CLOTHING. WASH AREA WIT!! LARGE AMOUNTS OF SOAP SOLUTION OR WATER FOR 15 MIN.IMMEDIATELY CONTACT PHYSICIAN EYE CONTACT *** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT C.NHALATIONEXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA. APPLY NECESSARY FIRST AID TREATMENT.IMMEDIATELY CONTACT A PHYSICIAN. INGESTION *** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED. CONTACT PHYSICIAN. DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER
SECTION 6-----------SPILL, DISPOSAL AND FIRE INSTRUCTIONS---------
SPILL INSTRUCTIONS *** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND -ABSORB ON ABSORBENT MATERIAL. PLACE IN WASTE DISPOSAL CONTAINER.THE CONTAMINATED ABSORBENT SHOULD BE CONSIDERED A PESTICIDE AND DISPOSED OF IN AN APPROVED PESTICIDE LANDFILL.SEE PRODUCT LABEL STORAGE AND DISPOSAL INSTRUCTIONS. REMOVE IGNITION SOURCES. FLUSH AREA WITH WATER. SPREAD SAND / GRIT. DISPOSAL INSTRUCTIONS ***- WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT (AS IS)-- DISPOSE OF IN APPROVED PESTIC7DE FACILITY OR ACCORDING TO LABEL INSTRUCTIONS FIRE EXTINGUISHING INSTRUCTIONS *** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING (, ;', APPARATUS (FULL FACE-PIECE TYPE). DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER i l
9 i DET: MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: CLAM-TROL CT-1 EFFECTIVE DATE 05-18-8:
SECTION 7-----------SPECIAL PROTECTIVE EQUIPMENT-----------------
USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE ESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. (s
- ENTILATION PROTECTION ***
ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION *** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE & DUST / MIST PREFILTER RuCOMMENDED SKIN PROTECTION *** GAUNTLET-TYPE RUBBER GLOVES, CHEMICAL RESISTANT APRON WASH OFF AFTER EACH USE. REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION *** SPLASH PROOF CHEMICAL GOGGLES. FACE SHIELD
SECTION 8-----------STORAGE AND HANDLING PRECAUTIONS-------------
STORAGE INSTRUCTIONS *** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. ETORE IN COOL VENTILATED LOCATION. STORE AWAY FROM OXIDI ERS HANDLING INSTRUCTIONS *** GENERAL-IMMEDIATELY REHOVE CONTAMINATFD CLOTHING, WASH BEFORE REUSE SPECIFIC-COMBUSTIBLE. DO NOT USE AROUND SPARKS OR FLAMES. BOND CONTAINERS DURING FILLING OR DISCHARGE WHEN PERFORMED AT TEMPERATURES AT OR ABOVE THE PRODUCT FLASH POINT. THIS MSDS COMPLIES WITH THE OSHA HAZARD CCMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR)
- d***************************
( APPENDIX: REGULATORY INFORMATION \\ 4HE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION ICIOWN TO BET CN THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO DE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ... FIFRA(4 0CFR) : EPA REG.NO. 3876-145 ... REPORTABLE QUANTITY (RQ) FOR UNDILUTED PRODUCT: NOT APPLICABLE ... RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: DOO1= IGNITABLE;D002= CORROSIVE ... DOT HAZARD CLASSIFICATION: CORROSIVE TO SKIN. COMBUSTIBLE ... DOT SHIPPING DESIGNATION IS: UN1760 CORROSIVE LIQUID, N.O.S. ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: NONE PRESENT IN SIGNIFICANT AMOUNTS ... SARA SECTION 302 CHEMICALS: NONE PRESENT IN STGNIFICANT AMOUNTS ... SARA SECTION 313 CHEMICALS: ETHYLENE GLYCOL (107-21-1) 21.0-30.0% ; ... SARA SECTION 312 HAZARD CLASS: IMMEDI ATE ( ACUTE), DELAYED (CHRONIC) AND FIRE- ... MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS :~ HEALTH - 3 ; FIRE - 2 ; REACTIVITY - 0 ; SPECIAL - CORR ; PE - D C
