ML20084D824

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Ro:On 701020,sodium Pentaborate Solution in Standby Liquid Control Sys Failed to Meet Tech Spec Requirements.Procedures Initiated Requiring Duplicate Sampling & Analysis for Corroboratory Assurance of Monthly Samples
ML20084D824
Person / Time
Site: Dresden Constellation icon.png
Issue date: 11/30/1970
From: Hoyt H
COMMONWEALTH EDISON CO.
To: Morris P
US ATOMIC ENERGY COMMISSION (AEC)
Shared Package
ML20084D827 List:
References
NUDOCS 8304120447
Download: ML20084D824 (2)


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Dr. Peter A. Morris, Director

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SUBJECT:

LICENSE DPR-19 DRESDEN NUCLEAR PO'.!ER STATION UNIT #2, SECTION 6.6.C.1 0F THE TEClGICAL SPECIFICATIONS

Dear Dr. Morris:

This is to report two conditicas relating to the operation of the station in which, during the October and November Surveillance Tests of the Standby Liquid Control System, the sodium pentaborate solution failed to meet the requirements of Section 3.4.C of the Technical Speci-fications.

Problem, Investigation, and Corrective Action During shutdown on October 20, 1970, at 3:20 p.m.,

a sodium pentaborate analysis of the Unit 12 Standby Liquid Control System indi-cated that the sedium pentaborate solution did not meet the requirements of Section 3.4.C of the Technical Specifications.

The reactor was in the shutdown mode from October 13, 1970, at 9:'45 a.m. until October 25, 1970, at 6:45 a.m.

Subsequent Analyses at 3:15 a.m. and at 6:00 a.u. on October 22, 1970, verified the October 20, 1970, analysis.

Tae concentration of the solution was determined to be 11.27. by weight of sodium pentaborate, and the volume which could be injected to the reactor was 3,940 gallons.

The September 30, 1970, sur-veillance analysis indicated a 12.07. solution with an injection volume of 3,990 gallons, which was in compliance with the DPR-19 license.

At 2:00 p.m. on October 22, 1970, a recommendation for chemical addition was made by the Radiation-Chemistry Group.

The chemical addition was initiated at 4:00 p.m. on October 22, 1970, and was completed at 11:00 p.m.

on October 22, 1970.

Af ter recirculation of the tank, analyses of the pentaborate solution at 4:15 a.m. and 5:45 a.m. on October 23, 1970, verified the solution concentration to be 12.97. b weight codium penta-borate, and to have an injection volume of 3,99 gallons.

These results demonstrated comoliance with Section 3.4.C of the Technical Specifications.

8304120447 701130

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y Dr. Peter A. Morris Page 2 November 30, 1970 On November 13, 1970, at 10:50 a.m., sodium pentaborate analysis of the Unit #2 Standby Liquid Control System indicated non-compliance with Section 3.4.C of the Technical Specifications. At this time the penta-borate tank had been on Air Sparge for two hours.

Paired samples were analyzed at 11:50 a.m., 12:50 p.m., and at 2:20 p.m. on November 13, 1970, in a special test to determine the optimum time for air sparge recirculation.

Seven of the eight samples indicated a 12.17. solution and an injection volume of 3,800 gallons. At about 3:00 p.m., a pentaborate tank recirculation pump was placed in operation to determine if this recirculation technique was superior to the air sparge method.

At 10:30 a.m.

on November 14, 1970, the tank was resampled and yielded results similar to those on November 13, 1970.

Following analysis of these samples, the recirculation on pump was shutdown.

The reactor was in a scheduled shut-down mode from 1:30 a.m. on November 14, 1970, until 7:35 p.m. on November 18, 1970. At 6:00 p.n. on November 14, 1970, the Radiation-Chemistry Croup had completed calculations and recommended the addition of chemicals to the tank.

The chemical addition was initiated at,8:00 a.m. on Novem-ber 15, 1970, and was completed by 4:00 p.m. on November 15., 1970.

The recirculation pump was then placed in service until 1:00 p.m. on November 16, 1970.

Samples taken at 8:00 a.m. and at 1:00 p.m. on November 16, 1970, yielded similar results.

The sodium pentaborate concentration was 12.87. and the injection volume was 3,850 gallons which satisfied the requirements of Section 3.4.C of the Technical Specifications.

The corrective action initiated consisted of a procedural review and the development of several specific formulas which are applicable to the various pentaborate concentrations and injection volumes available at the time of sampling.

Further corrective action already initiated requires duplicate sampling and analysis for corroboratory assurance of the monthly l

surveillance samples and the periodic standardization of reagents used in the testing procedure.

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H. K. Hoyt Superintendent HKH:dthe 4

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