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e %g EISBN p' C 3C s CLAM-TROL $ CT-1 Mollusk Control Agent METHYL ORANGE METHOD APPARATUS REQUIRED CT 1 Buffor Reagent 1591 Methanol (reagent grade or equivalent) 322 Beaker, glass,50 mL (2 required) Code Cylinder, graduated,25 mL 2022 Drying Reagent, with a plastic dipper 1271 Funnel Rack, separatory 930
SUMMARY
OF METHOD Funnel, separatory, with a Teflon stopcock,250 mL (2 required) In this procedure the dye in the CT 1 Buffer Reagent com-plexes with the active ingredients in Clam Trol CT-1. This Glass Rod 114 complex la extracted into 1, 2 - dichloroethane. The or-ganic layer containing the complex is separated from the Optical Cell, (2 roquired) aqueous layw anmeM a % reagetontaining Safety Bulb, rubber 1575 anhydrous sodlum sulfate.The color intensity of the 1,2 Spectrophotometer dichloroethane layer is then measured in a spectropho-tometer at 415 nm. GENERAL APPARATUS
- This method must be customized to each specific appil-Cylindor, graduated,100 mL Code 121 cation. Vary the volumes of sample, CT 1 Buffer r,eagont, CytInder, graduated,250 mL 917 and 1,2 - dichloroethane according to the test range (see Table 1). If a higher absorbance is needed, increase Flask, volumetric,1 L, glass (4 required) 935 the volume of sample or decrease the volume of 1,2 -
Pipet, glass, gra1uated,1 mL 140 dichloroethane. When increasing the sample volume it Pipet, glass, volumetric,1 mL 866 may be necessary to increase the volume of CT 1 Buffer Reagent used. For samples < 150 mL use 10 mL of CT-1 Pipet, glass, volumetric,3 mL Buffer Reagcat; for samples between 150 and 300 mL Pipet, glass, volumetric, 5 mL 124 use 15 mL of CT1 Buffer Reagent. Make sure that enough 1,2 dichloroethane is used to leave a small Pipet, glass, volumetric,10 mL 123 plug of solvent in the separatory funnel when the bottom Pipet, glass, volumetric,15 mL 801_ layer of solvent is removed and to fill the optical cell E'UE"'iY' Pipet, glass, volumetric,20 mL 1278 Pipet, glass, volumetric,25 mL 117 GENERAL PROCEDURE Use a well-ventilated or hooded area to run the test.
- The general apparatus required for the test is deter-Always use a safety bulb when pipetting liquids, mined by the specific test procedure used.
1,2 - Dicloroethaqe (also known as Emylene Dimb " Apparatus not availab!e through Betz Lab Supply ride) is a priority pollutant and a specifically listed should be obtained through a local supplier, RCRA-regulated material subject to specific disposai re, i CHEMICALS REQUIRED smetions and/or prohibitions. For this reason, all used 1 1,2 - dichloroethane should be segregated from other 1,2 Dichloroethane (reagert Code 1666 wacte streams. Dispose of waste 1,2 dichloroethane in grade or equivalent) an approved manner (e.g., labpacking or incineration). l. AP 368 0009
- 1990 BETZ LABORATORIES. INC. ALL RIGHTS RESERVED, Page 1
1. Refer to Table 1 for the appropriate range and vol-CALIBRATION CURVE PREPARATION umas to use in this procedure. Transfer an aliquot of p e the water sample to a separatory funnel (the sam-Y ple). Transfer the same volume of distilled (or deion-deionized) water. Ized) water to a second separatory funnel (the blank). Run the blank once for each set of samples 2. Pipet designated volumes of the stock solution into tested (see Notes 1,2. and 3). 1 L volumetric flasks. These are the standard solu-tions used in preparing a calibration curve. Use 2. Add CT-1 Buffer Reagent to both the sample and the Table 2 to make appropriate dilutions of the stock dank
- Solution for each specific appilcation.
3. Using a pipet, add 1,2 - dichloroethane to both se-3. Folluw the General Procedure using the specific so-paratory funnels. lution volumes that have been determined for the 4. Insert the stoppers in each of the separatory funnels. application and prepare a calibration curve. Deter-Invert and briefly open the stopcock to vent the fun-mins the absotDance of a blank solution using dis-nels (see Notes 4 and 5). When venting the funnels, tilled (or deionized) water. This blank can be sub-point the tip of the funnel away from yourse4 and tracted from the sample absorbant'e or used to others. zero the spectrophotometer so that the calibration 5. Shake the funnels moderately for 30 sec. vent the curve goes through the origin. The calibration wrve should be linear over tho indicated funnels, then allow them to stand for 10 min (but no ranges. longor than 15 min), 6. Collect the lower layer (1, 2 - dichloroathane) from Table 2. Dilutions for Calibratlon Curve Prepara. each funnel in 50-mL beakers leaving about 1 2 mL tion Based on a Final Solution Volume in the funnel. This will prevent significant removal of of1 L. water. Concentration CT 1 Stock Solo-7. Using the plastic dipper add 2 scoops of Drying Re-CT-1 Desired t!on Added to Make age" to each beaker and stir with a glass rod for 15 (mg/L) 1 L (mL) w- @ut no longer than 30 sec). 0.2 0.2
- 8. Walt approximately 1 to 2 min (but not more than 5 min). Then carefully decant the extract off of the dry-0.4 0.4 Ing reagent into an optical cell.
0.6 0.6 9. Set the spectrophotometer at 415 nm and zero with 8 0.8 1,2 dichloroethane. Measure and record the absor-1.0 1.0 bance of the blank and the sample (see Note 6). 5.0 5.0
- 10. The saniple absorDance minus the blank absor-bance is used to determine the concentration of 10.0 10.0 CT 1 in the sample. From a prepared callb'ation 15.0 15.0 curve, determine the CT-1 concentration in the sam-pie (see Calibration Curve Preparation).
20.0 20.0
- 11. Clean the cells after eae.h measurement 25.0 25.0 (see Note 7).
Table 1. Suggested Volumes for Various Ranges of CT 1. Range Volume Volume Volume Optical ( l CT 1 (mg/L) CT 1 Buffer Dichloroethane Sample Cell Size l (mL) (mL) (mL) 0.2 - 3.0 15 10 250 1.0 cm
- 1.0 25.0 10 30 50 2.5 cm "
l 0.2-1.0 15 O 200 5.0 cm " *
- The1.0.cm cell (Code 1312) can be used with Hach spectrophotometers using a 1-ctn cell adapter (Code 2776C).
" The 'c.5-cm cell is the standard Hach 1 in, cell (Betz Code 2001). k "* Five centimater cells are not available foi use with the Hach photometers. Many laboratory spectropnotometers require an adapter to accommodate 5-cm cells. Check with the instnJment manufacturer AP M8 9o39 Page 2
____.,____-----e----~ ~ ~ ' - - ' ' ' ' ' ' - ~ ' - - -' ?h NOTES 6/ ' 7. It is imperative that the sample cells are kept clean P'gr 1. For maximum accuracy the calibration cunto should during the running et the test. It is recommended that Q. be checked by every operator using this test and the celts are cleaned after each measurement using abould be verifled a minimum of twice per month us-the following procedure: ing a freshly prepared CT1 standard. a) Flinse the ce!! three times with distilled (or 2. A blank measurement (the blank should be a sam, dstonized) wa'er, pie of tf4 svstan water prior to CT l treatment) must be recorded for each set of sam b) Rinse the cell three times with methanol. readingmayvaryslightly;howwer,ples. The blank ti a absolute tilf. forerice between the sample end the blank remains c) Rinse the cell three times with 1,2 dichloro-relatively constant, ethane to remove methanol from the cell.
- 3. Chlorine causes a negative Interference in the test.
8, 1brbidity can interfere with this test proceduro. This can be eliminatto by adding 0.1 N Sodlum Turbidity may: Thiosulfate (Code 235) to the water sample before funning the test. The amount added is based on the e create an emulsion in the 1,2, dichloro-concentration of chlorine in the system. For a ethane layer that does not separate after 100wel. water sample containing 0.3 mg/L chlorine, standing for 10 min when the runnello add 10 drops of 0.1 N Sodlum Thiosulfate to remove shaken' the interference. e create a positive interference. ( A yellow 4. A slight emulsion may form when using natural water color is extracted into the 1.2 dichloro. samples. When this happens, vary step 5 of the ethane layer. ) procedure. Shake the funnel for 30 sec, vent it, then These problems can be removed by centrifuging the allow it to stand for 5 min. Gently invert the funnel sample (10 min at 3500 rpm or 30 min at 2500 rpm) beforre once then allow the funnel to stand for 5 min. performing step 1 of the procedure. _ 5. It is important to vent the separatory furviel both be-9. If you neod to change test conditions (i.e., use differ. fore and af'er shaking it. Otherwise, a pressure wit! ent volumes than those in Table 1), contact the Ana-build up in the funnel that can cause the stopper to tytical Testing and Development Group in Trevose ba forced out of the top of the furviel. for asshtance. i ('( 6. Use caution v.tien inserting or removing the sample
- 10. This metnod ls adapted from Wa,19, L. K.; Langly, D.
cellin the photometer. The 1,2 dichloroethane can damage the cell compartment. F. Ind. Eng. Chem., Prod. Res. Dev., 1975,14,3, 210-212. l l I' Ap ges goog
- 19E10 CETZ LABolIAToRiE3.4NC ALA. RsGHTS RESERVEo.
p g. 3 , - - = ~ - = - ~ ~ ~ ~ ~ ~ ~
~ . AQUATIC LABORATORIES, INC. BORATO i fue l 4x*' SOMEATON ACAD.TAUVCEE.PA 1 DO47.U.SA / TEL 215 355 33CO. TELEX: 173140er3 AX a 355 GG60 Acute Toxicity (LC50's) Clam-Trol CT-1 Marine oreranisma Sheepshead Minnow 96 hr Lc50 = 7.0 mg/L Mysid Shrimp 96 hr LC50 = 1. 4 5 mg/ L C Silverside (Menidia menidi,.g) 96 hr LC50 - 6.0 mg/L Amphipod (Eban93Y.Diga abronius) 96 hr LC50 = 1.24 mg/L m->,m
AQUATIC LABORATORIES, INC. B0 ATORY SOMEATON ACAD.TAnv0SE PA iGO47.U S A / TCL.215 355-33OO tELEN 173140.F AX # 355.G003 Chronic.. Toxicity of _glam-Trol CT-1 to shamhead Minnow A 7-day static rennwal toxicity test was conducted to estimato the chronic toxicity of Clam-Trol to Shoopshead minnow, using newly hatched larvso. The ondpoints of this toxicity test are based on advorno offects on survival and growth. This toxicity test was conducted in accordcnce to EPA protocol "Short-Term Methods for Estimating the Chronic Toxicity of Effluents and Recalving Waters to Marine and Estuarino Organismo, EPA /600/4-87/028." The no observed effect concentration (NOEC) and the lowest cbserved offect concentration (LOEC) to a 7-day exposure to Clam-Trol CT-1 was 5.0 mg/L and 10.0 mg/L respectively. Mortality and Growth of the Shoopshead minnow after a 7 day Chronic Exposurs to Clam-Trol CT-1. CT-1 Concontration Mortality Dry Woich (ma) 7,1gh mtT/L li2AD LL. Banco 0.0 0 1.23 0.09 1.13-1.32 0.62f 2.5 1.14 0.10 1.06-1.24 1.25 2.5 3.35 0.20 1.12-1.53 2.5 0 1.50 0.35 1.17-2.02 5.0 0 1.32 0.11 1.22-1.47 10.0 55 1.03 0.11 0.90-1.13
AQUATIC LABORATOAlES, INC. 0 1A1 11 GCME ATON ACAD.T AHVOGE.PA 1 GOs37.U o A. / 7tiL 21 S.355 3300.TE'.E X: 1731 30 82 AX ** 355 200G t I Chronic Toxigity of Clam-Trol CT-1 to Mvsid Shri_mg A 7-day static renewal toxicity toat was conducted to estimato the chronic toxicity of Clam-Trol to Mysid shrimp, Mvsidong.in kghin, using 7-day old juvenilos. The toxicity tout incorporated chronic and points of survival, growth and reproduction. This toxicity tant van conducted in accordance to EPA protocol "Short-Term Methods for Estimating the Chronic Toxicity of Effluenta and Recuiving Waters to Marine and Estuarino Organismo, EPA /600/4-87/028." The no oboarved effect concontration (NoEC) and the lowest observed affect concentration (LOEC) to 7-day a::posure to Clam-Trol CT-1 is 1.25 mg/L and 2.5 mg/L respectively for survival, growth and reproduction. C Mortality, Growth and Reproduction of the Mysidonsig kahia af ter a 7-day expecure to Clam-Trol CT-1 Avorago Dry Mean Porcentage of Concentration Mortality Weight (ag/L) Fomale with Eggs malD Mnn L CU. UgDD 0.0 0 .461 .097 80 0.32 10 .457 .040 93 0.63 10 .481 .054 98 1.25 5 .463 .071 85 2.50 100 5.00 100 l l L i
r I n[gILSSION OFTilE USE,OF AS1510NIA FOR 11010:}{ IVATERylMN.ll(QL AT CALVERT_CI.lFFS NUCifAR POWER PIANT (NPDESfERN1tT NQJftDf,:91Jtl1 During this NPDES permit cycle, perinission was requested and granted by htDE to use Morpholino for pli control at CCNPP, and there was some question after the prmit was modinct! whether or not Morpholine was to replace Ammonia completely or to be cons dered an alternative option to it. We do bave a need to use Arnmonia in one of the CCNPP units due to a different de rce of tube leakage and the resulting intrusion of salt water and it's huffering effect on pil ad ustment. Samples wrc analyzed for Total Ammonia at cach outfall and the intake waters!.e results are attached. Selected points were tested for ifydrazine and Morpholine as well, as dey could contribute Ammonia as a byproduct. The reference selected to determine if these levels are toxi::is " Ambient Water Quality Criteria for Ammonia F84"(PlVt5 227114). The summary (attached) includes tabulated criteila concentrations as a function of pli and temperature. Usin7, Table B, page 96, as Total Ammonia.1.11 discharge points show Ammonia levels below their respective toxic concentrations, with the exception of MP 103. (Boiler blowdown) and MP 104 (Condensate dcmineralizer regeneration waste). At the extreme end of their pli and temperature range (pil = 9.0+, temperaturo = 35 C) 0 the measured Ammonia concentration of these two discharges exceed the table value of 0.82 mg/l, llowever, discharges at conditions other than the extremes, e.g. pil = 8.5 or h)wer, represent cases where these levels would not be toxic. We request that the use of Ammosia be permitted considering the following: We are not aware of any existing Federal limitations on Ammonia. The data comparison discussed here shows Icvels of concern for fresh water conditions; the water in the Calvert Cliffs area is saline which generally tolerates higher levels before toxicity is exhibited. - A brief poll indicates that North Carolina, South Carolina, Tennessee, and New York do not impose Ammonia limits at their nuclear power plants. North Carolina specifies monthly monitoring, which we suggest as a perinit requirement. h. Wa. (J. D. Warner, Senior Engineer l Environmental Programs Section JDW:sg 1 ..~ m.
l NATIONAL CRITERIA The procedures described in the "Goldelines for Deriving Humerical Nacional Wacer Qualtcy Criteria for the Protection of Aquatic Organisms and Their Uses" indicate chac, except possibly shere a locally importar.c species is very sensitive, freshwater aquatic organisms and their uses should not be t affected unacceptably ift (1) che one-hoJr* average concentration of un-ionized ammonia (in mg/licgr NH ) does not Jxceed, more often chan once every three 3 years on the averste, che neserical value gh en by 0.52/TT/TPH/2, where = 10 03(20-TCAP); TCAP i T 1 30 0 TT 10 03(20-T)
- O i T i TCAP 0
vPU = 1
- 8f,pH19 7
1 + 10 4-PE 1.25
- 6.5 i pH 1 8 U
20 C; Salmonids or other sensitive coldwater species TCAP presenc = 25 C; Salmonids and ocher sensitive coldwater species absenc (*An averaging period of one haut may not be appropriato if excursions of concentracions to greater chan 1.5 cimes the average occur during the hour; in such cases, a shorter averaging period may be needed.) (2) the 4-day average concentracion of un-ionized ammonia (in af/ liter NH ) does noc 4xceed, acre of ten chan once every three years on 3 the average, che average
- numerical value given by 0.80/TT/FPH/ RATIO, vaere FT and TPH are as above and 4
94 i
r-- i RATIO = 16 i 7.? i pH i 9 7 10 7-9H = 24
- 1 + 10 *A*Pg
- 6.5 1 pH i 7.7 I
TCAP = 15 C; salmonids or ocher sensitive coldwater species s present 1 = 10 Ci Scimonias and other sensicive coldwater species absent n (*5ecause these formulas are nonlinear in pH and temperature, the a critation should be the average of separate evaluations of the I formulas reflective of the fluctuations of flow, pH, and temperature within the averaging periodi it is not appropriate in general to simply apply the formula to average pH, temperature and flow.) i The excremes for camperature (0, 30) and pH (6.5, 9) given in the above formulas are absoluce. It is not permissible with current data to condt.at i ; any extrapolations beyond chase limics. In particular, there is reason to ]$ j believe that appropetate criteria at pH > 9 will be lower than the plateau given above between pH 9 and 9. i Cricaria concentracions for the on range 6.5 to 9.0 and the temperature l range O C co 30 C are provided in the following cables. Tocal ammonia l { concentracions equivalent to each un-lonized ammonia concentration are also (- provided in these cables. There is limited data on the ef fect of temperature 4 i on chronic coxicity. EPA will be conducting additional research on the effects of temperacute on ammonia toxicity in order to fill perceived daca Because of this unesttainty, additional site-specific inforuation gaps. should be developed before chase criteria are used in ussteload allocation l modelling. Fot example, the chronic criteria cabulated for sites lacking 95 - - ~ - ~ - - - _. _ _ _. _ _
/ til One-hour everage concentrations for eneont s.' pe OC 30 10 C IS C 20 C 2S C 50 C g Sainwwilds or 0+%ee Seatitive Oold. ster S rocl e, prenant Un-lont red Ammonie (mg/ liter NH 1 3 6.so 0.0091 0.0129 0.0182 0.026 0.036 0.036 0.036 6.73 0.0149 0.021 0.030 J.04 2 0.059 0.059 0.099 7.00 0.023 0.033 0.046 0.066 0.093 0.093 0.093 7JS 0.014 0.048 0.068 0.09 5 0.135 0.135 0.135 7.50 0.041 0.064 0.091 0.128 0.181 0.181 0.181 7.73 0.036 0.080 0.113 0.159 t).22 0.22 0.22 8.00 0.065 % 392 0.150 0.184 0J6 0.26 046 6JS 0.065 0.092 0.130 0.184 0.26 0.26 0.26 8.20 0.06S 0.092 0.13C 0.184 0J6 0J6 0.26 8.73 0.065 0.092 0.130 0.184 0.26 0.26 OJ6 9.00 0.065 0.092 0.130
- 0. 64 0J6 0.26 0.26 Total annonia (mg/ liter NH )
3 6.30 35 33 31 30 29 20 14.3 8.75 32 30 28 27 27 18,6 13.2 7.00 28 26 23 24 23 16.4 11.6 7JS 23 22 20 19.7 19.2 13.4 9.3 7.50 17.4 16.3 13.3 14.9 14.6 10.2 1.3 7.73 12.2 11.4 10.9 10.3 10.3 7.2 S.2 0,04 8.0 7.5 7.1 6.7 6.8 4.8 3.5 8.25 4.S 4.2 4.1 4.0 3.9 2.8 2.1 8.30 2.6 2.4 2.3 2.3 2.3 1.71 148 8.75 1.47 1.40 1.37 1.38 1.42 1.07 0.83 9.00 0.66 0.83 0.8) 0.06 0.91 0.72 0.58 e. talmonido end Otn=e Nel+lve Coldwatee iceclet o b t ea t_ ba-loet ted annonle Ing/Il ter NH ) 3 6.50 0.0091 0.0129 0.0192 0.026 0.036 0.031 0.051 6.7) 0.0149 0.021 0.030 0.042 0.099 0.084 0.084 7.00 0.023 0.033 0.046 0.066 0.093 0.131 0.131 7.25 0.034 0.048 0.068 0.091 0.135 0.190 0.190 7.50 0.043 0.064 0.091 0.12d 0.181 0.26 0.26 7.75 0.096 0.060 0.113 0.199 0.22 0.32 0.32 8.00 0.065 0.092 0.130 0.184 0.26 0.37 0.37 8.25 0.065 0.092 0.130 0.184 046 0.37 0.37 8.50 0.063 0.092 0.130 0.104 0.26 0.37 0.37 8.75 0.065 0.092 0.130 0.18 4 0.26 0.37 0.37 9.00 0.065 0.072 0.130 0.184 046 0.37 0.37 --b:0
- a t m f vt/li ter NH )
3 6.30 33 53 31 30 29 79 20 6.75 32 30 28 27 27 26 18.6 7.00 28 26 23 24 23 23 16.4 7.25 23 22 20 19.7 19.2 19.0 13.5 7.50 17.4 16.3 I S.S 14.9 14.6 14.S 10.3 7.75 12.2 11.4 10.1 10.5 10.3 10.2 7.3 8.00 8.0 7.S 7.1 6.9 6.8 6.8 4.9 8.25 4.5 4.2 8.1 4.0 3.9 4.0 2.9 a.50 2.6 2.4 2.3 2.3 2.3 2.4 1.81 8.75 1,47 1.40 1.37 l.36 1.42 1.52 1.18 9.00 0.86 0.83 0.83 0.86 0.91 1.01 0.02 .n =__
- To convert these values to m0/ liter M, eultiply by 0.822.
96
4 (21 4-day everegs eccentrations for nanonia.' p.* OC 5C to C 15 C i0 C 25 C 30 C A. $aimnlos or Otner Seasl+1ve Cold.eter t eeelen present Ure lont red Amonia (mg/11*er NH3) 6.50 0.0007 0.0009 0.0013 0.0019 0.0019 0.00t9 0.0019 6.75 0.0012 0.0017 0.0023 0.0033 0.0033 0.0033 0.0033 7.00 0.0021 0.0029 0.0042 0.0059 0.0059 0.00!9 0.0059 6 2 7.25 0.0037 0.0052 0.0074 0.0105 0.0105 0.0105 0.0105 1, j 7.50 0.0066 0.0093 0.0132 0.0186 0.')186 0.0186 n.0186 y* 7.75 0.0109 0.0153 0.022 0.031 0.031 0.031 0.031 8.00 0.0126 0.0177 0.025 0.035 0.035 0.015 0.035 .h 8.25 0.0126 0.0177 0.025 0.035 0.035 0.035 0.035 9P 8.50 0.0126 0.0177 0.025 0.035 0.035 0.035 0.035 h 8.75 0.0126 0.0177 0.025 0.035 0.035 0.035 0.335 g 9.00 0.0126 0.0177 0.025 0.035 0.035 0.035 0,035 n IA g-Total Amont a (mg/ll ter NH3) I 6.*0 2.5 2.4 2.2 2.2 1.49 1.04 0.73 ( 6.75 2.5 2.4 2.2 2.2 1.49 1.04 0.73 i 7.00 2.5 2.4 2.2 2.2 1.49 1.04 0.74 7.25 2.5 2.4 2.2 2.2 1.50 1.04 0.74 I-7.50 2.5 2.4 2.2 22 1.50 1.05 0.74 b3 7.75 2.3 2.2 2.1 2.0 1.40 0.99 0.71 7 8.00 1.53 1.44 1.37 1.33 0.13 0.66 0.47 Q 8.25 0.57 0.82 0.78 0.76 0.54 0.39 0.28 8.50 0.49 0.47 0.45 0.44 0.32 0.23 0.17 d, 8.75 0.28 0.27 0.26 0.27 0.19 0.15 0.11 y 9.00 0.16 0.16 0.16 0.16 0.13 0.10 0.08 n. talmnios and Other Sensitive Coldwater species Absag Un-lont red Amonia (mt liter NH ) / 3 ) 6.50 0.0007 0.0009 0.0013 0.0019 0.0026 0.0026 0.0026 t 6.75 0.0012 0.0017 0.0023 0.0033 0.0047 0.0047 J.0047 4 7.00 0.0021 0.0029 0.0042 0.0059 0.0083 0.0083 0.0083 4 7.25 0.00 ', 0.00*2 0.0074 0.0105 0.0148 0.0148 0.0148 f. 7.50 0.0066 0.0093 0.0132 0.0186 0.026 0.026 0.L26 4 7.75 0.0109 0.0153 0.022 0.031 0.04 3 0.043 0.043 8.00 0.0126 0.0177 0.025 0.035 0.0t0 0.050 0.050 8.23 0.0126 0.0177 0.025 0.035 0.050 0.050 0.050 8.50 0.0126 0.0177 0.025 0.035 0.0!0 0.050 0.050 l l 8.75 0.0126 0.0177 0.025 0.035 0.050 0.050 0.050 l 9.00 0.0126 0.0177 0.025 0.035 0.050 0.050 0.050 l Total Amonta (mg/ liter NH ) 3 6.50 2.5 2.4 2.2 2.2 2.1 1.46 1.03 6.75 2.5 2.4 2.2 2.2 2.1 1,47 1.04 7.00 2.5 2.4 2.2 2.2 2.1 1.47 1.04 7.25 2.5 2.4 2.2 2.2 2.1 1.48 1.05 7.50 2.5 2.4 2.2 2.2 2.1 1.49 1.06 7.75 2.3 2.2 2.1 2.0 1.98 1.39 1.00 8.00 1.53 1.44 l.37 1.33 1.31 0.93 0.67 8.25 0.87 0.82 0.78 0.76 0.76 0.54 0.40 8.50 0.49 0.47 0.* S 0.44 0.45 0.33 0.25 8.75 0.28 0.27 2.26 0.27 0.27 0.21 0.16 9.00 0.16 0.16 0.16 0.16 0.17 0.14 0.11 l .~
- To convert these values to mg/ll er N. wit t ply by 0.822.
t Site-speci fic criterla develooment it strongly suggested at 'em our.3 aoove 20 C b, because et the limitM data avellable to generate the criterna re nmendation. and at temperatures below 20 C because of.no limi ted data and bw.ause wasil dienges 'h the criterla may have significant impact on tho level of trae r. cont required in H meeting the recommendeej cri ter i a. 97
~M e t 1 salmonids. are less certain ac temperscures much below 20 C chan chose cabu-laced ac comparacures near 20 C. Where che creatmenc levels needed to meet chose criteria below 20 C may be subscancial, use of site-specific criteria is strongly suggested. Development of such criteria should be based upon sice-specific coxicity cents. Data available for saltwater species are insufficient to derive a criterion for sale water. The recommended exceedence frequency of chree years is the Agenc.y's best scientific judgment of the average amounc of time it will cake an unscressed syscem to cecover from a pollucion event in which exposure to ammonia exceeds the criterion. Scressed systems, for example, one in which several outfalls occur in a limited area, would be expected to recuire more time for recovery. The resilience of ecosystems and choir ability to recover differ greatly, however, and site-specific criceria may be established if adequace justifica-clon is providea. 'the use of criceria in designing vaste creactnent facilities requires the seleccion of an appropriate wascoload allocacion model. Dynamic models are preferred for che appilcation of these cricerla. 1.imited data or other factors may make cheir use impractical, in which case one should rely on a steady-scace model. The Agency recommends the incerim use of IQ5 or IQto for Celterion Maxiuuts Concentration (CMC) design flow and 7Q5 or 7Q10 for che Criterion Continuous Concentracion (CCC) design flow in scandy-scace models for unscressed and screased systems respectively. The Agency acknowledges chac che CCC scream flow averaging period used for sceady-scace vascoload allocacion modelling may be as long as 30 days in situacions involving POTWs designed to remove ammonia where limited variability of ef fluent pollucanc concencracion and resultant concentrations in receiving waters can be 98 1
e - ~ - _. demonstraced. In cases where low variability can be demonstrated, longer averaging periods for the aussonia CCC (e.g., 30-day averaging periods) would be acceptable becsuss the magnitude and duracion of exceedences above che CCC would be sufficiently limited. These macents are discussed in more decall in ( che Technical Support Docuruent for f4acer Qualicy-Based Toxies Control (U.S. ij .) EPA, 1985a). g + l L L1 4 1 i l j! I i e h ce Y ; ,1 l .h l1 : 99 ii IL.
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